TW442919B - Method to form source/drain extension junction by using borosilicate glass in manufacturing CMOS transistor - Google Patents
Method to form source/drain extension junction by using borosilicate glass in manufacturing CMOS transistor Download PDFInfo
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;-4 4 429 Ί 9 ____號咖卿〇2 ___年 月 日 你( 五、發明說明(1) 5 _ 1發明領域: 本發明係有關於一種製造互補式金氧半場效 CMOS)的方法’特別是有關於—種製造互補式金 電晶體使用删石夕玻璃形成一源極/没極延伸接面自 5-2發明背景: 近來,由於巨大型積體電路(ultra Urge integration, ULS I)形成於半導體基板上具有引 半導體技術,.使得在單一晶片上的積體電路密度 ’造成個別元件的尺寸 ’高解析度的微影技術 體技術的革新,有顯著 。然而’未來需要更高 和在電子元件的需求上 一金氧半場效電晶體(m〇sfet) 所::的。一般而言’於-相當薄的閑U 一未摻雜的多晶矽化金屬(p〇lycide); -4 4 429 Ί 9 ____Ca Qing 0 2 _ ___________ (V. Description of the invention (1) 5 _ 1 Field of invention: The present invention relates to a method for manufacturing complementary metal-oxide-semiconductor half field-effect CMOS) The method 'is particularly related to the manufacture of a complementary gold transistor using a cut-out glass to form a source / electrode extension interface. Background from 5-2: Recently, due to the huge Urge integration (ULS) I) The semiconductor technology is formed on the semiconductor substrate, so that the integrated circuit density on a single wafer 'results in the size of individual components' and the high-resolution lithography technology's innovation is significant. However, ‘the future needs to be higher and the demand for electronic components is a metal oxide half field effect transistor (m0sfet). Generally speaking, ′-rather thin free U- undoped polycrystalline silicon silicide (p〇lycide)
PolysUicon)材料,藉以製造金氧 效曰曰曰 晶矽化金屬或多晶矽材料和薄认日日& f政電曰日 電晶體( 乳半場效 丨方法。 積體電路密度增加的結果 增加元件群的密度。近來 性蝕刻技術、及其他半導 藉以達成元件尺寸的減小 度,在半導體製程技術上 附加的要求。 scale 人注目的 增加。此 減小,和 、非等向 的進步, 的電路密 ,以達成 過程是眾 上,放置 ( 。完成多 、4 42 9 1 9 --索號 88〗彳的的_年月日_修正 _ 五、發明說明(2) 植入一摻雜雜質的材料,於閘極導體和源極/汲極區域上 。假如使用摻雜雜質的材料,形成η型的源極/汲極區域, 這樣結果的金氧半場效電晶體稱之為 η型金氧半場效電晶 體元件(η通道)。相對地,假如使用摻雜雜質的材料,形 成一 Ρ型的源極/汲極區域,這樣結果的金氧半場效電晶體 稱之為一 Ρ型金氧半場效電晶體元件(ρ通道)。 使用微影技術(p h 〇 t ο 1 i 1; h 〇 g r a p h y t e c h n i q u e )形成閘 極導體和鄰近的源極/汲極區域。透過一厚的場氧化層, 在窗口出現閘極導體和源極/汲極區域。形成電晶體的那 些窗口,稱之為主動區域(active region)。因此,主動 區域的範圍,介於場氧化層之間。於場氧化層之上,安排 金屬内連線去連接多晶矽閘極導體和源極/汲極區域,藉 以形成一完整的電路結構。 積體電路利用η通道元件、ρ通道元件、或兩者組成的 元件於單一基板之上。當形成兩者型式元件時,基本上元 件必須各別植入不同摻雜雜質的源極/汲極區域。在源極/ 汲極區域植入η型雜質形成一 η通道元件,而在源極/汲極 區域植入ρ型雜質形成一 ρ通道元件,唯一的問題相關於每 一元件。如此增加密度,將使得問題更加惡化。元件發現 不良,可調整製程參數和製程步驟。在大多數的例子之中 ,由於每種型式元件的單一性問題,使得 η通道的製程不 同於ρ通道的製程。首先先討論η通道的製程,接著再討論 ρ通道的製程。PolysUicon) materials, which are used to make gold-oxide effects, are crystalline silicidated metal or polycrystalline silicon materials, and thin-plate solar cells are used in Japan ’s Japanese electric crystal (milk half field effect) method. As a result of the increase in the density of integrated circuits, the density of component groups is increased. .Recent etching technology, and other semiconductors to achieve the reduction in component size, additional requirements on semiconductor process technology. Scale noticeable increase. This reduction, and anisotropic progress, circuit density, In order to achieve the process is the public, put (. Completed more, 4 42 9 1 9-cable number 88〗 彳 _ year month day _ correction _ V. Description of the invention (2) implanting a doped impurity material, On the gate conductor and source / drain region. If an impurity-doped material is used to form an n-type source / drain region, the resulting metal-oxide half-field effect transistor is called an n-type metal-oxide half-field effect Transistor element (η channel). In contrast, if a doped impurity material is used to form a P-type source / drain region, the resulting metal-oxide-semiconductor field-effect transistor is called a P-type metal-oxide half-field effect. Transistor element Channel). Using lithography technology (ph 0t ο 1 i 1; h 〇graphytechnique) to form the gate conductor and the adjacent source / drain region. Through a thick field oxide layer, the gate conductor and source appear in the window The electrode / drain region. The windows that form the transistor are called the active region. Therefore, the range of the active region is between the field oxide layer. Above the field oxide layer, metal interconnects are arranged. The polysilicon gate conductor and the source / drain region are connected to form a complete circuit structure. The integrated circuit uses an η channel element, a ρ channel element, or both components on a single substrate. When forming both In the case of a type element, basically the element must be implanted with different doped source / drain regions. Implanted n-type impurities in the source / drain region to form an n-channel element, and in the source / drain region Implanting a p-type impurity to form a p-channel element, the only problem is related to each element. Such an increase in density will make the problem worse. The component is found to be bad, and the process parameters and process steps can be adjusted. In most cases, the process of the η channel is different from the process of the ρ channel due to the unity of each type of component. The process of the η channel is discussed first, and then the process of the ρ channel is discussed.
第6頁 五、發明說明(3) -ES__88116902 曰 修正 通道元件對於所謂的短通.道效應(short channel e f f ec t)特別敏感。源極和没極區域之間的距離,通常根 據實際的通道長度(phySicai channel length)。然而, 源極和’及極在離子佈植和擴散程序之後,源極和汲極區域 之間的距離變得小於實際的通道長度,此乃稱之為有效通 道長度(effective channel length)。在超大型積體電路 t 4之中’實際的通道變短,使得短通道效應變成一個更 加明顯的問題。 一般而言,短 元件的臨界電壓( (sub-thresho1d 短,則源極和汲極 •端,產生實際的 乏,對於閘極電壓 閘極電荷’去反轉 相對於臨界電壓 此一概念。即使當 間的電流存在於電 通道效應將 threshold current)° 區域相對的 通道區域。 沒有任何影 具有一短的 影響元件的操作,藉以降低 volt age)和增加次臨界電流 像有效通道長度變得十分的 空乏區域可以向前延伸至另 因此,一些通道將部份地空 響。逭結果使得需要較低的 有效通道長度電晶體的通道 的下降,其次臨界電流的流量也應具有 閘極電壓低於臨界量時,源極和汲極之 晶體’具有一相當短的有效通道長度。 然而,增加次臨界電流主要的兩個原因是貫穿(punch through)和沒極導致阻障下降(drain-induced barrier lower ing)。貫穿的結果是源自於寬的汲極空乏區域,當 供給一反向偏壓給汲極井二極體時。汲極電場可能貫穿源Page 6 V. Explanation of the invention (3) -ES__88116902 Modification Channel elements are particularly sensitive to the so-called short channel e f f ec t. The distance between the source and non-polar regions is usually based on the actual channel length (phySicai channel length). However, after the ion implantation and diffusion processes, the distance between the source and the drain region becomes smaller than the actual channel length. This is called the effective channel length. In the ultra-large integrated circuit t 4 ', the actual channel becomes shorter, making the short channel effect a more obvious problem. In general, the short-circuit voltage of a short element ((sub-thresho1d is short, the source and drain terminals will produce a practical shortage, for the gate voltage, the gate charge 'goes to reverse the concept relative to the threshold voltage. Even When the current is present in the electrical channel effect, the current will be in the opposite channel area. There is no effect on the operation of the device with a short influence, thereby reducing the volt age) and increasing the subcritical current like the effective channel length becomes very empty. The area can extend forward to another. As a result, some channels will be partially empty.逭 As a result, the channel of the transistor requiring a lower effective channel length is reduced, and the flow rate of the critical current should also have a gate voltage lower than the critical amount. The source and drain crystals have a relatively short effective channel length. . However, the two main reasons for increasing the sub-critical current are punch through and drain-induced barrier lowering. The result of the penetration is derived from the wide drain empty region when a reverse bias is applied to the drain well diode. The drain field may run through the source
4429 1 9 ---1S_88H6902_年月日 修正_ 五、發明說明(4) 極區域’藉以降低源極至基板接面的位能障。貫穿電流和 基板材料相連於基板表面之下。相對於貫穿電流,汲極導 致阻障下降引起電流幾乎發生在基板表面。一汲極電壓的 應用可能造成基板表面位能下降,這樣的結果在基板表面 具有一較低的位能障,這將造成在通道附近的矽一二氧化 矽表面的次臨界電流增加。一種控制短通道效應的方法, 為增加元件基板的雜質濃度。不幸地,增加基板雜質有害 於確保元件増加位能梯度。 增加位能梯度產生一額外的效應,此效應稱之為熱載 體效應(hot carrier effect)。熱載體效應的現象是藉由 增加載體(電子或電洞)的動能,加速通過大的位能梯度, 接著在閘極氧化層之中變成缺陷。最大的位能梯度通常根 據最大電場,此最大電場發生於接近飽和操作期間。特別 是,在接近通道没極的橫向接面,電場效應更為明顯。 以η通道元件為例,電場產生電子動能於汲極,造成 通道電子打入閘極。電子一電子之間的動能隨機散射,使 得電子變得十分的”熱"。這些熱電子有足夠的能量去產生 電子一電洞對’這將影響矽原子的離子化。當電洞流入基 板產生一基板電流於元件之中,加入通道電子的流量,將 影響離子化產生電子。於元件之中,基板電流第一次創造 出熱載體。以 ρ通道元件為例,除了電洞和電子的角色是 相反的以外,基本的製造過程具有相同的本質。4429 1 9 --- 1S_88H6902_year, month, day, revision_ five. Description of the invention (4) Pole region ’is used to reduce the potential barrier at the interface from the source to the substrate. The through current and the substrate material are connected below the substrate surface. Compared to the through current, the drain causes the barrier to drop and causes the current to occur almost on the substrate surface. The application of a drain voltage may cause the surface potential of the substrate to drop. As a result, there is a lower potential barrier on the substrate surface, which will cause the subcritical current of the silicon-silicon dioxide surface near the channel to increase. A method for controlling the short channel effect is to increase the impurity concentration of the element substrate. Unfortunately, the addition of substrate impurities is detrimental to ensuring the component's puppet energy gradient. Increasing the potential energy gradient creates an additional effect, which is called the hot carrier effect. The phenomenon of heat carrier effect is to increase the kinetic energy of the carrier (electron or hole), accelerate through a large potential energy gradient, and then become a defect in the gate oxide layer. The maximum potential energy gradient is usually based on the maximum electric field, which occurs during near-saturation operation. In particular, the effect of the electric field is more pronounced at the lateral junction near the channel pole. Taking an n-channel element as an example, the electric field generates electron kinetic energy at the drain, causing the channel electrons to enter the gate. The kinetic energy between electrons and electrons is randomly scattered, making the electrons very "hot". These hot electrons have enough energy to generate an electron-hole pair, which will affect the ionization of silicon atoms. When the holes flow into the substrate Generate a substrate current in the element, and add the flow of channel electrons, which will affect the ionization to generate electrons. In the element, the substrate current creates the heat carrier for the first time. Take the ρ channel element as an example, except for holes and electrons. Apart from the opposite roles, the basic manufacturing process has the same essence.
442919 _案號 88116902 曰 修正 五、發明說明(5) 熱載體效應的發生為當一些熱載體射入接近汲極接面 附近的閘極氧化層時,熱載體將破壞閘極氧化層,造成缺 陷的閘極氧化層。一般在閘極氧化層的缺陷將變成電子缺 陷,即使這些電子缺陷在初始時為電洞所填滿。缺陷電荷 累積的時間,將影響η通道元件和ρ通道元件的正臨界漂移 。就我們所知,熱電子的遷移率遠超過熱電洞。在 η通道 元件和 ρ通道元件之中,熱載體效應造成一巨大的臨界斜 率。因此,一 ρ通道元件將經歷負臨界斜率。 除了修正製造電晶體的結構之外,次臨界電流和臨界 漂移的問題,將導致短通道效應和熱載體效應保持原狀。 克服這些問題,必須遵擇任一汲極結構使用雙重擴散的汲 極(D D D )或輕微摻雜的没極(L D D )。上述之兩種型式的結構 具有相同的目的,就是去吸收於汲極之中的一些位能,藉 以降低最大電場。雙重擴散的汲極結構的流行性已讓步給 輕微摻雜的汲極結構,這是因為雙重擴散的汲極會造成不 可接受的深接面和有害的接面電容。 一傳統的輕微摻雜的没極是藉由一低濃度的雜質自行 對準閘極電極,接著於兩已形成的側壁間隙壁之上,藉由 一較高的雜質自行對準閘極電極。接近閘極邊緣的通道, 第一次植入劑量的用途在源極和;:及極兩區域產生一輕微摻 雜的截面。第二次植入劑量的空間,藉由側壁間隙壁的厚 度,植入劑量距通道有一段距離。第一次和第二次植入的 結果,一雜質梯度發生在源極和通道之間的接面,和發生442919 _ Case No. 88116902 Amendment V. Description of the invention (5) The heat carrier effect occurs when some heat carriers are injected into the gate oxide layer near the drain junction, the heat carrier will destroy the gate oxide layer and cause defects. Gate oxide. Defects in the gate oxide layer generally become electron defects, even if these electron defects are initially filled with holes. The accumulated time of the defect charge will affect the positive critical drift of the η-channel element and the ρ-channel element. To our knowledge, the mobility of hot electrons far exceeds that of thermo holes. Among the n-channel element and the p-channel element, the heat carrier effect causes a huge critical slope. Therefore, a p-channel element will experience a negative critical slope. In addition to modifying the structure of the transistor, the problems of subcritical current and critical drift will cause the short channel effect and heat carrier effect to remain intact. To overcome these problems, one must choose to use either a double-diffused drain (D D D) or a lightly doped non-drain (L D D). The two types of structures mentioned above have the same purpose, that is, to absorb some potential energy in the drain to reduce the maximum electric field. The popularity of double-diffused drain structures has given way to lightly doped drain structures because double-diffused drains can cause unacceptable deep junctions and harmful junction capacitances. A conventional lightly doped electrode is self-aligned to the gate electrode by a low-concentration impurity, and then is aligned to the gate electrode by a higher impurity above the two formed sidewall spacers. The channel near the gate edge, the use of the first implant dose produces a slightly doped cross-section in the source and; regions. The space for the second implant dose is a distance from the channel by the thickness of the side wall gap. As a result of the first and second implants, an impurity gradient occurs at the junction between the source and the channel, and occurs
4 429 1 9 案號 88116902 年 月 曰 修正 五、發明說明(6) 在·汲極和通道之間的接面是一樣的 適當地定義輕微摻雜的汲極結構必須具有一最小的熱 敎廄,相太能招生猫林66、:JS扬/ :¾搞雷阻。此外"""_工 載體效應,但不能損失額外的源極/汲極電阻。此外一輕 微摻雜的汲極植入於通道的附近,不幸地加入了電卩旦進^ 源極/汲極路徑。加入的電阻,一般稱之為寄生電阻’把 寄生電阻具有很多有害的效應。首先,寄生電阻可能降低 飽和電流。其次,寄生電阻可能降低整個電晶體的速度° 適當地設計輕微摻雜的源極/汲極,克服上述的問題 ’藉以應用於η通道電晶體和p通道電晶體。然而’ 一種方 法將使用於互補式金氧半場效電晶體(CMOS)製造過程之中 。使用現存之製程技術,製造互補式金氧半場效電晶體。 依據很多現有的製程技術,改善互補式金氧半場效電晶體 ’藉以達成所期望具有低電阻(1 〇 w r e s i s t a n c e)和超歲接 面(ultra shallow junction)的互補式金氧半場效電晶體 5-3發明目的及概述: 繁於上述之發明背景中,提供一種形成低電阻(l〇w resistance)和超淺接面(ultra shallow junction)的互 補式金氧半場效電晶體(CMOS)的方法。此外,典型的互補 式金氧半場效電晶體的結構包含 p型井互補式金氧半場效4 429 1 9 Case No. 88116902 Amendment V. Description of the Invention (6) The junction between the drain and the channel is the same. The lightly doped drain structure must have a minimum thermal chirp. , Xiangtai can enroll Maolin 66,: JS 扬 /: ¾ for thunder. In addition " " " _ carrier effect, but can not lose additional source / drain resistance. In addition, a lightly doped drain is implanted near the channel, which unfortunately adds an electrical source / drain path. The added resistance is generally referred to as parasitic resistance. The parasitic resistance has many harmful effects. First, parasitic resistance may reduce saturation current. Secondly, the parasitic resistance may reduce the speed of the entire transistor. Appropriately designing a lightly doped source / drain to overcome the above-mentioned problems ′ can be applied to n-channel transistors and p-channel transistors. However, a method will be used in the manufacturing process of complementary metal-oxide-semiconductor field-effect transistor (CMOS). Use existing process technology to manufacture complementary metal-oxide-semiconductor half-field-effect transistors. Based on many existing process technologies, the complementary metal-oxide-semiconductor half-effect transistor is improved to achieve the desired complementary metal-oxide-semiconductor half-effect transistor with low resistance (100wresistance) and ultra shallow junction 5- 3 Object and Summary of the Invention: In the background of the present invention, a method for forming a complementary metal-oxide-semiconductor half-field-effect transistor (CMOS) with low resistance and ultra shallow junction is provided. In addition, the structure of a typical complementary metal-oxide-semiconductor field-effect transistor includes a p-type complementary metal-oxide-semiconductor field-effect transistor.
第10頁 Λ 4429 1 9 -----案號88116902_年月日 修正_ 五、發明說明(7) 電晶體(p-we丨i CMOS) ' η型井互補式金氧半場效電晶體 (p-well CMOS)、和雙井互補式金氧半場效電晶體( •t w i η - w e 1 1 c Μ 0 S )。然而’在本實施例中僅詳細描述n型井 互補式金氧半場效電晶體’至於其他兩種互補式金氧半場 效電晶體的結構亦包含在其中。在本實施例中,此製造方 法步驟如下。首先,於一 P型雜質的單晶矽基板之上或之 中’提供一互補式金氧半場效電晶體的區域。然後,於一 P型半導體基板(p-type semiconductor substrate)之中 ’形成一 η型井區域(n-well region)。之後,於p型半導 體基板和一部份的 η型井區域之中,形成一相當深的淺溝 渠隔離(STI),藉以形成一 ρ型金氧半場效電晶體主動區域 (PMOSFET active r e g i ο η )和一 η型金氧半場效電晶體主動 區域(NMOSFET active region)。於ρ型金氧半場效電晶體 主動區域和 η型金氧半場效電晶體主動區域之中,形成一 通道。之後’於ρ型金氧半场效電晶體主動區域和η型金氧 半場效電晶體主動區域之上,形成一閘極氧化層(gate ox i de 1 ay er)。然後’於閘極氧化層之上,沉積一多晶石夕 閘極(po 1 y s i 1 i con gat e)。接著,蝕刻多晶矽閘極和閘 極氧化層,藉以形成ρ型金氧半場效電晶體閘極圖案( PMOSFET gate pattern)於ρ型金氧半場效電晶體主動區域 之上和一 η型金氧半場效電晶體閘極圖案(NMOSFET gate pattern)於η型金氧半場效電晶體主動區域之上。於ρ型金 氧半場效電晶體主動區域和一部份的淺溝渠隔離之上,形 成一第一已定義光阻層。之後,於 η型金氧半場效電晶體 主動區域之中’植入一 η型雜質,藉以形成一輕微摻雜的Page 10 Λ 4429 1 9 ----- Case No. 88116902_Year Month and Day Amendment_ V. Description of the invention (7) Transistor (p-we 丨 i CMOS) 'η-type complementary metal-oxide half field effect transistor (p-well CMOS), and dual-well complementary metal-oxide-semiconductor field-effect transistor (twi η-we 1 1 c M 0 S). However, in this embodiment, only the n-type complementary metal-oxide-semiconductor field-effect transistor is described in detail. As for the structures of the other two complementary metal-oxide-semiconductor half-field-effect transistors, it is also included therein. In this embodiment, the steps of this manufacturing method are as follows. First, a region of a complementary metal-oxide-semiconductor field-effect transistor is provided on or in a single crystal silicon substrate of a P-type impurity. Then, an n-well region is formed in a p-type semiconductor substrate. Then, a relatively deep shallow trench isolation (STI) is formed in the p-type semiconductor substrate and a part of the n-type well region, thereby forming a p-type metal-oxide-semiconductor field-effect transistor active region (PMOSFET active regi ο η). ) And an n-type metal-oxide-semiconductor half-field-effect transistor active region (NMOSFET active region). A channel is formed in the active region of the p-type metal-oxide half-field effect transistor and the active region of the n-type metal-oxide half-field effect transistor. After that, a gate oxide layer (gate ox i de 1 ay er) is formed on the active region of the p-type metal-oxide-semiconductor field-effect transistor and the active region of the n-type metal-oxide-semiconductor field-effect transistor. Then on top of the gate oxide layer, a polycrystalline stone gate (po 1 y s i 1 i con gat e) is deposited. Next, the polysilicon gate and gate oxide layers are etched to form a p-type metal-oxide-semiconductor half-field-effect transistor gate pattern (PMOSFET gate pattern) over the active region of the p-type metal-oxide-semiconductor half-field effect transistor and an n-type metal-oxide half-field The NMOSFET gate pattern is above the active area of the n-type MOSFET. A first defined photoresist layer is formed above the active region of the p-type metal-oxide-semiconductor field-effect transistor and a portion of the shallow trench. After that, an n-type impurity is implanted in the active region of the n-type metal-oxide-semiconductor field-effect transistor to form a lightly doped
第II頁 Λ429 1 9 _案號88116902_年月曰 修正_ 五、發明說明(8) 源極/汲極(lightly doped source/drain)。然後,移除 第一已定義光阻層。於淺溝渠隔離、η型金氧半場效電晶 體閘極圖案、ρ型金氧半場效電晶體閘極圖案、η型金氧半 場效電晶體主動區域、和 ρ型金氧半場效電晶體主動區域 之上,沉積一介電層。於介電層之上,形成一第二已定義 光阻層。之後,於 ρ型金氧半場效電晶體主動區域和一部 份的淺溝渠隔離之上,第一次蝕刻一部份的介電層。然後 ,在一部份的介電層蝕刻步驟期間,於 ρ型金氧半場效電 晶體主動區域之上,形成一補償間隙壁(〇 f f s e t s p a c e r ) 。接著,移除第二已定義光阻層。於一部份的淺溝渠隔離 、ρ型金氧半場效電晶體主動區域、ρ型金氧半場效電晶體 閘極圖案、補償間隙壁、和介電層之上,沉積一棚石夕玻璃 層(B S G 1 a y e r )。然後,融刻一部份的砸石夕玻璃層和第二 次蝕刻一部份的介電層,藉以形成一第一硼矽玻璃間隙壁 (first BSG spacer)和一第二棚石夕玻璃間隙壁(second BSG spacer)。之後,於ρ型金氧半場效電晶體主動區域之. 中,植入一 ρ型雜質,藉以形成一 ρ型重摻雜的源極/汲極 (heavily doped source/drain)。接著,於 η型金氧半場 效電晶體主動區域之中,植入一 η型雜質,藉以形成一 η 1 型重摻雜的源極/汲極。最後,回火第一硼矽玻璃間隙壁 ,於第一硼矽玻璃間隙壁的下方區域擴散硼原子,藉以形 成一源極/汲極延伸接面於一 ρ型金氧半場效電晶體之中。 5-4發明詳細說明:Page II Λ429 1 9 _Case No. 88116902_ Year and month Amendment_ V. Explanation of the invention (8) Lightly doped source / drain. Then, the first defined photoresist layer is removed. In shallow trench isolation, n-type metal-oxide-semiconductor field-effect transistor gate pattern, p-type metal-oxide-semiconductor field-effect transistor gate pattern, n-type metal-oxide-semiconductor field-effect transistor active region, and p-type metal-oxide semi-effect transistor active region Above the area, a dielectric layer is deposited. A second defined photoresist layer is formed on the dielectric layer. After that, a part of the dielectric layer is etched for the first time on the active region of the p-type metal-oxide-semiconductor half field effect transistor and a part of the shallow trench isolation. Then, during a part of the dielectric layer etching step, a compensation gap (0 f f s e t s p a c e r) is formed over the active region of the p-type metal-oxide half field effect transistor. Then, the second defined photoresist layer is removed. On a part of the shallow trench isolation, the active region of the p-type MOSFET, the gate pattern of the p-type MOSFET, the compensation gap, and the dielectric layer, a shed glass layer is deposited. (BSG 1 ayer). Then, a part of the stone crushing glass layer and a part of the dielectric layer are etched for a second time, thereby forming a first borosilicate glass spacer and a second shed glass spacer Wall (second BSG spacer). After that, a p-type impurity is implanted in the active region of the p-type metal-oxide half field-effect transistor to form a p-type heavily doped source / drain. Next, an n-type impurity is implanted in the active region of the n-type metal-oxide-semiconductor half-effect transistor to form a n-type heavily doped source / drain. Finally, the first borosilicate glass spacer is tempered, and the boron atoms are diffused in the area below the first borosilicate glass spacer, thereby forming a source / drain extension junction in a p-type gold-oxygen half field effect transistor. . 5-4 Invention Details:
第12頁 Λ429 1 9 案號 88116902 曰 修正 五、發明說明(9) 一種製造互補式金氧半場效電晶體使用蝴碎玻璃形成 P型金氧半場效電晶體源極/汲極延伸接面的方法,詳細描 述如下。典型的互補式金氧半場效電晶體的結構包含 p型 井互補式金氧半場效電晶體(P-well CMOS)、η型井互補式 金氧半場效電晶體(p-well CMOS)、和雙井互補式金氧半 場效電晶體(t w i η - w e 1 1 C Μ 0 S )。然而,在本實施例中僅詳 細描述 η型井互補式金氧半場效電晶體,至於其他兩種互 補式金氧半場效電晶體的結構亦包含在其中。第一圖至第 八圖的圖式所示,根據本發明之實施例去製造互補式金氧 半場效電晶體流程的截面圖。 依據第一圖的圖式所示,於一 <100 >晶格指向的ρ型單 晶矽基板之上或之中,提供一互補式金氧半場效電晶體的 區域。此ρ型半導體基板(p-type semiconductor subs ΐ ra t e) 1 0具有一濃度大約小於每立方公分1. 0 E 1 5個 原子。然後,形成一 η型井區域(η - w e 1 1 r e g i ο η ) 1 5,使用 磷(P)為一離子源的離子佈植程序,於一能量大約lOOKeV 至2 0 0 KeV之間,植入一劑量大約每平方公分1. 0E 1 2至1. 0 E 1 3之間個原子,接著,使用一驅入(d r i v e - i η )程序於一 溫度大約1 0 0 0度,形成一濃度大約每立方公分 1. 0 Ε 1 6個 原子的η型井區域1 5,於ρ型半導體基板1 0之上。之後,於 Ρ型半導體基板1 0和一部份的η型井區域1 5周圍,形成一相 當深的淺溝渠隔離(ST I ) 2 0,去隔離各元件區域之間的漏 電流,藉以形成一 ρ型金氧半場效電晶體主動區域(Page 12 Λ429 1 9 Case No. 88116902 Amendment V. Description of the Invention (9) A method for manufacturing complementary metal-oxide-semiconductor half-field-effect transistors using butterfly glass to form P-type metal-oxide-semiconductor half-field effect source / drain extension junctions The method is described in detail below. The structure of a typical complementary metal-oxide-semiconductor field-effect transistor includes a p-well complementary metal-oxide-semiconductor field-effect transistor (P-well CMOS), an n-well complementary metal-oxide-semiconductor field-effect transistor (p-well CMOS), and Double well complementary metal-oxide half-field effect transistor (twi η-we 1 1 C Μ 0 S). However, in this embodiment, only the η-type complementary metal-oxide-semiconductor field-effect transistor is described in detail, and the structures of the other two complementary metal-oxide-semiconductor half-field-effect transistors are also included therein. The first to eighth drawings are cross-sectional views of a process for manufacturing a complementary metal-oxide-semiconductor field-effect transistor according to an embodiment of the present invention. According to the diagram of the first figure, a region of a complementary metal-oxide-semiconductor field-effect transistor is provided on or in a p-type single crystal silicon substrate with a < 100 > crystal lattice orientation. This p-type semiconductor substrate (p-type semiconductor subs ΐ ra t e) 1 0 has a concentration of less than about 1.0 E 1 5 atoms per cubic centimeter. Then, an n-type well region (η-we 1 1 regi ο η) 15 is formed, and an ion implantation procedure using phosphorus (P) as an ion source is performed at an energy of about 10 OKeV to 2 0 KeV. Inject a dose of approximately 1.0E 1 2 to 1.0 E 1 3 atoms per square centimeter, and then use a drive-i η procedure at a temperature of approximately 1000 degrees to form a concentration The n-type well region 15 having a diameter of 1.0 0 E 1 per cubic centimeter is above the p-type semiconductor substrate 10. After that, a relatively deep shallow trench isolation (ST I) 20 is formed around the P-type semiconductor substrate 10 and a part of the n-type well region 15 to isolate the leakage current between the element regions, thereby forming Active region of a p-type metal oxide half field effect transistor (
第13頁 ".V 4Λ29 1 9 r_案號88116902 _iL_月 日 修正 五、發明說明(10) PMOSFET active region ) 5 0 0和一砲金氧半場效電晶體主 動區域(NMOSFET active regi〇n)505。於p型金氧半場效 電晶體主動區域5 0 0和η型金氧半場效電晶體主動區域5 〇 5 之中’使用硼(Β )或氟化硼(BF 2)為一離子源的離子佈植程 序,於一能量大約1 0 K e V,植入一劑量大約每平方公分1. 〇 E 12個原子,形成一通道(channel)25。之後,於p型金氧 半場效電晶體主動區域5 0 0和η型金氧半場效電晶體主動區 域505之上,使用熱氧化法(thermal oxidation),此熱 氧化法包含一乾式氧化法(d r y ο X i d a t i ο η )和一濕式氧化 法(wet oxidation),形成一閘極氧化層(gate oxide 1 a y e r) 3 0。然後,於閘極氧化層3 0之上,沉積一多晶石夕閘 極(polysilicon gate)35。使用石夕甲烧(silane)作為一來 源氣體,以低壓化學氣相沉積(LPCVD)技術’於一溫度大 約6 0 0度至6 5 0度之間,形成多晶矽層,其厚度大約為1 0 0 0 埃至2 5 0 0埃之間。接著,蝕刻多晶矽閘極3 5和閘極氧化層 30,藉以形成p型金氡半場效電晶體閘極圖案(PM0SFET gate pattern) 4 5於p型金氧半場效電晶體主動區域50 0之 上和一 η型金氧半場效電晶體閘極圖案(NMOSFET gate pattern)4 0於η型金氧半場效電晶體主動區域50 5之上。 依據第二圖的圖式所示,於 Ρ型金氧半場效電晶體主 動區域 5 0 0和一部份的淺溝渠隔離2 〇之上,形成一第一已 定義光阻層5 0 Α。之後’於η型金氧半場效電晶體主動區域 5 0 5之中,使用靖(Ρ)或砷(A s )為一離子源的離子佈植程序 ,於一能量大約小於 3 0 K e V ’植入一劑量大约每平方公分Page 13 " .V 4Λ29 1 9 r_ Case No. 88116902 _iL_ Month Day Amendment V. Description of the invention (10) PMOSFET active region) 5 0 0 and a shot of metal-oxide-semiconductor half field effect transistor active region ) 505. An ion using boron (B) or boron fluoride (BF 2) as an ion source in the active region 500 of the p-type metal-oxide-semiconductor field-effect transistor and the active region 500 of the eta-type metal-oxide-semiconductor half-field-effect transistor. In the implantation procedure, a dose of about 1.0 OE 12 atoms per square centimeter is implanted at an energy of about 10 K e V to form a channel 25. After that, a thermal oxidation method is used on the p-type metal-oxide-semiconductor active region 500 and the n-type metal-oxide-semiconductor active region 505. This thermal oxidation method includes a dry oxidation method ( dry ο X idati η) and a wet oxidation method to form a gate oxide 1 ayer 3 0. Then, a polysilicon gate 35 is deposited on the gate oxide layer 30. Using silane as a source gas, low-pressure chemical vapor deposition (LPCVD) technology is used to form a polycrystalline silicon layer at a temperature of about 600 to 650 degrees, with a thickness of about 10 0 0 Angstroms to 2 500 Angstroms. Next, the polysilicon gate 35 and the gate oxide layer 30 are etched to form a p-type gold-alloy half-field-effect transistor gate pattern (PM0SFET gate pattern) 4 5 above the p-type metal-oxide half-field-effect transistor active region 50 0. And an n-type metal-oxide-semiconductor half-field-effect transistor gate pattern (NMOSFET gate pattern) 40 above the n-type metal-oxide-semiconductor half-field-effect transistor active region 505. According to the diagram in the second figure, a first defined photoresistive layer 50 A is formed above the active region 500 of a P-type metal-oxide-semiconductor field-effect transistor and a portion of the shallow trench isolation 200. Afterwards, in the active region of the η-type metal-oxide-semiconductor field-effect transistor 5 05, an ion implantation procedure using Jing (P) or arsenic (A s) as an ion source is performed at an energy of less than 30 K e V 'Implant a dose approximately
第14頁 ___案號 88116902 五、發明說明(11) 年月曰_修正Page 14 ___ Case No. 88116902 V. Description of Invention (11)
1. 0E 14至5. 0E 15之間個原子,形成一 rr型輕微摻雜的源 極 /没極(lightly doped source/drain)50。然後,移除 第一已定義光阻層50A。1. 0E 14 to 5. 0E 15 atoms to form a lightly doped source / drain 50 of rr type. Then, the first defined photoresist layer 50A is removed.
依據第三圖的圖式所示,於淺溝渠隔離 2 0、η型金氧 半·%效電晶體閘.極圖案4 0、 ρ型金氧半場效電晶體間極圖 案45、η型金氧半場效電晶體主動區域 5 0 5、和d型金氧半 場效電晶體主動區域 50 0之上,沉積一介電層60’此介電 層60包含一二氧化石夕層(siiiC0I1 oxide layer)、一氣化 石夕層(silicon nitride layer)、或一氧化石夕/氮化石夕層 (silicon oxide/silicon nitride layer)。其沉積方法 與條件如下。在沉積二氧化矽層時,使用正矽酸乙酯( TE0S)作為一來源氣體,以低壓化學氣相沉積(LPCVD)技術. ’於一溫度大約5 0 0度至8 0 0度之間,沉積二氧化矽層,其 厚度大約5 0埃至 3 0 0埃之間。在沈.積氮化矽層時,使用低 壓化學氣相沉積(LpCVD)技術,於一溫度大約75〇度,沈積 氮化梦詹’其厚度大約50埃至3 0 0埃之間。在沈積氧化破/ 氮化破層時’使用低壓化學氣相沉積(LPCVD)技術,於_ 溫度大約5 0 〇度至8 〇 〇度之間,沈積氧化矽/氮化矽層,其 厚度大約1 0 0埃至3 〇 〇埃之間。 依據第四圖的圖式所示,於介電層60之上,形成一第 二已疋義光阻層60A。之後’於p型金氧半場效電晶體主動 區域500和—部份的淺溝渠隔離20之上,使用CHF作為蝕 刻劑的反應性離子蝕刻(R I E )技術,第一次蝕刻一部份的According to the diagram in the third figure, a 20, η-type metal-oxide-semiconductor half-efficiency transistor gate is isolated in a shallow trench. A pole pattern of 40, ρ-type metal-oxide-semiconductor half-effect transistor pattern 45, η-type gold On top of the active area of the oxygen half field effect transistor 505 and the active area of the d-type metal oxide half field effect transistor 50 0, a dielectric layer 60 'is deposited. The dielectric layer 60 includes a siiiC0I1 oxide layer ), A silicon nitride layer (silicon nitride layer), or a silicon oxide / silicon nitride layer. The deposition method and conditions are as follows. During the deposition of the silicon dioxide layer, TEOS was used as a source gas, and low pressure chemical vapor deposition (LPCVD) technology was used. 'At a temperature of about 500 degrees to 800 degrees, A silicon dioxide layer is deposited to a thickness of about 50 angstroms to 300 angstroms. When depositing a silicon nitride layer, a low-pressure chemical vapor deposition (LpCVD) technique is used to deposit a nitrided nitride Mg ’s at a temperature of about 75 ° C and a thickness of about 50 angstroms to 300 angstroms. When depositing oxide / nitride layers, using low pressure chemical vapor deposition (LPCVD) technology, a silicon oxide / silicon nitride layer is deposited at a temperature of about 500 ° to 800 ° 100 angstroms to 300 angstroms. According to the diagram in the fourth figure, a second photoresist layer 60A is formed on the dielectric layer 60. After that, on the p-type metal-oxide-semiconductor field-effect transistor active region 500 and a portion of the shallow trench isolation 20, a reactive ion etching (R I E) technique using CHF as an etchant was used to etch a portion of the first
第15頁 V 4 429 1 9 __案號 88116902 - !_Λ..曰 絛正 _ 五、發明說明(12) 介電層6 0。然後,在一部份的介電層6 0蝕刻步驟期間,於 Ρ型金氧半場效電晶體主動區域5 0 0之上,形成一補償間隙 壁(offset spacer)65。接著’移除第二已定義光阻層60Α 依據第五圖的圖式所示’於一部份的淺溝渠隔離2 0、 P型金氧半場效電晶體主動區域500、p型金氧半場效電晶 體閘極圖案4 5、補償間隙壁6 5、和介電層6 0之上,使用常 壓化學氣相沉積(APCVD)技術、低壓化學氣相沉積(LPCVD) 技術、或電漿輔助化學氣相沉積(PEC VD)技術,沉積硼矽 玻璃層(BSG layer)70,其厚度大約5 0 0埃至20 00埃之間。 沈積的蝴碎玻璃層7 0,包含一蝴劑量大約百分之一至百分 之十之間。 依據第六圖的圊式所示,使用CHF3作為蝕刻劑的反應 性離子领刻(R I E )技術’敍刻一部份的领矽玻璃層7 〇和第 二次姓刻一部份的介電層6 0 ’藉以形成一第一硼石夕玻璃間 隙壁(f i r s t BSG spacer ) 7 5和一第二硼矽玻璃間隙壁 (second BSG spacer)80 。 依據第七A圖的圖式所示,以第一區域光阻5i 1覆蓋η 型金氧半場效電晶體主動區域5 0 5,然後在ρ型金氛半場效 電晶體主動區域5 0 0之中,執行使用硼(Β)或氟化硼(Β]ρ2) 作為p型.佈植離子5 1 2的離子佈植程序,藉以形成—p+型重 摻雜的源極/ 汲極(heavi ly doped source/drain ) 85,在Page 15 V 4 429 1 9 __ Case No. 88116902-! _Λ .. Said Zheng Zheng _ V. Description of the invention (12) Dielectric layer 60. Then, during a part of the dielectric layer 60 etching step, an offset spacer 65 is formed on the P-type metal-oxide-semiconductor field-effect transistor active area 500. Then 'remove the second defined photoresist layer 60A according to the diagram of the fifth figure' to isolate a part of the shallow trench 20, P-type metal-oxide-semiconductor field-effect transistor active region 500, p-type metal-oxide-semiconductor half-field Effect transistor gate pattern 4 5. Compensating spacers 6 5 and dielectric layer 60. Using atmospheric pressure chemical vapor deposition (APCVD) technology, low pressure chemical vapor deposition (LPCVD) technology, or plasma assist The chemical vapor deposition (PEC VD) technology deposits a borosilicate glass layer (BSG layer) 70 with a thickness between about 500 angstroms and 20,000 angstroms. The deposited butterfly glass layer 70 contains a butterfly dose between about one and ten percent. According to the formula in the sixth figure, a reactive ion collar etch (RIE) technique using CHF3 as an etchant is used to 'etch a part of the collar silica glass layer 70 and a second part of the dielectric is etched. The layer 60 ′ forms a first borosilicate glass spacer (first BSG spacer) 75 and a second borosilicate glass spacer (second BSG spacer) 80. According to the diagram in FIG. 7A, the first region photoresist 5i 1 is used to cover the active region of the n-type metal-oxide-semiconductor field-effect transistor 5 0 5 and In the process, an ion implantation procedure using boron (B) or boron fluoride (Β) ρ2) as the p-type implanted ion 5 1 2 is performed to form a -p + -type heavily doped source / drain (heavi ly doped source / drain) 85, in
第16頁 V 4 429 1 9 _ΕΒ_8«Ι16902_ 五、發明說明(13) 2 2 Ϊ :子的t量大約1KeV至8〇KeV之間,而其植入劑量 ΐ::1,15至UE 16之間個原子。之後: ΐI:所示二般Λ移除第一區域光阻511並形成第二區域光 :?型’氧半場效電晶體主動區域5 0 0上’然後在 ΛΓί效電晶體主動㈣5 0 5中’執行使用-(ρ)或坤 S為η型佈植離子5 1 4的離子佈植程序,藉以形成—η + 型重換雜的源極/沒極9 〇,在此離子的佈植能量大約小於 1 0 K e ¥至8 0 K e V之間,而其佈植劑量則大約每平方公分^〇 E 1 5至1. 〇 E 1 6之間個原子,。 依據第八圖的圖式所示’回火第一硼矽玻璃間隙壁7 5 ,使用一快速熱製程(RTP),於—溫度大約95〇度至1〇5〇度 之間,擴散一硼原子於第一硼矽玻璃間隙壁75的下方區域 ’其時間大約1 0秒至6 0秒之間。藉以,於一 p型金氧半場 效電晶體之中’形成一源極/汲極延伸接面(s〇urce/drain extension junction ) 100° 以上所述僅為本發明之較佳實施例而已,並非用以限 定本發明之申請專利範圍;凡其它未脫離本發明所揭示之 精神下所完成之等效改變或修飾,均應包含在下述之申請 專利範圍内。Page 16 V 4 429 1 9 _ΕΒ_8 «Ι16902_ V. Description of the invention (13) 2 2 Ϊ: The amount of t in the child is between about 1 KeV and 80 KeV, and its implantation dose is ΐ :: 1, 15 to UE 16 Between atoms. After: ΐI: shown in the two general Λ remove the first area photoresist 511 and form a second area light:? -Type 'oxygen half field effect transistor active area 50 0' and then in ΛΓ effect transistor active ㈣ 5 0 5 'Implement an ion implantation procedure using-(ρ) or Kun S as the η-type implant ion 5 1 4 to form a -η + -type re-transformed heterogeneous source / dimer 9 〇, where the ion implantation energy It is less than about 10 Ke e ¥ to 80 Ke V, and its implantation dose is about 15 to 1. OE 16 atoms per square centimeter. According to the diagram in the eighth figure, 'Tempering the first borosilicate glass partition wall 7 5 uses a rapid thermal process (RTP) to diffuse a boron at a temperature of about 95 ° to 1050 °. The time period of the atoms in the region below the first borosilicate glass spacer 75 is about 10 seconds to 60 seconds. Thereby, forming a source / drain extension junction (100 °) in a p-type metal-oxide-semiconductor half-field-effect transistor is only a preferred embodiment of the present invention. It is not intended to limit the scope of patent application of the present invention; all other equivalent changes or modifications made without departing from the spirit disclosed by the present invention shall be included in the scope of patent application described below.
第17頁 4 429 1 9 _案號88116902_年月日__ 圖式簡單說明 第一圖至第八圖的圖式所示,根據本發明之實施例去 製造互補式金氧半場效電晶體流程的截面圖。 要部分 之代表符號: 10 P型半導體基板 15 η型井區域 20 淺溝渠隔離 25 通道 30 閘極氧化層 35 多晶梦閘極 40 η型金氧半場效電晶體閘極圖案 45 ρ型金氧半場效電晶體閘極圖案 50 輕微摻雜的源極/汲極 50A 第一已定義光阻層 60 介電層 60A 第二已定義光阻層 65 補償間隙壁 70 硼矽玻璃層 75 第一硼矽玻璃間隙壁 80 第二硼矽玻璃間隙壁 85 Ρ +型重摻雜的源極/汲極 90 η +型重摻雜的源極/没極 100 源極/汲極延伸接面 500 ρ型金氧半場效電晶體主 動 區域 505 η型金氧半場效電晶體主 動 區域Page 17 4 429 1 9 _Case No. 88116902_Year Month Date __ Schematic illustrations The diagrams in the first to eighth figures are shown. According to the embodiment of the present invention, a complementary metal-oxide-semiconductor field-effect transistor is manufactured. A cross-sectional view of the process. Main symbols: 10 P-type semiconductor substrate 15 η-type well area 20 Shallow trench isolation 25 Channel 30 Gate oxide layer 35 Polycrystalline gate 40 η-type metal-oxide-semiconductor field-effect transistor gate pattern 45 ρ-type metal oxide Half field effect transistor gate pattern 50 Lightly doped source / drain 50A First defined photoresist layer 60 Dielectric layer 60A Second defined photoresist layer 65 Compensation barrier 70 Borosilicate glass layer 75 First boron Silica glass spacer 80 Second borosilicate glass spacer 85 P + -type heavily doped source / drain 90 η + -type heavily doped source / inverted 100 source / drain extension junction 500 ρ type Active region of metal oxide half field effect transistor 505 Active region of η type metal oxide half field effect transistor
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