TW399034B - Method of manufacturing sintered body whose capillary mineral has evenly mixed texture and a large volume plane style and apparatus for its manufacture - Google Patents

Method of manufacturing sintered body whose capillary mineral has evenly mixed texture and a large volume plane style and apparatus for its manufacture Download PDF

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Publication number
TW399034B
TW399034B TW086105257A TW86105257A TW399034B TW 399034 B TW399034 B TW 399034B TW 086105257 A TW086105257 A TW 086105257A TW 86105257 A TW86105257 A TW 86105257A TW 399034 B TW399034 B TW 399034B
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Taiwan
Prior art keywords
shaped
soil
needle
middle ring
same direction
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TW086105257A
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Chinese (zh)
Inventor
Hideo Ikami
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Clay Burn Ceramics K K
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/12Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein one or more rollers exert pressure on the material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/20Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein the material is extruded
    • B28B3/22Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein the material is extruded by screw or worm
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/16Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
    • C04B35/22Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in calcium oxide, e.g. wollastonite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/52Constituents or additives characterised by their shapes
    • C04B2235/5208Fibers
    • C04B2235/5216Inorganic
    • C04B2235/522Oxidic

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Oxide Ceramics (AREA)
  • Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)
  • Finishing Walls (AREA)

Abstract

The present invention is to reinforce the texture with capillary mineral and establish the condition under which the large volume plane style sintered body having evenly mixed texture just as it has been proved that the sintered body in which the capillary mineral has texture evenly oriented in one direction the orientation is also a very important factor in principle of high molecule or metallurgic material. In order to strengthen the orientation of capillary mineral inside pot earth, wollastonite containing <beta>-CaO.SiO2 as material which has aspect ratio over 20. As to method of manufacture, it adopts a method which does not apply rigidity from its when pressing the pot earth with anger machine. Also the apparatus is developed and used which can rotate freely the rotor bearing of the extruding portion of the anger machine, strengthen the orientation of the capillary mineral, and make the best of orientation using a re-twisting roller. As a result, the flexural strength becomes twice the prior art.

Description

經濟部中央樣準局系工消费合作社印31 A7 B7 五、發明説明(I ) [發明所鼷之技術領域] 本發明係有關改菩陶瓷質堍結體最大缺點之「朦弱性」 ,而欲製造具有彌性之大形建築用陶瓷瓷磚之技術者。 並且,有蘭將在這些技術領域之先行技術,經大幅度改 菩之强性陶瓷瓷磚。 [先行技術] 有關本發明之先行技術由本發明人所發明之專利係具 有;日本專利第1366443號,日本專利第1576834號,日 本專利第154970號,及將上述日本專利向外國提出申請 而獲准之美國專利4,495,118,西德專利3,313,596,英國 專利2,317,552,澳洲專利541 ,735,而已經由瑄些技術廣 泛地進行工業生產。若將上述先行技術之主要者摘要說 明就是如下。 1)第1先行技術 日本專利第1366443號(日本特願昭54-129476號.日本 特公昭61-30887)之内容,係將拌土狀可塑性陶瓷原料_ 組成物欲Μ板狀從吹口(mouthpiece)拔出成形時,夾住 於向輥輪中央部互相相反方向具有進給之螺旋狀之表胃 溝之一對或複數對輥輪之間輥軌組成物步驟之板狀陶瓷 成形體之成形方法。亦即,從拌土吠可塑性陶瓷之原料 組成物成形爲板狀陶瓷成形體時,將成為大缺點從吹□ 之拔出流動阻力引起之内部密度差之分布或將因粒子之 取向性之一定方向性,成為全體而言成為具有均句品質 内部姐绷之成形賭之成形方法之技術。 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) n-^^i ^»1 - —II I - n^— ml 1^1 ml ^^^1 — I - - n —^ϋ —I I (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消费合作社印裝 Α7 Β7 五、發明説明(&gt;) 2 )第2先行技術 日本專利第1576834號(日本特顳昭第56-174528,曰本 待公平1-60403)之内容,你一種陶瓷板之製造方法,其 特德[為;從成形機拔出之剖面為打開具有曲線之筒狀胚 料成為板狀胚狀,将該板狀胚料棍軋成與從上述成形機 之拔出方向同一方向之後經過乾燥,為了上述拔出方法 可以變成搬蓮方向使用滾筒嫌床窯(roller hearth 燒成。茚即,有蘭陶瓷板之製造方法,尤其有效率地製 造面積寛廣而薄型之陶瓷板方法之技術。 3 &gt;第3先行技術 日本專利第1584970號(日本特願昭59-39374,日本待 公平1-59231)之内容傜如下; (1) 包含彡-CaO· Si02及天然之雲母族礦物而呈藥Η狀 之素片或結晶含有60重量3;以上.,其中,至少30重量J:為 /5 -CaO· Si〇2,並且,燒結成莫氏硬度(Mohs hardness) 5以下為其待激之優於切削特性之陶瓷燒結體(以下將 ;8-CaO· Si02稱為元件1,而含有雲母族礦物將板狀或 葉Η狀之素片或結晶稱為元件2)。並且, (2) —種優於加工性之陶瓷燒結體及其製造方法,其待 傲為;含有上述元件1含有莫氏硬度5以下之原枓類及元 件2,而莫氏硬度5以下之原料類中將1種類以上以燒 结體為基本,上述元件1與元件2之合計變成6〇重量1 以上,其中,摻配成至少30重量X為變成iS-Ca〇. Si02 ,破碎混合調整約略留存上逑板狀或葉片狀之素Η或結 本紙張尺度適用中國國家標準(CNS ) Α4規格(210Χ297公釐) ---;--^---.--裝---Κ--Γ 訂------線 -* V. (請先閲讀背面之注意事項再填寫本買) 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明(3 ) 晶原形之原形,而經遇成形後,在1200PM下燒结成莫 氏硬度5以下而只約略保有上述原形程度之技術。 [發明所欲解決之問題] 上述各種先行技術係,將本發明目的之大形建築用陶 瓷瓷磚之脆弱性變成更小,並且,充分具有彈性所需, 遢不充分。若將其等就各先行技術加Μ指摘就是如下。 1) 第1先行技術係將可塑性陶瓷原料使用拌土機拔出形 成為圓筒狀時,因位於吹口中心之心型(core)藉固定於 主螺旋軸之中環支持軸Μ剛性地支撐,所Κ,碰到存在 於變成软泥狀原料内部之细長片反而具有其取向發生紊 亂之問題。又,此先行技術,係只Κ 一般存在於陶瓷原 料組成物之扁平结晶粒子做為對象,所Κ,原枓本身之 選擇具有變成不充分之問題。 2) 第2先行技術係,從拌土機拔出之茼吠胚料打開變成 板狀胚料,向同一方向輥軋,而燒成為拔出方向變成搬 運方向之方法,但是,由於剛性之心型袖而會發生取向 紊亂之趨向所Μ不充分。又,原料本身之選擇係,並沒有 特別進行,所Μ,做為大形薄壁之陶瓷燒結體之製造方 法,尚具有不充分之問題。 3) 第3先行技術其目的為優於切削加工性之陶瓷燒结體 與其製造方法,此方法並不一定可製造尺寸變形極小之 大形平板狀陶瓷燒结體。又,此先行技術係關於在拌土 步驟之拌土原料中之细長物之取向,並沒有採取特別之 手段,所Μ做為上述大形平板狀燒结體之製造具有不充 本吹適用中國固家標牟(CNS ) Α4規格(210Χ297公釐) ----.-------' ------、1T------^ (請先閱讀背面之注意事項再填寫本頁) 經濟部中央標準局負工消費合作社印製 A7 B7 五、發明説明(4 ) 分之問題。 再做具體說明時,於日本專利第158 49 70號,属於本 發明主元件之/S-CaO*Si〇2 ,亦即,靥於針狀结晶礦 物之矽灰石,係雖然約略相同者,但是,本發明之目的 係,製造優於切削加工性之陶瓷燒结體為其目的,利用 矽灰石特有之莫氏硬度為其特擞,並且,如一般陶瓷質 即使沒有生成玻璃相也可獲得充分高強度之特徵者,尤 其關於矽灰石之排列取向,並沒有加Μ考慮之發明。並 且,日本專利第1567 8 3 4號,係琨在,採用於工業生產, 而被採用於薄而大形尺寸之陶瓷瓷磚之製造技術,所Μ ,從真空拌土機拔出圓曲線狀,使用軋輥輥輪向拔出方 向軋輥之方法,國外專利,也成為這些製造方法之基本 ,但是,於本發明,通常關於一般之陶瓷原料之锻帶狀 结晶礦物之高峨石(kaolinnite)之取向之持激為其目的 ,做為燒结體之強度提升效果為少,而K減少不良率之 效果做為其目的。如上述,本發明之目的係,鼷於針狀 结晶礦物之矽灰石之结晶為具有$同一方向均勻地取向排 列之組绷之燒结體,製造在強度與彈性上具有特徵之製 品者。如上述日本鲁利第I576834號之高嶙石之结晶取向 係,在從胚料到乾煉及700t:程度之不上釉之燒成階段時 ,雖然會呈規缎帶狀之结晶體取向之效果,但是,若超 遇800¾時就被脫水而變成無定形狀態,但是,矽灰石中 之針吠之/S-CaO· Si〇2形者,係有肋益於保持到12001C 附近之燒結體之補強姐織。又,依據許多實驗與如高嶙 -6- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) (請先閲讀背面之注意事項再填寫本頁) 裝. k 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明(r ) 石之砍锻帶狀之结晶相異,靨於強针狀原料之矽灰石, 做為可塑性之坏土組成物加Μ推壓流動時就容易取向, 但是,若變成不均匀之取向時就會發揮強大形狀記憶性 而容易發生變形。在此就先行技術之裝置要點說明如下 。第3圖係,先行技術之真空拌土機之排出側半部之說 明圖。由設於外腼1中之主螺旋袖5之螺旋6而坏土 7 將被向左向押出。通過在上述外胴1被剛性固定之中環 支持框8間,通過在上述中環支持框8再被剛性固定之 中環铀3 Κ被剛性固定之中環2之周圍與上述外胴1之 間,坏土 7從吹口 14押出。中環軸3及中環2係受到剛 性固定,所Μ,坏土 7中之針狀结晶9係,碰到這些而 發生取向之紊亂。 因而,本發明係,消除上述各先行技術之問題,各種 缺點,所開發之更加新穎手段,又加上技術之進步,就有 鼷這些發明,期待更強強度等之性能提升效果,具有將 鼷於針狀结晶磺物之矽灰石取向排列之姐織之大形平板狀 之燒结體為其目的者。因此,欲達成本發明目的之關鍵 係,必須解決如何將潛在應變少而均勻取向排列在製造 工廠之各個條件下達成這一點。 換言之,其目的係首先創作出先行技術不能製造之超 大形薄壁板狀陶瓷燒结體,而一併提供其製造方法與裝 置。 [解決問題之手段] 本發明係為了解決上述目的獨創開發了 Μ下之手段。 -7- 本紙張尺度適用中《家鏢攀(CNS &gt; Α4規格(210X297公釐) ---Τ------- 裝------訂------妒· (請先閲讀背面之注意事項再填寫本頁)Printed by the Central Bureau of Standards, Ministry of Economic Affairs, Industrial and Consumer Cooperatives 31 A7 B7 V. Description of the Invention (I) [Technical Fields Invented by the Invention] The present invention relates to the "faintness" of the biggest shortcomings of the modified ceramic body. Technicians who want to manufacture large-scale architectural ceramic tiles. In addition, Youlan will advance the technology in these technical fields, and greatly change the strength of the ceramic tiles. [Advanced technology] The advanced technology related to the present invention is owned by the patents invented by the present inventor; Japanese Patent No. 1366443, Japanese Patent No. 1576834, Japanese Patent No. 154970, and the above-mentioned Japanese patents were granted to foreign countries for application and approval U.S. Patent 4,495,118, West German Patent 3,313,596, British Patent 2,317,552, Australian Patent 541,735, have been extensively industrially produced by these technologies. The summary of the main technologies of the above-mentioned prior art is as follows. 1) The content of the first advanced technology Japanese Patent No. 1366443 (Japanese Patent Application No. 54-129476. Japanese Patent Application No. 61-30887) is to mix clay-like plastic ceramic material _ the composition is to be plate-shaped from the mouthpiece Method for forming a plate-shaped ceramic formed body sandwiched between one or a plurality of pairs of roller-shaped surface grooves having a spiral-shaped surface sulcus having a feed toward the central part of the roller in a direction opposite to each other during the pull-out forming . That is, when forming a plate-shaped ceramic molded body from a raw material composition of a plastic clay that is mixed with clay, it will become a major disadvantage. The distribution of the internal density difference caused by the flow resistance from the blowout or the certain orientation of the particles will be constant. Directionality has become the forming technique of forming gambling with uniform internal quality. This paper size applies to China National Standard (CNS) A4 (210X297 mm) n-^^ i ^ »1-—II I-n ^ — ml 1 ^ 1 ml ^^^ 1 — I--n — ^ ϋ —II (Please read the precautions on the reverse side before filling out this page) Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Consumer Cooperatives, printed A7 Β7 V. Description of Invention (&gt;) 2) Second Advanced Technology Japanese Patent No. 1576834 (Japanese special Temporary Zhao No. 56-174528, said to be fair 1-60403), a method of manufacturing a ceramic plate, its Ted [is; the section pulled out from the forming machine is to open the cylindrical blank with a curve into a plate This plate-shaped blank is rolled into the same direction as the drawing direction from the forming machine, and then dried. In order to change the drawing method, it can be turned into a lotus direction using a roller hearth kiln. Indene That is, a method for manufacturing a ceramic plate with blue, particularly a method for efficiently manufacturing a ceramic plate with a large area and a thin area. 3 &gt; The third leading technology Japanese Patent No. 1584970 (Japanese Patent Application No. 59-39374, Japan to be The contents of Fair 1-592923 are as follows; (1) Contains 彡 -CaO · Si02 and sky The mica group minerals are in the form of medicine tablets or crystals containing 60 weight 3 or more. Among them, at least 30 weight J: / 5 -CaO · Si〇2, and sintered to Mohs hardness 5 or less is a ceramic sintered body which is better than the cutting characteristics to be excited (hereinafter, 8-CaO · Si02 is referred to as element 1, and plate-shaped or leaf-shaped plain pieces or crystals containing mica group minerals are referred to as element 2 ). And, (2) — a ceramic sintered body superior in processability and a method for manufacturing the ceramic sintered body; the above-mentioned element 1 contains the original slag and element 2 having a Mohs hardness of 5 or less, and the Mohs hardness is 5 In the following raw materials, more than one type is based on a sintered body, and the total of the above-mentioned element 1 and element 2 becomes 60 weight 1 or more. Among them, at least 30 weight X is blended to become iS-Ca. Si02, broken Mixing adjustments to retain approximately the top plate or leaf-shaped plain or final paper size applicable to China National Standard (CNS) A4 specifications (210 × 297 mm) ---;-^ ---.-- pack- -Κ--Γ Order ------ line- * V. (Please read the precautions on the back before filling in this purchase) A7 B7 printed by the company V. Description of the invention (3) The original shape of the crystal original shape, and after being formed, it is sintered at 1200PM to a Mohs hardness of 5 or less, and only slightly maintains the above-mentioned original shape degree technology. Problem] The above-mentioned various prior art systems reduce the vulnerability of ceramic tiles for large buildings, which is the object of the present invention, and have sufficient elasticity, which is insufficient. If they are equal to each prior art plus M accusation, it is as follows. 1) In the first advanced technology, when a plastic ceramic material was pulled out using a soil mixer and formed into a cylindrical shape, the core (core) located at the center of the mouthpiece was rigidly supported by a ring support shaft M fixed to the main spiral shaft. Κ, encounters the problem that the elongated sheet existing inside the raw material that becomes a slime has disordered orientation. In addition, this prior art only uses flat crystal particles, which are generally present in the ceramic raw material composition, as a target, so the choice of the raw material itself becomes insufficient. 2) The second advanced technology is that the bark bark material pulled out from the soil mixer is opened to become a plate-shaped bar material, rolled in the same direction, and burned into a method in which the direction of extraction is changed to the direction of conveyance. However, due to the rigidity of the heart The tendency of the sleeves to cause disordered orientation is insufficient. In addition, the selection of the raw material itself is not particularly carried out. Therefore, as a method for manufacturing a large-shaped thin-walled ceramic sintered body, there is still an insufficient problem. 3) The third advanced technology is aimed at ceramic sintered bodies superior to machinability and its manufacturing method. This method does not necessarily produce large flat ceramic sintered bodies with extremely small dimensional deformation. In addition, this advanced technology is about the orientation of the slender objects in the soil mixing material in the soil mixing step, and no special measures are taken. Therefore, the manufacture of the large flat plate-shaped sintered body described above is not sufficient for China. Gujia Mou (CNS) Α4 specification (210 × 297 mm) ----.------- '------, 1T ------ ^ (Please read the precautions on the back first (Fill in this page again.) A7 B7 printed by the Consumers' Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs. To make specific explanation, in Japanese Patent No. 158 49 70, / S-CaO * Si〇2, which is the main component of the present invention, that is, wollastonite pinched in a needle-shaped crystalline mineral, although it is about the same, However, the object of the present invention is to produce a ceramic sintered body that is superior to machinability, and use the Mohs hardness unique to wollastonite as its characteristic. In addition, it can be used as ordinary ceramics without forming a glass phase. Those who obtain sufficiently high strength characteristics, especially regarding the arrangement and orientation of wollastonite, have not considered the invention. In addition, Japanese Patent No. 1567 8 3 4 is used in industrial production, and is used in the manufacturing technology of thin and large-sized ceramic tiles. Therefore, the circular curve shape is pulled out from the vacuum mixer. The method of using the rollers to roll in the direction of extraction, foreign patents have also become the basis of these manufacturing methods. However, in the present invention, it is generally related to the kaolinnite of forged band-shaped crystalline minerals of general ceramic raw materials. Persistent orientation is the purpose, and the effect of improving the strength of the sintered body is small, while the effect of reducing the defect rate by K is the purpose. As described above, the object of the present invention is to manufacture crystalline sintered bodies of wollastonite acicular crystalline minerals into a group of sintered bodies having a uniform orientation in the same direction, and to manufacture products having characteristics in strength and elasticity. For example, the crystal orientation of the high vermiculite of Japanese Luli No. I576834 mentioned above, during the firing stage from the raw material to the dry smelting and the 700t: degree of enamel, although the crystal orientation of the regular ribbon-like Effect, however, if it exceeds 800¾, it will be dehydrated and become amorphous, but the needle bark / S-CaO · Si〇2 shape in wollastonite is ribbed and it is beneficial to maintain the sintering near 12001C The body reinforces sister weaving. In addition, according to many experiments and such as Gao Gao-6- this paper size applies Chinese National Standard (CNS) A4 specifications (210X297 mm) (please read the precautions on the back before filling this page). K Central Standards Bureau of the Ministry of Economic Affairs Printed by employees' consumer cooperatives A7 B7 V. Description of the invention (r) The crystalline shape of chopped and forged stone is different, and the wollastonite, which is strong needle-shaped raw material, is used as a plastic bad soil composition plus M to push and flow. Orientation is easy, but if it becomes an uneven orientation, it will exhibit strong shape memory and easily deform. The main points of the prior art device are explained below. Fig. 3 is an explanatory diagram of a discharge side half of a prior art vacuum soil mixer. The bad soil 7 will be pushed out to the left by the spiral 6 of the main spiral sleeve 5 provided in the outer sleeve 1. The outer ring 1 is rigidly fixed between the middle ring support frame 8 and the middle ring support frame 8 is further rigidly fixed between the middle ring uranium 3 κ and the middle ring 2 is rigidly fixed between the outer ring 1 and the outer ring 1. 7 Extruded from the mouthpiece 14. The central ring axis 3 and the central ring 2 series are rigidly fixed. Therefore, the needle-like crystal 9 series in the bad soil 7 encounters these and the orientation disorder occurs. Therefore, the present invention eliminates the problems and disadvantages of each of the prior arts described above, and develops more novel means, coupled with technological advancements, and has these inventions. Expect performance enhancement effects such as stronger strength. The large flat plate-shaped sintered body woven by the sister of wollastonite oriented in needle-shaped crystal sulfonate is the object. Therefore, in order to achieve the purpose of the invention, it is necessary to solve how to arrange the uniform orientation with less potential strain under various conditions in the manufacturing plant to achieve this. In other words, the purpose is to first create an ultra-thin, thin-walled, plate-shaped ceramic sintered body that cannot be manufactured with prior technology, and to provide its manufacturing method and device together. [Means for Solving the Problem] The present invention has developed a means for solving the above-mentioned problems. -7- The standard of this paper is applicable to "Home Dart Climbing (CNS &gt; Α4 Specification (210X297mm) --- T ------- Install -------- Order -------- Envy · (Please read the notes on the back before filling this page)

第1 ,本發明之針狀結晶礦物爲在同一方向具有取向 (請先閲讀背面之注意事項再填寫本頁) 排列組織之大形平板狀燒晶體之特徵爲,均質地含有將觸 於針状結晶礦物之召-CaO* Si02&amp;無水換算成爲30〜70 重量%,與將黏土及滑石之一般陶瓷質物以無水換算均質 地被包含在內,上述針狀結晶確物向同一方向均勻地取向 排列而成形成所需形狀,而在1000〜1250°C之溫度範圍內 加以燒結。 經濟部智慧財產局員工消費合作社印製 第2,本發明之針狀結晶礦物具有向同一方向取向排列之 組織之大形平板狀燒結體之製造方法之特徽爲,含有沒-Ca0*Si02之針狀結晶礦物之原料,該針狀結晶長度爲Irani 以上,而幅形比爲將20以上之矽灰石以無水換算成30〜 70重鼉%,與將可塑膠性之黏土質原料以無水換算爲60〜30 重量%,做爲取向性改良之疏水性潤滑材之滑石爲10〜20 重鼉%與,視其需要,將從長石,陶石,黏土熟料(法 chamotte)所選擇之1以上之一般陶瓷用原料添加0〜30 〔重童%〕,並調整爲合計1〇〇〔%〕,並加水使含水率爲14 〜20〔重量%〕,加以均質化調整,將可塑狀態之坏土,使 用真空拌土機裝置,押出爲圃筒狀,其後,將其切開展 開成爲板狀,在與擠出方向同一方向使用輥軋輥輪成形爲 所需之厚度大小之板狀胚料,接著,乾燥該板狀胚料之 後,在1000〜1250°C之溫度範圍內燒成。 第3,本發明之針狀結晶礦物爲具有向同一方向取向排 列之組織之大形平板狀燒結體之製造方法之下列特徵爲, 上述之真空拌土機裝置爲,在出口之押出壓力爲15〜 -8-本紙張尺度適用中國國家標準(CNS &gt; A4規格(210X297公釐) 經濟部中央標準局貝工消費合作社印装 A7 B7 五、發明説明(7 ) 30kg/Ci/ ,該真空拌土機中之外胴與保持中環所構成之 吹口之軸及軸承為與該真空拌土機之主嫘旋軸之迴轉絕 緣,並且,中環作由於坏土之流動阻力而自主地迴轉位 移提升坏土中之上述針狀结晶之取向性,並且,將圓筒 狀成形體之厚度自動地調整後,切斷展開上述圓筒胚料 成為平板狀而與押出方向同一方向所成形之胚料使用輥 钆輥輪以加輥軋。 第4,本發明之針狀结晶礦物為具有向同一方向取向排 列之組缃之大形平板吠燒结體之製造方法之另一特徵為 ,將上述被成形之胚料使用輥軋輥輪進行輥軋之方法為 對於最初輥軋之輥輪,係為了復原為由於真空拌土機主 嫘旋之旋轉所發生之曲線狀之取向組織,邊給與相反方 向之扭力進行輥軋具有螺旋狀溝之一對輥輪加Μ輥軋之 後,Μ後經過數段之輥軋步驟輥軋成所需厚度大小之板 狀胚料者。 第5係,本發明之針狀结晶確物為具有向同一方向取 向排列之組纈之大形平板狀燒结體之製造方法之特徴為 ,壓送收容於近似圓筒形外胴之坏土之主嫘旋,與迴轉 該主螺旋軸之電動機,與將該坏土送入於上述之螺旋內 ,設於上述近似圓筒形之外胴上部端之戽斗,與設於上 述近似圓荷形外胴内之真空室,與中環支持軸與中環, 與具有將在該真空室排除空氣之坏土押出之吹口之真空 拌土櫬,在上述主螺旋軸與中環支持軸之接合部,防止 坏土洩漏之中環軸承般,在該中環袖承殻内部,裝設裝 本紙張尺度適用中國國家標準(CNS ) Α4爱籌(2丨0&gt;&lt; 297公釐) —ρ 訂 ~~ .&quot; (請先閲讀背面之注意事項再填寫本頁) 經濟部中央標準局貝工消费合作社印製 A7 B7 五、發明説明(ί ) 有絕緣剛性之止推軸承之中環軸承,中環粬與中環依照 坏土之流動柔砍地動作,而具有含有坏土中之針狀结晶 為向同一方向沒有阻力取向功能之裝置。 接著,有闞上述本發明各特擞,具體地說明如下。將 先行技術係一般陶瓷瓷磚或磚瓦類,使用真空拌土機進 行濕式柙出成形時之基本問題,係從古由文獻由學問上 也被解析。又,對於這些對策之專利也有許多已被知曉 ,但是,被旋轉之螺旋壓送坏土,透過規定吹口成形之 製程,連黏土之柔軟之髙嶙土之结晶物被取向時之加壓 力之潛在應變會留下,做為形狀記憶性乾燥或燒成時被 復原便其成為高不良率。又,成形吹口之形狀為四角形 時,由於吹口内壁部與中心部之摩擦阻力之差距而被押 出之速度發生差距,尤其在模具內壁部,發生渦流而變 成很紊亂之取向組織,係依據文獻已變成常識。上述之 日本專利第1 576834號,係良這些事項,改成為圓筒狀 之吹口所改良者,但是,經過數年之製造經驗即使於胚 料也會發壁厚之差時,依經驗成為潛在應變而存留下來 ,致使不良率偏高,於本發明,如(申請專利範圍第3項) 所示,進行成形吹口及周邊設備之改良研究所發明者。 然而,這些係只改良吹口時,由於旋轉螺旋所發生之螺 旋狀之取向,變成潛在應變而乾燥,燒成後復原者,所 M,如(申請専利範園第4項),輥輪輥軋時,設置將第一 次之輥軋輥輪由於拌土機之旋轉所發生之「螺旋狀之取 向j扭回之溝使其復原為均勻而獲得具有正確取向之胚 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) ----1--.--- 种衣------11------i (請先閱讀背面之注意事項再填寫本頁) 一 A7 B7 經濟部中央標準局貝工消費合作社印製 五、發明説明( 1 ) 1 1 料 而 發 明 了 再 另外 以上之方法 〇所 以 將 (申請專利範圍 1 1 第 1 項 )所示之組成物原料之含有率界限限定為上述, 乃 1 I 若 矽 灰 石 為 303!以下時,就不能獲得充分之取向,補強 請 Ί 效 果 9 又 * 若 超過 7〇χ時,就欲谋足押出或棍軋成形之 先 閲 1 ·. I 1 條 件 之 可 塑 性 坏土 之物性變成 困難 所 致 〇 背 1 又 f 黏 土 質 原料 之含有率傜 ,於 可 塑 性坏 土 之條 件 範 之 注 | 意 I 圍 j 若 良 質 而 可塑 性高之黏土 時, 雖 然 少也 可 以, 但 是 举 項 1 再 1 1 9 在 3〇 χ以下時,就不能獲得滿足條件之原料, 若超過 填 1 60% 時, 乾燥就需要花時間,而降低生産生所致。滑石 本 頁 裝 1 像 需 要 103:〜2 0J:之 範圍所致。 可塑 性 黏 土, 由 拌土 機 加 1 1 壓 流 動 9 欲 將 針狀 結晶變成容 易取 向 時 ,就 需 要具 有 潤 1 | 滑 劑 功 能 之 原 料, 雖然對於石 墨, 雲 母 等疏 水 性之 原 料 1 進 行 研 究 9 但 是, 對於針狀結 晶物 以 容 積比 率 ,若 不 佔 訂 I 約 3 οχ 時, 就不能獲得充分之效果所致&lt;» 又, 視其需要 1 I 所 加 之 長 石 f 陶石 ,黏土熟料 類僳 對 應 於製 品 之生 産 要 1 1 求 時 加 以 選 擇 ,或 加以取代來 調整 組 成 物所 需 者。 並 且 1 1 9 於 為 了 達 成 這些 目的之諸條 件下 9 若 將真 空 拌土 機 之 、'旅 I 押 出 壓 力 所 以 定為 15〜30kg/c nf , 乃 若 壓力 超 過30 1 1 kg/c η〜 1時, 由於潛在應變之復原不充分所致〇 又, 若1 5 1 I k g/ c nf 以 下 時 由於 不耐於棍軋 成形 體 時 所發 生 之剪 斷 應 1 I 力 所 致 〇 [發明之實施形態] I U 就 本 發 明 之實 施形態參照 圖面 詳 述 如下 〇 首先 9 於 丨 第 1圖, 外 胴 1 係配 置於真空拌 土機 (圓示從略) 先端 者 在其 吹 Ρ 1 4 之 部 位 配置 在中環2。接,在中環2外 -1 1 - 周 與外 胴 1 1 1 1 1 本紙張尺度適用中國國家標準(CNS &gt; A4規格(210 X Μ -蠼) 經濟部中央標準局員工消費合作社印製 A7 B7五、發明説明(β ) 之吹口 14内周之間設定有間隙。中環2係為了減低滑動 阻力由塑膠材料所構成,而如圖不形成為維狀。支持中 環2之中環軸3係由設於中環軸承殼4内之滾珠軸承4a 樞支其基端側,同時,由止推袖承4b進行止推支持。按 ,嵌著中環軸承殺4之密封蓋4c來防止坏土之侵入,以 保護滾珠軸承4a及止推軸承4b。又,中環袖3係由直徑 8〜1 5 m m之彈簧網所構成,而可容易發生彈性變形。另一 方面,在中環紬承殻4連结有裝設螺旋6之主螺旋軸5。 由Μ上之構造,藉主螺旋軸5之迴轉而由螺旋6押出 之可塱性坏土係邊旋轉外胴1内被送給,在中環軸承殻 4之部分一部分為變成渦流狀態,而取向變成紊亂,其 後,在吹口 14部分,再次進行取向,但是,基本全體而 言在螺旋狀之取向組織從吹口 14.部分押出。按,在吹口 14部分若胚料壁厚發生偏差時,狹隘部分就變快,而寬 廣部分之速度變慢,在數秒鐘自動地調整流動。此調整 係由中環袖3之彈性變形進行。 於第2圖,輥軋前胚料10係如第1圖所示由真空拌土 機押出而切開,展開坏土成為平板狀者,由螺旋6對於 輥軋前坏土形成針狀之和媛嫘旋狀之針狀结晶9。此輥 軋前胚料10係由具有與上述螺旋類相反方向溝之輥軋輥 輪對12加Κ輥軋。輥軋輥輪12之溝11其深度為約2mm寬 度為4〜5mm者Μ 20〜30mB之節距排列所成。由輥軋輥輪 對12所輥軋之平板10係由輥軋輥輪對12之溝11矯正其针 狀结晶9而加Μ扭回,而變成具有約略排列成筆直取向 -12- (請先閱讀背面之注意事項再填寫本頁) 裝- *1Τ 乂 本紙張尺度適用中國國家標準(CNS ) Α4規格(210'〆297公釐) 經濟部中央標準局員工消費合作社印聚 A7 B7 五、發明説明(”) 之輥軋胚料13。按,在第2圖雖然將輥軋輥輪對12成為 一段者,但是,當然也可以使用具有二段,三段之扭回 溝之附溝輥輪加Μ輥軋。 (實施例) 玆就本發明之超大形薄壁陶瓷燒结板依據下列各條件 實施製造之實施例說明如下。 1) 使用原料 矽灰石:美國HYCO公司G级60〜40(網目) 中國產矽灰石 60〜40 (網目) 鈷土 :本山木節等级品 滑石 :中國產滑石 250 (網目)以下 長石 :蘇打長石 250(網目)以下 2) 坏土之調整 將秤稱為規定摻配率之乾燥粉末投入於混合碾碎機 (mix muller),混合10分鐘之後,外加水分20Χ再混合 授拌10分鐘成為可塑性拌土。 3) 圓筒生產 切開,展開直徑250mm(外)壁厚25nm成為寬度720〜 730mm,厚度25mm,長度300mm之輥?L前之生產板,以上 述之輥軋輥輪對12做一次輥軋,並且Μ平面輥輪進行輥 軋成為厚度5βιπ,寬度700mm,長度約1500ββ之胚料平板。 4) 乾燥及素燒 乾燥係使用瘪紅外線照射處理5分鐘之後,而後使用 網目皮帶乾燥機經過50分鐘乾燥到350t:,持缜使用滾简 本紙張尺度適用中國國家標準(CNS ) A4規格(210X297公釐) Ί Ί I 訂 (請先閲讀背面之注意事項再填寫本頁) A7 B7 五、發明説明(《&gt; ) 爐床窯燒成到1150TC之溫度。由Μ上之胚料平板之接配 率,吸水率,強度等之特性表示於表1。 [表1 ] 慘配率,吸水率,強度等之特性 試料 矽灰石 (美國產) % 滑石 % 黏土 % 長石 % 吸水率 % 彎曲特性 kg/cnf ' 彈性係數 cgf /c# 本發明品 Nol 50 10 40 一 12.5 565 35 χ 1〇4 先行技術 品 No2 10 40 50 6.3 310 80 ΧΙΟ4 I m n·——— - - —L n — I n^i · (請先閲讀背面之注意事項再填寫本頁) 經濟部中央橾準局貝工消费合作社印裝 如Μ上之結果所示,對於鼷於针狀结晶礦物之砂灰石 之強度及彈性特性之效果為極大,如H〇2所示先行技術 之一般陶瓷組成物係吸水率為本發明之約1/2之極為胃 结性良好之先行技術品做比較鸾曲強度為較本發明品;^ Hoi係較先行技術品N〇2大到1.7〜1.8倍,尤其本發明品 之彈性特性將變小,嘵得了具有先行技術之2倍Μ上之 彈性。又,Hoi之本發明品也沒有因取向之不均勻引起 之變形等,較先行技術可獲得無可比擬之薄而大形之陶 瓷瓷《。按,接著瑄些實胞例進行最大寬度1 200mm長度 3000»b,厚度4bb之超大形板之生產。 [發明之效果] 如Μ上所詳述,本發明之效果係如下地具有飛躍性顯 著,且甚大者。 -1 4 - 本紙张尺度適用中國國家標準(CNS ) Α4規格(2丨0X297公釐) &quot; &quot;~~— - -、I5J—II I - 111 I t —i -..... - - 11 *·- 0S I ^^1 - · 經濟部中央標準局員工消費合作社印製 A7 B7 五、發明説明(*〇 (1)於做為建築用資材被世界性地廣泛使用之陶瓷瓷 磚之領域,胞工工法之近代化,帷幕猜(curtain wall) • 等之大形平板化之合理化,或社區建築物之污染或「霉菌」 等之問題也由於生活環境之變化要求因應之對策,所Μ ,各廠家係盛行著尺寸之大型化與輕量化為目的之研究 。但是,由於輕量化變薄,而增大尺寸時就會發生「陶 瓷」最大缺點之「脆弱性」。本發明係於這些問題遠超過 先行技術之「陶瓷j之常識具有高弾性(與石棉板相等) ,而圼現劃時代之物性。此係,完成了世界之陶瓷廠家 堪沒有達成之寬度1.2η,長度3m而厚度為4πιβ之大形陶瓷 瓷磚之實用化者,首先,可舉出技術上獲得了大幅度之 進步之效果。 (2) 以上述之寬度1.2m,長度3m,約略完全去除脆弱性之 缺點之大形薄壁陶瓷板係,因其長度為3.0m,剛好高樓 大腹之1樓分,其高度可由一張貼,所K,具有壁面之 施工費可特別更宜之很大經濟效果。 * (3) 本發明係先行技術之混凝土板等相異,因原本就有 卓越防水性,所K也不需要張貼防水層,與4mm之薄,其 重量也與先行技術所沒有者而最輕,無論鋼骨大廈,或 混凝土大魔,連設計上,柱,樑,基礎就其分量可達成 減重,所M,構造物全體之經濟效果將變成甚大。 圖式之簡單說明 第1圖係本發明之坏土中之針狀结晶取向功能增大裝 置之剖面說明圖。 -15- 本紙張尺度適用中國國家標準(CNS ) A4規格(210X 297公釐) .^1- In - — I 士又 I - - I i - -- - - «^^1 XV • * 、? (請先閱讀背面之注意事項再填寫本頁) 399034 A7 B7 五、發明説明(4) 第2匾係本發明之坏土中之針狀结晶取向作用之說明 圖,(a)係平面園,(b)係側面圖。 第3圖係先行技術之拌土機坏土押出裝置之剖面說 明圖。 [符號之說明] 1真空拌土機之外胴 4中環軸承骰, 4 c密封蓋, 7坏土, 1 0輥軋前胚料, 1 3輥軋胚料, 2中環, 4a滾珠軸承 5螺旋軸, 8中環支持框 11溝, 14吹口。 3中環軸, 4b止推軸承, 6 螺旋, 9 $十狀结晶, 1 2輥軋輥輪對, (請先閱讀背面之注意事項再填寫本頁) 裝.First, the needle-like crystalline mineral of the present invention has an orientation in the same direction (please read the precautions on the back before filling this page). The large flat-shaped sintered crystals of the arranged structure are characterized by homogeneous inclusion that will touch the needle-like shape. The call of crystalline minerals-CaO * Si02 &amp; anhydrous conversion into 30 ~ 70% by weight, and it is included in the ordinary ceramic material of clay and talc in an anhydrous conversion. It is uniformly aligned in the same direction. It is formed into a desired shape and sintered in a temperature range of 1000 to 1250 ° C. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs. The special emblem of the manufacturing method of the large slab-shaped sintered body with the needle-shaped crystalline minerals of the present invention having a structure aligned in the same direction is that containing -Ca0 * Si02. Raw material of acicular crystalline mineral. The length of the acicular crystalline mineral is Irani or more, and the aspect ratio is 30 to 70% by weight of wollastonite converted from anhydrous to 30% by weight. It is converted into 60 to 30% by weight. The talc used as the hydrophobic lubricant with improved orientation is 10 to 20% by weight. If necessary, it will be selected from feldspar, pottery, and clay chamotte. Add 1 to 30 [wt.%] Of general ceramic raw materials above 1 and adjust to a total of 100 [%], add water to make the moisture content 14 to 20 [% by weight], and adjust by homogenization to make it plastic. For the bad soil, use a vacuum mixer device to extrude it into a cylindrical shape, and then cut it into a plate shape, and use a rolling roller to form a plate-shaped embryo of the required thickness in the same direction as the extrusion direction. Material, then, drying the plate-shaped embryo After firing, it is fired in a temperature range of 1000 to 1250 ° C. Third, the acicular crystalline mineral of the present invention is a manufacturing method of a large flat sintered body having a structure aligned in the same direction. The above-mentioned vacuum mixer device has an extrusion pressure of 15 at the outlet. ~ -8- This paper size applies Chinese National Standards (CNS &gt; A4 size (210X297mm), printed by the Central Standards Bureau of the Ministry of Economic Affairs, Shellfish Consumer Cooperative, printed A7 B7 V. Description of the invention (7) 30kg / Ci /, the vacuum mix The shaft and bearing of the mouthpiece formed by the outer ring and the middle ring of the earthmoving machine are insulated from the rotation of the main shaft of the vacuum soil mixer, and the middle ring acts as a self-rotating displacement due to the flow resistance of the bad soil. The orientation of the needle-like crystals in the soil, and after the thickness of the cylindrical shaped body is automatically adjusted, the cylindrical blank is cut and unfolded into a flat shape, and the blank that is formed in the same direction as the extrusion direction uses a roll.钆 Roller rolls are rolled up. Fourth, the acicular crystalline mineral of the present invention is a method for manufacturing a large-shaped plate bark sintered body having a group of 缃 aligned in the same direction. The method of rolling the blank with rolling rollers is to roll the rollers that were initially rolled in order to restore the curve-like orientation structure caused by the rotation of the main scroll of the vacuum mixer. Torque rolling is performed by rolling a pair of rollers with a spiral groove and rolling by M. After M, rolling through several stages to roll into a plate-shaped blank with a desired thickness. 5th series, the needle of the present invention The crystalline solid is a method for manufacturing a large flat sintered body having a group of vales aligned in the same direction. The main process of pressure feeding the bad soil contained in an approximately cylindrical outer body is to rotate the The motor of the main screw shaft, the bucket that feeds the bad soil into the above-mentioned spiral, is set at the upper end of the above-mentioned approximately cylindrical outer ring, and the vacuum chamber is provided inside the above-mentioned approximately round-shaped outer ring, and The middle ring support shaft and the middle ring, and a vacuum soil mixer with a blow-out port for evacuating bad soil from the air in the vacuum chamber. At the joint between the main screw shaft and the middle ring support shaft, the middle ring bearing is prevented from leaking. The inner sleeve housing is fitted inside The paper size of this paper applies the Chinese National Standard (CNS) Α4 Love Chip (2 丨 0 &gt; &lt; 297 mm) — ρ order ~~. &Quot; (Please read the precautions on the back before filling this page) Central Standard of the Ministry of Economic Affairs Printed by Bureau Coconut Consumer Cooperative A7 B7 V. Description of the invention (ί) Insulating rigid thrust bearing middle ring bearing, the middle ring and the middle ring softly chop the ground according to the flow of bad soil, and have a needle shape containing bad soil The crystal is a device that does not have a resistance orientation function in the same direction. Next, there are the features of the present invention described above, and the details are as follows. The prior art is a general ceramic tile or tile type, and is wet-extracted using a vacuum mixer. The basic problems in forming are also analyzed from ancient literature and knowledge. Many patents for these countermeasures have been known. However, the soil is pressed by the rotating spiral pressure, and the process is formed by a prescribed mouthpiece. The latent strain of clay's soft ocher crystals will be left behind when it is oriented. As a shape memory, it will be recovered when it is dried or fired, and it will become a high defect rate. In addition, when the shape of the molding mouthpiece is a quadrangle, the speed of being extruded varies due to the difference in frictional resistance between the inner wall portion of the mouthpiece and the center portion. Especially in the inner wall portion of the mold, vortex occurs and becomes a very disordered oriented structure. Has become common sense. The above-mentioned Japanese Patent No. 1 576834 is related to these matters, and has been improved by a cylindrical mouthpiece. However, after several years of manufacturing experience, even if the thickness of the blank is different, it will be based on experience. Potential strains are left behind, resulting in a high defect rate. In the present invention, as shown in (Patent Application Scope 3), the inventor of the Research Institute for the Improvement of Forming Nozzles and Peripheral Equipment. However, when these nozzles only improve the mouthpiece, due to the helical orientation of the rotating helix, it becomes a potential strain and is dried. It is recovered after firing. Therefore, (for example, (applied to Yuli Fanyuan No. 4)) At the time of setting, the "spiral orientation j twisted back ditch" caused by the rotation of the soil mixer for the first time is set to restore the uniformity to obtain the embryo paper with the correct orientation. The Chinese paper standard is applicable ( CNS) A4 size (210X297mm) ---- 1 --.--- Seed coat ------ 11 ------ i (Please read the precautions on the back before filling this page) A7 B7 Printed by the Shellfish Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. 5. Description of the invention (1) 1 1 and invented the above method. Therefore, the composition materials shown in (Scope of application for patent 1 1 item 1) will be used. The content rate limit is limited to the above, but it is 1 I. If wollastonite is 303! Or less, sufficient orientation cannot be obtained. Reinforcing please Ί Effect 9 and * If it exceeds 7〇χ, it is necessary to seek out or roll. Read Before Forming 1 ·. I 1 The physical properties of the plastic bad soil become difficult. 背 1 and f The content rate of the clay material is too high. Note on the conditions of the plastic bad soil. | I I j If the clay is of good quality and high plasticity, it may be less. However, if the item 1 and 1 1 9 are less than 30 ×, the raw materials that meet the conditions cannot be obtained. If it exceeds 160%, it will take time to dry and reduce the production. Talc on this page 1 image Requires the range of 103: ~ 2 0J :. Plastic clay, 1 1 pressure flow from the soil mixer 9 To make needle-like crystals easily oriented, you need raw materials with lubricant function | Although graphite Hydrophobic raw materials such as mica 1 are studied. 9 However, if the volume ratio of acicular crystals does not account for about 3 οχ, sufficient effects cannot be obtained. &Lt; »Also, 1 I Addition of feldspar f pottery, clay clinker Production of articles selected to add to 11:00 request, or be substituted into the composition to adjust required by the group. And 1 1 9 Under the conditions for achieving these purposes, 9 If the pressure of the vacuum mixer is set to 15 ~ 30kg / c nf, the pressure is more than 30 1 1 kg / c η ~ 1 It is caused by insufficient recovery of potential strains. Also, if it is below 15 1 I kg / c nf, it is caused by 1 I force due to the shear that occurs when it is not resistant to rolling the formed body. [Implementation of the invention Form] IU The detailed description of the embodiment of the present invention with reference to the drawings is as follows. First of all, as shown in Figure 1, the outer shell 1 is arranged in a vacuum soil mixer (circle is omitted). The front end blows P 1 4 Configured in Central 2. Then, outside of Central 2 -1 1-Zhou and nephew 1 1 1 1 1 This paper size applies to Chinese National Standards (CNS &gt; A4 size (210 X Μ-蠼)) Printed by A7, Consumer Cooperatives of Central Standards Bureau, Ministry of Economic Affairs B7 Fifth, there is a gap between the inner circumference of the mouthpiece 14 of the description of the invention (β). The middle ring 2 is made of plastic material to reduce sliding resistance, but it is not formed in a dimensional shape as shown in the figure. The ball bearing 4a provided in the middle ring bearing housing 4 is pivotally supported at the base end side, and is supported by a thrust sleeve bearing 4b. Pressing, the sealing cover 4c of the middle ring bearing 4 is inserted to prevent the invasion of bad soil, In order to protect the ball bearing 4a and the thrust bearing 4b. The middle sleeve 3 is composed of a spring net with a diameter of 8 to 15 mm, and can be easily deformed elastically. On the other hand, the middle ring bearing housing 4 is connected to Install the main screw shaft 5 of the spiral 6. The structure on the M, by the rotation of the main screw shaft 5 and extruded from the rotatable bad soil system edge 1 which is extruded by the screw 6, is sent to the middle ring bearing housing 4 Part of it became vortex, and the orientation became disordered. Orientation of the mouth portion 14 is performed again, but basically, the spirally oriented tissue is extruded from the mouthpiece portion 14. In general, if the thickness of the blank material in the mouthpiece portion 14 deviates, the narrow portion becomes faster and wider. The speed of the part slows down and automatically adjusts the flow in a few seconds. This adjustment is made by the elastic deformation of the middle sleeve 3. In Figure 2, the blank 10 before rolling is extruded by a vacuum mixer as shown in Figure 1. While cutting and spreading the bad soil into a flat shape, the spiral 6 forms needle-like and swirl-like needle-shaped crystals 9 with respect to the bad soil before rolling. The grooves of the directional groove are rolled by 12 plus K. The groove 11 of the rolled roller 12 has a depth of about 2mm and a width of 4 ~ 5mm, and a pitch of 20 ~ 30mB. It is formed by the roll of 12 rollers The rolled flat plate 10 is made by correcting the needle-like crystals 9 by rolling the groove 11 of the roller pair 12 and twisting it back, so that it has an approximately straight alignment -12- (Please read the precautions on the back before filling this page) -* 1Τ Τ This paper is sized for China National Standard (CNS) Α4 (210'〆297 mm) Employees' Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs, A7 B7, V. Description of the invention (") of the rolled billet 13. According to Figure 2, although the rolled roller pair 12 becomes a segment However, of course, it is also possible to use an attached grooved roller with two or three sections of twisting grooves and M rolling. (Example) The super-large thin-walled ceramic sintered plate of the present invention is manufactured according to the following conditions The examples are explained as follows: 1) Raw material wollastonite: GY 60 ~ 40 (mesh) from HYCO in the United States 60 ~ 40 (mesh) made from China Cobalt: Benshan Wood Festival grade talc: 250 from China (Mesh) the following feldspar: soda feldspar 250 (mesh) or less 2) adjustment of bad soil Put dry powder called scale with specified mixing ratio into a mix muller, mix for 10 minutes, add water 20 × and then Mix for 10 minutes and become plastic soil. 3) Cylindrical production Cutting, unrolling, 250mm diameter (outer) wall thickness 25nm becomes a roll with a width of 720 ~ 730mm, a thickness of 25mm, and a length of 300mm? For the production plate before L, the above-mentioned rolling roller pair 12 is rolled once, and the M flat roller is rolled into a blank plate having a thickness of 5βι, a width of 700mm, and a length of about 1500ββ. 4) Drying and sintering drying are performed by using 瘪 infrared irradiation for 5 minutes, and then using a mesh belt dryer to dry to 350t in 50 minutes: The use of rolled paper is compliant with China National Standard (CNS) A4 specifications (210X297) (Mm) Ί Ί Order I (please read the notes on the back before filling in this page) A7 B7 V. Description of the invention (&gt;) The hearth kiln is fired to a temperature of 1150TC. The characteristics of the mating ratio, water absorption, and strength of the blank plate on M are shown in Table 1. [Table 1] Wollastonite (made in the United States)% wollastonite (used in the United States)% talc% clay feldspar% water absorption% flexural characteristics kg / cnf 'elasticity coefficient cgf / c # This product Nol 50 10 40-12.5 565 35 χ 1〇4 Advanced technology No2 10 40 50 6.3 310 80 ΧΙΟ4 I mn · ————--—L n — I n ^ i · (Please read the precautions on the back before filling in this page) As shown by the results on M, printed by the Central Laboratories of the Ministry of Economic Affairs, Shellfish Consumer Cooperatives, the effect on the strength and elastic properties of wollastonite acicular crystalline minerals is extremely great, as shown in H02 In general, the ceramic composition system has a water absorption rate of about 1/2 of the present invention, and the prior art product with very good gastric texture is compared with the product of the present invention; ^ Hoi is larger than the prior art product No. 02 to 1.7 ~ 1.8 times, especially the elasticity of the product of the present invention will become smaller, and it will have 2 times the elasticity of the previous technology. In addition, Hoi's products of the present invention have not been deformed due to uneven orientation, etc. Compared with the prior art, an incomparable thin and large ceramic porcelain "can be obtained. Press, and then take a few cell examples to produce super-large plates with a maximum width of 1 200mm, a length of 3000 »b, and a thickness of 4bb. [Effects of the Invention] As described in detail above, the effects of the present invention are significant and significant as follows. -1 4-This paper size applies Chinese National Standard (CNS) Α4 specification (2 丨 0X297 mm) &quot; &quot; ~~ —--, I5J—II I-111 I t —i -.....- -11 * ·-0S I ^^ 1-· A7 B7 printed by the Consumer Cooperatives of the Central Bureau of Standards of the Ministry of Economic Affairs 5. Description of the invention (* 〇 (1) is used for ceramic tiles widely used worldwide as construction materials Fields, modernization of cellular engineering methods, curtain wall • Rationalization of large flat slabs, etc., or problems such as pollution of community buildings or “molds”, etc. are also responding to changes in the living environment and require countermeasures. Μ, various manufacturers are carrying out research for the purpose of increasing the size and weight of the size. However, due to the reduction in weight and thickness, the "fragility", the biggest disadvantage of "ceramics", occurs when the size is increased. The present invention relates to These problems far surpass the advanced technology of "the common sense of ceramics j is high-quality (equivalent to asbestos board), and it is now an epoch-making physical property. This series has completed the world's ceramic manufacturers with a width of 1.2η, a length of 3m, and a thickness Practical for large ceramic tiles of 4πιβ First, we can cite the technically significant progress. (2) With the width of 1.2m and length of 3m, the large-thin thin-walled ceramic plate system, which almost completely removes the disadvantages of vulnerability, is because The length is 3.0m, which is just the first floor of the tall belly of high-rise buildings. Its height can be posted, so the construction cost of the wall surface can be particularly more economical. * (3) The invention is a prior art concrete Boards are different, because it has excellent waterproofness originally, so K does not need to put a waterproof layer, and it is 4mm thin, and its weight is the lightest than that of advanced technology. Whether it is a steel-frame building or a concrete demon, In terms of design, columns, beams, and foundations can achieve weight reduction based on their components, so the economic effect of the structure as a whole will become very large. Brief description of the drawing Figure 1 shows the needle-like crystal orientation in the bad soil of the present invention A cross-section illustration of a function increasing device. -15- This paper size applies to the Chinese National Standard (CNS) A4 (210X 297 mm). ^ 1- In-— I 士 又 I--I i----- «^^ 1 XV • *,? (Please read the notes on the back before filling out this page) 399034 A7 B7 V. Explanation of the invention (4) The second plaque is an explanatory diagram of the needle-like crystal orientation in the bad soil of the present invention, (a) is a plane garden, and (b) is a side view. [Explanation of the symbols] 1 The outside of the vacuum mixer 4 middle ring bearing dice, 4 c sealing cover, 7 bad soil, 10 blank before rolling, 1 3 rolls Rolled billet, 2 middle rings, 4a ball bearings, 5 spiral shafts, 8 middle ring support frames, 11 grooves, 14 mouthpieces. 3 middle ring shaft, 4b thrust bearing, 6 spiral, 9 $ ten crystals, 1 2 roller roll pairs, (Please read the precautions on the back before filling this page).

、1T 經濟部中央標準局員工消費合作社印製 16- 本紙張Κ度4 家標率(CNS ) Α4说格(210X297公釐)、 1T Printed by the Consumer Cooperatives of the Central Standards Bureau of the Ministry of Economic Affairs 16- This paper has 4 standard rates (CNS) Α4 grid (210X297 mm)

Claims (1)

公告本3&quot;〇34 C8 —^--- 六、申請專利範園 第86105257號「由具有以同一方向取向排列組織之針狀結晶礦物所形 成大形平板燒結髏,其製造方法及製造裝置」專利案 (88年9月30日修正) 六申請專利範圍: 1. 一種由具有以同一方向取向排列組織之針狀結晶礦物 所形成大形板狀燒結體,其特徽爲; 均質地含有將属於針状結晶礦物之β-CaO· Si02以 無水換算爲30〜70 [重童%],與含有黏土及滑石之一 般陶瓷質物以無水換算爲70〜30 [重量,上述針狀結 晶礦物爲形成以同一方向均勻地取向排列爲所需形狀, 而在1000〜1250 [°C]之溫度範圍燒結》 2. —種由具有以同一方向取向排列組織之針狀結晶礦物 所形成大形板狀燒結體之製造方法,係含有&gt;8-CaO · Si022針狀結晶礦物之原料,其特徵爲; 該針狀結晶之長度爲l[mrn]以上,將幅形比爲20以 上之矽灰石以無水換算成爲30〜70[重量%],與可塑性 之黏土質原料以無水換算成爲60〜30[重量%],與將 做爲取向性改良料之疏水性水性潤滑材之滑石以10〜 20[重纛%],與視其霈要時,就從長石,陶石,黏土 熟料(法chmotte)之中所選擇一種以上之一般陶瓷用 原料成爲0〜30[重量%]而添加,加水以調整爲合計 100%,使含水率爲14〜20[重量%],爲調整爲均質化, 將成爲塑狀態之坯土,使用真空拌土機裝屋擠出成圓 本紙張尺度逋用中鬮國家揉準(CNS ) A4规格(210X297公釐) (請先聞讀背面之注$項再填寫本頁) -订· _ 經濟部智慧財產局員工消費合作社印製 399034 ?| D8_ 六、申請專利範圍 (請先Μ讀背面之注意事項再壤寫本頁) 简狀,其後,將其切開,展開爲板狀,與擠出方向 同一方向使用輥軋輥輪作成所要厚度大小之板狀胚料, 接著,乾燥該板狀胚料之後,以1000〜1250[°C]之溫 度範圍燒成》 3 .如申請専利範園第2項之由具有以同一方向取向排列 組織之針狀結晶礦物所形成大形板狀燒結體之製造方 法,其中上述真空拌土機裝犀,其出口部之擠出屋力 爲15〜30[kg/cra2],保持該真空拌土機中之外胴與中 環所構成吹口之中環之軸及軸承爲與該真空拌土機之 主螺旋軸之迴轉絕緣,並且,中環係由於坏土之流動 阻力以自如地迴轉移位來提高該坏土中之上述針狀結 晶之取向性,再者,將圓筒狀成形體之厚度自動地調 整後,切開,展開上述面筒胚料爲平板狀而與擠出方 向同一方向成形之胚料使用輥軋輥輪加以輥軋。 經濟部智慧財產局員工消費合作社印製 4.如申請專利範圍第3項之由具有以同一方向取向排列 組織之針狀結晶礦物所形成大形板狀燒結體之製造方 法,其中將上述所成形之胚料使用輥軋輥輪進行輥軋之 方法,在最初欲輥軋之輥輪,爲了復原爲由真空拌土 機主螺旋之旋轉所產生曲線狀之取向組織,由具有一 邊給予相反方向之扭力進行輥軋之螺旋狀溝之一對輥 輪加以輥軋之後,再經過數段之輥軋步驟輥軋成所需 厚度大小之板狀胚料。 -2- 本紙張尺度適用中國國家捸率(CNS ) A4規格(210X297公釐) 經濟部智慧財產局員工消費合作社印製 399034 ?S D8六、申請專利範圍 5.—種由具有以同一方向取向排列組織之針狀結晶礦物 所形成大形板狀燒結體之製造裝置,其具有由: 壓送收容於近似園筒形外胴(1)內之坏土(7)之主螺 旋(6),轉動該主螺旋軸(5)之電動機;將該坏土送入 上述主螺旋(6)內,裝設於上述近似圖筒形外胴(1)上 部端之戽斗:與設於上述近似圖筒形外胴U)內之真空 室:中環支持軸與中環(2):及具有在該真空室將空氣 已排除之坏土(7)擠出之吹口(14)所構成的真空拌土機, 其特徵爲:在該主螺旋軸(5)與中環支持軸(3)之接合部, 裝設防止坏土洩入之中環軸承殻(4),該中環軸承殻(4) 內部,設置裝有絕緣剛性之止推軸承(4b)之中環軸承 (4a),中環支持軸(3)與中環(2)爲沿著坏土(7)之流 動柔軟地動作,將含在坏(7) 土中之針狀結晶向同一 方向以無阻力地加以取向》 (請先聞讀背面之注f項再壤寫本頁) -,I II -I m - Kn t! l·— ··1 ί -ί— I 本紙浪尺度適用中國國家榡準(CNS ) A4規格(210X297公釐)Announcement 3 &quot; 〇34 C8 — ^ --- VI. Patent Application Fanyuan No. 86105257 "Large flat plate sintered skeleton formed by needle-shaped crystalline minerals with a structure aligned in the same direction, its manufacturing method and manufacturing device" Patent case (Amended on September 30, 88) Six patent application scope: 1. A large plate-shaped sintered body formed by needle-shaped crystalline minerals with an organization arranged in the same direction, the special emblem is: Β-CaO · Si02, which belongs to acicular crystalline minerals, is 30 to 70 [wt.%] In terms of anhydrous conversion, and ordinary ceramics containing clay and talc are 70 to 30 in weight, based on anhydrous conversion. The above acicular crystalline minerals form Oriented and aligned uniformly in the same direction into the desired shape, and sintered in a temperature range of 1000 to 1250 [° C] "2. A large plate-shaped sintered formed by needle-like crystalline minerals with a structure aligned in the same direction The manufacturing method of the body is a raw material containing> 8-CaO · Si022 needle-shaped crystal mineral, characterized in that the length of the needle-shaped crystal is 1 [mrn] or more, and the wollastonite having an aspect ratio of 20 or more is used. Anhydrous conversion 30 to 70 [% by weight], 60 to 30 [% by weight] of plastic clay material and 60 to 30 [% by weight] in terms of anhydrous conversion, and 10 to 20 [weight] %], And when necessary, select one or more general ceramic raw materials from feldspar, pottery, and clay clinker (French chmotte) to add 0 to 30 [% by weight], add water to adjust to The total moisture content is 100%, and the moisture content is 14 to 20 [wt%]. In order to adjust for homogenization, the clay in a plastic state will be extruded into a round paper size using a vacuum soil mixing machine. Standard (CNS) A4 (210X297 mm) (Please read the note on the back before filling in this page)-Order · _ Printed by the Intellectual Property Bureau Staff Consumer Cooperatives of the Ministry of Economic Affairs 399034? | D8_ VI. Scope of Patent Application ( Please read the precautions on the back before writing this page.) Simplified, then cut it open, unfolded into a plate shape, using the same direction as the extrusion direction to make a plate-shaped blank with the required thickness, and then After drying the plate-shaped blank, the temperature is 1000 ~ 1250 [° C] "Range firing" 3. For example, the method for manufacturing a large plate-shaped sintered body formed by needle-shaped crystalline minerals having an organization aligned in the same direction as in item 2 of the Lili Fanyuan, wherein the above-mentioned vacuum mixer is equipped with rhino, The extrusion housing force at the exit is 15 ~ 30 [kg / cra2]. The shaft and bearing of the middle ring of the mouthpiece formed by the outer ring and the middle ring of the vacuum soil mixer are the same as the main screw shaft of the vacuum soil mixer. Rotary insulation, and the middle ring system can be freely rotated and displaced due to the flow resistance of the bad soil to improve the orientation of the needle-like crystals in the bad soil. Furthermore, after the thickness of the cylindrical shaped body is automatically adjusted, Cut and unfold the dough tube blank into a flat plate shape and the blank material formed in the same direction as the extrusion direction is rolled using a rolling roller. Printed by the Consumer Cooperative of the Intellectual Property Bureau of the Ministry of Economic Affairs 4. As described in item 3 of the scope of patent application, a method for manufacturing a large plate-shaped sintered body formed by needle-shaped crystalline minerals with an organization arranged in the same direction, wherein The blank is rolled using a rolling roller. In order to restore the curved orientation structure produced by the rotation of the main spiral of the vacuum mixer on the roller to be rolled initially, the side has a torque in the opposite direction. One of the helical grooves to be rolled is used to roll the roller, and then rolled into a plate-shaped blank of a desired thickness after several rolling steps. -2- This paper size applies to China's National Standard (CNS) A4 specification (210X297 mm) Printed by the Consumer Cooperatives of the Intellectual Property Bureau of the Ministry of Economic Affairs 399034? S D8 VI. Application for patent scope An apparatus for manufacturing a large plate-shaped sintered body formed by acicular crystalline minerals arranged in a structure, comprising: a main spiral (6) for pressure-feeding bad soil (7) contained in an approximately cylindrical outer ridge (1), The motor that rotates the main screw shaft (5); sends the bad soil into the main screw (6), and is installed in the bucket on the upper end of the cylindrical outer casing (1) of the approximate diagram: with the approximate cylinder Vacuum chamber inside U): Central ring supporting shaft and middle ring (2): and a vacuum soil mixer with blower (14) formed by extruding bad soil (7) from which air has been removed in the vacuum chamber, It is characterized in that a middle ring bearing housing (4) is installed at the joint of the main screw shaft (5) and the middle ring support shaft (3) to prevent the soil from leaking into the middle ring bearing housing (4). Insulating rigid thrust bearing (4b), middle ring bearing (4a), middle ring support shaft (3) and middle ring (2) are along With the soft movement of the bad soil (7), the needle-like crystals contained in the bad soil (7) are oriented in the same direction without resistance "(please read the note f on the back and write this page first) )-, I II -I m-Kn t! L · — ·· 1 ί -ί— I The paper scale is applicable to China National Standard (CNS) A4 (210X297 mm)
TW086105257A 1997-02-25 1997-04-23 Method of manufacturing sintered body whose capillary mineral has evenly mixed texture and a large volume plane style and apparatus for its manufacture TW399034B (en)

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US10384369B2 (en) 2012-11-30 2019-08-20 Corning Incorporated Extrusion systems and methods with temperature control
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