TW376390B - Multinuclear metallocene compound, a process for its preparation and its use as catalyst - Google Patents

Multinuclear metallocene compound, a process for its preparation and its use as catalyst

Info

Publication number
TW376390B
TW376390B TW085108809A TW85108809A TW376390B TW 376390 B TW376390 B TW 376390B TW 085108809 A TW085108809 A TW 085108809A TW 85108809 A TW85108809 A TW 85108809A TW 376390 B TW376390 B TW 376390B
Authority
TW
Taiwan
Prior art keywords
metallocene
another
metallocene compound
different
catalyst
Prior art date
Application number
TW085108809A
Other languages
English (en)
Inventor
Michael Aulbach
Michael-Joachom Brekner
Frank Kuber
Roland Zenk
Original Assignee
Hoechst Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19514301A external-priority patent/DE19514301A1/de
Priority claimed from DE1995120599 external-priority patent/DE19520599A1/de
Application filed by Hoechst Ag filed Critical Hoechst Ag
Application granted granted Critical
Publication of TW376390B publication Critical patent/TW376390B/zh

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/03—Multinuclear procatalyst, i.e. containing two or more metals, being different or not
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61912—Component covered by group C08F4/60 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/61916—Component covered by group C08F4/60 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/619—Component covered by group C08F4/60 containing a transition metal-carbon bond
    • C08F4/6192—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/61922—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/61927—Component covered by group C08F4/60 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
TW085108809A 1995-04-27 1996-07-19 Multinuclear metallocene compound, a process for its preparation and its use as catalyst TW376390B (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19514301A DE19514301A1 (de) 1995-04-27 1995-04-27 Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator
DE1995120599 DE19520599A1 (de) 1995-06-06 1995-06-06 Mehrkernige Metallocenverbindung, Verfahren zu ihrer Herstellung und ihre Anwendung als Katalysator

Publications (1)

Publication Number Publication Date
TW376390B true TW376390B (en) 1999-12-11

Family

ID=26014445

Family Applications (1)

Application Number Title Priority Date Filing Date
TW085108809A TW376390B (en) 1995-04-27 1996-07-19 Multinuclear metallocene compound, a process for its preparation and its use as catalyst

Country Status (10)

Country Link
US (1) US6262197B1 (zh)
EP (1) EP0739897A1 (zh)
JP (1) JPH08295696A (zh)
KR (1) KR960037693A (zh)
CN (1) CN1066153C (zh)
AU (1) AU718870B2 (zh)
BR (1) BR9602087A (zh)
CA (1) CA2175159A1 (zh)
NO (1) NO961683L (zh)
TW (1) TW376390B (zh)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2129323B1 (es) * 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
US6235917B1 (en) 1998-08-28 2001-05-22 The Dow Chemical Company Dinuclear complexes and polymerization catalysts therefrom
US6284698B1 (en) 1997-09-15 2001-09-04 The Dow Chemical Company Highly activated bimetallic complexes and polymerization process
ATE222917T1 (de) * 1997-09-15 2002-09-15 Dow Chemical Co Bimetallische komplexe und diese enthaltende polymerisationskatalysatoren
US5986024A (en) * 1997-10-17 1999-11-16 Sri International Preparation of multimodal polymer compositions using multinuclear metallocene catalysts
US6096677A (en) * 1997-10-17 2000-08-01 Sri International Supported metallocene catalysts
US5892079A (en) * 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use
EP0955306B1 (en) * 1998-04-29 2003-01-22 Repsol Quimica S.A. Functionalized metallocene compounds, synthesis process and use thereof
US6228790B1 (en) * 1998-06-29 2001-05-08 Industrial Technology Research Institute Dinuclear metallocene catalyst for preparing high molecular weight olefin polymer
US6455458B1 (en) 1998-07-10 2002-09-24 Exxonmobil Chemical Patents Inc. Tethered monocyclopentadienyl polymerization catalysts
EP0985677A1 (en) * 1998-09-07 2000-03-15 Industrial Technology Research Institute Dinuclear metallocene catalyst for olefin polymerization
AU764177B2 (en) * 1998-12-18 2003-08-14 Univation Technologies Llc Haloaryl containing group 13 substituents on bridged metallocene polyolefin catalysts
US6544919B1 (en) 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
PT1095944E (pt) * 1999-10-26 2004-08-31 Repsol Quimica Sa Compostos de bis ciclopentadienilo com ponte por um atomo de carbono e complexos de metalogeno contendo-os
US6420580B1 (en) * 1999-11-05 2002-07-16 Univation Technologies, Llc Catalyst compositions and method of polymerization therewith
KR100349979B1 (ko) * 1999-11-18 2002-08-22 삼성전자 주식회사 스티렌계 중합용 다중금속 메탈로센 촉매 및 이를 이용한스티렌계 중합체의 제조방법
KR20020012346A (ko) * 2000-08-07 2002-02-16 유현식 신디오탁틱 폴리스티렌을 고수율로 제조하고 반응기부착물을 감소시키는 담지촉매
KR100455713B1 (ko) * 2001-01-29 2004-11-06 호남석유화학 주식회사 올레핀 중합용 다중핵 메탈로센 촉매 및 이를 이용한중합방법
US6642400B2 (en) 2001-09-26 2003-11-04 Univation Technologies, Llc Linked metallocene complexes, catalyst systems, and olefin polymerization processes using same
US6753390B2 (en) * 2002-09-04 2004-06-22 Univation Technologies, Llc Gas phase polymerization process
US6841500B2 (en) * 2002-12-03 2005-01-11 Equistar Chemicals, Lp Bimetallic indenoindolyl catalysts
US6812183B1 (en) * 2003-04-23 2004-11-02 Equistar Chemicals, Lp Triple-decker catalysts based on delocalized dianionic ligands
KR100677869B1 (ko) * 2004-07-01 2007-02-02 대림산업 주식회사 다중핵 금속 화합물, 이를 포함하는 촉매 시스템 및 이를이용한 올레핀의 중합 방법
KR101918484B1 (ko) * 2017-11-15 2019-01-31 금호폴리켐 주식회사 탄성 공중합체 제조용 촉매 조성물 및 이를 이용한 에틸렌 및 알파-올레핀 또는 에틸렌, 알파-올레핀 및 비공액 디엔을 포함하는 탄성 공중합체의 제조 방법
US10851187B2 (en) 2018-01-31 2020-12-01 Exxonmobil Chemical Patents Inc. Bridged metallocene catalysts with a pendant group 13 element, catalyst systems containing same, processes for making a polymer product using same, and products made from same
US10865258B2 (en) 2018-01-31 2020-12-15 Exxonmobil Chemical Patents Inc. Mixed catalyst systems containing bridged metallocenes with a pendant group 13 element, processes for making a polymer product using same, and products made from same
US11802170B2 (en) 2021-04-29 2023-10-31 Exxonmobil Chemical Patents Inc. Polyolefins prepared with binuclear metallocene catalysts

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3443087A1 (de) 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US5243001A (en) 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
JP3117231B2 (ja) * 1991-03-11 2000-12-11 三井化学株式会社 幅広い分子量分布を有するシンジオタクチックポリ−α−オレフィンの製造方法
TW300901B (zh) 1991-08-26 1997-03-21 Hoechst Ag
TW318184B (zh) 1991-11-30 1997-10-21 Hoechst Ag
DE59206948D1 (de) 1991-11-30 1996-09-26 Hoechst Ag Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
EP0578838A1 (en) 1992-04-29 1994-01-19 Hoechst Aktiengesellschaft Olefin polymerization catalyst, process for its preparation, and its use
TW294669B (zh) 1992-06-27 1997-01-01 Hoechst Ag
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
ES2154664T3 (es) * 1993-11-24 2001-04-16 Targor Gmbh Metalocenos, procedimientos para su obtencion, y su empleo como catalizadores.
US5892079A (en) * 1997-10-17 1999-04-06 Sri International Metallocene catalysts and associated methods of preparation and use

Also Published As

Publication number Publication date
US6262197B1 (en) 2001-07-17
NO961683L (no) 1996-10-28
CA2175159A1 (en) 1996-10-28
AU718870B2 (en) 2000-04-20
AU5080796A (en) 1996-11-07
CN1141925A (zh) 1997-02-05
NO961683D0 (no) 1996-04-26
JPH08295696A (ja) 1996-11-12
KR960037693A (ko) 1996-11-19
CN1066153C (zh) 2001-05-23
BR9602087A (pt) 1998-10-06
EP0739897A1 (de) 1996-10-30

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