TW212748B

TW212748B -

Info

Publication number: TW212748B
Application number: TW081103074A
Authority: TW
Original assignee: Dowelanco
Priority date: 1991-04-26
Filing date: 1992-04-20
Publication date: 1993-09-11
Also published as: KR920019247A; JPH0565201A; JP3350863B2; KR100220267B1

Description

Λ 6 Π 6 經濟部中央樑準局貝工消伢合作杜印製五、發明説明（1 ) 本發明像關於水田用除草劑組成物，詳言之，其僳有關於一棰待別適合於植苗後之水田在滿水下處理為目的之除草用粒劑組成物。按以往水田之滿水下處理用除草劑的製劑形態，基於可用手輕易散佈之理由，大部分概分為粒_和植苗前原液散佈乳劑二種類，其中有一部分偽使用以大量水稀釋而散佈之乳劑和水和剛。植苗前原液散佈用乳剤，一般像不使用器具而可用手輕易散佈，雖有以少量有效成份量加以散佈之粒劑具有相同效果等優黏，然於植苗後在移植幼苗水稻時将此乳液進行原液散佈，基於在製剤中含有多量有櫬溶劑等而對水稻有發生蕖害之缺點，因此，現今所實施之乳剤原液散佈僅限制於植苗前使用，，惟在檀苗前散佈除草劑乳液之原液時，往往由於檀苗時之下水作業而導致_劑流入於河川引起琛境污染間題的缺點。至於，以往所實施之用大置水稀釋而散佈型式之乳劑以及水和劑，由於每10公畝需用50〜100公升之大量水稀轉_劑而散佈，因此該種散佈方式需耗用大量勞役〇故比較粒爾以及植苗前原液敗佈型乳劑其施用之機會很少。另一方面，粒劑由於散佈較為方便故最常使用。此種粒—般像將除草活性化合物與皂土，滑土，黏土等黴粉末載醱一起混合粉碎後加以造粒，亦可使用預先成 * 3 ~ (請先WI讀背而之注意本項#^-转人 ) 本紙張尺度遑用中Η國家楳準(CNS) T4規格(210X297公*) 81. 2. 20,000 218748 Λ 6 η 6 总、發明説明（2 形為粒狀之撤粉末載鶄吸着以除草活性化合物等方·法予以製_ .依此方法所製造之粒劑，因除草活性成份型堅牢地附着在載鼸上面，而有降低除草活性成份之有效利用率問題。因此.當散佈粒_時，欲能獲得乳劑或水和劑以大*水稀蘀而散佈時具有相同之除草效果，例如，有必要在粒爾中加多除草活性化合物的配合量，惟如此不但提高製劑成本，而且就琛境污染之層面加以考量亦不甚合宜。本發明者針對上述無缺黏之水田用除草爾刻意檢討之結果，在調製粒劑之際，將除草活性化合物併用某種特定的油性液體.而與微細固體載體材料一起加以製劑，如此得以使用比較少悬之除草活性化合物而發揮高度之除草活性，發現不具有藥害及琛境污染等問題之水田除草用粒劑，尤其可獲得適用於湛水下處理之水田除草用由種 1 供提為微特其 0 * 明’明發發本本成照完依而，遽而劑因粒請先閱讀背而之意事項艰. % 裝 π 經濟部屮央標準局貞工消伢合作杜印製及以物30 合在體化度液性黏性活而油草 1 条除連酯用未之田至性水乃溶型80不收0.呈吸為水藥重對莖比上質實下以份量重料 0 材物 1 11 體載 0 固細微之性溶不呈水對上質實上以成組劑粒用草除田水之成組所份量 S 3 本紙張尺度遑用中國困家標準(CNS) T4規格(210X297公《) 81. 2. 20,000 818748 A G Π 6 五、發明説明（3 ) 以下，就本發明之粒_組成物詳細説明之。 (a >除草活性化合物關於本發明之所使用粒劑組成物之除草活性成份，像從水田雜草的莖葉部被吸收而發揮除草效果類型之除草活性化合物（在本說明書則槪稱為「莖藥吸收型水田用除草活性化合物」），此種類並無持別之限制，以往所習知之Μ葉吸收型均可廣泛使用。具髏而言，例如可遽用以下一般式 CH3 >_〇~ 式中，Ar代表下式之基圃，Λ 6 Π 6 The Ministry of Economic Affairs, Central Liangzhun Bureau, Beigong Consumer Co., Ltd. cooperated in the production of Du. V. Description of the invention (1) The present invention is about the herbicide composition for paddy fields. In detail, the invention is about The herbicide composition for the purpose of treating the paddy field under full water after planting. According to the form of the herbicide used for underwater treatment of paddy fields in the past, most of them are divided into two types: granules and pre-planting liquid dispersion emulsions, based on the reason that they can be easily distributed by hand. The emulsion and water and Gang. The milk powder used to disperse the stock solution before planting is generally easy to spread by hand without using utensils. Although there are granules dispersed in a small amount of effective ingredients, it has the same effect and excellent viscosity. However, after planting seedlings, this emulsion is applied The dispersion of the stock solution has the disadvantage of causing damage to rice due to the large amount of solvents contained in the preparation. Therefore, the distribution of the stock solution of the milk stock is only limited to use before planting, but the herbicide emulsion is distributed before the seedlings. In the case of the original solution, it is often due to the water operation of Tan Miao that causes the _ agent to flow into the river and cause the shortcomings of the pollution problem in the Chen border. As for the emulsions and waters that have been implemented in the past and diluted with large water to disperse the type, since every 10 acres need to use a large amount of 50 to 100 liters of water to dilute the agent to disperse, so this kind of dispersing method needs to be consumed A lot of labor. Therefore, there are few opportunities to apply the gel and pre-embedded liquid emulsion type emulsions. On the other hand, granules are most commonly used because they are more convenient to disperse. This kind of granules is like mixing herbicidal active compounds with bentonite, landslide, clay and other mildew powders and then crushing them to make granules. It can also be pre-formed * 3 ~ (Please read the WI first and pay attention to this item # ^-转人) This paper uses the National Standards (CNS) T4 specifications (210X297 g *) 81. 2. 20,000 218748 Λ 6 η 6 General, invention description (2 granular powder withdrawal) It is made by herbicidal active compounds and other methods. The granules produced by this method have the problem of reducing the effective utilization rate of the herbicidal active ingredients because the herbicidal active ingredient type is firmly attached to the carrier mule. When distributing granules, if you want to obtain emulsion or water and the agent is dispersed with large * water dilute, it has the same herbicidal effect. For example, it is necessary to add more compounding amount of the herbicidal active compound in the granules, but this not only improves The cost of the preparation, and it is not very appropriate to consider the level of pollution in the environment. The inventors deliberately reviewed the results of the herbicide used in the above-mentioned non-sticky paddy field. When preparing granules, the herbicide active compound was used in combination with a specific Oily liquid. It is formulated with a fine solid carrier material, so that it can use a relatively small amount of herbicidal active compound to exert a high degree of herbicidal activity. It is found that the granules for paddy field weeding that do not have the problems of phytotoxicity and pollution in the environment are particularly suitable for use. The weeding of the paddy field treated by Zhan underwater is provided by the species 1 and provided as a micro-specific 0 * Ming 'Mingfa issued the book according to the completion of the book, and the agent should be read first because of the grain. The matter is difficult.% Π Economy The Ministry of Standards, Bureau of Standards, Zhen Gong Consumers cooperated to produce and print the material 30 in the degree of liquid viscosity viscous activity and 1 oil grass except for the use of esters. The field is water-soluble and 80 is not collected. 0. It is absorbed as water. The weight of the medicine is higher than that of the stem. The weight is the same as the weight of the material. 0 Material 1 11 Body load 0 The fine and sexually soluble is not the water. Serving size S 3 This paper standard uses the Chinese Standard for the Sleepy Family (CNS) T4 specification (210X297). 81. 2. 20,000 818748 AG Π 6 5. Description of the invention (3) The following is a detailed description of the granules_composition of the invention Of. (A > except Herbicidal active compounds The herbicidal active ingredients of the granule composition used in the present invention are like herbicidal active compounds that are absorbed from the stems and leaves of weeds in paddy fields to exert the herbicidal effect (referred to in this specification as "stem herb absorption" Type herbicidal active compound for paddy field "), this type is not restricted, and the conventionally known M leaf absorption type can be widely used. For the skeleton, for example, the following general formula CH3 > _〇 ~ formula can be used In, Ar represents the base garden of the following formula,

Ar_〇_^^^--O-CH-COORAr_〇 _ ^^^-O-CH-COOR

Tk 先閱背而之注意事· 項 # Ί % 裝 π 線Tk first read the notes on the back. Item # Ί% loading π line

經濟部中央標準局A工消货合作杜印製 , 又li 其中X代表豳素原子，三«甲基或氰基，Y為氳原子或齒素原子，R代表氫原子，烷基，烯基，炔基，烷氣烷基或烷硫烷基（此等基·宜具有1〜8镝，最好為2〜4镝硪原子），所代表之苯氣基丙酸衍生物，其中以 2-[4-(2-覦-4-氰苯氣）笨氧基]丙酸之Ci〜C8烷基酯（例如，甲酯，正丁酯）最為適用。惟亦可使用其他之莖葉吸收型除草活性化合物，例如 -5 冬紙張尺度遑用中國國家楳準(CNS) ΤΜ規格(210X297公：¢) 81. 2. 20,000 n»749 Λ 6 η 6 經濟部中央梂準局貝工消伢合作杜印5i 五、發明説明（4 ) 2 -甲硫基-4,6 -雙（乙胺基）-S-三吖嗪， S -苄基-1,2 -二甲丙（乙基）硫代氨基甲酸 S-1-甲基-1-苯乙基-哌啶-1-羧硫代酸酯， S-(4 -氱苄基）-N,H -二乙基硫代氛基甲酸酯， 2-苯並瞎唑-2-基氣-N-甲基乙脯， 2-氰-2’，6’-二乙基1-(丁氧甲基）乙«, 2-氯-2’，6’-二乙基- H-(2-丙氣乙基）乙腈， 2 -異丙基-2,1,3 -苯並哮嗪酮- (4)-2,2-二氣化物等。以上所述除草活性化合物彼此可單玀使用.或併用二種以上使用。 (b )油性液鼸本發明之粒狀組成物的一種特微為，使用组合上述之除草活性化合物，實質上像對水呈不溶性之酯条油性液體。此種酯糸油性液鼸，其比重傺在0.80乃至未達1 ,最好傈介於0.85〜1之範圍且黏度在300cps以下，最好偽使用200cps以下之低黏度，對上述除草活性化合物實質上為不活性，混合該除草化合物而組成，例如在25¾下至少含有5重量X以上之除草活性化合物，而較適合者换使用溶解10重以上之除草活性化合物。又，上述醣条油性液體以蒸氣壓較离者最為適宜，例如在2 5 υ之蒸氣壓偽使用未滿1 P a ,而以0 . 5 P a以下者最為有利。 -* 6 ~ (請先閲讀背而之注意事項#填寫4| 本紙張尺度遑用中S »家糅準(CNS)甲4規格(210><297公*) 81. 2. 20,000 »13748 Λ 6 Π 6 經濟部屮央橾準局貝工消t合作杜印製五、發明説明（ί>) 具有如上所述特性之酯糸油性液鼸，具醱而言，僳包含有以下之化合物。 (1) 高级脂肪酸酯類：例如油酸甲酯，油酸異丁油酸辛酯，油酸2 -乙已酯，油酸癸酯，油酸月桂酯，油酸油酯，肉豆寇酸甲酯 ,肉豆兹酸異丙肉豆蔻酸十八烷酯，.棕櫊酸異丙酯 ,棕櫊酸2 -乙己硬脂酸丁 _，硬脂酸2 -乙己酯，硬脂酸異十三烷脂，月桂酸甲酯，2 -乙己酸十六烷酯，芥酸十八烷酯，癸酸甲酯，櫛子油脂肪酸甲酷，牛脂脂肪酸甲酯，棕椭油脂肪酸甲酯等高级脂肪酸之烷酯； (2) 脂肪族或芳番族多鹽基酸酯類：例如，己二酸二油基酯，己二酸二異丁酯，己二酸二異癸酯等之脂肪酸二硪酸之二烷基酯；酞酸二癸酯，酞酸二十三烷酯，酞酸二2 -乙醋，酞酸琛己基2 -乙己酯等之芳香族二硪酸之二烷基苯褊三酸三2 -乙己酯，苯偏三酸三乙BI,苯«三酸三正丁酯，苯僱三酸三異癸酯等之芳香族多硪酸之聚烷基酯； (3 )甘油脂肪酸酯類：例如油酸甘油一酸酯，油酸甘油二酸酯，山梨耱酵酐單油酸酯，山梨糖酵酐單月桂酸酯，癸酸甘油一酸酯，癸酸甘油二酸酯，二乙醯基癸酸甘油二乙醏基椰子油脂肪酸甘油酯等； (4 )琢氣化脂肪酸酯類： -7- (請先閲讀背而之注意事項再塡寫41·) 本紙張尺度遑用中明《家樣準(CNS) f 4規格(210X297公 81. 2. 20,000 M&S4 五、趟 a Η 6 發明説明（6 ) 經濟部中央標準局员工消赀合作杜印製例如，琢氧化脂肪酸丁酯，環氣氣化脂肪酸烷基脂。此等酯糸油性液醱可分別單獮使使用n在該等油性液體中，待別適烷酯，己二酸二油酸酯，油酸辛酯酵酐單油醣，琛氣化脂肪酸辛酯等上述酯条油性液鐮，對1重量份 (a)傜使用1〜50重量份，宜為5〜 5〜20重量份之範園。 (c >載醱材料關於本發明所使用之載體材料，於製造粒劑時通常使用而比重為1 之任意固體材料，具龌而言，包括石膏，滑土，皂土，黏土，离嶺土 ,蒙脱石，長石，石英，矽石（白固黼粉末；大豆粉，小麥粉，菸草之植物性粉末等，此等載《可以分二種以上使用。又，縱然其本身之材料，在成形為粒基材之際，使其成比重為1以上而與其他載匾材料土，黏土，》土，硪酸鈣或為其混又，本發明所使用之載體材料， «上述之油性液體者最佳，吸油率化脂肪酸辛_等之瓌用，或混合二種以上宜者為，酞酸二十三，油酸甲酯，山梨糖 0 之除草活性化合物 25重量份，而最好為包含有實質上有矽藻 ,磺酸磺），粉，毅別單》比重為粒基材組合使合物最以得以一般為製造農_領域對水里不溶性土，磷灰石， 0 ,酸性白土礬土等無機質粉，木粉等等使用，或併合未滿1之載體全體之比重形用。特別以皂具適用。吸收或易於吸 5〜30X,最好先閏背而之注意事項填 8 - 本紙張尺度边用中國國家樣準(CNS)肀4規格(210X297公龙) 81· 2. 20,000 212748 Λ 6 Β 6 經濟部中央榣準局貝工消t合作杜印製五、發明説明（7 ) 僳介於10〜20S；範圍内者為佳。本發明所指吸油率可由下述方法澜定。用三角瓶正確秤量10克之載體材料，加入少量之亞麻油，振鼉三角瓶，使載鼸材料吸油。基此澜定載體材料對於亞麻油所呈現之最大吸油限度之重量。最後，振盤三角傾，邸在瓶壁上面産生黏着現象，此時載體材料繡結在一起而形成不流動之前之狀態。添加亞麻油之重量（g) 吸油率（¾ j = -- X 1〇〇基薄I之重量（10g > 如上所述之載齷材料，對上述1重量份之除草性活性化合物（a),可使用1〜98重量份，宜為20〜90重量份，最好為30〜70重量份。例如，適宜之載體材料為上述之皂上，黏土，滑土，硪酸鈣，對1重量份之除草活性化合物（a)可使用30〜60重量份之皂土和10〜68重量份之黏土，滑土及/或硪酸鈣的混合物。 (d )其他之添加物本發明之粒劑組成物，因應其所需，可配合界面活性劑及/崩壊促進劑。界面活性劑主要者可使用陰離子或非離子界面活性劑或水溶性高分子物霣3陰離子界面活性劑，例如包括有 Cu〜Cis之烷基硫酸鹽（Na鹽，K鹽，銨鹽，各種胺鹽等 >,聚氣乙烯（：8〜12烷苯基醚硫酸饔（Na馥，銨鹽， -9- (請先閲讀背而之注意事項#塡窍'>\) 本紙張尺度遑用中BB家«平(CNS)T4規格(210X297公;《：) S1. 2. 20,000 Λ 6 15 6 212748 五、發明説明（8) 各種胺囅等 >,聚氣乙烯聚氣丙烯分段聚合物硫酸鹽（Na 鹽，銨薷，各種胺鹽）等之硫酸麴糸陰離子界面活性劑；十二苯礒酸馥（N a鹽，銨》,各律胺等），單-或雙-Cs〜C12烷萊基磺酸_(Na鹽，銨鹽等 >,莆磺酸鹽（Na 鹽等）-福馬林縮合物，二-C6〜C8烷基硫代琥珀酸鹽 (Na鹽等），木質素磺酸鹽（Na鹽，Ca鹽等）之磺酸蘧条陰離子界面活性聚氣乙烯月桂醚磷酸酯铵鹽，聚氧乙氣壬苯醚磷酸酯納鹽等之聚氣乙烯醚型磷酸酯条陰離界面活性劑等。又.非離子界面活性劑包括有，例如聚氣乙烯壬苯釀 ,聚氣乙烯苯乙烯苯醴，聚氣乙烯苄笨醚，聚氣乙烯山梨糖酵酐烷酸酯，聚氧乙烯C12〜Cis脂肪酸酯等之聚氣乙烯型非離子界面活性劑；沙威諾104, 104A, 104E, 104H, TG, TG-E, PC, 61, 82, 440, 465， 485等商品名（均為空氣産物公司産品）所習知之乙炔乙二醇条界面活性劑。更且，水溶性离分子物質例如包括有，聚乙烯酵，羧甲基鐵維素，海藻酸馥，聚丙烯酸鹽，澱粉，酵素分解糊精或異番卜 1,卜2, 1-3, 2-1, 2-2, 2-3, 3-1, 3-2 ，3-3, SF-837, SP-842等商品名（均為庫拉箱，異坡蘭，化學公司産製）之習知馬來酸異丁基♦共聚物_(Ha戀 ,K蜜，“鹽，銨鹽，各種胺鹽等）。又，視製備情況，亦可使用陽離子界面活性劑或兩性 -10- (請先閲讀背而之注急事項洱填寫^ 裝- 線· 經濟部中央榣準局β工消#合作社印製本紙》•尺_度遑用中國《家《毕(CNS)肀4規格（210父297公龙） 81. 2. 20,000 ϋ974θ Λ fi li 6 經濟部中央梂準局β工消#合作社印製五、發明説明（9 ) 離子界面活性劑。以上所述界面活性劑可單玀或併合二種以上使用，其傺對100重量份之上述載龌材料，通常係使用0.1〜20 重量份，宜為0.1〜10重量份，而最好為1〜5重量份。又，本發明之粒劑組成物，傜將該粒劑組成物施用於滿水下之水田時，為能在滿水中進一步確實連鑛搛放活性成份，因應其所需，得以配合崩壤促進劑。而崩壊促進劑卽包括有，可使用氛化鈣，氯化納，氛化銨，硫酸銨，硝醚銨，無水硫酸鎂，尿素，檸樺酸，檸檬酸納，酒石酸納，》萄糖，果糖等對水呈可溶性之無機或有機質固體粉末。其中以氱化鈣，氱化納，硫酸銨，尿酸最具適用。此等崩壞促進劑的使用雖無嚴格之限制，通常對100 重量份之上述載體材料傜偽用1〜97重量份，宜為5〜90 重量份，而最佳者為10〜70重量份。更且，本發明之粒劑組成物，視其所需可適量_混以一般農藥常用之其他補助劑，例如，擴展剤，防腐爾，乳化劑，分解防止劑，固化防止劑，活性增強劑（例如大豆卵磷脂 >，又，因應其所需亦可混用乃至併用殺巖劑，粒蠘剤，殺線蟲劑，殺翹劑，抗病毒劑，誘怒劑，植物生長讕節劑，肥料等其他之農_成份。粒籲紐成物夕謳豔：本發明之粒嫌組成物，例如，得由下列方法加以製造 -1 1 - (請先閲請背而之注意事項#填寫< 裝· 線· 本紙張尺度遑用中a «家榣準(CNS)T4規格（210x297公;¢) 81. 2. 20,000 212748 Λ 6 W 6 經濟部中央#準总EC工消t合作社印製五、發明説明（10) 〇 (1>将除草活性化合物U)及油性液龌（b)以外成份，經由帶型混合機，螺旋型混合機，揑和機等之混合機或錘磨機，銷磨機，噴射磨等之粉碎機處理，均勻混合，加水由造粒機形成適當大小之粒狀，九形狀，在所播得之粒基繭含浸在可溶解乃至分散除草活性化合物（a>之油狀液體（b)之方法； (2)將油性液醱（b)以外之成份，仿上述（1)項相同之操作予以處理.使所擭得之粒基劑含浸在油性液釅 (b )之方法； (3>將油性液醱（b>之一部分及殘餘之成份仿上述（1> 項相同之操作處理方式，得粒基劑。於所謂之粒基劑含浸於殘餘之油性液體（b!之方法； (4)將全成份仿上述（1)項相同之操作方式加以處理，而播得粒劑之方法。由本發明所提供之粒劑組成物，作為水田用除草劑，在滿水狀態之水田使用手搖乃至手動或動力散粒櫬金面散佈。例如，以狗牙根為防除對象，每一公畝施用50〜 400克活性成份可完全防除自萌芽至4〜5藥期之雜草。本發明之粒劑組成物有異於一般之粒劑，既使有某程度不均勻之散佈，包含在粒劑中之油狀液龌與活性成份同時展開在田面水表層，亦能期望播得均勻之效果。又，使用本發明所用粒麵，由於和一般之粒劑不同，由於不 -12- (請先閱讀背而之注意事項丼填寫太裝< 訂線· 本紙张尺度遑用中《國家《準（CNS)f 4規格（210X297公it) 81. 2. 20,000 Λ 6 η 6 經濟部屮央標準局员工消#合作杜印製 am48 五、發明説明（11) 損及莖葉處理型組成物的活性成份效果，防止雜草所需之活性成份量，比較通常之粒赖，例如可顯箸減少1/2 〜1/8 。或者使用本發明之粒劑於施用同一活性成份量時，比較使用一般之粒劑，對於狗芽根之槃效顯著增加，可搏得安定化且能顯擴大其處理適期的幅度。其次依實施例及試驗例具體説明本發明。又資施例中之「份」偽表示「重量份」之意義。而實施例所用之除草活性化合物偽如下述。化合物编號1:甲基- 2- [4-(2 -氣-4-氱苯氣）苯氣基]丙酸酯化合物编號2:正丁基基-2-[4-(2-«-4 -氰苯氣 > 苯氣基] 丙酸酯實施例1 將木質素磺酸納3份，磺酸二辛酯1份，皂土 10份及滑石86份混合後粉碎，加水混練後，造粒乾燥，製粒成 14〜32網目之粒子得粒基劑。90份之粒基劑於預先加溫條件下含浸於1份化合物鏞號1溶解於9份酞酸二十三烷基所生成之溶液，得100份含有化合物编號1之粒劑〇實施例2 混合1份海藻酸納，1份十二苯磺酸納，1份萊磺酸鲂及97份黏土充分粉碎，加水混練後，造粒乾燦，整粒成14〜32網目得粒基_。將90份粒基_含浸在1份化合 -13- (請先閲讀背而之注意事項存填复 3 裝· 線· 本紙張尺度遑用中國《家«準(CNS)TM規格(2丨0X297公龙) 81. 2. 20,000 212748 Λ (i Η 6 經濟部中央榀準局A工消费合作社印Μ 五、發明説明（12) 物编號2溶解於9份傲酸二十三烷酯所形成之溶液，得 100份含有化合物编號2之粒劑。啻施例3 充分混合1.1份化合物编號2 , 2份聚丙烯酸銷，10 份皂土及86.9份滑石經加粉碎，加水混練後，造粒乾燥 ,整粒成14〜32網目得粒劑。將91份粒劑含浸在91份油酸甲酯得100份含有化合物编號2之粒劑。竇施例4 充分混合1份木質素磺酸納，10份皂土及89份硪酸鈣，並加以粉碎，加水混練後，造粒乾燥，整粒成14〜32 網目得粒基劑^此90份粒基劑含浸在將1份化合物编號 1於加溫條件下溶解於9份己二酸二油脂及4份環氣化脂肪酸丁酯所生成之溶液得100份含有1份化合物编號 1之粒剤。實施例5 充分混合15份氣化鈣，1份海藻酸納及84份黏土充加以粉碎，加水混練後，造粒乾燥，經整粒成14〜32網目得粒基劑。此92份粒基_含浸在將1份化合物编號2於加通條件下溶解於7份環氣化脂肪酸辛酯所生成之溶液，得100份含有1份化合物编號2之粒劑。實施例6 充分混合10份氯化納，3份酵素變性期精及87份滑土並加以粉碎，加水混練後，造粒乾燥，整粒成14〜32網 -14- (請先閲讀背而之注意事項#欢寫j 裝· 線. 本紙張尺度边用中钃Β家樣準(CNS) Τ 4規格(210X297公;¢) 81. 2. 20,000 212748 Λ (ί \\6 經濟部中央檁準局员工消#合作社印製五、發明説明（13) 目得粒基劑。此95份粒基劑含浸在將1份化合物编號1 於加溫條件下溶解於4份棕櫊脂肪酸甲酯所生成之溶液，得100份含有1份化合物編號1之粒劑。實施例7 充分混合10份檸檬酸，20份氯化鉀，1.份海藻酸納及 69份黏土並加以粉碎，加水混練後，造粒乾燥，經整粒成14〜32網目得粒基劑。此89份粒基劑含浸於將Γ份化合物编號2在加溫條件下溶解於5份肉豆寇酸異丙酯及 5份肽酸二正烷酯所生成之溶液得100份含有化合物编號2之粒劑。實施例8 充分混合1份桊磺酸納，1份磺酸二辛酯，10份皂土 ,3份白炭及85份滑土經粉碎後，加水混練後，造粒乾燥，經整粒成14〜32網目得粒基薄|。此84份粒基雨含浸在將1份化合物编號2在加溫條件下溶解於1 5份油酸甲酯所生成之溶液得100份含有1份化合物编號2之粒劑〇實施例9 充分混合40份氛化鉀，2份酵素變性糊精，2份白W ,5份皂土及51份滑石經加以粉碎，加水混練後，造粒乾燥，經整粒成14〜32網目得粒基劑。此87份粒基薄|含浸在將1份化合物纗號1在加溫條件下溶解於6份油酸甲酯及6份酞酸十三烷酯所生成之溶液得100份含有1 -15- (請先閲讀背而之注意事項孙填寫入 ) 本紙張尺度遑用中國國家搮準(CNS)肀4規格(210X297公t) 81. 2. 20,000 Λ ί) η 6 五、發明説明（14)Printed by the Ministry of Economic Affairs, Central Bureau of Standards A, and cooperated with China Consumer Goods Co., Ltd., where li represents Xuan atom, trimethyl or cyano group, Y represents radium atom or halogen atom, and R represents hydrogen atom, alkyl group, alkenyl group , Alkynyl, alkanealkyl or alkanethioalkyl (these groups should preferably have 1 to 8 dysprosium, preferably 2 to 4 dysprosium atoms), represented by phenylaminopropionic acid derivatives, of which 2 -Ci-C8 alkyl esters of [4- (2- 觎 -4-cyanobenzene) benzyloxy] propionic acid (for example, methyl ester, n-butyl ester) are most suitable. However, other herbicidal active compounds that absorb stems and leaves can also be used, for example, -5 winter paper scale, using the Chinese National Standard (CNS) TM specifications (210X297): 81. 2. 20,000 n »749 Λ 6 η 6 Economy Ministry of Central Bureau of Industry and Fisheries Cooperation Du Yin 5i 5. Description of the invention (4) 2-Methylthio-4,6-bis (ethylamino) -S-triazine, S-benzyl-1, 2-Dimethylpropyl (ethyl) thiocarbamate S-1-methyl-1-phenethyl-piperidine-1-carboxythioate, S- (4-benzyl) -N, H -Diethylthiocarbamate, 2-benzoxazol-2-yl gas-N-methylethylproline, 2-cyano-2 ', 6'-diethyl 1- (butoxymethyl Group) ethyl «, 2-chloro-2 ', 6'-diethyl-H- (2-propane ethyl) acetonitrile, 2-isopropyl-2,1,3-benzoxazinone- ( 4) -2,2-Digasification, etc. The herbicidal active compounds described above can be used alone or in combination of two or more. (b) Oily liquid mule A special feature of the granular composition of the present invention is that the herbicidal active compound in combination with the above is substantially like an oily liquid of an ester strip that is insoluble in water. This kind of ester oily liquid mole has a specific gravity of 0.80 or less than 1, preferably a range of 0.85 ~ 1 and a viscosity of less than 300 cps, preferably using a low viscosity of less than 200 cps, which is essential for the above herbicidal active compounds. The above is inactive, and the herbicidal compound is mixed to form, for example, under 25¾, it contains at least 5 weight X or more of the herbicidal active compound, and it is more suitable to use a herbicide active compound that dissolves more than 10 weight. In addition, the above-mentioned sugar bar oily liquid is most suitable for those whose vapor pressure is far away. For example, if the vapor pressure at 2 5 υ is less than 1 Pa, the one below 0.5 Pa is most advantageous. -* 6 ~ (please read the notes on the back #Fill 4 | This paper is used in the standard S »Homepage Standard (CNS) A 4 specifications (210 > < 297 public *) 81. 2. 20,000» 13748 Λ 6 Π 6 Co-production by the Ministry of Economic Affairs, the Central Bureau of Industry and Economics of Peking Co., Ltd. Du Printing V. Description of the invention (ί >) Ester oil oily liquid mollusc with the above-mentioned characteristics, in general, Li contains the following compounds (1) Higher fatty acid esters: such as methyl oleate, octyl isobutyl oleate, 2-ethylhexyl oleate, decyl oleate, lauryl oleate, oleic oleate, myristic acid Methyl ester, isopropyl myristate myristate, .isopropyl myristate, palmitate isopropyl, palmitate 2-ethylhexyl stearate, 2-ethylhexyl stearate, isodecyl stearate Trialkyl fat, methyl laurate, cetyl 2-ethylhexanoate, octadecyl erucate, methyl caprate, fatty acid methyl ester of comb oil, tallow fatty acid methyl ester, palm oval oil fatty acid methyl ester, etc. Alkyl esters of fatty acids; (2) Aliphatic or aromatic polybasic acid esters: for example, dioleyl adipate, diisobutyl adipate, diisodecyl adipate, etc. Acid bis Base ester; didecyl phthalate, tricosyl phthalate, bisphthalic phthalate, ethylhexyl phthalate, 2-ethylhexyl phthalate, dialkyl benzoic acid tri 2 -Ethylhexyl ester, triethyl trimellitate BI, benzene «tri-n-butyl triacid, polytricarboxylic acid polyalkyl ester of triisodecyl trimellitate, etc .; (3) glycerol fatty acid esters: For example, oleic monoglyceride, oleic diglyceride, sorbitan monooleate, sorbitan monolaurate, capric monoglyceride, capric diglyceride, diacetyl Decanoic acid glycerol diethylacetate coconut oil fatty acid glycerides, etc .; (4) cut gasified fatty acid esters: -7- (please read the precautions before writing 41) "Home Sample Standard (CNS) f 4 specifications (210X297 male 81. 2. 20,000 M & S4 V. Trip a Η 6 Description of invention (6) Employees of the Central Bureau of Standards of the Ministry of Economic Affairs cooperated with the du printing to produce, for example, oxidized fatty acid butyl Ester, cyclic gasification fatty acid alkyl ester. These ester oils can be used separately in these oily liquids, suitable for alkyl esters and adipic acid dioleate. , Oleic acid oleic anhydride monoole, sugar vaporized fatty acid octyl ester and other ester oily sickles, use 1 ~ 50 parts by weight for 1 part by weight (a), preferably 5 ~ 5 ~ 20 parts by weight (C > loaded materials) The carrier material used in the present invention is usually any solid material with a specific gravity of 1 used in the manufacture of granules, including gypsum, talc, bentonite, clay, etc. Limonite, montmorillonite, feldspar, quartz, silica (white solid blue powder; soybean powder, wheat flour, plant powder of tobacco, etc., which can be used in two or more types. In addition, even if its own material is formed into a granular base material, its specific gravity is 1 or more, and it is mixed with other plaque-bearing materials, such as clay, clay, clay, calcium silicate, etc., and is used in the present invention The carrier material, «the above oily liquid is the best, the oil absorption rate of fatty acid octane _ etc. is used, or a mixture of two or more is suitable, the herbicidal activity of phthalic acid twenty-three, methyl oleate, sorbose 0 25 parts by weight of the compound, and preferably contains substantially diatoms, sulfonate, powder, yibeidan> The specific gravity is a combination of granules and base materials, so that the compound can be generally manufactured for agricultural insoluble in water Inorganic powders such as soil, apatite, 0, acid clay, etc., wood powder, etc., or combined with the specific gravity of the whole carrier less than 1. Especially suitable for soap. Absorb or easy to suck 5 ~ 30X, it is best to first leap back to the precautions and fill in 8-The size of this paper uses the Chinese National Standard (CNS) 4 specifications (210X297 male dragon) 81. 2. 20,000 212748 Λ 6 Β 6 Printed in cooperation with Beigongxiao, Central Bureau of Economics, Ministry of Economic Affairs. 5. Description of Invention (7) The value is between 10 and 20S; those within the range are preferred. The oil absorption rate referred to in the present invention can be determined by the following method. Weigh accurately 10 grams of carrier material with a triangular flask, add a small amount of linseed oil, and vibrate the triangular flask to make the lamb material absorb oil. Based on the weight of the maximum oil absorption limit of the Landing carrier material for linseed oil. Finally, the triangle of the vibrating disk tilted, and the Di produced a sticking phenomenon on the bottle wall. At this time, the carrier material was embroidered and formed into a state before it did not flow. The weight of added linseed oil (g) The oil absorption rate (¾ j = --X 100% of the weight of the thin I (10g > the above mentioned load-bearing materials, for the above 1 part by weight of herbicidal active compound (a) , You can use 1 ~ 98 parts by weight, preferably 20 ~ 90 parts by weight, preferably 30 ~ 70 parts by weight. For example, suitable carrier materials are the above soap, clay, clay, calcium citrate, for 1 weight One part of the herbicidal active compound (a) can be a mixture of 30 to 60 parts by weight of bentonite and 10 to 68 parts by weight of clay, clay and / or calcium phosphate. (D) Other additives The granules of the present invention The composition, according to its needs, can be combined with surfactants and / or collapse accelerators. Surfactants can mainly use anionic or nonionic surfactants or water-soluble polymer 霣 3 anionic surfactants, such as Cu ~ Cis alkyl sulfate (Na salt, K salt, ammonium salt, various amine salts, etc.), Polyethylene (: 8 ~ 12 alkylphenyl ether sulfate (Na Fu, ammonium salt, -9- (please First read the notes on the back # 塡乔 '> \) This paper is not used in the BB «Ping (CNS) T4 specification (210X297; ) S1. 2. 20,000 Λ 6 15 6 212748 Fifth, the description of the invention (8) various amines, etc., polystyrene polyglycol propylene segmented polymer sulfates (Na salt, ammonium hydrazide, various amine salts), etc. Koji sulfate anionic surfactant; dodecanoic acid (N a salt, ammonium, various amines, etc.), mono- or di-Cs ~ C12 alkalyl sulfonic acid _ (Na salt, ammonium salt, etc.> ;, Pusulfonate (Na salt, etc.)-formalin condensate, di-C6 ~ C8 alkyl sulfosuccinate (Na salt, etc.), lignin sulfonate (Na salt, Ca salt, etc.) Acid gas strip anion interface active poly gas ethylene lauryl ether phosphate ammonium salt, polyoxyethylene gas nonyl ether phosphate sodium salt and other poly gas vinyl ether phosphate strip anion surfactant, etc .. Non-ionic interface activity Agents include, for example, polystyrene nonyl styrene, polystyrene styrene styrene, polystyrene benzyl ether, polyoxyethylene sorbitan alkanoate, polyoxyethylene C12 ~ Cis fatty acid ester, etc. Gas ethylene type non-ionic surfactant; Shavino 104, 104A, 104E, 104H, TG, TG-E, PC, 61, 82, 440, 465, 485 and other trade names (all produced by Air Products Corporation) ) Known surfactants for acetylene glycol strips. Furthermore, water-soluble ionomers include, for example, polyvinyl yeast, carboxymethyl ferricin, alginate, polyacrylate, starch, and enzyme-decomposed dextrin. Or different Fanbu 1, Bu 2, 1-3, 2-1, 2-2, 2-3, 3-1, 3-2, 3-3, SF-837, SP-842 and other trade names (all Kura box, isopolan, manufactured by the chemical company) conventional isobutyl maleate copolymer _ (Ha Lian, K honey, "salt, ammonium salt, various amine salts, etc.). Also, depending on the preparation situation, cationic surfactants or amphoteric -10- can also be used (please read the back-to-back urgent matters to fill in ^ Pack-Thread · Ministry of Economic Affairs Central Bureau of Quorum β 工消 # Cooperative printed paper " • The ruler_degree is printed in China ’s “Home” Bi (CNS) 4 specifications (210 father 297 male dragons) 81. 2. 20,000 ϋ974θ Λ fi li 6 Printed by the Central Bureau of Economic Affairs β 工消 # Cooperative Society Description (9) Ionic surfactants. The above surfactants can be used alone or in combination of two or more. For 100 parts by weight of the above-mentioned loaded materials, usually 0.1 to 20 parts by weight, preferably 0.1 to 10 parts by weight, and preferably 1 to 5 parts by weight. Furthermore, when the granule composition of the present invention is applied to a paddy field full of water under the water, it is possible to further secure the mine in the full water. The active ingredients can be combined with the soil collapse accelerator according to their needs. The collapse accelerators include the following: calcium hydroxide, sodium chloride, ammonium chloride, ammonium sulfate, ammonium nitrate, anhydrous magnesium sulfate, urea , Citric acid, sodium citrate, sodium tartrate, sugar, fructose, etc. Soluble inorganic or organic solid powder. Among them, calcium trichloride, sodium trihydroxide, ammonium sulfate, and uric acid are most suitable. Although the use of these collapse accelerators is not strictly limited, usually 100 parts by weight of the above carrier materials For falsification, 1 ~ 97 parts by weight, preferably 5 ~ 90 parts by weight, and the best one is 10 ~ 70 parts by weight. Furthermore, the granule composition of the present invention can be mixed with general pesticides in an appropriate amount depending on its needs Other commonly used supplements, such as expansion, preservatives, emulsifiers, decomposition inhibitors, solidification inhibitors, activity enhancers (such as soy lecithin), and can also be mixed or even combined with rock killers according to their needs , Grain beetle, nematicide, warping agent, antiviral agent, irritant, plant growth agent, fertilizer, and other agricultural ingredients. Granules and New Products: Xiyuyan: The composition of the invention Objects, for example, can be manufactured by the following method -1 1-(please read the notes to the back # fill in &install; line · the paper size is used in a «Home Standard (CNS) T4 specification (210x297 Public; ¢) 81. 2. 20,000 212748 Λ 6 W 6 Ministry of Economic Affairs Printed by EC Gongxiaot Cooperative V. Description of the invention (10) 〇 (1> The herbicidal active compound U) and the oily liquid (b) other ingredients, through a belt mixer, screw mixer, kneader, etc. Mixers or hammer mills, pin mills, jet mills and other pulverizers are processed and mixed evenly. Add water to form granules of appropriate size and nine shapes with granulator. The seeded cocoons impregnated in the seed are soluble and even soluble The method of dispersing the herbicidally active compound (a > oily liquid (b); (2) The components other than the oily liquid compound (b) are treated in the same manner as in item (1) above. The method of impregnating the agent with the oily liquid (b); (3> Part of the oily liquid (b >) and the remaining components are imitated by the same operation and processing method as the above item (1>) to obtain the granule base. The so-called granule base is impregnated with the residual oily liquid (b! Method); (4) The whole ingredients are processed in the same manner as in item (1) above, and the method of broadcasting granules is provided by the present invention. The granule composition is used as a herbicide for paddy fields. In a paddy field full of water, use hand-shake or manual or power to disperse the grains to disperse the gold surface. For example, using bermudagrass as the control object, apply 50 to 400 grams of activity per acre The ingredients can completely control weeds from germination to 4 ~ 5 medicinal periods. The granule composition of the present invention is different from ordinary granules, even if there is a certain degree of uneven distribution, the oily liquid contained in the granules Qiang and the active ingredients are spread on the surface of the field surface water at the same time, and it can also be expected to spread evenly. Also, the grain used in the present invention is different from the general granules, because it is not -12- (please read the notes first Matters: Fill in the Taizhang < Threading · The paper standard is used in the "National Standards (CNS) f 4 specifications (210X297 public it) 81. 2. 20,000 Λ 6 η 6 Ministry of Economic Affairs Bureau of Standards and Standardization Staff Elimination # Cooperation Du printed am48 V. Description of the invention (11) Damage to the stem The effect of the active ingredient of the treatment type composition, the amount of active ingredient required to prevent weeds, compared with the usual grains, for example, it can be significantly reduced by 1/2 to 1/8. Or use the granules of the present invention to apply the same active ingredient In comparison with the general granules, the effect on dog bud root is significantly increased, it can be stabilized and can significantly expand the range of its treatment period. Secondly, the present invention will be described in detail according to the examples and test examples. The "part" pseudo in the examples means "parts by weight". The herbicidal active compounds used in the examples are as follows. Compound No. 1: Methyl-2- [4- (2-gas-4- 氱 benzene gas ) Benzene group] propionate compound No. 2: n-butyl-2- [4- (2-«-4 -cyanobenzene gas> benzene group] propionate Example 1 The lignin sulfonic acid 3 parts of sodium, 1 part of dioctyl sulfonate, 10 parts of bentonite and 86 parts of talc are mixed and crushed, after mixing with water, granulation and drying, granulation into 14 ~ 32 mesh particles to obtain a granule base. 90 parts of granules The base was impregnated with a solution of 1 part compound Yung No. 1 dissolved in 9 parts tricalic acid phthalate under pre-heating conditions to obtain 100 parts containing Granule No. 1 of Example 0 Example 2 Mix 1 part of sodium alginate, 1 part of sodium dodecyl sulfonate, 1 part of bream lysine and 97 parts of clay, and pulverize after mixing with water. Whole grain into 14 ~ 32 mesh to get grain base_. Dip 90 parts of grain base_ into 1 part of compound-13- (please read the precautions and fill in 3 sets · thread · the paper size is not using Chinese Home «Precision (CNS) TM specifications (2 丨 0X297 male dragon) 81. 2. 20,000 212748 Λ (i Η 6 Printed by the Ministry of Economic Affairs Central Bureau of Industry and Commerce A Industrial and Consumer Cooperatives. V. Description of the invention (12) Article number 2 dissolved In 9 parts of a solution of tricosyl aurate, 100 parts of granules containing Compound No. 2 were obtained. Example 3 Fully mix 1.1 parts of compound No. 2, 2 parts of polyacrylic acid pin, 10 parts of bentonite and 86.9 parts of talc are crushed, mixed with water, granulated and dried, and granulated into 14-32 mesh granules. 91 parts of granules were impregnated with 91 parts of methyl oleate to obtain 100 parts of granules containing compound number 2. Dou Shi 4 Fully mix 1 part sodium lignosulfonate, 10 parts bentonite and 89 parts calcium citrate, and pulverize, after adding water to knead, granulate and dry, the whole granule is 14 ~ 32 mesh to get the granule base ^ this 90 parts of the granule base is impregnated with a solution of 1 part of compound number 1 dissolved in 9 parts of adipic acid diglyceride and 4 parts of cyclic vaporized fatty acid butyl ester under heating conditions to obtain 100 parts containing 1 part of compound number 1 grain. Example 5 Fifteen parts of vaporized calcium, 1 part of sodium alginate and 84 parts of clay were added and crushed. After mixing with water, the granules were dried and granulated into 14-32 meshes to obtain a granule base. The 92 parts of granules were impregnated with a solution of 1 part of compound number 2 dissolved in 7 parts of cyclic vaporized fatty acid octyl ester under addition conditions to obtain 100 parts of granules containing 1 part of compound number 2. Example 6 Fully mix 10 parts of sodium chloride, 3 parts of enzyme-denatured stage fines and 87 parts of soil and crush them. After mixing with water, granulate and dry to make the whole into 14 ~ 32 net-14- (please read the back first之 notes # 欢写 j 装 · 线. This paper is used on the side of the standard (CNS) Τ 4 specifications (210X297; ¢) 81. 2. 20,000 212748 Λ (ί \\ 6 Central Purlin of the Ministry of Economic Affairs Printed by the quasi-bureau employee Xiao # Cooperative V. Description of the invention (13) Obtained the granule base. This 95 parts granule base is impregnated with 1 part compound number 1 dissolved in 4 parts palm fat fatty acid methyl ester under heating conditions The resulting solution yielded 100 parts of granules containing 1 part of compound number 1. Example 7 10 parts of citric acid, 20 parts of potassium chloride, 1. parts of sodium alginate and 69 parts of clay were thoroughly mixed and pulverized, and kneaded with water After granulation and drying, the granules are made into 14 ~ 32 meshes to obtain a granule base. 89 parts of the granule base are impregnated with Γ part of compound number 2 dissolved in 5 parts of isopropyl myristate under heating conditions And 5 parts of the resulting solution of peptide acid di-n-alkyl ester to obtain 100 parts of granules containing compound number 2. Example 8 1 part of sodium sulfonate and 1 part of sulfonic acid were thoroughly mixed Octyl ester, 10 parts of bentonite, 3 parts of white carbon and 85 parts of slippery soil are crushed, mixed with water, granulated and dried, and adjusted into 14 ~ 32 mesh to obtain a thin base |. This 84 parts of base rain is impregnated in 1 part of Compound No. 2 was dissolved in 15 parts of methyl oleate solution under heating to obtain 100 parts of granules containing 1 part of Compound No. 2. Example 9 40 parts of potassium oxychloride were mixed thoroughly, 2 parts of enzyme-denatured dextrin, 2 parts of white W, 5 parts of bentonite and 51 parts of talc are crushed, mixed with water, granulated and dried, and granulated into 14 ~ 32 mesh to obtain a granular base. The 87 parts of granular base Thin | Immersed in a solution formed by dissolving 1 part of compound No. 1 in 6 parts of methyl oleate and 6 parts of tridecyl phthalate under heating conditions to get 100 parts containing 1 -15- (please read the back (Note that Sun fills in) This paper uses the Chinese National Standards (CNS) 4 specifications (210X297 g) 81. 2. 20,000 Λ ί) η 6 V. Description of the invention (14)

(請先閱讀背而之注意~#項#-填農S 份化合物编號1之粒劑。實施例10 充分混合20份氛化納，25份氛化1份海藻酸納及 54份鲇土並加以粉碎，加水涯練後，造粒乾燥，經整粒成14〜32網目得粒基赖。此90份粒基劑含漫在將1份化合物编號1在加溫條件下溶解於4份油酸甲酯，4份酞酸十三烷酯及〗份油酸辛酷所生成之溶液得100份含有 1份化合物编號2之粒劑。實施例1 1 充分混合1份聚丙烯酸納，1份聚氣乙烯烷苯醚硫酸酯銨鹽，3份酵素變性糊精，3份乙醯基乙二酵糸活性商（[Sulfanal TG-E(空氣産物公司商標>],30份皂土以及62份黏土並加以粉碎，加水混練後，造粒乾燥，經整粒成14〜32網目得粒基_。此90份粒基_含浸在將1份化合物蹁號1經加溫條件下溶解於9份酞酸二十三烷基所生成之溶液得100份含有1份化合物编號2之粒劑。實施例12 經濟部屮央橾準局员工消货合作社印製充分混合1份聚丙烯酸納，1份聚氣乙烯烷苯醚硫酸酯銨邇，3份酵素變性糊精，3份馬來酸異了酯共聚物条活性劑[異番卜2(庫拉禮，異坡菌-化學公司商檫）], 30份皂土及62份黏土並加以粉碎，加水混練後，造粒乾燥，經整粒成14〜32網目得粒基劑。此93份粒基劑含浸在将1份化合物鏞號2在加溫條件下溶解於6份酞酸二(Please read the notes first ~ # 项 # -Filling S parts of Compound No. 1 granules. Example 10 20 parts of chlorinated sodium, 25 parts of 1 part of alginate and 54 parts of catfish soil are thoroughly mixed And crushed, after adding water to practice, granulation and drying, after granulation into 14 ~ 32 mesh to obtain granules. This 90 parts of granule base contains 1 part of compound number 1 dissolved in 4 under heating conditions One part of methyl oleate, four parts of tridecyl phthalate, and one part of octyl oleate produced 100 parts of granules containing 1 part of compound number 2. Example 1 1 1 part of sodium polyacrylate was thoroughly mixed, 1 part ammonium salt of polyoxyethylene alkylphenyl ether sulfate, 3 parts denatured dextrin of enzyme, 3 parts active agent of acetyl-glyphosate ([Sulfanal TG-E (Trademark of Air Products Co., Ltd.)], 30 parts bentonite And 62 parts of clay are crushed, mixed with water, kneaded, granulated and dried, and granulated into 14 ~ 32 mesh to obtain a particle base. This 90 parts of particle base_ is impregnated with 1 part of compound No. 1 dissolved under heating conditions A solution of 9 parts of trityl phthalate yielded 100 parts of granules containing 1 part of compound number 2. Example 12 Employee Consumer Goods Cooperative of Biyang Bureau, Ministry of Economic Affairs Fully mix 1 part of polyacrylic acid sodium, 1 part of polyoxyethylene alkyl phenyl ether ether ammonium sulfate, 3 parts of enzyme denatured dextrin, 3 parts of maleic acid isoester copolymer active agent [isofanb 2 (Kura Li, Heterobacteria-Chemical Co., Ltd. (Sassafras)), 30 parts of bentonite and 62 parts of clay are crushed, mixed with water, granulated and dried, and granulated into 14 ~ 32 mesh to obtain a granule base. These 93 parts of granules Base is impregnated with 1 part compound Yung No. 2 dissolved in 6 parts phthalic acid

I -16- 本紙ft尺度遑用中B國家«準（CNS) «Ρ4規格（210x297公货） 81· 2. 20,000 212748 Λ 6 It 6 經濟部屮央標準而员工消费合作社印製五、發明説明（.15) 十三烷酯所生成之溶液得100份含有1份化合物编號2 之粒劑。實施例13 充分混合1份聚丙烯酸納，1份聚氣乙烯烷苯醚硫酸酯銨3份酵素變性期精，3份萊磺酸銪，30份皂土及62份黏土並加以粉碎，加水混練後，迪粒乾燥，經整粒成14〜32網目得粒基劑。此90份粒基劑含浸在1份化合物編號2於加溫條件下溶解於9份酞酸二十三烷醏所生成之溶液得100份含有1份化合物编號2之粒_。實施例14 充分混合3份木霣素磺酸納，1份十二烷苯磺酸 60份皂土及36你滑土並加以粉碎，加水混練，造粒乾燥，經整粒成14〜32網目得粒基劑，此90份粒基劑即含浸在將1份化合物縝號1於加溫條件下溶解於9份油酸甲酯所生成之溶液得100份含有1份化合物軀號1之粒劑〇比較例1 在實施例1之組成份中不使用酞酸二十三烷酯，將99 份粒基劑含浸在用丙酮溶解1份化合物编號1所生成之溶液，將丙嗣揮發得100份含有1份化合物缳號1之粒劑。比較例2 在實施例2之組成份中不使用酞酸二十三烷酯，將99 (請先閲讀背而之注意爭項外塡3>1) 本紙張尺度遑用中《Β家«毕(CNS)T4規格(210X297公#) 81. 2. 20,000 Λ 6 Η 6 五、發明説明（16) 份粒基劑含浸在以丙酮溶解1份化合物編號2所生成之溶液，将丙酮揮發得100份含有1份化合物繙號2之粒劑。比較例3 在實施例3的組成份中，不使用油酸甲酯而改用1份化合物编號2及87份滑土得100份含有1份化合物编號 2之粒薄I。比較例4 在實施例4的組成份中，不使用己二酸油酯及琿氣化脂肪酸丁酯，而將99份粒基劑含浸在1份化合物编號1 溶解於丙酮所生成之溶液，將丙酮揮散得100份含有1 份化合物编號1之粒剤。比較例5 在實施例5的組成份中，不使用環氣化脂肪酸辛酯，而將99份粒基劑含浸在1份化合物编號2溶解於丙酮所生成之溶液，揮散丙醑得100份含有1份化合物编號2 之粒劑。比較例6 經濟部中央橾準局员工消"合作社印製 (請先閲請背而之注意苹項#塡寫^.) 在實施例6的組成份中，不使用棕檷脂肪酸甲酯，而將份粒基_含浸在1份化合物编號1溶解於丙酮所生成之溶液，揮散丙酮得100份含有1份化合物《號1之粒劑。比較例7 - -1 8 - 本紙張尺度遑用中a國家樣毕(CNS) «Ρ4規格(2丨0X297公*) 81. 2. 20,〇〇〇 212748 五、發明説明（17) 經濟部中央櫺準局员工消费合作社印製在實施例 99份粒基劑之溶液，揮劑〇比較例8 在實施例粒基劑含浸液，揮散丙比較例9 在實施例烷酯，而將丙酮所生成编號1之粒比較例1 0 在實施例烷酯及油酸號2溶解在 1份化合物比較例11 在實施例 99份粒基劑之溶液，揮劑。 7的組成份中，不使用酞酸二正烷酯，而將含浸在1份化合物编號2溶解於丙副所生成散丙酮得100份含有1份化合物纗獷2之粒 8之組成份中，不使用油酸甲酯，而將99份在1份化合物缠號2溶解在丙酮所生成之溶酮得100份含有1份化合物编號2之粒劑。 9之組成份中，不使用油酸甲酯及酞酸十三 99份粒基劑含浸在1份化合物編號1溶解在之溶液，揮散丙酮得100份含有1份化合物剤。 1 0之組成份中，不使用油酸甲酯，酞酸十三辛酯，而將99份粒基劑含浸在1份化合物编丙酮所生成之溶液，揮散丙釅得100份含有编號2之粒劑。 11之組成份中，不使用酞酸+三烷酯，而將含浸在1份化合物編號2溶解在丙酮所生成散丙酮得100份含有1份化合物编號2之粒 -19- 本蛛張又度遑用中《國家楳平（CNS) T4規格（210X297公龙) 81. 2. 20,000 先閲讀背而之注意事項填. 寫五、發明説明（18) 比較例1 2 在實施例12之組成份中，不使用酞酸二十三烷酯，而将99份粒基劑含浸在1份化合物编號2溶解在丙_所生成之溶液，揮散丙_得100份含有1份化合物編號2之粒劑。比較例1 3 在實施例13之組成份中，不使用酞酸二十三烷而將99份粒基劑含浸在1份化合物编號2溶解在丙請所生、成之溶液，揮散化合物得100份含有1份化合物编號2 之粒薄I。比較例1 4 在實施例14之組成份中，不使用油酸甲酯，而將99份粒基劑含浸在1份化合物编號1溶解在丙酮所生成之溶液，揮散丙_得100份含有1份化合物编號1之粒劑。比較例1 5 經濟部中央櫺準局貝工消费合作社印製 (請先閲讀背而之注意事項孙填寫义 ) 在.實施例15之組成份中，不使用肽酸二十三烷而將99份粒基劑含浸在1份化合物編號2溶解在丙酮所生成之溶液，揮散丙酮得100份含有1份化合物编號2之粒剤。試驗例1 将加入預定董肥料之水田土禳（壤植土）500克（以乾土為計）裝《在直徑13cm之塑醪体中，灌充以自來水，作成水田狀態。移植2株稻苗，每株有三棵幼苗，同時播 -20- 本紙Λ尺度遑用中國Η家«準(CNS) <P 4規格(210X297公;it) 81. 2. 20,000 21^74^ 五、發明説明（19) 逹於效到對草根錄殺芽記之狗察現笛觀呈 C 後所顆週根 5 二芽約，狗子劑於捶粒對 5ΜΠ 根之察 c 芽量觀示狗定後所之預週 1 理以 4 表處佈於下穿散.以催，害如過時藥果經期之結以藥株 c 種 1 稻果I -16- The ft scale of this paper is in the B country «quasi (CNS)« P4 specification (210x297 public goods) 81 · 2. 20,000 212748 Λ 6 It 6 Standards issued by the Ministry of Economics and printed by the employee consumer cooperative V. Description of the invention (.15) The solution of tridecyl ester yields 100 parts of granules containing 1 part of compound number 2. Example 13 1 part of polyacrylic acid sodium, 1 part of poly (vinyl alkane ether sulfate ammonium ester), 3 parts of enzyme denatured sperm, 3 parts of europium sulfonate, 30 parts of bentonite and 62 parts of clay were crushed and mixed with water Afterwards, the granules are dried and granulated into 14 ~ 32 meshes to obtain granule base. This 90 parts of granule base was impregnated with 1 part of compound number 2 dissolved in 9 parts of phthalic acid phthalic acid under heating conditions to obtain 100 parts of granules containing 1 part of compound number 2. Example 14 Fully mix 3 parts of sodium mayophylsulfonate, 1 part of dodecanebenzenesulfonic acid, 60 parts of bentonite, and 36 pulverized soil and pulverize them, add water to knead, granulate and dry, and make into 14 ~ 32 mesh A granule base is obtained. This 90 parts granule base is impregnated with a solution formed by dissolving 1 part Compound No. 1 in 9 parts methyl oleate under heating conditions to obtain 100 parts containing 1 part Compound No. 1 Agent 〇Comparative Example 1 In the composition of Example 1, tricalyl phthalate was not used, and 99 parts of the granule base was impregnated with a solution of 1 part of Compound No. 1 dissolved in acetone, and the propylene was volatilized. 100 parts containing 1 part of compound No. 1 granules. Comparative Example 2 In the composition of Example 2, tricalyl phthalate is not used, and 99 (please read first and pay attention to the content of the foreign language 3> 1). (CNS) T4 specification (210X297 公 #) 81. 2. 20,000 Λ 6 Η 6 V. Description of the invention (16) A portion of the granule base is impregnated with a solution generated by dissolving 1 part of Compound No. 2 in acetone, and the acetone is volatilized to obtain 100 One part contains 1 part of compound number 2 granules. Comparative Example 3 In the composition of Example 3, instead of using methyl oleate, 1 part of Compound No. 2 and 87 parts of clay were used to obtain 100 parts of Granule I containing 1 part of Compound No. 2. Comparative Example 4 In the composition of Example 4, instead of using oleic adipic acid ester and butylated fatty acid butyl ester, 99 parts of granule base was impregnated with 1 part of Compound No. 1 and dissolved in acetone. Evaporate acetone to obtain 100 parts of the granules containing 1 part of compound number 1. Comparative Example 5 In the composition of Example 5, instead of using cyclic vaporized fatty acid octyl ester, 99 parts of the granule base was impregnated with 1 part of Compound No. 2 and dissolved in acetone to dissolve 100 parts of propylene oxide. Contains 1 part Compound No. 2 granules. Comparative Example 6 Printed by the Cooperative Society of the Central Ministry of Economic Affairs of the Ministry of Economic Affairs (please read first, please note 張项 # 塡写 ^.) In the composition of Example 6, palmetate fatty acid methyl ester is not used, The granule base is impregnated with 1 part of the compound No. 1 solution dissolved in acetone, and the acetone is evaporated to obtain 100 parts of the granule containing 1 part of the compound No. 1. Comparative Example 7--1 8-This paper uses the National Standards (CNS) «P4 Specification (2 丨 0X297 g *) 81. 2. 20, 200,212,748 V. Description of the invention (17) Ministry of Economic Affairs Printed by the Central Bureau of Employee's Consumer Cooperative in 99 parts of the solution of the granular base in Example 1 and the volatile agent. Comparative Example 8 Comparative Example 1 of the granule No. 1 was produced. In Example 1, the alkyl ester and oleic acid No. 2 were dissolved in 1 part of the compound. Comparative Example 11 In the solution of 99 parts of the granular base in Example, the agent was swept. 7 components, without using di-n-alkyl phthalate, and impregnated with 1 part of compound number 2 dissolved in propylene to produce 100 parts of acetone containing 100 parts of 1 part compound Instead of using methyl oleate, 99 parts of ketone dissolved in 1 part of compound No. 2 dissolved in acetone yielded 100 parts of granules containing 1 part of compound number 2. Among the components of 9, do not use methyl oleate and thirteen phthalic acid. 99 parts of granule base is impregnated with 1 part of compound No. 1 dissolved in the solution, and 100 parts containing 1 part of compound can be obtained by dispersing acetone. In the composition of 10, instead of using methyl oleate and tridecyl phthalate, 99 parts of the granule base is impregnated with 1 part of the compound to produce a solution of acetone, and 100 parts of No. 2 are obtained by dispersing propylene. Granules. 11 components, instead of using phthalic acid + trialkyl ester, and impregnated with 1 part of compound number 2 dissolved in acetone to produce 100 parts of acetone containing 1 part of compound number 2 Do not use "China National Ping (CNS) T4 specification (210X297 male dragon) 81. 2. 20,000 read the notes before filling in. Write five, description of the invention (18) Comparative Example 1 2 Composition in Example 12 In one part, instead of using tricalyl phthalate, 99 parts of granule base is impregnated with 1 part of compound No. 2 dissolved in the solution of propylene, and 100 parts containing 1 part of compound no. Granules. Comparative Example 1 3 In the composition of Example 13, 99 parts of granule base was impregnated with 1 part of compound number 2 without using tricalic acid phthalate, and dissolved in a solution produced and produced by Bing Please disperse the compound. 100 parts contains 1 part of the thin film I of compound number 2. Comparative Example 14 In the composition of Example 14, instead of using methyl oleate, 99 parts of the granule base was impregnated with 1 part of Compound No. 1 and dissolved in acetone to dissolve the propylene to obtain 100 parts. 1 part Compound No. 1 granule. Comparative Example 1 5 Printed by the Beigong Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs (please read the precautions to be filled out by Sun Sunyi). In the composition of Example 15, instead of using the peptide acid tricosane, 99 One part of the granule base is impregnated with 1 part of the solution of Compound No. 2 dissolved in acetone, and acetone is evaporated to give 100 parts of the granule containing 1 part of Compound No. 2. Test Example 1 500 g of paddy field soil (loam soil) added with a predetermined Dong fertilizer (calculated as dry soil) was filled into a plastic mash with a diameter of 13 cm and filled with tap water to make a paddy field state. Transplant 2 rice seedlings, each plant has three seedlings, and sow at the same time -20- This paper uses Λ scale to use the Chinese HJZ (CNS) < P 4 specifications (210X297; it) 81. 2. 20,000 21 ^ 74 ^ V. Description of the invention (19) The effect of the dog's observation on the roots of the shoots recorded on the roots of the grass roots is C. The roots of the roots are about 2 buds after the C. After the dog is set, the pre-week 1 should be distributed on the bottom of the table in 4 places. To remind, such as the outdated medicinal fruit menstrual period, the medicinal plant c species 1 rice fruit

..... ...............^.....# & (請先閲請背而之注意事項#填寫< G 經濟部屮央標準扃CX工消#合作杜印製本紙張尺度逍用中B國家樣準(CNS) 規格(210X297公故) 81. 2. 20,000 212748 Λ f> 15 6 五、發明説明（20) 經濟部中央標準局员工消费合作社印製供試蕖劑處理量粒劑kg/ΙΟ公畝稻蕖害《α) 殺草效果*2) 由實施例1 3 0 5 所得之粒_ 1.5 0 5 0.75 0 4 由實施例5 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例6 3 0 5 所得之粒爾 1.5 0 5 0.75 0 5 由實施例12 3 0 5 所得之粒劑 1 .5 0 5 0.75 0 5 由實施例14 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由比較例1 3 0 4 所得之粒劑 1.5 0 3 0.75 0 1 由比較例5 3 0 5 所得之粒劑 1.5 0 4 0.75 0 2 由比較例6 3 0 4 所得之粒劑 1.5 0 3 0.75 0 2 由比較例12 3 0 5 所得之粒劑 1.5 0 3 0.75 0 2 由比較例14 3 0 4 所得之粒劑 1.5 0 3 0.75 0 1 *1)稻SI害：0-無機蕖害〜5-發育抑制率在50Χ以上 ϊ=2)殺草效果：0-無症狀〜5-完全枯死 -22- (請先閲ϊίί背而之注意事項#蜞寫《Ϊ) 裝· 訂' 線- 本紙ft尺度遑用中國國家«準(CNS)T4規格(210X297公货) 81. 2. 20,000 21S748 Λ 6 Π () 五、發明説明（21) 試驗例2仿試驗例1相同方法栽培稻子和狗芽根，當狗芽根到逹2藥期時用_劑處理，並進行相同之觀察。所播得結果如表2所示。 (請先閲讀背而之注意事項#_填寫{?) 經濟部屮央楳準而ΕΧ工消#合作社印t 本紙徕尺度遑用中《明家楳毕(CNS) T4規格(210X297公*) 81. 2. 20,000 23 212748 Λ () η 6 五、發明説明（22) 經濟部屮央榣準局β工消t合作杜印製表1 供試麵ϋ 處理量粒《ί kg/ΙΟ公畝稻蕖害殺草效果由實施例1 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例2 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例3 3 0 5 所得之粒劑 1.5 0 5 0.75 0 4 由實施例4 3 0 5 所得之粒_ 1.5 0 5 0.75 0 4 由實施例5 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例6 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例7 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例8 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例9 3 0 5 所得之粒爾 1.5 0 5 0.75 0 5 —24— 本紙張尺度逍用中《明家榣準(CNS>T4規格(210X297公；Jt) 81. 2. 20,000 212748 五、發明説明（2 3) 經濟部中央檑準局员工消费合作社印製轰鑛）供試藥劑處9 S 粒劑kg/ΙΟ公畝稻槩害殺草效果由實施例10 3 0 5 所得之粒爾 1.5 0 5 0.75 0 5 由實施例11 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例13 3 0 5 所得之粒劑 1 . 5 0 5 0.75 0 4 由實施例15 3 0 5 .所得之粒劑 1.5 0 5 0.75 0 4 由比較例1 3 0 3 所得之粒剤 1.5 0 3 0.75 0 1 由比較例2 3 0 4 所得之粒劑 1.5 0 3 0.75 0 1 由比較例3 3 0 4 所得之粒劑 1.5 0 3 0.75 0 2 由Η:較例4 3 0 4 所得之粒劑 1.5 0 3 0.75 0 1 由比較例5 3 0 4 所得之粒劑 1 . 5 0 3 0.75 0 2 -25- 本紙》尺度边用中B Η家標準(CNS) T4規格(210x297公;!t) 81. 2. 20,000 五、發明説明（24) Λ 6 Π 6 轰鑲）供試蕖劑處理量粒劑kg/ΙΟ公畝稻義害殺草效果由比較例6 3 0 3 所得之粒劑 1.5 0 3 0.75 0 1 由比較例7 3 0 4 所得之粒_ 1.5 0 3 0.75 0 1 由比較例8 3 0 4 所得之粒_ 1.5 0 2 0.75 0 2 由比較例10 3 0 4 所得之粒劑 1.5 0 3 0.75 0 2 試驗例3 仿試驗例1相同方法栽培稻子和狗穿根，當狗芽根到逹3葉期時，用蕖劑處理，並進行相同之觀察。所得結果如表3所示。 (請先聞讀背而之注意事項#^- 線- 經濟部中央櫺準局3工消费合作社印製 -26- 本紙张尺度逍用中B Η家«毕(CNS)T4規格(210x297公*) 81. 2. 20,000....................... ^ ..... # & (please read the notes to the back #Fill in < G Ministry of Economic Affairs Standard Standard CX 工消 #Cooperate to print the paper size of the paper. The national B standard (CNS) specifications (210X297 official) 81. 2. 20,000 212748 Λ f > 15 6 V. Description of invention (20) Central Bureau of Standards, Ministry of Economic Affairs Employee Consumer Cooperatives print trial doses of grains / kg / ΙΟ acres of rice roots for trial use. "Α) Herbicidal effect * 2) Pellets obtained from Example 1 3 0 5 _ 1.5 0 5 0.75 0 4 From examples 5 3 0 5 Granules obtained 1.5 0 5 0.75 0 5 Granules obtained from Example 6 3 0 5 1.5 0 5 0.75 0 5 Granules obtained from Example 12 3 0 5 1.5 0 5 0.75 0 5 Granules obtained from Example 14 3 0 5 1.5 0 5 0.75 0 5 Granules obtained from Comparative Example 1 3 0 4 1.5 0 3 0.75 0 1 Granules obtained from Comparative Example 5 3 0 5 1.5 0 4 0.75 0 2 Granules obtained from Comparative Example 6 3 0 4 1.5 0 3 0.75 0 2 Granules obtained from Comparative Example 12 3 0 5 1.5 0 3 0.75 0 2 Granules obtained from Comparative Example 14 3 0 4 1.5 0 3 0.75 0 1 * 1) Rice SI damage: 0-inorganic damage ~ 5-inhibition of development The production rate is above 50Χ ϊ = 2) Herbicidal effect: 0- asymptomatic ~ 5-completely withered-22- (please read ϊίί while the precautions # 蜞写《Ϊ）装 · 定 '线-本纸 ftoti Using Chinese National Standard (CNS) T4 (210X297 public goods) 81. 2. 20,000 21S748 Λ 6 Π () V. Description of the invention (21) Test example 2 Imitate test example 1 to cultivate rice and dog bud root When the dog bud root reached the 2nd drug period, it was treated with the agent and the same observation was made. The broadcasted results are shown in Table 2. (Please read the back-end precautions # _Fill in (?)) Ministry of Economic Affairs 屮央泳准而 ΕΧ 工消 # Cooperative society printed t This paper is used in the standard "Ming Jiayu Bi (CNS) T4 specification (210X297 public *) 81. 2. 20,000 23 212748 Λ () η 6 V. Description of the invention (22) The Ministry of Economic Affairs, the Central Bureau of Economics and Trade, β Gong Xiaot, co-operation, du printing and printing of the table 1 for the interview. Ϋ kg / ΙΟ acres The effect of rice stalks on killing grasses The granules obtained from Example 1 3 0 5 1.5 0 5 0.75 0 5 The granules obtained from Example 2 3 0 5 1.5 0 5 0.75 0 5 The granules obtained from Example 3 3 0 5 Agent 1.5 0 5 0.75 0 4 Granules obtained from Example 4 3 0 5 _ 1.5 0 5 0.75 0 4 Granules obtained from Example 5 3 0 5 1.5 0 5 0.75 0 5 Granulated from Example 6 3 0 5 Granules 1.5 0 5 0.75 0 5 Granules obtained from Example 7 3 0 5 1.5 0 5 0.75 0 5 Granules obtained from Example 8 3 0 5 1.5 0 5 0.75 0 5 Obtained from Example 9 3 0 5 Zhilier 1.5 0 5 0.75 0 5 —24— In this paper standard, "Ming Jiayu Zhun (CNS> T4 specification (210X297; Jt) 81. 2. 20,000 212748 V. Invention description (2 3) in Printed by Bengkuang, the Consumers ’Cooperative of the Bureau of Quality Control) 9 S granules kg / ΙΟ acres of rice chaff killing herbicidal effect of the test pharmacy from Example 10 3 0 5 The obtained grain size 1.5 0 5 0.75 0 5 by example 11 3 0 5 Granules obtained 1.5 0 5 0.75 0 5 Granules obtained from Example 13 3 0 5 1. 5 0 5 0.75 0 4 Granules obtained from Example 15 3 0 5. Granules obtained from Example 15 3 0 5. 1.5 0 5 0.75 0 4 Granules obtained from Comparative Example 1 3 0 3 1.5 0 3 0.75 0 1 Granules obtained from Comparative Example 2 3 0 4 1.5 0 3 0.75 0 1 Granules obtained from Comparative Example 3 3 0 4 1.5 0 3 0.75 0 2 Granules obtained from Η: Comparative Example 4 3 0 4 1.5 0 3 0.75 0 1 Granules obtained from Comparative Example 5 3 0 4 1. 5 0 3 0.75 0 2 -25- Original Paper》 Scale Side Use B Η Standard (CNS) T4 specification (210x297 g;! T) 81. 2. 20,000 V. Description of the invention (24) Λ 6 Π 6 bombardment) The amount of granule kg / ΙΟ acre for rice treatment Herbicidal effect Granules obtained from Comparative Example 6 3 0 3 1.5 0 3 0.75 0 1 Granules obtained from Comparative Example 7 3 0 4 _ 1.5 0 3 0.75 0 1 Granules obtained from Comparative Example 8 3 0 4 _ 1.5 0 2 0.75 0 2 The granules obtained from Comparative Example 10 3 0 4 1.5 0 3 0.75 0 2 Test Example 3 Rice and dog roots were cultivated in the same way as Test Example 1, and when the dog bud root reached the 3-leaf stage, it was treated with a chewing agent, and Make the same observation. The results are shown in Table 3. (Please read the notes on the back # ^-Line-Printed by the Central Bureau of Economic Affairs, Ministry of Economic Affairs, 3 Industrial and Consumer Cooperatives -26- This paper standard is used in the B Η 家 «Bi (CNS) T4 specification (210x297 g * ) 81. 2. 20,000

8 4 Γ-9. 4 A 經濟部中央櫺準局员工消t合作杜印Μ 五、發明説明（25) 供試藥劑處理量粒劑kg/ΙΟ公畝稻藥害殺草效果由實施例1 3 0 5 所得之粒_ 1.5 0 5 0.75 0 4 由實施例2 3 0 5 所得之粒劑 1,5 0 5 0.75 0 5 由實施例3 3 0 5 所得之粒劑 1.5 0 5 0.75 0 4 , 由實施例4 3 0 5 所得之粒劑 1.5 0 5 0.75 0 4 由實施例7 3 0 5 所得之粒劑 1 . 5 0 5 0.75 0 5 由實施例10 3 0 5 所得之粒劑】.5 0 5 0.75 0 5 由實施例11 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由實施例13 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 由資施例15 3 0 5 所得之粒劑 1.5 0 5 0.75 0 5 一 27 — 本Λ»尺度逍用中國鷗家«毕(CNS) 1Μ規格(210X297公釐) 81. 2. 20,000 (請先閱讀背而之注意事項#.填J3 212748 A 6 Π 6 五、發明説明（26)8 4 Γ-9. 4 A Cooperation between employees of the Central Bureau of Economic Development of the Ministry of Economic Affairs Du Yin M 5. Description of the invention (25) The amount of grains tested kg / ΙΟ acres of rice pesticides for herbicide efficacy 3 0 5 granules obtained_ 1.5 0 5 0.75 0 4 Granules obtained from Example 2 3 0 5 1,5 0 5 0.75 0 5 Granules obtained from Example 3 3 0 5 1.5 0 5 0.75 0 4, Granules obtained from Example 4 3 0 5 1. 5 0 5 0.75 0 4 Granules obtained from Example 7 3 0 5 1. 5 0 5 0.75 0 5 Granules obtained from Example 10 3 0 5] .5 0 5 0.75 0 5 Granules obtained from Example 11 3 0 5 1.5 0 5 0.75 0 5 Granules obtained from Example 13 3 0 5 1.5 0 5 0.75 0 5 Granules obtained from Zi Shi 15 3 0 5 Agent 1.5 0 5 0.75 0 5-27 — This Λ »scale is easy to use Chinese Oujia« Bi (CNS) 1Μ specification (210X297 mm) 81. 2. 20,000 (please read the notes on the back #fill J3 212748 A 6 Π 6 5. Description of the invention (26)

經濟部中央#準局员工消t合作杜印M 紅（鑛> 供試_劑處理量粒劑kg/ΙΟ公畝稻藥害殺草效果由比較例1 3 0 3 所得之粒劑 1.5 0 2 0.75 0 1 由比較例2 3 0 4 所得之粒劑 1.5 0 2 0.75 0 1 由比較例3 3 0 4 所得之粒劑 1.5 0 3 0.75 0 2 由比較例4 3 0 3 所得之粒劑 1.5 0 3 0.75 0 0 由比較例7 3 0 4 所得之粒劑 1.5 0 3 0.75 0 1 由比較例10 3 0 3 所得之粒劑 1.5 0 3 0.75 0 2 由比較例11 3 0 4 所得之粒劑 1.5 0 3 0.75 0 2 由比較例13 3 0 4 所得之粒劑 1.5 0 2 0.75 0 1 由比較例15 3 0 4 所得之粒劑 1.5 0 3 0.75 0 2 —28— (請先Ml讀背而之注意事項#塡穷{ H) 裝. 訂線· 本紙張疋度遑用中騙國家«準(CNS)肀4規格(210X297公*) 81. 2. 20,000 Λ () Β 6 五、發明説明（27) 試驗例4 仿試驗例1相同方法栽培稻子和狗芽根，當狗芽根到達4葉期時，用麵劑處理，並進行相同之觀察。結果如表4所示。 (請先閲讀背而之注意事項#-塡農 3 經濟部屮央#準局K3C工消伢合作社印製本紙张尺度遑用中国《家«半(0邶）1^規格(210父297公*) 81. 2. 20,000 aia#8 經濟部屮央橾準局员工消货合作社印製五、發明説明（28) 供試藥劑處理量粒劑kg/ΙΟ公畝稻麵害殺草效果由實施例2 4 0 5 所得之粒劑 2 0 4 1 0 2 由實施例6 .4 0 5 所得之粒劑 2 0 4 1 0 1 由實施例11 4 0 5 所得之粒劑 2 0 4 1 0 3 由實施例15 4 0 5 所得之粒劑 2 0 4 1 0 3 由比較例2 4 0 3 所得之粒劑 2 0 2 1 0 0 由比較例6 4 0 3 所得之粒劑 2 0 2 1 0 0 由比較例11 4 0 3 所得之粒劑 2 0 2 1 0 1 由比較例15 4 0 3 所得之粒劑 2 0 2 1 0 1 先閲讀背而之注事項裝玎線本紙張尺度边用中國B家樣準(CNS)甲4規格(210X297公;ft) 81. 20,000Ministry of Economic Affairs Central # quasi-bureau employee elimination cooperation Du Yin M red (mine> test_agent processing amount of granules kg / ΙΟ acres of rice phytotoxicity and herbicidal effect The granules obtained from Comparative Example 1 3 0 3 1.5 0 2 0.75 0 1 Granules obtained from Comparative Example 2 3 0 4 1.5 0 2 0.75 0 1 Granules obtained from Comparative Example 3 3 0 4 1.5 0 3 0.75 0 2 Granules obtained from Comparative Example 4 3 0 3 0 3 0.75 0 0 Granules obtained from Comparative Example 7 3 0 4 1.5 0 3 0.75 0 1 Granules obtained from Comparative Example 10 3 0 3 1.5 0 3 0.75 0 2 Granules obtained from Comparative Example 11 3 0 4 1.5 0 3 0.75 0 2 Granules obtained from Comparative Example 13 3 0 4 1.5 0 2 0.75 0 1 Granules obtained from Comparative Example 15 3 0 4 1.5 0 3 0.75 0 2 —28— (Please read Ml Note: # 塡穷 {H) Packing. Thread · The paper is used in the country deceptively (CNS) 4 specifications (210X297 g *) 81. 2. 20,000 Λ () B 6 V. Description of the invention (27) Test Example 4 Rice and dog bud roots were cultivated in the same way as Test Example 1. When the dog bud roots reached the 4-leaf stage, they were treated with a facial preparation and the same observation was made. The results are shown in Table 4. (Please first Read the notes to the contrary #-塡农 3 Economic Ministry 屮央 # The quasi-bureau K3C industrial consumer cooperatives printed this paper. The paper size is not the same as the Chinese "home" half (0 邶) 1 ^ specifications (210 father 297 public *) 81 2. 20,000 aia # 8 Printed by the Employee Consumers ’Co-operative of the Central Bureau of Economics, Ministry of Economic Affairs V. Description of the invention (28) The effect of the test agent on the amount of granules kg / ΙΟ acres of rice noodles killing grass by Example 2 4 0 5 Granules obtained 2 0 4 1 0 2 Granules obtained from Example 6.4 0 5 2 0 4 1 0 1 Granules obtained from Example 11 4 0 5 Granules obtained from Example 11 4 0 5 2 0 4 1 0 3 15 4 0 5 Granules obtained 2 0 4 1 0 3 Granules obtained from Comparative Example 2 4 0 3 Granules obtained from Comparative Example 2 0 2 1 0 0 Granules obtained from Comparative Example 6 4 0 3 2 0 2 1 0 0 Comparable Example 11 4 0 3 The granules obtained 2 0 2 1 0 1 The granules obtained from Comparative Example 15 4 0 3 2 0 2 1 0 1 Sample Standard (CNS) A 4 specifications (210X297 g; ft) 81. 20,000

Claims

六、 Shenmao Patent Fan® No. 81103074 »" The Pellet Composition for Paddy Field Weeding "(Amendment in March 1982) 1. A pill composition for paddy field weeding _ composition whose deception includes U) 2- [ 4- (2-gas-4-triphenylene) benzene gas] propionic acid 1 part by weight of Ci-β alkyl ester, (b) dialkyl esters of fumaric acid, dialkyl adipate, triphenylhexan Trialkyl formate, cycloalkylated fatty acid alkyl ester, octyl oleate and their blends, esters that are substantially insoluble in water are as follows specific oily liquid β 1 ~ 50 parts by weight: (bl) tb weighs 0.85 ~ less than 1.0 (b-2) Viscosity below 300CPS (b-3) Vapor pressure at 25¾ <6 1 Pa (c) Oil absorption rate 5 ~ 3096 is selected from bentonite, talc, kaolin, magnesium aluminum sepiolite, skimming Ridge stone, mulch and its combination are composed of 1 ~ 98 parts of the fine solid material that is substantially insoluble in water. Printed by the Employee Consumer Cooperative of the Central Bureau of Economic Development of the Ministry of Economic Affairs (please read the precautions on the back and then fill out this page) • Order ·. Coal · 2. For example, the granule composition of item 1 of the patent model nursery, which is oily The liquid β can dissolve the herbicidal active compound with a reset value of K or more at 251C. 3. For example, the granule composition of Patent Application _ Item 1 in which the herbicidal active compound contains 5 to 25 parts by weight of oily liquid to 1 part by weight. 4. For example, the granule composition according to item 1 of the application form • One part by weight of the active compound except the single part contains 20 to 90 parts by weight of the carrier material. The standard of this paper is applicable to Β 家殮准 (CNS > A 4 specifications (210x297) »2iS748 ^ C7 D7 6. Apply for a patent Fan Gu Di Yuan Fan 0 The benefit agent should be applied as if it were 5 objects in groups _ tablets The item world has a pack of 50. It ’s a good thing. It ’s a good thing. It ’s like a bully. It ’s a group of 6 grains. It has a pack like a pack. (Please read the precautions on the back and then slap it. Page) • Installed • • Played. Printed by Beiyi Consumer Cooperatives of the Central Committee of the Central Committee of the Yiyi Department • Green • This paper ”applies to the Chinese Tune Standard (CNS) T4 (210X297mm)