以下係提出相關實施例,配合圖式以詳細說明本揭露所提出之記憶裝置及其製造方法。然而,本揭露並不以此為限。實施例中之敘述,例如細部結構、製造方法之步驟和材料應用等,僅為舉例說明之用,本揭露欲保護之範圍並非僅限於所述態樣。Relevant embodiments are provided below, and the memory device and the manufacturing method thereof provided by the present disclosure are described in detail in conjunction with the drawings. However, the present disclosure is not limited thereto. The descriptions in the embodiments, such as the detailed structure, the steps of the manufacturing method, and the material application, etc., are only for the purpose of illustration, and the scope of protection of the present disclosure is not limited to the above-mentioned aspects.
同時,須注意的是,本揭露並非顯示出所有可能的實施例。相關技術領域者當可在不脫離本揭露之精神和範圍之前提下,對實施例之結構和製造方法加以變化與修飾,以符合實際應用所需。因此,未於本揭露提出的其他實施態樣也可能可以應用。再者,圖式係簡化以利清楚說明實施例之內容,圖式上的尺寸比例並非按照實際產品等比例繪製。因此,說明書和圖式僅作敘述實施例之用,而非用以限縮本揭露保護範圍。相同或相似的元件符號用以代表相同或相似的原件。At the same time, it should be noted that the present disclosure does not show all possible embodiments. Those skilled in the relevant art can make changes and modifications to the structures and manufacturing methods of the embodiments to meet the needs of practical applications without departing from the spirit and scope of the present disclosure. Therefore, other implementation aspects not proposed in the present disclosure may also be applicable. Furthermore, the drawings are simplified for the purpose of clearly explaining the contents of the embodiments, and the dimension ratios in the drawings are not drawn according to the actual product scale. Therefore, the description and the drawings are only used to describe the embodiments, rather than to limit the protection scope of the present disclosure. The same or similar reference numerals are used to represent the same or similar elements.
第1圖係繪示根據本發明之一實施例之記憶裝置10的示意立體圖。記憶裝置10可包含三維非揮發性記憶體,例如反或閘快閃記憶體(NOR flash memory)、反及閘快閃記憶體(NAND flash memory)、或其它種類記憶體。記憶裝置10可包含堆疊結構S。堆疊結構S可包含主堆疊結構100、階梯結構101與絕緣堆疊結構102。主堆疊結構100、階梯結構101與絕緣堆疊結構102可設置為相鄰於彼此。主堆疊結構100、階梯結構101與絕緣堆疊結構102可設置為於垂直方向上互不重疊,垂直方向例如是Z方向。主堆疊結構100與階梯結構101可沿著橫向方向設置,橫向方向例如是Y方向,但主堆疊結構100與階梯結構101於縱向方向上可互不重疊,縱向方向例如是X方向。主堆疊結構100與絕緣堆疊結構102可沿著X方向設置,但主堆疊結構100與絕緣堆疊結構102於Y方向上可互不重疊。相似地,階梯結構101與絕緣堆疊結構102可沿著X方向設置,但階梯結構101與絕緣堆疊結構102於Y方向上可互不重疊。FIG. 1 is a schematic perspective view of a memory device 10 according to an embodiment of the present invention. The memory device 10 may include three-dimensional non-volatile memory, such as NOR flash memory, NAND flash memory, or other types of memory. The memory device 10 may include a stacked structure S. The stack structure S may include a main stack structure 100 , a stepped structure 101 and an insulating stack structure 102 . The main stack structure 100 , the stepped structure 101 and the insulating stack structure 102 may be disposed adjacent to each other. The main stack structure 100 , the stepped structure 101 and the insulating stack structure 102 may be arranged not to overlap each other in a vertical direction, such as the Z direction. The main stack structure 100 and the stepped structure 101 may be disposed along the lateral direction, such as the Y direction, but the main stack structure 100 and the stepped structure 101 may not overlap each other in the longitudinal direction, such as the X direction. The main stack structure 100 and the insulating stack structure 102 may be disposed along the X direction, but the main stack structure 100 and the insulating stack structure 102 may not overlap each other in the Y direction. Similarly, the stepped structure 101 and the insulating stacked structure 102 may be disposed along the X direction, but the stepped structure 101 and the insulating stacked structure 102 may not overlap each other in the Y direction.
在一實施例中,如第1圖所示,記憶裝置10可具有四個階梯結構101/101A/101B/101C,階梯結構101與階梯結構101A設置為相鄰於彼此,且絕緣條103使階梯結構101隔離於階梯結構101A。階梯結構101B與階梯結構101C設置為相鄰於彼此,且絕緣條103使階梯結構101B隔離於階梯結構101C。階梯結構101與階梯結構101C設置於主堆疊結構100之相對側。階梯結構101A與階梯結構101B設置於主堆疊結構100之相對側。在一實施例中,階梯結構101與階梯結構101C可對稱設置。在一實施例中,階梯結構101A與階梯結構101B可對稱設置。在一實施例中,記憶裝置10可具有設置於主堆疊結構100之相對側的兩個絕緣堆疊結構102/102A;階梯結構101/101A/101B/101C和絕緣堆疊結構102/102A設置於主堆疊結構100的不同側。在一實施例中,兩個絕緣堆疊結構102/102A可對稱設置。In one embodiment, as shown in FIG. 1, the memory device 10 may have four stepped structures 101/101A/101B/101C, the stepped structures 101 and 101A are disposed adjacent to each other, and the insulating strips 103 make the stepped structures The structure 101 is isolated from the stepped structure 101A. The stepped structure 101B and the stepped structure 101C are disposed adjacent to each other, and the insulating strip 103 isolates the stepped structure 101B from the stepped structure 101C. The stepped structure 101 and the stepped structure 101C are disposed on opposite sides of the main stack structure 100 . The stepped structure 101A and the stepped structure 101B are disposed on opposite sides of the main stack structure 100 . In one embodiment, the stepped structure 101 and the stepped structure 101C may be arranged symmetrically. In one embodiment, the stepped structure 101A and the stepped structure 101B may be arranged symmetrically. In one embodiment, the memory device 10 may have two insulating stack structures 102/102A disposed on opposite sides of the main stack structure 100; the stepped structures 101/101A/101B/101C and the insulating stack structures 102/102A are disposed on the main stack Different sides of structure 100. In one embodiment, the two insulating stack structures 102/102A may be arranged symmetrically.
絕緣條103可沿著Y方向延伸,使主堆疊結構100隔離於主堆疊結構100A。依據不同的設計,記憶裝置10可具有一或更多的主堆疊結構100/100A、一或更多的階梯結構101/101A/101B/101C與一或更多的絕緣堆疊結構102/102A。如第1圖所示,絕緣條103可沿著Y方向延伸以使階梯結構101隔離於階梯結構101A、使主堆疊結構100隔離於主堆疊結構100A、以及階梯結構101B隔離於階梯結構101C。在一實施例中,絕緣條103可包含絕緣材料。The insulating strips 103 may extend along the Y direction to isolate the main stack structure 100 from the main stack structure 100A. According to different designs, the memory device 10 may have one or more main stacked structures 100/100A, one or more stepped structures 101/101A/101B/101C, and one or more insulating stacked structures 102/102A. As shown in FIG. 1 , the insulating strips 103 may extend along the Y direction to isolate the stepped structure 101 from the stepped structure 101A, the main stack structure 100 from the main stacked structure 100A, and the stepped structure 101B from the stepped structure 101C. In one embodiment, the insulating strips 103 may include insulating material.
第2A圖係繪示記憶裝置10的示意立體圖,不包含記憶裝置10對應於第1圖中的絕緣堆疊結構102之部分。請同時參照第1圖及第2A圖,主堆疊結構100可包含多個導電膜104與多個第一絕緣層105沿著Z方向交錯堆疊。多個導電膜104使多個第一絕緣層105相互隔離。在一實施例中,主堆疊結構100之導電膜104可包含導電材料,例如鎢(tungsten; W)。主堆疊結構100之第一絕緣層105可包含絕緣材料,絕緣材料包含氧化物,例如氧化矽(silicon oxide)。FIG. 2A is a schematic perspective view of the memory device 10 , excluding the portion of the memory device 10 corresponding to the insulating stack structure 102 in FIG. 1 . Referring to FIG. 1 and FIG. 2A at the same time, the main stack structure 100 may include a plurality of conductive films 104 and a plurality of first insulating layers 105 stacked alternately along the Z direction. The plurality of conductive films 104 isolate the plurality of first insulating layers 105 from each other. In one embodiment, the conductive film 104 of the main stack structure 100 may include a conductive material, such as tungsten (W). The first insulating layer 105 of the main stack structure 100 may include an insulating material, and the insulating material includes an oxide, such as silicon oxide.
階梯結構101可包含多個導電階梯層106與多個絕緣階梯層107沿著Z方向交錯堆疊。多個導電階梯層106使多個絕緣階梯層107相互隔離。每一導電階梯層106具有在X-Y平面上不同的橫向面積。例如,導電階梯層106之橫向面積從階梯結構101之底表面108往階梯結構101之頂表面109逐漸變小。例如,位於較低階層(距離階梯結構101之底表面108較近的階層)的導電階梯層106之橫向面積大於位於較高階層(距離階梯結構101之底表面108較遠的階層)的導電階梯層106之橫向面積。在一實施例中,階梯結構101之導電階梯層106可包含導電材料,例如鎢。階梯結構101之絕緣階梯層107可包含絕緣材料,絕緣材料包含氧化物,例如氧化矽。The stepped structure 101 may include a plurality of conductive stepped layers 106 and a plurality of insulating stepped layers 107 stacked alternately along the Z direction. The plurality of conductive stepped layers 106 isolate the plurality of insulating stepped layers 107 from each other. Each conductive step layer 106 has a different lateral area in the X-Y plane. For example, the lateral area of the conductive stepped layer 106 gradually decreases from the bottom surface 108 of the stepped structure 101 to the top surface 109 of the stepped structure 101 . For example, the lateral area of the conductive stepped layer 106 at the lower level (the level closer to the bottom surface 108 of the stepped structure 101 ) is larger than that of the conductive stepped layer at the higher level (the level farther from the bottom surface 108 of the stepped structure 101 ) Lateral area of layer 106 . In one embodiment, the conductive stepped layer 106 of the stepped structure 101 may include a conductive material, such as tungsten. The insulating stepped layer 107 of the stepped structure 101 may include an insulating material, and the insulating material includes an oxide, such as silicon oxide.
絕緣堆疊結構102可包含多個第二絕緣層110與多個第三絕緣層111沿著Z方向交錯堆疊。多個第二絕緣層110使多個第三絕緣層111相互隔離。在一實施例中,絕緣堆疊結構102之第二絕緣層110可包含絕緣材料,絕緣材料包含氮化物,例如氮化矽(silicon nitride)。絕緣堆疊結構102之第三絕緣層111可包含絕緣材料,絕緣材料包含氧化物,例如氧化矽。在一實施例中,第二絕緣層110與第三絕緣層111可包含不同材料。The insulating stack structure 102 may include a plurality of second insulating layers 110 and a plurality of third insulating layers 111 stacked alternately along the Z direction. The plurality of second insulating layers 110 isolate the plurality of third insulating layers 111 from each other. In one embodiment, the second insulating layer 110 of the insulating stack structure 102 may include an insulating material, and the insulating material includes a nitride, such as silicon nitride. The third insulating layer 111 of the insulating stack structure 102 may include an insulating material, and the insulating material includes an oxide, such as silicon oxide. In one embodiment, the second insulating layer 110 and the third insulating layer 111 may include different materials.
在一實施例中,主堆疊結構100之導電膜104可電性連接至階梯結構101之導電階梯層106。絕緣堆疊結構102可為電性絕緣。主堆疊結構100之導電膜104與階梯結構101之導電階梯層106可做為記憶裝置10之閘極結構。In one embodiment, the conductive film 104 of the main stack structure 100 may be electrically connected to the conductive stepped layer 106 of the stepped structure 101 . The insulating stack structure 102 may be electrically insulating. The conductive film 104 of the main stack structure 100 and the conductive stepped layer 106 of the stepped structure 101 can be used as the gate structure of the memory device 10 .
在一實施例中,主堆疊結構100之多個第一絕緣層105、階梯結構101之多個絕緣階梯層107與絕緣堆疊結構102之多個第三絕緣層111具有一對一對應關係,換言之,一第一絕緣層105、與該第一絕緣層105對應之一絕緣階梯層107、以及與該第一絕緣層105對應之一第三絕緣層111可具有Z方向上相同高度(或階層)。In one embodiment, the plurality of first insulating layers 105 of the main stacked structure 100 , the plurality of insulating stepped layers 107 of the stepped structure 101 and the plurality of third insulating layers 111 of the insulating stacked structure 102 have a one-to-one correspondence, in other words , a first insulating layer 105, an insulating step layer 107 corresponding to the first insulating layer 105, and a third insulating layer 111 corresponding to the first insulating layer 105 may have the same height (or level) in the Z direction .
記憶裝置10可包含多個柱體結構112,分散地配置於絕緣堆疊結構102與階梯結構101中。多個柱體結構112在Z方向上通過絕緣堆疊結構102與階梯結構101。每一柱體結構112包含管狀元件113與導電柱114。管狀元件113貫穿堆疊結構S。具體而言,導電柱114被管狀元件113圍繞。在一實施例中,柱體結構112可具有類似於同軸電纜(coaxial cable)之結構。導電柱114與管狀元件113可沿著Z方向延伸,且通過絕緣堆疊結構102與階梯結構101。導電柱114可包含導電材料,例如鎢。The memory device 10 may include a plurality of pillar structures 112 that are distributed in the insulating stack structure 102 and the stepped structure 101 . The plurality of pillar structures 112 pass through the insulating stack structure 102 and the stepped structure 101 in the Z direction. Each column structure 112 includes a tubular element 113 and a conductive column 114 . The tubular element 113 penetrates the stacked structure S. Specifically, the conductive post 114 is surrounded by the tubular element 113 . In one embodiment, the column structure 112 may have a structure similar to a coaxial cable. The conductive pillars 114 and the tubular element 113 may extend along the Z direction and pass through the insulating stack structure 102 and the stepped structure 101 . The conductive pillars 114 may include a conductive material, such as tungsten.
在絕緣堆疊結構102中,每一柱體結構112通過相同數量的第二絕緣層110。在階梯結構101中,多個柱體結構112分別通過不同數量的導電階梯層106。例如,階梯結構101可包含多個階梯部115 (如第2A圖所示),每一階梯部115所包含的導電階梯層106的數量可不相同,且階梯結構101中的柱體結構112可個別設置於不同階梯部115中,具體而言,一柱體結構112設置於一階梯部115中。In the insulating stack structure 102 , each column structure 112 passes through the same number of the second insulating layers 110 . In the stepped structure 101 , the plurality of pillar structures 112 pass through different numbers of conductive stepped layers 106 respectively. For example, the stepped structure 101 may include a plurality of stepped portions 115 (as shown in FIG. 2A ), the number of conductive stepped layers 106 included in each stepped portion 115 may be different, and the column structures 112 in the stepped structure 101 may be individually are disposed in different stepped portions 115 , specifically, a column structure 112 is disposed in one stepped portion 115 .
記憶裝置10可包含多個導電插塞(plug) 116,設置於階梯結構101之導電階梯層106上。具體而言,每一導電插塞116可設置於階梯結構101中的不同階層之導電階梯層106上。多個導電插塞116可個別配置於不同階梯部115中。導電插塞116電性連接於此導電插塞116所設置的一導電階梯層106,且管狀元件113與導電柱114通過此導電階梯層106。The memory device 10 may include a plurality of conductive plugs 116 disposed on the conductive stepped layer 106 of the stepped structure 101 . Specifically, each conductive plug 116 may be disposed on the conductive stepped layers 106 of different levels in the stepped structure 101 . A plurality of conductive plugs 116 may be individually arranged in different stepped portions 115 . The conductive plug 116 is electrically connected to a conductive stepped layer 106 disposed on the conductive plug 116 , and the tubular element 113 and the conductive column 114 pass through the conductive stepped layer 106 .
第2B圖係繪示第1圖所示之絕緣堆疊結構102中的多個柱體結構112中的一者。第2C圖係繪示第1圖所示之階梯結構101中的多個柱體結構112中的一者。FIG. 2B shows one of the plurality of pillar structures 112 in the insulating stack structure 102 shown in FIG. 1 . FIG. 2C shows one of the plurality of column structures 112 in the stepped structure 101 shown in FIG. 1 .
請參照第1圖與第2B-2C圖,在絕緣堆疊結構102與階梯結構101中,管狀元件113可包含記憶膜117、虛設通道層118與絕緣膜119。導電柱114被管狀元件113圍繞,且導電柱114延伸超過虛設通道層118的底表面120。在一實施例中,虛設通道層118的底表面120可沿著Z方向延伸超過絕緣堆疊結構102的底表面121與階梯結構101的底表面108,且導電柱114可沿著Z方向延伸超過絕緣堆疊結構102的底表面121、階梯結構101的底表面108與虛設通道層118的底表面120。Referring to FIGS. 1 and 2B-2C, in the insulating stack structure 102 and the stepped structure 101 , the tubular element 113 may include a memory film 117 , a dummy channel layer 118 and an insulating film 119 . The conductive pillars 114 are surrounded by the tubular element 113 and the conductive pillars 114 extend beyond the bottom surface 120 of the dummy channel layer 118 . In one embodiment, the bottom surface 120 of the dummy channel layer 118 may extend beyond the bottom surface 121 of the insulating stack structure 102 and the bottom surface 108 of the stepped structure 101 along the Z direction, and the conductive pillars 114 may extend beyond the insulating layer along the Z direction. The bottom surface 121 of the stacked structure 102 , the bottom surface 108 of the stepped structure 101 , and the bottom surface 120 of the dummy channel layer 118 .
記憶膜117可包含記憶體技術領域中已知的多層結構(multilayer structure),例如ONO (氧化物-氮化物-氧化物)結構、ONONO (氧化物-氮化物-氧化物-氮化物-氧化物)結構、ONONONO (氧化物-氮化物-氧化物-氮化物-氧化物-氮化物-氧化物)結構、SONOS (矽-氧化矽-氮化矽-氧化矽-矽)結構、BE-SONOS (能帶隙矽-氧化矽-氮化矽-氧化矽-矽)結構、TANOS (氮化鉭-氧化鋁-氮化矽-氧化矽-矽)結構、MA BE-SONOS (金屬-高介電常數材料能帶隙矽-氧化矽-氮化矽-氧化矽-矽)結構及其組合。記憶膜117可具有管狀且圍繞導電柱114。The memory film 117 may include a multilayer structure known in the memory technology field, such as an ONO (oxide-nitride-oxide) structure, ONONO (oxide-nitride-oxide-nitride-oxide) ) structure, ONONONO (Oxide-Nitride-Oxide-Nitride-Oxide-Nitride-Oxide) structure, SONOS (Silicon-Silicon Oxide-Silicon Nitride-Silicon Oxide-Silicon) structure, BE-SONOS ( Band gap silicon-silicon oxide-silicon nitride-silicon oxide-silicon) structure, TANOS (tantalum nitride-alumina-silicon nitride-silicon oxide-silicon) structure, MA BE-SONOS (metal-high dielectric constant) Material energy band gap silicon-silicon oxide-silicon nitride-silicon oxide-silicon) structure and its combination. The memory film 117 may have a tubular shape and surround the conductive pillars 114 .
在一實施例中,記憶裝置10之記憶層可包含記憶膜117與記憶材料,記憶材料形成於記憶膜117與主堆疊結構100之導電膜104之間。記憶層可包含記憶體技術領域中已知的任意電荷捕捉(charge trapping)結構,例如ONO結構、ONONO結構、ONONONO結構、SONOS結構、BE-SONOS結構、TANOS結構、MA BE-SONOS結構及其組合等。電荷捕捉結構可使用氮化物例如氮化矽,或是其他類似的高介電常數物質包括金屬氧化物,例如三氧化二鋁(alumina; Al2
O3
)、氧化鋯(hafnium dioxide; HfO2
)等。記憶胞可定義在記憶層中。舉例來說,在記憶層包含記憶膜117與記憶材料的情況下,記憶膜117可理解為穿隧氧化層(tunneling oxide layer),記憶膜117可包含二氧化矽(silicon dioxide; SiO2
)或者僅包含二氧化矽;而記憶材料可包含記憶體技術領域中已知的多層記憶材料,例如三氧化二鋁、氮化鈦(titanium nitride; TiN)、ONO結構、ONONO結構、ONONONO結構、SONOS結構、BE-SONOS結構、TANOS結構、MA BE-SONOS結構及其組合等。In one embodiment, the memory layer of the memory device 10 may include a memory film 117 and a memory material, and the memory material is formed between the memory film 117 and the conductive film 104 of the main stack structure 100 . The memory layer may comprise any charge trapping structure known in the field of memory technology, such as ONO structure, ONONO structure, ONONONO structure, SONOS structure, BE-SONOS structure, TANOS structure, MA BE-SONOS structure and combinations thereof Wait. The charge trapping structure can use nitrides such as silicon nitride, or other similar high dielectric constant materials including metal oxides, such as aluminum oxide (alumina; Al 2 O 3 ), zirconium oxide (hafnium dioxide; HfO 2 ) Wait. Memory cells can be defined in memory layers. For example, when the memory layer includes a memory film 117 and a memory material, the memory film 117 can be understood as a tunneling oxide layer, and the memory film 117 can include silicon dioxide (SiO 2 ) or Only silicon dioxide is included; and the memory material may include multi-layer memory materials known in the field of memory technology, such as aluminum oxide, titanium nitride (TiN), ONO structure, ONONO structure, ONONONO structure, SONOS structure , BE-SONOS structure, TANOS structure, MA BE-SONOS structure and combinations thereof, etc.
虛設通道層118設置於記憶膜117與導電柱114之間。虛設通道層118可包含半導體材料,例如摻雜的(doped)半導體材料或未摻雜的(undoped)半導體材料。在一實施例中,虛設通道層118可包含多晶矽(polysilicon),例如摻雜的多晶矽或未摻雜的多晶矽。虛設通道層118可具有管狀且圍繞導電柱114。在一實施例中,虛設通道層118可意指不具有驅動電路的虛設通道層118。在一實施例中,虛設通道層118可理解為電性浮接(floating)的元件。The dummy channel layer 118 is disposed between the memory film 117 and the conductive pillar 114 . The dummy channel layer 118 may include a semiconductor material, such as a doped semiconductor material or an undoped semiconductor material. In one embodiment, the dummy channel layer 118 may comprise polysilicon, such as doped polysilicon or undoped polysilicon. The dummy channel layer 118 may have a tubular shape and surround the conductive pillars 114 . In one embodiment, the dummy channel layer 118 may refer to the dummy channel layer 118 without a driving circuit. In one embodiment, the dummy channel layer 118 can be understood as an element that is electrically floating.
絕緣膜119設置於導電柱114與虛設通道層118之間。絕緣膜119可具有管狀且圍繞導電柱114。絕緣膜119可包含介電材料,介電材料包含氧化物(例如氧化矽)。The insulating film 119 is disposed between the conductive pillar 114 and the dummy channel layer 118 . The insulating film 119 may have a tubular shape and surround the conductive post 114 . The insulating film 119 may include a dielectric material including an oxide (eg, silicon oxide).
第3圖係繪示根據本發明之一實施例之主堆疊結構100的示意俯視圖。請同時參照第1圖及第3圖,記憶裝置10可包含多個柱元件122,分散地配置於主堆疊結構100中。柱元件122沿著Z方向延伸且通過主堆疊結構100。FIG. 3 is a schematic top view of the main stack structure 100 according to an embodiment of the present invention. Please refer to FIG. 1 and FIG. 3 at the same time, the memory device 10 may include a plurality of column elements 122 , which are distributed in the main stack structure 100 . The pillar elements 122 extend along the Z direction and pass through the main stack structure 100 .
柱元件122可包含記憶膜117、通道層118A、源極/汲極柱123、源極/汲極柱124、絕緣柱125與絕緣膜119。絕緣柱125設置於源極/汲極柱123和源極/汲極柱124之間。絕緣柱125使源極/汲極柱123隔離於源極/汲極柱124彼此。源極/汲極柱123和源極/汲極柱124中的一者係為源極,另一者係為汲極。絕緣膜119設置於通道層118A與源極/汲極柱123、源極/汲極柱124和絕緣柱125之間。通道層118A設置於絕緣膜119與記憶膜117之間。通道層118A可具有管狀且圍繞源極/汲極柱123、源極/汲極柱124、絕緣膜119與絕緣柱125。記憶膜117可具有管狀且圍繞通道層118A。柱元件122之記憶膜117可相似於管狀元件113之記憶膜117。源極/汲極柱123和源極/汲極柱124可包含摻雜的半導體材料,例如N+多晶矽,或可包含未摻雜的半導體材料。絕緣柱125可包含絕緣材料,絕緣材料包含氮化物,例如氮化矽。The pillar element 122 may include a memory film 117 , a channel layer 118A, a source/drain pillar 123 , a source/drain pillar 124 , an insulating pillar 125 and an insulating film 119 . The insulating pillar 125 is disposed between the source/drain pillar 123 and the source/drain pillar 124 . The insulating pillars 125 isolate the source/drain pillars 123 from the source/drain pillars 124 from each other. One of the source/drain posts 123 and the source/drain posts 124 is a source, and the other is a drain. The insulating film 119 is disposed between the channel layer 118A and the source/drain pillars 123 , the source/drain pillars 124 and the insulating pillars 125 . The channel layer 118A is provided between the insulating film 119 and the memory film 117 . The channel layer 118A may have a tubular shape and surround the source/drain pillars 123 , the source/drain pillars 124 , the insulating film 119 and the insulating pillars 125 . The memory film 117 may have a tubular shape and surround the channel layer 118A. The memory film 117 of the column element 122 may be similar to the memory film 117 of the tubular element 113 . Source/drain pillars 123 and source/drain pillars 124 may comprise doped semiconductor material, such as N+ polysilicon, or may comprise undoped semiconductor material. The insulating pillars 125 may include insulating materials including nitrides, such as silicon nitride.
記憶裝置10可包含多個記憶胞,設置於主堆疊結構100與主堆疊結構100A中。記憶胞可定義於導電膜104與柱元件122之通道層118A交錯處的記憶膜117中。柱元件122可理解為主動柱元件。在一實施例中,主堆疊結構100可設置於陣列區域(array region),且階梯結構101可設置於階梯區域(staircase region)。The memory device 10 may include a plurality of memory cells disposed in the main stack structure 100 and the main stack structure 100A. The memory cells may be defined in the memory film 117 where the conductive film 104 and the channel layer 118A of the column element 122 intersect. The column element 122 can be understood as an active column element. In one embodiment, the main stack structure 100 may be disposed in an array region, and the stair structure 101 may be disposed in a staircase region.
管狀元件113之虛設通道層118與柱元件122之通道層118A的不同之處在於,當施加電壓至記憶裝置10時,虛設通道層118並非用來提供通道給電子或電洞。The dummy channel layer 118 of the tubular element 113 differs from the channel layer 118A of the pillar element 122 in that the dummy channel layer 118 is not used to provide a channel for electrons or holes when a voltage is applied to the memory device 10 .
第4圖係繪示根據本發明另一實施例之主堆疊結構100中的柱元件122A的示意立體圖。第4圖所示之柱元件122A與第3圖所示之柱元件122的不同之處說明如下。柱元件122A包含通道層118B、源極/汲極柱123、源極/汲極柱124與絕緣膜119。絕緣膜119使源極/汲極柱123隔離於源極/汲極柱124。第4圖所示之通道層118B與第3圖所示之通道層118A的不同之處在於通道層118B具有開環形狀,且通道層118B具有相對的端部分別電性連接至源極/汲極柱123與源極/汲極柱124。第4圖所示之記憶膜417與第3圖所示之記憶膜117的不同之處在於記憶膜417設置於主堆疊結構100之導電膜104的上表面與下表面,且可延伸於柱元件122A的外側壁與導電膜104之間。FIG. 4 is a schematic perspective view of the column element 122A in the main stack structure 100 according to another embodiment of the present invention. The difference between the pillar element 122A shown in FIG. 4 and the pillar element 122 shown in FIG. 3 is described below. The pillar element 122A includes a channel layer 118B, a source/drain pillar 123 , a source/drain pillar 124 and an insulating film 119 . The insulating film 119 isolates the source/drain posts 123 from the source/drain posts 124 . The difference between the channel layer 118B shown in FIG. 4 and the channel layer 118A shown in FIG. 3 is that the channel layer 118B has an open-loop shape, and the channel layer 118B has opposite ends electrically connected to the source/drain, respectively The pole 123 and the source/drain pole 124 . The difference between the memory film 417 shown in FIG. 4 and the memory film 117 shown in FIG. 3 is that the memory film 417 is disposed on the upper surface and the lower surface of the conductive film 104 of the main stack structure 100 and can extend over the column element between the outer sidewall of 122A and the conductive film 104 .
在一實施例中,在主堆疊結構100之示意立體圖中,第3圖所示之記憶膜117可配置於導電膜104的上表面與下表面,且可延伸於柱元件122的外側壁與導電膜104之間,類似於第4圖所示之記憶膜417的配置方式。In one embodiment, in the schematic three-dimensional view of the main stack structure 100 , the memory film 117 shown in FIG. 3 can be disposed on the upper surface and the lower surface of the conductive film 104 , and can extend on the outer sidewall and the conductive film of the column element 122 . Between the membranes 104, the arrangement of the memory membrane 417 shown in FIG. 4 is similar.
請再次參照第1圖,記憶裝置10可包含多晶半導體層(poly semiconductor) 126,位於主堆疊結構100、階梯結構101與絕緣堆疊結構102下方。換言之,多晶半導體層126位於記憶胞下方。管狀元件113、導電柱114與柱元件122通過多晶半導體層126。多晶半導體層126可包含摻雜的半導體材料,例如P+多晶矽,或未摻雜的半導體材料。導電柱114可具有上導電柱端部127與相對於上導電柱端部127之下導電柱端部128。導電柱114之上導電柱端部127位於絕緣堆疊結構102與階梯結構101的上方。導電柱114之下導電柱端部128位於多晶半導體層126的下方。Referring to FIG. 1 again, the memory device 10 may include a poly semiconductor layer 126 located under the main stack structure 100 , the stepped structure 101 and the insulating stack structure 102 . In other words, the polycrystalline semiconductor layer 126 is located under the memory cells. The tubular element 113 , the conductive pillar 114 and the pillar element 122 pass through the polycrystalline semiconductor layer 126 . The polycrystalline semiconductor layer 126 may comprise a doped semiconductor material, such as P+ polysilicon, or an undoped semiconductor material. The conductive post 114 may have an upper conductive post end portion 127 and a lower conductive post end portion 128 opposite to the upper conductive post end portion 127 . The ends 127 of the conductive pillars on the conductive pillars 114 are located above the insulating stack structure 102 and the stepped structure 101 . The ends 128 of the conductive pillars below the conductive pillars 114 are located below the polycrystalline semiconductor layer 126 .
記憶裝置10可包含電晶體(transistor) 161、下導電結構163與下導電結構165。下導電結構163電性連接於導電柱114之下導電柱端部128與電晶體161之汲極與源極中的一者之間。下導電結構165電性連接於導電柱114之下導電柱端部128與電晶體161之汲極與源極中的另一者之間。The memory device 10 may include a transistor 161 , a lower conductive structure 163 and a lower conductive structure 165 . The lower conductive structure 163 is electrically connected between the end portion 128 of the conductive column below the conductive column 114 and one of the drain electrode and the source electrode of the transistor 161 . The lower conductive structure 165 is electrically connected between the end portion 128 of the conductive column below the conductive column 114 and the other of the drain electrode and the source electrode of the transistor 161 .
第5圖係繪示根據本發明之一實施例之記憶裝置10的示意俯視圖。第1圖與第5圖的不同之處在於,第5圖所示之記憶裝置10包含更多的主堆疊結構100/100A/100B/100C,以及更多的階梯結構101/101A/101B/101C/101D/101E/101F/101G,第5圖並未示出絕緣堆疊結構102/102A。請同時參照第1圖及第5圖,記憶裝置10可包含導電層130。導電層130可設置於主堆疊結構100、階梯結構101與絕緣堆疊結構102的上方。導電層130可包含上導電結構171、上導電結構173、上導電結構181、上導電結構183與上導電結構191,設置於柱元件122及/或柱體結構112的上方。FIG. 5 is a schematic top view of a memory device 10 according to an embodiment of the present invention. The difference between FIG. 1 and FIG. 5 is that the memory device 10 shown in FIG. 5 includes more main stack structures 100/100A/100B/100C and more stepped structures 101/101A/101B/101C /101D/101E/101F/101G, FIG. 5 does not show the insulating stack structure 102/102A. Please refer to FIG. 1 and FIG. 5 simultaneously, the memory device 10 may include a conductive layer 130 . The conductive layer 130 may be disposed above the main stack structure 100 , the stepped structure 101 and the insulating stack structure 102 . The conductive layer 130 may include an upper conductive structure 171 , an upper conductive structure 173 , an upper conductive structure 181 , an upper conductive structure 183 and an upper conductive structure 191 , and is disposed above the column element 122 and/or the column structure 112 .
上導電結構173可電性連接於絕緣堆疊結構102中的一柱體結構112之一導電柱114。上導電結構171可電性連接於絕緣堆疊結構102中的其他多個柱體結構112之多個導電柱114。上導電結構171電性連接於柱元件122之源極或汲極中的一者與導電柱114之間。上導電結構171電性連接於記憶胞與絕緣堆疊結構102中的導電柱114之上導電柱端部127之間。絕緣堆疊結構102中的一柱體結構112之一導電柱114電性連接於下導電結構165與上導電結構173之間。絕緣堆疊結構102中的其他多個柱體結構112之多個導電柱114電性連接於下導電結構163與上導電結構171之間。The upper conductive structure 173 can be electrically connected to a conductive column 114 of a column structure 112 in the insulating stack structure 102 . The upper conductive structure 171 can be electrically connected to the plurality of conductive pillars 114 of the other plurality of pillar structures 112 in the insulating stack structure 102 . The upper conductive structure 171 is electrically connected between one of the source electrode or the drain electrode of the column element 122 and the conductive column 114 . The upper conductive structure 171 is electrically connected between the memory cells and the upper conductive column ends 127 of the conductive columns 114 in the insulating stack structure 102 . A conductive column 114 of a column structure 112 in the insulating stack structure 102 is electrically connected between the lower conductive structure 165 and the upper conductive structure 173 . The conductive pillars 114 of the other pillar structures 112 in the insulating stack structure 102 are electrically connected between the lower conductive structure 163 and the upper conductive structure 171 .
上導電結構183可電性連接於絕緣堆疊結構102A中的一柱體結構112之一導電柱114。上導電結構181可電性連接於絕緣堆疊結構102A中的其他多個柱體結構112之多個導電柱114。上導電結構181電性連接於柱元件122之源極或汲極中的另一者(例如是相對於上導電結構171所電性連接的一者)與導電柱114之間。上導電結構181電性連接於記憶胞與絕緣堆疊結構102A中的導電柱114之上導電柱端部127之間。絕緣堆疊結構102A中的一柱體結構112之一導電柱114電性連接於下導電結構165與上導電結構183之間。絕緣堆疊結構102A中的其他多個柱體結構112之多個導電柱114電性連接於下導電結構163與上導電結構181之間。The upper conductive structure 183 can be electrically connected to a conductive column 114 of a column structure 112 in the insulating stack structure 102A. The upper conductive structure 181 can be electrically connected to the plurality of conductive pillars 114 of the other plurality of pillar structures 112 in the insulating stack structure 102A. The upper conductive structure 181 is electrically connected between the other of the source electrode or the drain electrode of the pillar element 122 (eg, the one electrically connected relative to the upper conductive structure 171 ) and the conductive pillar 114 . The upper conductive structure 181 is electrically connected between the memory cell and the upper conductive column end 127 of the conductive column 114 in the insulating stack structure 102A. A conductive column 114 of a column structure 112 in the insulating stack structure 102A is electrically connected between the lower conductive structure 165 and the upper conductive structure 183 . The conductive pillars 114 of the other pillar structures 112 in the insulating stack structure 102A are electrically connected between the lower conductive structure 163 and the upper conductive structure 181 .
在一實施例中,例如,柱元件122之源極電性連接至上導電結構171、絕緣堆疊結構102中的導電柱114、上導電結構173、下導電結構163、電晶體161與下導電結構165。上導電結構171、絕緣堆疊結構102中的導電柱114、上導電結構173、及電性連接於絕緣堆疊結構102中的多個導電柱114 (即有效導電柱或主動導電柱)之多個下導電柱端部128之間的下導電結構163與下導電結構165可做為源極線。例如,上導電結構173可做為全域源極線(global source line)或共同源極線(common source line)。電晶體161 (開關)可做為源極線電晶體(源極線開關)。絕緣堆疊結構102中的導電柱114可做為用於記憶胞之源極線接觸結構。In one embodiment, for example, the source of the column element 122 is electrically connected to the upper conductive structure 171 , the conductive column 114 in the insulating stack structure 102 , the upper conductive structure 173 , the lower conductive structure 163 , the transistor 161 and the lower conductive structure 165 . . The upper conductive structure 171 , the conductive pillars 114 in the insulating stack structure 102 , the upper conductive structure 173 , and a plurality of lower portions of the plurality of conductive pillars 114 (ie, effective conductive pillars or active conductive pillars) electrically connected to the insulating stacked structure 102 . The lower conductive structure 163 and the lower conductive structure 165 between the ends 128 of the conductive pillars can be used as source lines. For example, the upper conductive structure 173 can be used as a global source line or a common source line. Transistor 161 (switch) can be used as a source line transistor (source line switch). The conductive pillars 114 in the insulating stack structure 102 can be used as source line contact structures for the memory cells.
在一實施例中,例如,柱元件122之汲極電性連接至上導電結構181、絕緣堆疊結構102A中的導電柱114、上導電結構183、下導電結構163、電晶體161與下導電結構165。上導電結構181、絕緣堆疊結構102A中的導電柱114、上導電結構183、及電性連接於絕緣堆疊結構102A中的多個導電柱114 (即有效導電柱或主動導電柱)之多個下導電柱端部128之間的下導電結構163與下導電結構165可做為位元線。例如,上導電結構181可做為區域位元線(local bit line),上導電結構183可做為全域位元線(global bit line)或共同位元線(common bit line),區域位元線透過絕緣堆疊結構102A中的多個導電柱114、下導電結構163、電晶體161與下導電結構165電性連接於全域位元線。電晶體161 (開關)可做為位元線電晶體(位元線開關)。絕緣堆疊結構102A中的導電柱114可做為用於記憶胞之位元線接觸結構。In one embodiment, for example, the drain of the column element 122 is electrically connected to the upper conductive structure 181 , the conductive column 114 in the insulating stack structure 102A, the upper conductive structure 183 , the lower conductive structure 163 , the transistor 161 and the lower conductive structure 165 . . The upper conductive structure 181 , the conductive pillars 114 in the insulating stack structure 102A, the upper conductive structure 183 , and a plurality of lower ones electrically connected to the plurality of conductive pillars 114 (ie, the active conductive pillars or the active conductive pillars) in the insulating stacked structure 102A The lower conductive structure 163 and the lower conductive structure 165 between the ends of the conductive pillars 128 can be used as bit lines. For example, the upper conductive structure 181 can be used as a local bit line, the upper conductive structure 183 can be used as a global bit line or a common bit line, a local bit line The plurality of conductive pillars 114 , the lower conductive structure 163 , the transistor 161 and the lower conductive structure 165 in the insulating stack structure 102A are electrically connected to the global bit line. Transistor 161 (switch) may function as a bitline transistor (bitline switch). The conductive pillars 114 in the insulating stack structure 102A can serve as bit line contact structures for the memory cells.
上導電結構191可電性連接於導電插塞116與階梯結構101中的柱體結構112之導電柱114之上導電柱端部127之間。半導體裝置129可包含電晶體192與下導電結構194。下導電結構194電性連接於電晶體192。下導電結構194電性連接於電晶體192與階梯結構101中的柱體結構112之導電柱114之下導電柱端部128之間。在多個實施例中,階梯結構101中的柱體結構112之導電柱114 (即有效導電柱或主動導電柱)、上導電結構191、導電插塞116、下導電結構194可做為字元線。電晶體192 (開關)可做為字元線電晶體(字元線開關)。階梯結構101中的導電柱114可做為用於記憶胞之字元線接觸。The upper conductive structure 191 can be electrically connected between the conductive plug 116 and the conductive column end 127 on the conductive column 114 of the column structure 112 in the stepped structure 101 . The semiconductor device 129 may include a transistor 192 and a lower conductive structure 194 . The lower conductive structure 194 is electrically connected to the transistor 192 . The lower conductive structure 194 is electrically connected between the transistor 192 and the bottom conductive column end 128 of the conductive column 114 of the column structure 112 in the stepped structure 101 . In various embodiments, the conductive pillars 114 (ie, the effective conductive pillars or active conductive pillars), the upper conductive structures 191 , the conductive plugs 116 , and the lower conductive structures 194 of the pillar structures 112 in the stepped structure 101 can be used as characters Wire. Transistor 192 (switch) may act as a wordline transistor (wordline switch). The conductive pillars 114 in the stepped structure 101 can be used as word line contacts for the memory cells.
階梯結構101中的多個柱體結構112之部分導電柱114可電性浮接且從而被稱為虛設(dummy)導電柱。例如,如第5圖所示,階梯結構101、階梯結構101B、階梯結構101D與階梯結構101F中的多個柱體結構112之導電柱114係為電性浮接,而階梯結構101A、階梯結構101C、階梯結構101E與階梯結構101G中的多個柱體結構112之導電柱114。A portion of the conductive pillars 114 of the plurality of pillar structures 112 in the stepped structure 101 may be electrically floating and are thus called dummy conductive pillars. For example, as shown in FIG. 5, the conductive pillars 114 of the plurality of pillar structures 112 in the ladder structure 101, the ladder structure 101B, the ladder structure 101D and the ladder structure 101F are electrically floating, and the ladder structure 101A, the ladder structure The conductive pillars 114 of the plurality of pillar structures 112 in the stair structure 101C, the stair structure 101E and the stair structure 101G.
解碼器可設置於主堆疊結構100與階梯結構101的下方。位元線電晶體與源極線電晶體可設置於基板(未繪示)上,相鄰於記憶裝置10之外圍區域(periphery region)。在一實施例中,位元線電晶體與源極線電晶體可設置於基板且位於記憶裝置10之正下方區域,以形成驅動電路置於陣列之下的架構(CMOS under array)。The decoder may be disposed below the main stack structure 100 and the ladder structure 101 . The bit line transistors and the source line transistors may be disposed on a substrate (not shown) adjacent to a peripheral region of the memory device 10 . In one embodiment, the bit line transistors and the source line transistors may be disposed on the substrate and located in the region directly below the memory device 10 to form a structure (CMOS under array) in which the driving circuits are placed under the array.
在一實施例中,下導電結構163與下導電結構165可包含但不限於第一下金屬層(BM1)、第二下金屬層(BM2)、第三下金屬層(BM3)與設置於多個下金屬層之間且提供多個下金屬層之間電連接的多個下導孔(vias)。In one embodiment, the lower conductive structure 163 and the lower conductive structure 165 may include, but are not limited to, a first lower metal layer ( BM1 ), a second lower metal layer ( BM2 ), a third lower metal layer ( BM3 ), and are disposed in multiple A plurality of lower vias (vias) are provided between the lower metal layers and provide electrical connections between the plurality of lower metal layers.
在一實施例中,導電層130可包含第一上金屬層(TM1)及/或第二上金屬層(TM2)。In one embodiment, the conductive layer 130 may include a first upper metal layer ( TM1 ) and/or a second upper metal layer ( TM2 ).
階梯結構101與絕緣堆疊結構102中的管狀元件113可具有相同的橫向剖面尺寸(例如直徑),例如,在X-Y平面上的剖面尺寸(例如直徑)。管狀元件113之橫向剖面尺寸可大於柱元件122之橫向剖面尺寸,例如,在X-Y平面上,管狀元件113的剖面直徑大於柱元件122的剖面直徑。The tubular elements 113 in the stepped structure 101 and the insulating stack structure 102 may have the same lateral cross-sectional dimension (eg, diameter), eg, cross-sectional dimension (eg, diameter) in the X-Y plane. The transverse cross-sectional dimension of the tubular element 113 may be larger than the transverse cross-sectional dimension of the column element 122 .
第6-15圖係示例性繪示用以製造根據本發明之一實施例之記憶裝置10之方法。6-15 are exemplary illustrations of a method for fabricating the memory device 10 according to one embodiment of the present invention.
請參照第6圖,半導體裝置129提供於多晶半導體層126之下。半導體裝置129可具有如前所述之的結構(參照第1圖)。在一實施例中,半導體裝置129可包含但不限於第一下金屬層(BM1)、第二下金屬層(BM2)、第三下金屬層(BM3)與設置於多個下金屬層之間且提供多個下金屬層之間電連接的多個下導孔。半導體裝置129可包含其他形成於層間(inter-layer)介電層中或層間介電層上的導電線路。本揭露對此不做侷限。在一實施例中,半導體裝置129在前段製程(front-end-of-line; FEOL)中形成於基板(未繪示)上。Referring to FIG. 6 , a semiconductor device 129 is provided under the polycrystalline semiconductor layer 126 . The semiconductor device 129 may have the structure as described above (refer to FIG. 1). In one embodiment, the semiconductor device 129 may include, but is not limited to, a first lower metal layer ( BM1 ), a second lower metal layer ( BM2 ), a third lower metal layer ( BM3 ) and disposed between the plurality of lower metal layers And a plurality of lower vias for electrical connection between the plurality of lower metal layers are provided. Semiconductor device 129 may include other conductive traces formed in or on inter-layer dielectric layers. This disclosure does not limit this. In one embodiment, the semiconductor device 129 is formed on a substrate (not shown) in a front-end-of-line (FEOL) process.
半導體裝置可包含介電層136 (上介電層)。在一實施例中,介電層136可形成於第三下金屬層(BM3)上。介電層136可包含介電材料,介電材料包含氧化物,例如氧化矽。然後,多晶半導體層126形成於介電層136上。多晶半導體層126可包含摻雜的半導體材料,例如P+多晶矽,或未摻雜的半導體材料。在一實施例中,介電層136與多晶半導體層126可藉由沉積處理來形成,例如是藉由化學氣相沉積處理(chemical vapor deposition; CVD)。The semiconductor device may include a dielectric layer 136 (upper dielectric layer). In one embodiment, the dielectric layer 136 may be formed on the third lower metal layer (BM3). The dielectric layer 136 may include a dielectric material including an oxide, such as silicon oxide. Then, the polycrystalline semiconductor layer 126 is formed on the dielectric layer 136 . The polycrystalline semiconductor layer 126 may comprise a doped semiconductor material, such as P+ polysilicon, or an undoped semiconductor material. In one embodiment, the dielectric layer 136 and the polycrystalline semiconductor layer 126 may be formed by a deposition process, such as by chemical vapor deposition (CVD).
絕緣堆疊結構102’形成於多晶半導體層126上。絕緣堆疊結構102’可包含多個第二絕緣層110’與多個第三絕緣層111’交錯堆疊,例如沿著Z方向。多個第二絕緣層110’使多個第三絕緣層111’相互隔離。在一實施例中,第二絕緣層110’可包含絕緣材料,絕緣材料包含氮化物,例如氮化矽。第三絕緣層111’可包含絕緣材料,絕緣材料包含氧化物,例如氧化矽。在一實施例中,第二絕緣層110’與第三絕緣層111’包含不同材料。在一實施例中,絕緣堆疊結構102’可藉由依序沉積第三絕緣層111’與第二絕緣層110’來形成。The insulating stack structure 102' is formed on the polycrystalline semiconductor layer 126. The insulating stack structure 102' may include a plurality of second insulating layers 110' and a plurality of third insulating layers 111' stacked alternately, for example, along the Z direction. The plurality of second insulating layers 110' isolate the plurality of third insulating layers 111' from each other. In one embodiment, the second insulating layer 110' may include an insulating material, and the insulating material includes a nitride, such as silicon nitride. The third insulating layer 111' may include an insulating material including an oxide, such as silicon oxide. In one embodiment, the second insulating layer 110' and the third insulating layer 111' include different materials. In one embodiment, the insulating stack structure 102' may be formed by sequentially depositing the third insulating layer 111' and the second insulating layer 110'.
請參照第7圖,絕緣堆疊結構102’被圖案化,例如是藉由光刻(photolithography)處理來圖案化,以在絕緣堆疊結構102’中形成第一孔137、第二孔138與第三孔139。第一孔137、第二孔138與第三孔139在Z方向上通過絕緣堆疊結構102’與多晶半導體層126。第一孔137、第二孔138與第三孔139使絕緣堆疊結構102’與多晶半導體層126之側壁暴露。在一實施例中,第一孔137、第二孔138與第三孔139之形成可藉由對絕緣堆疊結構102’進行蝕刻(etching)處理,例如是溼式蝕刻(wet etching)或乾式蝕刻(dry etching),然後當蝕刻處理稍微超過多晶半導體層126之底表面140時停止蝕刻。在一實施例中,多晶半導體層126可被視為蝕刻停止層。蝕刻處理可停止於介電層136中。在一實施例中,第一孔137、第二孔138與第三孔139可沿著Z方向從絕緣堆疊結構102’之頂表面141往多晶半導體層126之底表面140逐漸變窄。在一實施例中,第一孔137、第二孔138與第三孔139中的每一者可具有沿著Z方向從絕緣堆疊結構102’之頂表面141往多晶半導體層126之底表面140逐漸變小的橫向剖面尺寸(例如在X-Y平面上的橫向剖面尺寸)。在一實施例中,在任意一個X-Y平面(此X-Y平面和第一孔137、第二孔138與第三孔139交錯)上,第一孔137的橫向剖面尺寸小於第二孔138的橫向剖面尺寸,第一孔137的橫向剖面尺寸小於第三孔139的橫向剖面尺寸,第二孔138的橫向剖面尺寸大致和第三孔139的橫向剖面尺寸相同。Referring to FIG. 7 , the insulating stack structure 102 ′ is patterned, for example, by photolithography, to form the first hole 137 , the second hole 138 and the third hole in the insulating stack structure 102 ′. hole 139. The first hole 137 , the second hole 138 and the third hole 139 pass through the insulating stacked structure 102 ′ and the polycrystalline semiconductor layer 126 in the Z direction. The first hole 137 , the second hole 138 and the third hole 139 expose the sidewalls of the insulating stack structure 102 ′ and the polycrystalline semiconductor layer 126 . In one embodiment, the first hole 137 , the second hole 138 and the third hole 139 can be formed by etching the insulating stack structure 102 ′, such as wet etching or dry etching. (dry etching), and then stop etching when the etching process slightly exceeds the bottom surface 140 of the polycrystalline semiconductor layer 126 . In one embodiment, the polycrystalline semiconductor layer 126 may be regarded as an etch stop layer. The etching process may stop in the dielectric layer 136 . In one embodiment, the first hole 137 , the second hole 138 and the third hole 139 may be gradually narrowed along the Z direction from the top surface 141 of the insulating stack structure 102 ′ to the bottom surface 140 of the polycrystalline semiconductor layer 126 . In one embodiment, each of the first hole 137 , the second hole 138 and the third hole 139 may have a direction along the Z direction from the top surface 141 of the insulating stack structure 102 ′ to the bottom surface of the polycrystalline semiconductor layer 126 140 Tapered transverse cross-sectional dimension (eg, transverse cross-sectional dimension in the X-Y plane). In one embodiment, on any X-Y plane (this X-Y plane intersects with the first hole 137 , the second hole 138 and the third hole 139 ), the transverse cross-sectional dimension of the first hole 137 is smaller than the transverse cross-section of the second hole 138 The transverse cross-sectional dimension of the first hole 137 is smaller than that of the third hole 139 , and the transverse cross-sectional dimension of the second hole 138 is approximately the same as the transverse cross-sectional dimension of the third hole 139 .
請參照第8圖,記憶膜117與通道層118’形成於絕緣堆疊結構102’上且襯裡式地形成於第一孔137、第二孔138與第三孔中。在第一孔137、第二孔138與第三孔中,記憶膜117與通道層118’形成於第一孔137、第二孔138與第三孔之內側壁與底部。在一實施例中,記憶膜117與通道層118’可藉由沉積處理來形成,例如是藉由化學氣相沉積處理。在一示例中,記憶膜117與通道層118’形成於爐管(furnace)中。Referring to FIG. 8, the memory film 117 and the channel layer 118' are formed on the insulating stack structure 102' and are lined in the first hole 137, the second hole 138 and the third hole. In the first hole 137, the second hole 138 and the third hole, the memory film 117 and the channel layer 118' are formed on the inner sidewall and bottom of the first hole 137, the second hole 138 and the third hole. In one embodiment, the memory film 117 and the channel layer 118' may be formed by a deposition process, such as by chemical vapor deposition. In one example, the memory film 117 and the channel layer 118' are formed in a furnace.
記憶膜117可包含記憶體技術領域中已知的多層結構,例如ONO結構、ONONO結構、ONONONO結構、SONOS (矽-氧化矽-氮化矽-氧化矽-矽)結構、BE-SONOS結構、TANOS結構、MA BE-SONOS結構及其組合。通道層118’可包含半導體材料,例如是摻雜的半導體材料或未摻雜的半導體材料。在一實施例中,通道層118’可包含多晶矽,例如摻雜的多晶矽或未摻雜的多晶矽。The memory film 117 may include a multi-layer structure known in the field of memory technology, such as ONO structure, ONONO structure, ONONONO structure, SONOS (silicon-silicon oxide-silicon nitride-silicon oxide-silicon) structure, BE-SONOS structure, TANOS structure Structure, MA BE-SONOS structure and combinations thereof. The channel layer 118' may comprise a semiconductor material, such as a doped semiconductor material or an undoped semiconductor material. In one embodiment, the channel layer 118' may comprise polysilicon, such as doped polysilicon or undoped polysilicon.
請參照第9圖,絕緣堆疊結構102’上的記憶膜117與通道層118’被移除以暴露絕緣堆疊結構102’之頂部,且形成在X-Y平面上平坦的頂部表面。通道層118’可包含如第1圖繪示之虛設通道層118、通道層118A等。在此處理階段,位於第一孔137、第二孔138與第三孔139底部之通道層118’與記憶膜117被移除以暴露出介電層136。換言之,位於第一孔137、第二孔138與第三孔139底部之通道層118/118A未相連,以避免漏電流路徑 (current leakage path)。通道層118/118A可具有管狀且具有兩開放的端部。在一實施例中,絕緣堆疊結構102’上的記憶膜117、絕緣堆疊結構102’上的通道層118’與第一孔137、第二孔138和第三孔139底部之通道層118’、記憶膜117之移除可藉由回蝕(etching-back)處理來進行。Referring to FIG. 9, the memory film 117 and the channel layer 118' on the insulating stack structure 102' are removed to expose the top of the insulating stack structure 102' and form a flat top surface on the X-Y plane. The channel layer 118' may include a dummy channel layer 118, a channel layer 118A, etc. as shown in FIG. 1 . At this stage of processing, the channel layer 118' and the memory film 117 at the bottom of the first hole 137, the second hole 138 and the third hole 139 are removed to expose the dielectric layer 136. In other words, the channel layers 118/118A at the bottoms of the first hole 137, the second hole 138 and the third hole 139 are not connected to avoid a current leakage path. The channel layer 118/118A may have a tubular shape and have two open ends. In one embodiment, the memory film 117 on the insulating stack structure 102', the channel layer 118' on the insulating stack structure 102', and the channel layer 118' at the bottom of the first hole 137, the second hole 138 and the third hole 139, The removal of the memory film 117 may be performed by an etching-back process.
請參照第10圖,絕緣膜119形成於第一孔137、第二孔138與第三孔139中。絕緣膜119可包含介電材料,介電材料包含氧化物,例如氧化矽。在一實施例中,絕緣膜119可藉由以下步驟來形成:在絕緣堆疊結構102’上沉積絕緣膜119,且填充第一孔137、第二孔138與第三孔139;移除絕緣堆疊結構102’上的絕緣膜119以暴露絕緣堆疊結構102’之頂表面141,例如是藉由化學機械平坦化(chemical-mechanical planarization)處理或回蝕處理;第一開孔142、第二開孔143與第三開孔144分別形成於第一孔137、第二孔138與第三孔139中的絕緣膜119中,例如是藉由溼式蝕刻或乾式蝕刻。第一開孔142、第二開孔143與第三開孔144沿著Z方向延伸且暴露第一孔137、第二孔138與第三孔139中的絕緣膜119之側壁。在一實施例中,用以形成第一開孔142、第二開孔143與第三開孔144之蝕刻處理可停止於絕緣膜119。在一實施例中,第一開孔142、第二開孔143與第三開孔144可分別位於第一孔137、第二孔138與第三孔139的中央。Referring to FIG. 10 , the insulating film 119 is formed in the first hole 137 , the second hole 138 and the third hole 139 . The insulating film 119 may include a dielectric material including an oxide such as silicon oxide. In one embodiment, the insulating film 119 may be formed by the following steps: depositing the insulating film 119 on the insulating stack structure 102' and filling the first hole 137, the second hole 138 and the third hole 139; removing the insulating stack The insulating film 119 on the structure 102' to expose the top surface 141 of the insulating stacked structure 102', for example, by chemical-mechanical planarization or etch-back; the first opening 142, the second opening 143 and the third opening 144 are respectively formed in the insulating film 119 in the first hole 137, the second hole 138 and the third hole 139, for example, by wet etching or dry etching. The first opening 142 , the second opening 143 and the third opening 144 extend along the Z direction and expose the sidewalls of the insulating film 119 in the first opening 137 , the second opening 138 and the third opening 139 . In one embodiment, the etching process for forming the first opening 142 , the second opening 143 and the third opening 144 may stop at the insulating film 119 . In one embodiment, the first opening 142 , the second opening 143 and the third opening 144 may be located at the center of the first hole 137 , the second hole 138 and the third hole 139 , respectively.
在一實施例中,在任意一個X-Y平面(此X-Y平面和第一開孔142、第二開孔143與第三開孔144交錯)上,第一開孔142的橫向剖面尺寸小於第二開孔143的橫向剖面尺寸,第一開孔142的橫向剖面尺寸小於第三開孔144的橫向剖面尺寸,第二開孔143的橫向剖面尺寸大致和第三開孔144的橫向剖面尺寸相同。In one embodiment, on any X-Y plane (this X-Y plane intersects with the first opening 142, the second opening 143 and the third opening 144), the transverse cross-sectional dimension of the first opening 142 is smaller than that of the second opening. The transverse cross-sectional dimension of the hole 143 , the transverse cross-sectional dimension of the first opening 142 is smaller than that of the third opening 144 , and the transverse cross-sectional dimension of the second opening 143 is approximately the same as that of the third opening 144 .
請參照第11圖,絕緣柱125分別形成於第一開孔142、第二開孔143與第三開孔144中。絕緣柱125可包含絕緣材料,絕緣材料包含氮化物,例如氮化矽。絕緣柱125可藉由沉積處理來形成,例如是藉由化學氣相沉積處理。Referring to FIG. 11 , the insulating pillars 125 are respectively formed in the first opening 142 , the second opening 143 and the third opening 144 . The insulating pillars 125 may include insulating materials including nitrides, such as silicon nitride. The insulating pillars 125 may be formed by a deposition process, such as by chemical vapor deposition.
請參照第12圖,源極/汲極柱123和源極/汲極柱124形成於第一開孔142中的絕緣柱125之相對側。絕緣柱125使源極/汲極柱123隔離於源極/汲極柱124彼此。源極/汲極柱123和源極/汲極柱124可以以下步驟來形成:在第一開孔142中的絕緣柱125之相對側形成兩個窄開孔,該些窄開孔可使通道層118A之側壁、及/或絕緣柱125之側壁暴露;源極/汲極柱123和源極/汲極柱124分別形成於窄開孔中以填滿該些窄開孔。在一實施例中,窄開孔可藉由蝕刻處理來形成,例如是藉由溼式蝕刻或乾式蝕刻。窄開孔可彼此不重疊。在一實施例中,源極/汲極柱123和源極/汲極柱124可藉由沉積處理來形成,例如是藉由化學氣相沉積處理。源極/汲極柱123和源極/汲極柱124可包含摻雜的半導體材料,例如N+多晶矽,或可包含未摻雜的半導體材料。在源極/汲極柱123和源極/汲極柱124之間設置絕緣柱125有助於提升製程視窗(process window)以避免衝穿(PLG-to-PLG punch)發生。Referring to FIG. 12 , the source/drain pillars 123 and the source/drain pillars 124 are formed on opposite sides of the insulating pillars 125 in the first openings 142 . The insulating pillars 125 isolate the source/drain pillars 123 from the source/drain pillars 124 from each other. The source/drain pillars 123 and the source/drain pillars 124 may be formed by forming two narrow openings on opposite sides of the insulating pillars 125 in the first openings 142, the narrow openings allowing the channel The sidewalls of the layer 118A, and/or the sidewalls of the insulating pillars 125 are exposed; the source/drain pillars 123 and the source/drain pillars 124 are respectively formed in the narrow openings to fill the narrow openings. In one embodiment, the narrow openings may be formed by an etching process, such as by wet etching or dry etching. The narrow openings may not overlap each other. In one embodiment, the source/drain pillars 123 and the source/drain pillars 124 may be formed by a deposition process, such as by a chemical vapor deposition process. Source/drain pillars 123 and source/drain pillars 124 may comprise doped semiconductor material, such as N+ polysilicon, or may comprise undoped semiconductor material. Disposing the insulating pillars 125 between the source/drain pillars 123 and the source/drain pillars 124 helps to improve the process window to avoid PLG-to-PLG punch.
請參照第13圖,溝槽145形成於絕緣堆疊結構102’中。溝槽145在Z方向上通過絕緣堆疊結構102’。溝槽145使絕緣堆疊結構102’與多晶半導體層126之側壁暴露。在一實施例中,可對絕緣堆疊結構102’進行蝕刻處理,例如是藉由溼式蝕刻或乾式蝕刻,以形成溝槽145,且使蝕刻處理停止於多晶半導體層126。Referring to FIG. 13, trenches 145 are formed in the insulating stack structure 102'. Trench 145 passes through insulating stack 102' in the Z direction. The trenches 145 expose the sidewalls of the insulating stack structure 102' and the polycrystalline semiconductor layer 126. In one embodiment, the insulating stack structure 102 ′ may be etched, such as by wet etching or dry etching, to form the trenches 145 and stop the etching process at the polycrystalline semiconductor layer 126 .
請參照第14圖,透過溝槽145進行蝕刻處理以移除部分的第二絕緣層110’ (即第一孔137與第二孔138周圍的第二絕緣層110’),以形成第三絕緣層111’之間的空間。在一實施例中,蝕刻處理可使用熱磷酸(phosphoric acid; H3
PO4
)。藉由控制蝕刻處理的時間,可使部分的第二絕緣層110’ (即第一孔137與第二孔138周圍的第二絕緣層110’)被移除,同時保留其他部分的第二絕緣層110’ (即第三孔139周圍的第二絕緣層110’)。換言之,第三孔139周圍的第二絕緣層110’不會在蝕刻處理中被移除。然後,介電膜146可襯裡式地形成於第三絕緣層111’之間的空間中。導電材料147,例如鎢,可形成以填充第三絕緣層111’之間的空間,以形成如第1圖所示之導電膜104與導電階梯層106。介電膜146可包含儲存層與阻擋層(未繪示)。介電膜146可包含高介電常數(high-k)材料。在一實施例中,導電膜104可做為閘極。在一實施例中,介電膜146與導電膜104可藉由HKMG (High-k Metal Gate)製程來形成。包含於第14圖之製程可被理解為閘極取代(gate replacement)製程。Referring to FIG. 14, etching is performed through the trench 145 to remove part of the second insulating layer 110' (ie, the second insulating layer 110' around the first hole 137 and the second hole 138) to form a third insulating layer space between layers 111'. In one embodiment, the etching process may use hot phosphoric acid (phosphoric acid; H 3 PO 4 ). By controlling the etching time, part of the second insulating layer 110 ′ (ie, the second insulating layer 110 ′ around the first hole 137 and the second hole 138 ) can be removed, while remaining part of the second insulating layer layer 110' (ie, the second insulating layer 110' around the third hole 139). In other words, the second insulating layer 110' around the third hole 139 is not removed in the etching process. Then, a dielectric film 146 may be lined in the space between the third insulating layers 111'. A conductive material 147 , such as tungsten, may be formed to fill the space between the third insulating layers 111 ′ to form the conductive film 104 and the conductive stepped layer 106 as shown in FIG. 1 . The dielectric film 146 may include a storage layer and a barrier layer (not shown). The dielectric film 146 may include a high dielectric constant (high-k) material. In one embodiment, the conductive film 104 can be used as a gate. In one embodiment, the dielectric film 146 and the conductive film 104 may be formed by an HKMG (High-k Metal Gate) process. The process included in FIG. 14 may be understood as a gate replacement process.
在一實施例中,記憶裝置10之記憶層可包含第14圖所示之記憶膜117與介電膜146。也就是說,介電膜146可做為記憶材料。記憶層可包含記憶體技術領域中已知的任意電荷捕捉結構,例如ONO結構、ONONO結構、ONONONO結構、SONOS結構、BE-SONOS結構、TANOS結構、MA BE-SONOS結構及其組合等。電荷捕捉結構可使用氮化物例如氮化矽,或是其他類似的高介電常數物質包括金屬氧化物,例如三氧化二鋁(Al2
O3
)、氧化鋯(HfO2
)等。記憶胞可定義在記憶層中。舉例來說,在記憶層包含記憶膜117與介電膜146的情況下,記憶膜117可理解為穿隧氧化層,記憶膜117可包含二氧化矽(SiO2
)或者僅包含二氧化矽;而介電膜146可做為記憶材料,介電膜146可包含記憶體技術領域中已知的多層記憶材料,例如三氧化二鋁、氮化鈦(TiN)、ONO結構、ONONO結構、ONONONO結構、SONOS結構、BE-SONOS結構、TANOS結構、MA BE-SONOS結構及其組合等。In one embodiment, the memory layer of the memory device 10 may include the memory film 117 and the dielectric film 146 shown in FIG. 14 . That is, the dielectric film 146 may serve as a memory material. The memory layer may include any charge trapping structure known in the memory technology field, such as ONO structure, ONONO structure, ONONONO structure, SONOS structure, BE-SONOS structure, TANOS structure, MA BE-SONOS structure and combinations thereof. The charge trapping structure may use nitrides such as silicon nitride, or other similar high dielectric constant materials including metal oxides such as aluminum oxide (Al 2 O 3 ), zirconium oxide (HfO 2 ), and the like. Memory cells can be defined in memory layers. For example, when the memory layer includes the memory film 117 and the dielectric film 146, the memory film 117 can be understood as a tunnel oxide layer, and the memory film 117 can include silicon dioxide (SiO 2 ) or only silicon dioxide; The dielectric film 146 can be used as a memory material, and the dielectric film 146 can include multilayer memory materials known in the field of memory technology, such as aluminum oxide, titanium nitride (TiN), ONO structure, ONONO structure, ONONONO structure , SONOS structure, BE-SONOS structure, TANOS structure, MA BE-SONOS structure and combinations thereof, etc.
然後,絕緣條103形成以填充溝槽145,例如藉由沉積處理。Then, insulating strips 103 are formed to fill trenches 145, eg, by a deposition process.
請參照第15圖,導電柱114形成於第二孔138與第三孔139中的絕緣膜119中。導電柱114沿著Z方向延伸、通過介電層136、且接觸半導體裝置129,例如是接觸第三下金屬層(BM3)。導電柱114可包含導電材料,例如鎢。在一實施例中,導電柱114可藉由以下步驟來形成:藉由蝕刻處理,例如是藉由溼式蝕刻或乾式蝕刻,來移除形成於第二開孔143與第三開孔144中的絕緣柱125 (如第10-11圖所示);蝕刻處理可停止於介電層136的底表面148;藉由蝕刻處理形成深開孔;藉由沉積處理使導電柱114分別形成於深開孔中,例如是藉由化學氣相沉積處理。導電柱114電性連接於半導體裝置129。在此處理階段中,形成於第二孔138中的導電柱114可理解為第1圖所示之階梯結構101中的導電柱114,且形成於第三孔139中的導電柱114可理解為第1圖所示之絕緣堆疊結構102A中的導電柱114。Referring to FIG. 15 , the conductive pillars 114 are formed in the insulating film 119 in the second hole 138 and the third hole 139 . The conductive pillars 114 extend along the Z direction, pass through the dielectric layer 136, and contact the semiconductor device 129, eg, the third lower metal layer (BM3). The conductive pillars 114 may include a conductive material, such as tungsten. In one embodiment, the conductive pillars 114 may be formed by the following steps: removing the conductive pillars 114 formed in the second openings 143 and the third openings 144 by an etching process, such as wet etching or dry etching 10-11); the etching process can be stopped at the bottom surface 148 of the dielectric layer 136; deep openings are formed by the etching process; the conductive posts 114 are respectively formed in the deep The openings are processed, for example, by chemical vapor deposition. The conductive pillar 114 is electrically connected to the semiconductor device 129 . In this processing stage, the conductive pillars 114 formed in the second holes 138 can be understood as the conductive pillars 114 in the stepped structure 101 shown in FIG. 1 , and the conductive pillars 114 formed in the third holes 139 can be understood as The conductive pillars 114 in the insulating stack structure 102A shown in FIG. 1 .
本揭露提供記憶裝置,其具有被虛設通道層圍繞之位元線接觸、源極線接觸及/或字元線接觸,且位元線接觸、源極線接觸及/或字元線接觸可被管狀元件保護與電性絕緣。由於具有這樣的配置,可省略記憶裝置中用以使位元線接觸、源極線接觸及/或字元線接觸電性絕緣之額外的隔離區,可提升記憶裝置之空間效率、可降低生產成本、可提升記憶裝置之設計自由度,且可改善製程整合度。此外,本揭露提供具有多晶半導體層之記憶裝置,多晶半導體層用來作為蝕刻停止層,多晶半導體層有助於提升用於柱元件之孔的均勻度,且同時可提升蝕刻處理之可控性。The present disclosure provides memory devices having bit line contacts, source line contacts, and/or word line contacts surrounded by dummy channel layers, and the bit line contacts, source line contacts, and/or word line contacts can be Tubular element protection and electrical insulation. With such a configuration, additional isolation regions for electrically insulating bit line contacts, source line contacts and/or word line contacts in the memory device can be omitted, which can improve the space efficiency of the memory device and reduce production cost, can improve the design freedom of memory devices, and can improve the degree of process integration. In addition, the present disclosure provides a memory device having a polycrystalline semiconductor layer used as an etch stop layer, the polycrystalline semiconductor layer helps to improve the uniformity of holes for pillar elements, and at the same time can improve the efficiency of the etching process controllability.
應注意的是,如上所述之圖式、結構和步驟,是用以敘述本揭露之部分實施例或應用例,本揭露並不限制於上述結構和步驟之範圍與應用態樣。其他不同結構態樣之實施例,例如不同內部組件的已知構件都可應用,其示例之結構和步驟可根據實際應用之需求而調整。因此圖式之結構僅用以舉例說明之,而非用以限制本發明。通常知識者當知,應用本揭露之相關結構和步驟過程,例如半導體結構中的相關元件和層的排列方式或構型,或製造步驟細節等,都可能依實際應用樣態所需而可能有相應的調整和變化。It should be noted that the above-mentioned diagrams, structures and steps are used to describe some embodiments or application examples of the present disclosure, and the present disclosure is not limited to the scope and application of the above-mentioned structures and steps. Other embodiments with different structural aspects, such as known components of different internal components, can be applied, and the exemplary structures and steps can be adjusted according to the needs of practical applications. Therefore, the structures in the drawings are only used to illustrate, but not to limit the present invention. Those skilled in the art should know that the related structures and steps in the application of the present disclosure, such as the arrangement or configuration of the related elements and layers in the semiconductor structure, or the details of the manufacturing steps, etc., may be required according to the actual application. Adjustments and changes accordingly.
綜上所述,雖然本發明已以實施例揭露如上,然而其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍前提下,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。To sum up, although the present invention has been disclosed by the above embodiments, it is not intended to limit the present invention. Those skilled in the art to which the present invention pertains can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be determined by the scope of the appended patent application.