TW202203430A - Semiconductor device and method of manufacturing the same - Google Patents

Semiconductor device and method of manufacturing the same Download PDF

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TW202203430A
TW202203430A TW109123184A TW109123184A TW202203430A TW 202203430 A TW202203430 A TW 202203430A TW 109123184 A TW109123184 A TW 109123184A TW 109123184 A TW109123184 A TW 109123184A TW 202203430 A TW202203430 A TW 202203430A
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capacitor
semiconductor device
floating gate
dielectric layer
upper electrode
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TW109123184A
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TWI725891B (en
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黃聖惠
張三榮
張立鵬
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力晶積成電子製造股份有限公司
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Priority to CN202010729805.5A priority patent/CN113921521A/en
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B41/00Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
    • H10B41/30Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
    • H10B41/35Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region with a cell select transistor, e.g. NAND
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/30DRAM devices comprising one-transistor - one-capacitor [1T-1C] memory cells
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B12/00Dynamic random access memory [DRAM] devices
    • H10B12/50Peripheral circuit region structures
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10BELECTRONIC MEMORY DEVICES
    • H10B43/00EEPROM devices comprising charge-trapping gate insulators
    • H10B43/30EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region
    • H10B43/35EEPROM devices comprising charge-trapping gate insulators characterised by the memory core region with cell select transistors, e.g. NAND

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Abstract

A semiconductor device and a method of manufacturing the same are provided. The semiconductor device with a cell region and a periphery region, and it includes a substrate, a capacitor over bitline (COB) dynamic random access memory (DRAM), and a multi-time programmable memory (MTP). The COB DRAM is disposed in the cell region and includes a bit line and a first capacitor. The MTP is disposed in the periphery region, and includes a floating gate formed on the substrate, a second capacitor on the floating gate, and at least one contact electrically connecting the floating gate and the second capacitor. The floating gate is a structure patterned simultaneously with the bit line, and the second capacitor is a capacitor structure manufactured simultaneously with the first capacitor.

Description

半導體裝置及其製造方法Semiconductor device and method of manufacturing the same

本發明是有關於一種半導體技術,且特別是有關於一種半導體裝置及其製造方法。The present invention relates to a semiconductor technology, and more particularly, to a semiconductor device and a method of manufacturing the same.

記憶體為用以儲存資訊或資料的半導體元件,廣泛地應用於個人電腦、行動電話、網路等方面,已成為生活中不可或缺的重要電子產品。由於電腦微處理器的功能越來越強,軟體所進行的程式與運算也隨之增加,且各種資料儲存量也日趨增加,因此記憶體的容量需求也就越來越高。Memory is a semiconductor device used to store information or data. It is widely used in personal computers, mobile phones, networks, etc., and has become an indispensable and important electronic product in life. As the functions of computer microprocessors are getting stronger and stronger, the programs and operations performed by software are also increasing, and the storage capacity of various data is also increasing day by day, so the demand for memory capacity is getting higher and higher.

傳統的多次可程式化(multi-time programmable memory,MTP)記憶胞結構是以摻雜多晶矽製作浮置閘極與控制閘極,以進行抹除/寫入的操作。近來為了避免因過度抹除/寫入而導致資料誤判的問題,將記憶胞的一側串接一選擇電晶體(select transistor),而形成兩個電晶體結構,並藉由選擇電晶體來控制記憶胞的程式化和讀取。In a traditional multi-time programmable memory (MTP) memory cell structure, a floating gate and a control gate are fabricated by doped polysilicon for erase/write operations. Recently, in order to avoid the problem of data misjudgment caused by excessive erasing/writing, one side of the memory cell is connected in series with a select transistor to form a two transistor structure, which is controlled by the select transistor. Programming and reading of memory cells.

然而,由於晶片上同時有單元區與周邊區的元件需要製作,而記憶體單元與周邊元件的製程通常是分開進行的,因此需要多道光罩以及複雜的製程步驟,導致成本與時間增加。However, since there are devices in both the cell area and the peripheral area on the wafer to be fabricated, and the fabrication processes of the memory cell and peripheral devices are usually performed separately, multiple masks and complicated process steps are required, resulting in increased cost and time.

本發明提供一種半導體裝置,具有與位元線上電容器(capacitor over bitline,COB)式動態隨機存取記憶體(DRAM)同時製作的多次可程式化記憶體(MTP),能降低製程成本與時間。The present invention provides a semiconductor device having a multi-time programmable memory (MTP) simultaneously fabricated with a capacitor over bitline (COB) type dynamic random access memory (DRAM), which can reduce process cost and time .

本發明另提供一種半導體裝置的製造方法,能將MTP的浮置閘極、閘間介電層與控制閘極整合至COB式DRAM的製程中。The present invention further provides a manufacturing method of a semiconductor device, which can integrate the floating gate of the MTP, the inter-gate dielectric layer and the control gate into the COB-type DRAM manufacturing process.

本發明的半導體裝置具有單元區與周邊區,包括基板、位元線上電容器(COB)式動態隨機存取記憶體(DRAM)與多次可程式化記憶體(MTP)。COB式DRAM設置於單元區,並且包括位元線以及第一電容器。MTP設置於周邊區,並且包括形成於所述基板上的浮置閘極、位於浮置閘極上的第二電容器以及電性連接所述浮置閘極與所述第二電容器的至少一接觸窗。浮置閘極係與所述位元線同時圖案化的結構,第二電容器是與第一電容器同時製作的電容器結構。The semiconductor device of the present invention has a cell area and a peripheral area, including a substrate, a capacitor on bit line (COB) type dynamic random access memory (DRAM) and a multiple time programmable memory (MTP). The COB-type DRAM is disposed in the cell region and includes a bit line and a first capacitor. The MTP is disposed in the peripheral region, and includes a floating gate formed on the substrate, a second capacitor located on the floating gate, and at least one contact window electrically connecting the floating gate and the second capacitor . The floating gate is a structure patterned at the same time as the bit line, and the second capacitor is a capacitor structure fabricated at the same time as the first capacitor.

在本發明的一實施例中,上述MTP還可包括穿隧氧化層,位於所述基板與所述浮置閘極之間。In an embodiment of the present invention, the MTP may further include a tunnel oxide layer located between the substrate and the floating gate.

在本發明的一實施例中,上述浮置閘極的材料包括摻雜的多晶矽或多晶矽化金屬。In an embodiment of the present invention, the material of the floating gate includes doped polysilicon or polysilicon metal.

在本發明的一實施例中,上述MTP還可包括一金屬膜,形成於浮置閘極表面並與接觸窗直接接觸。In an embodiment of the present invention, the MTP may further include a metal film formed on the surface of the floating gate and in direct contact with the contact window.

在本發明的一實施例中,上述金屬膜與上述位元線係同時沉積的結構層。In an embodiment of the present invention, the metal film and the bit line are structural layers deposited simultaneously.

在本發明的一實施例中,上述第一電容器包括第一下電極、第一介電層與第一上電極,上述第二電容器包括第二下電極、第二介電層與第二上電極,其中第二下電極係與第一下電極同時製作的電極結構,且第二上電極係與第一上電極同時製作的電極結構。In an embodiment of the present invention, the first capacitor includes a first lower electrode, a first dielectric layer and a first upper electrode, and the second capacitor includes a second lower electrode, a second dielectric layer and a second upper electrode , wherein the second lower electrode is an electrode structure fabricated at the same time as the first lower electrode, and the second upper electrode is an electrode structure fabricated at the same time as the first upper electrode.

在本發明的一實施例中,上述半導體裝置還可包括第零層金屬層,介於第二下電極與接觸窗之間,並與所述接觸窗直接接觸。In an embodiment of the present invention, the above-mentioned semiconductor device may further include a zero-th metal layer between the second lower electrode and the contact window and in direct contact with the contact window.

在本發明的一實施例中,上述第一電容器與上述第二電容器為具有凹槽的結構,且第一上電極與第二上電極各自包括位於所述凹槽上方的上電極層以及填入所述凹槽內並位於上電極層下方的導體材料。In an embodiment of the present invention, the first capacitor and the second capacitor have a structure with a groove, and the first upper electrode and the second upper electrode each include an upper electrode layer located above the groove and a filling Conductive material within the groove and below the upper electrode layer.

在本發明的一實施例中,上述導體材料包括多晶矽或多晶矽化金屬,且第二電容器內的導體材料係作為上述MTP的控制閘極。In an embodiment of the present invention, the conductor material includes polysilicon or polysilicon, and the conductor material in the second capacitor is used as the control gate of the MTP.

在本發明的一實施例中,上述第二電容器中的凹槽的數量為多個,可構成並聯的電容器。In an embodiment of the present invention, the number of grooves in the second capacitor is multiple, which can form parallel capacitors.

在本發明的一實施例中,上述第二介電層與上述第一介電層為高介電常數材料。In an embodiment of the present invention, the second dielectric layer and the first dielectric layer are high dielectric constant materials.

在本發明的一實施例中,上述第二介電層的厚度可大於上述第一介電層的厚度。In an embodiment of the present invention, the thickness of the second dielectric layer may be greater than the thickness of the first dielectric layer.

在本發明的一實施例中,上述第二電容器的數量為多個,可構成串聯的電容器。In an embodiment of the present invention, the number of the above-mentioned second capacitors is plural, which can constitute capacitors connected in series.

本發明的半導體裝置的製造方法包括在單元區形成位元線上電容器(COB)式動態隨機存取記憶體(DRAM)的DRAM元件,所述DRAM元件包括位元線。在周邊區形成浮置閘極,且浮置閘極係與上述位元線同時圖案化的結構。在所述浮置閘極上形成至少一接觸窗,然後同時製作第一電容器與第二電容器,所述第一電容器形成於DRAM元件上,所述第二電容器形成於接觸窗上。第二電容器通過所述接觸窗電性連接至浮置閘極,以使浮置閘極、接觸窗與第二電容器構成多次可程式化記憶體(MTP)。A method of manufacturing a semiconductor device of the present invention includes forming a DRAM element of a capacitor on bit line (COB) type dynamic random access memory (DRAM) in a cell region, the DRAM element including a bit line. A floating gate is formed in the peripheral region, and the floating gate is a structure patterned simultaneously with the bit line. At least one contact window is formed on the floating gate, and then a first capacitor and a second capacitor are simultaneously fabricated, the first capacitor is formed on the DRAM element, and the second capacitor is formed on the contact window. The second capacitor is electrically connected to the floating gate through the contact window, so that the floating gate, the contact window and the second capacitor constitute a multi-time programmable memory (MTP).

在本發明的另一實施例中,形成上述浮置閘極之前還可先在周邊區的基板上形成穿隧氧化層。In another embodiment of the present invention, a tunnel oxide layer may also be formed on the substrate in the peripheral region before forming the floating gate.

在本發明的另一實施例中,形成上述浮置閘極之後還可在上述浮置閘極表面形成一金屬膜。In another embodiment of the present invention, after the floating gate is formed, a metal film may also be formed on the surface of the floating gate.

在本發明的另一實施例中,同時製作上述第一與第二電容器的方法包括先同時製作第一電容器的第一下電極以及第二電容器的第二下電極,在第一下電極上形成第一介電層以及在第二下電極上形成第二介電層,然後同時在第一介電層上形成上述第一電容器的第一上電極以及在第二介電層上形成上述第二電容器的第二上電極。In another embodiment of the present invention, the method for simultaneously fabricating the first and second capacitors includes simultaneously fabricating the first lower electrode of the first capacitor and the second lower electrode of the second capacitor, and forming the first lower electrode on the first lower electrode. The first dielectric layer and the second dielectric layer are formed on the second lower electrode, and then the first upper electrode of the first capacitor is formed on the first dielectric layer and the second dielectric layer is formed on the second dielectric layer at the same time. the second top electrode of the capacitor.

在本發明的另一實施例中,同時製作上述第一與第二電容器之前還可先在DRAM元件上與浮置閘極上各自形成凹槽結構。In another embodiment of the present invention, a groove structure may be formed on the DRAM element and the floating gate before the first and second capacitors are simultaneously fabricated.

在本發明的另一實施例中,形成上述第一上電極與上述第二上電極的方法包括於上述凹槽結構內填入導體材料,再於所述導體材料上形成上電極層,且上述第二電容器內的導體材料係作為MTP的控制閘極。In another embodiment of the present invention, the method for forming the first upper electrode and the second upper electrode includes filling a conductor material in the groove structure, and then forming an upper electrode layer on the conductor material, and the above The conductor material in the second capacitor acts as the control gate of the MTP.

在本發明的另一實施例中,在浮置閘極上形成的上述凹槽結構的數量例如多個。In another embodiment of the present invention, the number of the above-mentioned groove structures formed on the floating gate is, for example, multiple.

在本發明的另一實施例中,上述第一介電層與上述第二介電層是同時形成的。In another embodiment of the present invention, the first dielectric layer and the second dielectric layer are formed simultaneously.

在本發明的另一實施例中,上述第一介電層與上述第二介電層是分開形成的,且第二介電層的厚度大於第一介電層的厚度。In another embodiment of the present invention, the first dielectric layer and the second dielectric layer are formed separately, and the thickness of the second dielectric layer is greater than that of the first dielectric layer.

在本發明的另一實施例中,同時製作上述第一與第二電容器之前還可先在上述接觸窗上形成第零層金屬層。In another embodiment of the present invention, a zeroth metal layer may be formed on the contact window before the first and second capacitors are simultaneously fabricated.

在本發明的另一實施例中,上述第二電容器的數量為多個且彼此串聯。In another embodiment of the present invention, the number of the above-mentioned second capacitors is multiple and connected in series with each other.

基於上述,本發明藉由特定製程能將多次可程式化記憶體的浮置閘極、閘間介電層與控制閘極,整合至位元線上電容器式動態隨機存取記憶體的製程中,因此不但增加製程整合的可能性,還能進一步降低製程時間與成本。Based on the above, the present invention can integrate the floating gate, the inter-gate dielectric layer and the control gate of the multi-time programmable memory into the process of the capacitor dynamic random access memory on the bit line through a specific process. , thus not only increasing the possibility of process integration, but also further reducing process time and cost.

為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。In order to make the above-mentioned features and advantages of the present invention more obvious and easy to understand, the following embodiments are given and described in detail with the accompanying drawings as follows.

圖1是依照本發明的第一實施例的一種半導體裝置的剖面示意圖,其中圖1左顯示的是形成於單元(cell)區的位元線上電容器(capacitor over bitline,COB)式動態隨機存取記憶體(DRAM),圖1右顯示的是形成於周邊(periphery)區的多次可程式化記憶體(multi-time programmable memory,MTP)。1 is a schematic cross-sectional view of a semiconductor device according to a first embodiment of the present invention, wherein the left side of FIG. 1 shows a capacitor over bitline (COB) type dynamic random access formed in a cell region Memory (DRAM), shown on the right in Figure 1 is a multi-time programmable memory (MTP) formed in the peripheral area.

請參照圖1,第一實施例的半導體裝置具有單元區與周邊區,且包括基板10、COB式DRAM 100a與MTP 100b。Referring to FIG. 1 , the semiconductor device of the first embodiment has a cell region and a peripheral region, and includes a substrate 10 , a COB-type DRAM 100 a and an MTP 100 b.

在圖1中,COB式DRAM 100a設置於單元區,並且包括第一電容器102,其中第一電容器102包括第一下電極104、第一介電層106與第一上電極108,且第一下電極104例如Ti/TiN、第一介電層106例如高介電常數(high-k)材料。由於第一電容器102可以是具有凹槽110的結構,所以第一上電極108還可包括位於凹槽110上方的上電極層112以及填入所述凹槽110內並位於上電極層112下方的導體材料114,其中上電極層112例如鎢層、導體材料114例如多晶矽或多晶矽化金屬。MTP 100b是設置於周邊區,並且包括形成於基板10上的浮置閘極(FG)116、位於浮置閘極116上的第二電容器118以及電性連接浮置閘極116與第二電容器118的至少一接觸窗120。浮置閘極116可包括導體層122(材料例如摻雜的多晶矽或多晶矽化金屬)與其上方的一金屬膜124(材料例如鎢),而接觸窗120例如鎢插塞。In FIG. 1, the COB type DRAM 100a is disposed in the cell area, and includes a first capacitor 102, wherein the first capacitor 102 includes a first lower electrode 104, a first dielectric layer 106 and a first upper electrode 108, and the first lower The electrode 104 is, for example, Ti/TiN, and the first dielectric layer 106 is, for example, a high-k material. Since the first capacitor 102 may have a structure with the groove 110 , the first upper electrode 108 may further include the upper electrode layer 112 located above the groove 110 and the upper electrode layer 112 filled in the groove 110 and located below the upper electrode layer 112 . The conductor material 114, wherein the upper electrode layer 112 is such as a tungsten layer, and the conductor material 114 is such as polysilicon or polysilicon metal. The MTP 100b is disposed in the peripheral region, and includes a floating gate (FG) 116 formed on the substrate 10 , a second capacitor 118 located on the floating gate 116 , and electrically connecting the floating gate 116 and the second capacitor At least one contact window 120 of 118 . The floating gate 116 may include a conductor layer 122 (material such as doped polysilicon or polysilicon metal) and a metal film 124 (material such as tungsten) above it, while the contact 120 is such as a tungsten plug.

請繼續參照圖1,MTP 100b的第二電容器118是與第一電容器102同時製作的電容器結構,其中第二電容器118包括第二下電極126、第二介電層128與第二上電極130,且第二下電極126係與第一下電極104同時製作的電極結構,第二上電極130係與第一上電極108同時製作的電極結構,第二介電層128也可與第一介電層106同時製作。因此,第二下電極126與第一下電極104同樣可為Ti/TiN、第二介電層128與第一介電層106同樣可為高介電常數材料。在一實施例中,由於MTP 100b可能承受大電壓,所以第二介電層128也可與第一介電層106分開製作,使第二介電層128的厚度t2大於第一介電層106的厚度t1。Please continue to refer to FIG. 1 , the second capacitor 118 of the MTP 100 b is a capacitor structure fabricated at the same time as the first capacitor 102 , wherein the second capacitor 118 includes a second lower electrode 126 , a second dielectric layer 128 and a second upper electrode 130 , Furthermore, the second lower electrode 126 is an electrode structure fabricated at the same time as the first lower electrode 104 , the second upper electrode 130 is an electrode structure fabricated at the same time as the first upper electrode 108 , and the second dielectric layer 128 may also be connected to the first dielectric layer. Layer 106 is fabricated simultaneously. Therefore, the second lower electrode 126 and the first lower electrode 104 can also be made of Ti/TiN, and the second dielectric layer 128 and the first dielectric layer 106 can also be made of high dielectric constant materials. In one embodiment, since the MTP 100b may withstand a large voltage, the second dielectric layer 128 can also be fabricated separately from the first dielectric layer 106 , so that the thickness t2 of the second dielectric layer 128 is greater than that of the first dielectric layer 106 thickness t1.

COB式DRAM 100a一般還包含位於第一電容器102下方的DRAM元件132,例如位元線134(例如金屬導線)、基板10內的埋入式字元線136、基板10表面的摻雜區138、電性連接位元線134與摻雜區138的位元線接觸窗140(例如鎢插塞)、電性連接第一下電極104與另一摻雜區138的儲存節點接觸窗142等。然而,本發明並不限於此,凡是於COB式DRAM領域中已知的DRAM元件均可用於本發明。此外,在上述結構中還存在電性隔絕用的絕緣層144(例如氧化物層)以及內層介電層(ILD)146a、146b、146c、146d等。而在第一電容器102上方可設置第一層金屬層M1,與上電極層112經由接觸窗148(例如鎢插塞)電性連接,基板10內則有主動區隔離結構150(例如STI)。The COB-type DRAM 100a generally further includes DRAM elements 132 located under the first capacitor 102, such as bit lines 134 (eg, metal wires), buried word lines 136 in the substrate 10, doped regions 138 on the surface of the substrate 10, The bit line contacts 140 (eg, tungsten plugs) electrically connecting the bit lines 134 and the doped regions 138 , the storage node contacts 142 electrically connecting the first lower electrodes 104 and the other doped regions 138 , and the like. However, the present invention is not limited thereto, and any DRAM device known in the field of COB DRAM can be used in the present invention. In addition, an insulating layer 144 (eg, an oxide layer) for electrical isolation and inner layer dielectric layers (ILD) 146a, 146b, 146c, 146d, etc. exist in the above structure. A first metal layer M1 may be disposed above the first capacitor 102 to be electrically connected to the upper electrode layer 112 through a contact window 148 (eg, a tungsten plug), and an active region isolation structure 150 (eg, STI) is provided in the substrate 10 .

請繼續參照圖1,由於第一電容器102是具有凹槽110的結構,第二電容器118也可為具有凹槽152的結構,但是凹槽152與凹槽110的大小是根據光罩設計而定,所以兩者的尺寸與形狀可相同或不同。舉例來說,凹槽152與凹槽110例如具有圓柱狀的壁面,但是凹槽152的直徑可大於或小於凹槽110的直徑,且凹槽152的數量可根據需求設計為一個或多個。至於第二上電極130與第一上電極108因為是同時製作的,所以同樣可包括位於凹槽152上方的上電極層112以及填入凹槽152內並位於上電極層112下方的導體材料114,且第二電容器118內的導體材料114係作為MTP 100b的控制閘極(CG)。Please continue to refer to FIG. 1 , since the first capacitor 102 has a structure with a groove 110 , the second capacitor 118 can also have a structure with a groove 152 , but the size of the groove 152 and the groove 110 is determined according to the design of the photomask , so the size and shape of the two can be the same or different. For example, the grooves 152 and 110 have cylindrical walls, but the diameter of the grooves 152 can be larger or smaller than the diameter of the grooves 110 , and the number of the grooves 152 can be designed as one or more according to requirements. As for the second upper electrode 130 and the first upper electrode 108, since they are fabricated at the same time, they can also include the upper electrode layer 112 located above the groove 152 and the conductive material 114 filled in the groove 152 and located below the upper electrode layer 112. , and the conductor material 114 in the second capacitor 118 acts as the control gate (CG) of the MTP 100b.

在圖1中,MTP 100b一般還可包括一層位於基板10與浮置閘極116之間的穿隧氧化層(tunneling oxide)154,且於浮置閘極116兩側的基板10內可形成作為源極與汲極的摻雜區156。第一實施例的MTP 100b的金屬膜124還可與DRAM元件132的位元線134同時製作,因此位元線134的材料可與金屬膜124的材料相同。舉例來說,可在形成位元線接觸窗140之後,先於周邊區形成穿隧氧化層154以及沉積導體層122,再於整個基板10上全面地形成一層金屬膜,然後在進行圖案化得到浮置閘極116的步驟時,同時圖案化上述金屬膜,以製得DRAM元件132的位元線134。而且,MTP 100b的控制閘極不但可與COB式DRAM的電容器同時製作,其結構也可整合至一般半導體製程中,而包括第零層金屬層M0,其介於第二下電極126與接觸窗120之間,並與接觸窗120直接接觸。此外,在COB式DRAM 100a與MTP 100b中用來電性隔絕的內層介電層146b與146c都可同時製作。而在第二電容器118上方同樣可設置第一層金屬層M1,並與上電極層112經由接觸窗148電性連接。前述相同元件符號的構造可利用一樣的製程形成,以簡化製程。然而本發明並不限於此,也可利用不同製程形成。In FIG. 1 , the MTP 100 b generally further includes a tunneling oxide layer 154 between the substrate 10 and the floating gate 116 , and can be formed in the substrate 10 on both sides of the floating gate 116 as a Doped regions 156 for source and drain. The metal film 124 of the MTP 100b of the first embodiment can also be fabricated at the same time as the bit line 134 of the DRAM element 132, so the material of the bit line 134 can be the same as that of the metal film 124. For example, after the bit line contact window 140 is formed, the tunnel oxide layer 154 and the conductor layer 122 can be formed in the peripheral area first, and then a metal film can be formed on the entire substrate 10, and then patterned to obtain During the step of floating the gate electrode 116 , the above-mentioned metal film is patterned at the same time to form the bit line 134 of the DRAM element 132 . Moreover, the control gate of the MTP 100b can not only be fabricated at the same time as the capacitor of the COB DRAM, but its structure can also be integrated into the general semiconductor process, and includes the zeroth metal layer M0 between the second lower electrode 126 and the contact window. 120, and in direct contact with the contact window 120. In addition, both the interlayer dielectric layers 146b and 146c for electrical isolation in the COB DRAM 100a and the MTP 100b can be fabricated simultaneously. A first metal layer M1 may also be disposed above the second capacitor 118 and electrically connected to the upper electrode layer 112 through the contact window 148 . The aforementioned structures with the same reference numerals can be formed by the same process to simplify the process. However, the present invention is not limited to this, and can also be formed by different processes.

圖2A至圖2J是依照本發明的第二實施例的一種半導體裝置的製造流程剖面示意圖。2A to 2J are schematic cross-sectional views illustrating a manufacturing process of a semiconductor device according to a second embodiment of the present invention.

請先參照圖2A,在周邊區200a與單元區200b的基板20內先形成主動區隔離結構202,再於單元區200b的基板20內形成摻雜區204。然後,在單元區200b的基板20內形成埋入式字元線206,且形成埋入式字元線206之前可先形成絕緣層208。Referring to FIG. 2A first, the active region isolation structure 202 is formed in the substrate 20 of the peripheral region 200a and the cell region 200b, and then the doped region 204 is formed in the substrate 20 of the cell region 200b. Then, buried word lines 206 are formed in the substrate 20 of the cell region 200b, and an insulating layer 208 may be formed before the buried word lines 206 are formed.

然後,請參照圖2B,在單元區200b的基板20上形成一層內層介電層210之後,在內層介電層210內形成位元線接觸窗212;另外在周邊區200a的基板20上形成一層穿隧氧化層214與一層導體層216。接著,在周邊區200a與單元區200b的基板20上全面地沉積一層金屬膜,其中單元區200b的金屬膜218a可作為位元線、周邊區200a的金屬膜218b可作為MTP的浮置閘極的一部分,以利後續電特性。Then, referring to FIG. 2B , after forming an inner layer dielectric layer 210 on the substrate 20 of the unit region 200b, bit line contact windows 212 are formed in the inner layer dielectric layer 210; in addition, on the substrate 20 of the peripheral region 200a A tunnel oxide layer 214 and a conductor layer 216 are formed. Next, a metal film is fully deposited on the substrate 20 of the peripheral region 200a and the cell region 200b, wherein the metal film 218a of the cell region 200b can be used as a bit line, and the metal film 218b of the peripheral region 200a can be used as a floating gate of the MTP part to facilitate subsequent electrical characteristics.

之後,請參照圖2C,圖案化單元區200b的金屬膜218a與周邊區200a的金屬膜218b,以形成單元區200b的位元線218c,並繼續蝕刻去除金屬膜218b底下的導體層216與穿隧氧化層214,以形成周邊區200a的浮置閘極220。然後,在周邊區200a的基板20內形成作為源極與汲極的摻雜區222。Then, referring to FIG. 2C, the metal film 218a of the cell region 200b and the metal film 218b of the peripheral region 200a are patterned to form the bit line 218c of the cell region 200b, and the conductor layer 216 and the through-holes under the metal film 218b are continuously removed by etching. The tunnel oxide layer 214 is formed to form the floating gate 220 of the peripheral region 200a. Then, doped regions 222 serving as source and drain electrodes are formed in the substrate 20 of the peripheral region 200a.

接著,請參照圖2D,於整個基板20表面覆蓋一層內層介電層224。Next, referring to FIG. 2D , the entire surface of the substrate 20 is covered with an interlayer dielectric layer 224 .

然後,請參照圖2E,在周邊區200a的內層介電層224內形成電性連接浮置閘極220的至少一接觸窗226,其中接觸窗226例如鎢插塞,並可與金屬膜218b直接接觸。此外,形成接觸窗226的同時或者前後,可形成與摻雜區222接觸的接觸窗228。另外,在單元區200b則可形成連接至摻雜區204的儲存節點接觸窗230,並且在形成儲存節點接觸窗230之前可先形成與位元線218c隔絕的絕緣層232,即可完成COB式DRAM的DRAM元件234的製作。然而,本發明並不限於此,根據現有DRAM元件234的結構設計,還可在以上製程中增加其他步驟。接著,在內層介電層224上可形成第零層金屬層M0,並經由接觸窗226與金屬膜218b電性連接至浮置閘極220。第零層金屬層M0還可與接觸窗228接觸。Then, referring to FIG. 2E, at least one contact window 226 electrically connected to the floating gate 220 is formed in the ILD 224 of the peripheral region 200a, wherein the contact window 226 is, for example, a tungsten plug, and can be connected to the metal film 218b. direct contact. In addition, a contact window 228 in contact with the doped region 222 may be formed at the same time as or before or after the formation of the contact window 226 . In addition, a storage node contact window 230 connected to the doped region 204 can be formed in the cell region 200b, and an insulating layer 232 isolated from the bit line 218c can be formed before the storage node contact window 230 is formed, so as to complete the COB type Fabrication of the DRAM element 234 of the DRAM. However, the present invention is not limited to this. According to the structural design of the existing DRAM device 234, other steps may be added to the above process. Next, a zeroth metal layer M0 may be formed on the ILD 224 and electrically connected to the floating gate 220 through the contact window 226 and the metal film 218b. The zeroth metal layer M0 may also be in contact with the contact window 228 .

之後,請參照圖2F,可在周邊區200a與單元區200b的內層介電層224上形成另一內層介電層500,再於DRAM元件234上與浮置閘極220上方的內層介電層500中各自形成凹槽結構502,其中周邊區200a的凹槽結構502露出浮置閘極220上方的第零層金屬層M0、單元區200b的凹槽結構502露出儲存節點接觸窗230。在圖2F中的周邊區200a雖然顯示一個凹槽結構502,然而本發明並不限於此,在浮置閘極220上形成的凹槽結構502的數量也可以是多個。After that, referring to FIG. 2F , another ILD 500 can be formed on the ILD 224 of the peripheral region 200 a and the cell region 200 b , and then the ILD 500 can be formed on the DRAM element 234 and the internal layer above the floating gate 220 A groove structure 502 is formed in each of the dielectric layers 500, wherein the groove structure 502 of the peripheral region 200a exposes the zeroth metal layer M0 above the floating gate 220, and the groove structure 502 of the cell region 200b exposes the storage node contact window 230 . Although the peripheral region 200a in FIG. 2F shows one groove structure 502, the present invention is not limited thereto, and the number of groove structures 502 formed on the floating gate 220 may also be multiple.

然後,請參照圖2G,在基板20上全面地形成一層與凹槽結構502共形的導體層504,例如Ti/TiN。Then, referring to FIG. 2G , a conductor layer 504 , such as Ti/TiN, which is conformal to the groove structure 502 , is formed on the entire surface of the substrate 20 .

接著,請參照圖2H,去除周邊區200a與單元區200b的凹槽結構502以外的導體層504,保留下來的就是單元區200b的第一下電極504a以及周邊區200a的第二下電極504b。去除凹槽結構502以外的導體層504的方法例如直接將凹槽結構502以外的導體層504移除;或者,先全面地形成罩幕層(未繪示),再將凹槽結構502以外的罩幕層移除,直到露出導體層504,然後將暴露出的導體層504移除,留下凹槽結構502內的第一下電極504a以及第二下電極504b。2H, the conductor layer 504 outside the groove structure 502 of the peripheral region 200a and the cell region 200b is removed, and what remains is the first lower electrode 504a of the cell region 200b and the second lower electrode 504b of the peripheral region 200a. The method of removing the conductor layer 504 other than the groove structure 502 is, for example, to directly remove the conductor layer 504 other than the groove structure 502; The mask layer is removed until the conductor layer 504 is exposed, and then the exposed conductor layer 504 is removed, leaving the first lower electrode 504 a and the second lower electrode 504 b in the groove structure 502 .

之後,請參照圖2I,形成第一介電層506a與第二介電層506b。在本實施例中,單元區200b的第一介電層506a與周邊區200a的第二介電層506b是同時形成的,所以材料是相同的(例如高介電常數材料)、厚度也是相同的。然而,在另一實施例中,第一介電層506a與第二介電層506b是分開形成的,且周邊區200a的第二介電層506b的厚度可大於單元區200b的第一介電層506a的厚度,以應用於大電壓的操作。然後,同時在凹槽結構502內填入導體材料508(例如多晶矽或多晶矽化金屬),再於導體材料508上形成上電極層510,其中單元區200b的導體材料508與上電極層510構成第一上電極512,因此已完成由第一下電極504a、第一介電層506a和第一上電極512構成的第一電容器520。After that, referring to FIG. 2I, a first dielectric layer 506a and a second dielectric layer 506b are formed. In this embodiment, the first dielectric layer 506a of the cell region 200b and the second dielectric layer 506b of the peripheral region 200a are formed simultaneously, so the materials are the same (eg high dielectric constant material) and the thickness is also the same . However, in another embodiment, the first dielectric layer 506a and the second dielectric layer 506b are formed separately, and the thickness of the second dielectric layer 506b in the peripheral region 200a may be greater than that of the first dielectric layer in the cell region 200b thickness of layer 506a for high voltage operation. Then, a conductor material 508 (such as polysilicon or polysilicon metal) is filled into the groove structure 502 at the same time, and an upper electrode layer 510 is formed on the conductor material 508, wherein the conductor material 508 of the cell region 200b and the upper electrode layer 510 form the first electrode layer 510. An upper electrode 512, thus the first capacitor 520 formed by the first lower electrode 504a, the first dielectric layer 506a and the first upper electrode 512 has been completed.

接著,請參照圖2J,圖案化周邊區200a的內層介電層500上的結構,以形成由第二下電極504b、第二介電層506b和第二上電極514(含導體材料508a和上電極層510a)構成的第二電容器522,且第二電容器522內的導體材料508a係作為MTP的控制閘極。Next, referring to FIG. 2J, the structure on the inner layer dielectric layer 500 of the peripheral region 200a is patterned to form a second lower electrode 504b, a second dielectric layer 506b and a second upper electrode 514 (including the conductor material 508a and The second capacitor 522 formed by the upper electrode layer 510a), and the conductor material 508a in the second capacitor 522 is used as the control gate of the MTP.

在圖2J中,第一電容器520形成於DRAM元件234上,第二電容器522形成於接觸窗216上。第二電容器522通過所述接觸窗216電性連接至浮置閘極220,以使浮置閘極220、接觸窗226與第二電容器522構成多次可程式化記憶體(MTP)。而且從以上說明可得到本實施例能將MTP的浮置閘極、閘間介電層與控制閘極整合至COB式DRAM的製程中。In FIG. 2J , the first capacitor 520 is formed on the DRAM element 234 and the second capacitor 522 is formed on the contact window 216 . The second capacitor 522 is electrically connected to the floating gate 220 through the contact window 216 , so that the floating gate 220 , the contact window 226 and the second capacitor 522 form a multi-time programmable memory (MTP). Furthermore, it can be seen from the above description that the floating gate, the inter-gate dielectric layer and the control gate of the MTP can be integrated into the COB DRAM process in this embodiment.

圖3是依照本發明的第三實施例的一種半導體裝置中的MTP的剖面示意圖,其中使用與圖1右相同的元件符號來表示相同或近似的構件,且相同或近似的構件內容也可參照上述,不再贅述。3 is a schematic cross-sectional view of an MTP in a semiconductor device according to a third embodiment of the present invention, wherein the same reference numerals as those on the right side of FIG. 1 are used to denote the same or similar components, and the content of the same or similar components can also be referred to The above will not be repeated.

請參照圖3,本實施例是通過增加浮置閘極116上的凹槽152的數量,來增加電容耦合率(coupling ratio)。詳細而言,凹槽152變為多個,則浮置閘極116(如導體層122和金屬膜124)的尺寸可能變大,並可增加接觸窗120的數量,使得第二電容器300如同並聯的多個電容器。Referring to FIG. 3 , the present embodiment increases the capacitive coupling ratio by increasing the number of grooves 152 on the floating gate 116 . In detail, if the grooves 152 become plural, the size of the floating gate 116 (eg, the conductor layer 122 and the metal film 124 ) may become larger, and the number of the contact windows 120 may be increased, so that the second capacitors 300 are connected in parallel of multiple capacitors.

圖4是依照本發明的第四實施例的一種半導體裝置中的MTP的剖面示意圖,其中使用與圖1右相同的元件符號來表示相同或近似的構件,且相同或近似的構件內容也可參照上述,不再贅述。4 is a schematic cross-sectional view of an MTP in a semiconductor device according to a fourth embodiment of the present invention, wherein the same reference numerals as those on the right side of FIG. 1 are used to denote the same or similar components, and the content of the same or similar components can also be referred to The above will not be repeated.

請參照圖4,本實施例是通過形成多個串聯的第二電容器400,達到降壓的效果,其中除了浮置閘極116正上方的第二電容器400,其他第二電容器400可利用第零層金屬層M0做電路的串聯,且最終連至第一層金屬層M1。Referring to FIG. 4 , in this embodiment, a plurality of second capacitors 400 connected in series are formed to achieve the effect of voltage reduction. Except for the second capacitor 400 directly above the floating gate 116 , other second capacitors 400 can use the zeroth The metal layer M0 is used to connect the circuits in series, and is finally connected to the first metal layer M1.

綜上所述,本發明將MTP的浮置閘極、閘間介電層與控制閘極整合至COB式DRAM的製程,因此能降低製程時間與成本。To sum up, the present invention integrates the floating gate, the inter-gate dielectric layer and the control gate of the MTP into the COB DRAM process, thereby reducing the process time and cost.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed above by the embodiments, it is not intended to limit the present invention. Anyone with ordinary knowledge in the technical field can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, The protection scope of the present invention shall be determined by the scope of the appended patent application.

10、20:基板 100a:COB式DRAM 100b:MTP 102、520:第一電容器 104、504a:第一下電極 106、506a:第一介電層 108、512:第一上電極 110、152:凹槽 112、510、510a:上電極層 114、508、508a:導體材料 116、220:浮置閘極 118、300、522:第二電容器 120、148、226、228:接觸窗 122、216、504:導體層 124、218a、218b:金屬膜 126、504b:第二下電極 128、506b:第二介電層 130、514:第二上電極 132、234:DRAM元件 134、218c:位元線 136、206:埋入式字元線 138、156、204、222:摻雜區 140、212:位元線接觸窗 142、230:儲存節點接觸窗 144、208、232:絕緣層 146a、146b、146c、146d、210、224、500:內層介電層 150:主動區隔離結構 154、214:穿隧氧化層 200a:周邊區 200b:單元區 502:凹槽結構 M0:第零層金屬層 M1:第一層金屬層 t1、t2:厚度10, 20: Substrate 100a: COB DRAM 100b: MTP 102, 520: The first capacitor 104, 504a: the first lower electrode 106, 506a: first dielectric layer 108, 512: The first upper electrode 110, 152: groove 112, 510, 510a: upper electrode layer 114, 508, 508a: Conductor materials 116, 220: floating gate 118, 300, 522: Second capacitor 120, 148, 226, 228: Contact window 122, 216, 504: Conductor layer 124, 218a, 218b: metal film 126, 504b: the second lower electrode 128, 506b: the second dielectric layer 130, 514: Second upper electrode 132, 234: DRAM components 134, 218c: bit line 136, 206: Buried word line 138, 156, 204, 222: doped regions 140, 212: bit line contact window 142, 230: Storage node contact window 144, 208, 232: insulating layer 146a, 146b, 146c, 146d, 210, 224, 500: inner dielectric layer 150: Active Zone Isolation Structure 154, 214: Tunneling oxide layer 200a: Surrounding area 200b: Unit Area 502: groove structure M0: zeroth metal layer M1: first metal layer t1, t2: thickness

圖1是依照本發明的第一實施例的一種半導體裝置的剖面示意圖。 圖2A至圖2J是依照本發明的第二實施例的一種半導體裝置之製造流程剖面示意圖。 圖3是依照本發明的第三實施例的一種半導體裝置中的MTP的剖面示意圖。 圖4是依照本發明的第四實施例的一種半導體裝置中的MTP的剖面示意圖。FIG. 1 is a schematic cross-sectional view of a semiconductor device according to a first embodiment of the present invention. 2A to 2J are schematic cross-sectional views illustrating a manufacturing process of a semiconductor device according to a second embodiment of the present invention. 3 is a schematic cross-sectional view of an MTP in a semiconductor device according to a third embodiment of the present invention. 4 is a schematic cross-sectional view of an MTP in a semiconductor device according to a fourth embodiment of the present invention.

10:基板10: Substrate

100a:COB式DRAM100a: COB DRAM

100b:MTP100b: MTP

102:第一電容器102: First capacitor

104:第一下電極104: The first lower electrode

106:第一介電層106: first dielectric layer

108:第一上電極108: The first upper electrode

110、152:凹槽110, 152: groove

112:上電極層112: Upper electrode layer

114:導體材料114: Conductor material

116:浮置閘極116: floating gate

118:第二電容器118: Second capacitor

120、148:接觸窗120, 148: Contact window

122:導體層122: Conductor layer

124:金屬膜124: metal film

126:第二下電極126: Second lower electrode

128:第二介電層128: Second Dielectric Layer

130:第二上電極130: Second upper electrode

132:DRAM元件132: DRAM components

134:位元線134: bit line

136:埋入式字元線136: Buried word line

138、156:摻雜區138, 156: Doping region

140:位元線接觸窗140: bit line contact window

142:儲存節點接觸窗142: Storage node contact window

144:絕緣層144: Insulation layer

146a、146b、146c、146d:內層介電層146a, 146b, 146c, 146d: inner dielectric layers

150:主動區隔離結構150: Active Zone Isolation Structure

154:穿隧氧化層154: Tunneling oxide layer

t1、t2:厚度t1, t2: thickness

M0:第零層金屬層M0: zeroth metal layer

M1:第一層金屬層M1: first metal layer

Claims (24)

一種半導體裝置,具有單元區與周邊區,所述半導體裝置包括: 基板; 位元線上電容器(capacitor over bitline,COB)式動態隨機存取記憶體(DRAM),設置於所述單元區,所述COB式DRAM包括位元線以及第一電容器;以及 多次可程式化記憶體(multi-time programmable memory,MTP),設置於所述周邊區,其中所述MTP包括: 浮置閘極,形成於所述基板上,係與所述位元線同時圖案化的結構; 第二電容器,位於所述浮置閘極上,係與所述第一電容器同時製作的電容器結構;以及 至少一接觸窗,電性連接所述浮置閘極與所述第二電容器。A semiconductor device having a cell region and a peripheral region, the semiconductor device comprising: substrate; A capacitor over bitline (COB) type dynamic random access memory (DRAM) is disposed in the cell region, and the COB type DRAM includes a bit line and a first capacitor; and A multi-time programmable memory (MTP) is arranged in the peripheral area, wherein the MTP includes: A floating gate, formed on the substrate, is a structure patterned simultaneously with the bit line; a second capacitor on the floating gate, a capacitor structure fabricated at the same time as the first capacitor; and At least one contact window is electrically connected to the floating gate and the second capacitor. 如請求項1所述的半導體裝置,其中所述MTP更包括穿隧氧化層,位於所述基板與所述浮置閘極之間。The semiconductor device of claim 1, wherein the MTP further comprises a tunnel oxide layer located between the substrate and the floating gate. 如請求項1所述的半導體裝置,其中所述浮置閘極的材料包括摻雜的多晶矽或多晶矽化金屬。The semiconductor device of claim 1, wherein the material of the floating gate comprises doped polysilicon or polysilicon metal. 如請求項1所述的半導體裝置,其中所述MTP更包括一金屬膜,形成於所述浮置閘極表面,並與所述至少一接觸窗直接接觸。The semiconductor device of claim 1, wherein the MTP further comprises a metal film formed on the surface of the floating gate electrode and in direct contact with the at least one contact window. 如請求項4所述的半導體裝置,其中所述金屬膜與所述位元線係同時沉積的結構層。The semiconductor device of claim 4, wherein the metal film and the bit line are structural layers deposited simultaneously. 如請求項1所述的半導體裝置,其中所述第一電容器包括第一下電極、第一介電層與第一上電極,所述第二電容器包括第二下電極、第二介電層與第二上電極,所述第二下電極係與所述第一下電極同時製作的電極結構,且所述第二上電極係與所述第一上電極同時製作的電極結構。The semiconductor device of claim 1, wherein the first capacitor includes a first lower electrode, a first dielectric layer and a first upper electrode, and the second capacitor includes a second lower electrode, a second dielectric layer and The second upper electrode, the second lower electrode is an electrode structure fabricated at the same time as the first lower electrode, and the second upper electrode is an electrode structure fabricated at the same time as the first upper electrode. 如請求項6所述的半導體裝置,更包括第零層金屬層,介於所述第二下電極與所述至少一接觸窗之間,並與所述至少一接觸窗直接接觸。The semiconductor device of claim 6, further comprising a zeroth metal layer interposed between the second lower electrode and the at least one contact window and in direct contact with the at least one contact window. 如請求項6所述的半導體裝置,其中所述第一電容器與所述第二電容器為具有凹槽的結構,且所述第一上電極與所述第二上電極各自包括: 上電極層,位於所述凹槽上方;以及 導體材料,填入所述凹槽內,並位於所述上電極層下方。The semiconductor device of claim 6, wherein the first capacitor and the second capacitor are structures having grooves, and each of the first upper electrode and the second upper electrode comprises: an upper electrode layer over the groove; and A conductor material is filled into the groove and located under the upper electrode layer. 如請求項8所述的半導體裝置,其中所述導體材料包括多晶矽或多晶矽化金屬,且所述第二電容器內的所述導體材料係作為所述MTP的控制閘極。The semiconductor device of claim 8, wherein the conductor material comprises polysilicon or polysilicon, and the conductor material in the second capacitor acts as a control gate of the MTP. 如請求項8所述的半導體裝置,其中所述第二電容器中的所述凹槽的數量為多個,構成並聯的電容器。The semiconductor device of claim 8, wherein the number of the grooves in the second capacitor is plural to form a parallel capacitor. 如請求項6所述的半導體裝置,其中所述第二介電層與所述第一介電層為高介電常數材料。The semiconductor device of claim 6, wherein the second dielectric layer and the first dielectric layer are high dielectric constant materials. 如請求項6所述的半導體裝置,其中所述第二介電層的厚度大於所述第一介電層的厚度。The semiconductor device of claim 6, wherein the thickness of the second dielectric layer is greater than the thickness of the first dielectric layer. 如請求項1所述的半導體裝置,其中所述第二電容器的數量為多個,構成串聯的電容器。The semiconductor device according to claim 1, wherein the number of the second capacitors is plural to constitute capacitors connected in series. 一種半導體裝置的製造方法,包括: 在單元區形成位元線上電容器(capacitor over bitline,COB)式動態隨機存取記憶體(DRAM)的DRAM元件,所述DRAM元件包括位元線; 在周邊區形成浮置閘極,且所述浮置閘極係與所述位元線同時圖案化的結構; 在所述浮置閘極上形成至少一接觸窗; 同時製作第一電容器與第二電容器,所述第一電容器形成於所述DRAM元件上,所述第二電容器形成於所述至少一接觸窗上,並通過所述至少一接觸窗電性連接至所述浮置閘極,以使所述浮置閘極、所述至少一接觸窗與所述第二電容器構成多次可程式化記憶體(multi-time programmable memory,MTP)。A method of manufacturing a semiconductor device, comprising: forming a DRAM element of a capacitor over bitline (COB) type dynamic random access memory (DRAM) in the cell region, the DRAM element comprising a bit line; A floating gate is formed in the peripheral region, and the floating gate is a structure patterned simultaneously with the bit line; forming at least one contact window on the floating gate; A first capacitor and a second capacitor are fabricated at the same time, the first capacitor is formed on the DRAM element, the second capacitor is formed on the at least one contact window, and is electrically connected to the at least one contact window through the at least one contact window. the floating gate, so that the floating gate, the at least one contact window and the second capacitor form a multi-time programmable memory (MTP). 如請求項14所述的半導體裝置的製造方法,其中形成所述浮置閘極之前更包括:在所述周邊區的基板上形成穿隧氧化層。The method for manufacturing a semiconductor device according to claim 14, wherein before forming the floating gate, the method further comprises: forming a tunnel oxide layer on the substrate in the peripheral region. 如請求項14所述的半導體裝置的製造方法,其中形成所述浮置閘極之後更包括:在所述浮置閘極表面形成一金屬膜。The method for manufacturing a semiconductor device according to claim 14, wherein after forming the floating gate electrode, the method further comprises: forming a metal film on the surface of the floating gate electrode. 如請求項14所述的半導體裝置的製造方法,其中同時製作所述第一電容器與所述第二電容器的方法包括: 同時製作所述第一電容器的第一下電極以及所述第二電容器的所述第二下電極; 在所述第一下電極上形成第一介電層; 在所述第二下電極上形成第二介電層;以及 同時在所述第一介電層上形成所述第一電容器的第一上電極以及在所述第二介電層上形成所述第二電容器的第二上電極。The method for manufacturing a semiconductor device according to claim 14, wherein the method for simultaneously manufacturing the first capacitor and the second capacitor comprises: Simultaneously making the first lower electrode of the first capacitor and the second lower electrode of the second capacitor; forming a first dielectric layer on the first lower electrode; forming a second dielectric layer on the second lower electrode; and At the same time, a first upper electrode of the first capacitor is formed on the first dielectric layer and a second upper electrode of the second capacitor is formed on the second dielectric layer. 如請求項17所述的半導體裝置的製造方法,其中同時製作所述第一電容器與所述第二電容器之前更包括:在所述DRAM元件上與所述浮置閘極上各自形成凹槽結構。The method for fabricating a semiconductor device according to claim 17, wherein before simultaneously fabricating the first capacitor and the second capacitor, the method further comprises: forming a groove structure on the DRAM element and on the floating gate, respectively. 如請求項18所述的半導體裝置的製造方法,其中形成所述第一上電極與所述第二上電極的方法包括: 於所述凹槽結構內填入導體材料;以及 於所述導體材料上形成上電極層,且所述第二電容器內的所述導體材料係作為所述MTP的控制閘極。The method for manufacturing a semiconductor device according to claim 18, wherein the method for forming the first upper electrode and the second upper electrode comprises: Filling the groove structure with conductor material; and An upper electrode layer is formed on the conductor material, and the conductor material in the second capacitor acts as a control gate of the MTP. 如請求項18所述的半導體裝置的製造方法,其中在所述浮置閘極上形成的所述凹槽結構的數量為多個。The method of manufacturing a semiconductor device according to claim 18, wherein the number of the groove structures formed on the floating gate is plural. 如請求項17所述的半導體裝置的製造方法,其中所述第一介電層與所述第二介電層是同時形成的。The method of manufacturing a semiconductor device according to claim 17, wherein the first dielectric layer and the second dielectric layer are formed simultaneously. 如請求項17所述的半導體裝置的製造方法,其中所述第一介電層與所述第二介電層是分開形成的,且所述第二介電層的厚度大於所述第一介電層的厚度。The method of manufacturing a semiconductor device according to claim 17, wherein the first dielectric layer and the second dielectric layer are formed separately, and the thickness of the second dielectric layer is larger than that of the first dielectric layer thickness of the electrical layer. 如請求項14所述的半導體裝置的製造方法,其中同時製作所述第一電容器與所述第二電容器之前更包括:在所述至少一接觸窗上形成第零層金屬層。The method for manufacturing a semiconductor device according to claim 14, wherein before simultaneously fabricating the first capacitor and the second capacitor, the method further comprises: forming a zeroth metal layer on the at least one contact window. 如請求項14所述的半導體裝置的製造方法,其中所述第二電容器的數量為多個且彼此串聯。The method of manufacturing a semiconductor device according to claim 14, wherein the number of the second capacitors is plural and connected in series with each other.
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