TW202031617A - Quartz glass dummy wafer - Google Patents
Quartz glass dummy wafer Download PDFInfo
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- TW202031617A TW202031617A TW108132390A TW108132390A TW202031617A TW 202031617 A TW202031617 A TW 202031617A TW 108132390 A TW108132390 A TW 108132390A TW 108132390 A TW108132390 A TW 108132390A TW 202031617 A TW202031617 A TW 202031617A
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 45
- 238000005488 sandblasting Methods 0.000 claims abstract description 29
- 239000004065 semiconductor Substances 0.000 claims abstract description 23
- 230000003746 surface roughness Effects 0.000 claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 claims abstract description 20
- 239000000758 substrate Substances 0.000 claims description 39
- 229920002120 photoresistant polymer Polymers 0.000 claims description 12
- 239000006061 abrasive grain Substances 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 239000010432 diamond Substances 0.000 claims description 4
- 229910003460 diamond Inorganic materials 0.000 claims description 4
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 4
- 229910052581 Si3N4 Inorganic materials 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims description 3
- 239000003082 abrasive agent Substances 0.000 claims 4
- 239000007789 gas Substances 0.000 claims 2
- 238000000034 method Methods 0.000 abstract description 29
- 238000005406 washing Methods 0.000 abstract description 25
- 239000012535 impurity Substances 0.000 abstract description 22
- 239000002184 metal Substances 0.000 abstract description 19
- 229910052751 metal Inorganic materials 0.000 abstract description 19
- 238000000206 photolithography Methods 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- 238000004140 cleaning Methods 0.000 abstract description 3
- 238000005201 scrubbing Methods 0.000 abstract description 2
- 235000012431 wafers Nutrition 0.000 description 39
- 230000007547 defect Effects 0.000 description 27
- 238000001035 drying Methods 0.000 description 12
- 239000002245 particle Substances 0.000 description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 229910052710 silicon Inorganic materials 0.000 description 9
- 239000010703 silicon Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 6
- 238000005530 etching Methods 0.000 description 5
- 239000000428 dust Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QZPSXPBJTPJTSZ-UHFFFAOYSA-N aqua regia Chemical compound Cl.O[N+]([O-])=O QZPSXPBJTPJTSZ-UHFFFAOYSA-N 0.000 description 2
- 238000000231 atomic layer deposition Methods 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 229910021642 ultra pure water Inorganic materials 0.000 description 2
- 239000012498 ultrapure water Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 238000000918 plasma mass spectrometry Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000001039 wet etching Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C1/00—Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods
- B24C1/04—Methods for use of abrasive blasting for producing particular effects; Use of auxiliary equipment in connection with such methods for treating only selected parts of a surface, e.g. for carving stone or glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24C—ABRASIVE OR RELATED BLASTING WITH PARTICULATE MATERIAL
- B24C11/00—Selection of abrasive materials or additives for abrasive blasts
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/44—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the method of coating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Metallurgy (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
- Chemical Vapour Deposition (AREA)
Abstract
Description
本發明係關於一種石英玻璃製之虛設晶圓,其係於批次式半導體裝置處理裝置中,與製品用半導體基板之矽晶圓一併設置於半導體裝置製造裝置內而使用之包含石英玻璃之虛設晶圓,其用以藉由使半導體裝置製造裝置內之成膜氣體之分佈均勻化而減小所形成之膜厚之不均。The present invention relates to a dummy wafer made of quartz glass, which is used in a batch-type semiconductor device processing device, which is installed in the semiconductor device manufacturing device together with the silicon wafer of the semiconductor substrate for the product. The dummy wafer is used to reduce the unevenness of the formed film thickness by making the distribution of the film forming gas in the semiconductor device manufacturing apparatus uniform.
於半導體製造中,對矽晶圓進行ALD(Atomic Layer Deposition,原子層沉積)或CVD(Chemical Vapor Deposition,化學氣相沉積)等成膜處理。使用批次式縱型熱處理裝置,對複數片矽晶圓一次性進行成膜處理。
如專利文獻1及專利文獻2所示,已知如下方法:以減少複數片矽晶圓中之成膜厚度之不均為目的,將具有與形成半導體元件之矽晶圓同等之表面積的虛設晶圓配置於裝置內。In semiconductor manufacturing, silicon wafers are subjected to film formation processes such as ALD (Atomic Layer Deposition) or CVD (Chemical Vapor Deposition). A batch-type vertical heat treatment device is used to process multiple silicon wafers at one time.
As shown in
又,作為虛設晶圓,如專利文獻1(日本專利特開2015-173154號公報)及專利文獻2(日本專利特開2017-22233號公報)所示,已知藉由在表面形成矩形之凹凸而擴大表面積。又,如專利文獻2所示,已知:藉由變更作為矩形之凹凸而形成之槽之根數,而具有與形成半導體元件之矽晶圓同等之表面積,從而調整表面積。作為於表面形成凹凸圖案之方法,已知雷射加工或機械加工等。
[先前技術文獻]
[專利文獻]In addition, as dummy wafers, as shown in Patent Document 1 (Japanese Patent Laid-Open No. 2015-173154) and Patent Document 2 (Japanese Patent Laid-Open No. 2017-22233), it is known to form rectangular irregularities on the surface. And expand the surface area. In addition, as shown in
[專利文獻1]日本專利特開2015-173154號公報 [專利文獻2]日本專利特開2017-22233號公報[Patent Document 1] Japanese Patent Laid-Open No. 2015-173154 [Patent Document 2] Japanese Patent Laid-Open No. 2017-22233
[發明所欲解決之問題][The problem to be solved by the invention]
隨著半導體元件之微細化,對於虛設晶圓,要求導致半導體元件之不良的金屬雜質更少,且作為虛設晶圓表面之金屬雜質,要求各金屬元素少於1×1010 atoms/cm2 。With the miniaturization of semiconductor components, for dummy wafers, fewer metal impurities that cause defects in semiconductor components are required, and as metal impurities on the surface of the dummy wafer, each metal element is required to be less than 1×10 10 atoms/cm 2 .
於製作在表面形成凹凸而擴大表面積之虛設晶圓之情形時,當形成於表面之凹凸之側面垂直時,即便藉由其後之洗滌,亦容易於凹凸之側面殘留加工時之污垢,存在金屬雜質量增多之問題。又,於凹凸形狀之高低差大之情形、或凹凸形成時之加工面之表面粗糙度大之情形時,均同樣存在容易成為洗滌不良之問題。 本發明之目的為提供一種金屬雜質少之清潔之半導體元件製造用虛設晶圓。 [解決問題之手段]When fabricating a dummy wafer with bumps formed on the surface to enlarge the surface area, when the sides of the bumps formed on the surface are vertical, even by subsequent washing, it is easy to leave processing dirt on the bumps and metals, and metal The problem of increased impurities. In addition, in the case where the height difference of the uneven shape is large, or the surface roughness of the processed surface when the unevenness is formed is large, the same problem is that it is likely to cause poor washing. The purpose of the present invention is to provide a clean dummy wafer for semiconductor device manufacturing with less metal impurities. [Means to Solve the Problem]
半導體元件製造用虛設晶圓係將形成於石英玻璃基板之表面上之凹凸之側面設為傾斜面,提高刷子之擦洗或噴水器之水流等之物理性洗滌效果,減少洗滌後之金屬雜質者,且於石英玻璃基板之至少一面,週期性地排列有頂面平坦且側面為傾斜面之突起。 進而,半導體元件製造用虛設晶圓之突起之週期為100 μm~2500 μm,突起之平坦頂面之寬度為50 μm~2450 μm,凹凸之高低差為50 μm~700 μm,突起之側面之傾斜角度相對於鉛直為5度~25度,突起與凹部之表面粗糙度Ra為1.6 μm以下。 [發明之效果]Dummy wafers for semiconductor device manufacturing use the concave and convex sides formed on the surface of the quartz glass substrate as inclined surfaces to improve the physical cleaning effect of brush scrubbing or water jets and reduce metal impurities after cleaning. And on at least one surface of the quartz glass substrate, there are periodically arranged protrusions with a flat top surface and an inclined surface. Furthermore, the period of the protrusions of the dummy wafer for semiconductor device manufacturing is 100 μm to 2500 μm, the width of the flat top surface of the protrusions is 50 μm to 2450 μm, the height difference of the unevenness is 50 μm to 700 μm, and the side surface of the protrusion is inclined The angle is 5°-25° with respect to the vertical, and the surface roughness Ra of the protrusion and the recess is 1.6 μm or less. [Effects of Invention]
藉由將本發明之半導體元件製造用虛設晶圓之形成於基板表面上之凹凸之側面設為傾斜面,而獲得高洗滌效果,可將虛設晶圓表面之金屬雜質設為各元素分別為1×1010 atoms/cm2 以下,係金屬雜質少之清潔之虛設晶圓,可防止所製造之半導體元件成為不良品。By setting the side surface of the unevenness formed on the substrate surface of the dummy wafer for semiconductor device manufacturing of the present invention as an inclined surface, a high cleaning effect can be obtained. The metal impurities on the surface of the dummy wafer can be set to 1 for each element. ×10 10 atoms/cm 2 or less, it is a clean dummy wafer with less metal impurities, which can prevent the manufactured semiconductor device from becoming defective.
虛設晶圓由於設置於進行成膜處理之矽晶圓之保持構件之晶圓舟上,故而使用如圖1所示,與進行成膜處理之矽晶圓為同一形狀、同一直徑之圓板狀之石英玻璃基板1。Since the dummy wafer is set on the wafer boat of the holding member of the silicon wafer for film formation, it is used as shown in Fig. 1, which has the same shape and diameter as the silicon wafer for film formation.的
於在石英玻璃基板1之接近外周緣之區域形成凹凸之情形時,當插入至虛設晶圓之保持構件即晶圓舟中時,凹凸接觸晶圓舟,存在凸部被削除或破裂而發塵之可能性。因此,雖亦取決於石英玻璃基板1之尺寸、以及晶圓舟之保持部之形狀,但較佳為於從石英玻璃基板1之外周緣起朝向內側的寬度4 mm~12 mm以外之部分,週期性地設置頂面平坦之突起、或者底部平坦之凹部,將其邊界以E表示。In the case where irregularities are formed in the area near the outer periphery of the
作為於圖1所示之石英玻璃基板1之表面之至少一面形成側面為傾斜面4之凹凸(參照圖2)之製造方法,藉由將光微影法與噴砂加以組合來進行表面加工,可形成所需形狀之凹凸,可將該凹凸之側面設為傾斜面,進而可調整表面粗糙度。
藉由變更形成於石英玻璃基板1之表面上之凹凸之大小,可變更虛設晶圓之表面積。藉由凹凸之形成,與石英玻璃基板表面平坦之情形相比,所形成之凹凸之側面部分之面積增加。As a manufacturing method for forming the uneven side surface of the
圖2所示之例係形成有頂面平坦且側面為傾斜面4之週期性排列之突起2之情形,如圖4中示出各部分之大小,突起2係以週期a(突起2之間隔)來排列,突起2之平坦之頂面2a為四角形,側面傾斜而成為斜面4,突起2為梯形狀。藉由變更突起2之平坦頂面之寬度b、從頂面2a至凹部3之平坦部分為止之高度c、以及凹凸之側面之傾斜角度θ,可增減突起2之側面之面積,因此可將虛設晶圓之表面積調整為所需值。The example shown in FIG. 2 is a case where the
若增大突起2之週期a,則所形成之突起2之數量減少,突起2之側面4之面積減少。因此,突起2之週期(間隔)a較佳為100 μm~2500 μm,特佳為100 μm~1000 μm。If the period a of the
突起2之平坦頂面2a之寬度b較佳為設定為小於突起2之週期a之值,但於相對於突起2之週期a而言過小之情形時,突起2之側面之寬度變窄,突起2之側面之面積減少。因此,突起2之平坦頂面2a之寬度b較佳為設定為50 μm~2450 μm,特佳為設定為比突起2之週期a小50 μm~500 μm左右之值。The width b of the
若將從突起2之頂面2a至凹部3之平坦底部3a為止之高度c增大,則加工時於突起2之間即凹部3中容易殘留異物,容易導致其後之洗滌不良。又,突起2容易發生缺損,故而欠佳。因此,從突起2之頂面2a至凹部3之平坦底面3a為止之高度c較佳為設為50 μm~700 μm。If the height c from the
圖3所示之例係將週期性設置有頂面2a平坦之突起2的凹凸形狀之凹凸反轉,週期性地設置平坦之底面3a之凹部3而將表面設為凹凸形狀。於該情形時,可以與週期性地設置上述頂面2a平坦之突起2之情形相同之方式,調整虛設晶圓之表面積。In the example shown in FIG. 3, the irregularities of the convex and concave shapes periodically provided with the
若將突起2及凹部之傾斜之側面4之傾斜角度θ增大,則傾斜側面4之洗滌性提高,但於過大之情形時,槽3之平坦部分減少,因此無法使表面積增大太多。又,相反地,於較小之情形時,難以獲得對於突起2之傾斜側面4之高洗滌效果。因此,突起2之傾斜側面4之傾斜角度θ較佳為5度~25度,尤其更佳為6度~10度。If the inclination angle θ of the
於突起2及凹部3之表面粗糙度Ra大之情形時,於表面之微細凹凸上殘留污垢,容易成為洗滌不良。因此,表面粗糙度Ra較佳為1.6 μm以下。於藉由光微影法及噴砂來週期性地設置頂面平坦之突起2之情形時,傾斜側面4與凹部3之底部3a藉由噴砂加工而成為相同之表面粗糙度,但由光致抗蝕膜所保護之非加工部即突起2之頂面2a維持噴砂加工前之表面粗糙度,因此有於噴砂加工部與非加工部中表面粗糙度成為不同之情形,但任一部位均只要表面粗糙度Ra為1.6 μm以下即可。
於將週期性地設置頂面2a平坦之突起2的凹凸反轉之情形時,同樣亦有於噴砂加工部及非加工部中表面粗糙度不同之情形,但任一部位均只要表面粗糙度Ra為1.6 μm以下即可。When the surface roughness Ra of the
若突起2及凹部3之表面粗糙度Ra之值不同,則於進行表面檢查時,存在難以判別異物等問題,因此較佳為於藉由噴砂而形成凹凸後,對基板整面實施噴砂加工而將整面設為均勻之表面粗糙度。If the values of the surface roughness Ra of the
對於虛設晶圓,要求導致半導體元件之不良的金屬雜質更少,因此作為構件表面之金屬雜質,較佳為各元素分別少於1×1010 atoms/cm2 。For dummy wafers, fewer metal impurities are required to cause defects in semiconductor devices. Therefore, as metal impurities on the surface of the component, it is preferable that each element is less than 1×10 10 atoms/cm 2 .
於石英玻璃基板之表面形成凹凸時,於表面、尤其是凹凸之側面與底面產生金屬雜質之附著。因此,加工後必須進行洗滌,為了去除金屬離子或顆粒而使用洗滌劑與刷子及噴水器來洗滌,然後於無塵室內進行使用超純水之洗滌與淋洗、以及乾燥。洗滌時,較佳為將使用氫氟酸之蝕刻加以組合來進行。將噴砂處理中產生之微裂紋或微碎屑之前端部、以及微粉化之石英藉由蝕刻而溶解,藉此防止從表面產生顆粒。When unevenness is formed on the surface of the quartz glass substrate, adhesion of metal impurities occurs on the surface, especially the side and bottom surfaces of the unevenness. Therefore, washing must be carried out after processing. In order to remove metal ions or particles, detergents, brushes and water jets are used for washing, and then washing and rinsing with ultrapure water and drying are carried out in a clean room. When washing, it is preferable to combine etching with hydrofluoric acid. The front end of microcracks or microchips generated in the sandblasting process and the micronized quartz are dissolved by etching, thereby preventing particles from being generated from the surface.
若於形成於基板表面之突起2、或者凹部3之周緣部3b產生缺損,則存在缺損部分之前端部等進而破損而發塵之可能性,故而形成於表面之突起2、或者凹部3之周緣部3b之缺損較佳為設為0.02%以下。If a defect occurs in the peripheral portion 3b of the
為了於石英玻璃基板上形成週期性之凹凸部,較佳為藉由光微影法及噴砂來進行加工。利用光微影法,於凹凸形狀之相當於凸部的部位(成為平坦頂面2a的部分)形成光致抗蝕膜,且於成為凹部之部分不形成光致抗蝕膜。
光致抗蝕膜形成後,藉由對石英玻璃基板1表面整面進行噴砂加工,則不存在光致抗蝕膜之部位被選擇性地削除而形成凹部,因此去除光致抗蝕膜而獲得既定之凹凸形狀。由於藉由噴砂而從石英玻璃基板1之表面削除,故而藉由噴砂而切削之下側之切削量少,因此突起2或凹部3之側面形成為傾斜面4。In order to form periodic irregularities on the quartz glass substrate, it is preferable to perform processing by photolithography and sandblasting. Using the photolithography method, a photoresist film is formed on the portion corresponding to the convex portion of the uneven shape (the portion that becomes the flat
藉由調整光致抗蝕膜之圖案、噴砂之研磨粒噴射壓力、以及研磨粒噴射噴嘴角度等,可變更突起2之傾斜面4或者凹部3之側面之傾斜面4之傾斜角度θ。又,藉由調整噴砂之加工時間,可變更凹凸形狀之高度c。
又,藉由變更用於噴砂之研磨粒尺寸,可變更加工面之表面粗糙度。The inclination angle θ of the
於藉由光微影法及利用氫氟酸之濕式蝕刻來形成凹凸形狀之情形時,蝕刻係等向性地進行,因此所形成之凹凸形狀之側面彎曲,無法獲得既定之傾斜角度。 於藉由使用研磨石之切削加工、研削加工來形成凹凸形狀之情形時,凹凸側面成為大致垂直,又,由於工具精度以及機械精度之影響而產生刀尖之晃動,因此難以將凹凸側面之傾斜角度以既定之角度進行加工。 於藉由CO2 雷射加工來形成凹凸形狀之情形時,當藉由CO2 雷射而溶解之石英玻璃粉塵之吸引去除不完全時,藉由殘存之粉塵遮擋雷射光,而容易形成凹凸形狀斜面之傾斜未達到既定角度之部位。When forming the uneven shape by photolithography and wet etching using hydrofluoric acid, the etching is performed isotropically. Therefore, the side surface of the formed uneven shape is curved and the predetermined inclination angle cannot be obtained. When the uneven shape is formed by cutting and grinding using a grinding stone, the uneven side surface becomes approximately vertical, and the tool tip shakes due to the influence of tool precision and mechanical accuracy, so it is difficult to tilt the uneven side surface The angle is processed at a predetermined angle. In the case of forming uneven shapes by CO 2 laser processing, when the suction and removal of the quartz glass dust dissolved by the CO 2 laser is incomplete, the remaining dust will block the laser light, and the uneven shape will be easily formed The part where the inclination of the inclined plane does not reach the predetermined angle.
光微影法所使用之光致抗蝕膜之厚度較佳為50 μm~100 μm。若薄於此,則對噴砂之耐性不足,難以獲得所設定之凹凸形狀,於厚之情形時,無法獲得高解析度,因此難以形成100 μm以下之週期之微細週期之凹凸形狀。 光微影法所使用之感光性材料之顯影液較佳為鹼性水溶液。感光性材料之膨潤或溶出少,獲得對構件表面之高密接性。The thickness of the photoresist film used in the photolithography method is preferably 50 μm-100 μm. If it is thinner, the resistance to sandblasting is insufficient, and it is difficult to obtain the set uneven shape. In the case of thick, high resolution cannot be obtained, so it is difficult to form the uneven shape with a fine period of 100 μm or less. The developer of the photosensitive material used in the photolithography method is preferably an alkaline aqueous solution. The photosensitive material has little swelling or dissolution, and high adhesion to the surface of the component is obtained.
用於噴砂之研磨粒較佳為氧化鋁系研磨粒、碳化矽系研磨粒、氮化矽系研磨粒、以及鑽石系研磨粒。氧化鋁系研磨粒由於比重高,故而加工能力高,可於短時間內形成凹凸形狀。碳化矽系研磨粒係由碳元素及矽元素形成,因此成分中不包含可成為金屬雜質之雜質,可進行清潔之加工。 氮化矽系研磨粒、以及鑽石系研磨粒亦於成分中不包含可成為金屬雜質之雜質,可進行清潔之加工。The abrasive particles used for sandblasting are preferably alumina-based abrasive particles, silicon carbide-based abrasive particles, silicon nitride-based abrasive particles, and diamond-based abrasive particles. Alumina-based abrasive grains have high specific gravity, so they have high processing ability and can be formed into uneven shapes in a short time. Silicon carbide abrasive particles are formed of carbon and silicon, so the composition does not contain impurities that can become metal impurities, and can be cleaned. Silicon nitride-based abrasive grains and diamond-based abrasive grains also contain no impurities that can become metallic impurities in the composition, and can be cleaned.
用於噴砂之研磨粒之型號較佳為#400~#2000。於比#400粗之情形時,難以獲得加工面之表面粗糙度Ra 1.6 μm以下。於比#2000細之情形時,加工面之表面粗糙度無問題,但加工時間大幅度增加,生產性下降,因此欠佳。 噴砂加工可以1種研磨粒來進行全部加工,亦可於加工之途中切換研磨粒,將2種以上組合使用。The model of abrasive particles used for sandblasting is preferably #400~#2000. When it is thicker than #400, it is difficult to obtain the surface roughness Ra 1.6 μm or less of the processed surface. When it is thinner than #2000, the surface roughness of the processed surface is no problem, but the processing time is greatly increased, and the productivity is reduced, so it is not good. Sandblasting can be done with one type of abrasive grains for all processing, and it is also possible to switch abrasive grains in the middle of processing and use two or more types in combination.
以下,藉由實施例,對本發明進行具體說明,但本發明並不限定於實施例。 實施例1 準備對兩面進行鏡面研磨之厚度1.5 mm、直徑300 mm之圓板狀石英玻璃基板。 於基板之單面,層壓感光性材料之厚度為100 μm之噴砂用乾膜抗蝕劑(三菱製紙製造之MS7100)後,使用膜遮罩進行UV曝光,其後,利用溶解有碳酸鈉之鹼性水溶液進行顯影,形成週期性圖案之光致抗蝕膜。Hereinafter, the present invention will be described in detail through examples, but the present invention is not limited to the examples. Example 1 Prepare a disc-shaped quartz glass substrate with a thickness of 1.5 mm and a diameter of 300 mm that is mirror-polished on both sides. Laminate a photosensitive material with a thickness of 100 μm with a dry film resist for sandblasting (MS7100 manufactured by Mitsubishi Paper Manufacturing) on one side of the substrate, and then use a film mask to perform UV exposure. The alkaline aqueous solution is developed to form a photoresist film with periodic patterns.
繼而,對於石英玻璃基板表面,從鉛直方向,自噴嘴中噴射#800之氧化鋁系研磨粒來掃描整面,藉此進行噴砂加工。其後,將石英玻璃基板浸漬於抗蝕劑剝離液中,將殘存之光致抗蝕膜剝離去除,獲得虛設晶圓,其於石英玻璃基板之單側表面之從外周緣起7 mm以外之部分,以格子圖案來週期性地設置平坦面之突起。Then, on the surface of the quartz glass substrate, #800 alumina-based abrasive grains were sprayed from the nozzle from the vertical direction to scan the entire surface, thereby performing sandblasting. After that, the quartz glass substrate was immersed in a resist stripping solution, and the remaining photoresist film was stripped and removed to obtain a dummy wafer, which was 7 mm from the outer periphery of the one side surface of the quartz glass substrate , The protrusions on the flat surface are periodically arranged in a grid pattern.
突起2之週期a為500 μm,突起之平坦部分之寬度b為370 μm,從突起2之平坦面2a至凹部3之底面3a為止之高度c為350 μm。凹凸側面4之平均傾斜角度θ為6.5度。The period a of the
噴砂處理後,使用中性洗劑(獅王(股)製造之Mamalemon)與刷子及噴水器進行洗滌及淋洗後,使用氫氟酸進行蝕刻,將噴砂處理中產生之微裂紋或微碎屑之前端部、以及微粉化之石英玻璃溶解。進而,使用洗劑(花王(股)製造之Cleanthrough KS-3030)與刷子及噴水器進行洗滌及淋洗,然後於無塵室內使用超純水進行洗滌及淋洗,使其乾燥。
藉由目視來檢查乾燥後形成於表面之梯形狀之突起2之缺損,結果,缺損為6處。After sandblasting, use neutral lotion (Mamalemon manufactured by Lion King), brushes and water jets for washing and rinsing, and then use hydrofluoric acid for etching to remove the microcracks or microchips generated during the sandblasting process The front end and the micronized quartz glass dissolve. Furthermore, use a lotion (Cleanthrough KS-3030 manufactured by Kao Co., Ltd.), brushes and water jets for washing and rinsing, and then washing and rinsing with ultrapure water in a clean room to dry.
The defects of the
將完成之石英玻璃製虛設晶圓,浸漬於將鹽酸與硝酸以3:1之體積比混合而成之王水中後,使回收之王水蒸發乾固,將殘渣以酸進行溶解後,利用感應耦合電漿質譜法來測定金屬雜質量。將所獲得之金屬雜質量除以構件之表面積而得之值作為構件表面之金屬雜質量。The completed dummy wafer made of quartz glass is immersed in aqua regia which is mixed with hydrochloric acid and nitric acid in a volume ratio of 3:1, the recovered aqua regia is evaporated to dryness, the residue is dissolved with acid, and then induction Coupled plasma mass spectrometry to determine the amount of metal impurities. The value obtained by dividing the obtained amount of metallic impurities by the surface area of the component is regarded as the amount of metallic impurities on the surface of the component.
實施例2
以與實施例1相同之順序,將#400之碳化矽系研磨粒用於噴砂,於石英玻璃基板之單側表面之從外周緣起7 mm以外之部分,形成以格子圖案來週期性地設置有表面平坦之突起的凹凸形狀。
突起2之週期a為500 μm,突起2之平坦頂面2a之寬度b為370 μm,從突起之平坦之頂面2a至凹部3之平坦之底面3a為止之高度c為350 μm,凹凸側面之平均傾斜角度θ為7.3度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之突起2之缺損,結果為11處。Example 2
In the same procedure as in Example 1, the #400 silicon carbide abrasive grains were used for sandblasting, and the part 7 mm from the outer periphery of the one side surface of the quartz glass substrate was formed in a grid pattern with periodic arrangement Concave-convex shape with flat protrusions.
The period a of the
實施例3
以與實施例1相同之順序,於石英玻璃基板之單側表面之從外周緣起6 mm以外之部分,形成以格子圖案來週期性地設置有頂面平坦之突起的凹凸形狀。
突起2之週期a為2500 μm,突起2之平坦頂面2a之寬度b為2320 μm,從突起2之平坦之頂面2a至凹部3之平坦底面3a為止之高度c為700 μm,凹凸側面之平均傾斜角度θ為6.9度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之梯形狀之突起之缺損,結果,缺損為2處。Example 3
In the same procedure as in Example 1, the part of the single side surface of the quartz glass substrate 6 mm from the outer periphery was formed into a concave-convex shape periodically provided with flat projections in a lattice pattern.
The period a of the
實施例4
以與實施例1相同之順序,將殘存抗蝕膜剝離去除後,再次對整面進行噴砂加工,獲得虛設晶圓,其於晶圓之單側表面之石英玻璃基板1之從外周緣起7 mm以外之部分,形成有以格子圖案來週期性地設置有表面平坦之頂面之突起2的凹凸形狀。Example 4
In the same procedure as in Example 1, the remaining resist film was stripped and removed, and the entire surface was sandblasted again to obtain a dummy wafer, which was 7 mm from the outer periphery of the
突起2之週期a為500 μm,突起2之平坦頂面2a之寬度為200 μm,從突起2之平坦之頂面2a至凹部3之平坦之底面3a為止之高度c為350 μm,凹凸側面之平均傾斜角度θ為23.2度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之梯形狀之突起之缺損,結果,缺損為2處。The period a of the
實施例5
以與實施例1相同之順序,於石英玻璃基板1之單側表面之從外周緣起7 mm以外之部分,形成以格子圖案來週期性地設置有表面平坦之突起的凹凸形狀。
突起2之週期a為500 μm,突起2之平坦頂面2a之寬度b為390 μm,從突起2之平坦頂面2a至凹部之平坦底面3a為止之高度c為200 μm,凹凸側面之平均傾斜角度θ為9.9度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之梯形狀之突起之缺損,結果,缺損為5處。Example 5
In the same procedure as in Example 1, a portion of the one-side surface of the
實施例6
以與實施例1相同之順序,於石英玻璃基板1之單側表面之從外周緣起7 mm以外之部分,形成以格子圖案來週期性地設置有表面平坦之突起的凹凸形狀。
突起2之週期a為200 μm,突起2之平坦頂面2a之寬度b為70 μm,從突起之平坦頂面2a至凹部之平坦底面3a為止之高度c為500 μm,凹凸側面之平均傾斜角度θ為5.7度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之突起2之缺損,結果,缺損為23處。Example 6
In the same procedure as in Example 1, a portion of the one-side surface of the
實施例7
以與實施例1相同之順序,使用感光性材料之厚度為50 μm之噴砂用乾膜抗蝕劑(三菱製紙製造之MS7050),於石英玻璃基板之單側表面之從外周緣起7 mm以外之部分,形成以格子圖案來週期性地設置有表面平坦之突起的凹凸形狀。
突起2之週期a為200 μm,突起之平坦頂面2a之寬度b為140 μm,從突起之平坦頂面至凹部之平坦底面為止之高度c為200 μm,凹凸側面之平均傾斜角度θ為7.1度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之梯形狀之突起之缺損,結果,缺損為11處。Example 7
In the same procedure as in Example 1, use a photosensitive material with a thickness of 50 μm dry film resist for sandblasting (MS7050 manufactured by Mitsubishi Paper) on one side surface of the quartz glass substrate 7 mm from the outer periphery In part, a concave-convex shape in which protrusions with a flat surface are periodically provided in a lattice pattern is formed.
The period a of the
實施例8
以與實施例1相同之順序,於石英玻璃基板1之單側表面之從外周緣起7 mm以外之部分,形成以格子圖案來週期性地設置有底面3a平坦之凹部3的凹凸形狀。
凹部3之週期a為500 μm,凹部3之平坦底面3a之寬度d為390 μm,從凸部2之平坦頂面2a至凹部之平坦底面3a為止之高度c為200 μm,凹凸側面之平均傾斜角度θ為9.8度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面上之凹部除外的平坦部分之缺損,結果,缺損為3處。Example 8
In the same procedure as in Example 1, a portion of the single side surface of the
比較例1
以與實施例1相同之順序,於石英玻璃基板1之單側表面之從外周緣起7 mm以外之部分,以格子圖案來週期性地設置具有平坦頂面2a之突起2而形成凹凸面。
突起2之週期a為500 μm,突起2之平坦頂部2a之寬度b為370 μm,從突起2之平坦頂部2a至凹部3之平坦底面3a為止之高度c為350 μm,凹凸側面之平均傾斜角度θ為3.3度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之突起2之缺損,結果,缺損為10處。Comparative example 1
In the same procedure as in Example 1,
比較例2
準備將兩面進行鏡面研磨之厚度1.5 mm、直徑150 mm之石英玻璃基板。
將石英玻璃基板1設置於微切片機上,使用#800之鑽石研磨石,於石英玻璃基板之單面,以格子圖案來週期性地設置頂面平坦之突起2而形成凹凸形狀。
突起2之週期a為500 μm,突起2之平坦頂面2a之寬度b為350 μm,從突起2之平坦頂面2a至凹部3之平坦底面3a為止之高度c為800 μm,凹凸側面4之平均傾斜角度θ為1.1度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之突起2之缺損,結果,外周部以外之缺損為8處。Comparative example 2
Prepare a quartz glass substrate with a thickness of 1.5 mm and a diameter of 150 mm that will be mirror-polished on both sides.
The
比較例3
以與實施例1相同之順序,將#320之氧化鋁系研磨粒用於噴砂,於晶圓之單側表面之從晶圓外周緣起7 mm以外之部分,形成以格子圖案來週期性地設置有頂面平坦之突起2的凹凸形狀。
突起之週期a為500 μm,突起2之平坦頂部2a之寬度b為370 μm,從突起之平坦頂部2a至凹部3之平坦底面3a為止之高度c為350 μm,凹凸側面之平均傾斜角度θ為8.1度。
以與實施例1相同之順序進行洗滌,藉由目視來檢查乾燥後形成於表面之突起之缺損,結果,缺損為19處。
將實施例及比較例之石英玻璃製虛設晶圓之凹凸之各種要素、以及金屬雜質量與表面粗糙度之測定結果示於表1中。Comparative example 3
In the same procedure as in Example 1, the #320 alumina-based abrasive grains were used for sandblasting, and the part of the single side surface of the wafer beyond 7 mm from the outer periphery of the wafer was formed in a grid pattern to be periodically arranged Concave-convex shape of
[表1]
1:石英玻璃基板
2:突起
2a:突起之平坦頂面
3:凹部(槽)
3a:凹部之底面
E:表示形成凹凸之邊界之線
4:傾斜面(側面)
a:突起之週期(間隔)
b:突起之平坦頂部之寬度
c:突起與凹部之高低差
d:凹部之寬度
θ:傾斜面之角度1: Quartz glass substrate
2:
圖1係表示本發明之虛設晶圓之石英玻璃基板之形狀的俯視圖。 圖2係本發明之凹凸圖案之實施例之立體圖及剖面圖。 圖3係本發明之凹凸圖案之其他實施例之立體圖及剖面圖。 圖4係本發明之凹凸圖案之實施例之詳細剖面圖。FIG. 1 is a plan view showing the shape of the quartz glass substrate of the dummy wafer of the present invention. 2 is a perspective view and a cross-sectional view of an embodiment of the concave-convex pattern of the present invention. Fig. 3 is a perspective view and a cross-sectional view of another embodiment of the concave-convex pattern of the present invention. 4 is a detailed cross-sectional view of an embodiment of the concave-convex pattern of the present invention.
1:石英玻璃基板 1: Quartz glass substrate
E:表示形成凹凸之邊界之線 E: indicates the line forming the boundary of the bump
Claims (5)
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WOPCT/JP2018/038785 | 2018-10-18 |
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