TW202012324A - Glass for display suppressing the occurrence of defects such as cracks on end faces in display glass - Google Patents

Glass for display suppressing the occurrence of defects such as cracks on end faces in display glass Download PDF

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TW202012324A
TW202012324A TW108131634A TW108131634A TW202012324A TW 202012324 A TW202012324 A TW 202012324A TW 108131634 A TW108131634 A TW 108131634A TW 108131634 A TW108131634 A TW 108131634A TW 202012324 A TW202012324 A TW 202012324A
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glass
display
degrees
end surface
angle
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TW108131634A
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TWI825162B (en
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石田渉
小峯聡
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日商Agc股份有限公司
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B33/00Severing cooled glass
    • C03B33/02Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
    • C03B33/023Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor the sheet or ribbon being in a horizontal position
    • C03B33/03Glass cutting tables; Apparatus for transporting or handling sheet glass during the cutting or breaking operations
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B18/00Shaping glass in contact with the surface of a liquid
    • C03B18/02Forming sheets
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B33/00Severing cooled glass
    • C03B33/02Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor
    • C03B33/023Cutting or splitting sheet glass or ribbons; Apparatus or machines therefor the sheet or ribbon being in a horizontal position
    • C03B33/033Apparatus for opening score lines in glass sheets
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/133302Rigid substrates, e.g. inorganic substrates

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Nonlinear Science (AREA)
  • Mathematical Physics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
  • Devices For Indicating Variable Information By Combining Individual Elements (AREA)

Abstract

Disclosed is a display glass that has four sides and is rectangular in a plan view, and each of the four sides in relation to the other sides that intersect is between +0.3 degree to -0.3 degree with respect to the direction of 90 degrees. The end face strength of the end face on each of the four sides is 100 MPa or more, the distance between the highest point and the lowest point to the surface of the end face is the largest height that is 100μm or less, the thickness is 0.3mm or more, and the length of at least one side is 2500 mm or more and 5000 mm or less.

Description

顯示器用玻璃Display glass

本發明係關於一種顯示器用玻璃及顯示器用玻璃之製造方法。The invention relates to a display glass and a method for manufacturing display glass.

作為FPD(Flat Panel Display,平板顯示器)用玻璃基板、尤其是液晶用玻璃所使用之玻璃板之製造方法,已知有專利文獻1等中所揭示之被稱作浮式法之製法。該浮式法係如下製法:使熔融玻璃流入至熔融錫浴內之錫上,使熔融玻璃於錫上擴展而製成玻璃帶,最終成形為具有特定之板厚之帶狀板玻璃。藉由熔融錫浴成形之帶狀板玻璃被引出至設置於熔融錫浴之下游側之徐冷部,於此處冷卻至特定之溫度後,由輥式輸送機等搬送機構連續搬送至切折裝置而切折為所需尺寸之玻璃板。切折而得之玻璃板由輥式輸送機搬送至特定之收容部,於此處被逐片收容至托板等,作為成品或作為半成品被採板。As a manufacturing method of a glass substrate for FPD (Flat Panel Display) glass substrates, in particular for glass for liquid crystals, a manufacturing method known as a float method disclosed in Patent Document 1 and the like is known. The float method is a method of making molten glass flow onto tin in a molten tin bath, spreading the molten glass over tin to make a glass ribbon, and finally forming a ribbon-shaped plate glass with a specific thickness. The ribbon-shaped sheet glass formed by the molten tin bath is led out to the cold cooling section provided on the downstream side of the molten tin bath, where it is cooled to a specific temperature, and then continuously transported to the fold by a transport mechanism such as a roller conveyor The device is cut and folded into a glass plate of the required size. The cut and folded glass sheet is transported by a roller conveyor to a specific storage section, where it is stored piece by piece to a pallet, etc., and is picked as a finished product or as a semi-finished product.

專利文獻2揭示有一種為了實現帶狀板玻璃之正確之切折,而使用特定之搬送量檢測裝置檢測帶狀板玻璃之搬送量之技術。該搬送量檢測裝置具備抵接於帶狀板玻璃並旋轉之第1輥、及抵接於第1輥並旋轉之第2輥,且第2輥之熱膨脹率低於第1輥之片材之熱膨脹率。Patent Document 2 discloses a technique for detecting the conveyance amount of a strip-shaped plate glass by using a specific conveyance amount detection device in order to achieve correct cutting and folding of the strip-shaped plate glass. The conveyance amount detection device includes a first roll that is in contact with the band-shaped plate glass and rotates, and a second roll that is in contact with the first roll and rotates, and the thermal expansion coefficient of the second roll is lower than that of the sheet of the first roll Thermal expansion rate.

專利文獻3揭示有一種將玻璃板沿著切斷線切斷之切斷裝置。該切斷裝置使於輥表面具備第1突起之切斷用輥旋轉,利用第1突起將切斷線之下方之玻璃板之下表面頂起。進而,於切斷用輥之第1突起之旋轉方向上游側表面設置有第2突起。 [先前技術文獻] [專利文獻]Patent Document 3 discloses a cutting device that cuts a glass sheet along a cutting line. This cutting device rotates a cutting roller provided with a first protrusion on the surface of the roller, and uses the first protrusion to push up the lower surface of the glass plate below the cutting line. Furthermore, a second protrusion is provided on the upstream surface of the cutting roller in the rotation direction. [Prior Technical Literature] [Patent Literature]

[專利文獻1]日本專利特開平8-277131號公報 [專利文獻2]日本專利特開2012-12123號公報 [專利文獻3]日本專利第5605726號[Patent Document 1] Japanese Patent Laid-Open No. 8-277131 [Patent Document 2] Japanese Patent Laid-Open No. 2012-12123 [Patent Document 3] Japanese Patent No. 5605726

[發明所欲解決之問題][Problems to be solved by the invention]

上述多種先前之技術係以製造時之加工精度之提昇或破碎之防止等為目的,並未對所製造之玻璃、尤其是較薄之顯示器用玻璃之操作中之擔憂事項進行研究。例如,未實施端面之倒角加工之顯示器用玻璃於端面存在特定量之凹凸,端面強度亦不充分。因此,顯示器用玻璃有時會於搬運時等在端面產生裂紋等不良,針對此種不良之對策尚不充分。The above-mentioned various previous technologies are for the purpose of improving the processing accuracy at the time of manufacture or preventing the breakage, etc., and have not studied the concerns in the operation of the manufactured glass, especially the thinner display glass. For example, a glass for a display that has not been chamfered with an end face has a certain amount of unevenness on the end face, and the strength of the end face is also insufficient. Therefore, the glass for displays may have defects such as cracks on the end surface during transportation, etc., and the countermeasures against such defects are insufficient.

又,作為可獲得凹凸相對較少之端面之玻璃板之切斷方法,已知有使用雷射之整體切斷。該切斷方法適於例如200 μm左右之較薄之玻璃板之切斷。但,伴隨玻璃板之厚度之增加,存在切斷之時間增加而難以實現實用時間內之切斷、難以實現直進性較高之切斷等問題。In addition, as a method for cutting a glass plate having an end surface with relatively few irregularities, a whole cutting using a laser is known. This cutting method is suitable for cutting a thin glass plate of, for example, about 200 μm. However, with the increase in the thickness of the glass sheet, there is a problem that the cutting time increases, it is difficult to realize the cutting within the practical time, and it is difficult to achieve the cutting with a high linearity.

本發明提供一種可抑制產生如端面之裂紋之不良之顯示器用玻璃。 [解決問題之技術手段]The present invention provides a display glass that can suppress defects such as cracks on the end surface. [Technical means to solve the problem]

本發明之顯示器用玻璃係具有4邊且俯視下為矩形狀之顯示器用玻璃,且4邊之各者對於相交之其他邊,於相對於90度之方向在+0.3度~-0.3度之範圍內相交,4邊之各者之端面之端面強度為100 MPa以上,端面之表面上之最高點與最低點之距離即最大高度為100 μm以下,厚度為0.3 mm以上,至少1邊之長度為2500 mm以上且為5000 mm以下。The display glass of the present invention has four sides and a rectangular display glass in plan view, and each of the four sides has a range of +0.3 degrees to -0.3 degrees relative to the direction of 90 degrees for the other sides that intersect Inner intersection, the strength of the end face of each of the four sides is more than 100 MPa, the distance between the highest point and the lowest point on the surface of the end face is the maximum height of less than 100 μm, the thickness is more than 0.3 mm, and the length of at least one side is 2500 mm or more and 5000 mm or less.

於本發明之顯示器用玻璃中,例如,上述端面對於俯視下之第1主面及第2主面,於相對於90度之方向在+5度~-5度之範圍內相交。 [發明之效果]In the display glass of the present invention, for example, the above-mentioned end face intersects the first principal surface and the second principal surface in a plan view in the range of +5 degrees to -5 degrees with respect to the direction of 90 degrees. [Effect of invention]

根據本發明,可抑制顯示器用玻璃中產生如端面之裂紋之不良。According to the present invention, it is possible to suppress defects such as cracks on the end surface in the glass for display.

以下,根據隨附圖式對本發明之顯示器用玻璃及顯示器用玻璃之製造方法之較佳之實施形態進行說明。Hereinafter, preferred embodiments of the glass for displays and the method for manufacturing the glass for displays of the present invention will be described based on the accompanying drawings.

圖1係本發明之一實施形態之顯示器用玻璃之俯視圖。顯示器用玻璃110於俯視下呈矩形狀(正方形或長方形),且具有包含第1邊101、第2邊102、第3邊103及第4邊104之4條邊。俯視下形成顯示器用玻璃110之整體形狀之第1主面121及與該第1主面121對向之第2主面122由4條邊包圍,第1主面121或第2主面122構成顯示器用玻璃110之正面或背面。FIG. 1 is a plan view of a display glass according to an embodiment of the present invention. The display glass 110 is rectangular (square or rectangular) in plan view, and has four sides including a first side 101, a second side 102, a third side 103, and a fourth side 104. The first main surface 121 forming the overall shape of the display glass 110 in plan view and the second main surface 122 facing the first main surface 121 are surrounded by four sides, and the first main surface 121 or the second main surface 122 constitute a display Use the front or back of the glass 110.

此處之顯示器用玻璃110相當於例如組裝成液晶面板之前之作為半成品之玻璃板,且係被稱作所謂之素板之製造物。顯示器用玻璃110可為以與最終之液晶面板之尺寸一致之方式切出者,亦可為大於該尺寸者。但,未對4條邊上所存在之端面實施倒角加工或研磨加工。Here, the display glass 110 corresponds to, for example, a glass plate that is a semi-finished product before being assembled into a liquid crystal panel, and is called a so-called plain plate. The display glass 110 may be cut out in a manner consistent with the size of the final liquid crystal panel, or may be larger than the size. However, no chamfering or grinding was applied to the end faces existing on the four sides.

顯示器用玻璃110之厚度較佳為0.3 mm以上,更佳為0.4 mm以上,進而較佳為0.5 mm以上,進而更佳為0.6 mm以上。顯示器用玻璃之厚度之上限並無特別限定,通常為1 mm以下。又,顯示器用玻璃110較理想為不包括厚度為0.3 mm以下者。 藉由使厚度處於此種範圍,可容易地製造薄型液晶面板。 然而,此種較薄之顯示器用玻璃難以製造及操作。例如,於製造後轉移至其他場所並實施倒角加工或研磨加工之情形時,必須充分注意,以免於搬運時在端面產生裂紋等不良。然而,業界對此種擔憂事項尚未進行充分之考慮。鑒於此種情況,發明者進行了努力研究,發現較佳為滿足以下多種必要條件之顯示器用玻璃。The thickness of the display glass 110 is preferably 0.3 mm or more, more preferably 0.4 mm or more, further preferably 0.5 mm or more, and still more preferably 0.6 mm or more. The upper limit of the thickness of the glass for display is not particularly limited, and is usually 1 mm or less. Moreover, it is desirable that the glass 110 for displays does not include the thickness of 0.3 mm or less. By setting the thickness to such a range, a thin liquid crystal panel can be easily manufactured. However, such thin display glass is difficult to manufacture and handle. For example, when transferring to another location after manufacturing and performing chamfering or grinding, sufficient care must be taken to avoid defects such as cracks on the end surface during transportation. However, the industry has not fully considered such concerns. In view of this situation, the inventors have conducted intensive studies and found that the glass for displays that satisfies the following various necessary conditions is preferred.

首先,於本實施形態之顯示器用玻璃110中,4邊之各者滿足所謂之特定之直進性。所謂直進性係指特定之1邊相對於與以角相交之其他邊成90度之垂直方向,以特定角度範圍內之斜率延伸。如圖2所示,傾斜角度γ1 對應於在自第3邊103朝向第1邊101之方向上,第4邊104以向顯示器用玻璃110之外側延伸之方式傾斜之角度,且以(+)角度表示(圖2中之第4邊104A)。另一方面,傾斜角度γ2 對應於在自第3邊103朝向第1邊101之方向上,第4邊104以向顯示器用玻璃110之內側延伸之方式傾斜之角度,且以(-)角度表示(圖2中之第4邊104B)。於本實施形態之顯示器用玻璃110中,作為1條邊之第4邊104與以角相交之其他邊(第3邊103),於相對於90度之方向在+0.3度~-0.3度之範圍內相交。於本實施形態中,藉由各邊採用此種直進性(亦稱作直角度),而抑制搬運時之端面111之裂紋、龜裂等之產生。再者,於本例中,表示假定第2邊102與第3邊103所成之角度為90度,使用直角游標尺150測定直進性之狀態。First, in the display glass 110 of the present embodiment, each of the four sides satisfies the so-called specific linearity. The so-called straightness means that a specific side extends at a 90-degree vertical direction with respect to other sides that intersect at an angle, and extends at a slope within a specific angle range. As shown in FIG. 2, the inclination angle γ 1 corresponds to the angle at which the fourth side 104 inclines so as to extend outward of the display glass 110 in the direction from the third side 103 toward the first side 101, and is (+ ) Angle display (the fourth side 104A in FIG. 2). On the other hand, the inclination angle γ 2 corresponds to the angle at which the fourth side 104 inclines so as to extend inside the display glass 110 in the direction from the third side 103 toward the first side 101, and the angle (-) It is shown (the fourth side 104B in FIG. 2). In the display glass 110 of the present embodiment, the fourth side 104 as one side and the other side (the third side 103) intersecting at an angle are in the range of +0.3 degrees to -0.3 degrees with respect to the direction of 90 degrees Intersect. In this embodiment, by adopting such straightness (also referred to as a straight angle) on each side, the occurrence of cracks, cracks, etc. on the end surface 111 during transportation is suppressed. Furthermore, in this example, it is assumed that the angle formed by the second side 102 and the third side 103 is 90 degrees, and the rectilinearity is measured using the right-angle vernier 150.

又,4邊之各者之端面111(參照圖3、圖4)之強度係藉由依據JIS(Japanese Industrial Standards,日本工業標準) R1601:2008或ISO(International Organization for Standardization,國際標準組織)14704:2000之4點彎曲試驗或3點彎曲試驗進行驗證,並設為端面強度進行評估。於本實施形態之顯示器用玻璃110中,藉由此種規定驗證之端面強度為100 MPa以上。先前之玻璃之端面強度小於100 MPa,但於本實施形態中,藉由端面111具有此種充分大之強度,而抑制搬運時之裂紋、龜裂等之產生。In addition, the strength of the end faces 111 (refer to FIGS. 3 and 4) of each of the four sides is based on JIS (Japanese Industrial Standards) R1601:2008 or ISO (International Organization for Standardization) 14704 : 2000 4 point bending test or 3 point bending test to verify, and set the end surface strength for evaluation. In the display glass 110 of the present embodiment, the strength of the end face verified by such a regulation is 100 MPa or more. The strength of the end face of the previous glass is less than 100 MPa. However, in the present embodiment, the end face 111 has such a sufficiently large strength to suppress the occurrence of cracks and cracks during transportation.

為了儘可能地切出較多之液晶面板用之玻璃,顯示器用玻璃110之4邊中之至少1邊之長度為2500 mm以上且為5000 mm以下。更佳為1邊之長度為2800 mm以上。由於尺寸變大而容易產生端面111中之裂紋等不良,但於本實施形態之顯示器用玻璃110中此種不良之產生得到抑制。In order to cut out as much glass as possible for the liquid crystal panel, at least one of the four sides of the glass 110 for display has a length of 2500 mm or more and 5000 mm or less. More preferably, the length of one side is 2800 mm or more. As the size becomes larger, defects such as cracks in the end surface 111 are likely to occur, but the occurrence of such defects is suppressed in the display glass 110 of the present embodiment.

本實施形態之顯示器用玻璃110之4邊及4邊之端面111全部滿足上述所有必要條件。藉由此種構成,提供一種可有效地抑制端面之不良之顯示器用玻璃110。進而,本實施形態之顯示器用玻璃110較理想為滿足以下所說明之必要條件。The four sides of the display glass 110 and the end surfaces 111 of the four sides of the present embodiment all satisfy all the above-mentioned necessary conditions. With such a configuration, a glass 110 for a display that can effectively suppress the defects of the end face is provided. Furthermore, the glass 110 for a display of this embodiment preferably satisfies the requirements described below.

如圖3所示,顯示器用玻璃110於4邊之各者具有上述端面111。圖3(a)表示理想狀態之端面111,端面111相對於第1主面121及第2主面122,以90度之方向相交。然而,端面111並不限定於以此種理想狀態形成,如圖3(b),亦存在端面111以斜向偏移之狀態形成之情況。此處,端面111之斜向偏移之狀態如圖3(c)所示,由端面111之角度、尤其是相對於第1主面121或第2主面122之角度規定。As shown in FIG. 3, each of the four sides of the display glass 110 has the above-mentioned end surface 111. FIG. 3( a) shows an end surface 111 in an ideal state. The end surface 111 intersects the first main surface 121 and the second main surface 122 at 90 degrees. However, the end surface 111 is not limited to being formed in such an ideal state, as shown in FIG. 3(b), there are cases where the end surface 111 is formed in a state of being obliquely offset. Here, as shown in FIG. 3( c ), the state of the oblique deviation of the end surface 111 is defined by the angle of the end surface 111, especially the angle with respect to the first main surface 121 or the second main surface 122.

傾斜角度θ1 對應於在自第2主面122朝向第1主面121之方向上,端面111以向顯示器用玻璃110之外側延伸之方式傾斜之角度,且以(+)角度表示(圖3(c)中之端面111A)。另一方面,傾斜角度θ2 對應於在自第2主面122朝向第1主面121之方向上,端面111以向顯示器用玻璃110之內側延伸之方式傾斜之角度,且以(-)角度表示(圖3(c)中之端面111B)。於本實施形態之顯示器用玻璃110中,較佳為端面111與第1主面121或第2主面122,於相對於虛線所示之90度之方向在+5度~-5度之範圍內相交。藉由端面111採用此種配置,尤其會抑制搬運時之端面111之裂紋、龜裂等之產生。The inclination angle θ 1 corresponds to the angle at which the end surface 111 inclines so as to extend outward of the display glass 110 in the direction from the second main surface 122 toward the first main surface 121, and is expressed as a (+) angle (FIG. 3 (c) the end face 111A). On the other hand, the inclination angle θ 2 corresponds to the angle at which the end surface 111 inclines so as to extend inward of the display glass 110 in the direction from the second main surface 122 toward the first main surface 121, and the angle (-) Is shown (the end face 111B in FIG. 3(c)). In the display glass 110 of the present embodiment, it is preferable that the end surface 111 and the first main surface 121 or the second main surface 122 are within a range of +5 degrees to -5 degrees with respect to a direction of 90 degrees shown by a broken line. Intersect. By adopting such a configuration of the end surface 111, the occurrence of cracks, cracks, etc. of the end surface 111 during transportation is particularly suppressed.

圖4表示端面111之表面之放大圖。端面111之表面形成為凹凸形狀,但於本實施形態之顯示器用玻璃110中,將端面111之表面上之最高點與最低點之距離即最大高度Δz抑制為100 μm以下。先前之玻璃之端面係Δz>100 μm,但於本實施形態中,藉由端面111採用此種粗糙度較小之表面形狀,得以抑制搬運時之端面111之裂紋、龜裂等之產生。FIG. 4 shows an enlarged view of the surface of the end surface 111. The surface of the end surface 111 is formed into a concave-convex shape. However, in the display glass 110 of the present embodiment, the maximum height Δz, which is the distance between the highest point and the lowest point on the surface of the end surface 111, is suppressed to 100 μm or less. The end face of the previous glass is Δz>100 μm. However, in this embodiment, the end face 111 adopts such a surface shape with a small roughness to suppress the occurrence of cracks and cracks on the end face 111 during transportation.

本實施形態之顯示器用玻璃110較理想為4邊及4邊之端面111全部滿足上述所有必要條件。藉由此種構成,提供一種可有效地抑制端面之不良之顯示器用玻璃110。In the glass 110 for a display of this embodiment, it is desirable that the four sides and the end surfaces 111 of all four sides satisfy all the above-mentioned necessary conditions. With such a configuration, a glass 110 for a display that can effectively suppress the defects of the end face is provided.

其次,對實施形態之顯示器用玻璃110之製造方法進行說明。圖5表示製造顯示器用玻璃110之製造裝置。Next, a method of manufacturing the display glass 110 of the embodiment will be described. FIG. 5 shows a manufacturing apparatus for manufacturing glass 110 for a display.

如圖示,製造裝置具備:玻璃熔融槽51,其供將玻璃原料熔融並將已熔融之玻璃澄清;浮式浴53,其使熔融玻璃流出至熔融金屬錫等熔融金屬層52之上,並使其一面漂浮一面行進,藉此成形為一定之寬度及厚度之平坦之帶狀玻璃(玻璃帶);徐冷爐57,其具有將自浮式浴53搬出之帶狀玻璃G徐冷並儘可能減少於帶狀玻璃G之內部產生應變之情況的第1徐冷室55及第2徐冷室56;切斷台58,其將自徐冷爐57搬出之帶狀玻璃G切斷為特定尺寸;以及採板台59,其將以經切斷之板玻璃之形式製造之圖1之顯示器用玻璃110分類並進行裝箱等。再者,帶狀玻璃G係利用實線表示,故而表示為於圖5之浮式浴中在熔融金屬層52之上隔開間隔地朝圖之右方向之箭頭A之方向流動,但實際上,帶狀玻璃G與熔融金屬面相接而流動。As shown in the figure, the manufacturing apparatus includes: a glass melting tank 51 for melting glass raw materials and clarifying the melted glass; a floating bath 53 for flowing molten glass onto the molten metal layer 52 such as molten metal tin, and It floats and travels on one side, thereby forming a flat ribbon glass (glass ribbon) of a certain width and thickness; Xu Leng furnace 57, which has ribbon glass G to remove the self-floating bath 53 and cool it as much as possible The first chilling chamber 55 and the second chilling chamber 56 where strain occurs inside the ribbon glass G; a cutting table 58 that cuts the ribbon glass G carried out from the chilling furnace 57 to a specific size; and The pallet 59 sorts and packs the display glass 110 of FIG. 1 manufactured in the form of cut sheet glass. Furthermore, the ribbon glass G is represented by a solid line, so it is shown as flowing in the direction of arrow A in the right direction of the figure at intervals on the molten metal layer 52 in the floating bath of FIG. , The ribbon glass G flows in contact with the molten metal surface.

於該例中,玻璃熔融槽51、浮式浴53及徐冷爐57設置於相對於外部大氣成為包圍構造之一個建築物(以下稱作第1建築物60)內,切斷台58與採板台59亦設置於成為包圍構造之一個建築物(以下稱作第2建築物61)內。但,何部分配置於何建築物等製造裝置之具體設計並無特別限定。In this example, the glass melting tank 51, the floating bath 53, and the Xu Cooling Furnace 57 are installed in a building (hereinafter referred to as the first building 60) that is surrounded by the outside atmosphere, and the cutting table 58 and the picking table 59 is also installed in a building (hereinafter referred to as a second building 61) that becomes a surrounding structure. However, the specific design of the manufacturing device such as which part is disposed in which building is not particularly limited.

於採板台59被裝箱或裝載至集裝箱中之顯示器用玻璃110通常會被搬運至其他場所,實施端面111之倒角加工、研磨加工等並組裝成液晶面板。The display glass 110 that is packed or loaded into the container at the pallet 59 is usually transported to another place, and chamfering and polishing the end surface 111 are processed to assemble the liquid crystal panel.

圖6係表示浮式浴53與第2建築物61之內部之製造步驟之概念圖,圖7係圖6之P-P線處之剖視圖。使自玻璃熔融槽51流出至浮式浴53內之熔融狀態之帶狀玻璃G於浮式浴53內之熔融金屬層(熔融錫等)52上流動而成形為板狀之帶狀玻璃G。已熔融之帶狀玻璃G一面朝A方向(搬送方向)流動一面逐漸冷卻而變硬,從而成為板狀之帶狀玻璃G。帶狀玻璃G於下游區域被自熔融金屬層52提拉,藉由輥式輸送機12之旋轉而搬送至下游之徐冷爐57、切斷台58。FIG. 6 is a conceptual diagram showing the manufacturing steps inside the floating bath 53 and the second building 61, and FIG. 7 is a cross-sectional view taken along line P-P in FIG. The molten glass ribbon G flowing out of the glass melting tank 51 into the floating bath 53 flows on the molten metal layer (melted tin, etc.) 52 in the floating bath 53 to form a plate-shaped ribbon glass G. The melted ribbon glass G gradually cools and hardens while flowing in the direction A (transport direction), thereby becoming a plate-shaped ribbon glass G. The ribbon-shaped glass G is pulled from the molten metal layer 52 in the downstream region, and is conveyed to the downstream chilling furnace 57 and the cutting table 58 by the rotation of the roller conveyor 12.

浮式浴53具備於寬度方向上對熔融金屬層52上之已熔融之帶狀玻璃G施加張力之上輥40。藉由上輥40之作用,帶狀玻璃G被加工為具有所需之寬度、厚度。如圖6所示,上輥40係成對地使用,按壓熔融金屬層52上之熔融狀態之帶狀玻璃G之兩側緣部,於寬度方向上對帶狀玻璃G施加張力。沿著帶狀玻璃G之流動方向隔開間隔地配設複數對上輥40。The floating bath 53 includes an upper roller 40 that applies tension to the molten ribbon glass G on the molten metal layer 52 in the width direction. By the action of the upper roller 40, the ribbon glass G is processed to have a desired width and thickness. As shown in FIG. 6, the upper rollers 40 are used in pairs, pressing both side edges of the molten ribbon glass G on the molten metal layer 52 to apply tension to the ribbon glass G in the width direction. A plurality of pairs of upper rollers 40 are arranged at intervals along the flow direction of the ribbon glass G.

上輥40於前端部具有與帶狀玻璃G接觸之旋轉構件。藉由旋轉構件進行旋轉,而將帶狀玻璃G朝特定方向送出。於利用複數對上輥40施加張力之期間,帶狀玻璃G一面朝特定方向流動一面逐漸冷卻而變硬。The upper roller 40 has a rotating member in contact with the ribbon glass G at the front end portion. By rotating the rotating member, the ribbon glass G is sent out in a specific direction. While applying tension to the upper roller 40 by a plurality, the ribbon glass G gradually cools and hardens while flowing in a specific direction.

藉由上輥40之拉伸作用,於帶狀玻璃G之寬度方向(圖6之Y方向)之兩側緣部F,形成厚壁之兩側緣部(所謂之邊緣部)F,於兩側緣部F之表面,於徐冷過程中自然地形成特定之條紋狀之花紋。兩側緣部F係於更下游之任一位置,在任一時點被去除。By the stretching action of the upper roller 40, thick side edges (so-called edge portions) F are formed on both side edges F of the ribbon glass G in the width direction (Y direction in FIG. 6). The surface of the side edge portion F naturally forms a specific stripe pattern during the chilling process. The edge portions F on both sides are located at any position further downstream and are removed at any time.

帶狀玻璃G由輥式輸送機12搬送至更下游並通過徐冷爐57,且搬送至第2建築物61之切斷台58,由配置於切斷台58上之特定位置之切割線加工裝置切斷。圖8係表示設置於切斷台58之切割線加工裝置80之概要之立體圖。切割線加工裝置80係與對自第1建築物60利用輥式輸送機12連續搬送來之帶狀玻璃G加工縱切割線及橫切割線之、被稱作所謂不同尺寸切割之切割線加工方法對應的切割線加工裝置,且至少設置於較下述圖6、圖7之攝像裝置71、72更靠下游側。但,切割線加工裝置10並不限定於不同尺寸切割。The ribbon glass G is transported by the roller conveyor 12 further downstream and passes through the chilling furnace 57 and is transported to the cutting table 58 of the second building 61, which is cut by a cutting line processing device arranged at a specific position on the cutting table 58 Break. FIG. 8 is a perspective view showing the outline of the cutting wire processing device 80 provided on the cutting table 58. The cutting line processing device 80 is a cutting line processing method called so-called different-size cutting of a longitudinal cutting line and a transverse cutting line for processing the ribbon glass G continuously transported from the first building 60 by the roller conveyor 12 Corresponding cutting line processing devices are provided at least on the downstream side of the imaging devices 71 and 72 in FIGS. 6 and 7 described below. However, the cutting line processing device 10 is not limited to cutting with different sizes.

切割線加工裝置80包括設置於帶狀玻璃G之搬送方向上游側之縱切割線加工機14、及設置於其下游側之橫切割線加工機16。利用該縱切割線加工機14於帶狀玻璃G上加工出與帶狀玻璃G之搬送方向平行之縱切割線(圖6之X方向),於其下游側利用橫切割線加工機16於帶狀玻璃G上加工出與帶狀玻璃之搬送方向正交之橫切割線(圖6之Y方向)。The dicing wire processing apparatus 80 includes a longitudinal dicing wire processing machine 14 provided on the upstream side of the ribbon glass G in the conveyance direction, and a lateral dicing wire processing machine 16 provided on the downstream side thereof. A longitudinal cutting line (the X direction in FIG. 6) parallel to the conveying direction of the ribbon glass G is processed on the ribbon glass G by the longitudinal cutting line processing machine 14, and a transverse cutting line processing machine 16 is applied to the belt on the downstream side A transverse cutting line (Y direction in FIG. 6) orthogonal to the conveying direction of the ribbon glass is processed on the glass G.

縱切割線加工機14具備設置於帶狀玻璃G之寬度方向之複數個刀輪18、18…。該等刀輪18、18…係藉由周知之進退移動機構而相對於由輥式輸送機12搬送中之帶狀玻璃G進退移動,而藉由進出移動而被以特定之按壓力按壓至帶狀玻璃G。藉此,在帶狀玻璃G上加工出與帶狀玻璃G之搬送方向平行之縱切割線。The slitting machine 14 includes a plurality of cutter wheels 18, 18... provided in the width direction of the ribbon glass G. The cutter wheels 18, 18... are moved forward and backward with respect to the ribbon glass G being conveyed by the roller conveyor 12 by a well-known forward and backward movement mechanism, and are pressed to the belt with a specific pressing force by the forward and backward movement Shaped glass G. With this, a longitudinal cutting line parallel to the conveying direction of the ribbon glass G is processed on the ribbon glass G.

刀輪18經由進給機構22以特定之間隔安裝於樑部(導引架)26。該樑部26跨設於輥式輸送機12並且設置於與帶狀玻璃G之搬送方向正交之方向。又,進給機構22具有:固定部30,其可移動地固定於細長地形成在樑部26之水平方向之兩個狹縫28;及支持構件46,其一端連接於固定部30,且於另一端設置有刀輪18。又,與進給機構22之固定部30連接之滾珠螺桿裝置設置於中空之樑部26內,藉由驅動該滾珠螺桿裝置,於形成在樑部26之水平之狹縫28內,固定部30移動,且支持構件46、刀輪18連動地進行滑動移動。藉此,調整與帶狀玻璃G之搬送方向正交之方向之刀輪18之位置。The cutter wheel 18 is attached to the beam portion (guide frame) 26 at specific intervals via the feed mechanism 22. The beam portion 26 spans the roller conveyor 12 and is provided in a direction orthogonal to the conveying direction of the ribbon glass G. In addition, the feed mechanism 22 has: a fixing portion 30 that is movably fixed to two slits 28 that are elongated in the horizontal direction of the beam portion 26; and a support member 46, one end of which is connected to the fixing portion 30, and The other end is provided with a cutter wheel 18. In addition, the ball screw device connected to the fixed portion 30 of the feed mechanism 22 is provided in the hollow beam portion 26. By driving the ball screw device, in the horizontal slit 28 formed in the beam portion 26, the fixed portion 30 The support member 46 and the cutter wheel 18 move in a sliding manner in conjunction with each other. By this, the position of the cutter wheel 18 in the direction orthogonal to the conveyance direction of the ribbon glass G is adjusted.

另一方面,橫切割線加工機16具備一片刀輪20,該刀輪20與帶狀玻璃G之搬送速度同步地,相對於帶狀玻璃G之搬送方向朝斜方向之Z方向斜行移動,藉此於帶狀玻璃G上加工出與帶狀玻璃G之搬送方向正交之方向之橫切割線。On the other hand, the cross-cutting machine 16 includes a cutter wheel 20 that moves diagonally in the Z direction with respect to the conveying direction of the ribbon glass G in synchronization with the conveying speed of the ribbon glass G. With this, a transverse cutting line in a direction orthogonal to the conveying direction of the ribbon glass G is processed on the ribbon glass G.

使刀輪20斜行移動之未圖示之馬達與帶狀玻璃G之搬送速度同步地,由控制裝置對其斜行移動速度進行運動控制,藉此,於帶狀玻璃G上加工出與帶狀玻璃G之搬送方向正交之方向之橫切割線。又,刀輪20以藉由氣缸、伺服馬達等致動器而相對於帶狀玻璃G上下移動自如之方式設置。為了加工出良好之切入深度之橫切割線,刀輪20藉由該致動器而於切割線加工開始點之特定量近前位置預先開始下降。此後,刀輪20藉由馬達之驅動力而沿著導引架21於帶狀玻璃G上斜行移動。藉此,加工出橫切割線。此後,刀輪20於通過切割線加工結束點特定量後,藉由致動器自帶狀玻璃G上升移動,其後,藉由馬達回歸移動至原本之切割線待機位置。A motor (not shown) that causes the cutter wheel 20 to move obliquely is synchronized with the conveyance speed of the ribbon glass G, and the oblique movement speed of the blade glass is controlled by the control device. The transverse cutting line of the direction perpendicular to the conveying direction of the glass G. Moreover, the cutter wheel 20 is provided so that it can move up and down with respect to the band-shaped glass G by actuators, such as an air cylinder and a servo motor. In order to produce a transverse cutting line with a good cutting depth, the cutter wheel 20 starts to descend in advance by a specific amount of the cutting line machining start point by the actuator. After that, the cutter wheel 20 moves diagonally on the ribbon glass G along the guide frame 21 by the driving force of the motor. With this, the horizontal cutting line is processed. After that, the cutter wheel 20 moves up from the ribbon glass G by the actuator after a certain amount of the end point through the cutting line processing, and then returns to the original cutting line standby position by the motor.

如上所述,於切斷台58對帶狀玻璃G實施縱切割線及橫切割線之加工,利用設置於更下游之切斷裝置(參照圖10),切出圖1所示之顯示器用玻璃110之尺寸。為了以正確之尺寸切出顯示器用玻璃110,必須於正確之位置加工出縱切割線及橫切割線。帶狀玻璃G藉由輥式輸送機12之旋轉而始終朝搬送方向(A方向)移動,故而於搬送方向上切出切割線、即橫切割線之時點較為重要,必須正確地掌握搬送方向上之帶狀玻璃G之移動速度,於正確之時點切出橫切割線。As described above, the slit glass 58 is subjected to the processing of the longitudinal cutting line and the horizontal cutting line on the cutting table 58, and the display glass shown in FIG. 1 is cut out by a cutting device (see FIG. 10) provided further downstream 110 size. In order to cut out the display glass 110 with the correct size, the vertical cutting line and the horizontal cutting line must be processed at the correct position. The ribbon glass G always moves in the conveying direction (direction A) by the rotation of the roller conveyor 12, so it is important to cut the cutting line in the conveying direction, that is, the horizontal cutting line, and it is necessary to correctly grasp the conveying direction The moving speed of the ribbon glass G is cut at the correct time.

於專利文獻2等所記載之先前之技術中,使用如抵接於帶狀玻璃並旋轉之特定之輥之構件來掌握A方向上之移動速度。然而,無論使用何種輥,均會因熱膨脹等因素而導致輥發生變形,故而難以維持正確之移動速度之檢測。In the prior art described in Patent Document 2 etc., a member of a specific roller such as abutting and rotating the ribbon glass is used to grasp the moving speed in the A direction. However, no matter what kind of roller is used, the roller will be deformed due to thermal expansion and other factors, so it is difficult to maintain the correct detection of the moving speed.

因此,於本實施形態之顯示器用玻璃之製造方法、製造裝置中,使用圖6、圖7所示之於任一時點被切除之兩側緣部F來檢測帶狀玻璃G之移動速度。形成於兩側緣部F之表面之條紋狀之花紋始終在變動,不存在完全相同之花紋形成於兩處以上之位置之情況。因此,如圖6、圖7所示,於第2建築物61之內部設置有可拍攝該花紋之至少2台攝像裝置71、72。未圖示之電腦擷取並保持上游側之第1攝像裝置71所拍攝之圖像。進而,電腦擷取並保持下游側之第2攝像裝置72所拍攝之圖像,並以特定之速率將兩個圖像加以比較而對比兩個圖像是否一致。於兩個圖像一致之情形時,電腦可根據各個拍攝時點以及第1攝像裝置71及第2攝像裝置72之距離,對帶狀玻璃G之移動速度進行運算。Therefore, in the manufacturing method and manufacturing apparatus of the display glass of the present embodiment, the moving speed of the ribbon glass G is detected using the two-sided edge portions F cut off at any time as shown in FIGS. 6 and 7. The stripe patterns formed on the surface of the edge portions F on both sides are constantly changing, and there is no case where the exact same pattern is formed at two or more positions. Therefore, as shown in FIGS. 6 and 7, at least two camera devices 71 and 72 capable of photographing the pattern are provided inside the second building 61. An unillustrated computer captures and maintains the image captured by the first camera device 71 on the upstream side. Furthermore, the computer captures and maintains the image captured by the second camera 72 on the downstream side, and compares the two images at a specific rate to compare whether the two images are consistent. When the two images match, the computer can calculate the moving speed of the ribbon glass G according to the shooting time and the distance between the first imaging device 71 and the second imaging device 72.

電腦可基於運算出之移動速度,決定存在於較攝像裝置71、72更靠下游之切割線加工裝置80之橫切割線加工機16進行切斷之時點,並對切割線加工裝置80發送適當之時點之驅動信號。其結果,橫切割線加工機16可於正確之帶狀玻璃G之長邊方向(圖6之X方向)之位置切出橫切割線。再者,由攝像裝置71、72進行之拍攝之位置並無特別限定,亦可於徐冷爐57之內部進行,且至少於利用切斷台58之兩側緣部F之切除位置(未圖示)、或較切割線加工裝置80之位置更靠上游側之位置實施。Based on the calculated moving speed, the computer can determine the time when the cross-cutting line processing machine 16 of the cutting line processing device 80 located downstream of the camera devices 71 and 72 cuts, and send the cutting line processing device 80 the appropriate Driving signal at time. As a result, the cross-cutting line processing machine 16 can cut the cross-cutting line at the correct position in the longitudinal direction (the X direction in FIG. 6) of the ribbon glass G. In addition, the shooting position by the imaging devices 71 and 72 is not particularly limited, and it can also be performed inside the Xu Leng furnace 57 and at least at the cutting position (not shown) of the edge F on both sides of the cutting table 58 , Or more upstream than the position of the cutting line processing device 80.

圖9(a)表示橫切割線加工機16之刀輪20或縱切割線加工機14之刀輪18之放大前視圖。切斷前之帶狀玻璃G之表面與刀輪之間之角度

Figure 02_image001
通常因由玻璃之重量或搬送輥之重量引起之搬送輥之撓曲或搬送輥之熱變形、裝置之振動、樑部26或導引架21之撓曲等各種因素,而於玻璃板之製造中發生變動,從而不會成為90度±1度以內。本發明人等反覆進行實驗,發現藉由上述方法獲得之端面之狀態變差,且於所獲得之顯示器用玻璃之端面容易產生裂紋或龜裂。因此,於本實施形態中,將角度
Figure 02_image001
控制為90度±1度以內。藉由此種控制,能以相對於帶狀玻璃G之表面接近垂直之角度形成切割線L(橫切割線或縱切割線),可適當地形成顯示器用玻璃110之端面111。角度
Figure 02_image001
係於製造裝置之運轉開始前進行調整,但亦可於運轉中監視角度並自動地進行控制。FIG. 9( a) shows an enlarged front view of the cutter wheel 20 of the horizontal wire cutting machine 16 or the cutter wheel 18 of the longitudinal wire cutting machine 14. The angle between the surface of the band glass G before cutting and the cutter wheel
Figure 02_image001
Usually due to various factors such as the deflection of the conveying roller caused by the weight of the glass or the weight of the conveying roller or the thermal deformation of the conveying roller, the vibration of the device, the deflection of the beam portion 26 or the guide frame 21, etc. There is a change so that it does not fall within 90 degrees ± 1 degree. The inventors repeatedly conducted experiments and found that the state of the end surface obtained by the above method deteriorates, and cracks or cracks are easily generated on the end surface of the obtained display glass. Therefore, in this embodiment, the angle
Figure 02_image001
Control within 90 degrees ± 1 degree. By such control, the cutting line L (horizontal cutting line or vertical cutting line) can be formed at an angle close to the vertical with respect to the surface of the band glass G, and the end surface 111 of the display glass 110 can be appropriately formed. angle
Figure 02_image001
It is adjusted before the operation of the manufacturing device is started, but the angle can be monitored and automatically controlled during operation.

又,如圖9(a)所示,刀輪20或刀輪18一面形成橫切割線或縱切割線,一面自鄰接地設置之未圖示之油供給裝置持續地供給如煤油之油。煤油使刀輪與切割線之形成同時地順滑地行進,防止來自切割線之玻璃屑之飛散。如圖9(b)所示,油供給裝置以對相對於切割線L為±0.5 mm~±1 mm以內之寬度之區域(0.5 mm≦D1 ≦1 mm、0.5 mm≦D2 ≦1 mm)供給油之方式控制油之供給量。藉由此種控制,可順暢地形成切割線L。As shown in FIG. 9(a), the cutter wheel 20 or the cutter wheel 18 forms a horizontal cutting line or a vertical cutting line, and continuously supplies oil such as kerosene from an oil supply device (not shown) provided adjacent to each other. Kerosene allows the cutter wheel and cutting line to travel smoothly at the same time, preventing the scattering of glass chips from the cutting line. As shown in FIG. 9(b), the oil supply device is used for the area with a width within ±0.5 mm to ±1 mm relative to the cutting line L (0.5 mm≦D 1 ≦1 mm, 0.5 mm≦D 2 ≦1 mm ) The way of supplying oil controls the oil supply. With this control, the cutting line L can be formed smoothly.

圖10係配置於圖8之切割線加工裝置80之下游側之切斷裝置(玻璃折斷裝置)90之概略圖。切斷裝置90具備切斷用輥91及按壓輥92,此處所示之裝置係沿著橫切割線將帶狀玻璃G依次切斷而切出顯示器用玻璃110之裝置。切斷用輥91於切割線L(橫切割線)到來之時點,如箭頭B所示般上升並抵接於帶狀玻璃G之下表面。另一方面,按壓輥92於切割線L(橫切割線或縱切割線)到來之時點,如箭頭C所示般下降並抵接於帶狀玻璃G之上表面。藉由切斷用輥91與按壓輥92自上下之相反方向壓住帶狀玻璃G,可沿著切割線L將帶狀玻璃G切斷。FIG. 10 is a schematic view of a cutting device (glass breaking device) 90 arranged on the downstream side of the cutting line processing device 80 of FIG. 8. The cutting device 90 includes a cutting roller 91 and a pressing roller 92. The device shown here is a device that sequentially cuts the ribbon glass G along a horizontal cutting line to cut out the display glass 110. The cutting roller 91 rises as shown by the arrow B at the time when the cutting line L (transverse cutting line) arrives, and abuts against the lower surface of the ribbon glass G. On the other hand, when the cutting line L (horizontal cutting line or vertical cutting line) arrives, the pressing roller 92 descends as shown by the arrow C and abuts on the upper surface of the band glass G. When the cutting roller 91 and the pressing roller 92 press the ribbon glass G from opposite directions up and down, the ribbon glass G can be cut along the cutting line L.

因此,切斷用輥91之上升及按壓輥92之下降之時點、尤其是切斷用輥91之上升之時點為重要事項。於本實施形態中,對該時點進行控制,於如切斷用輥91在相對於切割線L為搬送方向上之±0.5 mm~±1 mm之區域W中與帶狀玻璃G之表面相接之時點,使切斷用輥上升。藉此,可順暢地形成切割線L,從而適當地形成顯示器用玻璃110之端面111。例如,可將拍攝切割線L(橫切割線)之兩個攝像裝置配置於切割線加工裝置80與切斷裝置90之間,電腦根據各個拍攝時點及距離,對帶狀玻璃G之移動速度、尤其是切割線L之移動速度進行運算。電腦可基於運算出之移動速度,決定切斷用輥91上升之時點,並對切斷裝置90發送適當之時點之驅動信號。Therefore, the timing of raising the cutting roller 91 and the lowering of the pressing roller 92, especially the timing of raising the cutting roller 91 are important matters. In this embodiment, the timing is controlled such that, for example, the cutting roller 91 is in contact with the surface of the ribbon glass G in a region W that is ±0.5 mm to ±1 mm in the conveyance direction relative to the cutting line L. At this point, the cutting roller is raised. As a result, the cutting line L can be smoothly formed, and the end surface 111 of the glass 110 for a display can be appropriately formed. For example, two camera devices that shoot the cutting line L (transverse cutting line) can be arranged between the cutting line processing device 80 and the cutting device 90. According to each shooting time and distance, the computer moves the speed of the ribbon glass G, Especially the calculation of the moving speed of the cutting line L. The computer can determine the timing at which the cutting roller 91 rises based on the calculated moving speed, and send a drive signal to the cutting device 90 at the appropriate timing.

圖11表示將輥式輸送機12之中央區域予以支持之支持構件。輥式輸送機12具有特定之長度,即便由確保特定之剛性之材料製成亦可能產生撓曲,導致角度

Figure 02_image001
偏離90度±1度之範圍,從而對帶狀玻璃G、進而顯示器用玻璃110之品質造成影響。因此,於本實施形態中,適當配置將輥式輸送機12之中央區域予以支持之支持構件43,從而抑制輥式輸送機12之撓曲。藉此,可實現帶狀玻璃G、顯示器用玻璃110之品質之穩定化。FIG. 11 shows a supporting member that supports the central area of the roller conveyor 12. The roller conveyor 12 has a certain length, even if it is made of a material that ensures a certain rigidity, it may deflect, resulting in an angle
Figure 02_image001
Deviating from the range of 90 degrees ± 1 degree, thereby affecting the quality of the ribbon glass G and further the glass 110 for display. Therefore, in this embodiment, the support member 43 that supports the central area of the roller conveyor 12 is appropriately arranged to suppress the deflection of the roller conveyor 12. As a result, the quality of the ribbon glass G and the display glass 110 can be stabilized.

如圖11所示,支持構件43具備支持桿41及輥42,於輥式輸送機12之長邊方向中央部,輥式輸送機12之表面凹陷而形成凹部12a,並且形成縮徑部12b。支持桿41之一端固定於地面L,輥42可旋轉地配置於支持桿41之另一端。As shown in FIG. 11, the support member 43 includes a support rod 41 and a roller 42. The surface of the roller conveyor 12 is recessed at the central portion in the longitudinal direction of the roller conveyor 12 to form a concave portion 12 a and a reduced diameter portion 12 b. One end of the support rod 41 is fixed to the ground L, and the roller 42 is rotatably disposed at the other end of the support rod 41.

圖12(a)係自橫向觀察圖11所得之輥式輸送機12與支持構件43之接觸部分之側面放大圖,支持構件43之輥42以可旋轉之狀態與輥式輸送機12之縮徑部12b相接,並且自下方支持縮徑部12b。由此,支持構件43可抑制輥式輸送機12之撓曲,從而防止對帶狀玻璃G、進而顯示器用玻璃110之品質造成不良影響。圖12(b)係圖12(a)之應用形態,亦可利用複數個輥42(本例中為兩個)自下方支持縮徑部12b,而使穩定性提昇。又,支持構件43亦可沿著輥式輸送機12之長邊方向設置複數個。FIG. 12(a) is an enlarged side view of the contact portion of the roller conveyor 12 and the support member 43 obtained from the lateral view of FIG. 11. The roller 42 of the support member 43 is in a rotatable state and the reduced diameter of the roller conveyor 12 The portion 12b is in contact, and supports the reduced diameter portion 12b from below. Thereby, the support member 43 can suppress the deflection of the roller conveyor 12, and prevent the adverse effect on the quality of the ribbon glass G and the glass 110 for a display. FIG. 12(b) is the application form of FIG. 12(a), and a plurality of rollers 42 (two in this example) may be used to support the diameter-reducing portion 12b from below to improve stability. In addition, a plurality of support members 43 may be provided along the longitudinal direction of the roller conveyor 12.

圖13係對積層有複數片之顯示器用玻璃110進行捆包之板狀體捆包箱301之概略圖,圖13(a)表示整體之剖視圖及支持部之放大圖。板狀體捆包箱301係於圖5所示之製造裝置中之採板台59或其他台上準備,供載置所製造之顯示器用玻璃110。FIG. 13 is a schematic view of a plate-shaped body packing box 301 for packing a plurality of sheets of display glass 110 laminated, and FIG. 13(a) shows an overall cross-sectional view and an enlarged view of a support portion. The plate-shaped body packing box 301 is prepared on the board picking table 59 or other tables in the manufacturing apparatus shown in FIG. 5 and is used to place the manufactured display glass 110.

本實施形態之板狀體捆包箱301(以下亦簡稱為「捆包箱301」)將複數片(例如120片)顯示器用玻璃110以大致水平地積層之狀態予以收納。當平放至捆包箱內時,為了避免顯示器用玻璃110彼此直接接觸,較佳為以於板狀體間隔著較薄之間隔紙之狀態積層。捆包箱301包括台座302、設置於該台座上之上蓋303、及配設於台座之側面之卡止部304。捆包箱301較佳為與所收納之顯示器用玻璃110之形狀一致,俯視為矩形。The plate-shaped body packing box 301 of the present embodiment (hereinafter also simply referred to as "bundling box 301") stores a plurality of pieces (for example, 120 pieces) of display glass 110 in a state of being stacked substantially horizontally. When placed flat in the packing box, in order to prevent the display glass 110 from directly contacting each other, it is preferable to laminate the plate-like body with a thin spacer paper in between. The packing box 301 includes a pedestal 302, an upper cover 303 disposed on the pedestal, and a locking portion 304 disposed on a side of the pedestal. The packing box 301 preferably conforms to the shape of the stored display glass 110 and is rectangular in plan view.

於本實施形態之台座302之一側面設置有底桿306。於將顯示器用玻璃110堆載於台座302時,一般而言於使台座302斜向傾斜之狀態下堆載顯示器用玻璃110,此時以設置有底桿306之面朝下之方式使台座302傾斜。底桿306係矩形板狀之構件,支持所堆載之顯示器用玻璃110之底邊部。就確保顯示器用玻璃110之穩定性之觀點而言,底桿306較佳為於台座之一側面設置複數個,例如於台座302之一側面設置兩個底桿306。A bottom bar 306 is provided on one side of the base 302 of this embodiment. When stacking the display glass 110 on the pedestal 302, generally, the display glass 110 is stacked in a state where the pedestal 302 is tilted obliquely. At this time, the pedestal 302 is placed with the bottom pole 306 facing down tilt. The bottom rod 306 is a rectangular plate-shaped member that supports the bottom edge portion of the stacked display glass 110. From the viewpoint of ensuring the stability of the display glass 110, it is preferable that a plurality of bottom rods 306 are provided on one side of the base, for example, two bottom rods 306 are provided on one side of the base 302.

又,於台座之302之四角設置有四個柱307。如圖13之由單點虛線包圍之放大圖所示,於柱307之頂部形成有圓錐之頂部被切除之形狀且剖面為梯形之支持部309,可經由支持部309於台座302之上載置其他台座。如圖13(b)之變化例所示,亦可使用具有接近純圓錐之形狀(僅前端成為曲面)之支持部310。In addition, four posts 307 are provided at four corners of the base 302. As shown in the enlarged view surrounded by a single dotted line in FIG. 13, a support part 309 having a conical shape with a truncated top and a trapezoidal cross section is formed on the top of the column 307. The support part 309 can be placed on the base 302 via the support part 309. Pedestal. As shown in the variation of FIG. 13(b), the support portion 310 having a shape close to a pure cone (only the front end becomes a curved surface) may be used.

上蓋3係下表面開口並自上包圍所堆載之顯示器用玻璃110者,可如圖13所示裝卸於配置在最上方之台座302。The upper cover 3 is an opening on the lower surface and surrounds the stacked display glass 110 from above, and can be attached to and detached from the uppermost base 302 as shown in FIG. 13.

為了使所收納之顯示器用玻璃110穩定,卡止部304配設於台座302之4個側面中之至少2個側面,但較佳為配設於3個側面。於配設在3個側面之情形時,較佳為配設於除設置有上述底桿306之側面以外之3個側面。又,卡止部304可於台座302之每個側面配設單個亦可配設複數個,例如可於台座302之1個側面配設1個,亦可配設兩個。In order to stabilize the stored display glass 110, the locking portion 304 is arranged on at least two of the four sides of the pedestal 302, but it is preferably arranged on three sides. When it is arranged on three sides, it is preferably arranged on three sides other than the side on which the bottom bar 306 is provided. In addition, the locking portion 304 may be arranged on each side of the pedestal 302 individually or in plural, for example, one may be arranged on one side of the pedestal 302 or two.

卡止部304只要為可確保支持顯示器用玻璃110之強度之材質即可,亦可為鋁等非鐵金屬或樹脂等非金屬。形狀亦並無特別限定,例如可設為如圖13所示之L字形。The locking portion 304 may be a material that can ensure the strength of the glass 110 for supporting the display, and may also be a non-ferrous metal such as aluminum or a non-metal such as resin. The shape is not particularly limited, and for example, it may be an L-shape as shown in FIG. 13.

圖14係表示卡止部304配設於台座302時之固定構造之圖。 於本實施形態中,於台座302之供配設卡止部304之側面,在水平方向上至少設置有2個以上之固定銷320,該固定銷320包括軸部321及直徑大於軸部之頭部322。又,於卡止部304,以與固定銷320對應之方式於水平方向上至少設置有2個以上之用以承收固定銷320之固定槽323。固定槽係包括向卡止部304之下端開放之垂直部324及與垂直部324連續地形成之2個水平部325的倒F字狀之槽,垂直部324、水平部325之寬度均大於固定銷320之軸部321之直徑且小於頭部322之直徑。於本實施形態中,與2個水平部325對應地,於垂直方向上亦設置有2根固定銷320。FIG. 14 is a diagram showing a fixing structure when the locking portion 304 is arranged on the base 302. In this embodiment, at least two fixing pins 320 are provided on the side of the base 302 where the locking portion 304 is provided, the fixing pin 320 includes a shaft portion 321 and a head with a diameter larger than the shaft portion部322. In addition, at least two or more fixing grooves 323 for receiving the fixing pin 320 are provided in the horizontal direction corresponding to the fixing pin 320 in the locking portion 304. The fixing groove includes an inverted F-shaped groove that is open to the lower end of the locking portion 304 and two horizontal portions 325 formed continuously with the vertical portion 324. The widths of the vertical portion 324 and the horizontal portion 325 are larger than the fixed The diameter of the shaft portion 321 of the pin 320 is smaller than the diameter of the head 322. In this embodiment, corresponding to the two horizontal portions 325, two fixing pins 320 are also provided in the vertical direction.

於將卡止部304安裝於台座302時,首先,如圖14(a)所示,將固定銷320之軸部321插入至固定槽323之垂直部324之下端,使卡止部304向下方向滑動。其後,當固定銷320之軸部321到達至固定槽323之垂直部324與水平部325之連結部分後,如圖14(b)所示,使卡止部304於水平方向上滑動而使固定銷320之軸部321到達至固定槽323之水平部325之末端,藉此可將卡止部304固定於台座302。圖4(c)係表示卡止部304固定於台座302之狀態之圖。When mounting the locking portion 304 on the pedestal 302, first, as shown in FIG. 14(a), the shaft portion 321 of the fixing pin 320 is inserted into the lower end of the vertical portion 324 of the fixing groove 323 so that the locking portion 304 is downward Swipe in the direction. After that, when the shaft portion 321 of the fixing pin 320 reaches the connecting portion of the vertical portion 324 and the horizontal portion 325 of the fixing groove 323, as shown in FIG. 14(b), the locking portion 304 is slid in the horizontal direction to make The shaft portion 321 of the fixing pin 320 reaches the end of the horizontal portion 325 of the fixing groove 323, whereby the locking portion 304 can be fixed to the base 302. 4(c) is a diagram showing a state where the locking portion 304 is fixed to the base 302. FIG.

以此方式積層於台座302上之顯示器用玻璃110係以於搬送過程中不振動之方式,由設置於台座302之卡止部304以一定之力按壓至台座302。其結果,即便於捆包箱搬送時自外側受到衝擊,捆包箱本身伴隨搬送而振動,顯示器用玻璃110亦以穩定之狀態被保持。又,較佳為於經平放之最後之板狀體上,載置樹脂、瓦楞紙板、木材等板狀體(未圖示)作為緩衝材,以免卡止部直接接觸而產生瑕疵、污垢等。In this way, the display glass 110 stacked on the pedestal 302 is pressed against the pedestal 302 with a certain force by the locking portion 304 provided on the pedestal 302 in a manner that does not vibrate during transportation. As a result, even if an impact is received from the outside when the packaging box is transported, the packaging box itself vibrates with the transportation, and the display glass 110 is held in a stable state. Moreover, it is preferable to place a plate-like body (not shown) such as resin, corrugated cardboard, wood, etc. on the last plate-like body after being laid flat as a buffer material, so as to avoid the direct contact of the locking portion to cause defects, dirt, etc. .

<實施例> 以下,將本發明之實施例示於表1,將比較例示於表2。於下述表1、表2中,參數1之「直角度」相當於圖2中之傾斜角度γ1 、傾斜角度γ2 ,參數2之「端面強度」相當於藉由4點彎曲試驗所得之圖3、圖4之端面之強度,參數3之「端面之凹凸」相當於圖4之最大高度Δz,參數4之「端面之角度」相當於圖3(c)中之傾斜角度θ1 、傾斜角度θ2<Examples> Hereinafter, Examples of the present invention are shown in Table 1, and Comparative Examples are shown in Table 2. In the following Table 1 and Table 2, the "straight angle" of parameter 1 corresponds to the inclination angle γ 1 and the inclination angle γ 2 in FIG. 2, and the “end surface strength” of parameter 2 corresponds to the result obtained by the 4-point bending test The strength of the end faces in Figures 3 and 4; the "concaveness of the end face" in parameter 3 is equivalent to the maximum height Δz in Figure 4, and the "angle of the end face" in parameter 4 is equivalent to the inclination angle θ 1 and inclination in Figure 3(c). Angle θ 2 .

製法條件1之「與刀輪之間之角度」相當於圖9(a)之玻璃之表面與刀輪之角度

Figure 02_image001
,製法條件2之「折斷方法」中,「攝像」相當於使用有攝像裝置之圖10之切斷用輥上升之控制方法,「輥壓」相當於有效利用專利文獻2中所揭示之輥之方法,製法條件3之「煤油之寬度」相當於圖9(b)之煤油之供給區域D1 、D2 。The "angle with the cutter wheel" of manufacturing method condition 1 is equivalent to the angle between the surface of the glass and the cutter wheel in Fig. 9(a)
Figure 02_image001
In the "breaking method" of manufacturing method condition 2, "imaging" is equivalent to the control method for raising the cutting roller of FIG. 10 using an imaging device, and "rolling" is equivalent to effectively using the roller disclosed in Patent Document 2. In the method, the "width of kerosene" in manufacturing method 3 corresponds to the kerosene supply areas D 1 and D 2 in FIG. 9(b).

「對玻璃之負荷」係指使積層有100片以上之2500 mm×2800 mm以上之大小之玻璃的集裝箱以時速40 km~100 km移行1小時以上之情形時對玻璃施加之最大負荷。將施加有此種負荷時所堆載之玻璃均未破裂之情形以〇表示,且即便一片破裂亦以×表示。"Load on glass" refers to the maximum load applied to the glass when the container with more than 100 sheets of glass of 2500 mm × 2800 mm or more is moved at a speed of 40 km to 100 km per hour for more than 1 hour. The case where none of the glass piled up when such a load is applied is broken is indicated by 0, and even if one piece is broken, it is indicated by ×.

[表1]

Figure 108131634-A0304-0001
[Table 1]
Figure 108131634-A0304-0001

[表2]

Figure 108131634-A0304-0002
[Table 2]
Figure 108131634-A0304-0002

關於實施例1之玻璃之參數,直角度為0.1度,端面強度為102 MPa,端面之凹凸為5.0 μm,端面之角度為0.42度。該玻璃係於與刀輪之間之角度為90.2度、折斷方法為圖10之方法、煤油之寬度為0.8 mm的製造條件下所製造者。判明即便於上述條件下對100片以上之實施例1之玻璃賦予負荷,亦不會產生1片破裂之玻璃,而可獲得優異之顯示器用玻璃。Regarding the parameters of the glass of Example 1, the straight angle is 0.1 degrees, the end surface strength is 102 MPa, the end surface irregularities are 5.0 μm, and the end surface angle is 0.42 degrees. The glass was manufactured under the manufacturing conditions that the angle with the cutter wheel is 90.2 degrees, the breaking method is the method of FIG. 10, and the width of the kerosene is 0.8 mm. It was found that even if more than 100 pieces of the glass of Example 1 were applied under the above conditions, one piece of broken glass would not occur, and excellent glass for display could be obtained.

關於實施例2之玻璃之參數,直角度為-0.13度,端面強度為107 MPa,端面之凹凸為-4.0 μm,端面之角度為-0.33度。該玻璃係於與刀輪之間之角度為89.7度,折斷方法為圖10之方法、煤油之寬度為0.6 mm的製造條件下所製造者。判明即便於上述條件下對100片以上之實施例2之玻璃賦予負荷,亦不會產生1片破裂之玻璃,而可獲得優異之顯示器用玻璃。Regarding the parameters of the glass of Example 2, the straight angle is -0.13 degrees, the end surface strength is 107 MPa, the end surface irregularities are -4.0 μm, and the end surface angle is -0.33 degrees. The glass was manufactured under the manufacturing condition that the angle with the cutter wheel was 89.7 degrees, the breaking method was the method of FIG. 10, and the width of the kerosene was 0.6 mm. It was found that even if more than 100 pieces of the glass of Example 2 were applied under the above conditions, one piece of broken glass would not occur, and excellent glass for display could be obtained.

關於實施例3之玻璃之參數,直角度為0.05度,端面強度為148 MPa,端面之凹凸為3.1 μm,端面之角度為0.12度。該玻璃係於與刀輪之間之角度為89.9度、折斷方法為圖10之方法、煤油之寬度為0.9 mm的製造條件下所製造者。判明即便於上述條件下對100片以上之實施例3之玻璃賦予負荷,亦不會產生1片破裂之玻璃,而可獲得優異之顯示器用玻璃。Regarding the parameters of the glass of Example 3, the straight angle is 0.05 degrees, the strength of the end surface is 148 MPa, the unevenness of the end surface is 3.1 μm, and the angle of the end surface is 0.12 degrees. The glass was manufactured under the manufacturing conditions that the angle with the cutter wheel was 89.9 degrees, the breaking method was the method of FIG. 10, and the width of the kerosene was 0.9 mm. It was found that even if more than 100 pieces of the glass of Example 3 were applied under the above conditions, one piece of broken glass would not occur, and excellent glass for display could be obtained.

關於實施例4之玻璃之參數,直角度為-0.06度,端面強度為145 MPa,端面之凹凸為-4.1 μm,端面之角度為-0.11度。該玻璃係於與刀輪之間之角度為90.1度、折斷方法為圖10之方法、煤油之寬度為0.7 mm的製造條件下所製造者。判明即便於上述條件下對100片以上之實施例4之玻璃賦予負荷,亦不會產生1片破裂之玻璃,而可獲得優異之顯示器用玻璃。Regarding the parameters of the glass of Example 4, the straight angle is -0.06 degrees, the end surface strength is 145 MPa, the end surface irregularities are -4.1 μm, and the end surface angle is -0.11 degrees. The glass was manufactured under the manufacturing conditions that the angle with the cutter wheel is 90.1 degrees, the breaking method is the method of FIG. 10, and the width of the kerosene is 0.7 mm. It was found that even if more than 100 pieces of the glass of Example 4 were applied under the above conditions, one piece of broken glass would not occur, and excellent display glass could be obtained.

關於實施例5之玻璃之參數,直角度為0.03度,端面強度為186 MPa,端面之凹凸為1.8 μm,端面之角度為0.04度。該玻璃係於與刀輪之間之角度為90.0度、折斷方法為圖10之方法、煤油之寬度為0.8 mm的製造條件下所製造者。判明即便於上述條件下對100片以上之實施例5之玻璃賦予負荷,亦不會產生1片破裂之玻璃,而可獲得優異之顯示器用玻璃。Regarding the parameters of the glass of Example 5, the straight angle is 0.03 degrees, the end surface strength is 186 MPa, the end surface irregularities are 1.8 μm, and the end surface angle is 0.04 degrees. The glass was manufactured under the manufacturing condition that the angle with the cutter wheel is 90.0 degrees, the breaking method is the method of FIG. 10, and the width of the kerosene is 0.8 mm. It was found that even if more than 100 pieces of the glass of Example 5 were applied under the above conditions, one piece of broken glass was not generated, and excellent glass for display was obtained.

關於實施例6之玻璃之參數,直角度為-0.02度,端面強度為210 MPa,端面之凹凸為-1.1 μm,端面之角度為-0.05度。該玻璃係於與刀輪之間之角度為90.0度、折斷方法為圖10之方法、煤油之寬度為0.6 mm的製造條件下所製造者。判明即便於上述條件下對100片以上之實施例6之玻璃賦予負荷,亦不會產生1片破裂之玻璃,而可獲得優異之顯示器用玻璃。Regarding the parameters of the glass of Example 6, the straight angle is -0.02 degrees, the end surface strength is 210 MPa, the end surface irregularities are -1.1 μm, and the end surface angle is -0.05 degrees. The glass was manufactured under the manufacturing conditions that the angle with the cutter wheel is 90.0 degrees, the breaking method is the method of FIG. 10, and the width of the kerosene is 0.6 mm. It was found that even if more than 100 pieces of the glass of Example 6 were applied under the above conditions, one piece of broken glass would not occur, and excellent glass for display could be obtained.

根據如上所述之結果可理解,於顯示器用玻璃之4邊之各者對於相交之其他邊,於相對於90度之方向在+0.3度~-0.3度之範圍內相交,且4邊之各者之端面之端面強度為100 MPa以上之情形時,可獲得優異之顯示器用玻璃。又,判明於端面之表面上之最高點與最低點之距離即最大高度(端面之凹凸)為100 μm以下,且端面對於俯視下之第1主面及第2主面,於相對於90度之方向在+5度~-5度之範圍內相交之情形時,可獲得尤其優異之顯示器用玻璃。According to the results as described above, it can be understood that each of the four sides of the display glass intersects the other sides in the range of +0.3 degrees to -0.3 degrees relative to the direction of 90 degrees, and each of the four sides When the end surface strength of the end surface is 100 MPa or more, excellent display glass can be obtained. Also, it was found that the distance between the highest point and the lowest point on the surface of the end face, that is, the maximum height (concavo-convex of the end face) is 100 μm or less, and the end face is 90 degrees relative to the first and second principal faces in plan view When the directions intersect within the range of +5 degrees to -5 degrees, particularly excellent display glass can be obtained.

另一方面,關於比較例1之玻璃之參數,直角度為0.4度,端面強度為80 MPa,端面之凹凸為111 μm,端面之角度為6.11度。該玻璃係於與刀輪之間之角度為92.0度、折斷方法為專利文獻2之方法、煤油之寬度為0.1 mm的製造條件下所製造者。判明當於上述條件下對100片以上之比較例1之玻璃賦予負荷時,於負荷為0~0.5 G時未產生破裂之玻璃,但於負荷為0.5~10 G時產生破裂之玻璃,而不適於顯示器用玻璃。On the other hand, regarding the parameters of the glass of Comparative Example 1, the straight angle is 0.4 degrees, the strength of the end surface is 80 MPa, the unevenness of the end surface is 111 μm, and the angle of the end surface is 6.11 degrees. This glass was manufactured under the manufacturing conditions that the angle with the cutter wheel is 92.0 degrees, the breaking method is the method of Patent Document 2, and the width of kerosene is 0.1 mm. It was found that when more than 100 pieces of the glass of Comparative Example 1 were applied under the above conditions, the glass that did not break at a load of 0 to 0.5 G, but the glass that broke at a load of 0.5 to 10 G was uncomfortable Used for display glass.

關於比較例2之玻璃之參數,直角度為-0.5度,端面強度為73 MPa,端面之凹凸為-123 μm,端面之角度為-5.29度。該玻璃係於與刀輪之間之角度為88.0度、折斷方法為專利文獻2之方法、煤油之寬度為0.1 mm的製造條件下所製造者。判明當於上述條件下對100片以上之比較例2之玻璃賦予負荷時,於負荷為0~0.5 G時未產生破裂之玻璃,但於負荷為0.5~10 G時產生破裂之玻璃,而不適於顯示器用玻璃。Regarding the parameters of the glass of Comparative Example 2, the straight angle is -0.5 degrees, the end surface strength is 73 MPa, the end surface irregularities are -123 μm, and the end surface angle is -5.29 degrees. The glass was manufactured under the manufacturing conditions that the angle with the cutter wheel was 88.0 degrees, the breaking method was the method of Patent Document 2, and the width of kerosene was 0.1 mm. It was found that when a load of 100 or more glasses of Comparative Example 2 was applied under the above conditions, the glass that did not break at a load of 0 to 0.5 G, but the glass that broke at a load of 0.5 to 10 G was uncomfortable Used for display glass.

關於比較例3之玻璃之參數,直角度為0.3度,端面強度為85 MPa,端面之凹凸為21.2 μm,端面之角度為2.52度。該玻璃係於與刀輪之間之角度為88.2度、折斷方法為專利文獻2之方法、煤油之寬度為0.3 mm的製造條件下所製造者。判明當於上述條件下對100片以上之比較例3之玻璃賦予負荷時,於負荷為0~0.5 G時未產生破裂之玻璃,但於負荷為0.5~10 G時產生破裂之玻璃,而不適於顯示器用玻璃。Regarding the parameters of the glass of Comparative Example 3, the straight angle was 0.3 degrees, the end surface strength was 85 MPa, the end surface irregularities were 21.2 μm, and the end surface angle was 2.52 degrees. This glass was manufactured under the manufacturing conditions that the angle with the cutter wheel was 88.2 degrees, the breaking method was the method of Patent Document 2, and the width of kerosene was 0.3 mm. It was found that when more than 100 pieces of glass of Comparative Example 3 were loaded under the above conditions, the glass that did not break when the load was 0 to 0.5 G, but the glass that broke when the load was 0.5 to 10 G, was uncomfortable Used for display glass.

關於比較例4之玻璃之參數,直角度為-0.4度,端面強度為88 MPa,端面之凹凸為-18.8 μm,端面之角度為-3.05度。該玻璃係於與刀輪之間之角度為91.7度、折斷方法為專利文獻2之方法、煤油之寬度為0.2 mm的製造條件下所製造者。判明當於上述條件下對100片以上之比較例4之玻璃賦予負荷時,於負荷為0~0.5 G時未產生破裂之玻璃,但於負荷為0.5~10 G時產生破裂之玻璃,而不適於顯示器用玻璃。Regarding the parameters of the glass of Comparative Example 4, the straight angle is -0.4 degrees, the end surface strength is 88 MPa, the end surface irregularities are -18.8 μm, and the end surface angle is -3.05 degrees. This glass was manufactured under the manufacturing conditions that the angle with the cutter wheel is 91.7 degrees, the breaking method is the method of Patent Document 2, and the width of kerosene is 0.2 mm. It was found that when a load of more than 100 glasses of Comparative Example 4 was applied under the above conditions, the glass that did not break at a load of 0 to 0.5 G, but the glass that broke at a load of 0.5 to 10 G was uncomfortable Used for display glass.

關於比較例5之玻璃之參數,直角度為0.21度,端面強度為95 MPa,端面之凹凸為13.3 μm,端面之角度為1.80度。該玻璃係於與刀輪之間之角度為88.7度、折斷方法為專利文獻2之方法、煤油之寬度為0.4 mm的製造條件下所製造者。判明當於上述條件下對100片以上之比較例5之玻璃賦予負荷時,於負荷為0~0.5 G時未產生破裂之玻璃,但於負荷為0.5~10 G時產生破裂之玻璃,而不適於顯示器用玻璃。Regarding the parameters of the glass of Comparative Example 5, the straight angle is 0.21 degrees, the end surface strength is 95 MPa, the end surface irregularities are 13.3 μm, and the end surface angle is 1.80 degrees. The glass was manufactured under the manufacturing conditions that the angle with the cutter wheel was 88.7 degrees, the breaking method was the method of Patent Document 2, and the width of kerosene was 0.4 mm. It was found that when a load of 100 or more glasses of Comparative Example 5 was applied under the above conditions, the glass that did not break at a load of 0 to 0.5 G, but the glass that broke at a load of 0.5 to 10 G was uncomfortable Used for display glass.

關於比較例6之玻璃之參數,直角度為-0.18度,端面強度為90 MPa,端面之凹凸為-9.2 μm,端面之角度為-1.30度。該玻璃係於與刀輪之間之角度為91.2度、折斷方法為專利文獻2之方法、煤油之寬度為0.3 mm的製造條件下所製造者。判明當於上述條件下對100片以上之比較例6之玻璃賦予負荷時,於負荷為0~0.5 G時未產生破裂之玻璃,但於負荷為0.5~10 G時產生破裂之玻璃,而不適於顯示器用玻璃。Regarding the parameters of the glass of Comparative Example 6, the straight angle is -0.18 degrees, the end surface strength is 90 MPa, the end surface irregularities are -9.2 μm, and the end surface angle is -1.30 degrees. This glass was manufactured under the manufacturing conditions that the angle with the cutter wheel was 91.2 degrees, the breaking method was the method of Patent Document 2, and the width of kerosene was 0.3 mm. It was found that when more than 100 pieces of the glass of Comparative Example 6 were applied under the above conditions, the glass that did not break at a load of 0 to 0.5 G, but the glass that broke at a load of 0.5 to 10 G was uncomfortable Used for display glass.

根據如上所述之結果可理解,於顯示器用玻璃之4邊之各者未對於相交之其他邊,於相對於90度之方向在+0.3度~-0.3度之範圍內相交之情形時,及/或於4邊之各者之端面之端面強度並非100 MPa以上之情形時,難以獲得優異之顯示器用玻璃。又,判明於端面之表面上之最高點與最低點之距離即最大高度(端面之凹凸)並非100 μm以下之情形時,及/或於端面未對於俯視下之第1主面及第2主面,於相對於90度之方向在+5度~-5度之範圍內相交之情形時,亦難以獲得優異之顯示器用玻璃。According to the results described above, it can be understood that when each of the four sides of the display glass does not intersect the other sides, it intersects within the range of +0.3 degrees to -0.3 degrees relative to the direction of 90 degrees, and /Or when the end surface strength of the end surfaces of each of the four sides is not 100 MPa or more, it is difficult to obtain excellent display glass. In addition, when it is determined that the distance between the highest point and the lowest point on the surface of the end face, that is, the maximum height (concave-convex of the end face) is not 100 μm or less, and/or the end face does not correspond to the first and second principal faces in plan view Even when the surface intersects within the range of +5 degrees to -5 degrees with respect to the direction of 90 degrees, it is difficult to obtain excellent display glass.

又,為了進一步詳細調查製造顯示器用玻璃時,切斷前之帶狀玻璃G之表面與刀輪之間之角度

Figure 02_image001
、所獲得之顯示器用玻璃之端面強度、及端面之表面上之最高點與最低點之距離即最大高度Δz和端面裂紋之產生容易度之關係,進行以下所示之試驗1~試驗5。In order to further investigate in detail when manufacturing the glass for display, the angle between the surface of the band glass G before cutting and the cutter wheel
Figure 02_image001
The relationship between the strength of the end face of the obtained display glass and the distance between the highest point and the lowest point on the surface of the end face, that is, the maximum height Δz and the ease of occurrence of end face cracks, were tested as shown in Tests 1 to 5 below.

(試驗1) 上述製法條件2係設為「攝像」,製法條件3係設為固定,使製法條件1之角度

Figure 02_image001
於90°-1.8°~90°+1.8°為止之範圍內變動,而製造顯示器用玻璃。於各
Figure 02_image001
下製造3000片顯示器用玻璃。於上述「對玻璃之負荷」成為0.5~10 G之條件下將所獲得之顯示器用玻璃搬運50 km以上,對產生端面裂紋之片數進行計數。將結果示於表3及圖15。(Test 1) The above manufacturing method condition 2 was set to "imaging", and the manufacturing method condition 3 was set to be fixed, so that the angle of manufacturing method condition 1
Figure 02_image001
It can be changed within the range of 90°-1.8°~90°+1.8° to manufacture display glass. Yu Ge
Figure 02_image001
3000 pieces of glass for display are manufactured below. Under the condition that the "load to glass" is 0.5 to 10 G, the obtained display glass is transported for more than 50 km, and the number of cracks on the end face is counted. The results are shown in Table 3 and FIG. 15.

[表3]

Figure 108131634-A0304-0003
[table 3]
Figure 108131634-A0304-0003

根據上述表3及圖15可明確,藉由將角度

Figure 02_image001
保持於90度±1度以內,而獲得不易產生端面裂紋之顯示器用玻璃。It can be made clear from the above Table 3 and FIG. 15 that by changing the angle
Figure 02_image001
Keep it within 90 degrees ± 1 degree, and obtain display glass that is less prone to end cracks.

(試驗2) 上述製法條件2係設為「攝像」,製法條件3係設為固定,使製法條件1之角度

Figure 02_image001
於90°-2.2°~90°+2.2°之範圍內每次變動0.2°,而製造顯示器用玻璃。於各
Figure 02_image001
下製造3000片顯示器用玻璃,測定所獲得之顯示器用玻璃之端面強度。將結果示於表4及圖16。(Test 2) The above manufacturing method condition 2 is set to "imaging", and the manufacturing method condition 3 is set to be fixed, so that the angle of manufacturing method condition 1 is
Figure 02_image001
Within the range of 90°-2.2°~90°+2.2°, each change is 0.2°, and the glass for display is manufactured. Yu Ge
Figure 02_image001
Next, 3000 pieces of display glass were manufactured, and the end surface strength of the obtained display glass was measured. The results are shown in Table 4 and Figure 16.

[表4]

Figure 108131634-A0304-0004
[Table 4]
Figure 108131634-A0304-0004

根據上述表4及圖16可明確,藉由將角度

Figure 02_image001
保持為90度±1度以內,而獲得端面強度為100 MPa以上之顯示器用玻璃。It can be made clear from the above Table 4 and Figure 16 that
Figure 02_image001
Keep the temperature within 90 degrees ± 1 degree, and obtain the display glass with an end surface strength of 100 MPa or more.

(試驗3) 測定試驗2中獲得之顯示器用玻璃之端面之最大高度Δz。將結果示於表5及圖17。 [表5]

Figure 108131634-A0304-0005
(Test 3) The maximum height Δz of the end surface of the glass for display obtained in Test 2 was measured. The results are shown in Table 5 and FIG. 17. [table 5]
Figure 108131634-A0304-0005

根據上述表5及圖17可明確,藉由將角度

Figure 02_image001
保持為90度±1度以內,而獲得端面之最大高度Δz為100 μm以下之顯示器用玻璃。It can be made clear from the above Table 5 and FIG. 17 that by changing the angle
Figure 02_image001
Keep the temperature within 90 degrees ± 1 degree, and obtain the display glass with a maximum height Δz of 100 μm or less.

(試驗4) 將端面強度不同之顯示器用玻璃以各端面強度準備3000片。於上述「對玻璃之負荷」成為0.5~10 G之條件下將所準備之顯示器用玻璃搬運50 km以上,對產生端面裂紋之片數進行計數。將結果示於表6及圖18。(Test 4) 3000 pieces of display glass with different end strengths were prepared at each end strength. Under the condition that the "load to glass" is 0.5 to 10 G, the prepared display glass is transported for more than 50 km, and the number of end cracks is counted. The results are shown in Table 6 and Figure 18.

[表6]

Figure 108131634-A0304-0006
[Table 6]
Figure 108131634-A0304-0006

根據上述表6及圖18可明確,端面強度為100 MPa以上之顯示器用玻璃尤其不易產生端面裂紋。It is clear from the above Table 6 and FIG. 18 that the display glass having an end surface strength of 100 MPa or more is particularly unlikely to cause end surface cracks.

(試驗5) 將Δz不同之顯示器用玻璃以各Δz準備3000片。於上述「對玻璃之負荷」成為0.5~10 G之條件下將所準備之顯示器用玻璃搬運50 km以上,對產生端面裂紋之片數進行計數。將結果示於表7及圖19。(Test 5) 3000 pieces of glass with different Δz were prepared for each Δz. Under the condition that the "load to glass" is 0.5 to 10 G, the prepared display glass is transported for more than 50 km, and the number of end cracks is counted. The results are shown in Table 7 and FIG. 19.

[表7]

Figure 108131634-A0304-0007
[Table 7]
Figure 108131634-A0304-0007

根據上述表7及圖19可明確,Δz為100 μm以下之顯示器用玻璃尤其不易產生端面裂紋。It is clear from the above Table 7 and FIG. 19 that the display glass having a Δz of 100 μm or less is particularly unlikely to cause end-face cracks.

根據本發明,可抑制如運輸中等之顯示器用玻璃之端面之裂紋、龜裂等不良之產生。運輸時之顯示器用玻璃之堆積方法(縱置、平放等)、捆包之態樣(間隔紙、托板等)並無特別限定。According to the present invention, it is possible to suppress the occurrence of defects such as cracks and cracks on the end surface of the display glass for transportation. The method of stacking the display glass during transportation (vertical, horizontal, etc.) and the form of packing (spacer, pallet, etc.) are not particularly limited.

再者,本發明並不限定於上述實施形態,可適當變化、改良等。此外,上述實施形態中之各構成要素之材質、形狀、尺寸、數值、形態,數量、配置部位等只要為可達成本發明者則為任意,並無限定。 [產業上之可利用性]In addition, the present invention is not limited to the above-mentioned embodiment, and can be appropriately changed, improved, or the like. In addition, the material, shape, size, numerical value, form, number, arrangement location, etc. of each constituent element in the above-mentioned embodiments are arbitrary and not limited as long as they can reach the cost of the inventor. [Industry availability]

參照特定之實施態樣對本發明進行了詳細說明,但對本領域技術人員而言顯而易見可不脫離本發明之精神及範圍地施加多種變更或修正。 本申請係基於2018年9月4日提出申請之日本專利申請2018-165344者,其內容係以參照之形式引用於本文。The present invention has been described in detail with reference to specific embodiments, but it is obvious to those skilled in the art that various changes or modifications can be applied without departing from the spirit and scope of the present invention. This application is based on the Japanese patent application 2018-165344 filed on September 4, 2018, and the contents thereof are incorporated herein by reference.

根據本發明,可抑制於顯示器用玻璃中產生如端面之裂紋之不良,可有效率地且價廉地提供顯示器用玻璃。According to the present invention, it is possible to suppress the occurrence of defects such as cracks on the end surface in the glass for displays, and it is possible to provide the glass for displays efficiently and inexpensively.

12:輥式輸送機 12a:凹部 12b:縮徑部 14:縱切割線加工機 16:橫切割線加工機 18:刀輪 20:刀輪 21:導引架 22:進給機構 26:樑部(導引架) 28:狹縫 30:固定部 40:上輥 41:支持桿 42:輥 43:支持構件 46:支持構件 51:玻璃熔融槽 52:熔融金屬層 53:浮式浴 55:第1徐冷室 56:第2徐冷室 57:徐冷爐 58:切斷台 59:採板台 60:第1建築物 61:第2建築物 71:第1攝像裝置 72:第2攝像裝置 80:切割線加工裝置 90:切斷裝置 91:切斷用輥 92:按壓輥 101:第1邊 102:第2邊 103:第3邊 104:第4邊 104A:第4邊 104B:第4邊 110:顯示器用玻璃 111:端面 111A:端面 111B:端面 121:第1主面 122:第2主面 150:直角游標尺 301:板狀體捆包箱 302:台座 303:上蓋 304:卡止部 306:底桿 307:柱 309:支持部 310:支持部 320:固定銷 321:軸部 322:軸部之頭部 323:固定槽 324:垂直部 325:水平部 D1:煤油之供給區域 D2:煤油之供給區域 F:側緣部 G:帶狀玻璃 L:切割線 W:區域 X:方向 Y:方向 γ1:傾斜角度 γ2:傾斜角度 θ1:傾斜角度 θ2:傾斜角度 Δz:最大高度

Figure 02_image001
:角度12: roller conveyor 12a: concave portion 12b: reduced diameter portion 14: longitudinal cutting line processing machine 16: horizontal cutting line processing machine 18: cutter wheel 20: cutter wheel 21: guide frame 22: feed mechanism 26: beam section (Guide frame) 28: slit 30: fixed part 40: upper roller 41: support rod 42: roller 43: support member 46: support member 51: glass melting tank 52: molten metal layer 53: floating bath 55: No. 1 Xu cold room 56: second Xu cold room 57: Xu cold furnace 58: cutting table 59: picking table 60: first building 61: second building 71: first camera 72: second camera 80: Cutting line processing device 90: cutting device 91: cutting roller 92: pressing roller 101: first side 102: second side 103: third side 104: fourth side 104A: fourth side 104B: fourth side 110 : Display glass 111: End surface 111A: End surface 111B: End surface 121: First main surface 122: Second main surface 150: Right-angle vernier scale 301: Plate-shaped packing box 302: Pedestal 303: Upper cover 304: Locking portion 306 : Bottom bar 307: column 309: support part 310: support part 320: fixing pin 321: shaft part 322: head of the shaft part 323: fixing groove 324: vertical part 325: horizontal part D 1 : kerosene supply area D 2 : Supply area of kerosene F: Side edge G: Ribbon glass L: Cutting line W: Area X: Direction Y: Direction γ 1 : angle of inclination γ 2 : angle of inclination θ 1 : angle of inclination θ 2 : angle of inclination Δz: maximum height
Figure 02_image001
:angle

圖1係本發明之一實施形態之顯示器用玻璃之俯視圖。 圖2係表示邊之直進性之概念圖。 圖3表示顯示器用玻璃之端面附近之放大剖視圖,(a)係理想狀態之端面,(b)係斜向偏移之狀態之端面,(c)係規定有端面之角度之圖。 圖4係表示端面之最大高度之概念圖。 圖5係顯示器用玻璃之製造裝置之整體圖。 圖6係顯示器用玻璃之兩側緣部(邊緣部)之圖及對其進行拍攝之攝像裝置之概念圖。 圖7係圖6之P-P線處之剖視圖。 圖8係切割線加工裝置之整體圖。 圖9(a)係切割線加工裝置中之刀輪之放大圖,圖9(b)係表示針對切割線之煤油之供給區域之概念圖。 圖10係切斷裝置(玻璃折斷裝置)之概念圖。 圖11係支持輥式輸送機之支持構件之前視圖。 圖12係自橫向觀察圖11而得之輥式輸送機與支持構件之接觸部分之側面放大圖,(a)係基本形態,(b)係應用形態。 圖13係表示收納有顯示器用玻璃之狀態之板狀體捆包箱之圖,(a)係整體之剖視圖及支持部之放大圖,(b)係支持部之變化例之放大圖。 圖14係表示卡止部向台座之固定方法之圖,(a)係表示將固定銷之軸部插入至固定槽之狀態之圖,(b)係表示使卡止部於水平方向上滑動之狀態之圖,(c)係表示卡止部固定於台座之狀態之圖。 圖15係表示試驗1之結果之圖。 圖16係表示試驗2之結果之圖。 圖17係表示試驗3之結果之圖。 圖18係表示試驗4之結果之圖。 圖19係表示試驗5之結果之圖。FIG. 1 is a plan view of a display glass according to an embodiment of the present invention. Fig. 2 is a conceptual diagram showing the straightness of an edge. Fig. 3 shows an enlarged cross-sectional view near the end surface of the display glass, (a) is the end surface in an ideal state, (b) is the end surface in a state of being obliquely shifted, and (c) is a diagram defining the angle of the end surface. Fig. 4 is a conceptual diagram showing the maximum height of the end face. Fig. 5 is an overall view of a display glass manufacturing apparatus. FIG. 6 is a diagram of both side edges (edge portions) of display glass and a conceptual diagram of an imaging device that photographs it. 7 is a cross-sectional view taken along line P-P in FIG. 6. Fig. 8 is an overall view of a cutting line processing device. Fig. 9(a) is an enlarged view of the cutter wheel in the cutting line processing device, and Fig. 9(b) is a conceptual view showing the supply area of kerosene for the cutting line. Fig. 10 is a conceptual diagram of a cutting device (glass breaking device). Fig. 11 is a front view of the supporting member supporting the roller conveyor. Fig. 12 is an enlarged side view of the contact portion of the roller conveyor and the supporting member obtained by observing Fig. 11 from the lateral direction, (a) is a basic form, and (b) is an application form. 13 is a diagram showing a plate-shaped body packing box in which glass for a display is stored, (a) is a cross-sectional view of the entire body and an enlarged view of a support portion, and (b) is an enlarged view of a modification of the support portion. 14 is a diagram showing a method of fixing the locking portion to the pedestal, (a) is a view showing a state in which the shaft portion of the fixing pin is inserted into the fixing groove, and (b) is a diagram showing the locking portion sliding in the horizontal direction State diagram, (c) is a diagram showing the state where the locking portion is fixed to the pedestal. 15 is a graph showing the results of Test 1. Fig. 16 is a graph showing the results of Test 2. Fig. 17 is a graph showing the results of Test 3. Fig. 18 is a graph showing the results of Test 4. Fig. 19 is a graph showing the results of Test 5.

101:第1邊 101: Side 1

102:第2邊 102: 2nd side

103:第3邊 103: 3rd side

104:第4邊 104: 4th side

110:顯示器用玻璃 110: glass for display

121:第1主面 121: 1st main face

122:第2主面 122: 2nd main face

Claims (2)

一種顯示器用玻璃,其係具有4邊且俯視下為矩形狀之顯示器用玻璃,且 4邊之各者對於相交之其他邊,於相對於90度之方向在+0.3度~-0.3度之範圍內相交, 4邊之各者之端面之端面強度為100 MPa以上, 上述端面之表面上之最高點與最低點之距離即最大高度為100 μm以下, 厚度為0.3 mm以上, 至少1邊之長度為2500 mm以上且為5000 mm以下。A display glass, which has four sides and is rectangular in plan view, and Each of the four sides intersects the other sides that intersect within the range of +0.3 degrees to -0.3 degrees relative to the direction of 90 degrees, The strength of the end face of each of the four sides is 100 MPa or more, The distance between the highest point and the lowest point on the surface of the above end surface, that is, the maximum height is 100 μm or less, The thickness is more than 0.3 mm, The length of at least one side is 2500 mm or more and 5000 mm or less. 如請求項1之顯示器用玻璃,其中上述端面對於俯視下之第1主面及第2主面,於相對於90度之方向在+5度~-5度之範圍內相交。The display glass according to claim 1, wherein the end face intersects the first principal surface and the second principal surface in a plan view in a range of +5 degrees to -5 degrees with respect to a direction of 90 degrees.
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