TW202004949A - Coating apparatus, coating method and organic EL display in which the number of contact holes for auxiliary electrodes is optimized - Google Patents
Coating apparatus, coating method and organic EL display in which the number of contact holes for auxiliary electrodes is optimized Download PDFInfo
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Abstract
Description
本開示關於塗布裝置、塗布方法及有機EL顯示器。This publication discloses a coating device, a coating method, and an organic EL display.
使用有機発光二極體(OLED:Organic Light Emitting Diode)的有機EL顯示器,薄型輕量而且低消費電力,在響應速度或視角、對比度之面具有極佳優點。有機発光二極體,係藉由像素電極與對向電極夾持包含發光層的有機EL層而構成。Organic EL displays using organic light emitting diodes (OLED: Organic Light Emitting Diode) are thin, lightweight and have low power consumption. They have excellent advantages in response speed, viewing angle and contrast. The organic photodiode is composed of a pixel electrode and a counter electrode sandwiching an organic EL layer including a light-emitting layer.
專利文獻1揭示藉由將低電阻率之材料所形成的補助電極連接於對向電極,來抑制伴隨有機EL顯示器之大畫面化的配線電阻之增加的技術。
[先前技術文獻]
[專利文獻]
[專利文獻1]特開2016-197240號公報[Patent Document 1] JP 2016-197240
[發明所欲解決之課題][Problems to be solved by the invention]
本開示提供補助電極用之接觸孔之數目為最佳化的有機EL顯示器。 [解決課題之手段]This disclosure provides an organic EL display in which the number of contact holes for auxiliary electrodes is optimized. [Means to solve the problem]
本開示之一態樣的塗布裝置,係具備:基板保持部;吐出單元;及移動機構。基板保持部係將基板保持。吐出單元包含在第1方向並列設置有複數個噴嘴的複數個噴頭噴頭。移動機構係使吐出單元與基板保持部沿著與第1方向交叉的第2方向相對地移動。基板具備:複數個像素電極,與複數個副像素對應而設置;堤岸(bank),覆蓋複數個像素電極,並且形成有使至少1個像素電極露出的複數個開口部;及複數個接觸孔,用以將與複數個像素電極對向的對向電極電連接於補助電極。接觸孔係按每2個以上之副像素設置。吐出單元係從噴嘴朝向基板保持部所保持的基板之開口部吐出有機材料之液滴。 [發明效果]The coating device according to one aspect of the present disclosure includes: a substrate holding portion; a discharge unit; and a moving mechanism. The substrate holding portion holds the substrate. The discharge unit includes a plurality of nozzle heads in which a plurality of nozzles are arranged in parallel in the first direction. The moving mechanism relatively moves the discharge unit and the substrate holding portion in the second direction crossing the first direction. The substrate includes: a plurality of pixel electrodes corresponding to the plurality of sub-pixels; a bank covering the plurality of pixel electrodes and forming a plurality of openings exposing at least one pixel electrode; and a plurality of contact holes, It is used to electrically connect the counter electrode facing the plurality of pixel electrodes to the auxiliary electrode. The contact holes are set for every two or more sub-pixels. The discharge unit discharges droplets of organic material from the nozzle toward the opening of the substrate held by the substrate holding portion. [Effect of the invention]
依據本開示,可以提供使補助電極用之接觸孔之數目成為最佳化的有機EL顯示器。According to this disclosure, it is possible to provide an organic EL display that optimizes the number of contact holes for auxiliary electrodes.
以下,參照圖面詳細說明實施本揭示之塗布裝置、塗布方法及有機EL顯示器之形態(以下,標記為「實施形態」)。又,該實施形態並非用來限定本揭示之塗布裝置、塗布方法及有機EL顯示器。又,各實施形態,在處理內容不矛盾之範圍內可以適當組合。又,以下各實施形態中同一之部位被附加同一之符號,並省略重複之說明。Hereinafter, referring to the drawings, the coating device, the coating method, and the form of the organic EL display (hereinafter, referred to as "embodiment") for implementing the present disclosure will be described in detail. In addition, this embodiment is not intended to limit the coating device, coating method, and organic EL display of the present disclosure. In addition, each embodiment can be combined as appropriate within a range where the processing contents are not contradictory. In addition, in the following embodiments, the same parts are denoted by the same symbols, and repeated explanations are omitted.
又,以下參照的各圖面中,為了容易理解說明,而有表示對相互正交的X軸方向、Y軸方向及Z軸方向進行規定,將Z軸正方向設為鉛直向上方向的正交座標系之情況。In addition, in the drawings referred to below, for easy understanding of the description, it is defined that the mutually orthogonal X-axis direction, Y-axis direction, and Z-axis direction are defined, and the positive Z-axis direction is orthogonal to the vertical upward direction The situation of the coordinate system.
使用有機發光二極體的有機EL顯示器,薄型輕量而且低消費電力,在響應速度或視角、對比度之面上具有極佳優點。因此,近年來,有機EL顯示器作為次世代之平板顯示器(FPD)受到注目。Organic EL displays using organic light-emitting diodes are thin, lightweight and have low power consumption. They have excellent advantages in response speed, viewing angle, and contrast. Therefore, in recent years, organic EL displays have attracted attention as the next-generation flat panel displays (FPD).
有機發光二極體,係藉由像素電極與對向電極夾持包含發光層的有機EL層而構成,有機EL層之形成係使用噴墨方式之塗布裝置。The organic light-emitting diode is composed of a pixel electrode and a counter electrode sandwiching an organic EL layer including a light-emitting layer. The organic EL layer is formed using an inkjet coating device.
近年來,伴隨有機EL顯示器之大畫面化,配線長度有變長之趨勢。若配線長度變長則配線電阻增加,據此,例如對位於遠離電源的位置之像素電極供給發光所必要的電力有可能變為困難。In recent years, with the increase in the size of organic EL displays, the wiring length tends to become longer. As the wiring length becomes longer, the wiring resistance increases, and accordingly, for example, it may become difficult to supply power necessary for light emission to the pixel electrode located at a position away from the power source.
於此,作為降低配線電阻的技術,提案將由低電阻率之材料所形成的補助電極連接於對向電極的技術。該技術中,補助電極之導通用之接觸孔係按每一副像素形成。副像素係指,構成1個像素的R(紅)、G(綠)、B(藍)之各別之點。亦即,於上述技術中,於紅色之副像素、綠色之副像素及藍色之副像素分別各形成1個接觸孔。Here, as a technique for reducing wiring resistance, a technique of connecting a supplementary electrode formed of a material with low resistivity to a counter electrode is proposed. In this technique, the contact holes of the auxiliary electrodes are formed for each sub-pixel. The sub-pixel refers to the respective points of R (red), G (green), and B (blue) that constitute one pixel. That is, in the above technique, one contact hole is formed in each of the red sub-pixel, the green sub-pixel, and the blue sub-pixel.
圖1係表示補助電極用之接觸孔按每一副像素形成的有機EL顯示器之構成例之模式平面圖。如圖1所示,有機EL顯示器1X具有複數個像素電極21X,及覆蓋複數個像素電極21X的堤岸30X。於堤岸30X按每一像素電極21X形成使像素電極21X之一部分露出的開口部31X。亦即,對1個像素電極21X形成1個開口部31X。FIG. 1 is a schematic plan view showing a configuration example of an organic EL display in which contact holes for auxiliary electrodes are formed for each sub-pixel. As shown in FIG. 1, the
於各開口部31X形成有機EL層23X。有機EL層23X,係藉由噴墨方式對各開口部31X吐出有機材料之液滴而形成。An
於有機EL層23X上配置有未圖示的對向電極。對向電極,係被複數個像素電極21X共有者,與複數個像素電極21X對向。如此般,藉由像素電極21X與對向電極夾持有機EL層23X來形成1個副像素。因此,俯視狀態下像素電極21X與開口部31X重疊的領域相當於1個副像素之區域。A counter electrode (not shown) is arranged on the
補助電極用之接觸孔50X按每一副像素形成。換言之,有機EL顯示器1X中,相對於1個像素電極21X或者1個開口部31X形成1個接觸孔50X。The
但是,近年來,為了提高有機EL顯示器之像素密度,有縮小副像素之尺寸之趨勢。通常,於堤岸按每一副像素形成有接受有機材料之液滴的開口部(參照圖1)。因此,若伴隨副像素之尺寸之縮小而縮小開口部之尺寸時,液滴之著陸位置之容許誤差變小,液滴容易從開口部溢出。However, in recent years, in order to increase the pixel density of organic EL displays, there is a tendency to reduce the size of sub-pixels. Generally, openings for receiving liquid droplets of organic material are formed for each sub-pixel on the bank (see FIG. 1 ). Therefore, when the size of the opening is reduced as the size of the sub-pixel is reduced, the allowable error of the landing position of the droplet becomes smaller, and the droplet is likely to overflow from the opening.
於此,為了緩和液滴之著陸位置之容許誤差,提案將供作為液滴著陸的開口部,不按每一副像素,而是按同色之相鄰的每複數個副像素形成的技術(以下標記為「像素連結」)。Here, in order to alleviate the allowable error of the landing position of the droplet, it is proposed that the opening for the landing of the droplet not be formed for each sub-pixel, but for each plurality of adjacent sub-pixels of the same color (below Marked as "Pixel Link").
但是,在補助電極用之接觸孔50X按每一副像素設置的有機EL顯示器1X中,難以進行像素連結。亦即,如圖1所示,各接觸孔50X形成於相鄰的2個同色之有機EL層23X之間之區域。因此,假設形成將圖1所示相鄰的2個同色之有機EL層23X連結的1個開口部之情況下,圖1所示2個接觸孔50X之中之上側之接觸孔50X成為位於開口部內。如此則,吐出至開口部的有機材料將流入接觸孔50X,無法完成將對向電極與補助電極電連接之功能。又,若有機材料流入接觸孔50X,有機EL層23X之膜厚均勻性有可能降低。However, in the
於此,補助電極用之接觸孔之數目被最佳化的有機EL顯示器之提供被期待。Here, the provision of an organic EL display in which the number of contact holes for auxiliary electrodes is optimized is expected.
<有機EL顯示器>
圖2係表示實施形態之有機EL顯示器之電路構成之一例之圖。又,圖2中將一個單位電路11擴大表示。<Organic EL display>
FIG. 2 is a diagram showing an example of the circuit configuration of the organic EL display of the embodiment. In addition, one
如圖2所示,有機EL顯示器1具備:基板10;複數個單位電路11;掃描線驅動電路14;及資料線驅動電路15。複數個單位電路11、掃描線驅動電路14及資料線驅動電路15係設置於基板10上。As shown in FIG. 2, the
單位電路11設置於,與掃描線驅動電路14連接的複數個掃描線16,及與資料線驅動電路15連接的複數個資料線17所包圍的區域。該單位電路11包含TFT層12及有機發光二極體13。The
TFT層12具有複數個TFT(Thin Film Transistor)。複數個TFT之中之一TFT具有作為開關元件之功能,另一之TFT具有作為對流入有機發光二極體13之電流量進行控制的電流控制用元件之功能。TFT層12藉由掃描線驅動電路14及資料線驅動電路15進行動作,對有機發光二極體13供給電流。TFT層12按每一單位電路11設置,複數個單位電路11被獨立控制。The
又,TFT層12只要是一般的構成即可,不限定於圖2所示構成。又,實施形態中,有機EL顯示器1之驅動方式以主動矩陣方式之情況下之例進行說明,但驅動方式為被動矩陣方式亦可。In addition, the
圖3係表示實施形態之有機EL顯示器1之模式平面圖。又,圖3中,省略後述之陰極22之圖示。又,圖3中,形成有同一色之發光層26的區域以同一之斜線表示。FIG. 3 is a schematic plan view showing the
如圖3所示,實施形態之有機EL顯示器1中,對2個副像素形成1個開口部31。具體而言,實施形態之有機EL顯示器1中,堤岸30之開口部31係使與相鄰的2個同色之副像素對應而設置的2個陽極21露出。於此,複數個同色之副像素沿著Y軸方向被配列,開口部31使在Y軸方向相鄰的2個陽極21之各一部分露出。As shown in FIG. 3, in the
如此般,將使形成有機EL層23用的有機材料之液滴著陸的開口部31,並非按每一副像素,而是按相鄰的每2個同色之副像素來形成,據此,可以緩和液滴之著陸位置之容許誤差。In this way, the
圖4為圖3中的IV-IV線剖面圖。如圖4所示,有機EL顯示器1中,於基板10上形成有TFT層12,於TFT層12上形成有為了使基於TFT層12而形成的段差平坦化之平坦化層18。基板10例如為玻璃基板或樹脂基板等之透明基板。FIG. 4 is a cross-sectional view taken along line IV-IV in FIG. 3. As shown in FIG. 4, in the
平坦化層18具有絕緣性。在貫穿平坦化層18的接觸孔形成有接觸栓塞19。接觸栓塞19係將形成於平坦化層18之平坦面的作為像素電極之陽極21與TFT層12進行電連接。接觸栓塞19藉由與陽極21同一之材料同時形成亦可。The
有機發光二極體13形成於平坦化層18之平坦面上。有機發光二極體13具有:作為像素電極之陽極21;以像素電極為基準而設置於基板10之相反側的作為對向電極之陰極22;及形成於陽極21與陰極22之間的有機EL層23。藉由使TFT層12動作,於陽極21與陰極22之間被施加電壓,有機EL層23發光。The organic
作為像素電極之陽極21,例如藉由ITO (Indium Tin Oxide)等形成,使來自有機EL層23之光透過。透過陽極21的光係透過基板10而被取出於外部。陽極21按每一單位電路11、換言之按每一副像素設置。The
作為對向電極之陰極22,例如由鋁等形成,使來自有機EL層23之光朝向有機EL層23反射。被陰極22反射之光透過有機EL層23、陽極21、基板10而被取出於外部。陰極22係被複數個單位電路11共有者。The
又,於此,針對陽極21為像素電極,陰極22為對向電極之情況下之例進行說明,但陰極22為像素電極,陽極21為對向電極亦可。In addition, here, an example in the case where the
有機EL層23,例如具有電洞注入層24、電洞輸送層25、發光層26、電子輸送層27及電子注入層28。電洞注入層24、電洞輸送層25、發光層26、電子輸送層27及電子注入層28由陽極21側向陰極22側依序被積層。The
在陽極21與陰極22之間被施加電壓時,電洞從陽極21被注入電洞注入層24,電子從陰極22被注入電子注入層28。注入電洞注入層24的電洞,係藉由電洞輸送層25被輸送至發光層26。被注入電子注入層28的電子,係藉由電子輸送層27被輸送至發光層26。於發光層26內電洞與電子再結合,發光層26之發光材料被激發,發光層26發光。When a voltage is applied between the
作為發光層26,例如圖3所示,形成有紅色發光層26R、綠色發光層26G及藍色發光層26B。紅色發光層26R係由發出紅色光的紅色發光材料形成。綠色發光層26G係由發出綠色光的綠色發光材料形成。藍色發光層26B係由發出藍色光的藍色發光材料形成。As the
有機EL顯示器1中的1個像素,係包含具有紅色發光層26R的副像素,及與該副像素鄰接且具有藍色發光層26B的副像素,及與該副像素鄰接且具有綠色發光層26G的副像素而構成。紅色發光層26R、綠色發光層26G及藍色發光層26B,俯視狀態下係在作為像素電極之陽極21與作為對向電極之陰極22所重疊的區域中發出。One pixel in the
堤岸30係將紅色發光層26R用之塗布液、綠色發光層26G用之塗布液、與藍色發光層26B用之塗布液隔開,防止彼等塗布液之混合。堤岸30具有絕緣性,將貫穿平坦化層18的接觸孔填埋。The
如圖3所示,於實施形態之有機EL顯示器1,對1個開口部31形成1個接觸孔50。換言之,接觸孔50係按由開口部31露出的2個陽極21所對應的每2個同色之陽極21設置。As shown in FIG. 3, in the
圖5為圖3中的V-V線剖面圖。如圖5所示,接觸孔50以貫穿堤岸30及平坦化層18的方式形成。接觸孔50開設於堤岸30之上面,使設置於基板10上的補助電極51之一部分露出。FIG. 5 is a cross-sectional view taken along line V-V in FIG. 3. As shown in FIG. 5, the
於接觸孔50例如埋設有W(鎢)等之導電性材料。據此,可以將陰極22與補助電極51電連接。A conductive material such as W (tungsten) is buried in the
如圖3所示,接觸孔50係形成於複數個開口部31之中之一個開口部31,於該一個開口部31在Y軸方向相鄰的另一個開口部31之間之區域。換言之,接觸孔50係形成於形成有同色之發光層26之於Y軸方向相鄰的2個開口部31之間之區域。因此,塗布處理時,有機材料不易進入接觸孔50。As shown in FIG. 3, the
如此般,補助電極用之接觸孔50係按由開口部31露出的2個陽極21所對應的每2個同色之陽極21而設置。據此,在進行像素連結時接觸孔50不會成為障礙。因此,即使對補助電極為必要的大型之有機EL顯示器,亦能適用像素連結。如上述般,作為對向電極之陰極22係被複數個單位電路11共有者,接觸孔50未必一定要按每一副像素設置。In this way, the
又,於此,雖示出按每2個副像素設置1個接觸孔50,但例如依據陽極21之面積或配線之粗細,按每3個以上之副像素設置1個接觸孔50亦可能。Here, although it is shown that one
<有機發光二極體之製造方法>
圖6係表示實施形態之有機發光二極體13之製造方法之流程圖。圖6所示各處理順序,係在基板10上形成TFT層12、補助電極51、平坦化層18、堤岸30、開口部31及接觸孔50,而且,對在接觸孔50埋設有導電性材料之後之有機EL顯示器進行。<Manufacturing method of organic light emitting diode>
FIG. 6 is a flowchart showing a method of manufacturing the organic
首先,於步驟S101中,進行作為像素電極之陽極21之形成。陽極21之形成例如可以使用蒸鍍法。陽極21係在平坦化層18之平坦面按每一單位電路11形成。又,同時形成陽極21與接觸栓塞19亦可。First, in step S101, the
接著,步驟S102中,進行堤岸30之形成。堤岸30例如使用光阻劑形成,藉由光微影成像處理圖案化成為規定之圖案。於堤岸30之開口部31中使陽極21之一部分露出。Next, in step S102, the
接著,於步驟S103中,進行電洞注入層24之形成。電洞注入層24之形成係使用噴墨法。藉由噴墨法將電洞注入層24用之塗布液塗布於陽極21上而形成塗布層。之後,對塗布層進行乾燥、燒結,形成圖4所示電洞注入層24。Next, in step S103, the
接著,於步驟S104中,進行電洞輸送層25之形成。電洞輸送層25之形成係和電洞注入層24之形成同樣地使用噴墨法。藉由噴墨法將電洞輸送層25用之塗布液塗布於電洞注入層24上而形成塗布層。之後,對塗布層進行乾燥、燒結,而形成電洞輸送層25。Next, in step S104, the
接著,於步驟S105中,進行發光層26之形成。發光層26之形成,係和電洞注入層24或電洞輸送層25之形成同樣地使用噴墨法。藉由噴墨法將發光層26用之塗布液塗布於電洞輸送層25上而形成塗布層。之後,對塗布層進行乾燥、燒結而形成發光層26。如上述般,作為發光層26而形成例如紅色發光層26R、綠色發光層26G及藍色發光層26B。Next, in step S105, the
接著,於步驟S106中,進行電子輸送層27之形成。電子輸送層27之形成,例如使用蒸鍍法等。電子輸送層27可以是被複數個單位電路11共有者,因此不僅形成於堤岸30之開口部31內之發光層26上,形成於堤岸30上亦可。Next, in step S106, the
接著,於步驟S107中,進行電子注入層28之形成。電子注入層28之形成,例如使用蒸鍍法等。電子注入層28係形成於電子輸送層27上。和電子輸送層27同樣,電子注入層28亦可以是被複數個單位電路11共有者。Next, in step S107, the
接著,於步驟S108中,進行陰極22之形成。陰極22之形成,例如使用蒸鍍法等。陰極22係形成於電子注入層28上。陰極22係被複數個單位電路11共有者。有機EL顯示器1之驅動方式為被動矩陣方式之情況下,陰極22被圖案化成為規定之圖案。Next, in step S108, the
藉由以上之工程製造有機發光二極體13。有機EL層23之中,在電洞注入層24、電洞輸送層25及發光層26之形成時使用基板處理系統。The organic
<基板處理系統>
圖7係表示實施形態之基板處理系統之構成之模式平面圖。圖7所示基板處理系統100,係藉由進行和圖6之步驟S103~S105相當的各處理,而在陽極21上形成電洞注入層24、電洞輸送層25及發光層26。<Substrate processing system>
7 is a schematic plan view showing the configuration of the substrate processing system of the embodiment. The
圖7所示基板處理系統100具有搬入站110;處理站120;搬出站130;及控制裝置140。The
搬入站110從外部搬入收納有複數個基板10的基板收納盒C,從基板收納盒C依序取出複數個基板10。於各基板10事先形成有TFT層12、平坦化層18、陽極21、堤岸30、開口部31及接觸孔50等。The carrying-in
搬入站110具備:載置基板收納盒C的基板收納盒載置台111;設置於基板收納盒載置台111與處理站120之間的搬送路112;及設置於搬送路112的基板搬送體113。基板搬送體113係在基板收納盒載置台111所載置的基板收納盒C與處理站120之間進行基板10之搬送。The
處理站120係於陽極21上形成電洞注入層24、電洞輸送層25及發光層26。處理站120具備:形成電洞注入層24的電洞注入層形成區塊121;形成電洞輸送層25的電洞輸送層形成區塊122;及形成發光層26的發光層形成區塊123。The
電洞注入層形成區塊121係將電洞注入層24用之塗布液塗布於陽極21上形成塗布層,對該塗布層進行乾燥、燒結而形成電洞注入層24。電洞注入層24用之塗布液包含有機材料及溶劑。有機材料可以是聚合物、單體之任一。單體之情況下,藉由燒結聚合而成為聚合物亦可。The hole injection
電洞注入層形成區塊121具備:塗布裝置121a;緩衝裝置121b;減壓乾燥裝置121c;熱處理裝置121d;及溫度調節裝置121e。塗布裝置121a係使電洞注入層24用之塗布液之液滴朝向堤岸30之開口部31吐出。緩衝裝置121b係將待處理之基板10暫時收納。減壓乾燥裝置121c係對經由塗布裝置121a塗布的塗布層進行減壓乾燥,將包含於塗布層的溶劑除去。熱處理裝置121d係對經由減壓乾燥裝置121c乾燥的塗布層進行加熱處理。溫度調節裝置121e係將經由熱處理裝置121d加熱處理的基板10之溫度調節成為規定之溫度例如常溫。The hole injection
塗布裝置121a、緩衝裝置121b、熱處理裝置121d及溫度調節裝置121e之內部被維持於大気氛圍。減壓乾燥裝置121c係將內部之氛圍切換為大氣氛圍與減壓氛圍。The inside of the
又,電洞注入層形成區塊121中,塗布裝置121a、緩衝裝置121b、減壓乾燥裝置121c、熱處理裝置121d及溫度調節裝置121e之配置或個數、內部之氛圍可以任意選擇。In addition, in the hole injection
又,電洞注入層形成區塊121具備:基板搬送裝置CR1~CR3;及交接裝置TR1~TR3。基板搬送裝置CR1~CR3分別將基板10搬送至鄰接的各裝置。例如,基板搬送裝置CR1係將基板10搬送至鄰接的塗布裝置121a及緩衝裝置121b。基板搬送裝置CR2係將基板10搬送至鄰接的減壓乾燥裝置121c。基板搬送裝置CR3係將基板10搬送至鄰接的熱處理裝置121d及溫度調節裝置121e。交接裝置TR1~TR3分別依序設置於搬入站110與基板搬送裝置CR1之間、基板搬送裝置CR1與基板搬送裝置CR2之間、基板搬送裝置CR2與基板搬送裝置CR3之間,在彼等間進行基板10之中繼。基板搬送裝置CR1~CR3或交接裝置TR1~TR3之內部被維持於大氣氛圍。In addition, the hole injection
在電洞注入層形成區塊121之基板搬送裝置CR3與電洞輸送層形成區塊122之基板搬送裝置CR4之間,設置有在彼等間進行基板10之中繼的交接裝置TR4。交接裝置TR4之內部被維持於大氣氛圍。Between the substrate transport device CR3 of the hole injection
電洞輸送層形成區塊122係將電洞輸送層25用之塗布液塗布於電洞注入層24上而形成塗布層,對該塗布層進行乾燥、燒結而形成電洞輸送層25。電洞輸送層25用之塗布液包含有機材料及溶劑。有機材料可以是聚合物、單體之任一。單體之情況下,藉由燒結聚合而形成聚合物亦可。The hole transport
電洞輸送層形成區塊122具備塗布裝置122a、緩衝裝置122b、減壓乾燥裝置122c、熱處理裝置122d、及溫度調節裝置122e。塗布裝置122a係使電洞輸送層25用之塗布液之液滴朝向堤岸30之開口部31吐出。緩衝裝置122b係將待處理之基板10暫時收納。減壓乾燥裝置122c係對經由塗布裝置122a塗布的塗布層進行減壓乾燥,將包含於塗布層的溶劑除去。熱處理裝置122d係對經由減壓乾燥裝置122c乾燥的塗布層進行加熱處理。溫度調節裝置122e係將經由熱處理裝置122d加熱處理的基板10之溫度調節成為規定之溫度例如常溫。The hole transport
塗布裝置122a及緩衝裝置122b之內部被維持於大氣氛圍。另一方面,熱處理裝置122d及溫度調節裝置122e,為了抑制電洞輸送層25之有機材料之劣化,其內部被維持於低氧而且低露點之氛圍。減壓乾燥裝置122c,其內部之氛圍在低氧而且低露點之氛圍與減壓氛圍進行切換。The inside of the
於此,低氧之氛圍係指氧濃度比大氣低的氛圍,例如氧濃度為10ppm以下之氛圍。又,低露點之氛圍係指露點溫度比大氣低的氛圍,例如露點溫度為-10℃以下之氛圍。低氧而且低露點之氛圍例如由氮氣體等之惰性氣體形成。Here, the low-oxygen atmosphere refers to an atmosphere with a lower oxygen concentration than the atmosphere, for example, an atmosphere with an oxygen concentration of 10 ppm or less. The low dew point atmosphere refers to an atmosphere with a dew point temperature lower than that of the atmosphere, for example, an atmosphere with a dew point temperature of -10°C or lower. An atmosphere with low oxygen and low dew point is formed by an inert gas such as nitrogen gas.
又,電洞輸送層形成區塊122中,塗布裝置122a、緩衝裝置122b、減壓乾燥裝置122c、熱處理裝置122d、及溫度調節裝置122e之配置或個數、內部之氛圍可以任意選擇。In the hole transport
又,電洞輸送層形成區塊122具備基板搬送裝置CR4~CR6及交接裝置TR5~TR6。基板搬送裝置CR4~CR6分別將基板10搬送至鄰接的各裝置。交接裝置TR5~TR6分別依序設置於基板搬送裝置CR4與基板搬送裝置CR5之間、及基板搬送裝置CR5與基板搬送裝置CR6之間,在彼等間進行基板10之中繼。In addition, the hole transport
基板搬送裝置CR4之內部被維持於大氣氛圍。另一方面,基板搬送裝置CR5~CR6之內部被維持於低氧而且低露點之氛圍。與基板搬送裝置CR5鄰接的減壓乾燥裝置122c之內部被切換於低氧而且低露點之氛圍與減壓氛圍之間。又,與基板搬送裝置CR6隣接的熱處理裝置122d或溫度調節裝置122e之內部被維持於低氧而且低露點之氛圍。The interior of the substrate transfer device CR4 is maintained in an atmospheric atmosphere. On the other hand, the interior of the substrate transfer devices CR5 to CR6 is maintained in an atmosphere of low oxygen and low dew point. The inside of the reduced-
交接裝置TR5係作為將其內部之氛圍切換於大氣氛圍與低氧而且低露點之氛圍之間的裝載鎖定(loadlock)裝置而構成。在交接裝置TR5之下游側隣接設置有減壓乾燥裝置122c。另一方面,交接裝置TR6之內部被維持於低氧而且低露點之氛圍。The transfer device TR5 is configured as a loadlock device that switches the internal atmosphere between the atmospheric atmosphere and the atmosphere of low oxygen and low dew point. A
在電洞輸送層形成區塊122之基板搬送裝置CR6與發光層形成區塊123之基板搬送裝置CR7之間,設置有在彼等間進行基板10之中繼的交接裝置TR7。基板搬送裝置CR6之內部被維持於低氧而且低露點之氛圍,基板搬送裝置CR7之內部被維持於大氣氛圍。因此交接裝置TR7作為將其內部之氛圍切換於低氧而且低露點之氛圍與大氣氛圍之間的裝載鎖定裝置而構成。Between the substrate transport device CR6 of the hole transport
發光層形成區塊123係將發光層26用之塗布液塗布於電洞輸送層25上而形成塗布層,對形成的塗布層進行乾燥、燒結而形成發光層26。發光層26用之塗布液包含有機材料及溶劑。有機材料可以是聚合物、單體之任一。單體之情況下,藉由燒結聚合而形成聚合物亦可。The light-emitting
發光層形成區塊123具備塗布裝置123a、緩衝裝置123b、減壓乾燥裝置123c、熱處理裝置123d及溫度調節裝置123e。塗布裝置123a係使發光層26用之塗布液之液滴朝向堤岸30之開口部31吐出。緩衝裝置123b係將待處理之基板10暫時收納。減壓乾燥裝置123c係對經由塗布裝置123a塗布的塗布層進行減壓乾燥,將包含於塗布層的溶劑除去。熱處理裝置123d係對經由減壓乾燥裝置123c乾燥的塗布層進行加熱處理。溫度調節裝置123e係將經由熱處理裝置123d加熱處理的基板10之溫度調節成為規定之溫度例如常溫。The light emitting
塗布裝置123a及緩衝裝置123b之內部被維持於大氣氛圍。另一方面,熱處理裝置123d及溫度調節裝置123e,為了抑制發光層26之有機材料之劣化,因此內部被維持於低氧而且低露點之氛圍。減壓乾燥裝置123c係將內部之氛圍切換於低氧而且低露點之氛圍與減壓氛圍。The inside of the
又,發光層形成區塊123中,塗布裝置123a、緩衝裝置123b、減壓乾燥裝置123c、熱處理裝置123d及溫度調節裝置123e之配置或個數、內部之氛圍可以任意選擇。In the light-emitting
又,發光層形成區塊123具備基板搬送裝置CR7~CR9與交接裝置TR8~TR9。基板搬送裝置CR7~CR9分別將基板10搬送至鄰接的各裝置。交接裝置TR8~TR9分別依序設置於基板搬送裝置CR7與基板搬送裝置CR8之間、基板搬送裝置CR8與基板搬送裝置CR9之間,在彼等間進行基板10之中繼。In addition, the light-emitting
基板搬送裝置CR7之內部被維持於大氣氛圍。另一方面,基板搬送裝置CR8~CR9之內部被維持於低氧而且低露點之氛圍。與基板搬送裝置CR8鄰接的減壓乾燥裝置123c之內部被切換於低氧而且低露點之氛圍與減壓氛圍之間。又,與基板搬送裝置CR9隣接的熱處理裝置123d或溫度調節裝置123e之內部被維持於低氧而且低露點之氛圍。The interior of the substrate transfer device CR7 is maintained in an atmospheric atmosphere. On the other hand, the interior of the substrate transfer devices CR8 to CR9 is maintained in an atmosphere of low oxygen and low dew point. The inside of the reduced-
交接裝置TR8作為將其內部之氛圍切換於大氣氛圍與低氧而且低露點之氛圍之間的裝載鎖定裝置而構成。在交接裝置TR8之下游側隣接設置有減壓乾燥裝置123c。交接裝置TR9之內部被維持於低氧而且低露點之氛圍。The transfer device TR8 is configured as a load lock device that switches the internal atmosphere between an atmospheric atmosphere and an atmosphere of low oxygen and low dew point. A
在發光層形成區塊123之基板搬送裝置CR9與搬出站130之間設置有在彼等間進行基板10之中繼的交接裝置TR10。基板搬送裝置CR9之內部被維持於低氧而且低露點之氛圍,搬出站130之內部被維持於大氣氛圍。因此交接裝置TR7作為將其內部之氛圍切換於低氧而且低露點之氛圍與大氣氛圍之間的裝載鎖定裝置而構成。A transfer device TR10 that relays the
搬出站130將複數片基板10依序收納於基板收納盒C,將基板收納盒C搬出外部。搬出站130具備:載置基板收納盒C的基板收納盒載置台131;設置於基板收納盒載置台131與處理站120之間的搬送路132;及設置於搬送路132的基板搬送體133。基板搬送體133係在處理站120與基板收納盒載置台131所載置的基板收納盒C之間進行基板10之搬送。The unloading
控制裝置140具備控制部141及記憶部142。控制裝置140例如包含具有CPU(Central Processing Unit)、ROM(Read Only Memory)、RAM(Random Access Memory)、HDD(Hard Disk Drive)、及輸出入埠等的電腦或各種之電路。The
電腦之CPU例如讀出記憶於ROM的程式並執行。據此,電腦之CPU作為控制部141而發揮功能。又,控制部141之一部分或全部由硬體構成亦可。硬體例如為ASIC(Application Specific Integrated Circuit)或FPGA(Field Programmable Gate Array)等。The CPU of the computer, for example, reads and executes programs stored in the ROM. Accordingly, the CPU of the computer functions as the
又,記憶部142例如與RAM或HDD對應。又,控制裝置140經由以有線或無線之網路連接的其他之電腦或可攜式記憶媒體取得上述程式或各種資訊亦可。作為電腦可讀取的記憶媒體例如有硬碟(HD)、軟碟(FD)、光碟(CD)、光磁碟(MO)、記憶卡等。Moreover, the
接著,對使用基板處理系統100的基板處理方法進行說明。收納有複數片基板10的基板收納盒C被載置於基板收納盒載置台111上時,基板搬送體113從基板收納盒載置台111上之基板收納盒C依序取出基板10,搬送至電洞注入層形成區塊121。Next, a substrate processing method using the
電洞注入層形成區塊121係將電洞注入層24用之塗布液塗布於陽極21上形成塗布層,對形成的塗布層進行乾燥、燒結而形成電洞注入層24。形成有電洞注入層24的基板10係經由交接裝置TR4從電洞注入層形成區塊121被交接至電洞輸送層形成區塊122。The hole injection
電洞輸送層形成區塊122係將電洞輸送層25用之塗布液塗布於電洞注入層24上而形成塗布層,對形成的塗布層進行乾燥、燒結而形成電洞輸送層25。形成有電洞輸送層25的基板10係藉由交接裝置TR7從電洞輸送層形成區塊122被交接至發光層形成區塊123。The hole transport
發光層形成區塊123係將發光層26用之塗布液塗布於電洞輸送層25上而形成塗布層,對形成的塗布層進行乾燥、燒結而形成發光層26。形成有發光層26的基板10係藉由交接裝置TR10從發光層形成區塊123被交接至搬出站130。The light-emitting
搬出站130之基板搬送體133,係將從交接裝置TR10受取的基板10收納於基板收納盒載置台131上之規定之基板收納盒C。據此,基板處理系統100中的一連串之基板10之處理結束。The
基板10被收納於基板收納盒C之狀態下,從搬出站130搬出至外部。對搬出至外部的基板10形成電子輸送層27或電子注入層28、陰極22等。In a state where the
<塗布裝置及塗布方法>
接著,參照圖8及圖9說明發光層形成區塊123之塗布裝置123a。圖8係表示實施形態之塗布裝置123a之構成之模式平面圖。又,圖9係表示實施形態之塗布裝置123a之構成之模式側面圖。<Coating device and coating method>
Next, the
圖8及圖9中,Y軸方向為吐出同一塗布液之液滴的複數個噴嘴並列的行方向,X軸方向為與Y軸方向正交的掃描方向。又,行方向與掃描方向只要交叉即可,不一定要正交。In FIGS. 8 and 9, the Y-axis direction is a row direction in which a plurality of nozzles ejecting droplets of the same coating liquid are aligned, and the X-axis direction is a scanning direction orthogonal to the Y-axis direction. In addition, the row direction and the scanning direction only need to cross, and need not be orthogonal.
如圖8及圖9所示,塗布裝置123a例如具備:對基板10進行保持並移動的站台150;向基板10吐出液滴的吐出單元160;及維持吐出單元160之功能的保養單元170。As shown in FIGS. 8 and 9, the
站台150與保養單元170並列設置於Y軸方向。在站台150之上方與保養單元170之上方之間架設有Y軸導引部180。吐出單元160設為沿著Y軸導引部180在Y軸方向移動自如。作為使吐出單元160在Y軸方向移動的驅動部可以使用線性馬達等。The
站台150具備將基板10以水平方式進行保持的基板保持部151,及使基板保持部151移動的移動機構152。基板保持部151係使塗布基板10之液滴的塗布面向上而對基板10進行保持。作為基板保持部151例如真空吸盤,但亦可以使用靜電吸盤等。移動機構152具備:使基板保持部151朝X軸方向移動的X軸方向驅動部153,使基板保持部151朝Y軸方向移動的Y軸方向驅動部154,及使基板保持部151繞Z軸旋轉的旋轉驅動部155等。The
吐出單元160係於在站台150之上方向基板10吐出液滴的位置,與接受基於保養單元170之功能維持之處理的位置之間移動自如。吐出單元160在Y軸方向配置有複數個(於此為10個)。複數個吐出單元160,獨立沿著Y軸方向移動亦可,一體沿著Y軸方向移動亦可。The
各吐出單元160具備運輸部161,及設置於運輸部161之下面的複數個噴頭162。於各噴頭162設置有至少1列由沿著Y軸方向並列的複數個噴嘴163構成的噴嘴列。設置於同一噴頭162的複數個噴嘴163吐出同一塗布液之液滴。吐出紅色發光層26R用之塗布液之液滴的噴嘴163,與吐出綠色發光層26G用之塗布液之液滴的噴嘴163,與吐出藍色發光層26B用之塗布液之液滴的噴嘴163係設置於個別之噴頭162。Each
保養單元170進行維持吐出單元160之功能的處理,消除吐出單元160之吐出不良。保養單元170具備對噴嘴之吐出口之周圍進行擦拭的擦拭單元171;及從噴嘴之吐出口吸引液滴的吸引單元172。吸引單元172亦達成塞住休止狀態之噴嘴之吐出口,抑制乾燥引起的堵塞任務。The
接著,說明使用上述構成之塗布裝置123a的塗布方法。塗布裝置123a之以下之動作係藉由控制裝置140控制。又,圖7中,控制裝置140,係和塗布裝置123a係分別設置,但亦可以作為塗布裝置123a之一部分而設置。Next, a coating method using the
首先,從塗布裝置123a之外部搬入內部的基板10被載置於基板保持部151時,基板保持部151將基板10保持。接著,依據對基板10之對準標記攝影的圖像,進行基於移動機構152的基板保持部151之位置補正。之後,移動機構152使基板保持部151朝X軸方向移動,通過吐出單元160之下。於該期間,吐出單元160向基板10吐出塗布液之液滴。之後,移動機構152變更基板保持部151之Y軸方向之位置,使基板保持部151再度朝X軸方向移動,通過吐出單元160之下。於該期間,吐出單元160向基板10吐出塗布液之液滴。藉由重複進行上述,塗布裝置123a在基板10上描繪規定之圖案。First, when the
已描畫結束的基板10從基板保持部151被取出,從塗布裝置123a之內部搬出至外部。接著,次一基板10從塗布裝置123a之外部被搬入內部,塗布裝置123a在基板10上描繪規定之圖案。又,藉由保養單元170維持吐出單元160之功能的處理,基板10之更換之空檔等適當進行。The drawn
又,塗布裝置123a使向基板10吐出液滴的吐出單元160移動亦可,使基板保持部151及吐出單元160之兩方移動亦可。亦即,塗布裝置123a只要使基板保持部151與吐出單元160可以相對地移動即可。In addition, the
<塗布裝置描繪的描畫圖案>
接著,參照圖10說明塗布裝置123a描繪的描畫圖案。圖10係表示實施形態之塗布裝置123a描繪的描畫圖案之平面圖。<Drawing pattern drawn by the coating device>
Next, the drawing pattern drawn by the
如圖10所示,有機EL顯示器1按每一個像素例如具有紅色發光區域261R、綠色發光區域261G、及藍色發光區域261B。As shown in FIG. 10, the
紅色發光區域261R相當於具有紅色發光層26R的有機EL層23中的被陽極21與陰極22夾持的區域。綠色發光區域261G相當於具有綠色發光層26G的有機EL層23中的被陽極21與陰極22夾持的區域。藍色發光區域261B相當於具有藍色發光層26B的有機EL層23中的被陽極21與陰極22夾持的區域。各發光區域261R、261G、261B按每一陽極21獨立發光,其發光量藉由陽極21與陰極22之間之電壓進行調整。The red
紅色發光區域261R、綠色發光區域261G及藍色發光區域261B係沿著X軸方向依據該順序隔開間隔重複進行配列,據此,而形成發光區域群262。於有機EL顯示器1,使複數個發光區域群262沿著Y軸方向隔開間隔進行配列。因此,於有機EL顯示器1,在Y軸方向並列有發出同一色的複數個發光區域。The red light-emitting
以朝向在Y軸方向隔開間隔而且發出同一色之光的複數個發光區域可以同時且吐出同一塗布液之液滴的方式,使複數個噴嘴163沿著Y軸方向並列設置在吐出單元160之各噴頭162。設置於同一噴頭162的複數個噴嘴163係吐出同一塗布液之液滴。A plurality of
塗布裝置123a吐出單元160與基板保持部151朝X軸方向相對地移動,從噴嘴163朝向基板保持部151所保持的基板10上事先形成的堤岸30之開口部31塗布液滴。The
如圖10所示,堤岸30之開口部31跨越在Y軸方向相鄰的2個發光區域。因此,可以緩和Y軸方向中的塗布液之液滴之著陸位置之容許誤差。As shown in FIG. 10, the
又,從2個噴嘴163朝向1個開口部31吐出塗布液之液滴,因此各噴嘴163之吐出量之誤差被分散,可以抑制吐出量之總量之偏差。又,朝向1個開口部31吐出液滴的噴嘴163之選擇範圍增加,吐出量之控制性良好的噴嘴163可以被選擇使用。據此,發光層26之厚度可以均勻化。In addition, since the droplets of the coating liquid are discharged from the two
<第1變形例的描畫圖案> 接著,對本實施形態中的第1變形例的描畫圖案參照圖11進行說明。圖11係表示實施形態中的第1變形例的描畫圖案之平面圖。<Drawing pattern of the first modification> Next, the drawing pattern of the first modification in this embodiment will be described with reference to FIG. 11. Fig. 11 is a plan view showing a drawing pattern in a first modification of the embodiment.
紅色發光區域261R、綠色發光區域261G及藍色發光區域261B之面積比依據個別之發光特性或發光壽命等適當設定。例如發光效率良好,每一單位面積之發光亮度越高者,具有越小面積。The area ratio of the red light-emitting
圖11中,紅色發光區域261R之面積最小,綠色發光區域261G之面積第2小,藍色發光區域261B之面積最大。彼等發光區域261R、261G、261B之Y軸方向之尺寸YR、YG、YB相同,X軸方向之尺寸XR、XG、XB分別不同。具體言之,紅色發光區域261R之Y軸方向之尺寸YR、綠色發光區域261G之Y軸方向之尺寸YG及藍色發光區域261B之Y軸方向之尺寸YB相同。又,紅色發光區域261R之X軸方向之尺寸XR較綠色發光區域261G之X軸方向之尺寸XG為小,綠色發光區域261G之X軸方向之尺寸XG較藍色發光區域261B之X軸方向之尺寸XB為小。In FIG. 11, the area of the red
第1變形例中,沿著X軸方向以使2個紅色發光區域261R相鄰的方式配列有複數個紅色發光區域261R、綠色發光區域261G及藍色發光區域261B。具體言之,綠色發光區域261G、藍色發光區域261B、紅色發光區域261R、紅色發光區域261R、綠色發光區域261G、藍色發光區域261B依序重複進行配列而形成1個發光區域群262。換言之,在X軸方向相鄰的2個像素中,紅色發光區域261R、綠色發光區域261G及藍色發光區域261B之配列順序反轉。In the first modification, a plurality of red light-emitting
第1變形例中,堤岸30之開口部31,係和上述實施形態同樣地,使與在Y軸方向相鄰的2個同色之副像素對應而設置的2個陽極21露出。據此,可以緩和Y軸方向中的塗布液之液滴之著陸位置之容許誤差。In the first modification, the
還有,第1變形例中,堤岸30之開口部31係使與在X軸方向相鄰的2個同色之副像素對應而設置的2個陽極21露出。於此,使與在X軸方向相鄰的2個紅色發光區域261R對應的2個陽極21露出。據此,一邊使吐出單元160與基板保持部151沿著X軸方向相對地移動,一邊使液滴著陸於紅色用開口部31R變為容易。因此,可以緩和X軸方向中的紅色發光區域261R用之塗布液之液滴之著陸位置之容許誤差。又,藉由將X軸方向之尺寸最小的紅色發光區域261R在X軸方向連結,可以有效緩和X軸方向中的塗布液之液滴之著陸位置之容許誤差。In the first modification, the
如此般,第1變形例中,堤岸30之開口部31係使與Y軸方向及X軸方向相鄰的4個同色(於此為紅色)之副像素對應而設置的4個陽極21露出。據此,可以緩和Y軸方向及X軸方向中的塗布液之液滴之著陸位置之容許誤差。又,藉由將面積最小的紅色發光區域261R在Y軸方向及X軸方向連結,可以有效緩和Y軸方向及X軸方向中的塗布液之液滴之著陸位置之容許誤差。In this way, in the first modification, the
第1變形例中,於有機EL顯示器1,係和上述實施形態同樣地,對1個開口部31形成1個接觸孔50。因此,第1變形例的有機EL顯示器1中,對4個紅色發光區域261R形成1個接觸孔50。又,第1變形例的有機EL顯示器1中,對2個綠色發光區域261G形成1個接觸孔50,對2個藍色發光區域261B形成1個接觸孔50。In the first modification, in the
於此,示出1個開口部31使與X軸方向相鄰的2個同色之副像素對應而設置的2個陽極21露出的情況之例。但不限定於此,開口部31使與X軸方向相鄰的3個以上之同色之副像素對應而設置的2個陽極21露出亦可。Here, an example is shown in which one
又,於此,示出1個開口部31使與Y軸方向及X軸方向相鄰的4個紅色發光區域261R對應而設置的4個陽極21露出的情況之例。但不限定於此,開口部31使與Y軸方向及X軸方向相鄰的4個綠色發光區域261G對應而設置的4個陽極21露出亦可。該情況下,發光區域群262例如使紅色發光區域261R、藍色發光區域261B、綠色發光區域261G、綠色發光區域261G、藍色發光區域261B、紅色發光區域261R依序重複進行配列而形成亦可。Here, an example is shown in which one
同樣地,開口部31使與Y軸方向及X軸方向相鄰的4個藍色發光區域261B對應而設置的4個陽極21露出亦可。該情況下,發光區域群262例如和圖11同樣,使綠色發光區域261G、藍色發光區域261B、紅色發光區域261R、紅色發光區域261R、綠色發光區域261G、藍色發光區域261B依序重複進行配列而形成亦可。Similarly, the
又,第1變形例中,在Y軸方向及X軸方向之兩方向將發光區域連結,但開口部31為僅在X軸方向將發光區域連結者亦可。亦即,開口部31為僅使與X軸方向相鄰的2個同色之副像素對應而設置的2個陽極21露出者亦可。Furthermore, in the first modification, the light-emitting regions are connected in both the Y-axis direction and the X-axis direction, but the
<第2變形例的描畫圖案>
圖12係表示實施形態中的第2變形例的描畫圖案之平面圖。如圖12所示,第2變形例的有機EL顯示器1,具有使與在Y軸方向相鄰的複數個同色之副像素對應而設置的複數個陽極21露出的開口部31。例如第2變形例的開口部31,係使並列於Y軸方向之全部之陽極21之各一部分露出。換言之,第2變形例的開口部31,係跨越Y軸方向之複數個陽極21之中之位於最靠近Y軸正方向側的陽極21至最靠近Y軸方向負方向側的陽極21而形成。<Drawing pattern of the second modification>
12 is a plan view showing a drawing pattern of a second modification in the embodiment. As shown in FIG. 12, the
第2變形例中,接觸孔50係形成於在X軸方向相鄰的2個開口部31之間之區域。如第2變形例這樣,開口部31在Y軸方向長的情況下,若在Y軸方向與開口部31相鄰的位置形成接觸孔50時,對有機EL顯示器1形成足夠數之接觸孔50會有困難。In the second modification, the
於此,第2變形例中,將接觸孔50形成於在X軸方向相鄰的2個開口部31之間之區域。據此,即使在Y軸方向較長的開口部31被形成於有機EL顯示器1之情況下,亦可以將最適宜之數之接觸孔50形成於有機EL顯示器1。Here, in the second modification, the
於此,X軸方向相鄰的2個開口部31之間之區域,在確保形成接觸孔50必要的X軸方向之尺寸上會有困難之情況。Here, in the area between the two
於此,如圖12所示,在X軸方向相鄰的2個開口部31之間之區域之中,僅使形成接觸孔50之區域局部性朝X軸方向擴大亦可。換言之,開口部31中,與接觸孔50相鄰的部分中的X軸方向之尺寸XR1、XG1、XB1形成為比其他部分中的X軸方向之尺寸XR2、XG2、XB2窄亦可。據此,在不增大X軸方向中的開口部31彼此之間隔之情況下可以確保形成接觸孔50之空間。Here, as shown in FIG. 12, in the region between the two
如第2變形例這樣使形成接觸孔50之區域朝X軸方向擴大之情況下,較好是使與接觸孔50相鄰的部分中的開口部31之X軸方向之尺寸XR1、XG1、XB1形成為比噴嘴163之吐出口之口徑大。藉由這樣的形成,可以抑制從噴嘴163吐出的塗布液之液滴溢出開口部31而進入接觸孔50。When the area where the
於此,示出按同色之2個副像素形成1個接觸孔50之情況之例。但不限定於此,接觸孔50按同色之每3個以上之副像素形成亦可。Here, an example is shown in which one
<第3變形例的描畫圖案>
圖13係表示實施形態中的第3變形例的描畫圖案之平面圖。第3變形例中,接觸孔50按相鄰的每複數個不同色之副像素設置亦可。例如圖13所示有機EL顯示器1中,接觸孔50按構成1個像素的每3個副像素亦即紅色之副像素、綠色之副像素及藍色之副像素設置。換言之,接觸孔50按1像素設置1個。<Drawing pattern of the third modification>
13 is a plan view showing a drawing pattern in a third modification of the embodiment. In the third modification, the contact holes 50 may be provided for each adjacent plurality of sub-pixels of different colors. For example, in the
於此,綠色發光區域261G之開口部31與藍色發光區域261B之開口部31之間隔,形成為比紅色發光區域261R之開口部31與綠色發光區域261G之開口部31之間隔大。因此,將接觸孔50形成於綠色發光區域261G之開口部31與藍色發光區域261B之開口部31之間之區域為較佳。又,但不限定於此,接觸孔50例如形成於Y軸方向相鄰的2個像素之間之區域亦可,形成於X軸方向相鄰的2個像素之間之區域亦可。又,接觸孔50按相鄰的每複數個像素設置亦可。Here, the distance between the opening 31 of the green
又,接觸孔50不限定於像素單位(紅色、藍色及綠色之每3個副像素),按相鄰的不同色之每2個副像素設置亦可,按包含不同色的相鄰的每4個副像素設置亦可。相鄰的方向不限定於上下左右,斜向亦可。又,接觸孔50按不相鄰的每2個以上之副像素設置亦可。如此般,接觸孔50按複數個任意之副像素單位設置亦可。In addition, the
於此,以未形成像素連結的有機EL顯示器1為例進行說明,但有機EL顯示器1,例如圖10、圖12所示,具有跨越Y軸方向相鄰的複數個同色之發光區域的開口部31亦可。Here, the
如上述說明,實施形態之塗布裝置123a具備基板保持部151、吐出單元160及移動機構152。基板保持部151將基板10進行保持。吐出單元160包含複數個噴頭162,該噴頭162在第1方向(一例為Y軸方向)並列設置有複數個噴嘴163。移動機構152使吐出單元160與基板保持部151相對地沿著與第1方向交叉的第2方向(一例為X軸方向)移動。基板10具備:與複數個副像素對應而設置的複數個像素電極(一例為陽極21);堤岸30,覆蓋複數個像素電極,並且形成有使至少1個像素電極露出的複數個開口部31;及複數個接觸孔50,用以將與複數個像素電極對向的對向電極電連接於補助電極51。接觸孔50按每2個以上之副像素設置。吐出單元160從噴嘴163朝向基板保持部151所保持的基板10之開口部31吐出有機材料之液滴。As described above, the
因此,依據實施形態之塗布裝置123a,可以提供補助電極51用之接觸孔50之數目被最佳化的有機EL顯示器1。Therefore, according to the
開口部31使與相鄰的2個以上之同色之副像素對應而設置的2個以上之像素電極露出亦可。該情況下,接觸孔50按由開口部31露出的2個以上之像素電極所對應的每2個以上之同色之副像素設置亦可。The
使供作為有機材料之液滴著陸的開口部31,不按每一副像素,而按相鄰的每2個同色之副像素形成,據此,可以緩和液滴之著陸位置之容許誤差。又,按由開口部31露出的2個以上之像素電極所對應的每2個以上之同色之副像素設置接觸孔50,據此而進行像素連結,則接觸孔50不會進行障礙。The
開口部31使與在第1方向相鄰的2個以上之同色副像素對應而設置的2個以上之像素電極露出亦可。據此,可以緩和第1方向中的有機材料之液滴之著陸位置之容許誤差。The
開口部31使與在第2方向相鄰的2個同色之副像素對應而設置的2個像素電極露出亦可。據此,可以緩和第2方向中的有機材料之液滴之著陸位置之容許誤差。The
開口部31使與在第1方向及第2方向相鄰的4個以上之同色之副像素對應而設置的4個以上之像素電極露出亦可。據此,可以緩和第1方向及第2方向中的有機材料之液滴之著陸位置之容許誤差。The
接觸孔50形成於在第1方向相鄰的2個開口部31之間之區域亦可。據此,進行像素連結且接觸孔50不會成為障礙。The
接觸孔50形成於在第2方向相鄰的2個開口部31之間之區域亦可。即使將Y軸方向長的開口部31形成於有機EL顯示器1之情況下,亦可以將最適當數量之接觸孔50形成於有機EL顯示器1。The
開口部31中,與接觸孔50相鄰的部分中的第2方向之尺寸形成為較其他部分中的第2方向之尺寸窄亦可。據此,可以不必擴大第2方向中的開口部31彼此之間隔,而可以確保形成接觸孔50之空間。In the
此次揭示的實施形態全部僅為例示,並非用來限定者。實際上,上述實施形態可以多樣之形態具體實現。又,上述實施形態在不脫離申請專利範圍及其趣旨之範圍內,可以各樣的形態進行省略、置換、變更。The embodiments disclosed this time are only examples and are not intended to be limiting. In fact, the above-mentioned embodiments can be realized in various forms. In addition, the above-mentioned embodiment can be omitted, replaced, or changed in various forms without departing from the scope of the patent application and its purport.
例如發光色之組合不限定於紅色、綠色、藍色之3原色。發光色之組合,除紅色、綠色及藍色之3原色以外,還可以使用紅色與綠色之中間色亦即黄色及綠色與藍色之中間色亦即青色(cyan)之至少1種。For example, the combination of luminescent colors is not limited to the three primary colors of red, green, and blue. In addition to the three primary colors of red, green, and blue, at least one of the intermediate colors of red and green, that is, yellow, and the intermediate color of green and blue, that is, cyan, can be used in addition to the three primary colors of luminescent colors.
上述實施形態及各變形例中,係以從基板10側取出來自發光層26之光的底部發光方式(bottom emission)之有機EL顯示器1為例。但不限定於此,有機EL顯示器1,亦可以是從基板10之相反側取出來自發光層26之光的頂部發光方式(top emission)。In the above-mentioned embodiment and each modification, the bottom emission type
頂部發光方式之情況下,基板10未必一定要透明基板。又,頂部發光方式之情況下,透明電極之陽極21作為對向電極使用,陰極22作為按每一單位電路11設置的像素電極使用。該情況下,陽極21與陰極22之配置相反,因此於陰極22上依序形成電子注入層28、電子輸送層27、發光層26、電洞輸送層25及電洞注入層24。In the case of the top emission method, the
上述實施形態及各變形例中,說明有機EL層23具有電洞注入層24、電洞輸送層25、發光層26、電子輸送層27及電子注入層28的情況之例,但有機EL層23只要至少具有發光層26即可。In the above-described embodiment and each modification, an example in which the
1‧‧‧有機EL顯示器
10‧‧‧基板
13‧‧‧有機發光二極體
21‧‧‧陽極
22‧‧‧陰極
23‧‧‧有機EL層
26‧‧‧發光層
30‧‧‧堤岸
31‧‧‧開口部
50‧‧‧接觸孔
51‧‧‧補助電極
100‧‧‧基板處理系統
123a‧‧‧塗布裝置
151‧‧‧基板保持部
152‧‧‧移動機構
160‧‧‧吐出單元
162‧‧‧噴頭
163‧‧‧噴嘴
261R‧‧‧紅色發光區域
261G‧‧‧綠色發光區域
261B‧‧‧藍色發光區域1‧‧‧
[圖1]圖1係表示補助電極用之接觸孔按每一副像素形成的有機EL顯示器之構成例之模式平面圖。 [圖2]圖2係表示實施形態之有機EL顯示器之電路構成之一例之圖。 [圖3]圖3係表示實施形態之有機EL顯示器之模式平面圖。 [圖4]圖4係圖3中的IV-IV線剖面圖。 [圖5]圖5係圖3中的V-V線剖面圖。 [圖6]圖6係表示實施形態之有機發光二極體之製造方法之流程圖。 [圖7]圖7係表示實施形態之基板處理系統之構成之模式平面圖。 [圖8]圖8係表示實施形態之塗布裝置之構成之模式平面圖。 [圖9]圖9係表示實施形態之塗布裝置之構成之模式側面圖。 [圖10]圖10係表示實施形態之塗布裝置描繪的描畫圖案之平面圖。 [圖11]圖11係表示實施形態中的第1變形例的描畫圖案之平面圖。 [圖12]圖12係表示實施形態中的第2變形例的描畫圖案之平面圖。 [圖13]圖13係表示實施形態中的第3變形例的描畫圖案之平面圖。[FIG. 1] FIG. 1 is a schematic plan view showing a configuration example of an organic EL display in which contact holes for auxiliary electrodes are formed for each sub-pixel. [FIG. 2] FIG. 2 is a diagram showing an example of a circuit configuration of an organic EL display of an embodiment. [Fig. 3] Fig. 3 is a schematic plan view showing an organic EL display of an embodiment. [Fig. 4] Fig. 4 is a sectional view taken along the line IV-IV in Fig. 3. [Fig. [Fig. 5] Fig. 5 is a sectional view taken along the line V-V in Fig. 3. [Fig. [Fig. 6] Fig. 6 is a flowchart showing a method of manufacturing an organic light-emitting diode according to an embodiment. [Fig. 7] Fig. 7 is a schematic plan view showing the configuration of the substrate processing system of the embodiment. [FIG. 8] FIG. 8 is a schematic plan view showing the configuration of the coating apparatus of the embodiment. [Fig. 9] Fig. 9 is a schematic side view showing the configuration of the coating apparatus of the embodiment. [Fig. 10] Fig. 10 is a plan view showing a drawing pattern drawn by the coating apparatus of the embodiment. [Fig. 11] Fig. 11 is a plan view showing a drawing pattern of a first modification in the embodiment. [Fig. 12] Fig. 12 is a plan view showing a drawing pattern of a second modification in the embodiment. [Fig. 13] Fig. 13 is a plan view showing a drawing pattern of a third modification in the embodiment.
1‧‧‧有機EL顯示器 1‧‧‧ organic EL display
21‧‧‧陽極 21‧‧‧Anode
30‧‧‧堤岸 30‧‧‧Embankment
31‧‧‧開口部 31‧‧‧Opening
50‧‧‧接觸孔 50‧‧‧Contact hole
261R‧‧‧紅色發光區域 261R‧‧‧Red light emitting area
261G‧‧‧綠色發光區域 261G‧‧‧Green light emitting area
261B‧‧‧藍色發光區域 261B‧‧‧Blue light emitting area
262‧‧‧發光區域群 262‧‧‧Glowing area group
Claims (13)
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JP2018088890A JP2019194960A (en) | 2018-05-02 | 2018-05-02 | Coating device, coating method and organic el display |
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JP2004006313A (en) * | 2002-04-18 | 2004-01-08 | Seiko Epson Corp | Manufacturing method of electro-optical device, electro-optical device, and electronic apparatus |
US7221095B2 (en) | 2003-06-16 | 2007-05-22 | Semiconductor Energy Laboratory Co., Ltd. | Light emitting device and method for fabricating light emitting device |
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JP2010267416A (en) * | 2009-05-12 | 2010-11-25 | Panasonic Corp | Organic electroluminescent display device, method of manufacturing the same, and deposition method |
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