TW202004949A - Coating apparatus, coating method and organic EL display in which the number of contact holes for auxiliary electrodes is optimized - Google Patents

Coating apparatus, coating method and organic EL display in which the number of contact holes for auxiliary electrodes is optimized Download PDF

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TW202004949A
TW202004949A TW108113699A TW108113699A TW202004949A TW 202004949 A TW202004949 A TW 202004949A TW 108113699 A TW108113699 A TW 108113699A TW 108113699 A TW108113699 A TW 108113699A TW 202004949 A TW202004949 A TW 202004949A
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substrate
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pixels
pixel electrodes
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篠木武虎
林輝幸
大島澄美
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日商東京威力科創股份有限公司
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10Deposition of organic active material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J2/00Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
    • B41J2/005Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by bringing liquid or particles selectively into contact with a printing material
    • B41J2/01Ink jet
    • B41J2/21Ink jet for multi-colour printing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41JTYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J3/00Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed
    • B41J3/407Typewriters or selective printing or marking mechanisms characterised by the purpose for which they are constructed for marking on special material
    • B41J3/4073Printing on three-dimensional objects not being in sheet or web form, e.g. spherical or cubic objects
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02612Formation types
    • H01L21/02617Deposition types
    • H01L21/02631Physical deposition at reduced pressure, e.g. MBE, sputtering, evaporation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67017Apparatus for fluid treatment
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • H10K59/122Pixel-defining structures or layers, e.g. banks
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • H10K59/123Connection of the pixel electrodes to the thin film transistors [TFT]
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/10OLED displays
    • H10K59/12Active-matrix OLED [AMOLED] displays
    • H10K59/131Interconnections, e.g. wiring lines or terminals
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • H10K59/30Devices specially adapted for multicolour light emission
    • H10K59/35Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels
    • H10K59/353Devices specially adapted for multicolour light emission comprising red-green-blue [RGB] subpixels characterised by the geometrical arrangement of the RGB subpixels
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass
    • H10K71/10Deposition of organic active material
    • H10K71/12Deposition of organic active material using liquid deposition, e.g. spin coating
    • H10K71/13Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing
    • H10K71/135Deposition of organic active material using liquid deposition, e.g. spin coating using printing techniques, e.g. ink-jet printing or screen printing using ink-jet printing

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Abstract

This invention provides an organic EL display in which the number of contact holes for auxiliary electrodes is optimized. The coating apparatus according to one embodiment of this invention comprises a substrate holding part, a discharge unit, and a moving mechanism. The discharge unit includes a plurality of nozzle?heads with a plurality of nozzles arranged in parallel in a first direction. The moving mechanism relatively moves the discharge unit and the substrate holding part along the second direction intersecting the first direction. The substrate includes a plurality of pixel electrodes disposed corresponding to the plurality of sub-pixels, a bank covering the plurality of pixel electrodes and having a plurality of openings for exposing at least one pixel electrode, and a plurality of contact holes for electrically connecting the counter electrodes opposed to the plurality of pixel electrodes to the auxiliary electrode. The contact hole is set for every two or more sub-pixels. The discharge unit discharges the droplet of an organic material from the nozzle toward the opening of the substrate held in the substrate holding part.

Description

塗布裝置、塗布方法及有機EL顯示器Coating device, coating method and organic EL display

本開示關於塗布裝置、塗布方法及有機EL顯示器。This publication discloses a coating device, a coating method, and an organic EL display.

使用有機発光二極體(OLED:Organic Light Emitting Diode)的有機EL顯示器,薄型輕量而且低消費電力,在響應速度或視角、對比度之面具有極佳優點。有機発光二極體,係藉由像素電極與對向電極夾持包含發光層的有機EL層而構成。Organic EL displays using organic light emitting diodes (OLED: Organic Light Emitting Diode) are thin, lightweight and have low power consumption. They have excellent advantages in response speed, viewing angle and contrast. The organic photodiode is composed of a pixel electrode and a counter electrode sandwiching an organic EL layer including a light-emitting layer.

專利文獻1揭示藉由將低電阻率之材料所形成的補助電極連接於對向電極,來抑制伴隨有機EL顯示器之大畫面化的配線電阻之增加的技術。 [先前技術文獻] [專利文獻]Patent Document 1 discloses a technique for suppressing an increase in wiring resistance accompanying the enlargement of an organic EL display by connecting an auxiliary electrode formed of a low-resistivity material to a counter electrode. [Prior Technical Literature] [Patent Literature]

[專利文獻1]特開2016-197240號公報[Patent Document 1] JP 2016-197240

[發明所欲解決之課題][Problems to be solved by the invention]

本開示提供補助電極用之接觸孔之數目為最佳化的有機EL顯示器。 [解決課題之手段]This disclosure provides an organic EL display in which the number of contact holes for auxiliary electrodes is optimized. [Means to solve the problem]

本開示之一態樣的塗布裝置,係具備:基板保持部;吐出單元;及移動機構。基板保持部係將基板保持。吐出單元包含在第1方向並列設置有複數個噴嘴的複數個噴頭噴頭。移動機構係使吐出單元與基板保持部沿著與第1方向交叉的第2方向相對地移動。基板具備:複數個像素電極,與複數個副像素對應而設置;堤岸(bank),覆蓋複數個像素電極,並且形成有使至少1個像素電極露出的複數個開口部;及複數個接觸孔,用以將與複數個像素電極對向的對向電極電連接於補助電極。接觸孔係按每2個以上之副像素設置。吐出單元係從噴嘴朝向基板保持部所保持的基板之開口部吐出有機材料之液滴。 [發明效果]The coating device according to one aspect of the present disclosure includes: a substrate holding portion; a discharge unit; and a moving mechanism. The substrate holding portion holds the substrate. The discharge unit includes a plurality of nozzle heads in which a plurality of nozzles are arranged in parallel in the first direction. The moving mechanism relatively moves the discharge unit and the substrate holding portion in the second direction crossing the first direction. The substrate includes: a plurality of pixel electrodes corresponding to the plurality of sub-pixels; a bank covering the plurality of pixel electrodes and forming a plurality of openings exposing at least one pixel electrode; and a plurality of contact holes, It is used to electrically connect the counter electrode facing the plurality of pixel electrodes to the auxiliary electrode. The contact holes are set for every two or more sub-pixels. The discharge unit discharges droplets of organic material from the nozzle toward the opening of the substrate held by the substrate holding portion. [Effect of the invention]

依據本開示,可以提供使補助電極用之接觸孔之數目成為最佳化的有機EL顯示器。According to this disclosure, it is possible to provide an organic EL display that optimizes the number of contact holes for auxiliary electrodes.

以下,參照圖面詳細說明實施本揭示之塗布裝置、塗布方法及有機EL顯示器之形態(以下,標記為「實施形態」)。又,該實施形態並非用來限定本揭示之塗布裝置、塗布方法及有機EL顯示器。又,各實施形態,在處理內容不矛盾之範圍內可以適當組合。又,以下各實施形態中同一之部位被附加同一之符號,並省略重複之說明。Hereinafter, referring to the drawings, the coating device, the coating method, and the form of the organic EL display (hereinafter, referred to as "embodiment") for implementing the present disclosure will be described in detail. In addition, this embodiment is not intended to limit the coating device, coating method, and organic EL display of the present disclosure. In addition, each embodiment can be combined as appropriate within a range where the processing contents are not contradictory. In addition, in the following embodiments, the same parts are denoted by the same symbols, and repeated explanations are omitted.

又,以下參照的各圖面中,為了容易理解說明,而有表示對相互正交的X軸方向、Y軸方向及Z軸方向進行規定,將Z軸正方向設為鉛直向上方向的正交座標系之情況。In addition, in the drawings referred to below, for easy understanding of the description, it is defined that the mutually orthogonal X-axis direction, Y-axis direction, and Z-axis direction are defined, and the positive Z-axis direction is orthogonal to the vertical upward direction The situation of the coordinate system.

使用有機發光二極體的有機EL顯示器,薄型輕量而且低消費電力,在響應速度或視角、對比度之面上具有極佳優點。因此,近年來,有機EL顯示器作為次世代之平板顯示器(FPD)受到注目。Organic EL displays using organic light-emitting diodes are thin, lightweight and have low power consumption. They have excellent advantages in response speed, viewing angle, and contrast. Therefore, in recent years, organic EL displays have attracted attention as the next-generation flat panel displays (FPD).

有機發光二極體,係藉由像素電極與對向電極夾持包含發光層的有機EL層而構成,有機EL層之形成係使用噴墨方式之塗布裝置。The organic light-emitting diode is composed of a pixel electrode and a counter electrode sandwiching an organic EL layer including a light-emitting layer. The organic EL layer is formed using an inkjet coating device.

近年來,伴隨有機EL顯示器之大畫面化,配線長度有變長之趨勢。若配線長度變長則配線電阻增加,據此,例如對位於遠離電源的位置之像素電極供給發光所必要的電力有可能變為困難。In recent years, with the increase in the size of organic EL displays, the wiring length tends to become longer. As the wiring length becomes longer, the wiring resistance increases, and accordingly, for example, it may become difficult to supply power necessary for light emission to the pixel electrode located at a position away from the power source.

於此,作為降低配線電阻的技術,提案將由低電阻率之材料所形成的補助電極連接於對向電極的技術。該技術中,補助電極之導通用之接觸孔係按每一副像素形成。副像素係指,構成1個像素的R(紅)、G(綠)、B(藍)之各別之點。亦即,於上述技術中,於紅色之副像素、綠色之副像素及藍色之副像素分別各形成1個接觸孔。Here, as a technique for reducing wiring resistance, a technique of connecting a supplementary electrode formed of a material with low resistivity to a counter electrode is proposed. In this technique, the contact holes of the auxiliary electrodes are formed for each sub-pixel. The sub-pixel refers to the respective points of R (red), G (green), and B (blue) that constitute one pixel. That is, in the above technique, one contact hole is formed in each of the red sub-pixel, the green sub-pixel, and the blue sub-pixel.

圖1係表示補助電極用之接觸孔按每一副像素形成的有機EL顯示器之構成例之模式平面圖。如圖1所示,有機EL顯示器1X具有複數個像素電極21X,及覆蓋複數個像素電極21X的堤岸30X。於堤岸30X按每一像素電極21X形成使像素電極21X之一部分露出的開口部31X。亦即,對1個像素電極21X形成1個開口部31X。FIG. 1 is a schematic plan view showing a configuration example of an organic EL display in which contact holes for auxiliary electrodes are formed for each sub-pixel. As shown in FIG. 1, the organic EL display 1X has a plurality of pixel electrodes 21X, and a bank 30X covering the plurality of pixel electrodes 21X. An opening 31X that exposes a part of the pixel electrode 21X is formed in the bank 30X for each pixel electrode 21X. That is, one opening 31X is formed for one pixel electrode 21X.

於各開口部31X形成有機EL層23X。有機EL層23X,係藉由噴墨方式對各開口部31X吐出有機材料之液滴而形成。An organic EL layer 23X is formed in each opening 31X. The organic EL layer 23X is formed by ejecting droplets of an organic material to each opening 31X by an inkjet method.

於有機EL層23X上配置有未圖示的對向電極。對向電極,係被複數個像素電極21X共有者,與複數個像素電極21X對向。如此般,藉由像素電極21X與對向電極夾持有機EL層23X來形成1個副像素。因此,俯視狀態下像素電極21X與開口部31X重疊的領域相當於1個副像素之區域。A counter electrode (not shown) is arranged on the organic EL layer 23X. The counter electrode is the one shared by the plurality of pixel electrodes 21X and faces the plurality of pixel electrodes 21X. In this way, one sub-pixel is formed by sandwiching the organic EL layer 23X between the pixel electrode 21X and the counter electrode. Therefore, the area where the pixel electrode 21X overlaps the opening 31X in a plan view corresponds to the area of one sub-pixel.

補助電極用之接觸孔50X按每一副像素形成。換言之,有機EL顯示器1X中,相對於1個像素電極21X或者1個開口部31X形成1個接觸孔50X。The contact hole 50X for the auxiliary electrode is formed for each sub-pixel. In other words, in the organic EL display 1X, one contact hole 50X is formed with respect to one pixel electrode 21X or one opening 31X.

但是,近年來,為了提高有機EL顯示器之像素密度,有縮小副像素之尺寸之趨勢。通常,於堤岸按每一副像素形成有接受有機材料之液滴的開口部(參照圖1)。因此,若伴隨副像素之尺寸之縮小而縮小開口部之尺寸時,液滴之著陸位置之容許誤差變小,液滴容易從開口部溢出。However, in recent years, in order to increase the pixel density of organic EL displays, there is a tendency to reduce the size of sub-pixels. Generally, openings for receiving liquid droplets of organic material are formed for each sub-pixel on the bank (see FIG. 1 ). Therefore, when the size of the opening is reduced as the size of the sub-pixel is reduced, the allowable error of the landing position of the droplet becomes smaller, and the droplet is likely to overflow from the opening.

於此,為了緩和液滴之著陸位置之容許誤差,提案將供作為液滴著陸的開口部,不按每一副像素,而是按同色之相鄰的每複數個副像素形成的技術(以下標記為「像素連結」)。Here, in order to alleviate the allowable error of the landing position of the droplet, it is proposed that the opening for the landing of the droplet not be formed for each sub-pixel, but for each plurality of adjacent sub-pixels of the same color (below Marked as "Pixel Link").

但是,在補助電極用之接觸孔50X按每一副像素設置的有機EL顯示器1X中,難以進行像素連結。亦即,如圖1所示,各接觸孔50X形成於相鄰的2個同色之有機EL層23X之間之區域。因此,假設形成將圖1所示相鄰的2個同色之有機EL層23X連結的1個開口部之情況下,圖1所示2個接觸孔50X之中之上側之接觸孔50X成為位於開口部內。如此則,吐出至開口部的有機材料將流入接觸孔50X,無法完成將對向電極與補助電極電連接之功能。又,若有機材料流入接觸孔50X,有機EL層23X之膜厚均勻性有可能降低。However, in the organic EL display 1X in which the contact hole 50X for the auxiliary electrode is provided for each sub-pixel, it is difficult to connect pixels. That is, as shown in FIG. 1, each contact hole 50X is formed in a region between two adjacent organic EL layers 23X of the same color. Therefore, assuming that one opening portion connecting two adjacent organic EL layers 23X of the same color shown in FIG. 1 is formed, the upper contact hole 50X of the two contact holes 50X shown in FIG. 1 is located at the opening Within the ministry. In this way, the organic material discharged into the opening will flow into the contact hole 50X, and the function of electrically connecting the counter electrode and the auxiliary electrode cannot be completed. Also, if the organic material flows into the contact hole 50X, the uniformity of the film thickness of the organic EL layer 23X may be reduced.

於此,補助電極用之接觸孔之數目被最佳化的有機EL顯示器之提供被期待。Here, the provision of an organic EL display in which the number of contact holes for auxiliary electrodes is optimized is expected.

<有機EL顯示器> 圖2係表示實施形態之有機EL顯示器之電路構成之一例之圖。又,圖2中將一個單位電路11擴大表示。<Organic EL display> FIG. 2 is a diagram showing an example of the circuit configuration of the organic EL display of the embodiment. In addition, one unit circuit 11 is enlarged and shown in FIG. 2.

如圖2所示,有機EL顯示器1具備:基板10;複數個單位電路11;掃描線驅動電路14;及資料線驅動電路15。複數個單位電路11、掃描線驅動電路14及資料線驅動電路15係設置於基板10上。As shown in FIG. 2, the organic EL display 1 includes: a substrate 10; a plurality of unit circuits 11; a scanning line drive circuit 14; and a data line drive circuit 15. A plurality of unit circuits 11, a scanning line drive circuit 14, and a data line drive circuit 15 are provided on the substrate 10.

單位電路11設置於,與掃描線驅動電路14連接的複數個掃描線16,及與資料線驅動電路15連接的複數個資料線17所包圍的區域。該單位電路11包含TFT層12及有機發光二極體13。The unit circuit 11 is provided in a region surrounded by a plurality of scan lines 16 connected to the scan line drive circuit 14 and a plurality of data lines 17 connected to the data line drive circuit 15. The unit circuit 11 includes a TFT layer 12 and an organic light-emitting diode 13.

TFT層12具有複數個TFT(Thin Film Transistor)。複數個TFT之中之一TFT具有作為開關元件之功能,另一之TFT具有作為對流入有機發光二極體13之電流量進行控制的電流控制用元件之功能。TFT層12藉由掃描線驅動電路14及資料線驅動電路15進行動作,對有機發光二極體13供給電流。TFT層12按每一單位電路11設置,複數個單位電路11被獨立控制。The TFT layer 12 has a plurality of TFTs (Thin Film Transistor). One of the TFTs has a function as a switching element, and the other TFT has a function as a current control element that controls the amount of current flowing into the organic light-emitting diode 13. The TFT layer 12 is operated by the scanning line drive circuit 14 and the data line drive circuit 15 to supply current to the organic light-emitting diode 13. The TFT layer 12 is provided for each unit circuit 11, and a plurality of unit circuits 11 are independently controlled.

又,TFT層12只要是一般的構成即可,不限定於圖2所示構成。又,實施形態中,有機EL顯示器1之驅動方式以主動矩陣方式之情況下之例進行說明,但驅動方式為被動矩陣方式亦可。In addition, the TFT layer 12 may have a general structure, and is not limited to the structure shown in FIG. 2. In addition, in the embodiment, the driving method of the organic EL display 1 is described as an example in the case of an active matrix method, but the driving method may be a passive matrix method.

圖3係表示實施形態之有機EL顯示器1之模式平面圖。又,圖3中,省略後述之陰極22之圖示。又,圖3中,形成有同一色之發光層26的區域以同一之斜線表示。FIG. 3 is a schematic plan view showing the organic EL display 1 of the embodiment. In FIG. 3, illustration of the cathode 22 described later is omitted. In addition, in FIG. 3, the region where the light-emitting layer 26 of the same color is formed is indicated by the same diagonal line.

如圖3所示,實施形態之有機EL顯示器1中,對2個副像素形成1個開口部31。具體而言,實施形態之有機EL顯示器1中,堤岸30之開口部31係使與相鄰的2個同色之副像素對應而設置的2個陽極21露出。於此,複數個同色之副像素沿著Y軸方向被配列,開口部31使在Y軸方向相鄰的2個陽極21之各一部分露出。As shown in FIG. 3, in the organic EL display 1 of the embodiment, one opening 31 is formed for two sub-pixels. Specifically, in the organic EL display 1 of the embodiment, the opening 31 of the bank 30 exposes two anodes 21 provided corresponding to two adjacent sub-pixels of the same color. Here, a plurality of sub-pixels of the same color are arranged along the Y-axis direction, and the opening 31 exposes each part of the two anodes 21 adjacent in the Y-axis direction.

如此般,將使形成有機EL層23用的有機材料之液滴著陸的開口部31,並非按每一副像素,而是按相鄰的每2個同色之副像素來形成,據此,可以緩和液滴之著陸位置之容許誤差。In this way, the opening 31 where the droplets of the organic material for forming the organic EL layer 23 land is formed not for each sub-pixel, but for every two adjacent sub-pixels of the same color. Alleviate the tolerance of the landing position of the droplet.

圖4為圖3中的IV-IV線剖面圖。如圖4所示,有機EL顯示器1中,於基板10上形成有TFT層12,於TFT層12上形成有為了使基於TFT層12而形成的段差平坦化之平坦化層18。基板10例如為玻璃基板或樹脂基板等之透明基板。FIG. 4 is a cross-sectional view taken along line IV-IV in FIG. 3. As shown in FIG. 4, in the organic EL display 1, a TFT layer 12 is formed on a substrate 10, and a flattening layer 18 is formed on the TFT layer 12 to flatten the step formed by the TFT layer 12. The substrate 10 is, for example, a transparent substrate such as a glass substrate or a resin substrate.

平坦化層18具有絕緣性。在貫穿平坦化層18的接觸孔形成有接觸栓塞19。接觸栓塞19係將形成於平坦化層18之平坦面的作為像素電極之陽極21與TFT層12進行電連接。接觸栓塞19藉由與陽極21同一之材料同時形成亦可。The planarization layer 18 has insulating properties. A contact plug 19 is formed in the contact hole penetrating the planarization layer 18. The contact plug 19 electrically connects the anode 21 as the pixel electrode formed on the flat surface of the planarization layer 18 and the TFT layer 12. The contact plug 19 may be formed by the same material as the anode 21 at the same time.

有機發光二極體13形成於平坦化層18之平坦面上。有機發光二極體13具有:作為像素電極之陽極21;以像素電極為基準而設置於基板10之相反側的作為對向電極之陰極22;及形成於陽極21與陰極22之間的有機EL層23。藉由使TFT層12動作,於陽極21與陰極22之間被施加電壓,有機EL層23發光。The organic light emitting diode 13 is formed on the flat surface of the planarization layer 18. The organic light-emitting diode 13 has: an anode 21 as a pixel electrode; a cathode 22 as a counter electrode provided on the opposite side of the substrate 10 based on the pixel electrode; and an organic EL formed between the anode 21 and the cathode 22 Layer 23. By operating the TFT layer 12, a voltage is applied between the anode 21 and the cathode 22, and the organic EL layer 23 emits light.

作為像素電極之陽極21,例如藉由ITO (Indium Tin Oxide)等形成,使來自有機EL層23之光透過。透過陽極21的光係透過基板10而被取出於外部。陽極21按每一單位電路11、換言之按每一副像素設置。The anode 21 as the pixel electrode is formed by, for example, ITO (Indium Tin Oxide) or the like, and transmits light from the organic EL layer 23. The light transmitted through the anode 21 passes through the substrate 10 and is taken out to the outside. The anode 21 is provided for each unit circuit 11, in other words, for each sub-pixel.

作為對向電極之陰極22,例如由鋁等形成,使來自有機EL層23之光朝向有機EL層23反射。被陰極22反射之光透過有機EL層23、陽極21、基板10而被取出於外部。陰極22係被複數個單位電路11共有者。The cathode 22 as the counter electrode is formed of aluminum or the like, for example, and reflects the light from the organic EL layer 23 toward the organic EL layer 23. The light reflected by the cathode 22 passes through the organic EL layer 23, the anode 21, and the substrate 10 and is taken out to the outside. The cathode 22 is shared by a plurality of unit circuits 11.

又,於此,針對陽極21為像素電極,陰極22為對向電極之情況下之例進行說明,但陰極22為像素電極,陽極21為對向電極亦可。In addition, here, an example in the case where the anode 21 is a pixel electrode and the cathode 22 is a counter electrode will be described, but the cathode 22 may be a pixel electrode and the anode 21 may be a counter electrode.

有機EL層23,例如具有電洞注入層24、電洞輸送層25、發光層26、電子輸送層27及電子注入層28。電洞注入層24、電洞輸送層25、發光層26、電子輸送層27及電子注入層28由陽極21側向陰極22側依序被積層。The organic EL layer 23 has, for example, a hole injection layer 24, a hole transport layer 25, a light-emitting layer 26, an electron transport layer 27, and an electron injection layer 28. The hole injection layer 24, the hole transport layer 25, the light emitting layer 26, the electron transport layer 27, and the electron injection layer 28 are sequentially stacked from the anode 21 side to the cathode 22 side.

在陽極21與陰極22之間被施加電壓時,電洞從陽極21被注入電洞注入層24,電子從陰極22被注入電子注入層28。注入電洞注入層24的電洞,係藉由電洞輸送層25被輸送至發光層26。被注入電子注入層28的電子,係藉由電子輸送層27被輸送至發光層26。於發光層26內電洞與電子再結合,發光層26之發光材料被激發,發光層26發光。When a voltage is applied between the anode 21 and the cathode 22, holes are injected into the hole injection layer 24 from the anode 21, and electrons are injected into the electron injection layer 28 from the cathode 22. The holes injected into the hole injection layer 24 are transported to the light emitting layer 26 via the hole transport layer 25. The electrons injected into the electron injection layer 28 are transported to the light-emitting layer 26 through the electron transport layer 27. The holes and electrons recombine in the light-emitting layer 26, the light-emitting material of the light-emitting layer 26 is excited, and the light-emitting layer 26 emits light.

作為發光層26,例如圖3所示,形成有紅色發光層26R、綠色發光層26G及藍色發光層26B。紅色發光層26R係由發出紅色光的紅色發光材料形成。綠色發光層26G係由發出綠色光的綠色發光材料形成。藍色發光層26B係由發出藍色光的藍色發光材料形成。As the light emitting layer 26, for example, as shown in FIG. 3, a red light emitting layer 26R, a green light emitting layer 26G, and a blue light emitting layer 26B are formed. The red light-emitting layer 26R is formed of a red light-emitting material that emits red light. The green light-emitting layer 26G is formed of a green light-emitting material that emits green light. The blue light-emitting layer 26B is formed of a blue light-emitting material that emits blue light.

有機EL顯示器1中的1個像素,係包含具有紅色發光層26R的副像素,及與該副像素鄰接且具有藍色發光層26B的副像素,及與該副像素鄰接且具有綠色發光層26G的副像素而構成。紅色發光層26R、綠色發光層26G及藍色發光層26B,俯視狀態下係在作為像素電極之陽極21與作為對向電極之陰極22所重疊的區域中發出。One pixel in the organic EL display 1 includes a sub-pixel having a red light-emitting layer 26R, a sub-pixel adjacent to the sub-pixel and having a blue light-emitting layer 26B, and a green light-emitting layer 26G adjacent to the sub-pixel Sub-pixels. The red light-emitting layer 26R, the green light-emitting layer 26G, and the blue light-emitting layer 26B are emitted in a region where the anode 21 as the pixel electrode overlaps with the cathode 22 as the counter electrode in a plan view.

堤岸30係將紅色發光層26R用之塗布液、綠色發光層26G用之塗布液、與藍色發光層26B用之塗布液隔開,防止彼等塗布液之混合。堤岸30具有絕緣性,將貫穿平坦化層18的接觸孔填埋。The bank 30 separates the coating liquid for the red light-emitting layer 26R, the coating liquid for the green light-emitting layer 26G, and the coating liquid for the blue light-emitting layer 26B to prevent mixing of the coating liquids. The bank 30 has insulating properties, and fills the contact hole penetrating the planarization layer 18.

如圖3所示,於實施形態之有機EL顯示器1,對1個開口部31形成1個接觸孔50。換言之,接觸孔50係按由開口部31露出的2個陽極21所對應的每2個同色之陽極21設置。As shown in FIG. 3, in the organic EL display 1 of the embodiment, one contact hole 50 is formed in one opening 31. In other words, the contact holes 50 are provided for every two anodes 21 of the same color corresponding to the two anodes 21 exposed by the opening 31.

圖5為圖3中的V-V線剖面圖。如圖5所示,接觸孔50以貫穿堤岸30及平坦化層18的方式形成。接觸孔50開設於堤岸30之上面,使設置於基板10上的補助電極51之一部分露出。FIG. 5 is a cross-sectional view taken along line V-V in FIG. 3. As shown in FIG. 5, the contact hole 50 is formed so as to penetrate the bank 30 and the planarization layer 18. The contact hole 50 is opened above the bank 30 to expose a part of the auxiliary electrode 51 provided on the substrate 10.

於接觸孔50例如埋設有W(鎢)等之導電性材料。據此,可以將陰極22與補助電極51電連接。A conductive material such as W (tungsten) is buried in the contact hole 50, for example. According to this, the cathode 22 and the auxiliary electrode 51 can be electrically connected.

如圖3所示,接觸孔50係形成於複數個開口部31之中之一個開口部31,於該一個開口部31在Y軸方向相鄰的另一個開口部31之間之區域。換言之,接觸孔50係形成於形成有同色之發光層26之於Y軸方向相鄰的2個開口部31之間之區域。因此,塗布處理時,有機材料不易進入接觸孔50。As shown in FIG. 3, the contact hole 50 is formed in one of the plurality of openings 31 in a region between the other opening 31 adjacent to the one opening 31 in the Y-axis direction. In other words, the contact hole 50 is formed in the region between the two openings 31 adjacent to each other in the Y-axis direction where the light-emitting layer 26 of the same color is formed. Therefore, during the coating process, the organic material does not easily enter the contact hole 50.

如此般,補助電極用之接觸孔50係按由開口部31露出的2個陽極21所對應的每2個同色之陽極21而設置。據此,在進行像素連結時接觸孔50不會成為障礙。因此,即使對補助電極為必要的大型之有機EL顯示器,亦能適用像素連結。如上述般,作為對向電極之陰極22係被複數個單位電路11共有者,接觸孔50未必一定要按每一副像素設置。In this way, the contact hole 50 for the auxiliary electrode is provided for every two anodes 21 of the same color corresponding to the two anodes 21 exposed from the opening 31. According to this, the contact hole 50 does not become an obstacle during pixel connection. Therefore, even a large-scale organic EL display that is necessary for the auxiliary electrode can be applied to pixel connection. As described above, the cathode 22 as the counter electrode is shared by a plurality of unit circuits 11, and the contact holes 50 are not necessarily provided for each sub-pixel.

又,於此,雖示出按每2個副像素設置1個接觸孔50,但例如依據陽極21之面積或配線之粗細,按每3個以上之副像素設置1個接觸孔50亦可能。Here, although it is shown that one contact hole 50 is provided for every two sub-pixels, for example, it is possible to provide one contact hole 50 for every three or more sub-pixels according to the area of the anode 21 or the thickness of the wiring.

<有機發光二極體之製造方法> 圖6係表示實施形態之有機發光二極體13之製造方法之流程圖。圖6所示各處理順序,係在基板10上形成TFT層12、補助電極51、平坦化層18、堤岸30、開口部31及接觸孔50,而且,對在接觸孔50埋設有導電性材料之後之有機EL顯示器進行。<Manufacturing method of organic light emitting diode> FIG. 6 is a flowchart showing a method of manufacturing the organic light emitting diode 13 of the embodiment. In each processing sequence shown in FIG. 6, the TFT layer 12, the auxiliary electrode 51, the planarization layer 18, the bank 30, the opening 31, and the contact hole 50 are formed on the substrate 10, and a conductive material is buried in the contact hole 50 The subsequent organic EL display is carried out.

首先,於步驟S101中,進行作為像素電極之陽極21之形成。陽極21之形成例如可以使用蒸鍍法。陽極21係在平坦化層18之平坦面按每一單位電路11形成。又,同時形成陽極21與接觸栓塞19亦可。First, in step S101, the anode 21 as a pixel electrode is formed. For the formation of the anode 21, for example, a vapor deposition method can be used. The anode 21 is formed for each unit circuit 11 on the flat surface of the planarization layer 18. Also, the anode 21 and the contact plug 19 may be formed at the same time.

接著,步驟S102中,進行堤岸30之形成。堤岸30例如使用光阻劑形成,藉由光微影成像處理圖案化成為規定之圖案。於堤岸30之開口部31中使陽極21之一部分露出。Next, in step S102, the bank 30 is formed. The bank 30 is formed using a photoresist, for example, and is patterned into a predetermined pattern by photolithography. A part of the anode 21 is exposed in the opening 31 of the bank 30.

接著,於步驟S103中,進行電洞注入層24之形成。電洞注入層24之形成係使用噴墨法。藉由噴墨法將電洞注入層24用之塗布液塗布於陽極21上而形成塗布層。之後,對塗布層進行乾燥、燒結,形成圖4所示電洞注入層24。Next, in step S103, the hole injection layer 24 is formed. The hole injection layer 24 is formed by an inkjet method. The coating liquid for the hole injection layer 24 is applied on the anode 21 by an inkjet method to form a coating layer. After that, the coating layer is dried and sintered to form the hole injection layer 24 shown in FIG. 4.

接著,於步驟S104中,進行電洞輸送層25之形成。電洞輸送層25之形成係和電洞注入層24之形成同樣地使用噴墨法。藉由噴墨法將電洞輸送層25用之塗布液塗布於電洞注入層24上而形成塗布層。之後,對塗布層進行乾燥、燒結,而形成電洞輸送層25。Next, in step S104, the hole transport layer 25 is formed. The formation of the hole transport layer 25 is the same as the formation of the hole injection layer 24 using the inkjet method. The coating liquid for the hole transport layer 25 is applied on the hole injection layer 24 by an inkjet method to form a coating layer. After that, the coating layer is dried and sintered to form the hole transport layer 25.

接著,於步驟S105中,進行發光層26之形成。發光層26之形成,係和電洞注入層24或電洞輸送層25之形成同樣地使用噴墨法。藉由噴墨法將發光層26用之塗布液塗布於電洞輸送層25上而形成塗布層。之後,對塗布層進行乾燥、燒結而形成發光層26。如上述般,作為發光層26而形成例如紅色發光層26R、綠色發光層26G及藍色發光層26B。Next, in step S105, the light emitting layer 26 is formed. The formation of the light-emitting layer 26 is the same as the formation of the hole injection layer 24 or the hole transport layer 25 using the inkjet method. The coating liquid for the light-emitting layer 26 is applied on the hole transport layer 25 by an inkjet method to form a coating layer. Thereafter, the coating layer is dried and sintered to form the light-emitting layer 26. As described above, as the light-emitting layer 26, for example, a red light-emitting layer 26R, a green light-emitting layer 26G, and a blue light-emitting layer 26B are formed.

接著,於步驟S106中,進行電子輸送層27之形成。電子輸送層27之形成,例如使用蒸鍍法等。電子輸送層27可以是被複數個單位電路11共有者,因此不僅形成於堤岸30之開口部31內之發光層26上,形成於堤岸30上亦可。Next, in step S106, the electron transport layer 27 is formed. For the formation of the electron transport layer 27, for example, a vapor deposition method or the like is used. Since the electron transport layer 27 may be shared by a plurality of unit circuits 11, it may be formed not only on the light-emitting layer 26 in the opening 31 of the bank 30 but also on the bank 30.

接著,於步驟S107中,進行電子注入層28之形成。電子注入層28之形成,例如使用蒸鍍法等。電子注入層28係形成於電子輸送層27上。和電子輸送層27同樣,電子注入層28亦可以是被複數個單位電路11共有者。Next, in step S107, the electron injection layer 28 is formed. The electron injection layer 28 is formed using, for example, a vapor deposition method. The electron injection layer 28 is formed on the electron transport layer 27. Like the electron transport layer 27, the electron injection layer 28 may be shared by a plurality of unit circuits 11.

接著,於步驟S108中,進行陰極22之形成。陰極22之形成,例如使用蒸鍍法等。陰極22係形成於電子注入層28上。陰極22係被複數個單位電路11共有者。有機EL顯示器1之驅動方式為被動矩陣方式之情況下,陰極22被圖案化成為規定之圖案。Next, in step S108, the cathode 22 is formed. For the formation of the cathode 22, for example, a vapor deposition method or the like is used. The cathode 22 is formed on the electron injection layer 28. The cathode 22 is shared by a plurality of unit circuits 11. When the driving method of the organic EL display 1 is a passive matrix method, the cathode 22 is patterned into a predetermined pattern.

藉由以上之工程製造有機發光二極體13。有機EL層23之中,在電洞注入層24、電洞輸送層25及發光層26之形成時使用基板處理系統。The organic light emitting diode 13 is manufactured through the above process. Among the organic EL layers 23, a substrate processing system is used when forming the hole injection layer 24, the hole transport layer 25, and the light-emitting layer 26.

<基板處理系統> 圖7係表示實施形態之基板處理系統之構成之模式平面圖。圖7所示基板處理系統100,係藉由進行和圖6之步驟S103~S105相當的各處理,而在陽極21上形成電洞注入層24、電洞輸送層25及發光層26。<Substrate processing system> 7 is a schematic plan view showing the configuration of the substrate processing system of the embodiment. The substrate processing system 100 shown in FIG. 7 forms the hole injection layer 24, the hole transport layer 25, and the light emitting layer 26 on the anode 21 by performing processes corresponding to steps S103 to S105 of FIG.

圖7所示基板處理系統100具有搬入站110;處理站120;搬出站130;及控制裝置140。The substrate processing system 100 shown in FIG. 7 has a loading station 110; a processing station 120; a carrying station 130; and a control device 140.

搬入站110從外部搬入收納有複數個基板10的基板收納盒C,從基板收納盒C依序取出複數個基板10。於各基板10事先形成有TFT層12、平坦化層18、陽極21、堤岸30、開口部31及接觸孔50等。The carrying-in station 110 carries in a substrate storage box C that stores a plurality of substrates 10 from the outside, and sequentially takes out the plurality of substrates 10 from the substrate storage box C. On each substrate 10, a TFT layer 12, a planarization layer 18, an anode 21, a bank 30, an opening 31, a contact hole 50, and the like are formed in advance.

搬入站110具備:載置基板收納盒C的基板收納盒載置台111;設置於基板收納盒載置台111與處理站120之間的搬送路112;及設置於搬送路112的基板搬送體113。基板搬送體113係在基板收納盒載置台111所載置的基板收納盒C與處理站120之間進行基板10之搬送。The loading station 110 includes: a substrate storage box mounting table 111 on which the substrate storage box C is mounted; a transport path 112 provided between the substrate storage box mounting table 111 and the processing station 120; and a substrate transport body 113 provided on the transport path 112. The substrate transfer body 113 transfers the substrate 10 between the substrate storage box C placed on the substrate storage box mounting table 111 and the processing station 120.

處理站120係於陽極21上形成電洞注入層24、電洞輸送層25及發光層26。處理站120具備:形成電洞注入層24的電洞注入層形成區塊121;形成電洞輸送層25的電洞輸送層形成區塊122;及形成發光層26的發光層形成區塊123。The processing station 120 forms a hole injection layer 24, a hole transport layer 25, and a light emitting layer 26 on the anode 21. The processing station 120 includes a hole injection layer forming block 121 forming the hole injection layer 24; a hole transport layer forming block 122 forming the hole transport layer 25; and a light emitting layer forming block 123 forming the light emitting layer 26.

電洞注入層形成區塊121係將電洞注入層24用之塗布液塗布於陽極21上形成塗布層,對該塗布層進行乾燥、燒結而形成電洞注入層24。電洞注入層24用之塗布液包含有機材料及溶劑。有機材料可以是聚合物、單體之任一。單體之情況下,藉由燒結聚合而成為聚合物亦可。The hole injection layer forming block 121 applies the coating solution for the hole injection layer 24 on the anode 21 to form a coating layer, and the coating layer is dried and sintered to form the hole injection layer 24. The coating solution for the hole injection layer 24 contains an organic material and a solvent. The organic material may be either a polymer or a monomer. In the case of a monomer, it may be polymerized by sintering polymerization.

電洞注入層形成區塊121具備:塗布裝置121a;緩衝裝置121b;減壓乾燥裝置121c;熱處理裝置121d;及溫度調節裝置121e。塗布裝置121a係使電洞注入層24用之塗布液之液滴朝向堤岸30之開口部31吐出。緩衝裝置121b係將待處理之基板10暫時收納。減壓乾燥裝置121c係對經由塗布裝置121a塗布的塗布層進行減壓乾燥,將包含於塗布層的溶劑除去。熱處理裝置121d係對經由減壓乾燥裝置121c乾燥的塗布層進行加熱處理。溫度調節裝置121e係將經由熱處理裝置121d加熱處理的基板10之溫度調節成為規定之溫度例如常溫。The hole injection layer forming block 121 includes: a coating device 121a; a buffer device 121b; a reduced-pressure drying device 121c; a heat treatment device 121d; and a temperature adjustment device 121e. The coating device 121 a causes the droplets of the coating liquid for the hole injection layer 24 to be discharged toward the opening 31 of the bank 30. The buffer device 121b temporarily stores the substrate 10 to be processed. The reduced-pressure drying device 121c dries the coating layer applied via the coating device 121a under reduced pressure, and removes the solvent contained in the coating layer. The heat treatment device 121d heat-treats the coating layer dried by the reduced-pressure drying device 121c. The temperature adjustment device 121e adjusts the temperature of the substrate 10 heated by the heat treatment device 121d to a predetermined temperature, for example, normal temperature.

塗布裝置121a、緩衝裝置121b、熱處理裝置121d及溫度調節裝置121e之內部被維持於大気氛圍。減壓乾燥裝置121c係將內部之氛圍切換為大氣氛圍與減壓氛圍。The inside of the coating device 121a, the buffer device 121b, the heat treatment device 121d, and the temperature adjustment device 121e are maintained in a large atmosphere. The reduced-pressure drying device 121c switches the internal atmosphere to an atmospheric atmosphere and a reduced-pressure atmosphere.

又,電洞注入層形成區塊121中,塗布裝置121a、緩衝裝置121b、減壓乾燥裝置121c、熱處理裝置121d及溫度調節裝置121e之配置或個數、內部之氛圍可以任意選擇。In addition, in the hole injection layer forming block 121, the arrangement or number of the coating device 121a, the buffer device 121b, the reduced-pressure drying device 121c, the heat treatment device 121d, and the temperature adjustment device 121e, and the internal atmosphere can be arbitrarily selected.

又,電洞注入層形成區塊121具備:基板搬送裝置CR1~CR3;及交接裝置TR1~TR3。基板搬送裝置CR1~CR3分別將基板10搬送至鄰接的各裝置。例如,基板搬送裝置CR1係將基板10搬送至鄰接的塗布裝置121a及緩衝裝置121b。基板搬送裝置CR2係將基板10搬送至鄰接的減壓乾燥裝置121c。基板搬送裝置CR3係將基板10搬送至鄰接的熱處理裝置121d及溫度調節裝置121e。交接裝置TR1~TR3分別依序設置於搬入站110與基板搬送裝置CR1之間、基板搬送裝置CR1與基板搬送裝置CR2之間、基板搬送裝置CR2與基板搬送裝置CR3之間,在彼等間進行基板10之中繼。基板搬送裝置CR1~CR3或交接裝置TR1~TR3之內部被維持於大氣氛圍。In addition, the hole injection layer forming block 121 includes: substrate transfer devices CR1 to CR3; and transfer devices TR1 to TR3. The substrate transfer devices CR1 to CR3 transfer the substrate 10 to the adjacent devices, respectively. For example, the substrate transfer device CR1 transfers the substrate 10 to the adjacent coating device 121a and buffer device 121b. The substrate transfer device CR2 transfers the substrate 10 to the adjacent decompression drying device 121c. The substrate transfer device CR3 transfers the substrate 10 to the adjacent heat treatment device 121d and temperature adjustment device 121e. The transfer devices TR1 to TR3 are sequentially installed between the loading station 110 and the substrate transfer device CR1, between the substrate transfer device CR1 and the substrate transfer device CR2, and between the substrate transfer device CR2 and the substrate transfer device CR3, and between them. Relay of the substrate 10. The interior of the substrate transfer devices CR1 to CR3 or the transfer devices TR1 to TR3 is maintained in the atmosphere.

在電洞注入層形成區塊121之基板搬送裝置CR3與電洞輸送層形成區塊122之基板搬送裝置CR4之間,設置有在彼等間進行基板10之中繼的交接裝置TR4。交接裝置TR4之內部被維持於大氣氛圍。Between the substrate transport device CR3 of the hole injection layer forming block 121 and the substrate transport device CR4 of the hole transport layer forming block 122, a transfer device TR4 that relays the substrate 10 between them is provided. The interior of the transfer device TR4 is maintained in an atmospheric atmosphere.

電洞輸送層形成區塊122係將電洞輸送層25用之塗布液塗布於電洞注入層24上而形成塗布層,對該塗布層進行乾燥、燒結而形成電洞輸送層25。電洞輸送層25用之塗布液包含有機材料及溶劑。有機材料可以是聚合物、單體之任一。單體之情況下,藉由燒結聚合而形成聚合物亦可。The hole transport layer forming block 122 applies a coating solution for the hole transport layer 25 on the hole injection layer 24 to form a coating layer, and the coating layer is dried and sintered to form the hole transport layer 25. The coating solution for the hole transport layer 25 contains organic materials and solvents. The organic material may be either a polymer or a monomer. In the case of a monomer, the polymer may be formed by sintering polymerization.

電洞輸送層形成區塊122具備塗布裝置122a、緩衝裝置122b、減壓乾燥裝置122c、熱處理裝置122d、及溫度調節裝置122e。塗布裝置122a係使電洞輸送層25用之塗布液之液滴朝向堤岸30之開口部31吐出。緩衝裝置122b係將待處理之基板10暫時收納。減壓乾燥裝置122c係對經由塗布裝置122a塗布的塗布層進行減壓乾燥,將包含於塗布層的溶劑除去。熱處理裝置122d係對經由減壓乾燥裝置122c乾燥的塗布層進行加熱處理。溫度調節裝置122e係將經由熱處理裝置122d加熱處理的基板10之溫度調節成為規定之溫度例如常溫。The hole transport layer forming block 122 includes a coating device 122a, a buffer device 122b, a reduced-pressure drying device 122c, a heat treatment device 122d, and a temperature adjustment device 122e. The coating device 122 a causes the droplets of the coating liquid for the hole transport layer 25 to be discharged toward the opening 31 of the bank 30. The buffer device 122b temporarily stores the substrate 10 to be processed. The reduced-pressure drying device 122c dries the coating layer applied via the coating device 122a under reduced pressure, and removes the solvent contained in the coating layer. The heat treatment device 122d heat-treats the coating layer dried by the reduced-pressure drying device 122c. The temperature adjustment device 122e adjusts the temperature of the substrate 10 heated by the heat treatment device 122d to a predetermined temperature, for example, normal temperature.

塗布裝置122a及緩衝裝置122b之內部被維持於大氣氛圍。另一方面,熱處理裝置122d及溫度調節裝置122e,為了抑制電洞輸送層25之有機材料之劣化,其內部被維持於低氧而且低露點之氛圍。減壓乾燥裝置122c,其內部之氛圍在低氧而且低露點之氛圍與減壓氛圍進行切換。The inside of the coating device 122a and the buffer device 122b is maintained in an atmosphere. On the other hand, in order to suppress the deterioration of the organic material of the hole transport layer 25, the heat treatment device 122d and the temperature adjustment device 122e are maintained in a low oxygen and low dew point atmosphere. The decompression drying device 122c has a low-oxygen and low-dew point atmosphere and a reduced-pressure atmosphere.

於此,低氧之氛圍係指氧濃度比大氣低的氛圍,例如氧濃度為10ppm以下之氛圍。又,低露點之氛圍係指露點溫度比大氣低的氛圍,例如露點溫度為-10℃以下之氛圍。低氧而且低露點之氛圍例如由氮氣體等之惰性氣體形成。Here, the low-oxygen atmosphere refers to an atmosphere with a lower oxygen concentration than the atmosphere, for example, an atmosphere with an oxygen concentration of 10 ppm or less. The low dew point atmosphere refers to an atmosphere with a dew point temperature lower than that of the atmosphere, for example, an atmosphere with a dew point temperature of -10°C or lower. An atmosphere with low oxygen and low dew point is formed by an inert gas such as nitrogen gas.

又,電洞輸送層形成區塊122中,塗布裝置122a、緩衝裝置122b、減壓乾燥裝置122c、熱處理裝置122d、及溫度調節裝置122e之配置或個數、內部之氛圍可以任意選擇。In the hole transport layer forming block 122, the arrangement or number of the coating device 122a, the buffer device 122b, the reduced pressure drying device 122c, the heat treatment device 122d, and the temperature adjustment device 122e, and the internal atmosphere can be arbitrarily selected.

又,電洞輸送層形成區塊122具備基板搬送裝置CR4~CR6及交接裝置TR5~TR6。基板搬送裝置CR4~CR6分別將基板10搬送至鄰接的各裝置。交接裝置TR5~TR6分別依序設置於基板搬送裝置CR4與基板搬送裝置CR5之間、及基板搬送裝置CR5與基板搬送裝置CR6之間,在彼等間進行基板10之中繼。In addition, the hole transport layer forming block 122 includes substrate transfer devices CR4 to CR6 and transfer devices TR5 to TR6. The substrate transfer devices CR4 to CR6 transfer the substrate 10 to the adjacent devices, respectively. The transfer devices TR5 to TR6 are sequentially provided between the substrate transfer device CR4 and the substrate transfer device CR5, and between the substrate transfer device CR5 and the substrate transfer device CR6, and relay the substrate 10 between them.

基板搬送裝置CR4之內部被維持於大氣氛圍。另一方面,基板搬送裝置CR5~CR6之內部被維持於低氧而且低露點之氛圍。與基板搬送裝置CR5鄰接的減壓乾燥裝置122c之內部被切換於低氧而且低露點之氛圍與減壓氛圍之間。又,與基板搬送裝置CR6隣接的熱處理裝置122d或溫度調節裝置122e之內部被維持於低氧而且低露點之氛圍。The interior of the substrate transfer device CR4 is maintained in an atmospheric atmosphere. On the other hand, the interior of the substrate transfer devices CR5 to CR6 is maintained in an atmosphere of low oxygen and low dew point. The inside of the reduced-pressure drying device 122c adjacent to the substrate transfer device CR5 is switched between an atmosphere of low oxygen and low dew point and a reduced-pressure atmosphere. In addition, the interior of the heat treatment device 122d or the temperature adjustment device 122e adjacent to the substrate transfer device CR6 is maintained in an atmosphere of low oxygen and low dew point.

交接裝置TR5係作為將其內部之氛圍切換於大氣氛圍與低氧而且低露點之氛圍之間的裝載鎖定(loadlock)裝置而構成。在交接裝置TR5之下游側隣接設置有減壓乾燥裝置122c。另一方面,交接裝置TR6之內部被維持於低氧而且低露點之氛圍。The transfer device TR5 is configured as a loadlock device that switches the internal atmosphere between the atmospheric atmosphere and the atmosphere of low oxygen and low dew point. A decompression drying device 122c is provided adjacent to the downstream side of the delivery device TR5. On the other hand, the interior of the transfer device TR6 is maintained in a low oxygen and low dew point atmosphere.

在電洞輸送層形成區塊122之基板搬送裝置CR6與發光層形成區塊123之基板搬送裝置CR7之間,設置有在彼等間進行基板10之中繼的交接裝置TR7。基板搬送裝置CR6之內部被維持於低氧而且低露點之氛圍,基板搬送裝置CR7之內部被維持於大氣氛圍。因此交接裝置TR7作為將其內部之氛圍切換於低氧而且低露點之氛圍與大氣氛圍之間的裝載鎖定裝置而構成。Between the substrate transport device CR6 of the hole transport layer forming block 122 and the substrate transport device CR7 of the light emitting layer forming block 123, a transfer device TR7 that relays the substrate 10 between them is provided. The interior of the substrate transfer device CR6 is maintained in an atmosphere of low oxygen and low dew point, and the interior of the substrate transfer device CR7 is maintained in an atmospheric atmosphere. Therefore, the transfer device TR7 is configured as a load lock device that switches the internal atmosphere between a low-oxygen and low-dew point atmosphere and an atmospheric atmosphere.

發光層形成區塊123係將發光層26用之塗布液塗布於電洞輸送層25上而形成塗布層,對形成的塗布層進行乾燥、燒結而形成發光層26。發光層26用之塗布液包含有機材料及溶劑。有機材料可以是聚合物、單體之任一。單體之情況下,藉由燒結聚合而形成聚合物亦可。The light-emitting layer forming block 123 applies the coating solution for the light-emitting layer 26 on the hole transport layer 25 to form a coating layer, and the formed coating layer is dried and sintered to form the light-emitting layer 26. The coating liquid for the light-emitting layer 26 contains an organic material and a solvent. The organic material may be either a polymer or a monomer. In the case of a monomer, the polymer may be formed by sintering polymerization.

發光層形成區塊123具備塗布裝置123a、緩衝裝置123b、減壓乾燥裝置123c、熱處理裝置123d及溫度調節裝置123e。塗布裝置123a係使發光層26用之塗布液之液滴朝向堤岸30之開口部31吐出。緩衝裝置123b係將待處理之基板10暫時收納。減壓乾燥裝置123c係對經由塗布裝置123a塗布的塗布層進行減壓乾燥,將包含於塗布層的溶劑除去。熱處理裝置123d係對經由減壓乾燥裝置123c乾燥的塗布層進行加熱處理。溫度調節裝置123e係將經由熱處理裝置123d加熱處理的基板10之溫度調節成為規定之溫度例如常溫。The light emitting layer formation block 123 includes a coating device 123a, a buffer device 123b, a reduced-pressure drying device 123c, a heat treatment device 123d, and a temperature adjustment device 123e. The coating device 123a discharges the droplets of the coating liquid for the light-emitting layer 26 toward the opening 31 of the bank 30. The buffer device 123b temporarily stores the substrate 10 to be processed. The reduced-pressure drying device 123c dries the coating layer applied via the coating device 123a under reduced pressure, and removes the solvent contained in the coating layer. The heat treatment device 123d heat-treats the coating layer dried by the reduced-pressure drying device 123c. The temperature adjustment device 123e adjusts the temperature of the substrate 10 heated by the heat treatment device 123d to a predetermined temperature, for example, normal temperature.

塗布裝置123a及緩衝裝置123b之內部被維持於大氣氛圍。另一方面,熱處理裝置123d及溫度調節裝置123e,為了抑制發光層26之有機材料之劣化,因此內部被維持於低氧而且低露點之氛圍。減壓乾燥裝置123c係將內部之氛圍切換於低氧而且低露點之氛圍與減壓氛圍。The inside of the coating device 123a and the buffer device 123b is maintained in an atmosphere. On the other hand, in order to suppress the deterioration of the organic material of the light-emitting layer 26, the heat treatment device 123d and the temperature adjustment device 123e are maintained in a low oxygen and low dew point atmosphere. The reduced-pressure drying device 123c switches the internal atmosphere to a low oxygen and low dew point atmosphere and a reduced pressure atmosphere.

又,發光層形成區塊123中,塗布裝置123a、緩衝裝置123b、減壓乾燥裝置123c、熱處理裝置123d及溫度調節裝置123e之配置或個數、內部之氛圍可以任意選擇。In the light-emitting layer formation block 123, the arrangement or number of the coating device 123a, the buffer device 123b, the reduced-pressure drying device 123c, the heat treatment device 123d, and the temperature adjustment device 123e, and the internal atmosphere can be arbitrarily selected.

又,發光層形成區塊123具備基板搬送裝置CR7~CR9與交接裝置TR8~TR9。基板搬送裝置CR7~CR9分別將基板10搬送至鄰接的各裝置。交接裝置TR8~TR9分別依序設置於基板搬送裝置CR7與基板搬送裝置CR8之間、基板搬送裝置CR8與基板搬送裝置CR9之間,在彼等間進行基板10之中繼。In addition, the light-emitting layer formation block 123 includes substrate transfer devices CR7 to CR9 and transfer devices TR8 to TR9. The substrate transfer devices CR7 to CR9 transfer the substrate 10 to the adjacent devices, respectively. The transfer devices TR8 to TR9 are sequentially provided between the substrate transfer device CR7 and the substrate transfer device CR8, and between the substrate transfer device CR8 and the substrate transfer device CR9, and relay the substrate 10 between them.

基板搬送裝置CR7之內部被維持於大氣氛圍。另一方面,基板搬送裝置CR8~CR9之內部被維持於低氧而且低露點之氛圍。與基板搬送裝置CR8鄰接的減壓乾燥裝置123c之內部被切換於低氧而且低露點之氛圍與減壓氛圍之間。又,與基板搬送裝置CR9隣接的熱處理裝置123d或溫度調節裝置123e之內部被維持於低氧而且低露點之氛圍。The interior of the substrate transfer device CR7 is maintained in an atmospheric atmosphere. On the other hand, the interior of the substrate transfer devices CR8 to CR9 is maintained in an atmosphere of low oxygen and low dew point. The inside of the reduced-pressure drying device 123c adjacent to the substrate transfer device CR8 is switched between an atmosphere of low oxygen and low dew point and a reduced-pressure atmosphere. In addition, the interior of the heat treatment device 123d or the temperature adjustment device 123e adjacent to the substrate transfer device CR9 is maintained in an atmosphere of low oxygen and low dew point.

交接裝置TR8作為將其內部之氛圍切換於大氣氛圍與低氧而且低露點之氛圍之間的裝載鎖定裝置而構成。在交接裝置TR8之下游側隣接設置有減壓乾燥裝置123c。交接裝置TR9之內部被維持於低氧而且低露點之氛圍。The transfer device TR8 is configured as a load lock device that switches the internal atmosphere between an atmospheric atmosphere and an atmosphere of low oxygen and low dew point. A decompression drying device 123c is provided adjacent to the downstream side of the transfer device TR8. The interior of the transfer device TR9 is maintained in a low oxygen and low dew point atmosphere.

在發光層形成區塊123之基板搬送裝置CR9與搬出站130之間設置有在彼等間進行基板10之中繼的交接裝置TR10。基板搬送裝置CR9之內部被維持於低氧而且低露點之氛圍,搬出站130之內部被維持於大氣氛圍。因此交接裝置TR7作為將其內部之氛圍切換於低氧而且低露點之氛圍與大氣氛圍之間的裝載鎖定裝置而構成。A transfer device TR10 that relays the substrate 10 between them is provided between the substrate transfer device CR9 of the light-emitting layer formation block 123 and the transfer station 130. The interior of the substrate transfer device CR9 is maintained in a low oxygen and low dew point atmosphere, and the interior of the transfer station 130 is maintained in an atmospheric atmosphere. Therefore, the transfer device TR7 is configured as a load lock device that switches the internal atmosphere between a low-oxygen and low-dew point atmosphere and an atmospheric atmosphere.

搬出站130將複數片基板10依序收納於基板收納盒C,將基板收納盒C搬出外部。搬出站130具備:載置基板收納盒C的基板收納盒載置台131;設置於基板收納盒載置台131與處理站120之間的搬送路132;及設置於搬送路132的基板搬送體133。基板搬送體133係在處理站120與基板收納盒載置台131所載置的基板收納盒C之間進行基板10之搬送。The unloading station 130 sequentially stores the plurality of substrates 10 in the substrate storage box C, and transports the substrate storage box C out of the outside. The unloading station 130 includes: a substrate storage box mounting table 131 on which the substrate storage box C is mounted; a transport path 132 provided between the substrate storage box mounting table 131 and the processing station 120; and a substrate transport body 133 provided on the transport path 132. The substrate transport body 133 transports the substrate 10 between the processing station 120 and the substrate storage box C placed on the substrate storage box mounting table 131.

控制裝置140具備控制部141及記憶部142。控制裝置140例如包含具有CPU(Central Processing Unit)、ROM(Read Only Memory)、RAM(Random Access Memory)、HDD(Hard Disk Drive)、及輸出入埠等的電腦或各種之電路。The control device 140 includes a control unit 141 and a memory unit 142. The control device 140 includes, for example, a computer or various circuits including a CPU (Central Processing Unit), ROM (Read Only Memory), RAM (Random Access Memory), HDD (Hard Disk Drive), and I/O ports.

電腦之CPU例如讀出記憶於ROM的程式並執行。據此,電腦之CPU作為控制部141而發揮功能。又,控制部141之一部分或全部由硬體構成亦可。硬體例如為ASIC(Application Specific Integrated Circuit)或FPGA(Field Programmable Gate Array)等。The CPU of the computer, for example, reads and executes programs stored in the ROM. Accordingly, the CPU of the computer functions as the control unit 141. Furthermore, part or all of the control unit 141 may be made of hardware. The hardware is, for example, ASIC (Application Specific Integrated Circuit) or FPGA (Field Programmable Gate Array).

又,記憶部142例如與RAM或HDD對應。又,控制裝置140經由以有線或無線之網路連接的其他之電腦或可攜式記憶媒體取得上述程式或各種資訊亦可。作為電腦可讀取的記憶媒體例如有硬碟(HD)、軟碟(FD)、光碟(CD)、光磁碟(MO)、記憶卡等。Moreover, the memory unit 142 corresponds to, for example, RAM or HDD. In addition, the control device 140 may obtain the above program or various information through another computer or a portable memory medium connected by a wired or wireless network. Examples of computer-readable memory media include hard disks (HD), floppy disks (FD), optical disks (CD), optical disks (MO), and memory cards.

接著,對使用基板處理系統100的基板處理方法進行說明。收納有複數片基板10的基板收納盒C被載置於基板收納盒載置台111上時,基板搬送體113從基板收納盒載置台111上之基板收納盒C依序取出基板10,搬送至電洞注入層形成區塊121。Next, a substrate processing method using the substrate processing system 100 will be described. When the substrate storage box C storing the plurality of substrates 10 is placed on the substrate storage box mounting table 111, the substrate transport body 113 sequentially takes out the substrate 10 from the substrate storage box C on the substrate storage box mounting table 111 and transports it to the electric The hole injection layer forms block 121.

電洞注入層形成區塊121係將電洞注入層24用之塗布液塗布於陽極21上形成塗布層,對形成的塗布層進行乾燥、燒結而形成電洞注入層24。形成有電洞注入層24的基板10係經由交接裝置TR4從電洞注入層形成區塊121被交接至電洞輸送層形成區塊122。The hole injection layer forming block 121 applies the coating solution for the hole injection layer 24 to the anode 21 to form a coating layer, and the formed coating layer is dried and sintered to form the hole injection layer 24. The substrate 10 on which the hole injection layer 24 is formed is transferred from the hole injection layer formation block 121 to the hole transport layer formation block 122 via the transfer device TR4.

電洞輸送層形成區塊122係將電洞輸送層25用之塗布液塗布於電洞注入層24上而形成塗布層,對形成的塗布層進行乾燥、燒結而形成電洞輸送層25。形成有電洞輸送層25的基板10係藉由交接裝置TR7從電洞輸送層形成區塊122被交接至發光層形成區塊123。The hole transport layer forming block 122 applies the coating solution for the hole transport layer 25 on the hole injection layer 24 to form a coating layer, and the formed coating layer is dried and sintered to form the hole transport layer 25. The substrate 10 on which the hole transport layer 25 is formed is transferred from the hole transport layer formation block 122 to the light emitting layer formation block 123 by the transfer device TR7.

發光層形成區塊123係將發光層26用之塗布液塗布於電洞輸送層25上而形成塗布層,對形成的塗布層進行乾燥、燒結而形成發光層26。形成有發光層26的基板10係藉由交接裝置TR10從發光層形成區塊123被交接至搬出站130。The light-emitting layer forming block 123 applies the coating solution for the light-emitting layer 26 on the hole transport layer 25 to form a coating layer, and the formed coating layer is dried and sintered to form the light-emitting layer 26. The substrate 10 on which the light-emitting layer 26 is formed is transferred from the light-emitting layer formation block 123 to the carry-out station 130 by the transfer device TR10.

搬出站130之基板搬送體133,係將從交接裝置TR10受取的基板10收納於基板收納盒載置台131上之規定之基板收納盒C。據此,基板處理系統100中的一連串之基板10之處理結束。The substrate transport body 133 of the unloading station 130 is a predetermined substrate storage box C that stores the substrate 10 received from the transfer device TR10 on the substrate storage box mounting table 131. Accordingly, the series of processing of the substrate 10 in the substrate processing system 100 ends.

基板10被收納於基板收納盒C之狀態下,從搬出站130搬出至外部。對搬出至外部的基板10形成電子輸送層27或電子注入層28、陰極22等。In a state where the substrate 10 is stored in the substrate storage box C, it is carried out from the carry-out station 130 to the outside. An electron transport layer 27, an electron injection layer 28, a cathode 22, and the like are formed on the substrate 10 carried out to the outside.

<塗布裝置及塗布方法> 接著,參照圖8及圖9說明發光層形成區塊123之塗布裝置123a。圖8係表示實施形態之塗布裝置123a之構成之模式平面圖。又,圖9係表示實施形態之塗布裝置123a之構成之模式側面圖。<Coating device and coating method> Next, the coating device 123a of the light-emitting layer formation block 123 will be described with reference to FIGS. 8 and 9. 8 is a schematic plan view showing the configuration of the coating device 123a of the embodiment. 9 is a schematic side view showing the configuration of the coating device 123a of the embodiment.

圖8及圖9中,Y軸方向為吐出同一塗布液之液滴的複數個噴嘴並列的行方向,X軸方向為與Y軸方向正交的掃描方向。又,行方向與掃描方向只要交叉即可,不一定要正交。In FIGS. 8 and 9, the Y-axis direction is a row direction in which a plurality of nozzles ejecting droplets of the same coating liquid are aligned, and the X-axis direction is a scanning direction orthogonal to the Y-axis direction. In addition, the row direction and the scanning direction only need to cross, and need not be orthogonal.

如圖8及圖9所示,塗布裝置123a例如具備:對基板10進行保持並移動的站台150;向基板10吐出液滴的吐出單元160;及維持吐出單元160之功能的保養單元170。As shown in FIGS. 8 and 9, the coating device 123 a includes, for example, a platform 150 that holds and moves the substrate 10; a discharge unit 160 that discharges liquid droplets to the substrate 10; and a maintenance unit 170 that maintains the function of the discharge unit 160.

站台150與保養單元170並列設置於Y軸方向。在站台150之上方與保養單元170之上方之間架設有Y軸導引部180。吐出單元160設為沿著Y軸導引部180在Y軸方向移動自如。作為使吐出單元160在Y軸方向移動的驅動部可以使用線性馬達等。The platform 150 and the maintenance unit 170 are arranged in parallel in the Y-axis direction. A Y-axis guide 180 is erected between the top of the platform 150 and the top of the maintenance unit 170. The discharge unit 160 is configured to move freely in the Y-axis direction along the Y-axis guide 180. As a driving unit that moves the discharge unit 160 in the Y-axis direction, a linear motor or the like can be used.

站台150具備將基板10以水平方式進行保持的基板保持部151,及使基板保持部151移動的移動機構152。基板保持部151係使塗布基板10之液滴的塗布面向上而對基板10進行保持。作為基板保持部151例如真空吸盤,但亦可以使用靜電吸盤等。移動機構152具備:使基板保持部151朝X軸方向移動的X軸方向驅動部153,使基板保持部151朝Y軸方向移動的Y軸方向驅動部154,及使基板保持部151繞Z軸旋轉的旋轉驅動部155等。The platform 150 includes a substrate holding portion 151 that holds the substrate 10 horizontally, and a moving mechanism 152 that moves the substrate holding portion 151. The substrate holding portion 151 holds the substrate 10 with the coating surface of the droplets coating the substrate 10 upward. As the substrate holding portion 151, for example, a vacuum chuck, an electrostatic chuck or the like may be used. The moving mechanism 152 includes an X-axis direction driving portion 153 that moves the substrate holding portion 151 in the X-axis direction, a Y-axis direction driving portion 154 that moves the substrate holding portion 151 in the Y-axis direction, and moves the substrate holding portion 151 around the Z axis The rotation drive unit 155 and the like rotate.

吐出單元160係於在站台150之上方向基板10吐出液滴的位置,與接受基於保養單元170之功能維持之處理的位置之間移動自如。吐出單元160在Y軸方向配置有複數個(於此為10個)。複數個吐出單元160,獨立沿著Y軸方向移動亦可,一體沿著Y軸方向移動亦可。The discharge unit 160 is freely movable between the position where the liquid droplet is discharged toward the substrate 10 above the platform 150 and the position subjected to the processing maintained by the function of the maintenance unit 170. A plurality of discharge units 160 are arranged in the Y-axis direction (here, 10). The plurality of discharge units 160 may move independently along the Y-axis direction, or may move integrally along the Y-axis direction.

各吐出單元160具備運輸部161,及設置於運輸部161之下面的複數個噴頭162。於各噴頭162設置有至少1列由沿著Y軸方向並列的複數個噴嘴163構成的噴嘴列。設置於同一噴頭162的複數個噴嘴163吐出同一塗布液之液滴。吐出紅色發光層26R用之塗布液之液滴的噴嘴163,與吐出綠色發光層26G用之塗布液之液滴的噴嘴163,與吐出藍色發光層26B用之塗布液之液滴的噴嘴163係設置於個別之噴頭162。Each discharge unit 160 includes a transport unit 161 and a plurality of heads 162 provided below the transport unit 161. Each nozzle 162 is provided with at least one nozzle row composed of a plurality of nozzles 163 aligned in the Y-axis direction. A plurality of nozzles 163 provided in the same head 162 eject droplets of the same coating liquid. Nozzle 163 for discharging liquid droplets of the coating liquid for the red light-emitting layer 26R, nozzle 163 for discharging liquid droplets of the coating liquid for the green light-emitting layer 26G, and nozzle 163 for discharging liquid droplets of the coating liquid for the blue light-emitting layer 26B It is set in the individual nozzle 162.

保養單元170進行維持吐出單元160之功能的處理,消除吐出單元160之吐出不良。保養單元170具備對噴嘴之吐出口之周圍進行擦拭的擦拭單元171;及從噴嘴之吐出口吸引液滴的吸引單元172。吸引單元172亦達成塞住休止狀態之噴嘴之吐出口,抑制乾燥引起的堵塞任務。The maintenance unit 170 performs a process of maintaining the function of the discharge unit 160 to eliminate the discharge failure of the discharge unit 160. The maintenance unit 170 includes a wiping unit 171 that wipes around the discharge port of the nozzle; and a suction unit 172 that sucks liquid droplets from the discharge port of the nozzle. The suction unit 172 also achieves the discharge port that plugs the nozzle in the rest state, and suppresses the clogging task caused by drying.

接著,說明使用上述構成之塗布裝置123a的塗布方法。塗布裝置123a之以下之動作係藉由控制裝置140控制。又,圖7中,控制裝置140,係和塗布裝置123a係分別設置,但亦可以作為塗布裝置123a之一部分而設置。Next, a coating method using the coating device 123a configured as described above will be described. The following operations of the coating device 123a are controlled by the control device 140. In addition, in FIG. 7, the control device 140 and the coating device 123a are provided separately, but they may be provided as part of the coating device 123a.

首先,從塗布裝置123a之外部搬入內部的基板10被載置於基板保持部151時,基板保持部151將基板10保持。接著,依據對基板10之對準標記攝影的圖像,進行基於移動機構152的基板保持部151之位置補正。之後,移動機構152使基板保持部151朝X軸方向移動,通過吐出單元160之下。於該期間,吐出單元160向基板10吐出塗布液之液滴。之後,移動機構152變更基板保持部151之Y軸方向之位置,使基板保持部151再度朝X軸方向移動,通過吐出單元160之下。於該期間,吐出單元160向基板10吐出塗布液之液滴。藉由重複進行上述,塗布裝置123a在基板10上描繪規定之圖案。First, when the substrate 10 carried into the interior from the outside of the coating device 123a is placed on the substrate holding portion 151, the substrate holding portion 151 holds the substrate 10. Next, based on the image of the alignment mark of the substrate 10, the position of the substrate holding portion 151 by the moving mechanism 152 is corrected. Thereafter, the moving mechanism 152 moves the substrate holding portion 151 in the X-axis direction and passes under the discharge unit 160. During this period, the discharge unit 160 discharges the droplets of the coating liquid onto the substrate 10. After that, the moving mechanism 152 changes the position of the substrate holding portion 151 in the Y-axis direction, and moves the substrate holding portion 151 again in the X-axis direction to pass under the discharge unit 160. During this period, the discharge unit 160 discharges the droplets of the coating liquid onto the substrate 10. By repeating the above, the coating device 123a draws a predetermined pattern on the substrate 10.

已描畫結束的基板10從基板保持部151被取出,從塗布裝置123a之內部搬出至外部。接著,次一基板10從塗布裝置123a之外部被搬入內部,塗布裝置123a在基板10上描繪規定之圖案。又,藉由保養單元170維持吐出單元160之功能的處理,基板10之更換之空檔等適當進行。The drawn substrate 10 is taken out from the substrate holding portion 151, and carried out from the inside of the coating device 123a to the outside. Next, the next substrate 10 is carried into the interior from the outside of the coating device 123 a, and the coating device 123 a draws a predetermined pattern on the substrate 10. In addition, the process of maintaining the function of the discharge unit 160 by the maintenance unit 170, the replacement of the substrate 10, and the like are appropriately performed.

又,塗布裝置123a使向基板10吐出液滴的吐出單元160移動亦可,使基板保持部151及吐出單元160之兩方移動亦可。亦即,塗布裝置123a只要使基板保持部151與吐出單元160可以相對地移動即可。In addition, the coating device 123a may move the discharge unit 160 that discharges liquid droplets to the substrate 10, or may move both the substrate holding portion 151 and the discharge unit 160. That is, the coating device 123a only needs to move the substrate holding portion 151 and the discharge unit 160 relatively.

<塗布裝置描繪的描畫圖案> 接著,參照圖10說明塗布裝置123a描繪的描畫圖案。圖10係表示實施形態之塗布裝置123a描繪的描畫圖案之平面圖。<Drawing pattern drawn by the coating device> Next, the drawing pattern drawn by the coating device 123a will be described with reference to FIG. 10 is a plan view showing a drawing pattern drawn by the coating device 123a of the embodiment.

如圖10所示,有機EL顯示器1按每一個像素例如具有紅色發光區域261R、綠色發光區域261G、及藍色發光區域261B。As shown in FIG. 10, the organic EL display 1 has, for example, a red light-emitting region 261R, a green light-emitting region 261G, and a blue light-emitting region 261B for each pixel.

紅色發光區域261R相當於具有紅色發光層26R的有機EL層23中的被陽極21與陰極22夾持的區域。綠色發光區域261G相當於具有綠色發光層26G的有機EL層23中的被陽極21與陰極22夾持的區域。藍色發光區域261B相當於具有藍色發光層26B的有機EL層23中的被陽極21與陰極22夾持的區域。各發光區域261R、261G、261B按每一陽極21獨立發光,其發光量藉由陽極21與陰極22之間之電壓進行調整。The red light emitting region 261R corresponds to a region sandwiched between the anode 21 and the cathode 22 in the organic EL layer 23 having the red light emitting layer 26R. The green light emitting region 261G corresponds to a region sandwiched between the anode 21 and the cathode 22 in the organic EL layer 23 having the green light emitting layer 26G. The blue light emitting region 261B corresponds to a region sandwiched between the anode 21 and the cathode 22 in the organic EL layer 23 having the blue light emitting layer 26B. Each light-emitting area 261R, 261G, 261B emits light independently for each anode 21, and the amount of light emitted is adjusted by the voltage between the anode 21 and the cathode 22.

紅色發光區域261R、綠色發光區域261G及藍色發光區域261B係沿著X軸方向依據該順序隔開間隔重複進行配列,據此,而形成發光區域群262。於有機EL顯示器1,使複數個發光區域群262沿著Y軸方向隔開間隔進行配列。因此,於有機EL顯示器1,在Y軸方向並列有發出同一色的複數個發光區域。The red light-emitting region 261R, the green light-emitting region 261G, and the blue light-emitting region 261B are repeatedly arranged at intervals along the X-axis direction according to the order, and accordingly, the light-emitting region group 262 is formed. In the organic EL display 1, a plurality of light-emitting region groups 262 are arranged at intervals along the Y-axis direction. Therefore, in the organic EL display 1, a plurality of light-emitting regions emitting the same color are arranged in parallel in the Y-axis direction.

以朝向在Y軸方向隔開間隔而且發出同一色之光的複數個發光區域可以同時且吐出同一塗布液之液滴的方式,使複數個噴嘴163沿著Y軸方向並列設置在吐出單元160之各噴頭162。設置於同一噴頭162的複數個噴嘴163係吐出同一塗布液之液滴。A plurality of nozzles 163 are arranged side by side in the discharge unit 160 along the Y-axis direction in such a manner that a plurality of light-emitting areas spaced apart in the Y-axis direction and emit light of the same color can be discharged simultaneously and simultaneously Each nozzle 162. A plurality of nozzles 163 provided in the same head 162 eject droplets of the same coating liquid.

塗布裝置123a吐出單元160與基板保持部151朝X軸方向相對地移動,從噴嘴163朝向基板保持部151所保持的基板10上事先形成的堤岸30之開口部31塗布液滴。The coating device 123a discharge unit 160 relatively moves in the X-axis direction with the substrate holding portion 151, and applies droplets from the nozzle 163 toward the opening 31 of the bank 30 formed in advance on the substrate 10 held by the substrate holding portion 151.

如圖10所示,堤岸30之開口部31跨越在Y軸方向相鄰的2個發光區域。因此,可以緩和Y軸方向中的塗布液之液滴之著陸位置之容許誤差。As shown in FIG. 10, the opening 31 of the bank 30 spans two light-emitting regions adjacent in the Y-axis direction. Therefore, the tolerance of the landing position of the droplet of the coating liquid in the Y-axis direction can be alleviated.

又,從2個噴嘴163朝向1個開口部31吐出塗布液之液滴,因此各噴嘴163之吐出量之誤差被分散,可以抑制吐出量之總量之偏差。又,朝向1個開口部31吐出液滴的噴嘴163之選擇範圍增加,吐出量之控制性良好的噴嘴163可以被選擇使用。據此,發光層26之厚度可以均勻化。In addition, since the droplets of the coating liquid are discharged from the two nozzles 163 toward one opening 31, the error in the discharge amount of each nozzle 163 is dispersed, and the variation in the total amount of discharge can be suppressed. In addition, the selection range of the nozzle 163 that ejects liquid droplets toward one opening 31 is increased, and the nozzle 163 with excellent controllability of the ejection amount can be selected for use. Accordingly, the thickness of the light-emitting layer 26 can be made uniform.

<第1變形例的描畫圖案> 接著,對本實施形態中的第1變形例的描畫圖案參照圖11進行說明。圖11係表示實施形態中的第1變形例的描畫圖案之平面圖。<Drawing pattern of the first modification> Next, the drawing pattern of the first modification in this embodiment will be described with reference to FIG. 11. Fig. 11 is a plan view showing a drawing pattern in a first modification of the embodiment.

紅色發光區域261R、綠色發光區域261G及藍色發光區域261B之面積比依據個別之發光特性或發光壽命等適當設定。例如發光效率良好,每一單位面積之發光亮度越高者,具有越小面積。The area ratio of the red light-emitting region 261R, the green light-emitting region 261G, and the blue light-emitting region 261B is appropriately set according to individual light-emitting characteristics, light-emitting life, and the like. For example, the luminous efficiency is good. The higher the luminous brightness per unit area, the smaller the area.

圖11中,紅色發光區域261R之面積最小,綠色發光區域261G之面積第2小,藍色發光區域261B之面積最大。彼等發光區域261R、261G、261B之Y軸方向之尺寸YR、YG、YB相同,X軸方向之尺寸XR、XG、XB分別不同。具體言之,紅色發光區域261R之Y軸方向之尺寸YR、綠色發光區域261G之Y軸方向之尺寸YG及藍色發光區域261B之Y軸方向之尺寸YB相同。又,紅色發光區域261R之X軸方向之尺寸XR較綠色發光區域261G之X軸方向之尺寸XG為小,綠色發光區域261G之X軸方向之尺寸XG較藍色發光區域261B之X軸方向之尺寸XB為小。In FIG. 11, the area of the red light emitting region 261R is the smallest, the area of the green light emitting region 261G is the second smallest, and the area of the blue light emitting region 261B is the largest. The dimensions YR, YG, and YB of the light-emitting regions 261R, 261G, and 261B in the Y-axis direction are the same, and the dimensions XR, XG, and XB in the X-axis direction are different from each other. Specifically, the size YR of the red light emitting region 261R in the Y axis direction, the size YG of the green light emitting region 261G in the Y axis direction, and the size YB of the blue light emitting region 261B in the Y axis direction are the same. Moreover, the X-axis dimension XR of the red light-emitting region 261R is smaller than the X-axis direction XG of the green light-emitting region 261G, and the X-axis direction XG of the green light-emitting region 261G is smaller than the X-axis direction of the blue light-emitting region 261B The size XB is small.

第1變形例中,沿著X軸方向以使2個紅色發光區域261R相鄰的方式配列有複數個紅色發光區域261R、綠色發光區域261G及藍色發光區域261B。具體言之,綠色發光區域261G、藍色發光區域261B、紅色發光區域261R、紅色發光區域261R、綠色發光區域261G、藍色發光區域261B依序重複進行配列而形成1個發光區域群262。換言之,在X軸方向相鄰的2個像素中,紅色發光區域261R、綠色發光區域261G及藍色發光區域261B之配列順序反轉。In the first modification, a plurality of red light-emitting regions 261R, green light-emitting regions 261G, and blue light-emitting regions 261B are arranged along the X-axis direction so that two red light-emitting regions 261R are adjacent to each other. Specifically, the green light-emitting region 261G, the blue light-emitting region 261B, the red light-emitting region 261R, the red light-emitting region 261R, the green light-emitting region 261G, and the blue light-emitting region 261B are repeatedly arranged in sequence to form one light-emitting region group 262. In other words, in the two pixels adjacent in the X-axis direction, the arrangement order of the red light emitting region 261R, the green light emitting region 261G, and the blue light emitting region 261B is reversed.

第1變形例中,堤岸30之開口部31,係和上述實施形態同樣地,使與在Y軸方向相鄰的2個同色之副像素對應而設置的2個陽極21露出。據此,可以緩和Y軸方向中的塗布液之液滴之著陸位置之容許誤差。In the first modification, the opening 31 of the bank 30 exposes two anodes 21 provided corresponding to two sub-pixels of the same color adjacent in the Y-axis direction, as in the above-described embodiment. According to this, the allowable error of the landing position of the droplet of the coating liquid in the Y-axis direction can be alleviated.

還有,第1變形例中,堤岸30之開口部31係使與在X軸方向相鄰的2個同色之副像素對應而設置的2個陽極21露出。於此,使與在X軸方向相鄰的2個紅色發光區域261R對應的2個陽極21露出。據此,一邊使吐出單元160與基板保持部151沿著X軸方向相對地移動,一邊使液滴著陸於紅色用開口部31R變為容易。因此,可以緩和X軸方向中的紅色發光區域261R用之塗布液之液滴之著陸位置之容許誤差。又,藉由將X軸方向之尺寸最小的紅色發光區域261R在X軸方向連結,可以有效緩和X軸方向中的塗布液之液滴之著陸位置之容許誤差。In the first modification, the opening 31 of the bank 30 exposes two anodes 21 provided corresponding to two sub-pixels of the same color adjacent in the X-axis direction. Here, the two anodes 21 corresponding to the two red light emitting regions 261R adjacent in the X-axis direction are exposed. According to this, it becomes easy to land the liquid droplet on the red opening 31R while moving the discharge unit 160 and the substrate holding portion 151 relatively in the X-axis direction. Therefore, the tolerance of the landing position of the droplet of the coating liquid for the red light-emitting region 261R in the X-axis direction can be alleviated. In addition, by connecting the red light emitting region 261R with the smallest dimension in the X-axis direction in the X-axis direction, the allowable error of the landing position of the droplet of the coating liquid in the X-axis direction can be effectively alleviated.

如此般,第1變形例中,堤岸30之開口部31係使與Y軸方向及X軸方向相鄰的4個同色(於此為紅色)之副像素對應而設置的4個陽極21露出。據此,可以緩和Y軸方向及X軸方向中的塗布液之液滴之著陸位置之容許誤差。又,藉由將面積最小的紅色發光區域261R在Y軸方向及X軸方向連結,可以有效緩和Y軸方向及X軸方向中的塗布液之液滴之著陸位置之容許誤差。In this way, in the first modification, the opening 31 of the bank 30 exposes four anodes 21 provided corresponding to four sub-pixels of the same color (here, red) adjacent to the Y-axis direction and the X-axis direction. According to this, the allowable error of the landing position of the droplet of the coating liquid in the Y-axis direction and the X-axis direction can be alleviated. In addition, by connecting the red light-emitting region 261R with the smallest area in the Y-axis direction and the X-axis direction, the allowable error of the landing position of the droplet of the coating liquid in the Y-axis direction and the X-axis direction can be effectively alleviated.

第1變形例中,於有機EL顯示器1,係和上述實施形態同樣地,對1個開口部31形成1個接觸孔50。因此,第1變形例的有機EL顯示器1中,對4個紅色發光區域261R形成1個接觸孔50。又,第1變形例的有機EL顯示器1中,對2個綠色發光區域261G形成1個接觸孔50,對2個藍色發光區域261B形成1個接觸孔50。In the first modification, in the organic EL display 1, one contact hole 50 is formed in one opening 31 in the same manner as in the above embodiment. Therefore, in the organic EL display 1 of the first modification, one contact hole 50 is formed for the four red light emitting regions 261R. Furthermore, in the organic EL display 1 of the first modification, one contact hole 50 is formed for two green light emitting regions 261G, and one contact hole 50 is formed for two blue light emitting regions 261B.

於此,示出1個開口部31使與X軸方向相鄰的2個同色之副像素對應而設置的2個陽極21露出的情況之例。但不限定於此,開口部31使與X軸方向相鄰的3個以上之同色之副像素對應而設置的2個陽極21露出亦可。Here, an example is shown in which one opening 31 exposes two anodes 21 provided corresponding to two sub-pixels of the same color adjacent to the X-axis direction. However, it is not limited to this, and the opening 31 may expose two anodes 21 provided corresponding to three or more sub-pixels of the same color adjacent in the X-axis direction.

又,於此,示出1個開口部31使與Y軸方向及X軸方向相鄰的4個紅色發光區域261R對應而設置的4個陽極21露出的情況之例。但不限定於此,開口部31使與Y軸方向及X軸方向相鄰的4個綠色發光區域261G對應而設置的4個陽極21露出亦可。該情況下,發光區域群262例如使紅色發光區域261R、藍色發光區域261B、綠色發光區域261G、綠色發光區域261G、藍色發光區域261B、紅色發光區域261R依序重複進行配列而形成亦可。Here, an example is shown in which one opening 31 exposes four anodes 21 provided corresponding to four red light emitting regions 261R adjacent to the Y-axis direction and the X-axis direction. However, it is not limited to this, and the opening 31 may expose the four anodes 21 provided corresponding to the four green light emitting regions 261G adjacent to the Y-axis direction and the X-axis direction. In this case, for example, the light emitting region group 262 may be formed by repeatedly arranging the red light emitting region 261R, the blue light emitting region 261B, the green light emitting region 261G, the green light emitting region 261G, the blue light emitting region 261B, and the red light emitting region 261R in this order. .

同樣地,開口部31使與Y軸方向及X軸方向相鄰的4個藍色發光區域261B對應而設置的4個陽極21露出亦可。該情況下,發光區域群262例如和圖11同樣,使綠色發光區域261G、藍色發光區域261B、紅色發光區域261R、紅色發光區域261R、綠色發光區域261G、藍色發光區域261B依序重複進行配列而形成亦可。Similarly, the opening 31 may expose the four anodes 21 provided corresponding to the four blue light emitting regions 261B adjacent to the Y-axis direction and the X-axis direction. In this case, the light-emitting region group 262, for example, as shown in FIG. 11, repeats the green light-emitting region 261G, the blue light-emitting region 261B, the red light-emitting region 261R, the red light-emitting region 261R, the green light-emitting region 261G, and the blue light-emitting region 261B sequentially It can be formed by arrangement.

又,第1變形例中,在Y軸方向及X軸方向之兩方向將發光區域連結,但開口部31為僅在X軸方向將發光區域連結者亦可。亦即,開口部31為僅使與X軸方向相鄰的2個同色之副像素對應而設置的2個陽極21露出者亦可。Furthermore, in the first modification, the light-emitting regions are connected in both the Y-axis direction and the X-axis direction, but the opening 31 may be the one that connects the light-emitting regions only in the X-axis direction. That is, the opening 31 may be exposed only by two anodes 21 provided corresponding to two sub-pixels of the same color adjacent to the X-axis direction.

<第2變形例的描畫圖案> 圖12係表示實施形態中的第2變形例的描畫圖案之平面圖。如圖12所示,第2變形例的有機EL顯示器1,具有使與在Y軸方向相鄰的複數個同色之副像素對應而設置的複數個陽極21露出的開口部31。例如第2變形例的開口部31,係使並列於Y軸方向之全部之陽極21之各一部分露出。換言之,第2變形例的開口部31,係跨越Y軸方向之複數個陽極21之中之位於最靠近Y軸正方向側的陽極21至最靠近Y軸方向負方向側的陽極21而形成。<Drawing pattern of the second modification> 12 is a plan view showing a drawing pattern of a second modification in the embodiment. As shown in FIG. 12, the organic EL display 1 of the second modification has an opening 31 that exposes a plurality of anodes 21 provided corresponding to a plurality of sub-pixels of the same color adjacent in the Y-axis direction. For example, the opening 31 of the second modification exposes each part of all anodes 21 juxtaposed in the Y-axis direction. In other words, the opening 31 of the second modification is formed across the anode 21 located closest to the positive side of the Y axis to the anode 21 closest to the negative side of the Y axis in the plurality of anodes 21 in the Y axis direction.

第2變形例中,接觸孔50係形成於在X軸方向相鄰的2個開口部31之間之區域。如第2變形例這樣,開口部31在Y軸方向長的情況下,若在Y軸方向與開口部31相鄰的位置形成接觸孔50時,對有機EL顯示器1形成足夠數之接觸孔50會有困難。In the second modification, the contact hole 50 is formed in a region between two openings 31 adjacent in the X-axis direction. As in the second modification, when the opening 31 is long in the Y-axis direction, if a contact hole 50 is formed at a position adjacent to the opening 31 in the Y-axis direction, a sufficient number of contact holes 50 are formed in the organic EL display 1 There will be difficulties.

於此,第2變形例中,將接觸孔50形成於在X軸方向相鄰的2個開口部31之間之區域。據此,即使在Y軸方向較長的開口部31被形成於有機EL顯示器1之情況下,亦可以將最適宜之數之接觸孔50形成於有機EL顯示器1。Here, in the second modification, the contact hole 50 is formed in a region between two openings 31 adjacent in the X-axis direction. According to this, even in the case where the long opening 31 in the Y-axis direction is formed in the organic EL display 1, the most suitable number of contact holes 50 can be formed in the organic EL display 1.

於此,X軸方向相鄰的2個開口部31之間之區域,在確保形成接觸孔50必要的X軸方向之尺寸上會有困難之情況。Here, in the area between the two openings 31 adjacent in the X-axis direction, it may be difficult to ensure the size of the contact hole 50 in the X-axis direction.

於此,如圖12所示,在X軸方向相鄰的2個開口部31之間之區域之中,僅使形成接觸孔50之區域局部性朝X軸方向擴大亦可。換言之,開口部31中,與接觸孔50相鄰的部分中的X軸方向之尺寸XR1、XG1、XB1形成為比其他部分中的X軸方向之尺寸XR2、XG2、XB2窄亦可。據此,在不增大X軸方向中的開口部31彼此之間隔之情況下可以確保形成接觸孔50之空間。Here, as shown in FIG. 12, in the region between the two openings 31 adjacent in the X-axis direction, only the region where the contact hole 50 is formed may be partially enlarged in the X-axis direction. In other words, in the opening portion 31, the dimensions XR1, XG1, and XB1 in the X-axis direction in the portion adjacent to the contact hole 50 may be formed to be narrower than the dimensions XR2, XG2, and XB2 in the X-axis direction in the other portions. According to this, a space where the contact hole 50 is formed can be ensured without increasing the interval between the opening portions 31 in the X-axis direction.

如第2變形例這樣使形成接觸孔50之區域朝X軸方向擴大之情況下,較好是使與接觸孔50相鄰的部分中的開口部31之X軸方向之尺寸XR1、XG1、XB1形成為比噴嘴163之吐出口之口徑大。藉由這樣的形成,可以抑制從噴嘴163吐出的塗布液之液滴溢出開口部31而進入接觸孔50。When the area where the contact hole 50 is formed is enlarged in the X-axis direction as in the second modification, it is preferable to make the dimension XR1, XG1, XB1 in the X-axis direction of the opening 31 in the portion adjacent to the contact hole 50 It has a larger diameter than the discharge port of the nozzle 163. With such a formation, the droplets of the coating liquid discharged from the nozzle 163 can be prevented from overflowing the opening 31 and entering the contact hole 50.

於此,示出按同色之2個副像素形成1個接觸孔50之情況之例。但不限定於此,接觸孔50按同色之每3個以上之副像素形成亦可。Here, an example is shown in which one contact hole 50 is formed for two sub-pixels of the same color. However, it is not limited to this, and the contact hole 50 may be formed for every three or more sub-pixels of the same color.

<第3變形例的描畫圖案> 圖13係表示實施形態中的第3變形例的描畫圖案之平面圖。第3變形例中,接觸孔50按相鄰的每複數個不同色之副像素設置亦可。例如圖13所示有機EL顯示器1中,接觸孔50按構成1個像素的每3個副像素亦即紅色之副像素、綠色之副像素及藍色之副像素設置。換言之,接觸孔50按1像素設置1個。<Drawing pattern of the third modification> 13 is a plan view showing a drawing pattern in a third modification of the embodiment. In the third modification, the contact holes 50 may be provided for each adjacent plurality of sub-pixels of different colors. For example, in the organic EL display 1 shown in FIG. 13, the contact holes 50 are provided for every three sub-pixels that constitute one pixel, that is, red sub-pixels, green sub-pixels, and blue sub-pixels. In other words, one contact hole 50 is provided per pixel.

於此,綠色發光區域261G之開口部31與藍色發光區域261B之開口部31之間隔,形成為比紅色發光區域261R之開口部31與綠色發光區域261G之開口部31之間隔大。因此,將接觸孔50形成於綠色發光區域261G之開口部31與藍色發光區域261B之開口部31之間之區域為較佳。又,但不限定於此,接觸孔50例如形成於Y軸方向相鄰的2個像素之間之區域亦可,形成於X軸方向相鄰的2個像素之間之區域亦可。又,接觸孔50按相鄰的每複數個像素設置亦可。Here, the distance between the opening 31 of the green light emitting region 261G and the opening 31 of the blue light emitting region 261B is formed to be larger than the distance between the opening 31 of the red light emitting region 261R and the opening 31 of the green light emitting region 261G. Therefore, it is preferable to form the contact hole 50 between the opening 31 of the green light emitting region 261G and the opening 31 of the blue light emitting region 261B. In addition, but not limited to this, the contact hole 50 may be formed, for example, in a region between two pixels adjacent in the Y-axis direction, or may be formed in a region between two pixels adjacent in the X-axis direction. In addition, the contact holes 50 may be provided for every plurality of adjacent pixels.

又,接觸孔50不限定於像素單位(紅色、藍色及綠色之每3個副像素),按相鄰的不同色之每2個副像素設置亦可,按包含不同色的相鄰的每4個副像素設置亦可。相鄰的方向不限定於上下左右,斜向亦可。又,接觸孔50按不相鄰的每2個以上之副像素設置亦可。如此般,接觸孔50按複數個任意之副像素單位設置亦可。In addition, the contact hole 50 is not limited to the pixel unit (every 3 sub-pixels of red, blue, and green), and may be provided for every 2 sub-pixels of adjacent different colors, or each adjacent sub-pixel including different colors. 4 sub-pixels can also be set. The adjacent direction is not limited to up, down, left, and right, and may be diagonal. In addition, the contact holes 50 may be provided for every two or more sub-pixels that are not adjacent. In this way, the contact holes 50 may be provided in plural arbitrary sub-pixel units.

於此,以未形成像素連結的有機EL顯示器1為例進行說明,但有機EL顯示器1,例如圖10、圖12所示,具有跨越Y軸方向相鄰的複數個同色之發光區域的開口部31亦可。Here, the organic EL display 1 without pixel connection will be described as an example. However, the organic EL display 1 has, for example, as shown in FIGS. 10 and 12, openings of a plurality of light emitting regions of the same color adjacent in the Y-axis direction 31 is also possible.

如上述說明,實施形態之塗布裝置123a具備基板保持部151、吐出單元160及移動機構152。基板保持部151將基板10進行保持。吐出單元160包含複數個噴頭162,該噴頭162在第1方向(一例為Y軸方向)並列設置有複數個噴嘴163。移動機構152使吐出單元160與基板保持部151相對地沿著與第1方向交叉的第2方向(一例為X軸方向)移動。基板10具備:與複數個副像素對應而設置的複數個像素電極(一例為陽極21);堤岸30,覆蓋複數個像素電極,並且形成有使至少1個像素電極露出的複數個開口部31;及複數個接觸孔50,用以將與複數個像素電極對向的對向電極電連接於補助電極51。接觸孔50按每2個以上之副像素設置。吐出單元160從噴嘴163朝向基板保持部151所保持的基板10之開口部31吐出有機材料之液滴。As described above, the coating device 123a of the embodiment includes the substrate holding portion 151, the discharge unit 160, and the moving mechanism 152. The substrate holding portion 151 holds the substrate 10. The discharge unit 160 includes a plurality of heads 162, and the plurality of nozzles 163 are arranged in parallel in the first direction (an example is the Y-axis direction). The moving mechanism 152 moves the discharge unit 160 relative to the substrate holding portion 151 in a second direction (an example is the X-axis direction) crossing the first direction. The substrate 10 includes: a plurality of pixel electrodes (an anode 21) provided corresponding to the plurality of sub-pixels; a bank 30 covering the plurality of pixel electrodes, and a plurality of openings 31 exposing at least one pixel electrode are formed; And a plurality of contact holes 50 for electrically connecting the counter electrode facing the plurality of pixel electrodes to the auxiliary electrode 51. The contact holes 50 are provided for every two or more sub-pixels. The discharge unit 160 discharges droplets of organic material from the nozzle 163 toward the opening 31 of the substrate 10 held by the substrate holding portion 151.

因此,依據實施形態之塗布裝置123a,可以提供補助電極51用之接觸孔50之數目被最佳化的有機EL顯示器1。Therefore, according to the coating device 123a of the embodiment, it is possible to provide the organic EL display 1 in which the number of contact holes 50 for the auxiliary electrode 51 is optimized.

開口部31使與相鄰的2個以上之同色之副像素對應而設置的2個以上之像素電極露出亦可。該情況下,接觸孔50按由開口部31露出的2個以上之像素電極所對應的每2個以上之同色之副像素設置亦可。The opening 31 may expose two or more pixel electrodes provided corresponding to two or more adjacent sub-pixels of the same color. In this case, the contact holes 50 may be provided for every two or more sub-pixels of the same color corresponding to the two or more pixel electrodes exposed by the opening 31.

使供作為有機材料之液滴著陸的開口部31,不按每一副像素,而按相鄰的每2個同色之副像素形成,據此,可以緩和液滴之著陸位置之容許誤差。又,按由開口部31露出的2個以上之像素電極所對應的每2個以上之同色之副像素設置接觸孔50,據此而進行像素連結,則接觸孔50不會進行障礙。The opening 31 for the landing of the droplet as an organic material is formed not for every sub-pixel, but for every two adjacent sub-pixels of the same color, so that the tolerance of the landing position of the droplet can be reduced. In addition, the contact holes 50 are provided for every two or more sub-pixels of the same color corresponding to the two or more pixel electrodes exposed through the opening 31, and the pixel connection is performed accordingly, so that the contact holes 50 do not obstruct.

開口部31使與在第1方向相鄰的2個以上之同色副像素對應而設置的2個以上之像素電極露出亦可。據此,可以緩和第1方向中的有機材料之液滴之著陸位置之容許誤差。The opening 31 may expose two or more pixel electrodes provided corresponding to two or more same-color sub-pixels adjacent in the first direction. According to this, the allowable error of the landing position of the droplet of the organic material in the first direction can be alleviated.

開口部31使與在第2方向相鄰的2個同色之副像素對應而設置的2個像素電極露出亦可。據此,可以緩和第2方向中的有機材料之液滴之著陸位置之容許誤差。The opening 31 may expose two pixel electrodes provided corresponding to two sub-pixels of the same color adjacent in the second direction. Accordingly, the allowable error of the landing position of the organic material droplet in the second direction can be alleviated.

開口部31使與在第1方向及第2方向相鄰的4個以上之同色之副像素對應而設置的4個以上之像素電極露出亦可。據此,可以緩和第1方向及第2方向中的有機材料之液滴之著陸位置之容許誤差。The opening 31 may expose four or more pixel electrodes provided corresponding to four or more sub-pixels of the same color adjacent in the first direction and the second direction. According to this, the allowable error of the landing position of the droplet of the organic material in the first direction and the second direction can be alleviated.

接觸孔50形成於在第1方向相鄰的2個開口部31之間之區域亦可。據此,進行像素連結且接觸孔50不會成為障礙。The contact hole 50 may be formed in a region between two openings 31 adjacent in the first direction. According to this, the pixel connection is performed and the contact hole 50 does not become an obstacle.

接觸孔50形成於在第2方向相鄰的2個開口部31之間之區域亦可。即使將Y軸方向長的開口部31形成於有機EL顯示器1之情況下,亦可以將最適當數量之接觸孔50形成於有機EL顯示器1。The contact hole 50 may be formed in a region between two openings 31 adjacent in the second direction. Even if the opening 31 long in the Y-axis direction is formed in the organic EL display 1, the most suitable number of contact holes 50 can be formed in the organic EL display 1.

開口部31中,與接觸孔50相鄰的部分中的第2方向之尺寸形成為較其他部分中的第2方向之尺寸窄亦可。據此,可以不必擴大第2方向中的開口部31彼此之間隔,而可以確保形成接觸孔50之空間。In the opening portion 31, the size in the second direction in the portion adjacent to the contact hole 50 may be formed to be narrower than the size in the second direction in the other portion. According to this, it is possible to secure a space for forming the contact hole 50 without increasing the interval between the openings 31 in the second direction.

此次揭示的實施形態全部僅為例示,並非用來限定者。實際上,上述實施形態可以多樣之形態具體實現。又,上述實施形態在不脫離申請專利範圍及其趣旨之範圍內,可以各樣的形態進行省略、置換、變更。The embodiments disclosed this time are only examples and are not intended to be limiting. In fact, the above-mentioned embodiments can be realized in various forms. In addition, the above-mentioned embodiment can be omitted, replaced, or changed in various forms without departing from the scope of the patent application and its purport.

例如發光色之組合不限定於紅色、綠色、藍色之3原色。發光色之組合,除紅色、綠色及藍色之3原色以外,還可以使用紅色與綠色之中間色亦即黄色及綠色與藍色之中間色亦即青色(cyan)之至少1種。For example, the combination of luminescent colors is not limited to the three primary colors of red, green, and blue. In addition to the three primary colors of red, green, and blue, at least one of the intermediate colors of red and green, that is, yellow, and the intermediate color of green and blue, that is, cyan, can be used in addition to the three primary colors of luminescent colors.

上述實施形態及各變形例中,係以從基板10側取出來自發光層26之光的底部發光方式(bottom emission)之有機EL顯示器1為例。但不限定於此,有機EL顯示器1,亦可以是從基板10之相反側取出來自發光層26之光的頂部發光方式(top emission)。In the above-mentioned embodiment and each modification, the bottom emission type organic EL display 1 which takes out the light from the light emitting layer 26 from the substrate 10 side is taken as an example. However, it is not limited to this, and the organic EL display 1 may be a top emission method in which the light from the light-emitting layer 26 is taken out from the opposite side of the substrate 10.

頂部發光方式之情況下,基板10未必一定要透明基板。又,頂部發光方式之情況下,透明電極之陽極21作為對向電極使用,陰極22作為按每一單位電路11設置的像素電極使用。該情況下,陽極21與陰極22之配置相反,因此於陰極22上依序形成電子注入層28、電子輸送層27、發光層26、電洞輸送層25及電洞注入層24。In the case of the top emission method, the substrate 10 does not necessarily need to be a transparent substrate. In the case of the top emission method, the anode 21 of the transparent electrode is used as a counter electrode, and the cathode 22 is used as a pixel electrode provided for each unit circuit 11. In this case, the arrangement of the anode 21 and the cathode 22 is reversed, so the electron injection layer 28, the electron transport layer 27, the light emitting layer 26, the hole transport layer 25, and the hole injection layer 24 are sequentially formed on the cathode 22.

上述實施形態及各變形例中,說明有機EL層23具有電洞注入層24、電洞輸送層25、發光層26、電子輸送層27及電子注入層28的情況之例,但有機EL層23只要至少具有發光層26即可。In the above-described embodiment and each modification, an example in which the organic EL layer 23 has the hole injection layer 24, the hole transport layer 25, the light-emitting layer 26, the electron transport layer 27, and the electron injection layer 28 is described. However, the organic EL layer 23 It suffices to have at least the light emitting layer 26.

1‧‧‧有機EL顯示器 10‧‧‧基板 13‧‧‧有機發光二極體 21‧‧‧陽極 22‧‧‧陰極 23‧‧‧有機EL層 26‧‧‧發光層 30‧‧‧堤岸 31‧‧‧開口部 50‧‧‧接觸孔 51‧‧‧補助電極 100‧‧‧基板處理系統 123a‧‧‧塗布裝置 151‧‧‧基板保持部 152‧‧‧移動機構 160‧‧‧吐出單元 162‧‧‧噴頭 163‧‧‧噴嘴 261R‧‧‧紅色發光區域 261G‧‧‧綠色發光區域 261B‧‧‧藍色發光區域1‧‧‧ organic EL display 10‧‧‧ substrate 13‧‧‧ organic light emitting diode 21‧‧‧Anode 22‧‧‧Cathode 23‧‧‧ organic EL layer 26‧‧‧luminous layer 30‧‧‧Embankment 31‧‧‧Opening 50‧‧‧Contact hole 51‧‧‧Subsidiary electrode 100‧‧‧Substrate processing system 123a‧‧‧Coating device 151‧‧‧Substrate holding section 152‧‧‧Moving mechanism 160‧‧‧Spitting unit 162‧‧‧Sprinkler 163‧‧‧ nozzle 261R‧‧‧Red light emitting area 261G‧‧‧Green light emitting area 261B‧‧‧Blue light emitting area

[圖1]圖1係表示補助電極用之接觸孔按每一副像素形成的有機EL顯示器之構成例之模式平面圖。 [圖2]圖2係表示實施形態之有機EL顯示器之電路構成之一例之圖。 [圖3]圖3係表示實施形態之有機EL顯示器之模式平面圖。 [圖4]圖4係圖3中的IV-IV線剖面圖。 [圖5]圖5係圖3中的V-V線剖面圖。 [圖6]圖6係表示實施形態之有機發光二極體之製造方法之流程圖。 [圖7]圖7係表示實施形態之基板處理系統之構成之模式平面圖。 [圖8]圖8係表示實施形態之塗布裝置之構成之模式平面圖。 [圖9]圖9係表示實施形態之塗布裝置之構成之模式側面圖。 [圖10]圖10係表示實施形態之塗布裝置描繪的描畫圖案之平面圖。 [圖11]圖11係表示實施形態中的第1變形例的描畫圖案之平面圖。 [圖12]圖12係表示實施形態中的第2變形例的描畫圖案之平面圖。 [圖13]圖13係表示實施形態中的第3變形例的描畫圖案之平面圖。[FIG. 1] FIG. 1 is a schematic plan view showing a configuration example of an organic EL display in which contact holes for auxiliary electrodes are formed for each sub-pixel. [FIG. 2] FIG. 2 is a diagram showing an example of a circuit configuration of an organic EL display of an embodiment. [Fig. 3] Fig. 3 is a schematic plan view showing an organic EL display of an embodiment. [Fig. 4] Fig. 4 is a sectional view taken along the line IV-IV in Fig. 3. [Fig. [Fig. 5] Fig. 5 is a sectional view taken along the line V-V in Fig. 3. [Fig. [Fig. 6] Fig. 6 is a flowchart showing a method of manufacturing an organic light-emitting diode according to an embodiment. [Fig. 7] Fig. 7 is a schematic plan view showing the configuration of the substrate processing system of the embodiment. [FIG. 8] FIG. 8 is a schematic plan view showing the configuration of the coating apparatus of the embodiment. [Fig. 9] Fig. 9 is a schematic side view showing the configuration of the coating apparatus of the embodiment. [Fig. 10] Fig. 10 is a plan view showing a drawing pattern drawn by the coating apparatus of the embodiment. [Fig. 11] Fig. 11 is a plan view showing a drawing pattern of a first modification in the embodiment. [Fig. 12] Fig. 12 is a plan view showing a drawing pattern of a second modification in the embodiment. [Fig. 13] Fig. 13 is a plan view showing a drawing pattern of a third modification in the embodiment.

1‧‧‧有機EL顯示器 1‧‧‧ organic EL display

21‧‧‧陽極 21‧‧‧Anode

30‧‧‧堤岸 30‧‧‧Embankment

31‧‧‧開口部 31‧‧‧Opening

50‧‧‧接觸孔 50‧‧‧Contact hole

261R‧‧‧紅色發光區域 261R‧‧‧Red light emitting area

261G‧‧‧綠色發光區域 261G‧‧‧Green light emitting area

261B‧‧‧藍色發光區域 261B‧‧‧Blue light emitting area

262‧‧‧發光區域群 262‧‧‧Glowing area group

Claims (13)

一種塗布裝置,具備: 基板保持部,對基板進行保持; 吐出單元,包含複數個噴頭,該噴頭為在第1方向並列設置有複數個噴嘴者;及 移動機構,使上述吐出單元與上述基板保持部沿著與上述第1方向交叉的第2方向相對地移動; 上述基板具備: 複數個像素電極,與複數個副像素對應而設置;堤岸,覆蓋上述複數個像素電極,並且形成有複數個使至少1個上述像素電極露出的開口部;及複數個接觸孔,用以將與上述複數個像素電極對向的對向電極電連接於補助電極; 上述接觸孔,係按每2個以上之上述副像素設置, 上述吐出單元, 係從上述噴嘴朝向上述基板保持部所保持的上述基板之上述開口部吐出有機材料之液滴。A coating device with: The substrate holding section holds the substrate; The discharge unit includes a plurality of nozzles, the nozzles are provided with a plurality of nozzles juxtaposed in the first direction; and A moving mechanism that relatively moves the discharge unit and the substrate holding portion along a second direction crossing the first direction; The above substrate has: A plurality of pixel electrodes corresponding to the plurality of sub-pixels; a bank covering the plurality of pixel electrodes and forming a plurality of openings exposing at least one of the pixel electrodes; and a plurality of contact holes for The counter electrode facing the plurality of pixel electrodes is electrically connected to the auxiliary electrode; The above-mentioned contact holes are provided for every two or more of the above-mentioned sub-pixels, The above spitting unit, The organic material is discharged from the nozzle toward the opening of the substrate held by the substrate holding portion. 如申請專利範圍第1項之塗布裝置,其中 上述接觸孔, 係按每2個以上之同色之副像素設置。For example, the coating device according to item 1 of the patent application, where The above contact hole, It is set for every two or more sub-pixels of the same color. 如申請專利範圍第2項之塗布裝置,其中 上述開口部, 係使與相鄰的2個以上之同色之上述副像素對應而設置的2個以上之上述像素電極露出, 上述接觸孔, 係按與從上述開口部露出的2個以上之上述像素電極對應的每2個以上之同色之上述副像素設置。For example, the coating device according to item 2 of the patent application scope, in which The above opening, The two or more pixel electrodes provided corresponding to the two or more adjacent sub-pixels of the same color are exposed, The above contact hole, It is provided for every two or more sub-pixels of the same color corresponding to two or more pixel electrodes exposed from the opening. 如申請專利範圍第3項之塗布裝置,其中 上述開口部, 係使與上述第1方向相鄰的2個以上之同色之上述副像素對應而設置的2個以上之上述像素電極露出。For example, the coating device according to item 3 of the patent application scope, in which The above opening, The two or more pixel electrodes provided corresponding to the two or more sub-pixels of the same color adjacent to the first direction are exposed. 如申請專利範圍第3項之塗布裝置,其中 上述開口部, 係使與上述第2方向相鄰的2個同色之上述副像素對應而設置的2個上述像素電極露出。For example, the coating device according to item 3 of the patent application scope, in which The above opening, The two pixel electrodes provided corresponding to the two sub-pixels of the same color adjacent to the second direction are exposed. 如申請專利範圍第3項之塗布裝置,其中 上述開口部, 係使與上述第1方向及上述第2方向相鄰的4個以上之同色之上述副像素對應而設置的4個以上之上述像素電極露出。For example, the coating device according to item 3 of the patent application scope, in which The above opening, The four or more pixel electrodes provided corresponding to the four or more sub-pixels of the same color adjacent to the first direction and the second direction are exposed. 如申請專利範圍第3至6項中任一項之塗布裝置,其中 上述接觸孔, 係形成於在上述第1方向相鄰的2個上述開口部之間之區域。The coating device according to any one of patent application items 3 to 6, wherein The above contact hole, It is formed in a region between the two openings adjacent in the first direction. 如申請專利範圍第3至6項中任一項之塗布裝置,其中 上述接觸孔, 係形成於在上述第2方向相鄰的2個上述開口部之間之區域。The coating device according to any one of patent application items 3 to 6, wherein The above contact hole, It is formed in a region between two openings adjacent in the second direction. 如申請專利範圍第8項之塗布裝置,其中 上述開口部, 與上述接觸孔相鄰的部分中的上述第2方向之尺寸,係形成為比其他部分中的上述第2方向之尺寸窄。For example, the coating device according to item 8 of the patent application, where The above opening, The dimension in the second direction in the portion adjacent to the contact hole is formed to be narrower than the dimension in the second direction in the other portion. 如申請專利範圍第1項之塗布裝置,其中 上述接觸孔, 係按每2個以上之不同色之副像素設置。For example, the coating device according to item 1 of the patent application, where The above contact hole, It is set according to every two or more sub-pixels of different colors. 如申請專利範圍第10項之塗布裝置,其中 上述接觸孔, 係對至少1個像素設置1個。For example, the coating device according to item 10 of the patent application scope, in which The above contact hole, Set one for at least one pixel. 一種塗布方法,包含: 使用基板保持部對基板進行保持的保持工程,該基板具備:複數個像素電極,與複數個副像素對應而設置;堤岸,覆蓋上述複數個像素電極,並且形成有複數個使至少1個上述像素電極露出的開口部;及複數個接觸孔,用以將與上述複數個像素電極對向的對向電極連接於補助電極; 移動工程,使吐出單元與上述基板保持部沿著與上述第1方向交叉的第2方向相對地移動,該吐出單元為包含複數個在第1方向並列設置有複數個噴嘴的噴頭者;及 吐出工程,從上述噴嘴朝向上述基板保持部所保持的上述基板之上述開口部吐出有機材料之液滴; 上述接觸孔, 係按每2個以上之上述副像素設置。A coating method, including: A holding process for holding a substrate by using a substrate holding portion, the substrate including: a plurality of pixel electrodes corresponding to a plurality of sub-pixels; a bank covering the plurality of pixel electrodes and forming a plurality of at least one of the pixels Openings where the electrodes are exposed; and a plurality of contact holes for connecting the opposite electrode facing the plurality of pixel electrodes to the auxiliary electrode; A moving process to move the ejection unit and the substrate holding portion relatively in a second direction that intersects the first direction, the ejection unit being a head that includes a plurality of nozzles arranged in parallel in the first direction; and In the discharge process, a droplet of organic material is discharged from the nozzle toward the opening of the substrate held by the substrate holding portion; The above contact hole, It is set for every two or more of the above sub-pixels. 一種有機EL顯示器,具備: 複數個像素電極,於基板上與複數個副像素對應而設置; 堤岸,覆蓋上述複數個像素電極,並且形成有複數個使至少1個上述像素電極露出的開口部; 對向電極,與上述複數個像素電極對向; 有機EL層,在上述開口部中設置於上述像素電極與上述對向電極之間; 補助電極;及 複數個接觸孔,將上述對向電極連接於上述補助電極; 上述接觸孔, 係按每2個以上之上述副像素設置。An organic EL display with: A plurality of pixel electrodes are provided on the substrate corresponding to the plurality of sub-pixels; A bank covering the plurality of pixel electrodes and forming a plurality of openings that expose at least one of the pixel electrodes; The opposite electrode is opposite to the above-mentioned plurality of pixel electrodes; An organic EL layer provided between the pixel electrode and the counter electrode in the opening; Supplementary electrode; and A plurality of contact holes to connect the counter electrode to the auxiliary electrode; The above contact hole, It is set for every two or more of the above sub-pixels.
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