以下，對本發明之凝膠狀毛髮用組合物進行詳細說明。 (A)：陰離子性聚合物 陰離子性聚合物係僅使陰離子性聚合物溶解或分散於(C)水中進行中和之狀態之黏度為1550 mPa·s以上且170000 mPa·s以下。藉由溶解或分散於(C)水中進行中和之狀態之黏度為1550 mPa·s以上而可獲得凝膠之彈性，藉由為170000 mPa·s以下而可獲得水潤度。僅使陰離子性聚合物溶解或分散於(C)水中進行中和之狀態之黏度更佳為12000以上且50000以下，更佳為12000以上且50000以下。 陰離子性聚合物只要處於上述黏度範圍且可用作化妝料原料，則並無特別限定，例如較佳為含有羧基之水溶性聚合物，更佳為羧基乙烯基聚合物。作為羧基乙烯基聚合物，較佳為丙烯酸-甲基丙烯酸烷基酯共聚物。所謂丙烯酸-甲基丙烯酸烷基酯共聚物，係一併具有源自羧基之親水性部分、與源自烷基之親油性部分之共聚物。丙烯酸-甲基丙烯酸烷基酯共聚物可使凝膠狀毛髮用組合物向毛髮之附著性或耐鹽性變良好。 作為羧基乙烯基聚合物之具體例，例如可列舉：CARBOPOL940、CARBOPOL941、CARBOPOL980、CARBOPOL981(以上為Lubrizol Advanced Materials公司製造)等羧基乙烯基聚合物；PEMULEN TR-1、PEMULEN TR-2、Carbopol ETD2020 polymer、Carbopol 1342 polymer、Carbopol 1382 polymer、Carbopol Ultrez 20 polymer、Carbopol Ultrez 21 polymer(以上為Lubrizol Advanced Materials公司製造)等丙烯酸-甲基丙烯酸烷基酯共聚物；ACULYN 22、ACULYN 23(以上為ISP公司製造)等丙烯酸烷基酯-甲基丙烯酸烷基聚氧乙烯酯共聚物；STRUCTURE系列(以上為NSC公司製造)等丙烯酸烷基酯-亞甲基丁二酸烷基聚氧乙烯酯共聚物；STABILEZE系列(以上為ISP公司製造)等甲基乙烯基醚-順丁烯二酸酐-癸二烯共聚物。 本發明中所使用之丙烯酸-甲基丙烯酸烷基酯共聚物就確保凝膠狀毛髮用組合物之透明性、及黏度穩定性之觀點而言，較佳為甲基丙烯酸單元之烷基之碳數為10～30。 作為市售之丙烯酸-甲基丙烯酸烷基酯共聚物，可列舉：PEMULEN TR-1(丙烯酸酯/丙烯酸烷基酯(C10～30))交聯聚合物)、PEMULEN TR-2(商品名，Lubrizol Advanced Materials公司製造)等。 本發明中可僅調配一種陰離子性聚合物，亦可混合調配兩種以上。 相對於凝膠狀毛髮用組合物100質量%，陰離子性聚合物於組合物中之含量為0.2質量%以上且未達1.0質量%。更佳為0.3質量%以上且0.8質量%以下。藉由設為0.2質量%以上且未達1.0質量%，可不發黏而獲得水潤度。 (B)陽離子性聚合物 本發明之凝膠狀毛髮用組合物就使毛髮固著且賦予亮澤感之觀點而言，包含陽離子性聚合物。作為本發明中所用之陽離子性聚合物，可適當選擇公知者。例如可列舉：乙烯基吡咯啶酮-甲基丙烯酸N,N-二甲基胺基乙酯共聚物二乙基硫酸鹽、氯化二甲基二烯丙基銨-丙烯醯胺共聚物、聚氯化二甲基亞甲基哌啶鎓、氯化O-[2-羥基-3-(三甲基銨基)丙基]羥基乙基纖維素、氯化O-[2-羥基-3-(三甲基銨基)丙基瓜爾膠、2-甲基丙烯醯氧基乙基磷醯膽鹼-氯化2-羥基-3-甲基丙烯醯氧基丙基三甲基銨共聚物、氯化O-(2-羥基-3-(三甲基銨基)丙基)刺槐豆膠、氯化羥基丙基三甲基銨澱粉、乙烯基吡咯啶酮-甲基丙烯酸N,N-二甲基胺基乙酯-丙烯酸硬脂酯-二丙烯酸三丙二醇酯共聚物等。其中，較佳為乙烯基吡咯啶酮-甲基丙烯酸N,N-二甲基胺基乙酯共聚物二乙基硫酸鹽、氯化O-[2-羥基-3-(三甲基銨基)丙基]羥基乙基纖維素、氯化O-[2-羥基-3-(三甲基銨基)丙基瓜爾膠、氯化羥基丙基三甲基銨澱粉。 作為陽離子性聚合物之市售品，例如可列舉：Cosquat GA468(大阪有機化學工業股份有限公司製造)，H.C.聚合物1S(M)、H.C.聚合物1N(聚四級銨鹽-11)等H.C.聚合物系列(大阪有機股份有限公司製造)，Gafquat 755-S(ISP Japan股份有限公司製造)，HC聚合物1N(大阪有機化學工業股份有限公司製造)，聚合物JR-400(Nippon Union Carbide股份有限公司製造)，Rubbolgum CG-M(DSP Gokyo Food & Chemical股份有限公司製造)，Sensomer CI-50 polymer(Lubrizol Advanced Materials公司製造)，Lipidure C(日本油脂股份有限公司製造)等。本發明中可僅調配一種陽離子性聚合物，亦可混合調配兩種以上。 陽離子性聚合物之分子量較佳為10萬以上且150萬以下。 陽離子性聚合物之陽離子化氮含量較佳為1.0～2.5%。 陽離子化氮含量為1.0%～2.5%者中，尤佳為使用含有四級氮之纖維素醚衍生物、含有四級氮之澱粉、含有四級氮之瓜爾膠、乙烯基吡咯啶酮/甲基丙烯酸N,N-二甲基胺基乙酯共聚物二乙基硫酸鹽。 陽離子性聚合物於凝膠狀毛髮用組合物中之含量係以如下方式選擇：相對於凝膠狀毛髮用組合物100質量%而為例如0.3質量%以上之範圍，且下文將述之陽離子性聚合物/陰離子性聚合物之比成為0.17以上且1.80以下。 (陽離子性聚合物相對於陰離子性聚合物之比) 凝膠狀毛髮用組合物之陽離子性聚合物相對於陰離子性聚合物之比即陽離子性聚合物/陰離子性聚合物為0.17以上且1.80以下。藉由為0.17以上而可獲得定型力與亮澤感。藉由為1.80以下，於將組合物於手掌上延展時，在手上獲得劑崩解之觸感，水潤度優異而可抑制發黏。 (凝膠狀毛髮用組合物之pH值) 本發明之凝膠狀毛髮用組合物之25℃下之pH值就獲得透明的凝膠之觀點、及獲得水潤度之觀點而言為5.50以上且8.20以下。再者，pH值可藉由pH計等公知之方法測定。 (pH調整劑) 凝膠狀毛髮用組合物調整pH值。作為pH調整劑之鹼並無特別限定，可較佳地使用氫氧化鉀、氫氧化鈉、三乙醇胺、胺基甲基丙醇(AMP)、胺基甲基丙二醇等。更佳為胺基甲基丙醇(AMP)。 (凝膠狀毛髮用組合物之黏度) 凝膠狀毛髮用組合物之黏度大於僅使(A)陰離子性聚合物溶解或分散於(C)水中進行中和之狀態之黏度的1.0倍且未達8.0倍，較佳為6倍以下，進而較佳為2倍以下。藉由為1.0倍以上而可獲得凝膠之彈性。藉由未達8.0倍而可獲得水潤度。凝膠狀毛髮用組合物之黏度相對於陰離子性聚合物之黏度之比係含有陽離子性聚合物的該組合物之黏度相對於單獨使用陰離子性聚合物之黏度之比。再者，於8.0倍以上之情形時，複合物所擔載之水量變多，組合物之穩定性變差。 凝膠狀毛髮用組合物之黏度較佳為12000 mPa·s以上且170000 mPa·s以下，更佳為12000 mPa以上且160000 mPa以下，進而較佳為12000 mPa·s以上且60000 mPa·s以下。藉由凝膠狀毛髮用組合物之黏度為12000 mPa·s以上而可獲得凝膠之彈性，藉由為170000 mPa·s以下而可獲得水潤度。 再者，存在根據容器之結構而適當選擇凝膠狀毛髮用組合物之黏度之情形。 於本發明中，藉由更含有非離子性聚合物及/或兩性聚合物，可抑制於手上發黏並且提高定型力。例如，於使僅含有陰離子性聚合物作為聚合物之毛髮組合物中含有非離子性聚合物或兩性聚合物之情形時，雖定型力提高，但亦發黏。 (非離子性聚合物、兩性聚合物) 作為非離子性聚合物，例如可列舉：作為非離子性者之聚乙烯吡咯啶酮[Luviskol K17、Luviskol K30、Luviskol K90(以上為BASF公司製造)，PVP K(ISP公司製造)]、乙烯基吡咯啶酮-乙酸乙烯酯共聚物[PVP/VA S-630、PVP/VA E-735、PVP/VA E-335(以上為ISP公司製造)，Luviskol VA73W、Luviskol 37E(以上為BASF公司製造)，PVA-6450(大阪有機化學工業(股)製造)]、乙烯基甲醚-順丁烯二酸烷基酯共聚物[Gantrez A-425、Gantrez ES-225、Gantrez ES-335(均為ISP公司製造)]、乙烯基吡咯啶酮-甲基丙烯醯胺-乙烯基咪唑共聚物[Luviset Clear(BASF公司製造)]等。 作為兩性聚合物，例如可列舉：辛基丙烯醯胺-丙烯酸羥基丙基丙酯-甲基丙烯酸丁基胺基乙酯共聚物(AMPHOMER SH30、AMPHOMER LV-71(日本NCS股份有限公司製造))、甲基丙烯醯氧基乙基羧基甜菜鹼-甲基丙烯酸烷基酯共聚物(Yukaformer R205、Yukaformer301、Yukaformer SM、Yukaformer104D等(三菱化學股份有限公司製造)，RAM Resin-1000、RAM Resin-2000、RAM Resin-3000、RAM Resin-4000(大阪有機化學工業股份有限公司製造))、氯化二甲基二烯丙基銨-丙烯酸共聚物(Merquat 280、Merquat 295(Nalco公司製造))、氯化二甲基二烯丙基銨-丙烯醯胺-丙烯酸共聚物(Merquat Plus 3330、Merquat Plus 3331(Nalco公司製造))等。 (其他成分) 本發明之凝膠狀組合物可於不損及本發明之效果之範圍內適當調配助溶劑(乙醇、異丙醇、丁醇等)、多元醇類(乙二醇、聚乙二醇、丙二醇、二丙二醇、聚丙二醇、1,3-丁二醇、甘油、雙甘油、異戊二醇等)、糖類(山梨糖醇、麥芽糖醇、木糖醇、葡萄糖、果糖、甘露醇、肌醇等)、透明質酸等高分子類、抗氧化劑、紫外線吸收劑、防腐劑、螯合劑、香料、著色劑、增黏劑、金屬封阻劑(乙二胺四乙酸鹽等)、pH調整劑。 本發明之凝膠狀毛髮用組合物可用作毛髮用化妝料之基材。例如可用作護髮素、造型劑。 (製造方法) 本發明之凝膠狀毛髮用組合物例如可如下般製造。 於將陽離子性聚合物及鹼(pH調整劑)添加至水中而精製水溶液後，添加陰離子性聚合物。再者，於添加時，較佳為視需要一面攪拌一面進行添加。 [實施例] 以下，藉由實施例進一步詳細地對本發明進行說明，但本發明並不限定於該等實施例。 按照表1至表8所示之配方依照以下順序調整凝膠狀毛髮用組合物。 (調整法) 將陽離子性聚合物添加至純化水中，進行混合而製作陽離子性聚合物之水溶液。其次，於該水溶液中添加中和劑。再者，於添加時，視需要一面攪拌一面進行添加。最後，於陽離子性聚合物之水溶液中添加陰離子性聚合物而獲得凝膠狀毛髮用組合物。該組合物之黏度並未經時變動而穩定性優異。 [實施例1～3、比較例1～7] 製作適當變更陰離子性聚合物之種類的凝膠狀毛髮用組合物。藉由pH調整劑以凝膠狀毛髮用組合物之pH值成為6～6.5之方式調整。將配方與評估結果示於表1。 [實施例4～6、比較例8～10] 將陰離子性聚合物之含量設為一定且改變陽離子性聚合物之含量，製作陽離子性聚合物/陰離子性聚合物之比率不同的凝膠狀毛髮用組合物。藉由pH調整劑以凝膠狀毛髮用組合物之pH值成為6～6.5之方式調整。將配方與評估結果示於表2。 [實施例7～17、比較例11～比較例21] 改變陽離子性聚合物及陰離子性聚合物之含量而製作陽離子性聚合物/陰離子性聚合物之比率不同之凝膠狀毛髮用組合物。 藉由pH調整劑以凝膠狀毛髮用組合物之pH值成為6～6.5之方式調整。 將配方與評估結果示於表3、表4及表5。 [實施例18～24、比較例22～比較例27] 將陽離子性聚合物及陰離子性聚合物之含量設為一定，且將陽離子性聚合物/陰離子性聚合物之比率固定，藉由pH調整劑製作pH值不同之凝膠狀毛髮用組合物。將配方與評估結果示於表6及表7。 [實施例25～28、比較例28、29] 使用含氮率不同之陽離子性聚合物。將配方與評估結果示於表8。 實施例及比較例之評估試驗方法及評估基準如下。 ＜黏度測定＞ 藉由Bismetron黏度計(BH型，芝浦系統公司製造)使用6號轉子於轉數為10 rpm之條件下測定30℃下之黏度(mPa·s)。 ＜劑之崩解容易度＞ 由10名專業官能檢查員進行使用測試，根據下述評分基準對在手上延展基劑時之崩解容易度進行官能評估，並根據下述評估基準對其合計評分進行評估。將B以上判斷為具有劑之崩解容易度。 (評分基準) 5分：可見崩解容易度 4分：稍可見崩解容易度 3分：略微可見崩解容易度 2分：幾乎未見崩解容易度 0分：並無崩解容易度 (評估基準) A：合計分為40分以上 B：合計分為30分以上 C：合計分為20分以上且未達30分 D：合計分為10分以上且未達20分 E：合計分未達10分 ＜於手上之水潤度(不發黏)＞ 由10名專業官能檢查員進行使用測試，根據下述評分基準對在手上延展基劑時之水潤度進行官能評估，並根據下述評估基準對合計評分進行評估。將B以上判斷為具有水潤度。 (評分基準) 5分：可見水潤度 4分：稍可見水潤度 3分：略微可見水潤度 2分：幾乎未見水潤度 0分：並無水潤度 (評估基準) A：合計分為40分以上 B：合計分為25分以上且未達40分 C：合計分為10分以上且未達25分 D：合計分未達10分 ＜向毛髮之親和容易度＞ 由10名專業官能檢查員進行使用測試，根據下述評分基準對將已於手上延展之基劑塗抹至毛髮時之親和容易度進行官能評估，並根據下述評估基準對其合計評分進行評估。將B以上判斷為具有向毛髮之親和容易度。 (評分基準) 5分：可見向毛髮之親和容易度 4分：稍可見向毛髮之親和容易度 3分：略微可見向毛髮之親和容易度 2分：幾乎未見向毛髮之親和容易度 0分：並無向毛髮之親和容易度 (評估基準) A：合計分為40分以上 B：合計分為25分以上且未達40分 C：合計分為10分以上且未達25分 ＜亮澤感＞ 由10名專業官能檢查員進行使用測試，根據下述評分基準對塗抹至毛髮後之亮澤感進行官能評估，並根據下述評估基準對其合計評分進行評估。將C以上判斷為具有亮澤感。 (評分基準) 5分：可見亮澤感 4分：稍可見亮澤感 3分：略微可見亮澤感 2分：幾乎未見亮澤感 0分：並無亮澤感 (評估基準) A：合計分為40分以上 B：合計分為25分以上且未達40分 C：合計分為10分以上且未達25分 D：合計分未達10分 ＜定型力＞ 由10名專業官能檢查員進行使用測試，根據下述評分基準對塗抹至毛髮後之定型性進行官能評估，並根據下述評估基準對其合計評分進行評估。將C以上判斷為具有定型力。 (評分基準) 5分：可見定型性 4分：稍可見定型性 3分：略微可見定型性 2分：幾乎未見定型性 0分：並無定型性 (評估基準) A：合計分為40分以上 B：合計分為25分以上且未達40分 C：合計分為10分以上且未達25分 D：合計分未達10分 ＜外觀(透明性)＞ 藉由目測觀察各試樣之外觀(透明性)並進行評估。將B以上判斷為具有透明性。 (評估基準) A：非常透明 B：稍微透明 C：稍微渾濁 D：非常渾濁 ＜經時穩定性＞ 根據下述(外觀評估基準)及(黏度評估基準)如下般對各試樣進行評估。將B以上判斷為具有經時穩定性。 (外觀評估基準) 藉由目測觀察各試樣之外觀(透明性)並進行評估。將B以上判斷為具有透明性。 A：非常透明 B：稍微透明 C：稍微渾濁 D：非常渾濁 (黏度評估基準) 黏度係將剛製造後之黏度與於50℃下保管1個月之樣品之黏度進行比較而評估。 黏度比＝黏度(於50℃下保管1個月)/黏度(剛製造後) A：黏度比為0.5以上且未達1.5 B：黏度比為0.25以上且未達0.5、及1.5以上且未達2 C：黏度比為A及B之範圍以外 ＜經時穩定性之評估基準＞ A：外觀評估基準為A或B且黏度評估基準為A之情形 B：外觀評估基準為B且黏度評估基準為B、外觀評估基準為C且黏度評估基準為A之情形 C：上述A及B以外之情形 以下示出表1至表8。 [表1]
[表2]
[表3]
[表4]
[表5]
[表6]
[表7]
[表8]
上述表1至表8中之材料之詳細內容如下。 (陽離子性聚合物) ·商品名「H.C.聚合物1S(M)」(大阪有機化學工業股份有限公司製造) ·商品名「HC聚合物1N」(大阪有機化學工業股份有限公司製造) ·商品名「聚合物JR-400」(Union Carbide公司製造) ·商品名「Rubbolgum CG-M」(DSP Gokyo Food & Chemical股份有限公司製造) ·商品名「Sensomer CI-50 polymer」(Lubrizol Advanced Materials公司製造) ·商品名「Cosquat GA468」(大阪有機股份有限公司製造) ·商品名「Merquat 550L」(Lubrizol Advanced Materials公司製造) (陰離子性聚合物) ·商品名「PEMULEN TR-1」(Lubrizol Advanced Materials公司製造) ·商品名「PEMULEN TR-2」(Lubrizol Advanced Materials公司製造) ·商品名「CARBOPOL981」(Lubrizol Advanced Materials公司製造) (中和劑) ·商品名「AMP-ULTRA PC1000」(ANGUS Chemical Company公司製造) ·商品名「磷酸 國產1級」(國產化學股份有限公司製造) 如表1及2所示可知，本發明之凝膠狀毛髮用組合物不損及定型力而劑之崩解容易度、於手上之水潤度、向毛髮之親和容易度優異，且經時穩定性亦優異。比較例1、2、3、4及6係單獨使用陰離子性聚合物之凝膠狀毛髮用組合物，該等比較例係不存在複合物故而難以感受到劑之崩解容易度，使用感較差。尤其於如比較例4及6般黏度(因不含陽離子性聚合物，故而表中之黏度為單獨使用陰離子性聚合物之黏度)較低之情形時，難以感受到劑之崩解容易度，又，亦未獲得亮澤感而使用感較差。又，即便陽離子性聚合物/陰離子性聚合物之比率、黏度為特定範圍，如比較例5所示般黏度比較大者亦係複合物內擔載之水量較大而穩定性較差。 根據表3～表5可知，即便陽離子性聚合物/陰離子性聚合物之比率為0.17以上且1.80以下，若陰離子性聚合物之含量未達0.2質量%則向毛髮之親和容易度亦較差，若為1.0質量%以上則劑之崩解容易度、及於手上之水潤度亦較差。可知本發明之凝膠狀毛髮用組合物係劑之崩解容易度、於手上之水潤度、及向毛髮的親和容易度均優於比較例之凝膠狀毛髮用組合物。 又，根據表6及表7可知，若pH值未達5.50則透明性較差，若pH值超過8.20則劑之崩解容易度較差。 又進而，根據表8可知，於本發明之凝膠狀毛髮用組合物中亦可應用N含有率不同之陽離子性聚合物。Hereinafter, the gel-like hair composition of this invention is demonstrated in detail. (A): Anionic polymer Anionic polymer has a viscosity in a state where only an anionic polymer is dissolved or dispersed in (C) water for neutralization, which is 1550 mPa · s or more and 170,000 mPa · s or less. The elasticity of the gel can be obtained by dissolving or dispersing in (C) water for neutralization with a viscosity of 1550 mPa · s or more, and a wetness of 170,000 mPa · s or less. The viscosity in a state where the anionic polymer is only dissolved or dispersed in (C) water for neutralization is more preferably 12,000 to 50,000, and more preferably 12,000 to 50,000. The anionic polymer is not particularly limited as long as it is in the above-mentioned viscosity range and can be used as a raw material for cosmetics. For example, a water-soluble polymer containing a carboxyl group is preferred, and a carboxyvinyl polymer is more preferred. The carboxyvinyl polymer is preferably an acrylic acid-alkyl methacrylate copolymer. The so-called acrylic acid-alkyl methacrylate copolymer is a copolymer having a hydrophilic portion derived from a carboxyl group and a lipophilic portion derived from an alkyl group. The acrylic-alkyl methacrylate copolymer can improve the adhesion of the gel-like hair composition to the hair or the salt resistance. Specific examples of the carboxy vinyl polymer include carboxy vinyl polymers such as CARBOPOL940, CARBOPOL941, CARBOPOL980, CARBOPOL981 (above manufactured by Lubrizol Advanced Materials); PEMULEN TR-1, PEMULEN TR-2, Carbopol ETD2020 polymer , Carbopol 1342 polymer, Carbopol 1382 polymer, Carbopol Ultrez 20 polymer, Carbopol Ultrez 21 polymer (above manufactured by Lubrizol Advanced Materials) and other acrylic-methacrylic acid alkyl ester copolymers; ACULYN 22, ACULYN 23 (above manufactured by ISP) ) And other alkyl acrylates-alkyl methacrylate polyoxyethylene copolymers; STRUCTURE series (above manufactured by NSC) and other alkyl acrylates-methylene succinate alkyl polyoxyethylene copolymers; Series (above manufactured by ISP) and other methyl vinyl ether-maleic anhydride-decadiene copolymers. The acrylic-alkyl methacrylate copolymer used in the present invention is preferably a carbon of an alkyl group of a methacrylic unit from the viewpoint of ensuring transparency and viscosity stability of the gel-like hair composition. The number is 10-30. Examples of commercially available acrylic acid-alkyl methacrylate copolymers include PEMULEN TR-1 (acrylic acid / alkyl acrylate (C10-30)) crosslinked polymer), and PEMULEN TR-2 (trade name, Lubrizol Advanced Materials). In the present invention, only one kind of anionic polymer may be blended, or two or more kinds may be blended and blended. The content of the anionic polymer in the composition is 0.2 mass% or more and less than 1.0 mass% based on 100 mass% of the gel-like hair composition. It is more preferably 0.3% by mass or more and 0.8% by mass or less. By setting it to be 0.2% by mass or more and less than 1.0% by mass, it is possible to obtain wateriness without stickiness. (B) Cationic polymer The gel-like hair composition of the present invention contains a cationic polymer from the viewpoint of fixing hair and giving a luster. As the cationic polymer used in the present invention, a known one can be appropriately selected. Examples include vinylpyrrolidone-N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate, dimethyl diallylammonium chloride-acrylamide copolymer, poly Dimethylmethylene piperidinium chloride, O- [2-hydroxy-3- (trimethylammonyl) propyl] hydroxyethyl cellulose, O- [2-hydroxy-3-chloride (Trimethylammonium) propyl guar, 2-methacryloxyethylphosphoniumcholine-2-hydroxy-3-methacryloxypropyltrimethylammonium chloride copolymer O- (2-hydroxy-3- (trimethylammonium) propyl) locust bean gum, hydroxypropyl trimethylammonium chloride starch, vinylpyrrolidone-methacrylic acid N, N- Dimethylaminoethyl ester-stearyl acrylate-tripropylene glycol diacrylate copolymer and the like. Among them, vinylpyrrolidone-N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate, O- [2-hydroxy-3- (trimethylammonium group) are preferred ) Propyl] hydroxyethylcellulose, O- [2-hydroxy-3- (trimethylammonium) propyl guar gum, hydroxypropyltrimethylammonium chloride starch. Examples of commercially available cationic polymers include HC such as Cosquat GA468 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), HC polymer 1S (M), HC polymer 1N (polyquaternary ammonium salt-11), and the like. Polymer series (manufactured by Osaka Organic Co., Ltd.), Gafquat 755-S (manufactured by ISP Japan Co., Ltd.), HC polymer 1N (manufactured by Osaka Organic Chemical Industry Co., Ltd.), polymer JR-400 (Nippon Union Carbide Co., Ltd.) Co., Ltd.), Rubbolgum CG-M (manufactured by DSP Gokyo Food & Chemical Co., Ltd.), Sensomer CI-50 polymer (manufactured by Lubrizol Advanced Materials), Lipidure C (manufactured by Japan Oil & Fat Co., Ltd.), etc. In the present invention, only one kind of cationic polymer may be blended, or two or more kinds may be blended and blended. The molecular weight of the cationic polymer is preferably from 100,000 to 1.5 million. The cationic polymer preferably has a cationic nitrogen content of 1.0 to 2.5%. Among those having a cationized nitrogen content of 1.0% to 2.5%, it is particularly preferable to use a cellulose ether derivative containing quaternary nitrogen, starch containing quaternary nitrogen, guar gum containing quaternary nitrogen, and vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate. The content of the cationic polymer in the gel-like hair composition is selected in a range of, for example, 0.3% by mass or more with respect to 100% by mass of the gel-like hair composition, and cationic properties to be described later The polymer / anionic polymer ratio is 0.17 or more and 1.80 or less. (Ratio of cationic polymer to anionic polymer) The ratio of the cationic polymer to the anionic polymer of the gel-like hair composition, that is, the cationic polymer / anionic polymer is 0.17 or more and 1.80 or less . When it is 0.17 or more, a setting power and a shiny feeling can be obtained. When the composition is 1.80 or less, when the composition is stretched on the palm, a touch of disintegration of the agent is obtained on the hand, and the composition has excellent hydration and suppresses stickiness. (PH of gel-like hair composition) The pH value of the gel-like hair composition of the present invention at 25 ° C is 5.50 or more from the viewpoint of obtaining a transparent gel and the viewpoint of obtaining hydration. And below 8.20. The pH value can be measured by a known method such as a pH meter. (pH adjuster) The composition for gel-like hair adjusts pH. The base used as the pH adjuster is not particularly limited, and potassium hydroxide, sodium hydroxide, triethanolamine, aminomethylpropanol (AMP), aminomethylpropanediol, and the like can be preferably used. More preferred is aminomethylpropanol (AMP). (Viscosity of the gel-like hair composition) The viscosity of the gel-like hair composition is greater than 1.0 times the viscosity in a state where only the (A) anionic polymer is dissolved or dispersed in (C) water for neutralization, and is not It is 8.0 times, preferably 6 times or less, and further preferably 2 times or less. The elasticity of the gel can be obtained by 1.0 times or more. The hydration degree can be obtained by less than 8.0 times. The ratio of the viscosity of the gel-like hair composition to the viscosity of the anionic polymer is the ratio of the viscosity of the composition containing the cationic polymer to the viscosity of the anionic polymer used alone. Furthermore, in the case of 8.0 times or more, the amount of water carried by the composite is increased, and the stability of the composition is deteriorated. The viscosity of the gel-like hair composition is preferably 12,000 mPa · s or more and 170,000 mPa · s or less, more preferably 12,000 mPa or more and 160,000 mPa or less, and still more preferably 12,000 mPa · s or more and 60,000 mPa · s or less. . When the viscosity of the gel-like hair composition is 12,000 mPa · s or more, elasticity of the gel can be obtained, and when it is 170,000 mPa · s or less, hydration can be obtained. Furthermore, the viscosity of the gel-like hair composition may be appropriately selected depending on the structure of the container. In the present invention, by further containing a nonionic polymer and / or an amphoteric polymer, it is possible to suppress stickiness on the hand and improve the setting force. For example, when a nonionic polymer or an amphoteric polymer is contained in a hair composition containing only an anionic polymer as a polymer, the setting force is increased, but it is also sticky. (Non-ionic polymer, amphoteric polymer) Examples of the non-ionic polymer include polyvinylpyrrolidone [Luviskol K17, Luviskol K30, Luviskol K90 (above manufactured by BASF), which is a non-ionic polymer, PVP K (manufactured by ISP)], vinylpyrrolidone-vinyl acetate copolymer [PVP / VA S-630, PVP / VA E-735, PVP / VA E-335 (above manufactured by ISP), Luviskol VA73W, Luviskol 37E (above manufactured by BASF), PVA-6450 (manufactured by Osaka Organic Chemical Industry Co., Ltd.)], vinyl methyl ether-maleic acid alkyl ester copolymer [Gantrez A-425, Gantrez ES -225, Gantrez ES-335 (all manufactured by ISP)], vinylpyrrolidone-methacrylamide-vinylimidazole copolymer [Luviset Clear (manufactured by BASF)], and the like. Examples of the amphoteric polymer include octylacrylamide-hydroxypropylpropyl acrylate-butylaminoethyl methacrylate copolymer (AMPHOMER SH30, AMPHOMER LV-71 (manufactured by NCS Corporation, Japan)) , Methacryloxyethylcarboxybetaine-alkyl methacrylate copolymer (Yukaformer R205, Yukaformer301, Yukaformer SM, Yukaformer104D, etc. (manufactured by Mitsubishi Chemical Corporation), RAM Resin-1000, RAM Resin-2000 , RAM Resin-3000, RAM Resin-4000 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), dimethyldiallylammonium chloride-acrylic acid copolymer (Merquat 280, Merquat 295 (manufactured by Nalco)), chlorine Dimethyldiallylammonium-acrylamido-acrylic acid copolymer (Merquat Plus 3330, Merquat Plus 3331 (manufactured by Nalco)) and the like. (Other ingredients) The gel-like composition of the present invention can appropriately prepare co-solvents (ethanol, isopropanol, butanol, etc.) and polyols (ethylene glycol, polyethylene, etc.) within a range that does not impair the effects of the present invention. Glycol, propylene glycol, dipropylene glycol, polypropylene glycol, 1,3-butanediol, glycerol, diglycerol, isoamyl glycol, etc.), sugars (sorbitol, maltitol, xylitol, glucose, fructose, mannitol , Inositol, etc.), polymers such as hyaluronic acid, antioxidants, ultraviolet absorbers, preservatives, chelating agents, flavors, colorants, tackifiers, metal blocking agents (ethylenediaminetetraacetate, etc.), pH adjuster. The gel-like hair composition of the present invention can be used as a base material for hair cosmetics. For example, it can be used as a conditioner and a styling agent. (Manufacturing method) The gel-like hair composition of this invention can be manufactured as follows, for example. After adding a cationic polymer and a base (pH adjuster) to water to purify an aqueous solution, an anionic polymer is added. In addition, when adding, it is preferable to add while stirring, if necessary. [Examples] Hereinafter, the present invention will be described in more detail with examples, but the present invention is not limited to these examples. The gel-like hair composition was adjusted according to the formulation shown in Tables 1 to 8 in the following order. (Adjustment method) A cationic polymer is added to purified water and mixed to prepare an aqueous solution of the cationic polymer. Next, a neutralizing agent is added to this aqueous solution. In addition, when adding, if necessary, add it while stirring. Finally, an anionic polymer was added to the aqueous solution of the cationic polymer to obtain a gel-like hair composition. The viscosity of this composition does not change over time and has excellent stability. [Examples 1 to 3, Comparative Examples 1 to 7] A gel-like hair composition was prepared by appropriately changing the type of the anionic polymer. The pH of the gel-like hair composition was adjusted with a pH adjusting agent to be 6 to 6.5. The formulation and evaluation results are shown in Table 1. [Examples 4 to 6, Comparative Examples 8 to 10] The gel-like hair having different ratios of cationic polymer / anionic polymer was produced by setting the content of the anionic polymer to be constant and changing the content of the cationic polymer. With the composition. The pH of the gel-like hair composition was adjusted with a pH adjusting agent to be 6 to 6.5. Table 2 shows the formulation and evaluation results. [Examples 7 to 17, Comparative Example 11 to Comparative Example 21] Gel-like hair compositions having different cationic polymer / anionic polymer ratios were prepared by changing the content of the cationic polymer and the anionic polymer. The pH of the gel-like hair composition was adjusted with a pH adjusting agent to be 6 to 6.5. The formulation and evaluation results are shown in Tables 3, 4, and 5. [Examples 18 to 24, Comparative Examples 22 to 27] The content of the cationic polymer and the anionic polymer was fixed, the ratio of the cationic polymer / anionic polymer was fixed, and the pH was adjusted by The agent produces gel-like hair compositions having different pH values. Table 6 and Table 7 show the formulation and evaluation results. [Examples 25 to 28, Comparative Examples 28 and 29] Cationic polymers having different nitrogen content were used. The formulation and evaluation results are shown in Table 8. The evaluation test methods and evaluation criteria of the examples and comparative examples are as follows. <Viscosity measurement> The viscosity (mPa · s) at 30 ° C was measured using a No. 6 rotor using a Bismetron viscometer (BH type, manufactured by Shibaura Systems Co., Ltd.) at a rotation speed of 10 rpm. <Ease of Disintegration of Agents> A functional test was performed by ten professional functional inspectors, and the ease of disintegration when the base agent was stretched on the hand was evaluated based on the following scoring criteria, and they were totaled according to the following evaluation criteria Scoring for evaluation. B or more was judged to have the disintegration ease of an agent. (Scoring criteria) 5 points: ease of disintegration is visible 4 points: ease of disintegration is slightly visible 3 points: ease of disintegration is slightly visible 2 points: ease of disintegration is hardly seen 0 point: no ease of disintegration ( Evaluation criteria) A: The total score is 40 or more B: The total score is 30 or more C: The total score is 20 or more and less than 30 points D: The total score is 10 or more and less than 20 points E: The total score is not 10 points <Water-moisture on the hand (not sticky)> Ten professional functional inspectors conducted a use test, and the functional evaluation of the water-moisture when the base was spread on the hand was evaluated according to the following scoring criteria, and The total score was evaluated according to the following evaluation criteria. B or more was judged to have a degree of hydration. (Scoring Criteria) 5 points: 4 points of visible wateriness: 3 points of slightly visible wateriness: 3 points of slightly visible wateriness: 2 points of almost no wateriness 0 points: No wateriness (evaluation standard) A: Total A score of 40 or more B: A total score of 25 or more and less than 40 points C: A total score of 10 or more and less than 25 points D: A total score of less than 10 <Ease of affinity to hair> From 10 A professional sensory inspector performs a use test, evaluates the ease of affinity when applying the base that has been stretched on the hand to the hair according to the following scoring criteria, and evaluates the total score based on the following evaluation criteria. B or more was judged to have the affinity for hair. (Scoring criteria) 5 points: ease of affinity to hair 4 points: ease of affinity to hair slightly 3 points: ease of affinity to hair 2 slightly: ease of affinity to hair 0 : No affinity for hair (evaluation criteria) A: Total score is 40 points or more B: Total score is 25 points or more and less than 40 points C: Total score is 10 points or more and less than 25 points <Lightness Sensation> A test was conducted by 10 professional sensory inspectors. The sensory evaluation of the luster after application to the hair was performed according to the following scoring criteria, and the total score was evaluated according to the following evaluation criteria. C or more was judged to have a shiny feeling. (Scoring standard) 5 points: Visible luster feeling 4 points: Slight luster feeling 3 points: Slight luster feeling 2 points: Few luster feelings are hardly seen 0 point: No luster feeling (evaluation standard) A: A total score of 40 points or more B: A total score of 25 points or more and less than 40 points C: A total score of 10 points or more and less than 25 points D: A total score of less than 10 points <Styling power> Checked by 10 professionals The operator performs a use test, performs a sensory evaluation on the styling after application to the hair according to the following scoring criteria, and evaluates the total score based on the following evaluation criteria. It is judged that C or more has a setting force. (Scoring criteria) 5 points: Stereotype is visible 4 points: Slightly stereotyped 3 points: Slightly stereotyped 2 points: Stereotypes are hardly seen 0 points: No stereotypes (evaluation criteria) A: 40 points in total Above B: Total score is 25 points or more and less than 40 points C: Total score is 10 points or more and less than 25 points D: Total score is less than 10 points <Appearance (transparency)> Visual inspection of each sample Appearance (transparency) and evaluated. B or more was judged to have transparency. (Evaluation criteria) A: Very transparent B: Slightly transparent C: Slightly cloudy D: Very cloudy <stability over time> Each sample was evaluated according to the following (appearance evaluation criteria) and (viscosity evaluation criteria) as follows. B or more was judged to have stability over time. (Appearance Evaluation Criteria) The appearance (transparency) of each sample was visually observed and evaluated. B or more was judged to have transparency. A: Very transparent B: Slightly transparent C: Slightly cloudy D: Very cloudy (viscosity evaluation standard) Viscosity is evaluated by comparing the viscosity immediately after manufacturing with the viscosity of a sample stored at 50 ° C for one month. Viscosity ratio = viscosity (stored at 50 ° C for 1 month) / viscosity (just after manufacturing) A: viscosity ratio is 0.5 or more and less than 1.5 B: viscosity ratio is 0.25 or more and less than 0.5, and 1.5 or more and less than 2 C: The viscosity ratio is outside the range of A and B. <Evaluation criteria for stability over time> A: The case where the appearance assessment criterion is A or B and the viscosity assessment criterion is A B: The appearance assessment criterion is B and the viscosity assessment criterion is B. Case C in which the appearance evaluation criterion is C and the viscosity evaluation criterion is A: Cases other than the above A and B are shown in Tables 1 to 8 below. [Table 1] [Table 2] [table 3] [Table 4] [table 5] [TABLE 6] [TABLE 7] [TABLE 8] The details of the materials in the above Tables 1 to 8 are as follows. (Cationic polymer) · Trade name "HC Polymer 1S (M)" (manufactured by Osaka Organic Chemical Industry Co., Ltd.) · Trade name "HC polymer 1N" (manufactured by Osaka Organic Chemical Industry Co., Ltd.) · Trade name `` Polymer JR-400 '' (manufactured by Union Carbide) Product name `` Rubbolgum CG-M '' (manufactured by DSP Gokyo Food & Chemical Co., Ltd.) Product name `` Sensomer CI-50 polymer '' (manufactured by Lubrizol Advanced Materials) Trade name "Cosquat GA468" (manufactured by Osaka Organic Co., Ltd.) Trade name "Merquat 550L" (manufactured by Lubrizol Advanced Materials) (anionic polymer) Trade name "PEMULEN TR-1" (manufactured by Lubrizol Advanced Materials) ) · Trade name "PEMULEN TR-2" (manufactured by Lubrizol Advanced Materials) · Trade name "CARBOPOL981" (manufactured by Lubrizol Advanced Materials) (neutralizer) · Trade name "AMP-ULTRA PC1000" (manufactured by ANGUS Chemical Company) ) · Trade name "Phosphate Domestic Grade 1" (manufactured by Domestic Chemical Co., Ltd.) As shown in Tables 1 and 2, the gel-like hair of the present invention is used Styling compositions without compromising the force disintegrants easiness, in the hands of moistness to the hair affinity and is excellent in easiness, stability over time and also excellent. Comparative Examples 1, 2, 3, 4 and 6 are gel-like hair compositions using an anionic polymer alone. These comparative examples do not have a complex, so it is difficult to feel the ease of disintegration of the agent, and the use feeling is poor. . It is difficult to feel the ease of disintegration of the agent, especially when the viscosity (compared with the cationic polymer, the viscosity in the table is the viscosity of the anionic polymer alone) as in Comparative Examples 4 and 6. In addition, a feeling of luster was not obtained, and the feeling of use was poor. In addition, even if the ratio of cationic polymer / anionic polymer and the viscosity are in a specific range, a relatively large viscosity as shown in Comparative Example 5 means that the amount of water carried in the composite is large and the stability is poor. According to Tables 3 to 5, even if the ratio of the cationic polymer / anionic polymer is 0.17 to 1.80, if the content of the anionic polymer is less than 0.2% by mass, the affinity for hair is also poor. If it is 1.0% by mass or more, the disintegration easiness of the agent and the wetness on the hand are also poor. It is understood that the gel-like hair composition-based agent of the present invention is superior to the gel-like hair composition of the comparative example in terms of ease of disintegration, moisture on the hand, and ease of affinity to the hair. In addition, according to Tables 6 and 7, it can be seen that if the pH value is less than 5.50, the transparency is poor, and if the pH value exceeds 8.20, the disintegration of the agent is poor. Furthermore, it is understood from Table 8 that cationic polymers having different N content ratios can also be applied to the gel-like hair composition of the present invention.