JP2021059506A - Mist-like cosmetics - Google Patents
Mist-like cosmetics Download PDFInfo
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- JP2021059506A JP2021059506A JP2019183662A JP2019183662A JP2021059506A JP 2021059506 A JP2021059506 A JP 2021059506A JP 2019183662 A JP2019183662 A JP 2019183662A JP 2019183662 A JP2019183662 A JP 2019183662A JP 2021059506 A JP2021059506 A JP 2021059506A
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- 239000002537 cosmetic Substances 0.000 title claims abstract description 37
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 60
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 5
- -1 polyoxyethylene Polymers 0.000 claims description 22
- 229920001577 copolymer Polymers 0.000 claims description 21
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 239000010445 mica Substances 0.000 claims description 10
- 229910052618 mica group Inorganic materials 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 9
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- 229920000800 acrylic rubber Polymers 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 2
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 239000003595 mist Substances 0.000 description 9
- 239000006210 lotion Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000003814 drug Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 239000000284 extract Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 125000005250 alkyl acrylate group Chemical group 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- NNOKXWHHOOMPPR-UHFFFAOYSA-N 1-ethenyl-1h-imidazol-1-ium;trichloride Chemical compound [Cl-].[Cl-].[Cl-].C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1 NNOKXWHHOOMPPR-UHFFFAOYSA-N 0.000 description 1
- GGZKJFGVSZKFLD-UHFFFAOYSA-N 1-prop-1-enyl-1h-imidazol-1-ium;chloride Chemical compound [Cl-].CC=CN1C=C[NH+]=C1 GGZKJFGVSZKFLD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 1
- RKQDEBGTFVVJHA-UHFFFAOYSA-N 3-[3-(diethylamino)propyl]pyrrole-2,5-dione Chemical compound CCN(CC)CCCC1=CC(=O)NC1=O RKQDEBGTFVVJHA-UHFFFAOYSA-N 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 244000019459 Cynara cardunculus Species 0.000 description 1
- 235000019106 Cynara scolymus Nutrition 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 125000003282 alkyl amino group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000016520 artichoke thistle Nutrition 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- UTOVMEACOLCUCK-PLNGDYQASA-N butyl maleate Chemical compound CCCCOC(=O)\C=C/C(O)=O UTOVMEACOLCUCK-PLNGDYQASA-N 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
- 229940008406 diethyl sulfate Drugs 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
本発明はミスト状化粧料に関し、特に肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料に関する。 The present invention relates to a mist-like cosmetic, and more particularly to a mist-like cosmetic having excellent skin glossiness, dispersibility of a pearl agent, holding power of a pearl agent on the skin, and non-stickiness of the skin.
化粧水の使用方法として、手に化粧水を適量とり顔全体に馴染ませる方法、コットンに化粧水を適量含ませ顔全体に馴染ませる方法、アトマイザーやディスペンサー等の容器に化粧水を詰めてミスト状化粧料として顔全体に適量プッシュする方法などがある。中でも、簡単に広範囲に均一に塗布することができるミスト状化粧料は、市場で認知されており、一定の需要がある。 To use the lotion, take an appropriate amount of the lotion on your hands and let it blend into the entire face, add an appropriate amount of the lotion to the cotton and let it blend into the entire face, or fill a container such as an atomizer or dispenser with the lotion and make it mist-like. As a cosmetic, there is a method of pushing an appropriate amount over the entire face. Among them, mist-like cosmetics that can be easily and evenly applied over a wide area are recognized in the market and are in constant demand.
特に顔に使用するミスト状化粧料は、メーキャップ化粧料を塗布した後に使用されることが多いため、霧の細かさや肌に塗布した時の使用感に加えて、肌へのツヤを与えることが求められている。 In particular, mist-like cosmetics used on the face are often used after applying make-up cosmetics, so in addition to the fineness of the mist and the feeling of use when applied to the skin, it can give gloss to the skin. It has been demanded.
一般的に、肌へのツヤを与える方法として、パール剤等の高輝性粒子を配合することが知られている。高輝性粒子を配合した例として、高輝性粒子、皮膜形成性樹脂、アニオン性高分子、水を含有する液体化粧料（特許文献１）、ミスト状化粧料として、ジェランガムとアクリル酸メタクリル酸アルキル共重合体を含有する化粧料（特許文献２）が開示されているが、パール剤を多く配合することで肌のツヤ感が増す一方で、パール剤の分散性が悪くなることによるミストの詰まりおよび肌上のパール剤の保持力については課題があった。 In general, it is known to add bright particles such as a pearlizing agent as a method of giving gloss to the skin. Examples of blending high-brightness particles include liquid cosmetics containing high-brightness particles, film-forming resin, anionic polymer, and water (Patent Document 1), and mist-like cosmetics containing gellan gum and alkyl methacrylate. A cosmetic containing a polymer (Patent Document 2) has been disclosed. However, while adding a large amount of a pearl agent increases the glossiness of the skin, the dispersibility of the pearl agent deteriorates, resulting in mist clogging and mist clogging. There was a problem with the holding power of the pearlizing agent on the skin.
本発明は、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料を提供することを課題とする。 An object of the present invention is to provide a mist-like cosmetic having excellent skin glossiness, dispersibility of a pearl agent, holding power of a pearl agent on the skin, and non-stickiness of the skin.
本発明者は、（Ａ）パール剤、（Ｂ）非イオン性界面活性剤、（Ｃ）水溶性被膜形成剤を含有するミスト状化粧料に肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料が得られることを見出し、本発明を完成するに至った。 The present inventor has created a mist-like cosmetic containing (A) a pearl agent, (B) a nonionic surfactant, and (C) a water-soluble film-forming agent to give a glossy skin, dispersibility of the pearl agent, and on the skin. The present invention has been completed by finding that a mist-like cosmetic having excellent retention and non-stickiness of the skin can be obtained.
本発明により、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料を提供する。 INDUSTRIAL APPLICABILITY The present invention provides a mist-like cosmetic having excellent skin glossiness, dispersibility of a pearl agent, holding power of a pearl agent on the skin, and non-stickiness of the skin.
本発明は、（Ａ）パール剤、（Ｂ）非イオン性界面活性剤、（Ｃ）水溶性被膜形成剤を含有するミスト状化粧料である。 The present invention is a mist-like cosmetic containing (A) a pearl agent, (B) a nonionic surfactant, and (C) a water-soluble film-forming agent.
本発明は、肌のツヤ感を付与する観点から、（Ａ）パール剤を含有する。 The present invention contains (A) a pearl agent from the viewpoint of imparting a glossy feeling to the skin.
本発明で用いられる前記（Ａ）成分としては、特に限定されないが、例えば、酸化チタン被覆ガラス末、酸化チタン処理合成金雲母、酸化チタン被覆雲母、酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、シリカ処理雲母チタン、オキシ塩化ビスマス、魚鱗箔等の光輝性粉体、酸化鉄被覆雲母、有機顔料処理雲母チタン、無水ケイ酸・ベンガラ処理アルミニウム末等を挙げることができる。前記（Ａ）成分は１種以上を含有してよい。 The component (A) used in the present invention is not particularly limited, but for example, titanium oxide-coated glass powder, titanium oxide-treated synthetic gold mica, titanium oxide-coated mica, titanium oxide-coated bismuth oxychloride, titanium oxide mica, and the like. Navy blue treated titanium, carmine treated titanium, silica treated titanium, bismuth oxychloride, bright powder such as fish scale foil, iron oxide coated titanium oxide, organic pigment treated titanium, silicic anhydride / red iron oxide treated aluminum powder, etc. be able to. The component (A) may contain one or more kinds.
本発明で用いられる前記（Ａ）成分のうち、肌のツヤ感を付与する観点から、酸化チタン被覆雲母およびシリカ処理雲母チタンが好ましい。 Among the components (A) used in the present invention, titanium oxide-coated mica and silica-treated mica titanium are preferable from the viewpoint of imparting a glossy feeling to the skin.
本発明で用いられる前記（Ａ）成分の含有量は、好ましくは０．１〜４質量％、より好ましくは０．５〜２質量％がよい。前記（Ａ）成分の含有量が０．１質量％未満の場合、肌のツヤ感が得られない恐れがある。前記（Ａ）成分が４質量％を超える場合、パール剤の分散性および肌上のパール剤の保持力が悪くなる恐れがある。 The content of the component (A) used in the present invention is preferably 0.1 to 4% by mass, more preferably 0.5 to 2% by mass. If the content of the component (A) is less than 0.1% by mass, the glossiness of the skin may not be obtained. If the component (A) exceeds 4% by mass, the dispersibility of the pearlizing agent and the holding power of the pearlizing agent on the skin may deteriorate.
本発明は、パール剤の分散性を良好にする観点から、（Ｂ）非イオン性界面活性剤を含有する。 The present invention contains (B) a nonionic surfactant from the viewpoint of improving the dispersibility of the pearlizing agent.
本発明で用いられる前記（Ｂ）成分としては、特に限定されないが、例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレングリコール、アルキルグリセリルエーテル、ポリエチレングリコール脂肪酸エステル、ショ糖脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、アルキルアルカノールアミド、アルキル脂肪酸アルカノールアミド、アルキルポリグルコシド等が挙げることができる。前記（Ｂ）成分は１種以上を含有してよい。 The component (B) used in the present invention is not particularly limited, but for example, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid. Esters, polyoxyethylene alkyl ethers, polyoxyethylene polyoxypropylene glycols, alkyl glyceryl ethers, polyethylene glycol fatty acid esters, sucrose fatty acid esters, polyoxyethylene hydrogenated castor oil, alkyl alkanolamides, alkyl fatty acid alkanolamides, alkyl polyglucosides, etc. Can be mentioned. The component (B) may contain one or more kinds.
本発明で用いられる前記（Ｂ）成分のうち、パール剤の分散性の良さの観点から、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビタン脂肪酸エステルが好ましい。 Among the components (B) used in the present invention, polyoxyethylene hydrogenated castor oil and polyoxyethylene sorbitan fatty acid ester are preferable from the viewpoint of good dispersibility of the pearlizing agent.
本発明で用いられる前記（Ｂ）成分のうち、さらに好ましくは、ポリオキシエチレンの平均付加モル数が４０または６０であるポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンの平均付加モル数が２０であるモノステアリン酸ポリオキシエチレンソルビタンが好ましい。 Among the components (B) used in the present invention, more preferably, polyoxyethylene hydrogenated castor oil having an average addition mole number of 40 or 60 and polyoxyethylene having an average addition mole number of 20. Polyoxyethylene sorbitan monostearate is preferred.
本発明で用いられる前記（Ｂ）成分の含有量は、０．１〜２質量％、より好ましくは０．５〜１．５質量％がよい。前記（Ｂ）成分の含有量が０．１質量％未満の場合、パール剤の分散性が悪くなる恐れがある。前記（Ｂ）成分の含有量が２質量％を超える場合、べたつきが生じる恐れがある。 The content of the component (B) used in the present invention is preferably 0.1 to 2% by mass, more preferably 0.5 to 1.5% by mass. If the content of the component (B) is less than 0.1% by mass, the dispersibility of the pearlizing agent may deteriorate. If the content of the component (B) exceeds 2% by mass, stickiness may occur.
本発明は、肌上のパール剤の保持力および肌のべたつきのなさの観点から、（Ｃ）水溶性被膜形成剤を含有する。 The present invention contains (C) a water-soluble film-forming agent from the viewpoint of the holding power of the pearl agent on the skin and the non-stickiness of the skin.
本発明で用いられる前記（Ｃ）成分としては、特に限定されないが、例えば、陰イオン性被膜形成剤、陽イオン性被膜形成剤、両性被膜形成剤、非イオン性被膜形成剤等が挙げられる。前記（Ｃ）成分は１種以上を含有してよい。 The component (C) used in the present invention is not particularly limited, and examples thereof include an anionic film forming agent, a cationic film forming agent, an amphoteric film forming agent, and a nonionic film forming agent. The component (C) may contain one or more kinds.
本発明で用いられる前記（Ｃ）成分の陰イオン性被膜形成剤としては、例えば、アクリル酸アルキル共重合体、アクリル酸・アクリル酸アルキル共重合体、アクリル樹脂アルカノールアミン、メチルビニルエーテル／マレイン酸エステル共重合体、酢酸ビニル・クロトン酸共重合体、クロトン酸・酢酸ビニル・ネオデカン酸ビニル共重合体、酢酸ビニル／クロトン酸／プロピオン酸ビニル共重合体、酢酸ビニル／マレイン酸モノブチルエステル／イソボロリルアクリレート共重合体、アクリル酸／アクリル酸アルキルエステル／アルキルアクリルアミド共重合体、ビニルピロリドン／アクリレーツ／（メタ）アクリル酸アルキル共重合体、スチレン／（メタ）アクリル酸アルキル共重合体、スチレン／アクリル酸アミド共重合体、ウレタン−アクリル系共重合体、ポリスチレンスルホン酸ナトリウム等が挙げられる。 Examples of the anionic film-forming agent of the component (C) used in the present invention include an alkyl acrylate copolymer, an alkyl acrylate / alkyl acrylate copolymer, an acrylic resin alkanolamine, and a methyl vinyl ether / maleic acid ester. Copolymer, vinyl acetate / crotonic acid copolymer, crotonic acid / vinyl acetate / vinyl neodecanoate copolymer, vinyl acetate / crotonic acid / vinyl propionate copolymer, vinyl acetate / maleic acid monobutyl ester / isoboro Lil acrylate copolymer, acrylic acid / alkyl acrylate / alkyl acrylamide copolymer, vinyl pyrrolidone / acrylicite / (meth) alkyl acrylate copolymer, styrene / alkyl (meth) acrylate copolymer, styrene / acrylic Examples thereof include acid amide copolymers, urethane-acrylic copolymers, and sodium polystyrene sulfonate.
本発明で用いられる前記（Ｃ）成分の陽イオン性被膜形成剤としては、例えば、ビニルピロリドン・Ｎ，Ｎ−ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、塩化О−［２−ヒドロキシ−３−（トリメチルアンモニオ）プロピル］ヒドロキシエチルセルロース、ビニルイミダゾリウムトリクロライド／ビニルピロリドン共重合体、ヒドロキシエチルセルロース／ジメチルジアリルアンモニウムクロリド、ポリビニルピロリドン／アルキルアミノアクリレート／ビニルカプロラクタム共重合体、塩化メチルビニルイミダゾリウム・ビニルピロリドン共重合体、ビニルピロリドン／ジメチルアミノプロピルメタクリルアミド／ラウリルジメチルアミノプロピルメタクリルアミド共重合体等が挙げられる。 Examples of the cationic film-forming agent of the component (C) used in the present invention include vinylpyrrolidone / N, N-dimethylaminoethyl methacrylate copolymer diethyl sulfate, and О- [2-hydroxy-3 chloride. -(Trimethylammonio) propyl] hydroxyethyl cellulose, vinyl imidazolium trichloride / vinyl pyrrolidone copolymer, hydroxyethyl cellulose / dimethyldialyl ammonium chloride, polyvinylpyrrolidone / alkyl amino acrylate / vinyl caprolactam copolymer, methyl vinyl imidazolium chloride Examples thereof include vinylpyrrolidone copolymer, vinylpyrrolidone / dimethylaminopropylmethacrylamide / lauryldimethylaminopropylmethacrylate copolymer and the like.
本発明で用いられる前記（Ｃ）成分の両性被膜形成剤としては、例えば、Ｎ−メタクリロイルオキシエチルＮ，Ｎ−ジメチルアンモニウム−α−Ｎ−メチルカルボキシベタイン・メタクリル酸アルキルエステル共重合体、Ｎ，Ｎジメチル−Ｎ−（２−メタクリロイルオキシエチル）アミン−Ｎ−オキシド・メタクリル酸アルキルエステル共重合体、アクリル酸ヒドロキシプロピル／メタクリル酸ブチルアミノエチル／アクリル酸オクチルアミド共重合体、ジアルキルアミノエチルメタクリレート／メタクリル酸アルキルエステル共重合体のモノクロル酢酸両性化物、イソブチレン／ジエチルアミノプロピルマレイミド／マレイン酸共重合体等が挙げられる。 Examples of the amphoteric film-forming agent of the component (C) used in the present invention include N-methacryloyloxyethyl N, N-dimethylammonium-α-N-methylcarboxybetaine / alkyl methacrylate copolymer, N, N-dimethyl-N- (2-methacryloyloxyethyl) amine-N-oxide-alkyl methacrylate copolymer, hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer, dialkylaminoethyl methacrylate / Monochloroacetic acid amphoteric products of methacrylic acid alkyl ester copolymers, isobutylene / diethylaminopropyl maleimide / maleic acid copolymers and the like can be mentioned.
本発明で用いられる前記（Ｃ）成分の非イオン性被膜形成剤としては、例えば、ポリビニルピロリドン、酢酸ビニル・ビニルピロリドン共重合体、ビニルピロリドン／メタクリルアミド／ビニルイミダゾール共重合体、ポリビニルアルコール、ポリビニルカプロラクタム等が挙げられる。 Examples of the nonionic film-forming agent of the component (C) used in the present invention include polyvinylpyrrolidone, vinyl acetate / vinylpyrrolidone copolymer, vinylpyrrolidone / methacrylamide / vinylimidazole copolymer, polyvinyl alcohol, and polyvinyl. Caprolactam and the like can be mentioned.
本発明の前記（Ｃ）成分としては、肌上のパール剤の保持力および肌のべたつきのなさの観点から、非イオン性被膜形成剤および陰イオン性被膜形成剤から選ばれる１種以上を用いることが好ましく、これら良好な被膜形成剤の中でも、ポリビニルピロリドン、酢酸ビニル・ビニルピロリドン共重合体およびアクリル酸アルキル共重合体が好ましい。 As the component (C) of the present invention, one or more selected from nonionic film forming agents and anionic film forming agents are used from the viewpoint of the holding power of the pearlizing agent on the skin and the non-stickiness of the skin. Of these good film-forming agents, polyvinylpyrrolidone, a vinyl acetate / vinylpyrrolidone copolymer, and an alkyl acrylate copolymer are preferable.
本発明で用いられる前記（Ｃ）成分の含有量は、０．１〜１質量％、より好ましくは０．３〜０．５質量％がよい。前記（Ｃ）成分の含有量が０．１質量％未満の場合、肌上のパール剤の保持力が得られない恐れがある。前記（Ｃ）成分の含有量が１質量％を超える場合、肌のべたつきが悪くなる恐れがある。 The content of the component (C) used in the present invention is preferably 0.1 to 1% by mass, more preferably 0.3 to 0.5% by mass. If the content of the component (C) is less than 0.1% by mass, the holding power of the pearlizing agent on the skin may not be obtained. If the content of the component (C) exceeds 1% by mass, the stickiness of the skin may worsen.
本発明における２０℃条件下によるｐＨは、弱酸性の観点から４．５〜６．５であり、より好ましくは５〜６である。 The pH under the 20 ° C. condition in the present invention is 4.5 to 6.5, more preferably 5 to 6 from the viewpoint of weak acidity.
本発明における２０℃条件下によるｐＨは、常法にて調製して得られたミスト状化粧料をサンプル瓶（食品１４０：第一硝子株式会社製）に１２０ｇ充填し、２０℃条件下で２４時間静置した後に、ガラス電極式水素イオン濃度指示計（Ｆ−７１、堀場製作所製）にて原液のｐＨを測定し得られるものである。 The pH of the present invention under 20 ° C. conditions is such that 120 g of a mist-like cosmetic prepared by a conventional method is filled in a sample bottle (Food 140: manufactured by Daiichi Glass Co., Ltd.) and 24 under 20 ° C. conditions. After allowing to stand for a long time, the pH of the undiluted solution can be measured with a glass electrode type hydrogen ion concentration indicator (F-71, manufactured by Horiba Seisakusho).
本発明のミスト状化粧料は前記必須成分の他に、通常の化粧料、医薬部外品、医薬品等に用いられる各種成分、例えば、（Ａ）成分以外の紛体、ビタミン類、キレート剤、ｐＨ調整剤、増粘剤、油性成分、保湿剤、薬効成分、蛋白誘導体、加水分解蛋白、酸化防止剤、還元剤、植物性抽出物、生薬抽出物、香料、防腐剤、色素、顔料、紫外線吸収剤、（Ｂ）成分以外の界面活性剤等から選ばれる少なくとも１種以上を含有することができる。ただし、これら例示に限定されるものではない。 In addition to the essential ingredients, the mist-like cosmetics of the present invention have various ingredients used in ordinary cosmetics, quasi-drugs, pharmaceuticals, etc., for example, powders other than the component (A), vitamins, chelating agents, pH. Regulators, thickeners, oily ingredients, moisturizers, quasi-drugs, protein derivatives, hydrolyzed proteins, antioxidants, reducing agents, vegetable extracts, crude drug extracts, fragrances, preservatives, pigments, pigments, UV absorption It can contain at least one selected from agents, surfactants other than the component (B), and the like. However, the present invention is not limited to these examples.
本発明のミスト状化粧料は、液状、ジェル状等の形態で用いられ、ディスペンサー容器に充填され、使用時まで保存される。 The mist-like cosmetic of the present invention is used in the form of liquid, gel, etc., is filled in a dispenser container, and is stored until the time of use.
本発明のミスト状化粧水のミストディスペンサーとしては、特に限定はされないが、例えばミストディスペンサーＺ−１５５−Ｃ０９４−１−０６０（９５−０）、（吐出量０．１５ｍＬ／１プッシュ、三谷バルブ社製）を用いることができる。 The mist dispenser of the mist-like cosmetic water of the present invention is not particularly limited, but for example, mist dispenser Z-155-C094-1-060 (95-0), (discharge rate 0.15 mL / 1 push, Mitani Valve Co., Ltd.) ) Can be used.
以下に実施例を挙げて本発明をさらに詳細に説明するが、これらは本発明を何ら限定するものではない。 Hereinafter, the present invention will be described in more detail with reference to examples, but these are not intended to limit the present invention in any way.
本明細書に示す評価試験において、ミスト状化粧料に含まれる成分、およびその含有量を種々変更しながら実施した。各成分の含有量を示す単位はすべて質量％であり、これを常法にて調製した。 In the evaluation test shown in the present specification, the components contained in the mist-like cosmetics and their contents were variously changed. The unit indicating the content of each component is all mass%, which was prepared by a conventional method.
本明細書に示す評価試験において、「肌のツヤ感」、「パール剤の分散性」、「肌上のパール剤の保持力」および「肌のべたつきのなさ」について下記の方法で評価した。 In the evaluation test shown in the present specification, "skin glossiness", "dispersity of pearl agent", "holding power of pearl agent on skin" and "non-stickiness of skin" were evaluated by the following methods.
「肌のツヤ感」
各ミスト状化粧水を１００ｍＬ用ＰＥＴ容器に７０ｍＬ充填し、２５℃条件下でミストディスペンサー（Ｚ−１５５−Ｃ０９４−１−０６０（９５−０）：三谷バルブ社製）を用いて、実施例および比較例で得られた各ミスト状化粧料を塗布し、塗布後から５分間経過した後の肌のツヤ感を目視にて評価した。評価は専門のパネラー２０名が実施例および比較例のミスト状化粧料１０プッシュを顔面全体に塗布し、肌のツヤ感を評価した。
◎：２０名中１６名以上が肌のツヤ感があると評価した。
○：２０名中１１名以上１５名以下が肌のツヤ感があると評価した。
△：２０名中６名以上１０名以下が肌のツヤ感があると評価した。
×：２０名中５名以下が肌のツヤ感があると評価した。
"Glossy skin"
70 mL of each mist-like lotion is filled in a 100 mL PET container, and under 25 ° C. conditions, a mist dispenser (Z-155-C094-1-060 (95-0): manufactured by Mitani Valve Co., Ltd.) is used in Examples and Each mist-like cosmetic obtained in the comparative example was applied, and the glossiness of the skin 5 minutes after the application was visually evaluated. In the evaluation, 20 specialized panelists applied 10 pushes of mist-like cosmetics of Examples and Comparative Examples to the entire face to evaluate the glossiness of the skin.
⊚: 16 or more out of 20 evaluated that the skin had a glossy feeling.
◯: Among 20 persons, 11 to 15 persons evaluated that the skin had a glossy feeling.
Δ: 6 or more and 10 or less out of 20 evaluated that the skin had a glossy feeling.
X: 5 or less out of 20 evaluated that the skin had a glossy feeling.
「パール剤の分散性」
各ミスト状化粧水を１００ｍＬ用ＰＥＴ容器に７０ｍＬ充填し、２５℃条件下でミストディスペンサー（Ｚ−１５５−Ｃ０９４−１−０６０（９５−０）：三谷バルブ社製）を用いて、実施例および比較例で得られた各ミスト状化粧料を、２５℃条件下で２４時間静置し、パール剤を沈降させた後に、手で振り混ぜて再分散に要する回数で評価した。
◎：１０回以内に再分散した。
○：１１回以上３０回以内で再分散した。
×：３１回以上でも再分散しなかった。
"Dispersibility of pearl agent"
70 mL of each mist-like lotion was filled in a 100 mL PET container, and under 25 ° C. conditions, a mist dispenser (Z-155-C094-1-060 (95-0): manufactured by Mitani Valve Co., Ltd.) was used in Examples and Each mist-like cosmetic obtained in Comparative Example was allowed to stand for 24 hours under the condition of 25 ° C., the pearl agent was allowed to settle, and then shaken by hand to evaluate the number of times required for redispersion.
⊚: Redispersed within 10 times.
◯: Redispersed within 11 to 30 times.
X: No redispersion occurred even 31 times or more.
「肌上のパール剤の保持力」
各ミスト状化粧水を１００ｍＬ用ＰＥＴ容器に７０ｍＬ充填し、２５℃条件下でミストディスペンサー（Ｚ−１５５−Ｃ０９４−１−０６０（９５−０）：三谷バルブ社製）を用いて、実施例および比較例で得られた各ミスト状化粧料を塗布し、塗布後から５分間経過した後の肌上のパール剤の保持力を目視にて評価した。評価は専門のパネラー２０名が実施例および比較例のミスト状化粧料０．５ｇを顔面全体に塗布し、肌上のパール剤の保持力を評価した。
◎：２０名中１６名以上が肌上のパール剤の保持力があると評価した。
○：２０名中１１名以上１５名以下が肌上のパール剤の保持力があると評価した。
△：２０名中６名以上１０名以下が肌上のパール剤の保持力があると評価した。
×：２０名中５名以下が肌上のパール剤の保持力があると評価した。
"Holding power of pearl agent on the skin"
70 mL of each mist-like lotion was filled in a 100 mL PET container, and under 25 ° C. conditions, a mist dispenser (Z-155-C094-1-060 (95-0): manufactured by Mitani Valve Co., Ltd.) was used in Examples and Each mist-like cosmetic obtained in the comparative example was applied, and the holding power of the pearl agent on the skin 5 minutes after the application was visually evaluated. In the evaluation, 20 specialized panelists applied 0.5 g of the mist-like cosmetics of Examples and Comparative Examples to the entire face, and evaluated the holding power of the pearl agent on the skin.
⊚: 16 or more out of 20 evaluated that the pearl agent had a holding power on the skin.
◯: Of the 20 subjects, 11 or more and 15 or less evaluated that they had the ability to retain the pearl agent on the skin.
Δ: 6 or more and 10 or less out of 20 evaluated that the pearl agent had a holding power on the skin.
X: 5 or less out of 20 evaluated that the pearl agent had a holding power on the skin.
「べたつきのなさ」
各ミスト状化粧水を１００ｍＬ用ＰＥＴ容器に７０ｍＬ充填し、２５℃条件下でミストディスペンサー（Ｚ−１５５−Ｃ０９４−１−０６０（９５−０）：三谷バルブ社製）を用いて、実施例および比較例で得られた各ミスト状化粧料を塗布し、塗布後から５分間経過した後のべたつきを官能にて評価した。評価は専門のパネラー２０名が実施例および比較例のミスト状化粧料を２０℃に温度調整し、０．５ｇを２０℃の条件下で顔面全体に塗布し、べたつきを評価した。
◎：２０名中１６名以上がべたつきを感じないと評価した。
○：２０名中１１名以上１５名以下がべたつきを感じないと評価した。
△：２０名中６名以上１０名以下がべたつきを感じないと評価した。
×：２０名中５名以下がべたつきを感じないと評価した。
"Non-stickiness"
70 mL of each mist-like lotion is filled in a 100 mL PET container, and under 25 ° C. conditions, a mist dispenser (Z-155-C094-1-060 (95-0): manufactured by Mitani Valve Co., Ltd.) is used in Examples and Each mist-like cosmetic obtained in the comparative example was applied, and the stickiness after 5 minutes had passed after the application was sensoriwise evaluated. In the evaluation, 20 specialized panelists adjusted the temperature of the mist-like cosmetics of Examples and Comparative Examples to 20 ° C., and applied 0.5 g to the entire face under the condition of 20 ° C. to evaluate the stickiness.
⊚: More than 16 out of 20 people evaluated that they did not feel sticky.
◯: Among 20 people, 11 to 15 people evaluated that they did not feel sticky.
Δ: 6 or more and 10 or less out of 20 evaluated that they did not feel sticky.
X: 5 out of 20 people evaluated that they did not feel sticky.
表１〜表４に示す実施例１〜２７から、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさについて良好な結果を得ることが確認された。 From Examples 1 to 27 shown in Tables 1 to 4, it was confirmed that good results were obtained regarding the glossiness of the skin, the dispersibility of the pearl agent, the holding power of the pearl agent on the skin, and the non-stickiness of the skin. ..
実施例２８を使用して各種試験を行っても、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさのいずれの評価も良好であった。 Even when various tests were performed using Example 28, all of the evaluations of the glossiness of the skin, the dispersibility of the pearl agent, the holding power of the pearl agent on the skin, and the non-stickiness of the skin were good.
＜実施例２８＞
成 分 含有量（質量％）
（Ａ）酸化チタン被覆雲母（※１） ０．６００
（Ａ）シリカ処理雲母チタン（※２） ０．１００
（Ａ）シリカ処理雲母チタン（※３） ０．１００
（Ｂ）ポリオキシエチレン硬化ヒマシ油（６０ＥＯ） １．０００
（Ｃ）ポリビニルピロリドン ０．３００
安息香酸ナトリウム ０．３００
１， ３−ブチレングリコール ４．０００
エデト酸二ナトリウム ０．１００
クエン酸 ０．１００
クエン酸ナトリウム ０．３５０
アーチチョークエキス ０．０１０
植物性スクワラン ０．００１
ポリオキシエチレンラウリルエーテルリン酸ナトリウム（１０ＥＯ） ０．０１０
香料 ０．０２０
精製水 ９３．００９
合計 １００．０００
※１：Ｔｉｍｉｒｏｎ Ｓｕｐｅｒｓｈｅｅｎ ＭＰ−１００１（ＭＥＲＣＫ社製）
※２：Ｔｉｍｉｒｏｎ Ｓｐｌｅｎｄｉｄ Ｖｉｏｌｅｔ（ＭＥＲＣＫ社製）
※３：Ｔｉｍｉｒｏｎ Ｓｐｌｅｎｄｉｄ Ｒｅｄ（ＭＥＲＣＫ社製）
<Example 28>
Ingredient content (wt%)
(A) Titanium oxide-coated mica (* 1) 0.600
(A) Silica-treated mica titanium (* 2) 0.100
(A) Silica-treated mica titanium (* 3) 0.100
(B) Polyoxyethylene hydrogenated castor oil (60EO) 1,000
(C) Polyvinylpyrrolidone 0.300
Sodium benzoate 0.300
1, 3-butylene glycol 4.000
Disodium edetate 0.100
Citric acid 0.100
Sodium citrate 0.350
Artichoke extract 0.010
Vegetable squalane 0.001
Polyoxyethylene Lauryl Ether Sodium Phosphate (10EO) 0.010
Fragrance 0.020
Purified water 93.09
100.000 in total
* 1: Timiron Superseen MP-1001 (manufactured by MERCK)
* 2: Timiron Splendid Violet (manufactured by MERCK)
* 3: Timiron Splendid Red (manufactured by MERCK)
本発明は、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料を得ることができる。 INDUSTRIAL APPLICABILITY According to the present invention, it is possible to obtain a mist-like cosmetic having excellent skin glossiness, dispersibility of the pearl agent, holding power of the pearl agent on the skin, and non-stickiness of the skin.
Claims (7)
（Ｂ）非イオン性界面活性剤
（Ｃ）水溶性被膜形成剤
を含有することを特徴とするミスト状化粧料。 A mist-like cosmetic containing (A) a pearl agent (B) a nonionic surfactant (C) and a water-soluble film-forming agent.
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| JP2018108966A (en) * | 2017-01-04 | 2018-07-12 | 株式会社コーセー | Aerosol type cosmetic |
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| JP2010018598A (en) | 2008-07-10 | 2010-01-28 | Taiyo Sangyo Kk | Film-forming pharmaceutically effective composition |
| JP5416382B2 (en) | 2008-10-06 | 2014-02-12 | 花王株式会社 | Double layer cosmetic |
| JP6799490B2 (en) | 2016-03-28 | 2020-12-16 | 株式会社コーセー | Aerosol type cosmetics |
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