JP7431433B2 - mist cosmetics - Google Patents
mist cosmetics Download PDFInfo
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- JP7431433B2 JP7431433B2 JP2019183662A JP2019183662A JP7431433B2 JP 7431433 B2 JP7431433 B2 JP 7431433B2 JP 2019183662 A JP2019183662 A JP 2019183662A JP 2019183662 A JP2019183662 A JP 2019183662A JP 7431433 B2 JP7431433 B2 JP 7431433B2
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- 239000002537 cosmetic Substances 0.000 title claims description 30
- 239000003595 mist Substances 0.000 title description 32
- -1 polyoxyethylene Polymers 0.000 claims description 25
- 229920001577 copolymer Polymers 0.000 claims description 21
- 239000010445 mica Substances 0.000 claims description 14
- 229910052618 mica group Inorganic materials 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 8
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 229920000800 acrylic rubber Polymers 0.000 claims description 4
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 2
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 description 54
- 230000014759 maintenance of location Effects 0.000 description 19
- 235000014113 dietary fatty acids Nutrition 0.000 description 10
- 239000000194 fatty acid Substances 0.000 description 10
- 229930195729 fatty acid Natural products 0.000 description 10
- 239000006210 lotion Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 238000011156 evaluation Methods 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 3
- 206010051788 Sticky skin Diseases 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 2
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229940073609 bismuth oxychloride Drugs 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- JBKVHLHDHHXQEQ-UHFFFAOYSA-N epsilon-caprolactam Chemical compound O=C1CCCCCN1 JBKVHLHDHHXQEQ-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- BWOROQSFKKODDR-UHFFFAOYSA-N oxobismuth;hydrochloride Chemical compound Cl.[Bi]=O BWOROQSFKKODDR-UHFFFAOYSA-N 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 1
- NNOKXWHHOOMPPR-UHFFFAOYSA-N 1-ethenyl-1h-imidazol-1-ium;trichloride Chemical compound [Cl-].[Cl-].[Cl-].C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1.C=C[NH+]1C=CN=C1 NNOKXWHHOOMPPR-UHFFFAOYSA-N 0.000 description 1
- GGZKJFGVSZKFLD-UHFFFAOYSA-N 1-prop-1-enyl-1h-imidazol-1-ium;chloride Chemical compound [Cl-].CC=CN1C=C[NH+]=C1 GGZKJFGVSZKFLD-UHFFFAOYSA-N 0.000 description 1
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 1
- YZBOVSFWWNVKRJ-UHFFFAOYSA-M 2-butoxycarbonylbenzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1C([O-])=O YZBOVSFWWNVKRJ-UHFFFAOYSA-M 0.000 description 1
- QZPSOSOOLFHYRR-UHFFFAOYSA-N 3-hydroxypropyl prop-2-enoate Chemical compound OCCCOC(=O)C=C QZPSOSOOLFHYRR-UHFFFAOYSA-N 0.000 description 1
- FLCAEMBIQVZWIF-UHFFFAOYSA-N 6-(dimethylamino)-2-methylhex-2-enamide Chemical compound CN(C)CCCC=C(C)C(N)=O FLCAEMBIQVZWIF-UHFFFAOYSA-N 0.000 description 1
- 229920002126 Acrylic acid copolymer Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 244000019459 Cynara cardunculus Species 0.000 description 1
- 235000019106 Cynara scolymus Nutrition 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- 240000001624 Espostoa lanata Species 0.000 description 1
- 235000009161 Espostoa lanata Nutrition 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229920006322 acrylamide copolymer Polymers 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229920006318 anionic polymer Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000016520 artichoke thistle Nutrition 0.000 description 1
- 235000019437 butane-1,3-diol Nutrition 0.000 description 1
- 235000012730 carminic acid Nutrition 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- DENRZWYUOJLTMF-UHFFFAOYSA-N diethyl sulfate Chemical compound CCOS(=O)(=O)OCC DENRZWYUOJLTMF-UHFFFAOYSA-N 0.000 description 1
- 229940008406 diethyl sulfate Drugs 0.000 description 1
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229940124274 edetate disodium Drugs 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 229920003145 methacrylic acid copolymer Polymers 0.000 description 1
- 229940117841 methacrylic acid copolymer Drugs 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- WTGWCKSYRILKFO-UHFFFAOYSA-N n,n-dimethyl-2-(2-methylprop-2-enoyloxy)ethanamine oxide Chemical compound CC(=C)C(=O)OCC[N+](C)(C)[O-] WTGWCKSYRILKFO-UHFFFAOYSA-N 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229910052628 phlogopite Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001467 poly(styrenesulfonates) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- 230000037075 skin appearance Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229940006186 sodium polystyrene sulfonate Drugs 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
Description
本発明はミスト状化粧料に関し、特に肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料に関する。 The present invention relates to a cosmetic mist, and particularly to a cosmetic mist that is excellent in skin gloss, pearl agent dispersibility, pearl agent retention on the skin, and non-sticky skin.
化粧水の使用方法として、手に化粧水を適量とり顔全体に馴染ませる方法、コットンに化粧水を適量含ませ顔全体に馴染ませる方法、アトマイザーやディスペンサー等の容器に化粧水を詰めてミスト状化粧料として顔全体に適量プッシュする方法などがある。中でも、簡単に広範囲に均一に塗布することができるミスト状化粧料は、市場で認知されており、一定の需要がある。 How to use lotion: Take an appropriate amount of lotion in your hand and spread it over the entire face, soak a cotton ball with an appropriate amount of lotion and spread it over the entire face, or fill a container such as an atomizer or dispenser with lotion to create a mist. There are methods such as pushing an appropriate amount onto the entire face as a cosmetic. Among these, mist-type cosmetics that can be easily and uniformly applied over a wide area are recognized in the market and are in constant demand.
特に顔に使用するミスト状化粧料は、メーキャップ化粧料を塗布した後に使用されることが多いため、霧の細かさや肌に塗布した時の使用感に加えて、肌へのツヤを与えることが求められている。 In particular, mist-type cosmetics used on the face are often used after applying makeup cosmetics, so in addition to the fineness of the mist and the feeling of use when applied to the skin, it is possible to add shine to the skin. It has been demanded.
一般的に、肌へのツヤを与える方法として、パール剤等の高輝性粒子を配合することが知られている。高輝性粒子を配合した例として、高輝性粒子、皮膜形成性樹脂、アニオン性高分子、水を含有する液体化粧料（特許文献１）、ミスト状化粧料として、ジェランガムとアクリル酸メタクリル酸アルキル共重合体を含有する化粧料（特許文献２）が開示されているが、パール剤を多く配合することで肌のツヤ感が増す一方で、パール剤の分散性が悪くなることによるミストの詰まりおよび肌上のパール剤の保持力については課題があった。 Generally, it is known that a method of imparting luster to the skin is to incorporate high brightness particles such as pearlescent agents. Examples of formulations containing high-gloss particles include liquid cosmetics containing high-gloss particles, film-forming resins, anionic polymers, and water (Patent Document 1), and mist cosmetics containing gellan gum and alkyl acrylate methacrylates. Cosmetics containing polymers (Patent Document 2) have been disclosed, but while the inclusion of a large amount of pearlescent agent increases the glossiness of the skin, it also causes problems such as mist clogging and mist clogging due to poor dispersibility of the pearlescent agent. There was a problem with the retention of the pearl agent on the skin.
本発明は、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料を提供することを課題とする。 An object of the present invention is to provide a cosmetic mist that is excellent in skin gloss, pearl agent dispersibility, pearl agent retention on the skin, and non-sticky skin.
本発明者は、（Ａ）パール剤、（Ｂ）非イオン性界面活性剤、（Ｃ）水溶性被膜形成剤を含有するミスト状化粧料に肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料が得られることを見出し、本発明を完成するに至った。 The present inventor has developed a cosmetic mist containing (A) a pearl agent, (B) a nonionic surfactant, and (C) a water-soluble film-forming agent that improves skin gloss, dispersibility of the pearl agent, and improves skin appearance. The present inventors have discovered that it is possible to obtain a cosmetic mist that has excellent pearl agent retention and no stickiness on the skin, and has completed the present invention.
本発明により、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料を提供する。 ADVANTAGE OF THE INVENTION According to the present invention, there is provided a mist cosmetic which is excellent in skin gloss, pearl agent dispersibility, pearl agent retention on the skin, and no stickiness on the skin.
本発明は、（Ａ）パール剤、（Ｂ）非イオン性界面活性剤、（Ｃ）水溶性被膜形成剤を含有するミスト状化粧料である。 The present invention is a cosmetic mist containing (A) a pearlescent agent, (B) a nonionic surfactant, and (C) a water-soluble film-forming agent.
本発明は、肌のツヤ感を付与する観点から、（Ａ）パール剤を含有する。 The present invention contains (A) a pearl agent from the viewpoint of imparting a glossy feeling to the skin.
本発明で用いられる前記（Ａ）成分としては、特に限定されないが、例えば、酸化チタン被覆ガラス末、酸化チタン処理合成金雲母、酸化チタン被覆雲母、酸化チタン被覆オキシ塩化ビスマス、酸化鉄雲母チタン、紺青処理雲母チタン、カルミン処理雲母チタン、シリカ処理雲母チタン、オキシ塩化ビスマス、魚鱗箔等の光輝性粉体、酸化鉄被覆雲母、有機顔料処理雲母チタン、無水ケイ酸・ベンガラ処理アルミニウム末等を挙げることができる。前記（Ａ）成分は１種以上を含有してよい。 The component (A) used in the present invention is not particularly limited, but includes, for example, titanium oxide coated glass powder, titanium oxide treated synthetic phlogopite, titanium oxide coated mica, titanium oxide coated bismuth oxychloride, iron mica titanium oxide, Examples include dark blue treated mica titanium, carmine treated mica titanium, silica treated mica titanium, bismuth oxychloride, bright powder such as fish scale foil, iron oxide coated mica, organic pigment treated mica titanium, silicic anhydride/red iron treated aluminum powder, etc. be able to. The component (A) may contain one or more kinds.
本発明で用いられる前記（Ａ）成分のうち、肌のツヤ感を付与する観点から、酸化チタン被覆雲母およびシリカ処理雲母チタンが好ましい。 Among the components (A) used in the present invention, titanium oxide-coated mica and silica-treated titanium mica are preferred from the viewpoint of imparting a glossy feeling to the skin.
本発明で用いられる前記（Ａ）成分の含有量は、好ましくは０．１～４質量％、より好ましくは０．５～２質量％がよい。前記（Ａ）成分の含有量が０．１質量％未満の場合、肌のツヤ感が得られない恐れがある。前記（Ａ）成分が４質量％を超える場合、パール剤の分散性および肌上のパール剤の保持力が悪くなる恐れがある。 The content of the component (A) used in the present invention is preferably 0.1 to 4% by mass, more preferably 0.5 to 2% by mass. If the content of the component (A) is less than 0.1% by mass, there is a risk that the skin will not have a shiny feel. If the content of component (A) exceeds 4% by mass, the dispersibility of the pearl agent and the retention of the pearl agent on the skin may deteriorate.
本発明は、パール剤の分散性を良好にする観点から、（Ｂ）非イオン性界面活性剤を含有する。 The present invention contains (B) a nonionic surfactant from the viewpoint of improving the dispersibility of the pearl agent.
本発明で用いられる前記（Ｂ）成分としては、特に限定されないが、例えば、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステル、プロピレングリコール脂肪酸エステル、ソルビタン脂肪酸エステル、ポリオキシエチレンソルビタン脂肪酸エステル、ポリオキシエチレンアルキルエーテル、ポリオキシエチレンポリオキシプロピレングリコール、アルキルグリセリルエーテル、ポリエチレングリコール脂肪酸エステル、ショ糖脂肪酸エステル、ポリオキシエチレン硬化ヒマシ油、アルキルアルカノールアミド、アルキル脂肪酸アルカノールアミド、アルキルポリグルコシド等が挙げることができる。前記（Ｂ）成分は１種以上を含有してよい。 The component (B) used in the present invention is not particularly limited, but includes, for example, glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, propylene glycol fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester Ester, polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene glycol, alkyl glyceryl ether, polyethylene glycol fatty acid ester, sucrose fatty acid ester, polyoxyethylene hydrogenated castor oil, alkyl alkanolamide, alkyl fatty acid alkanolamide, alkyl polyglucoside, etc. can be mentioned. The component (B) may contain one or more kinds.
本発明で用いられる前記（Ｂ）成分のうち、パール剤の分散性の良さの観点から、ポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンソルビタン脂肪酸エステルが好ましい。 Among the components (B) used in the present invention, polyoxyethylene hydrogenated castor oil and polyoxyethylene sorbitan fatty acid ester are preferred from the viewpoint of good dispersibility of the pearl agent.
本発明で用いられる前記（Ｂ）成分のうち、さらに好ましくは、ポリオキシエチレンの平均付加モル数が４０または６０であるポリオキシエチレン硬化ヒマシ油、ポリオキシエチレンの平均付加モル数が２０であるモノステアリン酸ポリオキシエチレンソルビタンが好ましい。 Among the components (B) used in the present invention, more preferably polyoxyethylene hydrogenated castor oil has an average number of added moles of polyoxyethylene of 40 or 60, and polyoxyethylene hydrogenated castor oil has an average number of added moles of polyoxyethylene of 20. Polyoxyethylene sorbitan monostearate is preferred.
本発明で用いられる前記（Ｂ）成分の含有量は、０．１～２質量％、より好ましくは０．５～１．５質量％がよい。前記（Ｂ）成分の含有量が０．１質量％未満の場合、パール剤の分散性が悪くなる恐れがある。前記（Ｂ）成分の含有量が２質量％を超える場合、べたつきが生じる恐れがある。 The content of the component (B) used in the present invention is preferably 0.1 to 2% by mass, more preferably 0.5 to 1.5% by mass. When the content of the component (B) is less than 0.1% by mass, the dispersibility of the pearl agent may deteriorate. When the content of the component (B) exceeds 2% by mass, stickiness may occur.
本発明は、肌上のパール剤の保持力および肌のべたつきのなさの観点から、（Ｃ）水溶性被膜形成剤を含有する。 The present invention contains (C) a water-soluble film forming agent from the viewpoint of retention of the pearl agent on the skin and non-stickiness of the skin.
本発明で用いられる前記（Ｃ）成分としては、特に限定されないが、例えば、陰イオン性被膜形成剤、陽イオン性被膜形成剤、両性被膜形成剤、非イオン性被膜形成剤等が挙げられる。前記（Ｃ）成分は１種以上を含有してよい。 The component (C) used in the present invention is not particularly limited, but includes, for example, anionic film-forming agents, cationic film-forming agents, amphoteric film-forming agents, nonionic film-forming agents, and the like. The component (C) may contain one or more kinds.
本発明で用いられる前記（Ｃ）成分の陰イオン性被膜形成剤としては、例えば、アクリル酸アルキル共重合体、アクリル酸・アクリル酸アルキル共重合体、アクリル樹脂アルカノールアミン、メチルビニルエーテル／マレイン酸エステル共重合体、酢酸ビニル・クロトン酸共重合体、クロトン酸・酢酸ビニル・ネオデカン酸ビニル共重合体、酢酸ビニル／クロトン酸／プロピオン酸ビニル共重合体、酢酸ビニル／マレイン酸モノブチルエステル／イソボロリルアクリレート共重合体、アクリル酸／アクリル酸アルキルエステル／アルキルアクリルアミド共重合体、ビニルピロリドン／アクリレーツ／（メタ）アクリル酸アルキル共重合体、スチレン／（メタ）アクリル酸アルキル共重合体、スチレン／アクリル酸アミド共重合体、ウレタン－アクリル系共重合体、ポリスチレンスルホン酸ナトリウム等が挙げられる。 Examples of the anionic film forming agent of component (C) used in the present invention include alkyl acrylate copolymer, acrylic acid/alkyl acrylate copolymer, acrylic resin alkanolamine, methyl vinyl ether/maleate ester Copolymer, vinyl acetate/crotonic acid copolymer, crotonic acid/vinyl acetate/vinyl neodecanoate copolymer, vinyl acetate/crotonic acid/vinyl propionate copolymer, vinyl acetate/maleic acid monobutyl ester/isoboro Ryl acrylate copolymer, acrylic acid/alkyl acrylate ester/alkyl acrylamide copolymer, vinylpyrrolidone/acrylates/alkyl (meth)acrylate copolymer, styrene/alkyl (meth)acrylate copolymer, styrene/acrylic Examples include acid amide copolymers, urethane-acrylic copolymers, and sodium polystyrene sulfonate.
本発明で用いられる前記（Ｃ）成分の陽イオン性被膜形成剤としては、例えば、ビニルピロリドン・Ｎ，Ｎ－ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩、塩化О－［２－ヒドロキシ－３－（トリメチルアンモニオ）プロピル］ヒドロキシエチルセルロース、ビニルイミダゾリウムトリクロライド／ビニルピロリドン共重合体、ヒドロキシエチルセルロース／ジメチルジアリルアンモニウムクロリド、ポリビニルピロリドン／アルキルアミノアクリレート／ビニルカプロラクタム共重合体、塩化メチルビニルイミダゾリウム・ビニルピロリドン共重合体、ビニルピロリドン／ジメチルアミノプロピルメタクリルアミド／ラウリルジメチルアミノプロピルメタクリルアミド共重合体等が挙げられる。 Examples of the cationic film forming agent of component (C) used in the present invention include vinylpyrrolidone/N,N-dimethylaminoethyl methacrylic acid copolymer diethyl sulfate, O-[2-hydroxy-3 chloride - (trimethylammonio)propyl] hydroxyethylcellulose, vinylimidazolium trichloride/vinylpyrrolidone copolymer, hydroxyethylcellulose/dimethyldiallylammonium chloride, polyvinylpyrrolidone/alkylaminoacrylate/vinylcaprolactam copolymer, methylvinylimidazolium chloride. Examples include vinylpyrrolidone copolymer, vinylpyrrolidone/dimethylaminopropylmethacrylamide/lauryldimethylaminopropylmethacrylamide copolymer, and the like.
本発明で用いられる前記（Ｃ）成分の両性被膜形成剤としては、例えば、Ｎ－メタクリロイルオキシエチルＮ，Ｎ－ジメチルアンモニウム－α－Ｎ－メチルカルボキシベタイン・メタクリル酸アルキルエステル共重合体、Ｎ，Ｎジメチル－Ｎ－（２－メタクリロイルオキシエチル）アミン－Ｎ－オキシド・メタクリル酸アルキルエステル共重合体、アクリル酸ヒドロキシプロピル／メタクリル酸ブチルアミノエチル／アクリル酸オクチルアミド共重合体、ジアルキルアミノエチルメタクリレート／メタクリル酸アルキルエステル共重合体のモノクロル酢酸両性化物、イソブチレン／ジエチルアミノプロピルマレイミド／マレイン酸共重合体等が挙げられる。 Examples of the amphoteric film forming agent of component (C) used in the present invention include N-methacryloyloxyethyl N,N-dimethylammonium-α-N-methylcarboxybetaine/methacrylic acid alkyl ester copolymer, N, N-dimethyl-N-(2-methacryloyloxyethyl)amine-N-oxide/methacrylic acid alkyl ester copolymer, hydroxypropyl acrylate/butylaminoethyl methacrylate/acrylic acid octylamide copolymer, dialkylaminoethyl methacrylate/ Examples include monochloroacetic acid amphoteric products of methacrylic acid alkyl ester copolymers, isobutylene/diethylaminopropylmaleimide/maleic acid copolymers, and the like.
本発明で用いられる前記（Ｃ）成分の非イオン性被膜形成剤としては、例えば、ポリビニルピロリドン、酢酸ビニル・ビニルピロリドン共重合体、ビニルピロリドン／メタクリルアミド／ビニルイミダゾール共重合体、ポリビニルアルコール、ポリビニルカプロラクタム等が挙げられる。 Examples of the nonionic film forming agent of component (C) used in the present invention include polyvinylpyrrolidone, vinyl acetate/vinylpyrrolidone copolymer, vinylpyrrolidone/methacrylamide/vinylimidazole copolymer, polyvinyl alcohol, polyvinyl Examples include caprolactam.
本発明の前記（Ｃ）成分としては、肌上のパール剤の保持力および肌のべたつきのなさの観点から、非イオン性被膜形成剤および陰イオン性被膜形成剤から選ばれる１種以上を用いることが好ましく、これら良好な被膜形成剤の中でも、ポリビニルピロリドン、酢酸ビニル・ビニルピロリドン共重合体およびアクリル酸アルキル共重合体が好ましい。 As the component (C) of the present invention, one or more types selected from nonionic film-forming agents and anionic film-forming agents are used from the viewpoint of retention of the pearl agent on the skin and non-stickiness of the skin. Among these good film-forming agents, polyvinylpyrrolidone, vinyl acetate/vinylpyrrolidone copolymer and alkyl acrylate copolymer are preferred.
本発明で用いられる前記（Ｃ）成分の含有量は、０．１～１質量％、より好ましくは０．３～０．５質量％がよい。前記（Ｃ）成分の含有量が０．１質量％未満の場合、肌上のパール剤の保持力が得られない恐れがある。前記（Ｃ）成分の含有量が１質量％を超える場合、肌のべたつきが悪くなる恐れがある。 The content of the component (C) used in the present invention is preferably 0.1 to 1% by mass, more preferably 0.3 to 0.5% by mass. When the content of the component (C) is less than 0.1% by mass, there is a possibility that the retention force of the pearl agent on the skin may not be obtained. When the content of the component (C) exceeds 1% by mass, there is a risk that the skin will become less sticky.
本発明における２０℃条件下によるｐＨは、弱酸性の観点から４．５～６．５であり、より好ましくは５～６である。 In the present invention, the pH under 20°C conditions is 4.5 to 6.5, more preferably 5 to 6, from the viewpoint of weak acidity.
本発明における２０℃条件下によるｐＨは、常法にて調製して得られたミスト状化粧料をサンプル瓶（食品１４０：第一硝子株式会社製）に１２０ｇ充填し、２０℃条件下で２４時間静置した後に、ガラス電極式水素イオン濃度指示計（Ｆ－７１、堀場製作所製）にて原液のｐＨを測定し得られるものである。 The pH under 20°C conditions in the present invention is determined by filling a sample bottle (Food 140: Daiichi Glass Co., Ltd.) with 120g of a mist cosmetic prepared by a conventional method, and After allowing the solution to stand for a period of time, the pH of the stock solution is measured using a glass electrode hydrogen ion concentration indicator (F-71, manufactured by Horiba, Ltd.).
本発明のミスト状化粧料は前記必須成分の他に、通常の化粧料、医薬部外品、医薬品等に用いられる各種成分、例えば、（Ａ）成分以外の紛体、ビタミン類、キレート剤、ｐＨ調整剤、増粘剤、油性成分、保湿剤、薬効成分、蛋白誘導体、加水分解蛋白、酸化防止剤、還元剤、植物性抽出物、生薬抽出物、香料、防腐剤、色素、顔料、紫外線吸収剤、（Ｂ）成分以外の界面活性剤等から選ばれる少なくとも１種以上を含有することができる。ただし、これら例示に限定されるものではない。 In addition to the above-mentioned essential ingredients, the mist cosmetic of the present invention includes various ingredients used in ordinary cosmetics, quasi-drugs, pharmaceuticals, etc., such as powders other than component (A), vitamins, chelating agents, pH Regulators, thickeners, oily ingredients, humectants, medicinal ingredients, protein derivatives, hydrolyzed proteins, antioxidants, reducing agents, plant extracts, crude drug extracts, fragrances, preservatives, dyes, pigments, ultraviolet absorption The composition may contain at least one selected from surfactants other than component (B). However, the present invention is not limited to these examples.
本発明のミスト状化粧料は、液状、ジェル状等の形態で用いられ、ディスペンサー容器に充填され、使用時まで保存される。 The cosmetic mist of the present invention is used in a liquid, gel, or other form, filled into a dispenser container, and stored until use.
本発明のミスト状化粧水のミストディスペンサーとしては、特に限定はされないが、例えばミストディスペンサーＺ－１５５－Ｃ０９４－１－０６０（９５－０）、（吐出量０．１５ｍＬ／１プッシュ、三谷バルブ社製）を用いることができる。 The mist dispenser for the mist lotion of the present invention is not particularly limited, but for example, mist dispenser Z-155-C094-1-060 (95-0), (discharge volume 0.15 mL/1 push, manufactured by Mitani Valve Co., Ltd. (manufactured by) can be used.
以下に実施例を挙げて本発明をさらに詳細に説明するが、これらは本発明を何ら限定するものではない。 The present invention will be explained in more detail with reference to Examples below, but these are not intended to limit the present invention in any way.
本明細書に示す評価試験において、ミスト状化粧料に含まれる成分、およびその含有量を種々変更しながら実施した。各成分の含有量を示す単位はすべて質量％であり、これを常法にて調製した。 In the evaluation test shown in this specification, the components contained in the mist cosmetic and their contents were variously changed. All units indicating the content of each component are mass %, and were prepared by a conventional method.
本明細書に示す評価試験において、「肌のツヤ感」、「パール剤の分散性」、「肌上のパール剤の保持力」および「肌のべたつきのなさ」について下記の方法で評価した。 In the evaluation test shown in this specification, "skin gloss", "dispersibility of pearl agent", "holding power of pearl agent on skin", and "non-stickiness of skin" were evaluated using the following methods.
「肌のツヤ感」
各ミスト状化粧水を１００ｍＬ用ＰＥＴ容器に７０ｍＬ充填し、２５℃条件下でミストディスペンサー（Ｚ－１５５－Ｃ０９４－１－０６０（９５－０）：三谷バルブ社製）を用いて、実施例および比較例で得られた各ミスト状化粧料を塗布し、塗布後から５分間経過した後の肌のツヤ感を目視にて評価した。評価は専門のパネラー２０名が実施例および比較例のミスト状化粧料１０プッシュを顔面全体に塗布し、肌のツヤ感を評価した。
◎：２０名中１６名以上が肌のツヤ感があると評価した。
○：２０名中１１名以上１５名以下が肌のツヤ感があると評価した。
△：２０名中６名以上１０名以下が肌のツヤ感があると評価した。
×：２０名中５名以下が肌のツヤ感があると評価した。
"Skin glow"
70 mL of each mist lotion was filled into a 100 mL PET container, and the Examples and Each of the mist cosmetics obtained in the comparative examples was applied, and the glossiness of the skin 5 minutes after application was visually evaluated. For the evaluation, 20 expert panelists applied 10 pumps of the mist cosmetics of Examples and Comparative Examples to the entire face and evaluated the skin's glossiness.
◎: 16 or more out of 20 people rated the skin as having a glossy feel.
○: 11 to 15 out of 20 people rated the skin as having a shiny feel.
Δ: 6 to 10 people out of 20 people evaluated that the skin had a shiny feel.
x: 5 or less people out of 20 people evaluated that the skin had a glossy feel.
「パール剤の分散性」
各ミスト状化粧水を１００ｍＬ用ＰＥＴ容器に７０ｍＬ充填し、２５℃条件下でミストディスペンサー（Ｚ－１５５－Ｃ０９４－１－０６０（９５－０）：三谷バルブ社製）を用いて、実施例および比較例で得られた各ミスト状化粧料を、２５℃条件下で２４時間静置し、パール剤を沈降させた後に、手で振り混ぜて再分散に要する回数で評価した。
◎：１０回以内に再分散した。
○：１１回以上３０回以内で再分散した。
×：３１回以上でも再分散しなかった。
"Dispersibility of pearl agent"
70 mL of each mist lotion was filled into a 100 mL PET container, and the Examples and Each of the mist cosmetics obtained in the comparative examples was allowed to stand for 24 hours at 25°C to allow the pearl agent to settle, and then was shaken by hand and evaluated based on the number of times required for redispersion.
◎: Redispersed within 10 times.
○: Redispersed 11 times or more but less than 30 times.
x: No re-dispersion occurred even after 31 times or more.
「肌上のパール剤の保持力」
各ミスト状化粧水を１００ｍＬ用ＰＥＴ容器に７０ｍＬ充填し、２５℃条件下でミストディスペンサー（Ｚ－１５５－Ｃ０９４－１－０６０（９５－０）：三谷バルブ社製）を用いて、実施例および比較例で得られた各ミスト状化粧料を塗布し、塗布後から５分間経過した後の肌上のパール剤の保持力を目視にて評価した。評価は専門のパネラー２０名が実施例および比較例のミスト状化粧料０．５ｇを顔面全体に塗布し、肌上のパール剤の保持力を評価した。
◎：２０名中１６名以上が肌上のパール剤の保持力があると評価した。
○：２０名中１１名以上１５名以下が肌上のパール剤の保持力があると評価した。
△：２０名中６名以上１０名以下が肌上のパール剤の保持力があると評価した。
×：２０名中５名以下が肌上のパール剤の保持力があると評価した。
"Retention power of pearl agent on the skin"
70 mL of each mist lotion was filled into a 100 mL PET container, and the Examples and Each of the mist cosmetics obtained in the comparative examples was applied, and the retention power of the pearl agent on the skin was visually evaluated 5 minutes after application. For the evaluation, 20 expert panelists applied 0.5 g of the mist cosmetics of Examples and Comparative Examples to the entire face and evaluated the retention power of the pearl agent on the skin.
◎: 16 or more out of 20 people evaluated that the pearl agent had a good retention ability on the skin.
○: 11 to 15 out of 20 people evaluated that the pearl agent had a good retention ability on the skin.
Δ: 6 to 10 people out of 20 people evaluated that the pearl agent had a good retention ability on the skin.
×: 5 or less people out of 20 people evaluated that the pearl agent had a good retention ability on the skin.
「べたつきのなさ」
各ミスト状化粧水を１００ｍＬ用ＰＥＴ容器に７０ｍＬ充填し、２５℃条件下でミストディスペンサー（Ｚ－１５５－Ｃ０９４－１－０６０（９５－０）：三谷バルブ社製）を用いて、実施例および比較例で得られた各ミスト状化粧料を塗布し、塗布後から５分間経過した後のべたつきを官能にて評価した。評価は専門のパネラー２０名が実施例および比較例のミスト状化粧料を２０℃に温度調整し、０．５ｇを２０℃の条件下で顔面全体に塗布し、べたつきを評価した。
◎：２０名中１６名以上がべたつきを感じないと評価した。
○：２０名中１１名以上１５名以下がべたつきを感じないと評価した。
△：２０名中６名以上１０名以下がべたつきを感じないと評価した。
×：２０名中５名以下がべたつきを感じないと評価した。
"No stickiness"
70 mL of each mist lotion was filled into a 100 mL PET container, and the Examples and Each of the mist cosmetics obtained in the comparative examples was applied, and the stickiness was sensory evaluated 5 minutes after application. For the evaluation, 20 expert panelists adjusted the temperature of the mist cosmetics of Examples and Comparative Examples to 20°C, applied 0.5 g to the entire face at 20°C, and evaluated stickiness.
◎: 16 or more out of 20 people evaluated that it did not feel sticky.
○: 11 to 15 out of 20 people evaluated that the product did not feel sticky.
△: 6 or more and 10 or less out of 20 people evaluated that the product did not feel sticky.
x: 5 or less people out of 20 people evaluated that it did not feel sticky.
表１～表４に示す実施例１～２７から、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさについて良好な結果を得ることが確認された。 From Examples 1 to 27 shown in Tables 1 to 4, it was confirmed that good results were obtained in terms of skin gloss, dispersibility of the pearl agent, retention of the pearl agent on the skin, and lack of stickiness on the skin. .
実施例２８を使用して各種試験を行っても、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさのいずれの評価も良好であった。 Even when various tests were conducted using Example 28, all of the evaluations of skin gloss, dispersibility of the pearl agent, retention of the pearl agent on the skin, and lack of stickiness on the skin were good.
＜実施例２８＞
成 分 含有量（質量％）
（Ａ）酸化チタン被覆雲母（※１） ０．６００
（Ａ）シリカ処理雲母チタン（※２） ０．１００
（Ａ）シリカ処理雲母チタン（※３） ０．１００
（Ｂ）ポリオキシエチレン硬化ヒマシ油（６０ＥＯ） １．０００
（Ｃ）ポリビニルピロリドン ０．３００
安息香酸ナトリウム ０．３００
１， ３－ブチレングリコール ４．０００
エデト酸二ナトリウム ０．１００
クエン酸 ０．１００
クエン酸ナトリウム ０．３５０
アーチチョークエキス ０．０１０
植物性スクワラン ０．００１
ポリオキシエチレンラウリルエーテルリン酸ナトリウム（１０ＥＯ） ０．０１０
香料 ０．０２０
精製水 ９３．００９
合計 １００．０００
※１：Ｔｉｍｉｒｏｎ Ｓｕｐｅｒｓｈｅｅｎ ＭＰ－１００１（ＭＥＲＣＫ社製）
※２：Ｔｉｍｉｒｏｎ Ｓｐｌｅｎｄｉｄ Ｖｉｏｌｅｔ（ＭＥＲＣＫ社製）
※３：Ｔｉｍｉｒｏｎ Ｓｐｌｅｎｄｉｄ Ｒｅｄ（ＭＥＲＣＫ社製）
<Example 28>
Component content (mass%)
(A) Titanium oxide coated mica (*1) 0.600
(A) Silica-treated mica titanium (*2) 0.100
(A) Silica-treated mica titanium (*3) 0.100
(B) Polyoxyethylene hydrogenated castor oil (60EO) 1.000
(C) Polyvinylpyrrolidone 0.300
Sodium benzoate 0.300
1,3-butylene glycol 4.000
Edetate disodium 0.100
Citric acid 0.100
Sodium citrate 0.350
Artichoke extract 0.010
Vegetable squalane 0.001
Sodium polyoxyethylene lauryl ether phosphate (10EO) 0.010
Fragrance 0.020
Purified water 93.009
Total 100.000
*1: Timiron Superseen MP-1001 (manufactured by MERCK)
*2: Timiron Splendid Violet (manufactured by MERCK)
*3: Timiron Splendid Red (manufactured by MERCK)
本発明は、肌のツヤ感、パール剤の分散性、肌上のパール剤の保持力および肌のべたつきのなさに優れるミスト状化粧料を得ることができる。 INDUSTRIAL APPLICABILITY The present invention can provide a mist cosmetic that is excellent in skin gloss, pearl agent dispersibility, pearl agent retention on the skin, and non-sticky skin.
Claims (1)
（Ｂ）ポリオキシエチレン硬化ヒマシ油またはモノステアリン酸ポリオキシエチレンソルビタンから選ばれる１種以上
（Ｃ）ポリビニルピロリドン、酢酸ビニル・ビニルピロリドン共重合体またはアクリル酸アルキル共重合体から選ばれる１種以上
を含有し、前記（Ａ）成分の含有量が０．１～４質量％であり、前記（Ｂ）成分の含有量が０．１～２質量％であり、前記（Ｃ）成分の含有量が０．１～１質量％であることを特徴とするミスト状化粧料（ただし、エアゾール型化粧料を除く）。 (A) One or more types selected from titanium oxide coated mica or silica-treated mica titanium
(B) One or more selected from polyoxyethylene hydrogenated castor oil or polyoxyethylene sorbitan monostearate
(C) One or more types selected from polyvinylpyrrolidone, vinyl acetate/vinylpyrrolidone copolymer, or alkyl acrylate copolymer
, the content of the component (A) is 0.1 to 4% by mass, the content of the component (B) is 0.1 to 2% by mass, and the content of the component (C) is 0.1 to 4% by mass. A mist-like cosmetic (excluding aerosol-type cosmetics), characterized in that the content is 0.1 to 1% by mass .
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010018598A (en) | 2008-07-10 | 2010-01-28 | Taiyo Sangyo Kk | Film-forming pharmaceutically effective composition |
| JP2010090044A (en) | 2008-10-06 | 2010-04-22 | Kao Corp | Two-layer type cosmetic |
| JP2017178940A (en) | 2016-03-28 | 2017-10-05 | 株式会社コーセー | Aerosol type cosmetics |
| JP2018108966A (en) | 2017-01-04 | 2018-07-12 | 株式会社コーセー | Aerosol type cosmetic |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010018598A (en) | 2008-07-10 | 2010-01-28 | Taiyo Sangyo Kk | Film-forming pharmaceutically effective composition |
| JP2010090044A (en) | 2008-10-06 | 2010-04-22 | Kao Corp | Two-layer type cosmetic |
| JP2017178940A (en) | 2016-03-28 | 2017-10-05 | 株式会社コーセー | Aerosol type cosmetics |
| JP2018108966A (en) | 2017-01-04 | 2018-07-12 | 株式会社コーセー | Aerosol type cosmetic |
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