JP2022030727A - Aerosol-type foam temporary colorant composition - Google Patents

Abstract

To provide aerosol-type foam temporary colorant compositions, particularly aerosol-type foam temporary colorant compositions with good colorability, water resistance, abrasion resistance, and foam retention, without flaking and stickiness.SOLUTION: Provided is an aerosol-type foam temporary colorant composition that is discharged in a foam state from an aerosol container and used, the aerosol-type foam temporary colorant composition containing: (A) a polyoxyethylene alkyl ether type nonionic surfactant; (B) an acrylic resin alkanolamine; (C) a nonionic film-forming resin; (D) an alkyl acrylate copolymer emulsion; (E) an aerosol stock solution containing a colorant; and (F) a propellant.SELECTED DRAWING: None

Description

The present invention relates to an aerosol-type foam temporary colorant composition, and more particularly to an aerosol-type foam temporary colorant composition having good coloring property, water resistance, abrasion resistance and foam retention without flaking and stickiness.

In recent years, there has been an increasing need for products that can easily and easily change hair color without performing complicated operations. Among them, a hair temporary colorant composition, which is characterized by being able to easily change the color tone of hair, is attracting attention.

The hair temporary colorant composition generally colors the hair by adhering a colorant such as a pigment or an organic dye to the hair. Compared to so-called oxidative hair dyes, which use a chemical reaction (oxidative polymerization) using oxidative dyes and oxidants, there is almost no damage to the hair, and it is easy to wash off with a single hair wash, so it is common. Among them, aerosol-type temporary colorants using propellants are easy to apply over a wide range and are easy to use, so there is an increasing need in the market.

Conventionally, some aerosol-type temporary colorants use an anionic film-forming agent or a polymer thickener to fix the colorant on the hair in order to improve the friction resistance and water resistance after drying (. Patent Document 1).

Further, as a cosmetic having high coloring property to hair and having less secondary adhesion, a colored hair cosmetic containing an amphoteric polymer resin, an acid dye and a pigment is disclosed (Patent Document 2).

Further, as a kind of aerosol-type temporary colorant, an aerosol cosmetic containing a coloring material, which is used by ejecting it in a mist form using a spray nozzle, is disclosed (Patent Document 3).

Japanese Patent Application Laid-Open No. 2003-26553 Japanese Unexamined Patent Publication No. 11-12439 Japanese Patent Application Laid-Open No. 2003-81762

However, in Patent Document 1, when an aerosol-type temporary hair colorant composition is applied onto hair, an anionic film-forming agent or a polymer thickener is added for the purpose of improving friction resistance and water resistance after drying. As a result, not only the coloring agent is fixed to the hair, but also the hair sticks to each other, which makes the hair stiff, and the thick bundle is formed to give an unnatural finish without movement, and stickiness is likely to occur. As a result, it sometimes became difficult to pass fingers and feel.

Further, in Patent Document 2, although high coloring property to hair and suppression of secondary adhesion are achieved, attention is not paid to the degree of stickiness and flaking of hair at the time of finishing, and stickiness and flare are not paid attention to. There was still room for improvement in the natural finish without the king.

Further, as in Patent Document 3, as a spray type, a method of ejecting an aerosol cosmetic containing a coloring material, which is a kind of an aerosol-type temporary colorant composition, into a mist is known, but it is ejected in a mist over a wide range. Therefore, it is difficult to apply the mixture evenly on the hair, and the undiluted solution may adhere to unintended parts, which may contaminate the surrounding area.

As a result of diligent studies to solve the above problems, the present inventor is an aerosol-type foam temporary colorant composition used by being discharged into a foam-like (foam-like) form from an aerosol container, wherein (A) polyoxyethylene. An aerosol stock solution containing an alkyl ether type nonionic surfactant, (B) acrylic resin alkanolamine, (C) nonionic film-forming resin, (D) alkyl acrylate copolymer emulsion, and (E) colorant. And (F), they have found that an aerosol-type foam temporary colorant composition containing a propellant can be obtained, and have completed the present invention.

INDUSTRIAL APPLICABILITY According to the present invention, an aerosol-type foam temporary colorant composition having good coloring property, water resistance, abrasion resistance and foam retention without flaking and stickiness can be obtained.

Hereinafter, the present invention will be described in detail. Unless otherwise specified, the units indicating the content are all mass%.

In addition, flaking in the present invention means that the film-forming resin adhering to the hair is peeled off and the colorant fixed to the hair by the formed film is removed together with the film-forming resin. It means that the hair whose color tone has been changed by the colorant composition is exposed.

The aerosol-type foam temporary colorant composition of the present invention contains an aerosol stock solution and a propellant.

The aerosol stock solution of the present invention contains (A) a polyoxyethylene alkyl ether type nonionic surfactant from the viewpoint of foam retention.

The component (A) used in the present invention is not particularly limited, but for example, polyoxyethylene (hereinafter referred to as POE) (2) lauryl ether (HLB: 9.5), POE (4) lauryl ether (HLB). 11.5), POE (9) lauryl ether (HLB: 14.5), POE (21) lauryl ether (HLB: 19.0), POE (25) lauryl ether (HLB: 19.5), POE ( 2) Cetyl ether (HLB: 8.0), POE (6) Cetyl ether (HLB: 10.5), POE (7) Cetyl ether (HLB: 11.5), POE (10) Cetyl ether (HLB: 13) .5), POE (15) cetyl ether (HLB: 15.5), POE (20) cetyl ether (HLB: 17.0), POE (23) cetyl ether (HLB: 18.0), POE (25) Cetyl ether (HLB: 18.5), POE (30) cetyl ether (HLB: 19.5), POE (40) cetyl ether (HLB: 20.0), POE (2) stearyl ether (HLB: 8.0) ), POE (4) Stearyl Ether (HLB: 9.0), POE (20) Stearyl Ether (HLB: 18.0), POE (2) Oleyl Ether (HLB: 7.5), POE (7) Oleyl Ether (HLB: 10.5), POE (10) oleyl ether (HLB: 14.5), POE (15) oleyl ether (HLB: 16.0), POE (20) oleyl ether (HLB: 17.0), POE (50) oleyl ether (HLB: 18.0), POE (5) behenyl ether (HLB: 7.0), POE (10) behenyl ether (HLB: 10.0), POE (20) behenyl ether (HLB) : 16.5), POE (30) behenyl ether (HLB: 18.0), POE (3) alkyl (12-14) ether (HLB: 8.0), POE (5) alkyl (12-14) ether (HLB: 10.5), POE (7) Alkyl (12-14) Ether (HLB: 12.0), POE (9) Alkyl (12-14) Ether (HLB: 13.5), POE (12) Alkyl (12-14) ether (HLB: 14.5) and the like can be mentioned. Among them, POE (2) lauryl ether (HLB: 9.5), POE (4) lauryl ether (HLB: 11.5), POE (9) lauryl ether from the viewpoint of forming a foam when discharged from the aerosol container. (HLB: 14.5), POE (21) lauryl ether (HLB: 19.0), POE (25) lauryl ether (HLB: 19.5), POE (2) cetyl ether (HLB: 8.0), POE (6) cetyl ether (HLB: 10.5), POE (7) cetyl ether (HLB: 11.5), POE (10) cetyl ether (HLB: 13.5), POE (15) cetyl ether (HLB) : 15.5), POE (20) cetyl ether (HLB: 17.0), POE (23) cetyl ether (HLB: 18.0), POE (25) cetyl ether (HLB: 18.5), POE ( 30) Cetyl ether (HLB: 19.5), POE (40) cetyl ether (HLB: 20.0), POE (3) alkyl (12-14) ether (HLB: 8.0), POE (5) alkyl (12-14) Ether (HLB: 10.5), POE (7) Alkyl (12-14) Ether (HLB: 12.0), POE (9) Alkyl (12-14) Ether (HLB: 13.5) ), POE (12) alkyl (12-14) ether (HLB: 14.5), POE (3) alkyl (12-14) ether (HLB: 8.0), POE (12) alkyl (12-). 14) Ether (HLB: 14.5), POE (2) cetyl ether (HLB: 8.0), POE (40) cetyl ether (HLB: 20.0), POE (4) lauryl ether (HLB: 11. 5), POE (9) lauryl ether (HLB: 14.5), POE (25) lauryl ether (HLB: 19.5) are more preferable. The component (A) may contain one or more.

In addition, "HLB" is an abbreviation for hydrophilic lipophilic balance: Hydrophilic-Lipophile Balance, and is generally a parameter indicating the relative strength of hydrophilicity and lipophilicity of a surfactant molecule. The larger the HLB value, the stronger the hydrophilicity, and the smaller the HLB value, the stronger the lipophilicity. The HLB described in the present invention is based on an actually measured value. As the measurement method, the method described in "Handbook-Cosmetics / Pharmaceutical Materials-Revised Edition Nikko Chemicals Co., Ltd., 1977, pp. 854-855" was applied mutatis mutandis.

The content of the component (A) used in the present invention is preferably 0.5 to 3%, more preferably 0.6 to 2%, still more preferably 0.8 to 1.5%. If the component (A) is less than 0.5%, the foam retention of the foam may be reduced. If the component (A) exceeds 3%, it may be sticky.

The average HLB of the component (A) used in the present invention is preferably 8.5 or more, more preferably 10 or more. If the average HLB of the component (A) is less than 8.5, the foam retention of the foam may decrease.

The aerosol stock solution of the present invention contains (B) acrylic resin alkanolamine from the viewpoint of water resistance and abrasion resistance.

The component (B) used in the present invention is an acrylic resin neutralized with aminomethylpropanol (hereinafter referred to as AMP), aminomethylpropanediol (AMPD), triethanolamine (TEA), or the like. The component (B) is not particularly limited, and is, for example, (Acrylate / diacetoneacrylamide) copolymer AMP, Acrylate copolymer AMP, (Acrylate / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer. AMP and the like can be mentioned. Among them, (Acrylate / Diacetone Acrylamide) copolymer AMP and (Acrylate / Alkyl acrylate (C1-18) / Alkyl (C1-8) acrylamide) copolymer AMP are preferable from the viewpoint of water resistance and abrasion resistance, and further, flare. From the viewpoint of king suppression, the (acrylics / diacetoneacrylamide) copolymer AMP is more preferable. The component (B) may contain one or more.

The content of the component (B) used in the present invention is preferably 0.1 to 5%, more preferably 0.5 to 2.5%, still more preferably 0.7 to 2%. If the component (B) is less than 0.1%, water resistance and abrasion resistance may decrease. If the component (B) exceeds 5%, flaking and stickiness may be given.

The aerosol stock solution of the present invention contains (C) a nonionic film-forming resin from the viewpoint of suppressing flaking.

The component (C) used in the present invention is not particularly limited, and for example, a (dimethylacrylamide / hydroxyethyl acrylate / methoxyethyl acrylate) copolymer, a (hydroxyethyl acrylate / methoxyethyl acrylate) copolymer, ( Hydroxyethyl acrylate / butyl acrylate / methoxyethyl acrylate) copolymer, vinyl acetate / vinylpyrrolidone copolymer ((vinylpyrrolidone / VA) copolymer), polyvinylpyrrolidone, vinylmethyl ether / ethyl maleate copolymer, (vinyl) Pyrrolidone / methacrylicamide / vinyl imidazole) copolymer, polyvinyl alcohol and the like can be mentioned. Among them, from the viewpoint of suppressing flaking, (dimethylacrylamide / hydroxyethyl acrylate / methoxyethyl acrylate) copolymer, (hydroxyethyl acrylate / methoxyethyl acrylate) copolymer, (hydroxyethyl acrylate / butyl acrylate / acrylic) A methoxyethyl acrylate) copolymer is preferred, and a (hydroxyethyl acrylate / methoxyethyl acrylate) copolymer is more preferred from the standpoint of a natural finish after use. The component (C) may contain one or more.

The content of the component (C) used in the present invention is preferably 0.05 to 5%, more preferably 0.1 to 2%, still more preferably 0.2 to 1%. If the component (C) is less than 0.05%, flaking may occur. If the component (C) exceeds 5%, it may be sticky.

The aerosol stock solution of the present invention contains (D) an alkyl acrylate copolymer emulsion from the viewpoint of water resistance and abrasion resistance.

The component (D) used in the present invention is not particularly limited, and examples thereof include Acrylate Copolymer, Acrylate Copolymer Ammonium, Acrylate Copolymer Na, (Styrene / Alkyl Acrylate) Copolymer Ammonium, and the like, and flaking. Acrylate copolymer ammonium is preferred from the viewpoint of inhibition. The component (D) may contain one or more of them.

The content of the component (D) used in the present invention is preferably 0.1 to 5%, more preferably 0.5 to 4%, still more preferably 1 to 3%. If the component (D) is less than 0.1%, water resistance and abrasion resistance may decrease. If the component (D) exceeds 5%, flaking and stickiness may occur.

The aerosol stock solution of the present invention contains (E) a colorant from the viewpoint of colorability.

The component (E) used in the present invention is not particularly limited, and examples thereof include inorganic pigments, pearl pigments, organic pigments, dye resin solid solutions, daylight fluorescent pigments, and natural pigments. The component (E) may contain one or more. When two or more kinds of the component (E) are contained, various color tones can be produced.

Specific examples of the inorganic pigment include ultramarine, chromium oxide, red iron oxide, yellow iron oxide, titanium oxide, aluminum hydroxide, zinc oxide, cobalt oxide, black iron oxide, chromium hydroxide, aluminum hydroxide, dark blue, and barium sulfate. Examples thereof include hydrous silicate, aluminum hydroxide, aluminum silicate, mica, magnesium carbonate, manganese violet, carbon black, aluminum, copper and gold. These inorganic pigments may contain one or more kinds.

Specific examples of the pearl pigment include titanium oxide / iron oxide / mica, titanium oxide / conjo / mica, red iron oxide / mica, synthetic gold mica / iron oxide, alumina / silica / iron oxide and synthetic gold mica / titanium oxide / oxidation. Examples thereof include a combination of a composite powder of tin / iron oxide and the like. Examples of these composite powders include mica titanium, red iron oxide-coated mica, red iron oxide-coated mica titanium, black iron oxide-coated mica titanium, and chromium oxide-coated mica. These pearl pigments may contain one or more kinds.

Specific examples of the organic pigment include red 202, red 203, red 204, red 205, red 206, red 207, red 208, red 219, red 220, red 221 and red. 228, Red 404, Red 405, Daidai 203, Daidai 204, Daidai 401, Yellow 205, Yellow 401, Blue 404, Red 104 Aluminum Lake, Yellow 4 Aluminum Lake, Examples include yellow No. 203 aluminum lake and blue No. 1 aluminum lake. These organic pigments may contain one or more kinds.

Specific examples of the natural pigments include mineral pigments such as clay, natural dye lakes such as madder lake and cochineal lake, azo pigments, and phthalocyanine pigments. These natural pigments may contain one or more kinds.

Among the colorants, inorganic pigments, organic pigments and pearl pigments are preferable from the viewpoint of good color development on hair.

When the component (E) used in the present invention is an organic pigment or an inorganic pigment, the content is preferably 0.1 to 1%, more preferably 0.2 to 0.8%. If the amount of the pigment (E) is less than 0.1%, the coloring property may be deteriorated. If the component (E) exceeds 1%, flaking may occur and the friction resistance may decrease.

When the component (E) used in the present invention is a pearl pigment, the content is preferably 1 to 10%, more preferably 3 to 8%. If the pearl pigment (E) is less than 1%, the coloring property may be deteriorated. If the pearl pigment (E) exceeds 10%, flaking may occur and the abrasion resistance may decrease.

The present invention contains (F) a propellant from the viewpoint of discharging bubbles from the aerosol container.

The component (F) used in the present invention is not particularly limited, and examples thereof include dimethyl ether (DME), isobutane, liquefied petroleum gas (LPG), and nitrogen gas. Among them, liquefied petroleum gas or dimethyl ether is preferable from the viewpoint of preventing clogging, and liquefied petroleum gas is more preferable from the viewpoint of good dischargeability. The component (E) may contain one or more.

The component (F) used in the present invention has an initial internal pressure of 20 ° C., preferably in the range of 0.2 to 0.5 MPa. The liquefied petroleum gas can be adjusted to an arbitrary initial internal pressure by changing the composition, and can also be adjusted by combining types such as liquefied petroleum gas and dimethyl ether.

The mass ratio of the aerosol stock solution used in the present invention to the component (F) (aerosol stock solution: propellant) is preferably 97: 3 to 80:20, more preferably 96: 4 to 90, from the viewpoint of good ejection properties. : 10 is good. If the mass ratio of the component (F) is less than 3, there is a possibility that the aerosol container cannot be discharged in the form of bubbles. If the mass ratio of the component (F) exceeds 20, the undiluted solution may scatter and contaminate the surroundings.

In addition to the above-mentioned components (A) to (F), the aerosol-type foam temporary colorant composition of the present invention has various components used in ordinary cosmetics, non-pharmaceutical products, pharmaceuticals, etc., for example, the above-mentioned component (A). Other than surfactants, oily ingredients, moisturizers, thickeners, medicinal ingredients, protein derivatives, hydrolyzed proteins, stabilizers, antioxidants, vegetable extracts, crude drug extracts, vitamins, preservatives, pigments , Pigments, powders, pH adjusters, UV absorbers, fragrances and the like, and at least one of them can be contained within a range that does not impair the effects of the present invention. However, the present invention is not limited to these examples.

As the aerosol type foam temporary colorant composition of the present invention, an aerosol container made of metal, PET or the like can be used depending on the use, purpose, method, environment of use and the like. The specifications of the aerosol container are not particularly limited, and examples of the container include a pressure-resistant container made of aluminum, tin, or plastic, which is internally coated with epoxyphenol or the like. Among them, aluminum is more preferable in terms of moldability and lightness. As the valve, a valve usually used for foam is used, and a spout for foam (for example, "FD147W" 3 ": manufactured by Mitani Valve Co., Ltd.) is attached after the valve is attached and filled with an injection agent. Is preferable.

The aerosol-type foam temporary colorant composition of the present invention can be applied to hair by brush or by hand, and it is more preferable to apply by brush.

In the aerosol type foam temporary colorant composition of the present invention, a glass ball (12φ) may be added for the purpose of dispersing the colorant and the like.

Hereinafter, the present invention will be described in more detail with reference to examples, but these are not intended to limit the present invention in any way.

In the evaluation test shown in the present specification, the components contained in the aerosol-type foam temporary colorant composition and their contents were variously changed. The unit indicating the content of each component is all mass%, which was prepared by a conventional method.

<Evaluation>
In the evaluation test method shown in the present specification, evaluation by 10 panelists was performed with "no flaking", "no stickiness", "colorability", "water resistance" and "friction resistance" as evaluation items. In addition, one panelist evaluated the product with "foam mochi" as an evaluation item.

In the inventions shown herein, it was obtained in the evaluation tests of "no flaking", "no stickiness", "colorability", "water resistance", "rubbing resistance" and "foam stickiness". Fill an aluminum can (manufactured by Takeuchi Press Industry Co., Ltd., outer diameter: 35 mm, total length: 100 mm, inner surface coat: TPL-419) with the undiluted aerosol solution, insert two glass balls (12φ), and load the aerosol valve and spout. After that, a propellant was filled and the aerosol-type foam temporary colorant composition prepared to be 40 g was evaluated.

<No flaking>
Take 2 g of the obtained aerosol-type foam temporary colorant composition with the V-type straight brush attached to "Venezel Straight Perma EX (manufactured by Dariya Co., Ltd.)" under the condition of 25 ° C, and take a hair test doll (human hair black hair 100). %, Made by Bulux, Model: Queen Cut No. 775N) Directly and evenly applied to a part of the hair, combed for 5 minutes and dried with a dryer, "Venezel Straight Perma EX (made by Dariya Co., Ltd.)" The degree of dropping of the coated material when combed 50 times using the V-type straight brush attached to the above was visually evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Score]
Almost no peeling of the coated part: 5 points Some peeling of the coated part is seen: 4 points Peeling of the coated part is seen: 3 points The coated part is considerably peeled off: 2 points The coated part is almost peeled off: 1 point (Criteria for judging the average score)
[Average score]: [Judgment]
4.5 or above: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Non-sticky>
Take 2 g of the obtained aerosol-type foam temporary colorant composition with the V-type straight brush attached to "Venezel Straight Perma EX (manufactured by Dariya Co., Ltd.)" under 25 ° C conditions, and take a hair test doll (human hair black hair 100). %, Made by Bulux, Model: Queen Cut No. 775N) Directly and evenly applied to a part of the hair, dried with a dryer while combing for 5 minutes, and the feel of the hair without heat is judged as the following criteria. Evaluated in.

(Criteria for evaluation results)
[Evaluation result]: [Score]
No stickiness: 5 points No stickiness: 4 points Almost no stickiness: 3 points Sticky: 2 points Very sticky: 1 point (criteria for averaging points)
[Average score]: [Judgment]
4.5 or above: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Coloring>
Take 2 g of the obtained aerosol-type foam temporary colorant composition with the V-type straight brush attached to "Venezel Straight Perma EX (manufactured by Dariya Co., Ltd.)" under 25 ° C conditions, and take a hair test doll (human hair black hair 100). %, Made by Bulux, Model: Queen Cut No. 775N) Directly and evenly applied to a part of the hair and dried with a dryer while combing for 5 minutes. evaluated.

(Criteria for evaluation results)
[Evaluation result]: [Score]
Very good coloring: 5 points Good coloring: 4 points Somewhat good coloring: 3 points Somewhat bad coloring: 2 points Poor coloring: 1 point (criteria for averaging points)
[Average score]: [Judgment]
4.5 or above: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Water resistance>
The obtained aerosol-type foam temporary colorant composition was applied to 1 g of 100% black hair bundle (product number: BS-BA, manufactured by Burax Co., Ltd.) under the condition of 25 ° C. "Venezel Straight Perma EX (manufactured by Dariya Co., Ltd.)". ) ”, Then apply 0.25 g using the V-shaped straight brush attached to the hair, dry it with a dryer while combing for 5 minutes, and spray warm water adjusted to 40 ° C by mist from a distance of 20 cm to this hair bundle. Then, the drops dripping from the hair bundle are removed from the glass lightweight standard bottle No. It was collected at 5K, and the coloring in warm water was visually evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Score]
No coloring to water: 5 points Some coloring to water: 4 points Coloring to water is seen: 3 points There is considerable coloring to water: 2 points Very coloring to water: 1 point (Criteria for judging average score)
[Average score]: [Judgment]
4.5 or above: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Abrasion resistance>
The obtained aerosol-type foam temporary colorant composition was applied to 1 g of 100% black hair bundle (product number: BS-BA, manufactured by Burax Co., Ltd.) under the condition of 25 ° C. "Venezel Straight Perma EX (manufactured by Dariya Co., Ltd.)". ) ”, Apply 0.25 g using the V-type straight brush attached to the above, and let it air dry for 24 hours. Next, the hair bundle was fixed on a horizontal table, and a test white cloth (JIS L 0803 dyed fastness test attached white cloth) wrapped with a weight of 850 g was placed on the test hair bundle and rubbed three times to transfer color. Was visually evaluated according to the following criteria.

(Criteria for evaluation results)
[Evaluation result]: [Score]
No transfer at all: 5 points Almost no transfer: 4 points Transfer is seen: 3 points There is considerable transfer: 2 points Very transfer: 1 point (criteria for averaging points)
[Average score]: [Judgment]
4.5 or above: ◎
3.0 or more and less than 4.5: ○
1.5 or more and less than 3.0: △
Less than 1.5: ×

<Foam mochi of foam>
2 g of the obtained aerosol-type foam temporary colorant composition was discharged into a 300 mL tall beaker under 25 ° C. conditions, allowed to stand for 10 minutes, and then the appearance of bubbles remaining in the 300 mL tall beaker was visually determined as follows. Evaluated by criteria.

(Criteria for evaluation results)
[Evaluation result]: [Judgment]
More than 80% of bubbles remain compared to the initial stage: ◎
Compared to the initial stage, 50% or more and less than 80%, bubbles remain: ○
20% or more and less than 50% of bubbles remain compared to the initial stage: △
The rest of the bubbles is less than 20% compared to the initial stage: ×

From Examples 1 to 12 shown in Table 1, there was no flaking and stickiness, and good results were shown in terms of colorability, water resistance, abrasion resistance and foam retention.

From Examples 13 to 20 shown in Table 2, there was no flaking and stickiness, and good results were shown in terms of colorability, water resistance, abrasion resistance and foam retention.

From Examples 21 to 30 shown in Table 3, there was no flaking and stickiness, and good results were shown in terms of colorability, water resistance, abrasion resistance and foam retention of foam.

From Examples 31 to 40 shown in Table 4, there was no flaking and stickiness, and good results were shown in terms of colorability, water resistance, abrasion resistance and foam retention.

From Examples 41 to 50 shown in Table 5, there was no flaking and stickiness, and good results were shown in terms of colorability, water resistance, abrasion resistance and foam retention of foam.

From Examples 51 to 57 shown in Table 6, there was no flaking and stickiness, and good results were shown in terms of colorability, water resistance, abrasion resistance and foam retention of foam.

From Examples 58 to 66 shown in Table 7, there was no flaking and stickiness, and good results were shown in terms of colorability, water resistance, abrasion resistance and foam retention of foam.

The aerosol-type foam temporary colorant compositions obtained in Examples 67-70 below are non-flaking and non-sticky and give good results in terms of colorability, water resistance, abrasion resistance and foam retention. rice field.

Example 67
Component content (% by mass)
(A) POE (2) Cetyl ether (HLB: 8.0) 0.20%
(A) POE (40) cetyl ether (HLB: 20.0) 1.00%
(B) (Acrylate / Diacetone Acrylamide) Copolymer AMP 2.00%
(C) (Hydroxyethyl acrylate / methoxyethyl acrylate)
Copolymer 0.40%
(D) Acrylate Copolymer Ammonium 1.44%
(E) Bengala 0.20%
(E) Bengala / Mica * 3 4.80%
(E) Synthetic phlogopite / iron oxide * 4 1.60%
Concentrated glycerin 0.20%
Bentonite 1.50%
Ethanol 10.00%
Methyl paraoxybenzoate 0.10%
D-Pantothenyl alcohol 0.20%
Polyoxyethylene palm oil fatty acid glyceryl 0.60%
Camellia oil 0.01%
Fragrance 0.01%
Highly Polymerized Methyl Polysiloxane (1) 1.25%
Purified water 74.49%
Total 100.00%
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
The above aerosol stock solution (average HLB: 18.0) 95.00%
Liquefied petroleum gas (20 ° C, 0.39 MPa) 5.00%
Total 100.00%

Example 68
Component content (% by mass)
(A) POE (7) Alkyl (12-14) Ether (HLB: 12.0) 1.00%
(B) (Acrylate / Diacetone Acrylamide) Copolymer AMP 2.00%
(C) (Hydroxyethyl acrylate / methoxyethyl acrylate)
Copolymer 0.40%
(D) Acrylate Copolymer Ammonium 1.44%
(E) Bengala 0.20%
(E) Bengala / Mica * 3 3.20%
(E) Synthetic phlogopite / iron oxide * 4 3.20%
Concentrated glycerin 0.20%
Bent Night 1.50%
Ethanol 10.00%
Methyl paraoxybenzoate 0.10%
D-Pantothenyl alcohol 0.20%
Polyoxyethylene palm oil fatty acid glyceryl 0.60%
Camellia oil 0.01%
Fragrance 0.01%
Highly Polymerized Methyl Polysiloxane (1) 1.25%
Purified water 74.69%
Total 100.00%
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
The above aerosol stock solution 95.00%
Liquefied petroleum gas (20 ° C, 0.39 MPa) 5.00%
Total 100.00%

Example 69
Component content (% by mass)
(A) POE (4) Lauryl ether (HLB: 11.5) 0.83%
(A) POE (9) Lauryl ether (HLB: 14.5) 0.17%
(B) (Acrylate / Diacetone Acrylamide) Copolymer AMP 2.00%
(C) (Hydroxyethyl acrylate / methoxyethyl acrylate)
Copolymer 0.40%
(D) Acrylate Copolymer Ammonium 1.44%
(E) Bengala 0.20%
(E) Bengala / Mica * 3 3.20%
(E) Synthetic phlogopite / iron oxide * 4 3.20%
Concentrated glycerin 0.20%
Bentonite 1.50%
Ethanol 10.00%
Methyl paraoxybenzoate 0.10%
D-Pantothenyl alcohol 0.20%
Polyoxyethylene palm oil fatty acid glyceryl 0.60%
Camellia oil 0.01%
Fragrance 0.01%
Highly Polymerized Methyl Polysiloxane (1) 1.25%
Purified water 74.69%
Total 100.00%
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
The above aerosol stock solution (average HLB: 12.0) 95.00%
Liquefied petroleum gas (20 ° C, 0.39 MPa) 5.00%
Total 100.00%

Example 70
Component content (% by mass)
(A) POE (4) Lauryl ether (HLB: 11.5) 0.83%
(A) POE (9) Lauryl ether (HLB: 14.5) 0.17%
(B) (Acrylate / Diacetone Acrylamide) Copolymer AMP 2.00%
(C) (Hydroxyethyl acrylate / methoxyethyl acrylate)
Copolymer 0.40%
(D) Acrylate Copolymer Ammonium 1.44%
(E) Bengala 0.20%
(E) Bengala / Mica * 3 3.20%
(E) Synthetic phlogopite / iron oxide * 4 3.20%
POE (10) Sodium Lauryl Ether Phosphate 0.50%
Concentrated glycerin 0.20%
Bentonite 1.50%
Ethanol 10.00%
Methyl paraoxybenzoate 0.10%
D-Pantothenyl alcohol 0.20%
Polyoxyethylene palm oil fatty acid glyceryl 0.60%
Camellia oil 0.01%
Fragrance 0.01%
Highly Polymerized Methyl Polysiloxane (1) 1.25%
Purified water 74.19%
Total 100.00%
－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－－
The above aerosol stock solution (average HLB: 12.0) 95.00%
Liquefied petroleum gas (20 ° C, 0.39 MPa) 5.00%
Total 100.00%

INDUSTRIAL APPLICABILITY According to the present invention, it is possible to obtain an aerosol-type foam temporary colorant composition having good coloring property, water resistance, abrasion resistance and foam retention without flaking and stickiness.

Claims (9)

An aerosol-type foam temporary colorant composition that is discharged from an aerosol container into a foam and used.
(A) Polyoxyethylene alkyl ether type nonionic surfactant (B) Acrylic resin Alkanolamine (C) Nonionic film forming resin (D) Alkyl acrylate copolymer emulsion (E) Aerosol containing a colorant An aerosol-type foam temporary colorant composition comprising a stock solution and (F) propellant. The aerosol-type foam temporary colorant composition according to claim 1, wherein the content of the component (A) is 0.5 to 3% by mass. The component (B) is characterized by being one or more selected from the (Acrylate / Diacetone Acrylamide) copolymer AMP and the (Acrylate / Alkyl acrylate (C1-18) / Alkyl (C1-8) acrylamide) copolymer AMP. The aerosol-type foam temporary colorant composition according to claim 1 or 2. The aerosol-type foam temporary colorant composition according to any one of claims 1 to 3, wherein the content of the component (B) is 0.1 to 5% by mass. The component (C) is a (hydroxyethyl acrylate / methoxyethyl acrylate) copolymer, a (dimethylacrylamide / hydroxyethyl acrylate / methoxyethyl acrylate) copolymer and (hydroxyethyl acrylate / butyl acrylate / methoxyethyl acrylate) copolymer. ) The aerosol-type foam temporary colorant composition according to any one of claims 1 to 4, wherein the composition is one or more selected from copolymers. The aerosol-type foam temporary colorant composition according to any one of claims 1 to 5, wherein the content of the component (C) is 0.05 to 5% by mass. Claims 1 to 6 are characterized in that the component (D) is at least one selected from the Acrylate Copolymer Ammonium, the (Styrene / Alkyl Acrylate) Copolymer Ammonium, the Acrylate Copolymer and the Acrylate Copolymer Na. The aerosol-type foam temporary colorant composition according to any one of the above. The aerosol-type foam temporary colorant composition according to any one of claims 1 to 7, wherein the content of the component (D) is 0.1 to 5% by mass. The aerosol-type foam temporary colorant composition according to any one of claims 1 to 8, wherein the mass ratio of the aerosol stock solution to the component (F) is 97: 3 to 80:20. thing.