JP2627706B2 - Hairdressing composition - Google Patents

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hairdressing composition, and more particularly to a foaming hairdressing composition having excellent foam properties, hair styling properties and texture.

[0002]

2. Description of the Related Art In recent years,
Foam hair styling has gained popularity due to its simplicity and light finish, and has increased its market share. As foam aerosol compositions of such products, generally, polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, vinyl acetate / crotonic acid copolymer, carboxylated vinyl acetate copolymer, vinyl methyl ether / maleic acid half Ester copolymer, acrylic resin (anionic, amphoteric)
And the like, in which a film-forming polymer such as is dissolved in water, ethanol, an oil agent, a surfactant or the like, and further blended with a propellant such as liquefied petroleum gas. The foamy hair styling agent is a hair styling agent that applies the above-mentioned composition to the hair using a hand, a comb or the like to shape the hair and maintain the hair style.

[0003] In addition to sufficient hair styling properties, such foam hair styling materials are required to have excellent foam properties such as foam texture, stickiness and spreadability, and a texture such as gloss, softness and moist feeling of the hair. You.

[0004] However, a foam hairdressing composition that satisfies all of these has not yet been obtained. For example, when a polymer capable of forming a hard film is selected as a set base, the hair styling properties are good, but the finish is rough and the texture is poor, and in addition, the foam quality is satisfactory in terms of texture, stickiness, spreading, etc. Absent. On the other hand, when various oils, surfactants, etc. are blended to make the polymer film soft, the finish is soft, but the setting power and stickiness are reduced, the hairstyle is broken, and the original purpose of the hairdressing material is achieved. Can not.

[0005] Therefore, there has been a strong demand for the development of a foaming hair styling that is sufficiently satisfactory in terms of foam properties, texture, etc. as well as hair styling properties.

[0006]

Means for Solving the Problems The present inventors have conducted intensive studies in view of the above-mentioned circumstances, and as a result, as described later, a hair styling material obtained by mixing a specific polymer type with a propellant has a good hair styling property. The present invention was found to exhibit foam characteristics and texture, and completed the present invention.

That is, the present invention provides the following (a) and (b)
And (c): (a) a film-forming polymer; (b) one or more selected from unmodified guar gum, a non-ionic derivative of guar gum and a cationic derivative of guar gum; and (c) a propellant. It is intended to provide a hairdressing composition characterized by the following.

[0008] In addition, West German Patent Application No. 363030A discloses a hairdressing composition containing an anionic or cationic polymer in a film-forming resin, but this hairdressing composition has a foaming property and texture. It was not satisfactory.

The film-forming polymer of the component (a) used in the present invention includes, for example, anionic, cationic,
Examples include nonionic and amphoteric polymers, and specific examples include the following (1) to (8).

(1) Polyvinylpyrrolidone-based polymer compound: polyvinylpyrrolidone; commercially available product, Rubiscol K
12, K30 (from BASF), PVP K15,
K30 (all manufactured by GAF) and the like. -Vinylpyrrolidone / vinyl acetate copolymer; commercially available products such as Luviscol VA28, VA73 (all manufactured by BASF), PVP / VA E-735, S-630 (all G)
AF Co., Ltd.). -Vinylpyrrolidone / vinyl acetate / vinyl propionate terpolymer; commercially available product, Rubiscol VAP343
(Manufactured by BASF).・ Vinylpyrrolidone / alkylaminoacrylate (quaternary chloride) copolymer; Rubiflex (BA
SF), copolymers 845, 937, 958, and Guffcut 755N (all manufactured by GAF). -Vinyl pyrrolidone / acrylate / (meth) acrylic acid copolymer; Rubiflex VBM35 as a commercial product
(Manufactured by BASF). -Vinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer; Copolymer VC-713 (manufactured by GAF) and the like as commercial products.

(2) Acidic vinyl ether polymer compound: Methyl vinyl ether / alkyl maleic anhydride half ester copolymer; Gantrez ES- as a commercial product
225, ES-425, and SP-215 (all manufactured by GAF). (3) Acidic polyvinyl acetate-based polymer compound: Vinyl acetate / crotonic acid copolymer; commercially available products include Resin 28-1310 (manufactured by National Starch), and Rubiset CA66 (manufactured by BASF). Vinyl acetate / crotonic acid / vinyl neodecanoate copolymer; Resin 28-2930 (National.
Starch). -Vinyl acetate / crotonic acid / vinyl propionate copolymer; commercially available products include Rubiset CAP (manufactured by BASF).

(4) Acidic acrylic polymer compound (meth) acrylic acid / (meth) acrylate copolymer; plus size L53P (manufactured by Yoyo Chemical Co., Ltd.) as a commercial product, Diahold (Mitsubishi Yuka (Manufactured by Co., Ltd.). Acrylic acid / alkyl acrylate / alkyl acrylamide copolymer; commercially available products include Ultrahold 8 (manufactured by BASF) and Amphomer V-42 (manufactured by National Starch). (5) Amphoteric acrylic polymer compound ・ N-methacryloylethyl-N, N-dimethylammonium ・ α-N-methylcarboxybetaine / butyl methacrylate copolymer; Yukaformer M- as a commercial product
75, SM (all manufactured by Mitsubishi Yuka Co., Ltd.) and the like. Hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer; commercially available Amphomer 28-4910 (National
Starch).

(6) Basic acrylic polymer compound: acrylamide / acrylester quaternary copolymer;
Examples thereof include those described in JP-A-2-180911. (7) Cellulose derivatives Cationic cellulose derivatives; commercially available products include Cellcoat H-100 and L-200 (manufactured by National Starch). (8) Chitin / chitosan derivative / hydroxypropyl chitosan; commercially available products include chitofilmer (manufactured by Ichimaru Falcos).・ Carboxymethyl chitin ・ Carboxymethyl chitosan

[0014] Among these film-forming polymers, in particular, vinylpyrrolidone / dimethylaminoethyl methacrylate quaternary chloride copolymer, cetyldimethyl- (2-hydroxyethyl) ammonium phosphate, hydroxyethylcellulose hydroxypropyltrimethylammonium chloride ether and the like. Cationic polymers are preferred, especially
Vinyl pyrrolidone / dimethylaminoethyl methacrylate quaternary chloride copolymer is preferred.

Component (a) is present in the composition of the present invention in an amount of 0.1 to 10%.
Preferably it is used in% by weight.

The guar gum (general name: galactomannan) of the component (b) used in the present invention is a water-soluble natural polysaccharide obtained from the endosperm portion of guar beans, a one-year-old legume. And a mannose main chain and a galactose side chain in a ratio of 2: 1 with β-glucoside bonds.

As guar gum, unmodified and various modified derivatives are known. In the present invention, one or more selected from unmodified guar gum, nonionic derivatives of guar gum and cationic derivatives are used. used.

Specific examples thereof include unmodified guar gum (MEYPRO-GAT12 manufactured by MEYHALL).
0), hydroxypropylated guar gum (nonionic derivative: manufactured by MEYHALL, JAGUAR-HP-1)
1), hydroxypropyltrimethylammonium chloride guar gum (cationic derivative: MEYHALL)
And JAGUAR-C-13-S), preferably cationic derivatives of guar gum.

The component (b) is contained in the composition of the present invention in an amount of 0.005 to 0.005.
It is preferred to use up to 5% by weight.

The propellant of component (c) used in the present invention includes liquefied petroleum gas (LPG), dimethyl ether,
Methyl ethyl ether, diethyl ether and the like are preferred.

Component (c) is preferably used in the composition of the present invention in an amount of 1 to 15% by weight.

The hair styling composition of the present invention may further contain a humectant, a medicine, an ultraviolet absorber, a preservative,
Antioxidants, other components such as polymers, pigments, dispersants, sequestering agents, lower alcohols, crude drug extracts, mucopolysaccharides, amino acids, proteins, dyes, flavors, and other optional components can be added. . These optional ingredients are dissolved in water,
It is preferable to mix after dispersing.

The method for preparing the hair styling composition of the present invention is not particularly limited, but the component (a) and the component (b) are dissolved and mixed in water or a lower alcohol, and the component (c) is added.
The method of preparing by mixing is preferable.

The hair styling composition of the present invention is preferably applied directly to the hair and used as a soot-free agent, and can be made into various forms depending on the use. Examples thereof include set lotion, blow styling lotion, and styling. Preparations, hair treatment agents, hair mist agents, hair mousse agents, hair creams and the like.

[0025]

EFFECTS OF THE INVENTION The hair styling composition of the present invention has a hair styling property such as easiness of hair formation, set styling, foam texture, styling,
Foam properties such as good stretch, hair gloss, softness,
It is excellent in texture such as moist feeling.

[0026]

EXAMPLES The present invention will be described below in more detail with reference to examples, but the present invention is not limited to these examples.

Example 1 With respect to the compositions shown in Tables 1 to 14, first, a substance other than the propellant was mixed and dissolved to form a stock solution, and then the propellant was added thereto, and sealed in a pressure-resistant container to prepare a hairdressing composition. Was prepared.

About 20 g (about 15 to 20 cm) of hair of a Japanese woman who has not been subjected to beauty treatment such as cold perm and bleach are bundled, washed with a shampoo, dried with a towel, and dried. Are applied uniformly,
Furthermore, after drying with a dryer, the foam properties (good foam texture, good foam stickiness, foam growth), hair styling properties (easiness of making hair, hair setting power), texture (hair gloss, hair 10 panelists evaluated the following criteria for the softness and softness of the hair. Tables 1 to 14 also show the average values.

(Evaluation criteria) ：: Very good ○: Excellent △: Somewhat excellent ×: Not good

[0030]

[Table 1]

[0031]

[Table 2]

[0032]

[Table 3]

[0033]

[Table 4]

[0034]

[Table 5]

[0035]

[Table 6]

[0036]

[Table 7]

[0037]

[Table 8]

[0038]

[Table 9]

[0039]

[Table 10]

[0040]

[Table 11]

[0041]

[Table 12]

[0042]

[Table 13]

[0043]

[Table 14]

* 1) GAFQUAT755N manufactured by GAF * 2) LUVIQUAT MONO CP * 3) manufactured by BASF, NATURAL STARCH AND CHE
MICAL Co., Ltd., CELQUAT H-100 * 4) Mitsubishi Yuka Co., Ltd., Yuka Former M-75 * 5) GAF Co., Ltd., Lubiscol K30 * 6) Hyoka Chemical Co., Ltd., plus size L53P * 7) MEYHALL JAGUAR-C-13-S * 8) MEYHALL, MEYPRO-GAT120 * 9) MEYHALL, JAGUAR-HP-11 * 11) MEYHALL, JAGUAR-CMHP * 12) MEYHALL, MEYPRO -LOCUST
M-175 * 13) POLYMER, manufactured by UNION CARBIDE
JR400

As is apparent from Tables 1 to 14, all of the products of the present invention generally exhibited good foam properties, hair styling properties and texture.

Example 2 A hairdressing foam having the composition shown in Table 15 was prepared in the same manner as in Example 1.

[0047]

[Table 15]

All of the above-mentioned products of the present invention exhibited good foam properties, hair styling properties and texture.

Example 3 A foam hair dye having the composition shown in Table 16 was prepared in the same manner as in Example 1.

[0050]

[Table 16]

All of the above-mentioned products of the present invention exhibited good foaming properties, hair styling properties and texture.

Claims (3)

(57) [Claims] 1. The following (a), (b) and (c): (a) a film-forming polymer; (b) one selected from unmodified guar gum, nonionic derivatives of guar gum and cationic derivatives of guar gum; A hairdressing composition comprising two or more (c) propellants. 2. The hairdressing composition according to claim 1, wherein (a) the film-forming polymer is a cationic polymer. 3. The hairdressing composition according to claim 1, wherein (a) the film-forming polymer is a vinylpyrrolidone / dimethylaminoethyl methacrylate quaternary chloride copolymer.