JPH05345708A - Hair-fixing agent composition - Google Patents

Abstract

PURPOSE:To provide a hair-fixing agent composition having excellent hair-fixing property and foam characteristics such as the texture, stability and spreadability of foam and giving treated hair having excellent feeling such as gloss, softness and moistness. CONSTITUTION:The hair-fixing agent composition contains (A) 0.1-10wt.% of a film-forming polymer, preferably a cationic polymer, especially a copolymer of quaternized salt of vinylpyrrolidone/dimethylaminoethyl methacrylate, (B) 0.005-5wt.% of one or more components selected from unmodified guar gum, nonionic derivative of guar gum (e.g. hydroxypropylated guar gum) and cationic derivative of guar gum (e.g. hydroxypropyl trimethyl ammonium chloride guar gum) and (C) 1-15wt.% of a propellant such as liquefied petroleum gas and dimethyl ether.

Description

Detailed Description of the Invention

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hair styling composition, and more particularly to a foam hair styling material having excellent foaming properties, hair styling properties and texture.

[0002]

2. Description of the Related Art In recent years,
Foamed hair styling products are gaining popularity because of their simplicity and light finish, and are increasing their market share. Foam aerosol compositions for such products generally include polyvinylpyrrolidone, vinylpyrrolidone / vinyl acetate copolymer, vinyl acetate / crotonic acid copolymer, carboxylated vinyl acetate copolymer, vinyl methyl ether / maleic acid half. Ester copolymer, acrylic resin (anionic, amphoteric)
A film-forming polymer such as is dissolved in water, ethanol, an oil agent, a surfactant or the like, and further mixed with a propellant such as liquefied petroleum gas is used. The foamy hair styling agent is one in which the above composition is applied to the hair using a hand, a comb or the like to style the hair and maintain the hairstyle.

In addition to sufficient hair styling properties, such a foamy hair styling material is required to have excellent foaming properties such as texture, stickiness, and spreadability of the hair, and shine, softness, and moisturizing feel of the hair styling. It

However, a foamy hair styling material satisfying all of these has not been obtained yet. For example, when a polymer capable of forming a hard film is selected as the set base, the hair styling property is good, but the finish is stiff and the texture is poor, and in addition, the foam quality is satisfactory in terms of texture, stickiness, and spreadability. Absent. On the other hand, when various oil agents, surfactants, etc. are blended in order to make the polymer coating soft, the finish is soft, but the setting power and moisturizing deteriorate and the hairstyle collapses, achieving the original purpose of the hair styling product. Can not.

Therefore, there has been a strong demand for the development of a foamy hair styling material which is sufficiently satisfactory in terms of the hair styling property as well as the foam characteristics and the texture.

[0006]

Means for Solving the Problems As a result of intensive studies in view of the above circumstances, the present inventors have found that a hair styling product in which a propellant is blended with a combination of specific polymer species has a good hair styling property as described later. The present invention has been completed based on the finding that it exhibits foam characteristics and texture.

That is, the present invention provides the following (a) and (b)
And (c): (a) a film-forming polymer (b) containing one or more kinds selected from unmodified guar gum, a nonionic derivative of guar gum and a cationic derivative of guar gum, and (c) a propellant. The present invention provides a characteristic hair styling composition.

[0008] Incidentally, West German Patent Application No. 363,030A discloses a hair styling composition containing an anionic or cationic polymer in a film-forming resin. This hair styling composition has a foaming property and a texture. It was not satisfactory.

Examples of the film-forming polymer of the component (a) used in the present invention include anionic, cationic,
Examples include nonionic and amphoteric polymers, and specific examples include those shown in the following (1) to (8).

(1) Polyvinylpyrrolidone type polymer compound: polyvinylpyrrolidone; Rubiscol K as a commercial product
12, K30 (above BASF), PVP K15,
Examples include K30 (all manufactured by GAF). -Vinylpyrrolidone / vinyl acetate copolymer; as commercially available products, Rubiscol VA28, VA73 (above BASF), PVP / VA E-735, S-630 (above G
Manufactured by AF) and the like. -Vinylpyrrolidone / vinyl acetate / vinyl propionate terpolymer; rubiscol VAP343 as a commercial product
(Manufactured by BASF) and the like.・ Vinylpyrrolidone / alkylamino acrylate (quaternary chloride) copolymer; Rubiflex (BA
SF), copolymers 845, 937, 958, Gaffcut 755N (all manufactured by GAF) and the like. -Vinylpyrrolidone / acrylate / (meth) acrylic acid copolymer; Rubiflex VBM35 as a commercial product
(Manufactured by BASF) and the like. -Vinylpyrrolidone / alkylaminoacrylate / vinylcaprolactam copolymer; as a commercial item, copolymer VC-713 (manufactured by GAF) and the like can be mentioned.

(2) Polymeric compound of acidic vinyl ether-Methyl vinyl ether / maleic anhydride alkyl half ester copolymer; Gantrez ES- as a commercial product
225, ES-425, SP-215 (all manufactured by GAF). (3) Acidic polyvinyl acetate polymer compound-Vinyl acetate / crotonic acid copolymer; examples of commercially available products include Resin 28-1310 (manufactured by National Starch) and Rubyset CA66 (manufactured by BASF).・ Vinyl acetate / crotonic acid / vinyl neodecanoate copolymer; Resin 28-2930 (National
Starch) and the like. -Vinyl acetate / crotonic acid / vinyl propionate copolymer; commercially available products include Rubiset CAP (manufactured by BASF).

(4) Acidic acrylic polymer compound (meth) acrylic acid / (meth) acrylic acid ester copolymer; plus size L53P (manufactured by Mutual Chemical Co., Ltd.) as a commercial product, DIAHOLD (Mitsubishi Petrochemical Co., Ltd.) (Manufactured by Co., Ltd.) and the like. -Acrylic acid / acrylic acid alkyl ester / alkyl acrylamide copolymer; examples of commercially available products include Ultrahold 8 (manufactured by BASF) and Amphomer V-42 (manufactured by National Starch). (5) Amphoteric acrylic polymer compound-N-methacryloylethyl-N, N-dimethylammonium-α-N-methylcarboxybetaine / butyl methacrylate copolymer; Yukaformer M- as a commercial product
75, SM (all manufactured by Mitsubishi Petrochemical Co., Ltd.) and the like.・ Hydroxypropyl acrylate / butylaminoethyl methacrylate / octylamide acrylate copolymer; Amphomer 28-4910 (National
Starch) and the like.

(6) Basic acrylic polymer compound: acrylamide-acrylic ester quaternary copolymer;
The thing etc. which are described in Unexamined-Japanese-Patent No. 2-180911 are mentioned. (7) Cellulose derivative-Cationic cellulose derivative; commercially available products such as Cellcoat H-100 and L-200 (manufactured by National Starch). (8) Chitin / chitosan derivative-Hydroxypropyl chitosan; examples of commercially available products include chitofilmer (manufactured by Ichimaru Falcos).・ Carboxymethyl chitin ・ Carboxymethyl chitosan

Among these film-forming polymers, vinylpyrrolidone / dimethylaminoethyl methacrylate quaternary chloride copolymer, cetyldimethyl- (2-hydroxyethyl) ammonium phosphate, hydroxyethylcellulose hydroxypropyltrimethylammonium chloride ether, etc. Cationic polymers are preferred, especially
A vinylpyrrolidone / dimethylaminoethyl methacrylate quaternary chlorinated copolymer is preferred.

The component (a) is 0.1 to 10 in the composition of the present invention.
It is preferably used in weight percent.

The component (b), guar gum (generic name: galactomannan) used in the present invention is a water-soluble natural polysaccharide obtained from the endosperm portion of guar beans, which is an annual legume plant. , The main chain of mannose and the side chain of galactose are β-glucoside linked at a ratio of 2: 1.

Although unmodified guar gum and various modified derivatives are known, in the present invention, one or more selected from unmodified guar gum, nonionic derivative and cationic derivative of guar gum. used.

Specific examples of these include unmodified guar gum (manufactured by MEYHALL, MEYPRO-GAT12).
0), hydroxypropylated guar gum (nonionic derivative: manufactured by MEYHALL, JAGUAR-HP-1)
1), hydroxypropyltrimethylammonium chloride guar gum (cationic derivative: MEYHALL
Manufactured by JAGUAR-C-13-S) and the like, and preferably a cationic derivative of guar gum.

The component (b) is 0.005 in the composition of the present invention.
It is preferable to use -5% by weight.

As the propellant of the component (c) used in the present invention, liquefied petroleum gas (LPG), dimethyl ether,
Methyl ethyl ether, diethyl ether and the like are preferable.

Component (c) is preferably used in the composition of the present invention in an amount of 1 to 15% by weight.

The hair styling composition of the present invention further comprises a moisturizing agent, a drug, an ultraviolet absorber, an antiseptic, and a preservative, depending on the purpose of use.
Antioxidants, polymers other than the above, pigments, dispersants, sequestering agents, lower alcohols, crude drug extracts, mucopolysaccharides, amino acids, proteins, pigments, fragrances and other optional components can be added. .. These optional ingredients are soluble in water,
It is preferable to mix after dispersing.

The method for preparing the hair styling composition of the present invention is not particularly limited, but the component (c) is added to a mixture of the components (a) and (b) dissolved in water or a lower alcohol, and mixed,
A method of preparing by mixing is preferable.

The hair styling composition of the present invention is preferably applied directly to the hair and used as a soot-free agent, and can be made into various forms depending on the application, for example, set lotion, blow styling lotion, styling. Agent, hair treatment agent, hair mist agent, hair mousse agent, hair cream and the like.

[0025]

EFFECTS OF THE INVENTION The hair styling composition of the present invention is characterized by easiness of curling hair, hair styling property such as moisturizing of hair, texture of foam, and moisturizing effect.
Foam characteristics such as good spreadability, gloss of hair, softness,
It has an excellent moist feel.

[0026]

EXAMPLES The present invention will now be described in detail with reference to examples, but the present invention is not limited thereto.

Example 1 With respect to the compositions shown in Tables 1 to 14, first, a material other than a propellant was mixed and dissolved to form a stock solution, and then a propellant was added to this, which was then sealed in a pressure resistant container to prepare a hairdressing composition. The thing was prepared.

About 20 g (about 15 to 20 cm) of hair of a Japanese woman who has not been subjected to cosmetic treatment such as cold perm or bleach has been bundled, washed with shampoo and towel dried, and the above hairdressing composition is prepared. Evenly,
After further drying with a dryer, foam characteristics (good texture of foam, goodness of foam, spread of foam), hair styling (easiness of curling hair, setting power of hair), texture (luster of hair, hair) Softness, moist feeling of hair, etc.) was evaluated by 10 professional panelists according to the following evaluation criteria. The average values are also shown in Tables 1 to 14.

(Evaluation Criteria) ⊚: Very good ∘: Excellent Δ: Slightly excellent ×: Not good

[0030]

[Table 1]

[0031]

[Table 2]

[0032]

[Table 3]

[0033]

[Table 4]

[0034]

[Table 5]

[0035]

[Table 6]

[0036]

[Table 7]

[0037]

[Table 8]

[0038]

[Table 9]

[0039]

[Table 10]

[0040]

[Table 11]

[0041]

[Table 12]

[0042]

[Table 13]

[0043]

[Table 14]

* 1) GAF, GAFQUAT755N * 2) BASF, LUVIQUAT MONO CP * 3) NATUALAL STARCH AND CHE
MICAL, CELQUAT H-100 * 4) Mitsubishi Petrochemical Co., Ltd., Yucaformer M-75 * 5) GAF, Rubiscol K30 * 6) Mutsou Kagaku Co., Ltd., plus size L53P * 7) MEYHALL Company, JAGUAR-C-13-S * 8) MEYHALL, MEYPRO-GAT120 * 9) MEYHALL, JAGUAR-HP-11 * 11) MEYHALL, JAGUAR-CMHP * 12) MEYHALL, MEYPRO -LOCUST
M-175 * 13) made by UNION CARBIDE, POLYMER
JR400

As is clear from Tables 1 to 14, all the products of the present invention generally showed good foam characteristics, hair styling properties and texture.

Example 2 A foamy hair styling composition having the composition shown in Table 15 was prepared in the same manner as in Example 1.

[0047]

[Table 15]

The above-mentioned products of the present invention all showed good foam properties, hair styling properties and texture.

Example 3 A foam hair dye having the composition shown in Table 16 was prepared in the same manner as in Example 1.

[0050]

[Table 16]

The above-mentioned products of the present invention all showed good foam characteristics, hair styling properties and texture.

Claims (3)

[Claims] 1. The following (a), (b) and (c): (a) a film-forming polymer (b) one selected from unmodified guar gum, a nonionic derivative of guar gum and a cationic derivative of guar gum, or A hairdressing composition comprising two or more (c) propellants. 2. The hair styling composition according to claim 1, wherein the film-forming polymer (a) is a cationic polymer. 3. The hair styling composition according to claim 1, wherein the film-forming polymer (a) is a vinylpyrrolidone / dimethylaminoethyl methacrylate quaternary chlorinated copolymer.