WO2019064852A1 - Hairstyling composition - Google Patents

Hairstyling composition Download PDF

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Publication number
WO2019064852A1
WO2019064852A1 PCT/JP2018/027368 JP2018027368W WO2019064852A1 WO 2019064852 A1 WO2019064852 A1 WO 2019064852A1 JP 2018027368 W JP2018027368 W JP 2018027368W WO 2019064852 A1 WO2019064852 A1 WO 2019064852A1
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WO
WIPO (PCT)
Prior art keywords
component
mass
content
hair
less
Prior art date
Application number
PCT/JP2018/027368
Other languages
French (fr)
Japanese (ja)
Inventor
駿 占部
楓 阿部
Original Assignee
株式会社マンダム
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社マンダム filed Critical 株式会社マンダム
Priority to KR1020197038364A priority Critical patent/KR20200009094A/en
Priority to JP2019544331A priority patent/JP6884490B2/en
Priority to CN201880047693.6A priority patent/CN110913832A/en
Publication of WO2019064852A1 publication Critical patent/WO2019064852A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0204—Specific forms not provided for by any of groups A61K8/0208 - A61K8/14
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86—Polyethers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • the present invention relates to a hair styling composition which is suitably used for a hair styling composition for conditioning hair.
  • the hair setting properties that can be exhibited by the hair setting composition used to condition the hair include various hair setting properties.
  • properties for putting hairs together for example, properties for putting hair together tight, properties for putting hair together to make a hair bundle, etc.
  • properties for making hair flow, etc. make a hairstyle (for example, arranging power etc.)
  • Properties of firming hair, properties of raising hair, properties of holding hair style for a long time, properties of imparting gloss to hair, and properties of improving slippage between hairs and imparting a dry feeling, etc. may be mentioned.
  • the hair styling composition is designed to exhibit one or more of the hair styling characteristics described above, depending on the desired hair styling style, the quality of hair to be applied, and the like.
  • the hair styling composition also has various properties such as liquid, gel and grease, and the hair styling composition has different usability, feeling in use and hair styling characteristics.
  • different composition designs are performed for hair styling compositions having different properties.
  • the grease-like hair styling composition (so-called hair grease or hair pomade) has no fluidity, or has a flowability lower than that of a gel-like hair styling composition, It has solid or paste-like properties.
  • the grease-like hairdressing agent composition can be used by filling it in a jar container etc. and taking an appropriate amount from the container with a finger, etc., and is characterized by being excellent in handleability.
  • the grease-like hairdressing agent composition has an advantage of being superior in the characteristics (arrangement ability) of making a hair flow and making a hairdo and imparting gloss to the hair as compared with the gel-like hairdressing agent composition.
  • an oil-based grease-like hair styling composition containing a liquid oil and a solid oil, an aqueous grease-like hair styling agent containing water and a relatively large amount of polyoxyethylene hydrogenated castor oil Composition, an aqueous grease-like hair styling composition (see, for example, Patent Document 1) containing a large amount of polyhydric alcohol and greatly thickened with a thickener, and containing water and a film-forming polymer
  • water-based grease-like hair styling agent composition for example, refer patent document 2) etc. which were greatly thickened with the agent are mentioned.
  • Oily greasy hair styling compositions suffer from the characteristic stickiness of oils.
  • the aqueous grease-like hair styling composition containing a large amount of polyoxyethylene hydrogenated castor oil is easily sticky.
  • the stability of properties is insufficient, and in particular, the properties may change when exposed to high temperatures, and the high temperature stability (properties stability at high temperatures) May be lower.
  • the grease-like hairdressing agent composition has advantages in handling properties and characteristics for imparting luster, the current state is that it has problems in terms of stability of properties and moisture resistance.
  • an object of the present invention is to provide a hair styling composition which is excellent in stability of properties (particularly stability of properties under high temperature) and which can also enhance moisture resistance of hair after hair styling. .
  • the present invention comprises the following component (A), the following component (B), the following component (C), and the following component (D), and the content of the component (A) is 30.0 mass% or more. 45.0% by mass or less, the content of the component (B) is 0.1% by mass or more, and the content of the component (C) is 0.1% by mass or more and 5.0% by mass or less.
  • a hair styling composition wherein the mass ratio of the content of the component (A) to the content of the component (B) is 5.0 or more.
  • Component (B) Film-forming polymer obtained by using (meth) acrylic acid alkyl ester as an essential monomer component having a weight average molecular weight of 30,000 or more and 150,000 or less
  • Component (C) polyoxyethylene hydrogenated castor oil
  • the component (A) preferably contains the following component (A1).
  • Component (A1) polyoxyethylene stearyl ether having an average added mole number of oxyethylene groups of 20 to 50, polyoxyethylene behenyl ether having an average added mole number of oxyethylene groups of 20 to 50, and A polyoxyethylene alkyl ether selected from the group consisting of polyoxyethylene cetyl ether having an average addition mole number of oxyethylene groups of 30 or more and 50 or less
  • the component (B) preferably contains the following component (B1).
  • the hair styling composition of the present invention preferably further comprises the following component (E).
  • Component (E) Polyoxypropylene Sorbit
  • the properties of the hair styling composition of the present invention are in the form of grease.
  • the hair styling composition of the present invention comprises a specific component (A), a component (B), a component (C) and a component (D), and the content of the component (A) is 30.0% by mass or more, 45.
  • the content of the component (B) is 0.1% by mass or more
  • the content of the component (C) is 0.1% by mass or more and 5.0% by mass or less Since the mass ratio of the content of (A) to the content of component (B) is 5.0 or more, it is excellent in the stability of properties (particularly the stability of properties at high temperature), and hairdressed hair Moisture resistance can also be enhanced.
  • the hairdressing agent composition of the present invention comprises a polyoxyethylene alkyl ether having an alkyl group having an average addition mole number of oxyethylene groups of 20 or more and 50 or less and having 16 or more and 22 or less carbon atoms, and a weight average molecular weight Is 30,000 or more and 150,000 or less, and contains, as an essential monomer component, a film-forming polymer obtained by using (meth) acrylic acid alkyl ester, polyoxyethylene hydrogenated castor oil, and water.
  • component (A) is a polyoxyethylene alkyl ether having an alkyl group having an average addition mole number of oxyethylene group of 20 or more and 50 or less and a carbon number of 16 or more and 22 or less). In some cases.
  • component (B) is a film-forming polymer obtained by using (meth) acrylic acid alkyl ester as a monomer component having a weight average molecular weight of 30,000 or more and 150,000 or less and as an essential monomer component. It may be called.
  • component (C) polyoxyethylene hydrogenated castor oil
  • the hair styling composition of the present invention comprises the component (A), the component (B), the component (C) and the component (D), and the content of the component (A) is 30.0% by mass or more, 45.0
  • the content of the component (B) is 0.1% by mass or more
  • the content of the component (C) is 0.1% by mass or more and 5.0% by mass or less
  • the component (A) The mass ratio of the content of the component (B) to the content of the component (B) (content of component (A) / content of component (B)) is 5.0 or more.
  • the above-mentioned constitution makes it possible to obtain excellent stability of properties under high temperature (for example, at a temperature of 50 ° C.), and also to improve the moisture resistance of hair after hair styling.
  • the above-mentioned constitution can also impart an appropriate hardness to hair after hair setting.
  • the above-mentioned configuration can also reduce stickiness and improve the coating property.
  • the above-described configuration makes it possible to gather the hair together to form a hair bundle and to make the hair bundle well-assembled.
  • the hair styling composition of the present invention preferably further comprises a polyoxypropylene sorbite.
  • polyoxypropylene sorbite may be referred to as “component (E)".
  • the hairdressing composition of the present invention comprises at least the components (A), (B), (C) and (D).
  • the hair styling composition of the present invention may further contain component (E).
  • the hair styling composition of the present invention may contain other components other than the components (A) to (E).
  • component (A), component (B), component (C), component (D), component (E) and other components may be used alone or in combination of two or more. More than one species may be used in combination.
  • the component (A) is a polyoxyethylene alkyl ether having an alkyl group having an average addition mole number of oxyethylene group of 20 or more and 50 or less and a carbon number of 16 or more and 22 or less.
  • Component (A) is mainly a main component that forms a grease-like property.
  • the grease-like property can be obtained by the component (A) because the component (A) forms water and hexagonal liquid crystal and is presumed to form a non-flowable or extremely low-hard gel.
  • the reason is not limited to this.
  • the properties of the hair styling composition of the present invention become hard, it becomes easy to form the hair bundle by putting together the hair, and it is possible to make the hair bundle well-organized.
  • the component (A) is less sticky, it also has the effect of suppressing the stickiness of the hair styling composition.
  • the component (A) only one type may be used, or two or more types may be used in combination.
  • the average added mole number of the oxyethylene group of the component (A) is 20 or more and 50 or less.
  • the average addition mole number of the oxyethylene group of the component (A) is preferably 40 or less, from the viewpoint of effectively enhancing the formability of the grease-like hair styling composition and enhancing the high temperature stability.
  • Component (A) has an alkyl group having 16 or more and 22 or less carbon atoms.
  • alkyl group a stearyl group, a cetyl group, and a behenyl group etc. are mentioned, for example.
  • the alkyl group is preferably a stearyl group, a cetyl group or a behenyl group from the viewpoint of effectively enhancing the hair setting ability to effectively form the grease-like hair setting composition, and the alkyl group is preferably a cetyl group. Is more preferred.
  • Component (A) is a polyoxyethylene stearyl ether having an average addition mole number of an oxyethylene group of 20 or more and 50 or less, from the viewpoint of more effectively forming the grease-like hair styling composition, and oxyethylene
  • a polyoxyethylene selected from the group consisting of polyoxyethylene behenyl ether having an average addition mole number of groups of 20 or more and 50 or less, and polyoxyethylene cetyl ether having an average addition mole number of oxyethylene groups of 30 or more and 50 or less It is preferred to include ethylene alkyl ether (at least one polyoxyethylene alkyl ether).
  • polyoxyethylene stearyl ether having an average addition mole number of oxyethylene group of 20 or more and 50 or less, and polyoxyethylene behenyl having an average addition mole number of oxyethylene group of 20 or more and 50 or less The polyoxyethylene alkyl ether selected from the group consisting of ether and polyoxyethylene cetyl ether in which the average addition mole number of the oxyethylene group is 30 or more and 50 or less may be referred to as "component (A1)". That is, component (A) preferably contains component (A1).
  • the hair styling composition of the present invention preferably comprises the component (A1).
  • component (A1) only one type may be used, or two or more types may be used in combination.
  • the average added mole number of the oxyethylene group of the polyoxyethylene stearyl ether is preferably 20 or more, and preferably 50 or less.
  • the average added mole number of the oxyethylene group of the polyoxyethylene behenyl ether is preferably 30 or less.
  • the average addition mole number of the oxyethylene group of the polyoxyethylene cetyl ether is preferably 45 or less, more preferably 40 or less.
  • the content of the component (A) is 30.0% by mass or more, preferably 35.0% by mass or more, and 45.0% by mass or less, preferably 40. It is 0 mass% or less.
  • the hair styling composition can be appropriately hardened to have a grease-like property, and the hair bundle can be well consolidated.
  • stability of properties at high temperature can be effectively enhanced.
  • the component (A) since the content of the component (A) is not more than the above upper limit, the component (A) can be uniformly dissolved in the hair styling composition.
  • the content of the component (A) is less than 30.0% by mass in 100% by mass of the hairdressing agent composition, when the hairdressing composition is stored under high temperature, part of the hairdressing agent composition is easily liquefied Become.
  • the content of component (A) is the sum of the content of all components (A) in the hair styling composition of the present invention.
  • the content of the component (A1) is preferably 95% by mass or more, more preferably 98% by mass or more, and most preferably 100% by mass in 100% by mass of the component (A). Therefore, it is most preferable that the whole of component (A) is component (A1).
  • the content of the component (A1) is a ratio of the total content of all the components (A1) to the total content of all the components (A) in the hair styling composition of the present invention.
  • Component (B) is a film-forming polymer obtained by using (meth) acrylic acid alkyl ester as an essential monomer component having a weight average molecular weight of 30,000 or more and 150,000 or less.
  • the component (B) is a component that improves the moisture resistance of the trimmed hair. As the component (B), only one type may be used, or two or more types may be used in combination.
  • component (B) is an alkyl acrylate copolymer AMP, (alkyl acrylate / diacetone acrylamide) copolymer AMP, (acreates / alkyl acrylate (C1-) 18) / alkyl (C1-8) acrylamide) copolymer AMP, (alkyl acrylate octyl acrylamide) copolymer, (methacryloyloxyethyl carboxybetaine / alkyl methacrylate) copolymer, and (octyl acrylamide / hydroxypropyl acrylate / butyl methacrylate) It is preferred to include a film-forming polymer (at least one film-forming polymer) selected from the group consisting of aminoethyl) copolymers.
  • alkyl acrylate copolymer AMP (alkyl acrylate / diacetone acrylamide) copolymer AMP, (acrylate / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP, ( A film-forming polymer selected from the group consisting of alkyl acrylate octyl acrylamide) copolymer, (methacryloyloxyethyl carboxy betaine / alkyl methacrylate) copolymer, and (octyl acrylamide / hydroxypropyl acrylate / butyl aminoethyl methacrylate) copolymer It may be called "component (B1).” That is, the component (B) preferably contains the component (B1).
  • the hairdressing composition of the present invention preferably comprises the component (B1).
  • component (B1) only one type may be used, or two or more types may be used in combination.
  • the weight average molecular weight of the component (B) is 30,000 or more, preferably 50,000 or more, and 150,000 or less, preferably 100,000 or less. In the present invention, since the weight average molecular weight of the component (B) is equal to or more than the above lower limit, the moisture resistance of the trimmed hair can be further enhanced. Further, in the present invention, since the weight average molecular weight of the component (B) is not more than the above upper limit, stability of properties (particularly stability of properties at high temperature) can be enhanced.
  • the weight average molecular weight of the component (B1) is 30,000 or more, preferably 50,000 or more, and 150,000 or less, preferably 100,000 or less. In the present invention, since the weight average molecular weight of the component (B1) is not less than the above lower limit, it is possible to further improve the moisture resistance of the trimmed hair. Further, in the present invention, since the weight average molecular weight of the component (B1) is not more than the above upper limit, stability of properties (especially stability of properties at high temperature) can be enhanced.
  • component (B) for example, trade name "plus size L-9540 UW” ((alkyl acrylate / diacetone acrylamide) copolymer AMP, manufactured by HAZUKO CHEMICAL Co., Ltd.), and trade name “plus size L-6466” ((Acrylate alkyl / diacetone acrylamide) copolymer AMP, manufactured by Yuka Chemical Co., Ltd.) and the like.
  • the content of the component (B) is 0.1% by mass or more, preferably 1.0% by mass or more. In the present invention, since the content of the component (B) is not less than the above lower limit, the moisture resistance of the trimmed hair can be enhanced.
  • the content of component (B) is the sum of the content of all components (B) in the hair styling composition of the present invention.
  • the content of the component (B1) is preferably 95% by mass or more, more preferably 98% by mass or more, and most preferably 100% by mass in 100% by mass of the component (B). Therefore, it is most preferable that the whole of component (B) is component (B1).
  • the content of the component (B1) is a ratio of the total content of all the components (B1) to the total content of all the components (B) in the hair styling composition of the present invention.
  • the mass ratio of the content of component (A) to the content of component (B) (content of component (A) / component (B)
  • the content is 5.0 or more.
  • High temperature stability falls that the said mass ratio (content of component (A) / content of component (B)) is less than 5.0. It is presumed that this is because the hexagonal liquid crystal structure formed by the component (A) and water is broken by the component (B).
  • the mass ratio (content of component (A) / content of component (B)) is 5.0 or more, the moisture resistance can be enhanced while maintaining the grease-like property.
  • the mass ratio (content of component (A) / content of component (B)) is preferably 7.0 or more.
  • Component (C) is polyoxyethylene hydrogenated castor oil.
  • the hairdressing agent composition of the present invention contains the component (C), so that the hairs can be effectively combined, and the hair bundle can be well organized.
  • the component (C) only one type may be used, or two or more types may be used in combination.
  • the average addition mole number of the oxyethylene group of the component (C) is preferably 30 or more, more preferably 40 or more, preferably 40 or more, from the viewpoint of more effectively organizing the hairs and further improving the hair bundle cohesion. It is 100 or less, more preferably 60 or less.
  • the content of the component (C) is 0.1% by mass or more, preferably 1.0% by mass or more, and 5.0% by mass or less, preferably 3. It is 0 mass% or less.
  • the content of the component (C) is equal to or more than the above lower limit, the hairs can be combined more effectively to make the hair bundle cohesive.
  • the content of the component (C) is less than or equal to the above upper limit, stickiness can be reduced and stability of properties at high temperatures can be more effectively enhanced.
  • the content of component (C) is the sum of the content of all components (C) in the hair styling composition of the present invention.
  • Component (D) is water.
  • water By using water, an aqueous grease-like hair styling composition can be formed, and stickiness can be reduced.
  • the use of water facilitates the preparation of a grease-like hair styling composition.
  • the content of the component (D) can be appropriately adjusted by the content of other compounding components.
  • the content of the component (D) is preferably 30.0% by mass or more, more preferably 100% by mass of the hairdressing agent composition of the present invention Is 40.0% by mass or more, more preferably 50.0% by mass or more, preferably 69.0% by mass or less, and more preferably 65.0% by mass or less.
  • Component (E) is a polyoxypropylene sorbite. By using the component (E), it is possible to more effectively organize the hairs and to improve the hair bundle aggregation.
  • component (E) only one type may be used, or two or more types may be used in combination.
  • the number average molecular weight of the component (E) is not particularly limited.
  • the number average molecular weight of the component (E) is preferably 300 or more, more preferably 400 or more, preferably 1000 or less, more preferably from the viewpoint of bringing hairs together more effectively and improving hair bundle cohesion. It is 800 or less.
  • the content of the component (E) is preferably 0.1% by mass or more, more preferably 1.0% by mass or more, and preferably 5.0% by mass or less in 100% by mass of the hairdressing agent composition of the present invention And more preferably 3.0% by mass or less.
  • the content of the component (E) is equal to or more than the above lower limit, the hairs can be combined more effectively, and the bundle of hair bundles can be made favorable.
  • the content of the component (E) is less than or equal to the above upper limit, stickiness can be reduced and stability of properties at high temperature can be more effectively enhanced.
  • the content of component (E) is the sum of the content of all components (E) in the hair styling composition of the present invention.
  • the hairdressing composition of the present invention may contain components other than the components (A) to (E) described above.
  • the components other than the components (A) to (E) are not particularly limited.
  • lower alcohols having 2 to 5 carbon atoms such as ethanol; glycerin, diglycerin, 1,3-butylene glycol, propylene glycol, dipropylene Polyhydric alcohols such as glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol and polyoxypropylene methyl glucoside; sorbitol, Sugar alcohols such as maltitol and trehalose; higher alcohols having 12 to 18 carbon atoms such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol;
  • the hairdressing composition of the present invention preferably contains no ethanol or less than 7.0% by mass of ethanol, from the viewpoint of enhancing formulation stability.
  • 100% by mass of the hair styling composition according to the present invention contains ethanol
  • the content of ethanol is preferably less than 5.0% by mass, more preferably less than 1.0% by mass. It is. Can be mentioned.
  • the properties of the hair styling composition of the present invention are not particularly limited, but from the viewpoint of enhancing the handleability, it is preferably in the form of grease.
  • the hair styling composition of the present invention is preferably a grease-like hair styling composition.
  • Examples of the above-mentioned grease-like hairdressing composition include compositions referred to as hair grease, water grease, aqueous pomade and the like.
  • the manufacturing method of a well-known hair-dressing agent composition is employable.
  • the method of stirring each component with a paddle mixer etc. and homogenizing etc. are mentioned, for example.
  • the hair styling composition of the present invention is not particularly limited, and can be used, for example, in the form of being filled in a container.
  • the container is preferably a jar container.
  • the consistency at 25 ° C. of the hairdressing agent composition of the present invention is preferably 50 gf or more, more preferably 70 gf or more, preferably 800 gf or less, more preferably 600 gf or less .
  • the above-mentioned consistency can be measured under conditions of 25 ° C., speed 60 mm / min, and stroke 20 mm using a consistency meter equipped with a 10 ⁇ spherical adapter. Examples of the consistency meter include "RHEO METER" manufactured by Sun Scientific Co., Ltd.
  • the mass ratio of the content of the component (A) to the content of the component (B) is 5.0 or more is there. Further, from the viewpoint of further enhancing the high temperature stability, the mass ratio (content of component (A) / content of component (B)) is preferably 7.0 or more.
  • Content of a component (A) is 30.0 mass% or more and 45.0 mass% or less in 100 mass% of hair styling agent compositions of this invention.
  • content of the component (A) is less than 30.0% by mass in 100% by mass of the hairdressing agent composition, when the hairdressing composition is stored under high temperature, part of the hairdressing agent composition is easily liquefied Become.
  • Component (A) Polyoxyethylene cetyl ether (40 E. O.): average addition mole number of oxyethylene group 40, carbon number of alkyl group 16
  • Component (B) (Alkyl acrylate / diacetone acrylamide) copolymer AMP: trade name “plus size L-9540 UW”, manufactured by HAKURA CHEMICAL CO., LTD. (Alkyl acrylate / diacetone acrylamide) copolymer AMP, weight average molecular weight 110000
  • Component (C) Polyoxyethylene hydrogenated castor oil (50E.O.): average addition mole number of oxyethylene group 50
  • the hair styling agent composition was prepared by blending the blending components shown in Tables 1 and 2 below (blending unit is% by mass).
  • the compounding amount in Tables 1 and 2 (the compounding amount in 100% by mass of the hairdressing agent composition) was shown by the compounding amount (unit:% by mass) of the pure part.
  • the obtained hair styling composition is stored in a thermostat at 50 ° C. for 12 hours, and the properties after storage (the hardness of the composition, the transparency, the presence or absence of precipitation) are observed, and the high temperature stability according to the following criteria Was evaluated.
  • Example and Comparative Example The main components used in Examples and Comparative Examples are as follows.
  • Component (A) Polyoxyethylene cetyl ether (40 E. O.): average addition mole number of oxyethylene group 40, carbon number of alkyl group 16 Polyoxyethylene cetyl ether (30E.O.): average addition mole number of oxyethylene group, carbon number of alkyl group: 16 Polyoxyethylene stearyl ether (20E.O.): average addition mole number of oxyethylene group 20, carbon number of alkyl group 18
  • (Component (B)) (Alkyl acrylate / diacetone acrylamide) copolymer AMP (1): trade name "Plus size L-9540 UW", manufactured by Hakken, weight average molecular weight 110000 (Alkyl acrylate / diacetone acrylamide) copolymer AMP (2): trade name "plus size L-6466", manufactured by HAKOTO CHEMICAL Co., Ltd., weight average molecular weight 62000
  • component (B)) (Dimethyl acrylamide / hydroxyethyl acrylate / methoxy ethyl acrylate) copolymer: trade name "plus size L-2700", manufactured by HAKOTO CHEMICAL Co., Ltd., weight average molecular weight 15,000 Alkyl acrylate copolymer: trade name "Luviflex soft", manufactured by BASF, weight average molecular weight 500000
  • Polyvinyl pyrrolidone Brand name "PVP K-30", manufactured by ISP (Vinyl pyrrolidone / VA) copolymer: trade name "PVA-6450", manufactured by Osaka Organic Chemical Industry Ltd.
  • Polyquaternium-11 trade name "HC polymer 1N (M)", manufactured by Osaka Organic Chemical Industry Co., Ltd.
  • Component (C) Polyoxyethylene hydrogenated castor oil (50E.O.): average addition mole number of oxyethylene group 50
  • Blending components shown in Tables 3 to 5 below were blended (blending unit is% by mass) to prepare a hair styling composition.
  • the compounding amount in the table (the compounding amount in 100% by mass of the hairdressing agent composition) was shown by the compounding amount (unit: mass%) of the pure part.
  • the properties of the hair styling composition obtained in Examples 1 to 10 were all transparent and greasy.
  • the wig after hair setting was allowed to stand for 1 hour (humidity resistance test) in a thermo-hygrostat kept at high humidity conditions (35 ° C., 80% RH).
  • the hair was touched with a hand before standing (before the moisture resistance test) and after standing (after the moisture resistance test) to evaluate the hardness of the hair.
  • the directions of hair flow (hair flow) before and after the moisture resistance test were compared, and the moisture resistance was evaluated based on the following criteria.
  • the hair styling compositions of Comparative Examples 1 to 4, 6 and 8 to 11 were not tested.
  • the hardness of the hair was hardly changed before and after the moisture resistance test.
  • the hair after the moisture resistance test was slightly softer than the hair before the moisture resistance test.
  • the hair after the moisture resistance test was apparently softer than the hair before the moisture resistance test.

Abstract

Provided is a hairstyling composition which is in a highly stable state and can give styled hair having heightened moisture resistance. The hairstyling composition of the present invention comprises a polyoxyethylene alkyl ether (component A) in which the average number of moles of the added oxyethylene groups is 20-50 and the alkyl has 16-22 carbon atoms, a film-forming polymer (component B) having a weight-average molecular weight of 30,000-150,000 and obtained using an alkyl (meth)acrylate as an essential monomer ingredient, polyoxyethylene hydrogenated castor oil (component C), and water (component D), wherein the content of the component A is 30.0-45.0 mass%, the content of the component B is 0.1 mass% or greater, and the content of the component C is 0.1-5.0 mass%, the mass ratio of the content of the component A to the content of the component B being 5.0 or greater.

Description

整髪剤組成物Hair styling agent composition

　本発明は、毛髪を整える整髪剤に好適に用いられる整髪剤組成物に関する。
The present invention relates to a hair styling composition which is suitably used for a hair styling composition for conditioning hair.

　毛髪を整えるために用いられる整髪剤組成物が発揮し得る整髪特性には、様々な整髪特性がある。例えば、整髪特性としては、毛髪同士をまとめる特性（例えば、毛髪をタイトにまとめる特性、毛髪をまとめて毛束を作る特性等）、毛髪の流れを作り髪型を作る特性（例えば、アレンジ力等）、髪を固める特性、髪を立ち上げる特性、髪型を長時間保持する特性、毛髪に艶を付与する特性、並びに、毛髪同士の滑りを良くしてさらさら感を付与する特性等が挙げられる。
The hair setting properties that can be exhibited by the hair setting composition used to condition the hair include various hair setting properties. For example, as hair setting properties, properties for putting hairs together (for example, properties for putting hair together tight, properties for putting hair together to make a hair bundle, etc.), properties for making hair flow, etc. make a hairstyle (for example, arranging power etc.) Properties of firming hair, properties of raising hair, properties of holding hair style for a long time, properties of imparting gloss to hair, and properties of improving slippage between hairs and imparting a dry feeling, etc. may be mentioned.

　整髪剤組成物は、目的とする整髪スタイルや、適用対象である毛髪の髪質などに応じて、上記の整髪特性のうちの一つ又は複数を発揮するように設計されている。また、整髪剤組成物の性状についても、液状、ジェル状及びグリース状などの種々の性状があり、それぞれの性状の整髪剤組成物が、それぞれ異なる使用性、使用感や整髪特性を有する。また、性状が異なる整髪剤組成物では、異なる組成設計が行われている。
The hair styling composition is designed to exhibit one or more of the hair styling characteristics described above, depending on the desired hair styling style, the quality of hair to be applied, and the like. The hair styling composition also has various properties such as liquid, gel and grease, and the hair styling composition has different usability, feeling in use and hair styling characteristics. In addition, different composition designs are performed for hair styling compositions having different properties.

　整髪剤組成物の中でも、グリース状の整髪剤組成物（所謂、ヘアグリースやヘアポマード）は、流動性を有さないか、又はジェル状の整髪剤組成物と比べて低い流動性を有し、固形状又はペースト状の性状を有する。このため、グリース状の整髪剤組成物は、ジャー容器などに充填して、容器から指で適量をとるなどして使用することができ、取扱い性に優れるという特徴を有する。また、グリース状の整髪剤組成物は、ジェル状の整髪剤組成物と比べて、毛髪の流れを作り髪型を作る特性（アレンジ力）や毛髪に艶を付与する効果に優れるという利点を有する。このようなグリース状の整髪剤組成物としては、液状油及び固形油を含む油性のグリース状整髪剤組成物、水と比較的多量のポリオキシエチレン硬化ヒマシ油とを含む水性のグリース状整髪剤組成物、多価アルコールを多量に含みかつ増粘剤によって大きく増粘された水性のグリース状整髪剤組成物（例えば、特許文献１参照）、並びに、水と皮膜形成ポリマーとを含みかつ増粘剤によって大きく増粘された水性のグリース状整髪剤組成物（例えば、特許文献２参照）等が挙げられる。
Among the hair styling composition, the grease-like hair styling composition (so-called hair grease or hair pomade) has no fluidity, or has a flowability lower than that of a gel-like hair styling composition, It has solid or paste-like properties. For this reason, the grease-like hairdressing agent composition can be used by filling it in a jar container etc. and taking an appropriate amount from the container with a finger, etc., and is characterized by being excellent in handleability. In addition, the grease-like hairdressing agent composition has an advantage of being superior in the characteristics (arrangement ability) of making a hair flow and making a hairdo and imparting gloss to the hair as compared with the gel-like hairdressing agent composition. As such a grease-like hair styling composition, an oil-based grease-like hair styling composition containing a liquid oil and a solid oil, an aqueous grease-like hair styling agent containing water and a relatively large amount of polyoxyethylene hydrogenated castor oil Composition, an aqueous grease-like hair styling composition (see, for example, Patent Document 1) containing a large amount of polyhydric alcohol and greatly thickened with a thickener, and containing water and a film-forming polymer The aqueous | water-based grease-like hair styling agent composition (for example, refer patent document 2) etc. which were greatly thickened with the agent are mentioned.

特開平９－１１０６４９号公報Japanese Patent Laid-Open No. 9-110649 特開２０００－３４２１２号公報JP 2000-34212 A

　油性のグリース状整髪剤組成物では、油の独特のべたつきがあるという問題がある。また、多量のポリオキシエチレン硬化ヒマシ油を含む水性のグリース状整髪剤組成物でもべたつきが生じやすい。更に水性のグリース状整髪剤組成物では、性状の安定性が不十分であり、特に、高温下に晒されたときに性状が変化することがあり、高温安定性（高温での性状安定性）が低くなる場合がある。
Oily greasy hair styling compositions suffer from the characteristic stickiness of oils. In addition, the aqueous grease-like hair styling composition containing a large amount of polyoxyethylene hydrogenated castor oil is easily sticky. Furthermore, in the aqueous grease-like hair styling composition, the stability of properties is insufficient, and in particular, the properties may change when exposed to high temperatures, and the high temperature stability (properties stability at high temperatures) May be lower.

　上記特許文献１や２に記載の増粘剤によって大きく増粘された水性のグリース状整髪剤組成物では、整髪された毛髪の耐湿性に劣ることがある。
In the case of the aqueous grease-like hairdressing agent composition greatly thickened with the thickeners described in Patent Documents 1 and 2, the moisture resistance of hair after hair setting may be poor.

　このように、グリース状整髪剤組成物は、取扱い性や艶を付与する特性などで利点を有するものの、性状の安定性、耐湿性の点で課題を有するという現状がある。
As described above, although the grease-like hairdressing agent composition has advantages in handling properties and characteristics for imparting luster, the current state is that it has problems in terms of stability of properties and moisture resistance.

　そこで、本発明の目的は、性状の安定性（特に高温下での性状の安定性）に優れ、なおかつ、整髪された毛髪の耐湿性も高めることができる整髪剤組成物を提供することである。
Therefore, an object of the present invention is to provide a hair styling composition which is excellent in stability of properties (particularly stability of properties under high temperature) and which can also enhance moisture resistance of hair after hair styling. .

　本発明は、下記成分（Ａ）と、下記成分（Ｂ）と、下記成分（Ｃ）と、下記成分（Ｄ）とを含み、前記成分（Ａ）の含有量が３０．０質量％以上、４５．０質量％以下であり、前記成分（Ｂ）の含有量が０．１質量％以上であり、前記成分（Ｃ）の含有量０．１質量％以上、５．０質量％以下であり、前記成分（Ａ）の含有量の前記成分（Ｂ）の含有量に対する質量比が、５．０以上である、整髪剤組成物を提供する。
The present invention comprises the following component (A), the following component (B), the following component (C), and the following component (D), and the content of the component (A) is 30.0 mass% or more. 45.0% by mass or less, the content of the component (B) is 0.1% by mass or more, and the content of the component (C) is 0.1% by mass or more and 5.0% by mass or less There is provided a hair styling composition, wherein the mass ratio of the content of the component (A) to the content of the component (B) is 5.0 or more.

　成分（Ａ）：オキシエチレン基の平均付加モル数が２０以上、５０以下であり、かつ炭素数が１６以上、２２以下のアルキル基を有するポリオキシエチレンアルキルエーテル
Component (A): polyoxyethylene alkyl ether having an alkyl group having an average addition mole number of oxyethylene group of 20 or more and 50 or less and a carbon number of 16 or more and 22 or less

　成分（Ｂ）：重量平均分子量が３００００以上、１５００００以下であり、かつ必須のモノマー成分として、（メタ）アクリル酸アルキルエステルを用いて得られる皮膜形成ポリマー
Component (B): Film-forming polymer obtained by using (meth) acrylic acid alkyl ester as an essential monomer component having a weight average molecular weight of 30,000 or more and 150,000 or less

　成分（Ｃ）：ポリオキシエチレン硬化ヒマシ油
Component (C): polyoxyethylene hydrogenated castor oil

　成分（Ｄ）：水
Component (D): Water

　本発明の整髪剤組成物は、前記成分（Ａ）が、下記成分（Ａ１）を含むことが好ましい。
In the hair styling composition of the present invention, the component (A) preferably contains the following component (A1).

　成分（Ａ１）：オキシエチレン基の平均付加モル数が２０以上、５０以下であるポリオキシエチレンステアリルエーテル、オキシエチレン基の平均付加モル数が２０以上、５０以下であるポリオキシエチレンベヘニルエーテル、及びオキシエチレン基の平均付加モル数が３０以上、５０以下であるポリオキシエチレンセチルエーテルからなる群より選ばれるポリオキシエチレンアルキルエーテル
Component (A1): polyoxyethylene stearyl ether having an average added mole number of oxyethylene groups of 20 to 50, polyoxyethylene behenyl ether having an average added mole number of oxyethylene groups of 20 to 50, and A polyoxyethylene alkyl ether selected from the group consisting of polyoxyethylene cetyl ether having an average addition mole number of oxyethylene groups of 30 or more and 50 or less

　本発明の整髪剤組成物は、前記成分（Ｂ）が、下記成分（Ｂ１）を含むことが好ましい。
In the hair styling composition of the present invention, the component (B) preferably contains the following component (B1).

　成分（Ｂ１）：アクリル酸アルキルコポリマーＡＭＰ、（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ、（アクリレーツ／アクリル酸アルキル（Ｃ１－１８）／アルキル（Ｃ１－８）アクリルアミド）コポリマーＡＭＰ、（アクリル酸アルキル・オクチルアクリルアミド）コポリマー、（メタクリロイルオキシエチルカルボキシベタイン／メタクリル酸アルキル）コポリマー、及び（オクチルアクリルアミド／アクリル酸ヒドロキシプロピル／メタクリル酸ブチルアミノエチル）コポリマーからなる群より選ばれる皮膜形成ポリマー
Component (B1): alkyl acrylate copolymer AMP, (alkyl acrylate / diacetone acrylamide) copolymer AMP, (acrylate / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP, (alkyl acrylate) A film forming polymer selected from the group consisting of octyl acrylamide) copolymer, (methacryloyloxyethyl carboxy betaine / alkyl methacrylate) copolymer, and (octyl acrylamide / hydroxypropyl acrylate / butyl aminoethyl methacrylate) copolymer

　本発明の整髪剤組成物は、さらに、下記成分（Ｅ）を含むことが好ましい。
The hair styling composition of the present invention preferably further comprises the following component (E).

　成分（Ｅ）：ポリオキシプロピレンソルビット
Component (E): Polyoxypropylene Sorbit

　本発明の整髪剤組成物の性状は、グリース状であることが好ましい。
It is preferable that the properties of the hair styling composition of the present invention are in the form of grease.

　本発明の整髪剤組成物は、特定の成分（Ａ）、成分（Ｂ）、成分（Ｃ）、成分（Ｄ）を含み、成分（Ａ）の含有量が３０．０質量％以上、４５．０質量％以下であり、成分（Ｂ）の含有量が、０．１質量％以上であり、成分（Ｃ）の含有量が０．１質量％以上、５．０質量％以下であり、成分（Ａ）の含有量の成分（Ｂ）の含有量に対する質量比が５．０以上であるので、性状の安定性（特に高温下での性状の安定性）に優れ、なおかつ、整髪された毛髪の耐湿性も高めることができる。
The hair styling composition of the present invention comprises a specific component (A), a component (B), a component (C) and a component (D), and the content of the component (A) is 30.0% by mass or more, 45. The content of the component (B) is 0.1% by mass or more, and the content of the component (C) is 0.1% by mass or more and 5.0% by mass or less Since the mass ratio of the content of (A) to the content of component (B) is 5.0 or more, it is excellent in the stability of properties (particularly the stability of properties at high temperature), and hairdressed hair Moisture resistance can also be enhanced.

　以下、本発明を詳細に説明する。
Hereinafter, the present invention will be described in detail.

　本発明の整髪剤組成物は、オキシエチレン基の平均付加モル数が２０以上、５０以下であり、かつ炭素数が１６以上、２２以下のアルキル基を有するポリオキシエチレンアルキルエーテルと、重量平均分子量が３００００以上、１５００００以下であり、かつ必須のモノマー成分として、（メタ）アクリル酸アルキルエステルを用いて得られる皮膜形成ポリマーと、ポリオキシエチレン硬化ヒマシ油と、水とを含む。
The hairdressing agent composition of the present invention comprises a polyoxyethylene alkyl ether having an alkyl group having an average addition mole number of oxyethylene groups of 20 or more and 50 or less and having 16 or more and 22 or less carbon atoms, and a weight average molecular weight Is 30,000 or more and 150,000 or less, and contains, as an essential monomer component, a film-forming polymer obtained by using (meth) acrylic acid alkyl ester, polyoxyethylene hydrogenated castor oil, and water.

　本明細書においては、上記「オキシエチレン基の平均付加モル数が２０以上、５０以下であり、かつ炭素数が１６以上、２２以下のアルキル基を有するポリオキシエチレンアルキルエーテル」を「成分（Ａ）」と称する場合がある。
In the present specification, the “component (A) is a polyoxyethylene alkyl ether having an alkyl group having an average addition mole number of oxyethylene group of 20 or more and 50 or less and a carbon number of 16 or more and 22 or less). In some cases.

　本明細書においては、上記「重量平均分子量が３００００以上、１５００００以下であり、かつ必須のモノマー成分として、（メタ）アクリル酸アルキルエステルを用いて得られる皮膜形成ポリマー」を「成分（Ｂ）」と称する場合がある。
In the present specification, the “component (B)” is a film-forming polymer obtained by using (meth) acrylic acid alkyl ester as a monomer component having a weight average molecular weight of 30,000 or more and 150,000 or less and as an essential monomer component. It may be called.

　本明細書においては、上記「ポリオキシエチレン硬化ヒマシ油」を「成分（Ｃ）」と称する場合がある。
In the present specification, the above-mentioned "polyoxyethylene hydrogenated castor oil" may be referred to as "component (C)".

　本明細書においては、上記「水」を「成分（Ｄ）」と称する場合がある。
In the present specification, the above "water" may be referred to as "component (D)".

　本発明の整髪剤組成物は、成分（Ａ）、成分（Ｂ）、成分（Ｃ）、及び成分（Ｄ）を含み、成分（Ａ）の含有量が３０．０質量％以上、４５．０質量％以下であり、成分（Ｂ）の含有量が０．１質量％以上であり、成分（Ｃ）の含有量が０．１質量％以上、５．０質量％以下であり、成分（Ａ）の含有量の成分（Ｂ）の含有量に対する質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）が、５．０以上である。
The hair styling composition of the present invention comprises the component (A), the component (B), the component (C) and the component (D), and the content of the component (A) is 30.0% by mass or more, 45.0 The content of the component (B) is 0.1% by mass or more, the content of the component (C) is 0.1% by mass or more and 5.0% by mass or less, the component (A) The mass ratio of the content of the component (B) to the content of the component (B) (content of component (A) / content of component (B)) is 5.0 or more.

　本発明の整髪剤組成物では、上記の構成によって、高温下（例えば、５０℃の温度下）での性状の安定性に優れ、なおかつ、整髪された毛髪の耐湿性も高めることができる。本発明の整髪剤組成物では、上記の構成によって、整髪後の毛髪に適度な硬さを付与することもできる。また、本発明の整髪剤組成物では、上記の構成によって、べたつきを少なくし、塗布性を高めることもできる。さらに、本発明の整髪剤組成物では、上記の構成によって、毛髪をまとめて毛束を形成し、毛束のまとまりを良好にすることができる。
In the hairdressing composition of the present invention, the above-mentioned constitution makes it possible to obtain excellent stability of properties under high temperature (for example, at a temperature of 50 ° C.), and also to improve the moisture resistance of hair after hair styling. In the hairdressing composition of the present invention, the above-mentioned constitution can also impart an appropriate hardness to hair after hair setting. Moreover, in the hairdressing agent composition of the present invention, the above-mentioned configuration can also reduce stickiness and improve the coating property. Furthermore, in the hairdressing agent composition of the present invention, the above-described configuration makes it possible to gather the hair together to form a hair bundle and to make the hair bundle well-assembled.

　本発明の整髪剤組成物は、さらに、ポリオキシプロピレンソルビットを含むことが好ましい。
The hair styling composition of the present invention preferably further comprises a polyoxypropylene sorbite.

　本明細書においては、上記「ポリオキシプロピレンソルビット」を「成分（Ｅ）」と称する場合がある。
In the present specification, the above-mentioned "polyoxypropylene sorbite" may be referred to as "component (E)".

　上記のように、本発明の整髪剤組成物は、成分（Ａ）と成分（Ｂ）と成分（Ｃ）と成分（Ｄ）とを少なくとも含む。本発明の整髪剤組成物は、さらに、成分（Ｅ）を含んでいてもよい。
As described above, the hairdressing composition of the present invention comprises at least the components (A), (B), (C) and (D). The hair styling composition of the present invention may further contain component (E).

　本発明の整髪剤組成物は、成分（Ａ）～（Ｅ）以外の他の成分を含んでいてもよい。
The hair styling composition of the present invention may contain other components other than the components (A) to (E).

　上記の成分、例えば、成分（Ａ）、成分（Ｂ）、成分（Ｃ）、成分（Ｄ）、成分（Ｅ）や、他の成分は、それぞれ、１種のみが用いられてもよく、２種以上が併用されてもよい。
The above components, for example, component (A), component (B), component (C), component (D), component (E) and other components may be used alone or in combination of two or more. More than one species may be used in combination.

　以下、本発明の整髪剤組成物に用いられる各成分の詳細を説明する。
Hereinafter, the detail of each component used for the hair-dressing agent composition of this invention is demonstrated.

　（成分（Ａ））

　成分（Ａ）は、オキシエチレン基の平均付加モル数が２０以上、５０以下であり、かつ炭素数が１６以上、２２以下のアルキル基を有するポリオキシエチレンアルキルエーテルである。成分（Ａ）は、主として、グリース状の性状を形成する主成分である。成分（Ａ）によってグリース状の性状とすることができるのは、成分（Ａ）が水とヘキサゴナル液晶を形成し、流動性のない又は極めて低い強固なゲルを形成するためであると推察されるが、理由はこれに限定されない。成分（Ａ）により、本発明の整髪剤組成物の性状が硬くなり、毛髪をまとめて毛束を形成しやすくなり、毛束のまとまりを良好にすることができる。また、成分（Ａ）はべたつきが少ないため、整髪剤組成物のべたつきを抑える効果も有する。成分（Ａ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。
(Component (A))

The component (A) is a polyoxyethylene alkyl ether having an alkyl group having an average addition mole number of oxyethylene group of 20 or more and 50 or less and a carbon number of 16 or more and 22 or less. Component (A) is mainly a main component that forms a grease-like property. The grease-like property can be obtained by the component (A) because the component (A) forms water and hexagonal liquid crystal and is presumed to form a non-flowable or extremely low-hard gel. However, the reason is not limited to this. By the component (A), the properties of the hair styling composition of the present invention become hard, it becomes easy to form the hair bundle by putting together the hair, and it is possible to make the hair bundle well-organized. Moreover, since the component (A) is less sticky, it also has the effect of suppressing the stickiness of the hair styling composition. As the component (A), only one type may be used, or two or more types may be used in combination.

　成分（Ａ）のオキシエチレン基の平均付加モル数は、２０以上、５０以下である。グリース状の整髪剤組成物の形成性を効果的に高め、かつ、高温安定性を高める観点から、成分（Ａ）のオキシエチレン基の平均付加モル数は、好ましくは４０以下である。
The average added mole number of the oxyethylene group of the component (A) is 20 or more and 50 or less. The average addition mole number of the oxyethylene group of the component (A) is preferably 40 or less, from the viewpoint of effectively enhancing the formability of the grease-like hair styling composition and enhancing the high temperature stability.

　成分（Ａ）は、炭素数が１６以上、２２以下のアルキル基を有する。上記アルキル基としては、例えば、ステアリル基、セチル基、及びベヘニル基等が挙げられる。グリース状の整髪剤組成物の形成性を効果的に高める整髪力を効果的に高める観点から、上記アルキル基は、ステアリル基、セチル基、又はベヘニル基であることが好ましく、セチル基であることがより好ましい。
Component (A) has an alkyl group having 16 or more and 22 or less carbon atoms. As said alkyl group, a stearyl group, a cetyl group, and a behenyl group etc. are mentioned, for example. The alkyl group is preferably a stearyl group, a cetyl group or a behenyl group from the viewpoint of effectively enhancing the hair setting ability to effectively form the grease-like hair setting composition, and the alkyl group is preferably a cetyl group. Is more preferred.

　グリース状の整髪剤組成物の形成性をより一層効果的に高める観点から、成分（Ａ）は、オキシエチレン基の平均付加モル数が２０以上、５０以下であるポリオキシエチレンステアリルエーテル、オキシエチレン基の平均付加モル数が２０以上、５０以下であるポリオキシエチレンベヘニルエーテル、及びオキシエチレン基の平均付加モル数が３０以上、５０以下であるポリオキシエチレンセチルエーテルからなる群より選ばれるポリオキシエチレンアルキルエーテル（少なくとも１のポリオキシエチレンアルキルエーテル）を含むことが好ましい。
Component (A) is a polyoxyethylene stearyl ether having an average addition mole number of an oxyethylene group of 20 or more and 50 or less, from the viewpoint of more effectively forming the grease-like hair styling composition, and oxyethylene A polyoxyethylene selected from the group consisting of polyoxyethylene behenyl ether having an average addition mole number of groups of 20 or more and 50 or less, and polyoxyethylene cetyl ether having an average addition mole number of oxyethylene groups of 30 or more and 50 or less It is preferred to include ethylene alkyl ether (at least one polyoxyethylene alkyl ether).

　本明細書においては、上記「オキシエチレン基の平均付加モル数が２０以上、５０以下であるポリオキシエチレンステアリルエーテル、オキシエチレン基の平均付加モル数が２０以上、５０以下であるポリオキシエチレンベヘニルエーテル、及びオキシエチレン基の平均付加モル数が３０以上、５０以下であるポリオキシエチレンセチルエーテルからなる群より選ばれるポリオキシエチレンアルキルエーテル」を「成分（Ａ１）」と称する場合がある。すなわち、成分（Ａ）は、成分（Ａ１）を含むことが好ましい。本発明の整髪剤組成物は、成分（Ａ１）を含むことが好ましい。
In the present specification, the above-mentioned “polyoxyethylene stearyl ether having an average addition mole number of oxyethylene group of 20 or more and 50 or less, and polyoxyethylene behenyl having an average addition mole number of oxyethylene group of 20 or more and 50 or less The polyoxyethylene alkyl ether selected from the group consisting of ether and polyoxyethylene cetyl ether in which the average addition mole number of the oxyethylene group is 30 or more and 50 or less may be referred to as "component (A1)". That is, component (A) preferably contains component (A1). The hair styling composition of the present invention preferably comprises the component (A1).

　成分（Ａ１）は、１種のみが用いられてもよく、２種以上が併用されてもよい。
As the component (A1), only one type may be used, or two or more types may be used in combination.

　成分（Ａ１）の内、上記ポリオキシエチレンステアリルエーテルのオキシエチレン基の平均付加モル数は、好ましくは２０以上、好ましくは５０以下である。
Among the components (A1), the average added mole number of the oxyethylene group of the polyoxyethylene stearyl ether is preferably 20 or more, and preferably 50 or less.

　成分（Ａ１）の内、上記ポリオキシエチレンベヘニルエーテルのオキシエチレン基の平均付加モル数は、好ましくは３０以下である。
Among the components (A1), the average added mole number of the oxyethylene group of the polyoxyethylene behenyl ether is preferably 30 or less.

　成分（Ａ１）の内、上記ポリオキシエチレンセチルエーテルのオキシエチレン基の平均付加モル数は、好ましくは４５以下、より好ましくは４０以下である。
Among the components (A1), the average addition mole number of the oxyethylene group of the polyoxyethylene cetyl ether is preferably 45 or less, more preferably 40 or less.

　本発明の整髪剤組成物１００質量％中、成分（Ａ）の含有量は、３０．０質量％以上、好ましくは３５．０質量％以上であり、４５．０質量％以下、好ましくは４０．０質量％以下である。本発明では、成分（Ａ）の含有量が上記下限以上であるので、整髪剤組成物を適度に硬くし、グリース状の性状とすることができ、毛束のまとまりを良好にすることできる。また、本発明では、成分（Ａ）の含有量が上記下限以上であるので、高温下での性状の安定性を効果的に高めることができる。本発明では、成分（Ａ）の含有量が上記上限以下であるので、整髪剤組成物中で成分（Ａ）を均一に溶解することができる。整髪剤組成物１００質量％中、成分（Ａ）の含有量が３０．０質量％未満であると、整髪剤組成物を高温下で保管したとき、整髪剤組成物の一部が液状化しやすくなる。成分（Ａ）の含有量は、本発明の整髪剤組成物中の全ての成分（Ａ）の含有量の合計である。
In 100% by mass of the hairdressing agent composition of the present invention, the content of the component (A) is 30.0% by mass or more, preferably 35.0% by mass or more, and 45.0% by mass or less, preferably 40. It is 0 mass% or less. In the present invention, since the content of the component (A) is equal to or more than the above lower limit, the hair styling composition can be appropriately hardened to have a grease-like property, and the hair bundle can be well consolidated. Further, in the present invention, since the content of the component (A) is equal to or more than the above lower limit, stability of properties at high temperature can be effectively enhanced. In the present invention, since the content of the component (A) is not more than the above upper limit, the component (A) can be uniformly dissolved in the hair styling composition. When the content of the component (A) is less than 30.0% by mass in 100% by mass of the hairdressing agent composition, when the hairdressing composition is stored under high temperature, part of the hairdressing agent composition is easily liquefied Become. The content of component (A) is the sum of the content of all components (A) in the hair styling composition of the present invention.

　成分（Ａ）１００質量％中、成分（Ａ１）の含有量は、好ましくは９５質量％以上、より好ましくは９８質量％以上、最も好ましくは１００質量％である。したがって、成分（Ａ）の全体が、成分（Ａ１）であることが、最も好ましい。上記成分（Ａ１）の含有量は、本発明の整髪剤組成物中の全ての成分（Ａ）の含有量の合計に対する、全ての成分（Ａ１）の含有量の合計の割合である。
The content of the component (A1) is preferably 95% by mass or more, more preferably 98% by mass or more, and most preferably 100% by mass in 100% by mass of the component (A). Therefore, it is most preferable that the whole of component (A) is component (A1). The content of the component (A1) is a ratio of the total content of all the components (A1) to the total content of all the components (A) in the hair styling composition of the present invention.

　（成分（Ｂ））

　成分（Ｂ）は、重量平均分子量が３００００以上、１５００００以下であり、かつ必須のモノマー成分として、（メタ）アクリル酸アルキルエステルを用いて得られる皮膜形成ポリマーである。成分（Ｂ）は、整髪された毛髪の耐湿性を高める成分である。成分（Ｂ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。
(Component (B))

Component (B) is a film-forming polymer obtained by using (meth) acrylic acid alkyl ester as an essential monomer component having a weight average molecular weight of 30,000 or more and 150,000 or less. The component (B) is a component that improves the moisture resistance of the trimmed hair. As the component (B), only one type may be used, or two or more types may be used in combination.

　整髪された毛髪の耐湿性をより一層効果的に高める観点から、成分（Ｂ）は、アクリル酸アルキルコポリマーＡＭＰ、（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ、（アクリレーツ／アクリル酸アルキル（Ｃ１－１８）／アルキル（Ｃ１－８）アクリルアミド）コポリマーＡＭＰ、（アクリル酸アルキル・オクチルアクリルアミド）コポリマー、（メタクリロイルオキシエチルカルボキシベタイン／メタクリル酸アルキル）コポリマー、及び（オクチルアクリルアミド／アクリル酸ヒドロキシプロピル／メタクリル酸ブチルアミノエチル）コポリマーからなる群より選ばれる皮膜形成ポリマー（少なくとも１の皮膜形成ポリマー）を含むことが好ましい。
From the viewpoint of more effectively improving the moisture resistance of hair after hair setting, component (B) is an alkyl acrylate copolymer AMP, (alkyl acrylate / diacetone acrylamide) copolymer AMP, (acreates / alkyl acrylate (C1-) 18) / alkyl (C1-8) acrylamide) copolymer AMP, (alkyl acrylate octyl acrylamide) copolymer, (methacryloyloxyethyl carboxybetaine / alkyl methacrylate) copolymer, and (octyl acrylamide / hydroxypropyl acrylate / butyl methacrylate) It is preferred to include a film-forming polymer (at least one film-forming polymer) selected from the group consisting of aminoethyl) copolymers.

　本明細書においては、上記「アクリル酸アルキルコポリマーＡＭＰ、（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ、（アクリレーツ／アクリル酸アルキル（Ｃ１－１８）／アルキル（Ｃ１－８）アクリルアミド）コポリマーＡＭＰ、（アクリル酸アルキル・オクチルアクリルアミド）コポリマー、（メタクリロイルオキシエチルカルボキシベタイン／メタクリル酸アルキル）コポリマー、及び（オクチルアクリルアミド／アクリル酸ヒドロキシプロピル／メタクリル酸ブチルアミノエチル）コポリマーからなる群より選ばれる皮膜形成ポリマー」を「成分（Ｂ１）」と称する場合がある。すなわち、成分（Ｂ）は、成分（Ｂ１）を含むことが好ましい。本発明の整髪剤組成物は、成分（Ｂ１）を含むことが好ましい。
In the present specification, the above “alkyl acrylate copolymer AMP, (alkyl acrylate / diacetone acrylamide) copolymer AMP, (acrylate / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP, ( A film-forming polymer selected from the group consisting of alkyl acrylate octyl acrylamide) copolymer, (methacryloyloxyethyl carboxy betaine / alkyl methacrylate) copolymer, and (octyl acrylamide / hydroxypropyl acrylate / butyl aminoethyl methacrylate) copolymer It may be called "component (B1)." That is, the component (B) preferably contains the component (B1). The hairdressing composition of the present invention preferably comprises the component (B1).

　成分（Ｂ１）は、１種のみが用いられてもよく、２種以上が併用されてもよい。
As the component (B1), only one type may be used, or two or more types may be used in combination.

　成分（Ｂ）の重量平均分子量は、３００００以上、好ましくは５００００以上であり、１５００００以下、好ましくは１０００００以下である。本発明では、成分（Ｂ）の重量平均分子量が上記下限以上であるので、整髪された毛髪の耐湿性をより一層高めることができる。また、本発明では、成分（Ｂ）の重量平均分子量が上記上限以下であるので、性状の安定性（特に高温下での性状の安定性）を高めることができる。
The weight average molecular weight of the component (B) is 30,000 or more, preferably 50,000 or more, and 150,000 or less, preferably 100,000 or less. In the present invention, since the weight average molecular weight of the component (B) is equal to or more than the above lower limit, the moisture resistance of the trimmed hair can be further enhanced. Further, in the present invention, since the weight average molecular weight of the component (B) is not more than the above upper limit, stability of properties (particularly stability of properties at high temperature) can be enhanced.

　成分（Ｂ１）の重量平均分子量は、３００００以上、好ましくは５００００以上であり、１５００００以下、好ましくは１０００００以下である。本発明では、成分（Ｂ１）の重量平均分子量が上記下限以上であるので、整髪された毛髪の耐湿性をより一層高めることができる。また、本発明では、成分（Ｂ１）の重量平均分子量が上記上限以下であるので、性状の安定性（特に高温下での性状の安定性）を高めることができる。
The weight average molecular weight of the component (B1) is 30,000 or more, preferably 50,000 or more, and 150,000 or less, preferably 100,000 or less. In the present invention, since the weight average molecular weight of the component (B1) is not less than the above lower limit, it is possible to further improve the moisture resistance of the trimmed hair. Further, in the present invention, since the weight average molecular weight of the component (B1) is not more than the above upper limit, stability of properties (especially stability of properties at high temperature) can be enhanced.

　成分（Ｂ）の市販品としては、例えば、商品名「プラスサイズＬ－９５４０ＵＷ」（（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ、互応化学社製）、及び商品名「プラスサイズＬ－６４６６」（（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ、互応化学社製）等が挙げられる。
As a commercial item of component (B), for example, trade name "plus size L-9540 UW" ((alkyl acrylate / diacetone acrylamide) copolymer AMP, manufactured by HAZUKO CHEMICAL Co., Ltd.), and trade name "plus size L-6466" ((Acrylate alkyl / diacetone acrylamide) copolymer AMP, manufactured by Yuka Chemical Co., Ltd.) and the like.

　本発明の整髪剤組成物１００質量％中、成分（Ｂ）の含有量は、０．１質量％以上、好ましくは１．０質量％以上である。本発明では、成分（Ｂ）の含有量が上記下限以上であるので、整髪された毛髪の耐湿性を高めることができる。成分（Ｂ）の含有量は、本発明の整髪剤組成物中の全ての成分（Ｂ）の含有量の合計である。
In 100% by mass of the hairdressing agent composition of the present invention, the content of the component (B) is 0.1% by mass or more, preferably 1.0% by mass or more. In the present invention, since the content of the component (B) is not less than the above lower limit, the moisture resistance of the trimmed hair can be enhanced. The content of component (B) is the sum of the content of all components (B) in the hair styling composition of the present invention.

　成分（Ｂ）１００質量％中、成分（Ｂ１）の含有量は、好ましくは９５質量％以上、より好ましくは９８質量％以上、最も好ましくは１００質量％である。したがって、成分（Ｂ）の全体が、成分（Ｂ１）であることが、最も好ましい。上記成分（Ｂ１）の含有量は、本発明の整髪剤組成物中の全ての成分（Ｂ）の含有量の合計に対する、全ての成分（Ｂ１）の含有量の合計の割合である。
The content of the component (B1) is preferably 95% by mass or more, more preferably 98% by mass or more, and most preferably 100% by mass in 100% by mass of the component (B). Therefore, it is most preferable that the whole of component (B) is component (B1). The content of the component (B1) is a ratio of the total content of all the components (B1) to the total content of all the components (B) in the hair styling composition of the present invention.

　高温下での性状の安定性（高温安定性）を高める観点から、成分（Ａ）の含有量の成分（Ｂ）の含有量に対する質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）は５．０以上である。上記質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）が５．０未満であると、高温安定性が低下する。これは、成分（Ｂ）により、成分（Ａ）と水とで形成されたヘキサゴナル液晶構造が崩れるためであると推察される。本発明では、上記質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）が５．０以上であるので、グリース状の性状を維持しつつ、耐湿性を高めることができる。高温安定性をより一層高める観点からは、上記質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）は、好ましくは７．０以上である。
From the viewpoint of enhancing the stability of properties at high temperature (high temperature stability), the mass ratio of the content of component (A) to the content of component (B) (content of component (A) / component (B) The content is 5.0 or more. High temperature stability falls that the said mass ratio (content of component (A) / content of component (B)) is less than 5.0. It is presumed that this is because the hexagonal liquid crystal structure formed by the component (A) and water is broken by the component (B). In the present invention, since the mass ratio (content of component (A) / content of component (B)) is 5.0 or more, the moisture resistance can be enhanced while maintaining the grease-like property. From the viewpoint of further enhancing high-temperature stability, the mass ratio (content of component (A) / content of component (B)) is preferably 7.0 or more.

　（成分（Ｃ））

　成分（Ｃ）は、ポリオキシエチレン硬化ヒマシ油である。成分（Ａ）により形成されたグリース状の整髪剤組成物において、成分（Ｃ）を用いることにより、毛髪同士をまとめ毛束を良好に形成することができ、毛束のまとまりを良好にすることができる。整髪剤組成物が成分（Ｃ）を含まない場合には、毛束を良好に形成できず、毛髪同士がばらけやすくなる。本発明の整髪剤組成物は、成分（Ｃ）を含むので、毛髪同士を効果的にまとめることができ、毛束のまとまりを良好にすることができる。成分（Ｃ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。
(Component (C))

Component (C) is polyoxyethylene hydrogenated castor oil. In the grease-like hairdressing agent composition formed of the component (A), by using the component (C), it is possible to gather the hairs together and form a hair bundle well, and to make the hair bundle cohesive well. Can. In the case where the hair styling composition does not contain the component (C), the hair bundle can not be formed well, and the hairs are easily separated. The hairdressing agent composition of the present invention contains the component (C), so that the hairs can be effectively combined, and the hair bundle can be well organized. As the component (C), only one type may be used, or two or more types may be used in combination.

　毛髪同士をより一層効果的にまとめ、毛束のまとまりを一層良好にする観点から、成分（Ｃ）のオキシエチレン基の平均付加モル数は、好ましくは３０以上、より好ましくは４０以上、好ましくは１００以下、より好ましくは６０以下である。
The average addition mole number of the oxyethylene group of the component (C) is preferably 30 or more, more preferably 40 or more, preferably 40 or more, from the viewpoint of more effectively organizing the hairs and further improving the hair bundle cohesion. It is 100 or less, more preferably 60 or less.

　本発明の整髪剤組成物１００質量％中、成分（Ｃ）の含有量は、０．１質量％以上、好ましくは１．０質量％以上であり、５．０質量％以下、好ましくは３．０質量％以下である。本発明では、成分（Ｃ）の含有量が上記下限以上であるので、毛髪同士をより一層効果的にまとめ、毛束のまとまりを良好にすることができる。本発明では、成分（Ｃ）の含有量が上記上限以下であるので、べたつきを少なくし、高温下での性状の安定性をより一層効果的に高めることができる。整髪剤組成物１００質量％中、成分（Ｃ）の含有量が５．０質量％を超えると、整髪剤組成物を高温下で保管したとき、整髪剤組成物の一部が液状化しやすくなる。成分（Ｃ）の含有量は、本発明の整髪剤組成物中の全ての成分（Ｃ）の含有量の合計である。
In 100% by mass of the hairdressing composition of the present invention, the content of the component (C) is 0.1% by mass or more, preferably 1.0% by mass or more, and 5.0% by mass or less, preferably 3. It is 0 mass% or less. In the present invention, since the content of the component (C) is equal to or more than the above lower limit, the hairs can be combined more effectively to make the hair bundle cohesive. In the present invention, since the content of the component (C) is less than or equal to the above upper limit, stickiness can be reduced and stability of properties at high temperatures can be more effectively enhanced. When the content of the component (C) exceeds 5.0% by mass in 100% by mass of the hairdressing agent composition, when the hairdressing composition is stored under high temperature, part of the hairdressing composition tends to be liquefied. . The content of component (C) is the sum of the content of all components (C) in the hair styling composition of the present invention.

　（成分（Ｄ））

　成分（Ｄ）は、水である。水を用いることにより、水性のグリース状の整髪剤組成物を形成でき、べたつきを低減できる。また、水を用いることにより、グリース状の整髪剤組成物の調製が容易になる。
(Component (D))

Component (D) is water. By using water, an aqueous grease-like hair styling composition can be formed, and stickiness can be reduced. In addition, the use of water facilitates the preparation of a grease-like hair styling composition.

　成分（Ｄ）の含有量は、他の配合成分の含有量によって、適宜調整することができる。グリース状の整髪剤組成物の形成性を効果的に高める観点から、本発明の整髪剤組成物１００質量％中、成分（Ｄ）の含有量は、好ましくは３０．０質量％以上、より好ましくは４０．０質量％以上、更に好ましくは５０．０質量％以上、好ましくは６９．０質量％以下、より好ましくは６５．０質量％以下である。
The content of the component (D) can be appropriately adjusted by the content of other compounding components. From the viewpoint of effectively enhancing the formability of the grease-like hairdressing agent composition, the content of the component (D) is preferably 30.0% by mass or more, more preferably 100% by mass of the hairdressing agent composition of the present invention Is 40.0% by mass or more, more preferably 50.0% by mass or more, preferably 69.0% by mass or less, and more preferably 65.0% by mass or less.

　（成分（Ｅ））

　成分（Ｅ）は、ポリオキシプロピレンソルビットである。成分（Ｅ）を用いることにより、毛髪同士をより一層効果的にまとめ、毛束のまとまりを良好にすることができる。
(Component (E))

Component (E) is a polyoxypropylene sorbite. By using the component (E), it is possible to more effectively organize the hairs and to improve the hair bundle aggregation.

　成分（Ｅ）は、１種のみが用いられてもよく、２種以上が併用されてもよい。
As the component (E), only one type may be used, or two or more types may be used in combination.

　成分（Ｅ）の数平均分子量は、特に限定されない。毛髪同士をより一層効果的にまとめ、毛束のまとまりを良好にする観点から、成分（Ｅ）の数平均分子量は、好ましくは３００以上、より好ましくは４００以上、好ましくは１０００以下、より好ましくは８００以下である。
The number average molecular weight of the component (E) is not particularly limited. The number average molecular weight of the component (E) is preferably 300 or more, more preferably 400 or more, preferably 1000 or less, more preferably from the viewpoint of bringing hairs together more effectively and improving hair bundle cohesion. It is 800 or less.

　本発明の整髪剤組成物１００質量％中、成分（Ｅ）の含有量は、好ましくは０．１質量％以上、より好ましくは１．０質量％以上であり、好ましくは５．０質量％以下、より好ましくは３．０質量％以下である。成分（Ｅ）の含有量が上記下限以上であると、毛髪同士をより一層効果的にまとめ、毛束のまとまりを良好にすることができる。成分（Ｅ）の含有量が上記上限以下であると、べたつきを少なくし、高温下での性状の安定性をより一層効果的に高めることができる。成分（Ｅ）の含有量は、本発明の整髪剤組成物中の全ての成分（Ｅ）の含有量の合計である。
The content of the component (E) is preferably 0.1% by mass or more, more preferably 1.0% by mass or more, and preferably 5.0% by mass or less in 100% by mass of the hairdressing agent composition of the present invention And more preferably 3.0% by mass or less. When the content of the component (E) is equal to or more than the above lower limit, the hairs can be combined more effectively, and the bundle of hair bundles can be made favorable. When the content of the component (E) is less than or equal to the above upper limit, stickiness can be reduced and stability of properties at high temperature can be more effectively enhanced. The content of component (E) is the sum of the content of all components (E) in the hair styling composition of the present invention.

　（他の成分）

　さらに、本発明の整髪剤組成物は、上述した成分（Ａ）～（Ｅ）以外の成分を含んでいてもよい。成分（Ａ）～（Ｅ）以外の成分としては、特に限定されないが、例えば、エタノール等の炭素数２～５の低級アルコール；グリセリン、ジグリセリン、１，３－ブチレングリコール、プロピレングリコール、ジプロピレングリコール、１，２－ブタンジオール、１，２－ペンタンジオール、１，２－ヘキサンジオール、１，２－オクタンジオール、１，２－デカンジオール、ポリオキシプロピレンメチルグルコシド等の多価アルコール；ソルビトール、マルチトール及びトレハロース等の糖アルコール；ラウリルアルコール、ミリスチルアルコール、セチルアルコール、ステアリルアルコール、イソステアリルアルコール、セトステアリルアルコール、オレイルアルコール等の炭素数１２～１８の高級アルコール；パルミチン酸イソプロピル、トリ２－エチルヘキサン酸グリセリル、ミリスチン酸イソプロピル、モノステアリン酸プロピレングリコール、モノラウリン酸プロピレングリコール、イソステアリン酸ポリグリセリル等のエステル油；流動パラフィン、ワセリン、スクワレン、スクワラン等の炭化水素油；オリーブ油、ツバキ油、マカデミアナッツ油、アボカド油等の油脂；カルナバロウ、キャンデリラロウ、ミツロウ、ラノリン等のロウ；シリコーン油；ノニオン界面活性剤、カチオン界面活性剤、アニオン界面活性剤、両性界面活性剤等の界面活性剤；金属イオン封鎖剤；酸化防止剤；植物抽出エキス；染料；顔料；ｐＨ調整剤；香料；防腐剤；溶剤等が挙げられる。成分（Ａ）～（Ｅ）以外の成分は、１種のみが用いられてもよく、２種以上が併用されてもよい。
(Other ingredients)

Furthermore, the hairdressing composition of the present invention may contain components other than the components (A) to (E) described above. The components other than the components (A) to (E) are not particularly limited. For example, lower alcohols having 2 to 5 carbon atoms such as ethanol; glycerin, diglycerin, 1,3-butylene glycol, propylene glycol, dipropylene Polyhydric alcohols such as glycol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol, 1,2-decanediol and polyoxypropylene methyl glucoside; sorbitol, Sugar alcohols such as maltitol and trehalose; higher alcohols having 12 to 18 carbon atoms such as lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, isostearyl alcohol, cetostearyl alcohol, oleyl alcohol; isopropyl palmitate Ester oils such as glyceryl tri-2-ethylhexanoate, isopropyl myristate, propylene glycol monostearate, propylene glycol monolaurate, polyglyceryl isostearate; hydrocarbon oils such as liquid paraffin, vaseline, squalene, squalane; olive oil, camellia oil, Fats and oils such as macadamia nut oil and avocado oil; waxes such as carnauba wax, candelilla wax, beeswax and lanolin; silicone oils; surfactants such as nonionic surfactants, cationic surfactants, anionic surfactants and amphoteric surfactants; Sequestering agents; antioxidants; plant extracts; dyes; pigments; pH adjusters; perfumes; preservatives; The components other than the components (A) to (E) may be used alone or in combination of two or more.

　本発明の整髪剤組成物は、製剤安定性を高める観点から、エタノールを含まないか、又はエタノールを７．０質量％未満で含むことが好ましい。本発明の整髪剤組成物がエタノールを含む場合に、本発明の整髪剤組成物１００質量％中、エタノールの含有量は、好ましくは５．０質量％未満、より好ましくは１．０質量％未満である。

が挙げられる。
The hairdressing composition of the present invention preferably contains no ethanol or less than 7.0% by mass of ethanol, from the viewpoint of enhancing formulation stability. When 100% by mass of the hair styling composition according to the present invention contains ethanol, the content of ethanol is preferably less than 5.0% by mass, more preferably less than 1.0% by mass. It is.

Can be mentioned.

　（整髪剤組成物の他の詳細）

　本発明の整髪剤組成物の性状は、特に限定されないが、取扱い性を高める観点から、グリース状であることが好ましい。本発明の整髪剤組成物は、グリース状整髪剤組成物であることが好ましい。上記グリース状整髪剤組成物としては、例えば、ヘアグリース、ウォーターグリース、水性ポマード等と称される組成物などが挙げられる。
(Other details of hair care composition)

The properties of the hair styling composition of the present invention are not particularly limited, but from the viewpoint of enhancing the handleability, it is preferably in the form of grease. The hair styling composition of the present invention is preferably a grease-like hair styling composition. Examples of the above-mentioned grease-like hairdressing composition include compositions referred to as hair grease, water grease, aqueous pomade and the like.

　本発明の整髪剤組成物の製造方法としては、特に限定されないが、公知の整髪剤組成物の製造方法を採用することができる。本発明の整髪剤組成物の製造方法としては、例えば、各成分をパドルミキサー等で撹拌して均一化する方法等が挙げられる。
Although it does not specifically limit as a manufacturing method of the hair-dressing agent composition of this invention, The manufacturing method of a well-known hair-dressing agent composition is employable. As a manufacturing method of the hair-dressing agent composition of this invention, the method of stirring each component with a paddle mixer etc. and homogenizing etc. are mentioned, for example.

　本発明の整髪剤組成物は、特に限定されないが、例えば、容器に充填された形態で用いることができる。本発明の整髪剤組成物がグリース状整髪剤組成物である場合には、上記容器は、ジャー容器であることが好ましい。
The hair styling composition of the present invention is not particularly limited, and can be used, for example, in the form of being filled in a container. When the hair styling composition of the present invention is a grease-like hair styling composition, the container is preferably a jar container.

　取扱い性をより一層高める観点からは、本発明の整髪剤組成物の２５℃での稠度は、好ましくは５０ｇｆ以上、より好ましくは７０ｇｆ以上であり、好ましくは８００ｇｆ以下、より好ましくは６００ｇｆ以下である。上記稠度は、１０φ球型アダプターを備える稠度計を用いて、２５℃、スピード６０ｍｍ／分、ストローク２０ｍｍの条件で測定することができる。稠度計としては、サン科学社製「ＲＨＥＯ　ＭＥＴＥＲ」等が挙げられる。
From the viewpoint of further improving the handleability, the consistency at 25 ° C. of the hairdressing agent composition of the present invention is preferably 50 gf or more, more preferably 70 gf or more, preferably 800 gf or less, more preferably 600 gf or less . The above-mentioned consistency can be measured under conditions of 25 ° C., speed 60 mm / min, and stroke 20 mm using a consistency meter equipped with a 10φ spherical adapter. Examples of the consistency meter include "RHEO METER" manufactured by Sun Scientific Co., Ltd.

　以下、本発明について、実施例及び比較例を挙げて具体的に説明する。本発明は、以下の実施例のみに限定されない。
Hereinafter, the present invention will be specifically described by way of examples and comparative examples. The invention is not limited to the following examples.

　（試験例）

　本発明の整髪剤組成物では、成分（Ａ）の含有量の成分（Ｂ）の含有量に対する質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）は５．０以上である。また、高温安定性をより一層高める観点からは、上記質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）は、好ましくは７．０以上である。
(Test example)

In the hair styling composition of the present invention, the mass ratio of the content of the component (A) to the content of the component (B) (the content of the component (A) / the content of the component (B)) is 5.0 or more is there. Further, from the viewpoint of further enhancing the high temperature stability, the mass ratio (content of component (A) / content of component (B)) is preferably 7.0 or more.

　本発明の整髪剤組成物１００質量％中、成分（Ａ）の含有量は、３０．０質量％以上、４５．０質量％以下である。整髪剤組成物１００質量％中、成分（Ａ）の含有量が３０．０質量％未満であると、整髪剤組成物を高温下で保管したとき、整髪剤組成物の一部が液状化しやすくなる。
Content of a component (A) is 30.0 mass% or more and 45.0 mass% or less in 100 mass% of hair styling agent compositions of this invention. When the content of the component (A) is less than 30.0% by mass in 100% by mass of the hairdressing agent composition, when the hairdressing composition is stored under high temperature, part of the hairdressing agent composition is easily liquefied Become.

　上記質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）、及び成分（Ａ）の含有量が高温安定性に与える影響を、以下の試験例により確認した。
The influence of the above mass ratio (content of component (A) / content of component (B)) and content of component (A) on high temperature stability was confirmed by the following test examples.

　試験例では、下記の成分を用いた。
The following components were used in the test example.

　（成分（Ａ））

　ポリオキシエチレンセチルエーテル（４０Ｅ．Ｏ．）：オキシエチレン基の平均付加モル数４０、アルキル基の炭素数１６
(Component (A))

Polyoxyethylene cetyl ether (40 E. O.): average addition mole number of oxyethylene group 40, carbon number of alkyl group 16

　（成分（Ｂ））

　（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ：商品名「プラスサイズＬ－９５４０ＵＷ」、互応化学社製、（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ、重量平均分子量１１００００
(Component (B))

(Alkyl acrylate / diacetone acrylamide) copolymer AMP: trade name “plus size L-9540 UW”, manufactured by HAKURA CHEMICAL CO., LTD. (Alkyl acrylate / diacetone acrylamide) copolymer AMP, weight average molecular weight 110000

　（成分（Ｃ））

　ポリオキシエチレン硬化ヒマシ油（５０Ｅ．Ｏ．）：オキシエチレン基の平均付加モル数５０
(Component (C))

Polyoxyethylene hydrogenated castor oil (50E.O.): average addition mole number of oxyethylene group 50

　（成分（Ｄ））

　精製水
(Component (D))

purified water

　（成分（Ｅ））

　ポリオキシプロピレンソルビット：商品名「サンニックスＳＰ－７５０」、三洋化成工業社製、数平均分子量７５０
(Component (E))

Polyoxypropylene Sorbit: Brand name "Sannicks SP-750", Sanyo Chemical Industries, Ltd., number average molecular weight 750

　下記の表１、２に示す配合成分を配合（配合単位は質量％）し、整髪剤組成物を調製した。表１、２中の配合量（整髪剤組成物１００質量％中の配合量）は、純分の配合量（単位：質量％）で示した。
The hair styling agent composition was prepared by blending the blending components shown in Tables 1 and 2 below (blending unit is% by mass). The compounding amount in Tables 1 and 2 (the compounding amount in 100% by mass of the hairdressing agent composition) was shown by the compounding amount (unit:% by mass) of the pure part.

　（評価）

　得られた整髪剤組成物について、高温安定性の評価を行った。評価結果は表１、２中に示した。
(Evaluation)

Evaluation of high temperature stability was performed about the obtained hair styling agent composition. The evaluation results are shown in Tables 1 and 2.

　（試験例：高温安定性）

　得られた整髪剤組成物を、５０℃の恒温槽中に１２時間保管し、保管後の性状（組成物の硬さ、透明性、析出の有無）を観察し、下記の基準で高温安定性を評価した。
(Test example: High temperature stability)

The obtained hair styling composition is stored in a thermostat at 50 ° C. for 12 hours, and the properties after storage (the hardness of the composition, the transparency, the presence or absence of precipitation) are observed, and the high temperature stability according to the following criteria Was evaluated.

　＜高温安定性の評価基準＞

　○（良好）：透明で流動性のないグリース状の性状であった

　×（不良）：一部または全体に液状化（流動化）、白濁、又は析出が見られた
<Evaluation criteria for high temperature stability>

○ (Good): Transparent and non-flowing grease-like property

X (poor): Liquefaction (fluidization), cloudiness, or precipitation was observed partially or entirely

　組成及び結果を下記の表１、２に示す。
The composition and the results are shown in Tables 1 and 2 below.

Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001

Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002

　なお、試験例５、９では、保管した整髪剤組成物に極めて僅かな流動性（長時間で僅かに変形する程度）が見られた。
In Test Examples 5 and 9, very little fluidity (a degree of slight deformation in a long time) was observed in the hair styling composition stored.

　試験例の評価結果より、（１）整髪剤組成物１００質量％中、成分（Ａ）の含有量が３０．０質量％未満であると、高温安定性に劣る傾向があること、（２）上記質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）が５．０未満であると、高温安定性に劣る傾向があること、（３）上記質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）が５．０以上であると、高温安定性に優れること、（４）上記質量比（成分（Ａ）の含有量／成分（Ｂ）の含有量）が７．０以上であると、高温安定性により一層優れることが確認された。
From the evaluation results of the test examples, (1) that the content of the component (A) is less than 30.0% by mass in 100% by mass of the hairdressing agent composition, the high temperature stability tends to be inferior, (2) If the mass ratio (content of component (A) / content of component (B)) is less than 5.0, high temperature stability tends to be poor, (3) the mass ratio (component (A)) It is excellent in high temperature stability that content / content of component (B) of 5.0 is 5.0 or more, (4) content of content of the above-mentioned mass ratio (component (A) / component (B) It was confirmed that the high temperature stability is further excellent in the case where it is 7.0 or more.

　（実施例及び比較例）

　実施例及び比較例で用いた主な成分は下記の通りである。
(Example and Comparative Example)

The main components used in Examples and Comparative Examples are as follows.

　（成分（Ａ））

　ポリオキシエチレンセチルエーテル（４０Ｅ．Ｏ．）：オキシエチレン基の平均付加モル数４０、アルキル基の炭素数１６

　ポリオキシエチレンセチルエーテル（３０Ｅ．Ｏ．）：オキシエチレン基の平均付加モル数３０、アルキル基の炭素数１６

　ポリオキシエチレンステアリルエーテル（２０Ｅ．Ｏ．）：オキシエチレン基の平均付加モル数２０、アルキル基の炭素数１８
(Component (A))

Polyoxyethylene cetyl ether (40 E. O.): average addition mole number of oxyethylene group 40, carbon number of alkyl group 16

Polyoxyethylene cetyl ether (30E.O.): average addition mole number of oxyethylene group, carbon number of alkyl group: 16

Polyoxyethylene stearyl ether (20E.O.): average addition mole number of oxyethylene group 20, carbon number of alkyl group 18

　（成分（Ａ）に相当しない成分）

　ポリオキシエチレンラウリルエーテル（３０Ｅ．Ｏ．）：オキシエチレン基の平均付加モル数３０、アルキル基の炭素数１２

　ポリオキシエチレンセチルエーテル（１０Ｅ．Ｏ．）：オキシエチレン基の平均付加モル数１０、アルキル基の炭素数１６
(Component not equivalent to component (A))

Polyoxyethylene lauryl ether (30E.O.): average addition mole number of oxyethylene group, 30 carbon atoms of alkyl group

Polyoxyethylene cetyl ether (10E.O.): average addition mole number of oxyethylene group 10, carbon number of alkyl group 16

　（成分（Ｂ））

　（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ（１）：商品名「プラスサイズＬ－９５４０ＵＷ」、互応化学社製、重量平均分子量１１００００

　（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ（２）：商品名「プラスサイズＬ－６４６６」、互応化学社製、重量平均分子量６２０００
(Component (B))

(Alkyl acrylate / diacetone acrylamide) copolymer AMP (1): trade name "Plus size L-9540 UW", manufactured by Hakken, weight average molecular weight 110000

(Alkyl acrylate / diacetone acrylamide) copolymer AMP (2): trade name "plus size L-6466", manufactured by HAKOTO CHEMICAL Co., Ltd., weight average molecular weight 62000

　（成分（Ｂ）に相当しない成分）

　（ジメチルアクリルアミド／アクリル酸ヒドロキシエチル／アクリル酸メトキシエチル）コポリマー：商品名「プラスサイズＬ－２７００」、互応化学社製、重量平均分子量１５０００

　アクリル酸アルキルコポリマー：商品名「Ｌｕｖｉｆｌｅｘ　ｓｏｆｔ」、ＢＡＳＦ社製、重量平均分子量５０００００

　ポリビニルピロリドン：商品名「ＰＶＰ　Ｋ－３０」、アイエスピー社製

　（ビニルピロリドン／ＶＡ）コポリマー：商品名「ＰＶＡ－６４５０」、大阪有機化学工業社製

　ポリクオタニウム－１１：商品名「Ｈ．Ｃ．ポリマー１Ｎ（Ｍ）」、大阪有機化学工業社製
(Component not equivalent to component (B))

(Dimethyl acrylamide / hydroxyethyl acrylate / methoxy ethyl acrylate) copolymer: trade name "plus size L-2700", manufactured by HAKOTO CHEMICAL Co., Ltd., weight average molecular weight 15,000

Alkyl acrylate copolymer: trade name "Luviflex soft", manufactured by BASF, weight average molecular weight 500000

Polyvinyl pyrrolidone: Brand name "PVP K-30", manufactured by ISP

(Vinyl pyrrolidone / VA) copolymer: trade name "PVA-6450", manufactured by Osaka Organic Chemical Industry Ltd.

Polyquaternium-11: trade name "HC polymer 1N (M)", manufactured by Osaka Organic Chemical Industry Co., Ltd.

　（成分（Ｃ））

　ポリオキシエチレン硬化ヒマシ油（５０Ｅ．Ｏ．）：オキシエチレン基の平均付加モル数５０
(Component (C))

Polyoxyethylene hydrogenated castor oil (50E.O.): average addition mole number of oxyethylene group 50

　（成分（Ｄ））

　精製水
(Component (D))

purified water

　（成分（Ｅ））

　ポリオキシプロピレンソルビット：商品名「サンニックスＳＰ－７５０」、三洋化成工業社製、数平均分子量７５０
(Component (E))

Polyoxypropylene Sorbit: Brand name "Sannicks SP-750", Sanyo Chemical Industries, Ltd., number average molecular weight 750

　（実施例１～１０及び比較例１～１３）

　下記の表３～５に示す配合成分を配合（配合単位は質量％）し、整髪剤組成物を調製した。表中の配合量（整髪剤組成物１００質量％中の配合量）は、純分の配合量（単位：質量％）で示した。
(Examples 1 to 10 and Comparative Examples 1 to 13)

Blending components shown in Tables 3 to 5 below were blended (blending unit is% by mass) to prepare a hair styling composition. The compounding amount in the table (the compounding amount in 100% by mass of the hairdressing agent composition) was shown by the compounding amount (unit: mass%) of the pure part.

　実施例１～１０で得られた整髪剤組成物の性状はいずれも透明かつグリース状であった。
The properties of the hair styling composition obtained in Examples 1 to 10 were all transparent and greasy.

　（評価）

　得られた整髪剤組成物について、以下の評価を行った。評価結果は表３～５中に示した。
(Evaluation)

The following evaluation was performed about the obtained hair styling agent composition. The evaluation results are shown in Tables 3 to 5.

　（試験例１：高温安定性）

　得られた整髪剤組成物を、５０℃の恒温槽中に１２時間保管し、保管後の性状（組成物の硬さ、透明性、析出の有無）を観察し、下記の基準で高温安定性を評価した。
(Test Example 1: High-Temperature Stability)

The obtained hair styling composition is stored in a thermostat at 50 ° C. for 12 hours, and the properties after storage (the hardness of the composition, the transparency, the presence or absence of precipitation) are observed, and the high temperature stability according to the following criteria Was evaluated.

　＜高温安定性の評価基準＞

　○（良好）：透明で流動性のないグリース状の性状であった

　×（不良）：一部または全体に液状化（流動化）、白濁、又は析出が見られた
<Evaluation criteria for high temperature stability>

○ (Good): Transparent and non-flowing grease-like property

X (poor): Liquefaction (fluidization), cloudiness, or precipitation was observed partially or entirely

　（試験例２：耐湿性）

　得られた整髪剤組成物２ｇを手にとり、ショートヘアのウィッグ（レッスンマネキン：ユーカリジャパン社製）の毛髪に均一に塗布し、毛髪全体を、後頭部方向にクシでなでつけて整髪を施した。
(Test Example 2: Moisture Resistance)

2 g of the hair styling composition obtained was taken and hand-applied uniformly to the hair of short hair wig (Lesson Mannequin: made by Eucalyptus Japan Co., Ltd.), and the entire hair was brushed with a comb in the back head direction to give a hair styling .

　整髪後のウィッグを高湿度条件（３５℃、８０％ＲＨ）に設定した恒温恒湿器に１時間静置（耐湿試験）した。静置前（耐湿試験前）および静置後（耐湿試験後）の毛髪を手で触り、毛髪の硬さを評価した。耐湿試験前後の毛髪の流れ（毛流れ）の方向を比較し、耐湿性を下記の基準で評価した。なお、比較例１～４、６、８～１１の整髪剤組成物は、試験を行わなかった。
The wig after hair setting was allowed to stand for 1 hour (humidity resistance test) in a thermo-hygrostat kept at high humidity conditions (35 ° C., 80% RH). The hair was touched with a hand before standing (before the moisture resistance test) and after standing (after the moisture resistance test) to evaluate the hardness of the hair. The directions of hair flow (hair flow) before and after the moisture resistance test were compared, and the moisture resistance was evaluated based on the following criteria. The hair styling compositions of Comparative Examples 1 to 4, 6 and 8 to 11 were not tested.

　＜耐湿性の評価基準＞

　○○（かなり良好）：耐湿試験前後で毛流れの方向がほとんど変わらない。

　○（良好）：耐湿試験前の毛流れの方向に比べて、耐湿試験後の毛流れの方向がやや下方に垂れている。

　×（不良）：耐湿試験前の毛流れの方向に比べて、耐湿試験後の毛流れの方向が明らかに下方を向いて垂れている。
<Evaluation criteria for moisture resistance>

○ (very good): The direction of hair flow hardly changes before and after the moisture resistance test.

○ (Good): The direction of hair flow after the moisture resistance test is slightly lower than that of the hair flow before the moisture resistance test.

X (poor): The direction of the hair flow after the moisture resistance test is clearly directed downward as compared with the direction of the hair flow before the moisture resistance test.

　なお、耐湿性がかなり良好であった場合は、耐湿試験前後で毛髪の硬さがほとんど変わっていなかった。耐湿性が良好の場合は、耐湿試験後の毛髪が耐湿試験前の毛髪と比べてやや軟らかくなっていた。耐湿性が不良の場合は、耐湿試験後の毛髪が耐湿試験前の毛髪と比べて明らかに軟らかくなっていた。
In addition, when the moisture resistance was very good, the hardness of the hair was hardly changed before and after the moisture resistance test. When the moisture resistance was good, the hair after the moisture resistance test was slightly softer than the hair before the moisture resistance test. When the moisture resistance was poor, the hair after the moisture resistance test was apparently softer than the hair before the moisture resistance test.

　（試験例３:毛束のまとまり）

　得られた整髪剤組成物２ｇを手にとり、ショートヘアのウィッグ（レッスンマネキン：ユーカリジャパン社製）の毛髪に均一に塗布し、毛髪全体を、後頭部方向にクシでなでつけて整髪を施した。整髪後のウィッグの下部を床に１０回打ち付けて、ウィッグに縦方向の振動を与えた後に、毛流れが維持されているか観察し、毛束のまとまりを下記の基準で評価した。なお、比較例１～４、６、８～１１の整髪剤組成物は、試験を行わなかった。
(Test Example 3: Hair bundle bundle)

2 g of the hair styling composition obtained was taken and hand-applied uniformly to the hair of short hair wig (Lesson Mannequin: made by Eucalyptus Japan Co., Ltd.), and the entire hair was brushed with a comb in the back head direction to give a hair styling . The lower part of the wig after hair setting was hit on the floor 10 times, and after giving a longitudinal vibration to the wig, it was observed whether or not the hair flow was maintained, and hair bundle aggregation was evaluated based on the following criteria. The hair styling compositions of Comparative Examples 1 to 4, 6 and 8 to 11 were not tested.

　＜毛束のまとまりの評価基準＞

　○○（かなり良好）：毛束がまとまっており、ばらけた毛束が認められない。

　○（良好）：わずかにばらけた毛束が認められる。

　×（不良）：ほとんどすべての毛束がばらけており、毛束が崩れている。
<Evaluation criteria for hair bundle aggregation>

○ ○ (very good): Hair tresses are gathered, and loose hair tresses are not observed.

○ (Good): Slightly loose hair bundles are observed.

X (poor): Almost all the hair bundles are broken, and the hair bundles are broken.

　（試験例４：べたつきのなさ）

　得られた整髪剤組成物２ｇを手にとり、ショートヘアのウィッグ（レッスンマネキン：ユーカリジャパン社製）の毛髪に均一に塗布し、毛髪全体を、後頭部方向にクシでなでつけて整髪を施した。整髪後に毛髪を手で触り、べたつきのなさを下記の基準で評価した。なお、比較例１～４、６、８～１１の整髪剤組成物は、試験を行わなかった。
(Test Example 4: No Stickiness)

2 g of the hair styling composition obtained was taken and hand-applied uniformly to the hair of short hair wig (Lesson Mannequin: made by Eucalyptus Japan Co., Ltd.), and the entire hair was brushed with a comb in the back head direction to give a hair styling . After hair setting, the hair was touched by hand and no stickiness was evaluated according to the following criteria. The hair styling compositions of Comparative Examples 1 to 4, 6 and 8 to 11 were not tested.

　＜べたつきのなさの評価基準＞

　○（良好）：べたつきが少なく、気にならない程度である

　×（不良）：べたつきが強く感じられ、不快な使用感である
<Evaluation criteria for lack of stickiness>

○ (Good): There is little stickiness and it does not bother you

X (poor): Stickiness is felt strongly and it is an unpleasant feeling of use

　組成及び結果を下記の表３～５に示す。
The composition and the results are shown in Tables 3 to 5 below.

Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003

Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004

Figure JPOXMLDOC01-appb-T000005
Figure JPOXMLDOC01-appb-T000005

　以下、処方例を示す。
An example of prescription is shown below.

　（処方例１（水性ポマード））

　ポリオキシエチレンセチルエーテル（４０Ｅ．Ｏ．）：４０．０質量％

　（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ：４．０質量％

　ポリオキシエチレン硬化ヒマシ油（５０Ｅ．Ｏ．）：２．５質量％

　ポリオキシプロピレンソルビット（１０Ｐ．Ｏ．）：０．５質量％

　ジグリセリン：２．０質量％

　ジプロピレングリコール：１．０質量％

　フェノキシエタノール：０．５質量％

　メチルパラベン：０．３質量％

　香料：０．５質量％

　ヒアルロン酸Ｎａ：０．０１質量％

　加水分解ケラチン液：０．０１質量％

　水：残部

　合計：１００質量％
(Formulation example 1 (aqueous pomade))

Polyoxyethylene cetyl ether (40 E. O.): 40.0 mass%

(Alkyl acrylate / diacetone acrylamide) copolymer AMP: 4.0% by mass

Polyoxyethylene hydrogenated castor oil (50E.O.): 2.5% by mass

Polyoxypropylene Sorbit (10 P.O.): 0.5 mass%

Diglycerin: 2.0% by mass

Dipropylene glycol: 1.0% by mass

Phenoxyethanol: 0.5% by mass

Methyl paraben: 0.3 mass%

Perfume: 0.5% by mass

Hyaluronic acid Na: 0.01% by mass

Hydrolyzed keratin fluid: 0.01% by mass

Water: the rest

Total: 100% by mass

Claims (5)


  1. 　下記成分Ａと、下記成分Ｂと、下記成分Ｃと、下記成分Ｄとを含み、

    　前記成分Ａの含有量が３０．０質量％以上、４５．０質量％以下であり、

    　前記成分Ｂの含有量が０．１質量％以上であり、

    　前記成分Ｃの含有量が０．１質量％以上、５．０質量％以下であり、

    　前記成分Ａの含有量の前記成分Ｂの含有量に対する質量比が、５．０以上である、整髪剤組成物。

    　成分Ａ：オキシエチレン基の平均付加モル数が２０以上、５０以下であり、かつ炭素数が１６以上、２２以下のアルキル基を有するポリオキシエチレンアルキルエーテル

    　成分Ｂ：重量平均分子量が３００００以上、１５００００以下であり、かつ必須のモノマー成分として、（メタ）アクリル酸アルキルエステルを用いて得られる皮膜形成ポリマー

    　成分Ｃ：ポリオキシエチレン硬化ヒマシ油

    　成分Ｄ：水
    Containing the following component A, the following component B, the following component C, and the following component D,

    Content of the said component A is 30.0 mass% or more and 45.0 mass% or less,

    Content of the said component B is 0.1 mass% or more,

    The content of the component C is 0.1% by mass or more and 5.0% by mass or less,

    The hair styling agent composition whose mass ratio with respect to content of the said component B of content of the said component A is 5.0 or more.

    Component A: Polyoxyethylene alkyl ether having an alkyl group having an average addition mole number of oxyethylene group of 20 or more and 50 or less and a carbon number of 16 or more and 22 or less

    Component B: Film-forming polymer obtained by using (meth) acrylic acid alkyl ester as an essential monomer component having a weight average molecular weight of 30,000 or more and 150,000 or less

    Component C: Polyoxyethylene Cured Castor Oil

    Ingredient D: Water

  2. 　前記成分Ａが、下記成分Ａ１を含む、請求項１に記載の整髪剤組成物。

    　成分Ａ１：オキシエチレン基の平均付加モル数が２０以上、５０以下であるポリオキシエチレンステアリルエーテル、オキシエチレン基の平均付加モル数が２０以上、５０以下であるポリオキシエチレンベヘニルエーテル、及びオキシエチレン基の平均付加モル数が３０以上、５０以下であるポリオキシエチレンセチルエーテルからなる群より選ばれるポリオキシエチレンアルキルエーテル
    The hair styling composition according to claim 1, wherein the component A comprises the following component A1.

    Component A1: polyoxyethylene stearyl ether having an average addition mole number of oxyethylene groups of 20 or more and 50 or less, polyoxyethylene behenyl ether having an average addition mole number of oxyethylene groups of 20 or more and 50 or less, and oxyethylene Polyoxyethylene alkyl ether selected from the group consisting of polyoxyethylene cetyl ether in which the average addition mole number of groups is 30 or more and 50 or less

  3. 　前記成分Ｂが、下記成分Ｂ１を含む、請求項１又は２に記載の整髪剤組成物。

    　成分Ｂ１：アクリル酸アルキルコポリマーＡＭＰ、（アクリル酸アルキル／ジアセトンアクリルアミド）コポリマーＡＭＰ、（アクリレーツ／アクリル酸アルキル（Ｃ１－１８）／アルキル（Ｃ１－８）アクリルアミド）コポリマーＡＭＰ、（アクリル酸アルキル・オクチルアクリルアミド）コポリマー、（メタクリロイルオキシエチルカルボキシベタイン／メタクリル酸アルキル）コポリマー、及び（オクチルアクリルアミド／アクリル酸ヒドロキシプロピル／メタクリル酸ブチルアミノエチル）コポリマーからなる群より選ばれる皮膜形成ポリマー
    The hair styling composition according to claim 1, wherein the component B comprises the following component B1.

    Component B1: alkyl acrylate copolymer AMP, (alkyl acrylate / diacetone acrylamide) copolymer AMP, (acrylate / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP, (alkyl acrylate octyl) A film-forming polymer selected from the group consisting of acrylamide) copolymers, (methacryloyloxyethyl carboxybetaine / alkyl methacrylate) copolymers, and (octyl acrylamide / hydroxypropyl acrylate / butyl aminoethyl methacrylate) copolymers

  4. 　さらに、下記成分Ｅを含む、請求項１～３のいずれか１項に記載の整髪剤組成物。

    　成分Ｅ：ポリオキシプロピレンソルビット
    The hair styling composition according to any one of claims 1 to 3, further comprising the following component E:

    Component E: Polyoxypropylene Sorbit

  5. 　性状がグリース状である、請求項１～４のいずれか１項に記載の整髪剤組成物。
    The hair styling composition according to any one of claims 1 to 4, which is greasy like.
PCT/JP2018/027368 2017-09-29 2018-07-20 Hairstyling composition WO2019064852A1 (en)

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JPH09100219A (en) * 1995-10-03 1997-04-15 Shiseido Co Ltd Hair cosmetic
JP2002167317A (en) * 2000-11-30 2002-06-11 Mandom Corp Hair cosmetic composition
JP2006265217A (en) * 2005-03-19 2006-10-05 Estate Chemical Kk Cosmetic
JP2007320872A (en) * 2006-05-31 2007-12-13 Mandom Corp Hair cosmetic product
WO2008004502A1 (en) * 2006-07-03 2008-01-10 Shiseido Co., Ltd. Cosmetic hair preparation
JP2012006915A (en) * 2010-05-21 2012-01-12 Kao Corp Hairdressing agent contained in nonaerosol foamer container
JP2015098446A (en) * 2013-11-19 2015-05-28 株式会社マンダム Emulsifying agent composition for hairdressing
JP2015120661A (en) * 2013-12-24 2015-07-02 株式会社マンダム Emulsifying agent composition for hairdressing
JP2016216403A (en) * 2015-05-22 2016-12-22 株式会社マンダム Hairdressing agent composition
JP2017145224A (en) * 2016-02-18 2017-08-24 株式会社マンダム Hairdressing agent composition

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JP3418490B2 (en) 1995-10-23 2003-06-23 株式会社ノエビア Hair composition
JP3845203B2 (en) 1998-07-17 2006-11-15 株式会社コーセー Gel hair conditioner

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09100219A (en) * 1995-10-03 1997-04-15 Shiseido Co Ltd Hair cosmetic
JP2002167317A (en) * 2000-11-30 2002-06-11 Mandom Corp Hair cosmetic composition
JP2006265217A (en) * 2005-03-19 2006-10-05 Estate Chemical Kk Cosmetic
JP2007320872A (en) * 2006-05-31 2007-12-13 Mandom Corp Hair cosmetic product
WO2008004502A1 (en) * 2006-07-03 2008-01-10 Shiseido Co., Ltd. Cosmetic hair preparation
JP2012006915A (en) * 2010-05-21 2012-01-12 Kao Corp Hairdressing agent contained in nonaerosol foamer container
JP2015098446A (en) * 2013-11-19 2015-05-28 株式会社マンダム Emulsifying agent composition for hairdressing
JP2015120661A (en) * 2013-12-24 2015-07-02 株式会社マンダム Emulsifying agent composition for hairdressing
JP2016216403A (en) * 2015-05-22 2016-12-22 株式会社マンダム Hairdressing agent composition
JP2017145224A (en) * 2016-02-18 2017-08-24 株式会社マンダム Hairdressing agent composition

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