TW201819965A - Polarizer, polarizing plate and image display device - Google Patents

Polarizer, polarizing plate and image display device Download PDF

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TW201819965A
TW201819965A TW106134740A TW106134740A TW201819965A TW 201819965 A TW201819965 A TW 201819965A TW 106134740 A TW106134740 A TW 106134740A TW 106134740 A TW106134740 A TW 106134740A TW 201819965 A TW201819965 A TW 201819965A
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polarizer
cutting
polarizing plate
film
laminated body
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TW106134740A
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TWI728194B (en
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市原正寛
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日商住友化學股份有限公司
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    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/30Polarising elements
    • G02B5/3025Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid

Abstract

The present invention provides a polarizer that is less likely to crack with temperature changes. The means for solving the abovementioned problem is to adjust an average height Rc of roughness curve elements of an end face 2a of a film-like polarizer 2 to be 0.05 to 1.7 [mu]m.

Description

偏光片、偏光板及圖像顯示裝置  Polarizer, polarizing plate and image display device  

本發明係關於偏光片、偏光板及圖像顯示裝置。 The present invention relates to a polarizer, a polarizing plate, and an image display device.

近年來,係要求具備液晶單元或有機EL元件等的圖像顯示裝置之薄型化。 In recent years, it has been required to reduce the thickness of an image display device including a liquid crystal cell or an organic EL device.

因此,圖像顯示裝置用之偏光片亦成形為薄的膜狀。由於膜狀的偏光片脆且易裂,因此為了保護偏光片,係於製造偏光板時於偏光片的兩面貼合保護膜。而且,製造偏光板時,為了提高偏光板的尺寸精度,係將由保護膜及偏光片等所構成之積層體的端部進行研磨(例如參照專利文獻1)。 Therefore, the polarizer for the image display device is also formed into a thin film shape. Since the film-shaped polarizer is brittle and easily cracked, in order to protect the polarizer, a protective film is bonded to both surfaces of the polarizer when the polarizing plate is manufactured. In addition, in order to improve the dimensional accuracy of the polarizing plate, the end portion of the laminate including the protective film and the polarizer is polished (see, for example, Patent Document 1).

〔先前技術文獻〕  [Previous Technical Literature]   〔專利文獻〕  [Patent Document]  

〔專利文獻1〕 日本專利第3875331號公報 [Patent Document 1] Japanese Patent No. 3875331

近年來,為了使偏光板薄化,而進行僅於偏光片的單面貼合有保護膜之偏光板的開發。然而,僅於單面疊合保護膜之偏光片與於兩面疊合保護膜之偏光片相比,較容易產生破裂(龜裂)。此種破裂係由於隨著溫度變化之偏光片的膨脹或收縮所引起。尤其是瞭解到會容易因為偏光片的急劇溫度變化(熱衝擊)而產生破裂。 In recent years, in order to reduce the thickness of the polarizing plate, development of a polarizing plate in which a protective film is bonded to only one surface of the polarizing plate has been carried out. However, the polarizer which is only laminated on one side of the protective film is more likely to be cracked (cracked) than the polarizer which is laminated on both sides of the protective film. Such cracking is caused by expansion or contraction of the polarizer as a function of temperature. In particular, it is known that cracking easily occurs due to a sharp temperature change (thermal shock) of the polarizer.

而且,近年來,為了提升設計性,而要求圖像顯示裝置的邊框窄。對應此種要求,亦對偏光板的端部要求高的尺寸精度。為了以高精度調整偏光板的尺寸,需將由保護膜及偏光片等所構成之積層體的端部以高精度進行切削(研磨)。但是,僅於單面疊合保護膜之偏光片與於兩面疊合保護膜之偏光片相比,在切削時較容易對偏光片的端面造成負擔,偏光片的端面容易變粗糙。此種端面的粗度容易隨著溫度變化而引起偏光片的破裂。尤其是瞭解到,位於無保護膜之表面側的偏光片的端面與位於疊合保護膜之表面側的偏光片的端面相比,係較容易產生破裂。 Moreover, in recent years, in order to improve design, the frame of the image display device is required to be narrow. Corresponding to such requirements, high dimensional accuracy is also required for the ends of the polarizing plates. In order to adjust the size of the polarizing plate with high precision, it is necessary to cut (grind) the end portion of the laminated body composed of the protective film, the polarizing plate, and the like with high precision. However, the polarizer of the single-sided laminated protective film is more likely to cause a burden on the end face of the polarizer at the time of cutting than the polarizer in which the protective film is superposed on both sides, and the end face of the polarizer is likely to be rough. The thickness of such an end face tends to cause cracking of the polarizer as the temperature changes. In particular, it is understood that the end face of the polarizer located on the surface side of the non-protective film is more likely to be broken than the end face of the polarizer located on the surface side of the superposed protective film.

本發明係有鑑於上述情事所成者,目的在於提供一種尺寸精度高且不易隨著溫度變化而產生破裂之偏光片、具備該偏光片之偏光板、及包含該偏光板之圖像顯示裝置。 The present invention has been made in view of the above circumstances, and an object thereof is to provide a polarizing plate which is high in dimensional accuracy and which is less likely to be broken by temperature change, a polarizing plate including the polarizing plate, and an image display device including the polarizing plate.

本發明的一態樣之偏光片係膜狀的偏光片,偏光片的端面之粗度曲線要素的平均高度Rc為0.05至1.7μm。平均高度Rc亦可為0.05至0.28μm。 In one embodiment of the present invention, the polarizer is a film-shaped polarizer, and the average height Rc of the thickness curve elements of the end faces of the polarizer is 0.05 to 1.7 μm. The average height Rc may also be 0.05 to 0.28 μm.

本發明的一態樣之偏光板,係具備上述之偏光片、與疊合於偏光片的一表面之第一光學膜。 A polarizing plate according to an aspect of the present invention includes the above polarizing plate and a first optical film laminated on a surface of the polarizing plate.

本發明的一態樣中,偏光片的圍起一個端面的邊之中的第一邊係鄰接於第一光學膜,圍起端面的邊之中的第二邊係位於第一邊的相對側,端面中之沿著第二邊的部分之均方根粗度Rq可為0.03至0.15μm。 In one aspect of the invention, the first side of the side of the polarizer that encloses one end face is adjacent to the first optical film, and the second side of the side that surrounds the end face is located on the opposite side of the first side The root mean square roughness Rq of the portion along the second side in the end face may be 0.03 to 0.15 μm.

本發明的一態樣中,第一光學膜亦可為保護膜。 In one aspect of the invention, the first optical film may also be a protective film.

本發明的一態樣之偏光板,可進一步具備:疊合於偏光片的另一表面之黏著劑層、疊合於黏著劑層之第二光學膜。 The polarizing plate according to an aspect of the invention may further include: an adhesive layer laminated on the other surface of the polarizer; and a second optical film laminated on the adhesive layer.

本發明的一態樣之偏光板,可進一步具備:疊合於第一光學膜之黏著劑層、疊合於黏著劑層之第二光學膜。 The polarizing plate according to an aspect of the invention may further include: an adhesive layer laminated on the first optical film; and a second optical film laminated on the adhesive layer.

本發明的一態樣中,第二光學膜亦可為反射型偏光片。 In one aspect of the invention, the second optical film may also be a reflective polarizer.

本發明的一態樣之圖像顯示裝置包含上述之偏光板。 An image display device according to an aspect of the present invention includes the above polarizing plate.

依據本發明,可提供尺寸的精度高且不易隨著溫度變化而產生破裂之偏光片、具備該偏光片之偏光板、及包含該偏光板之圖像顯示裝置。 According to the present invention, it is possible to provide a polarizer having high dimensional accuracy, which is less likely to be broken by temperature changes, a polarizing plate including the polarizer, and an image display device including the polarizing plate.

1‧‧‧偏光板 1‧‧‧Polar plate

2‧‧‧膜狀的偏光片 2‧‧‧ Film-shaped polarizers

2a‧‧‧偏光片的端面 2a‧‧‧End face of polarizer

2as‧‧‧端面的側部(端面中之沿著第二邊的部分) 2as‧‧‧ Side of the end face (the part along the second side in the end face)

3‧‧‧保護膜(第一光學膜) 3‧‧‧Protective film (first optical film)

4‧‧‧反射型偏光片(第二光學膜) 4‧‧‧Reflective polarizer (second optical film)

5‧‧‧感壓式黏著劑層 5‧‧‧ Pressure-sensitive adhesive layer

10‧‧‧切削工具 10‧‧‧Cutting tools

10a‧‧‧支撐體 10a‧‧‧Support

100‧‧‧積層體 100‧‧‧Layer

100a‧‧‧端面 100a‧‧‧ end face

11a、11b、11c、11d、11e、11f‧‧‧切削部 11a, 11b, 11c, 11d, 11e, 11f‧‧‧ cutting part

1A‧‧‧偏光板 1A‧‧‧Polar plate

A‧‧‧旋轉軸線 A‧‧‧ axis of rotation

B‧‧‧切削刃 B‧‧‧ cutting edge

S‧‧‧切削面 S‧‧‧ cutting surface

S1‧‧‧第一邊 S1‧‧‧ first side

S2‧‧‧第二邊 S2‧‧‧ second side

S3‧‧‧第三邊 S3‧‧‧ third side

S4‧‧‧第四邊 S4‧‧‧ fourth side

第1圖中之(a)為本發明之一實施形態之偏光板的示意性斜視圖,第1圖中之(b)為第1圖中之(a)所示之偏光板的端面的一部分(部分b)的示意性擴大圖。 Fig. 1(a) is a schematic perspective view of a polarizing plate according to an embodiment of the present invention, and Fig. 1(b) is a part of an end surface of the polarizing plate shown in Fig. 1(a). A schematic enlarged view of (part b).

第2圖為本發明之一實施形態之偏光板的製造所使用之切削工具的側面圖。 Fig. 2 is a side view showing a cutting tool used in the production of a polarizing plate according to an embodiment of the present invention.

第3圖為第2圖所示之切削工具之正面圖。 Fig. 3 is a front view of the cutting tool shown in Fig. 2.

第4圖為表示第2圖所示之切削工具與由複數個偏光板所構成之積層體的位置之示意圖。 Fig. 4 is a view showing the position of the cutting tool shown in Fig. 2 and the laminated body composed of a plurality of polarizing plates.

第5圖為表示第3圖所示之切削工具與由複數個偏光板所構成之積層體的位置之示意圖。 Fig. 5 is a view showing the position of a cutting tool shown in Fig. 3 and a laminated body composed of a plurality of polarizing plates.

以下係參照圖式來說明本發明之適宜的實施形態。圖式中,係於同等的構成要素註以同等的符號。本發明並不限定於下述實施形態。各圖所示之X、Y及Z意指互為垂直相交的3個座標軸。各座標軸所表示的方向於全部圖中為共通。圖中所見之尺寸及尺寸的比率未必與實際者一致。 Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings. In the drawings, the same constituent elements are denoted by the same reference numerals. The present invention is not limited to the following embodiments. X, Y, and Z shown in the respective figures mean three coordinate axes that intersect each other perpendicularly. The directions indicated by the respective coordinate axes are common to all the figures. The ratios of dimensions and dimensions seen in the figures are not necessarily consistent with the actual ones.

〔偏光片、偏光板及圖像顯示裝置〕  [Polarizer, polarizing plate and image display device]  

如第1圖中之(a)所示,本實施形態之偏光板1係具備:膜狀的偏光片2、疊合於偏光片2的一表面之第一光學膜(3)、疊合於偏光片2的另一表面之感壓式黏著劑層5、疊合於感壓式黏著劑層5之第二光學膜(4)。第一光學膜係例如保護膜3。第二光學膜係例如反射型偏光片4。 偏光板1所具備之偏光片2、以及光學膜及層可皆為透明。本實施形態之偏光板1中,僅於偏光片2的單面,光學膜(第一光學膜)為非經由感壓式黏著劑層而是經由接著劑層直接密著於偏光片2。 As shown in FIG. 1(a), the polarizing plate 1 of the present embodiment includes a film-shaped polarizing plate 2, a first optical film (3) superposed on one surface of the polarizing plate 2, and a superposed film. The pressure-sensitive adhesive layer 5 on the other surface of the polarizer 2 is laminated on the second optical film (4) of the pressure-sensitive adhesive layer 5. The first optical film is, for example, a protective film 3. The second optical film is, for example, a reflective polarizer 4. The polarizing plate 2 and the optical film and the layer provided in the polarizing plate 1 may be transparent. In the polarizing plate 1 of the present embodiment, the optical film (first optical film) is directly adhered to the polarizing film 2 via the adhesive layer without passing through the pressure-sensitive adhesive layer only on one surface of the polarizing plate 2.

偏光片2、第一光學膜(3)、感壓式黏著劑層5及第二光學膜(4)皆為具有大致相同的尺寸之矩形。偏光板1整體亦為矩形的膜。惟,偏光片2及偏光板1等的各形狀係因偏光板1所貼附的圖像顯示元件的表面形狀而異,故不受限定。偏光片2及偏光板1各自的形狀,例如亦可為多角形、圓形或橢圓形。偏光片2及偏光板1各自之輪廓的一部分或全部,可為直線亦可為曲線。 The polarizer 2, the first optical film (3), the pressure-sensitive adhesive layer 5, and the second optical film (4) are each a rectangle having substantially the same size. The polarizing plate 1 as a whole is also a rectangular film. However, the respective shapes of the polarizer 2 and the polarizing plate 1 are different depending on the surface shape of the image display element to which the polarizing plate 1 is attached, and thus are not limited. The shape of each of the polarizer 2 and the polarizing plate 1 may be, for example, a polygonal shape, a circular shape, or an elliptical shape. A part or all of the outline of each of the polarizer 2 and the polarizing plate 1 may be a straight line or a curved line.

本實施形態之圖像顯示裝置,例如亦可為液晶顯示裝置或有機EL顯示裝置。液晶顯示裝置例如可包含:液晶單元、貼附於液晶單元的一表面或兩表面之偏光板1。有機EL顯示裝置例如可包含:有機EL元件、貼附於有機EL元件的表面之偏光板1。液晶單元中,通常可配置2片偏光板。配置於液晶單元的背面側之偏光板所具備之偏光片與配置於液晶單元的視認側之偏光板所具備之偏光片相比,較容易曝於熱中。因此,若將具備本實施形態之偏光片2的偏光板1配置於液晶單元的背面側,則能抑制隨著溫度變化之偏光片2的破裂。其理由如後所述。 The image display device of the present embodiment may be, for example, a liquid crystal display device or an organic EL display device. The liquid crystal display device may include, for example, a liquid crystal cell, and a polarizing plate 1 attached to one surface or both surfaces of the liquid crystal cell. The organic EL display device may include, for example, an organic EL element and a polarizing plate 1 attached to the surface of the organic EL element. In the liquid crystal cell, two polarizing plates can usually be disposed. The polarizer provided in the polarizing plate disposed on the back side of the liquid crystal cell is more likely to be exposed to heat than the polarizer provided on the polarizing plate disposed on the viewing side of the liquid crystal cell. Therefore, when the polarizing plate 1 including the polarizing plate 2 of the present embodiment is disposed on the back side of the liquid crystal cell, cracking of the polarizing plate 2 with temperature change can be suppressed. The reason is as described later.

偏光片2的端面2a之粗度曲線要素的平均高度Rc為0.05至1.7μm。平均高度Rc亦可為0.05至0.28μm、0.07至1.7μm、0.07至1.604μm、0.07至1.0μm 或0.07至0.28μm。端面2a之粗度曲線要素的平均高度Rc亦可由例如下述式1所定義。 The average height Rc of the thickness curve elements of the end faces 2a of the polarizer 2 is 0.05 to 1.7 μm. The average height Rc may also be 0.05 to 0.28 μm, 0.07 to 1.7 μm, 0.07 to 1.604 μm, 0.07 to 1.0 μm, or 0.07 to 0.28 μm. The average height Rc of the thickness curve elements of the end face 2a can also be defined, for example, by the following formula 1.

式1中,Rc為基準長度1之粗度曲線要素(輪廓曲線要素)的高度Zt的平均。i為1以上m以下的自然數,m為2以上的自然數。Zti為基準長度1之第i個輪廓曲線要素的高度。輪廓曲線要素係指相鄰接的一組山與谷,輪廓曲線要素的高度Zt係指相鄰接的一組山(極大值)與谷(極小值)之差。Rc可例如藉由雷射顯微鏡於偏光片2的端面2a上進行測定。 In Formula 1, Rc is an average of the heights Zt of the thickness curve elements (contour curve elements) of the reference length 1. i is a natural number of 1 or more and m or less, and m is a natural number of 2 or more. Zti is the height of the i-th profile element of the reference length 1. The contour curve element refers to a group of adjacent mountains and valleys, and the height Zt of the contour curve element refers to the difference between a group of adjacent mountains (maximum values) and valleys (minimum values). Rc can be measured on the end face 2a of the polarizer 2 by, for example, a laser microscope.

端面2a之粗度曲線要素的平均高度Rc越大,換言之,端面2a越粗糙,則端面2a越會因隨著溫度變化的膨脹或收縮而不均勻地變形。尤其是端面2a會因為隨著熱衝擊之急劇地膨脹或收縮而不均勻且急劇地變形。偏光片2往一軸方向或二軸方向延伸時,偏光片2的膨脹或收縮為非等向性(anisotropic)。由於該等因素,隨著偏光片2之溫度變化,容易以端面2a為起點而於偏光片2產生破裂。例如,以輪廓曲線要素之谷(即為端面2a之深凹處)為起點而產生破裂。但是,本實施形態中,端面2a之粗度曲線要素的平均高度Rc係0.05至1.7μm,故能減少如上所述之各項破裂因素,而能抑制偏光片2隨著溫度 變化而產生破裂。於平均高度Rc為0.05至1.7μm之端面2a形成之破裂的長度,係有較於平均高度Rc大於1.7μm之端面2a形成之破裂的長度更短的傾向。於偏光片2的兩面密著有保護膜時,於端面2a的整體範圍內,偏光片2的端面2a之粗度曲線要素的平均高度Rc為幾乎均勻。另一方面,僅於偏光片2的單面側密著有保護膜時,偏光片2的端面2a之粗度曲線要素的平均高度Rc係有隨著遠離偏光片2與保護膜之界面(接著面)而變大之傾向。因偏光片2係延伸膜,故容易開裂,尤其是位於無保護膜之表面側的偏光片的端面容易因研磨刃處理而變粗糙。因此,偏光片2的端面2a之粗度曲線要素的平均高度Rc容易隨著遠離偏光片2與保護膜之界面而變大。偏光片2的端面2a之粗度曲線要素的平均高度Rc並非均勻時,於偏光片2的端面2a所測定到的粗度曲線要素的平均高度Rc中之最大值,亦可為例如0.05至0.28μm。偏光片2的端面2a之粗度曲線要素的平均高度Rc並非均勻時,於平均高度Rc之最大值為0.05至0.28μm的端面2a所形成的破裂的長度,係有較於平均高度Rc之最大值大於0.28μm的端面2a所形成的破裂的長度更短之傾向。此外,偏光片2的端面2a之粗度曲線要素的平均高度Rc並非均勻時,於平均高度Rc之最大值為0.05至0.28μm之端面2a所形成的破裂的個數係有較於平均高度Rc之最大值大於0.28μm之端面2a所形成的破裂的個數更少之傾向。 The larger the average height Rc of the thickness curve elements of the end face 2a, in other words, the coarser the end face 2a, the more the end face 2a is unevenly deformed due to expansion or contraction with temperature. In particular, the end face 2a is unevenly and sharply deformed due to rapid expansion or contraction with thermal shock. When the polarizer 2 is extended in one axial direction or two axial directions, the expansion or contraction of the polarizer 2 is anisotropic. Due to these factors, as the temperature of the polarizer 2 changes, it is easy to cause cracking in the polarizer 2 with the end face 2a as a starting point. For example, a crack is generated starting from the valley of the contour curve element (that is, the deep recess of the end surface 2a). However, in the present embodiment, the average height Rc of the thickness curve elements of the end surface 2a is 0.05 to 1.7 μm, so that the respective cracking factors as described above can be reduced, and the polarizing plate 2 can be prevented from being cracked as the temperature changes. The length of the crack formed by the end face 2a having an average height Rc of 0.05 to 1.7 μm tends to be shorter than the length of the crack formed by the end face 2a having an average height Rc of more than 1.7 μm. When the protective film is adhered to both surfaces of the polarizer 2, the average height Rc of the roughness curve elements of the end face 2a of the polarizer 2 is almost uniform over the entire range of the end face 2a. On the other hand, when the protective film is adhered to only one side of the polarizer 2, the average height Rc of the thickness curve element of the end face 2a of the polarizer 2 is along with the interface away from the polarizer 2 and the protective film (followed) The tendency to become bigger. Since the polarizer 2 is a stretched film, it is easily cracked, and in particular, the end face of the polarizer located on the surface side of the unprotected film is liable to be roughened by the polishing blade treatment. Therefore, the average height Rc of the thickness curve elements of the end faces 2a of the polarizer 2 tends to become larger as it goes away from the interface between the polarizer 2 and the protective film. When the average height Rc of the thickness curve elements of the end surface 2a of the polarizer 2 is not uniform, the maximum value of the average height Rc of the thickness curve elements measured on the end surface 2a of the polarizer 2 may be, for example, 0.05 to 0.28. Mm. When the average height Rc of the thickness curve elements of the end face 2a of the polarizer 2 is not uniform, the length of the rupture formed by the end face 2a having a maximum value of the average height Rc of 0.05 to 0.28 μm is the largest than the average height Rc. The length of the crack formed by the end face 2a having a value larger than 0.28 μm tends to be shorter. Further, when the average height Rc of the thickness curve elements of the end faces 2a of the polarizer 2 is not uniform, the number of cracks formed by the end faces 2a having a maximum value of the average height Rc of 0.05 to 0.28 μm is higher than the average height Rc. The end face 2a whose maximum value is larger than 0.28 μm tends to have a smaller number of cracks.

偏光片或偏光板的端面未經研磨時,偏光片 的端面不會因研磨而變粗糙,故偏光片的端面的平均高度Rc大致為零,於偏光片的端面不易產生破裂。換言之,端面2a的平均高度Rc越小,則越不易於偏光片的端面產生破裂。但是,當不研磨偏光片或偏光板的端面時,難以將偏光片或偏光板的尺寸以高精度調整至期望值(例如,製品規格的公差之範圍)。因此,端面2a的平均高度Rc未達0.05μm之偏光片的尺寸的精度係較端面2a的平均高度Rc為0.05μm以上之偏光片的尺寸的精度更差。換言之,具有經研磨之端面的偏光片的尺寸精度係較具有未經研磨之端面的偏光片的尺寸精度更高。 When the end faces of the polarizer or the polarizing plate are not polished, the end faces of the polarizers are not roughened by polishing, so that the average height Rc of the end faces of the polarizers is substantially zero, and cracking is unlikely to occur at the end faces of the polarizers. In other words, the smaller the average height Rc of the end faces 2a, the less likely the crack is generated on the end faces of the polarizers. However, when the end faces of the polarizer or the polarizing plate are not polished, it is difficult to adjust the size of the polarizer or the polarizing plate to a desired value with high precision (for example, a range of tolerances of product specifications). Therefore, the accuracy of the size of the polarizer having an average height Rc of the end face 2a of less than 0.05 μm is worse than the accuracy of the size of the polarizer having an average height Rc of the end face 2a of 0.05 μm or more. In other words, the dimensional accuracy of the polarizer having the polished end face is higher than that of the polarizer having the unpolished end face.

矩形狀的偏光片2具有4個端面2a。可使偏光片2所具有的複數個端面2a之中,一部分的端面2a之粗度曲線要素的平均高度Rc係0.05至1.7μm。亦可使偏光片2所具有的全部的端面2a之粗度曲線要素的平均高度Rc係0.05至1.7μm。Rc為0.05至1.7μm的端面2a越多,則越容易抑制偏光片2之破裂的產生。 The rectangular polarizer 2 has four end faces 2a. Among the plurality of end faces 2a of the polarizer 2, the average height Rc of the thickness curve elements of a part of the end faces 2a may be 0.05 to 1.7 μm. The average height Rc of the thickness curve elements of all the end faces 2a of the polarizer 2 may be 0.05 to 1.7 μm. The more the end faces 2a having an Rc of 0.05 to 1.7 μm, the more easily the occurrence of cracking of the polarizer 2 is suppressed.

如第1圖中之(b)所示,偏光片2的一個端面2a,係由第一邊S1、第二邊S2、第三邊S3及第四邊S4所圍起。換言之,端面2a的周邊是由第一邊S1、第二邊S2、第三邊S3及第四邊S4所構成。圍起端面2a之四邊之中的第一邊S1係鄰接於保護膜3(第一光學膜)。圍起端面2a之四邊之中的第二邊S2係位於第一邊S1的相對側。換言之,第二邊S2鄰接於感壓式黏著劑層5。第二邊S2為未鄰接於保護膜3之邊。 As shown in (b) of FIG. 1, one end surface 2a of the polarizer 2 is surrounded by a first side S1, a second side S2, a third side S3, and a fourth side S4. In other words, the periphery of the end surface 2a is composed of the first side S1, the second side S2, the third side S3, and the fourth side S4. The first side S1 among the four sides of the enclosed end face 2a is adjacent to the protective film 3 (first optical film). The second side S2 among the four sides of the enclosed end face 2a is located on the opposite side of the first side S1. In other words, the second side S2 is adjacent to the pressure-sensitive adhesive layer 5. The second side S2 is a side that is not adjacent to the protective film 3.

端面2a中沿著第二邊S2的部分(2as)之均方根粗度Rq可為0.03至0.50μm。以下,有將端面2a中沿著第二邊S2的部分記為端面2a的「側部2as」之情形。均方根粗度Rq亦可為0.03至0.466μm、0.03至0.30μm、0.03至0.15μm、或0.031至0.081μm。端面2a的側部2as的均方根粗度Rq,例如可由下述式2定義。 The root mean square roughness Rq of the portion (2as) along the second side S2 in the end face 2a may be 0.03 to 0.50 μm. Hereinafter, the portion along the second side S2 of the end surface 2a is referred to as the "side portion 2as" of the end surface 2a. The root mean square roughness Rq may also be 0.03 to 0.466 μm, 0.03 to 0.30 μm, 0.03 to 0.15 μm, or 0.031 to 0.081 μm. The root mean square roughness Rq of the side portion 2as of the end surface 2a can be defined, for example, by the following formula 2.

式2中,1(英文字母的小寫L)為端面2a的側部2as的基準長度。Z(x)為基準長度1上的任意位置x之粗度曲線的高度。Rq可例如藉由雷射顯微鏡於端面2a的側部2as測定而得。換言之,Rq可沿著偏光片2的端面2a的第二邊S2測定而得。偏光片2的厚度方向(Z軸方向)之側部2as的寬度,只要能測定Rq,窄亦無妨。假如,將偏光片2的端面2a以第一邊S1與第二邊S2的正中間(中央)等分成二個區域時,Rq可謂是表示二個區域之中無保護膜3的第二邊S2側的一半的機械強度之指標。因此,偏光片2的厚度方向(Z軸方向)之側部2as的寬度亦可為偏光片2的厚度的一半以下。偏光片2的厚度方向(Z軸方向)之側部2as的寬度,亦可與Rq的測定所使用之雷射的點徑大致相同。偏光片2的厚度方向(Z軸方向)之側部2as的寬度亦可為相當於使用雷射顯微鏡 之Rq的量測極限的寬度。 In Formula 2, 1 (lowercase L of the English letter) is the reference length of the side portion 2as of the end face 2a. Z(x) is the height of the thickness curve of any position x on the reference length 1. Rq can be measured, for example, by a laser microscope at the side portion 2as of the end face 2a. In other words, Rq can be measured along the second side S2 of the end face 2a of the polarizer 2. The width of the side portion 2as in the thickness direction (Z-axis direction) of the polarizer 2 is not limited as long as Rq can be measured. If the end face 2a of the polarizer 2 is divided into two regions by the middle (center) of the first side S1 and the second side S2, Rq can be said to represent the second side S2 of the two regions without the protective film 3. An indicator of the mechanical strength of the half of the side. Therefore, the width of the side portion 2as in the thickness direction (Z-axis direction) of the polarizer 2 may be half or less of the thickness of the polarizing plate 2. The width of the side portion 2as in the thickness direction (Z-axis direction) of the polarizer 2 may be substantially the same as the spot diameter of the laser used for the measurement of Rq. The width of the side portion 2as in the thickness direction (Z-axis direction) of the polarizing plate 2 may be a width corresponding to the measurement limit using Rq of the laser microscope.

密著有保護膜3之第一邊S1側與無保護膜3之第二邊S2側相比,係較容易藉由保護膜3來抑制隨著溫度變化之偏光片2的膨脹或收縮。 The first side S1 side of the protective film 3 is denser than the second side S2 side of the non-protective film 3, and it is easier to suppress the expansion or contraction of the polarizer 2 with temperature change by the protective film 3.

相對而言,位於無保護膜3之第二邊S2側之側部2as與密著有保護膜3之第一邊S1側相比,係較容易隨著溫度變化而膨脹或收縮。並且,位於無保護膜3之第二邊S2側之側部2as的Rq越大,側部2as越會因隨著溫度變化膨脹或收縮而不均勻地變形。換言之,側部2as越粗糙,則側部2as越容易因隨著溫度變化膨脹或收縮而不均勻地變形。尤其是側部2as容易因為隨著熱衝擊之急劇的膨脹或收縮而不均勻且急劇地變形。偏光片2往一軸方向或二軸方向延伸時,偏光片2的膨脹或收縮為非等向性(anisotropic)。由於該等因素,容易隨著偏光片2的溫度變化而以側部2as為起點於偏光片2產生破裂。換言之,容易隨著偏光片2的溫度變化,而於端面2a中沿著未鄰接保護膜之第二邊S2的部分產生破裂。例如,容易以粗度曲線的谷(即側部2as之深凹處)為起點而產生破裂。但是,即使於偏光片2的第二邊S2側的表面未疊合保護膜之情形下,藉由減低位於無保護膜3之第二邊S2側之側部2as的Rq,也能容易地減少如上述之各項破裂的因素,而容易地抑制隨著溫度變化產生偏光片2的破裂。換言之,位於無保護膜3之第二邊S2側之側部2as的Rq小時,容易抑制產生位於第二邊S2側的側部2as的破裂。例如, 均方根粗度Rq為0.03至0.15μm時,容易抑制產生位於第二邊S2側的側部2as的破裂。未研磨偏光片或偏光板的端面時,偏光片的端面不會因為研磨而變粗,故均方根粗度Rq大致為零,不易於偏光片的端面產生破裂。但是,未研磨偏光片或偏光板的端面時,難以將偏光片或偏光板的尺寸以高精度調整為期望值(例如,製品規格的公差之範圍)。因此,均方根粗度Rq未達0.03μm之偏光片的尺寸的精度係有較均方根粗度Rq為0.03μm以上之偏光片的尺寸的精度更低之傾向。 On the other hand, the side portion 2as on the second side S2 side of the non-protective film 3 is more likely to expand or contract as the temperature changes due to the side portion S1 on which the protective film 3 is adhered. Further, the larger the Rq of the side portion 2as on the second side S2 side of the non-protective film 3, the more the side portion 2as is unevenly deformed due to expansion or contraction with temperature change. In other words, the rougher the side portion 2as, the more easily the side portion 2as is deformed unevenly due to expansion or contraction with temperature changes. In particular, the side portion 2as is liable to be unevenly and sharply deformed due to rapid expansion or contraction with thermal shock. When the polarizer 2 is extended in one axial direction or two axial directions, the expansion or contraction of the polarizer 2 is anisotropic. Due to these factors, it is easy to cause cracking of the polarizer 2 with the side portion 2as as a starting point as the temperature of the polarizer 2 changes. In other words, it is easy to cause cracks in the end face 2a along the portion of the end face 2a that is not adjacent to the second side S2 of the protective film as the temperature of the polarizer 2 changes. For example, it is easy to cause cracking from the valley of the roughness curve (i.e., the deep recess of the side portion 2as) as a starting point. However, even in the case where the surface on the second side S2 side of the polarizer 2 is not laminated with the protective film, the Rq located on the side portion 2as on the second side S2 side of the non-protective film 3 can be easily reduced. The rupture of the polarizer 2 is easily suppressed as the temperature changes as a factor of the above-described rupture. In other words, when Rq of the side portion 2as on the second side S2 side of the non-protective film 3 is small, it is easy to suppress the occurrence of cracking of the side portion 2as on the side of the second side S2. For example, when the root mean square roughness Rq is 0.03 to 0.15 μm, it is easy to suppress the occurrence of cracking of the side portion 2as on the side of the second side S2. When the end faces of the polarizer or the polarizing plate are not polished, the end faces of the polarizers are not thickened by polishing, so the root mean square roughness Rq is substantially zero, and it is not easy to cause cracks in the end faces of the polarizers. However, when the end faces of the polarizer or the polarizing plate are not polished, it is difficult to adjust the size of the polarizer or the polarizing plate to a desired value with high precision (for example, a range of tolerances of product specifications). Therefore, the accuracy of the size of the polarizer having a root mean square roughness Rq of less than 0.03 μm tends to be lower than the accuracy of the size of the polarizer having a root mean square roughness Rq of 0.03 μm or more.

矩形狀的偏光片2具有4個端面2a。可使偏光片2所具有的複數個端面2a之中,一部分的端面2a的側部2as的均方根粗度Rq係0.03至0.15μm。亦可使偏光片2所具有的全部的端面2a的側部2as的均方根粗度Rq係0.03至0.15μm。具有Rq為0.03至0.15μm之側部2as之端面2a越多,則越容易抑制於偏光片2的第二邊S2側產生破裂。 The rectangular polarizer 2 has four end faces 2a. Among the plurality of end faces 2a of the polarizer 2, the root mean square roughness Rq of the side portions 2as of a part of the end faces 2a may be 0.03 to 0.15 μm. The root mean square roughness Rq of the side portions 2as of all the end faces 2a of the polarizing plate 2 may be 0.03 to 0.15 μm. The more the end face 2a having the side portion 2as of Rq of 0.03 to 0.15 μm, the more easily it is suppressed from being cracked on the second side S2 side of the polarizing plate 2.

構成偏光片2之樹脂,例如可為:聚乙烯醇系樹脂、聚乙酸乙烯酯樹脂、乙烯/乙酸乙烯酯共聚合樹脂(EVA)樹脂、聚醯胺樹脂或聚酯系樹脂。偏光片2可往一軸方向或二軸方向延伸。偏光片2可經碘或二色性染料染色。染色後之偏光片2可經硼酸處理。偏光片2亦可為於聚乙烯醇膜吸附定向有碘者。 The resin constituting the polarizer 2 may be, for example, a polyvinyl alcohol resin, a polyvinyl acetate resin, an ethylene/vinyl acetate copolymer resin (EVA) resin, a polyamide resin or a polyester resin. The polarizer 2 may extend in one axial direction or two axial directions. The polarizer 2 can be dyed with iodine or a dichroic dye. The dyed polarizer 2 can be treated with boric acid. The polarizer 2 may also be one in which iodine is adsorbed on the polyvinyl alcohol film.

偏光片2的厚度,例如可為:2至30μm、2至15μm、或2至10μm。一般而言,偏光片的厚度越薄, 越容易於偏光片產生破裂。但是,具備本實施形態之偏光片2的偏光板1中,即使於偏光片2的厚度為10μm以下時,亦可良好地抑制於偏光片2之破裂。 The thickness of the polarizing plate 2 can be, for example, 2 to 30 μm, 2 to 15 μm, or 2 to 10 μm. In general, the thinner the thickness of the polarizer, the easier it is to cause cracking of the polarizer. However, in the polarizing plate 1 including the polarizing plate 2 of the present embodiment, even when the thickness of the polarizing plate 2 is 10 μm or less, the crack of the polarizing plate 2 can be satisfactorily suppressed.

保護膜3例如可為:纖維素系樹脂(三乙醯纖維素等)、聚烯烴系樹脂(聚丙烯系樹脂等)、環狀烯烴系樹脂(降莰烯系樹脂等)、丙烯酸系樹脂(聚甲基丙烯酸甲酯系樹脂等)或聚酯系樹脂(聚對苯二甲酸乙二酯系樹脂等)。 The protective film 3 may be, for example, a cellulose resin (such as triacetin cellulose), a polyolefin resin (such as a polypropylene resin), a cyclic olefin resin (such as a decene-based resin), or an acrylic resin (for example). Polymethyl methacrylate resin or the like or polyester resin (polyethylene terephthalate resin or the like).

保護膜3的厚度可為5至90μm、5至80μm或5至50μm。 The protective film 3 may have a thickness of 5 to 90 μm, 5 to 80 μm, or 5 to 50 μm.

保護膜3可經由接著劑層而貼合於偏光片2的表面。亦可將構成保護膜3之樹脂的溶液塗佈於偏光片2上而形成塗膜,並乾燥塗膜,藉此直接於偏光片2的表面形成保護膜。 The protective film 3 can be attached to the surface of the polarizer 2 via an adhesive layer. The solution constituting the resin of the protective film 3 may be applied onto the polarizer 2 to form a coating film, and the coating film may be dried to form a protective film directly on the surface of the polarizing film 2.

構成接著劑層之樹脂,例如可為環氧樹脂。環氧樹脂例如可為氫化環氧樹脂、脂環式環氧樹脂或脂肪族環氧樹脂。亦可於環氧樹脂添加聚合起始劑(光陽離子聚合起始劑、熱陽離子聚合起始劑、光自由基聚合起始劑或熱自由基聚合起始劑等)、或其他添加劑(增敏劑等)。構成接著劑層之樹脂,例如可為:丙烯醯胺、丙烯酸酯、胺基甲酸酯丙烯酸酯及環氧丙烯酸酯等丙烯酸系樹脂。亦可於接著劑層使用含聚乙烯醇系樹脂之水系接著劑。 The resin constituting the adhesive layer may be, for example, an epoxy resin. The epoxy resin may be, for example, a hydrogenated epoxy resin, an alicyclic epoxy resin or an aliphatic epoxy resin. A polymerization initiator (photocationic polymerization initiator, thermal cationic polymerization initiator, photoradical polymerization initiator or thermal radical polymerization initiator, etc.) or other additives may be added to the epoxy resin (sensitization) Agent, etc.). The resin constituting the adhesive layer may be, for example, an acrylic resin such as acrylamide, acrylate, urethane acrylate or epoxy acrylate. A water-based adhesive containing a polyvinyl alcohol-based resin may also be used as the adhesive layer.

構成感壓式黏著劑層5之樹脂,例如可為丙烯酸系樹脂、聚矽氧系樹脂、聚酯、聚胺基甲酸酯、或聚 醚等。可將包含該等樹脂及任意的添加成分之溶液塗佈於偏光片2的表面而形成塗膜,並乾燥塗膜,藉此形成感壓式黏著劑層5。 The resin constituting the pressure-sensitive adhesive layer 5 may be, for example, an acrylic resin, a polyoxymethylene resin, a polyester, a polyurethane, or a polyether. A solution containing the resin and any optional component may be applied to the surface of the polarizer 2 to form a coating film, and the coating film may be dried to form the pressure-sensitive adhesive layer 5.

感壓式黏著劑層5的厚度,例如可為2至500μm、2至200μm或2至50μm。 The thickness of the pressure-sensitive adhesive layer 5 may be, for example, 2 to 500 μm, 2 to 200 μm, or 2 to 50 μm.

亦可將形成於分隔件(separator)上之感壓式黏著劑層5轉印於偏光片2的表面。分隔件,係以保護感壓式黏著劑層或防止異物附著等為目的,而貼附於偏光片2其他光學膜。分隔件為可剝離的膜。例如,將偏光板1貼附於圖像顯示元件時,係將分隔件剝離而露出感壓式黏著劑層。分隔件係於偏光板1之製造過程中暫時性使用,之後可從偏光板1剝離。構成分隔件之樹脂,例如可為聚乙烯系樹脂、聚丙烯系樹脂或聚酯系樹脂(聚對苯二甲酸乙二酯等)。 The pressure-sensitive adhesive layer 5 formed on a separator may be transferred onto the surface of the polarizer 2. The separator is attached to the other optical film of the polarizer 2 for the purpose of protecting the pressure-sensitive adhesive layer or preventing foreign matter from adhering. The separator is a peelable film. For example, when the polarizing plate 1 is attached to an image display element, the separator is peeled off to expose the pressure-sensitive adhesive layer. The separator is temporarily used in the manufacturing process of the polarizing plate 1, and then peeled off from the polarizing plate 1. The resin constituting the separator may be, for example, a polyethylene resin, a polypropylene resin, or a polyester resin (polyethylene terephthalate or the like).

分隔件的厚度,例如可為2至500μm、2至200μm或2至100μm。 The thickness of the separator may be, for example, 2 to 500 μm, 2 to 200 μm, or 2 to 100 μm.

反射型偏光片4(第二光學膜)例如可為由聚碳酸酯等所成之多層膜。反射型偏光片4的厚度,例如可為15至200μm。 The reflective polarizer 4 (second optical film) may be, for example, a multilayer film made of polycarbonate or the like. The thickness of the reflective polarizer 4 can be, for example, 15 to 200 μm.

偏光板1整體的厚度,例如可為10至500μm、10至300μm、或10至200μm。 The thickness of the entire polarizing plate 1 may be, for example, 10 to 500 μm, 10 to 300 μm, or 10 to 200 μm.

〔偏光板的端部之切削加工〕  [Cutting of the end of the polarizing plate]  

藉由以下所說明之偏光板1的端部之切削加工,可將 偏光板1所具備之偏光片2的端面2a之粗度曲線要素的平均高度Rc調控於0.05至1.7μm之範圍內。而且,藉由以下所說明之切削加工,可將偏光板1所具備之偏光片2的端面2a的側部2as的均方根粗度Rq調控於0.03至0.15μm之範圍內。以下參照第2圖至第5圖詳細說明切削加工。 The average height Rc of the thickness curve elements of the end faces 2a of the polarizer 2 included in the polarizing plate 1 can be adjusted to be in the range of 0.05 to 1.7 μm by the cutting process of the end portions of the polarizing plate 1 described below. Moreover, the root mean square roughness Rq of the side portion 2as of the end surface 2a of the polarizing plate 2 included in the polarizing plate 1 can be adjusted to be in the range of 0.03 to 0.15 μm by the cutting processing described below. The cutting process will be described in detail below with reference to Figs. 2 to 5 .

首先,製作具有與本實施形態之偏光板1相同的積層構造之複數個偏光板1A。各偏光板1A除了其端面未經切削之外,係與本實施形態之偏光板1相同。未經切削之偏光板1A的端面2a未變粗糙,故各偏光板1A所具備之偏光片2的端面2a的Rc未達0.05。而且,未經切削之各偏光板1A的端面2a的側部2as的Rq未達0.03。如第4圖及第5圖所示,重疊複數個偏光板1A而形成積層體100。各偏光板1A的尺寸完全相同,於積層體100中各偏光板1A的表面整體係完全地互相疊合。第4圖所示之積層體100的端面100a為包含偏光片2的端面之面。換言之,於積層體100的端面100a內,匯集各偏光板1A所具備之偏光片2的端面。如第4圖所示,積層體100的端面100a(換言之,偏光片2的端面)係與切削工具10之切削面S相對,且與切削面S上的切削刃接觸。為了圖示上的方便,積層體100係由4個偏光板1A所構成,惟構成積層體100之偏光板1A的數目並不特別受到限定。 First, a plurality of polarizing plates 1A having the same laminated structure as that of the polarizing plate 1 of the present embodiment are produced. Each of the polarizing plates 1A is the same as the polarizing plate 1 of the present embodiment except that the end faces thereof are not cut. The end surface 2a of the unpolarized polarizing plate 1A is not roughened, so that the Rc of the end surface 2a of the polarizing plate 2 of each of the polarizing plates 1A is less than 0.05. Further, the Rq of the side portion 2as of the end face 2a of each of the unpolarized polarizing plates 1A is less than 0.03. As shown in FIGS. 4 and 5, a plurality of polarizing plates 1A are stacked to form a laminated body 100. The size of each of the polarizing plates 1A is completely the same, and the entire surface of each of the polarizing plates 1A in the laminated body 100 is completely overlapped with each other. The end surface 100a of the laminated body 100 shown in FIG. 4 is a surface including the end surface of the polarizing plate 2. In other words, the end faces of the polarizers 2 included in the respective polarizing plates 1A are collected in the end faces 100a of the laminated body 100. As shown in Fig. 4, the end surface 100a of the laminated body 100 (in other words, the end surface of the polarizer 2) faces the cutting surface S of the cutting tool 10 and comes into contact with the cutting edge on the cutting surface S. For the convenience of illustration, the laminated body 100 is composed of four polarizing plates 1A, but the number of the polarizing plates 1A constituting the laminated body 100 is not particularly limited.

如第2圖所示,切削工具10係固定於支撐體10a(cutter arbor,軸桿)。切削工具10係對著旋轉軸線A進行旋轉。切削工具10的旋轉數(旋轉速度)可調 整自如。又,如第2圖至第5圖所示,切削工具10為圓盤狀。切削工具10的旋轉軸線A係與被切削的積層體100的端面100a(換言之,各偏光片2的端面)垂直相交。將積層體100於水平方向移動1mm的時間設為單位時間時,每單位時間之切削工具10的旋轉數會影響偏光片2的端面2a之粗度曲線要素的平均高度Rc。而且,每單位時間之切削工具10的旋轉數亦會影響偏光片2的端面2a的側部2as的均方根粗度Rq。每單位時間之切削工具10的旋轉數,例如可為3.5至14次或5.6至10.2次。切削工具10的旋轉數於該等範圍內時,容易將偏光片2的端面2a之粗度曲線要素的平均高度Rc調控為0.05至1.7μm。而且,切削工具10的旋轉數於上述範圍內時,容易將偏光片2的端面2a的側部2as的均方根粗度Rq調控為0.03至0.15。 As shown in Fig. 2, the cutting tool 10 is fixed to a support 10a (cutter arbor). The cutting tool 10 is rotated against the rotation axis A. The number of rotations (rotation speed) of the cutting tool 10 is adjustable. Further, as shown in FIGS. 2 to 5, the cutting tool 10 has a disk shape. The rotation axis A of the cutting tool 10 is perpendicular to the end surface 100a of the laminated body 100 to be cut (in other words, the end faces of the respective polarizers 2). When the time in which the laminated body 100 is moved by 1 mm in the horizontal direction is set as the unit time, the number of rotations of the cutting tool 10 per unit time affects the average height Rc of the thickness curve elements of the end face 2a of the polarizing plate 2. Moreover, the number of rotations of the cutting tool 10 per unit time also affects the root mean square roughness Rq of the side portion 2as of the end surface 2a of the polarizing plate 2. The number of rotations of the cutting tool 10 per unit time may be, for example, 3.5 to 14 times or 5.6 to 10.2 times. When the number of rotations of the cutting tool 10 is within these ranges, the average height Rc of the thickness curve elements of the end faces 2a of the polarizer 2 is easily adjusted to 0.05 to 1.7 μm. Further, when the number of rotations of the cutting tool 10 is within the above range, the root mean square roughness Rq of the side portion 2as of the end surface 2a of the polarizing plate 2 is easily adjusted to 0.03 to 0.15.

切削工具10具有相對於旋轉軸線A而言為垂直的切削面S。因此,切削面S與被切削的積層體100的端面100a平行。換言之,切削面S與被切削的偏光片2的端面2a平行。如第2圖及第3圖所示,於切削面S上設有包含切削部11a、11b及11c的第1切削部群,與包含切削部11d、11e及11f的第2切削部群。各切削部具有用以削取端面之切削刃B。各切削部係於旋轉軸線A的周圍配置成大致等間隔。各切削部係由切削面S朝被切削的積層體100的端面100a突出。切削刃B係配置於各切削部之突出的頂面。各切削部所具有的切削刃B,係以相對於切削面S而言為平行且延伸存在之方式配置。換言之,各切 削部所具有的切削刃B,係以相對於積層體100中的各偏光片2的端面2a而言為平行且延伸存在之方式配置。又,為了圖示上的方便,第4圖及第5圖中係省略設置於切削工具10之切削面S的各切削部,惟與第2圖至第5圖所示之切削工具10係全為相同者。 The cutting tool 10 has a cutting surface S that is perpendicular to the rotation axis A. Therefore, the cutting surface S is parallel to the end surface 100a of the laminated body 100 to be cut. In other words, the cutting surface S is parallel to the end surface 2a of the polarizer 2 to be cut. As shown in FIGS. 2 and 3, the cutting surface S is provided with a first cutting portion group including the cutting portions 11a, 11b, and 11c, and a second cutting portion group including the cutting portions 11d, 11e, and 11f. Each cutting portion has a cutting edge B for cutting an end surface. Each of the cutting portions is disposed at substantially equal intervals around the rotation axis A. Each of the cutting portions protrudes from the cutting surface S toward the end surface 100a of the laminated body 100 to be cut. The cutting edge B is disposed on the protruding top surface of each of the cutting portions. The cutting edge B of each cutting portion is disposed so as to be parallel to the cutting surface S and extend. In other words, the cutting edges B of the respective cutting portions are arranged to extend parallel to the end faces 2a of the respective polarizers 2 in the laminated body 100. In addition, for the convenience of illustration, in FIGS. 4 and 5, each cutting portion provided on the cutting surface S of the cutting tool 10 is omitted, but the cutting tool 10 shown in FIGS. 2 to 5 is completely For the same person.

使切削工具10朝旋轉方向(第2圖至第5圖中的箭號方向)旋轉時,切削部11a、11b及11c係依此順序與積層體100的端面100a對接,切削該端面100a(各偏光片2的端面2a)。由切削面S算起至切削部11a的切削刃B為止的距離,係較由切削面S算起至切削部11b之切削刃B為止的距離更小。由切削面S算起至切削部11b之切削刃B為止的距離,係較由切削面S算起至切削部11c之切削刃B為止的距離更小。亦即,切削部11b之切削刃B的突出高度係較切削部11a的切削刃B的突出高度更高,切削部11c之切削刃B的突出高度係較切削部11b之切削刃B的突出高度更高。 When the cutting tool 10 is rotated in the rotation direction (the arrow direction in FIGS. 2 to 5), the cutting portions 11a, 11b, and 11c are in contact with the end surface 100a of the laminated body 100 in this order, and the end surface 100a is cut (each End face 2a) of the polarizer 2. The distance from the cutting surface S to the cutting edge B of the cutting portion 11a is smaller than the distance from the cutting surface S to the cutting edge B of the cutting portion 11b. The distance from the cutting surface S to the cutting edge B of the cutting portion 11b is smaller than the distance from the cutting surface S to the cutting edge B of the cutting portion 11c. That is, the protruding height of the cutting edge B of the cutting portion 11b is higher than the protruding height of the cutting edge B of the cutting portion 11a, and the protruding height of the cutting edge B of the cutting portion 11c is higher than the protruding height of the cutting edge B of the cutting portion 11b. higher.

使切削工具10朝旋轉方向旋轉時,切削部11d、11e及11f係依此順序與積層體100的端面100a對接,切削該端面100a(各偏光片2的端面2a)。由切削面S算起至切削部11d之切削刃B為止的距離,係較由切削面S算起至切削部11e之切削刃B為止的距離更小。由切削面S算起至切削部11e之切削刃B為止的距離,係較由切削面S算起至切削部11f之切削刃B為止的距離更小。亦即,切削部11e之切削刃B的突出高度係較切削部11d 之切削刃B的突出高度更高,切削部11f之切削刃B的突出高度係較切削部11e之切削刃B的突出高度更高。 When the cutting tool 10 is rotated in the rotational direction, the cutting portions 11d, 11e, and 11f are in contact with the end surface 100a of the laminated body 100 in this order, and the end surface 100a (the end surface 2a of each polarizing plate 2) is cut. The distance from the cutting surface S to the cutting edge B of the cutting portion 11d is smaller than the distance from the cutting surface S to the cutting edge B of the cutting portion 11e. The distance from the cutting surface S to the cutting edge B of the cutting portion 11e is smaller than the distance from the cutting surface S to the cutting edge B of the cutting portion 11f. That is, the protruding height of the cutting edge B of the cutting portion 11e is higher than the protruding height of the cutting edge B of the cutting portion 11d, and the protruding height of the cutting edge B of the cutting portion 11f is higher than the protruding height of the cutting edge B of the cutting portion 11e. higher.

如第3圖所示,由旋轉軸線A算起至切削部11b之切削刃B為止的距離,係較由旋轉軸線A算起至切削部11a的切削刃B為止的距離更短。由旋轉軸線A算起至切削部11c之切削刃B為止的距離,係較由旋轉軸線A算起至切削部11b之切削刃B為止的距離更短。由旋轉軸線A算起至切削部11e之切削刃B為止的距離,係較由旋轉軸線A算起至切削部11d之切削刃B為止的距離更短。由旋轉軸線A算起至切削部11f之切削刃B為止的距離,係較至切削部11e之切削刃B為止的距離更短。 As shown in Fig. 3, the distance from the rotation axis A to the cutting edge B of the cutting portion 11b is shorter than the distance from the rotation axis A to the cutting edge B of the cutting portion 11a. The distance from the rotation axis A to the cutting edge B of the cutting portion 11c is shorter than the distance from the rotation axis A to the cutting edge B of the cutting portion 11b. The distance from the rotation axis A to the cutting edge B of the cutting portion 11e is shorter than the distance from the rotation axis A to the cutting edge B of the cutting portion 11d. The distance from the rotation axis A to the cutting edge B of the cutting portion 11f is shorter than the distance from the cutting edge B of the cutting portion 11e.

切削部11a、11b、11d、11e為粗削用,該等切削刃B係例如以聚晶金剛石所構成。各切削部群中,位於最後端之切削部11c、11f為完善加工用,該等切削刃B係例如以單晶金剛石所構成。惟,各切削刃B的材質並不受限定。 The cutting portions 11a, 11b, 11d, and 11e are used for roughing, and the cutting edges B are made of, for example, polycrystalline diamond. Among the cutting portion groups, the cutting portions 11c and 11f at the rearmost end are used for perfect machining, and the cutting edges B are formed of, for example, single crystal diamond. However, the material of each cutting edge B is not limited.

各切削部藉由切削工具10的旋轉而描繪的圓,較佳為與積層體100中的各偏光片2的表面(朝向Z軸方向之各偏光片2的表面)幾乎垂直地相交。例如,與旋轉軸線A之距離最短的切削部11c及11f之各切削刃B所描繪的圓,較佳為與積層體100中的各偏光片2的表面幾乎垂直地相交。換言之,如第5圖所示,相對於各偏光片2的表面之各切削刃B的進入角θ係以越接近90°為越佳。換言之,相對於朝向Z軸方向之積層體100的表面之 各切削刃B的進入角θ係以越接近90°為越佳。例如,與旋轉軸線A之距離最短的切削部11c及11f之各切削刃B的進入角θ係以越接近90°為越佳。為了使進入角θ接近90°,切削工具10之切削面S的直徑係以大於積層體100的厚度為佳。而且,切削工具10之切削面S的直徑,係以足夠將堆疊的全部偏光板1A的各端面一併均勻地進行切削之程度的大小為較佳。如第4圖及第5圖所示,積層體100所配置的高度係以與切削工具10的旋轉軸線A的高度大致相同為較佳。換言之,平行於各偏光片2的端面2a的方向(Z軸方向)之積層體100的位置係以與同方向之切削工具10的旋轉軸線A的位置大致相同為較佳。換言之,平行於積層體100的端面100a的方向之積層體100的位置係以與同方向之切削工具10的旋轉軸線A的位置大致相同為較佳。亦可將調整切削刃B的進入角θ作為目的,而調整積層體100的厚度。換言之,可將調整切削刃B的進入角θ作為目的,而調整構成積層體100之偏光板1A的數目。與切削工具10的直徑相比,積層體100的厚度越小,則切削刃B的進入角θ越接近90°。亦可將調整積層體100與切削工具10的旋轉軸線A之相對位置關係作為目的,而調整積層體100的厚度。換言之,亦可將調整積層體100與切削工具10的旋轉軸線A的相對位置關係作為目的,而調整構成積層體100之偏光板1A的數目。如以上所述,將各切削刃B的進入角θ調整為大致垂直,並將積層體100的位置與切削工具10的旋轉軸線A的位 置對合,且適當地調整切削工具10的旋轉數,藉此容易將偏光板1所具備之偏光片2的端面2a之粗度曲線要素的平均高度Rc調控於0.05至1.7μm之範圍內。而且,將各切削刃B的進入角θ調整至大致垂直,將積層體100的位置與切削工具10的旋轉軸線A的位置對合,且適當地調整切削工具10的旋轉數,藉此容易將偏光板1所具備之偏光片2的側部2as的均方根粗度Rq調控於0.03至0.15μm之範圍內。為了將Rc及Rq分別調控於上述之範圍內所需的切削工具10的旋轉數,可藉由予備實驗掌握。為了調整積層體100與切削工具10的旋轉軸線A之相對位置關係,切削工具10可在相對於積層體100的端面100a(各偏光片2的端面2a)而言為平行的方向移動自如。例如,切削工具10的位置可在Z軸方向(上下方向)調整自如。此時,於Z軸方向之積層體100的位置可為固定。在相對於積層體100的端面100a(各偏光片2的端面2a)而言為平行的方向,積層體100可移動自如。例如,於Z軸方向(例如上下方向)之積層體100的位置可調整自如。此時,於Z軸方向之切削工具10的位置可為固定。 The circle drawn by the rotation of the cutting tool 10 in each cutting portion preferably intersects the surface of each of the polarizers 2 in the laminated body 100 (the surface of each of the polarizers 2 in the Z-axis direction) almost perpendicularly. For example, the circle drawn by each of the cutting edges B of the cutting portions 11c and 11f having the shortest distance from the rotation axis A preferably intersects the surface of each of the polarizers 2 in the laminated body 100 almost perpendicularly. In other words, as shown in Fig. 5, the entry angle θ of each of the cutting edges B with respect to the surface of each of the polarizers 2 is preferably as close as 90°. In other words, the entry angle θ of each of the cutting edges B with respect to the surface of the laminated body 100 facing the Z-axis direction is preferably as close as 90°. For example, the entry angle θ of each of the cutting edges B of the cutting portions 11c and 11f having the shortest distance from the rotation axis A is preferably closer to 90°. In order to bring the entry angle θ close to 90°, the diameter of the cutting face S of the cutting tool 10 is preferably larger than the thickness of the laminated body 100. Further, the diameter of the cutting surface S of the cutting tool 10 is preferably a size sufficient to uniformly cut the respective end faces of all of the stacked polarizing plates 1A. As shown in FIGS. 4 and 5, the height of the laminated body 100 is preferably substantially the same as the height of the axis of rotation A of the cutting tool 10. In other words, the position of the layered body 100 parallel to the direction (Z-axis direction) of the end faces 2a of the respective polarizers 2 is preferably substantially the same as the position of the axis of rotation A of the cutting tool 10 in the same direction. In other words, the position of the laminated body 100 parallel to the direction of the end surface 100a of the laminated body 100 is preferably substantially the same as the position of the rotational axis A of the cutting tool 10 in the same direction. The thickness of the laminated body 100 may be adjusted for the purpose of adjusting the entry angle θ of the cutting edge B. In other words, the number of the polarizing plates 1A constituting the laminated body 100 can be adjusted for the purpose of adjusting the entry angle θ of the cutting edge B. The smaller the thickness of the laminated body 100 is, the closer the entry angle θ of the cutting edge B is to 90° as compared with the diameter of the cutting tool 10. The thickness of the laminated body 100 may be adjusted for the purpose of adjusting the relative positional relationship between the laminated body 100 and the rotational axis A of the cutting tool 10. In other words, the number of the polarizing plates 1A constituting the laminated body 100 can be adjusted for the purpose of adjusting the relative positional relationship between the laminated body 100 and the rotational axis A of the cutting tool 10. As described above, the entry angle θ of each cutting edge B is adjusted to be substantially perpendicular, and the position of the laminated body 100 is aligned with the position of the rotation axis A of the cutting tool 10, and the number of rotations of the cutting tool 10 is appropriately adjusted. This makes it easy to adjust the average height Rc of the roughness curve elements of the end faces 2a of the polarizing plate 2 included in the polarizing plate 1 to be in the range of 0.05 to 1.7 μm. Further, the entry angle θ of each cutting edge B is adjusted to be substantially vertical, and the position of the laminated body 100 is aligned with the position of the rotation axis A of the cutting tool 10, and the number of rotations of the cutting tool 10 is appropriately adjusted, whereby it is easy to The root mean square roughness Rq of the side portion 2as of the polarizing plate 2 included in the polarizing plate 1 is controlled in the range of 0.03 to 0.15 μm. The number of rotations of the cutting tool 10 required to adjust Rc and Rq to the above-described ranges, respectively, can be grasped by preliminary experiments. In order to adjust the relative positional relationship between the laminated body 100 and the rotational axis A of the cutting tool 10, the cutting tool 10 can be moved in a direction parallel to the end surface 100a of the laminated body 100 (the end faces 2a of the polarizing plates 2). For example, the position of the cutting tool 10 can be adjusted freely in the Z-axis direction (up and down direction). At this time, the position of the laminated body 100 in the Z-axis direction can be fixed. The laminated body 100 is movably movable in a direction parallel to the end surface 100a of the laminated body 100 (the end surface 2a of each polarizing plate 2). For example, the position of the laminated body 100 in the Z-axis direction (for example, the up-and-down direction) can be adjusted freely. At this time, the position of the cutting tool 10 in the Z-axis direction may be fixed.

構成積層體100之各偏光板1A中,偏光片2較佳為位於較保護膜3更上方的位置。而且,保護膜3的彈性模數較佳為高於偏光片2的彈性模數。如第2圖至第5圖所示,切削工具10的各切削刃B,係由積層體100的上側往下側移動。因此,偏光片2位於較保護膜3更上方之處時,各切削刃B係先與偏光片2接觸,繼而與保護膜 3接觸。換言之,各切削刃B係由彈性模數低的偏光片2進入,繼而進入彈性模數高的保護膜3。以此方式配置偏光片2及保護膜3時,係容易將偏光片2的端面2a之粗度曲線要素的平均高度Rc調控於0.05至1.7μm之範圍內,容易將偏光片2的側部2as的均方根粗度Rq調控於0.03至0.15μm之範圍內。 In each of the polarizing plates 1A constituting the laminated body 100, the polarizing plate 2 is preferably located above the protective film 3. Moreover, the elastic modulus of the protective film 3 is preferably higher than the elastic modulus of the polarizing plate 2. As shown in FIGS. 2 to 5, each cutting edge B of the cutting tool 10 is moved downward from the upper side of the laminated body 100. Therefore, when the polarizer 2 is located above the protective film 3, each of the cutting edges B comes into contact with the polarizer 2, and then comes into contact with the protective film 3. In other words, each of the cutting edges B enters the polarizer 2 having a low modulus of elasticity, and then enters the protective film 3 having a high modulus of elasticity. When the polarizer 2 and the protective film 3 are disposed in this manner, it is easy to adjust the average height Rc of the thickness curve elements of the end face 2a of the polarizer 2 in the range of 0.05 to 1.7 μm, and the side portion 2 of the polarizer 2 is easily removed. The root mean square roughness Rq is controlled in the range of 0.03 to 0.15 μm.

可使旋轉的切削工具10於與積層體100的端面100a平行的方向(Y方向)以一定速度移動。隨著切削工具10的移動,積層體100的端面100a(各偏光片2的端面2a)被徐緩地切削。此時,可固定積層體100的位置。於與積層體100的端面100a平行的方向(Y方向),亦可使積層體100以一定的速度接近切削工具10。隨著積層體100的移動,積層體100的端面100a(各偏光片2的端面2a)被徐緩地切削。此時,切削工具10的位置可為固定。 The rotating cutting tool 10 can be moved at a constant speed in a direction (Y direction) parallel to the end surface 100a of the laminated body 100. As the cutting tool 10 moves, the end faces 100a of the laminated body 100 (the end faces 2a of the respective polarizers 2) are gently cut. At this time, the position of the laminated body 100 can be fixed. The layered body 100 can also approach the cutting tool 10 at a constant speed in a direction (Y direction) parallel to the end surface 100a of the laminated body 100. As the laminated body 100 moves, the end surface 100a of the laminated body 100 (the end surface 2a of each polarizer 2) is gently cut. At this time, the position of the cutting tool 10 can be fixed.

藉由上述之切削方法,與以往所採行之藉由雷射進行積層體100的裁切相比,係能以較高的精度調整構成積層體100之各偏光板1A的尺寸。 According to the cutting method described above, the size of each of the polarizing plates 1A constituting the laminated body 100 can be adjusted with higher precision than the conventional cutting of the laminated body 100 by laser.

以上,係說明本發明之適宜的實施形態,惟本發明並不受上述實施形態任何限定。 The above is a description of suitable embodiments of the present invention, but the present invention is not limited to the above embodiments.

例如,偏光板可具備:偏光片、疊合於偏光片之第一光學膜(例如保護膜)、疊合於第一光學膜之感壓式黏著劑層、疊合於感壓式黏著劑層之第二光學膜(例如反射型偏光片)。 For example, the polarizing plate may be provided with: a polarizer, a first optical film (for example, a protective film) laminated on the polarizer, a pressure-sensitive adhesive layer laminated on the first optical film, and a laminated pressure sensitive adhesive layer. A second optical film (eg, a reflective polarizer).

第一光學膜或第二光學膜亦可為:附防眩功能之膜、附抗表面反射功能之膜、反射膜、半透射反射膜、視野角補償膜、離型膜、光學補償層、觸控感應層、抗靜電層或防汙層。當然,第一光學膜亦可為反射型偏光片,第二光學膜亦可為保護膜。 The first optical film or the second optical film may also be: a film with anti-glare function, a film with anti-surface reflection function, a reflective film, a semi-transmissive reflective film, a viewing angle compensation film, a release film, an optical compensation layer, and a touch Control the sensing layer, antistatic layer or antifouling layer. Of course, the first optical film may also be a reflective polarizer, and the second optical film may also be a protective film.

〔實施例〕  [Examples]  

以下列舉實施例及比較例以進一步具體說明本發明之內容。又,本發明不限定於下述實施例。 The examples and comparative examples are enumerated below to further specifically describe the contents of the present invention. Further, the present invention is not limited to the following embodiments.

〔實施例1〕  [Example 1]   (1)偏光片之製作  (1) Production of polarizer  

準備厚度為20μm之聚乙烯醇膜。此聚乙烯醇膜的平均聚合度為約2400,皂化度為99.9莫耳%以上。 A polyvinyl alcohol film having a thickness of 20 μm was prepared. The polyvinyl alcohol film had an average degree of polymerization of about 2,400 and a degree of saponification of 99.9 mol% or more.

將聚乙烯醇膜以乾式進行約4倍的一軸延伸。保持延伸造成之聚乙烯醇膜的伸展狀態,同時將聚乙烯醇膜浸漬於40℃的純水1分鐘。繼而,將聚乙烯醇膜浸漬於第一染色液(水溶液)60秒鐘。第一染色液的溫度係調整為28℃。第一染色液中之碘:碘化鉀:水的質量比為0.1:5:100。繼而,將聚乙烯醇膜於第二染色液(水溶液)中浸漬300秒鐘。第二染色液的溫度係調整為68℃。第二染色液中之碘化鉀:硼酸:水的質量比為10.5:7.5:100。繼而,將聚乙烯醇膜以純水洗淨5秒鐘。純水的溫度係調整為5℃。將洗淨後之聚乙烯醇膜在70℃乾燥180秒鐘。藉由以上程序,得到屬於長條的帶狀膜之偏光片。偏光片係於經 一軸延伸之聚乙烯醇膜吸附定向有碘。偏光片的厚度為7μm。 The polyvinyl alcohol film was stretched about 4 times in one axis in a dry manner. The stretched state of the polyvinyl alcohol film caused by the stretching was maintained while the polyvinyl alcohol film was immersed in pure water at 40 ° C for 1 minute. Then, the polyvinyl alcohol film was immersed in the first staining solution (aqueous solution) for 60 seconds. The temperature of the first staining solution was adjusted to 28 °C. The mass ratio of iodine in the first staining solution: potassium iodide: water is 0.1:5:100. Then, the polyvinyl alcohol film was immersed in the second staining solution (aqueous solution) for 300 seconds. The temperature of the second staining solution was adjusted to 68 °C. The mass ratio of potassium iodide:boric acid:water in the second dyeing solution was 10.5:7.5:100. Then, the polyvinyl alcohol film was washed with pure water for 5 seconds. The temperature of the pure water was adjusted to 5 °C. The washed polyvinyl alcohol film was dried at 70 ° C for 180 seconds. By the above procedure, a polarizer of a strip film belonging to a long strip is obtained. The polarizer is oriented to adsorb iodine on a polyaxially stretched polyvinyl alcohol film. The thickness of the polarizer was 7 μm.

(2)水系接著劑的調製  (2) Modulation of water-based adhesives  

將聚乙烯醇粉末溶解於95℃的熱水,調製聚乙烯醇水溶液。將水溶液中之聚乙烯醇的濃度調整為3質量%。聚乙烯醇粉末係使用KURARAY股份公司製之「KL-318」。聚乙烯醇粉末的平均聚合度為1800。於聚乙烯醇水溶液中混合交聯劑,得到水系接著劑。交聯劑係使用田岡化學工業股份公司製之「Sumirez Resin 650」。添加至聚乙烯醇水溶液之交聯劑的質量係調整為相對於聚乙烯醇粉末2質量份為1質量份。 The polyvinyl alcohol powder was dissolved in hot water at 95 ° C to prepare an aqueous polyvinyl alcohol solution. The concentration of the polyvinyl alcohol in the aqueous solution was adjusted to 3% by mass. As the polyvinyl alcohol powder, "KL-318" manufactured by KURARAY Co., Ltd. was used. The polyvinyl alcohol powder had an average degree of polymerization of 1,800. The crosslinking agent was mixed with the polyvinyl alcohol aqueous solution to obtain a water-based adhesive. For the crosslinking agent, "Sumirez Resin 650" manufactured by Takaoka Chemical Industry Co., Ltd. was used. The mass of the crosslinking agent added to the aqueous polyvinyl alcohol solution was adjusted to be 1 part by mass based on 2 parts by mass of the polyvinyl alcohol powder.

(3)單面保護偏光板的製作  (3) Production of single-sided protective polarizer  

將上述之偏光片於其長方向連續地運送。於運送偏光片的同時,由卷軸體連續地送出保護膜,運送保護膜,同時對保護膜施行電暈處理。保護膜係使用日本zeon股份公司製之ZEONOR膜「ZF 14-023」。保護膜的厚度為23μm。運送偏光片及保護膜,同時由卷軸體連續地送出剝離膜,並運送剝離膜。剝離膜係使用Konica Minolta股份公司製之三乙醯纖維素膜(TAC膜)「KC8UX2MW」。剝離膜的厚度為80μm。剝離膜未經施行皂化處理。 The polarizer described above is continuously conveyed in the longitudinal direction thereof. While the polarizer is being transported, the protective film is continuously fed from the reel body, and the protective film is transported while the protective film is subjected to corona treatment. The protective film was a ZEONOR film "ZF 14-023" manufactured by Zeon Co., Ltd., Japan. The thickness of the protective film was 23 μm. The polarizer and the protective film are transported, and the release film is continuously fed from the reel body, and the release film is transported. As the release film, a triacetyl cellulose film (TAC film) "KC8UX2MW" manufactured by Konica Minolta Co., Ltd. was used. The thickness of the release film was 80 μm. The release film was not subjected to saponification treatment.

其次,使上述水系接著劑介於偏光片與保護膜之間,使純水介於偏光片與剝離膜之間,並將該等以一 對貼合輥夾起,藉此得到積層膜。此積層膜係具備:偏光片、疊合於偏光片的一表面之水系接著劑層、疊合於水系接著劑層之保護膜、疊合於偏光片的另一表面之純水層、疊合於純水層之剝離膜者。將此積層膜運送至乾燥裝置,將水系接著劑層進行乾燥,同時揮發去除純水層。乾燥裝置內的溫度係調整為80℃。乾燥時間為300秒。藉由從乾燥後之積層體將剝離膜進行剝離,得到單面保護偏光板。此單面保護偏光板為具備:偏光片、疊合於偏光片的一表面之經乾燥的水系接著劑層、疊合於水系接著劑層之保護膜者。 Next, the water-based adhesive is interposed between the polarizer and the protective film so that pure water is interposed between the polarizer and the release film, and the layers are sandwiched by a pair of bonding rolls, whereby a laminated film is obtained. The laminated film system includes a polarizer, a water-based adhesive layer laminated on one surface of the polarizer, a protective film laminated on the aqueous adhesive layer, a pure water layer laminated on the other surface of the polarizer, and a laminate The release film in the pure water layer. The laminated film is conveyed to a drying device, and the aqueous adhesive layer is dried while volatilizing to remove the pure water layer. The temperature in the drying apparatus was adjusted to 80 °C. The drying time is 300 seconds. The peeling film was peeled off from the laminated body after drying to obtain a single-sided protective polarizing plate. The one-side protective polarizing plate is provided with a polarizing plate, a dried water-based adhesive layer laminated on one surface of the polarizer, and a protective film laminated on the aqueous adhesive layer.

(4)附增亮膜之偏光板的製作  (4) Production of polarizing plate with brightness enhancement film  

於上述的單面保護偏光板所具備之偏光片的表面,經由感壓式黏著劑層貼合增亮膜,得到附增亮膜之偏光板。貼合時,以使偏光片之延伸方向與增亮膜之延伸軸成為平行之方式,調整單面保護偏光板及增亮膜各自的朝向。感壓式黏著劑層係使用丙烯酸系樹脂。增亮膜係使用3M股份公司製之反射型偏光片之「APF」。 On the surface of the polarizer provided on the one-side protective polarizing plate described above, a brightness enhancement film is bonded via a pressure-sensitive adhesive layer to obtain a polarizing plate with a brightness enhancement film. At the time of bonding, the orientation of each of the one-side protective polarizing plate and the brightness enhancing film is adjusted so that the extending direction of the polarizer is parallel to the extending axis of the brightness enhancing film. An acrylic resin is used for the pressure-sensitive adhesive layer. As the brightness enhancement film, "APF" of a reflective polarizer manufactured by 3M Co., Ltd. was used.

(5)附分隔件之偏光板的製作  (5) Production of polarizer with separator  

準備覆有感壓式黏著劑層之膜狀的分隔件。感壓式黏著劑層係使用丙烯酸系樹脂。將分隔件經由感壓式黏著劑層貼附於上述附增亮膜之偏光板所具備之增亮膜的表面,得到附分隔件之偏光板。 A film-shaped separator coated with a pressure-sensitive adhesive layer is prepared. An acrylic resin is used for the pressure-sensitive adhesive layer. The separator is attached to the surface of the brightness enhancement film provided on the polarizing plate with the brightness enhancement film via a pressure-sensitive adhesive layer to obtain a polarizing plate with a separator.

附分隔件之偏光板,係具備:偏光片、疊合於偏光片的一表面之水系接著劑層、疊合於水系接著劑層之保護膜(第一光學膜)、疊合於偏光片的另一表面之第一感壓式黏著劑層、疊合於第一感壓式黏著劑層之增亮膜(第二光學膜)、疊合於增亮膜之第二感壓式黏著劑層、疊合於第二感壓式黏著劑層之分隔件者。 The polarizing plate with a separator includes a polarizer, a water-based adhesive layer laminated on one surface of the polarizer, a protective film (first optical film) laminated on the aqueous adhesive layer, and a superimposed on the polarizer. a first pressure-sensitive adhesive layer on the other surface, a brightness enhancement film (second optical film) laminated on the first pressure-sensitive adhesive layer, and a second pressure-sensitive adhesive layer laminated on the brightness enhancement film a separator laminated to the second pressure-sensitive adhesive layer.

(6)切削加工  (6) Cutting processing  

將上述附分隔件之偏光板裁切為120mm×70mm之尺寸,得到100片偏光板。裁切係使用Super Cutter。100片偏光板的構造、組成及尺寸係相同。對齊100片偏光板的四邊,將100片偏光板重疊,藉此得到積層體。以下,為了說明上的方便,係將包含100片偏光板之積層體視為與第4圖及第5圖所示之積層體100相同。使用切削工具,切削積層體100所具有的4個端面100a。4個端面100a的切削加工之方法係完全相同。實施例所使用的切削工具,除了第1切削部群及第2切削部群分別具有5個切削部以外,係與第2圖至第5圖所示之切削工具10相同。以下為了方便說明,係將實施例所使用之切削工具視為與第2圖至第5圖所示之切削工具10相同。以下,將各圖中的Z軸方向視為上方向,將X軸方向及Y軸方向視為水平方向。形成積層體100時,係以在各偏光板1A中偏光片2位於保護膜3之上之方式重疊100片偏光板1A。 The polarizing plate with the above-mentioned separator was cut into a size of 120 mm × 70 mm to obtain 100 polarizing plates. The cutting system uses Super Cutter. The structure, composition and size of the 100 polarizing plates are the same. The four sides of the 100 polarizing plates were aligned, and 100 polarizing plates were overlapped, thereby obtaining a laminated body. Hereinafter, for the convenience of explanation, the laminated body including 100 polarizing plates is regarded as the same as the laminated body 100 shown in FIGS. 4 and 5. The four end faces 100a of the laminated body 100 are cut using a cutting tool. The cutting process of the four end faces 100a is identical. The cutting tool used in the embodiment is the same as the cutting tool 10 shown in FIGS. 2 to 5 except that the first cutting portion group and the second cutting portion group each have five cutting portions. Hereinafter, for convenience of explanation, the cutting tool used in the embodiment is considered to be the same as the cutting tool 10 shown in FIGS. 2 to 5. Hereinafter, the Z-axis direction in each drawing is regarded as the upper direction, and the X-axis direction and the Y-axis direction are regarded as the horizontal direction. When the laminated body 100 is formed, 100 polarizing plates 1A are stacked so that the polarizing plate 2 is positioned on the protective film 3 in each polarizing plate 1A.

以5個切削刃B的突出高度沿著與切削工具 10的旋轉方向為相反的方向而逐漸變高之方式,將各切削部群的5個切削刃B配置於切削面S上。而且,以由旋轉軸線A算起至切削部之切削刃B為止的距離沿著與切削工具10的旋轉方向為相反的方向而逐漸變短之方式,將各切削部群的5個切削部配置於切削面S上。將構成第1切削部群及第2切削部群的共計10個之切削部以圍起旋轉軸線A之方式等間隔配置。隔著旋轉軸線A而相對之一對切削刃B的高度為相同。隔著旋轉軸線A而相對之一對切削部之切削刃B與旋轉軸線A的距離為相同。切削工具10的各切削刃群係具有高度不同的5個切削刃B,故切削工具10的一次旋轉便相當於深度不同的5個階段之切削。 The five cutting edges B of the respective cutting portion groups are placed on the cutting surface S such that the protruding heights of the five cutting edges B gradually increase in a direction opposite to the direction of rotation of the cutting tool 10. Further, the distance from the rotation axis A to the cutting edge B of the cutting portion is gradually shortened in a direction opposite to the rotation direction of the cutting tool 10, and the five cutting portions of each cutting portion group are arranged. On the cutting surface S. A total of ten cutting portions constituting the first cutting portion group and the second cutting portion group are arranged at equal intervals so as to surround the rotation axis A. The height of the pair of cutting edges B is the same relative to each other across the rotation axis A. The distance between the cutting edge B of the cutting portion and the rotation axis A is the same across the rotation axis A. Since each cutting edge group of the cutting tool 10 has five cutting edges B having different heights, one rotation of the cutting tool 10 corresponds to cutting of five stages having different depths.

積層體100的端面100a的切削加工中,係使用一對的切削工具10。一對的切削工具10之切削面S係相向。以使積層體100能容納於一對的切削工具10之間之方式,調整一對的切削工具10的間隔。以切削工具10的旋轉軸線A成為水平之方式,調整切削工具10的朝向。固定各切削工具10的位置,使各切削工具10以旋轉軸線A為中心旋轉。以使積層體100的端面100a垂直於切削工具10的旋轉軸線A(切削面S之法線)之方式,調整積層體100的端面100a的朝向。而且,以使積層體100的表面成為水平之方式,調整積層體100的朝向。 In the cutting process of the end surface 100a of the laminated body 100, a pair of cutting tools 10 are used. The cutting faces S of the pair of cutting tools 10 are opposed to each other. The interval between the pair of cutting tools 10 is adjusted so that the laminated body 100 can be accommodated between the pair of cutting tools 10. The orientation of the cutting tool 10 is adjusted such that the rotation axis A of the cutting tool 10 is horizontal. The position of each cutting tool 10 is fixed, and each cutting tool 10 is rotated about the rotation axis A. The orientation of the end surface 100a of the laminated body 100 is adjusted so that the end surface 100a of the laminated body 100 is perpendicular to the rotation axis A of the cutting tool 10 (the normal to the cutting surface S). Further, the orientation of the laminated body 100 is adjusted so that the surface of the laminated body 100 is horizontal.

將具有與積層體100相同的厚度且較積層體100小一圈的合成樹脂盤配置於積層體100之下,調整積層體100所配置的高度。如第4圖及第5圖所示,藉由調 整積層體100所配置的高度,各切削刃B對於積層體100中的各偏光片2的表面之進入角θ成為大致垂直,積層體100所配置的高度成為與切削工具10的旋轉軸線A的高度大致相同。積層體100所配置的高度之調整所使用的合成樹脂盤的厚度為60mm。 A synthetic resin disk having the same thickness as the laminated body 100 and being smaller than the laminated body 100 is placed under the laminated body 100, and the height at which the laminated body 100 is placed is adjusted. As shown in FIGS. 4 and 5, by adjusting the height at which the laminated body 100 is disposed, the entry angle θ of each cutting edge B with respect to the surface of each polarizer 2 in the laminated body 100 is substantially perpendicular, and the laminated body 100 is The height of the arrangement is substantially the same as the height of the rotation axis A of the cutting tool 10. The thickness of the synthetic resin disk used for adjusting the height of the laminated body 100 was 60 mm.

切削加工中,係將積層體100所配置的高度維持一定。切削加工中,係使積層體100於水平方向(Y軸方向)以一定的速度移動,將積層體100徐緩地導入至旋轉的一對切削工具10之間。換言之,係藉由一切削工具10之切削面S而徐緩地切削積層體100的一個端面100a,同時藉由另一切削工具10之切削面S而徐緩地切削積層體100的另一個端面100a。使積層體100於水平方向(Y軸方向)持續移動,直到積層體100的端面100a整體被切削為止。 In the cutting process, the height at which the laminated body 100 is placed is maintained constant. In the cutting process, the laminated body 100 is moved at a constant speed in the horizontal direction (Y-axis direction), and the laminated body 100 is gradually introduced between the pair of rotating cutting tools 10. In other words, one end surface 100a of the laminated body 100 is slowly cut by the cutting surface S of the cutting tool 10, and the other end surface 100a of the laminated body 100 is slowly cut by the cutting surface S of the other cutting tool 10. The laminated body 100 is continuously moved in the horizontal direction (Y-axis direction) until the entire end surface 100a of the laminated body 100 is cut.

各偏光板1中,因偏光片2配置於保護膜3之上,故切削工具10的一次旋轉中,切削工具10的各切削刃B係先切削積層體100中的各偏光片2的端面,繼而切削鄰接於各偏光片2之各保護膜3的端面。 In each of the polarizing plates 1, since the polarizer 2 is disposed on the protective film 3, in the primary rotation of the cutting tool 10, each cutting edge B of the cutting tool 10 first cuts the end faces of the polarizing plates 2 in the laminated body 100. Then, the end faces of the respective protective films 3 adjacent to the respective polarizers 2 are cut.

將積層體100於水平方向移動1mm的時間視為單位時間時,將每單位時間之切削工具10的旋轉數調整為10.2次。 When the time in which the laminated body 100 was moved by 1 mm in the horizontal direction was regarded as the unit time, the number of rotations of the cutting tool 10 per unit time was adjusted to 10.2 times.

藉由以上的步驟,得到100片偏光板(實施例1之偏光板)。 Through the above steps, 100 polarizing plates (polarizing plates of Example 1) were obtained.

(7-1)粗度曲線要素的平均高度Rc的測定  (7-1) Determination of the average height Rc of the roughness curve elements  

以下述程序,測定實施例1之偏光板1所具備之偏光片2的端面2a之粗度曲線要素的平均高度Rc。測定對象之偏光片2的端面2a,意指藉由切削工具10施行切削之端面。Rc的測定,係使用olympus股份公司製之3D測定雷射顯微鏡「OLS4100」。由實施例1之100片偏光板中隨機地抽取5片偏光板1。測定一個偏光板1所具備之偏光片2的4個端面中相對於偏光片2的延伸軸方向而言為垂直的2個端面2a的Rc,算出2個端面2a的Rc的平均值。以相同的方法算出5片偏光板1所具備之偏光片2各自的Rc平均值,再將該等5個Rc的平均值進一步平均。用以上程序算出的實施例1之Rc為0.07μm。 The average height Rc of the thickness curve elements of the end faces 2a of the polarizer 2 included in the polarizing plate 1 of Example 1 was measured by the following procedure. The end face 2a of the polarizer 2 to be measured is measured, and the end face of the cutting by the cutting tool 10 is performed. For the measurement of Rc, a 3D measuring laser microscope "OLS4100" manufactured by Olympus Co., Ltd. was used. Five polarizing plates 1 were randomly taken out from the 100 polarizing plates of Example 1. Rc of the two end faces 2a perpendicular to the extending axis direction of the polarizing plate 2 among the four end faces of the polarizing plate 2 included in one polarizing plate 1 was measured, and the average value of Rc of the two end faces 2a was calculated. The average value of Rc of each of the polarizing plates 2 included in the five polarizing plates 1 was calculated in the same manner, and the average values of the five Rc were further averaged. The Rc of Example 1 calculated by the above procedure was 0.07 μm.

(7-2)均方根粗度Rq的測定  (7-2) Determination of root mean square roughness Rq  

以下述程序,測定實施例1之偏光板1所具備之偏光片2的端面2a的側部2as的均方根粗度Rq。測定對象之偏光片2的端面2a,意指藉由切削工具10施行切削之端面。Rq的測定,係使用olympus股份公司製之3D測定雷射顯微鏡「OLS4100」。由實施例1之100片偏光板中隨機地抽取5片偏光板1。測定一個偏光板1所具備之偏光片2的4個端面中相對於偏光片2的延伸軸方向而言為垂直的2個端面2a的Rq,算出2個端面2a的Rq的平均值。以相同的方法算出5片偏光板1所具備之偏光片2各自的Rq的平均值,再將該等5個Rq的平均值進一步平均。用 以上程序算出的實施例1之Rq為0.031μm。 The root mean square roughness Rq of the side portion 2as of the end surface 2a of the polarizing plate 2 of the polarizing plate 1 of the first embodiment was measured by the following procedure. The end face 2a of the polarizer 2 to be measured is measured, and the end face of the cutting by the cutting tool 10 is performed. For the measurement of Rq, a 3D measuring laser microscope "OLS4100" manufactured by Olympus Co., Ltd. was used. Five polarizing plates 1 were randomly taken out from the 100 polarizing plates of Example 1. Rq of the two end faces 2a perpendicular to the extending axis direction of the polarizing plate 2 among the four end faces of the polarizing plate 2 included in one polarizing plate 1 was measured, and the average value of Rq of the two end faces 2a was calculated. The average value of Rq of each of the polarizing plates 2 included in the five polarizing plates 1 was calculated in the same manner, and the average values of the five Rqs were further averaged. The Rq of Example 1 calculated by the above procedure was 0.031 μm.

(8)熱衝擊試驗  (8) Thermal shock test  

以下述程序,使用實施例1的一片偏光板(切削加工後之偏光板)進行熱衝擊試驗。 The thermal shock test was carried out using the one polarizing plate of Example 1 (polarizing plate after cutting) by the following procedure.

從附分隔件之偏光板將分隔件剝離,經由黏著劑層將偏光板貼附於無鹼玻璃板,得到試驗用之試樣。無鹼玻璃板係使用康寧公司製之「Eagle-XG」。將試樣封入高壓釜內20分鐘,對試樣施以加壓處理。高壓釜內的溫度係維持於50℃。高壓釜內的壓力係維持於5MPa。將加壓處理後之試樣於溫度為23℃且相對濕度為60%之氣體環境下放置1日。 The separator was peeled off from the polarizing plate with the separator, and the polarizing plate was attached to the alkali-free glass plate via the adhesive layer to obtain a test sample. The alkali-free glass plate is "Eagle-XG" manufactured by Corning Incorporated. The sample was sealed in an autoclave for 20 minutes, and the sample was subjected to a pressure treatment. The temperature in the autoclave was maintained at 50 °C. The pressure in the autoclave was maintained at 5 MPa. The sample after the press treatment was allowed to stand for 1 day in a gas atmosphere having a temperature of 23 ° C and a relative humidity of 60%.

將經過以上的步驟之試樣設置於冷熱衝擊試驗器之試驗槽內。並且,將包含下述工序1至工序3的循環重複12次。冷熱衝擊試驗器係使用ESPEC股份公司製之「TSA-301L-W」。 The sample subjected to the above steps was placed in a test tank of a thermal shock tester. Further, the cycle including the following steps 1 to 3 was repeated 12 times. The thermal shock tester used "TSA-301L-W" manufactured by ESPEC AG.

工序1:將試驗槽內的溫度維持於-40℃、30分鐘的工序。 Step 1: A step of maintaining the temperature in the test tank at -40 ° C for 30 minutes.

工序2:工序1後,將試驗槽內的溫度維持於23℃、5分鐘的工序。 Step 2: After the step 1, the temperature in the test tank was maintained at 23 ° C for 5 minutes.

工序3:工序2後,將試驗槽內的溫度維持於85℃、30分鐘的工序。 Step 3: After the step 2, the temperature in the test tank was maintained at 85 ° C for 30 minutes.

將循環重複12次後,將試樣由試驗槽取出。繼而,以光學顯微鏡觀察試樣的端邊,調查於偏光片2的 端面2a是否有破裂。光學顯微鏡係使用keyence股份公司製之「VHX-5000」。求出於偏光片2的端面2a之每單位長度的破裂數目。「單位長度」係指於偏光片的端面內之垂直於偏光片的厚度方向且長度為10mm之線段。「每單位長度的破裂數目」意指於偏光片的端面與單位長度交錯的破裂的個數。實施例1的破裂數目為零。 After repeating the cycle 12 times, the sample was taken out from the test tank. Then, the end of the sample was observed with an optical microscope, and it was investigated whether or not the end face 2a of the polarizer 2 was broken. The optical microscope is "VHX-5000" manufactured by Keyence Corporation. The number of cracks per unit length of the end face 2a of the polarizer 2 was determined. "Unit length" means a line segment in the end face of the polarizer perpendicular to the thickness direction of the polarizer and having a length of 10 mm. The "number of cracks per unit length" means the number of cracks in which the end faces of the polarizer are staggered with the unit length. The number of ruptures of Example 1 was zero.

(9)偏光板的尺寸的精度之評估  (9) Evaluation of the accuracy of the size of the polarizing plate  

測定實施例1之偏光板的一邊的長度,評估該測定值是否於目標值±50μm的公差之範圍內。實施例1之偏光板的一邊的長度的測定值係於目標值±50μm的公差之範圍內。換言之,確認到實施例1之偏光板的尺寸的精度高。 The length of one side of the polarizing plate of Example 1 was measured, and it was evaluated whether the measured value was within the tolerance of the target value ± 50 μm. The measured value of the length of one side of the polarizing plate of Example 1 was within the range of the tolerance of the target value ± 50 μm. In other words, it was confirmed that the accuracy of the size of the polarizing plate of Example 1 was high.

〔實施例2至9〕  [Examples 2 to 9]  

實施例2至9中,係將每單位時間之切削工具10的旋轉數調整為下述表1所示之值。實施例5至7及9之切削加工中,合成樹脂盤並未配置於積層體100之下。換言之,實施例5至7及9的各切削加工中,積層體100所配置的高度係較實施例1低。因此,實施例5至7及9各自的切削加工中,相對於積層體100中的各偏光片2的表面之各切削刃B的進入角θ並非垂直。而且,實施例5至7及9各自的切削加工中,積層體100所配置的高度並未與切削工具10的旋轉軸線A的高度大致相同。 In the second to ninth embodiments, the number of rotations of the cutting tool 10 per unit time was adjusted to the values shown in Table 1 below. In the cutting processes of Examples 5 to 7 and 9, the synthetic resin disk was not disposed under the laminated body 100. In other words, in each of the cutting processes of Examples 5 to 7 and 9, the height of the laminated body 100 is lower than that of the first embodiment. Therefore, in the cutting processes of each of the fifth to seventh embodiments, the entry angle θ of each of the cutting edges B with respect to the surface of each of the polarizers 2 in the laminated body 100 is not perpendicular. Further, in the cutting processes of each of the fifth to seventh embodiments, the height of the laminated body 100 is not substantially the same as the height of the rotation axis A of the cutting tool 10.

除了關於切削加工之上述事項之外,係以與 實施例1相同的方法製作實施例2至9之各偏光板。以與實施例1相同的方法測定實施例2至9各自的Rc及Rq。將實施例2至9各自的Rc及Rq示於下述表1。以與實施例1相同的方法測定實施例2至9各自的破裂數目。當於偏光片的端面形成破裂時,亦測定破裂的長度。破裂的長度,係指由位於偏光片的端面之破裂的端部算起至另一個破裂的端部為止的距離。將實施例2至9各自的破裂數目及破裂長度示於下述表1。表1所示之破裂的長度為於各偏光片的端面所形成的破裂之中最長的破裂的長度。以與實施例1相同的方法評估實施例2至9之各偏光板的尺寸精度。將實施例2至9之各偏光板的尺寸精度示於下述表1。 Each of the polarizing plates of Examples 2 to 9 was produced in the same manner as in Example 1 except for the above matters concerning the cutting process. Rc and Rq of each of Examples 2 to 9 were measured in the same manner as in Example 1. Rc and Rq of each of Examples 2 to 9 are shown in Table 1 below. The number of cracks of each of Examples 2 to 9 was measured in the same manner as in Example 1. When a crack is formed on the end face of the polarizer, the length of the crack is also measured. The length of the rupture refers to the distance from the end of the rupture of the end face of the polarizer to the end of the other rupture. The number of ruptures and the length of rupture of each of Examples 2 to 9 are shown in Table 1 below. The length of the crack shown in Table 1 is the length of the longest crack among the cracks formed by the end faces of the respective polarizers. The dimensional accuracy of each of the polarizing plates of Examples 2 to 9 was evaluated in the same manner as in Example 1. The dimensional accuracy of each of the polarizing plates of Examples 2 to 9 is shown in Table 1 below.

〔比較例1〕  [Comparative Example 1]  

比較例1之切削加工中,合成樹脂盤並未配置於積層體100之下。換言之,比較例1之切削加工中,積層體100所配置的高度係較實施例1低。因此,比較例1之切削加工中,相對於積層體100中的各偏光片2的表面之各切削刃B的進入角θ並非垂直。而且,比較例1之切削加工中,積層體100所配置的高度並未與切削工具10的旋轉軸線A的高度大致相同。此外,比較例1之切削加工中,係將每單位時間之切削工具10的旋轉數調整為下述表1所示之值。 In the cutting process of Comparative Example 1, the synthetic resin disk was not disposed under the laminated body 100. In other words, in the cutting process of Comparative Example 1, the height of the laminated body 100 is lower than that of the first embodiment. Therefore, in the cutting process of Comparative Example 1, the entry angle θ of each cutting edge B with respect to the surface of each polarizer 2 in the laminated body 100 is not perpendicular. Further, in the cutting process of Comparative Example 1, the height at which the laminated body 100 is disposed is not substantially the same as the height of the rotation axis A of the cutting tool 10. Further, in the cutting process of Comparative Example 1, the number of rotations of the cutting tool 10 per unit time was adjusted to the values shown in Table 1 below.

除了關於切削加工的上述事項之外,係以與 實施例1相同的方法製作比較例1之偏光板。以與實施例1相同的方法測定比較例1之Rc及Rq。比較例1之Rc及Rq係示於下述表1。以與實施例1至9相同的方法測定比較例1的破裂數目及破裂長度。將比較例1的破裂數目及破裂長度示於下述表1。以與實施例1相同的方法評估比較例1之偏光板的尺寸精度。將比較例1之偏光板的尺寸精度示於下述表1。 A polarizing plate of Comparative Example 1 was produced in the same manner as in Example 1 except for the above matters concerning the cutting process. Rc and Rq of Comparative Example 1 were measured in the same manner as in Example 1. Rc and Rq of Comparative Example 1 are shown in Table 1 below. The number of cracks and the length of the crack of Comparative Example 1 were measured in the same manner as in Examples 1 to 9. The number of cracks and the length of the crack of Comparative Example 1 are shown in Table 1 below. The dimensional accuracy of the polarizing plate of Comparative Example 1 was evaluated in the same manner as in Example 1. The dimensional accuracy of the polarizing plate of Comparative Example 1 is shown in Table 1 below.

〔比較例2〕  [Comparative Example 2]  

除了未進行切削加工之外,係以與實施例1相同的方法製作比較例2之偏光板。以與實施例1相同的方法測定比較例2的Rc及Rq。將比較例2的Rc及Rq示於下述表1。以與實施例1相同的方法測定比較例2的破裂數目。 A polarizing plate of Comparative Example 2 was produced in the same manner as in Example 1 except that the cutting was not performed. Rc and Rq of Comparative Example 2 were measured in the same manner as in Example 1. Rc and Rq of Comparative Example 2 are shown in Table 1 below. The number of cracks of Comparative Example 2 was measured in the same manner as in Example 1.

將比較例2的破裂數目示於下述表1。以與實施例1相同的方法評估比較例2之偏光板的尺寸精度。比較例2之偏光板的一邊的長度之測定值係於目標值±50μm的公差之範圍外。換言之,確認到比較例2之偏光板的尺寸的精度低。 The number of cracks of Comparative Example 2 is shown in Table 1 below. The dimensional accuracy of the polarizing plate of Comparative Example 2 was evaluated in the same manner as in Example 1. The measured value of the length of one side of the polarizing plate of Comparative Example 2 was outside the range of the tolerance of the target value of ±50 μm. In other words, it was confirmed that the accuracy of the size of the polarizing plate of Comparative Example 2 was low.

〔產業上之可利用性〕  [Industrial Applicability]  

本發明之偏光板,係可應用於例如貼附於液晶單元或有機EL元件等之構成液晶電視、有機EL電視或智慧型手機等圖像顯示裝置的光學零件。 The polarizing plate of the present invention can be applied to, for example, an optical component constituting an image display device such as a liquid crystal television, an organic EL television, or a smart phone attached to a liquid crystal cell or an organic EL device.

Claims (5)

一種偏光片,係膜狀的偏光片,前述偏光片的端面之粗度曲線要素的平均高度Rc為0.05至1.7μm。  A polarizer is a film-shaped polarizer, and an average height Rc of the thickness curve elements of the end faces of the polarizer is 0.05 to 1.7 μm.   一種偏光板,係具備申請專利範圍第1項所述之偏光片、疊合於前述偏光片的一表面之第一光學膜。  A polarizing plate comprising the polarizer described in claim 1 and a first optical film superposed on a surface of the polarizer.   如申請專利範圍第2項所述之偏光板,其中,圍起前述偏光片的一個端面的邊之中的第一邊係鄰接於前述第一光學膜,圍起前述端面的邊之中的第二邊係位於前述第一邊的相對側,前述端面中之沿著前述第二邊的部分之均方根粗度Rq為0.03至0.15μm。  The polarizing plate of claim 2, wherein a first side of the side of one end surface of the polarizer is adjacent to the first optical film, and the first side of the end face is enclosed The two sides are located on opposite sides of the first side, and the root mean square roughness Rq of the portion along the second side of the end faces is 0.03 to 0.15 μm.   如申請專利範圍第2項或第3項所述之偏光板,係進一步具備疊合於前述偏光片的另一表面之黏著劑層、與疊合於前述黏著劑層之第二光學膜。  The polarizing plate according to claim 2 or 3, further comprising an adhesive layer laminated on the other surface of the polarizer and a second optical film laminated on the adhesive layer.   一種圖像顯示裝置,係包含申請專利範圍第2項至第4項中任一項所述之偏光板。  An image display device comprising the polarizing plate according to any one of claims 2 to 4.  
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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6201025B1 (en) * 2016-10-14 2017-09-20 住友化学株式会社 Polarizer, polarizing plate and image display device
US11892423B2 (en) * 2018-03-30 2024-02-06 Sumitomo Chemical Company, Limited Sensor and production method for same
JP2020181184A (en) * 2019-03-14 2020-11-05 住友化学株式会社 Polarizer
JP7312038B2 (en) * 2019-06-25 2023-07-20 日東電工株式会社 Manufacturing method of polarizing plate
JP2021128202A (en) * 2020-02-12 2021-09-02 住友化学株式会社 Display device
JP7221256B2 (en) * 2020-09-14 2023-02-13 日東電工株式会社 A polarizing plate, a polarizing plate with a retardation layer, and an image display device comprising the polarizing plate or the polarizing plate with the retardation layer
JP7203879B2 (en) * 2021-03-25 2023-01-13 日東電工株式会社 Method for manufacturing polarizing plate and polarizing plate

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6361203A (en) * 1986-09-01 1988-03-17 Mitsubishi Chem Ind Ltd Polarizing plate and its production
JP3875331B2 (en) 1996-12-19 2007-01-31 日東電工株式会社 Optical member
JP2000347181A (en) * 1999-06-09 2000-12-15 Nitto Denko Corp Optical member and liquid crystal display device
JP2004167673A (en) 2002-10-29 2004-06-17 Nitto Denko Corp Cutting working method of laminated sheet, laminated sheet, optical element and picture image display device
JP2005224935A (en) * 2004-01-15 2005-08-25 Nitto Denko Corp Laminated sheet machining method, laminated sheet machining device, laminated sheet, optical element, and image display device
US20050158136A1 (en) * 2004-01-15 2005-07-21 Nitto Denko Corporation Cutting method and cutting apparatus for layered sheet, layered sheet, optical element and image display
JP4578140B2 (en) * 2004-04-21 2010-11-10 株式会社クラレ Polyvinyl alcohol film
WO2006077995A1 (en) * 2005-01-18 2006-07-27 Fujifilm Corporation Transparent film and method for manufacturing the same, polarized plate and image display device
JP2006272616A (en) * 2005-03-28 2006-10-12 Konica Minolta Opto Inc Optical film and its manufacturing device
JP4849665B2 (en) * 2005-11-18 2012-01-11 株式会社日本触媒 Polarizer protective film, polarizing plate, and image display device
JP4954662B2 (en) * 2006-01-27 2012-06-20 日東電工株式会社 Cutting method and manufacturing method of sheet-like member
JP5168813B2 (en) * 2006-04-14 2013-03-27 ソニー株式会社 Optical sheet, backlight device and liquid crystal display device
WO2008090513A2 (en) * 2007-01-22 2008-07-31 Element Six Limited Diamond electronic devices including a surface and methods for their manufacture
KR101157444B1 (en) * 2007-07-06 2012-06-22 닛토덴코 가부시키가이샤 Polarization plate
JP5382843B2 (en) * 2007-10-31 2014-01-08 住友化学株式会社 Manufacturing method of polarizing plate
JP5324316B2 (en) * 2008-05-27 2013-10-23 日東電工株式会社 Adhesive polarizing plate, image display device, and manufacturing method thereof
KR20100127954A (en) * 2009-05-27 2010-12-07 도레이첨단소재 주식회사 Antireflection film and polarizing plate comprisind the same
CN201927364U (en) * 2010-07-15 2011-08-10 北京工商大学 Reflecting polarization element for improving polarization ratio of soft X-ray
JP6006479B2 (en) * 2010-07-30 2016-10-12 旭化成株式会社 Polarized beam splitter and projection display device
JP6391442B2 (en) * 2014-11-26 2018-09-19 住友化学株式会社 Cutting method, polarizing plate manufacturing method including cutting method, and polarizing plate
TWI650234B (en) * 2014-12-26 2019-02-11 凸版巴川光學薄膜股份有限公司 Optical laminate, polarizing plate and display device
KR101747559B1 (en) * 2015-03-30 2017-06-14 스미또모 가가꾸 가부시키가이샤 Polarizing plate
TWI714581B (en) * 2015-05-13 2021-01-01 日商可樂麗股份有限公司 Polyvinyl alcohol film and its manufacturing method
JP6201025B1 (en) * 2016-10-14 2017-09-20 住友化学株式会社 Polarizer, polarizing plate and image display device

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