JP3875331B2 - Optical member - Google Patents

Optical member Download PDF

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Publication number
JP3875331B2
JP3875331B2 JP35509096A JP35509096A JP3875331B2 JP 3875331 B2 JP3875331 B2 JP 3875331B2 JP 35509096 A JP35509096 A JP 35509096A JP 35509096 A JP35509096 A JP 35509096A JP 3875331 B2 JP3875331 B2 JP 3875331B2
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JP
Japan
Prior art keywords
film
optical member
laminate
sensitive adhesive
adhesive layer
Prior art date
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Expired - Fee Related
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JP35509096A
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Japanese (ja)
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JPH10186129A (en
Inventor
功児 木村
一喜 土本
鉄夫 金子
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Nitto Denko Corp
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Nitto Denko Corp
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Priority to JP35509096A priority Critical patent/JP3875331B2/en
Publication of JPH10186129A publication Critical patent/JPH10186129A/en
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Publication of JP3875331B2 publication Critical patent/JP3875331B2/en
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  • Polarising Elements (AREA)
  • Laminated Bodies (AREA)
  • Optical Filters (AREA)

Description

【0001】
【発明の技術分野】
本発明は、平滑面に接着しにくくて枠内装着体の取替性やライン搬送性などに優れる光学部材に関する。
【0002】
【従来の技術】
従来、長尺の光学フィルムに感圧接着層を付設した積層原反を所定サイズに切断した後、その切断で発生した微細なクラックや感圧接着層のはみ出し等に措置するために、切断後の積層体における切断面を切削等により平滑化処理した光学部材が知られていた(特開昭61−136746公報)。
【0003】
しかしながら、前記の光学部材を表示装置の額縁等の枠内に装着したものを取替える際に、光学部材の端面が枠内壁と接着していて取外しが困難であったり、製造や加工等のライン上を搬送する場合に、光学部材の端面がラインのガイド面に接着して走行を乱し、正常な搬送状態が害されて製造や加工等の効率が大きく低下する問題点があった。
【0004】
【発明の技術的課題】
本発明は、枠内装着物の取替の際の取外し性に優れ、製造や加工等のライン搬送時に正常な走行を乱すガイド面への接着を発生しにくくて、正常な搬送状態の維持性、ひいては製造や加工等の効率に優れる光学部材の開発を課題とする。
【0005】
【課題の解決手段】
本発明は、少なくとも光学フィルム層と感圧接着層を有する積層体からなり、その積層体の端辺が微細凹凸の粗面に形成されていると共に、前記の積層体が矩形体からなり、かつその矩形体の角部が辺中央部より広幅に形成された少なくとも一辺を有することを特徴とする光学部材を提供するものである。
【0006】
【発明の効果】
本発明によれば、微細凹凸の粗面に形成した端辺が、表示装置における額縁等の枠の内壁や製造・加工ライン等のガイド面に対する接触面積を減少させて接着力に乏しく、枠内装着物の取替の際の取外し性に優れると共に、製造や加工等のライン搬送時に正常な走行を乱すガイド面への接着を発生しにくく、かつその場合に角部が辺中央部よりも優先的に枠の内壁やラインのガイドに接触して、辺中央部での接触が防止されるため接触による接着力をより低下させることができ、正常な搬送状態の維持性、ひいては製造や加工等の効率に優れて大面積体にも有利に適用できる光学部材を得ることができる。
【0007】
【発明の実施形態】
本発明の光学部材は、少なくとも光学フィルム層と感圧接着層を有する積層体からなり、その積層体の端辺が微細凹凸の粗面に形成されると共に、前記の積層体が矩形体からなり、かつその矩形体の角部が辺中央部より広幅に形成された少なくとも一辺を有するものである。その例を図1、図2、図3に示した。1,4が光学フィルム層、2が感圧接着層であり、3はセパレータである。
【0008】
積層体を形成する光学フィルムは、例えば偏光や位相差、反射や拡散、反射防止や干渉、回折などの任意な光学特性を示す適宜なフィルムからなるものであってよい。また積層体は、例えば偏光板や位相差板、反射板や拡散板、反射防止板や干渉板、回折板などの適宜な光学フィルムを感圧接着層を介して2層以上含む状態に積層されたものであってもよい。
【0009】
光学フィルムを形成するポリマーとしては、例えばポリエステル系やセルロース系、ポリエーテルサルホン系やポリカーボネート系、ポリアミド系やポリイミド系、ポリオレフィン系やアクリル系等のプラスチック、あるいはアクリル系やウレタン系、アクリルウレタン系やエポキシ系やシリコーン系等の熱硬化型、ないし紫外線硬化型の樹脂、各種の液晶ポリマーなどがあげられるが、これらに限定されるものではなく、そのポリマーについては任意である。
【0010】
ちなみに偏光板は、ポリビニルアルコール系系フィルムや部分ホルマール化ポリビニルアルコール系系フィルム、エチレン・酢酸ビニル共重合体系部分ケン化フィルムの如き親水性高分子フィルムにヨウ素及び/又は二色性染料を吸着させて延伸したもの、ポリビニルアルコール系の脱水処理物やポリ塩化ビニルの脱塩酸処理物の如きポリエン配向フィルム、あるいはかかる偏光フィルムの片面又は両面に透明保護フィルムを付設したものなどからなるものが一般的である。
【0011】
なお前記した偏光板の表面損傷等の防止などを目的に付設される透明保護フィルム層は、通例、等方性の透明フィルムで形成される。また位相差板は、延伸フィルムや液晶ポリマーフィルムなどにより形成され、反射板は、例えば必要に応じマット処理したフィルムの片面にアルミニウム等の反射性金属からなる箔や蒸着膜を付設したものや、微粒子の添加で表面微細凹凸構造としたフィルムに蒸着方式やメッキ方式などの適宜な方式で金属反射層を付設したものなどとして形成される。
【0012】
一方、拡散板や反射防止板は、例えばマット処理したフィルムや微粒子の添加で表面微細凹凸構造としたフィルムなどとして形成され、干渉板は、フィルムに干渉性の薄膜を設けたものなどとして形成される。回折板は、フィルムに微細な凹凸や溝のラインを設けたものなどとして形成される。従って上記のように光学フィルムは、等方性や異方性などの適宜な特性が付与されたものからなっていてよい。
【0013】
光学フィルムに付設する感圧接着層の種類については特に限定はなく、例えばアクリル系やシリコーン系、ポリエステル系やポリウレタン系、ポリエーテル系やゴム系などからなる透明な適宜な感圧接着剤を用いて形成されたものであってよい。感圧接着層の厚さは、500μm以下、就中1〜300μm、特に5〜100μmが一般的であるが、これに限定されない。
【0014】
前記の感圧接着層は、必要に応じて例えば天然物や合成物の樹脂類、ガラス繊維やガラスビーズ、金属粉やその他の無機粉末等からなる充填剤や顔料、着色剤や酸化防止剤などの適宜な添加剤を含有していてもよい。また微粒子の含有で光拡散性を示すものであってもよい。
【0015】
なお上記した光学フィルムや感圧接着層は、例えばサリチル酸エステル系化合物やベンゾフェノール系化合物、ベンゾトリアゾール系化合物やシアノアクリレート系化合物、ニッケル錯塩系化合物等の紫外線吸収剤で処理する方式などにより紫外線吸収能をもたせたものであってもよい。
【0016】
積層体において感圧接着層が露出する場合には、図例の如くセパレータ3を仮着して保護することが好ましい。セパレータは、例えばシリコーン系や長鎖アルキル系やフッ素系等の適宜な剥離剤でコート処理したフィルムやそのラミネートなどとして得ることができる。
【0017】
光学部材は、例えば所定の積層状態とした原反を必要に応じ積み重ねて所定の矩形サイズに切断することにより得ることができる。本発明による積層体は、その端辺が微細凹凸の粗面に形成されたものであるが、かかる粗面は前記原反又は所定サイズに切断後の積層体を必要に応じ積み重ねて、その切断面の必要な面を1mm以下等のサンドブラストを吹き付ける方式や、40番手以下等のサンドペーパで研磨する方式などの適宜な方式で形成することができる。
【0018】
前記において粗面に形成する端面は、枠内装着用のものでは光学部材の周囲であることが好ましく、製造や加工等のラインで搬送する場合にはラインのガイドに接触するおそれのある対向の側辺であることが好ましい。なお前記の粗面化処理に際しては、従来技術の如く微細クラックの発生や感圧接着層のはみ出し防止等を目的とした切削等による平滑化処理を併用してもよい。
【0019】
端辺に形成する粗面における微細凹凸の状態は、平滑面との接触により発生する接着力の低さなどの点より、その凸部の突出幅が1μm以上であることが好ましく、また外観の低下による不良品扱いを防止する点などより100μm以下であることが好ましい。より好ましい凸部の突出幅は、2〜50μmである。
【0020】
また光学部材としての積層体を形成する矩形体は、図3に例示の如く、角部11,13,14,16が辺中央部12,15より広幅に形成された少なくとも一辺を有するものとされる。かかる形態は、角部が辺中央部よりも優先的に枠の内壁やラインのガイドに接触して、辺中央部での接触が防止されるため接触による接着力をより低下させることができ、大面積の光学部材に特に有利に適用することができる。なお前記の角部広幅形態は、角部に突出部を設ける方式などの適宜な方式で形成されていてよい。
【0021】
前記において、角部が辺中央部よりも広幅に形成された辺は、矩形体の一辺であってもよいし、図例の如く対向の2辺、又は全辺などであってもよく、適宜に決定することができる。また角部と辺中央部の幅差は、辺中央部での接触防止性や外観不良の防止性などの点より、1〜100μm、就中2〜50μmであることが好ましい。
【0022】
【実施例】
実施例1
幅90cm、厚さ70μmのポリビニルアルコール系偏光フィルムの長尺原反の両面に、厚さ20μmのアクリル系感圧接着層を介して厚さ80μmのトリアセチルセルロースフィルムを接着し、その片面に厚さ25μmのポリエステルフィルムをシリコーン系剥離剤で処理したセパレータ上に設けた厚さ20μmのアクリル系感圧接着層をセパレータと共に接着し、その積層原反より刃型を介し12.1インチLCD用サイズで積層体を打ち抜き、その50枚を積み重ねて切断面を60番手のサンドペーパで研磨処理し、光学部材を得た。
【0023】
実施例2
サンドペーパで研磨処理する前に、切断面を切削して平滑面としたほかは実施例1に準じて光学部材を得た。
【0024】
比較例
サンドペーパによる研磨処理を施さずに、打ち抜き体そのものとしたほかは実施例1に準じて光学部材を得た。
【0025】
評価試験
実施例、比較例で得た光学部材を1枚ずつ所定の間隔で、ステンレス製のガイドを装着したコンベアにて搬送したところ、実施例1,2では途中で停滞することなく正常に搬送することができたが、比較例では搬送途中で停滞するトラブルが多発した。
【図面の簡単な説明】
【図1】実施例の斜視断面図
【図2】他の実施例の正面断面図
【図3】さらに他の実施例の平面説明図
【符号の説明】
1,4:光学フィルム層
2:感圧接着層
3:セパレータ
[0001]
TECHNICAL FIELD OF THE INVENTION
The present invention relates to an optical member that hardly adheres to a smooth surface and is excellent in the ability to replace an in-frame mounting body, line transportability, and the like.
[0002]
[Prior art]
Conventionally, after cutting a laminated raw material provided with a pressure-sensitive adhesive layer on a long optical film to a predetermined size, after cutting, in order to prevent fine cracks or pressure-sensitive adhesive layer from protruding, etc. An optical member in which the cut surface of the laminate is smoothed by cutting or the like has been known (Japanese Patent Laid-Open No. 61-136746).
[0003]
However, when replacing the optical member mounted in a frame such as a frame of a display device, the end surface of the optical member is adhered to the inner wall of the frame, and it is difficult to remove it. However, the end face of the optical member adheres to the guide surface of the line and disturbs the running, and the normal carrying state is harmed and the efficiency of manufacturing, processing, etc. is greatly reduced.
[0004]
[Technical Problem of the Invention]
The present invention is excellent in detachability at the time of replacement of the attachment in the frame, is less likely to cause adhesion to the guide surface that disturbs normal travel during line conveyance such as manufacturing and processing, and maintains normal conveyance state, As a result, it is an object to develop an optical member that is excellent in manufacturing and processing efficiency.
[0005]
[Means for solving problems]
The present invention is composed of a laminate having at least an optical film layer and a pressure-sensitive adhesive layer, the edge of the laminate is formed on a rough surface with fine irregularities , and the laminate is a rectangular body, and An object of the present invention is to provide an optical member characterized in that the corner of the rectangular body has at least one side formed wider than the center of the side .
[0006]
【The invention's effect】
According to the present invention, the edge formed on the rough surface of the fine unevenness reduces the contact area to the inner wall of the frame such as the frame in the display device and the guide surface such as the manufacturing / processing line, and has poor adhesion, and the frame interior Excellent detachability when changing kimonos , and less likely to adhere to the guide surface that disturbs normal travel during line transportation during manufacturing and processing , and in that case, the corners have priority over the side center. The contact with the inner wall of the frame and the guide of the line is prevented and contact at the center of the side is prevented, so that the adhesive force due to the contact can be further reduced , and maintenance of normal conveyance state, as well as manufacturing and processing etc. excellent efficiency large area body can be obtained advantageously that can be applied to an optical member.
[0007]
DETAILED DESCRIPTION OF THE INVENTION
The optical member of the present invention, at least a multilayer body having an optical film layer and a pressure-sensitive adhesive layer, the edge of the laminate is formed on the rough surface of fine irregularities Rutotomoni, the laminate consists of a rectangular body And the corner | angular part of the rectangular body has at least one side formed wider than the center part of the side . Examples thereof are shown in FIGS. 1, 2 , and 3 . 1 and 4 are optical film layers, 2 is a pressure-sensitive adhesive layer, and 3 is a separator.
[0008]
The optical film forming the laminate may be made of an appropriate film exhibiting arbitrary optical characteristics such as polarization, retardation, reflection and diffusion, antireflection, interference, and diffraction. The laminate is laminated in a state including two or more appropriate optical films, such as a polarizing plate, a retardation plate, a reflecting plate, a diffusing plate, an antireflection plate, an interference plate, and a diffractive plate, with a pressure-sensitive adhesive layer interposed therebetween. It may be.
[0009]
Examples of the polymer forming the optical film include polyesters, celluloses, polyether sulfones, polycarbonates, polyamides, polyimides, polyolefins, acrylics, plastics, acrylics, urethanes, and acrylic urethanes. And thermosetting type such as epoxy type and silicone type, or ultraviolet curable type resin, various liquid crystal polymers, etc., but are not limited thereto, and the polymer is arbitrary.
[0010]
By the way, the polarizing plate adsorbs iodine and / or dichroic dye to hydrophilic polymer films such as polyvinyl alcohol film, partially formalized polyvinyl alcohol film, and ethylene / vinyl acetate copolymer partially saponified film. It is generally composed of a polyene oriented film such as a polyvinyl alcohol-based dehydrated product or polyvinyl chloride dehydrochlorinated product, or a polarizing film provided with a transparent protective film on one or both sides. It is.
[0011]
In addition, the transparent protective film layer provided for the purpose of preventing the surface damage of the polarizing plate described above is usually formed of an isotropic transparent film. Further, the retardation plate is formed of a stretched film, a liquid crystal polymer film, etc., and the reflector is, for example, a film or a film made of a reflective metal such as aluminum attached to one side of a mat-treated film if necessary, The film is formed as a film having a fine concavo-convex structure formed by adding fine particles, and a metal reflective layer attached thereto by an appropriate method such as a vapor deposition method or a plating method.
[0012]
On the other hand, the diffusion plate and the antireflection plate are formed as, for example, a mat-processed film or a film having a surface fine concavo-convex structure by adding fine particles, and the interference plate is formed as a film provided with an interference thin film. The The diffraction plate is formed as a film provided with fine irregularities and groove lines. Therefore, as described above, the optical film may be made of a film provided with appropriate characteristics such as isotropic property and anisotropy.
[0013]
The type of pressure-sensitive adhesive layer attached to the optical film is not particularly limited. For example, an appropriate transparent pressure-sensitive adhesive made of acrylic, silicone, polyester, polyurethane, polyether or rubber is used. May be formed. The thickness of the pressure-sensitive adhesive layer is generally 500 μm or less, especially 1 to 300 μm, particularly 5 to 100 μm, but is not limited thereto.
[0014]
The pressure-sensitive adhesive layer may be, for example, a natural or synthetic resin, a glass fiber or glass bead, a filler or pigment made of metal powder or other inorganic powder, a colorant, an antioxidant, or the like. The appropriate additive may be contained. Further, it may exhibit light diffusibility by containing fine particles.
[0015]
The optical film and pressure-sensitive adhesive layer described above absorb ultraviolet rays by a method of treating with an ultraviolet absorbent such as a salicylic acid ester compound, a benzophenol compound, a benzotriazole compound, a cyanoacrylate compound, or a nickel complex compound. It may have a function.
[0016]
When the pressure-sensitive adhesive layer is exposed in the laminate, it is preferable to temporarily protect the separator 3 as shown in the figure. The separator can be obtained, for example, as a film coated with an appropriate release agent such as silicone-based, long-chain alkyl-based, or fluorine-based, or a laminate thereof.
[0017]
The optical member can be obtained, for example, by stacking raw materials in a predetermined laminated state as necessary and cutting them into a predetermined rectangular size. The laminated body according to the present invention has an edge formed on a rough surface with fine irregularities, and the rough surface is laminated by cutting the raw material or the laminated body after cutting into a predetermined size as necessary. The required surface can be formed by an appropriate method such as a method of spraying sandblast of 1 mm or less or a method of polishing with sandpaper of 40 or less.
[0018]
In the above, the end surface formed on the rough surface is preferably around the optical member in the case of wearing the frame interior, and on the opposite side that may come into contact with the guide of the line when transported by a line such as manufacturing or processing A side is preferred. In the above roughening treatment, a smoothing treatment by cutting or the like for the purpose of preventing the occurrence of fine cracks or the pressure-sensitive adhesive layer from protruding as in the prior art may be used in combination.
[0019]
As for the state of fine irregularities on the rough surface formed on the edge, the protrusion width of the convex portion is preferably 1 μm or more from the viewpoint of low adhesive force generated by contact with the smooth surface, and the appearance The thickness is preferably 100 μm or less from the viewpoint of preventing the handling of defective products due to the decrease. A more preferable protrusion width of the protrusion is 2 to 50 μm.
[0020]
Further, the rectangular body forming the laminated body as the optical member has at least one side in which the corner portions 11, 13, 14, and 16 are formed wider than the side center portions 12 and 15 as illustrated in FIG. The In such a form, the corner portion is preferentially in contact with the inner wall of the frame and the guide of the line rather than the center portion of the side, and contact at the center portion of the side is prevented, so that the adhesive force due to contact can be further reduced. The present invention can be particularly advantageously applied to a large area optical member. In addition, the said corner | angular part wide form may be formed by appropriate | suitable systems, such as the system which provides a protrusion part in a corner | angular part.
[0021]
In the above, the side where the corner is formed wider than the center of the side may be one side of the rectangular body, or may be two opposite sides or all sides as shown in the figure. Can be determined. The width difference between the corner and the side center is preferably 1 to 100 μm, especially 2 to 50 μm, from the viewpoint of preventing contact at the side center and preventing appearance defects.
[0022]
【Example】
Example 1
An 80 μm thick triacetylcellulose film is bonded to both sides of a 90 cm wide and 70 μm thick polyvinyl alcohol polarizing film via an acrylic pressure sensitive adhesive layer having a thickness of 20 μm, and the thickness is thickened on one side. A 25 μm thick polyester film treated with a silicone release agent is bonded to a 20 μm thick acrylic pressure sensitive adhesive layer together with the separator. Then, the laminate was punched out, 50 of them were stacked, and the cut surface was polished with 60th sandpaper to obtain an optical member.
[0023]
Example 2
Before polishing with sand paper, an optical member was obtained according to Example 1 except that the cut surface was cut to a smooth surface.
[0024]
Comparative Example An optical member was obtained in the same manner as in Example 1 except that the punched body itself was not subjected to polishing treatment with sandpaper.
[0025]
When the optical members obtained in the evaluation test example and the comparative example were transported one by one at a predetermined interval on a conveyor equipped with a stainless steel guide, in Examples 1 and 2, they were transported normally without stagnation in the middle. However, in the comparative example, troubles that stagnate during transportation frequently occurred.
[Brief description of the drawings]
FIG. 1 is a perspective sectional view of an embodiment. FIG. 2 is a front sectional view of another embodiment. FIG. 3 is a plan view of still another embodiment.
1, 4: Optical film layer 2: Pressure-sensitive adhesive layer 3: Separator

Claims (2)

少なくとも光学フィルム層と感圧接着層を有する積層体からなり、その積層体の端辺が微細凹凸の粗面に形成されていると共に、前記の積層体が矩形体からなり、かつその矩形体の角部が辺中央部より広幅に形成された少なくとも一辺を有することを特徴とする光学部材。It consists of a laminate having at least an optical film layer and a pressure-sensitive adhesive layer, the edges of the laminate are formed on a rough surface with fine irregularities , and the laminate is a rectangular body, and the rectangular body An optical member characterized in that the corner portion has at least one side formed wider than the side center portion . 請求項1において、微細凹凸の粗面に形成された端辺における凸部の突出幅が1〜100μmである光学部材。Oite to claim 1, the optical member protruding width of the convex portion is 1~100μm in the rough surface formed end-edge of the fine irregularities.
JP35509096A 1996-12-19 1996-12-19 Optical member Expired - Fee Related JP3875331B2 (en)

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JP35509096A JP3875331B2 (en) 1996-12-19 1996-12-19 Optical member

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JPH10186129A JPH10186129A (en) 1998-07-14
JP3875331B2 true JP3875331B2 (en) 2007-01-31

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
JP3862924B2 (en) * 2000-03-27 2006-12-27 日東電工株式会社 Optical film laminate
JP2008260540A (en) * 2007-04-10 2008-10-30 Three M Innovative Properties Co Sheetlike optical film package
KR102568434B1 (en) * 2018-06-22 2023-08-18 산진 옵토일렉트로닉스 (쑤저우) 컴퍼니 리미티드 Method for deriving polarizer proper cutting condition

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JP2786865B2 (en) * 1988-11-24 1998-08-13 大日本印刷株式会社 Manufacturing method of color filter
JPH08114770A (en) * 1994-08-26 1996-05-07 Omron Corp Optical low-pass filter and dot matrix display device utilizing the same
JPH0891528A (en) * 1994-09-29 1996-04-09 Toray Ind Inc Conveyor chain
JPH08335043A (en) * 1995-06-09 1996-12-17 Omron Corp Dot matrix image display module and its manufacture

Cited By (1)

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Publication number Priority date Publication date Assignee Title
KR20190065377A (en) 2016-10-14 2019-06-11 스미또모 가가꾸 가부시키가이샤 Polarizer, Polarizer, and Image Display Device

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