近年來，除染髮、燙髮等化學處理以外，以年輕女性為中心而逐漸習慣化之利用燙髮器、吹風機等之熱之整髮等所導致之毛髮之損傷正嚴重化。已知毛髮損傷會伴隨覆蓋毛髮表面之作為脂肪酸之18-MEA(18-甲基二十烷酸)之喪失，會引起毛髮表面之親水化，並且會引起表面摩擦之增大。受到損傷而親水化之毛髮不僅會失去柔順性，於洗髮後亦不易乾，利用吹風機等之乾燥需要較長時間，於體力上而言會成為負擔。又，濕潤之損傷毛容易糾結，吹風機乾燥中所產生之打結會成為進一步之損傷之累積與消費者之心理負擔。 然而，先前之毛髮處理劑為了對毛髮賦予柔順性或濕潤感而使聚矽氧類或油劑類殘留於毛髮上，該等由於具有黏著性，故而存在會抑制毛髮一根一根散開而使洗髮後之頭髮變乾耗費時間之問題。 因此，本發明係關於一種藉由於洗髮精洗髮後應用於頭髮後進行沖洗，不論所含有之陽離子界面活性劑之種類而可極其容易地使濕潤之頭髮一根一根散開，且不會使其糾結而可於短時間內使頭髮乾燥，並且沖洗時之柔順性優異之毛髮化妝料。 再者，於上述專利文獻2中記載有將護髮組合物塗抹於毛髮後之乾燥較快之情況。然而，該文獻中具體揭示之乾燥較快之護髮組合物僅為免沖洗型，且該發明中之「塗抹後之乾燥較快」之效果亦指護髮組合物本身之乾燥較快。因此，於該文獻中，關於水自塗抹於毛髮後進行沖洗而充分地濕潤之毛髮乾燥之速度完全未暗示。 作為提高洗髮後之頭髮之乾燥速度之因素，「頭髮之散開」較為重要。即，藉由使頭髮散開，用毛巾擦乾時與毛巾之接觸面積增大而頭髮之水分被毛巾迅速吸收，又，吹風機乾燥時(於自然乾燥時亦同樣)與空氣之接觸面積增大而頭髮之水分迅速蒸散。 本發明者等人發現，於護髮素、潤髮乳等於洗髮精後使用之沖洗型之毛髮化妝料中，藉由將特定結構之胺基-聚醚共改性聚矽氧與揮發性聚矽氧併用，毛髮上之黏著成分吸附量減少，且蓬鬆之黏著成分不易附著於毛髮。並且，結果發現，可減弱毛髮一根一根之黏著性，處理後之濕潤頭髮極其容易散開，不會糾結而可卓越地提高乾燥速度。 [成分(A)：陽離子界面活性劑] 作為成分(A)之陽離子界面活性劑，例如可列舉(i)烷基三甲基銨鹽、(ii)烷氧基烷基三甲基銨鹽、(iii)二烷基二甲基銨鹽、(iv)烷基二甲基胺及其鹽、(v)烷氧基烷基二甲基胺及其鹽、(vi)烷基醯胺基烷基二甲基胺及其鹽等。 (i)烷基三甲基銨鹽 作為烷基三甲基銨鹽，例如可列舉下述通式(1)所表示者。 R1
-N+
(CH3
)3
X-
(1) [式中，R1
表示碳數12～22之烷基，X-
表示氯化物離子、溴化物離子等鹵化物離子；甲基硫酸根離子、乙基硫酸根離子、甲基磷酸根離子、乙基磷酸根離子、甲基碳酸根離子等] 具體而言，可列舉氯化鯨蠟基三甲基銨、氯化硬脂基三甲基銨、氯化山崳基三甲基銨、山崳基三甲基銨甲基硫酸鹽等。 (ii)烷氧基烷基三甲基銨鹽 作為烷氧基烷基三甲基銨鹽，例如可列舉下述通式(2)所表示者。 R2
-O-R3
-N+
(CH3
)3
X-
(2) [式中，R2
表示碳數12～22之烷基，R3
表示可經羥基取代之伸乙基或伸丙基，X-
表示氯化物離子、溴化物離子等鹵化物離子；甲基硫酸根離子、乙基硫酸根離子、甲基磷酸根離子、乙基磷酸根離子、甲基碳酸根離子等] 具體而言，可列舉氯化硬脂醯氧基丙基三甲基銨、氯化硬脂醯氧基乙基三甲基銨、氯化硬脂醯氧基羥基丙基三甲基銨等。 (iii)二烷基二甲基銨鹽 作為二烷基二甲基銨鹽，例如可列舉下述通式(3)所表示者。 (R4
)2
N+
(CH3
)2
X-
(3) [式中，R4
分別獨立地表示碳數12～22之烷基或苄基，X-
表示氯化物離子、溴化物離子等鹵化物離子；甲基硫酸根離子、乙基硫酸根離子、甲基磷酸根離子、乙基磷酸根離子、甲基碳酸根離子等] 具體而言，可列舉氯化二硬脂基二甲基銨等。 (iv)烷基二甲基胺及其鹽 烷基二甲基胺與酸反應變成四級銨鹽，從而成為界面活性劑。因此，此處，將烷基二甲基胺及其鹽定義為陽離子界面活性劑。又，其含量係以烷基二甲基胺之質量進行換算。作為烷基二甲基胺及其鹽，例如可列舉下述通式(4)所表示者及其鹽。 R5
-N(CH3
)2
(4) [式中，R5
表示碳數12～22之烷基] 作為鹽，可列舉利用有機酸或無機酸而成之鹽。作為有機酸，例如可列舉：乙酸、丙酸等單羧酸；丙二酸、琥珀酸、戊二酸、己二酸、順丁烯二酸、反丁烯二酸、鄰苯二甲酸等二羧酸；聚麩胺酸等多羧酸；乙醇酸、乳酸、羥基丙烯酸、甘油酸、蘋果酸、酒石酸、檸檬酸等羥基羧酸；麩胺酸、天冬胺酸等酸性胺基酸等。作為無機酸，例如可列舉：鹽酸、硫酸、磷酸等。該等之中，較佳為有機酸，較佳為二羧酸、羥基羧酸、酸性胺基酸，作為二羧酸，更佳為順丁烯二酸、琥珀酸。作為羥基羧酸，更佳為乙醇酸、乳酸、蘋果酸。作為酸性胺基酸，更佳為麩胺酸。 作為具體之烷基二甲基胺及其鹽，可列舉：N,N-二甲基山崳基胺、N,N-二甲基硬脂基胺及該等之有機酸鹽，較佳為N,N-二甲基山崳基胺之乳酸鹽、N,N-二甲基硬脂基胺之乙醇酸鹽等。 (v)烷氧基烷基二甲基胺及其鹽 烷氧基烷基二甲基胺與酸反應變成四級銨鹽，從而成為界面活性劑。因此，此處，將烷氧基烷基二甲基胺及其鹽定義為陽離子界面活性劑。又，其含量係以烷氧基烷基二甲基胺之質量進行換算。作為烷氧基烷基二甲基胺及其鹽，例如可列舉下述通式(5)所表示者及其鹽。 R6
-O-R7
-N(CH3
)2
(5) [式中，R6
表示碳素數12～22之烷基，R7
表示伸乙基或伸丙基] 作為鹽，可列舉利用有機酸或無機酸而成之鹽。作為有機酸，例如可列舉：乙酸、丙酸等單羧酸；丙二酸、琥珀酸、戊二酸、己二酸、順丁烯二酸、反丁烯二酸、鄰苯二甲酸等二羧酸；聚麩胺酸等多羧酸；乙醇酸、乳酸、羥基丙烯酸、甘油酸、蘋果酸、酒石酸、檸檬酸等羥基羧酸；麩胺酸、天冬胺酸等酸性胺基酸等。作為無機酸，例如可列舉：鹽酸、硫酸、磷酸等。該等之中，較佳為有機酸，較佳為二羧酸、羥基羧酸、酸性胺基酸，作為二羧酸，更佳為順丁烯二酸、琥珀酸。作為羥基羧酸，更佳為乙醇酸、乳酸、蘋果酸。作為酸性胺基酸，更佳為麩胺酸。 作為具體之烷氧基烷基二甲基胺及其鹽，可列舉：N,N-二甲基-3-十六烷基氧基丙基胺、N,N-二甲基-3-十八烷基氧基丙基胺及該等之有機酸鹽，較佳為N,N-二甲基-3-十六烷基氧基丙基胺之乳酸鹽、N,N-二甲基-3-十八烷基氧基丙基胺之乙醇酸鹽。 (vi)烷基醯胺基烷基二甲基胺及其鹽 烷基醯胺基烷基二甲基胺與酸反應變成四級銨鹽，從而成為界面活性劑。因此，此處，將烷基醯胺基烷基二甲基胺及其鹽定義為陽離子界面活性劑。又，其含量係以烷基醯胺基烷基二甲基胺之質量進行換算。作為烷基醯胺基烷基二甲基胺及其鹽，例如可列舉下述通式(6)所表示者及其鹽。 R8
-CONH-(CH2
)m
-N(CH3
)2
(6) [式中，R8
表示碳數12～22之烷基，m表示2～4之數] 該等之中，就沖洗時之柔順性、吹風機乾燥中之不易糾結性之觀點而言，R8
較佳為碳數14～22之烷基，更佳為碳數16～20之烷基。 作為鹽，可列舉利用有機酸或無機酸而成之鹽。作為有機酸，例如可列舉：乙酸、丙酸等單羧酸；丙二酸、琥珀酸、戊二酸、己二酸、順丁烯二酸、反丁烯二酸、鄰苯二甲酸等二羧酸；聚麩胺酸等多羧酸；乙醇酸、乳酸、羥基丙烯酸、甘油酸、蘋果酸、酒石酸、檸檬酸等羥基羧酸；麩胺酸、天冬胺酸等酸性胺基酸等。作為無機酸，例如可列舉：鹽酸、硫酸、磷酸等。該等之中，較佳為有機酸，較佳為二羧酸、羥基羧酸、酸性胺基酸，作為二羧酸，更佳為順丁烯二酸、琥珀酸。作為羥基羧酸，更佳為乙醇酸、乳酸、蘋果酸。作為酸性胺基酸，更佳為麩胺酸。 作為具體之烷基醯胺基烷基二甲基胺及其鹽，可列舉：N-(3-(二甲胺基)丙基)二十二醯胺及其鹽、N-(3-(二甲胺基)丙基)硬脂醯胺及其鹽。 該等之中，較佳為(i)烷基三甲基銨鹽、(ii)烷氧基烷基三甲基銨鹽、(v)烷氧基烷基二甲基胺及其鹽、(vi)烷基醯胺基烷基二甲基胺及其鹽，就感覺到已經乾燥之前之時間之較短程度之觀點而言，較佳為(v)烷氧基烷基二甲基胺及其鹽、(vi)烷基醯胺基烷基二甲基胺及其鹽。進而，就沖洗時之柔順性、毛束之散開容易性、吹風機乾燥中之不易糾結性、及乾燥之快速性之觀點而言，較佳為N,N-二甲基-3-十六烷基氧基丙基胺及其鹽、N,N-二甲基-3-十八烷基氧基丙基胺及其鹽、N-(3-(二甲胺基)丙基)二十二醯胺及其鹽、N-(3-(二甲胺基)丙基)硬脂醯胺及其鹽。 成分(A)之陽離子界面活性劑可單獨使用任1種或將2種以上組合使用。就使用潤髮乳時之柔順性與適當之速乾性能之觀點而言，本發明之毛髮化妝料中之成分(A)之含量較佳為0.1質量%以上，更佳為0.5質量%以上，進而較佳為0.75質量%以上，又，較佳為10質量%以下，更佳為8質量%以下，進而較佳為6質量%以下，進而較佳為4質量%以下，進而較佳為3質量%以下。 [成分(B)：高級醇] 作為成分(B)之高級醇，亦可為直鏈及支鏈或飽和及不飽和之任一種脂肪族醇，其碳數較佳為10以上，更佳為14以上，進而較佳為16以上，又，較佳為22以下，更佳為20以下，進而較佳為18以下。具體而言，可列舉：月桂醇、肉豆蔻醇、鯨蠟醇、硬脂醇、花生醇、己基癸醇、異硬脂醇、油醇、2-辛基十二烷醇等。該等之中，較佳為硬脂醇、鯨蠟醇、肉豆蔻醇。該等高級醇可單獨使用任1種或將2種以上組合使用。 就自塗抹後沖洗時及乾燥後賦予之柔順性之觀點而言，本發明之毛髮化妝料中之成分(B)之含量較佳為1質量%以上，更佳為2質量%以上，進而較佳為3質量%以上，又，就速乾性能、乾燥後之黏膩性抑制、及調整為容易使用之黏度之觀點而言，較佳為10質量%以下，更佳為8質量%以下，進而較佳為7質量%以下，進而較佳為6質量%以下。 [成分(C)：具有聚氧伸烷基側鏈及胺基烷基側鏈之聚矽氧] 作為成分(C)之具有聚氧伸烷基側鏈及胺基烷基側鏈之聚矽氧，例如可列舉下述通式(7)所表示者。 [化1][式中，r表示1～50之整數，s表示1～50之整數，t表示1～50之整數，a表示0～50之整數，b表示0～50(a與b不會同時為0)，括號內之各結構單元彼此之鍵結順序可為任何順序，鍵結形態既可為嵌段狀，亦可為無規狀；R9
表示碳數1～6之二價烴基，R10
表示具有-R11
Z所表示之胺基或銨基之取代基；此處，R11
表示碳數1～6之二價烴基，Z表示選自由-NR12 2
、-NR12
(CH2
)c
NR12 2
、及-NR12
(CH2
)c
NR12
C=O(R13
)所組成之群中之一價基，R12
表示氫原子或碳數1～4之烴基，R13
表示碳數1～4之烴基，c表示2～6之整數，R14
表示碳數1～4之烴基或三甲基矽烷基] 該等之中，較佳為R9
為碳數2～4之二價烴基，R10
為-R11
-NH2
，R11
為碳數2～4之二價烴基，R12
及R14
分別獨立地為甲基或乙基。 就極其容易使濕潤頭髮一根一根散開以提高梳理性、並且使沖洗時之柔順性優異之觀點而言，成分(C)之25℃下之黏度較佳為4000 mm2
/s以下，更佳為3000 mm2
/s以下，進而較佳為2000 mm2
/s以下，進而較佳為1000 mm2
/s以下，進而較佳為800 mm2
/s以下，又，較佳為100 mm2
/s以上，更佳為200 mm2
/s以上。 再者，25℃下之黏度係使用毛細管式黏度計，測定固定容量之液體於25℃、1013.25 hPa下流過黏度計之毛細管之時間，並根據該流出時間與黏度計常數使用下述式而算出。毛細管式黏度計通常使用烏氏或Cannon-Fenske等型號。 ＜黏度之算出方法＞ 黏度(mm2
/s)＝流出時間(秒)×黏度計常數 作為成分(C)之具體例，可列舉：ABIL SOFT AF100(Evonik Industries公司製造：黏度400 mm2
/s)、X-22-3939A(信越化學工業公司製造：黏度2,800 mm2
/s)、Silsense A21(Lubrizol公司製造：黏度250 mm2
/s)等。 成分(C)之具有聚氧伸烷基側鏈及胺基烷基側鏈之聚矽氧可單獨使用任1種或將2種以上組合使用。就容易使濕潤頭髮散開、不會糾結而於短時間內使頭髮乾燥之觀點而言，本發明之毛髮化妝料中之成分(C)之含量較佳為0.05質量%以上，更佳為0.1質量%以上，進而較佳為0.2質量%以上，進而較佳為0.3質量%以上，又，就沖洗時之柔順性、乾燥中之不易糾結性、速乾性能、乾燥後之黏膩性抑制、及調整為容易使用之黏度之觀點而言，較佳為5質量%以下，更佳為4質量%以下，進而較佳為3質量%以下，進而較佳為2.5質量%以下。 [成分(D)：揮發性聚矽氧] 作為成分(D)之揮發性聚矽氧，可使用選自由1013.25 hPa下之沸點為260℃以下之鏈狀及環狀之聚矽氧油所組成之群中之1種或2種以上。又，就保存時之穩定性之觀點而言，較佳為1013.25 hPa下之沸點為35℃以上者。 作為鏈狀之揮發性聚矽氧，例如可列舉下述式(8)或下述通式(9)所表示之鏈狀聚矽氧，作為環狀之揮發性聚矽氧，例如可列舉下述通式(10)所表示之環狀聚矽氧。 [化2][化3] [式中，x表示0～5之整數] [化4] [式中，y表示3～6之整數] 其中，就極其容易使濕潤頭髮一根一根散開以提高梳理性、並且使沖洗時之柔順性優異之觀點而言，較佳為式(8)所表示之甲基三甲基聚矽氧烷。 成分(D)之揮發性聚矽氧可單獨使用任1種或將2種以上組合使用。就容易使濕潤頭髮散開、不會糾結而於短時間內使頭髮乾燥之觀點而言，本發明之毛髮化妝料中之成分(D)之含量較佳為0.05質量%以上，更佳為0.1質量%以上，進而較佳為0.5質量%以上，又，就毛髮之散開容易性、乾燥之快速性、沖洗時之乾澀感抑制、及乾燥後之黏膩性抑制之觀點而言，較佳為10質量%以下，更佳為8質量%以下，進而較佳為6質量%以下，進而較佳為4質量%以下，進而較佳為3質量%以下，進而較佳為2質量%以下。 又，就可使潤髮成分均勻地吸附於毛髮表面整體以減弱毛髮一根一根之黏著性、極其容易使處理後之濕潤頭髮散開、不會糾結而卓越地提高乾燥速度之觀點而言，成分(C)相對於成分(D)之質量比(C)/(D)較佳為0.01以上，更佳為0.05以上，進而較佳為0.08以上，進而較佳為0.1以上，進而較佳為0.2以上，又，較佳為5以下，更佳為4以下，進而較佳為3以下，進而較佳為2以下，進而較佳為1以下，進而較佳為0.8以下。 [水] 本發明之毛髮化妝料含有水作為介質。水成為成分(A)～(D)及其他成分之剩餘量。 [其他任意成分] 於本發明之毛髮化妝料中，亦可根據目的進而調配毛髮化妝料通常使用之其他成分。例如可列舉：二甲基聚矽氧烷、環狀聚矽氧、胺基改性聚矽氧、二甲聚矽氧烷醇、聚醚改性聚矽氧、聚去水甘油改性聚矽氧、甲基苯基聚矽氧烷、脂肪酸改性聚矽氧、醇改性聚矽氧、烷氧基改性聚矽氧、環氧改性聚矽氧、氟改性聚矽氧、烷基改性聚矽氧等成分(C)及(D)以外之聚矽氧類；陽離子化纖維素、羥烷基纖維素、高聚合聚環氧乙烷等高分子化合物；聚氧乙烯烷基醚、聚氧乙烯山梨糖醇酐脂肪酸酯、甘油單肪酸酯、聚甘油脂肪酸酯、聚氧乙烯氫化蓖麻油、蔗糖脂肪酸酯、聚甘油烷基醚、脂肪酸烷醇醯胺、烷基糖苷等非離子界面活性劑；角鯊烯、角鯊烷、液態石蠟、液態石蠟、環烷等烴；蓖麻油、可可油、貂油、萼梨油、橄欖油等甘油酯類；蜂蠟、鯨蠟、羊毛脂、巴西棕櫚蠟等蠟類；棕櫚酸異丙酯、肉豆蔻酸異丙酯、肉豆蔻酸辛基十二烷基酯、月桂酸己酯、乳酸鯨蠟酯、單硬脂酸丙二醇、油酸油脂、2-乙基己酸十六烷基酯、異壬酸異壬酯、異壬酸十三烷基酯等酯；癸酸、月桂酸、肉豆蔻酸、棕櫚酸、硬脂酸、山萮酸、油酸、椰子油脂肪酸、羊毛脂脂肪酸、異硬脂酸、異棕櫚酸等高級脂肪酸；異硬脂基甘油醚、聚氧丙烯丁醚等油劑；乙醇、1-丙醇、2-丙醇、丁醇、乙二醇、丙二醇、苄醇、苯氧基乙醇、2-苄氧基乙醇、甲基卡必醇、乙基卡必醇、丙基卡必醇、丁基卡必醇、三乙二醇單乙醚、三乙二醇單丁醚、甘油等醇類；硫代嘧啶氧鋅、氯化苄烷銨等抗頭屑劑；pH值調整劑；維生素劑；殺菌劑；抗炎劑；防腐劑；螯合劑；泛醇等保濕劑；染料、顏料等著色劑；桉樹之極性溶劑萃取物、自具有珍珠層之貝殼或珍珠獲得之蛋白質或其水解物、自絲獲得之蛋白質或其水解物、自豆科植物之種子獲得之含蛋白之萃取物、人參萃取物、米胚芽萃取物、墨角藻萃取物、山茶萃取物、蘆薈萃取物、月桃葉萃取物、綠藻萃取物等萃取物類；雲母鈦等珍珠粉體；薄荷腦等清涼劑：香料；色素；紫外線吸收劑；抗氧化劑；此外ENCYCLOPEDIA OF SHAMPOO INGREDIENTS(MICELLE PRESS)所記載之成分等。 [pH值] 本發明之毛髮化妝料之pH值較佳為2.0以上，進而較佳為2.5以上，又，較佳為7.5以下，進而較佳為6.5以下，進而較佳為5.5以下。再者，於本發明中，毛髮化妝料之pH值係指利用水進行20質量倍稀釋時之25℃下之值。 又，本發明之毛髮化妝料係應用於頭髮後進行沖洗而使用者，例如可列舉：護髮素、潤髮乳、頭髮護理劑、護髮膜等於浴室內使用者。 於使用本發明之毛髮化妝料進行頭髮之潤髮處理時，只要將本發明之毛髮化妝料塗抹於頭髮後利用水進行沖洗即可。藉此，沖洗時之柔順性優異且極其容易使濕潤頭髮一根一根散開、不會糾結而梳理性良好，從而可於短時間內使頭髮乾燥。 關於以上所述之實施形態，以下進而揭示本發明之較佳之態樣。 ＜1＞一種毛髮化妝料，其含有成分(A)～(D)及水，且係應用於毛髮後進行沖洗而使用。 (A)陽離子界面活性劑 (B)高級醇 (C)具有聚氧伸烷基側鏈及胺基烷基側鏈之聚矽氧 (D)揮發性聚矽氧 ＜2＞如＜1＞之毛髮化妝料，其中成分(A)較佳為選自由烷基三甲基銨鹽、烷氧基烷基三甲基銨鹽、二烷基二甲基銨鹽、烷基二甲基胺及其鹽、烷氧基烷基二甲基胺及其鹽、以及烷基醯胺基烷基二甲基胺及其鹽所組成之群中之1種或2種以上之化合物。 ＜3＞如＜1＞或＜2＞之毛髮化妝料，其中成分(A)之含量較佳為0.1質量%以上，更佳為0.5質量%以上，進而較佳為0.75質量%以上，又，較佳為10質量%以下，更佳為8質量%以下，進而較佳為6質量%以下，進而較佳為4質量%以下，進而較佳為3質量%以下。 ＜4＞如＜1＞至＜3＞中任一項之毛髮化妝料，其中成分(B)較佳為碳數10以上、更佳為碳數14以上、進而較佳為碳數16以上且較佳為碳數22以下、更佳為碳數20以下、進而較佳為碳數18以下之直鏈或支鏈之飽和或不飽和之脂肪族醇。 ＜5＞如＜1＞至＜4＞中任一項之毛髮化妝料，其中成分(B)之含量較佳為1質量%以上，更佳為2質量%以上，進而較佳為3質量%以上，又，較佳為10質量%以下，更佳為8質量%以下，進而較佳為7質量%以下，進而較佳為6質量%以下。 ＜6＞如＜1＞至＜5＞中任一項之毛髮化妝料，其中成分(C)較佳為下述通式(7)所表示者。 [化5][式中，r表示1～50之整數，s表示1～50之整數，t表示1～50之整數，a表示0～50之整數，b表示0～50(a與b不會同時為0)，括號內之各結構單元彼此之鍵結順序可為任何順序，鍵結形態既可為嵌段狀，亦可為無規狀；R9
表示碳數1～6之二價烴基，R10
表示具有-R11
Z所表示之胺基或銨基之取代基；此處，R11
表示碳數1～6之二價烴基，Z表示選自由-NR12 2
、-NR12
(CH2
)c
NR12 2
、及-NR12
(CH2
)c
NR12
C=O(R13
)所組成之群中之一價基，R12
表示氫原子或碳數1～4之烴基，R13
表示碳數1～4之烴基，c表示2～6之整數，R14
表示碳數1～4之烴基或三甲基矽烷基] ＜7＞如＜1＞至＜6＞中任一項之毛髮化妝料，其中成分(C)之25℃下之黏度較佳為4000 mm2
/s以下，更佳為3000 mm2
/s以下，進而較佳為2000 mm2
/s以下，進而較佳為1000 mm2
/s以下，進而較佳為800 mm2
/s以下，又，較佳為100 mm2
/s以上，更佳為200 mm2
/s以上。 ＜8＞如＜1＞至＜7＞中任一項之毛髮化妝料，其中成分(C)之含量較佳為0.05質量%以上，更佳為0.1質量%以上，進而較佳為0.2質量%以上，進而較佳為0.3質量%以上，又，較佳為5質量%以下，更佳為4質量%以下，進而較佳為3質量%以下，進而較佳為2.5質量%以下。 ＜9＞如＜1＞至＜8＞中任一項之毛髮化妝料，其中成分(D)較佳為選自由1013.25 hPa下之沸點為260℃以下之鏈狀及環狀之聚矽氧油所組成之群中之1種或2種以上。 ＜10＞如＜9＞之毛髮化妝料，其中成分(D)較佳為選自由式(8)所表示之鏈狀聚矽氧、通式(9)所表示之鏈狀聚矽氧、及通式(10)所表示之環狀聚矽氧所組成之群中之1種或2種以上之揮發性聚矽氧。 [化6][化7] [式中，x表示0～5之整數] [化8] [式中，y表示3～6之整數] ＜11＞如＜1＞至＜10＞中任一項之毛髮化妝料，其中成分(D)之含量較佳為0.05質量%以上，更佳為0.1質量%以上，進而較佳為0.5質量%以上，又，較佳為10質量%以下，更佳為8質量%以下，進而較佳為6質量%以下，進而較佳為4質量%以下，進而較佳為3質量%以下，進而較佳為2質量%以下。 ＜12＞如＜1＞至＜11＞中任一項之毛髮化妝料，其中成分(C)相對於成分(D)之質量比(C)/(D)較佳為0.01以上，更佳為0.05以上，進而較佳為0.08以上，進而較佳為0.1以上，進而較佳為0.2以上，又，較佳為5以下，更佳為4以下，進而較佳為3以下，進而較佳為2以下，進而較佳為1以下，進而較佳為0.8以下。 ＜13＞如＜1＞至＜12＞中任一項之毛髮化妝料，其中利用水進行20質量倍稀釋時之25℃下之pH值較佳為2.0以上，更佳為2.5以上，又，較佳為7.5以下，更佳為6.5以下，進而較佳為5.5以下。 ＜14＞一種毛髮處理方法，其將如＜1＞至＜13＞中任一項之毛髮化妝料塗抹於毛髮並利用水進行沖洗。 [實施例] 實施例1～11及比較例1～3 製備表1所示之潤髮乳，並依據以下之方法及基準進行官能評價及乾燥之快速性之測定。 (評價用髮束之製作方法) 將針對使用長度40 cm、乾燥時重量20 g之毛髮而製作之日本人毛髮束，利用市售之漂白劑(花王公司製造，泡沫染髮漂白劑)進行2次漂白處理(塗抹毛髮之5質量倍之漂白劑，並於室溫下進行30分鐘處理)，並利用普通洗髮精進行2次洗淨處理所得者用於以下之評價。 普通洗髮精(pH值7.0)之組成如下所述。 25%聚氧乙烯(2.5)月桂基醚硫酸鈉鹽 62質量% 月桂酸二乙醇醯胺 2.3質量% 依地酸二鈉 0.15質量% 苯甲酸鈉 0.5質量% 氯化鈉 0.8質量% 75%磷酸 適量 香料、對羥基苯甲酸甲酯 微量 純化水 剩餘量 合計 100質量% (官能評價) 「沖洗時之柔順性」 關於利用普通洗髮精將利用上述方法而製作之評價用髮束洗淨後，將水氣輕微地去除，塗抹表1所記載之潤髮乳1 g，並利用自來水沖洗時之「柔順性」，利用5名研究員實施官能評價。評價係利用以下之5個等級進行，算出5名之合計分。 5：非常柔順 4：柔順 3：難以評價 2：並不大柔順 1：不柔順 「毛束之散開容易性」 於上述「沖洗時之柔順性」之評價後，以該評價所使用之髮束之含水量成為10 g之方式進行調整。繼而，於髮束之上下依序放置紙巾(大王製紙公司製造，ELLEAIR PROWIPE)、丙烯酸板、砝碼(丙烯酸板與砝碼之總重量1.3 kg)，而將多餘之水分去除。將手指通過該髮束時之毛束之解散容易性、較小之毛束之形成容易性設為「毛束之散開容易性」，利用5名研究員實施官能評價。評價係利用以下之5個等級進行，算出5名之合計分。 5：非常容易散開 4：容易散開 3：難以評價 2：略不易散開 1：不易散開 「吹風機乾燥中之不易糾結性」 於上述「毛束之散開容易性」之評價後，將該評價所使用之髮束朝下設置，以吹風機(National公司製造，TURBODRY1300)之吹出口至毛髮髮束之毛髮中心部之距離為25 cm、暖風約自45°斜上方吹來之方式固定吹風機。繼而，一面每隔4秒使手指通過髮束1次，一面進行吹風機乾燥。此時，關於完全乾燥之前之「不易糾結性」，利用5名研究員進行官能評價。評價係利用以下之5個等級進行，算出5名之合計分。 5：不會糾結 4：幾乎不會糾結 3：難以評價 2：略微容易糾結 1：容易糾結 (乾燥之快速性) 於利用普通洗髮精將利用上述方法而製作之評價用髮束洗淨後，將水氣輕微地去除，塗抹表1所記載之潤髮乳1 g後，利用自來水進行沖洗並自然排水60秒，然後於髮束之上依序放置紙巾(大王製紙公司製造，ELLEAIR PROWIPE)、丙烯酸板、砝碼(丙烯酸板與砝碼之總重量1.3 kg)，而將多餘之水分去除。 將該毛髮髮束朝向設置，並以吹風機(Tescom公司製造，Nobby NB2501)之吹出口至毛髮髮束之毛髮中心部之距離成為45 cm之方式固定吹風機(弱暖風模式：600 W)。繼而，一面每隔4秒使手指通過1次，一面進行吹風機乾燥。此時，測量吹風機乾燥開始至研究員可判斷出毛髮完全乾燥為止之時間(秒)。將該操作及測量重複進行3次，將其平均值設為速乾性評價。 [表1]
*1：Farmin DM-E80(花王公司製造) *2：NIKKOL AMIDOAMINE MPS(NIPPON SURFACTANT工業公司製造) *3：Amidet APΑ-22(Kao Corporation,S.A.製造) *4：Quartamin 2285E-(E)(花王公司製造) *5：Quartamin 60W(花王公司製造) *6：Kalcol 8098(花王公司製造) *7：Kalcol 6098(花王公司製造) *8：ABIL SOFT AF100(Evonik Industries公司製造；黏度400 mm2
/s) *9：Silsense A21(Lubrizol公司製造；黏度250 mm2
/s) *10：XS65-C0032(Momentive Performance Materials・Japan合同公司) *11：TMF-1.5(信越化學工業公司製造；沸點191℃) *12：聚矽氧SH245FLUID(東麗道康寧公司製造；沸點205℃)In recent years, in addition to chemical treatments such as hair dyeing and perming, hair damage caused by the use of hair conditioners such as hair irons and hair dryers, which are gradually accustomed to young women, is becoming serious. It is known that hair damage is accompanied by loss of 18-MEA (18-methyl eicosanoid) as a fatty acid covering the surface of the hair, which causes hydrophilization of the surface of the hair and causes an increase in surface friction. The hair that is hydrophilized by the damage not only loses its flexibility, but also does not dry easily after shampooing. It takes a long time to dry with a hair dryer or the like, which is a burden on the physical strength. Moreover, the damaged hair is easily entangled, and the knotting caused by the drying of the hair dryer becomes a cumulative burden of further damage and a psychological burden on the consumer. However, the prior hair treatment agent causes the silicone or the oil to remain on the hair in order to impart a feeling of softness or moistness to the hair, and since it has adhesiveness, it may inhibit the hair from spreading one by one. Hair drying after shampooing takes time. Accordingly, the present invention relates to a method in which hair is rinsed after application to hair after shampooing, and it is extremely easy to spread the wet hair one by one regardless of the type of cationic surfactant contained therein. A hair cosmetic which is entangled to dry hair in a short period of time and which is excellent in softness during rinsing. Furthermore, in the above-mentioned Patent Document 2, the case where the hair care composition is applied to the hair and dried quickly is described. However, the hair drying composition which is specifically disclosed in this document is only a rinse-free type, and the effect of "slow drying after application" in the invention also means that the hair care composition itself dries faster. Therefore, in this document, the speed at which the hair is sufficiently wetted by rinsing from the hair after application to the hair is not at all suggestive. As a factor in improving the drying speed of hair after shampooing, "spreading of hair" is more important. That is, by spreading the hair, the contact area with the towel is increased when the towel is dried, and the moisture of the hair is quickly absorbed by the towel, and the contact area with the air is increased when the hair dryer is dried (in the case of natural drying). The moisture of the hair quickly diverges. The present inventors have found that in the rinse-type hair cosmetic used after conditioner and conditioner, the amino-polyether co-modified polyoxyl and the volatile structure of the specific structure are obtained. When polyoxymethylene is used in combination, the amount of adsorption of the adhesive component on the hair is reduced, and the bulky adhesive component is less likely to adhere to the hair. Further, as a result, it has been found that the adhesion of the hair can be weakened one by one, and the wet hair after the treatment is extremely easy to spread, and the drying speed can be excellently improved without entanglement. [Component (A): Cationic surfactant] Examples of the cationic surfactant of the component (A) include (i) an alkyltrimethylammonium salt and (ii) an alkoxyalkyltrimethylammonium salt. (iii) dialkyl dimethyl ammonium salt, (iv) alkyl dimethyl amine and salts thereof, (v) alkoxyalkyl dimethyl amine and salts thereof, (vi) alkyl decyl alkane Dimethylamine and its salts, etc. (i) Alkyltrimethylammonium Salt As the alkyltrimethylammonium salt, for example, those represented by the following formula (1) can be mentioned. R 1 -N + (CH 3 ) 3 X - (1) wherein R 1 represents an alkyl group having 12 to 22 carbon atoms, X - represents a halide ion such as a chloride ion or a bromide ion; and methyl sulfate Ionic, ethyl sulfate ion, methyl phosphate ion, ethyl phosphate ion, methyl carbonate ion, etc.] Specific examples thereof include cetyltrimethylammonium chloride and stearyl trisyl chloride. Alkyl ammonium, ceramyltrimethylammonium chloride, behenyltrimethylammonium methyl sulfate, and the like. (ii) Alkoxyalkyltrimethylammonium salt As the alkoxyalkyltrimethylammonium salt, for example, those represented by the following formula (2) can be mentioned. R 2 -OR 3 -N + (CH 3 ) 3 X - (2) wherein R 2 represents an alkyl group having 12 to 22 carbon atoms, and R 3 represents an exoethyl or propyl group which may be substituted by a hydroxyl group. X - represents a halide ion such as a chloride ion or a bromide ion; a methyl sulfate ion, an ethyl sulfate ion, a methyl phosphate ion, an ethyl phosphate ion, a methyl carbonate ion, etc.] Examples thereof include stearyloxypropyltrimethylammonium chloride, stearyloxyethyltrimethylammonium chloride, and stearyloxyhydroxypropyltrimethylammonium chloride. (iii) Dialkyldimethylammonium salt The dialkyldimethylammonium salt is exemplified by the following formula (3). (R 4 ) 2 N + (CH 3 ) 2 X - (3) wherein R 4 each independently represents an alkyl group having 12 to 22 carbon atoms or a benzyl group, and X - represents a chloride ion or a bromide ion. Halide ion; methyl sulfate ion, ethyl sulfate ion, methyl phosphate ion, ethyl phosphate ion, methyl carbonate ion, etc.] Specifically, distearyl dimethyl chloride Ammonium, etc. (iv) The alkyl dimethylamine and its salt alkyl dimethylamine are reacted with an acid to form a quaternary ammonium salt, thereby becoming a surfactant. Thus, herein, alkyldimethylamine and its salts are defined as cationic surfactants. Further, the content thereof is converted based on the mass of the alkyldimethylamine. Examples of the alkyldimethylamine and the salt thereof include those represented by the following formula (4) and salts thereof. R 5 -N(CH 3 ) 2 (4) [wherein R 5 represents an alkyl group having 12 to 22 carbon atoms] The salt may, for example, be a salt of an organic acid or an inorganic acid. Examples of the organic acid include monocarboxylic acids such as acetic acid and propionic acid; malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, and phthalic acid; A carboxylic acid; a polycarboxylic acid such as polyglutamic acid; a hydroxycarboxylic acid such as glycolic acid, lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid or citric acid; or an acidic amino acid such as glutamic acid or aspartic acid. Examples of the inorganic acid include hydrochloric acid, sulfuric acid, phosphoric acid, and the like. Among these, an organic acid is preferred, and a dicarboxylic acid, a hydroxycarboxylic acid, or an acidic amino acid is preferred, and as the dicarboxylic acid, more preferably, maleic acid or succinic acid. The hydroxycarboxylic acid is more preferably glycolic acid, lactic acid or malic acid. As the acidic amino acid, glutamic acid is more preferable. Specific examples of the alkyl dimethylamine and the salt thereof include N,N-dimethyl behenylamine, N,N-dimethylstearylamine and the organic acid salts thereof, and preferably Lactate of N,N-dimethylbehenylamine, glycolate of N,N-dimethylstearylamine, and the like. (v) Alkoxyalkyldimethylamine and its salt alkoxyalkyldimethylamine are reacted with an acid to form a quaternary ammonium salt to form a surfactant. Thus, herein, alkoxyalkyl dimethylamines and salts thereof are defined as cationic surfactants. Further, the content thereof is converted based on the mass of the alkoxyalkyldimethylamine. Examples of the alkoxyalkyldimethylamine and the salt thereof include those represented by the following formula (5) and salts thereof. R 6 -OR 7 -N(CH 3 ) 2 (5) wherein R 6 represents an alkyl group having 12 to 22 carbon atoms, and R 7 represents an ethyl group or a propyl group. a salt made of an acid or an inorganic acid. Examples of the organic acid include monocarboxylic acids such as acetic acid and propionic acid; malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, and phthalic acid; A carboxylic acid; a polycarboxylic acid such as polyglutamic acid; a hydroxycarboxylic acid such as glycolic acid, lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid or citric acid; or an acidic amino acid such as glutamic acid or aspartic acid. Examples of the inorganic acid include hydrochloric acid, sulfuric acid, phosphoric acid, and the like. Among these, an organic acid is preferred, and a dicarboxylic acid, a hydroxycarboxylic acid, or an acidic amino acid is preferred, and as the dicarboxylic acid, more preferably, maleic acid or succinic acid. The hydroxycarboxylic acid is more preferably glycolic acid, lactic acid or malic acid. As the acidic amino acid, glutamic acid is more preferable. Specific examples of the alkoxyalkyldimethylamine and salts thereof include N,N-dimethyl-3-hexadecyloxypropylamine and N,N-dimethyl-3-deca An octadecyloxypropylamine and the organic acid salt thereof, preferably a lactate of N,N-dimethyl-3-hexadecyloxypropylamine, N,N-dimethyl- Glycolate of 3-octadecyloxypropylamine. (vi) The alkylguanidinoalkyldimethylamine and its salt alkylguanamine alkyl dimethylamine are reacted with an acid to form a quaternary ammonium salt to become a surfactant. Thus, herein, alkyl guanaminoalkyl dimethylamine and salts thereof are defined as cationic surfactants. Further, the content thereof is converted based on the mass of the alkylguanamine alkyldimethylamine. Examples of the alkylguanamine alkyl dimethylamine and a salt thereof include those represented by the following formula (6) and salts thereof. R 8 -CONH-(CH 2 ) m -N(CH 3 ) 2 (6) wherein R 8 represents an alkyl group having 12 to 22 carbon atoms, and m represents a number of 2 to 4; From the viewpoint of flexibility during rinsing and difficulty in entanglement in drying of the hair dryer, R 8 is preferably an alkyl group having 14 to 22 carbon atoms, more preferably an alkyl group having 16 to 20 carbon atoms. The salt is a salt obtained by using an organic acid or an inorganic acid. Examples of the organic acid include monocarboxylic acids such as acetic acid and propionic acid; malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, and phthalic acid; A carboxylic acid; a polycarboxylic acid such as polyglutamic acid; a hydroxycarboxylic acid such as glycolic acid, lactic acid, hydroxyacrylic acid, glyceric acid, malic acid, tartaric acid or citric acid; or an acidic amino acid such as glutamic acid or aspartic acid. Examples of the inorganic acid include hydrochloric acid, sulfuric acid, phosphoric acid, and the like. Among these, an organic acid is preferred, and a dicarboxylic acid, a hydroxycarboxylic acid, or an acidic amino acid is preferred, and as the dicarboxylic acid, more preferably, maleic acid or succinic acid. The hydroxycarboxylic acid is more preferably glycolic acid, lactic acid or malic acid. As the acidic amino acid, glutamic acid is more preferable. Specific examples of the alkyl guanamine alkyl dimethylamine and salts thereof include N-(3-(dimethylamino)propyl) behenylamine and salts thereof, and N-(3-( Dimethylamino)propyl)stearylamine and its salts. Among these, (i) alkyltrimethylammonium salt, (ii) alkoxyalkyltrimethylammonium salt, (v) alkoxyalkyldimethylamine and salts thereof, ( Vi) alkyl amidinoalkyl dimethylamine and salts thereof, preferably (v) alkoxyalkyl dimethylamine and from the viewpoint of a short period of time before the drying has been felt Its salt, (vi) alkylguanidinoalkyldimethylamine and salts thereof. Further, N,N-dimethyl-3-hexadecane is preferred from the viewpoints of flexibility at the time of rinsing, ease of spreading of the hair bundle, difficulty in entanglement in drying of the hair dryer, and rapidity of drying. Hydroxypropylamine and its salt, N,N-dimethyl-3-octadecyloxypropylamine and its salt, N-(3-(dimethylamino)propyl) 22 Indamine and its salts, N-(3-(dimethylamino)propyl)stearylamine and its salts. The cationic surfactant of the component (A) may be used alone or in combination of two or more. The content of the component (A) in the hair cosmetic of the present invention is preferably 0.1% by mass or more, and more preferably 0.5% by mass or more, from the viewpoint of flexibility in the use of the hair conditioner and appropriate quick-drying properties. Further, it is preferably 0.75% by mass or more, more preferably 10% by mass or less, still more preferably 8% by mass or less, further preferably 6% by mass or less, further preferably 4% by mass or less, and further preferably 3% by mass. Below mass%. [Component (B): Higher alcohol] The higher alcohol as the component (B) may be any of aliphatic alcohols which are linear or branched or saturated or unsaturated, and preferably have a carbon number of 10 or more, more preferably 14 or more, further preferably 16 or more, more preferably 22 or less, still more preferably 20 or less, still more preferably 18 or less. Specific examples thereof include lauryl alcohol, myristyl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol, hexyl decyl alcohol, isostearyl alcohol, oleyl alcohol, 2-octyldodecanol, and the like. Among these, stearyl alcohol, cetyl alcohol, and myristyl alcohol are preferable. These higher alcohols may be used alone or in combination of two or more. The content of the component (B) in the hair cosmetic of the present invention is preferably 1% by mass or more, more preferably 2% by mass or more, from the viewpoint of the flexibility imparted during the rinsing after rinsing and after drying. It is preferably 3% by mass or more, and is preferably 10% by mass or less, and more preferably 8% by mass or less, from the viewpoints of quick-drying performance, suppression of viscosity after drying, and adjustment to an easy-to-use viscosity. Further, it is preferably 7% by mass or less, and more preferably 6% by mass or less. [Component (C): polyfluorene having a polyoxyalkylene side chain and an aminoalkyl side chain] as a component (C) having a polyoxyalkylene side chain and an aminoalkyl side chain Examples of the oxygen include those represented by the following formula (7). [Chemical 1] [wherein, r represents an integer of 1 to 50, s represents an integer of 1 to 50, t represents an integer of 1 to 50, a represents an integer of 0 to 50, and b represents 0 to 50 (a and b are not simultaneously 0) The order of bonding the structural units in the parentheses may be any order, and the bonding form may be either block-like or random; R 9 represents a divalent hydrocarbon group having 1 to 6 carbon atoms, R 10 And a substituent having an amine group or an ammonium group represented by -R 11 Z; wherein R 11 represents a divalent hydrocarbon group having 1 to 6 carbon atoms, and Z represents a group selected from -NR 12 2 and -NR 12 (CH 2 ) c NR 12 2 , and -NR 12 (CH 2 ) c NR 12 C=O(R 13 ) one of the groups of valent groups, R 12 represents a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms, and R 13 represents a hydrocarbon group having 1 to 4 carbon atoms, c is an integer of 2 to 6, and R 14 is a hydrocarbon group having 1 to 4 carbon atoms or a trimethylsulfanyl group. Among them, R 9 is preferably a carbon number of 2 to 4 The divalent hydrocarbon group, R 10 is -R 11 -NH 2 , R 11 is a divalent hydrocarbon group having 2 to 4 carbon atoms, and R 12 and R 14 are each independently a methyl group or an ethyl group. The viscosity of the component (C) at 25 ° C is preferably 4000 mm 2 /s or less, from the viewpoint that it is extremely easy to spread the wet hair one by one to improve combability and to make the softness during rinsing excellent. Preferably, it is 3000 mm 2 /s or less, further preferably 2000 mm 2 /s or less, further preferably 1000 mm 2 /s or less, further preferably 800 mm 2 /s or less, and further preferably 100 mm 2 Above /s, more preferably 200 mm 2 /s or more. Further, the viscosity at 25 ° C was measured by using a capillary viscometer to measure the time during which the liquid of a fixed capacity flows through the capillary of the viscometer at 25 ° C and 1013.25 hPa, and calculated based on the outflow time and the viscosity constant using the following formula. . Capillary viscometers are usually available in Ubbel or Cannon-Fenske models. <Method for Calculating Viscosity> Viscosity (mm 2 /s) = Outflow Time (sec) × Viscosity Meter Constant As a specific example of the component (C), ABIL SOFT AF100 (manufactured by Evonik Industries: viscosity 400 mm 2 /s) ), X-22-3939A (manufactured by Shin-Etsu Chemical Co., Ltd.: viscosity 2,800 mm 2 /s), Silsense A21 (manufactured by Lubrizol: viscosity 250 mm 2 /s). The polyoxyl oxide having a polyoxyalkylene side chain and an aminoalkyl side chain of the component (C) may be used alone or in combination of two or more. The content of the component (C) in the hair cosmetic of the present invention is preferably 0.05% by mass or more, more preferably 0.1%, from the viewpoint of easily spreading the wet hair without tangling and drying the hair in a short time. % or more, more preferably 0.2% by mass or more, further preferably 0.3% by mass or more, and further, flexibility in rinsing, difficulty in tangling during drying, quick-drying property, viscosity inhibition after drying, and From the viewpoint of the viscosity to be easily used, it is preferably 5% by mass or less, more preferably 4% by mass or less, further preferably 3% by mass or less, and further preferably 2.5% by mass or less. [Component (D): Volatile polyoxo] As the volatile polyoxane of the component (D), a chain-like and cyclic polyoxyxene oil having a boiling point of 260 ° C or lower at 1013.25 hPa may be used. One or two or more of the group. Further, from the viewpoint of stability at the time of storage, it is preferably a boiling point of 35 ° C or higher at 1013.25 hPa. Examples of the chain-like volatile polyfluorene oxide include a chain polyfluorene represented by the following formula (8) or the following formula (9), and examples of the cyclic polyfluorinated oxygen include, for example, The cyclic polyfluorene represented by the formula (10). [Chemical 2] [Chemical 3] [where x represents an integer of 0 to 5] [Chemical 4] [wherein, y represents an integer of 3 to 6] Among them, it is preferable that the wet hair is spread out one by one to improve the combability and the flexibility at the time of rinsing is excellent, and it is preferable that the formula (8) Methyltrimethyl polyoxane represented. The volatile polysiloxane of the component (D) may be used alone or in combination of two or more. The content of the component (D) in the hair cosmetic of the present invention is preferably 0.05% by mass or more, more preferably 0.1%, from the viewpoint of easily spreading the wet hair without tangling and drying the hair in a short time. % or more, and more preferably 0.5% by mass or more, and it is preferably 10 in terms of ease of spreading of hair, rapidness of drying, suppression of dryness during rinsing, and suppression of stickiness after drying. The mass% or less is more preferably 8% by mass or less, further preferably 6% by mass or less, further preferably 4% by mass or less, further preferably 3% by mass or less, and further preferably 2% by mass or less. Moreover, the hair styling component can be uniformly adsorbed on the entire surface of the hair to reduce the stickiness of the hair, and it is extremely easy to spread the wet hair after the treatment, and it is not entangled, and the drying speed is excellently improved. The mass ratio (C)/(D) of the component (C) to the component (D) is preferably 0.01 or more, more preferably 0.05 or more, still more preferably 0.08 or more, still more preferably 0.1 or more, and still more preferably 0.2 or more, more preferably 5 or less, still more preferably 4 or less, further preferably 3 or less, further preferably 2 or less, further preferably 1 or less, further preferably 0.8 or less. [Water] The hair cosmetic of the present invention contains water as a medium. Water is the remaining amount of the components (A) to (D) and other components. [Other optional components] In the hair cosmetic of the present invention, other components generally used for the hair cosmetic may be further blended according to the purpose. For example, dimethyl polyoxyalkylene, cyclic polyfluorene oxide, amine modified polyoxyn oxide, dimethicone, polyether modified polyoxyl, polydehydrate modified poly Oxygen, methylphenyl polyoxyalkylene, fatty acid modified polyoxyl, alcohol modified polyoxyl, alkoxy modified polyoxyl, epoxy modified polyoxygen, fluorine modified polyoxyn, alkane a polyoxymethane other than the components (C) and (D), such as a modified polyfluorene oxygen; a polymer compound such as a cationized cellulose, a hydroxyalkyl cellulose or a highly polymerized polyethylene oxide; a polyoxyethylene alkyl group; Ether, polyoxyethylene sorbitan fatty acid ester, glycerol mono-fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene hydrogenated castor oil, sucrose fatty acid ester, polyglyceryl alkyl ether, fatty acid alkanolamine, alkane Nonionic surfactants such as glucosides; squalene, squalane, liquid paraffin, liquid paraffin, naphthenic hydrocarbons, etc.; glycerides such as castor oil, cocoa butter, eucalyptus oil, avocado oil, olive oil; beeswax, Waxes such as cetyl, lanolin, carnauba wax; isopropyl palmitate, isopropyl myristate, octyldodecyl myristate, month Acid hexyl ester, cetyl lactate, propylene glycol monostearate, oleic acid oil, cetyl 2-ethylhexanoate, isodecyl isononanoate, tridecyl isononate, etc.; Acid, lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, coconut oil fatty acid, lanolin fatty acid, isostearic acid, isopalmitic acid and other higher fatty acids; isostearyl glyceryl ether, Oil agent such as polyoxypropylene butyl ether; ethanol, 1-propanol, 2-propanol, butanol, ethylene glycol, propylene glycol, benzyl alcohol, phenoxyethanol, 2-benzyloxyethanol, methyl carbitol , ethyl carbitol, propyl carbitol, butyl carbitol, triethylene glycol monoethyl ether, triethylene glycol monobutyl ether, glycerol and other alcohols; thiopyrimidine zinc oxide, benzalkonium chloride Anti-dandruff agent; pH adjuster; vitamin agent; fungicide; anti-inflammatory agent; preservative; chelating agent; humectant such as panthenol; dye, pigment and other coloring agent; polar solvent extract of eucalyptus, self-having pearl a protein obtained by shell or pearl of a layer or a hydrolyzate thereof, a protein obtained from silk or a hydrolyzate thereof, and a seed obtained from a leguminous plant White extract, ginseng extract, rice germ extract, fucus extract, camellia extract, aloe extract, moon leaf extract, green algae extract, etc.; mica titanium and other pearl powder; mint Brain and other cooling agents: perfume; pigment; UV absorber; antioxidant; in addition to the ingredients described in ENCYCLOPEDIA OF SHAMPOO INGREDIENTS (MICELLE PRESS). [pH value] The pH of the hair cosmetic of the present invention is preferably 2.0 or more, more preferably 2.5 or more, still more preferably 7.5 or less, still more preferably 6.5 or less, still more preferably 5.5 or less. Further, in the present invention, the pH of the hair cosmetic refers to a value at 25 ° C when diluted with water by 20 times. Further, the hair cosmetic of the present invention is applied to the hair after being applied to the hair, and examples thereof include hair conditioner, hair lotion, hair care agent, and hair care film, which are equal to the user in the bathroom. When the hair cosmetic treatment of the present invention is carried out using the hair cosmetic of the present invention, the hair cosmetic of the present invention may be applied to the hair and rinsed with water. Thereby, the flexibility at the time of rinsing is excellent and it is extremely easy to make the wet hair spread one by one without entanglement and the combing is good, so that the hair can be dried in a short time. With regard to the above-described embodiments, the preferred aspects of the present invention are further disclosed below. <1> A hair cosmetic comprising components (A) to (D) and water, which are applied to the hair and rinsed. (A) Cationic surfactant (B) Higher alcohol (C) having a polyoxyalkylene side chain and an aminoalkyl side chain of polyoxyl (D) volatile polyoxo <2> such as <1> a hair cosmetic wherein component (A) is preferably selected from the group consisting of alkyltrimethylammonium salts, alkoxyalkyltrimethylammonium salts, dialkyldimethylammonium salts, alkyldimethylamines, and One or two or more compounds selected from the group consisting of a salt, an alkoxyalkyldimethylamine and a salt thereof, and a alkylguanamine alkyldimethylamine and a salt thereof. <3> The hair cosmetic of <1> or <2>, wherein the content of the component (A) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 0.75% by mass or more, and further, It is preferably 10% by mass or less, more preferably 8% by mass or less, further preferably 6% by mass or less, further preferably 4% by mass or less, and further preferably 3% by mass or less. The hair cosmetic according to any one of <1> to <3>, wherein the component (B) is preferably a carbon number of 10 or more, more preferably a carbon number of 14 or more, still more preferably a carbon number of 16 or more. A linear or branched saturated or unsaturated aliphatic alcohol having a carbon number of 22 or less, more preferably 20 or less carbon atoms, still more preferably 18 or less carbon atoms is preferable. The hair cosmetic of any one of <1> to <4>, wherein the content of the component (B) is preferably 1% by mass or more, more preferably 2% by mass or more, and still more preferably 3% by mass. In addition, it is preferably 10% by mass or less, more preferably 8% by mass or less, further preferably 7% by mass or less, and further preferably 6% by mass or less. <6> The hair cosmetic according to any one of <1> to <5> wherein the component (C) is preferably represented by the following formula (7). [Chemical 5] [wherein, r represents an integer of 1 to 50, s represents an integer of 1 to 50, t represents an integer of 1 to 50, a represents an integer of 0 to 50, and b represents 0 to 50 (a and b are not simultaneously 0) The order of bonding the structural units in the parentheses may be any order, and the bonding form may be either block-like or random; R 9 represents a divalent hydrocarbon group having 1 to 6 carbon atoms, R 10 And a substituent having an amine group or an ammonium group represented by -R 11 Z; wherein R 11 represents a divalent hydrocarbon group having 1 to 6 carbon atoms, and Z represents a group selected from -NR 12 2 and -NR 12 (CH 2 ) c NR 12 2 , and -NR 12 (CH 2 ) c NR 12 C=O(R 13 ) one of the groups of valent groups, R 12 represents a hydrogen atom or a hydrocarbon group having 1 to 4 carbon atoms, and R 13 represents a hydrocarbon group having 1 to 4 carbon atoms, c is an integer of 2 to 6, and R 14 is a hydrocarbon group having 1 to 4 carbon atoms or a trimethylsulfanyl group. <7> The hair of any one of <1> to <6> In the cosmetic, the viscosity at 25 ° C of the component (C) is preferably 4,000 mm 2 /s or less, more preferably 3,000 mm 2 /s or less, further preferably 2,000 mm 2 /s or less, and further preferably 1,000 or less. Mm 2 /s or less, further preferably 800 mm 2 /s or less, further preferably 100 mm 2 /s or more, More preferably 200 mm 2 /s or more. The hair cosmetic of any one of <1> to <7>, wherein the content of the component (C) is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, and still more preferably 0.2% by mass. The above is more preferably 0.3% by mass or more, further preferably 5% by mass or less, more preferably 4% by mass or less, still more preferably 3% by mass or less, and still more preferably 2.5% by mass or less. <9> The hair cosmetic according to any one of <1> to <8> wherein the component (D) is preferably a chain-like and cyclic polyoxyxene oil having a boiling point of 260 ° C or less at 1013.25 hPa. One or more of the group consisting of. <10> The hair cosmetic according to <9>, wherein the component (D) is preferably selected from the group consisting of chain polyoxyl represented by the formula (8), chain polyoxyl represented by the formula (9), and One or two or more kinds of volatile polyfluorene oxides of the group consisting of cyclic polyfluorene oxygen represented by the formula (10). [Chemical 6] [Chemistry 7] [where x represents an integer from 0 to 5] [Chemical 8] [In the formula, y represents an integer of 3 to 6] The hair cosmetic according to any one of <1> to <10>, wherein the content of the component (D) is preferably 0.05% by mass or more, more preferably 0.1% by mass or more, more preferably 0.5% by mass or more, further preferably 10% by mass or less, more preferably 8% by mass or less, further preferably 6% by mass or less, and further preferably 4% by mass or less. Further, it is preferably 3% by mass or less, and more preferably 2% by mass or less. <12> The hair cosmetic according to any one of <1> to <11> wherein the mass ratio (C)/(D) of the component (C) to the component (D) is preferably 0.01 or more, more preferably 0.05 or more, more preferably 0.08 or more, further preferably 0.1 or more, further preferably 0.2 or more, further preferably 5 or less, more preferably 4 or less, still more preferably 3 or less, still more preferably 2 Hereinafter, it is more preferably 1 or less, further preferably 0.8 or less. <13> The hair cosmetic according to any one of <1> to <12> wherein the pH at 25 ° C when diluted with water by 20 times is preferably 2.0 or more, more preferably 2.5 or more, and further, It is preferably 7.5 or less, more preferably 6.5 or less, still more preferably 5.5 or less. <14> A hair treatment method according to any one of <1> to <13>, which is applied to the hair and rinsed with water. [Examples] Examples 1 to 11 and Comparative Examples 1 to 3 The hair conditioners shown in Table 1 were prepared, and the sensory evaluation and the rapid measurement of the drying were carried out in accordance with the following methods and standards. (Method for producing hair bundle for evaluation) A Japanese hair bundle prepared by using a hair having a length of 40 cm and a weight of 20 g when dry is used twice by using a commercially available bleach (manufactured by Kao Corporation, foam dyed bleach). The bleaching treatment (5 mass times of bleaching agent applied to the hair, and treatment at room temperature for 30 minutes) was carried out twice by ordinary shampoo, and the obtained one was used for the following evaluation. The composition of ordinary shampoo (pH 7.0) is as follows. 25% polyoxyethylene (2.5) sodium lauryl ether sulfate 62% by mass lauric acid diethanol decylamine 2.3% by mass disodium edetate 0.15 mass% sodium benzoate 0.5 mass% sodium chloride 0.8 mass% 75% phosphoric acid (100% by mass of the residual amount of the purified water of methylparaben) (Functional evaluation) "Softness during rinsing" The water used for evaluation by the above method is washed with ordinary shampoo. The gas was slightly removed, and 1 g of the hair lotion described in Table 1 was applied, and the "smoothness" at the time of washing with tap water was used, and five researchers were used for the sensory evaluation. The evaluation was performed using the following five grades, and the total score of five was calculated. 5: Very compliant 4: Supple 3: Difficult to evaluate 2: Not very compliant 1: Not compliant "Easy to spread the hair bundle" After the above evaluation of "smoothness during rinsing", the hair bundle used for the evaluation The water content was adjusted to be 10 g. Then, paper towels ( ELLEAIR PROWIPE, ELLEAIR PROWIPE), acrylic plate, weight (1.3 kg total weight of acrylic plate and weight) were placed on top of the hair bundle to remove excess water. The ease of dissolving the hair bundle when the finger was passed through the hair bundle and the ease of formation of the small hair bundle were referred to as "easiness of spreading of the hair bundle", and the panelists performed the sensory evaluation by five researchers. The evaluation was performed using the following five grades, and the total score of five was calculated. 5: It is very easy to spread out 4: It is easy to spread out 3: It is difficult to evaluate 2: It is not easy to spread out 1: It is not easy to spread "It is not easy to entangle in the drying of the hair dryer" After the evaluation of the above-mentioned "easiness of spreading of the hair bundle", the evaluation is used. The hair bundle was set downward, and the hair dryer was fixed in such a manner that the distance from the air outlet of the hair dryer (National, TURBODRY 1300) to the hair center of the hair bundle was 25 cm, and the warm air was blown from the 45° obliquely upward. Then, the finger was passed through the hair bundle once every 4 seconds, and the hair dryer was dried. At this time, the "non-tangling property" before the complete drying was evaluated by five researchers. The evaluation was performed using the following five grades, and the total score of five was calculated. 5: No entanglement 4: Almost no entanglement 3: Difficult to evaluate 2: Slightly easy to entangle 1: Easy to entangle (fastness of drying) After washing the hair with the evaluation made by the above method using ordinary shampoo The water vapor was slightly removed, and 1 g of the hair lotion described in Table 1 was applied, and then rinsed with tap water and naturally drained for 60 seconds, and then the paper towel was placed on the hair bundle (manufactured by Dawang Paper Co., ELLEAIR PROWIPE). Acrylic plate, weight (1.3 kg total weight of acrylic plate and weight), and remove excess water. The hair bundle was placed facing the hair, and the hair dryer (weak warm air mode: 600 W) was fixed so that the distance from the air outlet of the hair dryer (Nobby NB2501 manufactured by Tescom, Nobby NB2501) to the hair center of the hair bundle was 45 cm. Then, the finger was passed once every 4 seconds, and the hair dryer was dried. At this time, the time (in seconds) from when the hair dryer is dried to when the researcher can judge that the hair is completely dry is measured. This operation and measurement were repeated three times, and the average value thereof was set as a quick-drying evaluation. [Table 1] *1: Farmin DM-E80 (manufactured by Kao Corporation) *2: NIKKOL AMIDOAMINE MPS (manufactured by NIPPON SURFACTANT Industries) *3: Amidet APΑ-22 (manufactured by Kao Corporation, SA) *4: Quartamin 2285E-(E) (Kao Manufactured by the company *5: Quartamin 60W (manufactured by Kao Corporation) *6: Kalcol 8098 (manufactured by Kao Corporation) *7: Kalcol 6098 (manufactured by Kao Corporation) *8: ABIL SOFT AF100 (manufactured by Evonik Industries; viscosity 400 mm 2 / s) *9: Silsense A21 (manufactured by Lubrizol; viscosity 250 mm 2 /s) *10: XS65-C0032 (Momentive Performance Materials, Japan Contract Company) *11: TMF-1.5 (manufactured by Shin-Etsu Chemical Co., Ltd.; boiling point 191 °C *12: Polyoxane SH245FLUID (manufactured by Toray Dow Corning; boiling point 205 ° C)