TW201726989A - Tough thread and its core thread, knitted fabric, and gloves not exposing a breaking end of a hard fiber making a wearer unpleasant - Google Patents

Tough thread and its core thread, knitted fabric, and gloves not exposing a breaking end of a hard fiber making a wearer unpleasant Download PDF

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Publication number
TW201726989A
TW201726989A TW105139065A TW105139065A TW201726989A TW 201726989 A TW201726989 A TW 201726989A TW 105139065 A TW105139065 A TW 105139065A TW 105139065 A TW105139065 A TW 105139065A TW 201726989 A TW201726989 A TW 201726989A
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Taiwan
Prior art keywords
fiber
fibers
hard
molten
thread
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TW105139065A
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Chinese (zh)
Inventor
Satoshi BINSHU
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Satoshi BINSHU
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Priority claimed from JP2016011777A external-priority patent/JP2016223054A/en
Application filed by Satoshi BINSHU filed Critical Satoshi BINSHU
Publication of TW201726989A publication Critical patent/TW201726989A/en

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Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00Gloves
    • A41D19/015Protective gloves
    • A41D19/01505Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/04Blended or other yarns or threads containing components made from different materials
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/36Cored or coated yarns or threads
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/40Yarns in which fibres are united by adhesives; Impregnated yarns or threads
    • D02G3/402Yarns in which fibres are united by adhesives; Impregnated yarns or threads the adhesive being one component of the yarn, i.e. thermoplastic yarn
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/44Yarns or threads characterised by the purpose for which they are designed
    • D02G3/442Cut or abrasion resistant yarns or threads
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2321/00Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D10B2321/02Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins
    • D10B2321/021Fibres made from polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds polyolefins polyethylene
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/061Load-responsive characteristics elastic
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2401/00Physical properties
    • D10B2401/06Load-responsive characteristics
    • D10B2401/062Load-responsive characteristics stiff, shape retention
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2501/00Wearing apparel
    • D10B2501/04Outerwear; Protective garments
    • D10B2501/041Gloves

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
  • Woven Fabrics (AREA)
  • Gloves (AREA)
  • Knitting Of Fabric (AREA)

Abstract

The present invention provides a tough thread and its core thread, knitted fabric, and gloves. The gloves herein are suitable for operators to wear in a knife-using workplace, a steel material factory, a plate glass factory, and the like; they are soft and economically superior, and it is impossible to expose a breaking end of a hard fiber making a wearer unpleasant. The method comprises providing a thread (20); a strong thread is formed by a thread that wraps the thread (20) as a core thread; a knitted fabric and gloves are formed by using the tough thread and knitted fabric of the other thread to have a yarn-adding knitting, a double faced knitting, a double layer knitting, and the like. The thread (20) herein comprises hard fibers (1) and melting fibers (2) made of metal fibers, glass fibers and the like. A superior option further comprises under-layer fibers (3) as a third fiber, which, after composite treatment (twisting or wrapping), is subjected to a heat treatment to melt (2b) the melting fibers (2) that are fused with the hard fibers (1) and the under-layer fibers (3), forming a single body.

Description

強韌線及其芯線、編織物及手套Tough line and its core wire, braid and gloves

本發明涉及作業者在使用刀具的作業場所、鋼材廠、板玻璃廠等處佩戴的手套、衣服及其它布製品所使用的編織物、以及該編織物所使用的線,並且涉及含有金屬纖維、玻璃纖維、碳纖維、多芳基化合物纖維等強韌但柔軟性差的纖維(下麵,稱為“硬質纖維”)的芯線、使用了該芯線的強韌線、具備耐切割性的編織物及手套。The present invention relates to a knitted fabric used for an operator to wear gloves, clothes, and other cloth products at a work place where a tool is used, a steel factory, a sheet glass factory, and the like, and a thread used for the knitted fabric, and relates to a metal fiber, A core wire of a tough but inflexible fiber (hereinafter referred to as "hard fiber") such as glass fiber, carbon fiber or polyarylate fiber, a tough line using the core wire, a knitted fabric having cut resistance, and a glove.

在使用刀具的作業場所、鋼材廠、板玻璃廠等處使用的布製品、特別是供作業者佩戴的手套、綁腿、圍裙等要求即使刀具的切削刃觸碰到也不被切斷的所謂耐切割性。作為具備耐切割性的手套、衣服所用的線,廣泛使用以ダイニーマ(注册商標)的名稱被廣為人知的超高密度聚乙烯纖維及芳綸纖維等强力絲。特別是超高密度聚乙烯纖維適合作為用於編織在使用刀具的作業場所使用的手套的線。A cloth product used in a work place where a tool is used, a steel factory, a plate glass factory, etc., in particular, a glove, a legging, an apron, etc., which are worn by an operator, are required to be cut even if the cutting edge of the tool is touched. Cutting. As a thread for gloves and clothing having cut resistance, a strong yarn such as ultra-high-density polyethylene fiber or aramid fiber, which is widely known by the name of ダイニーマ (registered trademark), is widely used. In particular, ultra high density polyethylene fibers are suitable as a thread for knitting gloves used in a work place where a cutter is used.

此外,作為以同樣目的使用的線,還使用以聚乙烯及尼龍包覆金屬細線及玻璃纖維而形成的線。這種線無伸縮性,在彎曲時金屬細線及玻璃纖維彎曲成銳角或容易折斷。此外,在使用這種線來編織手套等時,與聚氨酯纖維、生橡膠等具備伸縮性的編織線交織以賦予柔軟性及合身性。Further, as a wire used for the same purpose, a wire formed by coating metal fine wires and glass fibers with polyethylene and nylon is also used. This kind of wire has no stretchability, and the thin metal wires and the glass fibers are bent at an acute angle or easily broken when bent. In addition, when such a thread is used to knit a glove or the like, it is interlaced with a stretchable braided wire such as polyurethane fiber or raw rubber to impart flexibility and fit.

在專利文獻1和3中提出了以包裹的方式包覆由金屬細線和添紗構成的芯線而形成的包線和使用該線編織成的手套。此外,專利文獻2中公開了一種縫線,其以金屬線和熔融線作為芯線,通過用繞線包覆該芯線後進行加熱,從而借助於熔融線而將金屬線和繞線熔接。Patent Documents 1 and 3 propose a covered wire formed by wrapping a core wire composed of a metal thin wire and a reinforcing yarn in a wrapping manner, and a glove knitted using the wire. Further, Patent Document 2 discloses a suture in which a metal wire and a molten wire are used as a core wire, and the core wire is covered with a wire and heated, whereby the metal wire and the wire are welded by means of a molten wire.

此外,專利文獻4提出了主要採用以玻璃纖維等硬質纖維作為芯線、以熱塑性合成纖維作為繞線的硬質複合線和以高強度合成纖維作為芯線、以熱塑性合成纖維作為繞線的高強度複合線交織而成的防切割手套。作為硬質纖維,示出了以下示例:以50但尼爾~300但尼爾的玻璃絲束作為芯線,在其周圍包覆聚酯多絲的預撚加工線作為繞線以形成硬質複合線。Further, Patent Document 4 proposes a high-strength composite wire mainly comprising a hard fiber such as glass fiber as a core wire, a hard composite wire using a thermoplastic synthetic fiber as a winding, and a high-strength synthetic fiber as a core wire and a thermoplastic synthetic fiber as a winding. Interwoven cut-resistant gloves. As the hard fiber, the following example is shown: a glass strand of 50 denier to 300 denier is used as a core wire, and a pre-twisted processing line of polyester multifilament is coated around it as a winding to form a hard composite wire.

現有技術文獻Prior art literature

專利文獻Patent literature

專利文獻1:國際公開第2007/15333號手冊Patent Document 1: International Publication No. 2007/15333

專利文獻2:日本特開2013-253337號公報Patent Document 2: Japanese Laid-Open Patent Publication No. 2013-253337

專利文獻3:日本特開2012-21258號公報Patent Document 3: Japanese Patent Laid-Open Publication No. 2012-21258

專利文獻4:日本特開2001-164411號公報Patent Document 4: Japanese Laid-Open Patent Publication No. 2001-164411

如在專利文獻1等中指出的,存在如下問題:以金屬纖維及玻璃纖維等無機纖維作為芯線而使用以聚乙烯纖維或尼龍纖維包覆而成的線編織成的手套,在彎曲時彎曲成銳角或折斷的硬質纖維的折斷端刺穿繞線而露出,在直接穿戴在肌膚上的手套等的情況下,無機纖維的折斷端接觸到肌膚而帶來不適感。特別是,在為了提高柔軟性和合身感而將伸縮性優異的聚氨酯纖維及生橡膠等彈性線與金屬纖維複合的情況下,硬質纖維的折斷端容易露出而給穿戴者帶來不適。As pointed out in Patent Document 1 and the like, there is a problem in that a glove woven by a wire made of polyethylene fiber or nylon fiber is used as a core wire of an inorganic fiber such as a metal fiber or a glass fiber, and is bent at the time of bending. The broken end of the acute fiber or the broken hard fiber is pierced and exposed, and in the case of a glove or the like directly worn on the skin, the broken end of the inorganic fiber comes into contact with the skin and causes discomfort. In particular, when an elastic yarn such as a polyurethane fiber or a raw rubber having excellent stretchability is combined with a metal fiber in order to improve the flexibility and the fit, the broken end of the hard fiber is easily exposed to cause discomfort to the wearer.

本發明的課題在於,提供柔軟性及經濟性優異、並且不會發生硬質纖維的折斷端露出而給穿戴者帶來不適感的、具備優異的穿戴感的耐切割性手套、耐切割性圍裙及其它耐切割性編織物和這些所使用的強韌線。An object of the present invention is to provide a cut-resistant glove and a cut-resistant apron which are excellent in flexibility and economy, and which are not exposed to the broken end of the rigid fiber and which give the wearer an uncomfortable feeling and have an excellent wearing feeling. Other cut-resistant braids and the tough lines used in these.

技術方案1是一種強韌線的芯線,該芯線是由硬質纖維和熔融纖維複合而成的線,其中,在硬質纖維上熔接了熔融纖維。The first aspect of the invention is a core wire of a strong yarn which is a composite of a hard fiber and a molten fiber, in which a molten fiber is welded to the hard fiber.

技術方案2為,在技術方案1所述的芯線中,所述熔接後的熔融纖維的截面積等於或大於硬質纖維的截面積。According to a second aspect of the invention, in the core wire of the first aspect, the cross-sectional area of the molten fiber after the fusion is equal to or larger than a cross-sectional area of the hard fiber.

技術方案3為,在技術方案1所述的芯線中,所述芯線是使硬質纖維和熔融纖維複合並熔接而成的線,所述芯線還含有下層纖維,所述下層纖維由配置在該硬質纖維與熔融纖維之間的天然纖維或合成纖維構成,所述熔融纖維熔接在所述硬質纖維及未熔融的下層纖維上。According to a third aspect of the invention, in the core wire of the first aspect, the core wire is a wire obtained by combining and welding a hard fiber and a molten fiber, the core wire further comprising a lower layer fiber, and the lower layer fiber is disposed on the hard wire The fiber is composed of natural fibers or synthetic fibers between the molten fibers, and the molten fibers are welded to the hard fibers and the unmelted underlayer fibers.

技術方案4為,在技術方案1或2所述的芯線中,所述熔融纖維是其截面中的中心部的熔融溫度高於周邊部的熔融溫度的纖維,通過加熱處理,使得僅其周邊部熔融而與所述硬質纖維熔接。In the core wire according to claim 1 or 2, the molten fiber is a fiber whose melting temperature at a central portion in a cross section is higher than a melting temperature of a peripheral portion, and is heat-treated so that only a peripheral portion thereof Melt and weld to the hard fibers.

技術方案5為,在技術方案3所述的芯線中,所述熔融纖維是其截面中的中心部的熔融溫度高於周邊部的熔融溫度的纖維,通過加熱處理,使得僅其周邊部熔融而與所述硬質纖維熔接。According to a fifth aspect of the invention, in the core wire of the third aspect, the molten fiber is a fiber whose melting temperature at a central portion in a cross section is higher than a melting temperature of a peripheral portion, and is heated to cause only a peripheral portion thereof to be melted. Welding with the hard fiber.

技術方案6是一種強韌線,所述強韌線由繞線捲繞於芯線而形成,其中,芯線是技術方案1所述的芯線,所述熔融纖維未與所述繞線熔接。The sixth aspect is a tough line formed by winding a wire wound around a core wire, wherein the core wire is the core wire of the first aspect, and the molten fiber is not welded to the wire.

技術方案7是一種強韌線,所述強韌線由繞線捲繞於芯線而形成,其中,芯線是技術方案3或5所述的芯線,所述熔融纖維還與未熔融的所述繞線熔接。The seventh aspect is a tough line formed by winding a wire wound around a core wire, wherein the core wire is the core wire according to claim 3 or 5, and the molten fiber is also wound with the unmelted wire. Wire welding.

技術方案8是一種編織物,所述編織物為技術方案6或7所述的強韌線與不含硬質纖維的其它線的編織物,其中,所述強韌線多顯現在該編織物的一個面上,所述其它線多顯現在該編織物的另一面上。The technical solution 8 is a woven fabric which is a woven fabric of the tough line and the other thread containing no hard fibers according to claim 6 or 7, wherein the tough line is mostly present in the woven fabric. On one face, the other lines appear more on the other side of the braid.

技術方案9為,在技術方案8所述的編織物中,所述其它線是彈性線。According to a ninth aspect, in the woven fabric of the eighth aspect, the other thread is an elastic thread.

技術方案10是一種手套,所述手套由技術方案6或7所述的強韌線與彈性線編織而成,其中,所述強韌線多顯現在該手套的外表面,所述彈性線多顯現在該手套的內表面。The technical solution 10 is a glove which is woven by the tough line and the elastic thread according to claim 6 or 7, wherein the tough line is mostly on the outer surface of the glove, and the elastic thread is more Appears on the inner surface of the glove.

本發明的技術方案1和2的發明的芯線20(20a、20b)是成為技術方案6的發明的強韌線30(30a)的芯的線,並且是通過加熱處理12將熔融纖維2熔融2b而將實施了複合處理(撚合或包覆)11的硬質纖維1和熔融纖維2與硬質纖維1熔接成一體而成的線。The core wire 20 (20a, 20b) of the inventions of the first and second aspects of the invention is a wire which becomes the core of the tough wire 30 (30a) of the invention of the sixth aspect, and the molten fiber 2 is melted by the heat treatment 12 2b On the other hand, the hard fiber 1 subjected to the composite treatment (twisting or coating) 11 and the line in which the molten fiber 2 and the hard fiber 1 are welded together are integrally formed.

技術方案3的發明的芯線20(20c~20e)是成為技術方案7的發明的強韌線30(30c~30e)的芯線的線,並且是對硬質纖維1和熔融纖維2以及配置在它們之間的第三纖維(天然纖維或合成纖維。下面和在技術方案書中稱為“下層纖維”)3進行複合處理(撚合或包覆)11後通過加熱處理12將熔融纖維2熔融2b以與硬質纖維1和未熔融的下層纖維3熔接成一體而成的線。The core wire 20 (20c to 20e) of the invention of claim 3 is a wire of the core wire of the tough line 30 (30c to 30e) of the invention of claim 7 and is disposed on the hard fiber 1 and the molten fiber 2 and The third fiber (natural fiber or synthetic fiber. Hereinafter referred to as "lower fiber" in the technical proposal) 3 is subjected to a composite treatment (kneading or coating) 11 and then the molten fiber 2 is melted by heat treatment 12 to 2b. A line formed by welding a rigid fiber 1 and an unmelted lower layer fiber 3 together.

本發明的芯線20借助於硬質纖維1與其表面熔接的熔融纖維2b而成為一部分或整周被包覆的狀態。在採用周邊部2b是低熔點且中心部2a是高熔點的熔融纖維作為熔融纖維2時,成為以熔融纖維2的高熔點部2a未熔融地捲繞在硬質纖維1上的狀態一體化的結構。The core wire 20 of the present invention is partially or completely covered by the molten fiber 2b to which the hard fiber 1 is welded to the surface. When the molten fiber having a low melting point in the peripheral portion 2b and a high melting point in the center portion 2a is used as the molten fiber 2, the high-melting-point portion 2a of the molten fiber 2 is integrated in a state of being unwoundly wound around the hard fiber 1 .

本發明的強韌線30(30a、30c~30e)、40(40c~40e)是將尼龍、聚酯、聚乙烯、芳綸纖維、多芳基化合物、蜘蛛絲纖維等繞線5捲繞於芯線20而形成的線,並且用於編織具備耐切割性的編織物。The tough lines 30 (30a, 30c to 30e) and 40 (40c to 40e) of the present invention are wound around a winding 5 of nylon, polyester, polyethylene, aramid fiber, polyarylate, spider silk or the like. A wire formed by the core wire 20 and used to knit a knitted fabric having cut resistance.

優選的是,包覆處理13在複合線10(10a、10c~10f)的加熱處理12後進行,但在芯線含有下層纖維3、並且採用具備耐熱性的線5a作為繞線時,也可以在加熱處理12之前進行包覆處理13而形成強韌線40。在強韌線30的情況下,繞線5和芯線20未熔融。另一方面,在強韌線40的情況下,由於在包覆處理13後進行加熱處理12,因此,借助於熔融2b的熔融纖維2使繞線5和芯線20熔接。Preferably, the coating treatment 13 is performed after the heat treatment 12 of the composite wire 10 (10a, 10c to 10f), but when the core wire contains the lower fiber 3 and the heat-resistant wire 5a is used as the winding, The coating treatment 13 is performed before the heat treatment 12 to form the tough line 40. In the case of the tough line 30, the winding 5 and the core 20 are not melted. On the other hand, in the case of the tough line 40, since the heat treatment 12 is performed after the coating treatment 13, the winding 5 and the core wire 20 are welded by melting the molten fibers 2b.

硬質纖維1是不銹鋼纖維、碳纖維、玻璃纖維、多芳基化合物纖維,也可以根據用途而將多種硬質纖維複合後使用。在耐切割性這點上不銹鋼纖維優異,在經濟性這點上玻璃纖維優異。作為不銹鋼纖維,優選的是線徑10μm~150μm的單線或將2根~5根複合而成,作為玻璃纖維,優選的是10但尼爾~600但尼爾的多絲或紡織紗。The hard fiber 1 is a stainless steel fiber, a carbon fiber, a glass fiber, or a polyarylate fiber, and a plurality of hard fibers may be used in combination depending on the application. The stainless steel fiber is excellent in the cut resistance, and the glass fiber is excellent in economical efficiency. As the stainless steel fiber, a single wire having a wire diameter of 10 μm to 150 μm or a composite of two to five is preferable, and as the glass fiber, a multifilament or a woven yarn of 10 denier to 600 denier is preferable.

熔融纖維2可以採用低熔點聚酯纖維、低熔點聚醯胺纖維、低熔點聚乙烯纖維等,但優選的是低熔點聚酯纖維,特別優選的是中心部是高熔點且周邊部是低熔點的熔融纖維。採用了這樣的熔融纖維的芯線20成為如下結構:熔融纖維2的周邊部的低熔點部分熔融2b而與硬質纖維1和下層纖維3的表面熔接,高熔點的中心部2a未熔融而與硬質纖維1和下層纖維3撚合或包覆於硬質纖維1和下層纖維3(圖2、圖3、圖7、圖12、圖16)。The molten fiber 2 may be a low melting point polyester fiber, a low melting point polyamide fiber, a low melting point polyethylene fiber or the like, but is preferably a low melting point polyester fiber, and it is particularly preferred that the center portion has a high melting point and the peripheral portion has a low melting point. Molten fiber. The core wire 20 using such a molten fiber has a structure in which the low melting point portion of the peripheral portion of the molten fiber 2 is melted 2b and welded to the surfaces of the hard fiber 1 and the lower layer fiber 3, and the high melting point center portion 2a is not melted and hard fibers are used. 1 and the lower layer fiber 3 are twisted or coated on the hard fiber 1 and the lower layer fiber 3 (Fig. 2, Fig. 3, Fig. 7, Fig. 12, Fig. 16).

在使用金屬纖維作為硬質纖維的情況下,優選的是,熔融纖維2使用熔融而與硬質纖維一體化時的熔融纖維的截面積等於或大於硬質纖維的截面積的纖維。複合(撚合或包覆)後的熔融纖維2與硬質纖維1的撚數是每米40次~2000次,優選的是150次~1000次。When a metal fiber is used as the hard fiber, it is preferable that the molten fiber 2 is a fiber in which the cross-sectional area of the molten fiber when it is integrated with the hard fiber is equal to or larger than the cross-sectional area of the hard fiber. The number of turns of the molten fiber 2 and the hard fiber 1 after the compounding (kneading or coating) is 40 to 2,000 times per metre, preferably 150 times to 1,000 times.

在使用單絲作為硬質纖維1時,有時熔融後的熔融纖維2在長度方向上滑動而使針對硬質纖維1的折斷的保護不夠。在該情況下,形成芯線20b(圖3)是有效的,在所述芯線20b中,熔融纖維2是兩根,在複合處理11中將兩根熔融纖維2m、2n彼此向相反方向捲繞在硬質纖維1上。When a monofilament is used as the hard fiber 1, the molten fiber 2 after melting may slide in the longitudinal direction, and the protection against breakage of the hard fiber 1 may be insufficient. In this case, it is effective to form the core wire 20b (Fig. 3) in which two of the molten fibers 2 are wound, and in the composite processing 11, the two molten fibers 2m, 2n are wound in opposite directions to each other. Hard fiber 1 on it.

作為下層纖維3,也可以採用聚酯紡織紗或聚酯與棉等的混紡線,但優選的是羊毛酯、酯、尼龍、毛尼龍等。硬質纖維1、下層纖維3和熔融纖維2是纖維、單絲或多絲。As the lower layer fiber 3, a polyester spun yarn or a blended yarn of polyester and cotton may be used, but a lanolin ester, an ester, a nylon, a wool nylon or the like is preferable. The hard fibers 1, the lower fibers 3, and the molten fibers 2 are fibers, monofilaments or multifilaments.

本發明的編織物是本發明的強韌線30、40與不含硬質纖維的其它線的編織物,並且是如下的編織物:通過進行添紗編織、雙面織、雙層織等編織,強韌線30、40多顯現在所得到的編織物的一個面上,其它線8、9多顯現在該編織物的另一面上。為了賦予編織物柔軟性,優選的是,使用聚氨酯纖維或生橡膠等伸縮性大的線作為其它線8、9。The woven fabric of the present invention is a woven fabric of the tough line 30, 40 of the present invention and other threads which do not contain hard fibers, and is a woven fabric which is woven by weaving, double woven, double woven, etc. More of the tough lines 30, 40 appear on one side of the resulting braid, and the other lines 8, 9 appear on the other side of the braid. In order to impart flexibility to the woven fabric, it is preferable to use a thread having a large stretchability such as polyurethane fiber or raw rubber as the other threads 8 and 9.

對本發明的手套的編織組織做了多種考慮,認為特別優選的組織是如下的手套:添紗編織成:以強韌線30、40作為地紗,以彈性線8作為添織紗,地紗顯現在外表面,添織紗顯現在內表面。A variety of considerations have been made for the woven structure of the glove of the present invention, and it is considered that the particularly preferred structure is a glove in which the weaving is woven into a strong yarn 30, 40 as a ground yarn, and an elastic yarn 8 as an woven yarn, and the ground yarn is exposed. On the surface, the woven yarn appears on the inner surface.

發明效果Effect of the invention

本發明的芯線20是線彎曲時彎曲形變最大的部分、即內部應力最大的線的外周部分成為彈性大的下層纖維或熔融樹脂部分,由於與硬質纖維一體化的該熔融樹脂和下層纖維的內部應力,施加於硬質纖維的應力得以減輕,此外,即使在硬質纖維斷裂時,下層纖維及熔融樹脂也不斷裂。因此,使用本發明的強韌線編織而成的編織物的硬質纖維1的折斷端不易露出於編織物的表面,不會給穿戴者帶來刺紮那樣的不適感。The core wire 20 of the present invention is a portion where the bending deformation is the greatest when the wire is bent, that is, the outer peripheral portion of the wire having the largest internal stress becomes a lower elastic fiber or a molten resin portion, and the inside of the molten resin and the lower fiber integrated with the hard fiber The stress applied to the hard fibers is relieved, and the lower fibers and the molten resin are not broken even when the hard fibers are broken. Therefore, the broken end of the rigid fiber 1 of the knitted fabric knitted by the tough line of the present invention is less likely to be exposed on the surface of the knitted fabric, and does not give the wearer an uncomfortable feeling such as puncturing.

根據借助於熔融2b的熔融纖維2使硬質纖維1和下層纖維3一體化而成的芯線20c~20e,由於硬質纖維1被下層纖維3和熔融樹脂2b包覆,因此,發揮下層纖維3對硬質纖維1的斷裂及折斷的保護作用,因而,能夠得到比僅以熔融樹脂2包覆的芯線20a、20b更具備優異的柔軟性及合身感的強韌線。The core fibers 20c to 20e formed by integrating the hard fibers 1 and the lower fibers 3 by the molten fibers 2 of the molten 2b, the hard fibers 1 are coated with the lower fibers 3 and the molten resin 2b, so that the lower fibers 3 are hard. Since the fiber 1 is protected from breakage and breakage, it is possible to obtain a tough line having excellent flexibility and fit even more than the core wires 20a and 20b covered only with the molten resin 2.

此外,由於形成本發明的強韌線和與其它相比具備柔軟性的、添加例如聚氨酯纖維或生橡膠等的彈性線編織的添紗編織、雙面織、雙層織等的編織物,因此能夠形成肌膚觸感良好且柔軟性優異的編織物。特別是,添加彈性絲編織的手套具備優異的柔軟性和肌膚觸感。Further, since the tough line of the present invention is formed, and the woven fabric of the woven fabric, the double woven fabric, the double woven fabric, or the like which is softened by adding elastic yarns such as polyurethane fibers or raw rubber, etc., is formed. It is possible to form a knitted fabric which is excellent in skin feel and excellent in softness. In particular, the elastic yarn-woven gloves have excellent softness and skin feel.

因此,通過使用本發明的強韌線30、40和其它線來提供各種編織物、作業用手套、綁腿、作業用圍裙等,從而能夠提供柔軟性及經濟性優異、並且不會發生硬質纖維的折斷端露出而給穿戴者帶來不適感的具備耐切割性的手套及其它編織物。Therefore, by using the tough lines 30, 40 and other threads of the present invention, various woven fabrics, work gloves, leggings, work aprons, and the like are provided, thereby providing excellent flexibility and economy, and hard fibers are not generated. Gloves and other braids with cut-off resistance that are exposed to the wearer and give the wearer an uncomfortable feeling.

下麵,參照附圖對本發明的實施例進行說明。在圖中,1是硬質纖維,2是熔融纖維,3是配置在硬質纖維1與熔融纖維2之間的下層纖維,10a是將硬質纖維1和熔融纖維2複合(撚合或包覆)而成的複合線,10c~10f是將硬質纖維1與下層纖維3與熔融纖維2複合而成的複合線,20a、20b是將通過加熱處理12而熔融2b的熔融纖維2與硬質纖維1熔接而成為一體的芯線,20c~20e是將熔融2b的熔融纖維2與硬質纖維1和不熔融的下層纖維3熔接而成為一體的芯線,30a是將繞線5捲繞於芯線20a、20b而得到的強韌線,30c~30e是將繞線5捲繞於芯線20c~20e而得到的強韌線,40是繞線5a借助於熔融2b的熔融纖維2與芯線20c~20e熔接的強韌線。Embodiments of the present invention will now be described with reference to the accompanying drawings. In the figure, 1 is a hard fiber, 2 is a molten fiber, 3 is a lower fiber disposed between the hard fiber 1 and the molten fiber 2, and 10a is a composite (twisted or coated) of the hard fiber 1 and the molten fiber 2. The composite yarns 10c to 10f are composite wires in which the hard fibers 1 and the lower fibers 3 and the molten fibers 2 are combined, and 20a and 20b are obtained by welding the molten fibers 2 and the hard fibers 1 which are melted 2b by the heat treatment 12. 20c to 20e are core wires in which the molten 2b of the molten 2b and the hard fiber 1 and the lower layer 3 which is not melted are welded together, and 30a is obtained by winding the winding 5 around the core wires 20a and 20b. The tough line, 30c to 30e, is a tough line obtained by winding the winding 5 around the core wires 20c to 20e, and 40 is a tough line in which the winding 5a is welded to the core wires 20c to 20e by the molten fiber 2 of the molten 2b.

圖1~圖4是示出不具備下層纖維的第一和第二實施例的圖。圖5~圖20是示出含有下層纖維3的第三至第九實施例的圖,圖5~圖9是示出硬質纖維1和下層纖維3均為1根的第三實施例和第四實施例的圖。圖10~圖13是示出硬質纖維為2根1m、1n的第五實施例的圖。圖14~圖17是示出下層纖維3是2根3m、3n的第六實施例的圖。圖18~圖20是示出與第三至第六實施例中的加熱處理12和包覆處理13的工序順序相反的第七至第九實施例的圖。1 to 4 are views showing first and second embodiments in which the lower layer fibers are not provided. 5 to 20 are views showing third to ninth embodiments including the lower layer fibers 3, and Figs. 5 to 9 are third and fourth examples showing that both the hard fibers 1 and the lower layer fibers 3 are one. A diagram of an embodiment. Fig. 10 to Fig. 13 are views showing a fifth embodiment in which the hard fibers are two 1 m and 1 n. 14 to 17 are views showing a sixth embodiment in which the lower layer fibers 3 are two 3 m and 3 n. 18 to 20 are views showing seventh to ninth embodiments which are opposite to the order of the heat treatment 12 and the coating process 13 in the third to sixth embodiments.

圖1是示出第一實施例和第二實施例的發明的強韌線30a的製造工序的框圖。在第一工序的複合處理11中,將硬質纖維1和熔融纖維2複合,在第二工序中對得到的複合線10進行加熱處理12而將熔融纖維2的至少周邊部分熔融2b以使其附著在被複合了的硬質纖維1的表面。在該加熱處理12中得到的線是芯線20a。Fig. 1 is a block diagram showing a manufacturing process of the tough line 30a of the invention of the first embodiment and the second embodiment. In the composite treatment 11 of the first step, the hard fiber 1 and the molten fiber 2 are combined, and in the second step, the obtained composite wire 10 is subjected to a heat treatment 12 to melt at least a peripheral portion of the molten fiber 2 to adhere thereto. On the surface of the hard fiber 1 to be composited. The line obtained in this heat treatment 12 is the core wire 20a.

圖1的第二工序的加熱處理12是將與硬質纖維1複合了的熔融纖維2的至少周邊部熔融而與硬質纖維1的表面熔接以使二者一體化的處理。因此,加熱溫度和加熱時間是熔融纖維2的至少周邊部分熔融2b而熔解的樹脂與硬質纖維1的表面熔接的溫度和時間。在使用中心部2a是高熔點、周邊部是低熔點的熔融纖維作為熔融纖維2時,加熱處理12的加熱溫度是低熔點部分的樹脂熔融、高熔點部2a的樹脂不熔融的溫度。The heat treatment 12 in the second step of FIG. 1 is a process in which at least the peripheral portion of the molten fiber 2 combined with the hard fiber 1 is melted and welded to the surface of the hard fiber 1 to integrate the two. Therefore, the heating temperature and the heating time are temperatures and times at which the resin melted at least the peripheral portion of the molten fiber 2 is melted and the surface of the hard fiber 1 is welded. When the center portion 2a is a molten fiber having a high melting point and a low melting point in the peripheral portion, the heating temperature of the heat treatment 12 is a temperature at which the resin in the low melting point portion is melted and the resin in the high melting point portion 2a is not melted.

圖2和圖3是示意性地示出通過加熱處理得到的第一實施例的芯線20a和第二實施例的芯線20b的截面的放大圖,圖2是將一根熔融纖維2捲繞於多絲的玻璃纖維1而形成的芯線的示例,圖3是將細的熔融纖維和粗的熔融纖維彼此沿相反方向捲繞於單絲的不銹鋼纖維而形成的芯線的示例。2 and 3 are enlarged views schematically showing a cross section of the core wire 20a of the first embodiment and the core wire 20b of the second embodiment obtained by heat treatment, and Fig. 2 is a view in which a molten fiber 2 is wound up. An example of a core wire formed by the glass fiber 1 of the wire, and FIG. 3 is an example of a core wire formed by winding a thin molten fiber and a coarse molten fiber in opposite directions to the stainless steel fiber of the monofilament.

在第三工序的包覆處理13中,繞線5被捲繞於在第二工序中得到的芯線20a、20b。圖4是示出包覆處理13中的包覆中途的狀態的放大側視圖,示出了作為強韌線的繞線5被捲繞於作為芯線的芯線20a的狀態。圖4是單股包覆,當然也可以是雙股包覆。通過該第三工序能夠得到強韌線30a。In the coating treatment 13 of the third step, the winding 5 is wound around the core wires 20a and 20b obtained in the second step. 4 is an enlarged side view showing a state in the middle of the coating in the coating process 13, and shows a state in which the winding 5 as a tough wire is wound around the core wire 20a as a core wire. Figure 4 is a single-strand coating, which of course may also be a double-strand coating. The tough line 30a can be obtained by this third process.

圖5、圖10和圖14是示出強韌線30c~30e的製造工序的框圖。在第一工序的複合處理11中,將硬質纖維1、下層纖維3和熔融纖維2彼此複合,在第二工序中對得到的複合線10c~10e進行加熱處理12以使熔融纖維2的至少周邊部分熔融2b而附著於被複合了的硬質纖維1和下層纖維3。通過該加熱處理12得到的線是芯線20c~20e。另外,複合處理11也可以在一個工序中進行,但通常在多個撚合或包覆工序中進行。5, 10, and 14 are block diagrams showing manufacturing steps of the tough lines 30c to 30e. In the composite treatment 11 of the first step, the hard fibers 1, the lower fibers 3, and the molten fibers 2 are combined with each other, and in the second step, the obtained composite wires 10c to 10e are heat-treated 12 so that at least the periphery of the molten fibers 2 Part 2 is melted 2b and adhered to the composite hard fiber 1 and the lower layer fiber 3. The wires obtained by this heat treatment 12 are the core wires 20c to 20e. Further, the composite treatment 11 may be carried out in one step, but it is usually carried out in a plurality of twisting or coating steps.

如圖6、圖11和圖15所示,下層纖維3作為添紗被捲繞於硬質纖維1。下層纖維3被捲繞成不完全覆蓋硬質纖維1的表面而使硬質纖維1在相鄰的下層纖維之間露出。優選的下層纖維3的匝數是40次/米~1000次/米,優選的是100次/米~350次/米,但在下層纖維3是兩根的第六實施例中,通常,如圖15所示,兩根下層纖維3m、3n通過雙股包覆加工被複合,該情況下的硬質纖維1側的下層纖維3m優選的是3次/米~50次/米。As shown in FIGS. 6, 11, and 15, the lower layer fiber 3 is wound around the hard fiber 1 as a reinforcing yarn. The lower layer fiber 3 is wound so as not to completely cover the surface of the hard fiber 1 to expose the hard fiber 1 between adjacent lower layer fibers. Preferably, the number of turns of the lower layer fiber 3 is 40 times/m to 1000 times/m, preferably 100 times/m to 350 times/m, but in the sixth embodiment in which the lower layer fibers 3 are two, usually, As shown in Fig. 15, the two lower layers of fibers 3m and 3n are composited by a double-strand coating process, and in this case, the lower layer fibers 3m on the side of the hard fibers 1 are preferably 3 times/m to 50 times/m.

通常,熔融纖維2通過雙股包覆加工被覆合成與被捲繞於硬質纖維1的下層纖維(添紗)交叉。即,如圖6、圖11和圖15所示,將下層纖維3作為添紗捲繞於硬質纖維1,並與下層纖維3的捲繞方向相反地捲繞有作為上繞線的熔融纖維2。Usually, the molten fiber 2 is covered by a double-strand coating process and intersects with the lower layer fiber (stacking) wound around the hard fiber 1. In other words, as shown in FIG. 6, FIG. 11, and FIG. 15, the lower layer fiber 3 is wound as a reinforcing yarn on the hard fiber 1, and the molten fiber 2 as the upper winding is wound in the opposite direction to the winding direction of the lower layer fiber 3. .

圖6至圖8中的複合處理是將下層纖維3捲繞於硬質纖維1的處理,但也可以是將硬質纖維1捲繞於下層纖維3的處理。圖9是示出那樣處理下的複合線10f的圖。在複合處理中,以羊毛酯、酯、尼龍、毛尼龍作為下層纖維3而將硬質纖維1捲繞於該下層纖維,在其上捲繞熔融纖維2而進行了加熱處理的芯線和在該芯線上捲繞繞線而成的強韌線具備伸縮性,因此適合於要求更高柔軟性的編織物。The composite treatment in FIGS. 6 to 8 is a process of winding the lower layer fiber 3 around the hard fiber 1, but may be a process of winding the hard fiber 1 around the lower layer fiber 3. Fig. 9 is a view showing the composite wire 10f as processed. In the composite treatment, a core fiber in which the hard fiber 1 is wound around the lower layer fiber by using the lanolin ester, the ester, the nylon, the wool nylon as the lower layer fiber 3, and the molten fiber 2 is wound thereon, and the core is heated. The tough line formed by winding the wire on the wire is stretchable, so it is suitable for a knitted fabric that requires higher flexibility.

第二工序的加熱處理12是將通過第一工序的複合處理11得到的複合線10中的熔融纖維2的至少周邊部熔融並與硬質纖維1和下層的下層纖維3熔接以將三者一體化的處理。因此,加熱溫度和加熱時間是熔融纖維2的至少周邊部分熔融2b而熔解的樹脂與硬質纖維1和下層纖維3的表面熔接的溫度和時間。In the heat treatment 12 of the second step, at least the peripheral portion of the molten fiber 2 in the composite wire 10 obtained by the composite processing 11 in the first step is melted and welded to the hard fiber 1 and the lower layer fiber 3 of the lower layer to integrate the three. Processing. Therefore, the heating temperature and the heating time are temperatures and times at which the resin melted at least the peripheral portion of the molten fiber 2 is melted and the surfaces of the hard fibers 1 and the lower fibers 3 are welded.

圖7、圖12和圖16是示意性地示出通過加熱處理12得到的各個實施例的芯線20c~20e的截面的放大圖。如圖所示,在硬質纖維1的表面上熔融的樹脂2b以從熔融纖維的未熔解的中心部2a擴展的狀態與硬質纖維1和下層的下層纖維3的表面熔接,作為熔融纖維的中心部的高熔點部2a未熔融而以捲繞於硬質纖維1和下層纖維3的狀態留在熔融的樹脂2b內。7, 12, and 16 are enlarged views schematically showing a cross section of the core wires 20c to 20e of the respective embodiments obtained by the heat treatment 12. As shown in the figure, the resin 2b melted on the surface of the hard fiber 1 is welded to the surface of the hard fiber 1 and the lower layer fiber 3 in a state of being expanded from the unmelted center portion 2a of the molten fiber, and serves as a center portion of the molten fiber. The high melting point portion 2a is not melted and remains in the molten resin 2b in a state of being wound around the hard fiber 1 and the lower layer fiber 3.

如上所述,下層纖維3未將硬質纖維1的表面完全地覆蓋,硬質纖維1露出於所捲繞的下層纖維3之間。熔融的熔融纖維2在該露出的區域與硬質纖維1的表面熔接。另一方面,由於熔融纖維2與下層纖維3以交叉的方式複合,因此,在該交叉的部分與下層纖維3熔接。As described above, the lower layer fiber 3 does not completely cover the surface of the hard fiber 1, and the hard fiber 1 is exposed between the wound lower layer fibers 3. The molten molten fiber 2 is welded to the surface of the hard fiber 1 in the exposed region. On the other hand, since the molten fiber 2 and the lower layer fiber 3 are combined in an intersecting manner, the lower layer fiber 3 is welded at the intersecting portion.

在第三工序的包覆處理13中,繞線5被捲繞於在第二工序中得到的芯線20c~20e。In the coating treatment 13 of the third step, the winding 5 is wound around the core wires 20c to 20e obtained in the second step.

圖8、圖13和圖17是示出包覆處理13的包覆中途的狀態的放大側視圖,示出了繞線5被捲繞於芯線20c~20e的狀態。這些圖示出了單股包覆,當然也可以是雙股包覆。通過該包覆處理,能夠得到強韌線30c~30e。FIGS. 8 , 13 , and 17 are enlarged side views showing a state in the middle of the coating of the coating process 13 , and show a state in which the winding 5 is wound around the core wires 20 c to 20 e. These figures show a single-strand coating, which of course can also be a double-strand coating. The tough lines 30c to 30e can be obtained by this coating treatment.

在繞線5使用具備耐熱性的線、即在使熔融纖維2熔融而與硬質纖維1和下層纖維3熔接的加熱處理12中不會熔融的繞線5a的情況下,如圖18至圖20所示,可在加熱處理12之前進行包覆處理13。In the case where the wire 5 having heat resistance, that is, the wire 5a which does not melt in the heat treatment 12 in which the molten fiber 2 is melted and welded to the hard fiber 1 and the lower layer fiber 3 is used as the winding 5, as shown in FIGS. 18 to 20 As shown, the coating treatment 13 can be performed prior to the heat treatment 12.

圖18至圖20的第七至第九實施例的複合處理11、加熱處理12和包覆處理13分別與第三至第六實施例的複合處理11、加熱處理12和包覆處理13相同。僅如下方面與第三至第六實施例的強韌線30c~30e不同:得到的強韌線40的繞線被限定於具備耐熱性的線5a,並且,在加熱處理12中熔融的熔融纖維2還與繞線5a熔接。The composite processing 11, the heat treatment 12, and the coating treatment 13 of the seventh to ninth embodiments of Figs. 18 to 20 are the same as the composite processing 11, the heat treatment 12, and the coating treatment 13 of the third to sixth embodiments, respectively. Only the following aspects are different from the tough lines 30c to 30e of the third to sixth embodiments: the obtained winding of the tough line 40 is limited to the heat-resistant wire 5a, and the molten fiber melted in the heat treatment 12 2 is also welded to the winding 5a.

在發明人使用玻璃纖維作為硬質纖維1、使用羊毛酯作為下層纖維3、使用毛尼龍、羊毛酯、芳綸纖維作為繞線進行的試驗中,若硬質纖維、下層纖維、熔融纖維和繞線的種類及匝數等相同,則作為強韌線的功能或效果與第三至第六實施例的強韌線大致相同。In the experiments in which the inventors used glass fiber as the hard fiber 1, lanolin as the lower fiber 3, and wool, lanolin, and aramid fiber as the winding, if the hard fiber, the lower fiber, the molten fiber, and the wound wire When the type and the number of turns are the same, the function or effect as the tough line is substantially the same as that of the third to sixth embodiments.

所得到的強韌線30、40還能夠單獨進行編織或與含有其它硬質纖維的線一同進行編織,但通常與不含硬質纖維的其它線交編或交織。例如,在編織手套時,可以使用本發明的強韌線30、40作為地紗、使用含有聚氨酯纖維及生橡膠等高彈性線的線、蓬鬆加工線、天然纖維的線等伸縮性、吸濕性和肌膚觸感優異的線作為添織紗8來進行添紗編織(圖21),使得地紗30、40顯現在手套的表面、添織紗8顯現在內面。The resulting tenacity lines 30, 40 can also be woven separately or woven together with threads containing other hard fibers, but are typically interwoven or interwoven with other threads that do not contain hard fibers. For example, in the case of knitting a glove, the tough line 30, 40 of the present invention can be used as a ground yarn, a line containing a high elastic yarn such as a polyurethane fiber or a raw rubber, a fluffy processing line, a line of a natural fiber, etc., and moisture absorption can be used. A thread excellent in texture and skin feel is applied as a woven yarn 8 (Fig. 21) so that the ground yarns 30 and 40 appear on the surface of the glove, and the woven yarn 8 appears on the inner surface.

添紗編織作為表背面不同的用線的編織方法而廣泛被採用,但雙層織及雙面織等也為人所知,通過使用這些技術,能夠得到如下的編織物:外表面或表面具備耐切割性及強韌性,內面或背面具備柔軟性、吸濕性、肌膚觸感等與各個編織物的用途相應的性質。Weaving is widely used as a weaving method for different threads on the back side of the watch, but double weaving and double weaving are also known. By using these techniques, we can obtain a knitted fabric having an outer surface or a surface. Cut resistance and toughness, and the inner surface or the back surface has properties corresponding to the use of each knitted fabric, such as softness, moisture absorption, and skin feel.

例如,如圖22所示,是使用本發明的強韌線30、40織成外側的層21、使用由肌膚觸感優異的纖維構成的其它線9織成內側的層22、並在外側的層21上斷續地張繞其它線9而連接成的雙層結構的質地等。雙面織也是與雙層織同樣的雙層的針織物。 [表1] For example, as shown in Fig. 22, the layer 21 which is woven outside using the tough lines 30 and 40 of the present invention, the layer 22 which is woven by the other thread 9 which is composed of fibers having excellent skin feel, and the outer layer are provided on the outer side. The texture of the two-layer structure in which the layers 21 are intermittently wound around the other lines 9 and the like. The double-faced weave is also a double-layered knitted fabric similar to the double-layer weave. [Table 1]

表1是示出本申請的發明人試製的第一和第二實施例的強韌線的示例的表。在該表中,產品編號1~4的玻璃紗是裸線數為100根的玻璃纖維的多絲,產品編號5、6的玻璃紗是裸線數為200根的玻璃纖維的多絲,不銹鋼細線是單絲。Table 1 is a table showing an example of the tough lines of the first and second embodiments prototyped by the inventors of the present application. In the table, the glass yarns of product numbers 1 to 4 are multifilaments of glass fibers having a bare wire number of 100, and the glass yarns of product numbers 5 and 6 are multifilaments of glass fibers having a bare wire number of 200, and stainless steel. The thin line is a monofilament.

熔融纖維是由多根中心部為高熔點、周邊部為低熔點的纖維構成的線,產品編號1和7是紡織線,產品編號2~6和8~11是多絲。由多根紡織線和多絲構成的熔融纖維是通過圖1中的加熱處理12成為由多根未熔融而留下的纖維2a和一體地包含這些纖維的熔融後的樹脂2b構成的單絲狀,熔融的低熔點部分與玻璃絲和不銹鋼細線的表面熔接。The molten fiber is a line composed of a plurality of fibers having a high melting point at the center portion and a low melting point at the peripheral portion, and product numbers 1 and 7 are textile threads, and product numbers 2 to 6 and 8 to 11 are multifilaments. The molten fiber composed of a plurality of woven yarns and multifilaments is a monofilament composed of a plurality of unmelted fibers 2a and a molten resin 2b integrally containing these fibers by the heat treatment 12 in Fig. 1 . The molten low melting point portion is welded to the surface of the glass filament and the stainless steel thin wire.

繞線是多絲。玻璃絲、熔融纖維和繞線的各欄的( )內的數值是表示以各個纖維的整個截面積作為一根纖維時的線徑的數值。The winding is multifilament. The numerical value in ( ) of each of the glass filaments, the molten fibers, and the windings is a numerical value indicating the diameter of the wire when the entire cross-sectional area of each fiber is one fiber.

根據發明人進行的試驗,作為通過添紗編織來編成耐切割手套所使用的地紗,表1中示有繞線的種類的產品編號3、6和9、10的強韌線被認為特別優異。According to the test conducted by the inventors, the tough yarns of the product numbers 3, 6, and 9, 10, which are shown in Table 1 as the type of winding, are particularly excellent as the ground yarn used for knitting the cut resistant gloves by the weaving knitting. .

使用不銹鋼的單線(單絲)作為硬質纖維1而形成的芯線有時在不銹鋼與熔融後的樹脂之間發生線在長度方向上滑動而無法充分地實現硬質纖維1的包覆。如圖3所示,通過使用2m和2n這兩根作為熔融纖維2而進行複合化,從而能夠解決此問題。 [表2] A core wire formed by using a stainless steel single wire (monofilament) as the hard fiber 1 may cause a wire to slide in the longitudinal direction between the stainless steel and the molten resin, and the hard fiber 1 may not be sufficiently covered. As shown in FIG. 3, this problem can be solved by combining two of 2m and 2n as the molten fiber 2. [Table 2]

表2是示出發明人針對圖3所示的芯線20b進行的試驗的內容的表。即,進行了如下的試驗:將熔融纖維2m捲繞於硬質纖維1後,將熔融纖維2n捲繞成與成為下層的熔融纖維2m交叉而進行複合化,然後進行加熱處理12而將兩個熔融纖維2m、2n熔融。這些試驗的結果是,確認了使用單絲的不銹鋼纖維時的上述問題得以解決。Table 2 is a table showing the contents of the test conducted by the inventors with respect to the core wire 20b shown in Fig. 3. In other words, after the molten fiber 2m is wound around the hard fiber 1, the molten fiber 2n is wound to cross the molten fiber 2m which is the lower layer to be composited, and then the heat treatment 12 is performed to melt the two. The fibers 2m and 2n are melted. As a result of these tests, it was confirmed that the above problems when the monofilament stainless steel fiber was used were solved.

另外,關於表2中的硬質纖維2m、2n和繞線,對撚數不同的多個試製線總地進行了記載,在各欄中以多行記載的纖維及線的種類表示針對它們各自、並且針對以“,”劃分開的多個粗細的情況進行了試製。In addition, regarding the hard fibers 2m and 2n and the windings in Table 2, a plurality of trial lines having different numbers of turns are collectively described, and the types of fibers and lines described in a plurality of rows in each column are indicated for each of them. In addition, trial production was carried out for a case where a plurality of thicknesses were divided by ",".

在這些表中,GY是玻璃纖維的多絲,sus是不銹鋼單絲、熔融纖維是熔融聚酯的多絲,WE是羊毛酯,WN是毛尼龍,PET是聚酯,An丙烯酸,D是但尼爾,μ是線徑微米,T/m是每米的撚數。 [表3] [表4] [表5] In these tables, GY is a multifilament of glass fiber, sus is a stainless steel monofilament, molten fiber is a multifilament of molten polyester, WE is lanolin, WN is wool nylon, PET is polyester, An acrylic, D is but Neil, μ is the wire diameter micron, and T/m is the number of turns per meter. [table 3] [Table 4] [table 5]

表3、表4和表5是分別示出本申請的發明人試製的第三、第四和第六實施例的強韌線的示例的表。關於表3中的硬質纖維、下層纖維、熔融纖維和繞線,對撚數不同的多個試製線總地進行了記載,在各欄中以多行記載的纖維及線的種類表示針對它們各自、並且針對以“,”劃分開的多個情況進行了試製。Tables 3, 4, and 5 are tables each showing an example of the tough lines of the third, fourth, and sixth embodiments prototyped by the inventors of the present application. Regarding the hard fibers, the lower fibers, the molten fibers, and the windings in Table 3, a plurality of trial lines having different numbers of turns are collectively described, and the types of fibers and lines described in a plurality of rows are indicated for each of them. And trial production was carried out for a number of cases divided by ",".

熔融纖維通過加熱處理12至少各纖維的周緣部熔融而與硬質纖維和下層的羊毛酯纖維的表面熔接,並且多根纖維熔融後凝固而成為由熔融後的樹脂2b構成的單絲狀(參照圖7、圖12和圖16)。At least the peripheral portion of each of the fibers is melted by the heat treatment 12, and is welded to the surface of the hard fibers and the lower layer of the lanolin fibers, and the plurality of fibers are melted and solidified to form a monofilament composed of the resin 2b after melting (see the figure). 7, Figure 12 and Figure 16).

在表3中,針對使用玻璃纖維的多絲作為硬質纖維1的情況和使用不銹鋼的單絲的情況進行了試驗。在任一情況下均能夠通過在硬質纖維1與熔融纖維2之間配置下層纖維3來賦予所得到的強韌線及編織物優異的柔軟性和更良好的穿戴感。In Table 3, tests were carried out for the case where a multifilament of glass fiber was used as the hard fiber 1 and a case where a monofilament of stainless steel was used. In either case, the lower layer fibers 3 can be disposed between the hard fibers 1 and the molten fibers 2 to impart excellent flexibility and a better wearing feel to the obtained tough line and knitted fabric.

但是,使用1根不銹鋼單絲作為硬質纖維的芯線有時硬質纖維與熔融纖維的熔接力弱、無法充分地包覆硬質纖維1,使用該芯線的編織物的柔軟性也不夠。However, when one stainless steel monofilament is used as the core of the hard fiber, the welding power of the hard fiber and the molten fiber is weak, and the hard fiber 1 cannot be sufficiently coated, and the flexibility of the knitted fabric using the core wire is also insufficient.

與此相對,根據如表4和表11所示硬質纖維1為玻璃纖維1m和不銹鋼纖維1n的撚線的第五實施例、以及如表5和表15所示下層纖維3為捲繞方向為相反方向的兩根下層纖維3m、3n的第六實施例,能夠提高含有耐切割性優異的不銹鋼單絲的芯線或強韌線的柔軟性。On the other hand, according to the fifth embodiment in which the hard fiber 1 is a twisted yarn of the glass fiber 1m and the stainless steel fiber 1n as shown in Tables 4 and 11, and the lower layer fiber 3 shown in Tables 5 and 15 is in the winding direction. In the sixth embodiment of the two lower fibers 3m and 3n in the opposite direction, the flexibility of the core wire or the tough wire containing the stainless steel monofilament excellent in cut resistance can be improved.

在實用方面,重視耐切割性時,優選的是表4所示的實施例,通過形成將不銹鋼纖維1n捲繞於玻璃纖維的多絲1m上的結構,還能夠賦予柔軟性。另一方面,重視柔軟性時,能夠採用表5所示的實施例。In practical use, when the cut resistance is important, it is preferable to use the embodiment shown in Table 4, and it is also possible to impart flexibility by forming a structure in which the stainless steel fiber 1n is wound around the multifilament of the glass fiber 1 m. On the other hand, when importance is attached to flexibility, the embodiment shown in Table 5 can be employed.

1‧‧‧硬質纖維 2‧‧‧熔融纖維 3‧‧‧下層纖維 5、5a‧‧‧繞線 8、9‧‧‧彈性線 10(10a、10c~10f)‧‧‧複合線 11‧‧‧複合處理 12‧‧‧加熱處理 13‧‧‧包覆處理 20(20a~20e)‧‧‧芯線 30(30a、30c~30e)‧‧‧強韌線 40(40c~40e)‧‧‧強韌線1‧‧‧hard fiber 2‧‧‧Fusing fiber 3‧‧‧Under fiber 5, 5a‧‧‧ Winding 8, 9‧‧‧ elastic thread 10 (10a, 10c ~ 10f) ‧ ‧ composite line 11‧‧‧Combined treatment 12‧‧‧heat treatment 13‧‧‧ Coating treatment 20 (20a ~ 20e) ‧ ‧ core wire 30 (30a, 30c ~ 30e) ‧ ‧ strong line 40 (40c ~ 40e) ‧ ‧ strong line

圖1是示出第一和第二實施例的強韌線的製造工序的框圖。 圖2是第一實施例的芯線的示意剖視圖。 圖3是第二實施例的芯線的示意剖視圖。 圖4是示出第一實施例的包覆處理的示意側視圖。 圖5是示出第三實施例的強韌線的製造工序的框圖。 圖6是示出第三實施例的複合處理的示意側視圖。 圖7是示出第三實施例的芯線的示意剖視圖。 圖8是示出第三實施例的包覆處理的示意側視圖。 圖9是示出第四實施例的複合處理的示意側視圖。 圖10是示出第五實施例的強韌線的製造工序的框圖。 圖11是示出第五實施例的複合處理的示意側視圖。 圖12是示出第五實施例的芯線的示意剖視圖。 圖13是示出第五實施例的包覆處理的示意側視圖。 圖14是示出第六實施例的強韌線的製造工序的框圖。 圖15是示出第六實施例的複合處理的示意側視圖。 圖16是示出第六實施例的芯線的示意剖視圖。 圖17是示出第六實施例的包覆處理的示意側視圖。 圖18是示出第七實施例的強韌線的製造工序的框圖。 圖19是示出第八實施例的強韌線的製造工序的框圖。 圖20是示出第九實施例的強韌線的製造工序的框圖。 圖21是示出針織物的示例的說明圖。 圖22是示出針織物的示例的說明圖。Fig. 1 is a block diagram showing a manufacturing process of the tough line of the first and second embodiments. Fig. 2 is a schematic cross-sectional view of the core wire of the first embodiment. Fig. 3 is a schematic cross-sectional view of a core wire of a second embodiment. Fig. 4 is a schematic side view showing the coating process of the first embodiment. Fig. 5 is a block diagram showing a manufacturing process of a tough line of the third embodiment. Fig. 6 is a schematic side view showing a composite process of the third embodiment. Fig. 7 is a schematic cross-sectional view showing a core wire of a third embodiment. Fig. 8 is a schematic side view showing a coating process of the third embodiment. Fig. 9 is a schematic side view showing a composite process of the fourth embodiment. Fig. 10 is a block diagram showing a manufacturing process of the tough line of the fifth embodiment. Fig. 11 is a schematic side view showing a composite process of the fifth embodiment. Fig. 12 is a schematic cross-sectional view showing a core wire of a fifth embodiment. Fig. 13 is a schematic side view showing a coating process of the fifth embodiment. Fig. 14 is a block diagram showing a manufacturing process of the tough line of the sixth embodiment. Fig. 15 is a schematic side view showing a composite process of the sixth embodiment. Fig. 16 is a schematic cross-sectional view showing a core wire of a sixth embodiment. Fig. 17 is a schematic side view showing a coating process of the sixth embodiment. Fig. 18 is a block diagram showing a manufacturing process of the tough line of the seventh embodiment. Fig. 19 is a block diagram showing a manufacturing process of the tough line of the eighth embodiment. Fig. 20 is a block diagram showing a manufacturing process of the tough line of the ninth embodiment. 21 is an explanatory view showing an example of a knitted fabric. Fig. 22 is an explanatory view showing an example of a knitted fabric.

(無)(no)

1‧‧‧硬質纖維 1‧‧‧hard fiber

2‧‧‧熔融纖維 2‧‧‧Fusing fiber

2a‧‧‧中心部 2a‧‧‧ Central Department

2b‧‧‧熔融 2b‧‧‧melting

3‧‧‧下層纖維 3‧‧‧Under fiber

20c‧‧‧芯線 20c‧‧‧core

Claims (10)

一種強韌線的芯線,該芯線是由硬質纖維和熔融纖維複合而成的線,其中,在硬質纖維上熔接了熔融纖維。A core wire of a tough wire, which is a wire composed of a composite of hard fibers and molten fibers, in which molten fibers are welded to the hard fibers. 如請求項1所述的芯線,其中,所述熔接後的熔融纖維的截面積等於或大於硬質纖維的截面積。The core wire according to claim 1, wherein the melted fiber after the fusion has a cross-sectional area equal to or larger than a cross-sectional area of the hard fiber. 如請求項1所述的芯線,其中,所述芯線是使硬質纖維和熔融纖維複合並熔接而成的,所述芯線還含有下層纖維,所述下層纖維由配置在該硬質纖維與熔融纖維之間的天然纖維或合成纖維構成,所述熔融纖維熔接在所述硬質纖維及未熔融的下層纖維上。The core wire according to claim 1, wherein the core wire is formed by combining and welding a hard fiber and a molten fiber, the core wire further comprising an underlayer fiber, and the lower layer fiber is disposed between the hard fiber and the molten fiber. Between natural fibers or synthetic fibers, the molten fibers are welded to the hard fibers and the unmelted underlayer fibers. 如請求項1或2所述的芯線,其中,所述熔融纖維是其截面中的中心部的熔融溫度高於周邊部的熔融溫度的纖維,通過加熱處理,使得僅其周邊部熔融而與所述硬質纖維熔接。The core wire according to claim 1 or 2, wherein the molten fiber is a fiber whose melting temperature at a central portion in a cross section is higher than a melting temperature of a peripheral portion, and is heat-treated so that only a peripheral portion thereof is melted and Hard fiber fusion. 如請求項3所述的芯線,其中,所述熔融纖維是其截面中的中心部的熔融溫度高於周邊部的熔融溫度的纖維,通過加熱處理,使得僅其周邊部熔融而與所述硬質纖維熔接。The core wire according to claim 3, wherein the molten fiber is a fiber whose central portion has a melting temperature higher than a melting temperature of the peripheral portion, and is heat-treated so that only the peripheral portion thereof is melted and the hard fiber Fiber fusion. 一種強韌線,所述強韌線由繞線捲繞於芯線而形成,其中,芯線是請求項1所述的芯線,所述熔融纖維未與所述繞線熔接。A tough line formed by winding a wire wound around a core wire, wherein the core wire is the core wire of claim 1, and the molten fiber is not welded to the wire. 一種強韌線,所述強韌線由繞線捲繞於芯線而形成,其中,芯線是請求項3或5所述的芯線,所述熔融纖維還與未熔融的所述繞線熔接。A tough line formed by winding a wire wound around a core wire, wherein the core wire is the core wire of claim 3 or 5, and the molten fiber is also welded to the unmelted wire. 一種編織物,所述編織物為請求項6或7所述的強韌線與不含硬質纖維的其它線的編織物,其中,所述強韌線多顯現在該編織物的一個面上,所述其它線多顯現在該編織物的另一面上。A woven fabric, which is a woven fabric of the tough line of claim 6 or 7 and other threads without hard fibers, wherein the tough line is more likely to appear on one side of the woven fabric. The other lines appear more on the other side of the braid. 如請求項8所述的編織物,其中,所述其它線是彈性線。The woven fabric of claim 8, wherein the other thread is an elastic thread. 一種手套,所述手套由請求項6或7所述的強韌線與彈性線編織而成,其中,所述強韌線多顯現在該手套的外表面,所述彈性線多顯現在該手套的內表面。A glove obtained by weaving a tough line and an elastic thread according to claim 6 or 7, wherein the tough line is mostly present on an outer surface of the glove, and the elastic thread is mostly present in the glove Inner surface.
TW105139065A 2016-01-25 2016-11-28 Tough thread and its core thread, knitted fabric, and gloves not exposing a breaking end of a hard fiber making a wearer unpleasant TW201726989A (en)

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