TW201718899A - Chassis for small electronic device and method for forming same, and rolled aluminum alloy laminated sheet material for chassis for small electronic device - Google Patents

Chassis for small electronic device and method for forming same, and rolled aluminum alloy laminated sheet material for chassis for small electronic device Download PDF

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TW201718899A
TW201718899A TW105132391A TW105132391A TW201718899A TW 201718899 A TW201718899 A TW 201718899A TW 105132391 A TW105132391 A TW 105132391A TW 105132391 A TW105132391 A TW 105132391A TW 201718899 A TW201718899 A TW 201718899A
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aluminum alloy
small electronic
mass
alloy rolled
electronic device
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TWI657148B (en
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Masanori Takeuchi
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Showa Denko Packaging Co
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/082Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/088Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/09Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/095Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/281Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0012Mechanical treatment, e.g. roughening, deforming, stretching
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0012Mechanical treatment, e.g. roughening, deforming, stretching
    • B32B2038/0028Stretching, elongating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/40Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2311/00Metals, their alloys or their compounds
    • B32B2311/24Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2457/00Electrical equipment

Abstract

To provide a chassis for a small electronic device that can be formed efficiently by drawing work with low cost, is hard to cause forming failure, and causes no damage on the surface thereof on forming to provide an excellent appearance. The rolled aluminum alloy laminated sheet material is for forming a chassis for a small electronic device by drawing work, and contains a rolled aluminum alloy sheet material having a 0.2% proof stress of 200 MPa or more, and a covering material laminated at least one surface of both surfaces of the rolled aluminum alloy sheet material, and the covering material contains any one of a synthetic resin film, and a laminated material containing a metal foil having synthetic resin films laminated on both surfaces thereof. The rolled aluminum alloy sheet material may have a fibrous crystalline structure extending in a direction perpendicular to a thickness direction thereof.

Description

小型電子機器外殼及其成形方法以及小型電子機器外殼用鋁合金壓延積層板材 Small electronic machine casing and forming method thereof, and aluminum alloy rolled laminated board for small electronic machine casing

本發明係關於平板電腦終端、攜帶通訊終端機器、筆記型電腦、攜帶電話、攜帶音樂機器、數位相機等之小型電子機器的外殼及其成形方法、以及作為同外殼之成形材料使用之鋁合金壓延積層板材。 The present invention relates to a casing for a tablet computer, a communication terminal device, a notebook computer, a mobile phone, a portable electronic device, a digital camera, and the like, and a method for forming the same, and an aluminum alloy calender used as a molding material for the same casing Laminated sheets.

傳統上,小型電子機器之外殼,習知係對於厚板狀之鋁合金押出材進行切削加工(全面削刮)而成形者(例如,參照下述之專利文獻1)。 Conventionally, the outer casing of a small-sized electronic device is known to be formed by cutting (total shaving) a thick-plate-shaped aluminum alloy extruded material (for example, refer to Patent Document 1 below).

由於上述之外殼,可得到優異之外觀、精密度及強度,故可合適作為小型電子機器外殼使用。 Since the above-mentioned outer casing can obtain excellent appearance, precision and strength, it can be suitably used as a small electronic machine casing.

此外,一般而言,從鋁合金板材等之金屬板材成形為所定形狀之製品的手段,絞伸加工亦廣泛被使用。 Further, in general, a kneading process is widely used from a metal plate material such as an aluminum alloy plate to form a product having a predetermined shape.

【先前技術文獻】[Previous Technical Literature] 【專利文獻】[Patent Literature]

【專利文獻1】日本特開2012-246555號公報(JP2012-246555A) [Patent Document 1] Japanese Laid-Open Patent Publication No. 2012-246555 (JP2012-246555A)

然而,藉由切削加工成形之小型電子機器外殼之情形,因對於材料進行切削加工需較長時間,故製造効率較低,此外,伴隨著加工會有切削屑大量產生,而對於此等進行回收處理必須耗費非常多之能源,其結果係有成本提高之問題。 However, in the case of a small electronic machine casing formed by cutting, it takes a long time to cut the material, so the manufacturing efficiency is low, and in addition, a large amount of chips are generated along with the processing, and this is recovered. Processing must consume a lot of energy, and the result is a cost increase.

另一方面,絞伸加工之情形,因係以短時間進行成形,故製造効率優異,此外,因不會伴隨加工而產生飛屑,故可以低成本製造。但,小型電子機器外殼之形態,一般而言,係具備:從平面觀察時為略方形之底壁、及由底壁之周緣站立之側壁者。如此形態之外殼若藉由絞伸加工而成形,則在側壁之角落部分會產生裂痕,成形不良之虞極大。 On the other hand, in the case of the drawing process, since the molding is performed in a short time, the production efficiency is excellent, and since the flying chips are not generated accompanying the processing, the production can be performed at low cost. However, the form of the outer casing of the small electronic device generally includes a bottom wall which is slightly square when viewed in plan, and a side wall which is stood by the periphery of the bottom wall. When the outer casing of such a shape is formed by the drawing process, cracks are formed in the corner portions of the side wall, and the molding failure is extremely large.

並且,絞伸加工之情形,因金屬板材之表面與模具係滑動接觸,故會有因其導致成形品之表面產生傷痕,而損害製品外觀之虞。 Further, in the case of the skewing process, since the surface of the metal sheet is in sliding contact with the mold, there is a possibility that the surface of the molded article is scratched and the appearance of the product is impaired.

本發明之目的,係提供一種小型電子機器外殼,其除了可藉由絞伸加工而高効率且低成本地成形之外,亦難以發生成形不良,此外,其係不會因成形而損傷表面,具有優異外觀者。 SUMMARY OF THE INVENTION An object of the present invention is to provide a small electronic machine casing which is not only capable of being formed by high-efficiency and low-cost molding by butting processing, but also which is difficult to cause molding defects, and which does not damage the surface by molding. Has an excellent appearance.

本發明,為了達成上述目的,係由以下之態樣所成。 The present invention has been made in view of the following aspects in order to achieve the above object.

1)一種小型電子機器外殼用鋁合金壓延積層板材,其係藉由絞伸加工而成形為小型電子機器外殼之鋁合金壓延積層板材,其特徵係由鋁合金壓延板材及被覆材所構成,前述鋁合金壓延板材係0.2%耐力為200MPa以上;前述被覆材係積層於鋁合金壓延板材之兩面中至少一側的面;且被覆材係由合成樹脂薄膜、及在金屬箔之兩面積層合成樹脂薄膜之積層體中至少一者所成者。 1) An aluminum alloy rolled laminated sheet material for a small electronic machine casing, which is formed by an aluminum alloy rolled laminated sheet material which is formed into a small electronic machine casing by a drawing process, and is characterized in that it is composed of an aluminum alloy rolled sheet material and a covering material, The aluminum alloy rolled sheet has a 0.2% proof resistance of 200 MPa or more; the coated material is laminated on at least one of the two faces of the aluminum alloy rolled sheet; and the coated material is synthesized from a synthetic resin film and a two-layer layer of the metal foil. At least one of the laminates of the resin film is formed.

2)如上述1)之小型電子機器外殼用鋁合金壓延積層板材,其中,鋁合金壓延板材,係具有從與厚方向直交之方向延伸之纖維狀之結晶組織。 2) The aluminum alloy calendered laminate sheet for a small electronic machine casing according to the above 1), wherein the aluminum alloy rolled sheet has a fibrous crystal structure extending from a direction orthogonal to the thickness direction.

3)如上述1)或2)之小型電子機器外殼用鋁合金壓延積層板材,其中,鋁合金壓延板材,係由:Al-Mn-Mg系合金、Al-Si-Mg系合金、及Al-Zn-Mg系合金中任一者之鋁合金所成;且Al-Mn-Mg系合金,係由Mn:0.2~0.7質量%、Mg:2.0~5.0質量%、殘部Al及不可避雜質所成;Al-Si-Mg系合金,係由Si:0.2~0.8質量%、Mg:0.4~1.2質量%、殘部Al及不可避雜質所成;Al-Zn-Mg系合金,係由Zn:4.0~6.5質量%、Mg:0.5~3.0質量%、殘部Al及不可避雜質所成。 3) An aluminum alloy calendered laminate sheet for a small electronic machine casing according to the above 1) or 2), wherein the aluminum alloy rolled sheet is made of an Al-Mn-Mg alloy, an Al-Si-Mg alloy, and an Al- An aluminum alloy of any one of Zn-Mg alloys; and an Al-Mn-Mg alloy is composed of Mn: 0.2 to 0.7% by mass, Mg: 2.0 to 5.0% by mass, The Al-Si-Mg alloy is composed of Si: 0.2 to 0.8% by mass, Mg: 0.4 to 1.2% by mass, residual Al and unavoidable impurities; The Al-Zn-Mg-based alloy is formed of Zn: 4.0 to 6.5% by mass, Mg: 0.5 to 3.0% by mass, residual Al, and unavoidable impurities.

4)如上述1)~3)中任一項之小型電子機器外殼用鋁合金壓延積層板材,其中,被覆材之厚度,係鋁合金壓延板材之厚度的0.05~1.5倍。 4) The aluminum alloy rolled laminated board for a small electronic machine casing according to any one of the above 1), wherein the thickness of the covering material is 0.05 to 1.5 times the thickness of the aluminum alloy rolled sheet.

5)如上述1)~4)中任一項之小型電子機器外殼用鋁合 金壓延積層板材,其中,鋁合金壓延板材之厚度,係0.5~3.5mm。 5) Aluminum alloy for a small electronic machine casing according to any one of the above 1) to 4) The gold rolled laminate sheet, wherein the thickness of the aluminum alloy rolled sheet is 0.5 to 3.5 mm.

6)如上述1)~5)中任一項之小型電子機器外殼用鋁合金壓延積層板材,其中,鋁合金壓延板材之兩面中成為小型電子機器外殼之外面的面,係積層有厚度50~100μm之聚酯樹脂薄膜或聚醯胺樹脂薄膜所成被覆材。 (6) The aluminum alloy rolled laminated board for a small electronic machine casing according to any one of the above 1) to 5), wherein the surface of the outer surface of the small electronic machine casing is formed on both sides of the aluminum alloy rolled sheet, and the thickness of the laminated layer is 50~ A 100 μm polyester resin film or a polyamide resin film is used as a coating material.

7)如上述1)~6)中任一項之小型電子機器外殼用鋁合金壓延積層板材,其中,在鋁合金壓延板材之兩面中成為小型電子機器外殼之內面的面,係積層有厚度10~100μm之聚乙烯樹脂薄膜、聚丙烯樹脂薄膜或聚醯胺樹脂薄膜所成被覆材。 (7) The aluminum alloy rolled laminated sheet material for a small electronic machine casing according to any one of the above 1), wherein the surface of the inner surface of the small electronic machine casing is formed on both sides of the aluminum alloy rolled plate, and the thickness of the laminated layer is thick. A coating material of a polyethylene resin film, a polypropylene resin film or a polyamide resin film of 10 to 100 μm is used.

8)一種附被覆材小型電子機器外殼,其特徵係對於上述1)~7)中任一項之小型電子機器外殼用鋁合金壓延積層板材進行絞伸加工,並在內外兩面中至少一側的面被覆由合成樹脂薄膜或積層體所成被覆材者。 8) A small electronic device casing with a covering material, characterized in that the aluminum alloy rolled laminated sheet material for a small electronic machine casing according to any one of the above 1) to 7) is subjected to a drawing process, and at least one of the inner and outer surfaces The surface is covered with a synthetic resin film or a laminate to form a covering material.

9)一種小型電子機器外殼,其特徵係對於上述1)~7)中任一項之小型電子機器外殼用鋁合金壓延積層板材進行絞伸加工後,去除內外兩面中至少一側的面所被覆之被覆材。 9) A small electronic device casing characterized in that, after the aluminum alloy rolled laminated sheet material for a small electronic machine casing according to any one of the above 1) to 7) is subjected to a drawing process, the surface of at least one of the inner and outer faces is removed. The covering material.

10)如上述9)之小型電子機器外殼,其中,其係具備:底壁、從底壁之周緣站立之側壁,且側壁之高度係0.5~25mm,相對於底壁,側壁角度係90~150°。 10) The small electronic device casing according to the above 9), wherein the bottom wall has a side wall standing from the periphery of the bottom wall, and the height of the side wall is 0.5 to 25 mm, and the side wall angle is 90 with respect to the bottom wall. ~150°.

11)一種小型電子機器外殼之成形方法,其特徵係對於上述1)~7)中任一項之小型電子機器外殼用鋁合金壓延積層板材進行絞伸加工。 11) A method of forming a small electronic machine casing, characterized in that the aluminum alloy rolled laminated sheet material for a small electronic machine casing according to any one of the above items 1) to 7) is subjected to a drawing process.

根據上述1)之小型電子機器外殼用鋁合金壓延積層板材,由於作為外殼之材料之鋁合金壓延板材,係使用0.2%耐力為200MPa以上者,故可確保所望之外殼強度。 According to the above-mentioned 1), the aluminum alloy rolled laminated sheet material for the small electronic device casing is used as the aluminum alloy rolled sheet material of the outer casing, and the 0.2% proof force is 200 MPa or more, so that the desired outer shell strength can be ensured.

此外,根據上述1)之鋁合金壓延積層板材,由於在鋁合金壓延板材之兩面中至少一側的面,係積層有合成樹脂薄膜、或被覆材,且該被覆材係由在金屬箔之兩面積層合成樹脂薄膜之積層體所成摩擦阻力較小者,故除了不會因絞伸加工而導致在成形之外殼的側壁上產生皺摺,且側壁之角落部分不會產生裂痕,而可抑制成形不良的發生之外,可防止與模具接觸所導致之外殼之表面損傷,而不損及外殼之外觀。 Further, according to the aluminum alloy rolled laminated sheet material of the above 1), a synthetic resin film or a covering material is laminated on at least one of both surfaces of the aluminum alloy rolled sheet, and the covering material is on both sides of the metal foil. The laminated body of the laminated synthetic resin film has a small frictional resistance, so that wrinkles are not formed on the side wall of the formed outer casing due to the twisting process, and cracks are not formed in the corner portions of the side wall, thereby suppressing the forming. In addition to the occurrence of defects, the surface damage of the outer casing caused by contact with the mold can be prevented without damaging the appearance of the outer casing.

根據上述2)之小型電子機器外殼用鋁合金壓延積層板材,由於鋁合金壓延板材,係具有向與厚方向直交之方向延伸的纖維狀之結晶組織,故對於彎折,板材之強度變高,使皺褶或裂痕等之成形不良難以產生。 According to the aluminum alloy rolled laminated sheet material for the small electronic device casing of the above 2), since the aluminum alloy rolled sheet has a fibrous crystal structure extending in a direction orthogonal to the thick direction, the strength of the sheet is increased for bending. It is difficult to cause formation defects such as wrinkles or cracks.

根據上述3)之小型電子機器外殼用鋁合金壓延積層板材,由於鋁合金壓延板材,係由具有上述各組成之Al-Mn-Mg系合金、Al-Si-Mg系合金、Al-Zn-Mg系合金中任一者之鋁合金所成,可良好地進行藉由絞伸加工之成形,從而得到精密性及強度皆極高且外觀性優異之外殼。 The aluminum alloy rolled laminated sheet material for the small electronic machine casing according to the above 3), the aluminum alloy rolled sheet material is composed of the Al-Mn-Mg alloy, the Al-Si-Mg alloy, and the Al-Zn-Mg having the above respective compositions. The aluminum alloy of any of the alloys can be formed by a drawing process, and an outer casing having excellent precision and strength and excellent appearance can be obtained.

根據上述4)之小型電子機器外殼用鋁合金壓延積層板材,由於被覆材之厚度係鋁合金壓延板材之厚度的0.05~1.5倍,故可 迴避以下之問題。 According to the above 4), the aluminum alloy rolled laminated plate material for the small electronic machine casing is 0.05 to 1.5 times the thickness of the aluminum alloy rolled plate because the thickness of the coated material is 0.05 to 1.5 times. Avoid the following questions.

亦即,被覆材之厚度未達鋁合金壓延板材之厚度的0.05倍時,被覆材會破裂而導致成形品與模具接觸之位置損傷。另一方面,被覆材之厚度超過鋁合金壓延板材之厚度的1.5倍時,無法得到以上之效果,而僅會提高成本。 That is, when the thickness of the covering material is less than 0.05 times the thickness of the aluminum alloy rolled sheet, the covering material is broken and the position where the molded article comes into contact with the mold is damaged. On the other hand, when the thickness of the covering material exceeds 1.5 times the thickness of the aluminum alloy rolled sheet, the above effects cannot be obtained, and only the cost is increased.

根據上述5)之小型電子機器外殼用鋁合金壓延積層板材,由於鋁合金壓延板材之厚度係0.5~3.5mm,故可迴避以下之問題。 According to the above-mentioned 5), the aluminum alloy rolled laminated plate material for the small electronic device casing has the following problems because the thickness of the aluminum alloy rolled plate is 0.5 to 3.5 mm.

亦即,鋁合金壓延板材材之厚度未達0.5mm時,最終製品之強度會不足。另一方面,鋁合金壓延板材之厚度超過3.5mm時,彎折部或角落部之曲率半徑(R)會過大。 That is, when the thickness of the aluminum alloy rolled sheet material is less than 0.5 mm, the strength of the final product may be insufficient. On the other hand, when the thickness of the aluminum alloy rolled sheet exceeds 3.5 mm, the radius of curvature (R) of the bent portion or the corner portion is excessively large.

根據上述6)之小型電子機器外殼用鋁合金壓延積層板材,可奏效以下之効果。亦即,在對於鋁合金壓延積層板材進行絞伸加工而成形為小型電子機器外殼時,板材兩面中成為小型電子機器外殼之外面的面,雖然會局部性與模具摩擦,但若使用厚度50~100μm之聚酯樹脂薄膜或聚醯胺樹脂薄膜作為被覆同面之被覆材,則不會發生模具之摩擦導致之破斷,從而可確實迴避成形品之表面損傷,此外,可抑制薄膜之厚度過大時成本的增加,進一步,可迴避薄膜之剛性過大而導致外殼之彎折成形部分突起或剝離。 According to the above 6), the aluminum alloy rolled laminated sheet material for the small electronic machine casing can achieve the following effects. That is, when the aluminum alloy rolled laminated sheet material is subjected to the drawing process and formed into a small electronic machine casing, the surface of the outer surface of the small electronic machine casing is formed on both sides of the plate material, and although the surface is partially rubbed with the mold, if the thickness is 50~ When a 100 μm polyester resin film or a polyamide resin film is used as a coating material coated with the same surface, the film is not broken by friction of the mold, and the surface damage of the molded article can be surely avoided, and the thickness of the film can be suppressed from being excessively large. Further, the increase in cost can further avoid the excessive rigidity of the film, resulting in protrusion or peeling of the bent portion of the outer casing.

根據上述7)之小型電子機器外殼用鋁合金壓延積層板材,可奏效以下之効果。亦即,在對於鋁合金壓延積層板材進行絞伸加工而成形為小型電子機器外殼時,板材兩面中成為小型電子機器外殼之內面的面,雖不會與模具摩擦,但為了在凹方向使彎折成形之部分產生,使用厚 度10~100μm之聚乙烯樹脂薄膜、聚丙烯樹脂薄膜或聚醯胺樹脂薄膜作為被覆同面之被覆材,可迴避因薄膜之剛性過大所導致外殼之彎折成形之部分突起或剝離,此外,可迴避因外殼之彎折成形之部分之曲率半徑(R)增大而無法得到尖銳形狀的事態。 According to the above 7), the aluminum alloy rolled laminated sheet material for the small electronic machine casing can achieve the following effects. That is, when the aluminum alloy rolled laminated sheet material is subjected to the drawing process and formed into a small electronic machine casing, the surface of the inner surface of the small electronic machine casing is formed on both sides of the plate material, and although it does not rub against the mold, in order to make it in the concave direction Part of the bending forming, use thick A polyethylene resin film, a polypropylene resin film or a polyamide resin film having a degree of 10 to 100 μm is used as a coating material covering the same surface, and it is possible to avoid partial protrusion or peeling of the outer shape of the outer casing due to excessive rigidity of the film. It is possible to avoid a situation in which the radius of curvature (R) of the portion formed by bending of the outer casing is increased and a sharp shape cannot be obtained.

根據上述8)之附被覆材小型電子機器外殼,除了藉由絞伸加工可良好地進行鋁合金壓延板材的成形之外,成形時不會損傷表面,從而得到具有高精密度及強度且美麗外觀之外殼。 According to the above-mentioned 8), the small-sized electronic machine casing with the covering material can perform the forming of the aluminum alloy rolled sheet well by the drawing process, and the surface is not damaged during the forming, thereby obtaining a beautiful appearance with high precision and strength. The outer casing.

並且,根據上述8)之附被覆材小型電子機器外殼,由於係外殼之表面由被覆材被覆狀態,故可防止在保管時或搬運時等導致表面損傷。 Further, according to the above-mentioned 8), the small electronic device casing with the covering material is covered by the covering material, so that surface damage during storage or transportation can be prevented.

根據上述9)之小型電子機器外殼,除了藉由絞伸加工可良好地進行鋁合金壓延板材的成形之外,成形時及進一步保管時或搬運時皆不會損傷表面,從而可得到高精密度及強度且呈現美麗外觀之外殼。 According to the small electronic device casing of the above 9), the aluminum alloy rolled sheet can be favorably formed by the drawing process, and the surface is not damaged during molding, further storage, or transportation, so that high precision can be obtained. And a shell that is strong and has a beautiful appearance.

根據上述10)之小型電子機器外殼,由於側壁之高度係0.5~25mm,且相對於底壁,側壁之角度係150°,故可迴避以下之問題。 According to the small electronic device casing of the above 10), since the height of the side wall is 0.5 to 25 mm and the angle of the side wall is 150 with respect to the bottom wall, the following problems can be avoided.

亦即,側壁之高度未達0.5mm時,後步驟之切削部分較多。另一方面,側壁之高度超過25mm時,小型電子機器之厚度會增大而不佳。 That is, when the height of the side wall is less than 0.5 mm, the cutting portion of the latter step is more. On the other hand, when the height of the side wall exceeds 25 mm, the thickness of the small electronic machine may increase.

此外,相對於底壁,側壁之角度未達90°時,亦即,側壁向內側傾斜時,角落部會產生皺摺導致加工困難。另一方面,相對於底壁,側壁之角度超過150°時,外殼之深度會變淺,從而導致收容小型電子機器之部件的收容容積減少。 Further, when the angle of the side wall is less than 90 with respect to the bottom wall, that is, when the side wall is inclined inward, the corner portion may wrinkle and the processing is difficult. On the other hand, when the angle of the side wall exceeds 150° with respect to the bottom wall, the depth of the outer casing becomes shallow, and the storage volume of the components accommodating the small electronic device is reduced.

根據上述11)之小型電子機器外殼之成形方法,具有高精 密度及強度且呈現美麗外觀之小型電子機器外殼,可藉由絞伸加工而効率良好且低成本地成形。 According to the above 11) small electronic machine housing forming method, with high precision A small electronic machine casing that has a high density and strength and a beautiful appearance can be formed efficiently and at low cost by the drawing process.

(1)‧‧‧鋁合金壓延積層板材 (1)‧‧‧Aluminum rolled laminated sheets

(2)‧‧‧鋁合金壓延板材 (2)‧‧‧Aluminum alloy rolled sheet

(3)(4)‧‧‧被覆材 (3) (4) ‧‧‧ Covering materials

(30)(40)‧‧‧合成樹脂薄膜 (30) (40) ‧‧‧Synthetic resin film

(31)(41)‧‧‧金屬箔 (31) (41)‧‧‧Metal foil

(32)(33)(42)(43)‧‧‧合成樹脂薄膜 (32)(33)(42)(43)‧‧‧Synthetic resin film

(5)‧‧‧固定雌型 (5) ‧ ‧ fixed female

(6)‧‧‧可動雄型 (6) ‧‧‧ movable male

(20)‧‧‧小型電子機器外殼 (20)‧‧‧Small electronic machine housing

(21)‧‧‧底壁 (21) ‧‧‧ bottom wall

(22)‧‧‧側壁 (22)‧‧‧ Sidewall

(22a)‧‧‧(側壁之)角落部 (22a) ‧‧‧ (side wall) corner

【圖1】表示本發明之小型電子機器外殼用鋁合金壓延積層板材之層構造的部分擴大斷面圖。 Fig. 1 is a partially enlarged cross-sectional view showing a layer structure of an aluminum alloy rolled laminated sheet material for a small electronic device casing of the present invention.

【圖2】依序表示對於同板材進行絞伸加工使小型電子機器外殼成形之步驟的垂直斷面圖。 Fig. 2 is a vertical sectional view showing, in order, a step of forming a small electronic machine casing by twisting a same plate.

【圖3】本發明之小型電子機器外殼的斜視圖。 Fig. 3 is a perspective view showing the outer casing of the small electronic machine of the present invention.

【圖4】表示對於鋁合金壓延板材進行彎折加工並觀察斷面之纖維狀結晶組織時之斷面方向的斜視圖。 Fig. 4 is a perspective view showing a cross-sectional direction when a rolled aluminum alloy rolled sheet is bent and a fibrous crystal structure of a cross section is observed.

【圖5】同鋁合金壓延板材之彎折材(內曲徑:0mm)之斷面(相對於壓延方向之斷面方向:90°)的顯微鏡相片。 Fig. 5 is a photomicrograph of a section of the bent material (inner labyrinth: 0 mm) of the aluminum alloy rolled sheet (section direction with respect to the rolling direction: 90°).

【圖6】同鋁合金壓延板材之彎折材(內曲徑:0.4mm)之斷面(相對於壓延方向之斷面方向:90°)的顯微鏡相片。 Fig. 6 is a photomicrograph of a section of the bent material (inner labyrinth: 0.4 mm) of the aluminum alloy rolled sheet (section direction with respect to the rolling direction: 90°).

【圖7】同鋁合金壓延板材之彎折材(內曲徑:0mm)之斷面(相對於壓延方向之斷面方向:0°)的顯微鏡相片。 Fig. 7 is a photomicrograph of a section of the bent material (inner labyrinth: 0 mm) of the aluminum alloy rolled sheet (section direction with respect to the rolling direction: 0°).

【圖8】同鋁合金壓延板材之彎折材(內曲徑:0.4mm)之斷面(相對於壓延方向之斷面方向:0°)的顯微鏡相片。 Fig. 8 is a photomicrograph of a section of a bent material (inner labyrinth: 0.4 mm) of an aluminum alloy rolled sheet (section direction with respect to the rolling direction: 0°).

以下,參照圖1~8,說明本發明之實施型態。 Hereinafter, an embodiment of the present invention will be described with reference to Figs.

圖1,係表示本發明之小型電子機器外殼用鋁合金壓延積層板材(1)之層構造者。 Fig. 1 is a view showing a layer structure of an aluminum alloy rolled laminated sheet (1) for a small electronic machine casing of the present invention.

如圖示,小型電子機器外殼用鋁合金壓延積層板材(1),係由鋁合金壓延板材(2)、及鋁合金壓延板材(2)之兩面個別積層之被覆材(3)(4)所構成。 As shown in the figure, the aluminum alloy rolled laminated sheet (1) for the small electronic machine casing is made of aluminum alloy rolled sheet (2) and aluminum alloy rolled sheet (2) on both sides of the laminated layer (3) (4). Composition.

上述之鋁合金壓延板材(2),係使用0.2%耐力為200MPa以上,較佳為250MPa以上,進一步較佳為300MPa以上者。藉此,可得到所望之外殼的強度。此外,鋁合金壓延板材(2),係適宜地使用斷裂伸長率為5%以上20%以下者。藉此,可提升絞伸加工之成形性。在此,「0.2%耐力」及「斷裂伸長率」,係藉由使用JIS Z 2241-2011所規定之5號試驗片,並在壓延方向進行並行方向之拉伸試驗而得者。 The aluminum alloy rolled sheet (2) is 0.2% or more, preferably 250 MPa or more, and more preferably 300 MPa or more. Thereby, the strength of the desired outer casing can be obtained. Further, in the aluminum alloy rolled sheet (2), those having an elongation at break of 5% or more and 20% or less are suitably used. Thereby, the formability of the stretching process can be improved. Here, "0.2% proof stress" and "elongation at break" were obtained by using a test piece No. 5 prescribed in JIS Z 2241-2011 and performing a tensile test in parallel in the rolling direction.

此外,鋁合金壓延板材(2),具有在與厚度方向直交之方向延伸的纖維狀之結晶組織。 Further, the aluminum alloy rolled sheet (2) has a fibrous crystal structure extending in a direction orthogonal to the thickness direction.

前述纖維狀之結晶組織,係藉由將均質化處理之鋁合金鑄塊在熱間壓延後,以所定之條件進行熱處理,之後進行冷間壓延而形成。前述熱處理,係藉由在200~400℃保持1小時以上而進行。藉由前述熱處理,Mg2Si可微細且均勻析出,且可減少壓延材料中所存在之加工應變。之後藉由冷間加工而使其加工硬化,從而可得到不損及之後的成形加工性之範圍之高強度之鋁合金壓延板材。 The fibrous crystal structure is formed by calendering the homogenized aluminum alloy ingot after heat treatment, heat treatment under predetermined conditions, and then performing cold rolling. The heat treatment is carried out by holding at 200 to 400 ° C for 1 hour or more. By the aforementioned heat treatment, Mg 2 Si can be finely and uniformly precipitated, and the processing strain existing in the rolled material can be reduced. Then, it is work hardened by cold working, and a high-strength aluminum alloy rolled sheet which does not impair the range of subsequent moldability can be obtained.

鋁合金鑄塊之均質化處理的條件並無特別限制,根據常法以500℃以上、2小時以上進行為佳。 The conditions for the homogenization treatment of the aluminum alloy ingot are not particularly limited, and it is preferably carried out at 500 ° C or more and 2 hours or more according to a usual method.

熱間壓延,藉由在以任意之路徑步驟中所定之溫度條件進行壓延時溫度降低而得到與淬火相同之効果。因此,路徑前之材料溫度,必須係可將Mg及Si保持在固溶狀態之溫度,為350~440℃。為了使路徑完成溫度成為上述200~400℃之溫度範囲,亦可在熱間壓延完成時,立即進行高壓淋浴水冷等之強制冷却。此外,為了得到淬火効果,路徑間之冷却速度係50℃/分以上,路徑完成溫度係250~340℃,此外,路徑壓延速度係50m/分以上,完成板厚係10mm以下。 The inter-heat rolling is obtained by the same effect as quenching by performing a temperature reduction of the temperature at a temperature determined in an arbitrary path step. Therefore, the material temperature before the path must be at a temperature of 350 to 440 ° C which can maintain Mg and Si in a solid solution state. In order to make the path completion temperature into the temperature range of 200 to 400 ° C described above, it is also possible to perform forced cooling such as high-pressure shower water cooling immediately after the hot-rolling is completed. Further, in order to obtain the quenching effect, the cooling rate between the paths is 50 ° C / min or more, the path completion temperature is 250 to 340 ° C, and the path rolling speed is 50 m / min or more, and the thickness is 10 mm or less.

冷間壓延,為了得到藉由加工硬化所成所定之強度,係壓下率為30%以上。較佳係壓下率為50%以上。 Calender rolling, in order to obtain a predetermined strength by work hardening, the system reduction ratio is 30% or more. Preferably, the reduction ratio is 50% or more.

進一步,因應必要,可將冷間壓延之合金板以130~150℃之溫度進行最終燒鈍。藉由在低溫進行熱處理,可使其時効硬化而進一步提升強度,且可提升延伸。此外,亦有使機械之諸物性安定化之効果。 Further, if necessary, the cold-rolled alloy sheet may be finally blunt at a temperature of 130 to 150 °C. By heat-treating at a low temperature, it is aged hardened to further increase the strength, and the elongation can be improved. In addition, there is also the effect of making the physical properties of the machine stable.

鋁合金壓延板材(2),可適宜地使用以下任一者之鋁合金所成者。 The aluminum alloy rolled sheet (2) can be suitably formed using any of the following aluminum alloys.

i)Al-Mn-Mg系合金,含有Mn:0.2~0.7質量%、Mg:2.0~5.0質量%,且由殘部Al及不可避雜質所成 i) Al-Mn-Mg-based alloy containing Mn: 0.2 to 0.7% by mass, Mg: 2.0 to 5.0% by mass, and formed by residual Al and unavoidable impurities

ii)Al-Si-Mg系合金,含有Si:0.2~0.8質量%、Mg:0.4~1.2質量%,且由殘部Al及不可避雜質所成 Ii) Al-Si-Mg alloy containing Si: 0.2 to 0.8% by mass, Mg: 0.4 to 1.2% by mass, and formed by residual Al and unavoidable impurities

iii)Al-Zn-Mg系合金,含Zn:4.0~6.5質量%、Mg:0.5~3.0質量%,且由殘部Al及不可避雜質所成 Iii) Al-Zn-Mg alloy containing Zn: 4.0 to 6.5 mass%, Mg: 0.5 to 3.0 mass%, and formed by residual Al and unavoidable impurities

上述i)之合金,可列舉如,含有Si:0.4質量%以下、Mn:0.4~0.6質量%、Mg:4.0~4.9質量%、Fe:0.4質量%以下、Cr:0.05~0.25質量%、Zn:0.25質量%以 下,且由殘部Al及不可避雜質所成之鋁合金。 The alloy of the above i) may, for example, contain Si: 0.4% by mass or less, Mn: 0.4 to 0.6% by mass, Mg: 4.0 to 4.9% by mass, and Fe: 0.4 mass. % or less, Cr: 0.05 to 0.25 mass%, and Zn: 0.25 mass% The aluminum alloy is made of the residue Al and the unavoidable impurities.

上述ii)之合金,可列舉如,含有Si:0.2~0.6質量%、Mg:0.45~0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下,且由殘部Al及不可避雜質所成之鋁合金。 The alloy of the above ii) may, for example, contain Si: 0.2 to 0.6% by mass, Mg: 0.45 to 0.9% by mass, Fe: 0.35% by mass or less, and Cr: 0.1% by mass. % or less, Zn: 0.1% by mass or less, and an aluminum alloy formed of the residue Al and the unavoidable impurities.

上述iii)之合金,可列舉如,含有Si:0.4質量%以下、Mg:2.1~2.9質量%、Fe:0.5質量%以下、Cu:1.2~2.0質量%、Mn:0.3質量%以下、Cr:0.18~0.28質量%、Zn:5.1~6.1質量%,且由殘部Al及不可避雜質所成之鋁合金。 The alloy of the above iii) may, for example, contain Si: 0.4% by mass or less, Mg: 2.1 to 2.9% by mass, Fe: 0.5% by mass or less, and Cu: 1.2 to 2.0. Mass%, Mn: 0.3% by mass or less, Cr: 0.18 to 0.28% by mass, Zn: 5.1 to 6.1% by mass, and an aluminum alloy formed of the residue Al and the unavoidable impurities.

此等之中,特別係,含有Si:0.2~0.6質量%、Mg:0.45~0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下,且由殘部Al及不可避雜質所成之鋁合金而成鋁合金壓延板材(2),可合適地作為小型電子機器外殼之成形材料。 Among these, Si: 0.2 to 0.6% by mass, Mg: 0.45 to 0.9% by mass, Fe: 0.35% by mass or less, and Cr: 0.1% by mass or less. Zn: 0.1% by mass or less, and an aluminum alloy rolled sheet (2) made of an aluminum alloy having a residual portion Al and an unavoidable impurity, can be suitably used as a molding material for a small electronic machine casing.

此外,使用之鋁合金壓延板材(2)之厚度,可因應成形條件或成形品之外殼的尺寸等進行適宜設定,較佳係0.5~3.5mm,更佳係0.8~1.2mm。 Further, the thickness of the aluminum alloy rolled sheet (2) to be used may be appropriately set depending on the molding conditions or the size of the outer shell of the molded article, and is preferably 0.5 to 3.5 mm, more preferably 0.8 to 1. 2mm.

被覆材(3)(4),係為了提升鋁合金壓延板材(2)進行絞伸加工時之成形性,此外,減少成形時之潤滑劑的使用,以及,防止成形時板材(2)表面損傷,進一步,外殼成形後,例如保管時或搬運時保護外殼表面者。 The covering material (3) (4) is used to improve the formability of the aluminum alloy rolled sheet (2) during the drawing process, and to reduce the use of the lubricant during forming and to prevent surface damage of the sheet (2) during forming. Further, after the outer casing is formed, for example, the surface of the outer casing is protected during storage or transportation.

被覆材(3)(4),有如圖1(a)所示,使用在金屬箔(31)(41)之兩面積層合成樹脂薄膜(32)(33)(42)(43)所成積層體(3)(4)之情形,亦有如圖1(b) 所示,使用合成樹脂薄膜(30)(40)之情形。 The covering material (3) (4) has a laminate formed by using two-layer synthetic resin films (32) (33) (42) (43) of the metal foil (31) (41) as shown in Fig. 1 (a). (3) (4), as shown in Figure 1(b) As shown, the case of the synthetic resin film (30) (40) is used.

圖1(a)所示第1態樣之小型電子機器外殼用鋁合金壓延積層板材(1)中,構成被覆材之積層體(3)(4)的金屬箔(31)(41),可列舉如鋁箔、不鏽鋼箔、銅箔。此外,積層體(3)(4)之合成樹脂薄膜(32)(33)(42)(43),可列舉如:未延伸聚丙烯樹脂薄膜(CPP)、聚乙烯對苯二甲酸乙二酯樹脂薄膜(PET)、尼龍樹脂薄膜(Ny)、聚醯亞胺樹脂薄膜(PI)、聚乙烯樹脂薄膜(PE)等,抑或,此等之延伸薄膜等。金屬箔(31)(41)與合成樹脂薄膜(32)(33)(42)(43)的積層,例如,係介由聚酯胺基甲酸乙酯樹脂(PAUR)、丙烯酸樹脂、酸變性聚烯烴樹脂(APO)等與硬化劑所成接著劑層(省略圖示)而進行。 The metal foil (31) (41) constituting the laminated body (3) (4) of the covering material in the aluminum alloy rolled laminated board (1) for a small electronic device casing according to the first aspect shown in Fig. 1(a), Listed as aluminum foil, stainless steel foil, copper foil. Further, the synthetic resin film (32) (33) (42) (43) of the laminate (3) (4) may, for example, be an unstretched polypropylene resin film (CPP) or polyethylene terephthalate. Resin film (PET), nylon resin film (Ny), polyimide film (PI), polyethylene resin film (PE), etc., or such stretch film. Lamination of the metal foil (31) (41) and the synthetic resin film (32) (33) (42) (43), for example, by polyester urethane resin (PAUR), acrylic resin, acid denaturation polymerization An olefin resin (APO) or the like is formed as an adhesive layer (not shown) with a curing agent.

圖1(b)所示第2態樣之小型電子機器外殼用鋁合金壓延積層板材(1)中,構成被覆材(3)(4)之合成樹脂薄膜(30)(40),例如,可使用聚丙烯樹脂薄膜、聚酯樹脂薄膜、聚醯胺樹脂薄膜、聚醯亞胺樹脂薄膜、聚乙烯樹脂薄膜,較佳係使用2軸延伸聚乙烯對苯二甲酸乙二酯樹脂薄膜(PET)、2軸延伸尼龍樹脂薄膜(ONy)、聚乙烯樹脂薄膜、2軸延伸聚醯胺樹脂薄膜、2軸延伸聚丙烯樹脂薄膜(OPP)、未延伸聚丙烯樹脂薄膜(CPP)、未延伸尼龍樹脂薄膜(CNy)中任一者之薄膜。 In the aluminum alloy rolled laminated board (1) for a small electronic device casing of the second aspect shown in Fig. 1(b), the synthetic resin film (30) (40) constituting the covering material (3) (4), for example, A polypropylene resin film, a polyester resin film, a polyamide resin film, a polyimide film, a polyethylene resin film, preferably a 2-axis extended polyethylene terephthalate resin film (PET) is used. , 2-axis extended nylon resin film (ONy), polyethylene resin film, 2-axis extended polyamide resin film, 2-axis extended polypropylene resin film (OPP), unstretched polypropylene resin film (CPP), unstretched nylon resin A film of any of the films (CNy).

此外,鋁合金壓延板材(2)之兩面中成為小型電子機器外殼之外面的面(圖1(b)係下面)所積層之被覆材(3),係使用厚度10~200μm之合成樹脂薄膜(30)為佳,成為小型電子機器外殼之內面的面(圖1(b)係上面)所積層之被覆材(4),係使用厚度10~100μm之合成樹脂薄膜(40)為佳。 In addition, the covering material (3) which is laminated on the outer surface of the outer surface of the small electronic device (the lower surface of Fig. 1(b)) on both sides of the aluminum alloy rolled sheet (2) is a synthetic resin film having a thickness of 10 to 200 μm ( 30) Preferably, the covering material (4) laminated on the inner surface of the outer surface of the small electronic device casing (the upper surface of Fig. 1(b)) is preferably a synthetic resin film (40) having a thickness of 10 to 100 μm.

更佳係,鋁合金壓延板材(2)之兩面中成為小型電子機器外殼之外面的面(圖1(b)係下面)所積層之被覆材(3),由厚度50~100μm之聚酯樹脂薄膜或聚醯胺樹脂薄膜構成,進一步更佳係,由厚度50~100μm之2軸延伸聚乙烯對苯二甲酸乙二酯樹脂薄膜(PET)、2軸延伸聚乙烯萘二甲酸樹脂薄膜(PEN)、或2軸延伸6-尼龍樹脂薄膜(ONy)(30)構成。上述之薄膜(30),可適宜地使用拉伸強度180~330MPa、拉伸斷裂伸長率80~180%者。其中,可合適地使用拉伸強度或拉伸斷裂伸長率之MD/TD之比係0.8~1.2之範圍的薄膜(30)。 More preferably, the coated material (3) which is laminated on the outer surface of the outer surface of the small electronic machine casing (the bottom surface of Fig. 1(b)) on both sides of the aluminum alloy rolled sheet (2) is made of a polyester resin having a thickness of 50 to 100 μm. A film or a polyimide film is further preferably a polyethylene-terephthalate resin film (PET) and a 2-axis extended polyethylene naphthalene resin film (PEN) having a thickness of 50 to 100 μm. ) or a 2-axis extended 6-nylon resin film (ONy) (30). As the film (30), a tensile strength of 180 to 330 MPa and a tensile elongation at break of 80 to 180% can be suitably used. Among them, a film (30) having a ratio of MD/TD of tensile strength or tensile elongation at break in the range of 0.8 to 1.2 can be suitably used.

此外,鋁合金壓延板材(2)之兩面中成為小型電子機器外殼之內面的面(圖1(b)係上面)所積層之被覆材(4),由厚度10~100μm(更佳係20~80μm)之聚乙烯樹脂薄膜、聚丙烯樹脂薄膜或聚醯胺樹脂薄膜構成為佳,更佳係,由未延伸聚乙烯樹脂薄膜、未延伸聚丙烯樹脂薄膜(CPP)、延伸聚丙烯樹脂薄膜(OPP)、或延伸尼龍樹脂薄膜(ONy)(40)構成。上述之薄膜(40),可合適地使用楊氏模量係30~400MPa者。 Further, the coated material (4) which is a layer of the inner surface of the outer surface of the small electronic device (the upper surface of Fig. 1(b)) on both sides of the aluminum alloy rolled sheet (2) has a thickness of 10 to 100 μm (more preferably 20) Preferably, a polyethylene resin film, a polypropylene resin film or a polyamide resin film of ~80 μm) is preferably, more preferably, an unstretched polyethylene resin film, an unstretched polypropylene resin film (CPP), an extended polypropylene resin film. (OPP) or an extended nylon resin film (ONy) (40). As the film (40) described above, a Young's modulus system of 30 to 400 MPa can be suitably used.

又,被覆材,雖在鋁合金壓延板材(2)之兩面中至少一側的面,更詳細係在構成外殼之外面的面積層即可,惟根據成形性的提升或成形時.成形後之外殼表面的保護之觀點,係如圖1,在鋁合金壓延板材(2)之兩面積層為佳。 Further, the covering material may be formed on at least one of the surfaces of the aluminum alloy rolled sheet (2) in more detail, and may be formed in an area layer constituting the outer surface of the outer casing, depending on the formability or the forming. The viewpoint of the protection of the surface of the outer casing after forming is as shown in Fig. 1, and it is preferable to form two layers of the aluminum alloy rolled sheet (2).

在鋁合金壓延板材(2)之兩面積層被覆材時,各面所積層之2個被覆材可係相同者,亦可互相係不同材料/厚度者。 When the two-layer coating material of the aluminum alloy rolled sheet (2) is coated, the two covering materials stacked on each surface may be the same or different materials/thickness.

又,鋁合金壓延板材(2)之彎折強度較小時或厚度較小時,被覆材係使 用合成樹脂薄膜(30)(40)即可(圖1(b)參照),鋁合金壓延板材(2)之彎折強度較大時或厚度較大時,若被覆材係使用合成樹脂薄膜,因有絞伸加工時破裂而成形品之表面產生皺摺之虞,故被覆材係以積層體(3)(4)構成(圖1(a)參照)為佳。 Moreover, when the bending strength of the aluminum alloy rolled sheet (2) is small or the thickness is small, the covering material is made When the synthetic resin film (30) (40) is used (refer to Fig. 1 (b)), when the bending strength of the aluminum alloy rolled sheet (2) is large or the thickness is large, if the coated material is a synthetic resin film, Since the surface of the molded article is wrinkled by cracking during the stretching process, the covering material is preferably composed of the laminated body (3) (4) (refer to Fig. 1 (a)).

對於鋁合金壓延板材(2)之面進行被覆材(3)(4)的積層,考慮到必須在外殼成形後將被覆材(3)(4)從表面去除,故如圖1所示,係介由黏著劑層(34)(44)進行為佳。黏著劑層(34)(44),例如,可使用胺基甲酸乙酯系黏著劑、丙烯酸系黏著劑、橡膠系黏著劑。對於鋁合金壓延板材(2)之黏著劑層(34)(44)的黏著力,較佳係0.5~15N/25mm(進一步較佳係1~10N/25mm)。在此,「黏著力」,係藉由以JIS Z 0237:2000為基準之180°剝離黏著力而表示者。黏著劑層(34)(44)之黏著力未達0.5N/25mm的話,於處裡外殼成形前之鋁合金壓延積層板材(1)時,會有一不注意即將被覆材(3)(4)從鋁合金壓延板材(2)剝離,另一方面,黏著劑層(34)(44)之黏著力超過15N/25mm的話,除了會降低外殼成形後將被覆材(3)(4)剝離去除時之作業性之外,因黏著劑之一部分殘留於外殼之表面而導致後步驟之研磨等產生問題。 For the lamination of the covering material (3) (4) on the surface of the aluminum alloy rolled sheet (2), it is necessary to remove the covering material (3) (4) from the surface after the outer casing is formed, as shown in Fig. 1, It is preferred to carry out the adhesive layer (34) (44). As the adhesive layer (34) (44), for example, an urethane-based adhesive, an acrylic adhesive, or a rubber-based adhesive can be used. The adhesion of the adhesive layer (34) (44) of the aluminum alloy rolled sheet (2) is preferably 0.5 to 15 N/25 mm (further preferably 1 to 10 N/25 mm). Here, the "adhesion" is represented by a 180° peeling adhesion based on JIS Z 0237:2000. If the adhesive force of the adhesive layer (34) (44) is less than 0.5N/25mm, there will be an unintentional coating (3) when the aluminum alloy rolled laminated sheet (1) before the outer shell is formed. ) peeling from the aluminum alloy rolled sheet (2), on the other hand, if the adhesive force of the adhesive layer (34) (44) exceeds 15 N/25 mm, the peeling material (3) (4) is peeled off after the outer shell is formed. In addition to the workability at the time, a part of the adhesive remains on the surface of the outer casing, causing problems such as grinding of the subsequent step.

被覆材(3)(4)之厚度,較佳係鋁合金壓延板材(2)之厚度的0.05~1.5倍,更佳係同厚度之0.2~1.0倍。 The thickness of the covering material (3) (4) is preferably 0.05 to 1.5 times the thickness of the aluminum alloy rolled sheet (2), more preferably 0.2 to 1.0 times the same thickness.

圖2,係表示對於上述鋁合金壓延積層板材(1)進行絞伸加工,成形為小型電子機器外殼之步驟者。 Fig. 2 is a view showing a step of forming a small-sized electronic machine casing by subjecting the aluminum alloy rolled laminated sheet material (1) to a drawing process.

首先,將裁切為所定尺寸之略方形狀之鋁合金壓延積層板材(1),與模具下側之固定雌型(沖模)(5)的上面組合(參照圖2(a))。在此,鋁合 金壓延積層板材(1)之上下兩面中,至少成為外殼之外側之下面,亦即,下側之被覆材(3)之表面,例如,塗佈矽氧系潤滑劑、礦油、或合成石油系潤滑劑所成潤滑劑為佳,藉此可進一步提高成形性。 First, the aluminum alloy rolled laminated plate material (1) cut into a rectangular shape of a predetermined size is combined with the upper surface of the fixed female (die) (5) on the lower side of the mold (see Fig. 2(a)). Here, aluminum alloy The upper and lower surfaces of the gold rolled laminate sheet (1) are at least the outer side of the outer side of the outer casing, that is, the surface of the underlying cladding material (3), for example, coated with a bismuth-based lubricant, mineral oil, or synthetic petroleum. It is preferred to form a lubricant by a lubricant, whereby the formability can be further improved.

並且,將模具之上側的可動雄型(沖床)(6)降下時,鋁合金壓延積層板材(1)中周緣部除外之部分受到雄型(6)之先端部向下加壓,藉此同周緣部之直線部分向上彎折,且同周緣部之角落部分絞伸成形(參照圖2(b))。此時,鋁合金壓延板材(2),由於其兩面由被覆材(3)(4)被覆,故可抑制皺褶產生,其結果,亦不會發生破裂。此外,鋁合金壓延板材(2)之表面,由於並未直接接觸雌型(5)及雄型(6),故不會因摩擦而損傷。 Further, when the movable male type (punch) (6) on the upper side of the mold is lowered, the portion excluding the peripheral portion of the aluminum alloy rolled laminated board (1) is pressed downward by the tip end portion of the male type (6). The straight portion of the peripheral portion is bent upward and is formed by the corner portion of the peripheral portion (see Fig. 2(b)). At this time, since the aluminum alloy rolled sheet (2) is coated on both sides by the covering material (3) (4), generation of wrinkles can be suppressed, and as a result, cracking does not occur. In addition, since the surface of the aluminum alloy rolled sheet (2) is not directly in contact with the female (5) and male (6), it is not damaged by friction.

因此,得到附被覆材(3)(4)小型電子機器外殼(20)。小型電子機器外殼(20)之表面,由於被覆有被覆材(3)(4),故在例如保管時或搬運時不會因與其他之物接觸而損傷,從而保持美麗狀態。 Therefore, a small electronic machine casing (20) with a covering material (3) (4) is obtained. Since the surface of the small electronic device casing (20) is covered with the covering material (3) (4), it is not damaged by contact with other objects during storage or transportation, for example, and is maintained in a beautiful state.

圖3,係表示小型電子機器外殼(20)者。此外殼(20),係從上述之附被覆材(3)(4)小型電子機器外殼(20)之內外兩面將被覆材(3)(4)剝離去除後,施予部分性切削加工完成成形,並進一步藉由對於表面進行陽極氧化處理而得者。 Figure 3 shows a small electronic machine housing (20). The outer casing (20) is peeled off from the inner and outer surfaces of the small electronic machine casing (20) of the above-mentioned attached covering material (3) (4), and then subjected to partial cutting to complete forming. And further obtained by anodizing the surface.

小型電子機器外殼(20),其係由:從平面觀察時為略方形之底壁(21)、及由底壁(21)之4邊個別站立之4個側壁(22)所構成。相鄰側壁(22)之端部彼此連接,藉由4個側壁(22)圍繞底壁(21)。 The small electronic machine casing (20) is composed of a bottom wall (21) which is slightly square when viewed from a plane, and four side walls (22) which are individually stood by four sides of the bottom wall (21). The ends of adjacent side walls (22) are connected to each other, and the bottom wall (21) is surrounded by four side walls (22).

側壁(22)之高度(換言之,成形高度)係0.5~25mm,較佳係1~15mm,進一步較佳係2~10mm。 The height of the side wall (22) (in other words, the forming height) is 0.5 to 25 mm, preferably 1 to 15 mm, and more preferably 2 to 10 mm.

相對於底壁(21),側壁(22)之角度係90~150°(圖示為約90°), 較佳係90~120°,進一步較佳係90~100°。 The angle of the side wall (22) is 90 to 150° with respect to the bottom wall (21) (the figure is about 90°). It is preferably 90 to 120°, more preferably 90 to 100°.

底壁(21)與側壁(22)之境界部附有曲徑,此外,側壁(22)之角落部(22a)亦附有曲徑。此等曲徑部分中,纖維狀之結晶組織係沿著曲徑延伸。 A curved path is attached to the boundary portion between the bottom wall (21) and the side wall (22), and a corner portion (22a) of the side wall (22) is also attached with a labyrinth. In these labyrinth portions, the fibrous crystal structure extends along the labyrinth.

纖維狀結晶組織,可藉由使用偏光顯微鏡觀察:將鋁合金壓延板材(2),抑或鋁合金壓延板材(2)絞伸成形之外殼(20)的斷面,從而確認。 The fibrous crystal structure can be confirmed by using a polarizing microscope: a section of the aluminum alloy rolled sheet (2) or the aluminum alloy rolled sheet (2) which is formed by the stranded outer casing (20).

較佳係,纖維狀結晶組織,可在相對於鋁合金壓延板材之壓延方向,從0°、90°、45°、135°等之任意方向切斷所得斷面中觀察。折疊部或角落部中亦可同樣地觀察。 Preferably, the fibrous crystal structure can be observed in the cross section cut from any direction such as 0°, 90°, 45°, or 135° with respect to the rolling direction of the aluminum alloy rolled sheet. The same can be observed in the folded portion or the corner portion.

具體而言,例如,如圖4(a)(b)所示,將厚度0.25mm之鋁合金壓延板材(2),彎折加工為內曲徑係0mm或0.4mm,關於此等彎折材,使用偏光顯微鏡觀察:相對於壓延方向(X)係從90°(直角)或0°(平行)之方向(Y)切斷所得斷面。如此一來,由圖5~8之顯微鏡相片可知,內曲徑:0mm、相對於壓延方向之斷面方向:90°(圖5)、內曲徑:0.4mm、相對於壓延方向之斷面方向:90°(圖6)、內曲徑:0mm、相對於壓延方向之斷面方向:0°(圖7)、內曲徑:0.4mm、相對於壓延方向之斷面方向:0°(圖8)中之任一斷面,纖維狀之結晶組織皆沿著曲徑,在與板材之厚度方向直交之方向延伸。 Specifically, for example, as shown in Fig. 4 (a) and (b), the aluminum alloy rolled sheet (2) having a thickness of 0.25 mm is bent and processed into an inner labyrinth of 0 mm or 0.4 mm, with respect to such a bend. The folded material was observed using a polarizing microscope: the obtained cross section was cut from the direction (Y) of 90 (right angle) or 0 (parallel) with respect to the rolling direction (X). In this way, from the micrographs of Figures 5-8, the inner labyrinth: 0 mm, the cross-sectional direction with respect to the rolling direction: 90° (Fig. 5), the inner labyrinth: 0.4 mm, and the fracture direction with respect to the rolling direction. Surface direction: 90° (Fig. 6), internal meander diameter: 0 mm, cross-sectional direction with respect to the rolling direction: 0° (Fig. 7), internal meander diameter: 0.4 mm, cross-sectional direction with respect to the rolling direction: 0 In any of the sections (Fig. 8), the fibrous crystal structure extends along the labyrinth in a direction orthogonal to the thickness direction of the sheet.

【實施例】[Examples]

接著,說明本發明之具體實施例。但,本發明並非係限定為此等實施例者。 Next, specific embodiments of the present invention will be described. However, the invention is not limited to the embodiments.

<實施例1> <Example 1>

將含有Si:0.2~0.6質量%、Mg:0.45~0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下,且由殘部Al及不可避雜質所成之鋁合金鑄塊以580℃、10小時進行均質化處理後切削表面,以500℃進行予備加熱,開始熱間壓延。熱間壓延之最終路徑開始溫度為400℃,路徑後,以80℃/分之速度冷卻。之後,以240℃、4小時之條件進行熱處理。之後,以86%之壓下率進行冷間壓延。藉此,得到0.2%耐力為310MPa、斷裂伸長率為7%的厚度1mm之鋁合金壓延板材。 Si: 0.2 to 0.6% by mass, Mg: 0.45 to 0.9% by mass, Fe: 0.35% by mass or less, Cr: 0.1% by mass or less, and Zn: 0.1% by mass The aluminum alloy ingot formed of the residue Al and the unavoidable impurities was homogenized at 580 ° C for 10 hours, and the surface was cut, and preheated at 500 ° C to start the inter-heat rolling. The final path start temperature of the inter-heat rolling was 400 ° C, and after the path, it was cooled at a rate of 80 ° C / min. Thereafter, heat treatment was performed at 240 ° C for 4 hours. Thereafter, cold rolling was performed at a reduction ratio of 86%. Thereby, an aluminum alloy rolled sheet having a thickness of 1 mm with a 0.2% proof endurance of 310 MPa and a breaking elongation of 7% was obtained.

上述板材之斷面,藉由光學顯微鏡及偏光鏡片觀察,可發現在與厚度方向直交之方向延伸的纖維狀之結晶組織。 The cross section of the above-mentioned sheet material was observed by an optical microscope and a polarizing lens to find a fibrous crystal structure extending in a direction orthogonal to the thickness direction.

並且,構成小型電子機器外殼之外面的鋁合金壓延板材之下面,係介由丙烯酸系黏著劑所成黏著劑層與被覆材積層,且前述被覆材係厚度120μm之鋁箔的單面介由聚酯胺基甲酸乙酯樹脂及六亞甲基二異氰酸酯所成接著劑層與厚度30μm之未延伸聚丙烯樹脂薄膜積層,同時另一面藉由接著劑層與厚度200μm之未延伸聚丙烯樹脂薄膜積層所成積層體。 Further, the underside of the aluminum alloy rolled sheet constituting the outer surface of the small electronic device casing is laminated with an adhesive layer formed of an acrylic adhesive, and the coated material is a single side of the aluminum foil having a thickness of 120 μm. The adhesive layer of the urethane resin and hexamethylene diisocyanate is laminated with the unstretched polypropylene resin film having a thickness of 30 μm, and the other side is laminated with the unstretched polypropylene resin film having a thickness of 200 μm by the adhesive layer. A layered body.

此外,構成小型電子機器外殼之內面的鋁合金壓延板材之上面,係介由丙烯酸系黏著劑所成黏著劑層與被覆材積層,且前述被覆材係厚度30μm之尼龍樹脂薄膜。 Further, the upper surface of the aluminum alloy rolled sheet constituting the inner surface of the outer casing of the small electronic device was laminated with an adhesive layer formed of an acrylic adhesive, and the coated material was a nylon resin film having a thickness of 30 μm.

將藉此所得之鋁合金壓延積層板材,裁切為縱150mm、橫82mm、角落部曲徑14.5mm之略方形狀,從而製作實施例1之成形材料。 The aluminum alloy rolled laminated sheet obtained therefrom was cut into a rectangular shape of 150 mm in length, 82 mm in width, and a tortuous diameter of 14.5 mm in the corner portion to prepare a molding material of Example 1.

<實施例2> <Example 2>

含有Si:0.4質量%以下、Mn:0.4~0.6質量%、Mg: 4.0~4.9質量%、Fe:0.4質量%以下、Cr:0.05~0.25質量%、Zn:0.25質量%以下,且由殘部Al及不可避雜質所成之鋁合金鑄塊以580℃、10小時進行均質化處理後切削表面,以500℃進行予備加熱,開始熱間壓延。熱間壓延之最終路徑開始溫度為400℃,路徑後,以80℃/分之速度冷卻。之後,以240℃、4小時之條件進行熱處理。之後,以79%之壓下率進行冷間壓延後,最終燒鈍130℃、4小時。藉此,得到0.2%耐力為210MPa、斷裂伸長率為7%的厚度1.5mm之鋁合金壓延板材。 Si: 0.4% by mass or less, Mn: 0.4 to 0.6% by mass, Mg: 4.0 to 4.9 mass%, Fe: 0.4 mass% or less, Cr: 0.05 to 0.25 mass%, Zn: 0.25 mass% or less, and formed of residual portion Al and unavoidable impurities The aluminum alloy ingot was homogenized at 580 ° C for 10 hours, and the surface was cut, and preheated at 500 ° C to start the inter-heat rolling. The final path start temperature of the inter-heat rolling was 400 ° C, and after the path, it was cooled at a rate of 80 ° C / min. Thereafter, heat treatment was performed at 240 ° C for 4 hours. Thereafter, the mixture was subjected to cold rolling at a reduction ratio of 79%, and finally blunt at 130 ° C for 4 hours. Thereby, an aluminum alloy rolled sheet having a thickness of 1.5 mm and a breaking elongation of 7% of 0.2% was obtained.

上述板材之斷面,藉由光學顯微鏡及偏光鏡片觀察,可發現在與厚度方向直交之方向延伸的纖維狀之結晶組織。 The cross section of the above-mentioned sheet material was observed by an optical microscope and a polarizing lens to find a fibrous crystal structure extending in a direction orthogonal to the thickness direction.

並且,鋁合金壓延板材之上下兩面,係介由丙烯酸系黏著劑所成黏著劑層個別與被覆材積層,且前述被覆材係厚度90μm之尼龍樹脂薄膜。 Further, the upper and lower surfaces of the aluminum alloy rolled sheet were laminated with the covering material by an adhesive layer formed of an acrylic adhesive, and the covering material was a nylon resin film having a thickness of 90 μm.

將藉此所得之鋁合金壓延積層板材,裁切為縱150mm、橫82mm、角落部曲徑14.5mm之略方形狀,從而製作實施例2之成形材料。 The aluminum alloy rolled laminated sheet obtained therefrom was cut into a rectangular shape of 150 mm in length, 82 mm in width, and a tortuous diameter of 14.5 mm in the corner portion to prepare a molding material of Example 2.

<實施例3> <Example 3>

含有Si:0.4質量%以下、Mg:2.1~2.9質量%、Fe:0.5質量%以下、Cu:1.2~2.0質量%、Mn:0.3質量%以下、Cr:0.18~0.28質量%、Zn:5.1~6.1質量%,且由殘部Al及不可避雜質所成鋁合金鑄塊,藉由與實施例2相同之步驟.條件進行壓延,得到0.2%耐力為550MPa、斷裂伸長率為9%的厚度1.5mm之鋁合金壓延板材。 Si: 0.4% by mass or less, Mg: 2.1 to 2.9% by mass, Fe: 0.5% by mass or less, Cu: 1.2 to 2.0% by mass, and Mn: 0.3% by mass Hereinafter, Cr: 0.18 to 0.28 mass%, Zn: 5.1 to 6.1 mass%, and an aluminum alloy ingot formed by the residual portion Al and the unavoidable impurities, by the same procedure as in the second embodiment. The condition was rolled to obtain an aluminum alloy rolled sheet having a thickness of 1.5 mm and a fracture elongation of 9% of 0.2%.

上述板材之斷面,藉由光學顯微鏡及偏光鏡片觀察,可發現在與厚度 方向直交之方向延伸的纖維狀之結晶組織。 The cross section of the above-mentioned plate can be found in the thickness and thickness by observation with an optical microscope and a polarizing lens. A fibrous crystal structure extending in a direction orthogonal to the direction.

並且,構成小型電子機器外殼之外面的鋁合金壓延板材之下面,係介由丙烯酸系黏著劑所成黏著劑層與被覆材積層,且前述被覆材係厚度90μm之尼龍樹脂薄膜。 Further, the underside of the aluminum alloy rolled sheet which constitutes the outer surface of the outer casing of the small electronic device is laminated with an adhesive layer formed of an acrylic adhesive, and the coated material is a nylon resin film having a thickness of 90 μm.

將藉此所得之鋁合金壓延積層板材,裁切為縱150mm、橫82mm、角落部曲徑14.5mm之略方形狀,從而製作實施例3之成形材料。 The aluminum alloy rolled laminated sheet obtained therefrom was cut into a rectangular shape of 150 mm in length, 82 mm in width, and a tortuous diameter of 14.5 mm in the corner portion to prepare a molding material of Example 3.

<實施例4> <Example 4>

準備與實施例1相同之鋁合金壓延板材。 An aluminum alloy rolled sheet similar to that of Example 1 was prepared.

並且,構成小型電子機器外殼之外面的鋁合金壓延板材之下面,係介由丙烯酸系黏著劑所成黏著劑層與被覆材積層,且前述被覆材係厚度90μm之尼龍樹脂薄膜。 Further, the underside of the aluminum alloy rolled sheet which constitutes the outer surface of the outer casing of the small electronic device is laminated with an adhesive layer formed of an acrylic adhesive, and the coated material is a nylon resin film having a thickness of 90 μm.

將藉此所得之鋁合金壓延積層板材,裁切為縱150mm、橫82mm、角落部曲徑14.5mm之略方形狀,從而製作實施例4之成形材料。 The aluminum alloy rolled laminated sheet obtained therefrom was cut into a rectangular shape of 150 mm in length, 82 mm in width, and a tortuous diameter of 14.5 mm in the corner portion to prepare a molding material of Example 4.

<比較例1> <Comparative Example 1>

準備含有Si:0.4質量%以下、Mn:0.4~1.0質量%、Mg:4.0~4.9質量%、Fe:0.4質量%以下、Cr:0.05~0.25質量%、Zn:0.25質量%以下,且由殘部Al及不可避雜質所成鋁合金而成,0.2%耐力為230MPa、斷裂伸長率為14%的厚度2mm之鋁合金押出板材。板材,係押出成形者,不具在與厚度方向直交之方向延伸的纖維狀之結晶組織。 Preparation: Si: 0.4% by mass or less, Mn: 0.4 to 1.0% by mass, Mg: 4.0 to 4.9% by mass, Fe: 0.4% by mass or less, Cr: 0.05% 0.25 mass%, Zn: 0.25 mass% or less, and an aluminum alloy formed of a residual portion Al and an unavoidable impurity, and an aluminum alloy having a thickness of 230 mm and a tensile elongation of 14% and a thickness of 2 mm are extruded. Plate. The sheet material is extruded into a molded body and does not have a fibrous crystal structure extending in a direction orthogonal to the thickness direction.

並且,鋁合金押出板材之上下兩面,係介由丙烯酸系黏著劑所成黏著劑層個別與被覆材積層,且前述被覆材係厚度90μm之尼龍樹脂薄膜。 Further, the aluminum alloy was extruded on the lower surface of the sheet material, and the adhesive layer formed of the acrylic adhesive was separately laminated with the covering material, and the covering material was a nylon resin film having a thickness of 90 μm.

將藉此所得之鋁合金押出積層板材,裁切為縱150mm、橫82mm、角落部曲徑14.5mm之略方形狀,從而製作比較例1之成形材料。 The aluminum alloy thus obtained is extruded from the laminated board The molding material of Comparative Example 1 was produced by cutting into a rectangular shape of 150 mm in length, 82 mm in width, and 14.5 mm in corner corner.

<比較例2> <Comparative Example 2>

準備含有Si:0.4質量%以下、Mg:2.1~2.9質量%、Fe:0.5質量%以下、Cu:1.2~2.0質量%、Mn:0.3質量%以下、Cr:0.18~0.28質量%、Zn:5.1~6.1質量%,且由殘部Al及不可避雜質所成鋁合金而成,0.2%耐力為510MPa、斷裂伸長率為11%的厚度1.5mm之鋁合金押出板材。板材,係押出成形者,不具在與厚度方向直交之方向延伸的纖維狀之結晶組織。 Preparation: Si: 0.4% by mass or less, Mg: 2.1 to 2.9% by mass, Fe: 0.5% by mass or less, Cu: 1.2 to 2.0% by mass, Mn: 0.3 mass % or less, Cr: 0.18 to 0.28 mass%, Zn: 5.1 to 6.1 mass%, and the aluminum alloy formed by the residual portion Al and the unavoidable impurities, the 0.2% proof stress is 510 MPa, and the fracture is 510 MPa. An aluminum alloy having an elongation of 11% and a thickness of 1.5 mm was extruded. The sheet material is extruded into a molded body and does not have a fibrous crystal structure extending in a direction orthogonal to the thickness direction.

並且,將此鋁合金押出板材裁剪為縱150mm、橫82mm、角落部曲徑14.5mm之略方形狀,從而製作比較例2之成形材料。 Further, the aluminum alloy extruded sheet was cut into a rectangular shape of 150 mm in length, 82 mm in width, and a tortuous diameter of 14.5 mm in the corner portion to prepare a molding material of Comparative Example 2.

<比較例3> <Comparative Example 3>

含有Si:0.2~0.6質量%、Mg:0.45~0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下,且由殘部Al及不可避雜質所成之鋁合金鑄塊以580℃、10小時進行均質化處理後切削表面,以500℃進行予備加熱,開始熱間壓延。熱間壓延之最終路徑開始溫度為400℃,路徑後,以80℃/分之速度冷卻。之後,以240℃、4小時之條件進行熱處理。之後,以57%之壓下率進行冷間壓延後,熱處理250℃、2小時。藉此,得到0.2%耐力為150MPa、斷裂伸長率為14%的厚度3mm之鋁合金壓 延板材。板材,係在冷間壓延中進行自然時効處理者,不具在與厚度方向直交之方向延伸的纖維狀之結晶組織。 Si: 0.2 to 0.6% by mass, Mg: 0.45 to 0.9% by mass, Fe: 0.35% by mass or less, Cr: 0.1% by mass or less, and Zn: 0.1% by mass In the following, the aluminum alloy ingot made of the residue Al and the unavoidable impurities was homogenized at 580 ° C for 10 hours, and then the surface was cut, and preheated at 500 ° C to start the inter-heat rolling. The final path start temperature of the inter-heat rolling was 400 ° C, and after the path, it was cooled at a rate of 80 ° C / min. Thereafter, heat treatment was performed at 240 ° C for 4 hours. Thereafter, the mixture was subjected to cold rolling at a reduction ratio of 57%, and then heat-treated at 250 ° C for 2 hours. Thereby, an aluminum alloy pressure having a thickness of 3 mm with a 0.2% proof endurance of 150 MPa and an elongation at break of 14% was obtained. Extend the sheet. The sheet material is subjected to natural aging treatment in cold rolling, and does not have a fibrous crystal structure extending in a direction orthogonal to the thickness direction.

並且,在鋁合金壓延板材之上下兩面,係介由丙烯酸系黏著劑所成黏著劑層個別與被覆材積層,且前述被覆材係厚度30μm之尼龍樹脂薄膜。 Further, on the lower surface of the aluminum alloy rolled sheet, the adhesive layer formed of the acrylic adhesive was separately laminated with the covering material, and the covering material was a nylon resin film having a thickness of 30 μm.

將藉此所得鋁合金壓延積層板材,裁切為縱150mm、橫82mm、角落部曲徑14.5mm之略方形狀,從而製作比較例3之成形材料。 The aluminum alloy rolled laminated sheet obtained therefrom was cut into a rectangular shape of 150 mm in length, 82 mm in width, and a tortuous diameter of 14.5 mm in the corner portion to prepare a molding material of Comparative Example 3.

<比較例4> <Comparative Example 4>

準備含有Si:0.2~0.6質量%、Mg:0.45~0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下,且由殘部Al及不可避雜質所成鋁合金而成,0.2%耐力為145MPa、斷裂伸長率為12%的厚度2mm之鋁合金壓延板材。板材,係將押出板材進行冷間壓延(壓下率33%)者,不具在與厚度方向直交之方向延伸的纖維狀之結晶組織。 Preparation: Si: 0.2 to 0.6% by mass, Mg: 0.45 to 0.9% by mass, Fe: 0.35% by mass or less, Cr: 0.1% by mass or less, Zn: 0.1 mass An aluminum alloy rolled sheet having a thickness of 2 mm with a 0.2% proof endurance of 145 MPa and a breaking elongation of 12%, which is made of an aluminum alloy having a residual portion of Al and an unavoidable impurity. For the sheet, the sheet is pressed for cold rolling (33% reduction), and there is no fibrous crystal structure extending in the direction orthogonal to the thickness direction.

並且,在鋁合金壓延板材之上下兩面,係介由丙烯酸系黏著劑所成黏著劑層個別與被覆材積層,且前述被覆材係厚度30μm之尼龍樹脂薄膜。 Further, on the lower surface of the aluminum alloy rolled sheet, the adhesive layer formed of the acrylic adhesive was separately laminated with the covering material, and the covering material was a nylon resin film having a thickness of 30 μm.

將藉此所得鋁合金壓延積層板材,裁切為縱150mm、橫82mm、角落部曲徑14.5mm之略方形狀,從而製作比較例4之成形材料。 The aluminum alloy rolled laminated sheet obtained therefrom was cut into a rectangular shape of 150 mm in length, 82 mm in width, and a tortuous diameter of 14.5 mm in the corner portion to prepare a molding material of Comparative Example 4.

<小型電子機器外殼之成形> <Formation of small electronic machine casing>

實施例1~4及比較例1~4之成形材料,係藉由使用圖2所示之絞伸加工裝置進行絞伸加工,從而成形為縱140.5mm、橫70.5mm、側壁高度(成形高度)7mm、側壁角落部曲徑2mm之小型電子機器外殼。相對於底壁,側壁之角度為90°。 The molding materials of Examples 1 to 4 and Comparative Examples 1 to 4 were subjected to a drawing process by using a stretching apparatus shown in Fig. 2, and were formed into a longitudinal direction of 140.5 mm, a width of 70.5 mm, and a side wall height (forming). A small electronic machine case with a height of 7 mm and a corner diameter of 2 mm at the corner of the side wall. The angle of the side wall is 90° with respect to the bottom wall.

以肉眼觀察成形之各外殼,關於實施例1~4之成形材料所成者,在側壁之角落部未產生皺摺或裂痕,此外,側壁之外面,並未發現與下模接觸所產生之傷痕。 The molded outer casings were observed with the naked eye. The molded materials of Examples 1 to 4 were free from wrinkles or cracks in the corner portions of the side walls, and the outer surfaces of the side walls were not found to be in contact with the lower mold. .

另一方面,關於比較例1~4之成形材料所成外殼,其側壁之角落部產生有皺摺或裂痕。此外,以比較例1,3,4之成形材料所成外殼時,雖未發現其等之側壁外面有傷痕,但比較例2所成外殼之側壁外面,形成有與下模接觸導致之傷痕。 On the other hand, in the outer casing of the molding materials of Comparative Examples 1 to 4, wrinkles or cracks were formed in the corner portions of the side walls. Further, when the molded materials of Comparative Examples 1, 3, and 4 were formed into a casing, the outer side walls of the casings were not found to have scratches, but the outer surface of the outer casing of Comparative Example 2 was formed with a flaw caused by contact with the lower mold.

【產業上利用可能性】[Industrial use possibility]

本發明,可合適地利用於成形平板電腦終端、攜帶通訊終端機器、筆記型電腦、攜帶電話、攜帶音樂機器、數位相機等之小型電子機器的外殼。 The present invention can be suitably utilized for housings of a tablet computer terminal, a portable terminal device, a notebook computer, a mobile phone, a portable electronic device, a digital camera, and the like.

(1)‧‧‧鋁合金壓延積層板材 (1)‧‧‧Aluminum rolled laminated sheets

(2)‧‧‧鋁合金壓延板材 (2)‧‧‧Aluminum alloy rolled sheet

(3)(4)‧‧‧被覆材 (3) (4) ‧‧‧ Covering materials

(5)‧‧‧固定雌型 (5) ‧ ‧ fixed female

(6)‧‧‧可動雄型 (6) ‧‧‧ movable male

(20)‧‧‧小型電子機器外殼 (20)‧‧‧Small electronic machine housing

Claims (13)

一種小型電子機器外殼用鋁合金壓延積層板材,其係藉由絞伸加工而成形為小型電子機器外殼之鋁合金壓延積層板材,其特徵係由鋁合金壓延板材及被覆材所構成,前述鋁合金壓延板材係0.2%耐力為200MPa以上;前述被覆材係積層於鋁合金壓延板材之兩面中至少一側的面;且被覆材係由合成樹脂薄膜、及在金屬箔之兩面積層合成樹脂薄膜之積層體中至少一者所成者。 An aluminum alloy calendered laminated board for a small electronic machine casing, which is formed by a stranding process and formed into an aluminum alloy rolled laminated board of a small electronic machine casing, characterized in that the aluminum alloy rolled sheet and the covering material are composed of the aluminum alloy The rolled sheet has a 0.2% proof stress of 200 MPa or more; the coated material is laminated on at least one of the two faces of the aluminum alloy rolled sheet; and the coated material is a synthetic resin film and a synthetic resin film on the two-layer layer of the metal foil. At least one of the laminates is formed. 如申請專利範圍第1項所記載之小型電子機器外殼用鋁合金壓延積層板材,其中,鋁合金壓延板材,係具有從與厚方向直交之方向延伸之纖維狀之結晶組織。 The aluminum alloy rolled laminated board for a small electronic device casing according to the first aspect of the invention, wherein the aluminum alloy rolled sheet has a fibrous crystal structure extending from a direction orthogonal to the thickness direction. 如申請專利範圍第1項所記載之小型電子機器外殼用鋁合金壓延積層板材,其中,鋁合金壓延板材,係由:Al-Mn-Mg系合金、Al-Si-Mg系合金、及Al-Zn-Mg系合金中任一者之鋁合金所成;且Al-Mn-Mg系合金,係含有Mn:0.2~0.7質量%、Mg:2.0~5.0質量%,並由殘部Al及不可避雜質所成;Al-Si-Mg系合金,係含有Si:0.2~0.8質量%、Mg:0.4~1.2質量%,並由殘部Al及不可避雜質所成;Al-Zn-Mg系合金,係含有Zn:4.0~6.5質量%、Mg:0.5~3.0質量%,並由殘部Al及不可避雜質所成。 The aluminum alloy rolled laminated board for a small electronic machine casing according to the first aspect of the patent application, wherein the aluminum alloy rolled sheet is made of an Al-Mn-Mg alloy, an Al-Si-Mg alloy, and an Al- The aluminum alloy of any one of the Zn-Mg alloys; and the Al-Mn-Mg alloy contains Mn: 0.2 to 0.7% by mass, and Mg: 2.0 to 5.0% by mass. It is composed of the residue Al and the unavoidable impurities; the Al-Si-Mg alloy contains Si: 0.2 to 0.8% by mass, Mg: 0.4 to 1.2% by mass, and is inevitably left by the residue Al and The Al-Zn-Mg-based alloy contains Zn: 4.0 to 6.5 mass%, Mg: 0.5 to 3.0 mass%, and is formed of the residue Al and the unavoidable impurities. 如申請專利範圍第2項所記載之小型電子機器外殼用鋁合金壓延 積層板材,其中,鋁合金壓延板材,係由:Al-Mn-Mg系合金、Al-Si-Mg系合金、及Al-Zn-Mg系合金中任一者之鋁合金所成;且Al-Mn-Mg系合金,係含有Mn:0.2~0.7質量%、Mg:2.0~5.0質量%,並由殘部Al及不可避雜質所成;Al-Si-Mg系合金,係含有Si:0.2~0.8質量%、Mg:0.4~1.2質量%,並由殘部Al及不可避雜質所成;Al-Zn-Mg系合金,係含有Zn:4.0~6.5質量%、Mg:0.5~3.0質量%,並由殘部Al及不可避雜質所成。 Aluminum alloy rolling for small electronic machine casing as described in item 2 of the patent application scope a laminated board, wherein the aluminum alloy rolled sheet is made of an aluminum alloy of any one of an Al-Mn-Mg alloy, an Al-Si-Mg alloy, and an Al-Zn-Mg alloy; and Al- The Mn-Mg alloy contains Mn: 0.2 to 0.7% by mass, Mg: 2.0 to 5.0% by mass, and is formed of residual Al and unavoidable impurities; and Al-Si-Mg alloy, It contains Si: 0.2-0.8 mass%, Mg: 0.4-1.2 mass%, and is formed by residual Al and unavoidable impurities; Al-Zn-Mg alloy contains Zn: 4. 0 to 6.5% by mass, Mg: 0.5 to 3.0% by mass, and formed by the residue Al and the unavoidable impurities. 如申請專利範圍第1項所記載之小型電子機器外殼用鋁合金壓延積層板材,其中,被覆材之厚度,係鋁合金壓延板材之厚度的0.05~1.5倍。 The aluminum alloy rolled laminated board for a small electronic device casing according to the first aspect of the invention, wherein the thickness of the covering material is 0.05 to 1.5 times the thickness of the aluminum alloy rolled sheet. 如申請專利範圍第1項所記載之小型電子機器外殼用鋁合金壓延積層板材,其中,鋁合金壓延板材之厚度,係0.5~3.5mm。 The aluminum alloy rolled laminated board for a small electronic machine casing as described in the first aspect of the patent application, wherein the thickness of the aluminum alloy rolled sheet is 0.5 to 3.5 mm. 如申請專利範圍第1項所記載之小型電子機器外殼用鋁合金壓延積層板材,其中,鋁合金壓延板材之兩面中成為小型電子機器外殼之外面的面,係積層有厚度50~100μm之聚酯樹脂薄膜或聚醯胺樹脂薄膜所成被覆材。 The aluminum alloy rolled laminated sheet material for a small electronic device casing according to the first aspect of the invention, wherein the aluminum alloy rolled sheet has a surface on the outer surface of the small electronic device casing, and has a polyester layer having a thickness of 50 to 100 μm. A resin film or a polyamide resin film is used as a covering material. 如申請專利範圍第4項所記載之小型電子機器外殼用鋁合金壓延積層板材,其中,鋁合金壓延板材之兩面中成為小型電子機器外殼之外面的面,係積層有厚度50~100μm之聚酯樹脂薄膜或聚醯胺樹脂薄膜所成被覆材。 An aluminum alloy rolled laminated sheet material for a small electronic device casing according to the fourth aspect of the invention, wherein the aluminum alloy rolled sheet has a surface on the outer surface of the small electronic device casing, and a polyester layer having a thickness of 50 to 100 μm is laminated. A resin film or a polyamide resin film is used as a covering material. 如申請專利範圍第1項所記載之小型電子機器外殼用鋁合金壓延 積層板材,其中,鋁合金壓延板材之兩面中成為小型電子機器外殼之內面的面,係積層有厚度10~100μm之聚乙烯樹脂薄膜、聚丙烯樹脂薄膜或聚醯胺樹脂薄膜所成被覆材。 Aluminum alloy rolling for small electronic machine casing as described in item 1 of the patent application scope A laminated board in which a surface of an inner surface of a small electronic machine casing is formed on both sides of an aluminum alloy rolled sheet, and a polyethylene resin film having a thickness of 10 to 100 μm, a polypropylene resin film or a polyimide film is used as a covering material. . 一種附被覆材小型電子機器外殼,其特徵係對於申請專利範圍第1~9項中任一項所記載之小型電子機器外殼用鋁合金壓延積層板材進行絞伸加工,並在內外兩面中至少一側的面被覆由合成樹脂薄膜或積層體所成被覆材者。 A small electronic device casing with a covering material, characterized in that the aluminum alloy rolled laminated sheet material for a small electronic machine casing described in any one of claims 1 to 9 is subjected to a drawing process, and at least one of the inner and outer surfaces The side surface is covered with a synthetic resin film or a laminate to form a covering material. 一種小型電子機器外殼,其特徵係對於申請專利範圍第1~9項中任一項所記載之小型電子機器外殼用鋁合金壓延積層板材進行絞伸加工後,去除內外兩面中至少一側的面所被覆之被覆材。 A small electronic device casing characterized in that the aluminum alloy rolled laminated sheet material for a small electronic machine casing described in any one of claims 1 to 9 is subjected to a drawing process, and at least one of the inner and outer surfaces is removed. Covered material covered. 如申請專利範圍第11項所記載之小型電子機器外殼,其中,其係具備:底壁、從底壁之周緣站立之側壁,且側壁之高度係0.5~25mm,相對於底壁,側壁角度係90~150°。 The small electronic device casing according to claim 11, wherein the bottom wall has a side wall standing from a periphery of the bottom wall, and the height of the side wall is 0.5 to 25 mm, and the side wall is opposite to the bottom wall. The angle is 90~150°. 一種小型電子機器外殼之成形方法,其特徵係對於申請專利範圍第1~9項中任一項所記載之小型電子機器外殼用鋁合金壓延積層板材進行絞伸加工。 A method of forming a small-sized electronic device casing, which is characterized in that the aluminum alloy rolled laminated sheet material for a small electronic machine casing described in any one of claims 1 to 9 is subjected to a drawing process.
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