JP2017081149A - Small sized electronic device case, molding method thereof and aluminum alloy rolled laminate sheet material for small sized electronic device case - Google Patents

Small sized electronic device case, molding method thereof and aluminum alloy rolled laminate sheet material for small sized electronic device case Download PDF

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JP2017081149A
JP2017081149A JP2016180193A JP2016180193A JP2017081149A JP 2017081149 A JP2017081149 A JP 2017081149A JP 2016180193 A JP2016180193 A JP 2016180193A JP 2016180193 A JP2016180193 A JP 2016180193A JP 2017081149 A JP2017081149 A JP 2017081149A
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aluminum alloy
electronic device
sheet material
alloy rolled
small electronic
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JP2017081149A5 (en
JP6832102B2 (en
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雅規 竹内
Masaki Takeuchi
雅規 竹内
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Resonac Packaging Corp
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Showa Denko Packaging Co Ltd
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Priority to TW105132391A priority Critical patent/TWI657148B/en
Priority to KR1020160138880A priority patent/KR102500876B1/en
Priority to DE102016220960.4A priority patent/DE102016220960A1/en
Priority to CN201610947840.8A priority patent/CN107009698B/en
Priority to US15/333,200 priority patent/US11633769B2/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B15/082Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising vinyl resins; comprising acrylic resins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/088Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
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    • B32B15/09Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/095Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/20Layered products comprising a layer of metal comprising aluminium or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/28Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/281Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyimides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/308Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising acrylic (co)polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0012Mechanical treatment, e.g. roughening, deforming, stretching
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/02Alloys based on aluminium with silicon as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • C22C21/08Alloys based on aluminium with magnesium as the next major constituent with silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/10Alloys based on aluminium with zinc as the next major constituent
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0012Mechanical treatment, e.g. roughening, deforming, stretching
    • B32B2038/0028Stretching, elongating
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2311/24Aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
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    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2457/00Electrical equipment

Abstract

PROBLEM TO BE SOLVED: To provide a small sized electronic device case capable of being molded by contraction processing at good efficiency and low cost, hardly generating molding defects, having no scratch on a surface by molding and having excellent appearance.SOLUTION: An aluminum alloy rolled laminate sheet material is used for molding a small sized electronic device case by contraction molding and is constituted by an aluminum alloy rolled sheet material having 0.2% bearing force of 200 MPa or more and a coating material laminated on at least one surface of both surfaces of the aluminum alloy rolled sheet material. The coating material consists of one of a synthetic resin film and a laminate wherein the synthetic resin film is laminated on both surfaces of a metal foil. The aluminum alloy rolled sheet material has a fibrous crystal structure extending in a direction orthogonal to a thickness direction.SELECTED DRAWING: Figure 2

Description

この発明は、タブレット端末、携帯通信端末機器、ノート型パソコン、携帯電話、携帯音楽機器、デジタルカメラ等の小型電子機器のケースおよびその成形方法、ならびに同ケースの成形材料として用いられるアルミニウム合金圧延積層板材に関する。   The present invention relates to a case of a small electronic device such as a tablet terminal, a portable communication terminal device, a notebook personal computer, a mobile phone, a portable music device, a digital camera, and a method for forming the same, and an aluminum alloy rolled laminate used as a molding material for the case It relates to plate materials.

従来、小型電子機器のケースとして、厚板状のアルミニウム合金押出材を切削加工(全面削り出し)することにより成形されたものが知られている(例えば、下記の特許文献1参照)。
上記のケースは、優れた外観、精密度および強度が得られるため、小型電子機器ケースとして好適に用いられている。
Conventionally, as a case of a small electronic device, a case formed by cutting (entirely cutting out) a thick plate-like aluminum alloy extruded material is known (for example, see Patent Document 1 below).
The above case can be suitably used as a small electronic device case because it has excellent appearance, precision and strength.

また、一般に、アルミニウム合金板材等の金属板材から所定形状の製品を成形する手段として、絞り加工も広く行われている。   In general, drawing is also widely performed as means for forming a product having a predetermined shape from a metal plate such as an aluminum alloy plate.

特開2012−246555号公報JP 2012-246555 A

しかしながら、切削加工によって成形された小型電子機器ケースの場合、材料を切削加工する時間が長くかかるため、製造効率が低く、また、加工に伴って切削屑が大量に発生し、これを回収処理するのに多くのエネルギーを必要とするため、結果的にコストが高くなるという問題があった。   However, in the case of a small electronic device case formed by cutting, since it takes a long time to cut the material, the manufacturing efficiency is low, and a large amount of cutting waste is generated along with the processing, and this is recovered. However, since a lot of energy is required, there is a problem that the cost becomes high as a result.

一方、絞り加工の場合、短時間で成形が行われるので、製造効率に優れており、また、加工に伴う屑の発生もないため、低コストで製造することができる。ただし、小型電子機器ケースの形態は、一般に、平面より見て略方形をした底壁と、底壁の周縁から立ち上がった側壁とを備えたものである。このような形態のケースを絞り加工により成形しようとすると、側壁のコーナー部分に割れが生じて、成形不良となるおそれが大きい。
加えて、絞り加工の場合、金属板材の表面が金型とすべり接触するため、それによって成形品の表面に傷が生じ、製品の外観が損なわれるおそれがある。
On the other hand, in the case of drawing, since molding is performed in a short time, the manufacturing efficiency is excellent, and there is no generation of debris accompanying the processing, so that it can be manufactured at low cost. However, the form of the small electronic device case is generally provided with a bottom wall that is substantially rectangular when viewed from above and a side wall that rises from the periphery of the bottom wall. If the case having such a configuration is to be molded by drawing, there is a high possibility that the corner portion of the side wall is cracked, resulting in molding failure.
In addition, in the case of drawing, the surface of the metal plate material is in sliding contact with the mold, which may cause damage to the surface of the molded product and impair the appearance of the product.

この発明の目的は、絞り加工によって効率よく低コストで成形することができる上、成形不良が生じにくく、また、成形により表面に傷が付かず、優れた外観を有する小型電子機器ケースを提供することにある。   An object of the present invention is to provide a small electronic device case that can be molded efficiently and at low cost by drawing processing, is less prone to molding defects, has no scratch on the surface, and has an excellent appearance. There is.

この発明は、上記の目的を達成するために、以下の態様からなる。   In order to achieve the above object, the present invention comprises the following aspects.

1)絞り加工により小型電子機器ケースを成形するためのアルミニウム合金圧延積層板材であって、0.2%耐力が200MPa以上であるアルミニウム合金圧延板材と、アルミニウム合金圧延板材の両面のうち少なくともいずれか一方の面に積層されている被覆材とで構成されており、被覆材は、合成樹脂フィルム、および金属箔の両面に合成樹脂フィルムが積層されている積層体のうちいずれか一方よりなる、小型電子機器ケース用アルミニウム合金圧延積層板材。 1) An aluminum alloy rolled laminated sheet for forming a small electronic device case by drawing, and at least one of both surfaces of an aluminum alloy rolled sheet having a 0.2% proof stress of 200 MPa or more and an aluminum alloy rolled sheet It is composed of a covering material laminated on one surface, and the covering material is a small size composed of either a synthetic resin film or a laminate in which a synthetic resin film is laminated on both surfaces of a metal foil. Aluminum alloy rolled laminate for electronic device cases.

2)アルミニウム合金圧延板材が、厚さ方向と直交する方向にのびた繊維状の結晶組織を有している、上記1)の小型電子機器ケース用アルミニウム合金圧延積層板材。 2) The aluminum alloy rolled laminated sheet material for small electronic device cases according to 1) above, wherein the aluminum alloy rolled sheet material has a fibrous crystal structure extending in a direction perpendicular to the thickness direction.

3)アルミニウム合金圧延板材が、Mn:0.2〜0.7質量%、Mg:2.0〜5.0質量%、残部Alおよび不可避不純物からなるAl−Mn−Mg系合金、Si:0.2〜0.8質量%、Mg:0.4〜1.2質量%、残部Alおよび不可避不純物からなるAl−Si−Mg系合金、ならびにZn:4.0〜6.5質量%、Mg:0.5〜3.0質量%、残部Alおよび不可避不純物からなるAl−Zn−Mg系合金のうちいずれか1つのアルミニウム合金からなる、上記1)または2)の小型電子機器ケース用アルミニウム合金圧延積層板材。 3) Al—Mn—Mg based alloy consisting of aluminum alloy rolled sheet material, Mn: 0.2 to 0.7 mass%, Mg: 2.0 to 5.0 mass%, balance Al and inevitable impurities, Si: 0 .2 to 0.8 mass%, Mg: 0.4 to 1.2 mass%, Al—Si—Mg based alloy composed of the balance Al and inevitable impurities, and Zn: 4.0 to 6.5 mass%, Mg : Aluminum alloy for small electronic device cases according to 1) or 2) above, which is made of any one aluminum alloy of Al-Zn-Mg alloys composed of 0.5 to 3.0% by mass, the balance Al and inevitable impurities Rolled laminated sheet material.

4)被覆材の厚さが、アルミニウム合金圧延板材の厚さの0.05〜1.5倍である、上記1)〜3)のいずれか1つの小型電子機器ケース用アルミニウム合金圧延積層板材。 4) The aluminum alloy rolled laminated sheet material for a small electronic device case according to any one of 1) to 3) above, wherein the thickness of the covering material is 0.05 to 1.5 times the thickness of the aluminum alloy rolled sheet material.

5)アルミニウム合金圧延板材の厚さが、0.5〜3.5mmである、上記1)〜4)のいずれか1つの小型電子機器ケース用アルミニウム合金圧延積層板材。 5) The aluminum alloy rolled laminated sheet material for a small electronic device case according to any one of 1) to 4) above, wherein the aluminum alloy rolled sheet material has a thickness of 0.5 to 3.5 mm.

6)アルミニウム合金圧延板材の両面のうち小型電子機器ケースの外面となる面に、厚さ50〜100μmのポリエステル樹脂フィルムまたはポリアミド樹脂フィルムよりなる被覆材が積層されている、上記1)〜5)のいずれか1つの小型電子機器ケース用アルミニウム合金圧延積層板材。 6) A covering material made of a polyester resin film or a polyamide resin film having a thickness of 50 to 100 μm is laminated on the outer surface of the small electronic device case among both surfaces of the aluminum alloy rolled sheet material, 1) to 5) above Aluminum alloy rolled laminated sheet material for any one of the small electronic device cases.

7)アルミニウム合金圧延板材の両面のうち小型電子機器ケースの内面となる面に、厚さ10〜100μmのポリエチレン樹脂フィルム、ポリプロピレン樹脂フィルムまたはポリアミド樹脂フィルムよりなる被覆材が積層されている、上記1)〜6)のいずれか1つの小型電子機器ケース用アルミニウム合金圧延積層板材。 7) A covering material made of a polyethylene resin film, a polypropylene resin film or a polyamide resin film having a thickness of 10 to 100 μm is laminated on a surface which is an inner surface of a small electronic device case among both surfaces of an aluminum alloy rolled plate material. The aluminum alloy rolled laminated sheet material for any one of small electronic device cases.

8)上記1)〜7)のいずれか1つの小型電子機器ケース用アルミニウム合金圧延積層板材を絞り加工してなり、内外両面のうち少なくともいずれか一方の面が合成樹脂フィルムまたは積層体よりなる被覆材で覆われている、被覆材付き小型電子機器ケース。 8) A coating obtained by drawing the aluminum alloy rolled laminated sheet for small electronic device cases according to any one of 1) to 7) above, wherein at least one of the inner and outer surfaces is made of a synthetic resin film or a laminate. A small electronic device case with a covering, covered with a material.

9)上記1)〜7)のいずれか1つの小型電子機器ケース用アルミニウム合金圧延積層板材を絞り加工した後、内外両面のうち少なくともいずれか一方の面を覆っている被覆材を除去してなる、小型電子機器ケース。 9) After drawing the aluminum alloy rolled laminated sheet material for small electronic device cases according to any one of 1) to 7) above, the covering material covering at least one of the inner and outer surfaces is removed. Small electronic equipment case.

10)底壁と、底壁の周縁から立ち上がった側壁とを備えており、側壁の高さが0.5〜25mmであり、底壁に対する側壁の角度が90〜150°である、上記9)の小型電子機器ケース。 10) The above-described 9), which includes a bottom wall and a side wall rising from the peripheral edge of the bottom wall, the side wall height is 0.5 to 25 mm, and the side wall angle is 90 to 150 °. Small electronic equipment case.

11)上記1)〜7)のいずれか1つの小型電子機器ケース用アルミニウム合金圧延積層板材を絞り加工する、小型電子機器ケースの成形方法。 11) A method for forming a small electronic device case, wherein the aluminum alloy rolled laminated sheet for the small electronic device case according to any one of 1) to 7) is drawn.

上記1)の小型電子機器ケース用アルミニウム合金圧延積層板材によれば、ケースの材料となるアルミニウム合金圧延板材として、0.2%耐力が200MPa以上のものが用いられているので、所望のケースの強度が確保される。
また、上記1)のアルミニウム合金圧延積層板材によれば、アルミニウム合金圧延板材の両面のうち少なくともいずれか一方の面に、合成樹脂フィルム、または金属箔の両面に合成樹脂フィルムが積層されている積層体よりなる摩擦抵抗の小さい被覆材が積層されているので、絞り加工により成形されたケースの側壁に皺が生じたり、側壁のコーナー部分に割れが生じたりせず、成形不良の発生が抑制される上、金型との接触によりケースの表面に傷が付くのが防止され、ケースの外観が損なわれない。
According to the aluminum alloy rolled laminated sheet material for a small electronic device case of 1) above, a 0.2% proof stress of 200 MPa or more is used as the aluminum alloy rolled sheet material as the material of the case. Strength is secured.
Moreover, according to the aluminum alloy rolled laminated sheet material of 1) above, a laminated structure in which a synthetic resin film or a synthetic resin film is laminated on both surfaces of a metal foil on at least one surface of both surfaces of the aluminum alloy rolled sheet material. Since the cover material with low frictional resistance is laminated, the side wall of the case formed by drawing is not wrinkled or cracked at the corner of the side wall, and the occurrence of molding defects is suppressed. In addition, the surface of the case is prevented from being damaged by contact with the mold, and the appearance of the case is not impaired.

上記2)の小型電子機器ケース用アルミニウム合金圧延積層板材によれば、アルミニウム合金圧延板材が、厚さ方向と直交する方向にのびた繊維状の結晶組織を有しているので、曲げに対する板材の強度が高くなり、皺や割れ等の成形不良が生じ難い。   According to the aluminum alloy rolled laminated sheet material for small electronic device cases of 2) above, since the aluminum alloy rolled sheet material has a fibrous crystal structure extending in a direction orthogonal to the thickness direction, the strength of the sheet material against bending And molding defects such as wrinkles and cracks are unlikely to occur.

上記3)の小型電子機器ケース用アルミニウム合金圧延積層板材によれば、アルミニウム合金圧延板材が、上記各組成を有するAl−Mn−Mg系合金、Al−Si−Mg系合金、Al−Zn−Mg系合金のうちいずれか1つのアルミニウム合金よりなるので、絞り加工による成形が良好に行われ、精密性および強度が高くかつ外観性に優れたケースが得られる。   According to the aluminum alloy rolled laminated sheet material for small electronic device cases of 3) above, the aluminum alloy rolled sheet material is an Al—Mn—Mg based alloy, Al—Si—Mg based alloy, Al—Zn—Mg having the above composition. Since it is made of any one aluminum alloy among the system alloys, the forming by drawing is performed well, and a case with high precision and strength and excellent appearance is obtained.

上記4)の小型電子機器ケース用アルミニウム合金圧延積層板材によれば、被覆材の厚さがアルミニウム合金圧延板材の厚さの0.05〜1.5倍であるので、以下のような問題が回避される。
即ち、被覆材の厚さがアルミニウム合金圧延板材の厚さの0.05倍未満であると、被覆材が破れて成形品が金型と接触する箇所に傷がつく。一方、被覆材の厚さがアルミニウム合金圧延板材の厚さの1.5倍を超えても、それ以上の効果が得られず、コストが高くなるだけである。
According to the aluminum alloy rolled laminated sheet material for small electronic device cases of 4) above, since the thickness of the covering material is 0.05 to 1.5 times the thickness of the aluminum alloy rolled sheet material, there are the following problems: Avoided.
That is, when the thickness of the coating material is less than 0.05 times the thickness of the aluminum alloy rolled sheet material, the coating material is broken and the portion where the molded product comes into contact with the mold is damaged. On the other hand, even if the thickness of the covering material exceeds 1.5 times the thickness of the aluminum alloy rolled sheet material, no further effect is obtained, and only the cost is increased.

上記5)の小型電子機器ケース用アルミニウム合金圧延積層板材によれば、アルミニウム合金圧延板材の厚さが0.5〜3.5mmであるので、以下のような問題が回避される。
即ち、アルミニウム合金圧延板材材の厚さが0.5mm未満であると、最終製品の強度が不足する。一方、アルミニウム合金圧延板材の厚さが3.5mmを超えると、折り曲げ部やコーナー部の曲率半径(R)が大きくなりすぎる。
According to the aluminum alloy rolled laminated sheet material for small electronic device cases of 5) above, since the thickness of the aluminum alloy rolled sheet material is 0.5 to 3.5 mm, the following problems are avoided.
That is, when the thickness of the aluminum alloy rolled plate material is less than 0.5 mm, the strength of the final product is insufficient. On the other hand, if the thickness of the rolled aluminum alloy sheet exceeds 3.5 mm, the radius of curvature (R) of the bent portion or corner portion becomes too large.

上記6)の小型電子機器ケース用アルミニウム合金圧延積層板材によれば、以下のような効果が奏される。すなわち、アルミニウム合金圧延積層板材を絞り加工して小型電子機器ケースを成形する際、板材両面のうち小型電子機器ケースの外面となる面は、部分的に金型によってしごかれるが、同面を覆う被覆材として、厚さ50〜100μmのポリエステル樹脂フィルムまたはポリアミド樹脂フィルムが用いられていれば、金型のしごきによって破断することがないので成形品の表面に傷が付くのを確実に回避することができ、また、フィルムの厚さが大きすぎることによるコストの増大が抑えられ、さらには、フィルムの剛性が大きすぎてケースの曲げ成形された部分から浮き上がったり剥がれたりするのを回避しうる。   According to the aluminum alloy rolled laminated sheet material for small electronic device cases of 6), the following effects are exhibited. That is, when a compact electronic device case is formed by drawing an aluminum alloy rolled laminated sheet material, the outer surface of the small electronic device case is partially squeezed by a mold. If a polyester resin film or a polyamide resin film having a thickness of 50 to 100 μm is used as the covering material to be covered, the surface of the molded product is surely avoided from being damaged by ironing of the mold. In addition, the increase in cost due to the film thickness being too large can be suppressed, and further, the rigidity of the film can be prevented from rising and peeling from the bent portion of the case. .

上記7)の小型電子機器ケース用アルミニウム合金圧延積層板材によれば、以下のような効果が奏される。すなわち、アルミニウム合金圧延積層板材を絞り加工して小型電子機器ケースを成形する際、板材両面のうち小型電子機器ケースの内面となる面は、金型によってしごかれることはないが、凹方向に曲げ成形される部分が生じるため、同面を覆う被覆材として、厚さ10〜100μmのポリエチレン樹脂フィルム、ポリプロピレン樹脂フィルムまたはポリアミド樹脂フィルムが用いられていれば、フィルムの剛性が大きすぎてケースの曲げ成形された部分から浮き上がったり剥がれたりするのが回避され、また、ケースの曲げ成形された部分の曲率半径(R)が大きくなってシャープな形状が得られないという事態を回避しうる。   According to the aluminum alloy rolled laminated sheet material for small electronic device case of 7), the following effects are exhibited. That is, when a compact electronic device case is formed by drawing aluminum alloy rolled laminated sheet material, the surface that is the inner surface of the small electronic device case is not squeezed by the mold, but in the concave direction. Since a part to be bent is formed, if a polyethylene resin film, polypropylene resin film or polyamide resin film having a thickness of 10 to 100 μm is used as a covering material for covering the same surface, the rigidity of the film is too large. It is possible to avoid floating and peeling from the bent portion, and it is possible to avoid a situation in which the radius of curvature (R) of the bent portion of the case becomes large and a sharp shape cannot be obtained.

上記8)の被覆材付き小型電子機器ケースによれば、絞り加工によるアルミニウム合金圧延板材の成形が良好に行われる上、成形時に表面に傷が付かないので、高い精密度および強度を有しかつ美しい外観のケースが得られる。
しかも、上記8)の被覆材付き小型電子機器ケースによれば、ケースの表面が被覆材で覆われた状態であるので、保管時や運搬時等に表面に傷が付くのが防止される。
According to the small electronic device case with a covering material of 8), the aluminum alloy rolled plate material is formed satisfactorily by drawing, and since the surface is not damaged during forming, it has high precision and strength and A case with a beautiful appearance can be obtained.
In addition, according to the above-mentioned 8) small electronic device case with a covering material, since the surface of the case is covered with the covering material, the surface is prevented from being damaged during storage or transportation.

上記9)の小型電子機器ケースによれば、絞り加工によるアルミニウム合金圧延板材の成形が良好に行われる上、成形時さらには保管時や運搬時にも表面に傷が付かないので、高い精密度および強度を有しかつ美しい外観を呈するケースが得られる。   According to the small electronic device case of the above 9), the aluminum alloy rolled plate material is formed well by drawing, and the surface is not scratched during forming, storage or transportation. A case having strength and a beautiful appearance can be obtained.

上記10)の小型電子機器ケースによれば、側壁の高さが0.5〜25mmであり、底壁に対する側壁の角度が150°であるので、以下のような問題が回避される。
即ち、側壁の高さが0.5mm未満であると、後工程で切削部分が多くなる。一方、側壁の高さが25mmを超えると、小型電子機器の厚さが大きくなるため好ましくない。
また、底壁に対する側壁の角度が90°未満である、即ち、側壁が内側に傾斜すると、コーナー部で皺が発生して加工が困難となる。一方、底壁に対する側壁の角度が150°を超えると、ケースの深さが浅くなり、小型電子機器の部品の収容容積が少なくなる。
According to the small electronic device case of the above 10), the height of the side wall is 0.5 to 25 mm, and the angle of the side wall with respect to the bottom wall is 150 °. Therefore, the following problems are avoided.
That is, if the height of the side wall is less than 0.5 mm, the number of cutting parts increases in the subsequent process. On the other hand, if the height of the side wall exceeds 25 mm, the thickness of the small electronic device increases, which is not preferable.
Further, when the angle of the side wall with respect to the bottom wall is less than 90 °, that is, when the side wall is inclined inward, wrinkles are generated at the corner portion, and the processing becomes difficult. On the other hand, if the angle of the side wall with respect to the bottom wall exceeds 150 °, the depth of the case becomes shallow, and the capacity for accommodating the components of the small electronic device decreases.

上記11)の小型電子機器ケースの成形方法によれば、高い精密度および強度を有しかつ美しい外観を呈する小型電子機器ケースを、絞り加工によって効率よく低コストで成形することができる。   According to the molding method of a small electronic device case of the above 11), a small electronic device case having high precision and strength and exhibiting a beautiful appearance can be efficiently molded at low cost by drawing.

この発明による小型電子機器ケース用アルミニウム合金圧延積層板材の層構造を示す部分拡大断面図である。It is a partial expanded sectional view which shows the layer structure of the aluminum alloy rolling laminated sheet material for small electronic device cases by this invention. 同板材を絞り加工して小型電子機器ケースを成形する工程を順次示す垂直断面図である。It is a vertical sectional view which shows sequentially the process of shape-drawing the board | plate material and shape | molding a small electronic device case. この発明による小型電子機器ケースの斜視図である。It is a perspective view of the small electronic device case by this invention. アルミニウム合金圧延板材を曲げ加工して断面の繊維状結晶組織を観察する際の断面方向を示すための斜視図である。It is a perspective view for showing the section direction at the time of bending the aluminum alloy rolled sheet material and observing the fibrous crystal structure of the section. 同アルミニウム合金圧延板材の曲げ材(内アール:0mm)の断面(圧延方向に対する断面方向:90°)の顕微鏡写真である。It is a microscope picture of the cross section (the cross-sectional direction with respect to a rolling direction: 90 degrees) of the bending material (inner round: 0 mm) of the aluminum alloy rolled sheet material. 同アルミニウム合金圧延板材の曲げ材(内アール:0.4mm)の断面(圧延方向に対する断面方向:90°)の顕微鏡写真である。It is a microscope picture of the cross section (cross-sectional direction with respect to a rolling direction: 90 degrees) of the bending material (inner radius: 0.4 mm) of the aluminum alloy rolled sheet material. 同アルミニウム合金圧延板材の曲げ材(内アール:0mm)の断面(圧延方向に対する断面方向:0°)の顕微鏡写真である。It is a microscope picture of the cross section (cross-sectional direction: 0 degree with respect to the rolling direction) of the bending material (inner round: 0 mm) of the aluminum alloy rolled sheet material. 同アルミニウム合金圧延板材の曲げ材(内アール:0.4mm)の断面(圧延方向に対する断面方向:0°)の顕微鏡写真である。It is a microscope picture of the cross section (cross-sectional direction: 0 degree with respect to the rolling direction) of the bending material (inner radius: 0.4 mm) of the aluminum alloy rolled sheet material.

以下、この発明の実施形態を、図1〜8を参照して説明する。   Hereinafter, an embodiment of the present invention will be described with reference to FIGS.

図1は、この発明による小型電子機器ケース用アルミニウム合金圧延積層板材(1)の層構造を示したものである。
図示の通り、小型電子機器ケース用アルミニウム合金圧延積層板材(1)は、アルミニウム合金圧延板材(2)と、アルミニウム合金圧延板材(2)の両面にそれぞれ積層された被覆材(3)(4)とで構成されている。
FIG. 1 shows a layer structure of an aluminum alloy rolled laminated sheet material (1) for a small electronic device case according to the present invention.
As shown in the figure, the aluminum alloy rolled laminated sheet (1) for a small electronic device case includes an aluminum alloy rolled sheet (2) and a covering material (3) (4) laminated on both sides of the aluminum alloy rolled sheet (2). It consists of and.

上記のアルミニウム合金圧延板材(2)としては、0.2%耐力が200MPa以上、好ましくは250MPa以上、より好ましくは300MPa以上のものが用いられる。これにより、所望のケースの強度が得られる。また、アルミニウム合金圧延板材(2)は、破断伸びが5%以上20%以下のものが好適に用いられる。これにより絞り加工の成形性が向上する。ここで、「0.2%耐力」および「破断伸び」は、JIS Z2241−2011に規定された、5号試験片を使用した、圧延方向に並行方向の引張試験によるものである。
また、アルミニウム合金圧延板材(2)は、厚さ方向と直交する方向にのびた繊維状の結晶組織を有している。
前記繊維状の結晶組織は、均質化処理したアルミニウム合金鋳魂を、熱間圧延後、所定の条件で熱処理を行い、その後に冷間圧延を行うことによって形成される。前記熱処理は、200〜400℃で1時間以上保持することにより行う。前記熱処理によって、MgSiを微細かつ均一に析出させるとともに、圧延材料中に存在する加工歪を減少させることができる。その後の冷間加工によって加工硬化させ、その後の成形加工性を損なわない範囲で高強度のアルミニウム合金圧延板材を得ることができる。
アルミニウム合金鋳魂の均質化処理の条件は特に限定されず、常法に従って500℃以上、2時間以上で行うのが好ましい。
熱間圧延では、任意のパス工程において所定の温度条件で圧延する間の温度降下により焼き入れと同等の効果を得る。従って、パス前の材料温度は、MgおよびSiが固溶された状態を保持しうる温度が必要であり、350〜440℃とする。パス上がり温度を上記200〜400℃の温度範囲とするためには、熱間圧延上がりで、直ちに高圧シャワー水冷等の強制冷却を行っても良い。また、焼き入れ効果を得るために、パス間の冷却速度は50℃/分以上、パス上がり温度は250〜340℃、また、パス圧延速度は50m/分以上、上り板厚が10mm以下とする。
冷間圧延では、加工硬化により所定の強度を得るために圧下率30%以上とする。好ましい圧下率は、50%以上である。
更に、必要に応じて、冷間圧延した合金板を130〜150℃の温度で最終焼鈍することができる。低温での熱処理を行うことにより、時効硬化させて更に強度を向上させるとともに、伸びを向上させることができる。また、機械的諸物性を安定化させる効果もある。
アルミニウム合金圧延板材(2)としては、以下のいずれかのアルミニウム合金からなるものが好適に用いられる。
i)Mn:0.2〜0.7質量%、Mg:2.0〜5.0質量%を含有し、残部Alおよび不可避不純物からなるAl−Mn−Mg系合金
ii)Si:0.2〜0.8質量%、Mg:0.4〜1.2質量%を含有し、残部Alおよび不可避不純物からなるAl−Si−Mg系合金
iii)Zn:4.0〜6.5質量%、Mg:0.5〜3.0質量%を含有し、残部Alおよび不可避不純物からなるAl−Zn−Mg系合金
上記i)の合金としては、Si:0.4質量%以下、Mn:0.4〜0.6質量%、Mg:4.0〜4.9質量%、Fe:0.4質量%以下、Cr:0.05〜0.25質量%、Zn:0.25質量%以下を含有し、残部Alおよび不可避不純物からなるアルミニウム合金が挙げられる。
上記ii)の合金としては、Si:0.2〜0.6質量%、Mg:0.45〜0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下を含有し、残部Alおよび不可避不純物からなるアルミニウム合金が挙げられる。
上記iii)の合金としては、Si:0.4質量%以下、Mg:2.1〜2.9質量%、Fe:0.5質量%以下、Cu:1.2〜2.0質量%、Mn:0.3質量%以下、Cr:0.18〜0.28質量%、Zn:5.1〜6.1質量%を含有し、残部Alおよび不可避不純物からなるアルミニウム合金が挙げられる。
これらの中でも、特に、Si:0.2〜0.6質量%、Mg:0.45〜0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下を含有し、残部Alおよび不可避不純物からなるアルミニウム合金よりなるアルミニウム合金圧延板材(2)が、小型電子機器ケースの成形材料として好適である。
また、使用するアルミニウム合金圧延板材(2)の厚さは、成形条件や成形品であるケースのサイズ等に応じて適宜設定されるが、好ましくは0.5〜3.5mm、より好ましくは0.8〜1.2mmとなされる。
As the aluminum alloy rolled sheet (2), a 0.2% proof stress is 200 MPa or more, preferably 250 MPa or more, more preferably 300 MPa or more. Thereby, the intensity | strength of a desired case is obtained. In addition, as the aluminum alloy rolled sheet (2), one having an elongation at break of 5% or more and 20% or less is suitably used. Thereby, the moldability of the drawing process is improved. Here, “0.2% proof stress” and “breaking elongation” are based on a tensile test parallel to the rolling direction using No. 5 test piece defined in JIS Z2241-2011.
The aluminum alloy rolled sheet (2) has a fibrous crystal structure extending in a direction orthogonal to the thickness direction.
The fibrous crystal structure is formed by subjecting a homogenized aluminum alloy cast soul to heat treatment under a predetermined condition after hot rolling, and then cold rolling. The said heat processing is performed by hold | maintaining at 200-400 degreeC for 1 hour or more. By the heat treatment, Mg 2 Si can be finely and uniformly precipitated, and processing strain existing in the rolled material can be reduced. It is possible to obtain a high-strength rolled aluminum alloy sheet within a range that does not impair subsequent workability by work hardening by subsequent cold working.
The conditions for the homogenization treatment of the aluminum alloy casting soul are not particularly limited, and it is preferably performed at 500 ° C. or more for 2 hours or more according to a conventional method.
In hot rolling, the same effect as quenching is obtained by a temperature drop during rolling at a predetermined temperature condition in an arbitrary pass process. Accordingly, the material temperature before the pass needs to be a temperature at which Mg and Si can be kept in a solid solution state, and is set to 350 to 440 ° C. In order to set the pass rising temperature in the temperature range of 200 to 400 ° C., forced cooling such as high pressure shower water cooling may be performed immediately after hot rolling. Further, in order to obtain a quenching effect, the cooling rate between passes is 50 ° C./min or more, the pass rising temperature is 250 to 340 ° C., the pass rolling rate is 50 m / min or more, and the ascending plate thickness is 10 mm or less. .
In cold rolling, the rolling reduction is 30% or more in order to obtain a predetermined strength by work hardening. A preferable rolling reduction is 50% or more.
Furthermore, the cold-rolled alloy plate can be finally annealed at a temperature of 130 to 150 ° C., if necessary. By performing the heat treatment at a low temperature, the strength can be further improved by age hardening, and the elongation can be improved. It also has the effect of stabilizing mechanical properties.
As the aluminum alloy rolled sheet (2), one made of any of the following aluminum alloys is preferably used.
i) Al—Mn—Mg-based alloy containing Mn: 0.2 to 0.7% by mass, Mg: 2.0 to 5.0% by mass, the balance being Al and inevitable impurities ii) Si: 0.2 -0.8 mass%, Mg: 0.4-1.2 mass%, Al-Si-Mg-based alloy iii consisting of the balance Al and inevitable impurities iii) Zn: 4.0-6.5 mass%, Mg: Al-Zn-Mg-based alloy containing 0.5 to 3.0% by mass, the balance being Al and inevitable impurities. 4 to 0.6 mass%, Mg: 4.0 to 4.9 mass%, Fe: 0.4 mass% or less, Cr: 0.05 to 0.25 mass%, Zn: 0.25 mass% or less The aluminum alloy which contains and consists of remainder Al and an unavoidable impurity is mentioned.
As the alloy of ii), Si: 0.2 to 0.6 mass%, Mg: 0.45 to 0.9 mass%, Fe: 0.35 mass% or less, Cr: 0.1 mass% or less, Zn: An aluminum alloy containing 0.1% by mass or less and composed of the balance Al and inevitable impurities may be mentioned.
As the alloy of the above iii), Si: 0.4 mass% or less, Mg: 2.1-2.9 mass%, Fe: 0.5 mass% or less, Cu: 1.2-2.0 mass%, Examples include an aluminum alloy containing Mn: 0.3% by mass or less, Cr: 0.18 to 0.28% by mass, Zn: 5.1 to 6.1% by mass, and the balance Al and inevitable impurities.
Among these, Si: 0.2-0.6 mass%, Mg: 0.45-0.9 mass%, Fe: 0.35 mass% or less, Cr: 0.1 mass% or less, Zn: An aluminum alloy rolled sheet (2) made of an aluminum alloy containing 0.1% by mass or less and the balance Al and inevitable impurities is suitable as a molding material for a small electronic device case.
Further, the thickness of the aluminum alloy rolled sheet (2) to be used is appropriately set according to the molding conditions, the size of the case as a molded product, etc., but is preferably 0.5 to 3.5 mm, more preferably 0. .8 to 1.2 mm.

被覆材(3)(4)は、アルミニウム合金圧延板材(2)を絞り加工する際の成形性を向上させ、また、成形時の潤滑剤の使用を低減し、加えて、成形時に板材(2)表面に傷が付くのを防止し、さらには、ケース成形後、例えば保管時や運搬時にケース表面を保護するためのものである。
被覆材(3)(4)としては、図1(a)に示すように、金属箔(31)(41)の両面に合成樹脂フィルム(32)(33)(42)(43)を積層してなる積層体(3)(4)が用いられる場合と、図1(b)に示すように、合成樹脂フィルム(30)(40)が用いられる場合とがある。
図1(a)に示す第1の態様の小型電子機器ケース用アルミニウム合金圧延積層板材(1)において、被覆材を構成する積層体(3)(4)の金属箔(31)(41)としては、アルミニウム箔、ステンレス箔、銅箔が挙げられる。また、積層体(3)(4)の合成樹脂フィルム(32)(33)(42)(43)としては、未延伸ポリプロピレン樹脂フィルム(CPP)、ポリエチレンテレフタレート樹脂フィルム(PET)、ナイロン樹脂フィルム(Ny)、ポリイミド樹脂フィルム(PI)、ポリエチレン樹脂フィルム(PE)など、或いは、これらの延伸フィルムなどが挙げられる。金属箔(31)(41)と合成樹脂フィルム(32)(33)(42)(43)との積層は、例えばポリエステルウレタン樹脂(PAUR)、アクリル樹脂、酸変性ポリオレフィン樹脂(APO)等と硬化剤とよりなる接着剤層(図示略)を介して行われる。
図1(b)に示す第2の態様の小型電子機器ケース用アルミニウム合金圧延積層板材(1)において、被覆材(3)(4)を構成する合成樹脂フィルム(30)(40)には、例えば、ポリプロピレン樹脂フィルム、ポリエステル樹脂フィルム、ポリアミド樹脂フィルム、ポリイミド樹脂フィルム、ポリエチレン樹脂フィルムが用いられ、好ましくは、2軸延伸ポリエチレンテレフタレート樹脂フィルム(PET)、2軸延伸ナイロン樹脂フィルム(ONy)、ポリエチレン樹脂フィルム、2軸延伸ポリアミド樹脂フィルム、2軸延伸ポリプロピレン樹脂フィルム(OPP)、未延伸ポリプロピレン樹脂フィルム(CPP)、未延伸ナイロン樹脂フィルム(CNy)のうちいずれかのフィルムが用いられる。
また、アルミニウム合金圧延板材(2)の両面のうち小型電子機器ケースの外面となる面(図1(b)では下面)に積層される被覆材(3)には、厚さ10〜200μmの合成樹脂フィルム(30)が用いられるのが好ましく、小型電子機器ケースの内面となる面(図1(b)では上面)に積層される被覆材(4)には、厚さ10〜100μmの合成樹脂フィルム(40)が用いられるのが好ましい。
より好適には、アルミニウム合金圧延板材(2)の両面のうち小型電子機器ケースの外面となる面(図1(b)では下面)に積層される被覆材(3)は、厚さ50〜100μmのポリエステル樹脂フィルムまたはポリアミド樹脂フィルムによって構成され、さらに好適には、厚さ50〜100μmの2軸延伸ポリエチレンテレフタレート樹脂フィルム(PET)、2軸延伸ポリエチレンナフタレート樹脂フィルム(PEN)、または2軸延伸6−ナイロン樹脂フィルム(ONy)(30)によって構成される。上記のフィルム(30)には、引張強度180〜330MPa、引張破断伸び80〜180%のものを適宜使用することができる。中でも、引張強度または引張破断伸びのMD/TDの比が0.8〜1.2の範囲のフィルム(30)を好適に使用することができる。
また、アルミニウム合金圧延板材(2)の両面のうち小型電子機器ケースの内面となる面(図1(b)では上面)に積層される被覆材(4)は、厚さ10〜100μm(より好ましくは20〜80μm)のポリエチレン樹脂フィルム、ポリプロピレン樹脂フィルムまたはポリアミド樹脂フィルムによって構成されるのが好ましく、より好ましくは、未延伸ポリエチレン樹脂フィルム、未延伸ポリプロピレン樹脂フィルム(CPP)、延伸ポリプロピレン樹脂フィルム(OPP)、または延伸ナイロン樹脂フィルム(ONy)(40)によって構成される。上記のフィルム(40)には、ヤング率が30〜400MPaのものを好適に使用することができる。
なお、被覆材は、アルミニウム合金圧延板材(2)の両面のうち少なくとも一方の面、より詳細にはケースの外面を構成する面に積層されていればよいが、成形性の向上や成形時・成形後のケース表面の保護の点では、図1のように、アルミニウム合金圧延板材(2)の両面に積層されているのが好ましい。
アルミニウム合金圧延板材(2)の両面に被覆材を積層する場合、各面に積層される2つの被覆材を同一のものとしてもよいし、互いに異なる材料/厚みのものとしてもよい。
なお、アルミニウム合金圧延板材(2)の曲げ強度が小さい場合や厚みが小さい場合には、被覆材として合成樹脂フィルム(30)(40)を用いればよいが(図1(b)参照)、アルミニウム合金圧延板材(2)の曲げ強度が大きい場合や厚みが大きい場合、被覆材として合成樹脂フィルムを用いると絞り加工時に破れて成形品の表面に皺を生じさせるおそれがあるため、被覆材を積層体(3)(4)で構成する(図1(a)参照)のが好ましい。
アルミニウム合金圧延板材(2)の面への被覆材(3)(4)の積層は、ケース成形後に被覆材(3)(4)を表面から除去する必要があることを考慮すると、図1に示すように、粘着剤層(34)(44)を介して行われるのが好ましい。粘着剤層(34)(44)には、例えば、ウレタン系粘着剤、アクリル系粘着剤、ゴム系粘着剤が用いられる。アルミニウム合金圧延板材(2)に対する粘着剤層(34)(44)の粘着力は、好ましくは0.5〜15N/25mm(より好ましくは1〜10N/25mm)となされる。ここで、「粘着力」は、JIS Z 0237:2000に準拠した180°引き剥がし粘着力によって表されたものである。粘着剤層(34)(44)の粘着力が0.5N/25mm未満であると、ケース成形前のアルミニウム合金圧延積層板材(1)を取り扱う際等に、アルミニウム合金圧延板材(2)から被覆材(3)(4)が不用意に剥がれやすくなる一方、粘着剤層(34)(44)の粘着力が15N/25mmを超えると、ケース成形後に被覆材(3)(4)を剥離除去する際の作業性が低下する上、粘着剤の一部がケースの表面に残って後工程の研磨等で不具合が生じるおそれがある。
被覆材(3)(4)の厚さは、好ましくは、アルミニウム合金圧延板材(2)の厚さの0.05〜1.5倍、より好ましくは、同厚さの0.2〜1.0倍となされる。
The covering materials (3) and (4) improve the formability when the aluminum alloy rolled plate (2) is drawn, reduce the use of lubricant during forming, and in addition, the plate (2 ) To prevent the surface from being scratched, and further to protect the case surface after molding the case, for example, during storage or transportation.
As the covering materials (3) and (4), synthetic resin films (32), (33), (42), and (43) are laminated on both sides of the metal foils (31) and (41) as shown in FIG. In some cases, the laminates (3) and (4) are used, and as shown in FIG. 1B, synthetic resin films (30) and (40) are used.
In the aluminum alloy rolled laminated sheet material (1) for the small electronic device case of the first aspect shown in FIG. 1 (a), as the metal foils (31) and (41) of the laminated bodies (3) and (4) constituting the covering material Examples include aluminum foil, stainless steel foil, and copper foil. In addition, as the synthetic resin films (32), (33), (42) and (43) of the laminates (3) and (4), unstretched polypropylene resin film (CPP), polyethylene terephthalate resin film (PET), nylon resin film ( Ny), a polyimide resin film (PI), a polyethylene resin film (PE), or a stretched film thereof. Lamination of metal foil (31) (41) and synthetic resin film (32) (33) (42) (43) is cured with, for example, polyester urethane resin (PAUR), acrylic resin, acid-modified polyolefin resin (APO), etc. It is carried out through an adhesive layer (not shown) made of an agent.
In the aluminum alloy rolled laminated sheet material (1) for a small electronic device case of the second aspect shown in FIG. 1 (b), the synthetic resin films (30) and (40) constituting the covering materials (3) and (4) are: For example, a polypropylene resin film, a polyester resin film, a polyamide resin film, a polyimide resin film, or a polyethylene resin film is used. Preferably, a biaxially stretched polyethylene terephthalate resin film (PET), a biaxially stretched nylon resin film (ONy), or polyethylene is used. Any one of a resin film, a biaxially stretched polyamide resin film, a biaxially stretched polypropylene resin film (OPP), an unstretched polypropylene resin film (CPP), and an unstretched nylon resin film (CNy) is used.
Also, the covering material (3) to be laminated on the outer surface of the small electronic device case (the lower surface in FIG. 1 (b)) of both surfaces of the aluminum alloy rolled plate (2) is a synthetic material having a thickness of 10 to 200 μm. A resin film (30) is preferably used, and the covering material (4) to be laminated on the surface (the upper surface in FIG. 1 (b)) of the small electronic device case has a synthetic resin thickness of 10 to 100 μm. A film (40) is preferably used.
More preferably, the covering material (3) laminated on the surface (the lower surface in FIG. 1 (b)) which is the outer surface of the small electronic device case out of both surfaces of the aluminum alloy rolled sheet (2) has a thickness of 50 to 100 μm. Of a biaxially stretched polyethylene terephthalate resin film (PET), a biaxially stretched polyethylene naphthalate resin film (PEN), or a biaxially stretched film. 6-Nylon resin film (ONy) (30). A film having a tensile strength of 180 to 330 MPa and a tensile elongation at break of 80 to 180% can be appropriately used for the film (30). Especially, the film (30) whose ratio of MD / TD of tensile strength or tensile breaking elongation is 0.8-1.2 can be used conveniently.
Further, the covering material (4) laminated on the surface (upper surface in FIG. 1 (b)) of the aluminum alloy rolled sheet (2) which is the inner surface of the small electronic device case has a thickness of 10 to 100 μm (more preferably Is preferably composed of a polyethylene resin film, a polypropylene resin film or a polyamide resin film, more preferably an unstretched polyethylene resin film, an unstretched polypropylene resin film (CPP), or a stretched polypropylene resin film (OPP). Or a stretched nylon resin film (ONy) (40). A film having a Young's modulus of 30 to 400 MPa can be suitably used for the film (40).
The covering material only needs to be laminated on at least one surface of both sides of the aluminum alloy rolled sheet material (2), more specifically, the surface constituting the outer surface of the case. From the viewpoint of protecting the case surface after forming, it is preferable that the aluminum alloy rolled sheet material (2) is laminated on both surfaces as shown in FIG.
When laminating the covering material on both surfaces of the aluminum alloy rolled sheet (2), the two covering materials laminated on each surface may be the same or different materials / thicknesses.
When the bending strength of the aluminum alloy rolled sheet (2) is small or the thickness is small, the synthetic resin films (30) and (40) may be used as the covering material (see FIG. 1 (b)). If the bending strength of the rolled alloy sheet (2) is large or the thickness is large, using a synthetic resin film as the coating material may break during drawing and cause wrinkles on the surface of the molded product. The body (3) (4) is preferable (see FIG. 1 (a)).
In view of the fact that the covering materials (3) and (4) are laminated on the surface of the rolled aluminum alloy sheet (2), it is necessary to remove the covering materials (3) and (4) from the surface after the case is formed. As shown, it is preferably carried out through the pressure-sensitive adhesive layers (34) and (44). For the pressure-sensitive adhesive layers (34) and (44), for example, urethane-based pressure-sensitive adhesives, acrylic pressure-sensitive adhesives, and rubber-based pressure-sensitive adhesives are used. The adhesive strength of the adhesive layers (34) and (44) to the aluminum alloy rolled sheet (2) is preferably 0.5 to 15 N / 25 mm (more preferably 1 to 10 N / 25 mm). Here, “adhesive strength” is expressed by 180 ° peeling adhesive strength in accordance with JIS Z 0237: 2000. When the adhesive strength of the adhesive layers (34) and (44) is less than 0.5 N / 25 mm, the aluminum alloy rolled sheet (2) is coated when handling the aluminum alloy rolled laminated sheet (1) before forming the case. While the materials (3) and (4) are easily peeled off, if the adhesive strength of the adhesive layers (34) and (44) exceeds 15 N / 25 mm, the covering materials (3) and (4) are peeled off after the case is molded. In addition, the workability at the time of performing may be reduced, and a part of the pressure-sensitive adhesive may remain on the surface of the case, resulting in problems in subsequent polishing or the like.
The thickness of the covering materials (3) and (4) is preferably 0.05 to 1.5 times the thickness of the aluminum alloy rolled sheet (2), more preferably 0.2 to 1. 0 times.

図2は、上記アルミニウム合金圧延積層板材(1)を絞り加工して、小型電子機器ケースを成形する工程を示したものである。
まず、所定寸法にカットされた略方形状のアルミニウム合金圧延積層板材(1)を、金型の下側の固定雌型(ダイ)(5)の上面にセットする(図2(a)参照)。ここで、アルミニウム合金圧延積層板材(1)の上下両面のうち少なくともケースの外側となる下面、即ち、下側の被覆材(3)の表面に、例えばシリコーン系潤滑剤、鉱油、または合成石油系潤滑剤よりなる潤滑剤を塗布しておくのが好ましく、それによってさらに成形性が高められる。
そして、金型の上側の可動雄型(ポンチ)(6)を降下させると、アルミニウム合金圧延積層板材(1)のうち周縁部を除いた部分が雄型(6)の先端部で下向きに加圧され、それによって同周縁部の直線部分が上向きに曲げられるとともに、同周縁部のコーナー部分が絞り成形される(図2(b)参照)。この際、アルミニウム合金圧延板材(2)は、その両面が被覆材(3)(4)で覆われているため、皺が生じるのが抑制され、結果的に割れも発生しない。また、アルミニウム合金圧延板材(2)の表面は、雌型(5)および雄型(6)とは直に接触しないので、擦れて傷が付くことがない。
こうして、被覆材(3)(4)付き小型電子機器ケース(20)が得られる。小型電子機器ケース(20)の表面は、被覆材(3)(4)で覆われているため、例えば保管時や運搬時に他のものと接触して傷が付くことがなく、美しい状態に保持される。
FIG. 2 shows a process of forming a small electronic device case by drawing the aluminum alloy rolled laminate (1).
First, a substantially rectangular aluminum alloy rolled laminated sheet material (1) cut to a predetermined dimension is set on the upper surface of a fixed female die (die) (5) on the lower side of the die (see FIG. 2 (a)). . Here, at least the lower surface of the upper and lower surfaces of the aluminum alloy rolled laminated sheet material (1), that is, the surface of the lower coating material (3), for example, a silicone-based lubricant, mineral oil, or synthetic petroleum-based material It is preferable to apply a lubricant composed of a lubricant, whereby the moldability is further improved.
Then, when the movable male die (punch) (6) on the upper side of the mold is lowered, the portion excluding the peripheral portion of the aluminum alloy rolled laminated sheet material (1) is added downward at the tip of the male die (6). As a result, the straight portion of the peripheral edge is bent upward, and the corner portion of the peripheral edge is drawn (see FIG. 2B). At this time, since both surfaces of the aluminum alloy rolled sheet (2) are covered with the covering materials (3) and (4), generation of wrinkles is suppressed, and as a result, cracks do not occur. Further, since the surface of the aluminum alloy rolled sheet (2) does not come into direct contact with the female mold (5) and the male mold (6), it is not rubbed and scratched.
Thus, the small electronic device case (20) with the covering materials (3) and (4) is obtained. Since the surface of the small electronic device case (20) is covered with the covering material (3) (4), it will not be damaged by contact with other objects during storage or transportation, and will be kept in a beautiful state. Is done.

図3は、小型電子機器ケース(20)を示すものである。このケース(20)は、上記の被覆材(3)(4)付き小型電子機器ケース(20)の内外両面から被覆材(3)(4)を剥がして除去した後、部分的に切削加工を施して仕上げ成形し、さらに表面をアルマイト処理することにより得られたものである。
小型電子機器ケース(20)は、平面より見て略方形状の底壁(21)と、底壁(21)の4辺からそれぞれ立ち上がった4つの側壁(22)とで構成されている。隣り合う側壁(22)の端部どうしは連続しており、4つの側壁(22)によって底壁(21)が囲繞されている。
側壁(22)の高さ(換言すれば、成形高さ)は、0.5〜25mm、好ましくは1〜15mm、さらに好ましくは2〜10mmである。
底壁(21)に対する側壁(22)の角度は、90〜150°(図示のものは約90°)、好ましくは90〜120°、さらに好ましくは90〜100°である。
底壁(21)と側壁(22)との境界部にはアールが付けられており、また、側壁(22)のコーナー部(22a)にもアールが付けられている。これらアール部分においては、繊維状の結晶組織が、アールに沿うようにのびている。
FIG. 3 shows a small electronic device case (20). This case (20) is partly cut after removing the covering material (3) (4) from both the inside and outside of the small electronic device case (20) with the covering material (3) (4). It is obtained by applying and finish-molding, and further anodizing the surface.
The small electronic device case (20) includes a bottom wall (21) having a substantially square shape when seen from the plane and four side walls (22) rising from the four sides of the bottom wall (21). The ends of adjacent side walls (22) are continuous, and the bottom wall (21) is surrounded by the four side walls (22).
The height of the side wall (22) (in other words, the molding height) is 0.5 to 25 mm, preferably 1 to 15 mm, and more preferably 2 to 10 mm.
The angle of the side wall (22) with respect to the bottom wall (21) is 90 to 150 ° (the one shown is about 90 °), preferably 90 to 120 °, more preferably 90 to 100 °.
The corners (22a) of the side wall (22) are also rounded at the boundary between the bottom wall (21) and the side wall (22). In these round portions, the fibrous crystal structure extends along the round.

繊維状結晶組織は、アルミニウム合金圧延板材(2)、あるいはアルミニウム合金圧延板材(2)を絞り成形したケース(20)の断面を、偏光顕微鏡を用いて観察することにより、確認することができる。
好ましくは、繊維状結晶組織は、アルミニウム合金圧延板材の圧延方向に対して、0°、90°、45°、135°などの任意の方向に切断した断面においても観察されるのが好ましい。折り曲げ部やコーナー部においても同様に観察することできる。
具体的には、例えば、図4(a)(b)に示すように、厚さ0.25mmのアルミニウム合金圧延板材(2)を、内アールが0mmまたは0.4mmとなるように曲げ加工し、これらの曲げ材について、圧延方向(X)に対して90°(直角)または0°(平行)の方向(Y)に切断した断面を、偏光顕微鏡で観察する。そうすると、図5〜8の顕微鏡写真から分かるように、内アール:0mm、圧延方向に対する断面方向:90°(図5)、内アール:0.4mm、圧延方向に対する断面方向:90°(図6)、内アール:0mm、圧延方向に対する断面方向:0°(図7)、内アール:0.4mm、圧延方向に対する断面方向:0°(図8)のいずれの断面においても、繊維状の結晶組織が、アールに沿うように、板材の厚さ方向と直交する方向にのびている。
The fibrous crystal structure can be confirmed by observing the cross section of the aluminum alloy rolled plate (2) or the case (20) formed by drawing the aluminum alloy rolled plate (2) using a polarizing microscope.
Preferably, the fibrous crystal structure is preferably observed even in a cross section cut in an arbitrary direction such as 0 °, 90 °, 45 °, and 135 ° with respect to the rolling direction of the aluminum alloy rolled sheet. The same can be observed in the bent portion and the corner portion.
Specifically, for example, as shown in FIGS. 4 (a) and 4 (b), a rolled aluminum alloy sheet (2) having a thickness of 0.25 mm is bent so that the inner radius is 0 mm or 0.4 mm. For these bending materials, a cross section cut in a direction (Y) of 90 ° (perpendicular) or 0 ° (parallel) with respect to the rolling direction (X) is observed with a polarizing microscope. Then, as can be seen from the micrographs of FIGS. 5 to 8, the inner radius is 0 mm, the cross-sectional direction with respect to the rolling direction: 90 ° (FIG. 5), the inner radius is 0.4 mm, and the cross-sectional direction with respect to the rolling direction is 90 ° (FIG. 6). ), Inner radius: 0 mm, sectional direction with respect to rolling direction: 0 ° (FIG. 7), inner radius: 0.4 mm, sectional direction with respect to rolling direction: 0 ° (FIG. 8) The structure extends in a direction orthogonal to the thickness direction of the plate material so as to be along the radius.

次に、この発明の具体的実施例について説明する。但し、この発明は、これらの実施例に限定されるものではない。   Next, specific examples of the present invention will be described. However, the present invention is not limited to these examples.

<実施例1>
Si:0.2〜0.6質量%、Mg:0.45〜0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下を含有し、残部Alおよび不可避不純物からなるアルミニウム合金鋳魂を580℃、10時間で均質化処理した後に面削して、500℃で予備加熱を行い、熱間圧延を開始した。熱間圧延の最終パス開始温度を400℃とし、パス後、80℃/分の速度で冷却した。その後、240℃、4時間の条件で熱処理を行った。その後、86%の圧下率で冷間圧延を行った。こうして、0.2%耐力が310MPa、破断伸びが7%である厚さ1mmのアルミニウム合金圧延板材を得た。
上記板材の断面を、光学顕微鏡および偏向レンズによって観察したところ、厚さ方向と直交する方向にのびる繊維状の結晶組織が見られた。
そして、小型電子機器ケースの外面を構成するアルミニウム合金圧延板材の下面に、被覆材として、厚さ120μmのアルミニウム箔の片面に厚さ30μmの未延伸ポリプロピレン樹脂フィルムをポリエステルウレタン樹脂とヘキサンメチレンイソシアナートよりなる接着剤層を介して積層するとともに同他面に厚さ200μmの未延伸ポリプロピレン樹脂フィルムを接着剤層を介して積層してなる積層体を、アクリル系粘着剤よりなる粘着剤層を介して積層した。
また、小型電子機器ケースの内面を構成するアルミニウム合金圧延板材の上面に、被覆材として、厚さ30μmのナイロン樹脂フィルムを、アクリル系粘着剤よりなる粘着剤層を介して積層した。
こうして得られたアルミニウム合金圧延積層板材を、縦150mm、横82mm、コーナー部アール14.5mmの略方形状にカットして、実施例1の成形材料を作製した。
<Example 1>
Si: 0.2-0.6 mass%, Mg: 0.45-0.9 mass%, Fe: 0.35 mass% or less, Cr: 0.1 mass% or less, Zn: 0.1 mass% or less The aluminum alloy casting soul containing the balance Al and inevitable impurities was homogenized at 580 ° C. for 10 hours, then face-cut, preheated at 500 ° C., and hot rolling was started. The final pass start temperature of hot rolling was 400 ° C., and after the pass, cooling was performed at a rate of 80 ° C./min. Thereafter, heat treatment was performed at 240 ° C. for 4 hours. Thereafter, cold rolling was performed at a reduction rate of 86%. Thus, a 1 mm-thick aluminum alloy rolled sheet material having a 0.2% proof stress of 310 MPa and a breaking elongation of 7% was obtained.
When the cross section of the plate was observed with an optical microscope and a deflecting lens, a fibrous crystal structure extending in a direction perpendicular to the thickness direction was observed.
And, on the lower surface of the aluminum alloy rolled plate constituting the outer surface of the small electronic device case, as a covering material, an unstretched polypropylene resin film with a thickness of 30 μm is coated on one surface of an aluminum foil with a thickness of 120 μm and polyester urethane resin and hexanemethylene isocyanate. A laminate formed by laminating an unstretched polypropylene resin film having a thickness of 200 μm on the other side with an adhesive layer and an adhesive layer made of an acrylic pressure-sensitive adhesive layer. And laminated.
Further, a nylon resin film having a thickness of 30 μm was laminated as a covering material on the upper surface of the aluminum alloy rolled plate constituting the inner surface of the small electronic device case via an adhesive layer made of an acrylic adhesive.
The aluminum alloy rolled laminated sheet material thus obtained was cut into a substantially rectangular shape having a length of 150 mm, a width of 82 mm, and a corner radius of 14.5 mm to produce a molding material of Example 1.

<実施例2>
Si:0.4質量%以下、Mn:0.4〜0.6質量%、Mg:4.0〜4.9質量%、Fe:0.4質量%以下、Cr:0.05〜0.25質量%、Zn:0.25質量%以下を含有し、残部Alおよび不可避不純物からなるアルミニウム合金鋳魂を580℃、10時間で均質化処理した後に面削して、500℃で予備加熱を行い、熱間圧延を開始した。熱間圧延の最終パス開始温度を400℃とし、パス後、80℃/分の速度で冷却した。その後、240℃、4時間の条件で熱処理を行った。その後、79%の圧下率で冷間圧延を行った後、130℃、4時間最終焼鈍した。こうして、0.2%耐力が210MPa、破断伸びが7%である厚さ1.5mmのアルミニウム合金圧延板材を得た。
上記板材の断面を、光学顕微鏡および偏向レンズによって観察したところ、厚さ方向と直交する方向にのびる繊維状の結晶組織が見られた。
そして、アルミニウム合金圧延板材の上下両面に、被覆材として、厚さ90μmのナイロン樹脂フィルムを、アクリル系粘着剤よりなる粘着剤層を介してそれぞれ積層した。
こうして得られたアルミニウム合金圧延積層板材を、縦150mm、横82mm、コーナー部アール14.5mmの略方形状にカットして、実施例2の成形材料を作製した。
<Example 2>
Si: 0.4 mass% or less, Mn: 0.4-0.6 mass%, Mg: 4.0-4.9 mass%, Fe: 0.4 mass% or less, Cr: 0.05-0. Aluminum alloy casting soul containing 25% by mass and Zn: 0.25% by mass or less and comprising the balance Al and inevitable impurities is homogenized at 580 ° C. for 10 hours and then face-cut, and preheated at 500 ° C. And hot rolling was started. The final pass start temperature of hot rolling was 400 ° C., and after the pass, cooling was performed at a rate of 80 ° C./min. Thereafter, heat treatment was performed at 240 ° C. for 4 hours. Then, after cold rolling at a reduction rate of 79%, final annealing was performed at 130 ° C. for 4 hours. Thus, an aluminum alloy rolled sheet material having a thickness of 1.5 mm having a 0.2% proof stress of 210 MPa and a breaking elongation of 7% was obtained.
When the cross section of the plate was observed with an optical microscope and a deflecting lens, a fibrous crystal structure extending in a direction perpendicular to the thickness direction was observed.
And the nylon resin film of thickness 90micrometer was laminated | stacked through the adhesive layer which consists of an acrylic adhesive as a coating | covering material on the upper and lower surfaces of the aluminum alloy rolled sheet material, respectively.
The aluminum alloy rolled laminated sheet material thus obtained was cut into a substantially rectangular shape having a length of 150 mm, a width of 82 mm, and a corner radius of 14.5 mm to produce a molding material of Example 2.

<実施例3>
Si:0.4質量%以下、Mg:2.1〜2.9質量%、Fe:0.5質量%以下、Cu:1.2〜2.0質量%、Mn:0.3質量%以下、Cr:0.18〜0.28質量%、Zn:5.1〜6.1質量%を含有し、残部Alおよび不可避不純物からなるアルミニウム合金鋳塊を、実施例2と同一の工程・条件で圧延することにより、0.2%耐力が550MPa、破断伸びが9%である厚さ1.5mmのアルミニウム合金圧延板材を得た。
上記板材の断面を、光学顕微鏡および偏向レンズによって観察したところ、厚さ方向と直交する方向にのびる繊維状の結晶組織が見られた。
そして、小型電子機器ケースの外面を構成するアルミニウム合金圧延板材の下面に、被覆材として、厚さ90μmのナイロン樹脂フィルムを、アクリル系粘着剤よりなる粘着剤層を介して積層した。
こうして得られたアルミニウム合金圧延積層板材を、縦150mm、横82mm、コーナー部アール14.5mmの略方形状にカットして、実施例3の成形材料を作製した。
<Example 3>
Si: 0.4% by mass or less, Mg: 2.1-2.9% by mass, Fe: 0.5% by mass or less, Cu: 1.2-2.0% by mass, Mn: 0.3% by mass or less , Cr: 0.18 to 0.28 mass%, Zn: 5.1 to 6.1 mass%, the aluminum alloy ingot consisting of the balance Al and inevitable impurities, the same process and conditions as in Example 2 Was rolled to obtain an aluminum alloy rolled sheet having a thickness of 1.5 mm and a 0.2% proof stress of 550 MPa and a breaking elongation of 9%.
When the cross section of the plate was observed with an optical microscope and a deflecting lens, a fibrous crystal structure extending in a direction perpendicular to the thickness direction was observed.
And the nylon resin film of thickness 90micrometer was laminated | stacked through the adhesive layer which consists of an acrylic adhesive as a coating | covering material on the lower surface of the aluminum alloy rolling board which comprises the outer surface of a small electronic device case.
The aluminum alloy rolled laminated sheet material thus obtained was cut into a substantially rectangular shape with a length of 150 mm, a width of 82 mm, and a corner radius of 14.5 mm, thereby producing a molding material of Example 3.

<実施例4>
実施例1と同じアルミニウム合金圧延板材を用意した。
そして、小型電子機器ケースの外面を構成するアルミニウム合金圧延板材の下面に、被覆材として、厚さ90μmのナイロン樹脂フィルムを、アクリル系粘着剤よりなる粘着剤層を介して積層した。
こうして得られたアルミニウム合金圧延積層板材を、縦150mm、横82mm、コーナー部アール14.5mmの略方形状にカットして、実施例4の成形材料を作製した。
<Example 4>
The same aluminum alloy rolled sheet material as in Example 1 was prepared.
And the nylon resin film of thickness 90micrometer was laminated | stacked through the adhesive layer which consists of an acrylic adhesive as a coating | covering material on the lower surface of the aluminum alloy rolling board which comprises the outer surface of a small electronic device case.
The aluminum alloy rolled laminated sheet material thus obtained was cut into a substantially rectangular shape having a length of 150 mm, a width of 82 mm, and a corner radius of 14.5 mm to produce a molding material of Example 4.

<比較例1>
Si:0.4質量%以下、Mn:0.4〜1.0質量%、Mg:4.0〜4.9質量%、Fe:0.4質量%以下、Cr:0.05〜0.25質量%、Zn:0.25質量%以下を含有し、残部Alおよび不可避不純物からなるアルミニウム合金よりなり、0.2%耐力が230MPa、破断伸びが14%である厚さ2mmのアルミニウム合金押出板材を用意した。板材は、押出成形したものであり、厚さ方向と直交する方向にのびる繊維状の結晶組織は有していない。
そして、アルミニウム合金押出板材の上下両面に、被覆材として、厚さ90μmのナイロン樹脂フィルムを、アクリル系粘着剤よりなる粘着剤層を介してそれぞれ積層した。
こうして得られたアルミニウム合金押出積層板材を、縦150mm、横82mm、コーナー部アール14.5mmの略方形状にカットして、比較例1の成形材料を作製した。
<Comparative Example 1>
Si: 0.4 mass% or less, Mn: 0.4-1.0 mass%, Mg: 4.0-4.9 mass%, Fe: 0.4 mass% or less, Cr: 0.05-0. Extruded aluminum alloy with a thickness of 2 mm, containing 25% by mass, Zn: 0.25% by mass or less, consisting of an aluminum alloy consisting of the balance Al and inevitable impurities, 0.2% proof stress 230 MPa, and breaking elongation 14% Board material was prepared. The plate material is extruded and does not have a fibrous crystal structure extending in a direction orthogonal to the thickness direction.
And the nylon resin film of thickness 90micrometer was laminated | stacked through the adhesive layer which consists of an acrylic adhesive as a coating | covering material on the upper and lower surfaces of the aluminum alloy extrusion board material, respectively.
The aluminum alloy extruded laminate obtained in this way was cut into a substantially rectangular shape having a length of 150 mm, a width of 82 mm, and a corner radius of 14.5 mm, thereby producing a molding material of Comparative Example 1.

<比較例2>
Si:0.4質量%以下、Mg:2.1〜2.9質量%、Fe:0.5質量%以下、Cu:1.2〜2.0質量%、Mn:0.3質量%以下、Cr:0.18〜0.28質量%、Zn:5.1〜6.1質量%を含有し、残部Alおよび不可避不純物からなるアルミニウム合金よりなり、0.2%耐力が510MPa、破断伸びが11%である厚さ1.5mmのアルミニウム合金押出板材を用意した。板材は、押出成形したものであり、厚さ方向と直交する方向にのびる繊維状の結晶組織は有していない。
そして、このアルミニウム合金押出板材を縦150mm、横82mm、コーナー部アール14.5mmの略方形状にカットして、比較例2の成形材料を作製した。
<Comparative example 2>
Si: 0.4% by mass or less, Mg: 2.1-2.9% by mass, Fe: 0.5% by mass or less, Cu: 1.2-2.0% by mass, Mn: 0.3% by mass or less , Cr: 0.18 to 0.28 mass%, Zn: 5.1 to 6.1 mass%, consisting of an aluminum alloy consisting of the balance Al and inevitable impurities, 0.2% proof stress of 510 MPa, elongation at break An aluminum alloy extruded plate material having a thickness of 1.5 mm and 11% was prepared. The plate material is extruded and does not have a fibrous crystal structure extending in a direction orthogonal to the thickness direction.
The aluminum alloy extruded plate was cut into a substantially rectangular shape having a length of 150 mm, a width of 82 mm, and a corner radius of 14.5 mm, thereby producing a molding material of Comparative Example 2.

<比較例3>
Si:0.2〜0.6質量%、Mg:0.45〜0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下を含有し、残部Alおよび不可避不純物からなるアルミニウム合金鋳魂を580℃、10時間で均質化処理した後に面削して、500℃で予備加熱を行い、熱間圧延を開始した。熱間圧延の最終パス開始温度を400℃とし、パス後、80℃/分の速度で冷却した。その後、240℃、4時間の条件で熱処理を行った。その後、57%の圧下率で冷間圧延を行った後、250℃、2時間熱処理した。こうして、0.2%耐力が150MPa、破断伸びが14%である厚さ3mmのアルミニウム合金圧延板材を得た。板材は、冷間圧延したのちに自然時効処理を行ったものであり、厚さ方向と直交する方向にのびる繊維状の結晶組織は有していない。
そして、アルミニウム合金圧延板材の上下両面に、被覆材として、厚さ30μmのナイロン樹脂フィルムを、アクリル系粘着剤よりなる粘着剤層を介してそれぞれ積層した。
こうして得られたアルミニウム合金圧延積層板材を、縦150mm、横82mm、コーナー部アール14.5mmの略方形状にカットして、比較例3の成形材料を作製した。
<Comparative Example 3>
Si: 0.2-0.6 mass%, Mg: 0.45-0.9 mass%, Fe: 0.35 mass% or less, Cr: 0.1 mass% or less, Zn: 0.1 mass% or less The aluminum alloy casting soul containing the balance Al and inevitable impurities was homogenized at 580 ° C. for 10 hours, then face-cut, preheated at 500 ° C., and hot rolling was started. The final pass start temperature of hot rolling was 400 ° C., and after the pass, cooling was performed at a rate of 80 ° C./min. Thereafter, heat treatment was performed at 240 ° C. for 4 hours. Then, after cold rolling at a reduction rate of 57%, heat treatment was performed at 250 ° C. for 2 hours. Thus, a rolled aluminum alloy sheet having a thickness of 3 mm and a 0.2% proof stress of 150 MPa and a breaking elongation of 14% was obtained. The plate material has been subjected to natural aging treatment after cold rolling, and does not have a fibrous crystal structure extending in a direction perpendicular to the thickness direction.
And the nylon resin film of thickness 30 micrometers was laminated | stacked as the coating | covering material through the adhesive layer which consists of an acrylic adhesive on both the upper and lower surfaces of an aluminum alloy rolled sheet material, respectively.
The aluminum alloy rolled laminated sheet material thus obtained was cut into a substantially rectangular shape having a length of 150 mm, a width of 82 mm, and a corner radius of 14.5 mm to produce a molding material of Comparative Example 3.

<比較例4>
Si:0.2〜0.6質量%、Mg:0.45〜0.9質量%、Fe:0.35質量%以下、Cr:0.1質量%以下、Zn:0.1質量%以下を含有し、残部Alおよび不可避不純物からなるアルミニウム合金よりなり、0.2%耐力が145MPa、破断伸びが12%である厚さ2mmのアルミニウム合金圧延板材を用意した。板材は、押出板材を冷間圧延(圧下率33%)したものであり、厚さ方向と直交する方向にのびる繊維状の結晶組織は有していない。
そして、アルミニウム合金圧延板材の上下両面に、被覆材として、厚さ30μmのナイロン樹脂フィルムを、アクリル系粘着剤よりなる粘着剤層を介してそれぞれ積層した。
こうして得られたアルミニウム合金圧延積層板材を、縦150mm、横82mm、コーナー部アール14.5mmの略方形状にカットして、比較例4の成形材料を作製した。
<Comparative example 4>
Si: 0.2-0.6 mass%, Mg: 0.45-0.9 mass%, Fe: 0.35 mass% or less, Cr: 0.1 mass% or less, Zn: 0.1 mass% or less An aluminum alloy rolled sheet material having a thickness of 2 mm, which is made of an aluminum alloy containing the balance Al and inevitable impurities, having a 0.2% proof stress of 145 MPa and a breaking elongation of 12%, was prepared. The plate material is obtained by cold rolling (33% reduction) of the extruded plate material, and does not have a fibrous crystal structure extending in a direction orthogonal to the thickness direction.
And the nylon resin film of thickness 30 micrometers was laminated | stacked as the coating | covering material through the adhesive layer which consists of an acrylic adhesive on both the upper and lower surfaces of an aluminum alloy rolled sheet material, respectively.
The aluminum alloy rolled laminated sheet material thus obtained was cut into a substantially rectangular shape having a length of 150 mm, a width of 82 mm, and a corner radius of 14.5 mm, thereby producing a molding material of Comparative Example 4.

<小型電子機器ケースの成形>
実施例1〜4および比較例1〜4の成形材料を、図2に示す絞り加工装置を用いて絞り加工することにより、縦140.5mm、横70.5mm、側壁高さ(成形高さ)7mm、側壁コーナー部アール2mmである小型電子機器ケースを成形した。底壁に対する側壁の角度は90°とした。
成形された各ケースを目視で観察したところ、実施例1〜4の成形材料よりなるものについては、側壁のコーナー部に皺や割れが生じておらず、また、側壁の外面には、下型との接触による傷も見られなかった。
一方、比較例1〜4の成形材料よりなるケースについては、側壁のコーナー部に皺や割れが生じていた。また、比較例1,3,4の成形材料よりなるケースの場合、それらの側壁外面に傷は見られなかったが、比較例2よりなるケースの側壁外面には、下型との接触による傷が形成されていた。
<Molding of small electronic equipment case>
By drawing the molding materials of Examples 1 to 4 and Comparative Examples 1 to 4 using the drawing apparatus shown in FIG. 2, the length is 140.5 mm, the width is 70.5 mm, and the side wall height (molding height). A small electronic device case having a size of 7 mm and a side wall corner portion of 2 mm was molded. The angle of the side wall with respect to the bottom wall was 90 °.
As a result of visual observation of each molded case, no wrinkles or cracks occurred in the corner portions of the side walls of the molding materials of Examples 1 to 4, and the lower mold was formed on the outer surface of the side walls. There were no scratches due to contact.
On the other hand, about the case which consists of a molding material of Comparative Examples 1-4, the wrinkles and the crack had arisen in the corner part of the side wall. Further, in the case of the case made of the molding material of Comparative Examples 1, 3, and 4, no scratch was found on the outer surface of the side wall, but the outer surface of the side wall of the case made of Comparative Example 2 was damaged by contact with the lower mold. Was formed.

この発明は、タブレット端末、携帯通信端末機器、ノート型パソコン、携帯電話、携帯音楽機器、デジタルカメラ等の小型電子機器のケースを成形するのに好適に利用することができる。   The present invention can be suitably used for forming a case of a small electronic device such as a tablet terminal, a mobile communication terminal device, a notebook computer, a mobile phone, a portable music device, a digital camera or the like.

(1):アルミニウム合金圧延積層板材
(2):アルミニウム合金圧延板材
(3)(4):被覆材
(30)(40):合成樹脂フィルム
(31)(41):金属箔
(32)(33)(42)(43):合成樹脂フィルム
(5):固定雌型
(6):可動雄型
(20):小型電子機器ケース
(21):底壁
(22):側壁
(22a):(側壁の)コーナー部
(1): Aluminum alloy rolled laminate
(2): Aluminum alloy rolled sheet
(3) (4): Coating material
(30) (40): Synthetic resin film
(31) (41): Metal foil
(32) (33) (42) (43): Synthetic resin film
(5): Fixed female type
(6): Movable male type
(20): Small electronic equipment case
(21): Bottom wall
(22): Side wall
(22a): Corner part (side wall)

Claims (11)

絞り加工により小型電子機器ケースを成形するためのアルミニウム合金圧延積層板材であって、0.2%耐力が200MPa以上であるアルミニウム合金圧延板材と、アルミニウム合金圧延板材の両面のうち少なくともいずれか一方の面に積層されている被覆材とで構成されており、被覆材は、合成樹脂フィルム、および金属箔の両面に合成樹脂フィルムが積層されている積層体のうちいずれか一方よりなる、小型電子機器ケース用アルミニウム合金圧延積層板材。   An aluminum alloy rolled laminated sheet material for forming a small electronic device case by drawing, wherein the 0.2% proof stress is 200 MPa or more, and at least one of both surfaces of the aluminum alloy rolled sheet material A small electronic device comprising a synthetic resin film and a laminate in which a synthetic resin film is laminated on both surfaces of a metal foil. Aluminum alloy rolled laminated sheet material for cases. アルミニウム合金圧延板材が、厚さ方向と直交する方向にのびた繊維状の結晶組織を有している、請求項1記載の小型電子機器ケース用アルミニウム合金圧延積層板材。   The aluminum alloy rolled laminated sheet material for a small electronic device case according to claim 1, wherein the aluminum alloy rolled sheet material has a fibrous crystal structure extending in a direction orthogonal to the thickness direction. アルミニウム合金圧延板材が、Mn:0.2〜0.7質量%、Mg:2.0〜5.0質量%を含有し、残部Alおよび不可避不純物からなるAl−Mn−Mg系合金、Si:0.2〜0.8質量%、Mg:0.4〜1.2質量%を含有し、残部Alおよび不可避不純物からなるAl−Si−Mg系合金、ならびにZn:4.0〜6.5質量%、Mg:0.5〜3.0質量%を含有し、残部Alおよび不可避不純物からなるAl−Zn−Mg系合金のうちいずれか1つのアルミニウム合金からなる、請求項1または2記載の小型電子機器ケース用アルミニウム合金圧延積層板材。   An aluminum alloy rolled sheet material contains Mn: 0.2 to 0.7% by mass, Mg: 2.0 to 5.0% by mass, and an Al—Mn—Mg based alloy composed of the balance Al and inevitable impurities, Si: Al-Si-Mg-based alloy containing 0.2 to 0.8 mass%, Mg: 0.4 to 1.2 mass%, the balance being Al and inevitable impurities, and Zn: 4.0 to 6.5 The mass%, Mg: 0.5-3.0 mass%, consisting of any one aluminum alloy of the Al-Zn-Mg based alloy consisting of the balance Al and inevitable impurities. Aluminum alloy rolled laminate for small electronic equipment cases. 被覆材の厚さが、アルミニウム合金圧延板材の厚さの0.05〜1.5倍である、請求項1〜3のいずれか1つに記載の小型電子機器ケース用アルミニウム合金圧延積層板材。   The aluminum alloy rolled laminated sheet material for a small electronic device case according to any one of claims 1 to 3, wherein the thickness of the covering material is 0.05 to 1.5 times the thickness of the aluminum alloy rolled sheet material. アルミニウム合金圧延板材の厚さが、0.5〜3.5mmである、請求項1〜4のいずれか1つに記載の小型電子機器ケース用アルミニウム合金圧延積層板材。   The aluminum alloy rolled laminated sheet material for a small electronic device case according to any one of claims 1 to 4, wherein the aluminum alloy rolled sheet material has a thickness of 0.5 to 3.5 mm. アルミニウム合金圧延板材の両面のうち小型電子機器ケースの外面となる面に、厚さ50〜100μmのポリエステル樹脂フィルムまたはポリアミド樹脂フィルムよりなる被覆材が積層されている、請求項1〜5のいずれか1つに記載の小型電子機器ケース用アルミニウム合金圧延積層板材。   The covering material which consists of a 50-100-micrometer-thick polyester resin film or a polyamide resin film is laminated | stacked on the surface used as the outer surface of a small electronic device case among both surfaces of an aluminum alloy rolled sheet material. The aluminum alloy rolled laminated sheet material for a small electronic device case according to one. アルミニウム合金圧延板材の両面のうち小型電子機器ケースの内面となる面に、厚さ10〜100μmのポリエチレン樹脂フィルム、ポリプロピレン樹脂フィルムまたはポリアミド樹脂フィルムよりなる被覆材が積層されている、請求項1〜6のいずれか1つに記載の小型電子機器ケース用アルミニウム合金圧延積層板材。   The covering material which consists of a 10-100-micrometer-thick polyethylene resin film, a polypropylene resin film, or a polyamide resin film is laminated | stacked on the surface used as the inner surface of a small electronic device case among both surfaces of an aluminum alloy rolled sheet material. The aluminum alloy rolled laminated sheet material for a small electronic device case according to any one of 6. 請求項1〜7のいずれか1つに記載の小型電子機器ケース用アルミニウム合金圧延積層板材を絞り加工してなり、内外両面のうち少なくともいずれか一方の面が合成樹脂フィルムまたは積層体よりなる被覆材で覆われている、被覆材付き小型電子機器ケース。   The aluminum alloy rolled laminated sheet material for small electronic device cases according to any one of claims 1 to 7, wherein at least one of the inner and outer surfaces is made of a synthetic resin film or a laminate. A small electronic device case with a covering, covered with a material. 請求項1〜7のいずれか1つに記載の小型電子機器ケース用アルミニウム合金圧延積層板材を絞り加工した後、内外両面のうち少なくともいずれか一方の面を覆っている被覆材を除去してなる、小型電子機器ケース。   After the aluminum alloy rolled laminated sheet for small electronic equipment case according to any one of claims 1 to 7 is drawn, the covering material covering at least one of the inner and outer surfaces is removed. Small electronic equipment case. 底壁と、底壁の周縁から立ち上がった側壁とを備えており、側壁の高さが0.5〜25mmであり、底壁に対する側壁の角度が90〜150°である、請求項9記載の小型電子機器ケース。   The bottom wall and a side wall rising from the periphery of the bottom wall, the height of the side wall is 0.5 to 25 mm, and the angle of the side wall to the bottom wall is 90 to 150 °. Small electronic device case. 請求項1〜7のいずれか1つに記載の小型電子機器ケース用アルミニウム合金圧延積層板材を絞り加工する、小型電子機器ケースの成形方法。   A method for forming a small electronic device case, comprising drawing the aluminum alloy rolled laminated sheet material for a small electronic device case according to any one of claims 1 to 7.
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