TW201718433A - Ceramic sintered body and production method thereof - Google Patents

Abstract

An electromagnetic wave-emitting ceramic sintered body is provided which has easier handling than a liquid and which has an efficacious effect resulting from a mineral component that has an electromagnetic wave-emitting action. This electromagnetic wave-emitting ceramic sintered body is formed from a ceramic sintered body which contains a mineral component that has an electromagnetic wave-emitting action. In the ceramic sintered body, the mineral component is immobilized in a non-eluting manner, and the ceramic sintered body has various effects resulting from the electromagnetic wave-emitting action generated by the ceramic sintered body.

Description

Ceramic sintered body and method of manufacturing same

The present invention is based on the Japanese Patent Application No. 2015-173942, the entire disclosure of which is incorporated herein by reference.

The present invention relates to a ceramic sintered body in which a beneficial mineral component is immobilized.

In water containing mineral components, there is a possibility of effects such as soil reforming, mass culture, decomposing of harmful chemicals, deodorization, air purification, etc. In the past, various mineral-containing waters and Mineral water manufacturing equipment was developed.

The inventors of the present invention have developed a mineral-containing water producing apparatus (A) including a conductive wire coated with an insulator and a mineral-imparting material (A) immersed in water to conduct a direct current to the conductive wire. The water around the conductive wire generates a water flow in the same direction as the DC current, imparts ultrasonic vibration to the water, forms a raw material mineral aqueous solution (A), and forms a raw material mineral aqueous solution (A) A far infrared ray is generated to form a far infrared ray generating means containing mineral water (A) (see Patent Document 1).

Further, the inventors of the present invention have also developed a mineral water manufacturing facility comprising a mineral water-containing water producing device (A) and a mineral-containing water producing device (B), and the mineral water-containing water producing device (B) And a plurality of water-passing containers filled with mineral material-imparting materials (B) having different types; and a water-feeding path in which a plurality of the water-passing containers are connected in series; and in a state in which a plurality of the water-passing containers are juxtaposed a bypass water passage connected to the water supply path; and a water flow switching valve provided in a branching portion of the water supply path and the bypass water passage (refer to Patent Document 2). Further, it is described that when the mineral water-producing equipment is used, it is possible to produce mineral functional water (far-infrared-generated water) having a function of generating far-infrared rays having a characteristic wavelength.

In addition, in the apparatus described in Patent Document 2, the types and blending ratios of the raw materials (mineral imparting materials) used in the mineral-containing water producing apparatuses (A) and (B) are complicated. In the meantime, it is not possible to know which kind of mineral-based material to be used, and it is possible to obtain mineral-functional water which has an effect. However, the inventors of the present invention used the mineral-functional water-making apparatus disclosed in Patent Document 2, As a result of the review, the mineral functional water produced under certain conditions has excellent pest control effects against single-celled organisms and viruses (Patent Document 3) and the body. Activation (Patent Document 4), combustion promoting action of hydrocarbons (Patent Document 5), antioxidant action (Patent Document 6), and the like.

[Previous Technical Literature] [Patent Document]

[Patent Document 1] Japanese Patent No. 4817817

[Patent Document 2] Japanese Laid-Open Patent Publication No. 2011-56366

[Patent Document 3] WO2016/043213

[Patent Document 4] WO2016/043214

[Patent Document 5] PCT/JP2016/058141

[Patent Document 6] PCT/JP2016/058362

The mineral functional waters described in the patent documents 3 to 6 and the like have a specific effective effect. However, since the mineral functional water is a liquid, there is an improvement in the convenience surface such as storage property and transportability. room.

Under the circumstances, an object of the present invention is to provide a ceramic sintered body having a beneficial effect produced by a mineral component having electromagnetic radiation, which can be easily handled compared to a liquid.

As a result of intensive studies to solve the above problems, the inventors of the present invention have found that the following invention has been completed in accordance with the above objects.

That is, the present invention is the invention described below.

<1> A ceramic sintered body in which a mineral component derived from mineral functional water is immobilized.

The ceramic sintered body according to the above aspect, wherein the ceramic sintered body is a sintered body of a clay-based powder containing the mineral component.

(3) The ceramic sintered body according to the above aspect, wherein the ceramic sintered body has a glaze layer covering the entire surface or a part of the surface.

<4> A ceramic sintered body according to any one of <1> to <3> wherein the ceramic sintered body is characterized in that the method comprises: mixing ceramic powder with a carrier a process of mixing a liquid into a clay-like mixture (i); calcining the clay-like mixture to obtain a porous calcined body (ii); and forming pores in the porous calcined body to form The ratio of 1:5 to 1:20 (weight ratio) contains mineral-containing water (A) formed by the following process (1), and mineral-containing water formed by the following process (2) (B) the mineral functional water is saturated and then dried, the mineral component is temporarily fixed to the porous calcined body (iii); and the porous calcined body after the process (iii) is further subjected to heat treatment to obtain the foregoing The process (iv) in which the mineral component is not immobilized on the ceramic sintered body of the ceramic carrier.

Process (1):

a conductive wire covered with an insulator, and a plant containing a compositae A plant material (A) impregnated with a plant material made of a plant of the genus Rosaceae and a woody plant material composed of one or more woody plants selected from maple, birch, pine, and cedar. In the water, a direct current is conducted to the conductive wire, and water around the conductive wire generates a water flow in the same direction as the direct current, and ultrasonic vibration is applied to the water to form a raw material mineral aqueous solution (A), and then, the raw material The mineral aqueous solution (A) is irradiated with far infrared rays (wavelength 6 to 14 μm) to form a mineral-containing water (A) process, wherein the mineral-donating material (A) is added to the water in an amount of 10 to 15% by weight, which is The current value and the voltage value of the direct current of the conductive line are respectively in the range of 0.05 to 0.1 A and 8000 to 8600 V;

Process (2):

A process for forming mineral-containing water (B) containing mineral water (B) by passing water through six water-passing containers, wherein the six water-passing containers are filled with inorganic mineral-affecting materials different in type (B) The first water-passing container to the sixth water-passing container connected in series: the mineral-importing material (B1) in the first water-passing container is 70% by weight of limestone and 15% by weight of coral fossil, respectively. a mixture of shells of % by weight; the mineral-imparting material (B2) in the second water-passing container contains 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon. a mixture; the mineral-imparting material (B3) in the third water-passing container is separately contained a mixture of 80% by weight of limestone, 15% by weight of coral fossils, and 5% by weight of shells; and the mineral-donating material (B4) in the fourth water-passing container contains 90% by weight of limestone and 5% by weight of coral fossils, respectively. a mixture of 5% by weight of the shell; the mineral-imparting material (B5) in the fifth water-passing container is a mixture containing 80% by weight of limestone, 10% by weight of coral fossil, and 10% by weight of shells, respectively; The mineral imparting material (B6) in the water container is a mixture containing 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shells, respectively.

The method for producing a ceramic sintered body according to the above <4>, wherein the mineral-importing material (A) is a plant material (A1-1) and a woody plant material (A2-1). The mineral-imparting material (A'-1) obtained by mixing the weight ratio in a ratio of 1:2.7 to 1:3.3, wherein the large scorpion (leaf, stem, flower), wormwood (leaf, Dry pulverized material of Compositae, which is mixed, dried, and pulverized at a ratio of 8 to 12% by weight, 55 to 65% by weight, and 27 to 33% by weight, respectively, in the stem portion and the mountain chrysanthemum (leaf portion and stem portion) And use wild rose (leaf, flower), bayberry (leaf, stem), raspberry (leaf, stem, flower) to be 17 to 23% by weight, 8 to 12% by weight, respectively 65~75% by weight of the dried pulverized material of the Rosaceae plant which is mixed, dried and then pulverized, and the dried pulverized material of the compositae and the dried pulverized material of the Rosaceae plant The plant material (A1-1) obtained by mixing 1:0.8~1:1.2 (weight ratio) is used as the raw material of the above-mentioned vegetation, from maple (leaf, stem), birch (leaf, stem) And the bark (the leaf part, the stem part, and the bark part) are mixed, dried, and pulverized at a ratio of 22 to 28% by weight, 22 to 28% by weight, and 45 to 55% by weight, respectively. The woody plant material (A2-1) composed of the pulverized material is used as the raw material of the woody plant.

(6) The method for producing a ceramic sintered body according to the above <4>, wherein the plant material of the plant is a large aphid (leaf, stem, flower), abalone (leaf, stem), mountain Chrysanthemum (leaf and stem), which are mixed at a ratio of 10% by weight, 60% by weight, and 30% by weight, dried and then pulverized, and dried pulverized plants of the compositae (leaf, flower) and arbutus (leaf, stem), raspberry (leaf, stem, flower), dried, pulverized, dried, and then pulverized at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively a plant material (A1-2) obtained by mixing 1:1 (weight ratio); and as a raw material of the aforementioned woody plant, from maple (deciduous), birch (deciduous, stem, and bark) A woody plant material (A2-) consisting of a dried pulverized material in which cedar (deciduous, stem, and bark portions) are mixed at a ratio of 20% by weight, 60% by weight, and 20% by weight, respectively, and then pulverized. 2) The mineral obtained by mixing the plant material (A1-2) with the woody plant material (A2-2) in a weight ratio of 1:5 Material imparting material (A'-2).

According to the present invention, it is possible to provide a ceramic sintered body having a beneficial effect due to a mineral component which has been immobilized.

1‧‧‧Mineral functional water manufacturing equipment

2‧‧‧Mineral water (A) manufacturing equipment

3‧‧‧Mineral water (B) manufacturing equipment

10‧‧‧Methods for the production of raw materials and mineral aqueous solutions

11, W‧‧‧ water

12‧‧‧ Mineral Substance (A)

13‧‧‧Reaction container

13a‧‧‧ wall

14‧‧‧Insulator

15‧‧‧Flexible wire

16‧‧‧Ultrasonic generation means

17‧‧‧DC power supply unit

18a, 18b, 18c‧‧ cycle path

19‧‧‧Drainage

20, 23‧‧‧ opening adjustment valve

21, 25‧‧‧Drain valve

22‧‧‧ housing trough

24‧‧‧Drainage pipe

26‧‧‧Water temperature meter

29,29a~29g, 29s, 29t‧‧‧ conductive cable

30‧‧‧ Terminal

31‧‧‧ storage container

31f‧‧‧ hook

40‧‧‧Processing container

41‧‧‧ Raw material mineral aqueous solution (A)

42‧‧‧Agitating blades

43‧‧‧ far infrared ray generation means

44‧‧‧ Mineral water (A)

45‧‧‧ Mineral water (B)

46‧‧‧ mixing tank

47‧‧‧Mineral functional water

51‧‧‧1st water container

52‧‧‧2nd water container

53‧‧‧3rd water container

54‧‧‧4th water container

55‧‧‧5th water container

56‧‧‧6th water container

51a~56a‧‧‧ Body Department

51b~56b‧‧‧Switch button

51c~56c‧‧‧Axis

51d~56d‧‧‧ cover

51f~56f‧‧‧Flange

51m~56m‧‧‧ Mineral Substance (B)

51p~56p‧‧‧迂回回路

51v~56v‧‧‧Water flow switching valve

57, 57x, 57y‧‧‧ water supply path

57a‧‧‧ Inlet

57b‧‧‧Water outlet

57c‧‧‧Filter

57d‧‧‧Automatic air valve

58‧‧‧Operation panel

59‧‧‧Signal cable

60‧‧‧ 台台

61‧‧‧ casters

62‧‧‧Level adjuster

63‧‧‧ original sink

DC‧‧‧ DC current

DW‧‧‧ tap water

R‧‧‧Water flow

Fig. 1 is a block diagram showing the schematic structure of a mineral water manufacturing facility.

Fig. 2 is a schematic view showing a part of a mineral-containing water (A) manufacturing apparatus which constitutes the mineral-functional water producing apparatus shown in Fig. 1, that is, a means for producing a mineral-containing aqueous solution.

Figure 3 is a partially omitted cross-sectional view taken along line A-A of Figure 2;

Fig. 4 is a perspective view showing a storage container of the mineral-importing material (A) used in the raw material mineral aqueous solution production means shown in Fig. 2 .

Fig. 5 is a perspective view showing a reaction state in the vicinity of a conductive wire of the raw material mineral aqueous solution manufacturing means shown in Fig. 2.

Fig. 6 is a schematic cross-sectional view showing a far infrared ray irradiation apparatus which is a part of a mineral water (A) manufacturing apparatus which constitutes the mineral water manufacturing apparatus shown in Fig. 1.

Fig. 7 is a block diagram showing a mineral-containing water (B) manufacturing apparatus constituting the mineral-functional water producing apparatus shown in Fig. 1.

Figure 8 is a view showing the construction of the mineral water manufacturing equipment shown in Figure 1. Front view of a mineral water (B) manufacturing facility.

Fig. 9 is a side view showing the apparatus for producing mineral-containing water (B) shown in Fig. 8.

Fig. 10 is a partially omitted perspective view showing the structure of the apparatus for producing mineral-containing water (B) shown in Fig. 8.

Fig. 11 is a side view showing a water-passing container constituting the apparatus for producing mineral-containing water (B) shown in Fig. 8.

Fig. 12 is a graph showing the ratio of the emission of the ceramic sintered body containing the mineral component (Example 1) and the ceramic sintered body (control sample) to the black body at 25 °C.

In the following, the present invention is described in detail with reference to the embodiments, and the present invention is not limited to the embodiments described below, and can be arbitrarily changed without departing from the scope of the invention.

<1. Electromagnetic wave radioactive ceramic sintered body>

The present invention relates to a ceramic sintered body composed of a ceramic sintered body containing a mineral component derived from mineral functional water (hereinafter referred to as [ceramic sintered body of the present invention]). In addition, the mineral component of the ceramic sintering system of the present invention is immobilized on the so-called [non-lead-type ceramics] which is a ceramic sintered body which becomes a base material without being eluted.

In the present specification, [mineral functional water] means water containing a mineral component and capable of producing at least one or more effective effects.

Further, in the present specification, [mineral-containing water] means raw material water in a previous stage when mineral water is produced, and mineral-containing water also contains a mineral component. The details of the method for producing the mineral functional water of the present invention will be described later. Furthermore, mineral-containing water itself may have effective efficacy or may not have effective efficacy.

In addition, in the present specification, [mineral component] does not mean the definition of minerals in a narrow sense, that is, [inorganic components (including trace elements) other than four elements (carbon, hydrogen, nitrogen, oxygen)], but The aspect in which the inorganic component coexists may also include the aforementioned four elements (carbon, hydrogen, nitrogen, oxygen) excluding the narrow definition. Therefore, for example, [a mineral component derived from a plant] is also a concept including an inorganic component derived from a plant such as calcium and an organic component derived from a plant.

In addition, examples of the inorganic component (constituting the mineral component) include sodium, potassium, calcium, magnesium, and phosphorus. Examples of the trace element include iron, zinc, copper, manganese, iodine, selenium, and chromium. And molybdenum, etc., but are not limited to this.

In the ceramic sintered body of the present invention, the mineral component is contained in the ceramic sintered body serving as the base material in a state of being immobilized without being eluted. Here, the state in which [the mineral component is immobilized in a non-sedimented state] is a state in which the mineral component is substantially not deposited and remains in the ceramic sintered body when the intended ceramic sintered body is brought into contact with water. kind.

That is, the ceramic sintered body of the present invention is clearly different from the mineral component-solubilized ceramic material in which the mineral component is immobilized. Here, [the mineral component is immobilized by elution] means that the target ceramic material is in contact with an extraction solvent (generally a solvent mainly composed of water). At the time, the mineral component gradually dissolves and eventually does not remain in the state of the ceramic material (except for the inevitable residual component).

The electromagnetic wave radioactivity of the ceramic sintered body of the present invention is measured by the following method, and the [radiation rate] and the [spectro-radiation rate] are measured, and the ceramic sintered body containing the mineral component to be measured and the mineral-free component are not contained. The spectroscopic spectroscopy spectrum of the ceramic sintered body (blank) was compared.

Here, the [radiation rate] means the ratio of the radiation emittance of the radiator to the radiation emittance of the black body at the same temperature as the radiator (JIS Z 8117), and [the spectral emissivity] means when The emissivity of the black body of the temperature is set to the emission ratio of the sample of 100%. Furthermore, the sample to be evaluated has a characteristic spectroradiance spectrum. The measurement method of the spectroradiance spectrum is defined by JIS R 180, and can be measured by an emissivity measuring system using Fourier transform type infrared spectrophotometry (FTIR) having a device structure according to JIS R 180. A far infrared ray radiation rate measuring device (JIR-E500) manufactured by JEOL Ltd. is preferable as an example of the emissivity measuring system. Specific examples of the method for measuring the spectroscopic spectroscopy spectrum of the ceramic sintered body of the present invention, evaluation of electromagnetic wave radiation, and the like will be described later.

The mineral component immobilized in the ceramic sintered body of the present invention may be a mineral component that generates a beneficial electromagnetic wave radiation when it is immobilized on a ceramic carrier, but is formed to be 1:5 to 1: The ratio of 20 (weight ratio) contains mineral-containing water (A) formed by the following process (1), and minerals formed by the following process (2) The mineral component of the mineral water of the quality water (B) is preferred.

In addition, the mineral component derived from [mineral functional water] refers to a mineral component remaining after the solvent component is removed from the target mineral water. However, as described above, the mineral component derived from a plant contains not only an inorganic component but also an organic component derived from a plant.

Process (1):

a conductive material covered with an insulator, a plant material composed of a plant of the family Asteraceae, and a plant of the family Rosaceae, and one or more woody plants selected from maple, birch, pine, and cedar. The mineral-imparting material (A) of the woody plant material is immersed in water to conduct a direct current to the conductive wire, and the water around the conductive wire generates a water flow in the same direction as the direct current, thereby giving the water a super The sound wave vibrates to form a raw material mineral aqueous solution (A), and then the raw material mineral aqueous solution (A) is irradiated with far infrared rays (wavelength 6 to 14 μm) to form a mineral-containing water (A) process, wherein the mineral material is supplied ( A) the amount of water added is 10 to 15% by weight, and the current value and voltage value of the direct current that is electrically connected to the conductive line are respectively 0.05 to 0.1 A and 8000 to 8600 V;

Process (2):

A process for forming mineral-containing water (B) containing mineral water (B) by passing water through six water-passing containers, wherein the six water-passing containers are filled with inorganic mineral-affecting materials different in type (B) And in series The first water-passing container to the sixth water-passing container to be connected: the mineral-importing material (B1) in the first water-passing container is 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight of shells. a mixture; the mineral-importing material (B2) in the second water-passing container is a mixture containing 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon, respectively; The mineral-imparting material (B3) in the water container is a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, respectively; and the mineral-imparting material (B4) in the fourth water-passing container is Each contains 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shell mixture; and the mineral-imparting material (B5) in the fifth water-passing container contains 80% by weight of limestone and 10% by weight, respectively. A mixture of coral fossils and 10% by weight of shells; and a mineral-imparting material (B6) in the sixth water-passing container is a mixture containing 60% by weight of limestone, 30% by weight of coral fossils, and 10% by weight of shells, respectively.

The details of the method for producing the mineral functional water will be described later together with the method for producing the ceramic sintered body of the present invention.

In the following, the mineral water of the present invention which is used in the production of the ceramic sintered body of the present invention is a mineral water (referred to as "the mineral water of the present invention"). . This hair The mineral functional water of the present invention has excellent control effects (WO2016/043213), body activation (WO2016/043214), and combustion promotion of hydrocarbons (PCT/JP2016/058141), for example, for single-celled organisms, viruses, and the like. The beneficial effects of antioxidant effects (PCT/JP2016/058362).

Further, as a common feature of the mineral functional water of the present invention, a mineral component derived from a plant (particularly, an organic component derived from a plant) may be mentioned.

One of the ideal mineral functional waters is a mineral functional water having excellent control effects on cell organisms, viruses, and the like as described in Patent Document 3 (WO2016/043213) (hereinafter referred to as [mineral functional water (1)) ]Case). The content of the method for producing the mineral functional water will be described later.

Further, the mineral functional water (1) meets all of the following requirements (i) to (iv): (i) a sample in which the weight of the mineral water is 15 parts or more and the weight of the ceramic carrier 100 is fixed. The average emission ratio (measuring temperature: 25 ° C) of the black body between the wavelengths of 5 to 7 μm and the wavelength of 14 to 24 μm is 90% or more; (ii) the functional water of the mineral is pH 12 or higher; (iii) having a single-celled organism And the prevention and treatment of at least one of the viruses; (iv) comprising mineral components derived from the plants (especially organic components derived from plants).

Further, in the case where the mineral functional water (1) has been immobilized, the average sintering ratio between the wavelength of 5 to 7 μm and the wavelength of 14 to 24 μm of the black body at 25 ° C in the ceramic sintering system of the present invention is 90% or more. . The average emission ratio between the wavelength of 5 to 7 μm of the black body and the wavelength of 14 to 24 μm at 25 ° C can be obtained from the emissivity spectrum of the sample and the black body in this wavelength region.

[Radiation ratio to black body at 25° C.] The intensity ratio of the spectroscopic spectroscopy spectrum of the spectroscopic spectroscopy spectrum (theoretical value) of the sample to be measured in the black body is shown. In other words, when the radiation intensity of the black body is 100%, the radiation intensity of the sample is expressed as the emissivity. Further, the value between the wavelengths of 5 to 7 μm and the wavelength of 14 to 24 μm in the black body radiation ratio amount curve at 25 ° C is totaled, and the average value is (between 25 ° C and the black body) wavelength between 5 and 7 μm and the wavelength. Average radiation ratio between 14 and 24 μm. Furthermore, the average radiation system between the wavelength of 5 to 7 μm and the wavelength of 14 to 24 μm at 25 ° C is equivalent to mid-infrared rays. Compared with near-infrared rays, the mid-infrared rays have a small photon energy but strong penetration, and can reach the living body. The nature of the ministry.

The ceramic sintered body of the present invention containing the mineral component derived from the mineral functional water (1), as one of its useful efficacies, has a single cell organism, a virus, etc., which is a cause of infectious diseases of humans and/or animals. Prevention and treatment. The detailed structure of the control effect of the ceramic sintered body of the present invention on single-celled organisms, viruses, and the like is still unclear, but it is presumed that it should be produced by the mineral component derived from the mineral functional water (1). Caused by electromagnetic waves.

In the present specification, [single cell organism] is a concept including bacteria, fungi, protozoa, and the like. The single-celled pathogenic bacteria such as bacteria, fungi, protozoa, etc. which can be inactivated (extinct) by the ceramic sintered body of the present invention are not particularly limited. Further, the virus to be controlled is not particularly limited as long as it is inactivated (extinct) by the ceramic sintered body of the present invention.

The method for controlling single cell organisms, viruses, and the like by the ceramic sintered body of the present invention is not particularly limited, and any single cell organism and/or virus to be treated may be administered by any method. For example, a method in which a ceramic sintered body is powdered and applied directly to a person or a domestic animal by application or spraying is used. Further, in the ceramic sintered body of the present invention, since the mineral component that has been immobilized does not elute, the durability is long. Therefore, it is also preferable to directly or pulverize the ceramic sintered body to a soil, a water area, a house, or the like for the purpose of prevention and control.

One of the ideal mineral functional waters is mineral functional water (hereinafter referred to as [mineral functional water] having a body activation action and a warming action which promote blood circulation and the like as described in Patent Document 4 (WO2016/043214). (2)])). The content of the method for producing the mineral functional water will be described later. The ceramic sintered body of the present invention containing the mineral component derived from the mineral functional water (2) has one of its useful functions as a body activation action, a warming action, and the like. Specific examples of the activation of the body function include a blood-improving action, a relaxation function of the nervous system, a promotion of metabolism, a reduction in muscle fatigue and muscle pain, and a relaxation of shoulder and neck stiffness, edema, and cold hands and feet.

The detailed structure of the ceramic sintered body of the present invention for the activation of bodily functions is still unknown, but it is presumed to be caused by electromagnetic waves generated by the mineral component derived from the mineral functional water (2). The blood improvement effect, warming action, etc., which are possessed by the mineral functional water (2), can cause other body functions to be activated.

Further, in the ceramic sintered body of the present invention, since the mineral component that has been immobilized does not elute, the durability is long. Therefore, the ceramic sintered body can be maintained in its state or pulverized, and then it can be directly or indirectly contacted with a human (or an animal or the like). Further, the body function activation method of the present invention includes both medical purpose and non-medical purposes. In addition, the ceramic sintered body of the present invention may be used in consideration of the purpose of use, individual differences (age, sex, etc.) of the subject, and then the amount of activation of the body function may be used.

One of the ideal mineral functional waters is a mineral functional water having a combustion-promoting action of a hydrocarbon type as described in Patent Document 5 (WO2016/043214) (hereinafter referred to as [mineral functional water (3)]. Happening). The content of the method for producing the mineral functional water will be described later.

The ceramic sintered body of the present invention containing the mineral component derived from the mineral functional water (3) has a possibility of providing a combustion promoting action of a hydrocarbon.

One of the ideal mineral functional waters is a mineral functional water (hereinafter referred to as [mineral functional water (4)) having an antioxidant action as described in Patent Document 6 (WO2016/058362). The content of the method for producing the mineral functional water will be described later.

The ceramic sintered body of the present invention containing the mineral component derived from the mineral functional water (4) has a possibility of providing a combustion promoting action of a hydrocarbon.

The preferred mineral water for use in the production of the ceramic sintered body of the present invention has been exemplified above, but is not limited thereto.

The mineral component of the ceramic sintered body of the present invention is contained in a ceramic sintered body (ceramic carrier) as a carrier, and is fixed without being eluted. The type of the oxide which is a raw material of the ceramic sintered body is not particularly limited as long as it is sinterable and does not impair the electromagnetic wave radiation of the mineral component derived from the mineral functional water. Examples of the oxide to be used as such a raw material include cerium oxide, titanium oxide, aluminum oxide, and a composite oxide thereof. Further, clays such as diatomaceous earth (main component: cerium oxide), kaolin (main component: cerium oxide-alumina), and hydrotalcite may be preferably used. Rocks containing such clays can also be pulverized and used as a raw material for ceramic carriers. For example, the rock powder produced by the Amakusa Oyao Island used in the examples described later is an ideal example of a ceramic carrier raw material.

The ceramic sintered body of the present invention may contain a conventional component which can be used for an oxide ceramic sintered body. The optional component is not particularly limited as long as it does not impair the object of the present invention.

The ceramic sintered body of the present invention may also have a glaze layer covering the entire surface or a part of its surface. By having the glaze layer, the elution of the mineral component immobilized on the ceramic sintered body can be further suppressed.

The type of the glaze which constitutes the glaze layer is not particularly limited, and examples thereof include a limestone, a lime glaze, a zinc glaze, and a gray glaze.

The thickness of the glaze layer is also not particularly limited, and is generally designed to have a film thickness of about 0.1 to 3 mm.

Further, when the thickness of the glaze layer is increased, the intensity of the electromagnetic wave is weakened, and therefore, the intensity of the electromagnetic wave generated by the ceramic sintered body of the present invention can be controlled by controlling the thickness of the glaze layer to be formed. Further, even in the case where the glaze layer is formed, in order to further increase the electromagnetic wave irradiation, it is preferable to contain a mineral component derived from the mineral functional water. The mineral component is preferably a mineral component derived from the mineral functional water of the present invention. The mineral component of the glaze layer can be the same mineral component as the internal ceramic sintered body, or it can be a different mineral component.

The shape of the ceramic sintered body of the present invention is not particularly limited, and it can be used in an ideal shape for application, and examples thereof include a powder, a pellet, and a plate. The size is also arbitrary and can be appropriately determined depending on the purpose of use. The molded body or the unformed mass may be pulverized and used as a powder, a granule or the like.

<2. Method for Producing Electromagnetic Wave Radioactive Ceramic Sintered Body>

In the method for producing a ceramic sintered body of the present invention, a method of immobilizing a mineral component derived from mineral functional water to a ceramic carrier by a physical action or a chemical action can be employed. An ideal production method of the ceramic sintered body of the present invention (hereinafter also referred to as "the production method of the present invention") is as follows.

The production method of the present invention is the production method of the present invention, which comprises mixing a ceramic powder for a carrier and a liquid for mixing into a clay shape. Process for the mixture (i); calcining the aforementioned clay-like mixture to obtain a porous calcined body process (ii); and the pores of the porous calcined body are formed to be 1:5 to 1:20 The ratio of (weight ratio) contains mineral water (A) formed by the following process (1), and mineral water (B) containing mineral water (B) formed by the following process (2) After the impregnation is further dried, the mineral component is temporarily fixed to the porous calcined body (iii); and the porous calcined body after the process (iii) is further subjected to heat treatment to obtain the non-solutionized fixation of the mineral component. Process (iv) for a ceramic sintered body of a ceramic carrier.

Process (1):

a conductive material covered with an insulator, a plant material composed of a plant of the family Asteraceae, and a plant of the family Rosaceae, and one or more woody plants selected from maple, birch, pine, and cedar. The mineral-imparting material (A) of the woody plant material is immersed in water to conduct a direct current to the conductive wire, and the water around the conductive wire generates a water flow in the same direction as the direct current, thereby giving the water a super The sound wave vibrates to form a raw material mineral aqueous solution (A), and then the raw material mineral aqueous solution (A) is irradiated with far infrared rays (wavelength 6 to 14 μm) to form a mineral-containing water (A) process, wherein the mineral material is supplied ( A) The amount of water added is 10 to 15% by weight, and the current value and voltage value of the direct current that is conducted to the conductive wire are 0.05 to 0.1 A and 8000 to 8600 V, respectively. Wai

Process (2):

A process for forming mineral-containing water (B) containing mineral water (B) by passing water through six water-passing containers, wherein the six water-passing containers are filled with inorganic mineral-affecting materials different in type (B) The first water-passing container to the sixth water-passing container connected in series: the mineral-importing material (B1) in the first water-passing container is 70% by weight of limestone and 15% by weight of coral fossil, respectively. a mixture of shells of % by weight; the mineral-imparting material (B2) in the second water-passing container contains 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon. The mixture; the mineral-importing material (B3) in the third water-passing container is a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells; and the mineral in the fourth water-passing container is given The material (B4) is a mixture containing 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells, respectively; and the mineral-imparting material (B5) in the fifth water-passing container contains 80% by weight of limestone, respectively. 10% by weight of coral fossil, 10% by weight of shell mixture; 6th water container Bay Minerals imparting member (B6), respectively containing 60% by weight of limestone, coral fossil 30 wt%, 10 wt% of a mixture of shells.

The details of the mineral functional water of the process (iii) will be described later.

According to the production method of the present invention, the ceramic sintered body of the present invention described above can be produced. In particular, the porous calcined body obtained in the process (ii) has many pores and can retain the mineral component derived from the mineral functional water in the pores, thereby improving the ceramic sintered body of the present invention. The content of the mineral component of the purpose.

Hereinafter, each process of the manufacturing method of this invention is demonstrated.

The process (i) is a process in which a mixing liquid (mixing dispersion medium) and a carrier ceramic powder are mixed to form a clay-like mixture.

The oxide of the raw material of the ceramic powder for the carrier is the same as the oxide described as the ceramic carrier, and has sinterability and does not impair the oxide of electromagnetic wave radiation derived from the mineral component having electromagnetic radiation. It is not particularly limited. Examples of the oxide to be used as such a raw material include cerium oxide, titanium oxide, aluminum oxide, and a composite oxide thereof. Further, a clay-based powder such as diatomaceous earth (main component: ceria), kaolin (main component: ceria-alumina), or hydrotalcite may be preferably used. Rocks containing such clays can also be pulverized as clay-based powders. For example, the rock powder produced by the Amakusa Oyao Island used in the examples described later is an ideal example of a ceramic carrier raw material.

The ceramic powder for the carrier is preferably a ceramic powder. The particle diameter of the powder is selected in a favorable range such as moldability and sinterability, and is generally 100 μm or less.

The liquid to be mixed is a liquid to be added when the ceramic powder for a carrier is mixed, and any liquid can be used. However, water or a liquid mainly composed of water is generally used. [Liquid-based liquid] A liquid containing 50% by weight or more (including 100% by weight) of water, and a component other than water, and an organic solvent having compatibility with water such as ethanol. Further, the mixing liquid may contain an optional component such as a pH adjuster in a range that does not impair the effects of the present invention.

The mixing method of the ceramic powder for the carrier and the liquid for mixing may be carried out by any method, and may be carried out by hand, or may be carried out by using a conventional mixing device.

In addition, the mixing ratio of the ceramic powder for carrier and the liquid for mixing is set in a range in which the viscosity can be maintained, and the weight of the ceramic powder for the carrier is 100 parts by weight, and the liquid for mixing is generally 5 parts by weight or more and 500 parts by weight. Hereinafter, it is preferably 10 parts by weight or more and 300 parts by weight or less.

Further, in the clay-like mixture, in addition to the carrier ceramic powder and the mixing liquid, it may contain a conventional tackifier, a pore generating agent, and a pH adjustment for use in ceramics, without damaging the effects of the present invention. Any component such as a agent.

The process (ii) is a process in which the obtained clay-like mixture is molded into a predetermined shape as needed, and then calcined (temporary firing) to obtain a ceramic calcined body having a plurality of pores.

Since the formation of the clay-like mixture is viscous, it is easy to carry out, and the appropriate shape can be controlled depending on the intended use. When it is formed into a particulate form, it can adjust to about 50-500 micrometers, for example. Also, it can make clay After drying in the state of the block, it is pulverized, and the particle size is adjusted, followed by calcination (temporary baking). In this manner, since the ceramic powder for the carrier can be formed into a clay-like mixture of an arbitrary shape and then molded and calcined, a sintered body having a desired shape can be easily obtained.

Calcination can be carried out by a conventional firing device. The calcination temperature is determined so that the obtained porous calcined body has sufficient pores and has a degree of mechanical strength which can be used in a post-process, and is determined by the type of the ceramic powder for the carrier, and is generally 500. Above °C and above 1000 °C, preferably from 700 °C to 900 °C. Further, the environment at the time of firing is not particularly limited, but is generally an atmospheric environment. The calcination time can be appropriately determined depending on the heat treatment temperature, the porosity of the object, the degree of sintering, and the like.

The process (iii) is a process in which mineral water is allowed to permeate the pores of the porous calcined body and then dried to temporarily immobilize the mineral component in the porous calcined body.

By allowing the porous calcined body to contain mineral functional water and then drying it, the mineral component contained in the mineral functional water can be contained in a larger amount.

Further, the mineral functional water will be described later together with the manufacturing method thereof.

The method of allowing the mineral water to permeate the pores of the porous calcined body is arbitrary, and for example, a method of immersing the porous calcined body in the mineral functional water is not limited thereto. Further, by repeating the operation of allowing the mineral functional water to permeate the porous calcined body, the mineral water can be permeated again after the solvent (water) evaporates, and more minerals can be obtained. The mass component is immobilized.

The amount of the mineral functional water impregnated in the porous calcined body is determined by the type and concentration of the mineral component contained in the mineral functional water, and depends on the pore physical properties and porosity of the porous calcined body, but generally The weight of the porous calcined body is 15% by weight or more.

In the process (iv), the porous calcined body after the process (iii) is further subjected to heat treatment (true firing) to obtain a ceramic sintered body in which the mineral component is immobilized on the ceramic carrier without being eluted.

The porous calcined body is sintered by the heat treatment of the process (iv) to form a sintered body, and the mineral component temporarily fixed to the porous calcined body is more strongly immobilized, and finally, the mineral component is formed into a non-leaching. .

The heat treatment can be carried out by a conventional firing device. The heat treatment temperature is generally 1000 ° C or higher, and preferably 1200 ° C or higher. When the heat treatment temperature is too low, the sinterability of the ceramic sintered body is insufficient, or the fixing strength of the mineral is insufficient, and the mineral component cannot be formed into non-leaching, which may cause sequestration of water. Further, the heat treatment time can be appropriately selected depending on the degree of the desired degree of sintering. Further, the environment at the time of heat treatment is not particularly limited, but is generally an atmospheric environment.

In the process (iv), the process of forming the glaze layer on the outer layer by heat-treating the glaze on the entire surface or part of the surface of the porous calcined body may also be employed. As described above, by having the glaze layer, the elution of the mineral component immobilized on the ceramic sintered body can be further suppressed. The type of the glaze constituting the glaze layer is not particularly limited, and examples thereof include a lime glaze, a lime glaze, a zinc glaze, and a gray glaze. The glaze layer can be porous The calcined body is formed by heat treatment in a state where glazing is performed by a dipping method, a spray method, or the like.

The coating amount of the glaze layer can be determined by considering the thickness of the glaze layer, and the film thickness is generally designed to be about 0.1 to 3 mm.

Further, when the thickness of the glaze layer is increased, the intensity of the electromagnetic wave is weakened, and therefore, the intensity of the electromagnetic wave generated by the ceramic sintered body of the present invention can be controlled by controlling the thickness of the glaze layer to be formed. Further, even in the case where the glaze layer is formed, in order to further increase the electromagnetic wave irradiation, it is preferable that the glaze layer contains a mineral component having electromagnetic wave radiation. The mineral component is preferably a mineral component derived from the mineral functional water of the present invention. The mineral component of the glaze layer can be the same mineral component as the internal ceramic sintered body, or it can be a different mineral component.

The amount of the mineral component contained in the glaze layer is determined in a range capable of forming a glaze layer which can suppress the density of elution of the mineral component from the inside of the ceramic sintered body. For example, the glaze layer accounts for about 1 to 20% by weight of the total amount of the mineral component immobilized in the ceramic sintered body of the present invention.

<3. Method for producing mineral functional water>

The mineral functional water (hereinafter referred to as "mine functional water of the present invention") of the mineral component used in the production of the ceramic ceramic sintered body of the present invention is not particularly limited, but is preferably The apparatus disclosed in the above-mentioned Patent Document 2 (JP-A-2011-56366) can be used, and the method disclosed in the document can be used. Manufacturing.

In addition to the production method of the production apparatus, the production method is not particularly limited as long as the mineral functional water containing the beneficial mineral component can be obtained.

In the following, a preferred embodiment of the method for producing the mineral functional water of the present invention using the apparatus disclosed in Patent Document 2 (JP-A-2011-56366) will be described with reference to the drawings. In the following description, for example, various mineral functional waters can be produced by appropriately changing the manufacturing conditions including raw materials.

As shown in Fig. 1, the mineral water-producing apparatus 1 is provided with: a mineral-containing water (A) manufacturing apparatus 2; a mineral-containing water (B) manufacturing apparatus 3; and a mixing tank 46 as a mixing means, the mixing tank The mineral-containing water (B) 45 produced in the mineral-containing water (B) manufacturing apparatus 3 is mixed with the mineral-containing water (A) 44 produced in the mineral-containing water (A) manufacturing apparatus 2 to form Mineral function water 47.

In the mineral water (A) manufacturing apparatus 2, the water 11 supplied from the water pipe and the mineral material (A) 12 (see FIG. 4) to be described later are used as raw materials to form a raw material of the raw material mineral aqueous solution (A) 41. The mineral aqueous solution production means 10; and the far-infrared rays generating means 43 which irradiates the far-infrared rays with the raw material mineral aqueous solution (A) 41 obtained by the raw material mineral aqueous solution manufacturing means 10, and changes to the mineral-containing water (A) 44.

The mineral water (B) manufacturing apparatus 3 has a function of forming a water containing a mineral component from a mineral-containing material by passing water W supplied from the outside through the water-passing containers 51 to 56. Mineral water (B) 45 function.

Hereinafter, the mineral-containing water (A) manufacturing apparatus 2 and the mineral-containing water (B) manufacturing apparatus 3 will be described in detail.

(3-1: Mineral-containing water (A) manufacturing device)

Next, a mineral-containing water (A) manufacturing apparatus 2 constituting the mineral-functional water producing apparatus 1 shown in Fig. 1 will be described with reference to Figs. 2 to 6 . As shown in Fig. 1, the mineral water (A) manufacturing apparatus 2 forms a raw material mineral aqueous solution by using the water 11 supplied from the water pipe and the mineral material (A) 12 (see Fig. 4) to be described later as a raw material. (A) 41 raw material mineral aqueous solution manufacturing means 10 (refer to FIG. 2); and the mineral-containing water (A) solution 41 obtained by the raw material mineral aqueous solution manufacturing means 10 is irradiated with far infrared rays, and is changed into mineral-containing water. The far infrared ray generating means 43 of (A) 44 (refer FIG. 6).

As shown in FIG. 2 and FIG. 3, the raw material mineral aqueous solution production means 10 includes a reaction container 13 that can accommodate the water 11 and the mineral-importing material (A) 12, and is immersed in the reaction container in a state of being covered with the insulator 14. a conductive line 15 in the water 11 in the 13; an ultrasonic generating means 16 for imparting ultrasonic vibration to the water 11 in the reaction vessel 13, a direct current power source means 17 for conducting a direct current DC to the conductive line 15, and a conductive line The water 11 around the 15 generates circulation paths 18a and 18b and a circulation pump P of the means of the water flow R in the same direction as the direct current DC. The DC power supply unit 17, the ultrasonic generating means 16 and the circulating pump P are all operated by power supply from a general commercial power source.

The reaction container 13 has an inverted conical tubular shape with an upper opening, and a drain port 19 is provided at a bottom portion corresponding to the apex thereof, and a circulation path 18a communicating with the suction port P1 of the circulation pump P is connected to the drain port 19 at the drain port. Immediately below the 19, an opening degree adjusting valve 20 for adjusting the amount of displacement toward the circulation path 18a, and a drain valve 21 for discharging water or the like in the reaction vessel 13 are provided.

A proximal end portion of the circulation path 18b is connected to the discharge port P2 of the circulation pump P, and a distal end portion of the circulation path 18b is connected to the accommodation groove 22. A proximal end portion for conveying the water 11 in the storage tub 22 to the circulation path 18c in the reaction container 13 is connected in the vicinity of the bottom of the outer periphery of the housing groove 22, and the distal end portion of the circulation path 18c is disposed in the opening facing the reaction container 13. The location. An opening degree regulating valve 23 for adjusting the amount of water sent from the storage tub 22 to the reaction container 13 is provided in the circulation path 18c.

At the bottom of the storage tub 22, a drain pipe 24 having a drain valve 25 and a water temperature gauge 26 is connected in a hanging manner. When the drain valve 25 is opened as needed, the water in the storage tub 22 can be discharged from the lower end portion of the drain pipe 24. At this time, the temperature of the water 11 passing through the drain pipe 24 can be measured by the water temperature gauge 26.

As shown in FIG. 5, a plurality of conductive cables 29 (29a to 29g) composed of a conductive wire 15 and an insulator 14 covering the conductive wire are arranged in a ring shape so as to have different depths in the reaction container 13 At these positions, the annular conductive cables 29a to 29g are disposed slightly coaxially with the reaction container 13. The inner diameters of the respective conductive cables 29a to 29g are gradually reduced in diameter in accordance with the inner diameter of the reaction container 13 having an inverted cone shape, and are formed to have inner diameters corresponding to the respective arrangement portions. Due to each conductivity The cables 29a to 29g are detachably connected to the insulating terminal device 30 provided in the wall body 13a of the reaction container 13, so that the annular portion can be removed or attached from the terminal device 30 as needed.

In the portion corresponding to the axial center of the reaction container 13, a bottomed cylindrical storage container 31 formed of an insulating mesh body is disposed, and the storage container 31 is filled with the mineral providing material (A) 12. The storage container 31 is detachably locked to the upper edge portion of the wall body 13a of the reaction container 13 by a hook 31f provided on the upper portion thereof.

As shown in Fig. 2, the outer circumferences of the circulation paths 18a and 18b are spirally wound around the conductive cables 29s and 29t, respectively, and DC current DC is supplied from the DC power supply unit 17 to the conductive cables 29s and 29t. The direction of the direct current DC flowing through the conductive cables 29s and 29t is set to substantially coincide with the direction of the water flow flowing through the circulation paths 18a and 18b.

In the raw material mineral aqueous solution production means 10, a predetermined amount of water 11 is placed in the reaction container 13, that is, in the storage tank 22, and the storage container 31 filled with the mineral-importing material (A) 12 is attached to the reaction container 13. After the center, the circulation pump P is actuated, and the opening degree adjustment valve 20 at the bottom of the reaction vessel 13 and the opening degree adjustment valve 23 of the circulation path 18c are adjusted, and the water 11 is passed from the reaction vessel 13 through the drain port 19, the circulation path 18a, The circulation pump P, the circulation path 18b, the storage tank 22, and the circulation path 18c are circulated again so as to return to the upper portion of the reaction container 13. When the DC power source device 17 and the ultrasonic wave generating means 16 are actuated, the mineral component starts from the elution reaction of the mineral material (A) 12 in the storage container 31 toward the water 11.

The working conditions in the case of producing the raw material mineral aqueous solution (A) using the raw material mineral aqueous solution production means 10 are not particularly limited. However, in the present embodiment, the raw material mineral aqueous solution (A) is produced under the following working conditions.

(1) A direct current DC of a voltage of 8000 to 8600 V and a current of 0.05 to 0.1 A is conducted to the conductive cables 29, 29s, and 29t. Further, the insulator 14 constituting the conductive cable 29 and the like is formed of a polytetrafluoroethylene resin.

(2) The mineral-importing material (A) 12 filled in the reaction container 13 is filled with water 11 at a mass ratio of 10 to 15%. The specific description of the mineral-imparting material (A) 12 will be described later.

(3) The water 11 may be a catalyst containing a DC current DC. For example, sodium carbonate which dissolves about 10 g of electrolyte for 100 liters of water can be used, and if it is groundwater, it can be used as it is.

(4) The ultrasonic wave generating means 16 is a means for supersonic waves having a frequency of 30 to 100 kHz, and the ultrasonic wave generating portion (not shown) is placed in direct contact with the water 11 in the reaction container 13 to oscillate the ultrasonic wave. Means 16.

When the raw material mineral aqueous solution manufacturing apparatus 10 is operated under such conditions, the water flow R sucked by the drain port 19 while rotating in the left spiral direction is generated in the reaction container 13, and the water 11 discharged from the drain port 19 passes through the foregoing. The state in which the circulation paths 18a, 18b, and the like are returned to the reaction vessel 13 again continues.

Therefore, by the stirring action of the water flow R, the action of the direct current flowing through the conductive cable 29, and the ultrasonic generating means 16 for the water 11 By imparting ultrasonic vibration, the mineral component can be rapidly eluted from the mineral-importing material (A) 12 into the water 11, and the raw mineral aqueous solution (A) in which the desired mineral component is appropriately dissolved can be efficiently produced. .

In the raw material mineral aqueous solution production means 10, a plurality of conductive cables 29a to 29g which are formed in an annular shape are disposed on substantially the same axis in the reaction container 13, and a water flow R which is rotated in the left-hand spiral direction is generated in the reaction container 13. Therefore, a relatively dense electric field can be formed in the reaction container 13 having a constant volume, and the raw material mineral aqueous solution (A) can be efficiently produced in the reaction container 13 having a small volume.

Further, since the reaction container 13 has an inverted conical tubular shape, the water flow R flowing along the plurality of electrically conductive cables 29a to 29g which are annular in shape is relatively easily and stably generated, whereby the elution of the mineral component can be promoted. Further, since the flow rate of the water R flowing in the inverted conical tubular reaction vessel 13 increases toward the drain port 19 at the bottom of the reaction vessel 13, the frequency of contact with the mineral-importing material (A) 12 is also Increasing, the mass of the mineral that captures and ionizes the free electrons e present in the water 11 can be increased.

Further, since the storage tank 22 that discharges the water 11 while being stored is provided between the circulation paths 18b and 18c, the mineral elution reaction can be performed while circulating the water 11 exceeding the volume of the reaction container 13. . Therefore, the raw material mineral aqueous solution (A) can be mass-produced efficiently.

When the circulating pump P is continuously operated to continue the reaction, the raw material minerals which are eluted by the mineral components are finally dissolved. Liquid (A). The water can be controlled by the size of the drain port 19 at the bottom of the reaction vessel 13, the amount of circulating water, the shape of the reaction vessel 13 (especially the angle γ formed by the axis C and the wall 13a as shown in Fig. 2), and the like. In the state of occurrence of the free electrons e in 11, the water content of the mineral component can be controlled by the action of the free electrons e on the mineral-imparting material (A) 12.

After the raw material mineral aqueous solution (A) is formed, the raw mineral aqueous solution (A) 41 is transferred to the processing container 40 as shown in FIG. In this case, the residue of the mineral-imparting material (A) 12 leaking from the storage container 31 in the reaction container 13 can be discharged from the drain valve 21 located at the bottom of the reaction container 13. The raw material mineral aqueous solution (A) 41 accommodated in the processing container 40 is irradiated with far infrared rays by the far infrared ray generating means 43 disposed in the processing container 40 while being slowly stirred by the stirring blade 42.

Further, the far-infrared ray generating means 43 may be a far-infrared ray having a wavelength of about 6 to 14 μm, and may be a heating method because it is not affected by materials, generating means, or the like. However, it is desirable to have a radiation ratio of 85% or more for black body radiation in a wavelength region of 6 to 14 μm at 25 °C.

In the raw material mineral aqueous solution manufacturing apparatus 10 shown in FIG. 2, the mineral-containing material (A) can be contained by the stirring action of the water flow R, the action of the direct current DC flowing through the conductive wire 15, and the ultrasonic vibration. The mineral component in 12 is rapidly dissolved in the water 11, and the desired mineral component is appropriately dissolved, whereby the mineral aqueous solution 41 can be efficiently produced.

Further, in the far-infrared ray generating means 43 shown in FIG. 6, by irradiating the mineral aqueous solution 41 with far-infrared rays, the dissolved mineral component is fused with water molecules to form a mineral-containing water having improved electronegativity (A) 44. .

In the mineral-containing water (A) manufacturing apparatus 2, the mineral-containing water (A) 44 formed by the above-described process is transported to the mixing tank 46 via the water supply path 57y as shown in Fig. 1, and is mixed in the mixing tank 46. The mineral-containing water (B) 45 sent from the mineral water (B) manufacturing apparatus 3 is mixed.

Hereinafter, the mineral-imparting material (A) will be described.

The mineral-improving material (A) is a plant material containing a plant of the genus Compositae and a plant of the family Rosaceae; and one or more woody plants selected from maple, birch, pine, and saplings. The woody plant material that is composed. The site to be used is preferably a part which is easy to elute mineral components such as leaves, stems, flowers, and bark, and can be used as it is, or a dried product can be used.

Further, in addition to the grass plants of Compositae and Rosaceae, other grass plants may be contained, but only grass plants of the family Asteraceae and Rosaceae are preferred.

An example of the mineral-imparting material (A) is a mineral-imparting material (A'-1). By using the mineral-imparting material (A'-1), it is possible to obtain mineral functional water (corresponding to the aforementioned mineral functional water (1)) having a control action against at least one of a single-celled organism and a virus.

Minerals-giving material (A'-1) is used: will be large (leaf, stem) Department, flower part), wormwood (leaf part, stem part), mountain chrysanthemum (leaf part and stem part) are mixed at a ratio of 8 to 12% by weight, 55 to 65% by weight, and 27 to 33% by weight, respectively. a dried pulverized material of a compositae plant which is pulverized after drying; and the use of wild rose (leaf, flower), arbutus (leaf, stem), raspberry (leaf, stem, flower) 17~23% by weight, 8-12% by weight, and 65-75% by weight of the dried pulverized material of the Rosaceae plant which is mixed, dried and then pulverized, and the dried pulverized material of the compositae and the dried smashed plant of the Rosaceae plant The plant material (A1-1) obtained by mixing 1:0.8~1:1.2 (weight ratio) is used as the raw material of the aforementioned plant, from maple (leaf, stem), birch (leaf, stem) The sap (and the bark) and the cedar (leaf, stem, and bark) are mixed at a ratio of 22 to 28% by weight, 22 to 28% by weight, and 45 to 55% by weight, respectively, and then pulverized. The woody plant material (A2-1) composed of the dried ground material is used as the raw material of the woody plant, and the weight ratio of the grass plant material (A1-1) to the woody plant material (A2-1) is 1:2.7~ 1 3.3 Mineral way to obtain the mixing timber imparted.

In the above-mentioned mineral-imparting material (A'-1), in particular, as the raw material of the aforementioned plant, the cockroach (leaf, stem, flower), wormwood (leaf, stem), and mountain daisy (leaf) The dried parts of the compositae, which are mixed, dried, and pulverized at a ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, are the wild sorghum (leaf, flower) and water yang Drying of rose (leaf, stem), raspberry (leaf, stem, and flower) at a ratio of 20% by weight, 10% by weight, and 70% by weight, dried, and then pulverized a plant material (A1-1) obtained by mixing the pulverized material at a ratio of 1:1 (weight ratio); and as a raw material of the aforementioned woody plant, from maple (leaf, stem), birch (leaf, stem) And the sap (the leaf part, the stem part, and the bark part) are mixed, dried, and pulverized by a dry pulverized product at a ratio of 25% by weight, 25% by weight, and 50% by weight, respectively. The woody plant material (A2-1) is preferably obtained by mixing the plant material (A1-1) and the woody plant material (A2-1) in a weight ratio of 1:3. .

For example, the RIKEN Techno System Co., Ltd. product [P-100 (product number)] is used as the plant material (A1-1) which is a raw material of the mineral-based material (A'-1). For example, [P-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. is used as the woody plant material (A2-1). In addition, the mineral functional water CAC-717 [Tera Protect (product name), CAC-717 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. is [P-100 (product number)], [P-200] (Product No.)] Mineral functional water.

Further, as an example of another preferable mineral-imparting material (A), a mineral-imparting material (A'-2) can be mentioned. By using the mineral-imparting material (A'-2), mineral functional water (corresponding to the aforementioned mineral functional water (2)) having body activation can be obtained.

The mineral-improving material (A'-2) is a mineral-imparting material, that is, as a raw material of the plant, the cockroach (leaf, stem, flower), wormwood (leaf, stem) The dried pulverized wild rose (leaf, flower) of the compositae, which is mixed with the ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, and then pulverized. , Rosaceae (leaf part, stem part), raspberry (leaf part, stem part, flower part) are mixed, dried and then pulverized in a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively. a dry pulverized material obtained by mixing 1:1 (weight ratio) of the plant material (A1-2); and as a raw material of the aforementioned woody plant, from maple (deciduous), birch (deciduous, stem, and Woody plant material composed of dried and pulverized material which is mixed, dried, and pulverized at a ratio of 20% by weight, 60% by weight, and 20% by weight, respectively, in the bark portion, cedar (deciduous, stem, and bark) (A2-2), obtained by mixing the plant material (A1-2) and the woody plant material (A2-2) in a weight ratio of 1:5 Minerals given material.

For example, the RIKEN Techno System Co., Ltd. product [P-101 (product) is used as the raw material of the plant material (A1-2) which is a raw material of the mineral-based material (A'-2). In the case of the woody plant material (A2-2), for example, [P-201 (product number)] manufactured by Riken Chemical Technology Co., Ltd. is mentioned. In this way, the mineral water A20ACA-717 [Tera Support (trade name), A20ACA-717) manufactured by Riken Chemical Technology Systems Co., Ltd. can be obtained. Product number)].

Further, as an example of another preferable mineral-imparting material (A), a mineral-imparting material (A'-3) can be mentioned. By using the mineral-imparting material (A'-3), it is possible to obtain mineral functional water (corresponding to the aforementioned mineral functional water (3)) having a combustion promoting action in the hydrocarbon.

The mineral-improving material (A'-3) is a mineral-improving material, that is, as a plant material of the above-mentioned plant, a large scorpion (leaf, stem, flower), wormwood (leaf, stem) The dried pulverized wild rose (leaf, flower) of the compositae, which is mixed with the ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, and then pulverized. , Rosaceae (leaf part, stem part), raspberry (leaf part, stem part, flower part) are mixed, dried and then pulverized in a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively. The dried pulverized material is obtained by mixing 1:1 (weight ratio) of the plant material (A1-1); and as the woody plant material, by maple (leaf and stem), birch (leaf) , the stem portion, and the bark portion, and the sap tree (leaf portion, stem portion, and bark portion) are mixed, dried, and pulverized at a ratio of 25% by weight, 25% by weight, and 50% by weight, respectively. a woody plant material (A2-1); and as activated carbon, an activated carbon powder (A3-1) which carbonizes a coconut shell at an activation temperature of 1000 ° C, The wood plant material (A1-1) and the woody plant material (A2-1) are mixed in a weight ratio of 1:3, and the activated carbon powder (A3- 1) A mineral imparting material obtained by mixing in a form of 2 to 8 parts by weight.

Here, the activated carbon powder (A3-1) is an activated carbon powder obtained by carbonizing a coconut shell at an activation temperature of 1000 ° C in an inert gas atmosphere, and when it is added to pure water in a form of 10% by weight. The pH is formed into an activated carbon powder of 9 to 11, preferably 9.5 to 10.5, more preferably pH 10.

Further, when the coconut shell is activated at a low temperature, the alkali tends to become strong, but when activated at 1000 ° C, it is formed into a weakly alkaline state.

The addition amount of the activated carbon powder (A3-1) is added to the mineral-imparting material (A-1) to form a pH of 11 to 12 when the mineral-containing water (A) and the mineral-containing water (B) are mixed. When the mixture of the plant material (A1-1) and the woody plant material (A2-1) is 100 parts by weight in a weight ratio of 1:3, it is formed into a range of 2 to 8 parts by weight. .

For example, the RIKEN Techno System Co., Ltd. product [P-100 (product number)] is used as the plant material (A1-1) which is a raw material of the mineral-based material (A'-3). In the case of the woody plant material (A2-1), for example, [P-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd., and the activated carbon powder (A3-1), for example, Riken Chemical Co., Ltd. Technical System Co., Ltd. [AS-100 (Product No.)].

Further, as an example of another preferable mineral-importing material (A), a mineral-imparting material (A'-4) can be mentioned. By using the mineral-giving material (A'-4), it is possible to obtain mineral functional water with antioxidant activity. (Equivalent to the aforementioned mineral functional water (4)).

The mineral-improving material (A'-4) is a mineral-imparting material, that is, as a plant material of the above-mentioned plant, a large aphid (leaf, stem, flower), abalone (leaf, stem) The dried pulverized wild rose (leaf, flower) of the compositae, which is mixed with the ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, and then pulverized. , Rosaceae (leaf part, stem part), raspberry (leaf part, stem part, flower part) are mixed, dried and then pulverized in a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively. The dried pulverized material is obtained by mixing 1:1 (weight ratio) of the plant material (A1-2); and as the woody plant material, it is composed of maple (leaf, stem) and birch (leaf) , the stem portion, and the bark portion, and the sap tree (leaf portion, stem portion, and bark portion) are mixed, dried, and pulverized at a ratio of 20% by weight, 60% by weight, and 20% by weight, respectively. The woody plant material (A2-2) and the volcanic sulfur (A3-2) as a sulfur raw material, and the plant material (A1-2) and the wood plant Starting material (A2-2) to form a weight ratio of 1: 5 by mixing the volcanic sulfur (A3-2) is formed from 2 to 8 weight portions embodiment is obtained by mixing the mineral material imparted.

Here, volcanic sulfur (A3-2) is a sulfur-containing substance present in a volcano. The volcanic sulphur (A3-2) is dissolved or dispersed when the water is circulated, and the sulphur component is dissolved in the mineral-containing water (A). Volcano When sulfur (A3-2) is used as sulfur, it is preferable to strongly produce the anti-inflammatory action and anti-oxidation characteristic peculiar to the mineral functional water of the present invention. It is preferred to pulverize the volcanic sulfur (A3-2) to form a powder.

The volcanic sulfur (A3-2) is added in an amount of 100 parts by mixing the plant material (A1-2) with the woody plant material (A2-2) in a weight ratio of 1:5. In the case of the part, it is formed in the range of 2 to 8 parts by weight.

As the grass plant material (A1-2), it is preferable to use [P-101 (product number)] manufactured by RIKEN Techno System Co., Ltd. as a woody plant material (A2-2). [P-201 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. was used. Further, as the volcanic sulfur (A3-2), [S-100 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.

(3-2: Mineral water (B) manufacturing equipment)

Next, the structure and function of the mineral-containing water (B) manufacturing apparatus 3 will be described with reference to Figs. 1 and 7 .

As shown in Fig. 1 and Fig. 7, the mineral water (B) manufacturing apparatus 3 is provided with a first water-passing container 51 to a sixth water-passing container 56 which are filled with mineral-specific material (B) of different types; The water supply path 57 that connects the first water-passing container 51 to the sixth water-passing container 56 in series, and is connected to the water-passing path of the water-feeding path 57 in a state in which the first water-passing container 51 to the sixth water-passing container 56 are arranged in parallel with each other. 51p~56p; and each is located in each roundabout 51p to 56p and the water flow switching valves 51v to 56v of the branching portion of the water supply path 57.

The switching operation of the water flow switching valves 51v to 56v can be performed by operating the six switching knobs 51b to 56b provided on the operation panel 58 connected to the water flow switching valves 51v to 56v by the signal cable 59. Since the six switching buttons 51b to 56b and the six water flow switching valves 51v to 56v correspond to individual numbers, when one of the switching buttons 51b to 56b is operated, the water flow switching valve 51v of the corresponding number is operated. The 56v is switched to change the direction of the water flow.

Further, the first water-passing container 51 is filled with a mineral-imparting material (B) 51m containing cerium oxide and iron oxide, and the second water-passing container 52 is filled with a cerium oxide-containing activated carbon ore. The material-imparting material (B) is 52 m, and the third water-passing container 53 is filled with a mineral-imparting material (B) 53 m containing cerium oxide and titanium nitride, and is filled in the fourth water-passing container 54 with two The mineral-supporting material (B) of cerium oxide and calcium carbonate is 54 m, and the fifth water-passing container 55 is filled with a mineral-imparting material (B) containing cerium oxide and magnesium carbonate (B) 55 m, and is in the sixth water-passing container 56. The inside was filled with a mineral-imparting material (B) containing cerium oxide and calcium phosphate (56 m).

Here, the mineral-imparting material (B) is 51 m to 56 m, and it is preferable to be produced by mixing raw materials containing limestone, coral fossils, and shells as a base material.

First, the components contained in limestone, coral fossils, and shells were analyzed, and the amounts of cerium oxide, iron oxide, activated carbon, titanium nitride, calcium carbonate, magnesium carbonate, and calcium phosphate contained in each of them were evaluated. Further, based on the content of each component Precisely, limestone, coral fossils and shells are mixed to produce minerals (B) 51m~56m.

In addition, it is expected that the mineral-based material (B) 51m to 56m is controlled by the mixing ratio of limestone, coral fossil, and shell, but the limestone, coral fossil, and shell as raw materials may have a relationship with the place of origin. Since the content of the contained component is insufficient, cerium oxide, iron oxide, activated carbon, titanium nitride, calcium carbonate, magnesium carbonate or potassium phosphate may be added as needed. In particular, activated carbon is rarely contained in limestone, coral fossils, and shells, so it is generally added.

The mineral-importing material (B) is 51 m to 56 m, and the mineral-imparting material (B1) in the first water-passing container 51 contains 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight of shells. a mixture; the mineral-importing material (B2) in the second water-passing container 52 is a mixture containing 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon; The mineral material supply material (B3) in the water-passing container 53 is a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, respectively; and the mineral in the fourth water-passing container 54 is imparted. The material (B4) is a mixture containing 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells, respectively; and the mineral-imparting material (B5) in the fifth water-passing container 55 is 80% by weight, respectively. Limestone, 10% by weight coral fossil, 10 weight a mixture of shells of %; the mineral-imparting material (B6) in the sixth water-passing container 56 is a mixture containing 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shells, respectively. When the substance water (A) is mixed, the mineral-containing water (B) having an excellent pest control effect can be obtained.

In particular, it is preferable that the limestone, the coral fossil, and the shell used for the mineral-imparting materials (B1) to (B6) are the following (1-1) to (1-3).

(1-1) Limestone:

About 3 cm of pebbles formed by pulverizing limestone in which volcanic sediments containing the following components are mixed

Calcium carbonate: 50% by weight

Iron oxide: 3~9 wt% iron

The total of titanium oxide, titanium carbide, and titanium nitride: 0.8% by weight or more

Magnesium carbonate: 7 to 10% by weight.

As such a limestone, [CC-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.

(1-2) Coral fossils:

The following two kinds of coral fossils are mixed in a weight ratio of 1:9 and pulverized into granules formed by 3 to 5 mm.

Produced from the ground below about 100 meters, by weighting the crystals to form a denatured coral fossil; Coral fossils (including other trace elements such as calcium carbonate and calcium phosphate) produced from the land near Okinawa Okinawa.

As such a coral fossil, [CC-300 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. can be preferably used.

(1-3) Shell:

Abalone, nine-hole, and barnacle are mixed and pulverized into 3~5mm granules with the same weight.

As such a shell, [CC-400 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.

(1-4) Activated carbon

As the activated carbon, those produced from any raw material can be used, but activated carbon produced by using coconut shell as a raw material is preferable. For example, [CC-500 (Product No.)] manufactured by Riken Chemical Technology Systems Co., Ltd., which is made from coconut shells made in Thailand.

When the switching knobs 51b to 56b of the operation panel 58 are operated and the water flow switching valves 51v to 56v are switched toward the water container side, the water flowing through the water supply path 57 is directed to the downstream side of the water flow switching valve that is already operated. When the first water-passing container 51 to the sixth water-passing container 56 are inflow, if the water-flow switching valves 51v to 56v are switched to the bypass waterway side, the water flowing through the water supply path 57 is further downstream toward the water flow switching valve that is already operated. The side of the bypass waterway 51p~56p flows in. Therefore, by selectively switching the water flow switching valves 51v to 56v by operating any of the switching buttons 51b to 56b, it is possible to form Mineral water (B) 45 in which the mineral components eluted from different mineral-imparting materials (B) 51m to 56m are selectively dissolved in each of the first water-passing container 51 to the sixth water-passing container 56 .

Next, the structure and function of the mineral-containing water (B) manufacturing apparatus 3 will be described with reference to Figs. 8 to 11 . Further, in FIGS. 8 to 10, the bypass water passages 51p to 56p, the water flow switching valves 51v to 56v, the operation panel 58 and the signal cable 59 are omitted.

As shown in FIG. 8 and FIG. 9 , the mineral water-containing (B) manufacturing apparatus 3 includes a first water-passing container 51 to a sixth water-passing container 56 that are mounted on the gantry 60 in a substantially cylindrical shape; The water supply path 57 in which the first water-passing container 51 to the sixth water-passing container 56 are connected in series, and the raw water tank 63 for storing the water W supplied from the water pipe is disposed at the uppermost portion of the gantry 60. In the raw water tank 63, an inorganic porous body 64 having a function of adsorbing impurities in the water W is housed. At the bottom of the gantry 60, a plurality of casters 61 and a level adjuster 62 are provided. The first water-passing container 51 to the sixth water-passing container 56 having a substantially cylindrical shape are placed on the gantry 60 of the rectangular parallelepiped lattice structure while holding the respective axial centers 51c to 56c (see FIG. 9) in the horizontal direction. The first water-passing container 51 to the sixth water-passing container 56 can detach the gantry 60.

As shown in FIG. 10, the first water-passing container 51 to the sixth water-passing container 56 have the same structure, and the disk-shaped lid bodies 51d to 56d are attached to the cylindrical body portions 51a to 56a. The flange portions 51f to 56f at both end portions form an airtight structure. When the shaft centers 51c to 56c are in a horizontal state, the water is provided at the lowermost portion of the body portions 51a to 56a. The water inlet 57a that communicates with the path 57 is provided with a water outlet 57b that communicates with the water supply path 57 at the uppermost portion of the lids 51d to 56d farther from the water inlet 57a, and a screen 57c is attached to the water outlet 57b. . An automatic air valve 57d for detaching the gas in the first water-passing container 51 to the sixth water-passing container 56 is attached to a portion directly above the water outlet 57b on the outer circumference of the main body portions 51a to 56a.

The water supplied from the upstream water supply path 57 flows into the first water-passing container 51 to the sixth water-passing container 56 through the water inlet 57a, and is in contact with the mineral-imparting material (B) 51m to 56m filled in each of the water. In this way, the mineral components are dissolved in the water, so that the water is contained in the water containing the mineral component corresponding to the individual mineral material (B) 51m to 56m, and the water supply path from the water outlet 57b to the downstream side. 57 outflow.

The mineral-containing water (B) manufacturing apparatus 3 shown in Figs. 8 to 10 is operated in the raw water tank 63 by operating one of the switching knobs 51b to 56b of the operation panel 58 as shown in Fig. 7. The water W passes through one or more water-passing containers in the first water-passing container 51 to the sixth water-passing container 56, and can form mineral-containing water (B) 45, which is selectively dissolved in individual water. The mineral component contained in the mineral-importing material (B) 51m to 56m filled in the first water-passing container 51 to the sixth water-passing container 56 is characteristic.

Further, in the mineral water-containing (B) manufacturing apparatus 3, since the first water-passing container 51 to the sixth water-passing container 56 are connected in series by the water supply path 57, the water is continuously flown to the water supply path. 57, can produce a large amount of mineral water (B) 45, the mineral water (B) 45 is dissolved The mineral component corresponding to the mineral-imparting material (B) in the first water-passing container 51 to the sixth water-passing container 56 is 51 m to 56 m.

Further, the mineral-containing water (B) 45 formed in the mineral-containing water (B) manufacturing apparatus 3 is transported into the mixing tank 46 via the water supply path 57x located further downstream than the sixth water-passing container 56. In the inside, it is mixed with the mineral-containing water (A) 44 produced by the mineral-containing water (A) manufacturing apparatus 2 shown in Fig. 1, thereby forming the mineral functional water 47.

The ratio of the mineral-containing water (A) to the mineral-containing water (B) is determined by considering the type of the raw material contained in the mineral-containing water (A) and the mineral-containing water (B) and the concentration of the dissolved components. Decide, however, that the weight ratio of mineral-containing water (A) to mineral-containing water (B) ([mineral water (A)]: [mineral water (B)]) is 1:5~ The range of 1:20 is ideally in the range of 1:7 to 1:12, and more preferably in the range of 1:10.

In the case of too little mineral water (A) (excessive mineral water (B)), and too much mineral water (A) (mineral water (B) too little), there will be mineral water The active ingredient is diluted and the effect of the desired purpose becomes insufficient.

In the above, a preferred embodiment of the method for producing mineral water according to the present invention is described. However, the present invention is not limited to the embodiments, and the mineral functional water of the present invention having the above configuration can be produced, and in addition to the above-described preferred embodiment. Various structures can also be used. In particular, in the embodiments disclosed herein, items that are not explicitly disclosed, such as operating conditions, operating conditions, various parameters, size, weight, volume, etc. of the components, are The use will not exceed the scope of the general implementation of the industry, if it is a value that the general industry can easily think of.

[Examples]

Hereinafter, the present invention will be specifically described by way of examples, but the invention is not limited to the examples.

<1>Manufacture of mineral functional water

As the mineral functional water, the mineral functional water produced in the above-described embodiment of the present invention is used, and the mineral water of the first embodiment produced by the following raw materials and methods is used. .

1. Manufacture of mineral-containing water (A)

The mineral-imparting material (A'-1) was used as the mineral-imparting material (A). As the plant material (A1-1) of the raw material of the mineral-importing material (A'-1) of the first embodiment, the RIKEN Techno System Co., Ltd. product [P-100 (product number)] was used. As a woody plant material (A2-1), [P-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. was used.

[P-100] is a plant material obtained by mixing the dried ground material of the following Compositae plants with the dried ground material of the Rosaceae plant at a ratio of 1:1 (weight ratio), [P-200] is described below. Woody plant material.

(A1) Raw material of grass plants (dried plants) (A1-1) Dry pulverized material of Compositae

The cockroach (leaf, stem, and flower), wormwood (leaf and stem), and gerbera (leaf and stem) were each 10% by weight, 60% by weight, and 30% by weight, respectively. The dried pulverized material is mixed, dried, and pulverized.

(A1-2) Dry pulverized material of Rosaceae plants

The ratio of 20% by weight, 10% by weight, and 70% by weight of wild rose (leaf, flower), bayberry (leaf and stem), and raspberry (leaf, stem, and flower) was used. A dried pulverized material of a Rosaceae plant which is mixed, dried and then pulverized.

(A2) Woody plant material (dried woody plant)

Maple (leaf and stem), birch (leaf, stem, and bark), cedar (leaf, stem, and bark) are 25% by weight, 25% by weight, and 50, respectively. The dry pulverized material is mixed, dried, and pulverized in a ratio of % by weight.

The mineral-imparting material (A) formed by mixing the grass plant material (A1) and the woody plant material (A2) in a ratio of 1:3 (weight ratio) to 10 to 15% by weight is placed. In the raw material mineral aqueous solution production means 10 (see FIG. 2) in the mineral-containing water (A) manufacturing apparatus 2 shown in FIG. 1, a direct current (DC8300V, 100 mA) is further conducted to the raw material mineral aqueous solution manufacturing means 10 To make conductive lines The surrounding water generates a water flow in the same direction as the direct current, and then imparts ultrasonic vibration (oscillation frequency: 50 kHz, amplitude: 1.5/1000 mm) to the water to form a raw material mineral aqueous solution (A). Then, the mineral-containing water (A) of Example 1 is irradiated with far-infrared rays (wavelength: 6 to 14 μm) by the raw material mineral aqueous solution (A) supplied to the far-infrared generation means 43 of the subsequent stage, thereby obtaining the mineral-containing water (A) of the first embodiment.

2. Manufacture of mineral-containing water (B)

As a raw material of the mineral-imparting material (B), a mixture in which limestone, coral fossil, shell, and activated carbon powder are divided and mixed is used. The raw material of the mineral-imparting material (B) and the mixture (mineral-imparting materials (B1) to (B6)) used in the first to sixth water-passing containers are as follows.

(1) Raw materials (1-1) Limestone: manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-200 (Product No.)]

About 3 cm of pebbles formed by pulverizing limestone in which volcanic sediments containing the following components are mixed

Calcium carbonate: 50% by weight

Iron oxide: 3~9 wt% iron

The total of titanium oxide, titanium carbide, and titanium nitride: 0.8% by weight or more

Magnesium carbonate: 7 to 10% by weight.

(1-2) Coral fossil: manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-300 (product number)]

The following two kinds of coral fossils are mixed in a weight ratio of 1:9 and pulverized into granules formed by 3 to 5 mm.

A coral fossil that is produced from a depth of about 100 meters under the ground, which is made into a denatured crystal by heavy pressure; a coral fossil (a trace element containing calcium carbonate, calcium phosphate, etc.) produced from the land near Okinawa Oshima.

(1-3) Limestone: manufactured by Liken Chemical Technology Systems Co., Ltd. [CC-400 (Product No.)]

The abalone, the nine holes, and the barnacle are mixed and pulverized into the granules of 3 to 5 mm with the same weight.

(1-4) Activated carbon (used only in the second water container): manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-500 (product number)] (2) Proportion of use in the first to sixth water containers The first water container:

Mineral imparting material (B1): a mixture containing 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight of shells, respectively;

2nd water container:

Mineral imparting material (B2): 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shell, and 5% by weight a mixture of activated carbon (corresponding to cerium oxide and activated carbon);

3rd water container:

Mineral imparting material (B3): a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, respectively;

4th water container:

Mineral imparting material (B4): a mixture containing 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells, respectively;

5th water container:

Mineral imparting material (B5): a mixture containing 80% by weight of limestone, 10% by weight of coral fossil, and 10% by weight of shells, respectively;

The sixth water container:

Mineral material-imparting material (B6): a mixture containing 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shells, respectively; and the mineral water-making equipment 1 of the structure of Fig. 1 by circulating water The mineral water (B) is obtained by using the first to sixth water-passing containers of the mineral-imparting materials (B1) to (B6). (B1) to (B6) were set to 50 kg (total 300 kg), the amount of water flowing was 1000 kg, and the flow rate was 500 mL/40 s.

The mineral-containing water (A) and the mineral-containing water (B) of Example 1 of the foregoing method are formed in a ratio of 1:10 (weight ratio). The mixture was mixed to obtain the mineral functional water of Example 1. The mineral functional water of Example 1 was measured by a pH meter (Glass Electrode Water Ion Concentration Indicator TPX-90 manufactured by Dongxing Chemical Research Institute), which was pH 12.5.

In addition, the mineral functional water of the first embodiment is equivalent to the mineral functional water CAC-717 manufactured by Riken Chemical Technology Co., Ltd. [Tera Protect (product name), CAC-717 (product number), development product number CA -C-01].

<2>Manufacture of ceramic sintered body

A predetermined amount of water was added to 100 parts by weight of the ceramic powder for carrier (the rock powder of Amakusa Oyao Island) to obtain a clay-like mixture. The obtained clay-like mixture was formed into a flat plate shape having a circular surface having a thickness of about 5 mm and a diameter of 2 cm, and baked at 500 ° C for 8 hours to obtain a porous calcined body.

Next, the weight portion of the porous calcined body 100 was uniformly impregnated with 15 parts by weight of the mineral functional water of Example 1, and dried for several days. The glazing treatment of the glaze which is equivalent to 5 parts by weight is performed, and then heat treatment (true firing) is performed at 1200 ° C to obtain the ceramic of the first embodiment in which the mineral component contained in the mineral functional water is immobilized. Sintered body.

Further, as a control sample, a ceramic sintered body in which the mineral functional water does not contain mineral functional water and is heat-treated is prepared.

<3> Evaluation of spectroradiation rate

The spectroradiance of the sample (ceramic sintered body) is a far infrared ray The luminosity measuring device (JIR-E500 manufactured by JEOL Ltd.) was measured. The device is composed of a Fourier transform infrared spectrophotometer (FTIR) body, a black body furnace, a sample heating furnace, a temperature controller, and an attached optical system.

Fig. 12 shows the results of evaluation of the ratio of the emission ratio of the ceramic sintered body of Example 1 and the ceramic sintered body (control sample) in which the mineral component was not fixed to the black body at 25 ° C, which corresponds to the radioactivity of the black body was set to 100. The ratio of the radiation intensity (radiation ratio) of each ceramic sintered body in the case of %.

It was confirmed that the ceramic sintered body of Example 1 containing the mineral component had a high emissivity in all of the measured wavelength ranges, and significantly produced electromagnetic wave radiation, compared to the control sample containing no minerals.

<4> Mineral dissolution test

The ceramic sintered body of Example 1 was allowed to stand in water for one day, and then dried, and the spectral emissivity was measured. It was confirmed that there was no significant difference in spectroradiance between before and after standing in water. Therefore, it was judged that the mineral component contained in the ceramic sintered body of Example 1 was hardly eluted into water.

<5> Single cell biological control test

Using the ceramic sintered body of the first embodiment (formed into a plate shape), the following bacteria (single cell organism) control test was carried out.

[Evaluation 1: Pathogenic Coliforms (O-157; Escherichia coli)]

O-157 was prepared into a bacterial liquid concentration of 2.0 × 10 ⁵ /mL using a 1/500 ordinary broth medium which was sterilized, and the bacterial liquid was used as a test bacterial liquid.

To the ceramic sintered body of Example 1 (50 × 50 mm), 5 mL of the test bacterial liquid was dropped and spread to the whole, and allowed to stand at room temperature at about 25 ° C for 24 hours.

As a comparative example (control), the same test was carried out using a ceramic sintered body (control sample) to which no mineral component was immobilized.

[Evaluation 2: Methicillin resistant Staphylococcus aureus]

The MRSA was prepared to have a bacterial liquid concentration of 2.5 × 10 ⁵ /mL using a 1/500 ordinary broth medium which was sterilized, and the bacterial liquid was used as a test bacterial liquid.

To the ceramic sintered body of Example 1 (50 × 50 mm), 5 mL of the test bacterial liquid was dropped and spread to the whole, and allowed to stand at room temperature at about 25 ° C for 24 hours.

As a comparative example (control), the same test was carried out using a ceramic sintered body (plate shape, 50 × 50 mm) in which a mineral component was not immobilized.

The results are shown in Table 1. From this result, it was confirmed that the ceramic sintered body of Example 1 has an excellent control effect on O-157 and MRSA.

[Embodiment 2]

The ceramic sintered body of Example 2 was produced by the following method. In addition, in the manufacturing method of the Example 2, the part common to the manufacturing method of Example 1 is suitably abbreviate|omitted.

<1>Manufacture of mineral functional water

The mineral functional water of Example 2 produced by the following raw materials and methods was produced.

1. Manufacture of mineral-containing water (A)

Example 1 was obtained in the same manner as in Example 1 except that the mineral-importing material (A'-2) was used as the mineral-importing material (A) in place of the mineral-imparting material (A'-1) of Example 1. 2 mineral water (A).

2. Manufacture of mineral-containing water (B)

Since it is the same as that of the first embodiment, the description thereof is omitted here.

The mineral-containing water (A) of Example 2 of the foregoing method The mineral functional water of Example 2 was obtained by mixing with the mineral-containing water (B) in a ratio of 1:10 (weight ratio).

In addition, the mineral functional water of the second embodiment is equivalent to the mineral functional water A20ACA-717 [Tera Support (trade name), A20ACA-717 (product number)] manufactured by Riken Chemical Technology Co., Ltd.

<2>Manufacture of ceramic sintered body

The ceramic sintered body of Example 2 was obtained by the same method as the production of the ceramic sintered body of Example 1 except that the mineral functional water of Example 2 was used instead of the mineral functional water of Example 1.

<3> Evaluation of spectroradiation rate

The evaluation of the spectral emissivity of the ceramic sintered body of Example 2 and the control sample was carried out in the same manner as in the above-described Example 1, and it was confirmed that Example 2 containing the mineral component was compared with the control sample containing no mineral. The ceramic sintered body has a high emissivity in all wavelength ranges measured, and intentionally generates electromagnetic wave radiation.

<4> Mineral dissolution test

The ceramic sintered body of Example 2 was allowed to stand in water for one day, and then dried, and the spectral emissivity was measured. It was confirmed that there was no significant difference in spectroradiance between before and after standing in water. Therefore, it can be judged that the mineral component contained in the ceramic sintered body of Example 2 is hardly eluted into water.

<5> Warming effect

The ceramic sintered body of Example 2 (plate shape, 50 × 50 mm) was used for evaluation of the warming action. As a comparative example (control), a ceramic sintered body (plate shape, 50 × 50 mm) in which a mineral component was not immobilized was used.

The evaluation was carried out by heating the sample with a heater and then performing thermal image shooting by a 90-degree parallel re-radiation method.

Furthermore, the 90-degree parallel re-radiation method is an evaluation method that evaluates at a higher temperature than the conventional 45-degree parallel re-radiation method at 90 ° C. Compared with the conventional 45-degree parallel re-radiation method, the evaluation is small and can be tested. The sample was measured under conditions in which the influence of the surrounding environment was small and stable.

The specific measurement procedure is that the sample is placed on the measurement table, and after the measurement chamber is adjusted to a predetermined temperature and humidity, the heater heated to 90° C. is slid and the image of the measurement sample is continuously introduced. After the heater was just heated and heated, the image was taken out for a certain period of time, and the average surface temperature was measured. Next, the arrangement of the ceramic sintered bodies of Example 2 and the comparative example was changed to the left and right, and the measurement was performed again. As a result, it was confirmed whether there was a difference in the characteristic values of the ceramic sintered bodies of Example 2 and the comparative example. When the average temperature rise after heating the heater for 60 seconds was compared from the temperature distribution image, it was confirmed that there was a temperature difference of 3.5 °C. From this result, the ceramic sintering system of Example 2 can be said to have a warming action.

[Industrial use possibility]

The electromagnetic wave radioactive ceramic sintered body of the present invention has the advantage that it has an effective effect due to the mineral component contained, It is solid and easy to handle.

1‧‧‧Mineral functional water manufacturing equipment

2‧‧‧Mineral water (A) manufacturing equipment

3‧‧‧Mineral water (B) manufacturing equipment

10‧‧‧Methods for the production of raw materials and mineral aqueous solutions

11, W‧‧‧ water

41‧‧‧ Raw material mineral aqueous solution (A)

43‧‧‧ far infrared ray generation means

44‧‧‧ Mineral water (A)

45‧‧‧ Mineral water (B)

46‧‧‧ mixing tank

47‧‧‧Mineral functional water

51‧‧‧1st water container

52‧‧‧2nd water container

53‧‧‧3rd water container

54‧‧‧4th water container

55‧‧‧5th water container

56‧‧‧6th water container

51m~56m‧‧‧ Mineral Substance (B)

51p~56p‧‧‧迂回回路

51v~56v‧‧‧Water flow switching valve

57, 57x, 57y‧‧‧ water supply path

Claims (6)

A ceramic sintered body in which a mineral component derived from mineral functional water is immobilized. The ceramic sintered body of the first aspect of the invention, wherein the ceramic sintered body is a sintered body of a clay-based powder containing the mineral component. The ceramic sintered body according to claim 1 or 2, wherein the ceramic sintered body has a glaze layer covering the entire surface or a part of the surface. A ceramic sintered body, which is a ceramic sintered body according to any one of claims 1 to 3, characterized in that the manufacturing method comprises: mixing ceramic powder for a carrier a process of mixing a liquid into a clay-like mixture (i); calcining the clay-like mixture to obtain a porous calcined body (ii); and forming pores in the porous calcined body to form The ratio of 1:5 to 1:20 (weight ratio) contains mineral-containing water (A) formed by the following process (1), and mineral-containing water formed by the following process (2) ( B) the mineral function water is saturated and then dried to temporarily fix the mineral component to the porous calcined body (iii); and the porous calcined body after the process (iii) is further subjected to heat treatment to obtain the above-mentioned ore a material that cannot be dissolved and fixed in a ceramic carrier Process for porcelain sintered body (iv) wherein, process (1): a conductive wire covered with an insulator, and a plant material composed of a plant of the family Asteraceae and a plant of the family Rosaceae, and from a maple tree and a birch tree The mineral material (A) of the woody plant material composed of one or more woody plants selected from pine and cedar is immersed in water to conduct a direct current to the conductive wire to allow water around the conductive wire. A water flow in the same direction as the DC current is generated, ultrasonic vibration is applied to the water to form a raw material mineral aqueous solution (A), and then the raw mineral aqueous solution (A) is irradiated with far infrared rays (wavelength 6 to 14 μm) to form a ore. The process of the material water (A), wherein the mineral-donating material (A) is added to the water in an amount of 10 to 15% by weight, and the current value and the voltage value of the direct current which is conducted to the conductive wire are 0.05 to 0.1 A, respectively. 8000~8600V range; process (2): a process for forming mineral water (B) containing mineral water (B) through 6 water-passing containers, wherein the 6 water-passing containers are filled with kinds Different inorganic minerals are given to each other (B) and The first water-passing container to the sixth water-passing container connected in series: the mineral-importing material (B1) in the first water-passing container contains 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight a mixture of shells; the mineral-giving material (B2) in the second water-passing container is separately contained a mixture of 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon; and the mineral-donating material (B3) in the third water-passing container contains 80% by weight of limestone, respectively. a mixture of 15% by weight of coral fossils and 5% by weight of shells; and the mineral-imparting material (B4) in the fourth water-passing container contains 90% by weight of limestone, 5% by weight of coral fossils, and 5% by weight a mixture of shells; the mineral-imparting material (B5) in the fifth water-passing container is a mixture containing 80% by weight of limestone, 10% by weight of coral fossil, 10% by weight of shells, respectively; and a mine in the sixth water-passing container The substance imparting material (B6) is a mixture containing 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shells, respectively. The method for producing a ceramic sintered body according to claim 4, wherein the mineral-imparting material (A) is formed by a weight ratio of the grass plant material (A1-1) to the woody plant material (A2-1). A mineral-donating material (A'-1) obtained by mixing in a manner of 1:2.7 to 1:3.3, in which a large scorpion (leaf, stem, flower), wormwood (leaf, stem) is used. And dried chrysanthemums of the compositae which are mixed, dried, and pulverized at a ratio of 8 to 12% by weight, 55 to 65% by weight, and 27 to 33% by weight, respectively; Wild rose (leaf, flower), bayberry (leaf, stem) Part), raspberry (leaf, stem, flower) dried, dried and then pulverized in a ratio of 17 to 23% by weight, 8 to 12% by weight, and 65 to 75% by weight, respectively. a pulverized material, which is obtained by mixing a dried pulverized material of a compositae plant with a dried pulverized material of a plant of the genus Rosaceae with a plant material (A1-1) obtained by mixing 1:0.8 to 1:1.2 (weight ratio) as the grass plant material. From maple (leaf, stem), birch (leaf, stem, and bark), cedar (leaf, stem, and bark) to 22 to 28% by weight, 22 to 28, respectively The woody plant material (A2-1) composed of a dry pulverized product which is mixed, dried, and pulverized at a ratio of weight% to 45 to 55% by weight is used as the woody plant material. The method for producing a ceramic sintered body according to claim 4, wherein the mineral-imparting material (A) is formed by a weight ratio of the grass plant material (A1-2) to the woody plant material (A2-2). A mineral-imparting material (A'-2) obtained by mixing in a 1:5 manner, in which a large scorpion (leaf, stem, flower), wormwood (leaf, stem), and mountain daisy (leaf) The dried parts of the compositae and the wild rose (leaf, flower) and arbutus (leaf) are mixed and dried at a ratio of 10% by weight, 60% by weight, and 30% by weight, respectively. The dried pulverized material of the Rosaceae plant which is mixed, dried, and pulverized at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively, in the portion, the stem portion, and the raspberry a plant material (A1-2) obtained by mixing 1:1 (weight ratio) as the raw material of the aforementioned plant; and The maple (deciduous), birch (deciduous, stem, and bark), cedar (deciduous, stem, and bark) are mixed at a ratio of 20% by weight, 60% by weight, and 20% by weight, respectively. The woody plant material (A2-2) composed of the dried pulverized material which is pulverized after drying is used as the raw material of the woody plant.