TW201718413A - Device for producing eluted functional water containing mineral component, and method of producing eluted functional water - Google Patents
Device for producing eluted functional water containing mineral component, and method of producing eluted functional water Download PDFInfo
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- TW201718413A TW201718413A TW105128493A TW105128493A TW201718413A TW 201718413 A TW201718413 A TW 201718413A TW 105128493 A TW105128493 A TW 105128493A TW 105128493 A TW105128493 A TW 105128493A TW 201718413 A TW201718413 A TW 201718413A
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- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/68—Treatment of water, waste water, or sewage by addition of specified substances, e.g. trace elements, for ameliorating potable water
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Abstract
Description
本發明係依據在2015年9月3日向日本特許廳申請之專利申請案的日本特願2015-173941、日本特願2015-173942、日本特願2015-173943主張優先權之發明申請案,參照日本特願2015-173941、日本特願2015-173942、日本特願2015-173943所有的內容,援用於本案中。 The present invention is based on the Japanese Patent Application No. 2015-173941, Japanese Patent Application No. 2015-173942, and Japanese Patent Application No. 2015-173943, which are incorporated herein by reference. All contents of the special purpose 2015-173941, Japan's special wish 2015-173942, and Japan's special wish 2015-173943 are used in this case.
本發明係關於含有具備有益效能的礦物質成分之溶析機能水的製造技術。 The present invention relates to a manufacturing technique for dissolving functional water containing a mineral component having beneficial effects.
在含有礦物質成分的水中,存在有具有土壤改質作用、植物育成作用、有害化學物質分解作用、除臭作用、空氣淨化作用等的效果之可能性,以往以來,各種含礦物質水、含礦物質水的製造設備被開發。 In water containing mineral components, there is a possibility of effects such as soil modification, plant growth, decomposition of harmful chemicals, deodorization, air purification, etc. In the past, various mineral-containing waters and Mineral water manufacturing equipment was developed.
本發明者們開發出一種含礦物質水製造裝置(A),其具備有:將以絕緣體被覆的導電線及礦物質賦予材(A)浸漬於水中,使直流電流導通於前述導電線,讓在前述導電 線周圍的水產生與前述直流電流相同方向的水流,對前述水賦予超音波振動,形成原料礦物質水溶液(A)的手段;及對所形成的原料礦物質水溶液(A)照射遠紅外線,形成含礦物質水(A)之遠紅外線產生手段(參照專利文獻1)。 The inventors of the present invention have developed a mineral-containing water producing apparatus (A) including a conductive wire coated with an insulator and a mineral-imparting material (A) immersed in water to conduct a direct current to the conductive wire. Conductive in the foregoing The water around the line generates a water flow in the same direction as the DC current, imparts ultrasonic vibration to the water to form a raw material mineral aqueous solution (A), and irradiates far infrared rays to the formed raw mineral aqueous solution (A) to form The far infrared ray generating means of the mineral-containing water (A) (refer to Patent Document 1).
又,本發明者們亦開發一種礦物質機能水製造設備,其具備有含礦物質水製造裝置(A)、和含礦物質水製造裝置(B),前述含礦物質水製造裝置(B)具有:填充有相互種類不同的礦物質賦予材(B)的複數個通水容器;將複數個前述通水容器串連地連通的送水路徑;分別與複數個前述通水容器並列的狀態下,連結於前述送水路徑的迂迴水路;及分別設在前述送水路徑與前述迂迴水路之分歧部的水流切換閥(參照專利文獻2)。又,記載有當採用該礦物質機能水製造設備時,能夠製造具有可產生具特徵的波長之遠紅外線的機能之礦物質機能水(遠紅外線產生水)。 Further, the inventors of the present invention have also developed a mineral water manufacturing facility comprising a mineral water-containing water producing device (A) and a mineral-containing water producing device (B), and the mineral water-containing water producing device (B) And a plurality of water-passing containers filled with mineral material-imparting materials (B) having different types; and a water-feeding path in which a plurality of the water-passing containers are connected in series; and in a state in which a plurality of the water-passing containers are juxtaposed a bypass water passage connected to the water supply path; and a water flow switching valve provided in a branching portion of the water supply path and the bypass water passage (refer to Patent Document 2). Further, it is described that when the mineral water-producing equipment is used, it is possible to produce mineral functional water (far-infrared-generated water) having a function of generating far-infrared rays having a characteristic wavelength.
另外,在專利文獻2所記載的裝置,特別是在含礦物質水製造裝置(A)及(B)所使用的礦物質成分之原料(礦物質賦予材)的種類、配合比例等變得複雜化,無法一定得知使用何種的礦物質賦予材的話,能夠獲得產生何種效果之礦物質機能水,但,本發明者們使用在專利文獻2所揭示的礦物質機能水製造設備,針對礦物質賦予材的種類、配合比例為重點進行檢討的結果發現,以某特定條件所製造的礦物質機能水,對單細胞生物、病毒等具有優良之有害生物防治作用(專利文獻3)、身體活化作用(專利文獻4)、碳氫化合物類的燃燒促進作用(專利文獻5)、抗 氧化作用(專利文獻6)等。 In addition, in the apparatus described in Patent Document 2, the types and blending ratios of the raw materials (mineral imparting materials) used in the mineral-containing water producing apparatuses (A) and (B) are complicated. In the meantime, it is not possible to know which kind of mineral-based material to be used, and it is possible to obtain mineral-functional water which has an effect. However, the inventors of the present invention used the mineral-functional water-making apparatus disclosed in Patent Document 2, As a result of the review, the mineral functional water produced under certain conditions has excellent pest control effects against single-celled organisms and viruses (Patent Document 3) and the body. Activation (Patent Document 4), combustion promotion of hydrocarbons (Patent Document 5), and resistance Oxidation (Patent Document 6) and the like.
[先行技術文獻] [Advanced technical literature]
[專利文獻] [Patent Literature]
[專利文獻1]日本專利第4817817號公報 [Patent Document 1] Japanese Patent No. 4817817
[專利文獻2]日本特開2011-56366號公報 [Patent Document 2] Japanese Laid-Open Patent Publication No. 2011-56366
[專利文獻3]WO2016/043213 [Patent Document 3] WO2016/043213
[專利文獻4]WO2016/043214 [Patent Document 4] WO2016/043214
[專利文獻5]PCT/JP2016/058141 [Patent Document 5] PCT/JP2016/058141
[專利文獻6]PCT/JP2016/058362 [Patent Document 6] PCT/JP2016/058362
專利文獻2所記載的製造裝置,雖適用於製造有益的礦物質機能水,但構造複雜、尺寸大,不容易移動。因此,期望能夠開發以更簡單的構造製造有益機能水之小型化的製造裝置。 The manufacturing apparatus described in Patent Document 2 is suitable for producing a useful mineral water, but has a complicated structure, a large size, and is not easily moved. Therefore, it is desirable to be able to develop a manufacturing apparatus that manufactures a miniaturization of beneficial function water in a simpler configuration.
因此,本發明的目的係在於提供容易且穩定地製造藉由包含礦物質成分具有有益的效能之機能水的技術。 Accordingly, it is an object of the present invention to provide a technique for easily and stably producing functional water having beneficial effects by containing a mineral component.
本發明係提供以下的技術。 The present invention provides the following techniques.
<1>一種溶析機能水的製造裝置,係用來製造含有礦物質成分的溶析機能水之裝置,其特徵為:具備有:2個以上的處理槽,前述處理槽具有入水路徑及出水路徑,並可在內部供從前述入水路徑流入的水或以水為主體的萃取溶劑朝前述出水路徑流動;及將一個前述處理槽的出水路徑與另一個前述處理槽的入水路徑連通之連結路徑,該二個以上的處理槽係經由前述連結路徑以串聯方式連接,在至少其中一個前述處理槽內,收容有礦物質成分可溶析地被固定化的溶析型陶瓷材料。 <1> A device for producing a leaching machine water, which is a device for producing a leaching machine water containing a mineral component, comprising: two or more treatment tanks, wherein the treatment tank has a water inlet path and a water outlet a path for internally flowing water flowing from the water inlet path or an extraction solvent mainly composed of water toward the water outlet path; and a connection path connecting the water outlet path of one of the treatment tanks to the water inlet path of the other treatment tank The two or more treatment tanks are connected in series via the connection path, and at least one of the treatment tanks contains a dissolution type ceramic material in which a mineral component is immobilized in a soluble manner.
<2>如前述<1>所記載的製造裝置,其中,該製造裝置設有連通於收容有前述溶析型陶瓷材料的前述處理槽內之注水路徑。 The manufacturing apparatus according to the above <1>, wherein the manufacturing apparatus is provided with a water injection path that communicates with the processing tank in which the eluted ceramic material is accommodated.
<3>如前述<1>或<2>所記載的製造裝置,其中,在收容有前述溶析型陶瓷材料的處理槽以外之處理槽,收容有非溶析地固定化有礦物質成分的非溶析型陶瓷材料。 (3) The manufacturing apparatus according to the above-mentioned <1> or <2>, wherein the processing tank other than the processing tank in which the eluted ceramic material is accommodated contains a mineral component which is immobilized without elution. Non-lead-type ceramic material.
<4>如前述<3>所記載的製造裝置,其中,在收容有前述溶析型陶瓷材料的處理槽中的至少一個處理槽,配置在收容有前述非溶析型陶瓷材料的處理槽之上游側。 (4) The manufacturing apparatus according to the above-mentioned <3>, wherein at least one of the treatment tanks in which the elution-type ceramic material is accommodated is disposed in a treatment tank in which the non-lead-type ceramic material is accommodated. Upstream side.
<5>如前述<3>或<4>所記載的製造裝置,其中,二個的處理槽係經由前述連結路徑以串聯方式連接。 <5> The manufacturing apparatus according to <3> or <4>, wherein the two processing tanks are connected in series via the connecting path.
<6>如前述<5>所記載的製造裝置,其中,將位於前述連結路徑上游側的其中一方之前述處理槽配置在較前述 另一方的前述處理槽更高的位置。 (6) The manufacturing apparatus according to the above [5], wherein the processing tank located on one of the upstream sides of the connecting path is disposed in the foregoing The other side of the processing tank is at a higher position.
<7>如前述<5>或<6>所記載的製造裝置,其中,將位於前述連結路徑下游側的前述處理槽之出水路徑設在前述處理槽的最上部。 The production apparatus according to the above-mentioned <5> or <6>, wherein the water discharge path of the processing tank located on the downstream side of the connection path is provided at the uppermost portion of the processing tank.
<8>一種溶析機能水的製造方法,其特徵為具有以下製程,亦即對如前述<1>至<7>中任一個所記載的製造裝置,供給水或以水為主體的萃取溶劑,使水或以水為主體的萃取溶劑與收容於前述處理槽中的其中一個處理槽之前述溶析型陶瓷材料接觸的製程。 <8> A method for producing a water for emulsification, which is characterized in that, in the production apparatus according to any one of the above items <1> to <7>, water or water-based extraction solvent is supplied. And a process of contacting water or a water-based extraction solvent with the aforementioned dissolution-type ceramic material of one of the treatment tanks contained in the treatment tank.
<9>一種溶析機能水的製造方法,其特徵為具有以下製程,亦即對如前述<3>至<7>中任一個所記載的製造裝置,供給水或以水為主體的萃取溶劑,使水或以水為主體的萃取溶劑與收容於前述處理槽中的其中一個處理槽之前述溶析型陶瓷材料及前述非溶析型陶瓷材料接觸的製程。 <9> A method for producing a water for emulsification, which is characterized in that, in the manufacturing apparatus described in any one of the above <3> to <7>, water or water-based extraction solvent is supplied. And a process of bringing water or a water-based extraction solvent into contact with the eluted ceramic material and the non-lead-type ceramic material of one of the treatment tanks contained in the treatment tank.
<10>如前述<9>所記載的析機能水的製造方法,其中,還具有以下製程,亦即使水或以水為主體的萃取溶劑與溶析型陶瓷材料接觸後,再使與溶析型陶瓷材料接觸之水或以水為主體的萃取溶劑與非溶析型陶瓷材料接觸的製程。 <10> The method for producing a functional water according to the above <9>, which further comprises the following process, and even if water or an extraction solvent mainly composed of water is contacted with the eluted ceramic material, and then eluted A process in which a ceramic material is contacted with water or a water-based extraction solvent is contacted with a non-lead-type ceramic material.
<11>如前述<10>所記載的製造方法,其中,使用如前述<5>至<7>中任一個所記載之製造裝置。 The production method according to any one of the above <5> to <7>, wherein the manufacturing apparatus according to any one of the above <5> to <7> is used.
藉由本發明,能夠提供容易且穩定地製造具有來自於從保持有礦物質成分的陶瓷材料溶析之礦物質成分的有益效能之溶析機能水的技術。 According to the present invention, it is possible to provide a technique for easily and stably producing a solvent-soluble water having a beneficial effect from a mineral component eluted from a ceramic material holding a mineral component.
1‧‧‧礦物質機能水製造設備 1‧‧‧Mineral functional water manufacturing equipment
2‧‧‧含礦物質水(A)製造裝置 2‧‧‧Mineral water (A) manufacturing equipment
3‧‧‧含礦物質水(B)製造裝置 3‧‧‧Mineral water (B) manufacturing equipment
10‧‧‧原料礦物質水溶液製造手段 10‧‧‧Methods for the production of raw materials and mineral aqueous solutions
11、W‧‧‧水 11, W‧‧‧ water
12‧‧‧礦物質賦予材(A) 12‧‧‧ Mineral Substance (A)
13‧‧‧反應容器 13‧‧‧Reaction container
13a‧‧‧壁體 13a‧‧‧ wall
14‧‧‧絕緣體 14‧‧‧Insulator
15‧‧‧導電線 15‧‧‧Flexible wire
16‧‧‧超音波產生手段 16‧‧‧Ultrasonic generation means
17‧‧‧直流電源裝置 17‧‧‧DC power supply unit
18a,18b,18c‧‧‧循環路徑 18a, 18b, 18c‧‧ cycle path
19‧‧‧排水口 19‧‧‧Drainage
20、23‧‧‧開度調節閥 20, 23‧‧‧ opening adjustment valve
21、25‧‧‧排水閥 21, 25‧‧‧Drain valve
22‧‧‧收容槽 22‧‧‧ housing trough
24‧‧‧排水管 24‧‧‧Drainage pipe
26‧‧‧水溫計 26‧‧‧Water temperature meter
29,29a~29g,29s,29t‧‧‧導電電纜 29,29a~29g, 29s, 29t‧‧‧ conductive cable
30‧‧‧終端機 30‧‧‧ Terminal
31‧‧‧收納容器 31‧‧‧ storage container
31f‧‧‧鉤 31f‧‧‧ hook
40‧‧‧處理容器 40‧‧‧Processing container
41‧‧‧原料礦物質水溶液(A) 41‧‧‧ Raw material mineral aqueous solution (A)
42‧‧‧攪拌葉片 42‧‧‧Agitating blades
43‧‧‧遠紅外線產生手段 43‧‧‧ far infrared ray generation means
44‧‧‧含礦物質水(A) 44‧‧‧ Mineral water (A)
45‧‧‧含礦物質水(B) 45‧‧‧ Mineral water (B)
46‧‧‧混合槽 46‧‧‧ mixing tank
47‧‧‧礦物質機能水 47‧‧‧Mineral functional water
51‧‧‧第1通水容器 51‧‧‧1st water container
51a~56a‧‧‧本體部 51a~56a‧‧‧ Body Department
51b~56b‧‧‧切換鈕 51b~56b‧‧‧Switch button
51c~56c‧‧‧軸心 51c~56c‧‧‧Axis
51d~56d‧‧‧蓋體 51d~56d‧‧‧ cover
51f~56f‧‧‧凸緣部 51f~56f‧‧‧Flange
51m~56m‧‧‧礦物質賦予材(B) 51m~56m‧‧‧ Mineral Substance (B)
51p~56p‧‧‧迂迴水路 51p~56p‧‧‧迂回回路
51v~56v‧‧‧水流切換閥 51v~56v‧‧‧Water flow switching valve
52‧‧‧第2通水容器 52‧‧‧2nd water container
53‧‧‧第3通水容器 53‧‧‧3rd water container
54‧‧‧第4通水容器 54‧‧‧4th water container
55‧‧‧第5通水容器 55‧‧‧5th water container
56‧‧‧第6通水容器 56‧‧‧6th water container
57,57x,57y‧‧‧送水路徑 57, 57x, 57y‧‧‧ water supply path
57a‧‧‧入水口 57a‧‧‧ Inlet
57b‧‧‧出水口 57b‧‧‧Water outlet
57c‧‧‧濾網 57c‧‧‧Filter
57d‧‧‧自動氣閥 57d‧‧‧Automatic air valve
58‧‧‧操作盤 58‧‧‧Operation panel
59‧‧‧訊號纜線 59‧‧‧Signal cable
60‧‧‧架台 60‧‧‧ 台台
61‧‧‧腳輪 61‧‧‧ casters
62‧‧‧水平調節器 62‧‧‧Level adjuster
63‧‧‧原水槽 63‧‧‧ original sink
100‧‧‧溶析機能水製造裝置(雙處理槽) 100‧‧‧Soliding machine water manufacturing device (double treatment tank)
110‧‧‧第一處理槽 110‧‧‧First treatment tank
111、151‧‧‧外殼 111, 151‧‧‧ shell
111a,111b,151a,151b‧‧‧凸緣 111a, 111b, 151a, 151b‧‧‧Flange
111x‧‧‧上部空間 111x‧‧‧Upper space
111y‧‧‧下部空間 111y‧‧‧low space
112,152‧‧‧入水路徑 112, 152‧‧‧ water path
112a,153a‧‧‧開口部 112a, 153a‧‧‧ openings
113,153‧‧‧出水路徑 113,153‧‧‧Water path
114‧‧‧注水路徑 114‧‧‧Water injection path
114a‧‧‧上端開口部 114a‧‧‧Upper opening
114b‧‧‧下端開口部 114b‧‧‧Bottom opening
115,116,155,156‧‧‧蓋體 115,116,155,156‧‧‧ cover
117‧‧‧供水管 117‧‧‧Water supply pipe
118‧‧‧隔壁 118‧‧‧ next door
118a‧‧‧貫通孔 118a‧‧‧through hole
119‧‧‧排水路徑 119‧‧‧Drainage path
120,154b‧‧‧開閉閥 120,154b‧‧‧Opening valve
121‧‧‧浮子 121‧‧‧Float
122‧‧‧臂 122‧‧‧ Arm
125‧‧‧支柱 125‧‧‧ pillar
150‧‧‧第二處理槽 150‧‧‧Second treatment tank
154a‧‧‧操作桿 154a‧‧‧Operation lever
155a‧‧‧下面 155a‧‧‧ below
157‧‧‧腳輪 157‧‧‧ casters
158‧‧‧連結路徑 158‧‧‧Link path
159‧‧‧出水管 159‧‧‧Outlet
160‧‧‧溶析機能水製造裝置(三處理槽) 160‧‧‧Soliding machine water manufacturing device (three treatment tanks)
170‧‧‧溶析機能水製造裝置(並聯式雙處理槽) 170‧‧‧Soliding machine water manufacturing device (parallel double treatment tank)
160A~160C,170A~170C‧‧‧處理槽 160A~160C, 170A~170C‧‧‧Processing tank
162,172‧‧‧入水路徑 162,172‧‧‧Water path
163,173‧‧‧出水路徑 163,173‧‧‧Water path
167,177‧‧‧供水管 167,177‧‧‧Water supply pipe
168,178‧‧‧連結路徑 168, 178‧‧‧ link path
169,179‧‧‧出水管 169,179‧‧‧Outlet
B‧‧‧氣泡 B‧‧‧ bubble
C1‧‧‧溶析型陶瓷材料 C1‧‧‧Solidized ceramic materials
C2‧‧‧非溶析型陶瓷材料 C2‧‧‧ Non-leolysis ceramic materials
DC‧‧‧直流電流 DC‧‧‧ DC current
DW‧‧‧自來水 DW‧‧‧ tap water
G‧‧‧地面 G‧‧‧ Ground
N‧‧‧透水性袋體 N‧‧‧ water-permeable bag body
P‧‧‧襯墊 P‧‧‧ cushion
R‧‧‧水流 R‧‧‧Water flow
W1‧‧‧溶析機能水 W1‧‧‧Solution water
W2‧‧‧溶析機能水 W2‧‧‧Solution water
W3‧‧‧溶析機能水 W3‧‧‧Solution water
圖1係顯示本發明的實施形態之溶析機能水製造裝置(雙處理槽)的正面圖。 Fig. 1 is a front elevational view showing a device for producing a melt-dissolving water (double treatment tank) according to an embodiment of the present invention.
圖2係構成圖1所示的溶析機能水製造裝置的第一處理槽附近的部分切除正面圖。 Fig. 2 is a partially cutaway front elevational view showing the vicinity of a first treatment tank constituting the apparatus for producing a solvable water shown in Fig. 1.
圖3係構成圖1所示的溶析機能水製造裝置的第二處理槽附近的部分切除正面圖。 Fig. 3 is a partially cutaway front elevational view showing the vicinity of a second treatment tank constituting the apparatus for producing a solvable water shown in Fig. 1.
圖4係如圖3所示的第二處理槽的部分放大圖。 Figure 4 is a partial enlarged view of the second processing tank shown in Figure 3.
圖5係顯示本發明的溶析機能水製造裝置的其他結構(三處理槽)的示意圖。 Fig. 5 is a schematic view showing another structure (three treatment tanks) of the apparatus for producing a water soluble in the present invention.
圖6係顯示本發明的溶析機能水製造裝置的其他結構(並聯式雙處理槽)的示意圖。 Fig. 6 is a schematic view showing another structure (parallel double treatment tank) of the apparatus for producing a solvable water of the present invention.
圖7係顯示礦物質機能水製造設備的概略結構之方塊圖。 Fig. 7 is a block diagram showing the schematic structure of a mineral water manufacturing facility.
圖8係顯示構成圖7所示的礦物質機能水製造設備之含礦物質水(A)製造裝置的一部分亦即含礦物質水溶液製造手段的示意圖。 Fig. 8 is a schematic view showing a part of a mineral-containing water (A) manufacturing apparatus which constitutes the mineral-functional water producing apparatus shown in Fig. 7, that is, a means for producing a mineral-containing aqueous solution.
圖9係圖8之A-A線局部省略斷面圖。 Figure 9 is a partially omitted cross-sectional view taken along line A-A of Figure 8.
圖10係顯示使用於如圖8所示的原料礦物質水溶液 製造手段的礦物質賦予材(A)之收納容器的斜視圖。 Figure 10 is a diagram showing the use of a raw material mineral aqueous solution as shown in Figure 8. A perspective view of the storage container of the mineral material (A) of the manufacturing means.
圖11係顯示如圖8所示的原料礦物質水溶液製造手段的導電線附近的反應狀態之斜視圖。 Fig. 11 is a perspective view showing a reaction state in the vicinity of a conductive wire of the raw material mineral aqueous solution manufacturing means shown in Fig. 8.
圖12係顯示構成圖7所示的礦物質機能水製造設備之含礦物質水(A)製造裝置的一部分亦即遠紅外線照射裝置的示意斷面圖。 Fig. 12 is a schematic cross-sectional view showing a far infrared ray irradiation apparatus which is a part of the apparatus for producing mineral water (A) constituting the mineral water manufacturing apparatus shown in Fig. 7.
圖13係構成圖7所示的礦物質機能水製造設備之含礦物質水(B)製造裝置的方塊圖。 Fig. 13 is a block diagram showing a manufacturing apparatus for mineral-containing water (B) constituting the mineral-functional water producing apparatus shown in Fig. 7.
圖14係顯示構成圖7所示的礦物質機能水製造設備之含礦物質水(B)製造裝置的正面圖。 Fig. 14 is a front elevational view showing the apparatus for producing mineral-containing water (B) constituting the mineral-functional water producing apparatus shown in Fig. 7.
圖15係圖14所示的含礦物質水(B)製造裝置的側面圖。 Fig. 15 is a side view showing the apparatus for producing mineral-containing water (B) shown in Fig. 14.
圖16係顯示圖14所示的含礦物質水(B)製造裝置的結構之局部省略斜視圖。 Fig. 16 is a partially omitted perspective view showing the structure of the apparatus for producing mineral-containing water (B) shown in Fig. 14.
圖17係構成圖14所示的含礦物質水(B)製造裝置的通水容器之側面圖。 Fig. 17 is a side view showing a water-passing container constituting the apparatus for producing mineral-containing water (B) shown in Fig. 14;
圖18係顯示含有礦物質成分的陶瓷燒結體(實施例1)及未含有陶瓷燒結體(對照試料)在25℃對黑體之放射比率的圖。 Fig. 18 is a graph showing the ratio of the emission of the ceramic sintered body containing the mineral component (Example 1) and the ceramic sintered body (control sample) to the black body at 25 °C.
以下,針對本發明顯示實施例等詳細地說明,但,本發明不限於以下的實施例等,在不超出本發明的技術思想範圍下能任意地進行變更而加以實施。 In the following, the present invention is described in detail with reference to the embodiments, and the present invention is not limited to the embodiments described below, and can be arbitrarily changed without departing from the scope of the invention.
<用語的定義> <Definition of terms>
在本說明書中,[礦物質機能水]係指含有礦物質成分,可產生至少一種以上的有效效能之水。 In the present specification, [mineral functional water] means water containing a mineral component and capable of producing at least one or more effective effects.
又,在本說明書中,[含礦物質水]係指當製造礦物質機能水時之前階段的原料水,含礦物質水亦含有礦物質成分。作為本發明的礦物質機能水之製造方法的詳細內容如後述。再者,含礦物質水,其本身可具有有效的效能,亦可不具有有效的效能。 Further, in the present specification, [mineral-containing water] means raw material water in a previous stage when mineral water is produced, and mineral-containing water also contains a mineral component. The details of the method for producing the mineral functional water of the present invention will be described later. Furthermore, mineral-containing water itself may have effective efficacy or may not have effective efficacy.
再者,在本說明書中,[礦物質成分]並非指狹義的礦物質的定義亦即[四元素(碳、氫、氮、氧)除外之無機成分(包含微量元素)],而是若為與無機成分共存的態樣,則亦可包含在狹義的定義中被除外的前述四元素(碳、氫、氮、氧)。因此,例如,[來自於植物之礦物質成分]為亦具有包含鈣等來自於植物的無機成分,以及來自於植物的有機成分之情況的概念。 In addition, in the present specification, [mineral component] does not mean the definition of minerals in a narrow sense, that is, [inorganic components (including trace elements) other than four elements (carbon, hydrogen, nitrogen, oxygen)], but The aspect in which the inorganic component coexists may also include the aforementioned four elements (carbon, hydrogen, nitrogen, oxygen) excluding the narrow definition. Therefore, for example, [a mineral component derived from a plant] is also a concept including an inorganic component derived from a plant such as calcium and an organic component derived from a plant.
又,作為(構成礦物質成分)的無機成分,可舉出例如鈉、鉀、鈣、鎂、及磷等,作為微量元素,可舉出例如鐵、鋅、銅、錳、碘、硒、鉻、及鉬等,但不限於此。 In addition, examples of the inorganic component (constituting the mineral component) include sodium, potassium, calcium, magnesium, and phosphorus. Examples of the trace element include iron, zinc, copper, manganese, iodine, selenium, and chromium. And molybdenum, etc., but are not limited to this.
再者,在本說明書中,[來自於礦物質機能水之礦物質成分]係指從作為對象的礦物質機能水除去溶劑成分後殘存的礦物質成分。但,如以上所述,來自於植物之礦物質成分,不僅含有無機成分,亦含有來自於植物的有機成分。 In the present specification, [a mineral component derived from mineral functional water] means a mineral component remaining after removing a solvent component from the target mineral water. However, as described above, the mineral component derived from a plant contains not only an inorganic component but also an organic component derived from a plant.
在本說明書中,[溶析型陶瓷材料]係指礦物質成分可溶析地被固定化的陶瓷材料。[礦物質成分可溶析地被固定化]係指使作為對象的陶瓷材料與萃取溶劑(一般為以水為主體的溶劑)接觸時,礦物質成分逐漸溶析,最終變得不會殘存於陶瓷材料之狀態(除了不可避免殘餘成分外)。 In the present specification, the [solumetric ceramic material] refers to a ceramic material in which a mineral component is immobilized in a soluble manner. [The mineral component is immobilized in a soluble state] When the ceramic material to be used is brought into contact with an extraction solvent (generally a solvent mainly composed of water), the mineral component gradually dissolves and eventually does not remain in the ceramic. The state of the material (except for the inevitable residuals).
再者,在後述中有將溶析型陶瓷材料稱為[本發明的陶瓷材料]或僅稱為[陶瓷材料]的情況。 In the following description, the eluted ceramic material is referred to as [the ceramic material of the present invention] or simply as the [ceramic material].
在本說明書中,[非溶析型陶瓷材料]係指礦物質成分非溶析地被固定化於成為基材的陶瓷材料之陶瓷材料。[(礦物質成分)非溶析地被固定化]係指當使成為對象的陶瓷材料與水接觸時,礦物質成分實質上不會溶析而殘存於陶瓷材料的態樣。非溶析型陶瓷材料係具有來自於已被固定化之礦物質成分的電磁波照射性。 In the present specification, the [non-lead-type ceramic material] refers to a ceramic material in which a mineral component is immobilized on a ceramic material to be a substrate without being eluted. [(Mineral component) is immobilized in a non-sedimented state] When the ceramic material to be contacted is brought into contact with water, the mineral component does not substantially elute and remains in the ceramic material. The non-lead-type ceramic material has electromagnetic wave irradiance from a mineral component that has been immobilized.
再者,在後述中有將非溶析型陶瓷材料稱為[本發明的陶瓷燒結體]或僅稱為[陶瓷燒結體]的情況。 In addition, in the following, the non-lead-type ceramic material is referred to as [ceramic sintered body of the present invention] or simply [ceramic sintered body].
在本說明書中,[溶析機能水]係指包含藉由溶析型陶瓷材料與萃取溶劑接觸[從溶析型陶瓷材料溶析的礦物質成分之機能水],意指具有至少一種以上的有效效能之機能水。再者,溶析機能水亦可稱為:礦物質機能水的一種,但在此將包含從溶析型陶瓷材料溶析出的礦物質成分之機能水稱為溶析機能水,將此以外的機能水稱為礦物質機能水加以區別。 In the present specification, [solubilizing function water] means a functional water containing a mineral component which is eluted from an elution-type ceramic material by contact with an extraction solvent, and means having at least one or more. Functional water for effective performance. Further, the solute functional water may also be referred to as one type of mineral functional water, but the functional water containing the mineral component eluted from the eluted ceramic material is referred to herein as the solvating water. Functional water is called mineral water to distinguish it.
再者,依據成為載體的陶瓷材料之種類、萃取溶劑的 種類、萃取條件等而有所不同,但,會有因即使與萃取溶劑的接觸,從溶析型陶瓷材料無法萃取全部的礦物質成分之情況。因此,使用於礦物質成分固定化之礦物質機能水的組成和溶析所獲得之溶析機能水的組成,一般並非完全一致。 Furthermore, depending on the kind of the ceramic material to be the carrier, the extraction solvent Although the type, the extraction conditions, and the like are different, there is a case where the entire mineral component cannot be extracted from the eluted ceramic material even if it is in contact with the extraction solvent. Therefore, the composition of the mineral functional water used for the immobilization of the mineral component and the composition of the dissolution functional water obtained by the dissolution are generally not completely identical.
<1.溶析機能水的製造裝置> <1. Manufacturing device for eluting functional water>
本發明的溶析機能水的製造裝置(以下有稱為[本發明的製造裝置]之情況),係用來製造含有礦物質成分的溶析機能水之裝置,其特徵為:具備有:2個以上的處理槽,前述處理槽具有入水路徑及出水路徑,並可在內部供從前述入水路徑流入的水或以水為主體的萃取溶劑朝前述出水路徑流動;及將一個前述處理槽的出水路徑與另一個前述處理槽的入水路徑連通之連結路徑,該二個以上的處理槽係經由前述連結路徑以串聯方式連接,在至少其中一個前述處理槽內,收容有礦物質成分可溶析地被固定化的溶析型陶瓷材料。 The apparatus for producing a melt-dissolving functional water of the present invention (hereinafter referred to as the "manufacturing apparatus of the present invention") is a device for producing a water for concentrating functional water containing a mineral component, and is characterized in that: More than one processing tank, the treatment tank has a water inlet path and a water outlet path, and may internally supply water flowing from the water inlet path or an extraction solvent mainly composed of water toward the water outlet path; and effluent of one of the treatment tanks a connection path connecting the path to another water inlet path of the processing tank, wherein the two or more processing tanks are connected in series via the connecting path, and at least one of the processing tanks contains a mineral component soluble The immobilized ceramic material is immobilized.
再者,在其他的前述處理槽一般為相鄰於一個前述處理槽的旁邊之處理槽。 Furthermore, the other processing tanks described above are generally processing tanks adjacent to one of the processing tanks.
藉由具有這樣的結構,藉由供給水或以水為主體的萃取溶劑,使得礦物質成分從溶析型陶瓷材料溶析至水或以水為主體的萃取溶劑,藉此製造含有礦物質成分 的溶析機能水。溶析型陶瓷材料收容於前述處理槽的至少其中一個處理槽即可。 By having such a structure, by supplying water or an extraction solvent mainly composed of water, the mineral component is eluted from the eluted ceramic material to water or an extraction solvent mainly composed of water, thereby producing a mineral-containing component. The solution is water. The eluted ceramic material may be contained in at least one of the treatment tanks of the treatment tank.
在與溶析型陶瓷材料接觸後之萃取液(溶析機能水),含有被保持於溶析型陶瓷材料的礦物質成分之一部分或全部。 The extract (solution water) after contact with the eluted ceramic material contains a part or all of the mineral component held in the eluted ceramic material.
[以水為主體的萃取溶劑]係指含有50重量%以上的水之液體,作為水以外的成分,包含乙醇等具有與水的相溶性之有機溶劑。又,在萃取溶劑,在不損本發明效果的範圍下,亦可包含pH調整劑等的任意成分。 [Extraction solvent mainly composed of water] is a liquid containing 50% by weight or more of water, and a component other than water, and an organic solvent having compatibility with water such as ethanol. Further, in the extraction solvent, an optional component such as a pH adjuster may be contained in a range that does not impair the effects of the present invention.
再者,以下的說明中,在水為萃取溶劑的情況,將水作為[水及以水為主體的萃取溶劑]使用。 In the following description, when water is an extraction solvent, water is used as [water and extraction solvent mainly composed of water].
作為前述溶析型陶瓷材料,能夠使用含有來自於礦物質機能水的礦物質成分之水泥硬化體、或將該礦物質成分支承於細孔內的陶瓷多孔體。詳細內容在<2-1.溶析型陶瓷材料(陶瓷材料)>進行說明。 As the eluted ceramic material, a cement hardened body containing a mineral component derived from mineral functional water or a ceramic porous body containing the mineral component in a pore can be used. The details are described in <2-1. Solvent-type ceramic material (ceramic material)>.
溶析型陶瓷材料的種類、收容量等可因應目的的溶析機能水加以決定。例如,考量固定化於要收容的溶析型陶瓷材料之礦物質成分的種類、流通之水的量、處理容器的容積、處理容器的數量及配置等再適宜決定。 The type and capacity of the eluted ceramic material can be determined in accordance with the elution function water of the intended purpose. For example, it is preferable to consider the type of the mineral component to be contained in the eluted ceramic material to be accommodated, the amount of water to be distributed, the volume of the processing container, the number and arrangement of the processing containers, and the like.
在本發明的製造裝置,設有連通於收容有前述溶析型陶瓷材料的前述處理槽內之注水路徑為佳。若為這樣的結構,可因應需要,從注水路徑供給任意的成分。 In the manufacturing apparatus of the present invention, it is preferable to provide a water injection path that communicates with the processing tank in which the eluted ceramic material is accommodated. In such a configuration, an arbitrary component can be supplied from the water injection path as needed.
本發明的製造裝置,係在收容有前述溶析型陶瓷材料的處理槽以外之處理槽,收容有非溶析地固定化 有礦物質成分的非溶析型陶瓷材料為佳。藉此,藉由使作為萃取溶劑的水不僅與溶析型陶瓷材料接觸,亦與具有電磁波照射性的非溶析型陶瓷材料接觸,具有能夠使溶析機能水的效能提升之傾向。此原因不明的點仍多數存在,但推測應為溶析機能水所含的礦物質成分(包含來自於植物的有機成分)的活性化等的作用。 In the manufacturing apparatus of the present invention, the processing tank other than the processing tank in which the above-described eluted ceramic material is accommodated is housed and fixed in a non-dissolved manner. A non-lead-type ceramic material having a mineral component is preferred. In this way, by making the water as the extraction solvent not only in contact with the elution-type ceramic material but also in contact with the non-lead-type ceramic material having electromagnetic wave irradiation properties, the water-soluble performance of the electrolyte can be improved. For the reason that the reason is unknown, it is presumed that it is an action of activation of mineral components (including organic components derived from plants) contained in the water for the dissolution of the functional water.
作為非溶析型陶瓷材料,能夠理想地使用含有將來自於礦物質機能水的礦物質成分予以固定化之陶瓷燒結體。詳細內容在<2-2.非溶析型陶瓷材料(陶瓷燒結體)>進行說明。 As the non-lead-type ceramic material, a ceramic sintered body containing a mineral component derived from mineral water can be preferably used. The details are described in <2-2. Non-lead-type ceramic material (ceramic sintered body)>.
期望將收容有前述溶析型陶瓷材料的處理槽中的至少一個處理槽,配置在收容有前述非溶析型陶瓷材料的處理槽之上游側。藉由如此結構,由於從溶析型陶瓷材料溶析的礦物質成分直接與非溶析型陶瓷材料接觸,故,具有使溶析機能水的效能進一步提升的傾向。 At least one of the treatment tanks in which the above-described eluted ceramic material is accommodated is disposed on the upstream side of the treatment tank in which the non-lead-type ceramic material is accommodated. According to this configuration, since the mineral component eluted from the eluted ceramic material is directly in contact with the non-lead-type ceramic material, the performance of the water for the electrolyte is further improved.
前述非溶析型陶瓷材料的種類、收容量等可因應目的的溶析機能水加以決定。例如,考量固定化於要收容的溶析型陶瓷材料之礦物質成分的種類、流通之水的量、處理容器的容積、處理容器的數量及配置等再適宜決定。 The type and capacity of the non-lead-type ceramic material can be determined in accordance with the elution function water of the intended purpose. For example, it is preferable to consider the type of the mineral component to be contained in the eluted ceramic material to be accommodated, the amount of water to be distributed, the volume of the processing container, the number and arrangement of the processing containers, and the like.
本發明的製造裝置中,2個以上的處理槽分別經由前述連結路徑以串聯方式連接的構造即可,處理槽的數量、配置等可因應目的加以適宜決定。 In the manufacturing apparatus of the present invention, the two or more processing tanks may be connected in series via the connecting path, and the number and arrangement of the processing tanks may be appropriately determined depending on the purpose.
其中,能夠作成為緊緻形態的2個處理槽經由前述連 結路徑以串聯方式連接的製造裝置為佳。作為本發明的實施形態之製造裝置的詳細內容如後述。 Among them, it is possible to make two processing tanks in a compact form via the aforementioned connection It is preferred that the junction paths are connected in series. The details of the manufacturing apparatus according to the embodiment of the present invention will be described later.
在這樣結構的製造裝置,期望將收容有前述溶析型陶瓷材料的處理槽中的至少一個處理槽,配置在收容有前述非溶析型陶瓷材料的處理槽之上游側。特別是將位於前述連結路徑上游側的其中一方之前述處理槽配置在較前述另一方的前述處理槽更高的位置為佳。 In the manufacturing apparatus having such a configuration, it is desirable that at least one of the processing tanks in which the eluted ceramic material is accommodated is disposed on the upstream side of the processing tank in which the non-lead-type ceramic material is accommodated. In particular, it is preferable that the processing tank located on one of the upstream sides of the connecting path is disposed at a position higher than the processing tank of the other one.
本發明的溶析機能水的製造方法之特徵是使用前述其中一個的本發明的製造裝置。 The method for producing a leaching machine water of the present invention is characterized in that the manufacturing apparatus of the present invention using one of the foregoing is used.
本發明的溶析機能水的製造方法之第1態樣為具有以下製程,亦即對本發明的製造裝置,供給水或以水為主體的萃取溶劑,使水或以水為主體的萃取溶劑與收容於前述處理槽中的其中一個處理槽之前述溶析型陶瓷材料接觸的製程。 The first aspect of the method for producing a water for dissolving functional water of the present invention has a process of supplying water or a water-based extraction solvent to the production apparatus of the present invention, and water or a water-based extraction solvent and a process of contacting the aforementioned elutive ceramic material in one of the processing tanks in the processing tank.
本發明的溶析機能水的製造方法之第2態樣為具有以下製程,亦即對本發明的製造裝置,供給水或以水為主體的萃取溶劑,使水或以水為主體的萃取溶劑與收容於前述處理槽中的其中一個處理槽之前述溶析型陶瓷材料及前述非溶析型陶瓷材料接觸的製程。在此情況,還具有以下製程為佳,亦即使水或以水為主體的萃取溶劑與溶析型陶瓷材料接觸後,再使與溶析型陶瓷材料接觸之水或以水為主體的萃取溶劑與非溶析型陶瓷材料接觸的製程。在第2態樣,使用在實施形態中後述的2個處理槽經由前述連結路徑以串聯方式連接的製造裝置為佳。 A second aspect of the method for producing a water for emulsification of the present invention is a process for supplying water or a water-based extraction solvent to the production apparatus of the present invention, and water or a water-based extraction solvent and a process of contacting the eluted ceramic material of the one of the treatment tanks in the treatment tank with the non-lead-type ceramic material. In this case, it is preferable to have the following processes, and even if water or a water-based extraction solvent is contacted with the eluted ceramic material, the water in contact with the eluted ceramic material or the water-based extraction solvent is used. Process in contact with non-lead-type ceramic materials. In the second aspect, it is preferable to use a manufacturing apparatus in which two processing tanks to be described later in the embodiment are connected in series via the connecting path.
以下,參照圖面說明關於本發明的溶析機能水的製造裝置之理想實施形態亦即經由連結路徑將2個處理槽以串聯方式連接的態樣之製造裝置、及其使用方法,但本發明不限於該實施形態。 Hereinafter, a manufacturing apparatus in which two processing tanks are connected in series via a connecting path, and a method of using the same according to a preferred embodiment of the apparatus for producing a melt-dissolving water according to the present invention will be described with reference to the drawings. It is not limited to this embodiment.
以下,依據圖1至圖4,說明關於本發明的實施形態之礦物質機能水製造裝置100。 Hereinafter, a mineral water-producing apparatus 100 according to an embodiment of the present invention will be described with reference to Figs. 1 to 4 .
如圖1所示,本實施形態的礦物質機能水製造裝置100具備有:沿著垂直方向配置成串聯狀的第一處理槽110及第二處理槽150;對第一處理槽110供水的供水管117;將第一處理槽110與第二處理槽150連通的連通路徑158;以及將在第二處理槽150內所形成的溶析機能水W2(參照圖3)輸出的出水路徑153。 As shown in Fig. 1, the mineral water-producing apparatus 100 of the present embodiment includes a first treatment tank 110 and a second treatment tank 150 which are arranged in series in the vertical direction, and a water supply for supplying water to the first treatment tank 110. The tube 117; a communication path 158 that connects the first treatment tank 110 and the second treatment tank 150; and a water discharge path 153 that outputs the elution functional water W2 (see FIG. 3) formed in the second treatment tank 150.
第一處理槽110係藉由在略圓筒狀的外殼111的上下端之凸緣111a、111b分別經由甜甜圈圓板狀的襯墊P將圓形的蓋體115、116加以安裝來形成。第二處理槽150也同樣地藉由在略圓筒狀的外殼151的上下端之凸緣151a、151b分別經由甜甜圈圓板狀的襯墊P將圓形的蓋體155、156加以安裝來形成。第一處理槽110與第二處理槽150的尺寸、形狀等相同,但不限於此。 The first treatment tank 110 is formed by attaching the circular lids 115 and 116 to the flanges 111a and 111b of the upper and lower ends of the substantially cylindrical casing 111 via the donut disk-shaped spacer P, respectively. . Similarly, the second processing tank 150 is attached to the circular lids 155 and 156 via the donut disc-shaped spacers P at the upper and lower end flanges 151a and 151b of the substantially cylindrical outer casing 151. To form. The first processing tank 110 is the same as the size, shape, and the like of the second processing tank 150, but is not limited thereto.
藉由將位於上方的第一處理槽110的下方之凸緣111b及蓋體116、和位於下方的第二處理槽150的上方之凸緣151a及蓋體155經由複數個支柱125連結,使得第一處理槽110與第二處理槽150在隔著因應支柱125的長度之預定距離的狀態下呈串連狀配置於垂直方向 上。在位於下方的第二處理槽150的下方之蓋體156的下面側,安裝有複數個腳輪157。 The flange 111b and the lid 116 below the first treatment tank 110 located above and the flange 151a and the lid 155 above the second treatment tank 150 located below are connected via a plurality of pillars 125, so that The processing tank 110 and the second processing tank 150 are arranged in series in a vertical direction in a state of being separated by a predetermined distance from the length of the supporting pillar 125. on. A plurality of casters 157 are attached to the lower surface side of the cover 156 below the second processing tank 150 located below.
如圖2所示,第一處理槽110具備有:將經由供水管117所輸送的水流入至外殼111內的入水路徑112;及用來將在外殼111內所形成的溶析機能水W1排出的出水路徑113。入水路徑112係設置成貫通外殼111的上方(靠近凸緣111a的部分),出水路徑113係設置成貫通外殼111的下方的蓋體116。 As shown in FIG. 2, the first treatment tank 110 is provided with a water inlet path 112 for flowing water transported through the water supply pipe 117 into the outer casing 111, and for discharging the melt water W1 formed in the outer casing 111. The water outlet path 113. The water inlet path 112 is provided to penetrate the upper portion of the outer casing 111 (portion close to the flange 111a), and the water discharge path 113 is provided to penetrate the lid body 116 below the outer casing 111.
在外殼111內突出的入水路徑112之肘部分,設有利用浮子121的下降、上升進行起伏的臂122對入水路徑112進行開放、關閉之開閉閥120。當第一處理槽110的外殼111內之水位下降時,浮子121下降而使開閉閥120打開,讓水從入水路徑112的開口部112a朝外殼111內吐出。當藉由來自於入水路徑112的開口部112a吐出之水使外殼111內之水位上升時,浮子121上升而使開閉閥120關閉,停止水從開口部112a吐出。 The elbow portion of the water inlet path 112 that protrudes in the outer casing 111 is provided with an opening and closing valve 120 that opens and closes the water inlet path 112 by the arm 122 that is undulated by the rise and fall of the float 121. When the water level in the outer casing 111 of the first treatment tank 110 is lowered, the float 121 is lowered to open the opening and closing valve 120, and water is discharged from the opening portion 112a of the water inlet path 112 toward the outer casing 111. When the water level in the casing 111 rises by the water discharged from the opening 112a of the water inlet path 112, the float 121 rises and the opening and closing valve 120 is closed, and the water is stopped from being discharged from the opening 112a.
外殼111的內部,係藉由從蓋體116隔著一定距離而與蓋體116平行地配置在靠近下方的蓋體116之部分的隔壁118區劃成上部空間111x與下部空間111y。在隔壁118開設有複數個貫通孔118a,在較隔壁118上方的上部空間111x內,收容有複數個透水性袋體N,該透水性袋體N內裝有溶析型陶瓷材料C1。 The inside of the casing 111 is partitioned into an upper space 111x and a lower space 111y by a partition wall 118 which is disposed in parallel with the lid 116 from a portion of the lid 116 which is disposed in parallel with the lid 116. A plurality of through holes 118a are formed in the partition wall 118, and a plurality of water permeable bag bodies N are accommodated in the upper space 111x above the partition wall 118, and the water permeable bag body N is provided with a dissolution type ceramic material C1.
連通於第一處理槽110的外殼111內之注水路徑114是以從第一處理槽110的外部貫通上方的蓋體 115的方式設在外殼111內。注水路徑114的上端開口部114a係位於第一處理槽110的外部,注水路徑114的下端側是貫通隔壁118的貫通孔118a,其下端開口部114b位於下部空間111y內。 The water injection path 114 in the outer casing 111 connected to the first treatment tank 110 is a cover body penetrating from the outside of the first treatment tank 110 The mode of 115 is provided in the casing 111. The upper end opening portion 114a of the water injection path 114 is located outside the first processing tank 110, and the lower end side of the water injection path 114 is a through hole 118a penetrating the partition wall 118, and the lower end opening portion 114b is located in the lower space 111y.
在外殼111中靠近上方的蓋體115之部分(與入水路徑112略相同高度的部分),設有與外殼111內連通的排水路徑119。當開閉閥120的關閉不良等的原因,造成水從開口部112a過剩地流入到外殼111內,使得外殼111內的水位上升時,能夠從排水路徑119使過剩的水溢出。 A portion of the outer casing 111 which is adjacent to the upper cover 115 (a portion having the same height as the water inlet path 112) is provided with a drainage path 119 communicating with the inside of the outer casing 111. When the opening and closing valve 120 is closed or the like, water excessively flows into the casing 111 from the opening portion 112a, and when the water level in the casing 111 rises, excess water can overflow from the drainage path 119.
如圖3所示,第二處理槽150具備有:用來將經由連結路徑158從第一處理槽110(參照圖1)所輸送的溶析機能水W1流入至外殼151內的入水路徑152;及用來將在外殼151內所形成的溶析機能水W2排出的出水路徑153。入水路徑152係貫通外殼151的下方(靠近凸緣151b的部分)而連通於外殼151內,出水路徑153係貫通外殼151的上方的蓋體155而連通於外殼151內。在外殼151的內部,收容有複數個透水性袋體N,該透水性袋體N內裝有非溶析型陶瓷材料C2。 As shown in FIG. 3, the second processing tank 150 is provided with a water inlet path 152 for flowing the elution functional water W1 conveyed from the first processing tank 110 (see FIG. 1) via the connecting path 158 into the outer casing 151; And a water discharge path 153 for discharging the elution function water W2 formed in the outer casing 151. The water inlet path 152 communicates with the inside of the casing 151 through the lower portion of the casing 151 (portion close to the flange 151b), and the water discharge path 153 passes through the lid 155 above the casing 151 to communicate with the inside of the casing 151. Inside the outer casing 151, a plurality of water-permeable bag bodies N are housed, and the water-permeable bag body N is provided with a non-lead-type ceramic material C2.
外殼151內之出水路徑153的開口部153a係設在從蓋體155的中心偏移的位置(朝蓋體155的外周側偏心之位置)。蓋體155的下面155a(外殼151的內部側的面)係呈朝開口部153a凹陷的傘狀,開口部153a位於其最上部。在出水路徑153,設有能以操作桿54a進行手動 操作的開閉閥154b,在其下游側連接有出水管159。 The opening portion 153a of the water discharge path 153 in the outer casing 151 is provided at a position offset from the center of the lid body 155 (a position eccentric toward the outer circumferential side of the lid body 155). The lower surface 155a of the lid body 155 (the surface on the inner side of the outer casing 151) has an umbrella shape recessed toward the opening portion 153a, and the opening portion 153a is located at the uppermost portion thereof. In the water outlet path 153, it is provided to be manually operated by the operating lever 54a. The operated opening and closing valve 154b is connected to an outlet pipe 159 on the downstream side thereof.
在礦物質機能水製造裝置100,被收容於位在第二處理槽150的上方之第一處理槽110的外殼111內的溶析型陶瓷材料C1係為來自於礦物質機能水的礦物質成分可溶析地被固定化(保持)的陶瓷材料。溶析型陶瓷材料C1係使用含有前述礦物質成分之水泥硬化體,但亦可使用將前述礦物質成分支承於細孔內的陶瓷多孔體。 In the mineral water-producing device 100, the eluted ceramic material C1 contained in the outer casing 111 of the first treatment tank 110 located above the second treatment tank 150 is a mineral component derived from mineral functional water. A ceramic material that is immobilized (held) by elution. In the eluted ceramic material C1, a cement hardened body containing the above-described mineral component is used, but a ceramic porous body in which the above-described mineral component is supported in the pores may be used.
在礦物質機能水製造裝置100,被收容於位在第一處理槽110的下方之第二處理槽150的外殼151內的非溶析型陶瓷材料C2係為含有具備電磁波放射作用之含有礦物質成分的陶瓷燒結體。 In the mineral water-producing device 100, the non-lead-type ceramic material C2 accommodated in the outer casing 151 of the second treatment tank 150 located below the first treatment tank 110 contains mineral-containing substances having electromagnetic radiation. A ceramic sintered body of the composition.
在此,其次,依據圖1至圖4,說明關於礦物質機能水製造裝置100之溶析機能水的製造方法。如圖1所示,將礦物質機能水製造裝置100設在地面G上,再將供水管117的上游側連接於供水源(例如自來水的水龍頭等),並將第二處理槽150的出水路徑153之開閉閥154b設成預定開度。然後,當從供水源經由供水管117進行供水時,水會經由入水路徑112流入至第一處理槽110的外殼111之內部,使得溶析型陶瓷材料C1與水接觸。 Here, next, a method of manufacturing the melt water of the mineral water manufacturing apparatus 100 will be described with reference to FIGS. 1 to 4 . As shown in FIG. 1, the mineral water manufacturing apparatus 100 is installed on the floor G, and the upstream side of the water supply pipe 117 is connected to a water supply source (for example, a tap of tap water, etc.), and the water outlet path of the second processing tank 150 is provided. The opening and closing valve 154b of 153 is set to a predetermined opening degree. Then, when water supply is performed from the water supply source via the water supply pipe 117, the water flows into the inside of the outer casing 111 of the first treatment tank 110 via the water inlet path 112, so that the eluted ceramic material C1 comes into contact with water.
當在外殼111內,水與溶析型陶瓷材料C1接觸時,已被固定化於溶析型陶瓷材料C1的礦物質成分會溶析至作為萃取溶劑之水,形成溶析機能水W1。 When the water is in contact with the eluted ceramic material C1 in the outer casing 111, the mineral component that has been immobilized on the eluted ceramic material C1 is eluted into water as an extraction solvent to form the elution functional water W1.
再者,當溶析型陶瓷材料C1為固定化有來自於容後詳述之專利文獻3(WO2016/043213)中所揭示的礦物質機 能水(後述的礦物質機能水(1))之礦物質成分的溶析型陶瓷材料時,會形成為pH上升至10.5~11.5左右的溶析機能水W1。 Further, when the eluted ceramic material C1 is immobilized, the mineral machine disclosed in Patent Document 3 (WO2016/043213), which is described later in detail, is incorporated. When the eluted ceramic material of the mineral component of the water (mineral functional water (1) to be described later) is formed, the electrolytic solution water W1 whose pH is raised to about 10.5 to 11.5 is formed.
藉由與第一處理槽110內的溶析型陶瓷材料C1接觸所形成的溶析機能水W1會經由出水路徑113、連結路徑158及入水路徑152,流入至第二處理槽150的外殼151內,在外殼151內與非溶析型陶瓷材料C2接觸。因在出水路徑13設有pH計(未圖示),所以,能夠始終檢測流動於出水路徑13內的溶析機能水W1之pH。 The elution functional water W1 formed by contact with the eluted ceramic material C1 in the first treatment tank 110 flows into the outer casing 151 of the second treatment tank 150 via the water discharge path 113, the connection path 158, and the water inlet path 152. It is in contact with the non-lead-type ceramic material C2 in the outer casing 151. Since a pH meter (not shown) is provided in the water discharge path 13, the pH of the elution function water W1 flowing in the water discharge path 13 can always be detected.
當在外殼151內,溶析機能水W1與非溶析型陶瓷材料C2接觸時,藉由自非溶析型陶瓷材料C2所放射的電磁波作用,將溶析機能水W1中所含的礦物質成分活性化而形成為溶析機能水W2,並經由外殼151的上方之出水路徑153及出水管159供給至預定場所。藉由非溶析型陶瓷材料C2之使礦物質成分活性化的詳細原因,不明的點仍多數存在,但推測應為溶析機能水W1所含的礦物質成分(包含來自於植物的有機成分)之離子化行進等的作用。 When the elution functional water W1 is in contact with the non-lead-type ceramic material C2 in the outer casing 151, the mineral contained in the melt water W1 is dissolved by the electromagnetic wave emitted from the non-solubilized ceramic material C2. The component is activated to form the elution functional water W2, and is supplied to a predetermined place via the water discharge path 153 and the outlet pipe 159 above the casing 151. The detailed reason for the activation of the mineral component by the non-lead-type ceramic material C2 is still unknown, but it is presumed that it is the mineral component contained in the soluble functional water W1 (including organic components derived from plants). The role of ionization travel, etc.
因在出水路徑153設有pH計(未圖示),所以,能夠始終檢測流動於出水路徑153內的溶析機能水W2之pH。 Since a pH meter (not shown) is provided in the water discharge path 153, the pH of the elution function water W2 flowing in the water discharge path 153 can always be detected.
再者,當非溶析型陶瓷材料C2為固定化有來自於容後詳述之專利文獻3(WO2016/043213)中所揭示的礦物質機能水(礦物質機能水(1))之礦物質成分的非溶析型陶瓷材 料時,會形成為pH上升至12左右的溶析機能水W2。 Further, when the non-lead-type ceramic material C2 is a mineral which is immobilized with mineral functional water (mineral functional water (1)) disclosed in Patent Document 3 (WO2016/043213), which is described later in detail. Insoluble ceramic material At the time of the material, the electrolytic solution water W2 whose pH rises to about 12 is formed.
如圖1所示,在溶析機能水製造裝置100,位於連通路徑158上游側的第一處理槽110是配置在較第二處理槽150更高的位置(第二處理槽150的正上方)。因此,若將水供給至第一處理槽110,則藉由重力的作用,使得水依次在第一處理槽110的內部及第二處理槽150的內部流動,藉此能夠形成預定的溶析機能水W2。亦即,礦物質機能水製造裝置100,若為對第一處理槽110可進行供水的供水源,則藉由無電源或其他動力源等,能夠容易且穩定地製造藉由包含預定的礦物質成分具有有益的效能之溶析機能水W2。 As shown in FIG. 1, in the elution functional water producing apparatus 100, the first processing tank 110 located on the upstream side of the communication path 158 is disposed at a position higher than the second processing tank 150 (directly above the second processing tank 150). . Therefore, when water is supplied to the first treatment tank 110, water is sequentially flowed inside the first treatment tank 110 and inside the second treatment tank 150 by gravity, whereby a predetermined dissolution function can be formed. Water W2. In other words, the mineral water-producing device 100 can be easily and stably manufactured by containing a predetermined mineral by using a power source that can supply water to the first treatment tank 110 without using a power source or other power source. The composition has a beneficial performance of the soluble functional water W2.
在礦物質機能水製造裝置100,藉由操作設在第二處理槽150的上部之出水路徑153的操作桿154a而調整開閉閥154b的開度,增減來自於出水路徑153的流水量,可調整經由入水路徑112供給至礦物質機能水製造裝置100之水滯留於第一處理槽110及第二處理槽150的滯留時間(反應時間),藉此能夠製造適當的pH之溶析機能水W2。 In the mineral water-producing device 100, the opening degree of the opening and closing valve 154b is adjusted by operating the operation lever 154a of the water discharge path 153 provided in the upper portion of the second treatment tank 150, and the amount of water flowing from the water discharge path 153 can be increased or decreased. By adjusting the residence time (reaction time) of the water supplied to the mineral water-producing device 100 via the water-intake path 112 in the first treatment tank 110 and the second treatment tank 150, it is possible to produce a suitable pH-soluble solvent water W2. .
因在第一處理槽110的外殼111內,設有藉由浮子121的升降來進行作動之開閉閥120,所以能夠防止過剩的水從入水路徑112流入至外殼111內。又,在假設過剩的水從入水路徑112流入到外殼111內之情況,因剩餘的水會從排水路徑119排出至外部,所以,也不會有第一處理槽110、第二處理槽150等受到水壓所損傷。 Since the opening and closing valve 120 that is actuated by the raising and lowering of the float 121 is provided in the outer casing 111 of the first treatment tank 110, it is possible to prevent excess water from flowing into the casing 111 from the water inlet path 112. Further, when it is assumed that excess water flows into the casing 111 from the water inlet path 112, since the remaining water is discharged from the drainage path 119 to the outside, the first treatment tank 110, the second treatment tank 150, and the like are not present. Damaged by water pressure.
再者,亦可可因應需要,自從第一處理槽110的上部突出之注水路徑114的上端開口部114a注入任意的成分。 Further, an optional component may be injected from the upper end opening portion 114a of the water injection path 114 that protrudes from the upper portion of the first treatment tank 110 as needed.
例如,溶析型陶瓷材料C1、非溶析型陶瓷材料C2分別為固定化有來自於礦物質機能水(1)的礦物質成分之溶析型陶瓷材料、非溶析型陶瓷材料的情況,可舉出以下這樣的運轉方法。 For example, the eluted ceramic material C1 and the non-lead-type ceramic material C2 are each a precipitated ceramic material or a non-lead-type ceramic material in which a mineral component derived from the mineral functional water (1) is immobilized. The following operation methods are mentioned.
在第一處理槽110形成且從出水路徑113流出之溶析機能水W1的pH低的情況(pH未滿10.5的情況),將從第二處理槽150的出水路徑153所吐出之溶析機能水W2的一部分自從第一處理槽110的上部突出之注水路徑114的上端開口部114a注入。藉此,因可將pH12左右的溶析機能水W2經由注水路徑114的下端開口部114b而供給至第一處理槽110的外殼111的下部空間111y而混入到溶析機能水W1內,所以,可將從:第一處理槽110經由出水路徑113流出的溶析機能水W1之pH作成為預定值。 When the pH of the elution functional water W1 formed in the first treatment tank 110 and flowing out from the water discharge path 113 is low (when the pH is less than 10.5), the dissolution function discharged from the water discharge path 153 of the second treatment tank 150 is discharged. A part of the water W2 is injected from the upper end opening portion 114a of the water injection path 114 that protrudes from the upper portion of the first treatment tank 110. Therefore, the elution functional water W2 having a pH of about 12 is supplied to the lower space 111y of the outer casing 111 of the first treatment tank 110 through the lower end opening portion 114b of the water injection path 114, and is mixed into the solute functional water W1. The pH of the elution functional water W1 flowing out from the first treatment tank 110 via the water discharge path 113 can be set to a predetermined value.
如圖3、圖4所示,用來封閉第二處理槽150的外殼151的上方之蓋體155的下面155a呈朝出水路徑153的開口部153a凹陷的傘狀,且開口部153a位於下面155a的最上部。因此,如圖4所示,在外殼151的內部的溶析機能水W2中所產生之氣泡B上升至蓋體155的下面155a後,沿著下面155a的傾斜而朝上方移動,從開口部153a與溶析機能水W2一同經由出水路徑153迅速地排出。因此,可防止氣泡B逐漸儲存到外殼151內的缺點 產生。 As shown in FIGS. 3 and 4, the lower surface 155a of the lid body 155 for closing the outer casing 151 of the second treatment tank 150 has an umbrella shape recessed toward the opening portion 153a of the water discharge path 153, and the opening portion 153a is located at the lower surface 155a. The top of the. Therefore, as shown in FIG. 4, the bubble B generated in the elution functional water W2 inside the outer casing 151 rises to the lower surface 155a of the lid body 155, and then moves upward along the inclination of the lower surface 155a, from the opening portion 153a. It is quickly discharged through the water discharge path 153 together with the dissolution functional water W2. Therefore, the disadvantage that the bubble B is gradually stored into the outer casing 151 can be prevented. produce.
如圖1、圖3所示,在外殼151的下方的蓋體156之下面,設有複數個腳輪157,因此,溶析機能水製造裝置100在與地面G形成接地的狀態下亦可容易移動,便利性佳。 As shown in FIG. 1 and FIG. 3, a plurality of casters 157 are provided on the lower surface of the cover 156 below the outer casing 151. Therefore, the melt water-producing device 100 can be easily moved while being grounded to the ground G. Good convenience.
構成溶析機能水製造裝置100的第一處理槽110及第二處理槽150的蓋體115、155分別可對外殼111、151進行裝卸,因此,亦可容易進行溶析型陶瓷材料C1、非溶析型陶瓷材料C2等的置入取出、更換作業等。 The lids 115 and 155 of the first treatment tank 110 and the second treatment tank 150 constituting the melt water-producing device 100 can be attached to and detached from the outer casings 111 and 151, respectively, so that the electrolytic ceramic materials C1 and C can be easily formed. The extraction and replacement work of the eluted ceramic material C2 or the like.
以上,說明了本發明的溶析機能水製造裝置之理想實施形態,但不限於該等實施形態,只要能夠製造溶析機能水即可,除了前述理想實施形態以外,亦可採用各種結構。特別是在此次所揭示的實施形態中,未明確揭示的事項例如運轉條件、操作條件、各種參數、構成物的尺寸、重量、體積等,是採用不會超出該業者一般實施的範圍,若為一般的該業者即可容易想到的值。 In the above, a preferred embodiment of the apparatus for producing a solvable water according to the present invention has been described. However, the present invention is not limited to the embodiments, and any configuration may be employed in addition to the above-described preferred embodiment. In particular, in the embodiments disclosed herein, items that are not explicitly disclosed, such as operating conditions, operating conditions, various parameters, size, weight, volume, etc. of the components, are used without exceeding the scope generally practiced by the industry. A value that can be easily imagined by a general practitioner.
再者,依據圖1至圖4說明過的溶析機能水製造裝置100為顯示本發明的一例,本發明之溶析機能水製造裝置不限於前述溶析機能水製造裝置100。溶析機能水製造裝置100雖具備各1個第一處理槽110及第二處理槽150,但可因應目的,具備3個以上的處理槽,其亦可任意進行配置。 Further, the elution functional water producing apparatus 100 described with reference to FIGS. 1 to 4 is an example of the present invention, and the eluting functional water producing apparatus of the present invention is not limited to the above-described electrolytic solvable water producing apparatus 100. The elution functional water producing apparatus 100 includes one first processing tank 110 and one second processing tank 150. However, three or more processing tanks may be provided depending on the purpose, and they may be arranged arbitrarily.
例如,可採用如圖5的示意圖所示,將3個處理槽以 串聯方式排列的結構、如圖6的示意圖所示,將上游的處理槽以並聯方式配置,並對該處理槽以串聯方式連接下游的處理槽之結構等,只要2個以上的處理槽以串聯方式連接,包含於本發明的製造裝置的概念。 For example, as shown in the schematic diagram of FIG. 5, three processing tanks may be used. As shown in the schematic diagram of FIG. 6, the upstream processing tanks are arranged in parallel, and the processing tanks are connected in series to the downstream processing tanks, and the like, as long as two or more processing tanks are connected in series. The mode connection is included in the concept of the manufacturing apparatus of the present invention.
又,在本發明的製造裝置,即使為具有2個以上的處理槽之情況,在1個以上的處理槽含有溶析型陶瓷材料即可。例如,在溶析機能水製造裝置100,以溶析機能水W1為目的之情況,可不將非溶析型陶瓷材料收容於第二處理槽150,僅使用溶析型陶瓷材料C1獲得溶析機能水W1。 Further, in the production apparatus of the present invention, even if it has two or more processing tanks, it is sufficient to contain a elution-type ceramic material in one or more processing tanks. For example, in the case of the analysis of the functional water W1, the non-leolysis-type ceramic material can be stored in the second treatment tank 150, and the elution-type ceramic material C1 can be used to obtain the elution function. Water W1.
<2.溶析型陶瓷材料及非溶析型陶瓷材料> <2. Solvent-type ceramic materials and non-lead-type ceramic materials>
以下說明關於使用於前述本發明的製造裝置之溶析型陶瓷材料及非溶析型陶瓷材料。在以下的說明中,有將[溶析型陶瓷材料]稱為[本發明的陶瓷材料]或僅稱為[陶瓷材料]的情況,其為相同的意思。又,有將[非溶析型陶瓷材料]稱為[本發明的陶瓷燒結體]或僅稱為[陶瓷燒結體]的情況,其為相同的意思。 The eluted ceramic material and the non-lead-type ceramic material used in the above-described production apparatus of the present invention will be described below. In the following description, the case of [solubility-type ceramic material] is referred to as [ceramic material of the present invention] or simply [ceramic material], and the same meaning is given. In addition, the case of [non-lead-type ceramic material] is referred to as [ceramic sintered body of the present invention] or simply as [ceramic sintered body], and the same meaning is given.
<2-1.溶析型陶瓷材料(陶瓷材料)> <2-1. Solvent-type ceramic material (ceramic material)>
本發明的陶瓷材料為礦物質成分可溶析地被固定化(保持)之溶析型陶瓷材料,大致可分成以下的2種態樣。 The ceramic material of the present invention is a dissolution type ceramic material in which a mineral component is immobilized (held) in a form of elution, and can be roughly classified into the following two aspects.
本發明的陶瓷材料(溶析型陶瓷材料)之第1態樣,為含有來自於礦物質機能水的礦物質成分之水泥硬化體。 The first aspect of the ceramic material (solubolytic ceramic material) of the present invention is a cement hardened body containing a mineral component derived from mineral functional water.
又,本發明的陶瓷材料之第2態樣,為在細孔內支承有來自於礦物質機能水的礦物質成分之陶瓷多孔質體。 Further, the second aspect of the ceramic material of the present invention is a ceramic porous body in which a mineral component derived from mineral functional water is supported in pores.
本發明的陶瓷材料之第1態樣、第2態樣均為礦物質成分可溶析地被固定化之陶瓷材料。在此,[礦物質成分可溶析地被固定化]係指使作為對象的陶瓷材料與萃取溶劑(一般為以水為主體的溶劑)接觸時,礦物質成分逐漸溶析,最終變得不會殘存於陶瓷材料之狀態(除了不可避免殘餘成分外)。 The first aspect and the second aspect of the ceramic material of the present invention are ceramic materials in which the mineral component is immobilized and dissolved. Here, [the mineral component is immobilized by elution] means that when the target ceramic material is brought into contact with an extraction solvent (generally a solvent mainly composed of water), the mineral component is gradually dissolved and eventually becomes not formed. Remains in the state of ceramic materials (except for unavoidable residual components).
固定化於本發明的陶瓷材料的礦物質成分,係為來自於礦物質機能水之礦物質成分為佳。再者,關於該礦物質機能水,與其製造方法一併如後進行說明。 The mineral component immobilized on the ceramic material of the present invention is preferably a mineral component derived from mineral functional water. Further, the mineral functional water will be described later in conjunction with the production method thereof.
以下,針對第1態樣、第2態樣之陶瓷材料,配合其製造方法一併詳細進行說明。 Hereinafter, the ceramic material of the first aspect and the second aspect will be described in detail together with the production method.
(1)第1態樣(水泥硬化體) (1) The first aspect (cement hardened body)
本發明的陶瓷材料之第1態樣,為含有礦物質成分之水泥硬化體(以下有記載為[本發明的水泥硬化體]之情況)。作為本發明的陶瓷材料的第1態樣之水泥硬化體,具有比起第2態樣的陶瓷多孔質體可將礦物質成分更多量地加以保持之優點。 The first aspect of the ceramic material of the present invention is a cement hardened body containing a mineral component (hereinafter referred to as "the cement hardened body of the present invention"). The cement hardened body according to the first aspect of the ceramic material of the present invention has an advantage that the mineral component can be held in a larger amount than the ceramic porous body of the second aspect.
本發明的水泥硬化體係可使用含有礦物質成分的礦物質機能水,將水泥混合物固化來加以製造。 The cement hardening system of the present invention can be produced by solidifying a cement mixture using mineral functional water containing a mineral component.
亦即,本發明的水泥硬化體的特徵為具有:將含有礦物質成分的礦物質機能水與水泥組成物進行拌合,獲得水 泥拌合物之拌合製程;及將所獲得的水泥拌合物進行養護而固化之固化製程。 That is, the cement hardened body of the present invention is characterized in that the mineral functional water containing the mineral component is mixed with the cement composition to obtain water. a mixing process of the mud mixture; and a curing process for curing the obtained cement mixture for curing.
再者,在此所稱的[水泥混合物]係指混合含有水泥粉末之原料者,[水泥拌合物]係指使水泥混合物含水而未固化之具有流動性者。又,本發明之[水泥硬化體]係指水泥拌合物硬化,一般亦包含具有水泥粉末以外的成分之砂漿、混凝土之概念。 In addition, the term "cement mixture" as used herein refers to a material in which a cement powder is mixed, and [cement mixture] means a fluidity in which a cement mixture is hydrated and uncured. Further, the [cement hardened body] of the present invention means that the cement mixture is hardened, and generally includes the concept of mortar and concrete having components other than cement powder.
拌合製程之[水泥混合物]能夠採用使用於水泥硬化體的製造之習知的水泥粉末、混合材(骨材等)。 The [cement mixture] of the mixing process can be a conventional cement powder or a mixed material (aggregate or the like) used for the production of a cemented body.
水泥粉末的水泥體的種類未特別限制,能夠採用一般波特蘭水泥、早強型波特蘭水泥、超早強型波特蘭水泥、中庸熱波特蘭水泥、低熱波特蘭水泥、耐硫酸鹽波特蘭水泥、白色波特蘭水泥(白水泥)等的各種波特蘭水泥及氧化鋁水泥等。 The type of cement body of cement powder is not particularly limited, and general Portland cement, early strength Portland cement, super early strong Portland cement, moderate hot Portland cement, low heat Portland cement, and resistance can be used. Portland cement and alumina cement such as sulfate Portland cement and white Portland cement (white cement).
又,亦可使用將高爐熔渣的微粉末與波特蘭水泥混合之高爐水泥、將飛灰(在火力發電廠等所產生的石灰之焚燒灰)與波特蘭水泥混合之飛灰水泥。 Further, blast furnace cement in which fine powder of blast furnace slag is mixed with Portland cement, fly ash cement in which fly ash (incineration ash of lime produced in a thermal power plant or the like) and Portland cement are mixed may be used.
與水泥粉末所混合的骨材等之混合材亦可採用使用於習知的水泥硬化體的製造之混合材,可舉出例如矽石等的含二氧化矽粉末、石灰石等的含碳酸鈣粉末等。 The mixture of the aggregates and the like which are mixed with the cement powder may be a mixture of the conventionally produced cement hardened body, and examples thereof include calcium carbonate powder containing cerium oxide powder or limestone such as vermiculite. Wait.
礦物質機能水與水泥粉末之混合比例可考量礦物質機能水所含有的礦物質成分之量、pH等,混合於水泥粉末之骨材等的種類、量等,作為水泥拌合物所必要的黏度等加以決定。作為理想的調配之一例,水分量為 15~30重量%、水泥粉末為40~60重量%(殘餘部為混合材等的其他成分)。 The mixing ratio of the mineral functional water and the cement powder can be considered as the amount of the mineral component contained in the mineral functional water, the pH, etc., and the type and amount of the aggregate of the cement powder, etc., which are necessary for the cement mixture. Viscosity, etc. are determined. As an ideal example of blending, the amount of water is 15 to 30% by weight and 40 to 60% by weight of the cement powder (the remaining part is a component such as a mixed material).
礦物質機能水與水泥粉末之拌合方法,未特別限制,使用以往習知的混合裝置充分地拌合成均勻即可。又,在水分不足之情況加水即可。進行加水的水,可為礦物質機能水以外的水分。又,可因應需要,添加使用於水泥硬化體的製造之以往習知的成分。作為任意的成分,若為不會有損本發明的目的之添加物則未特別限制,可舉出例如pH調整劑、減水劑、固化促進劑等。 The method of mixing the mineral functional water and the cement powder is not particularly limited, and it may be sufficiently mixed and synthesized using a conventional mixing device. In addition, water can be added in case of insufficient water. The water to be added may be water other than the mineral water. Further, conventionally used components for the production of a cemented body can be added as needed. The additive is not particularly limited as long as it does not impair the object of the present invention, and examples thereof include a pH adjuster, a water reducing agent, and a curing accelerator.
作為固化製程,將在前述拌合製程所獲得的水泥拌合物進行養護、固化,形成為水泥硬化體。養護條件係可考量使用於成為目的的水泥硬化體之水泥粉末、混合材的種類等、成為目的的水泥硬化體的硬度、要保持的礦物質成分的量等的各種條件,適宜選擇常溫養護、加熱養護、蒸氣養護等的習知之養護方法。 As a curing process, the cement mixture obtained in the aforementioned mixing process is cured and solidified to form a cement hardened body. The curing conditions are various conditions such as the cement powder to be used for the purpose of the cement hardened body, the type of the mixed material, the hardness of the cement hardened body to be used, the amount of the mineral component to be retained, and the like, and it is suitable to select the room temperature curing, Conventional curing methods such as heat curing, steam curing, and the like.
本發明的水泥硬化體之形狀未特別限制,可因應用途成形為理想形狀來使用,可舉出例如粉末狀、粒狀、板狀等。尺寸也為任意,可依據使用目的加以適宜決定。亦可將成形體、或未成形的塊狀物進行粉碎,作為粉體、粒狀體等使用。 The shape of the cement hardened body of the present invention is not particularly limited, and it can be used in an ideal shape for use in the application, and examples thereof include a powder, a pellet, and a plate. The size is also arbitrary and can be appropriately determined depending on the purpose of use. The molded body or the unformed mass may be pulverized and used as a powder, a granule or the like.
(2)第2態樣(陶瓷多孔質體) (2) The second aspect (ceramic porous body)
本發明的陶磁材料之第2態樣,為在細孔內支承礦物質成分的陶瓷多孔質體(以下有記載為[本發明的陶瓷多孔 質體]之情況)。 The second aspect of the ceramic material of the present invention is a ceramic porous body that supports a mineral component in pores (hereinafter referred to as [ceramic porous body of the present invention] The case of plastid].
本發明的陶瓷材料之第2態樣的陶瓷多孔質體,雖可保持的礦物質成分之絕對量少,但相對於第1態樣之水泥硬化體為使礦物質成分溶析後無法再生,第2態樣之陶瓷多孔質體可使礦物質成分溶析後,再次浸透礦物質機能水後乾燥,藉此能夠再生,因此具有可反復利用之優點。 In the ceramic porous body of the second aspect of the ceramic material of the present invention, the absolute amount of the mineral component that can be retained is small, but the cement hardened body of the first aspect cannot be regenerated after the mineral component is eluted. The ceramic porous body of the second aspect has the advantage that it can be reused after the mineral component is eluted and then re-impregnated with the mineral functional water and then dried.
本發明的陶瓷多孔質體之礦物質成分含有作為載體之陶瓷多孔質體,可溶析地被固定。 The mineral component of the ceramic porous body of the present invention contains a ceramic porous body as a carrier, and is fixed by elution.
成為陶瓷多孔質體的原料之氧化物的種類,若為具有適度的燒結性之氧化物即可,未特別限定。作為成為這種原料之氧化物,可舉出例如二氧化矽、氧化鈦、氧化鋁或這些的複合氧化物等。又,亦可理想地使用矽藻土(主成分:二氧化矽)、白陶土(主成分:二氧化矽-氧化鋁)、水滑石等的陶土類。亦可將含有這樣的陶土類之岩石予以粉碎後作為陶瓷載體的原料。例如,在後述的實施例使用的天草大矢野島出產的岩石粉末為陶瓷載體原料之一理想例。 The type of the oxide which is a raw material of the ceramic porous body is not particularly limited as long as it is an oxide having moderate sinterability. Examples of the oxide to be used as such a raw material include cerium oxide, titanium oxide, aluminum oxide, and a composite oxide thereof. Further, clays such as diatomaceous earth (main component: cerium oxide), kaolin (main component: cerium oxide-alumina), and hydrotalcite may be preferably used. Rocks containing such clays can also be pulverized and used as a raw material for ceramic carriers. For example, the rock powder produced by the Amakusa Oyao Island used in the examples described later is an ideal example of a ceramic carrier raw material.
在本發明的陶瓷多孔質體,亦可含有能夠使用於由氧化物所構成的陶瓷多孔質體之習知成分。作為任意的成分,若為不會有損本發明的目的之添加物則未特別限制。 The ceramic porous body of the present invention may contain a conventional component which can be used for a ceramic porous body composed of an oxide. The optional component is not particularly limited as long as it does not impair the object of the present invention.
本發明的陶瓷多孔質體之形狀未特別限制,可因應用途成形為理想形狀來使用,可舉出例如粉末狀、 粒狀、板狀等。尺寸也為任意,可依據使用目的加以適宜決定。亦可將成形體、或未成形的塊狀物進行粉碎,作為粉體、粒狀體等使用。 The shape of the ceramic porous body of the present invention is not particularly limited, and it can be used in an ideal shape for use in the application, and examples thereof include a powder form. Granular, plate-like, etc. The size is also arbitrary and can be appropriately determined depending on the purpose of use. The molded body or the unformed mass may be pulverized and used as a powder, a granule or the like.
本發明的陶瓷多孔質體,利用物理性作用、化學性作用,將礦物質機能水固定化於由陶瓷多孔質體所構成的載體之方法。 The ceramic porous body of the present invention is a method in which a mineral functional water is immobilized on a carrier composed of a ceramic porous body by a physical action or a chemical action.
亦即,本發明的陶瓷多孔質體之製造方法,具有:將混合用液體與載體用陶瓷粉末混合作成為黏土狀混合物之製程(I);將前述黏土狀混合物進行熱處理,獲得陶瓷多孔質體之製程(II);及使礦物質機能水浸透於前述陶瓷多孔質體所具有的細孔後再進行乾燥,將礦物質成分固定化於該陶瓷多孔質體之製程(III)。 That is, the method for producing a ceramic porous body of the present invention comprises a process of mixing a liquid for mixing and a ceramic powder for a carrier into a clay-like mixture (I); and heat-treating the clay-like mixture to obtain a ceramic porous body The process (II); and the process (III) of allowing the mineral water to permeate the pores of the ceramic porous body and then drying the mineral component to the ceramic porous body.
若依據本發明的製造方法,能夠製造前述本發明的陶瓷多孔質體。特別是製程(II)所獲得的陶瓷多孔質體(礦物質成分固定化前)具有多數細孔,可將來自於礦物質機能水的礦物質成分保持在細孔內部,因此,能夠提高本發明的陶瓷多孔質體之成為目的的礦物質成分之含有量。 According to the production method of the present invention, the ceramic porous body of the present invention described above can be produced. In particular, the ceramic porous body obtained before the process (II) (before the mineral component is immobilized) has a large number of pores, and the mineral component derived from the mineral functional water can be held inside the pores, thereby improving the present invention. The ceramic porous material is the content of the mineral component of interest.
以下,說明關於本發明的陶瓷多孔質體之製造方法的各製程。 Hereinafter, each process of the method for producing a ceramic porous body of the present invention will be described.
製程(I)為將混合用液體(混合用分散介質)與載體用陶瓷粉末混合作成為黏土狀混合物的製程。 The process (I) is a process in which a mixing liquid (mixing dispersion medium) and a carrier ceramic powder are mixed to form a clay-like mixture.
載體用陶瓷粉末的原料之氧化物,為與作為前述陶瓷載體進行說明過的氧化物相同,具有適度的燒結性之氧化 物即可,未特別限定。 The oxide of the raw material of the ceramic powder for carrier is the same as the oxide described as the ceramic carrier, and has an appropriate sinter oxidation. The material is not particularly limited.
作為成為這種原料之氧化物,可舉出例如二氧化矽、氧化鈦、氧化鋁或這些的複合氧化物等。又,亦可理想地使用矽藻土(主成分:二氧化矽)、白陶土(主成分:二氧化矽-氧化鋁)、水滑石等的陶土類。亦可將含有這樣的陶土類之岩石予以粉碎後作為陶瓷載體的原料。例如,在後述的實施例使用的天草大矢野島出產的岩石粉末為陶瓷載體原料之一理想例。 Examples of the oxide to be used as such a raw material include cerium oxide, titanium oxide, aluminum oxide, and a composite oxide thereof. Further, clays such as diatomaceous earth (main component: cerium oxide), kaolin (main component: cerium oxide-alumina), and hydrotalcite may be preferably used. Rocks containing such clays can also be pulverized and used as a raw material for ceramic carriers. For example, the rock powder produced by the Amakusa Oyao Island used in the examples described later is an ideal example of a ceramic carrier raw material.
載體用陶瓷粉末是陶土粉末為佳。粉末的粒徑,在成形性、燒結性等良好的範圍下進行選擇,一般為100μm以下。 The ceramic powder for the carrier is preferably a ceramic powder. The particle diameter of the powder is selected in a favorable range such as moldability and sinterability, and is generally 100 μm or less.
混合用液體為當拌合載體用陶瓷粉末時所添加的液體,能夠使用任意的液體,但一般使用水、或以水為主體的液體為佳。[以水為主體之液體]係指含有50重量%以上(包含100重量%)的水之液體,作為水以外的成分,包含乙醇等具有與水的相溶性之有機溶劑。又,在混合用液體,在不損本發明效果的範圍下,亦可包含pH調整劑等的任意成分。 The liquid to be mixed is a liquid to be added when the ceramic powder for a carrier is mixed, and any liquid can be used. However, water or a liquid mainly composed of water is generally used. [Liquid-based liquid] A liquid containing 50% by weight or more (including 100% by weight) of water, and a component other than water, and an organic solvent having compatibility with water such as ethanol. Further, the mixing liquid may contain an optional component such as a pH adjuster in a range that does not impair the effects of the present invention.
載體用陶瓷粉末與混合用液體之混合方法,可採用任意方法,能以人力進行拌合,亦可使用習知的拌合裝置進行拌合。 The mixing method of the ceramic powder for the carrier and the liquid for mixing may be carried out by any method, and may be carried out by hand, or may be carried out by using a conventional mixing device.
又,載體用陶瓷粉末與混合用液體之混合比例,是在成為可保持成形性的黏度之範圍下進行設定,對載體用陶瓷粉末100重量部,混合用液體一般為5重量部以上500 重量部以下,理想為10重量部以上300重量部以下。 In addition, the mixing ratio of the ceramic powder for carrier and the liquid for mixing is set within a range in which the viscosity can be maintained, and the weight of the ceramic powder for the carrier is 100 parts by weight, and the liquid for mixing is generally 5 parts by weight or more and 500. The weight portion or less is preferably 10 parts by weight or more and 300 parts by weight or less.
再者,在黏土狀混合物,除了載體用陶瓷粉末與混合用液體以外,在不損本發明效果的範圍下,亦可含有使用於陶瓷製造之習知的增黏劑、氣孔生成劑、pH調整劑等的任意成分。 Further, in the clay-like mixture, in addition to the carrier ceramic powder and the mixing liquid, it may contain a conventional tackifier, a pore generating agent, and a pH adjustment for use in ceramics, without damaging the effects of the present invention. Any component such as a agent.
製程(II)為將所獲得的黏土狀混合物因應需要成形為預定形狀後再進行熱處理,獲得具有多數細孔的陶瓷多孔質體之製程。 The process (II) is a process in which the obtained clay-like mixture is formed into a predetermined shape as needed, and then heat-treated to obtain a ceramic porous body having a plurality of pores.
黏土狀混合物的成形,由於具有黏性,故容易進行,可因應使用用途,控制適宜形狀。在成形為粒子狀之情況,能夠調整成例如50~500μm左右。又,亦可使黏土狀塊的狀態下進行乾燥後再予以粉碎而調整粒徑後再進行熱處理。如此,因可將載體用陶瓷粉末作成為成形任意形狀的黏土狀混合物後再成形並進行熱處理,所以,能夠容易獲得成為目的形狀之陶瓷多孔質體。 Since the formation of the clay-like mixture is viscous, it is easy to carry out, and the appropriate shape can be controlled depending on the intended use. When it is formed into a particulate form, it can adjust to about 50-500 micrometers, for example. Further, the clay-like mass may be dried, and then pulverized to adjust the particle diameter, followed by heat treatment. In this manner, since the ceramic powder for the carrier can be formed into a clay-like mixture of an arbitrary shape and then formed into a heat treatment, the ceramic porous body having the desired shape can be easily obtained.
熱處理可藉由習知的燒成裝置進行。熱處理溫度,為了所獲得之陶瓷多孔質體具有充分的細孔、且具有在後製程能使用之機械性強度程度之燒結度,考量載體用陶瓷粉末的種類等加以決定,通常為500℃以上1000℃以下,理想為700℃以上900℃以下。又,熱處理時的環境未特別限定,但一般為大氣環境。熱處理時間可因應熱處理溫度及目的之氣孔率、燒結度等加以適宜決定。 The heat treatment can be carried out by a conventional firing device. The heat treatment temperature is determined so that the obtained ceramic porous body has sufficient pores and has a degree of mechanical strength which can be used in a post-process, and is determined by the type of the ceramic powder for the carrier, and is usually 500 ° C or more. Below °C, it is preferably 700 ° C or more and 900 ° C or less. Further, the environment at the time of heat treatment is not particularly limited, but is generally an atmospheric environment. The heat treatment time can be appropriately determined depending on the heat treatment temperature, the porosity of the object, the degree of sintering, and the like.
製程(III)為使含有礦物質成分之礦物質機能水浸透於前述陶瓷多孔質體所具有的細孔後再進行乾燥, 將礦物質成分固定化於該陶瓷多孔質體之製程。藉由此製程,使得礦物質成分可溶析地被保持於陶瓷多孔質體。 Process (III) is to dry the mineral water containing the mineral component in the pores of the ceramic porous body, and then dry it. The process of immobilizing a mineral component on the ceramic porous body. By this process, the mineral component is retained in the ceramic porous body in a soluble manner.
由於陶瓷多孔質體具有多數細孔,故,藉由使該細孔含有礦物質機能水後再進行乾燥,可更多量地含有礦物質機能水中所含的礦物質成分。 Since the ceramic porous body has a large number of pores, the fine pores contain the mineral functional water and then dried, and the mineral components contained in the mineral functional water can be contained in a larger amount.
再者,關於含有礦物質成分的礦物質機能水,與其製造方法一併如後進行說明。 Further, the mineral functional water containing the mineral component will be described later together with the production method thereof.
使礦物質機能水浸透於陶瓷多孔質體所具有之細孔的方法為任意,可舉出例如,將陶瓷多孔質體浸漬於礦物質機能水之方法,但不限於此。又,亦可藉由反復進行使礦物質機能水浸透於陶瓷多孔質體,在溶劑(水)蒸發後再次使礦物質機能水浸透之作業,能夠使更多的礦物質成分固定化。 The method of allowing the mineral water to permeate the pores of the ceramic porous body is arbitrary, and for example, a method of immersing the ceramic porous body in the mineral functional water is not limited thereto. Further, by repeating the operation of allowing the mineral functional water to permeate the ceramic porous body and allowing the mineral water to permeate again after the solvent (water) evaporates, more mineral components can be immobilized.
浸透於陶瓷多孔質體的礦物質機能水之量是考量礦物質機能水所含的礦物質成分之種類、濃度等決定,取決於陶瓷多孔質體的細孔物性、氣孔率等,但一般為陶瓷多孔質體重量的15重量%以上。 The amount of mineral functional water impregnated in the porous ceramic body is determined by considering the type and concentration of the mineral component contained in the mineral functional water, depending on the pore physical properties and porosity of the ceramic porous body, but generally The weight of the ceramic porous body is 15% by weight or more.
使本發明的陶瓷材料之第2態樣的本發明的陶瓷多孔質體與以水為主體之萃取溶劑接觸,能讓該本發明的陶瓷多孔質體所含有的前述礦物質成分溶析於前述萃取溶劑中。在此,[以水為主體之萃取溶劑]係如前述(1)水泥硬化體所說明,因此,在此省略其說明。 When the ceramic porous body of the present invention of the second aspect of the ceramic material of the present invention is brought into contact with an extraction solvent mainly composed of water, the mineral component contained in the ceramic porous body of the present invention can be eluted into the foregoing. Extract solvent. Here, [the extraction solvent mainly composed of water] is as described in the above (1) cement hardened body, and thus the description thereof is omitted here.
在與本發明的陶瓷多孔質體接觸後之萃取液(溶析機能水),含有保持於陶瓷多孔質體的礦物質成分之 一部分或全部。 The extract liquid (solubilization function water) after contact with the ceramic porous body of the present invention contains a mineral component held in the ceramic porous body Part or all.
使用後(萃取出礦物質成分後)的本發明的陶瓷多孔質體,可藉由再次進行製程(III)進行再生。 The ceramic porous body of the present invention after use (after extracting the mineral component) can be regenerated by performing the process (III) again.
<2-2.非溶析型陶瓷材料(陶瓷燒結體)> <2-2. Non-lead type ceramic material (ceramic sintered body)>
本發明的陶瓷燒結體係指以礦物質成分非溶析地被固定化於成為基材的陶瓷燒結體之狀態下所含的非溶析型陶瓷材料。 The ceramic sintering system of the present invention refers to a non-lead-type ceramic material contained in a state in which a mineral component is immobilized on a ceramic sintered body serving as a substrate without being eluted.
在此,[(礦物質成分)非溶析地被固定化之狀態]係指當使成為對象的陶瓷燒結體與水接觸時,礦物質成分實質上不會溶析而殘存於陶瓷燒結體的態樣。 Here, [the state in which the (mineral component) is immobilized in a non-sedimented state] means that when the intended ceramic sintered body is brought into contact with water, the mineral component does not substantially elute and remains in the ceramic sintered body. Aspect.
亦即,本發明的陶瓷燒結體為與礦物質成分可溶析地被固定化之礦物質成分溶析性的陶瓷材料明確不同之態樣。在此,[礦物質成分可溶析地被固定化]係指使作為對象的陶瓷材料與萃取溶劑(一般為以水為主體的溶劑)接觸時,礦物質成分逐漸溶析,最終變得不會殘存於陶瓷材料之狀態(除了不可避免殘餘成分外)。 That is, the ceramic sintered body of the present invention is clearly different from the mineral material-soluble ceramic material in which the mineral component is dissolved and fixed. Here, [the mineral component is immobilized by elution] means that when the target ceramic material is brought into contact with an extraction solvent (generally a solvent mainly composed of water), the mineral component is gradually dissolved and eventually becomes not formed. Remains in the state of ceramic materials (except for unavoidable residual components).
本發明的陶瓷燒結體之電磁波放射作用,是藉由以下的方法測定[放射率]及[分光放射率],將含有作為測定對象之礦物質成分的陶瓷燒結體和不含有礦物質成分的陶瓷燒結體(毛坯)的分光放射率譜進行對比來進行的。 The electromagnetic wave radiation of the ceramic sintered body of the present invention is a ceramic sintered body containing a mineral component to be measured and a ceramic containing no mineral component by measuring [emissibility] and [spectral emissivity] by the following method. The spectroscopic spectroscopy spectrum of the sintered body (blank) was compared.
在此,[放射率]係指放射體的放射發散度和與該放射體同溫度的黑體的放射發散度之比(JIS Z 8117),[分光放 射率]係顯示當將該溫度之黑體的放射率設為100%時之試料的放射比率者。再者,進行評價的試料為具有特定的分光放射率譜。分光放射率譜的測定方法係被JIS R 180所規定,能夠藉由使用具有依據JIS R 180之裝置結構的傅立葉變換型紅外線分光光度測定法(FTIR)之放射率測定系統來進行測定。作為放射率測定系統的理想之一例,可舉出日本電子(股)製的遠紅外線輻射率測定裝置(JIR-E500)。關於本發明的陶瓷燒結體之分光放射率譜的測定方法之具體例、電磁波放射作用的評價等,以實施例如後說明。 Here, the [radiation rate] refers to the ratio of the radiation divergence of the radiator to the radiation divergence of the black body at the same temperature as the radiation (JIS Z 8117). The radiance] indicates the ratio of the radiation of the sample when the emissivity of the black body at this temperature is 100%. Furthermore, the sample to be evaluated has a specific spectroradiance spectrum. The measurement method of the spectroradiance spectrum is defined by JIS R 180, and can be measured by using an emissivity measuring system having Fourier transform type infrared spectrophotometry (FTIR) according to the device configuration of JIS R 180. An ideal example of the emissivity measuring system is a far-infrared radiance measuring device (JIR-E500) manufactured by JEOL Ltd. Specific examples of the method for measuring the spectroradiance spectrum of the ceramic sintered body of the present invention, evaluation of electromagnetic wave radiation, and the like will be described later.
固定化於本發明的陶瓷燒結體的礦物質成分,係為來自於礦物質機能水之礦物質成分為佳。再者,關於該礦物質機能水,與其製造方法一併如後進行說明。 The mineral component immobilized in the ceramic sintered body of the present invention is preferably a mineral component derived from mineral functional water. Further, the mineral functional water will be described later in conjunction with the production method thereof.
本發明的陶瓷燒結體之礦物質成分係含於作為載體之陶瓷燒結體(陶瓷載體),非溶析地被固定。成為陶瓷燒結體的原料之氧化物的種類,若為具有燒結性、且不會有損來藉由來自於礦物質機能水的礦物質成分之電磁波放射之氧化物即可,未特別限定。作為成為這種原料之氧化物,可舉出例如二氧化矽、氧化鈦、氧化鋁或這些的複合氧化物等。又,亦可理想地使用矽藻土(主成分:二氧化矽)、白陶土(主成分:二氧化矽-氧化鋁)、水滑石等的陶土類。亦可將含有這樣的陶土類之岩石予以粉碎後作為陶瓷載體的原料。例如,在後述的實施例使用的天草大矢野島出產的岩石粉末為陶瓷載體原料之一理想例。 The mineral component of the ceramic sintered body of the present invention is contained in a ceramic sintered body (ceramic carrier) as a carrier, and is fixed without being eluted. The type of the oxide which is a raw material of the ceramic sintered body is not particularly limited as long as it is sinterable and does not impair the electromagnetic radiation emitted by the mineral component derived from the mineral functional water. Examples of the oxide to be used as such a raw material include cerium oxide, titanium oxide, aluminum oxide, and a composite oxide thereof. Further, clays such as diatomaceous earth (main component: cerium oxide), kaolin (main component: cerium oxide-alumina), and hydrotalcite may be preferably used. Rocks containing such clays can also be pulverized and used as a raw material for ceramic carriers. For example, the rock powder produced by the Amakusa Oyao Island used in the examples described later is an ideal example of a ceramic carrier raw material.
在本發明的陶瓷燒結體,亦可含有能夠使用於氧化物陶瓷燒結體之習知成分。作為任意的成分,若為不會有損本發明的目的之添加物則未特別限制。 The ceramic sintered body of the present invention may contain a conventional component which can be used for an oxide ceramic sintered body. The optional component is not particularly limited as long as it does not impair the object of the present invention.
本發明的陶瓷燒結體亦可具備將其全表面或一部分表面被覆的釉藥層。藉由具有釉藥層,可進一步抑制固定化於陶瓷燒結體的礦物質成分之溶析。 The ceramic sintered body of the present invention may have a glaze layer covering the entire surface or a part of its surface. By having the glaze layer, the elution of the mineral component immobilized on the ceramic sintered body can be further suppressed.
構成釉藥層的釉藥之種類,未特別限制,可舉出例如矽灰石釉、石灰釉、鋅釉、灰釉等。 The type of the glaze constituting the glaze layer is not particularly limited, and examples thereof include a lime glaze, a lime glaze, a zinc glaze, and a gray glaze.
釉藥層的厚度也未特別限制,一般設計成膜厚0.1~3mm左右。 The thickness of the glaze layer is also not particularly limited, and is generally designed to have a film thickness of about 0.1 to 3 mm.
再者,當將釉藥層增厚時會造成電磁波強度減弱,故藉由抑制要形成的釉藥層之厚度,能夠控制本發明的陶瓷燒結體所發出之電磁波的強度。另外,即使在形成有釉藥層之情況,為了進一步提高電磁波照射,亦使釉藥層含有來自於礦物質機能水的礦物質成分為佳。該礦物質成分,係為來自於本發明的礦物質機能水之礦物質成分為佳。釉藥層的礦物質成分,可為與內部的陶瓷燒結體相同的礦物質成分,亦可為不同的礦物質成分。 Further, when the glaze layer is thickened, the electromagnetic wave intensity is weakened, so that the intensity of the electromagnetic wave emitted by the ceramic sintered body of the present invention can be controlled by suppressing the thickness of the glaze layer to be formed. Further, even in the case where the glaze layer is formed, in order to further increase the electromagnetic wave irradiation, it is preferable that the glaze layer contains a mineral component derived from the mineral functional water. The mineral component is preferably a mineral component derived from the mineral functional water of the present invention. The mineral component of the glaze layer may be the same mineral component as the internal ceramic sintered body, or may be a different mineral component.
本發明的陶瓷燒結體之形狀未特別限制,可因應用途成形為理想形狀來使用,可舉出例如粉末狀、粒狀、板狀等。尺寸也為任意,可依據使用目的加以適宜決定。亦可將成形體、或未成形的塊狀物進行粉碎,作為粉體、粒狀體等使用。 The shape of the ceramic sintered body of the present invention is not particularly limited, and it can be used in an ideal shape for application, and examples thereof include a powder, a pellet, and a plate. The size is also arbitrary and can be appropriately determined depending on the purpose of use. The molded body or the unformed mass may be pulverized and used as a powder, a granule or the like.
<3.礦物質機能水及其製造> <3. Mineral functional water and its manufacture>
<3-1.礦物質機能水> <3-1. Mineral function water>
在前述溶析型陶瓷材料(本發明的陶瓷材料)及非溶析型陶瓷材料(本發明的陶瓷燒結體),分別固定化有來自於礦物質機能水之礦物質成分。再者,來自於[礦物質機能水之礦物質成分]係指從作為對象的礦物質機能水除去溶劑成分後殘存的礦物質成分。但,如以上所述,來自於植物之礦物質成分,不僅含有無機成分,亦含有來自於植物的有機成分。 In the above-described eluted ceramic material (ceramic material of the present invention) and non-lead-type ceramic material (ceramic sintered body of the present invention), mineral components derived from mineral functional water are respectively fixed. In addition, the mineral component derived from [mineral functional water] refers to a mineral component remaining after the solvent component is removed from the target mineral water. However, as described above, the mineral component derived from a plant contains not only an inorganic component but also an organic component derived from a plant.
個別固定化於溶析型陶瓷材料及非溶析型陶瓷材料的礦物質成分,一般為來自於礦物質機能水之礦物質成分,但,亦可為來自於不同的礦物質機能水之礦物質成分。 The mineral components immobilized on the eluted ceramic material and the non-leaved ceramic material are generally mineral components derived from mineral functional water, but may also be minerals derived from different mineral functional waters. ingredient.
固定化於本發明的溶析型陶瓷材料(本發明的陶瓷材料)及/或非溶析型陶瓷材料(本發明的陶瓷燒結體)的礦物質成分,係來自於以形成為1:5~1:20(重量比)之比例含有藉由以下的製程(1)所形成的含礦物質水(A)、和藉由以下的製程(2)所形成的含礦物質水(B)的礦物質機能水之礦物質成分為佳。 The mineral component immobilized on the eluted ceramic material (ceramic material of the present invention) and/or the non-leaved ceramic material (ceramic sintered body of the present invention) of the present invention is derived from the formation of 1:5~ The ratio of 1:20 (weight ratio) contains mineral-containing water (A) formed by the following process (1), and ore-containing water (B) formed by the following process (2) The mineral component of the material function water is preferred.
製程(1): Process (1):
將以絕緣體被覆的導電線、和含有菊科的草木植物及薔薇科的草木植物所構成的草木植物原料以及由從楓樹、白樺樹、松樹及杉樹選擇的1種以上之木本植物所構成的 木本植物原料的礦物質賦予材(A)浸漬於水中,使直流電流導通於前述導電線,讓在前述導電線周圍的水產生與前述直流電流相同方向的水流,對前述水賦予超音波振動,形成原料礦物質水溶液(A),接著,對原料礦物質水溶液(A)照射遠紅外線(波長6~14μm),形成含礦物質水(A)之製程,其中,礦物質賦予材(A)對水之添加量為10~15重量%,導通於前述導電線的直流電流之電流值及電壓值分別為0.05~0.1A及8000~8600V之範圍; a conductive material covered with an insulator, a plant material composed of a plant of the family Asteraceae, and a plant of the family Rosaceae, and one or more woody plants selected from maple, birch, pine, and cedar. Constituent The mineral-imparting material (A) of the woody plant material is immersed in water to conduct a direct current to the conductive wire, and the water around the conductive wire generates a water flow in the same direction as the direct current, thereby imparting ultrasonic vibration to the water. Forming a raw material mineral aqueous solution (A), and then irradiating the raw material mineral aqueous solution (A) with far infrared rays (wavelength 6 to 14 μm) to form a mineral-containing water (A) process, wherein the mineral imparting material (A) The amount of water added is 10 to 15% by weight, and the current value and voltage value of the direct current that is conducted to the conductive wire are in the range of 0.05 to 0.1 A and 8000 to 8600 V, respectively;
製程(2): Process (2):
使水通過6個通水容器來製造含礦物質水(B)的含礦物質水(B)形成製程,其中該6個通水容器為填充有種類相互不同的無機系礦物質賦予材(B)且以串聯方式連接的第1通水容器至第6通水容器:第1通水容器內的礦物質賦予材(B1)為分別含有70重量%的石灰石、15重量%的珊瑚化石、15重量%的貝殼之混合物;第2通水容器內的礦物質賦予材(B2)為分別含有40重量%的石灰石、15重量%的珊瑚化石、40重量%的貝殼、5重量%的活性碳之混合物;第3通水容器內的礦物質賦予材(B3)為分別含有80重量%的石灰石、15重量%的珊瑚化石、5重量%的貝殼之混合物;第4通水容器內的礦物質賦予材(B4)為分別含有90 重量%的石灰石、5重量%的珊瑚化石、5重量%的貝殼之混合物;第5通水容器內的礦物質賦予材(B5)為分別含有80重量%的石灰石、10重量%的珊瑚化石、10重量%的貝殼之混合物;第6通水容器內的礦物質賦予材(B6)為分別含有60重量%的石灰石、30重量%的珊瑚化石、10重量%的貝殼之混合物。 A process for forming mineral-containing water (B) containing mineral water (B) by passing water through six water-passing containers, wherein the six water-passing containers are filled with inorganic mineral-affecting materials different in type (B) The first water-passing container to the sixth water-passing container connected in series: the mineral-importing material (B1) in the first water-passing container is 70% by weight of limestone and 15% by weight of coral fossil, respectively. a mixture of shells of % by weight; the mineral-imparting material (B2) in the second water-passing container contains 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon. The mixture; the mineral-importing material (B3) in the third water-passing container is a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells; and the mineral in the fourth water-passing container is given Material (B4) contains 90 respectively a mixture of % by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells; and the mineral-imparting material (B5) in the fifth water-passing container contains 80% by weight of limestone and 10% by weight of coral fossils, respectively. A mixture of shells of 10% by weight; the mineral-imparting material (B6) in the sixth water-passing container is a mixture containing 60% by weight of limestone, 30% by weight of coral fossils, and 10% by weight of shells, respectively.
以上,舉例說明了成為以前述礦物質機能水的製造方法所製造之礦物質成分的原料之理想的礦物質機能水,但不限於此。製造方法的詳細內容如<3-2.礦物質機能水的製造方法>進行說明。 In the above, an ideal mineral water which is a raw material of a mineral component produced by the above-described method for producing mineral water can be exemplified, but is not limited thereto. The details of the production method will be described as <3-2. Method for producing mineral functional water>.
作為使用於溶析型陶瓷材料(本發明的陶瓷材料)及非溶析型陶瓷材料(本發明的陶瓷燒結體)之製造的理想礦物質機能水,可舉出本發明者們所開發之礦物質機能水(有稱為[本發明的礦物質機能水]之情況)。本發明的礦物質機能水具有例如對單細胞生物、病毒等優良之防治作用(WO2016/043213)、身體活化作用(WO2016/043214)、碳氫化合物類的燃燒促進作用(PCT/JP2016/058141)、抗氧化作用(PCT/JP2016/058362)等之有益效能。 Examples of the ideal mineral functional water used for the production of the eluted ceramic material (the ceramic material of the present invention) and the non-lead-type ceramic material (the ceramic sintered body of the present invention) include the mine developed by the inventors. Material function water (in the case of [mineral functional water of the present invention]). The mineral functional water of the present invention has excellent control effects (WO2016/043213), body activation (WO2016/043214), and combustion promotion of hydrocarbons (PCT/JP2016/058141), for example, for single-celled organisms, viruses, and the like. , beneficial effects of antioxidant effects (PCT/JP2016/058362).
再者,作為本發明的礦物質機能水之共通特徵,可舉出含有來自於植物之礦物質成分(特別是來自於植物的有機成分)。 Further, as a common feature of the mineral functional water of the present invention, a mineral component derived from a plant (particularly, an organic component derived from a plant) may be mentioned.
理想的礦物質機能水中的一個為如專利文獻3 (WO2016/043213)所記載之對細胞生物、病毒等具有優良的防治作用之礦物質機能水(在本說明書中有稱為[礦物質機能水(1)]的情況)。關於該礦物質機能水之製造方法的內容如後述。 One of the ideal mineral functional waters is as in Patent Document 3 The mineral functional water (in the present specification, referred to as [mineral functional water (1)) in the present invention, which has an excellent control effect on cell organisms, viruses, and the like, as described in WO 2016/043213. The content of the method for producing the mineral functional water will be described later.
再者,礦物質機能水(1)符合以下的(i)至(iv)所有的要件:(i)將該礦物質機能水15重量部以上對陶瓷載體100重量部予以固定化的試料之在波長5~7μm間及波長14~24μm間對黑體的平均放射比率(測定溫度:25℃)為90%以上;(ii)該礦物質機能水為pH12以上;(iii)具有對單細胞生物及病毒中的至少一方之防治作用;(iv)包含來自於植物之礦物質成分(特別是來自於植物的有機成分)。 Further, the mineral functional water (1) meets all of the following requirements (i) to (iv): (i) a sample in which the weight of the mineral water is 15 parts or more and the weight of the ceramic carrier 100 is fixed. The average emission ratio (measuring temperature: 25 ° C) of the black body between the wavelengths of 5 to 7 μm and the wavelength of 14 to 24 μm is 90% or more; (ii) the functional water of the mineral is pH 12 or higher; (iii) having a single cell organism and The prevention and control of at least one of the viruses; (iv) the inclusion of mineral components derived from plants (especially organic components derived from plants).
使含有來自於礦物質機能水(1)的礦物質成分之本發明的陶瓷材料與以水為主體之萃取溶劑接觸而溶析所獲得之溶析機能水(以下有稱為[溶析機能水(1)]的情況),作為其有用的效能之一,具有成為人及/或動物的感染性疾病的原因之單細胞生物、病毒等的防治作用。再者,[具有防治作用],不僅包含作為對象的單細胞生物、病毒等完全地滅絕,亦包含單細胞生物、病毒等減少而可抑制增生者。因此,藉由將該溶析機能水使用於防治對象的單細胞生物及/或病毒,能夠進行防治對象的單細胞生 物及/或病毒之防治。 The dissolving functional water obtained by contacting the ceramic material of the present invention containing the mineral component derived from the mineral functional water (1) with the extraction solvent mainly composed of water (hereinafter referred to as [solution water] (1) In the case of one of its useful efficacies, it has a control action of single-celled organisms, viruses, and the like which are causes of infectious diseases of humans and/or animals. Furthermore, [having a preventive effect] includes not only the single-celled organism, the virus, and the like as a target, but also a single-celled organism, a virus, and the like, which can suppress hyperplasia. Therefore, by using the lysing machine water for the single-celled organism and/or virus to be controlled, it is possible to perform single-cell growth of the subject. Prevention of substances and / or viruses.
再者,溶析機能水(1),當與礦物質機能水(1)進行比較時,由於對單細胞生物及/或病毒的防治作用之持續性較低,故,對人、家畜等直接進行塗佈、噴霧等來賦予並使用為佳。 Furthermore, the dissolution of the functional water (1), when compared with the mineral functional water (1), is relatively low in the prevention and control of single-celled organisms and/or viruses, so that it is directly It is preferred to apply and apply it by application, spraying, or the like.
在本說明書中,[單細胞生物]為包含細菌、真菌、原蟲等的概念。成為藉由溶析機能水(1)進行防治的對象之單細胞生物,若為可藉由因溶析機能水(1)的含有成分所產生之作用,使其失活(滅絕)之細菌、真菌、原蟲等之單細胞病源菌則未特別限定。又,成為防治對象之病毒,若為可藉由因溶析機能水(1)的含有成分所產生之作用,使其失活(滅絕)之病毒則未特別限定。 In the present specification, [single cell organism] is a concept including bacteria, fungi, protozoa, and the like. The single-celled organism to be controlled by the elution functional water (1) is a bacteria that can be inactivated (extinct) by the action of the components contained in the water (1) of the elution function. The single-cell pathogenic bacteria such as fungi and protozoa are not particularly limited. Further, the virus to be controlled is not particularly limited as long as it can be inactivated (extinct) by the action of the component contained in the water (1) of the elution function.
理想的礦物質機能水中的一個為如專利文獻4(WO2016/043214)所記載之具有促進血液循環作用等之身體活化作用之礦物質機能水(以下有稱為[礦物質機能水(2)]的情況)。關於該礦物質機能水之製造方法的內容如後述。在使含有來自於此礦物質機能水的礦物質成分之本發明的陶瓷材料與萃取溶劑接觸所獲得之溶析機能水(溶析機能水(2)),含有與礦物質機能水(2)同樣的礦物質成分,有助於促進血液循環作用等的身體活化作用。 One of the ideal mineral functional waters is mineral functional water (hereinafter referred to as [mineral functional water (2)] having a body activation action such as that promotes blood circulation as described in Patent Document 4 (WO2016/043214). Case). The content of the method for producing the mineral functional water will be described later. The dissolving functional water (solvent water (2)) obtained by contacting the ceramic material of the present invention containing the mineral component derived from the functional water of the mineral with the extraction solvent, and the mineral functional water (2) The same mineral ingredients help to promote body activation such as blood circulation.
理想的礦物質機能水中的一個為如專利文獻5(WO2016/043214)所記載之具有碳氫化合物類的燃燒促進作用之礦物質機能水(以下有稱為[礦物質機能水(3)]的情況)。關於該礦物質機能水之製造方法的內容如後述。 One of the ideal mineral functional waters is a mineral functional water having a combustion-promoting action of a hydrocarbon type as described in Patent Document 5 (WO2016/043214) (hereinafter referred to as [mineral functional water (3)]. Happening). The content of the method for producing the mineral functional water will be described later.
在使含有來自於此礦物質機能水的礦物質成分之本發明的陶瓷材料與萃取溶劑接觸所獲得之溶析機能水(溶析機能水(3)),含有與礦物質機能水(3)同樣的礦物質成分。 The dissolving functional water (solvent water (3)) obtained by contacting the ceramic material of the present invention containing the mineral component derived from the functional water of the mineral with the extracting solvent, and the mineral functional water (3) The same mineral composition.
理想的礦物質機能水中的一個為如專利文獻6(WO2016/058362)所記載之具有抗氧化作用之礦物質機能水(以下有稱為[礦物質機能水(4)]的情況)。關於該礦物質機能水之製造方法的內容如後述。 One of the ideal mineral functional waters is a mineral functional water (hereinafter referred to as [mineral functional water (4)) having an antioxidant action as described in Patent Document 6 (WO2016/058362). The content of the method for producing the mineral functional water will be described later.
在使含有來自於此礦物質機能水的礦物質成分之本發明的陶瓷材料與萃取溶劑接觸所獲得之溶析機能水(溶析機能水(4)),含有與礦物質機能水(4)同樣的礦物質成分。 The dissolving functional water (solvent water (4)) obtained by contacting the ceramic material of the present invention containing the mineral component derived from the functional water of the mineral water with the extracting solvent, and the mineral functional water (4) The same mineral composition.
<3-2.礦物質機能水的製造方法> <3-2. Method for producing mineral functional water>
含有使用於前述本發明的陶瓷材料(溶析型陶瓷材料)、本發明的陶瓷燒結體(非溶析型陶瓷材料)之製造的礦物質成分之礦物質機能水(以下會有稱為[本發明的礦物質機能水]之情況),其製造方法未特別限定,但,理想能夠使用在前述專利文獻2(日本特開2011-56366號公報)所揭示的裝置,再藉由依據該文獻所揭示的方法之方法加以製造。 Mineral functional water containing a mineral component used in the production of the ceramic material (solubilized ceramic material) of the present invention and the ceramic sintered body (non-lead-type ceramic material) of the present invention (hereinafter referred to as [this] In the case of the mineral functional water of the invention, the production method is not particularly limited, and it is preferable to use the apparatus disclosed in the above-mentioned Patent Document 2 (JP-A-2011-56366), and The method of the disclosed method is manufactured.
再者,除了使用此製造裝置之製造方法以外,若能夠獲得含有有益的礦物質成分之礦物質機能水的話,則製造方法未特別限定。 In addition, the production method is not particularly limited as long as the mineral functional water containing a beneficial mineral component can be obtained in addition to the production method using the production apparatus.
以下,參照圖面,說明關於使用專利文獻2(日本特開2011-56366號公報)所揭示的裝置,製造本發 明的礦物質機能水之製造方法的理想實施形態。再者,在以下的說明,其為舉例說明,藉由適宜變更以原料為首的製造條件,能夠製造出各種礦物質機能水。 In the following, the device disclosed in Patent Document 2 (JP-A-2011-56366) is used to manufacture the present invention. An ideal embodiment of a method for producing mineral water. In the following description, for example, various mineral functional waters can be produced by appropriately changing the manufacturing conditions including raw materials.
如圖7所示,礦物質機能水製造設備1具備有:含礦物質水(A)製造裝置2;含礦物質水(B)製造裝置3;及作為混合手段之混合槽46,該混合槽是將在含礦物質水(B)製造裝置3所製造的含礦物質水(B)45混合於在含礦物質水(A)製造裝置2所製造的含礦物質水(A)44,形成礦物質機能水47。 As shown in Fig. 7, the mineral water manufacturing facility 1 is provided with: a mineral water (A) manufacturing apparatus 2; a mineral water (B) manufacturing apparatus 3; and a mixing tank 46 as a mixing means, the mixing tank The mineral-containing water (B) 45 produced in the mineral-containing water (B) manufacturing apparatus 3 is mixed with the mineral-containing water (A) 44 produced in the mineral-containing water (A) manufacturing apparatus 2 to form Mineral function water 47.
含礦物質水(A)製造裝置2係將從自來水管所供給的水11與後述的礦物質賦予材(A)12(參照圖10)作為原料,形成原料礦物質水溶液(A)41之原料礦物質水溶液製造手段10;及對以原料礦物質水溶液製造手段10所獲得的原料礦物質水溶液(A)41照射遠紅外線,變化成含礦物質水(A)44的遠紅外線產生手段43。 In the mineral water (A) manufacturing apparatus 2, the water 11 supplied from the water pipe and the mineral material (A) 12 (see FIG. 10) to be described later are used as raw materials to form a raw material of the raw material mineral aqueous solution (A) 41. The mineral aqueous solution production means 10; and the far-infrared rays generating means 43 which irradiates the far-infrared rays with the raw material mineral aqueous solution (A) 41 obtained by the raw material mineral aqueous solution manufacturing means 10, and changes to the mineral-containing water (A) 44.
含礦物質水(B)製造裝置3係具有以下功能,亦即,藉由使自外部所供給的水W通過通水容器51~56,形成含有自礦物質賦予材溶析出礦物質成分的含礦物質水(B)45之功能。 The mineral water (B) manufacturing apparatus 3 has a function of forming a water containing a mineral component from a mineral-containing material by passing water W supplied from the outside through the water-passing containers 51 to 56. Mineral water (B) 45 function.
以下,詳細地說明關於含礦物質水(A)製造裝置2及含礦物質水(B)製造裝置3。 Hereinafter, the mineral-containing water (A) manufacturing apparatus 2 and the mineral-containing water (B) manufacturing apparatus 3 will be described in detail.
(3-2-1:含礦物質水(A)製造裝置) (3-2-1: Mineral-containing water (A) manufacturing device)
其次,依據圖8至圖12,說明關於構成圖7所示的 礦物質機能水製造設備1之含礦物質水(A)製造裝置2。如圖7所示,含礦物質水(A)製造裝置2係將從自來水管所供給的水11與後述的礦物質賦予材(A)12(參照圖10)作為原料,形成原料礦物質水溶液(A)41之原料礦物質水溶液製造手段10(參照圖8);及對以原料礦物質水溶液製造手段10所獲得的含礦物質水(A)溶液41照射遠紅外線,變化成含礦物質水(A)44的遠紅外線產生手段43(參照圖12)。 Next, with reference to FIG. 8 to FIG. 12, the description will be made regarding the constitution shown in FIG. The mineral water (A) manufacturing apparatus 2 of the mineral water manufacturing equipment 1. As shown in Fig. 7, the mineral water (A) manufacturing apparatus 2 forms a raw material mineral aqueous solution by using the water 11 supplied from the water pipe and the mineral providing material (A) 12 (see Fig. 10) to be described later as a raw material. (A) 41 raw material mineral aqueous solution manufacturing means 10 (refer to FIG. 8); and the mineral-containing water (A) solution 41 obtained by the raw material mineral aqueous solution manufacturing means 10 is irradiated with far infrared rays, and is changed into mineral-containing water. The far infrared ray generating means 43 of (A) 44 (refer FIG. 12).
如圖8、圖9所示,原料礦物質水溶液製造手段10,具備有:可收容水11及礦物質賦予材(A)12之反應容器13;在以絕緣體14被覆的狀態下浸漬於反應容器13內的水11中之導電線15;用來對反應容器13內的水11賦予超音波振動之超音波產生手段16;使直流電流DC導通於導電線15之直流電源裝置17;在導電線15周圍的水11產生與直流電流DC相同方向的水流R的手段之循環路徑18a、18b及循環泵浦P。直流電源裝置17、超音波產生手段16及循環泵浦P均是藉由來自於一般的商用電源之供電來作動。 As shown in FIG. 8 and FIG. 9, the raw material mineral aqueous solution manufacturing means 10 is provided with the reaction container 13 which can accommodate the water 11 and the mineral-grant material (A) 12, and is immersed in the reaction container in the state covered with the insulator 14. a conductive line 15 in the water 11 in the 13; an ultrasonic generating means 16 for imparting ultrasonic vibration to the water 11 in the reaction vessel 13, a direct current power source means 17 for conducting a direct current DC to the conductive line 15, and a conductive line The water 11 around the 15 generates circulation paths 18a and 18b and a circulation pump P of the means of the water flow R in the same direction as the direct current DC. The DC power supply unit 17, the ultrasonic generating means 16 and the circulating pump P are all operated by power supply from a general commercial power source.
反應容器13為上面開口之倒立圓錐筒狀,在相當於其頂點的底部設有排水口19,在此排水口19連接有與循環泵浦P的吸入口P1連通之循環路徑18a,在排水口19的正下方設有用來調節朝循環路徑18a的排水量之開度調節閥20、和用來排出反應容器13內的水等之排水閥21。 The reaction container 13 has an inverted conical tubular shape with an upper opening, and a drain port 19 is provided at a bottom portion corresponding to the apex thereof, and a circulation path 18a communicating with the suction port P1 of the circulation pump P is connected to the drain port 19 at the drain port. Immediately below the 19, an opening degree adjusting valve 20 for adjusting the amount of displacement toward the circulation path 18a, and a drain valve 21 for discharging water or the like in the reaction vessel 13 are provided.
在循環泵浦P的吐出口P2連接有循環路徑18b的基端部,循環路徑18b的前端部連接於收容槽22。在收容槽22外周的底部附近,連接有用來將收容槽22內的水11輸送到反應容器13內的循環路徑18c的基端部,循環路徑18c的前端部配置於面臨反應容器13的開口部之位置。在循環路徑18c,設有用來調節從收容槽22輸送到反應容器13的水量之開度調節閥23。 A proximal end portion of the circulation path 18b is connected to the discharge port P2 of the circulation pump P, and a distal end portion of the circulation path 18b is connected to the accommodation groove 22. A proximal end portion for conveying the water 11 in the storage tub 22 to the circulation path 18c in the reaction container 13 is connected in the vicinity of the bottom of the outer periphery of the housing groove 22, and the distal end portion of the circulation path 18c is disposed in the opening facing the reaction container 13. The location. An opening degree regulating valve 23 for adjusting the amount of water sent from the storage tub 22 to the reaction container 13 is provided in the circulation path 18c.
在收容槽22的底部,具有排水閥25及水溫計26之排水管24呈垂下狀連接著。當因應需要打開排水閥25時,收容槽22的水可從排水管24的下端部排出,此時,能以水溫計26測量通過排水管24的水11之溫度。 At the bottom of the storage tub 22, a drain pipe 24 having a drain valve 25 and a water temperature gauge 26 is connected in a hanging manner. When the drain valve 25 is opened as needed, the water in the storage tub 22 can be discharged from the lower end portion of the drain pipe 24. At this time, the temperature of the water 11 passing through the drain pipe 24 can be measured by the water temperature gauge 26.
如圖11所示,由導電線15與被覆此導電線的絕緣體14所構成的複數個導電電纜29(29a~29g)以形成為圓環狀的方式分別配置於反應容器13內深度不同之複數個位置,這些圓環狀的導電電纜29a~29g均配置於與反應容器13略同軸上。各自的導電電纜29a~29g的內徑是配合倒立圓錐筒狀的反應容器13的內徑而階段性縮徑,形成為與各自的配置部位相對應的內徑。由於各導電電纜29a~29g是可裝卸地接線於設在反應容器13的壁體13a的絕緣性終端機30,故,可因應需要將圓環狀部分從終端機30取下或進行安裝。 As shown in FIG. 11, the plurality of conductive cables 29 (29a to 29g) composed of the conductive wire 15 and the insulator 14 covering the conductive wire are arranged in an annular shape so as to have different depths in the reaction container 13 At these positions, the annular conductive cables 29a to 29g are disposed slightly coaxially with the reaction container 13. The inner diameters of the respective conductive cables 29a to 29g are gradually reduced in diameter in accordance with the inner diameter of the reaction container 13 having an inverted cone shape, and are formed to have inner diameters corresponding to the respective arrangement portions. Since the respective conductive cables 29a to 29g are detachably connected to the insulating terminal device 30 provided in the wall body 13a of the reaction container 13, the annular portion can be removed or attached from the terminal device 30 as needed.
在反應容器13內相當於軸心的部分,配置有以絕緣性網狀體所形成的有底圓筒狀收納容器31,在此 收納容器31內填充有礦物質賦予材(A)12。此收納容器31係藉由設在其上部的鉤31f,可裝卸地卡止於反應容器13的壁體13a的上緣部。 A bottomed cylindrical storage container 31 formed of an insulating mesh body is disposed in a portion corresponding to the axial center of the reaction container 13 and is disposed therein. The storage container 31 is filled with a mineral imparting material (A) 12. The storage container 31 is detachably locked to the upper edge portion of the wall body 13a of the reaction container 13 by a hook 31f provided on the upper portion thereof.
如圖8所示,循環路徑18a、18b的外周,導電電纜29s、29t分別呈螺旋狀地被捲繞,對這些導電電纜29s、29t,從直流電源裝置17供給直流電流DC。在導電電纜29s、29t流動的直流電流DC之方向是設定成與在循環路徑18a、18b內流動的水流之方向大致一致。 As shown in Fig. 8, on the outer circumferences of the circulation paths 18a and 18b, the conductive cables 29s and 29t are spirally wound, and DC current DC is supplied from the DC power supply unit 17 to the conductive cables 29s and 29t. The direction of the direct current DC flowing through the conductive cables 29s and 29t is set to substantially coincide with the direction of the water flow flowing through the circulation paths 18a and 18b.
在原料礦物質水溶液製造手段10,將預定量的水11置入到反應容器13內及收容槽22內,將填充有礦物質賦予材(A)12的收納容器31安裝於反應容器13內的中心後,使循環泵浦P作動,並且調節反應容器13底部的開度調節閥20及循環路徑18c的開度調節閥23,從反應容器13使水11以經由排水口19、循環路徑18a、循環泵浦P、循環路徑18b、收容槽22及循環路徑18c再次返回到反應容器13的上部的方式進行循環。又,當使直流電源裝置17、超音波產生手段16作動時,礦物質成分從收納容器31內的礦物質賦予材(A)12朝水11的溶析反應開始進行。 In the raw material mineral aqueous solution production means 10, a predetermined amount of water 11 is placed in the reaction container 13 and in the storage tank 22, and the storage container 31 filled with the mineral-importing material (A) 12 is attached to the reaction container 13. After the center, the circulation pump P is actuated, and the opening degree adjustment valve 20 at the bottom of the reaction vessel 13 and the opening degree adjustment valve 23 of the circulation path 18c are adjusted, and the water 11 is passed from the reaction vessel 13 through the drain port 19, the circulation path 18a, The circulation pump P, the circulation path 18b, the storage tank 22, and the circulation path 18c are circulated again so as to return to the upper portion of the reaction container 13. When the DC power source device 17 and the ultrasonic wave generating means 16 are actuated, the mineral component starts from the elution reaction of the mineral material (A) 12 in the storage container 31 toward the water 11.
使用原料礦物質水溶液製造手段10製造原料礦物質水溶液(A)時的作業條件未特別限定,但在本實施形態,以以下的作業條件進行原料礦物質水溶液(A)的製造。 The working conditions in the case of producing the raw material mineral aqueous solution (A) using the raw material mineral aqueous solution production means 10 are not particularly limited. However, in the present embodiment, the raw material mineral aqueous solution (A) is produced under the following working conditions.
(1)使電壓8000~8600V、電流0.05~0.1A的直流電流 DC導通於導電電纜29、29s、29t。再者,構成導電電纜29等的絕緣體14是以聚四氟乙烯樹脂形成的。 (1) DC current with voltage of 8000~8600V and current of 0.05~0.1A The DC is conducted through the conductive cables 29, 29s, 29t. Further, the insulator 14 constituting the conductive cable 29 and the like is formed of a polytetrafluoroethylene resin.
(2)填充於反應容器13內的礦物質賦予材(A)12對水11以質量比10~15%進行填充。礦物質賦予材(A)12的具體說明如後述。 (2) The mineral-importing material (A) 12 filled in the reaction container 13 is filled with water 11 at a mass ratio of 10 to 15%. The specific description of the mineral-imparting material (A) 12 will be described later.
(3)水11為包含電解質可使直流電流DC作用者即可。例如,可使用對水100公升溶解10g左右的電解質之碳酸鈉者等,若為地下水的話則可直接使用。 (3) The water 11 may be a catalyst containing a DC current DC. For example, sodium carbonate which dissolves about 10 g of electrolyte for 100 liters of water can be used, and if it is groundwater, it can be used as it is.
(4)超音波產生手段16為頻率30~100kHz的超音波之手段,以其超音波振動部(未圖示)對反應容器13內的水11直接接觸而加振的方式配置該超音波產生手段16。 (4) The ultrasonic wave generating means 16 is a means for supersonic waves having a frequency of 30 to 100 kHz, and the ultrasonic wave generating portion (not shown) is placed in direct contact with the water 11 in the reaction container 13 to oscillate the ultrasonic wave. Means 16.
當在這樣的條件下使原料礦物質水溶液製造手段10運轉時,在反應容器13內,產生一邊朝左螺旋方向旋轉一邊被排水口19吸入之水流R,從排水口19排出之水11經由前述循環路徑18a、18b等再次返回到反應容器13內的狀態持續進行。 When the raw material mineral aqueous solution manufacturing apparatus 10 is operated under such conditions, the water flow R sucked by the drain port 19 while rotating in the left spiral direction is generated in the reaction container 13, and the water 11 discharged from the drain port 19 passes through the foregoing. The state in which the circulation paths 18a, 18b, and the like are returned to the reaction vessel 13 again continues.
因此,藉由水流R之攪拌作用、流動於導電電纜29的直流電流的作用及超音波產生手段16對水11所賦予的超音波振動,能夠使礦物質成分從礦物質賦予材(A)12迅速地溶出至水11中,可效率良好地製造所需的礦物質成分適度溶入之原料礦物質水溶液(A)。 Therefore, the action of the water flow R, the action of the direct current flowing through the conductive cable 29, and the ultrasonic vibration imparted by the ultrasonic wave generating means 16 to the water 11 can make the mineral component from the mineral material (A) 12 By rapidly dissolving into the water 11, the raw material mineral aqueous solution (A) in which the desired mineral component is moderately dissolved can be efficiently produced.
在原料礦物質水溶液製造手段10,將作成為圓環狀的複數個導電電纜29a~29g配置於反應容器13內大致相同軸上,並且在反應容器13內產生朝左螺旋方向 旋轉之水流R。因此,能夠在一定容積的反應容器13內形成較密狀態的電能場,可在較小容積的反應容器13內效率良好地製造原料礦物質水溶液(A)。 In the raw material mineral aqueous solution manufacturing apparatus 10, a plurality of conductive cables 29a to 29g which are formed in an annular shape are disposed on substantially the same axis in the reaction container 13, and a spiral direction toward the left is generated in the reaction container 13. Rotating water flow R. Therefore, a relatively dense electric field can be formed in the reaction container 13 having a constant volume, and the raw material mineral aqueous solution (A) can be efficiently produced in the reaction container 13 having a small volume.
又,由於反應容器13為倒立圓錐筒狀,故,較容易且穩定地產生沿著呈圓環狀的複數個導電電纜29a~29g流動的水流R,藉此,可促進礦物質成分的溶析。又,在倒立圓錐筒狀的反應容器13內流動之水流R,由於會隨著朝向反應容器13底部的排水口19,流速增大,故,與礦物質賦予材(A)12接觸之頻率也增大,可使將存在於水11中的自由電子e捕捉並予以離子化之礦物質量增加。 Further, since the reaction container 13 has an inverted conical tubular shape, it is easier and stable to generate a water flow R flowing along a plurality of annular conductive cables 29a to 29g, thereby facilitating elution of mineral components. . Further, since the flow rate of the water R flowing in the inverted conical tubular reaction vessel 13 increases toward the drain port 19 at the bottom of the reaction vessel 13, the frequency of contact with the mineral-importing material (A) 12 is also Increasing, the mass of the mineral that captures and ionizes the free electrons e present in the water 11 can be increased.
且,由於在循環路徑18b、18c之間設有將水11一邊儲存一邊排出之收容槽22,故,能夠一邊使超過反應容器13的容積之分量的水11循環一邊使礦物質溶析反應進行。因此,可有效率地大量生產原料礦物質水溶液(A)。 Further, since the storage tank 22 that discharges the water 11 while being stored is provided between the circulation paths 18b and 18c, the mineral elution reaction can be performed while circulating the water 11 exceeding the volume of the reaction container 13. . Therefore, the raw material mineral aqueous solution (A) can be mass-produced efficiently.
當使循環泵浦P連續運轉,使該等反應持續進行時,最終可產生礦物質成分溶析出來的原料礦物質水溶液(A)。藉由反應容器13底部的排水口19之大小、循環水量的多寡、反應容器13的形狀(特別是如圖8所示的軸心C與壁體13a所形成的角度γ)等,可控制水11中之自由電子e的出現狀況,藉由自由電子e對礦物質賦予材(A)12賦予的作用,可左右礦物質成分的水溶性。 When the circulation pump P is continuously operated to continue the reaction, the raw material mineral aqueous solution (A) in which the mineral component is eluted can be finally produced. The water can be controlled by the size of the drain port 19 at the bottom of the reaction vessel 13, the amount of circulating water, the shape of the reaction vessel 13 (especially the angle γ formed by the axis C and the wall 13a as shown in Fig. 8), and the like. In the state of occurrence of the free electrons e in 11, the water content of the mineral component can be controlled by the action of the free electrons e on the mineral-imparting material (A) 12.
在形成原料礦物質水溶液(A)後,將該原料礦 物質水溶液(A)41移送至如圖12所示的處理容器40內。在此情況,在反應容器13內從收納容器31漏出的礦物質賦予材(A)12之殘留物可自位於反應容器13底部的排水閥21排出。收容於處理容器40內的原料礦物質水溶液(A)41是一邊被攪拌葉片42緩慢地攪拌,一邊藉由配置於處理容器40內的遠紅外線產生手段43照射遠紅外線。 After forming the raw material mineral aqueous solution (A), the raw material ore is The aqueous substance solution (A) 41 is transferred to the processing container 40 as shown in FIG. In this case, the residue of the mineral-imparting material (A) 12 leaking from the storage container 31 in the reaction container 13 can be discharged from the drain valve 21 located at the bottom of the reaction container 13. The raw material mineral aqueous solution (A) 41 accommodated in the processing container 40 is irradiated with far infrared rays by the far infrared ray generating means 43 disposed in the processing container 40 while being slowly stirred by the stirring blade 42.
再者,遠紅外線產生手段43為可產生波長6~14μm左右的遠紅外線即可,因不受材質、產生手段等影響,所以亦可為加熱方式。但,期望為在25℃,對6~14μm波長區域的黑體放射具有85%以上的放射比率者。 Further, the far-infrared ray generating means 43 may be a far-infrared ray having a wavelength of about 6 to 14 μm, and may be a heating method because it is not affected by materials, generating means, or the like. However, it is desirable to have a radiation ratio of 85% or more for black body radiation in a wavelength region of 6 to 14 μm at 25 °C.
在如圖8所示的原料礦物質水溶液製造手段10,藉由水流R之攪拌作用、流動於導電線15的直流電流DC的作用及超音波振動,能夠使含於礦物質賦予材(A)12中的礦物質成分迅速地溶析至水11中,所需的礦物質成分適度溶入,可效率良好地製造礦物質水溶液41。 In the raw material mineral aqueous solution manufacturing apparatus 10 shown in FIG. 8, the action of the water flow R, the action of the direct current DC flowing on the conductive wire 15, and the ultrasonic vibration can make the mineral-containing material (A) The mineral component in 12 is rapidly dissolved in the water 11, and the desired mineral component is appropriately dissolved, whereby the mineral aqueous solution 41 can be efficiently produced.
又,在如圖12所示的遠紅外線產生手段43,藉由對礦物質水溶液41照射遠紅外線,溶解的礦物質成分與水分子融合而形成電負性提高之含礦物質水(A)44。 Further, in the far-infrared ray generating means 43 shown in FIG. 12, by irradiating the mineral aqueous solution 41 with far-infrared rays, the dissolved mineral component is fused with water molecules to form a mineral-containing water having improved electronegativity (A) 44. .
在含礦物質水(A)製造裝置2,藉由前述製程所形成的含礦物質水(A)44係如圖7所示,經由送水路徑57y輸送至混合槽46,在混合槽46內與從含礦物質水(B)製造裝置3送來的含礦物質水(B)45混合。 In the mineral-containing water (A) manufacturing apparatus 2, the mineral-containing water (A) 44 formed by the above-described process is transported to the mixing tank 46 via the water supply path 57y as shown in Fig. 7, and is mixed in the mixing tank 46. The mineral-containing water (B) 45 sent from the mineral water (B) manufacturing apparatus 3 is mixed.
以下,說明關於礦物質賦予材(A)。 Hereinafter, the mineral-imparting material (A) will be described.
礦物質賦予材(A)是含有由菊科的草木植物及薔薇科的草木植物所構成的草木植物原料;及由自楓樹、白樺樹、松樹及衫樹選擇1種以上的木本植物所構成的木本植物原料。所使用的部位,適宜選擇葉部、莖部、花部、樹皮部等容易溶析出礦物質成分的部位,可直接使用,亦可使用乾燥物。 The mineral-improving material (A) is a plant material containing a plant of the genus Compositae and a plant of the family Rosaceae; and one or more woody plants selected from maple, birch, pine, and saplings. The woody plant material that is composed. The site to be used is preferably a part which is easy to elute mineral components such as leaves, stems, flowers, and bark, and can be used as it is, or a dried product can be used.
再者,除了菊科及薔薇科的草木植物以外,亦可含有其他的草木植物,但僅含有菊科及薔薇科的草木植物為佳。 Furthermore, in addition to the plants of the genus Compositae and Rosaceae, other plants may be included, but only plants of the genus Compositae and Rosaceae are preferred.
作為理想的礦物質賦予材(A)之一例,可舉出礦物質賦予材(A’-1)。藉由使用礦物質賦予材(A’-1),能夠獲得具有對單細胞生物及病毒中的至少一方之防治作用的礦物質機能水(相當於前述礦物質機能水(1))。 An example of the mineral-imparting material (A) is a mineral-imparting material (A'-1). By using the mineral-imparting material (A'-1), it is possible to obtain mineral functional water (corresponding to the aforementioned mineral functional water (1)) having a control action against at least one of a single-celled organism and a virus.
礦物質賦予材(A’-1)係使用:將大薊(葉部、莖部、及花部)、苦艾(葉部及莖部)、山菊(葉部及莖部)以分別成為8~12重量%、55~65重量%、27~33重量%的比例進行混合、乾燥後再粉碎之菊科植物的乾燥粉碎物;及使用將野薔薇(葉部、花部)、水楊梅(葉部及莖部)、木莓(葉部、莖部、及花部)以分別成為17~23重量%、8~12重量%、65~75重量%的比例進行混合、乾燥後再粉碎之薔薇科植物的乾燥粉碎物,將菊科植物的乾燥粉碎物與薔薇科植物的乾燥粉碎物以1:0.8~1:1.2(重量比)進行混合所獲得之草木植物原料(A1-1)作為前述草木植物原料, 由楓樹(葉部及莖部)、白樺樹(葉部、莖部、及樹皮部)、杉樹(葉部、莖部、及樹皮部)以分別成為22~28重量%、22~28重量%、45~55重量%的比例進行混合、乾燥後再粉碎之乾燥粉碎物所構成的木本植物原料(A2-1)作為前述木本植物原料,以草木植物原料(A1-1)與木本植物原料(A2-1)的重量比形成為1:2.7~1:3.3的方式進行混合而獲得之礦物質賦予材。 For the mineral-based material (A'-1), the scorpion (leaf, stem, and flower), wormwood (leaf and stem), and mountain daisy (leaf and stem) are respectively a dried pulverized material of a compositae plant which is mixed, dried, and pulverized in a ratio of 8 to 12% by weight, 55 to 65% by weight, and 27 to 33% by weight; and use of wild rose (leaf, flower), and bayberry ( Leaf and stem), raspberry (leaf, stem, and flower) are mixed, dried, and pulverized at a ratio of 17 to 23% by weight, 8 to 12% by weight, and 65 to 75% by weight, respectively. A dry pulverized material of a plant of the genus Rosaceae, which is obtained by mixing the dried pulverized material of the genus Compositae with the dried pulverized material of the genus Rosaceae with a plant material (A1-1) obtained by mixing 1:0.8 to 1:1.2 (weight ratio) The aforementioned plant material, From maple (leaf and stem), birch (leaf, stem, and bark), cedar (leaf, stem, and bark) to 22 to 28% by weight, 22 to 28, respectively The woody plant material (A2-1) composed of a dry pulverized product which is mixed, dried, and pulverized at a ratio of 45% by weight to 45% by weight is used as the raw material of the woody plant, and the plant material (A1-1) is used as the plant material. The mineral material is obtained by mixing the weight ratio of the woody plant material (A2-1) to a ratio of 1:2.7 to 1:3.3.
在前述礦物質賦予材(A’-1)中,特別是作為前述草木植物原料,將大薊(葉部、莖部、及花部)、苦艾(葉部及莖部)、山菊(葉部及莖部)以分別成為10重量%、60重量%、30重量%的比例進行混合、乾燥後再粉碎之菊科植物的乾燥粉碎物、及野薔薇(葉部、花部)、水楊梅(葉部及莖部)、木莓(葉部、莖部、及花部)以分別成為20重量%、10重量%、70重量%的比例進行混合、乾燥後再粉碎之薔薇科植物的乾燥粉碎物以1:1(重量比)進行混合所獲得之草木植物原料(A1-1);和作為前述木本植物原料,由楓樹(葉部及莖部)、白樺樹(葉部、莖部、及樹皮部)、杉樹(葉部、莖部、及樹皮部)以分別成為25重量%、25重量%、50重量%的比例進行混合、乾燥後再粉碎之乾燥粉碎物所構成的木本植物原料(A2-1),以草木植物原料(A1-1)與木本植物原料(A2-1)的重量比形成為1:3的方式進行混合而獲得之礦物質賦予材為佳。 In the above-mentioned mineral-imparting material (A'-1), in particular, as the raw material of the plant, the cockroach (leaf, stem, and flower), wormwood (leaf and stem), and mountain daisy ( The leaf part and the stem part are mixed and dried, and then pulverized in a ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, and dried pulverized plants of the compositae, and wild rose (leaf, flower), arbutus Drying of the Rosaceae plant (leaf and stem) and raspberry (leaf, stem, and flower) at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively, and then pulverized a plant material (A1-1) obtained by mixing the pulverized material at a ratio of 1:1 (weight ratio); and as a raw material of the aforementioned woody plant, from maple (leaf and stem), birch (leaf, stem) And the sap (the leaf part, the stem part, and the bark part) are mixed, dried, and pulverized by a dry pulverized product at a ratio of 25% by weight, 25% by weight, and 50% by weight, respectively. The woody plant material (A2-1) is obtained by mixing the plant material (A1-1) and the woody plant material (A2-1) in a weight ratio of 1:3. Sheet material which imparts better.
作為形成為礦物質賦予材(A’-1)的原料之草木植物原料(A1-1),可舉出例如理研化工技術系統(RIKEN Techno System)株式會社製[P-100(產品編號)],作為木本植物原料(A2-1),可舉出例如理研化工技術系統株式會社製[P-200(產品編號)]。再者,理研化工技術系統株式會社製的礦物質機能水CAC-717[Tera Protect(商品名),CAC-717(產品編號)]是使用[P-100(產品編號)]、[P-200(產品編號)]之礦物質機能水。 For example, the RIKEN Techno System Co., Ltd. product [P-100 (product number)] is used as the plant material (A1-1) which is a raw material of the mineral-based material (A'-1). For example, [P-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. is used as the woody plant material (A2-1). In addition, the mineral functional water CAC-717 [Tera Protect (product name), CAC-717 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. is [P-100 (product number)], [P-200] (Product No.)] Mineral functional water.
又,作為其他理想的礦物質賦予材(A)之一例,可舉出礦物質賦予材(A’-2)。藉由使用礦物質賦予材(A’-2),能夠獲得具有身體活化作用的礦物質機能水(相當於前述礦物質機能水(2))。 Further, as an example of another preferable mineral-imparting material (A), a mineral-imparting material (A'-2) can be mentioned. By using the mineral-imparting material (A'-2), mineral functional water (corresponding to the aforementioned mineral functional water (2)) having body activation can be obtained.
前述礦物質賦予材(A’-2),為以下的礦物質賦予材,亦即作為前述草木植物原料,將大薊(葉部、莖部、及花部)、苦艾(葉部及莖部)、山菊(葉部及莖部)以分別成為10重量%、60重量%、30重量%的比例進行混合、乾燥後再粉碎之菊科植物的乾燥粉碎物、及野薔薇(葉部、花部)、水楊梅(葉部及莖部)、木莓(葉部、莖部、及花部)以分別成為20重量%、10重量%、70重量%的比例進行混合、乾燥後再粉碎之薔薇科植物的乾燥粉碎物以1:1(重量比)進行混合所獲得之草木植物原料(A1-2);和作為前述木本植物原料,由楓樹(落葉)、白樺樹(落葉、莖部、及樹皮部)、杉樹(落葉、莖部、及樹皮部)以分別成為20重量%、60重量%、20重量%的比例進行混 合、乾燥後再粉碎之乾燥粉碎物所構成的木本植物原料(A2-2),以草木植物原料(A1-2)與木本植物原料(A2-2)的重量比形成為1:5的方式進行混合而獲得的礦物質賦予材。 The mineral-improving material (A'-2) is a mineral-imparting material, that is, as a plant material of the above-mentioned plant, a large scorpion (leaf, stem, and flower), wormwood (leaf and stem) (part), the succulent (the leaf part and the stem part), which are mixed, dried, and pulverized at a ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, and dried smashed plants of the compositae, and wild rose (leaf, Flower part), bayberry (leaf part and stem part), raspberry (leaf part, stem part, and flower part) are mixed, dried, and pulverized at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively. a plant material (A1-2) obtained by mixing a dried pulverized plant of a Rosaceae plant at a ratio of 1:1 (weight ratio); and as a raw material of the aforementioned woody plant, a maple tree (deciduous), a birch tree (deciduous, The stem portion and the bark portion, and the cedar (deciduous, stem, and bark portions) are mixed at a ratio of 20% by weight, 60% by weight, and 20% by weight, respectively. The woody plant material (A2-2) composed of the dried and pulverized dried pulverized material is formed into a 1:5 weight ratio of the plant material (A1-2) to the wood material (A2-2). The mineral-donating material obtained by mixing is obtained.
作為形成為礦物質賦予材(A’-2)的原料之這種的草木植物原料(A1-2),可舉出例如理研化工技術系統(RIKEN Techno System)株式會社製[P-101(產品編號)],作為木本植物原料(A2-2),可舉出例如理研化工技術系統株式會社製[P-201(產品編號)]。藉此,能夠獲得理研化工技術系統株式會社製的礦物質機能水A20ACA-717[Tera Support(商品名),A20ACA-717(產品編號)]。 For example, the RIKEN Techno System Co., Ltd. product [P-101 (product) is used as the raw material of the plant material (A1-2) which is a raw material of the mineral-based material (A'-2). In the case of the woody plant material (A2-2), for example, [P-201 (product number)] manufactured by Riken Chemical Technology Co., Ltd. is mentioned. In this way, the mineral functional water A20ACA-717 [Tera Support (trade name), A20ACA-717 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. can be obtained.
又,作為其他理想的礦物質賦予材(A)之一例,可舉出礦物質賦予材(A’-3)。藉由使用礦物質賦予材(A’-3),能夠獲得具有碳化氫類的燃燒促進作用的礦物質機能水(相當於前述礦物質機能水(3))。 Further, as an example of another preferable mineral-imparting material (A), a mineral-imparting material (A'-3) can be mentioned. By using the mineral-imparting material (A'-3), it is possible to obtain mineral functional water (corresponding to the aforementioned mineral functional water (3)) having a combustion-promoting action of hydrocarbons.
前述礦物質賦予材(A’-3),為以下的礦物質賦予材,亦即作為前述草木植物原料,將大薊(葉部、莖部、及花部)、苦艾(葉部及莖部)、山菊(葉部及莖部)以分別成為10重量%、60重量%、30重量%的比例進行混合、乾燥後再粉碎之菊科植物的乾燥粉碎物、及野薔薇(葉部、花部)、水楊梅(葉部及莖部)、木莓(葉部、莖部、及花部)以分別成為20重量%、10重量%、70重量%的比例進行混合、乾燥後再粉碎之薔薇科植物的乾燥粉碎物以1:1(重量比)進行混合所獲得之草木植物原料(A1-1);和 作為前述木本植物原料,由楓樹(葉部及莖部)、白樺樹(葉部、莖部、及樹皮部)、杉樹(葉部、莖部、及樹皮部)以分別成為25重量%、25重量%、50重量%的比例進行混合、乾燥後再粉碎之乾燥粉碎物所構成的木本植物原料(A2-1);及作為活性碳,以活化溫度1000℃將椰殼碳化之活性碳粉末(A3-1)所構成,對將草木植物原料(A1-1)與木本植物原料(A2-1)以重量比形成為1:3進行混合者,將活性碳粉末(A3-1)形成為2~8重量部的方式進行混合所獲得之礦物質賦予材。 The mineral-improving material (A'-3) is a mineral-imparting material, that is, as a plant material of the above-mentioned plant, a large scorpion (leaf, stem, and flower), wormwood (leaf and stem) (part), the succulent (the leaf part and the stem part), which are mixed, dried, and pulverized at a ratio of 10% by weight, 60% by weight, and 30% by weight, respectively, and dried smashed plants of the compositae, and wild rose (leaf, Flower part), bayberry (leaf part and stem part), raspberry (leaf part, stem part, and flower part) are mixed, dried, and pulverized at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively. a plant material (A1-1) obtained by mixing a dry pulverized plant of a Rosaceae plant at a ratio of 1:1 (weight ratio); and As the raw material of the woody plant, the maple (leaf and stem), the birch (leaf, stem, and bark), the cedar (leaf, stem, and bark) are respectively 25 weights. a woody plant material (A2-1) composed of a dry pulverized product which is mixed, dried, and pulverized at a ratio of %, 25% by weight, and 50% by weight; and carbonized at a activation temperature of 1000 ° C as an activated carbon The activated carbon powder (A3-1) is composed of a mixture of the plant material (A1-1) and the wood material (A2-1) in a weight ratio of 1:3, and the activated carbon powder ( A3-1) A mineral-imparting material obtained by mixing in a form of 2 to 8 parts by weight.
在此,活性碳粉末(A3-1)係採用將椰殼在惰性氣體環境下以活化溫度1000℃進行碳化之活性碳粉末中,當以形成為10wt%的方式添加於純水中時pH形成為9~11、理想為9.5~10.5、更理想為pH10之活性碳粉末。 Here, the activated carbon powder (A3-1) is an activated carbon powder obtained by carbonizing a coconut shell at an activation temperature of 1000 ° C in an inert gas atmosphere, and when it is added to pure water in a form of 10% by weight. The activated carbon powder having a pH of 9 to 11, preferably 9.5 to 10.5, more preferably pH 10.
再者,當以低溫進行椰殼的活化時,會有鹼性變強的傾向,但當在1000℃進行活化時,則會形成為弱鹼性狀態。 Further, when the coconut shell is activated at a low temperature, the alkali tends to become strong, but when activated at 1000 ° C, it is formed into a weakly alkaline state.
活性碳粉末(A3-1)的添加量,係添加於礦物質賦予材(A-1)使含礦物質水(A)與含礦物質水(B)混合時的pH形成為11~12,當以重量比形成為1:3的方式將草木植物原料(A1-1)與木本植物原料(A2-1)混合的混合物設為100重量部時,形成為2~8重量部的範圍。 The addition amount of the activated carbon powder (A3-1) is added to the mineral-imparting material (A-1) to form a pH of 11 to 12 when the mineral-containing water (A) and the mineral-containing water (B) are mixed. When the mixture of the plant material (A1-1) and the woody plant material (A2-1) is 100 parts by weight in a weight ratio of 1:3, it is formed into a range of 2 to 8 parts by weight. .
作為形成為礦物質賦予材(A’-3)的原料之草木植物原料(A1-1),可舉出例如理研化工技術系統(RIKEN Techno System)株式會社製[P-100(產品編號)],作為木本植物原料(A2-1),可舉出例如理研化工技術系統株式會社製[P-200(產品編號)],作為活性碳粉末(A3-1),可舉出例如理研化工技術系統株式會社製[AS-100(產品編號)]。 As the plant material (A1-1) which is a raw material of the mineral-imparting material (A'-3), for example, the Riken Chemical Technology System (RIKEN) [P-100 (product number)] manufactured by Techno System Co., Ltd., and as a woody plant material (A2-1), for example, [P-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. The carbon powder (A3-1) is, for example, [AS-100 (product number)] manufactured by Riken Chemical Technology Co., Ltd.
又,作為其他理想的礦物質賦予材(A)之一例,可舉出礦物質賦予材(A’-4)。藉由使用礦物質賦予材(A’-4),能夠獲得具有抗氧化作用的礦物質機能水(相當於前述礦物質機能水(4))。 Further, as an example of another preferable mineral-importing material (A), a mineral-imparting material (A'-4) can be mentioned. By using the mineral-imparting material (A'-4), it is possible to obtain mineral functional water (corresponding to the aforementioned mineral functional water (4)) having an antioxidant action.
前述礦物質賦予材(A’-4),為以下的礦物質賦予材,亦即作為前述草木植物原料,將大薊(葉部、莖部、及花部)、苦艾(葉部及莖部)、山菊(葉部及莖部)以分別成為10重量%、60重量%、30重量%的比例進行混合、乾燥後再粉碎之菊科植物的乾燥粉碎物之野薔薇(葉部、花部)、水楊梅(葉部及莖部)、木莓(葉部、莖部、及花部)以分別成為20重量%、10重量%、70重量%的比例進行混合、乾燥後再粉碎之薔薇科植物的乾燥粉碎物以1:1(重量比)進行混合所獲得之草木植物原料(A1-2);和作為前述木本植物原料,將由楓樹(落葉)、白樺樹(落葉、莖部、及樹皮部)、杉樹(落葉、莖部、及樹皮部)以分別成為20重量%、60重量%、20重量%的比例進行混合、乾燥後再粉碎之乾燥粉碎物所構成的木本植物原料(A2-2);及作為硫磺原料之火山性硫磺(A3-2)所構成,對將草木植物原料(A1-2)與木本植物原料(A2-2)以重 量比形成為1:5進行混合者,將火山性硫磺(A3-2)形成為2~8重量部的方式進行混合所獲得之礦物質賦予材。 The mineral-improving material (A'-4) is a mineral-imparting material, that is, as a plant material of the above-mentioned plant, a large scorpion (leaf, stem, and flower), wormwood (leaf and stem) The part of the genus, the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus of the genus Part), bayberry (leaf and stem), raspberry (leaf, stem, and flower) are mixed, dried, and pulverized at a ratio of 20% by weight, 10% by weight, and 70% by weight, respectively. a plant material (A1-2) obtained by mixing a dry pulverized plant of a Rosaceae plant at a ratio of 1:1 (weight ratio); and as a raw material of the aforementioned woody plant, a maple tree (deciduous), a birch tree (deciduous, stalk) Wood, which is composed of dried pulverized material which is mixed, dried, and pulverized at a ratio of 20% by weight, 60% by weight, and 20% by weight, respectively, in cedar (deciduous, stalk, and bark) The plant material (A2-2); and the volcanic sulfur (A3-2) as a sulfur raw material, the plant material (A1-2) and the wood plant Starting material (A2-2) in a weight The mineral material obtained by mixing the volcanic sulfur (A3-2) to a weight of 2 to 8 parts by weight is formed by mixing 1:5.
在此,火山性硫磺(A3-2)為存在於火山之含硫磺物質。火山性硫磺(A3-2)係當使水流通時溶解或分散,硫磺成分溶解至含礦物質水(A)中者即可。當火山性硫磺(A3-2)作為硫磺時,可強力地產生本發明的礦物質機能水特有之消炎作用、抗氧化作用之特徵,因此較佳。將火山性硫磺(A3-2)予以粉碎而作成粉末再使用為佳。 Here, volcanic sulfur (A3-2) is a sulfur-containing substance present in a volcano. The volcanic sulphur (A3-2) is dissolved or dispersed when the water is circulated, and the sulphur component is dissolved in the mineral-containing water (A). When volcanic sulfur (A3-2) is used as sulfur, it is preferable to strongly produce the anti-inflammatory action and anti-oxidation characteristic characteristic of the mineral functional water of the present invention. It is preferred to pulverize the volcanic sulfur (A3-2) to form a powder.
火山性硫磺(A3-2)的添加量,係當以重量比形成為1:5的方式將草木植物原料(A1-2)與木本植物原料(A2-2)混合的混合物設為100重量部時,形成為2~8重量部的範圍。 The volcanic sulfur (A3-2) is added in an amount of 100 parts by mixing the plant material (A1-2) with the woody plant material (A2-2) in a weight ratio of 1:5. In the case of the part, it is formed in the range of 2 to 8 parts by weight.
作為前述草木植物原料(A1-2),可理想地使用理研化工技術系統(RIKEN Techno System)株式會社製[P-101(產品編號)],作為木本植物原料(A2-2),可理想地使用理研化工技術系統株式會社製[P-201(產品編號)]。又,作為火山性硫磺(A3-2),可理想地使用理研化工技術系統株式會社製[S-100(產品編號)]。 As the grass plant material (A1-2), it is preferable to use [P-101 (product number)] manufactured by RIKEN Techno System Co., Ltd. as a woody plant material (A2-2). [P-201 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. was used. Further, as the volcanic sulfur (A3-2), [S-100 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.
(3-2-2:含礦物質水(B)製造裝置) (3-2-2: Mineral water (B) manufacturing equipment)
其次,依據圖7、圖13,說明關於含礦物質水(B)製造裝置3的結構、功能等。 Next, the structure, function, and the like of the mineral-containing water (B) manufacturing apparatus 3 will be described with reference to Figs. 7 and 13 .
如圖7、圖13所示,含礦物質水(B)製造裝置3具備有:相互填充有種類不同的礦物質賦予材(B)之第1通水 容器51~第6通水容器56;將第1通水容器51~第6通水容器56串聯地連通之送水路徑57;在分別與第1通水容器51~第6通水容器56並排的狀態下連結於送水路徑57之迂迴水路51p~56p;及分別設在各迂迴水路51p~56p與送水路徑57的分歧部之水流切換閥51v~56v。 As shown in FIG. 7 and FIG. 13, the mineral water (B) manufacturing apparatus 3 is provided with the first water which is filled with the mineral material providing material (B) of a different type. The container 51 to the sixth water-passing container 56; the water supply path 57 that connects the first water-passing container 51 to the sixth water-passing container 56 in series; and the first water-passing container 51 to the sixth water-passing container 56 are arranged side by side. In the state, the bypass water passages 51p to 56p connected to the water supply path 57; and the water flow switching valves 51v to 56v provided in the branch portions of the respective bypass water passages 51p to 56p and the water supply path 57 are provided.
水流切換閥51v~56v的切換操作,可藉由操作設在以訊號纜線59來與這些水流切換閥51v~56v連結之操作盤58的6個切換鈕51b~56b來執行。因6個切換鈕51b~56b與6個水流切換閥51v~56v以個別的號碼相對應,當操作切換鈕51b~56b中的其中一個切換鈕時,與其相對應之號碼的水流切換閥51v~56v被切換,能夠改變水流方向。 The switching operation of the water flow switching valves 51v to 56v can be performed by operating the six switching knobs 51b to 56b provided on the operation panel 58 connected to the water flow switching valves 51v to 56v by the signal cable 59. Since the six switching buttons 51b to 56b and the six water flow switching valves 51v to 56v correspond to individual numbers, when one of the switching buttons 51b to 56b is operated, the water flow switching valve 51v of the corresponding number is operated. The 56v is switched to change the direction of the water flow.
又,在第1通水容器51內,填充有含有二氧化矽與氧化鐵之礦物質賦予材(B)51m,在第2通水容器52內,填充有含有二氧化矽與活性碳之礦物質賦予材(B)52m,在第3通水容器53內,填充有含有二氧化矽與氮化鈦之礦物質賦予材(B)53m,在第4通水容器54內,填充有含有二氧化矽與碳酸鈣之礦物質賦予材(B)54m,在第5通水容器55內,填充有含有二氧化矽與碳酸鎂之礦物質賦予材(B)55m,在第6通水容器56內,填充有含有二氧化矽與磷酸鈣之礦物質賦予材(B)56m。 Further, the first water-passing container 51 is filled with a mineral-imparting material (B) 51m containing cerium oxide and iron oxide, and the second water-passing container 52 is filled with a cerium oxide-containing activated carbon ore. The material-imparting material (B) is 52 m, and the third water-passing container 53 is filled with a mineral-imparting material (B) 53 m containing cerium oxide and titanium nitride, and is filled in the fourth water-passing container 54 with two The mineral-supporting material (B) of cerium oxide and calcium carbonate is 54 m, and the fifth water-passing container 55 is filled with a mineral-imparting material (B) containing cerium oxide and magnesium carbonate (B) 55 m, and is in the sixth water-passing container 56. The inside was filled with a mineral-imparting material (B) containing cerium oxide and calcium phosphate (56 m).
在此,礦物質賦予材(B)51m~56m,理想為能夠將以石灰石、珊瑚化石、貝殼為基材之原料加以混合來製造。 Here, the mineral-imparting material (B) is 51 m to 56 m, and it is preferable to be produced by mixing raw materials containing limestone, coral fossils, and shells as a base material.
首先,分析石灰石、珊瑚化石、貝殼所含的成分,評價各自所含的二氧化矽、氧化鐵、活性碳、氮化鈦、碳酸鈣、碳酸鎂、磷酸鈣之量。又,以各成分的含有量為基準,將石灰石、珊瑚化石、貝殼混合,製造礦物質賦予材(B)51m~56m。 First, the components contained in limestone, coral fossils, and shells were analyzed, and the amounts of cerium oxide, iron oxide, activated carbon, titanium nitride, calcium carbonate, magnesium carbonate, and calcium phosphate contained in each of them were evaluated. In addition, limestone, coral fossils, and shells are mixed to prepare a mineral-importing material (B) of 51 m to 56 m based on the content of each component.
再者,期望前述礦物質賦予材(B)51m~56m是藉由石灰石、珊瑚化石、貝殼的混合比來控制含有成分,但,因作為原料之石灰石、珊瑚化石、貝殼會有因產地的關係產生含有成分不足之情況,所以,亦可因應需要,追加二氧化矽、氧化鐵、活性碳、氮化鈦、碳酸鈣、碳酸鎂、磷酸鈣。特別是活性碳,由於在石灰石、珊瑚化石、貝殼幾乎不會含有,故,一般會另外追加。 In addition, it is expected that the mineral-based material (B) 51m to 56m is controlled by the mixing ratio of limestone, coral fossil, and shell, but the limestone, coral fossil, and shell as raw materials may have a relationship with the place of origin. In the case where the content of the component is insufficient, the cerium oxide, the iron oxide, the activated carbon, the titanium nitride, the calcium carbonate, the magnesium carbonate, or the calcium phosphate may be added as needed. In particular, activated carbon is rarely contained in limestone, coral fossils, and shells, so it is generally added.
作為礦物質賦予材(B)51m~56m,當第1通水容器51內的礦物質賦予材(B1)為分別含有70重量%的石灰石、15重量%的珊瑚化石、15重量%的貝殼之混合物;第2通水容器52內的礦物質賦予材(B2)為分別含有40重量%的石灰石、15重量%的珊瑚化石、40重量%的貝殼、5重量%的活性碳之混合物;第3通水容器53內的礦物質賦予材(B3)為分別含有80重量%的石灰石、15重量%的珊瑚化石、5重量%的貝殼之混合物;第4通水容器54內的礦物質賦予材(B4)為分別含有90重量%的石灰石、5重量%的珊瑚化石、5重量%的貝殼 之混合物;第5通水容器55內的礦物質賦予材(B5)為分別含有80重量%的石灰石、10重量%的珊瑚化石、10重量%的貝殼之混合物;第6通水容器56內的礦物質賦予材(B6)為分別含有60重量%的石灰石、30重量%的珊瑚化石、10重量%的貝殼之混合物時,在與含礦物質水(A)混合之際,能夠獲得具有優良有害生物防治作用之含礦物質水(B)。 The mineral-importing material (B) is 51 m to 56 m, and the mineral-imparting material (B1) in the first water-passing container 51 contains 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight of shells. The mixture-providing material (B2) in the second water-passing container 52 is a mixture containing 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon; The mineral-imparting material (B3) in the water-passing container 53 is a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, and a mineral-donating material in the fourth water-passing container 54 ( B4) is 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells The mixture-providing material (B5) in the fifth water-passing container 55 is a mixture containing 80% by weight of limestone, 10% by weight of coral fossil, and 10% by weight of shells, respectively; and 6th water-passing container 56 When the mineral-importing material (B6) is a mixture containing 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shells, it can be excellently detrimental when mixed with mineral-containing water (A). Mineral water (B) for biological control.
特別是使用於礦物質賦予材(B1)~(B6)之石灰石、珊瑚化石、貝殼為以下的(1-1)~(1-3)為佳。 In particular, it is preferable that the limestone, the coral fossil, and the shell used for the mineral-imparting materials (B1) to (B6) are the following (1-1) to (1-3).
(1-1)石灰石: (1-1) Limestone:
將混合存在有含有下述成分的火山沉積物之石灰岩粉碎形成的3cm左右的卵石狀物 About 3 cm of pebbles formed by pulverizing limestone in which volcanic sediments containing the following components are mixed
碳酸鈣:50重量%以上 Calcium carbonate: 50% by weight or more
氧化鐵:3~9重量%的鐵 Iron oxide: 3~9 wt% iron
氧化鈦、碳化鈦、氮化鈦的總合:0.8重量%以上 The total of titanium oxide, titanium carbide, and titanium nitride: 0.8% by weight or more
碳酸鎂:7~10重量%。 Magnesium carbonate: 7 to 10% by weight.
作為這樣的石灰石,可理想地使用理研化工技術系統株式會社製[CC-200(產品編號)]。 As such a limestone, [CC-200 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.
(1-2)珊瑚化石: (1-2) Coral fossils:
將以下2種的珊瑚化石以1:9的重量比混合再粉碎成3~5mm所形成之粒狀物 The following two kinds of coral fossils are mixed in a weight ratio of 1:9 and pulverized into granules formed by 3 to 5 mm.
從地底下約100公尺生產,藉由重壓使得結晶組成變性之珊瑚化石;從沖繩奄美大島附近的陸地生產的珊瑚化石(含有碳酸鈣、磷酸鈣等的其他微量元素)。 A coral fossil that is produced from a depth of about 100 meters under the ground, which is made into a denatured crystal by heavy pressure; a coral fossil (a trace element containing calcium carbonate, calcium phosphate, etc.) produced from the land near Okinawa Oshima.
作為這樣的珊瑚化石,可理想地使用理研化工技術系統株式會社製[CC-300(產品編號)]。 As such a coral fossil, [CC-300 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. can be preferably used.
(1-3)貝殼: (1-3) Shell:
鮑魚、九孔、藤壺以相同重量混合再粉碎成3~5mm之粒狀物 Abalone, nine-hole, and barnacle are mixed and pulverized into 3~5mm granules with the same weight.
作為這樣的貝殼,可理想地使用理研化工技術系統株式會社製[CC-400(產品編號)]。 As such a shell, [CC-400 (product number)] manufactured by Riken Chemical Technology Co., Ltd. can be preferably used.
(1-4)活性碳 (1-4) Activated carbon
活性碳可使用從任意的原料所製造者,但理想可舉出以椰殼作為原料所製造的活性碳。例如,以泰國產的椰殼為原料之理研化工技術系統株式會社製[CC-500(產品編號)]。 As the activated carbon, those produced from any raw material can be used, but activated carbon produced by using coconut shell as a raw material is preferable. For example, [CC-500 (Product No.)] manufactured by Riken Chemical Technology Systems Co., Ltd., which is made from coconut shells made in Thailand.
若操作前述操作盤58的切換鈕51b~56b,將水流切換閥51v~56v朝通水容器側切換,則流動於送水路徑57的水會朝處於較已被操作的水流切換閥更下游側的第1通水容器51~第6通水容器56內流入,若將水流切換閥51v~56v朝迂迴水路側切換的話,則流動於送水路徑57的水會朝較已被操作的水流切換閥更下游側的迂迴水 路51p~56p流入。因此,藉由操作切換鈕51b~56b中的其中任一者來選擇性地切換水流切換閥51v~56v,能夠形成針對各第1通水容器51~第6通水容器56使從不同的礦物質賦予材(B)51m~56m溶析出來的礦物質成分選擇性地溶入之含礦物質水(B)45。 When the switching knobs 51b to 56b of the operation panel 58 are operated and the water flow switching valves 51v to 56v are switched toward the water container side, the water flowing through the water supply path 57 is directed to the downstream side of the water flow switching valve that is already operated. When the first water-passing container 51 to the sixth water-passing container 56 are inflow, if the water-flow switching valves 51v to 56v are switched to the bypass waterway side, the water flowing through the water supply path 57 is directed to the water flow switching valve that is already operated. Downstream water The road 51p~56p flows in. Therefore, by selectively switching the water flow switching valves 51v to 56v by operating any of the switching buttons 51b to 56b, it is possible to form different mines for each of the first water passing containers 51 to the sixth water passing container 56. The material-imparting material (B) contains mineral water (B) 45 in which the mineral component eluted from 51 m to 56 m is selectively dissolved.
其次,依據圖14至圖17,說明關於含礦物質水(B)製造裝置3的結構、功能。再者,在圖14至圖16中,省略了前述迂迴水路51p~56p、水流切換閥51v~56v、操作盤58及訊號纜線59。 Next, the structure and function of the mineral-containing water (B) manufacturing apparatus 3 will be described with reference to Figs. 14 to 17 . Further, in FIGS. 14 to 16, the bypass water passages 51p to 56p, the water flow switching valves 51v to 56v, the operation panel 58 and the signal cable 59 are omitted.
如圖14、圖15所示,含礦物質水(B)製造裝置3係具備有:搭載於架台60之略圓筒狀的第1通水容器51~第6通水容器56;及將該等第1通水容器51~第6通水容器56串聯地連通的送水路徑57,用來儲存從自來水管所供給的水W之原水槽63配置在架台60的最上部。在原水槽63內,收容有具備用來吸附水W中的雜質的功能之無機質多孔體64。在架台60的底部,設有複數個腳輪61及水平調節器62。略圓筒狀的第1通水容器51~第6通水容器56係在將各自的軸心51c~56c(參照圖15)保持在水平方向的狀態下,配置於長方體格子構造之架台60。第1通水容器51~第6通水容器56對架台60可進行裝卸。 As shown in FIG. 14 and FIG. 15, the mineral water-containing (B) manufacturing apparatus 3 includes a first water-passing container 51 to a sixth water-passing container 56 that are mounted on the gantry 60 in a substantially cylindrical shape; The water supply path 57 in which the first water-passing container 51 to the sixth water-passing container 56 are connected in series, and the raw water tank 63 for storing the water W supplied from the water pipe is disposed at the uppermost portion of the gantry 60. In the raw water tank 63, an inorganic porous body 64 having a function of adsorbing impurities in the water W is housed. At the bottom of the gantry 60, a plurality of casters 61 and a level adjuster 62 are provided. The first water-passing container 51 to the sixth water-passing container 56 having a substantially cylindrical shape are placed on the gantry 60 of the rectangular parallelepiped lattice structure while holding the respective axial centers 51c to 56c (see FIG. 15) in the horizontal direction. The first water-passing container 51 to the sixth water-passing container 56 can detach the gantry 60.
如圖16所示,第1通水容器51~第6通水容器56均為相同構造,藉由將圓板狀的蓋體51d~56d安裝於設在圓筒狀的本體部51a~56a的兩端部之凸緣部 51f~56f,形成氣密構造。當軸心51c~56c處於水平狀態時,在位於本體部51a~56a的最下部之部位,設有與送水路徑57相連通的入水口57a,在較離入水口57a遠的位置之蓋體51d~56d的最上部,設有與送水路徑57相連通的出水口57b,在出水口57b安裝有濾網57c。在本體部51a~56a外周的出水口57b之正上方部位,安裝有使第1通水容器51~第6通水容器56內的氣體脫離的自動氣閥57d。 As shown in Fig. 16, the first water-passing container 51 to the sixth water-passing container 56 have the same structure, and the disk-shaped lid bodies 51d to 56d are attached to the cylindrical body portions 51a to 56a. Flange at both ends 51f~56f, forming an airtight structure. When the axial centers 51c to 56c are in a horizontal state, a water inlet 57a communicating with the water supply path 57 is provided at a portion located at the lowermost portion of the main body portions 51a to 56a, and a cover 51d at a position farther from the water inlet 57a. The uppermost portion of the ~56d is provided with a water outlet 57b that communicates with the water supply path 57, and a screen 57c is attached to the water outlet 57b. An automatic air valve 57d for detaching the gas in the first water-passing container 51 to the sixth water-passing container 56 is attached to a portion directly above the water outlet 57b on the outer circumference of the main body portions 51a to 56a.
從上游側的送水路徑57所供給之水,通過入水口57a流入至第1通水容器51~第6通水容器56內,與填充於各自的內部之礦物質賦予材(B)51m~56m接觸,藉此,各礦物質成分溶析到水中,因此,形成為含有與個別的礦物質賦予材(B)51m~56m對應之礦物質成分的水,再從出水口57b朝下游側的送水路徑57流出。 The water supplied from the upstream water supply path 57 flows into the first water-passing container 51 to the sixth water-passing container 56 through the water inlet 57a, and the mineral-imparting material (B) filled in each of the interiors is 51 m to 56 m. After the contact, the mineral components are dissolved in the water. Therefore, the water is contained in the water containing the mineral component corresponding to the individual mineral material (B) 51m to 56m, and the water is supplied from the water outlet 57b to the downstream side. Path 57 flows out.
在如圖14至圖16所示的含礦物質水(B)製造裝置3,藉由操作如圖13所示的操作盤58之切換鈕51b~56b中的其中一個,使原水槽63中的水W通過第1通水容器51~第6通水容器56中的1個以上之通水容器,能夠形成含礦物質水(B)45,該含礦物質水是選擇性地溶入有個別填充於從第1通水容器51到第6通水容器56的礦物質賦予材(B)51m~56m中所含之具有特徵的礦物質成分。 The mineral-containing water (B) manufacturing apparatus 3 shown in Figs. 14 to 16 is operated in the raw water tank 63 by operating one of the switching knobs 51b to 56b of the operation panel 58 as shown in Fig. 13. The water W passes through one or more water-passing containers in the first water-passing container 51 to the sixth water-passing container 56, and can form mineral-containing water (B) 45, which is selectively dissolved in individual water. The mineral component contained in the mineral-importing material (B) 51m to 56m filled in the first water-passing container 51 to the sixth water-passing container 56 is characteristic.
又,在含礦物質水(B)製造裝置3,由於第1通水容器51~第6通水容器56是以送水路徑57串聯地連 結,故,藉由使水連續地流動於該送水路徑57,可大量地生產含礦物質水(B)45,該含礦物質水(B)45是溶入有對應於第1通水容器51~第6通水容器56內的礦物質賦予材(B)51m~56m之礦物質成分。 Further, in the mineral-containing water (B) manufacturing apparatus 3, the first water-passing container 51 to the sixth water-passing container 56 are connected in series by the water supply path 57. Therefore, by continuously flowing water to the water supply path 57, the mineral-containing water (B) 45 can be produced in a large amount, and the mineral-containing water (B) 45 is dissolved in the first water-passing container. The mineral material of the 51 to 6th water-passing container 56 (B) is a mineral component of 51 m to 56 m.
再者,在含礦物質水(B)製造裝置3所形成的含礦物質水(B)45,係經由位於較第6通水容器56更下游側的送水路徑57x輸送至混合槽46內,在其內部,與在如圖7所示的含礦物質水(A)製造裝置2所製造的含礦物質水(A)44混合,藉此形成礦物質機能水47。 Further, the mineral-containing water (B) 45 formed in the mineral-containing water (B) manufacturing apparatus 3 is transported into the mixing tank 46 via the water supply path 57x located further downstream than the sixth water-passing container 56. In the inside thereof, it is mixed with the mineral-containing water (A) 44 produced by the mineral-containing water (A) manufacturing apparatus 2 shown in Fig. 7, thereby forming the mineral functional water 47.
含礦物質水(A)與含礦物質水(B)的配合比例,是考量含礦物質水(A)及含礦物質水(B)所含的原料之種類、溶析的成分濃度加以適宜決定,但,在含礦物質水(A)與含礦物質水(B)的重量比([含礦物質水(A)]:[含礦物質水(B)]),為1:5~1:20的範圍,理想為1:7~1:12的範圍,更理想為1:10的範圍。 The ratio of the mineral-containing water (A) to the mineral-containing water (B) is determined by considering the type of the raw material contained in the mineral-containing water (A) and the mineral-containing water (B) and the concentration of the dissolved components. Decide, however, that the weight ratio of mineral-containing water (A) to mineral-containing water (B) ([mineral water (A)]: [mineral water (B)]) is 1:5~ The range of 1:20 is ideally in the range of 1:7 to 1:12, and more preferably in the range of 1:10.
當含礦物質水(A)過少(含礦物質水(B)過多)的情況,及含礦物質水(A)過多(含礦物質水(B)過少)的情況,會有礦物質機能水的有效成分被稀釋造成期望目的的作用變得不充分之虞產生。 In the case of too little mineral water (A) (excessive mineral water (B)), and too much mineral water (A) (mineral water (B) too little), there will be mineral water The active ingredient is diluted and the effect of the desired purpose becomes insufficient.
以上,說明了本發明的礦物質機能水的製造方法之理想實施形態,但不限於該等實施形態,只要能夠製造具有前述結構的本發明的礦物質機能水即可,除了前述理想實施形態以外,亦可採用各種結構。特別是在此次所揭示的實施形態中,未明確揭示的事項例如運轉條件、 操作條件、各種參數、構成物的尺寸、重量、體積等,是採用不會超出該業者一般實施的範圍,若為一般的該業者即可容易想到的值。 In the above, a preferred embodiment of the method for producing mineral water according to the present invention is described. However, the present invention is not limited to the embodiments, and the mineral functional water of the present invention having the above configuration can be produced, and in addition to the above-described preferred embodiment. Various structures can also be used. In particular, in the embodiments disclosed herein, items that are not explicitly disclosed, such as operating conditions, The operating conditions, various parameters, the size, weight, volume, and the like of the components are those that do not exceed the scope generally practiced by the industry, and are generally conceivable values for the industry.
[實施例] [Examples]
以下,列舉實施例更具體地說明本發明,但,本發明不限於這些實施例。 Hereinafter, the present invention will be specifically described by way of examples, but the invention is not limited to the examples.
使用本發明的實施形態所揭示的溶析機能水製造裝置100製造溶析機能水。使用於該製造裝置之溶析型陶瓷材料、及非溶析型陶瓷材料、以及固定化於該等陶瓷材料之礦物質機能水如以下的方式進行準備。 The elution functional water manufacturing apparatus 100 disclosed in the embodiment of the present invention is used to produce the elution functional water. The eluted ceramic material used in the manufacturing apparatus, the non-lead-type ceramic material, and the mineral functional water fixed to the ceramic materials are prepared as follows.
[實施例1] [Example 1]
<1>礦物質機能水的製造 <1>Manufacture of mineral functional water
作為礦物質機能水,使用:採用前述礦物質機能水製造裝置(礦物質機能水製造裝置1),以前述的製造方法,用以下的原料及方式進行製造的實施例1之礦物質機能水。 As the mineral functional water, the mineral functional water of Example 1 produced by the following raw materials and methods was used in the above-described mineral functional water producing apparatus (mineral functional water producing apparatus 1).
1.含礦物質水(A)的製造 1. Manufacture of mineral-containing water (A)
使用礦物質賦予材(A’-1)作為礦物質賦予材(A)。作為實施例1之礦物質賦予材(A’-1)的原料中的草木植物原料(A1-1),使用理研化工技術系統(RIKEN Techno System)株式會社製[P-100(產品編號)],作為木本植物原料(A2-1), 使用理研化工技術系統株式會社製[P-200(產品編號)]。 The mineral-imparting material (A'-1) was used as the mineral-imparting material (A). As the plant material (A1-1) of the raw material of the mineral-importing material (A'-1) of the first embodiment, the RIKEN Techno System Co., Ltd. product [P-100 (product number)] was used. As a woody plant material (A2-1), [P-200 (product number)] manufactured by Riken Chemical Technology Systems Co., Ltd. was used.
[P-100]係將以下的菊科植物的乾燥粉碎物與薔薇科植物的乾燥粉碎物以1:1(重量比)進行混合所獲得之草木植物原料,[P-200]為以下所記載的木本植物原料。 [P-100] is a plant material obtained by mixing the dried ground material of the following Compositae plants with the dried ground material of the Rosaceae plant at a ratio of 1:1 (weight ratio), [P-200] is described below. Woody plant material.
(A1)草木植物原料(草木植物的乾燥物) (A1) Raw material of grass plants (dried plants)
(A1-1)菊科植物的乾燥粉碎物 (A1-1) Dry pulverized material of Compositae
將大薊(葉部、莖部及花部)、苦艾(葉部及莖部)、山菊(葉部及莖部)以分別成為10重量%、60重量%、30重量%的比例進行混合、乾燥後再粉碎之乾燥粉碎物。 The cockroach (leaf, stem, and flower), wormwood (leaf and stem), and gerbera (leaf and stem) were each 10% by weight, 60% by weight, and 30% by weight, respectively. The dried pulverized material is mixed, dried, and pulverized.
(A1-2)薔薇科植物的乾燥粉碎物 (A1-2) Dry pulverized material of Rosaceae plants
使用將野薔薇(葉部、花部)、水楊梅(葉部及莖部)、木莓(葉部、莖部及花部)以分別成為20重量%、10重量%、70重量%的比例進行混合、乾燥後再粉碎之乾燥粉碎物。 The ratio of 20% by weight, 10% by weight, and 70% by weight of wild rose (leaf, flower), bayberry (leaf and stem), and raspberry (leaf, stem, and flower) was used. The dried pulverized material is mixed, dried, and pulverized.
(A2)木本植物原料(木本植物的乾燥物) (A2) Woody plant material (dried woody plant)
將楓樹(葉部及莖部)、白樺樹(葉部、莖部、及樹皮部)、杉樹(葉部、莖部、及樹皮部)以分別成為25重量%、25重量%、50重量%的比例進行混合、乾燥後再粉碎之乾燥粉碎物。 Maple (leaf and stem), birch (leaf, stem, and bark), cedar (leaf, stem, and bark) are 25% by weight, 25% by weight, and 50, respectively. The dry pulverized material is mixed, dried, and pulverized in a ratio of % by weight.
以對水形成為10~15重量%的方式,將以1:3(重量比)混合前述草木植物原料(A1)與木本植物原料(A2) 所形成的礦物質賦予材(A)置入到如圖7所示的含礦物質水(A)製造裝置2中的原料礦物質水溶液製造手段10(參照圖8)中,再將直流電流(DC8300V、100mA)導通於原料礦物質水溶液製造手段10的導電線,使導電線周圍的水產生與直流電流相同方向的水流,然後對前述水賦予超音波振動(振盪頻率50kHz、振幅1.5/1000mm),形成原料礦物質水溶液(A)。接著,藉由被供給到後段的遠紅外線產生手段43之原料礦物質水溶液(A)照射遠紅外線(波長6~14μm),獲得實施例1的含礦物質水(A)。 The grass plant material (A1) and the woody plant material (A2) are mixed at a ratio of 1:3 (by weight) in a manner of 10 to 15% by weight of water. The formed mineral-imparting material (A) is placed in the raw material mineral aqueous solution manufacturing means 10 (refer to FIG. 8) in the mineral-containing water (A) manufacturing apparatus 2 shown in FIG. 7, and the direct current is further applied ( DC8300V, 100 mA) is conducted to the conductive wire of the raw material mineral aqueous solution manufacturing means 10, so that the water around the conductive wire generates a water flow in the same direction as the direct current, and then imparts ultrasonic vibration to the water (oscillation frequency: 50 kHz, amplitude: 1.5/1000 mm) Forming a raw material mineral aqueous solution (A). Then, the mineral-containing water (A) of Example 1 is irradiated with far-infrared rays (wavelength: 6 to 14 μm) by the raw material mineral aqueous solution (A) supplied to the far-infrared generation means 43 of the subsequent stage, thereby obtaining the mineral-containing water (A) of the first embodiment.
2.含礦物質水(B)的製造 2. Manufacture of mineral-containing water (B)
作為礦物質賦予材(B)的原料,使用將石灰石、珊瑚化石、貝殼、活性碳予以粉碎並混合之混合物。礦物質賦予材(B)的原料及在第1~6通水容器所使用的混合物(礦物質賦予材(B1)~(B6))如下述。 As a raw material of the mineral-imparting material (B), a mixture in which limestone, coral fossil, shell, and activated carbon are pulverized and mixed is used. The raw material of the mineral-imparting material (B) and the mixture (mineral-imparting materials (B1) to (B6)) used in the first to sixth water-passing containers are as follows.
(1)原料 (1) Raw materials
(1-1)石灰石:理研化工技術系統株式會社製[CC-200(產品編號)] (1-1) Limestone: manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-200 (Product No.)]
將混合存在有含有下述成分的火山沉積物之石灰岩粉碎形成的3cm左右的卵石狀物 About 3 cm of pebbles formed by pulverizing limestone in which volcanic sediments containing the following components are mixed
碳酸鈣:50重量%以上 Calcium carbonate: 50% by weight or more
氧化鐵:3~9重量%的鐵 Iron oxide: 3~9 wt% iron
氧化鈦、碳化鈦、氮化鈦的總合:0.8重量%以 上 The total of titanium oxide, titanium carbide, titanium nitride: 0.8% by weight on
碳酸鎂:7~10重量%。 Magnesium carbonate: 7 to 10% by weight.
(1-2)珊瑚化石:理研化工技術系統株式會社製[CC-300(產品編號)] (1-2) Coral fossil: manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-300 (Product No.)]
將以下2種的珊瑚化石以1:9的重量比混合再粉碎成3~5mm所形成之粒狀物 The following two kinds of coral fossils are mixed in a weight ratio of 1:9 and pulverized into granules formed by 3 to 5 mm.
從地底下約100公尺生產,藉由重壓使得結晶組成變性之珊瑚化石;從沖繩奄美大島附近的陸地生產的珊瑚化石(含有碳酸鈣、磷酸鈣等的其他微量元素)。 A coral fossil that is produced from a depth of about 100 meters under the ground, which is made into a denatured crystal by heavy pressure; a coral fossil (a trace element containing calcium carbonate, calcium phosphate, etc.) produced from the land near Okinawa Oshima.
(1-3)貝殼:理研化工技術系統株式會社製[CC-400(產品編號)] (1-3) Shell: manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-400 (Product No.)]
鮑魚、九孔、藤壺以相同重量混合再粉碎成3~5mm之粒狀物。 The abalone, the nine holes, and the barnacle are mixed and pulverized into the granules of 3 to 5 mm with the same weight.
(1-4)活性碳(僅第2通水容器使用):理研化工技術系統株式會社製[CC-500(產品編號)] (1-4) Activated carbon (used only in the second water container): manufactured by Riken Chemical Technology Systems Co., Ltd. [CC-500 (product number)]
(2)在第1~6通水容器的使用比例 (2) Proportion of use in the first to sixth water containers
第1通水容器: The first water container:
礦物質賦予材(B1):分別含有70重量%的石灰石、15重量%的珊瑚化石、15重量%的貝殼之混合物; Mineral imparting material (B1): a mixture containing 70% by weight of limestone, 15% by weight of coral fossil, and 15% by weight of shells, respectively;
第2通水容器: 2nd water container:
礦物質賦予材(B2):分別含有40重量%的石灰石、15重量%的珊瑚化石、40重量%的貝殼、5重量%的活性碳之混合物(相當於二氧化矽與活性炭); Mineral material-imparting material (B2): a mixture of 40% by weight of limestone, 15% by weight of coral fossil, 40% by weight of shells, and 5% by weight of activated carbon (corresponding to cerium oxide and activated carbon);
第3通水容器: 3rd water container:
礦物質賦予材(B3):分別含有80重量%的石灰石、15重量%的珊瑚化石、5重量%的貝殼之混合物; Mineral imparting material (B3): a mixture containing 80% by weight of limestone, 15% by weight of coral fossil, and 5% by weight of shells, respectively;
第4通水容器: 4th water container:
礦物質賦予材(B4):分別含有90重量%的石灰石、5重量%的珊瑚化石、5重量%的貝殼之混合物; Mineral imparting material (B4): a mixture containing 90% by weight of limestone, 5% by weight of coral fossil, and 5% by weight of shells, respectively;
第5通水容器: 5th water container:
礦物質賦予材(B5):分別含有80重量%的石灰石、10重量%的珊瑚化石、10重量%的貝殼之混合物; Mineral imparting material (B5): a mixture containing 80% by weight of limestone, 10% by weight of coral fossil, and 10% by weight of shells, respectively;
第6通水容器: The sixth water container:
礦物質賦予材(B6):分別含有60重量%的石灰石、30重量%的珊瑚化石、10重量%的貝殼之混合物;在圖7結構的礦物質機能水製造設備1,藉由使水流通於使用前述礦物質賦予材(B1)~(B6)的第1~6通水容器,獲得含礦物質水(B)。以(B1)~(B6)分別為50kg(總合300kg)、流通的水量為1000kg、流速為500mL/40s進行設定。 Mineral material-imparting material (B6): a mixture containing 60% by weight of limestone, 30% by weight of coral fossil, and 10% by weight of shells, respectively; and the mineral-functional water producing apparatus 1 structured as shown in Fig. 7 by circulating water The mineral water (B) is obtained by using the first to sixth water-passing containers of the mineral-imparting materials (B1) to (B6). (B1) to (B6) were set to 50 kg (total 300 kg), the amount of water flowing was 1000 kg, and the flow rate was 500 mL/40 s.
將在前述方法所實施的實施例1之含礦物質水(A)與含礦物質水(B)以形成為1:10(重量比)的方式進行混合,獲得實施例1的礦物質機能水。以pH測量器(東興化學研究所製玻璃電極式氫離子濃度指示計TPX-90) 測量實施例1的礦物質機能水,其為pH12.5。 The mineral-containing water (A) of Example 1 and the mineral-containing water (B) which were carried out in the above method were mixed to form a 1:10 (weight ratio) to obtain the mineral functional water of Example 1. . Using a pH measuring device (Glass Electrode Hydrogen Concentration Indicator TPX-90 made by Dongxing Chemical Research Institute) The mineral functional water of Example 1 was measured, which was pH 12.5.
再者,實施例1的礦物質機能水,是相當於理研化工技術系統株式會社製的礦物質機能水CAC-717[Tera Protect(商品名),CAC-717(產品編號),開發產品編號CA-C-01]。 In addition, the mineral functional water of the first embodiment is equivalent to the mineral functional water CAC-717 manufactured by Riken Chemical Technology Co., Ltd. [Tera Protect (product name), CAC-717 (product number), development product number CA -C-01].
<2-1>水泥硬化體(溶析型陶瓷材料)的製造 <2-1>Manufacture of hardened cement (solubility ceramic material)
將實施例1的礦物質機能水20重量部、與作為水泥組成物之白水泥(太平洋水泥製):50重量部、矽石粉末(SiO2)15重量部、石灰石(含有50重量%的CaCO3之堆積岩)15重量部以攪拌機進行拌合,獲得水泥拌合物。將所獲得的水泥拌合物進行養護3天並予以固化,獲得實施例1的水泥硬化體(實施例1的溶析型陶瓷材料)。 20 parts by weight of the mineral functional water of the first embodiment, white cement (made of Pacific cement) as a cement composition: 50 parts by weight, vermiculite powder (SiO 2 ) 15 parts by weight, limestone (containing 50% by weight of CaCO) 3 of sedimentary rocks) to 15 wt mixer unit for mixing to obtain a cement mixing material. The obtained cement mixture was cured for 3 days and cured to obtain a cement hardened body of Example 1 (the eluted ceramic material of Example 1).
<2-2>陶瓷燒結體(非溶析型陶瓷材料)的製造 <2-2> Manufacture of ceramic sintered body (non-lead-type ceramic material)
對載體用的陶瓷粉末(天草大矢野島產的岩石粉末)100重量部,添加預定量的水,獲得黏土狀混合物。將所獲得的黏土狀混合物成形為厚度5mm左右、直徑2cm之圓形表面平坦的板狀,在500℃下燒成8小時,獲得多孔質鍛燒體。 A predetermined amount of water was added to 100 parts by weight of the ceramic powder for carrier (the rock powder of Amakusa Oyao Island) to obtain a clay-like mixture. The obtained clay-like mixture was formed into a flat plate shape having a circular surface having a thickness of about 5 mm and a diameter of 2 cm, and baked at 500 ° C for 8 hours to obtain a porous calcined body.
接著,對多孔質鍛燒體100重量部,均等地浸透實施例1的礦物質機能水15重量部,再予以乾燥數日。進行賦予相當於5重量部之釉藥的施釉處理,接著,藉由在1200℃下進行熱處理(真燒成),獲得固定化有含於礦物質 機能水的礦物質成分之實施例1的陶瓷燒結體(實施例1的非溶析型陶瓷材料)。 Next, the weight portion of the porous calcined body 100 was uniformly impregnated with 15 parts by weight of the mineral functional water of Example 1, and dried for several days. The glazing treatment for imparting a glaze equivalent to 5 parts by weight is carried out, followed by heat treatment (true firing) at 1200 ° C to obtain immobilized minerals. The ceramic sintered body of Example 1 of the functional component of the functional water (non-lead-type ceramic material of Example 1).
又,作為對照試料,製作對多孔質煅燒體不含礦物質機能水而進行了熱處理之陶瓷燒結體。 Further, as a control sample, a ceramic sintered body in which the porous calcined body was not subjected to mineral functional water and heat-treated was produced.
試料(陶瓷燒結體)的分光放射率是以遠紅外線輻射率測定裝置(日本電子(股)製JIR-E500)進行測定。該裝置是由傅立葉變換型紅外線分光光度計(FTIR)本體、黑體爐、試料加熱爐、溫度控制器及附屬光學系統所構成。 The spectral emissivity of the sample (ceramic sintered body) was measured by a far-infrared emissivity measuring device (JIR-E500 manufactured by JEOL Ltd.). The device is composed of a Fourier transform infrared spectrophotometer (FTIR) body, a black body furnace, a sample heating furnace, a temperature controller, and an attached optical system.
圖18係顯示實施例1的陶瓷燒結體、及未固化有礦物質成分的陶瓷燒結體(對照試料)在25℃時對黑體之放射比率的評價結果,相當於當將黑體的放射強度設為100%的情況時之各自的陶瓷燒結體之放射強度的比率(放射比率)。 18 is a graph showing the results of evaluation of the ratio of the emission ratio of the ceramic sintered body of Example 1 and the ceramic sintered body of the uncured mineral component (control sample) to the black body at 25 ° C, which corresponds to when the radiation intensity of the black body is set to The ratio of the radiation intensity (radiation ratio) of each ceramic sintered body in the case of 100%.
確認到比起未含有礦物質之對照試料,含有礦物質成分的實施例1之陶瓷燒結體在所測定到的波長範圍,放射比率高,顯著地產生電磁波放射作用。 It was confirmed that the ceramic sintered body of Example 1 containing the mineral component had a high emission ratio in the measured wavelength range and significantly generated electromagnetic wave radiation, compared to the control sample containing no mineral.
<3>溶析機能水的評價 <3> Evaluation of dissolving functional water
<3-1 溶析試驗> <3-1 Solvent Test>
在溶析機能水製造裝置100中的第一處理槽110收容實施例1的水泥硬化體(溶析型陶瓷材料),在第二處理槽150收容實施例1的陶瓷燒結體(非溶析型陶瓷材料),從第一處理槽110的供水管117使作為萃取溶劑之水流通。要收容的水泥硬化體、陶瓷燒結體及要流通的水之量是以 使自第一處理槽110排出的溶析機能水W1形成為pH10.5~11.5、從第二處理槽150排出的溶析機能水W2形成為pH12以上的方式進行調整。以下將所獲得的溶析機能水W2記載為實施例1的溶析機能水。 In the first treatment tank 110 of the elution functional water production apparatus 100, the cement hardened body (the eluted ceramic material) of the first embodiment is housed, and the ceramic sintered body of the first embodiment is housed in the second treatment tank 150 (non-lytic type) The ceramic material circulates water as an extraction solvent from the water supply pipe 117 of the first treatment tank 110. The amount of cement hardened body, ceramic sintered body and water to be circulated to be contained is The elution functional water W1 discharged from the first treatment tank 110 is adjusted to have a pH of 10.5 to 11.5, and the elution functional water W2 discharged from the second treatment tank 150 is formed to have a pH of 12 or more. The obtained elution functional water W2 is described below as the elution functional water of Example 1.
將實施例1的溶析機能水進行成分分析,確認到鈣離子、矽離子、鈉離子等的礦物性無機系礦物質成分及植物性有機成分(聚酚)溶析出來。 The component analysis of the solute functional water of Example 1 revealed that the mineral inorganic mineral component such as calcium ion, strontium ion, or sodium ion and the plant organic component (polyphenol) were eluted.
<3-2.病毒不活性化試驗> <3-2. Virus inactivation test>
使用實施例1的溶析機能水,對以下的病毒進行不活性化試驗。 The following virus was subjected to an inactivation test using the leaching functional water of Example 1.
‧腺病毒5型(Human Adenovirus 5,ATCC VR-5) ‧Adenovirus 5 (ATCC VR-5)
‧單純皰疹病毒1型(Human Herpes Simplex Virus 1,ATCC VR-539) ‧ Herpes simplex virus 1 (ATCC VR-539)
‧貓杯狀病毒(Feline calicivirus,ATCC VR-782):諾羅病毒代替 ‧Feline calicivirus (ATCC VR-782): Norovirus instead
‧A型流感病毒(Influenza A virus,H1N1,ATCC VR-1469) ‧ Influenza A virus (Influenza A virus, H1N1, ATCC VR-1469)
作為對照例,使用以下液體。 As a comparative example, the following liquids were used.
對照例1:次氯酸鈉液 Comparative Example 1: sodium hypochlorite solution
對照例2:磷酸鹽緩衝鹽水(Phosphate buffered saline、PBS)。 Comparative Example 2: Phosphate buffered saline (PBS).
病毒不活性化試驗以下述的方式進行。 The virus inactivation test was carried out in the following manner.
(1)對實施例1的溶析機能水(或對照例1、2)100容量 (10mL)混入病毒液1容量(0.1mL)。在不使用試驗管攪拌器下進行平穩攪拌,在15秒期間使其作用於病毒。 (1) The capacity of the solvent functional water (or Comparative Examples 1, 2) of Example 1 (10 mL) was mixed with a virus solution 1 volume (0.1 mL). Stirring was carried out without using a test tube stirrer and allowed to act on the virus during 15 seconds.
(2)接著,以添加有0.1%的硫代硫酸鈉之SCDLP稀釋成10倍,停止試驗水對病毒之作用。 (2) Next, the effect of the test water on the virus was stopped by diluting it to 10-fold with SCDLP supplemented with 0.1% sodium thiosulfate.
(3)將(2)的液體作為感染效價測定用試料的原液,測定病毒感染效價。 (3) The liquid of (2) was used as a stock solution for the sample for measuring the titer of infection titer, and the viral infection titer was measured.
以下顯示腺病毒5型(表1)、單純皰疹病毒1型(表2)、貓杯狀病毒(表3)、A型流感病毒(表4)之不活性化試驗的結果。感染效價的單位為TCID50/mL、檢測界限值為1.3×101TCID50/mL、對數減少值為log10(初期感染效價/作用15秒後的感染效價)。 The results of the inactivation test of adenovirus type 5 (Table 1), herpes simplex virus type 1 (Table 2), feline calicivirus (Table 3), and influenza A virus (Table 4) are shown below. The unit of infection titer was TCID 50 /mL, the detection limit was 1.3 × 10 1 TCID 50 /mL, and the log reduction value was log 10 (initial infection titer / infection titer after 15 seconds of action).
在實施例1的溶析機能水,確認到在各別的病毒,對PBS產生優良的病毒不活性化,其效果可匹敵次氯酸鈉液。 In the leaching machine water of Example 1, it was confirmed that the virus was inactivated by PBS in each virus, and the effect was comparable to that of sodium hypochlorite.
[產業上的利用可能性] [Industry use possibility]
藉由本發明的溶析機能水製造裝置所生產的溶析機能水,由於具有來自於所含有的礦物質成分之有效效能,因此,能夠廣泛地利用於各種產業。 The leaching machine water produced by the lysate water-making apparatus of the present invention can be widely used in various industries because it has an effective performance derived from the mineral components contained therein.
100‧‧‧溶析機能水製造裝置(雙處理槽) 100‧‧‧Soliding machine water manufacturing device (double treatment tank)
110‧‧‧第一處理槽 110‧‧‧First treatment tank
111、151‧‧‧外殼 111, 151‧‧‧ shell
111a,111b,151a,151b‧‧‧凸緣 111a, 111b, 151a, 151b‧‧‧Flange
112,152‧‧‧入水路徑 112, 152‧‧‧ water path
113,153‧‧‧出水路徑 113,153‧‧‧Water path
114‧‧‧注水路徑 114‧‧‧Water injection path
115,116,155,156‧‧‧蓋體 115,116,155,156‧‧‧ cover
117‧‧‧供水管 117‧‧‧Water supply pipe
119‧‧‧排水路徑 119‧‧‧Drainage path
125‧‧‧支柱 125‧‧‧ pillar
150‧‧‧第二處理槽 150‧‧‧Second treatment tank
154a‧‧‧操作桿 154a‧‧‧Operation lever
154b‧‧‧開閉閥 154b‧‧‧Opening valve
157‧‧‧腳輪 157‧‧‧ casters
158‧‧‧連結路徑 158‧‧‧Link path
159‧‧‧出水管 159‧‧‧Outlet
G‧‧‧地面 G‧‧‧ Ground
P‧‧‧襯墊 P‧‧‧ cushion
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