TW201639648A - Method for producing an EUV module, EUV module and EUV lithography system - Google Patents
Method for producing an EUV module, EUV module and EUV lithography system Download PDFInfo
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Abstract
Description
本發明係關於一種製造用於EUV微影系統之EUV模組的方法、一種EUV模組以及一種EUV微影系統。 The present invention relates to a method of manufacturing an EUV module for an EUV lithography system, an EUV module, and an EUV lithography system.
在該等方法之中,用於製造半導體元件的是光微影成像(photolithographic)法,其中待生成的結構圖案借助於圖罩(倍縮光罩)以縮小比例投影到塗佈有光敏層的功能層上,然後在顯影該感光層後,藉助蝕刻製程轉移到該功能層中。製造日益精細結構使得微影製程有必要使用波長越來越短的光線。因此,現有的微影方法與電磁輻射共同作用進入極紫外光(Extremely ultraviolet light,EUV)範圍內。該用語EUV輻射用於指稱波長介於30nm(奈米)與5nm之間、特別是13.5nm的電磁輻射。EUV輻射通常是由電漿源所產生或作為同步加速器輻射。由於EUV輻射可被大多數已知材料高度吸收,因此EUV微影中的投影曝光系統一般使用反射性組件。為此目的使用專門設計的反射鏡系統,其以合適方式將輻射引導到該倍縮光罩上,隨後投影到該半導體晶圓所需區域上。該已知EUV微影系統同時 與擇一具有結構化吸收層設置於其上的反射性載體層形式或具有結構化反射層設置於其上的吸收性載體層形式的反射性倍縮光罩一起操作。 Among these methods, a semiconductor photolithographic method is used for fabricating a semiconductor element, wherein the structural pattern to be formed is projected to a photosensitive layer by a reduction ratio by means of a mask (doubler mask). The functional layer is then transferred to the functional layer by an etching process after developing the photosensitive layer. The manufacture of increasingly fine structures makes it necessary to use light with shorter and shorter wavelengths for lithography processes. Therefore, the existing lithography method interacts with electromagnetic radiation into the range of Extremely Ultraviolet Light (EUV). The term EUV radiation is used to refer to electromagnetic radiation having a wavelength between 30 nm (nano) and 5 nm, in particular 13.5 nm. EUV radiation is typically generated by a plasma source or as a synchrotron. Because EUV radiation is highly absorbed by most known materials, projection exposure systems in EUV lithography typically use reflective components. A specially designed mirror system is used for this purpose, which directs the radiation onto the reticle in a suitable manner and then onto the desired area of the semiconductor wafer. The known EUV lithography system simultaneously The reflective refracting reticle in the form of a reflective carrier layer having a structured absorbent layer disposed thereon or in the form of an absorbent carrier layer having a structured reflective layer disposed thereon is operated.
將該微影微米或奈米結構成像到該晶圓表面上時,通常不是所曝光的整個晶圓,而是只有狹窄區域。一般來說,該等晶圓表面是一塊一塊或透過狹縫曝光。這涉及該晶圓和該倍縮光罩兩者按步驟進行掃描及相對於彼此平行或反向平行移動。 When the lithographic micro- or nano-structure is imaged onto the surface of the wafer, it is typically not the entire wafer being exposed, but only a narrow area. Generally, the wafer surfaces are exposed one by one or through a slit. This involves both the wafer and the reticle being scanned in steps and moving parallel or anti-parallel relative to each other.
用於EUV微影系統之投影光學單元的組件是由現代技術陶瓷所製成,例如碳化矽(Silicon carbide,SiC)或矽滲透碳化矽(Silicon-infiltrated silicon carbide,Si:SiC),且特別是適用於接收感應器。這些材料結合許多正面技術特性:勁度佳(提供具優勢振動特性)、導熱性很好、熱膨脹性低(在負載下產生極佳幾何穩定性)、及重量輕。該等結構元件是從燒結坯體所製造,藉由後續在1600℃範圍內的高溫下鍛燒而加固。由此所產生的該等陶瓷組件相對較閉孔且具有高密度。儘管如此,這些陶瓷組件在EUV系統中不能在該未經處理狀態下使用。其中一個原因在於,即使後續經研磨或噴砂的表面有時仍只有低強度,並可能在該EUV微影系統中導致微粒污染之情況。而且,在大型陶瓷組件上經常有淺層細孔和裂縫。再者,在該等陶瓷組件之該等表面上的游離、未完全反應的矽污染物,可能被存在於該EUV微影系統中的該等氫自由基(由藉由該EUV輻射而分裂的H2分子所生成)分解,並沉積在該EUV微影系統中該等光學元件之該等表面上;如此會導致非所要之傳輸損耗。而且,該等未經處理陶瓷組件之 該等表面一般來說都非常粗糙,這使其明顯更難以真空相容方式進行清潔。關於以上所提及未經處理陶瓷組件之該等問題特性,也請參見圖1。圖1顯示在基板100之體積中具有非關鍵細孔102且在基板表面101上具有關鍵部分磨掉細孔104的陶瓷基板100。而且,在基板表面101上可看到淺層裂縫106和游離矽108。特別關鍵的是在基板表面101附近的弱鍵結區110,因為其可能變得分離且如同游離移動微粒可能妨害該EUV微影系統之功能。該等前述未經處理陶瓷組件之問題特性是由該製程所造成且不可避免。如此需要該等陶瓷組件之表面塗層,其鍵結鬆散微粒、保護從該等氫自由基出現的矽元素、封閉裂縫和細孔,並將該表面粗糙度降低至可能進行清潔程序而無任何問題的程度。如從先前技術已習知,在圖2中所顯示,為此對磨光陶瓷組件100之表面101塗佈鎳磷合金(Nickel-phosphorus alloys,NiP)之金屬塗層112。該塗佈舉例來說藉由電鍍沉積或化學處理(化學鎳)而進行。NiP層112之錨定純機械性發生,其中互鎖銜接藉由該等表面粗糙度而形成。互鎖連接藉助彼此銜接的至少兩個連接夥伴生成。因此,該等連接夥伴即使在無力傳遞或該力傳遞中斷時也不能散開。 The components of the projection optical unit for the EUV lithography system are made of modern technical ceramics, such as Silicon Carbide (SiC) or Silicon-infiltrated silicon carbide (Si: SiC), and in particular Suitable for receiving sensors. These materials combine many positive technical characteristics: good stiffness (providing superior vibration characteristics), good thermal conductivity, low thermal expansion (excellent geometric stability under load), and light weight. The structural elements are fabricated from a sintered body and are reinforced by subsequent calcination at a high temperature in the range of 1600 °C. The ceramic components thus produced are relatively closed and have a high density. Nonetheless, these ceramic components cannot be used in this untreated state in an EUV system. One reason for this is that even subsequent abrasive or sandblasted surfaces sometimes have only low strength and may cause particulate contamination in the EUV lithography system. Moreover, there are often shallow pores and cracks in large ceramic components. Furthermore, free, incompletely reacted antimony contaminants on the surfaces of the ceramic components may be present in the EUV lithography system by the hydrogen radicals (divided by the EUV radiation) The H 2 molecules are generated and decomposed and deposited on the surfaces of the optical components in the EUV lithography system; this can result in undesirable transmission losses. Moreover, the surfaces of the untreated ceramic components are generally very rough, which makes them significantly more difficult to clean in a vacuum compatible manner. See also Figure 1 for these problematic characteristics of the untreated ceramic components mentioned above. 1 shows a ceramic substrate 100 having non-critical pores 102 in the volume of the substrate 100 and having key portions on the substrate surface 101 to sharpen the pores 104. Moreover, shallow cracks 106 and free crucibles 108 are visible on the substrate surface 101. Of particular importance is the weak bond zone 110 near the substrate surface 101 as it may become separate and as free moving particles may interfere with the function of the EUV lithography system. The problematic characteristics of the aforementioned untreated ceramic components are caused by the process and are unavoidable. There is a need for a surface coating of such ceramic components that bonds loose particles, protects the ruthenium elements from the hydrogen radicals, seals cracks and pores, and reduces the surface roughness to possible cleaning procedures without any The extent of the problem. As is known from the prior art, as shown in Fig. 2, the surface 101 of the polished ceramic component 100 is coated with a metal coating 112 of nickel-phosphorus alloys (NiP). This coating is carried out, for example, by electroplating or chemical treatment (chemical nickel). The anchoring of the NiP layer 112 occurs purely mechanically, wherein the interlocking engagement is formed by the surface roughness. The interlocking connection is generated by means of at least two connection partners that are connected to each other. Therefore, the connection partners cannot be spread even when the force is transmitted or the force transmission is interrupted.
不過,藉由互鎖銜接而提供的低層鍵結和該陶瓷組件之不完善周圍區域,限制可經由NiP層112傳遞到陶瓷組件100中的該等力,以及例如可能隨著黏劑鍵結或隨著焊接或銅焊而發生的該等可容許溫度梯度。因此,NiP之膨脹係數與Si:SiC相當不同。如此結果為電鍍或化學所塗佈之陶瓷組件不能藉助黏劑鍵結或焊接接合以形成用於夾持感應器的較大型次組合件和附件(也習知為夾持組件),僅能不夠牢固地附接到塗佈有NiP的陶瓷組件。為從陶瓷組件形成較大型次組合件,藉由黏劑鍵結或焊接 而接合之許多組件因此必須在該未經塗佈狀態下進行,亦即無該NiP層。只有在接合後該等完全接合式陶瓷次組合件整體才塗佈有該NiP合金。不過,這引起由於該接合結果而由非均質材料組成的陶瓷次組合件不能再採用具有足夠品質之NiP合金進行塗佈的問題。舉例來說,電鍍沉積在黏劑鍵結上的NiP層不能充分附著,且該等黏劑被該塗佈損傷。 However, the low layer bonding provided by the interlocking engagement and the imperfect surrounding area of the ceramic component limit such forces that may be transferred into the ceramic component 100 via the NiP layer 112, and may, for example, be bonded with an adhesive or These allowable temperature gradients occur with soldering or brazing. Therefore, the expansion coefficient of NiP is quite different from that of Si:SiC. The result is that the electroplated or chemically coated ceramic components cannot be bonded by adhesive bonding or soldering to form larger subassemblies and accessories for gripping the inductor (also known as clamping assemblies), which are not sufficient Firmly attached to the ceramic component coated with NiP. To form a larger sub-assembly from a ceramic component, by adhesive bonding or soldering Many of the components joined must therefore be carried out in the uncoated state, i.e. without the NiP layer. The fully joined ceramic sub-assemblies are coated with the NiP alloy only after bonding. However, this causes a problem that the ceramic sub-assembly composed of the heterogeneous material can no longer be coated with a NiP alloy of sufficient quality due to the bonding result. For example, the NiP layer deposited by electroplating on the adhesive bond is not sufficiently adhered and the adhesive is damaged by the coating.
用於將陶瓷部件彼此連接的金屬焊料之前已說明許多次。針對藉由焊接個別零件而製造複雜陶瓷部件的一系列提議已變得習知。舉例來說,依據DE 19734211 A1,待連接的該等陶瓷部件首先進行金屬化,然後焊接。該用語金屬化係用於熱處理,以及從而固化、金屬焊料在該等陶瓷部件之該等表面上。不過,該金屬化在這種情況下只會在待彼此焊接的該等陶瓷部件上的該等位置處發生。不會發生藉由該金屬焊料而封閉該等陶瓷部件之該等整個表面。 Metal solders for joining ceramic components to each other have been described many times before. A series of proposals for manufacturing complex ceramic components by welding individual parts have become known. For example, according to DE 197 34 211 A1, the ceramic components to be joined are first metallized and then welded. The term metallization is used for heat treatment, and thereby curing, metal solder on the surfaces of the ceramic components. However, this metallization will only occur at such locations on the ceramic components to be welded to each other in this case. The entire surface of the ceramic components is not sealed by the metal solder.
在本申請案中,該用語「EUV子模組」係與該陶瓷組件同義使用,EUV模組係與包含多個陶瓷組件或多個接合式EUV子模組的次組合件同義使用。 In the present application, the term "EUV sub-module" is used synonymously with the ceramic component, and the EUV module is used synonymously with a secondary assembly comprising a plurality of ceramic components or a plurality of bonded EUV sub-modules.
鑑於上述該等缺點,接合陶瓷組件以在該絕對必要塗佈前形成次組合件時,該目的為提供使該等陶瓷組件之間可能足夠穩定連接的方法,同時封閉該等接合式陶瓷組件之表面。又一目的為提供具有該等前述正面特性的次組合件。 In view of the above disadvantages, in joining the ceramic component to form a secondary assembly prior to the absolutely necessary coating, the object is to provide a method of making a sufficiently stable connection between the ceramic components while enclosing the bonded ceramic component. surface. A further object is to provide a secondary assembly having the aforementioned positive characteristics.
此目的藉由塗佈適用於EUV微影系統之EUV模組的陶瓷材料之EUV子模組之表面的方法而依據本發明達成。依據本發明的方法具有至少下列步驟:首先,金屬焊料塗佈於該EUV子模組之表面整個表面區 域上方。接著,進行熱處理以在該陶瓷材料與該金屬焊料之間產生材料鍵結。於其中該等連接夥伴藉由原子或分子力而保持在一起的所有連接已習知為材料鍵結連接。它們同時為不可拆解的連接,只能藉由破壞連接之該等手段而隔開。該上述方法具有許多優勢。一方面,該陶瓷EUV子模組之該等鬆散微粒鍵結,且在該陶瓷材料中的裂縫和細孔封閉。再者,該封閉保護游離矽元素避免氫自由基之作用。為確保這種保護,該金屬焊料必須塗佈於該表面整個表面區域上方。依據本發明的方法之主要優勢在於該材料鍵結。只有這種材料鍵結藉由黏劑鍵結或焊接以形成EUV模組而能使EUV子模組穩定接合到EUV子模組。再者,該封閉使該EUV子模組之表面平滑;這使其更容易清潔。 This object is achieved in accordance with the present invention by a method of coating the surface of an EUV sub-module of a ceramic material suitable for use in an EUV module of an EUV lithography system. The method according to the invention has at least the following steps: first, a metal solder is applied over the entire surface area of the surface of the EUV sub-module Above the domain. Next, a heat treatment is performed to create a material bond between the ceramic material and the metal solder. All connections in which the linking partners are held together by atomic or molecular forces are known as material bonding connections. They are also non-removable connections and can only be separated by means of breaking the connection. This method has many advantages. In one aspect, the loose particles of the ceramic EUV sub-module are bonded and the cracks and pores in the ceramic material are closed. Furthermore, the encapsulation protects the free ruthenium element from the action of hydrogen radicals. To ensure this protection, the metal solder must be applied over the entire surface area of the surface. A major advantage of the method according to the invention is the bonding of the material. Only such material bonds can be bonded to the EUV sub-module by adhesive bonding or soldering to form an EUV module. Furthermore, the closure smoothes the surface of the EUV sub-module; this makes it easier to clean.
在一個具體實施例中,該金屬焊料藉由網版印刷、噴塗、浸漬、或延展而塗佈。 In a specific embodiment, the metal solder is applied by screen printing, spraying, dipping, or stretching.
在一個具體實施例中,該熱處理在700℃至1500℃下在真空中進行5分鐘至60分鐘。此溫度範圍和暴露於該熱能之時間特別具優勢,因為由此在該金屬焊料層與該陶瓷基板之間產生特別穩定的材料鍵結連接。 In a specific embodiment, the heat treatment is carried out in a vacuum at 700 ° C to 1500 ° C for 5 minutes to 60 minutes. This temperature range and the time of exposure to this thermal energy are particularly advantageous because a particularly stable material bond connection is thus produced between the metal solder layer and the ceramic substrate.
在一個具體實施例中,反應性金屬焊料塗佈作為該金屬焊料,特別是具有鈦(Ti)、錳(Mn)、鋯(Zr)、及/或鉿(Hf)之添加物的銀銅共熔物。該熱處理在這種情況下在700℃至900℃下進行較佳為5分鐘至10分鐘。該熱處理前可能先在100℃至120℃下進行乾燥階段5分鐘至10分鐘。依該金屬化寬度而定,這種材料鍵結連接之強度最大可達50MPa(兆帕)。 In a specific embodiment, the reactive metal solder is coated as the metal solder, in particular silver and copper having an additive of titanium (Ti), manganese (Mn), zirconium (Zr), and/or hafnium (Hf). Melt. The heat treatment is carried out in this case at 700 ° C to 900 ° C, preferably for 5 minutes to 10 minutes. The drying step may be carried out at 100 ° C to 120 ° C for 5 minutes to 10 minutes before the heat treatment. Depending on the metallization width, the bonding strength of such materials can be up to 50 MPa (megapascals).
在替代性具體實施例中,非反應性金屬焊料、特別是鎢焊膏 塗佈作為該金屬焊料。該熱處理在1000℃至1500℃下進行較佳為30分鐘至60分鐘。該高溫為必要,因為無化學反應發生,而是該等鎢原子必須擴散進入該陶瓷基板,且該基板之該等原子必須擴散進入該鎢焊料之微結構。該熱處理前可能先在100℃下進行乾燥階段10分鐘至15分鐘。 In an alternative embodiment, a non-reactive metal solder, particularly a tungsten solder paste Coating as the metal solder. The heat treatment is carried out at 1000 ° C to 1500 ° C, preferably for 30 minutes to 60 minutes. This high temperature is necessary because no chemical reactions occur, but the tungsten atoms must diffuse into the ceramic substrate, and the atoms of the substrate must diffuse into the microstructure of the tungsten solder. The drying step may be carried out at 100 ° C for 10 minutes to 15 minutes before the heat treatment.
在一個具體實施例中,EUV子模組整個表面區域上方塗佈有該金屬焊料之表面後續至少在某些區域中採用鎳(Ni)塗佈。在該鎳與該金屬化表面之間產生穩定的金屬鍵結。這一方面也提高該表面對氫和氫自由基之抵抗。另一方面,該鎳層改善具有該焊料的該金屬化表面之潤濕性。該等鎳所塗佈之區域也允許藉助黏劑鍵結及焊接穩定的接合。 In a specific embodiment, the surface of the EUV sub-module coated with the metal solder over the entire surface area is subsequently coated with nickel (Ni) at least in certain regions. A stable metal bond is created between the nickel and the metallized surface. This aspect also increases the resistance of the surface to hydrogen and hydrogen radicals. On the other hand, the nickel layer improves the wettability of the metallized surface of the solder. The areas to which the nickel is applied also allow for stable bonding by means of adhesive bonding and soldering.
在一個具體實施例中,該後續採用鎳的塗佈藉由物理氣相沉積(physical vapour deposition,PVD)或藉由化學氣相沉積(chemical vapour deposition,CVD)以電鍍製程進行。此外,鎳也特別適合後續塗佈,因為可非常良好地以恆定層厚度塗佈。或者或此外,該EUV子模組之完全金屬化表面後續也可以銅或金塗佈在某些區域。 In a specific embodiment, the subsequent coating using nickel is performed by an electroplating process by physical vapor deposition (PVD) or by chemical vapor deposition (CVD). Furthermore, nickel is also particularly suitable for subsequent coating since it can be coated very well with a constant layer thickness. Alternatively or in addition, the fully metallized surface of the EUV sub-module may subsequently be coated with copper or gold in certain areas.
開頭所提及之目的也藉由從EUV子模組產生EUV模組的方法而依據本發明達成。首先,提供依據本發明所塗佈之至少兩個EUV子模組。接著,所提供的該等EUV子模組接合。將相對較小且輕量的EUV子模組接合以形成相對較大且重的EUV模組基於幾個原因具優勢。在用於該等EUV子模組的該等陶瓷基板之製造中,一定數量之不良品不可避免。若EUV模組直接製造為單塊組件,則可能省略EUV子模組之間的接合製程。不過,若該大型單塊EUV模組由於製造缺陷而必須廢棄,則成本會比若必須丟棄只有小型缺陷的EUV子模組更高許多。 The objects mentioned at the outset are also achieved in accordance with the present invention by a method of generating an EUV module from an EUV sub-module. First, at least two EUV sub-modules coated in accordance with the present invention are provided. The EUV sub-modules provided are then joined. Joining relatively small and lightweight EUV sub-modules to form relatively large and heavy EUV modules has several advantages. In the manufacture of such ceramic substrates for such EUV sub-modules, a certain number of defective products are unavoidable. If the EUV module is fabricated directly as a single component, the bonding process between the EUV sub-modules may be omitted. However, if the large single EUV module has to be discarded due to manufacturing defects, the cost will be much higher than if the EUV sub-module with only small defects must be discarded.
在一個具體實施例中,所提供的該等EUV子模組藉由焊接而接合,特別是採用硬焊料。硬焊料指稱基於鎳銀或銅的高銀含量之合金,其通常可以條狀、桿狀、線狀、薄膜、及有時膏狀之形式供應。硬焊料膏已含有助焊劑,因此如在其他焊料形式之情況下,與焊膏同樣無需再另外添加。與軟焊料(基於錫/鉛)對比,硬焊料特別適合承受高機械和熱負載的金屬連接。或者或此外,所提供的該等EUV子模組藉由黏劑鍵結而接合,特別是採用陶瓷黏劑。陶瓷黏劑特別具優勢,因為它們在真空中幾乎不會逸出氣體。在陶瓷黏劑(也指稱為陶瓷膠結劑)之情況下,原則上陶瓷粉末是與無機黏合劑體系(例如水玻璃或磷酸鹽化合物)混合。有些黏劑提供為膏狀,其他則在使用前從該粉末和液體成分稍微混合。陶瓷黏劑有兩種群組。第一種,藉由一般為水的溶劑之揮發而物理性鍵結者。這些黏劑具有礦質填料,例如氧化鋁(Al2O3)、氧化鋯(ZrO2)、及氧化鎂(MgO)。第二種,藉由濃縮反應而精確的化學性固化者。 In one embodiment, the EUV sub-modules provided are joined by soldering, particularly with a hard solder. Hard solders refer to alloys based on high silver content of nickel silver or copper, which are typically supplied in the form of strips, rods, wires, films, and sometimes pastes. Hard solder pastes already contain flux, so as in the case of other solder forms, there is no need to add additional solder paste. In contrast to soft solders (based on tin/lead), hard solders are particularly suitable for metal connections that are subject to high mechanical and thermal loads. Alternatively or in addition, the EUV sub-modules provided are joined by adhesive bonding, particularly ceramic adhesives. Ceramic adhesives are particularly advantageous because they hardly escape gas in a vacuum. In the case of ceramic adhesives (also referred to as ceramic cements), in principle the ceramic powder is mixed with an inorganic binder system such as water glass or a phosphate compound. Some of the adhesives are provided as a paste, while others are slightly mixed from the powder and liquid ingredients prior to use. There are two groups of ceramic adhesives. The first type is physically bonded by volatilization of a solvent, typically water. These adhesives have mineral fillers such as alumina (Al 2 O 3 ), zirconia (ZrO 2 ), and magnesium oxide (MgO). Second, precise chemical curing by concentration reaction.
或者,關於該接合可使用有機黏劑,舉例來說採用甲基丙烯酸甲酯(methyl methacrylate,MMA)黏劑或環氧樹脂(epoxy resin)黏劑。 Alternatively, an organic binder may be used for the bonding, for example, a methyl methacrylate (MMA) adhesive or an epoxy resin adhesive.
開頭所提及之目的也藉由在EUV微影系統中所提供的所塗佈之EUV子模組而依據本發明達成。該EUV子模組具有陶瓷本體,其整個表面區域上方覆蓋有金屬焊料。在該陶瓷本體與該金屬焊料之間有材料鍵結。該材料鍵結為絕對必要,以使EUV子模組稍後可能藉助黏劑鍵結或焊接而彼此穩定接合。 The objects mentioned at the outset are also achieved in accordance with the invention by the coated EUV sub-modules provided in the EUV lithography system. The EUV sub-module has a ceramic body covered with metal solder over the entire surface area. There is a material bond between the ceramic body and the metal solder. This material bonding is absolutely necessary so that the EUV sub-modules may later be stably joined to each other by means of adhesive bonding or welding.
在一個具體實施例中,該EUV子模組具有該金屬化、亦即在該固化狀態下之金屬焊料、介於5μm(微米)至300μm之間、較佳為介於 10μm至200μm之間之厚度。此厚度足以用於藉助黏劑鍵結或焊接的接合;其不得低於5μm之下限,否則在該金屬化中有孔洞之風險。避免這些孔洞至關重要,以確保該EUV子模組之完全封閉。該金屬化所必要最小值之厚度,在此依該陶瓷基板之基本粗糙度而定。該基本粗糙度越低,則該金屬化可選擇越薄。該金屬化之顯著厚度關於該封閉之品質通常應視為正面。不過,300μm(含)以上之厚度有在該調護、亦即該熱處理過程中,使該鎢焊膏可延展的鎢焊膏之該等有機成分無法再完全燒盡的風險。如此會降低該陶瓷基板與該金屬化之間該材料鍵結之品質,並對該EUV微影系統引起污染之風險。 In a specific embodiment, the EUV sub-module has the metallization, that is, the metal solder in the cured state, between 5 μm (micrometer) and 300 μm, preferably between A thickness of between 10 μm and 200 μm. This thickness is sufficient for bonding by means of adhesive bonding or soldering; it must not be below the lower limit of 5 μm, otherwise there is a risk of holes in the metallization. Avoiding these holes is critical to ensure complete closure of the EUV sub-module. The thickness of the minimum necessary for the metallization depends on the basic roughness of the ceramic substrate. The lower the basic roughness, the thinner the metallization can be selected. The significant thickness of the metallization should generally be considered positive with respect to the quality of the closure. However, a thickness of 300 μm or more or more may have a risk that the organic components of the tungsten solder paste which can be stretched by the tungsten solder paste cannot be completely burned out during the conditioning, that is, during the heat treatment. This reduces the quality of the bond between the ceramic substrate and the metallization and poses a risk of contamination of the EUV lithography system.
在一個具體實施例中,該陶瓷材料包含氧化鋁(Al2O3)、碳化矽(SiC)、及/或矽滲透碳化矽(Si:SiC)。Si:SiC由於具有具優勢的振動特性、非常良好的導熱性、低熱膨脹、及在負載下極佳的幾何穩定性,因此在微影系統中的EUV子模組中使用特別具優勢。又一優勢在於相較於金屬材料的輕量。 In a specific embodiment, the ceramic material comprises alumina (Al 2 O 3 ), tantalum carbide (SiC), and/or niobium infiltrated niobium carbide (Si: SiC). Si: SiC is particularly advantageous for use in EUV sub-modules in lithography systems due to its superior vibration characteristics, very good thermal conductivity, low thermal expansion, and excellent geometric stability under load. Yet another advantage lies in the light weight compared to metallic materials.
在一個具體實施例中,反應性金屬焊料塗佈於該EUV子模組作為金屬焊料,特別是具有選自包含鈦(Ti)、錳(Mn)、鋯(Zr)、及鉿(Hf)的群組之添加物的銀銅共熔物。 In a specific embodiment, the reactive metal solder is applied to the EUV sub-module as a metal solder, in particular having a titanium oxide (Ti), manganese (Mn), zirconium (Zr), and hafnium (Hf). A silver-copper eutectic of the additive of the group.
在替代性具體實施例中,塗佈非反應性金屬焊料、特別是鎢焊膏於該EUV子模組作為該金屬焊料。 In an alternative embodiment, a non-reactive metal solder, in particular a tungsten solder paste, is applied to the EUV sub-module as the metal solder.
在一個具體實施例中,該EUV子模組至少在某些區域中具有覆蓋該金屬化(亦即在該固化狀態下之金屬焊料)的至少一層特別是鎳、鎳磷合金、銅、或金之又一金屬層。後續採用鎳塗佈之該等優勢如以上所提 及。 In a specific embodiment, the EUV sub-module has at least one layer covering at least some regions of the metallization (ie, the metal solder in the cured state), particularly nickel, nickel-phosphorus alloy, copper, or gold. Another metal layer. The advantages of subsequent nickel coating are as mentioned above. and.
開頭所陳述之目的也藉由具有如上述彼此接合之至少兩個EUV子模組的EUV模組而依據本發明達成。該等EUV子模組以介於5MPa至50MPa之間之拉伸強度彼此接合。各程度拉伸強度所取決於的因素在於接合手段之種類。這種強力鍵結是穩定EUV模組的基本先決條件。 The objects stated at the outset are also achieved in accordance with the present invention by an EUV module having at least two EUV sub-modules joined to each other as described above. The EUV sub-modules are joined to each other with a tensile strength of between 5 MPa and 50 MPa. The factors depending on the degree of tensile strength depend on the type of bonding means. This strong bond is a basic prerequisite for a stable EUV module.
在一個具體實施例中,至少一個夾持組件與該EUV子模組或與該EUV模組接合。該夾持組件可為感應器安裝架。 In a specific embodiment, at least one clamping assembly engages the EUV sub-module or with the EUV module. The clamping assembly can be an inductor mount.
在一個具體實施例中,該夾持組件藉由焊接而接合,特別是採用硬焊料。或者或此外,該夾持組件可能藉由黏劑鍵結而接合,特別是採用陶瓷黏劑及/或有機黏劑。 In a specific embodiment, the clamping assembly is joined by soldering, particularly with a hard solder. Alternatively or in addition, the clamping assembly may be joined by adhesive bonding, particularly with ceramic adhesives and/or organic adhesives.
而且,EUV微影系統依據本發明主張。這具有設計用於承載至少一個感應器,用作測量架構或作為測量標準的至少一個EUV模組。而且,該EUV微影系統具有用於承載至少一個光學組件、特別是反射鏡的至少一個力框架。該光學組件之確切位置可藉助該感應器判定。該力框架通常由鋼構成。除了力框架用語以外,也使用承載框架用語。該等多個EUV模組彼此隔開及解耦。該等EUV模組也從該力框架隔開及解耦。 Moreover, the EUV lithography system is claimed in accordance with the present invention. This has at least one EUV module designed to carry at least one inductor, used as a measurement architecture or as a measurement standard. Moreover, the EUV lithography system has at least one force frame for carrying at least one optical component, in particular a mirror. The exact position of the optical component can be determined by means of the sensor. The force frame is usually made of steel. In addition to the force framework terminology, the framework language is also used. The plurality of EUV modules are spaced apart from each other and decoupled. The EUV modules are also separated and decoupled from the force frame.
100‧‧‧基板 100‧‧‧Substrate
101‧‧‧基板表面 101‧‧‧ substrate surface
102‧‧‧在該基板之體積中的細孔 102‧‧‧Pores in the volume of the substrate
104‧‧‧在基板表面上部分磨掉的細孔 104‧‧‧ Partially worn pores on the surface of the substrate
106‧‧‧淺層裂縫 106‧‧‧Shallow cracks
108‧‧‧游離矽 108‧‧‧Free 矽
110‧‧‧在基板表面上的弱鍵結區 110‧‧‧ Weak bonding area on the surface of the substrate
112‧‧‧鎳磷合金 112‧‧‧Ni-P alloy
114‧‧‧金屬焊料 114‧‧‧Metal solder
115‧‧‧另一金屬層 115‧‧‧ another metal layer
116‧‧‧在該過渡帶之區域中的材料鍵結 116‧‧‧Material bonding in the area of the transition zone
120‧‧‧第一EUV子模組 120‧‧‧First EUV sub-module
130‧‧‧第二EUV子模組 130‧‧‧Second EUV sub-module
140‧‧‧在第一與第二EUV子模組之間的接合區 140‧‧‧Intersection between the first and second EUV sub-modules
150‧‧‧在EUV模組與夾持組件之間的接合區 150‧‧‧Intersection between the EUV module and the clamping assembly
160‧‧‧夾持組件 160‧‧‧Clamping components
170‧‧‧感應器 170‧‧‧ sensor
200‧‧‧EUV模組 200‧‧‧EUV module
204‧‧‧EUV模組和力框架之機械性解耦 204‧‧‧Mechanical decoupling of EUV modules and force frames
300‧‧‧力框架 300‧‧‧ force framework
302‧‧‧光學組件 302‧‧‧Optical components
304‧‧‧力框架和固定周圍環境之機械性解耦 304‧‧‧Mechanical decoupling of force frames and fixed surroundings
400‧‧‧固定周圍環境 400‧‧‧Fixed surroundings
500‧‧‧EUV微影系統 500‧‧‧EUV lithography system
502‧‧‧EUV光源 502‧‧‧EUV light source
504‧‧‧光束塑形與照明系統 504‧‧‧beam shaping and lighting system
506‧‧‧投影系統 506‧‧‧Projection system
510‧‧‧光罩 510‧‧‧Photomask
514‧‧‧晶圓 514‧‧‧ wafer
516‧‧‧EUV輻射 516‧‧‧EUV radiation
520‧‧‧真空殼體 520‧‧‧vacuum housing
610、612、614、616、618‧‧‧在光束塑形與照明系統中的反射鏡 610, 612, 614, 616, 618‧‧‧ mirrors in beam shaping and illumination systems
624‧‧‧投影系統之光軸 624‧‧‧The optical axis of the projection system
636‧‧‧反射鏡 636‧‧‧Mirror
M1、M2、M3、M4、M5‧‧‧在投影系統中的反射鏡 M1, M2, M3, M4, M5‧‧‧ mirrors in projection systems
各種示例性具體實施例以下基於該等圖示更詳細加以解說。相同、同一類型或以同樣方式作用的元件在該等圖示中具備相同參考標記。相對於彼此在該等圖示中所表示該等元件之該等圖示和該等相對大小,不應視為真實比例。而是,個別元件可能為了更好的表示及為了更好 的理解而放大尺寸或縮小尺寸顯示。 Various exemplary embodiments are described in greater detail below based on the figures. Elements that are the same, the same type, or function in the same manner have the same reference numerals in the drawings. The illustrations and relative sizes of the elements shown in the figures are not to be regarded as true. Instead, individual components may be better for better representation and for better The understanding is to enlarge the size or reduce the size display.
圖1顯示在該塗佈前的研磨陶瓷基板。 Figure 1 shows a ground ceramic substrate prior to the coating.
圖2顯示依據先前技術具有塗層的研磨陶瓷基板。 Figure 2 shows a ground ceramic substrate having a coating according to the prior art.
圖3顯示來自依據本發明所塗佈之EUV子模組的切圖。 Figure 3 shows a cutaway view of an EUV sub-module coated in accordance with the present invention.
圖4顯示來自依據本發明所塗佈之替代性EUV子模組的切圖。 Figure 4 shows a cutaway view of an alternative EUV sub-module coated in accordance with the present invention.
圖5以示意形式顯示從依據本發明所塗佈之兩個EUV子模組接合的依據本發明之EUV模組。 Figure 5 shows, in schematic form, an EUV module according to the invention joined from two EUV sub-modules coated in accordance with the present invention.
圖6以示意形式顯示具有接合式夾持組件和感應器之依據本發明的EUV模組。 Figure 6 shows, in schematic form, an EUV module in accordance with the present invention having a bonded clamp assembly and an inductor.
圖7以示意形式顯示來自EUV微影系統之對本發明而言至關重要的切圖。 Figure 7 shows, in schematic form, a cutaway view from the EUV lithography system that is critical to the invention.
圖8以示意形式顯示該EUV微影系統整體。 Figure 8 shows the entire EUV lithography system in schematic form.
圖1顯示在基板100中具有非關鍵細孔102且在基板表面101上具有關鍵部分磨掉細孔104的已習知陶瓷基板100。而且,在基板表面101上可看到淺層裂縫106和游離矽108。顯而易見特別關鍵的是在基板表面101附近的弱鍵結區110,因為其可能變得分離且如同游離移動微粒可能妨害該EUV微影系統之功能。基板100之材料是矽滲透碳化矽(Si:SiC)。圖1所示基板100同時是依據本發明之塗佈法的起始產物(其結果表示在圖3和圖4中),以及依據先前技術之塗佈法的起始產物(其結果表示在圖2中)。 1 shows a conventional ceramic substrate 100 having non-critical pores 102 in a substrate 100 and having key portions on the substrate surface 101 to sharpen the pores 104. Moreover, shallow cracks 106 and free crucibles 108 are visible on the substrate surface 101. It is apparent that particularly critical is the weak bond zone 110 near the substrate surface 101 as it may become separate and as free moving particles may interfere with the function of the EUV lithography system. The material of the substrate 100 is bismuth osmium carbide (Si: SiC). The substrate 100 shown in Fig. 1 is simultaneously the starting product of the coating method according to the present invention (the results of which are shown in Figs. 3 and 4), and the starting product according to the coating method of the prior art (the results are shown in the figure). 2)).
圖2顯示來自依據來自先前技術之方法的圖1之陶瓷基板100的塗佈之結果。鎳磷合金(NiP)112之金屬塗層已塗佈於研磨陶瓷組件100之表面101。該塗佈舉例來說藉由電鍍沉積或化學處理(化學鎳)而進行。NiP層112之錨定純機械性發生,其中互鎖銜接藉由該等表面粗糙度而形成。互鎖連接藉助彼此銜接的至少兩個連接夥伴生成。因此,該等連接夥伴即使在無力傳遞或該力傳遞中斷時也不能散開。 Figure 2 shows the results from the coating of the ceramic substrate 100 of Figure 1 in accordance with the method of the prior art. A metal coating of nickel phosphorus alloy (NiP) 112 has been applied to surface 101 of abrasive ceramic component 100. This coating is carried out, for example, by electroplating or chemical treatment (chemical nickel). The anchoring of the NiP layer 112 occurs purely mechanically, wherein the interlocking engagement is formed by the surface roughness. The interlocking connection is generated by means of at least two connection partners that are connected to each other. Therefore, the connection partners cannot be spread even when the force is transmitted or the force transmission is interrupted.
不過,藉由互鎖銜接而提供的低層鍵結和該陶瓷組件之不完善周圍區域,限制可經由NiP層112傳遞到陶瓷組件100中的該等力,以及例如可能隨著黏劑鍵結或隨著焊接或銅焊而發生的該等可容許溫度梯度。因此,NiP之膨脹係數與Si:SiC相當不同。如此結果為電鍍或化學所塗佈之陶瓷組件不能藉助焊接接合且藉助黏劑鍵結僅到有限範圍以形成用於夾持感應器的較大型次組合件和附件(也習知為夾持組件),僅能不夠牢固地附接到塗佈有NiP的陶瓷組件。 However, the low layer bonding provided by the interlocking engagement and the imperfect surrounding area of the ceramic component limit such forces that may be transferred into the ceramic component 100 via the NiP layer 112, and may, for example, be bonded with an adhesive or These allowable temperature gradients occur with soldering or brazing. Therefore, the expansion coefficient of NiP is quite different from that of Si:SiC. The result is that the electroplated or chemically coated ceramic components cannot be joined by soldering and bonded to the limited range by means of adhesive bonding to form larger secondary assemblies and accessories for clamping inductors (also known as clamping assemblies). ), it can only be attached to the ceramic component coated with NiP insufficiently firmly.
圖3顯示來自為了用於EUV微影系統而依據本發明所塗佈之EUV子模組120、130的切圖。首先,金屬焊料114藉由網版印刷、噴塗、浸漬、或延展而塗佈於基板表面101整個表面區域上方。接著,進行熱處理以在陶瓷材料100與金屬焊料114之間製造材料鍵結。該材料鍵結存在於在該金屬化(亦即在該固化狀態下之金屬焊料114)與陶瓷基板100之間的過渡帶116中。該熱處理在從700℃至1500℃的溫度範圍內在真空中進行5分鐘至60分鐘。 3 shows a cutaway view of an EUV sub-module 120, 130 coated in accordance with the present invention for use in an EUV lithography system. First, the metal solder 114 is applied over the entire surface area of the substrate surface 101 by screen printing, spraying, dipping, or stretching. Next, heat treatment is performed to make a material bond between the ceramic material 100 and the metal solder 114. The material bond is present in the transition zone 116 between the metallization (i.e., the metal solder 114 in the cured state) and the ceramic substrate 100. The heat treatment is carried out in a vacuum at a temperature ranging from 700 ° C to 1500 ° C for 5 minutes to 60 minutes.
材料之兩種群組可能依據本發明用作金屬焊料114。一方面,可能使用反應性金屬焊料,特別是具有鈦(Ti)、錳(Mn)、鋯(Zr)、及/或 鉿(Hf)之添加物的銀銅共熔物。該熱處理在這種情況下在700℃至900℃下進行5分鐘至10分鐘。另一方面,非反應性金屬焊料、特別是鎢焊膏可能用作金屬焊料114。該熱處理在這種情況下在1000℃至1500℃下進行30分鐘至60分鐘。 Two groups of materials may be used as the metal solder 114 in accordance with the present invention. On the one hand, it is possible to use reactive metal solders, in particular titanium (Ti), manganese (Mn), zirconium (Zr), and/or A silver-copper eutectic of an additive of hydrazine (Hf). This heat treatment is carried out in this case at 700 ° C to 900 ° C for 5 minutes to 10 minutes. On the other hand, a non-reactive metal solder, particularly a tungsten solder paste, may be used as the metal solder 114. This heat treatment is carried out in this case at 1000 ° C to 1500 ° C for 30 minutes to 60 minutes.
在該固化狀態下之金屬焊料114封閉陶瓷基板100之表面101,並由此鍵結尤其基板100之游離矽108和弱鍵結區110。在該改善後,EUV子模組120、130適合真空。 The metal solder 114 in the cured state closes the surface 101 of the ceramic substrate 100, and thereby bonds, for example, the free crucible 108 and the weak bonding region 110 of the substrate 100. After this improvement, the EUV sub-modules 120, 130 are suitable for vacuum.
該金屬化、亦即在該固化狀態下之金屬焊料114之厚度介於5μm至300μm之間。即使5μm之厚度也足以將金屬之該等特性賦予到該陶瓷EUV子模組之表面上。 The metallization, that is, the thickness of the metal solder 114 in the cured state is between 5 μm and 300 μm. Even a thickness of 5 μm is sufficient to impart such properties of the metal to the surface of the ceramic EUV sub-module.
圖4顯示來自依據本發明替代性所塗佈之EUV子模組120、130的切圖。塗佈有金屬焊料114的表面101後續至少在某些區域中採用鎳(Ni)塗佈。該後續採用鎳的塗佈藉由物理氣相沉積(PVD)或藉由化學氣相沉積(CVD)以電鍍製程進行。鎳塗層115與在該固化狀態下之金屬焊料114進入穩定連接,並以正好如同在該固化狀態下之金屬焊料114的方式適合後續接合製程。 4 shows a cutaway view of an EUV sub-module 120, 130 that is alternatively applied in accordance with the present invention. The surface 101 coated with the metal solder 114 is subsequently coated with nickel (Ni) at least in certain regions. This subsequent coating with nickel is carried out by physical vapor deposition (PVD) or by chemical vapor deposition (CVD) in an electroplating process. The nickel coating 115 enters a stable connection with the metal solder 114 in the cured state, and is suitable for the subsequent bonding process in a manner similar to the metal solder 114 in the cured state.
圖5以示意形式顯示從依據本發明所塗佈之兩個EUV子模組120、130接合的依據本發明之EUV模組200。為了製造EUV模組200,首先提供兩個所塗佈之EUV子模組120、130。接著,這兩個EUV子模組120、130接合。該接合可能藉由焊接而進行,特別是採用硬焊料。或者,該接合可能藉由黏劑鍵結而進行,特別是採用陶瓷黏劑。在第一EUV子模組120與第二EUV子模組130之間的接合區140,以介於5MPa至50MPa 之間之拉伸強度連接兩個EUV子模組120、130。該拉伸強度之各個數值取決於焊料之選擇和黏劑之選擇。所焊接的連接具有最大可達50MPa之拉伸強度。採用特別最適合在高純度真空中操作之陶瓷黏劑的黏劑所鍵結連接,具有介於5MPa至10MPa之間之拉伸強度。 Figure 5 shows, in schematic form, an EUV module 200 in accordance with the present invention joined from two EUV sub-modules 120, 130 coated in accordance with the present invention. To fabricate the EUV module 200, two coated EUV sub-modules 120, 130 are first provided. Then, the two EUV sub-modules 120, 130 are joined. This bonding may be performed by soldering, in particular using a hard solder. Alternatively, the bonding may be carried out by adhesive bonding, in particular using a ceramic adhesive. The junction area 140 between the first EUV sub-module 120 and the second EUV sub-module 130 is between 5 MPa and 50 MPa. The tensile strength between the two EUV sub-modules 120, 130 is connected. The individual values of the tensile strength depend on the choice of solder and the choice of adhesive. The welded joint has a tensile strength of up to 50 MPa. The bond is bonded using an adhesive which is particularly suitable for ceramic adhesives operating in high purity vacuum, having a tensile strength of between 5 MPa and 10 MPa.
圖6以示意形式顯示具有接合式夾持組件160之依據本發明的EUV模組200。此夾持組件160在本發明示例性具體實施例中設計為感應器安裝架。夾持組件160可能藉由焊接(特別是採用硬焊料)及/或藉由黏劑鍵結(特別是採用陶瓷黏劑),而接合到EUV模組200之在固化狀態下的金屬焊料114。在EUV模組200與夾持組件160之間生成具有該前述拉伸強度的接合區150。設置在夾持組件160上的是感應器170。在未顯示的示例性具體實施例中,具有複數感應器170的複數夾持組件160附接到EUV模組200。 Figure 6 shows, in schematic form, an EUV module 200 in accordance with the present invention having a bonded clamp assembly 160. This clamp assembly 160 is designed as an inductor mount in an exemplary embodiment of the invention. The clamping assembly 160 may be bonded to the metal solder 114 of the EUV module 200 in a cured state by soldering (especially using hard solder) and/or by adhesive bonding (especially using a ceramic adhesive). A land 150 having the aforementioned tensile strength is formed between the EUV module 200 and the clamp assembly 160. Disposed on the clamping assembly 160 is an inductor 170. In an exemplary embodiment not shown, a plurality of clamp assemblies 160 having a plurality of inductors 170 are attached to the EUV module 200.
圖7以示意形式顯示來自EUV微影系統500之對本發明而言至關重要的切圖。EUV模組200由機械性解耦204與力框架300隔開。EUV模組200藉由夾持組件160承載感應器170。力框架300承載光學組件302、特別是反射鏡。而且,用於致動光學組件302的該等致動器(在該圖示中未顯示)拴緊於力框架300。在未顯示的示例性具體實施例中,複數感應器170藉由複數夾持組件160而附著到EUV模組200。因此,EUV模組200也指稱為感應器框架、測量架構或測量標準。力框架300藉由機械性解耦304與堅固周圍環境400隔開。在這種情況下決定性在於EUV模組與力框架300之隔開。此隔開使得光學組件302之空間位置可能藉由感應器框架200之感應器170而沒有任何問題地感應到。在這種情況下,與此 感應器框架200相關的反射鏡之各個位置,可能藉由致動器(在該圖示中未顯示)而藉助位置感應器170進行測量及藉助控制器(在該圖示中未顯示)設定為該所需數值。此詳細資訊在DE 102011077315 A1中揭示。 Figure 7 shows, in schematic form, a cutaway view from the EUV lithography system 500 that is critical to the invention. The EUV module 200 is separated from the force frame 300 by a mechanical decoupling 204. The EUV module 200 carries the inductor 170 by the clamping assembly 160. The force frame 300 carries an optical component 302, in particular a mirror. Moreover, the actuators (not shown in this illustration) for actuating the optical assembly 302 are clamped to the force frame 300. In an exemplary embodiment not shown, the plurality of inductors 170 are attached to the EUV module 200 by a plurality of clamping assemblies 160. Thus, EUV module 200 is also referred to as a sensor frame, measurement architecture, or measurement standard. The force frame 300 is separated from the solid surrounding environment 400 by a mechanical decoupling 304. In this case it is decisive that the EUV module is separated from the force frame 300. This spacing allows the spatial position of the optical assembly 302 to be sensed by the inductor 170 of the sensor frame 200 without any problem. In this case, with this The respective positions of the mirrors associated with the sensor frame 200 may be measured by the position sensor 170 by means of an actuator (not shown in the illustration) and by means of a controller (not shown in the figure) being set to The required value. This detailed information is disclosed in DE 102011077315 A1.
在未顯示的示例性具體實施例中,EUV微影系統500具有複數EUV模組200。各EUV模組200都可能隨後設計用於感應光學組件302之各種群組之位置。EUV微影系統500之多個EUV模組200彼此完全機械性解耦。 In an exemplary embodiment not shown, the EUV lithography system 500 has a plurality of EUV modules 200. Each EUV module 200 may subsequently be designed to sense the location of various groups of optical components 302. The plurality of EUV modules 200 of the EUV lithography system 500 are completely mechanically decoupled from one another.
圖8示意性顯示EUV微影系統500整體,其包含一光束塑形與照明系統504以及一投影系統506。在真空殼體中分別提供光束塑形與照明系統504和投影系統506,各真空殼體都借助於未更具體表示的抽真空裝置進行抽真空。該等真空殼體由機械室(未更具體表示)圍繞,其中提供用於機械性移動或調整該等光學元件的該等驅動裝置。在此機械室中也可提供電力控制器及其類似物。 FIG. 8 schematically shows an EUV lithography system 500 as a whole that includes a beam shaping and illumination system 504 and a projection system 506. A beam shaping and illumination system 504 and projection system 506 are respectively provided in the vacuum housing, each vacuum housing being evacuated by means of a vacuuming device not more specifically shown. The vacuum housings are surrounded by a mechanical chamber (not more specifically shown) in which the drive means for mechanically moving or adjusting the optical elements are provided. A power controller and the like can also be provided in this machine room.
EUV微影系統500具有EUV光源502。發出EUV範圍內之輻射516的電漿源或同步加速器,可提供例如作為EUV光源502。在光束塑形與照明系統504中,EUV輻射516聚焦且該所需操作波長從EUV輻射516濾出。由EUV光源502所產生的EUV輻射516具有相對較低的空氣透射率,因此在光束塑形與照明系統504中和在投影系統506中的該等光束引導空間抽真空。 The EUV lithography system 500 has an EUV light source 502. A plasma source or synchrotron that emits radiation 516 in the EUV range can be provided, for example, as an EUV source 502. In beam shaping and illumination system 504, EUV radiation 516 is focused and the desired operating wavelength is filtered from EUV radiation 516. The EUV radiation 516 produced by the EUV source 502 has a relatively low air transmission, such that the beam guiding spaces in the beam shaping and illumination system 504 and in the projection system 506 are evacuated.
圖8所表示光束塑形與照明系統504具有五個反射鏡610、612、614、616、618。在通過光束塑形與照明系統504後,EUV輻射516導向光罩(倍縮光罩)510上。光罩510同樣形成作為反射光學元件,並可設 置在系統504、506外面。再者,EUV輻射516可能藉助反射鏡636導向至光罩510上。光罩510具有結構,其縮小影像藉助投影系統506在晶圓514或其類似物上描繪出。 The beam shaping and illumination system 504 shown in FIG. 8 has five mirrors 610, 612, 614, 616, 618. After passing through the beam shaping and illumination system 504, the EUV radiation 516 is directed onto the reticle (double reticle) 510. The mask 510 is also formed as a reflective optical element and can be provided Placed outside of the systems 504, 506. Furthermore, EUV radiation 516 may be directed to reticle 510 by means of mirror 636. The reticle 510 has a structure whose reduced image is depicted on the wafer 514 or the like by means of the projection system 506.
投影系統506具有用於在晶圓514上描繪出光罩510之影像的六個反射鏡M1-M6。在這種情況下,投影系統506之個別反射鏡M1-M6可能相對於投影系統506之光軸624對稱設置。應注意EUV微影系統500之反射鏡數量不限於所表示數量。也可能提供更多或更少數量之反射鏡。再者,該等反射鏡M1-M6為了光束塑形一般在其正面為曲面。 Projection system 506 has six mirrors M1-M6 for depicting an image of reticle 510 on wafer 514. In this case, the individual mirrors M1-M6 of the projection system 506 may be symmetrically disposed relative to the optical axis 624 of the projection system 506. It should be noted that the number of mirrors of the EUV lithography system 500 is not limited to the number indicated. It is also possible to provide more or fewer mirrors. Furthermore, the mirrors M1-M6 are generally curved on the front side for beam shaping.
此外,投影系統506還具有用於判定該等反射鏡M1-M6之一之位置的若干感應器170、特別是位置感應器裝置。 In addition, projection system 506 also has a number of inductors 170, particularly position sensor devices, for determining the position of one of the mirrors M1-M6.
舉例來說,假設投影系統506具有六個反射鏡M1-M6(N1=6),其中五個反射鏡可致動(N2=5)且各該等可致動反射鏡都可分配六個位置感應器裝置170(N4=6),則得到30之在投影系統506中的位置感應器裝置170之數量N3(N3=N4 x N2=6 x 5=30)。 For example, assume that projection system 506 has six mirrors M1-M6 (N1=6), five of which can be actuated (N2=5) and each of these actuable mirrors can be assigned six positions. The sensor device 170 (N4 = 6) obtains the number N3 of position sensor devices 170 in the projection system 506 (N3 = N4 x N2 = 6 x 5 = 30).
不限制一般性且為了簡化表示之原因,圖8僅顯示一個位置感應器裝置170。 Without limiting the generality and for reasons of simplifying the representation, FIG. 8 shows only one position sensor device 170.
位置感應器裝置170與未顯示的評估裝置耦合。該評估裝置設計為藉助位置感應器裝置170之輸出信號判定該等反射鏡M1-M6之可致動反射鏡之位置。該評估裝置就像位置感應器裝置170,可設置在投影系統506之真空殼體520中。在這種情況下,該評估裝置舉例來說整合到該信號處理單元中。或者,該評估裝置也可能設置在投影系統506之真空殼體520外部。 The position sensor device 170 is coupled to an evaluation device not shown. The evaluation device is designed to determine the position of the actuatable mirrors of the mirrors M1-M6 by means of the output signals of the position sensor device 170. The evaluation device, like the position sensor device 170, can be disposed in the vacuum housing 520 of the projection system 506. In this case, the evaluation device is integrated into the signal processing unit, for example. Alternatively, the evaluation device may also be disposed external to the vacuum housing 520 of the projection system 506.
依據該等前述示例性具體實施例之一的至少一個EUV模組200(在圖8中未顯示)設置在投影系統506中。 At least one EUV module 200 (not shown in FIG. 8) in accordance with one of the foregoing exemplary embodiments is disposed in projection system 506.
100‧‧‧陶瓷基板 100‧‧‧Ceramic substrate
114‧‧‧金屬焊料 114‧‧‧Metal solder
120、130‧‧‧EUV子模組 120, 130‧‧‧ EUV sub-module
140‧‧‧接合區 140‧‧‧ junction area
200‧‧‧EUV模組 200‧‧‧EUV module
Claims (15)
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DE102015208831.6A DE102015208831B4 (en) | 2015-05-12 | 2015-05-12 | Method for producing an EUV module, EUV module and EUV lithography system |
DE102015208831.6 | 2015-05-12 |
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TW201639648A true TW201639648A (en) | 2016-11-16 |
TWI685389B TWI685389B (en) | 2020-02-21 |
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EP (1) | EP3295248A1 (en) |
CN (1) | CN107531581B (en) |
DE (1) | DE102015208831B4 (en) |
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DE102017202642A1 (en) | 2017-02-20 | 2018-03-01 | Carl Zeiss Smt Gmbh | Optical element, EUV lithography system with it and coating process |
DE102021117043A1 (en) | 2021-07-01 | 2022-08-11 | Carl Zeiss Smt Gmbh | Process for non-destructive testing of a ceramic component |
DE102022204423A1 (en) | 2022-05-04 | 2023-11-09 | Carl Zeiss Smt Gmbh | Method for connecting components, optical assembly and lithography system |
CN116511752B (en) * | 2023-01-31 | 2024-02-06 | 度亘核芯光电技术(苏州)有限公司 | Copper surface structure, preparation method and welding method thereof |
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DE4105596A1 (en) * | 1991-02-22 | 1992-08-27 | Degussa | Prodn. of high temp. resistant soldered joint between ceramic parts - by metallising using active solder and then soldering with hard solder |
DE19734211C2 (en) | 1997-08-07 | 2001-08-30 | Forschungszentrum Juelich Gmbh | Process for soldering two ceramics or a ceramic to a metal |
US7843632B2 (en) * | 2006-08-16 | 2010-11-30 | Cymer, Inc. | EUV optics |
US7090362B2 (en) * | 2001-11-09 | 2006-08-15 | Carl Zeiss Smt Ag | Facet mirror having a number of mirror facets |
CN1226238C (en) * | 2003-10-16 | 2005-11-09 | 上海交通大学 | Carbon, ceramic-nonmetallic material and metal material connection method |
CN100434218C (en) * | 2004-09-30 | 2008-11-19 | 太原理工大学 | Application method of surface alloying ceramic |
DE102007005780A1 (en) * | 2006-08-10 | 2008-02-14 | Carl Zeiss Smt Ag | Composite structure for microlithography and optical arrangement |
US8831170B2 (en) * | 2006-11-03 | 2014-09-09 | Carl Zeiss Smt Gmbh | Mirror with a mirror carrier and projection exposure apparatus |
US8810775B2 (en) * | 2010-04-16 | 2014-08-19 | Media Lario S.R.L. | EUV mirror module with a nickel electroformed curved mirror |
DE102011077315A1 (en) | 2011-06-09 | 2012-08-02 | Carl Zeiss Smt Gmbh | Optical arrangement for projection lens of extreme UV (EUV) projection exposure system for manufacturing e.g. LCD, has diaphragm that is arranged outside workspace of projecting lens, based on operating position of positioning device |
DE102012202047A1 (en) * | 2012-02-10 | 2013-01-17 | Carl Zeiss Smt Gmbh | Method for manufacturing e.g. facet mirror, for extreme UV projection exposure system for microlithography, involves pressing optical functional body by applying pneumatic pressure on base body during reaction of reactive multi-layers |
DE102012110618A1 (en) * | 2012-11-06 | 2014-05-22 | Endress + Hauser Gmbh + Co. Kg | Assembly having at least two ceramic bodies joined together, in particular pressure measuring cell, and method for joining ceramic bodies by means of an active brazing solder |
DE102014224418A1 (en) * | 2014-11-28 | 2015-02-05 | Carl Zeiss Smt Gmbh | Holding device and lithography system |
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2015
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WO2016180609A1 (en) | 2016-11-17 |
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