TW201518551A - Surface treating method for metal housing - Google Patents
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
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- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/022—Anodisation on selected surface areas
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Abstract
Description
本發明涉及一種金屬基體表面處理方法,尤其涉及一種藉由複數陽極、染色處理形成不同顏色之金屬基體表面處理方法。The invention relates to a metal substrate surface treatment method, in particular to a metal substrate surface treatment method for forming different colors by a plurality of anodes and dyeing treatment.
由於鋁、鈦等合金材料具有強度高、質輕等優點,而廣泛應用於航空、電子、通訊等領域。為進一步提高表面品質及視覺效果,通常採用著色或陽極處理工藝來達成。陽極氧化前處理通常包括堿咬、化學打砂、化學拋光等制程,陽極氧化後處理包括染色、封孔等制程,使得表面處理較複雜。另,由上述制程處理後之表面所獲得之氧化膜厚度均一,且較難獲得複數種色彩之圖案。如需獲得複數種色彩之圖案,得複數次遮蔽、染色、封孔等制程,更加增加了加工流程。Alloy materials such as aluminum and titanium have advantages such as high strength and light weight, and are widely used in aviation, electronics, communications and other fields. In order to further improve the surface quality and visual effect, it is usually achieved by a coloring or anodizing process. Anodizing pretreatment usually includes processes such as biting, chemical sanding, chemical polishing, etc. The post-anodizing treatment includes dyeing, sealing and other processes, making the surface treatment more complicated. In addition, the thickness of the oxide film obtained by the surface treated by the above process is uniform, and it is difficult to obtain a pattern of a plurality of colors. If you need to obtain a variety of color patterns, you can add a number of masking, dyeing, sealing and other processes, which further increases the processing flow.
鑒於上述內容,有必要提供一種簡單且能夠在金屬基體表面形成複數色彩圖案之表面處理方法。In view of the above, it is necessary to provide a surface treatment method which is simple and capable of forming a plurality of color patterns on the surface of a metal substrate.
一種金屬基體表面處理方法,其包括以下步驟:提供一金屬基體;對金屬基體進行陽極氧化處理,並作封孔處理;按照需在金屬基體上形成之圖案,將金屬基體之表面上對應圖案之不同顏色劃分成複數處理區域,複數處理區域按照顏色分為複數有彩色處理區域和一無彩色處理區域,無彩色處理區域為黑色及灰色對應之處理區域,有彩色處理區域為除黑色、白色及灰色之外之顏色對應之處理區域;藉由鐳射雕刻剝離複數有彩色處理區域中之一有彩色處理區域上之氧化膜;對金屬基體進行陽極、對應色彩之染色及封孔處理,使得上述剝離氧化膜後之有彩色處理區域上形成具有對應色彩之彩色氧化膜;重複上述剝離有彩色處理區域上之氧化膜及進行陽極、對應顏色之染色及封孔處理過程,以在其他有彩色處理區域上形成具有對應色彩之彩色氧化膜;對無彩色處理區域進行鐳射打標,得到灰色或黑色圖案。A metal substrate surface treatment method comprising the steps of: providing a metal substrate; anodizing the metal substrate and performing a sealing treatment; and correspondingly patterning the surface of the metal substrate according to a pattern formed on the metal substrate The different colors are divided into complex processing regions, and the complex processing regions are divided into a plurality of colored processing regions and an achromatic processing region according to colors, and the achromatic processing regions are black and gray corresponding processing regions, and the color processing regions are black, white, and a processing area corresponding to a color other than gray; an oxide film on a color processing region in one of the plurality of colored processing regions is peeled off by laser engraving; an anode, a corresponding color dyeing, and a sealing treatment are performed on the metal substrate to cause the peeling Forming a color oxide film having a corresponding color on the colored processing region after the oxide film; repeating the stripping of the oxide film on the color processing region and performing the dyeing and sealing process on the anode, the corresponding color, in other colored processing regions Forming a colored oxide film having a corresponding color; Color processing laser marking area, to give a gray or black pattern.
另一種金屬基體表面處理方法,其包括以下步驟:提供一金屬基體;對金屬基體進行陽極氧化處理,並作封孔處理;按照需在金屬基體上形成之圖案,將金屬基體之表面上對應圖案之不同顏色劃分成二處理區域,該圖案包括灰色及一除黑色、白色及灰色之外之顏色,該二處理區域按照包括一有彩色處理區域和一無彩色處理區域,該無彩色處理區域為該圖案中灰色對應之處理區域,該有彩色處理區域為除黑色、白色及灰色之外之顏色對應之處理區域;藉由鐳射雕刻剝離該有彩色處理區域上之氧化膜;對金屬基體進行陽極、對應顏色之染色及封孔處理,使得該有彩色處理區域上形成具有對應色彩之彩色氧化膜;對該無彩色處理區域進行鐳射打標,得到灰色圖案。Another metal substrate surface treatment method comprises the steps of: providing a metal substrate; anodizing the metal substrate and performing a sealing treatment; and correspondingly patterning the surface of the metal substrate according to a pattern formed on the metal substrate The different colors are divided into two processing areas, the pattern includes gray and a color other than black, white, and gray, and the two processing areas include a chromatic processing area and an achromatic processing area, and the achromatic processing area is a processing area corresponding to gray in the pattern, the colored processing area being a processing area corresponding to a color other than black, white, and gray; peeling off the oxide film on the colored processing area by laser engraving; performing anode on the metal substrate Corresponding color dyeing and sealing treatment, so that a colored oxide film having a corresponding color is formed on the colored processing region; and the achromatic processing region is laser-marked to obtain a gray pattern.
上述方法無需堿咬、化學拋光及化學噴砂等過程,因此在處理過程中無需對金屬基體進行油墨遮蔽,減少加工流程,處理過程較簡單,降低了成本。藉由複數次對有彩色區域進行剝離氧化膜及陽極、染色、封孔,以及對無彩色區域進行打標,使得金屬基體表面形成複數色彩圖案。The above method does not require biting, chemical polishing and chemical blasting, so there is no need to shield the metal substrate during the processing, the processing flow is reduced, the processing is simple, and the cost is reduced. The surface of the metal substrate is formed into a plurality of color patterns by performing a plurality of stripping of the oxide film and the anode, dyeing, sealing, and marking the achromatic region.
圖1係本發明實施方式金屬基體表面處理方法之流程圖。1 is a flow chart of a method for treating a metal substrate according to an embodiment of the present invention.
下面結合附圖及具體實施方式對本發明之金屬基體表面處理方法做進一步之詳細說明。The metal substrate surface treatment method of the present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
請參閱圖1,本發明金屬基體表面處理方法主要包括如下步驟:Referring to FIG. 1, the metal substrate surface treatment method of the present invention mainly comprises the following steps:
S101:提供一金屬基體;S101: providing a metal substrate;
S102:對金屬基體進行陽極氧化處理,並作封孔處理;S102: performing anodizing treatment on the metal substrate and performing sealing treatment;
S103:按照需在金屬基體上形成之圖案,將金屬基體之表面上對應圖案之不同顏色劃分成複數處理區域,該複數處理區域按照顏色分為有彩色處理區域和無彩色處理區域,無彩色處理區域為黑色及灰色對應之處理區域,有彩色處理區域為除黑色、白色及灰色之外之顏色對應之處理區域;S103: dividing a different color of a corresponding pattern on a surface of the metal substrate into a plurality of processing regions according to a pattern to be formed on the metal substrate, wherein the plurality of processing regions are divided into a colored processing region and an achromatic processing region according to the color, and achromatic processing is performed. The area is a processing area corresponding to black and gray, and the color processing area is a processing area corresponding to colors other than black, white, and gray;
S104:藉由鐳射雕刻剝離複數有彩色處理區域之其中一有彩色處理區域上之氧化膜;S104: peeling off an oxide film on one of the plurality of colored processing regions by the laser processing by laser engraving;
S105:對金屬基體進行陽極、染色及封孔處理,使得金屬基體上述剝離氧化膜後之有彩色處理區域上形成對應色彩之彩色氧化膜;S105: performing an anode, a dyeing, and a sealing treatment on the metal substrate, so that a colored oxide film of a corresponding color is formed on the colored processing region after the metal substrate is stripped of the oxide film;
S106:重複S104~S105,以在其他有彩色處理區域上形成對應色彩之彩色氧化膜;S106: repeating S104~S105 to form a color oxide film of a corresponding color on other colored processing regions;
S107:對無彩色處理區域進行鐳射打標,根據無彩色處理區域之圖案,控制打標時之鐳射能量,得到不同色調之灰色或黑色外觀。鐳射能量從弱至強,打標後呈現之灰色越深,鐳射能量達到一定強度,打標後呈現黑色;S107: Perform laser marking on the achromatic processing area, and control the laser energy of the marking according to the pattern of the achromatic processing area to obtain a gray or black appearance with different tones. The laser energy is weak to strong, and the darker the gray color after marking, the laser energy reaches a certain intensity, and the black color is marked after marking;
S108:對金屬基體進行機械拋光,提高金屬基體之平整度。S108: Mechanically polishing the metal substrate to improve the flatness of the metal substrate.
可理解,在步驟S106中,如果無彩色處理區域之圖案為單一色彩,例如為同一色調之灰色,則對無彩色處理區域進行鐳射打標時,無需變更打標條件,在無彩色處理區域進行同一色調之灰色打標即可。It can be understood that, in step S106, if the pattern of the achromatic processing area is a single color, for example, the gray of the same color, when the laser marking of the achromatic processing area is performed, the marking condition is not changed, and the achromatic processing area is performed. Gray marking of the same color can be used.
可理解,當有彩色處理區域之數量為一時,即形成之圖案上僅有除黑色、白色及灰色之外之一種顏色時,S106之步驟可省略。It can be understood that when the number of color processing regions is one, that is, only one color other than black, white, and gray is formed on the formed pattern, the step of S106 can be omitted.
上述方法適用於鋁、鋁合金、鈦、鈦合金等金屬基體之表面處理,上述方法中,由於金屬基體已經過陽極氧化劑封孔處理,剝離其中一有彩色處理區域之氧化膜時採用鐳射雕刻方法,無需堿咬、化學拋光及化學噴砂等過程,因此在處理過程中無需對金屬基體之其他部分進行油墨遮蔽,減少了加工流程,使處理過程較簡單,降低了成本,同時避免油墨造成之化學污染。藉由複數次對不同有彩色處理區域進行剝離氧化膜及彩色陽極,實現對有彩色處理區域進行對應之彩色著色處理。同時,控制鐳射打標條件,實現漸變色之打標,實現無彩色處理區域之圖案之層次感。在圖案成型後,藉由機械拋光,提高產品表面之光澤度及平整度。The above method is applicable to the surface treatment of a metal substrate such as aluminum, aluminum alloy, titanium, titanium alloy, etc. In the above method, since the metal substrate has been sealed by the anode oxidizing agent, the laser engraving method is adopted when peeling off the oxide film of one of the colored processing regions. No need for biting, chemical polishing and chemical blasting, so there is no need to mask the ink on other parts of the metal substrate during processing, which reduces the processing flow, makes the process simpler, reduces the cost, and avoids the chemical caused by the ink. Pollution. By performing a stripping oxide film and a color anode on different colored processing regions in a plurality of times, color coloring processing corresponding to the colored processing region is realized. At the same time, the laser marking conditions are controlled to achieve the marking of the gradient color, and the layering of the pattern of the achromatic processing area is realized. After the pattern is formed, the surface gloss and flatness of the product are improved by mechanical polishing.
綜上所述,本發明符合發明專利要件,爰依法提出申請專利。惟,以上該者僅為本發明之較佳實施例,舉凡熟悉本案技藝之人士,在爰依本發明精神所作之等效修飾或變化,皆應涵蓋於以下之如申請專利範圍內。In summary, the present invention complies with the requirements of the invention patent, and submits a patent application according to law. However, the above is only a preferred embodiment of the present invention, and equivalent modifications or variations made by those skilled in the art will be included in the following claims.
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Claims (8)
提供一金屬基體;
對金屬基體進行陽極氧化處理,並作封孔處理;
按照需在金屬基體上形成之圖案,將金屬基體之表面上對應圖案之不同顏色劃分成複數處理區域,複數處理區域按照顏色分為複數有彩色處理區域和一無彩色處理區域,無彩色處理區域為黑色及灰色對應之處理區域,有彩色處理區域為除黑色、白色及灰色之外之顏色對應之處理區域;
藉由鐳射雕刻剝離複數有彩色處理區域中之其中一有彩色處理區域上之氧化膜;
對金屬基體進行陽極、對應色彩之染色及封孔處理,使得上述剝離氧化膜後之有彩色處理區域上形成具有對應色彩之彩色氧化膜;
重複上述剝離有彩色處理區域上之氧化膜及進行陽極、對應顏色之染色及封孔處理過程,以在其他有彩色處理區域上形成具有對應色彩之彩色氧化膜;
對無彩色處理區域進行鐳射打標,得到灰色或黑色圖案。A metal substrate surface treatment method comprising the following steps:
Providing a metal substrate;
The metal substrate is anodized and sealed for sealing;
According to the pattern to be formed on the metal substrate, the different colors of the corresponding patterns on the surface of the metal substrate are divided into a plurality of processing regions, and the plurality of processing regions are divided into a plurality of colored processing regions and an achromatic processing region according to the color, and the achromatic processing region is The processing area corresponding to black and gray, and the color processing area is a processing area corresponding to colors other than black, white, and gray;
Etching an oxide film on one of the plurality of colored processing regions by laser engraving;
Performing an anode, a corresponding color dyeing, and a sealing treatment on the metal substrate to form a colored oxide film having a corresponding color on the colored processing region after the peeling of the oxide film;
Repeating the stripping of the oxide film on the colored processing region and performing the dyeing and sealing process on the anode, the corresponding color to form a colored oxide film having a corresponding color on the other colored processing regions;
Laser marking of the achromatic processing area results in a gray or black pattern.
提供一金屬基體;
對金屬基體進行陽極氧化處理,並作封孔處理;
按照需在金屬基體上形成之圖案,將金屬基體之表面上對應圖案之不同顏色劃分成二處理區域,該圖案包括灰色及一除黑色、白色及灰色之外之顏色,該二處理區域包括一有彩色處理區域和一無彩色處理區域,該無彩色處理區域為該圖案中灰色對應之處理區域,該有彩色處理區域為除黑色、白色及灰色之外之顏色對應之處理區域;
藉由鐳射雕刻剝離該有彩色處理區域上之氧化膜;
對金屬基體進行陽極、對應顏色之染色及封孔處理,使得該有彩色處理區域上形成具有對應色彩之彩色氧化膜;
對該無彩色處理區域進行鐳射打標,得到灰色圖案。A metal substrate surface treatment method comprising the following steps:
Providing a metal substrate;
The metal substrate is anodized and sealed for sealing;
According to the pattern to be formed on the metal substrate, the different colors of the corresponding patterns on the surface of the metal substrate are divided into two processing regions, the pattern includes gray and a color other than black, white and gray, and the two processing regions include a a color processing area and a color processing area, wherein the achromatic processing area is a gray corresponding processing area in the pattern, and the colored processing area is a processing area corresponding to colors other than black, white, and gray;
Stripping the oxide film on the colored processing region by laser engraving;
Performing an anode, a corresponding color dyeing and a sealing treatment on the metal substrate to form a colored oxide film having a corresponding color on the colored processing region;
The achromatic processing area was laser-marked to obtain a gray pattern.
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CN101457380A (en) * | 2007-12-14 | 2009-06-17 | 深圳富泰宏精密工业有限公司 | Metallic surface anode treatment method |
US20090200175A1 (en) * | 2008-02-07 | 2009-08-13 | Yuan-Ting Chang | Multicolor anodizing treatment |
CN101597784B (en) * | 2008-06-04 | 2012-03-28 | 比亚迪股份有限公司 | Hole-sealing method for anode oxide film of light metal material |
CN101619477A (en) * | 2008-06-30 | 2010-01-06 | 比亚迪股份有限公司 | Preparation method for multicolor oxide film |
CN101649478B (en) * | 2008-08-14 | 2012-03-28 | 比亚迪股份有限公司 | Method and equipment for preparing material with multi-color oxide film on surface |
CN101665971A (en) * | 2008-09-03 | 2010-03-10 | 比亚迪股份有限公司 | Material with multicolor oxidation film on surface and preparation method thereof |
CN101665969A (en) * | 2008-09-03 | 2010-03-10 | 深圳富泰宏精密工业有限公司 | Method for processing anode of aluminum or aluminum alloy surface |
US8349462B2 (en) * | 2009-01-16 | 2013-01-08 | Alcoa Inc. | Aluminum alloys, aluminum alloy products and methods for making the same |
CN101619478A (en) * | 2009-07-29 | 2010-01-06 | 艾默生网络能源有限公司 | Method for oxygenizing aluminium base plate into characters, aluminium base plate manufacturing method and aluminium base plate |
CN102747401B (en) * | 2012-07-05 | 2015-07-15 | 惠州Tcl移动通信有限公司 | Processing method for aluminum components |
CN102946046B (en) * | 2012-11-22 | 2014-11-05 | 深圳市大族激光科技股份有限公司 | Laser energy control method and system |
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2013
- 2013-10-17 CN CN201310486798.0A patent/CN104562129A/en active Pending
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TWI535895B (en) | 2016-06-01 |
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