TW201404589A - Medical grade flame-resistant fabric and manufacturing method thereof - Google Patents
Medical grade flame-resistant fabric and manufacturing method thereof Download PDFInfo
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本發明係有關於一種防火布料,且特別是有關於一種透濕及耐燃效果兼具之醫療用可透濕之防火布料。 The present invention relates to a fireproof fabric, and more particularly to a fire permeable fabric for medical use which is compatible with both moisture permeability and flame resistance.
長久以來,高分子材料廣泛用於民生、國防及工業上,日常生活上與它可說是息息相關,但高分子有一致命弱點,就是具可燃或易燃性,因此阻燃技術成為一項重要課題。容易導致火災的材料例如窗簾、桌布、膠布或衣服等布類製品,通常在該等布類製品中會添加一些耐燃劑,以降低火災發生機率。 Polymer materials have been widely used in people's livelihood, national defense and industry for a long time. It is closely related to it in daily life, but polymer has a fatal weakness, which is flammable or flammable, so flame retardant technology has become an important issue. . Materials that are prone to fire, such as curtains, tablecloths, tapes, or clothing, usually contain some flame retardant in these fabrics to reduce the chance of fire.
一般來說,聚酯類與聚醚類的PU樹脂於織物上加工後無法具有耐高溫水洗的效果,造成織物於高溫水洗後會產生層間剝離的現象,為改善織物之耐燃效果,先前技術是利用磷氮系、非環保溴耐燃劑添加於聚氨脂樹脂加工後的織物。然而,上述之添加劑的生物相容性(ISO 10993-5)較差,且傳統加工方式還會增加材料成本問題,不利於大量生產。 In general, polyester and polyether PU resins cannot be subjected to high temperature washing after processing on fabrics, resulting in delamination of fabrics after high temperature water washing. In order to improve the flame resistance of fabrics, the prior art is A fabric treated with a polyurethane resin is added using a phosphorus-nitrogen-based, non-environmental bromine flame retardant. However, the biocompatibility (ISO 10993-5) of the above additives is inferior, and the conventional processing method also increases the material cost problem, which is disadvantageous for mass production.
有鑒於此,發明人依據多年從事相關產品之製造開發及設計經驗,針對上述之目標詳加設計與審慎評估之後,終於得到一種確具實用性之本發明。 In view of this, the inventors have finally obtained a practical invention based on the experience of manufacturing and designing related products for many years, and after detailed design and careful evaluation of the above objectives.
為了製造一種具有較佳耐燃及可透溼性的機能性織布,本發明提供一種醫療用可透溼之防火布料之製造方法。 In order to produce a functional woven fabric having better flame resistance and moisture permeability, the present invention provides a method for producing a fire permeable fabric for medical use.
根據本發明之具體實施例,所述可透溼之防火布料之製造方法包括以下之步驟:首先提供一基布,並於該基布上形成有一壓光面,接著形成一接著層於該基布之壓光面,其中該接著層包含有二液型聚氨酯樹脂,最後形成一面層於該接著層上,其中該面層包含有一液型聚碳酸樹脂。 According to a specific embodiment of the present invention, the method for manufacturing a moisture permeable fireproof fabric comprises the steps of: first providing a base fabric, and forming a calendering surface on the base fabric, and then forming an adhesive layer on the base The calendered surface of the cloth, wherein the adhesive layer comprises a two-component polyurethane resin, and finally a layer is formed on the adhesive layer, wherein the top layer comprises a liquid polycarbonate resin.
根據上述之製造方法,所述可透溼之防火布料包括一基布、一接著層及一面層,其中,該基布具有一壓光面,該接著層設置於該基布之壓光面且包含有二液型聚氨酯樹脂,該面層設置於該接著層上且包含有一液型聚碳酸樹脂。 According to the above manufacturing method, the moisture permeable fireproof cloth comprises a base fabric, an adhesive layer and a layer, wherein the base fabric has a calendering surface, and the adhesive layer is disposed on the calendering surface of the base fabric. The invention comprises a two-component polyurethane resin, the top layer is disposed on the adhesive layer and comprises a liquid type polycarbonate resin.
綜上所述,本發明之製造方法能夠製造出一種具有較佳耐燃及可透溼性的布料,其於高溫水洗後不會產生層間剝離的現象;再者,由於所述布料具有較佳的生物相容性,故不易對人體造成危害,可大幅提升使用之安全性;此外,所述製造方法不需添加成本較高的添加劑,因此具有成本上的優勢,能夠應用於大量生產。 In summary, the manufacturing method of the present invention can produce a fabric having better flame resistance and moisture permeability, which does not cause interlayer peeling after high-temperature water washing; further, since the cloth has better The biocompatibility is not easy to cause harm to the human body, and the safety of use can be greatly improved; in addition, the manufacturing method does not need to add a high-cost additive, so it has a cost advantage and can be applied to mass production.
以下藉由具體實施例詳加說明,使能更容易了解本發明之目的、技術內容及欲達成之功效。 The purpose of the present invention, the technical contents, and the effects to be achieved are more easily understood by the detailed description of the specific embodiments.
請參閱圖1所示,其為本發明之醫療用可透濕之防火布料之製造方法之流程示意圖。並請配合參閱圖2,其顯示利用所述製造方法製成的醫療用可透濕之防火布料1之截面示意圖。 Please refer to FIG. 1 , which is a schematic flow chart of a method for manufacturing a hygroscopic fire-resistant fabric for medical use according to the present invention. Referring to FIG. 2 together, a schematic cross-sectional view of the medically permeable moisture-permeable fabric 1 made by the manufacturing method is shown.
首先,如步驟S10,提供一基布11,其上形成有一壓 光面。在本具體實施例中,基布可選自針織布、平織布、不織布或皮膜的其中一種,並透過高溫熱壓之方式將基布11整平化,使基布11上形成有一壓光面。 First, as in step S10, a base fabric 11 is provided, and a pressure is formed thereon. Glossy. In this embodiment, the base fabric may be selected from one of a knitted fabric, a plain woven fabric, a non-woven fabric or a film, and the base fabric 11 is flattened by high-temperature hot pressing to form a calender on the base fabric 11. surface.
接著,如步驟S12,形成一接著層12於基布11之壓光面。在本具體實施例中,接著層12可以是由二液型聚脂型樹脂(黏度介於5000~7000 CPS)、架橋劑、環保型耐燃劑及其他添加劑經攪拌機在介於攝氏20至25度之間的溫度下攪拌5至10分鐘所形成,需注意的是,攪拌過程中不可過於劇烈,以避免產生氣泡而導致糊料受損。更詳細地說,接著層12的組成成分主要包括100重量份(PHR)之二液型聚氨酯樹脂(Polyurethane)、3至5重量份之異氰酸鹽(isocyanate)架橋劑及40重量份之環保型耐燃劑。 Next, in step S12, a bonding layer 12 is formed on the calendered surface of the base fabric 11. In this embodiment, the adhesive layer 12 may be composed of a two-component polyester resin (viscosity between 5000 and 7000 CPS), a bridging agent, an environmentally friendly flame retardant, and other additives through a mixer at 20 to 25 degrees Celsius. The mixture is stirred at a temperature of 5 to 10 minutes. It should be noted that the stirring process should not be too vigorous to avoid bubble formation and damage to the paste. In more detail, the composition of the subsequent layer 12 mainly includes 100 parts by weight (PHR) of a two-component polyurethane resin (Polyurethane), 3 to 5 parts by weight of an isocyanate bridging agent, and 40 parts by weight of the environmental protection. Type of flame retardant.
其中,二液型聚氨酯樹脂因分子量低,故需加入適量的架橋劑混合,以反應形成分子量較大的網狀交聯性構造,從而能夠增加塗層織物的耐水壓、光澤度及厚實感。另外,於反應時添加適量的促進劑,可增強其熟成程度及強化接著力,適合用於綁紗、塗層打底、填縫。 Among them, the two-component polyurethane resin has a low molecular weight, so it is necessary to add an appropriate amount of a bridging agent to react to form a network cross-linked structure having a relatively large molecular weight, thereby increasing the water pressure resistance, gloss and thickness of the coated fabric. In addition, an appropriate amount of an accelerator is added during the reaction to enhance the degree of ripening and strengthen the adhesion, and is suitable for use in tying, coating, and caulking.
值得一提的是,所述接著層12係經塗佈機於介於攝氏100至170度之間的溫度下,以上羅拉刮刀(knife on roll)或浮游刮刀(knife on air)之方式塗佈於基布11之壓光面,並停留20至60秒之預乾時間,此種塗佈方式能夠提高布料之耐燃及可透濕效果。此外,藉由添加環保型耐燃劑於二液型聚氨酯樹脂,可提高生物相容性的級數,由原先的3級提高至1~2級。 It is worth mentioning that the adhesive layer 12 is coated by a coater at a temperature between 100 and 170 degrees Celsius, above a knife on roll or a knife on air. On the calendering surface of the base fabric 11 and staying for a pre-drying time of 20 to 60 seconds, this coating method can improve the flame resistance and moisture permeability of the fabric. In addition, by adding an environmentally-friendly flame retardant to the two-component polyurethane resin, the number of biocompatibility can be increased from the original 3 to 1 to 2.
最後,如步驟S14,形成一面層13於接著層12上。 在本具體實施例中,面層13可以是由一液型聚碳酸樹脂(黏度介於18000~20000 CPS)、色料、滑劑、奈米銀離子抗菌劑及其他添加劑經攪拌機於介於攝氏20至25度之間的溫度下攪拌5至10分鐘所形成,同樣需注意的是,攪拌過程中不可過於劇烈,以避免產生氣泡而導致糊料受損。 Finally, as in step S14, a layer 13 is formed on the subsequent layer 12. In this embodiment, the surface layer 13 may be a liquid type polycarbonate resin (viscosity between 18000 and 20000 CPS), a colorant, a slip agent, a nano silver ion antibacterial agent, and other additives through a stirrer in between Celsius Stirring at a temperature between 20 and 25 degrees for 5 to 10 minutes, it should also be noted that the agitation process should not be too intense to avoid bubble formation and damage to the paste.
更詳細地說,面層的組成成份主要包括60重量份之一液型聚碳酸樹脂、40重量份之聚酯型樹脂、3至4重量份之滑劑及10至12重量份之耐燃劑。其中之重量份(PHR)單位代表每百份橡膠含量中添加物的百分含量,例如20PHR即代表每100g或kg單位之橡膠中添加20g或kg單位之添加物。 More specifically, the composition of the top layer mainly comprises 60 parts by weight of one liquid type polycarbonate resin, 40 parts by weight of a polyester type resin, 3 to 4 parts by weight of a slip agent, and 10 to 12 parts by weight of a flame resistant agent. The parts by weight (PHR) represent the percentage of the additive per hundred parts of rubber content, for example 20 PHR means that 20 g or kg of the additive is added per 100 g or kg of rubber.
同樣地,所述面層13係經塗佈機於介於攝氏100至170度之間的溫度下,以上羅拉的刮刀(knife on roll)或浮游刮刀(knife on air)之方式塗佈於該接著層上,並停留20至60秒之預乾時間,以提高布料之耐燃及可透濕效果。而進一步值得一提的是,藉由添加一液型聚碳酸樹脂可提高醫療用透濕之防火布料1之高溫水洗的效果,因此在高溫水洗後可避免產生層間剝離的現象。 Similarly, the top layer 13 is applied to the surface by a coater at a temperature between 100 and 170 degrees Celsius, a knife on roll or a knife on air. Then on the layer, and stay in the pre-drying time of 20 to 60 seconds to improve the flame resistance and moisture permeability of the fabric. Further, it is worth mentioning that by adding a one-pack type polycarbonate resin, the effect of high-temperature water washing of the fire-permeable fabric 1 for medical moisture permeability can be improved, so that the phenomenon of interlayer peeling can be avoided after high-temperature water washing.
此外,本發明之醫療用可透濕之防火布料1之製造方法還包括將經步驟S10~S14製成之半成品執行一熱乾燥處理程序。具體而言,熱乾燥處理程序之溫度範圍係介於攝氏100至170度之間,且停留時間為80至120秒。據此,令所述半成品得到兼具耐燃(NFPA-701)、可透濕(JIS L1099 A1)、耐水壓、堅固及耐用的功能,以製成本創作之後續加工便利性高的醫療用可透濕之防火布 料1。 Further, the method for manufacturing the medical moisture permeable fire-resistant fabric 1 of the present invention further comprises performing a heat drying treatment process on the semi-finished product produced in steps S10 to S14. Specifically, the thermal drying process has a temperature range of between 100 and 170 degrees Celsius and a residence time of 80 to 120 seconds. According to this, the semi-finished product is obtained with the functions of flameproof (NFPA-701), moisture permeable (JIS L1099 A1), water pressure resistance, sturdiness and durability, so as to make the medical processing with high convenience for subsequent processing of the present invention. Wet fireproof cloth Material 1.
復參閱圖2,利用上述之製造方法,本發明得以提供一種醫療用可透濕之防火布料1,其包括一基布11、一接著層12及一面層13。其中,基布11具有一壓光面,接著層12設置於基布11之壓光面且包含有二液型聚氨酯樹脂,面層13設置於接著層12上且包含有一液型聚碳酸樹脂。 Referring to Fig. 2, with the above manufacturing method, the present invention provides a medical moisture permeable fireproof fabric 1 comprising a base fabric 11, an adhesive layer 12 and a side layer 13. The base fabric 11 has a calendering surface, and the layer 12 is disposed on the calendering surface of the base fabric 11 and contains a two-component polyurethane resin. The top layer 13 is disposed on the adhesive layer 12 and contains a liquid type polycarbonate resin.
綜上所述,經由本創作之製造方法製成的醫療用可透濕之防火布料具有較佳的耐燃、可透濕、耐水壓、堅固及耐用性,除了可應用於醫療器材例如醫療床墊、防水工作服等,還能廣泛應用於製作風衣、雪衣、皮包、軟袋、手提袋、帳棚帆布等,產品的附加價值高。 In summary, the medical moisture permeable fireproof fabric made by the manufacturing method of the present invention has better flame resistance, moisture permeability, water pressure resistance, firmness and durability, and can be applied to medical equipment such as medical mattresses. Waterproof overalls, etc., can also be widely used in the production of windbreakers, snowsuits, leather bags, soft bags, handbags, tent canvas, etc., the added value of the product is high.
再者,所述醫療用可透濕之防火布料藉由將環保型耐燃劑添加於二液型聚氨酯樹脂,可提高生物相容性的級數,由原先的3級提高至1~2級,故不易對人體造成危害,可大幅提升使用之安全性。又,所述醫療用可透濕之防火布料之面層含有一液型聚碳酸樹脂,可提高醫療用透濕之防火布料之高溫水洗的效果,因此在高溫水洗後可避免產生層間剝離的現象。 Furthermore, the medical moisture-permeable fire-retardant fabric can increase the biocompatibility grade by adding an environmentally-friendly flame retardant to the two-component polyurethane resin, and the grade is improved from the original 3 grades to 1 to 2 grades. Therefore, it is not easy to cause harm to the human body, and the safety of use can be greatly improved. Moreover, the surface layer of the medically permeable moisture-permeable fabric contains a liquid type polycarbonate resin, which can improve the high-temperature water washing effect of the fire-permeable fabric for medical moisture permeability, so that the phenomenon of interlayer peeling can be avoided after high-temperature water washing. .
此外,所述可透濕之防火布料之製造方法不需添加成本較高的添加劑,因此具有成本上的優勢,能夠應用於大量生產。 In addition, the method for manufacturing the moisture permeable fireproof fabric does not require the addition of a higher cost additive, and thus has a cost advantage and can be applied to mass production.
以上所述者,僅為本發明一較佳實施例而已,並非用來限定本發明實施之範圍,故舉凡依本發明申請專利範圍所述之形狀、構造、特徵及精神所為之均等變化與修飾,均應包括於本發明之申請專利範圍內。 The above is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, so that the shapes, structures, features, and spirits described in the claims of the present invention are equally varied and modified. All should be included in the scope of the patent application of the present invention.
10‧‧‧醫療用可透濕之防火皮料 10‧‧‧Medical moisture permeable leather for medical use
11‧‧‧基布 11‧‧‧Kib
12‧‧‧接著層 12‧‧‧Next layer
13‧‧‧面層 13‧‧‧Face
圖1為本發明之醫療用可透濕之防火皮料之製造方法之流程示意圖;以及圖2為本發明之醫療用可透濕之防火皮料之截面示意圖。 1 is a schematic flow chart of a method for manufacturing a moisture permeable fireproof leather material for medical use according to the present invention; and FIG. 2 is a schematic cross-sectional view of a fireproof leather material for medical use according to the present invention.
10‧‧‧醫療用可透濕之防火皮料 10‧‧‧Medical moisture permeable leather for medical use
11‧‧‧基布 11‧‧‧Kib
12‧‧‧接著層 12‧‧‧Next layer
13‧‧‧面層 13‧‧‧Face
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CN201210284523.4A CN103572612B (en) | 2012-07-18 | 2012-08-06 | Moisture permeable fireproof cloth and manufacturing method thereof |
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CN105113257B (en) * | 2015-09-21 | 2017-03-15 | 康帝雅高档面料(苏州)有限公司 | A kind of Waterproof Breathable is prevented fires full terylene PU protective fabrics |
CN107722856A (en) * | 2017-11-10 | 2018-02-23 | 中纺新材料科技有限公司 | A kind of novel environment friendly water proof fire retardant sail adhesive plaster and preparation method thereof |
CN110271231A (en) * | 2019-05-13 | 2019-09-24 | 吴江福华织造有限公司 | A kind of production technology of inflaming retarding fabric |
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TWI284162B (en) * | 2004-06-29 | 2007-07-21 | Formosan Rubber Group Incorpor | Fabric formed with multi-layered PU film and with bactericidal fungicidal properties and method for producing the same |
CN101120044A (en) * | 2005-02-17 | 2008-02-06 | 通用电气公司 | Protected polycarbonate films having thermal and uv radiation stability, and method of making |
KR100869967B1 (en) * | 2006-12-29 | 2008-11-24 | 제일모직주식회사 | Polycarbonate Resin Composition with Good Flame Retardancy and Light Stability |
CN102233706B (en) * | 2010-04-30 | 2014-06-11 | 厚生股份有限公司 | Processing method of fabrics with high adhesiveness |
CN102373625A (en) * | 2010-08-11 | 2012-03-14 | 厚生股份有限公司 | Biocompatible fabric and production method thereof |
CN102373624B (en) * | 2010-08-26 | 2013-10-16 | 厚生股份有限公司 | Method for manufacturing high-strength typhoon prevention cloth |
CN202293465U (en) * | 2011-09-29 | 2012-07-04 | 昆山协兴合成革有限公司 | High-flame-retardant sofa leather |
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