CN105113257B - A kind of Waterproof Breathable is prevented fires full terylene PU protective fabrics - Google Patents
A kind of Waterproof Breathable is prevented fires full terylene PU protective fabrics Download PDFInfo
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- CN105113257B CN105113257B CN201510602775.0A CN201510602775A CN105113257B CN 105113257 B CN105113257 B CN 105113257B CN 201510602775 A CN201510602775 A CN 201510602775A CN 105113257 B CN105113257 B CN 105113257B
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Abstract
The full terylene PU protective fabrics the invention provides a kind of Waterproof Breathable is prevented fires, including base fabric, the surface of the base fabric is coated with the first water proof fire retardant coating, the second water proof fire retardant coating, the 3rd water proof fire retardant coating and the 4th water proof fire retardant coating successively.A kind of full terylene PU protective fabrics of Waterproof Breathable fire prevention of the invention, by special water proof fire retardant coating, reach the equilibrium point of the coating processing of two kinds of restrictions or checking relations in five elements, make final fabric reach the highest rain-proof moisture-inhibiting rank of 3/3 grade of EN343 class, the basic protection fire rating of EN531 can also be reached simultaneously, and the highest fire rating that chemical fiber plus material can reach, so that single fabric has multiple-protection-function, can apply to personal protection industry, it is formed into the main material of high visual fire prevention ready-made clothes, final personal protection clothes is made not only to absorb ventilative rain-proof water repellent, can also possess basic fire rating simultaneously.
Description
Technical field
The full terylene PU protective fabrics the present invention relates to a kind of Waterproof Breathable is prevented fires, belong to textile material technical field.
Background technology
At present, Waterproof Breathable PU coatings are mutually resisted in the principles of chemistry with the processing of fire protection flame retarding PU coatings.In order to
Ensure that feel and the waterproofing and moisture-penetration performances of good Waterproof Breathable terylene coating, fabric need to do spill resistant processing, spill resistant is helped
Substantially based on fluorine carbon (FLUOCARBON), this auxiliary agent contains C keys for agent, is combustion-supporting.And in flame retardant coating processing, fire-retardant
The interpolation of auxiliary agent can reduce the solid content of PU in formula, and the water resistance of fabric can be had a great impact.Therefore, existing fabric
It is difficult to reach the basic protection fire rating of EN14116INDEX I while Europe superscript EN343 rain-proof moisture-inhibiting specifications are reached.
Content of the invention
In view of the defect that above-mentioned prior art is present, the full terylene PU the purpose of the present invention is to propose to a kind of Waterproof Breathable is prevented fires
Protective fabric, can reach the highest rain-proof moisture-inhibiting rank of 3/3 grade of EN343class, while can also reach preventing substantially for EN531
Shield fire rating.
The purpose of the present invention is achieved by the following technical programs：
A kind of Waterproof Breathable is prevented fires full terylene PU protective fabrics, and including base fabric, the surface of the base fabric is coated with the successively
One water proof fire retardant coating, the second water proof fire retardant coating, the 3rd water proof fire retardant coating and the 4th water proof fire retardant coating；Described first prevents
Water flame retardant coating in terms of mass fraction, including：
The first water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 19000 ± 200cps；
The second water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100～110
White slurry 20～22
Bromine system fireproof agent 25～27.5
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps；
The 3rd water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100～110
White slurry 20～22
Bromine system fireproof agent 25～27.5
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps；
The 4th water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps.
Further, the first water proof fire retardant coating is in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 19000 ± 200cps；
The second water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100
White slurry 20
Bromine system fireproof agent 25
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps；
The 3rd water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100
White slurry 20
Bromine system fireproof agent 25
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps；
The 4th water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps.
Further, the base fabric is that polyester fabric is prepared after dyeing sizing, water-sprinkling and press polish are processed.
Further, the Waterproof Breathable prevents fires full terylene PU protective fabrics by being coated with the surface of the base fabric successively
Prepared by the first water proof fire retardant coating, the second water proof fire retardant coating, the 3rd water proof fire retardant coating and the 4th water proof fire retardant coating
Obtain.
It is a further object to provide one kind is prepared into by the full terylene PU protective fabrics of above-mentioned Waterproof Breathable fire prevention
The protective garment for arriving.
The present invention prominent effect be：A kind of full terylene PU protective fabrics of Waterproof Breathable fire prevention of the invention, by special
Water proof fire retardant coating, reach two kinds of restrictions or checking relations in five elements coating processing equilibrium point, make final fabric reach EN343class
3/3 grade of highest rain-proof moisture-inhibiting rank, while the basic protection fire rating of EN531 can be also reached, and chemical fiber plus material can reach
The highest fire rating for arriving, so that single fabric has multiple-protection-function, can apply to personal protection industry, be system
Into the main material of high visual fire prevention ready-made clothes, final personal protection clothes is made not only to absorb ventilative rain-proof water repellent, while can also
Possesses basic fire rating.
Specific embodiment
In order to be more clearly understood to the technical characteristic of the present invention, purpose and beneficial effect, now to skill of the invention
Art scheme carry out described further below, but it is not intended that to the present invention can practical range restriction.Institute in following embodiments
Experimental technique is stated, if no special instructions, conventional method is；The reagent and material, if no special instructions, can be from business way
Footpath obtains.
Embodiment 1：
The present embodiment provides a kind of Waterproof Breathable fire prevention full terylene PU protective fabrics, and including base fabric, the surface of base fabric is successively
It is coated with the first water proof fire retardant coating, the second water proof fire retardant coating, the 3rd water proof fire retardant coating and the 4th water proof fire retardant coating；
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 19000cps；
The second water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100
White slurry 20
Bromine system fireproof agent 25
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000cps；
The 3rd water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100
White slurry 20
Bromine system fireproof agent 25
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000cps；
The 4th water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000cps.
The Waterproof Breathable of the present embodiment prevent fires full terylene PU protective fabrics preparation method as follows：
1st, polyester fabric carries out dyeing sizing, and then polyester fabric surface clean is clean, surface do not remain softening agent or its
His auxiliary agent, makes big volume by connecing cloth machine；
2nd, water-sprinkling solution is got out, is placed in the compregnate equipment of coating machine, fabric makes fabric band by compregnate equipment
Liquid, makes liquid dried through baking oven, and fluorine carbon chemicals realize water-sprinkling effect in web surface film forming, arrives coating procedure after reducing
Coating adhesive infiltrates into the ratio in the gap of cloth；
3rd, base fabric is made in single-side high temperature press polish using calender, the purpose of press polish is to reduce the infiltration of coating, if applied
Layer infiltrates into the gap of cloth can increase coated weight, improve cost, can also make fabric become fragile, and reduce the strength of fabric；
4th, using the first water proof fire retardant coating, the second water proof fire retardant coating, the 3rd water proof fire retardant coating and for having configured
Four water proof fire retardant coatings, the surface for being coated to base fabric by coating machine, film forming after drying obtain final Waterproof Breathable fire prevention complete
Terylene PU protective fabrics.
Full terylene PU protective fabrics that the Waterproof Breathable of the present embodiment is prevented fires are measured, with reference to 811 side's methods of testing of ISO
Water proofing property：After 5X60 degree is washed>2000mm；With reference to ISO11092 methods test moisture permeability：<20M2PA/W；With reference to ISO4920 methods
Test water repellent：5 grades；With reference to EN14116INDEX I/12H/604 test fire prevention：I levels.
Therefore, a kind of Waterproof Breathable of the embodiment of the present invention is prevented fires full terylene PU protective fabrics, by special anti-
Water flame retardant coating, reaches the equilibrium point of the coating processing of two kinds of restrictions or checking relations in five elements, makes final fabric reach EN343 class 3/3
The highest rain-proof moisture-inhibiting rank of level, while can also reach the basic protection fire rating of EN531, and chemical fiber plus material can reach
Highest fire rating, so that single fabric has multiple-protection-function, can apply to personal protection industry, is formed into height
The main material of visual fire prevention ready-made clothes, makes final personal protection clothes not only absorb ventilative rain-proof water repellent, while can also possess
Basic fire rating.
Embodiment 2：
The present embodiment provides a kind of Waterproof Breathable fire prevention full terylene PU protective fabrics, and including base fabric, the surface of base fabric is successively
It is coated with the first water proof fire retardant coating, the second water proof fire retardant coating, the 3rd water proof fire retardant coating and the 4th water proof fire retardant coating；
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 19200cps；
The second water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 110
White slurry 22
Bromine system fireproof agent 27.5
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 7000cps；
The 3rd water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 110
White slurry 22
Bromine system fireproof agent 27.5
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 7000cps；
The 4th water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 7000cps.
Embodiment 3：
The present embodiment provides a kind of Waterproof Breathable fire prevention full terylene PU protective fabrics, and including base fabric, the surface of base fabric is successively
It is coated with the first water proof fire retardant coating, the second water proof fire retardant coating, the 3rd water proof fire retardant coating and the 4th water proof fire retardant coating；
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 18800cps；
The second water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 110
White slurry 22
Bromine system fireproof agent 27.5
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 5000cps；
The 3rd water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 110
White slurry 22
Bromine system fireproof agent 27.5
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 5000cps；
The 4th water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 5000cps.
Above-described is only some embodiments of the present invention.For the person of ordinary skill of the art, not
On the premise of departing from the invention design, some deformations and improvement can also be made, these belong to the protection model of the present invention
Enclose.
Claims (5)
1. a kind of Waterproof Breathable is prevented fires full terylene PU protective fabrics, it is characterised in that：Including base fabric, the surface of the base fabric is successively
It is coated with the first water proof fire retardant coating, the second water proof fire retardant coating, the 3rd water proof fire retardant coating and the 4th water proof fire retardant coating；
The first water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 19000 ± 200cps；
The second water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100～110
White slurry 20～22
Bromine system fireproof agent 25～27.5
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps；
The 3rd water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100～110
White slurry 20～22
Bromine system fireproof agent 25～27.5
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps；
The 4th water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps.
2. a kind of Waterproof Breathable according to claim 1 is prevented fires full terylene PU protective fabrics, it is characterised in that：Described first
Water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 19000 ± 200cps；
The second water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100
White slurry 20
Bromine system fireproof agent 25
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps；
The 3rd water proof fire retardant coating in terms of mass fraction, including：
Solvent-borne type PU resins 100
White slurry 20
Bromine system fireproof agent 25
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps；
The 4th water proof fire retardant coating in terms of mass fraction, including：
It is eventually adding 1:1 toluene-butanone mixed solvent adjustment viscosity is 6000 ± 1000cps.
3. a kind of Waterproof Breathable according to claim 1 is prevented fires full terylene PU protective fabrics, it is characterised in that：The base fabric
Prepare after dyeing sizing, water-sprinkling and press polish are processed for polyester fabric.
4. a kind of Waterproof Breathable according to claim 3 is prevented fires full terylene PU protective fabrics, it is characterised in that：The waterproof
Moisture-inhibiting prevent fires full terylene PU protective fabrics pass through the surface of the base fabric be coated with successively the first water proof fire retardant coating, second
Water proof fire retardant coating, the 3rd water proof fire retardant coating and the 4th water proof fire retardant coating are prepared.
5. Waterproof Breathable described in any one of claim 1-4 is prevented fires the protective garment that full terylene PU protective fabrics are prepared.
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| CN201510602775.0A CN105113257B (en) | 2015-09-21 | 2015-09-21 | A kind of Waterproof Breathable is prevented fires full terylene PU protective fabrics |
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| CN201510602775.0A CN105113257B (en) | 2015-09-21 | 2015-09-21 | A kind of Waterproof Breathable is prevented fires full terylene PU protective fabrics |
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| CN105113257A CN105113257A (en) | 2015-12-02 |
| CN105113257B true CN105113257B (en) | 2017-03-15 |
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| CN106590186A (en) * | 2016-12-09 | 2017-04-26 | 苏州陈恒织造有限公司 | Waterproof and flame-retarding coating for fabric and preparation method thereof |
| JP7009104B2 (en) * | 2017-07-31 | 2022-01-25 | セーレン株式会社 | Fiber structure and its manufacturing method |
| CN109023976A (en) * | 2018-09-28 | 2018-12-18 | 江苏瑞康安全装备有限公司 | A kind of preparation method of luggage case fabric |
| CN109487567A (en) * | 2018-10-09 | 2019-03-19 | 南京哈昵特户外用品有限公司 | A kind of manufacturing method of multicoat waterproof cloth |
| CN111501364A (en) * | 2020-05-14 | 2020-08-07 | 绍兴市三协纺织品有限公司 | Processing method of special fabric for medical isolation protective clothing |
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| CN1107192A (en) * | 1994-02-07 | 1995-08-23 | 财团法人中国纺织工业研究中心 | Fire-retardant water-proof products making method |
| EP0791613B1 (en) * | 1996-02-14 | 1999-04-14 | Sika AG, vorm. Kaspar Winkler & Co. | Flame-retardant polyurethane systems |
| TWI523759B (en) * | 2012-07-18 | 2016-03-01 | 厚生股份有限公司 | Medical grade flame-resistant fabric and manufacturing method thereof |
| CN104499301B (en) * | 2014-11-17 | 2016-05-11 | 杭州苏威进出囗有限公司 | A kind of preparation technology of durability environ mental protective wet type Pu synthetic leather |
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