TW201343803A - Colored photosensitive composition, color filter and method of manufacturing the same, and liquid crystal display device - Google Patents

Abstract

A colored photosensitive composition contains (A) a dye, (B) a photopolymerization initiator, (C) a polymerizable compound having at least two ethyleny unsaturated double bonds in a molecule, and (D) heat resistance particles excluding organic pigments having an average primary particle diameter of 100 nm or less. Compared to mass of all solid contents of the colored photosensitive composition, a content of (A) the dye ranges from 2 mass% to 20 mass%. In addition, compared to the mass of all solid contents of the colored photosensitive composition, a content of (D) the heat resistance particles ranges from 1 mass% to 10 mass%.

Description

Coloring photosensitive composition, color filter, method for producing color filter, and liquid crystal display device

The present invention relates to a coloring photosensitive composition, a color filter using the colored photosensitive composition, a method of producing a color filter, and a liquid crystal display device.

As one of methods for producing a color filter used in a liquid crystal display device, a pigment dispersion method is widely used. In the pigment dispersion method, there is a method in which a color filter is prepared by dispersing a pigment in various photosensitive compositions, and a color filter is produced by photolithography. In this method, since the photosensitive composition contains a pigment, it is stable to light or heat, and is patterned by photolithography, so that the positional accuracy is sufficiently ensured. Therefore, it is a method suitable for producing a color filter or the like used in a liquid crystal display device or the like.

As a coloring agent used in the production of color filters, not only pigments, but also pigments other than pigments such as dyes have been extensively studied. If a dye is used as the colorant, it can be made by the color purity of the dye itself or the vividness of its color tone. It is useful in terms of improving the hue or brightness of the displayed image when the image is displayed. A compound having a dye precursor such as a pyrrolethymidine dye, a pyrimidine azo dye, a pyrazole azo dye, or a dibenzopyran dye is known as a dye (for example, refer to Japanese Patent Laid-Open No. 2008-- Japanese Patent Publication No. 292970, Japanese Patent Laid-Open No. 2007-039478, and Japanese Patent No. 3,875,451.

In general, a liquid crystal display device can be manufactured by separately producing a color filter substrate and a thin film-transistor (TFT) substrate, and sandwiching the liquid crystal to bond them. In recent years, in order to increase the size of the display device and improve the image quality, the color filter array is increased by providing a color filter layer on the TFT substrate, and the color filter is high in brightness. The development of the On Array, COA) liquid crystal display device has become important.

In the COA method, since the color filter layer is provided on the TFT, the required characteristics of the color filter layer are required to have a low dielectric constant and a low dielectric constant in addition to the required characteristics of high transmittance and high contrast. The formation of fine pores (contact pores) of the wiring is good, and the resistance to the peeling liquid is good. A color-sensitive photosensitive composition that satisfies these required characteristics is required.

With respect to the color-sensitive photosensitive composition used in the COA liquid crystal display device, it is known that the resolution of the contact hole or the contact hole formation property is improved by the following technique: a technique containing a certain amount of a monomer having a carboxyl group. Or a technique of combining an exposure light source having a wavelength of 230 nm to 330 nm with an initiator such as an acetophenone-based or an anthracene salt, and the like (for example, refer to Japanese Patent Laid-Open No. 2011-64758, Japanese Patent Laid-Open No. 2008-292603 Bulletin).

However, in these techniques, the above requirements are not sufficiently satisfied, and in particular, the occurrence of a color-sensitive photosensitive composition having a low dielectric constant and simultaneously achieving contact hole formation properties is expected.

It is known that in a coloring photosensitive composition used for the production of a color filter, when a dye is used as a coloring agent, brightness or contrast is improved, but since a coloring pattern is required, heat such as post-baking is required, and the pattern is easy. Flow (hot reflow), even if a fine pattern is obtained by development, the shape of the pattern is impaired, and it is difficult to form fine pores such as contact holes. Moreover, it is difficult to achieve both a low dielectric constant and contact hole formation properties.

The present invention has been made in view of the above problems, and an object of the present invention is to provide a method for suppressing reflow of a pattern due to heat when used as a coloring agent even when a dye is used as a coloring agent, and in the case of producing a color filter. A color-sensitive photosensitive composition having a good dielectric constant and a low dielectric constant. Further, an object of the present invention is to provide a color filter using the colored photosensitive composition and a method for producing the same, and to provide a liquid crystal display device capable of high-quality image display, in particular, a COA liquid crystal display device.

The above problems can be achieved by the following means.

<1> A colored photosensitive composition comprising (A) a dye, (B) a photopolymerization initiator, (C) a polymerizable compound having at least two ethylenically unsaturated double bonds in a molecule, and (D) a heat-resistant particle other than the organic pigment having an average primary particle diameter of 100 nm or less, and the quality of all the solid matter of the colored photosensitive composition The content of the dye (A) is 2% by mass or more and 20% by mass or less, and the content of the heat-resistant particles (D) is 1 with respect to the mass of all the solid matter of the colored photosensitive composition. The mass% or more and 10% by mass or less.

<2> The colored photosensitive composition according to <1>, wherein the (D) heat resistant particles are hollow ceria particles.

<3> The colored photosensitive composition according to <1> or <2>, wherein the (A) dye is a metal which is represented by the following formula (I) and which is bonded to a metal atom or a metal compound. Compound:

In the formula (I), R ¹ to R ⁶ each independently represent a hydrogen atom or a monovalent substituent, and R ⁷ represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group.

The colored photosensitive composition according to any one of <1> to <3> wherein the (A) dye is a metal-substituted compound represented by the following formula (I-3): Formula (I-3)

In the formula (I-3), R ² , R ³ , R ⁴ and R ⁵ each independently represent a hydrogen atom or a monovalent substituent, and R ⁷ represents a hydrogen atom, a halogen atom, an alkyl group or an aryl group. Or a heterocyclic group; R ⁸ and R ⁹ each independently represent an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylamino group, an arylamino group, or a heterocyclic amino group. ;Ma represents a metal atom or a metal compound; X ³ and X ⁴ each independently represent NR ^a (R ^a represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkylsulfonyl group, or An arylsulfonyl group, an oxygen atom, or a sulfur atom; Y ¹ and Y ² each independently represent NR ^b (R ^b represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkyl group Sulfhydryl or arylsulfonyl), oxygen atom, sulfur atom, or carbon atom; X ⁵ represents a group bondable to Ma, a represents 0, 1, or 2; R ⁸ and Y ¹ may also Bonding to form a ring of 5 members, 6 members, or 7 members, and R ⁹ and Y ² may be bonded to each other to form a ring of 5 members, 6 members, or 7 members.

<5> A color filter comprising a coloring layer formed by using the coloring photosensitive composition according to any one of <1> to <4>.

<6> A method of producing a color filter, comprising: a colored layer forming step, wherein the colored photosensitive composition according to any one of <1> to <4> is applied onto a substrate to form a colored layer; An exposure step of patterning the colored layer Forming a latent image by exposure; and developing a step of developing a color layer on which the latent image is formed to form a pattern.

<7> A liquid crystal display device comprising the color filter according to <5>.

(8) A liquid crystal display device comprising the coloring photosensitive composition according to any one of <1> to <4>, which is formed on a substrate for driving a thin film transistor (TFT) liquid crystal display device. Picture.

According to the present invention, it is possible to obtain a color filter which can suppress the reflow of a pattern due to heat when used in pattern formation, and which has a low dielectric constant and at the same time realizes fine contact hole formation. This is considered to be because the coloring photosensitive composition contains heat-resistant particles. Therefore, after patterning by development, the pattern is prevented from reflowing due to heat such as post-baking, and thus the shape of the pattern is maintained. It is presumed that the heat-resistant particles themselves are hardly deformed by heat, and the reflow of the pattern is suppressed, and the heat-resistant particles form a quasi-crosslinking with the other constituent components of the colored photosensitive composition constituting the pattern, thereby suppressing the backflow of the pattern due to heat. In particular, when hollow cerium oxide fine particles in the cerium oxide microparticles are used as the heat-resistant particles, the backflow due to heat is suppressed. It is presumed that the reason is that the polar group on the surface of the cerium oxide microparticles forms a stronger quasi-crosslinking with the other constituent components of the colored photosensitive composition.

In particular, when it is used in a COA liquid crystal display device, the coloring photosensitive composition layer is thickly provided in order to smooth the step caused by the TFT or the like. In the conventional coloring photosensitive composition, when it is thick, the reflow due to heat becomes large, and the contact hole cannot be formed into a rectangular shape. On the other hand, if you use this hair By illuminating the photosensitive composition, the reflow due to heat can be reduced, so that fine contact holes can be formed. Therefore, the present invention is suitable for a COA liquid crystal display device.

The color filter obtained by the present invention has a low dielectric constant. It is presumed that the heat-resistant particles contain a heat-resistant particle, and therefore, the impurities (including ions, etc.) contained in the coloring photosensitive composition are hard to move, and the coloring photosensitive composition is contained. Since the polar group of the constituent component is aligned and adsorbed on the heat-resistant particles, it becomes difficult to induce.

According to the present invention, it is possible to suppress the reflow of the pattern due to heat when used as a coloring even when a dye is used as a coloring agent, and the contact hole formation property is good when a color filter is produced, and it is shown A color-sensitive photosensitive composition having a low dielectric constant. Further, according to the present invention, it is possible to provide a color filter using the colored photosensitive composition and a method of manufacturing the same, and to provide a liquid crystal display device capable of high-quality image display, in particular, a COA liquid crystal display device.

1‧‧‧Substrate

2‧‧‧Main electrode

3‧‧‧Protective electrode

4‧‧‧Chromium surface

Fig. 1 is a schematic view showing a main electrode and a guard electrode produced in the measurement of the relative dielectric constant of the examples.

The colored photosensitive composition of the present invention comprises (A) a dye, (B) a photopolymerization initiator, (C) a polymerizable compound having at least two ethylenically unsaturated double bonds in the molecule, and (D) an average of one time. Other than organic pigments with a particle size of 100 nm or less The heat-resistant particles have a content of the dye (A) of 2% by mass or more and 20% by mass or less relative to the mass of all the solid matter of the colored photosensitive composition, and all the solid matter with respect to the colored composition. The content of the (D) heat resistant particles is 1% by mass or more and 10% by mass or less.

In addition, in the present specification, "~" indicates a range equal to or greater than the lower limit value and equal to or less than the upper limit value. Further, in the expressions in the specification, it is not described that the substituted and unsubstituted expressions also include a group having no substituent and a group having a substituent.

In the present specification, the term "all solids of the coloring photosensitive composition" means a total of the remaining components from which all of the components constituting the coloring photosensitive composition are removed.

Hereinafter, each component constituting the colored photosensitive composition of the present invention will be described in detail.

[(D) Heat resistant particles]

The colored photosensitive composition of the present invention contains heat-resistant particles other than the organic pigment.

The heat-resistant particles in the present invention are particles other than the organic pigment, and may be particles which are not thermally deformed at 180 ° C. The organic resin particles, the inorganic pigment particles, and the inorganic particles may be coated with the inorganic particles. Particles such as composite particles.

The term "thermal deformation at 180 ° C" means that the particles dispersed in the acrylic resin used in the coloring photosensitive composition are applied onto a glass substrate, and the temperature is 180 ° C using an oven (thermostatic bath) or the like. Heating for 60 minutes, No deformation was observed when the shape of the particles before and after heating was observed by a Transmission Electron Microscope (TEM).

The organic resin particles are not particularly limited and may be appropriately selected, and examples thereof include particles of melamine resin, benzoguanamine resin, and crosslinked polystyrene resin.

Specific examples of the commercially available product which is suitable as the heat-resistant particle of the present invention include EPOSTAR RS (manufactured by Nippon Shokubai Co., Ltd.) as a melamine-formaldehyde condensate, and polymethyl methacrylate-based crosslinked product. EPOSTAR MX 20w, EPOSTAR MX 30w, EPOSTAR MX 50w (manufactured by Nippon Shokubai Co., Ltd.), SX866A, SX866B (manufactured by JSR Co., Ltd.), etc., which are crosslinked styrene-acrylic.

The inorganic pigment particles are not particularly limited and may be appropriately selected from known inorganic pigment particles, and examples thereof include kaolin, barium sulfate, barium titanate, cerium oxide powder, fine powdered cerium oxide, cerium oxide, talc, clay, and the like. Particles such as magnesium carbonate, calcium carbonate, aluminum oxide, aluminum hydroxide, mica, and the like.

Further, as the composite particles, an organic-inorganic hybrid resin in which sol-gel-hardened cerium oxide particles are formed, a Compoceran series (manufactured by Arakawa Chemical Co., Ltd.), or the like can be used.

By including the heat-resistant particles in the coloring photosensitive composition, the layer obtained by using the coloring photosensitive composition can suppress the dielectric constant to be low, and the pattern obtained by development can suppress the backflow due to heat. It becomes possible to form fine contact holes.

In the present invention, the cerium oxide fine particles have a dielectric constant of 3.8, and in particular, the dielectric constant of the colored photosensitive composition layer (hereinafter referred to as "colored layer" as appropriate) can be effectively reduced. The heat-resistant particles are more preferably cerium oxide fine particles among the various particles, from the viewpoint of lowering the dielectric constant of the obtained coloring layer and suppressing heat reflow.

Further, among the cerium oxide microparticles, hollow cerium oxide microparticles have a gas such as air or nitrogen gas therein, and the gas has a low dielectric constant, so that hollow cerium oxide microparticles are particularly preferable.

The heat-resistant particles of the present invention have an average primary particle diameter of 100 nm or less, more preferably 10 nm or more and 50 nm or less. When the average primary particle diameter of the heat-resistant particles is within this range, the decrease in brightness or the decrease in contrast due to light scattering in the visible region is reduced, and the dispersibility of the heat-resistant particles is good. Further, such particles are less likely to cause aggregation or increase in viscosity, and are excellent in usability.

Further, the average primary particle diameter was measured using a transmission electron microscope (TEM).

Further, the heat-resistant particles may have a spherical shape, and may have a disk shape, a flat shape, a cubic shape, or an amorphous shape. Particularly good is a spherical shape. In the case of a spherical shape, a clear coating film which does not cause haze, aggregation, and viscosity increase can be obtained.

- cerium oxide microparticles -

As the cerium oxide microparticles, the type of cerium oxide can be used, and the preparation method is known as cerium oxide microparticles, and vapor phase cerium oxide, or aqueous cerium oxide microparticles, colloidal cerium oxide, or organic cerium sol (organo-silica sol) can be used. )Wait. Which is suitable An organic cerium sol which is excellent in dispersibility in an organic solvent.

Preferably, the cerium oxide microparticles are transparent in the visible region. Particularly preferred is high transmission in the range of 400 nm to 500 nm. Moreover, it is preferred that no fluorescence is emitted in the visible region. When the fluorescent light is emitted in the visible region, the polarized light is released, causing a significant decrease in contrast or the like.

When the cerium oxide fine particles are blended in the coloring photosensitive composition of the present invention, it is preferred to use cerium oxide fine particles dispersed in an organic solvent in advance. As means for uniformly dispersing inorganic particles such as cerium oxide microparticles in an organic solvent, a surface of a surface of cerium oxide microparticles is generally modified by an organic polymer or the like, and commercially available oxidizing is also available. Obtained by smashing particles.

The organic solvent used as the dispersion medium preferably has a boiling point of 110 ° C or more and 200 ° C or less. By using an organic solvent having a boiling point in the above range, it is possible to suppress clogging of the nozzle or unevenness of photosensitive unevenness when the coloring photosensitive composition is applied by the inkjet method, and to perform a drying step, for example, vacuum drying, which will be described later. The solvent can be easily removed in a drying or prebaking step or the like of the apparatus (VCD).

The organic cerium sol can be exemplified as the cerium oxide fine particles dispersed in the organic solvent. More specifically, a methanol sol sol or the like can be mentioned. Further, the cerium oxide fine particles dispersed in the organic solvent can also be obtained as a commercial product, and examples thereof include SEAHOSTAR KE-W10, SEAHOSTAR KE-W30, SEAHOSTAR KE-W50, SEAHOSTAR KE-P10, SEAHOSTAR KE-P30, SEAHOSTAR KE-P50, SEAHOSTAR KE-P100, SEAHOSTAR KE-S30, SEAHOSTAR KE-S50, SEAHOSTAR KE-S100 (above Nippon Catalyst Co., Ltd.), organic bismuth sol PGM-ST, organic bismuth sol PMA-ST, organic bismuth sol IPA-ST, organic bismuth sol IPA-ST-UP, organic bismuth sol IPA-ST-ZL, organic 矽Sol EG-ST, organic cerium sol NPC-ST-30, organic cerium sol DMAC-ST, organic cerium sol MEK-ST, organic cerium sol MIBK-ST, organic cerium sol XBA-ST, organic cerium sol MIBK-SD (above Produced by Nissan Chemical Co., Ltd.). Among these commercially available products, PMA-ST and PGM-ST do not cause aggregation of the pigment in the case of using a pigment in combination, and the boiling point of the organic solvent used in the dispersion is also moderate, and there is no fear of coating by an inkjet method. It is more preferable that the cloth is colored when the photosensitive composition is colored, the nozzle is clogged by drying, or the foaming is caused by poor drying.

- hollow cerium oxide microparticles -

The hollow cerium oxide microparticles refer to cerium oxide microparticles having a space (cavity) inside the cerium oxide microparticles and being occluded by the shell. Therefore, particles such as a porous pigment having a pore-like space having pores on the surface of the particles are not included in the hollow cerium oxide microparticles of the present invention. In addition, the aggregated particles which are aggregated particles of the primary particles and the aggregated particles in which the primary particle group acts as a shell and which have spaces formed therein are not included in the hollow ceria particles in the present invention.

The shape of the hollow ceria microparticles is not particularly limited, and it is not necessarily required to be spherical, and may be a spherical shape, a disk shape, a flat shape, a cubic shape, or an amorphous shape.

In addition, the average primary particle diameter of the hollow cerium oxide microparticles means the maximum diameter of the primary particles of the hollow cerium oxide microparticles, and refers to 100 hollow cerium oxide microparticles observed by photomicrography (TEM). Maximum straight The average of the trails.

Further, the thickness (shell thickness) of the shell of the hollow ceria particles is preferably 5 nm to 15 nm. The shell thickness of the hollow ceria particles can also be measured by photomicrographing (TEM).

Further, if the hollow ceria particles are in a space of a nanometer size, it is difficult to cause insulation breakdown, and therefore it is considered that the average primary particles are small.

Further, commercially available products of hollow cerium oxide microparticles include a dispersion sol containing hollow cerium oxide microparticles having an average primary particle diameter of 10 nm to 100 nm and a refractive index of 1.16 to 1.39 (for example, manufactured by Catalyst Chemical Industries Co., Ltd.). The through rear, and REKYUMU, SiliNax (registered trademark) of Nippon Mining Co., Ltd., etc. can be suitably used as the heat resistant particle in the present invention.

The colored photosensitive composition of the present invention may contain two or more kinds of particles having different average primary particle diameters and different types as the heat-resistant particles, and may contain two or more kinds of particles having different average primary particle diameters as the heat-resistant particles, or Two or more kinds of particles having different types may be contained as the heat-resistant particles.

The content of all the heat-resistant particles (excluding the organic pigment) contained in the coloring photosensitive composition is 1% by mass or more and 10% by mass or less based on the mass of all the solids of the coloring photosensitive composition, and is self-transparent. The viewpoint of temporal stability of the coloring photosensitive composition is preferably 1% by mass or more and 5% by mass or less.

[(A) Dyes]

The colored photosensitive composition of the present invention contains a dye. Relative to the coloring sensitivity group The content of the (A) dye contained in the coloring photosensitive composition is 2% by mass or more and 20% by mass or less based on the mass of all the solid matter of the product, and the time-lapse of the pattern forming property or the coloring photosensitive composition From the viewpoint of stability, it is preferably 2% by mass or more and 15% by mass or less.

The dye is not particularly limited, and a pyrrolethymethylene system, a pyrazole azo system, an anilino azo system, a triphenylmethane system, an anthraquinone group, an anthrapyridone system, a benzylidene group, or an oxygen can be used as the chemical structure. Oxonol, pyrazolotriazole azo, pyridone azo, cyanine, phenothiazine, pyrrolopyrazole azomethine, diphenyl And dyes such as piperazine, phthalocyanine, benzopyran, and indigo.

Specific examples of the dyes include, for example, JP-A-64-90403, JP-A-64-91102, JP-A-1-94301, and JP-A-6-11614 Japanese Patent Publication No. 2, 592, 207, U.S. Patent No. 4, 808, 501, U.S. Patent No. 5,667, 920, U.S. Patent No. 5,059,500, Japanese Patent Laid-Open No. Hei 5-333207, and Japanese Patent Laid-Open No. Hei 6-35183 Japanese Patent Laid-Open No. Hei 6-51115, Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Application Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Special Open No. 8-146215, Japan Japanese Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Patent Publication No. 2002-14223, Japanese Patent Application Publication No. Hei 8-302224, Japanese Patent Application Laid-Open No. Hei No. Hei No. Hei 8- No. The pigments described.

Among the dyes, the dye which is suitable for the coloring photosensitive composition of the present invention may be a metal-substituted compound having a structure represented by the following formula (I) and which is bonded to a metal atom or a metal compound (hereinafter referred to as "two Pyrrolemethylene metal complex compound", "pyrromethene dye").

In the formula (I), R ¹ to R ⁶ each independently represent a hydrogen atom or a monovalent substituent, and R ⁷ represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group. R ¹ and R ² , R ² and R ³ , R ⁴ and R ⁵ , and R ⁵ and R ⁶ may each independently bond to each other to form a ring of 5 members, 6 members, or 7 members. However, R ¹ and R ⁶ are not bonded to each other to form a ring.

A monovalent substituent means a halogen atom (for example, a fluorine atom, a chlorine atom, or a bromine A), an alkyl group (preferably a linear, branched or cyclic alkyl group having a carbon number of 1 to 48, more preferably a linear, branched or cyclic alkane having a carbon number of 1 to 24) Base, for example, methyl, ethyl, propyl, isopropyl, butyl, tert-butyl, pentyl, hexyl, heptyl, octyl, 2-ethylhexyl, dodecyl, hexadecyl , cyclopropyl, cyclopentyl, cyclohexyl, 1-norbornyl, 1-adamantyl), alkenyl (preferably an alkenyl group having 2 to 48 carbon atoms, more preferably 2 carbon atoms) Alkenyl group of ~18, such as vinyl, allyl, 3-buten-1-yl), aryl (preferably an aryl group having a carbon number of 6 to 48, more preferably a carbon number of 6~) An aryl group of 24, for example, a phenyl group, a naphthyl group, a heterocyclic group (preferably a heterocyclic group having 1 to 32 carbon atoms, more preferably a heterocyclic group having 1 to 18 carbon atoms, for example, 2 Thienyl, 4-pyridyl, 2-furyl, 2-pyrimidinyl, 1-pyridyl, 2-benzothiazolyl, 1-imidazolyl, 1-pyrazolyl, benzotriazol-1-yl) a decyl group (preferably a decyl group having a carbon number of 3 to 38, more preferably a decyl group having a carbon number of 3 to 18, such as a trimethyl decyl group, a triethyl decyl group, a tributyl decyl group , Tributyl dimethyl decyl, tert-hexyl dimethyl decyl), hydroxy, cyano, nitro, alkoxy (preferably alkoxy having a carbon number of 1 to 48, more preferably Alkoxy having 1 to 24 carbon atoms, such as methoxy, ethoxy, 1-butoxy, 2-butoxy, isopropoxy, tert-butoxy, dodecyloxy, and It may also be a cycloalkoxy group such as a cyclopentyloxy group, a cyclohexyloxy group, an aryloxy group (preferably an aryloxy group having a carbon number of 6 to 48, more preferably a carbon number of 6 to 24). An aryloxy group such as a phenoxy group, a 1-naphthyloxy group, a heterocyclic oxy group (preferably a heterocyclic oxy group having 1 to 32 carbon atoms, more preferably a heterocyclic ring having 1 to 18 carbon atoms) An oxy group such as 1-phenyltetrazole-5-oxy, 2-tetrahydropyranyloxy), a decyloxy group (preferably a decyloxy group having a carbon number of 1 to 32, more preferably a decyloxy group having a carbon number of 1 to 18, for example Trimethyldecyloxy, tert-butyldimethylsilyloxy, diphenylmethylnonyloxy), mercaptooxy (preferably a decyloxy group having a carbon number of 2 to 48, more Preferred is a fluorenyloxy group having a carbon number of 2 to 24, such as an ethoxymethyloxy group, a trimethylethenyloxy group, a benzhydryloxy group, a decyloxy group, and an alkoxycarbonyl group. An oxy group (preferably an alkoxycarbonyloxy group having a carbon number of 2 to 48, more preferably an alkoxycarbonyloxy group having a carbon number of 2 to 24, such as an ethoxycarbonyloxy group, a third butyl group An oxycarbonyloxy group, and may also be a cycloalkoxycarbonyloxy group such as a cyclohexyloxycarbonyloxy group, an aryloxycarbonyloxy group (preferably an aryloxycarbonyl group having a carbon number of 7 to 32). An oxy group, more preferably an aryloxycarbonyloxy group having a carbon number of 7 to 24, such as a phenoxycarbonyloxy group,

Aminomethyl methoxyl (preferably an aminomethyl decyloxy group having a carbon number of 1 to 48, more preferably an amine carbaryloxy group having a carbon number of 1 to 24, such as N,N-dimethyl Base amine methyl decyloxy, N-butylamine methyl decyloxy, N-phenylamine methyl decyloxy, N-ethyl-N-phenylamine methyl decyloxy), amine sulfonium sulfonate a oxy group (preferably an sulfonyloxy group having a carbon number of 1 to 32, more preferably an sulfonyloxy group having a carbon number of 1 to 24, such as N,N-diethylamine sulfonate a mercaptooxy group, an N-propylaminesulfonyloxy group, an alkylsulfonyloxy group (preferably an alkylsulfonyloxy group having a carbon number of 1 to 38, more preferably a carbon number) Is an alkylsulfonyloxy group of 1 to 24, such as methylsulfonyloxy, hexadecanosulfonyloxy, cyclohexylsulfonyloxy), arylsulfonyloxy (more) Preferred is an arylsulfonyloxy group having a carbon number of 6 to 32, more preferably an arylsulfonyloxy group having a carbon number of 6 to 24, such as a phenylsulfonyloxy group, or a fluorenyl group ( Preferred is a fluorenyl group having a carbon number of from 1 to 48, more preferably a fluorenyl group having a carbon number of from 1 to 24, such as a fluorenyl group, an ethyl fluorenyl group, a trimethyl ethane group, a benzamidine group, and ten groups. Tetradecyl, cyclohexyl), alkoxy Group (preferably having a carbon number 2 to 48 alkoxycarbonyl, more preferably an alkoxycarbonyl group having 2 to 24 carbon atoms, such as methoxycarbonyl, ethoxycarbonyl, octadecyloxycarbonyl, cyclohexyloxycarbonyl, 2 , 6-di-t-butyl-4-methylcyclohexyloxycarbonyl), aryloxycarbonyl (preferably an aryloxycarbonyl group having a carbon number of 7 to 32, more preferably a carbon number of 7) ~24 aryloxycarbonyl group, such as phenoxycarbonyl), amine mercapto group (preferably, the aminomethyl group having a carbon number of 1 to 48, more preferably an amine formazan having a carbon number of 1 to 24) Base, for example, an amine methyl sulfonyl group, N,N-diethylamine methyl fluorenyl group, N-ethyl-N-octylamine methyl fluorenyl group, N,N-dibutylamine methyl fluorenyl group, N-propyl group Aminomethyl sulfhydryl, N-phenylamine methyl hydrazino, N-methyl-N-phenylamine methyl fluorenyl, N,N-dicyclohexylamine fluorenyl), amine group (preferably carbon number) It is an amino group of 32 or less, more preferably an amine group having a carbon number of 24 or less, such as an amine group, a methylamino group, an N,N-dibutylamino group, a tetradecylamino group, a 2-ethyl group. a hexylamino group, a cyclohexylamino group, an anilino group (preferably an anilino group having a carbon number of 6 to 32, more preferably an anilino group having a carbon number of 6 to 24, such as an anilino group or an N-methylaniline. Heterocycle a base (preferably a heterocyclic amino group having 1 to 32 carbon atoms, more preferably a heterocyclic amino group having 1 to 18 carbon atoms, such as a 4-pyridylamino group) or a carbonamide group. (preferably a carboguanamine group having a carbon number of 2 to 48, more preferably a carboxyamino group having a carbon number of 2 to 24, such as an acetamino group, a benzamidine group or a tetradecylamino group. , trimethylacetamido, cyclohexylamino), ureido (preferably a ureido group having a carbon number of 1 to 32, more preferably a ureido group having a carbon number of 1 to 24, such as a ureido group , N,N-dimethylureido, N-phenylureido), quinone imine (preferably a quinone imine having a carbon number of 36 or less, more preferably a carbon number of 24 or less) An imido group, such as N-succinimide group, N-phthalimido group, alkoxycarbonylamino group (preferably an alkoxycarbonylamino group having a carbon number of 2 to 48, More preferably, the carbon number is 2~ Alkoxycarbonylamino group of 24, such as methoxycarbonylamino group, ethoxycarbonylamino group, tert-butoxycarbonylamino group, octadecyloxycarbonylamino group, cyclohexyloxycarbonylamino group) An aryloxycarbonylamino group (preferably an aryloxycarbonylamino group having a carbon number of 7 to 32, more preferably an aryloxycarbonylamino group having a carbon number of 7 to 24, such as phenoxycarbonylamine a sulfonamide group (preferably a sulfonamide group having a carbon number of 1 to 48, more preferably a sulfonamide group having a carbon number of 1 to 24, such as methanesulfonamido, Butanesulfonamido, benzenesulfonamido, hexadecanesulfonamido, cyclohexanesulfonamido, aminesulfonylamino (preferably It is an aminesulfonylamino group having a carbon number of 1 to 48, more preferably an aminesulfonylamino group having a carbon number of 1 to 24, such as N,N-dipropylaminesulfonylamino group, N- Ethyl-N-dodecylamine sulfonylamino), azo (preferably an azo group having a carbon number of 1 to 32, more preferably an azo group having a carbon number of 1 to 24) , for example, phenyl azo, 3-pyrazolylazo), alkylthio (preferred An alkylthio group having 1 to 48 carbon atoms, more preferably an alkylthio group having 1 to 24 carbon atoms, such as methylthio, ethylthio, octylthio, cyclohexylthio) or arylthio( Preferred are arylthio groups having a carbon number of from 6 to 48, more preferably an arylthio group having a carbon number of from 6 to 24, such as a phenylthio group, or a heterocyclic thio group (preferably having a carbon number of from 1 to 32). a heterocyclic thio group, more preferably a heterocyclic thio group having 1 to 18 carbon atoms, such as a 2-benzothiazolylthio group, a 2-pyridylthio group, a 1-phenyltetrazolylthio group, An alkylsulfinyl group (preferably an alkylsulfinyl group having a carbon number of 1 to 32, more preferably an alkylsulfinyl group having a carbon number of 1 to 24, such as dodecylsulfinium) An arylsulfinyl group (preferably an aryl group having a carbon number of 6 to 32) A sulfinyl group, more preferably an arylsulfinyl group having a carbon number of 6 to 24, such as a phenylsulfinyl group, or an alkylsulfonyl group (preferably an alkane having a carbon number of 1 to 48) More preferably, the alkylsulfonyl group is an alkylsulfonyl group having a carbon number of 1 to 24, such as methylsulfonyl, ethylsulfonyl, propylsulfonyl, butylsulfonyl, isopropyl. Sulfonyl, 2-ethylhexylsulfonyl, hexadecylsulfonyl, octylsulfonyl, cyclohexylsulfonyl), arylsulfonyl (preferably, carbon number 6 to 48) The arylsulfonyl group, more preferably an arylsulfonyl group having a carbon number of 6 to 24, such as a phenylsulfonyl group, a 1-naphthylsulfonyl group, an aminesulfonyl group (preferably a carbon) The number of the sulfonyl group of 32 or less, more preferably the sulfonyl group having a carbon number of 24 or less, such as an amine sulfonyl group, N, N-dipropylamine sulfonyl group, N-ethyl-N- Dodecylamine sulfonyl, N-ethyl-N-phenylamine sulfonyl, N-cyclohexylamine sulfonyl), sulfo, phosphonyl (preferably, carbon number is a phosphonium group of 1 to 32, more preferably a phosphonium group having a carbon number of 1 to 24, such as a phenoxyphosphonium group, an octyloxyphosphonium group, a phenylphosphonium group, or a phosphinium decylamine. Phosphine Oylamino) (preferably a phosphinylamino group having a carbon number of 1 to 32, more preferably a phosphinylamino group having a carbon number of 1 to 24, such as a diethoxyphosphine decylamino group , dioctyloxyphosphine decylamino).

When the above monovalent group is a group which can be further substituted, it may be further substituted by any of the above groups. Further, in the case of having two or more substituents, the substituents may be the same or different.

In the formula (I), R ¹ and R ² , R ² and R ³ , R ⁴ and R ⁵ , and R ⁵ and R ⁶ may each independently bond to each other to form 5 members, 6 members, or 7 Ring of staff. Further, the ring formed has a saturated ring or an unsaturated ring. Examples of the saturated or unsaturated ring of the 5-, 6-, or 7-membered compounds include a pyrrole ring, a furan ring, a thiophene ring, a pyrazole ring, an imidazole ring, a triazole ring, an oxazole ring, a thiazole ring, and a pyrrolidine ring. The piperidine ring, the cyclopentene ring, the cyclohexene ring, the benzene ring, the pyridine ring, the pyrazine ring, and the pyridazine ring are preferably a benzene ring or a pyridine ring.

Further, in the case where the formed ring of 5 members, 6 members, and 7 members is a group which may be further substituted, it may be substituted by any of the substituents R; in the case of being substituted by 2 or more substituents The substituents may be the same or different.

Further, in the case where R ⁷ is a halogen atom, an alkyl group, an aryl group or a heterocyclic group in the formula (I), the preferred range is the same as the above-mentioned halogen atom or alkane of R ¹ to R ⁶ . The preferred ranges of the aryl group, the aryl group or the heterocyclic group are the same.

In the formula (I), as the above R ¹ and R ⁶ , preferred among the above are an alkylamino group, an arylamino group, a carboxy oxime amino group, a ureido group, a quinone imine group, an alkoxycarbonyl group. Amino, sulfonylamino, more preferably carboxy oxime, ureido, alkoxycarbonylamino, sulfonylamino, more preferably carboxy oxime, ureido, alkoxycarbonylamine The sulfonium amide group is preferably a carboxy guanamine group or a ureido group.

In the formula (I), as the above R ² and R ⁵ , preferred among the above are an alkoxycarbonyl group, an aryloxycarbonyl group, an aminecarbamyl group, an alkylsulfonyl group, an arylsulfonyl group, Nitrile group, quinone imine group, amine carbaryl sulfonyl group, more preferably alkoxycarbonyl group, aryloxycarbonyl group, amine carbaryl group, alkyl sulfonyl group, nitrile group, quinone imine group, amine Further, a mercaptosulfonyl group is more preferably an alkoxycarbonyl group, an aryloxycarbonyl group, an aminecarbamyl group, a nitrile group, a quinone imido group, an amine formylsulfonyl group, and particularly preferably an alkoxy group. Carbonyl group, aryloxycarbonyl group, amine carbenyl group.

In the formula (I), as the above R ³ and R ⁴ , preferred among the above are substituted or unsubstituted alkyl, substituted or unsubstituted aryl, substituted or unsubstituted. The heterocyclic group is more preferably a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group.

In the general formula (I), when R ³ and R ⁴ represent an alkyl group, the alkyl group is preferably a linear, branched or cyclic substituted or unsubstituted carbon number of 1 to 12. The alkyl group, more specifically, for example, methyl, ethyl, n-propyl, isopropyl, cyclopropyl, n-butyl, isobutyl, tert-butyl, cyclobutyl, cyclopentyl, a cyclohexyl group and a benzyl group; more preferably a branched chain having a carbon number of 1 to 12, or a cyclic substituted or unsubstituted alkyl group, and more specifically, for example, an isopropyl group, a cyclopropyl group, Isobutyl, tert-butyl, cyclobutyl, cyclopentyl, cyclohexyl; further more preferably a substituted or unsubstituted alkyl group having a carbon number of 1 to 12, or more, more specific Examples thereof include an isopropyl group, a cyclopropyl group, an isobutyl group, a tert-butyl group, a cyclobutyl group, and a cyclohexyl group.

In the general formula (I), the aryl group in the case where R ³ and R ⁴ represent an aryl group is preferably a substituted or unsubstituted phenyl group, a substituted or unsubstituted naphthyl group, more preferably It is a substituted or unsubstituted phenyl group.

When R ³ and R ⁴ represent a heterocyclic group, the heterocyclic group preferably includes a substituted or unsubstituted 2-thienyl group, a substituted or unsubstituted 4-pyridyl group, substituted or unsubstituted. Substituted 3-pyridyl, substituted or unsubstituted 2-pyridyl, substituted or unsubstituted 2-furyl, substituted or unsubstituted 2-pyrimidinyl, substituted or unsubstituted 2-benzothiazolyl, substituted or unsubstituted 1-imidazolyl, substituted or unsubstituted 1-pyrazolyl, substituted or unsubstituted benzotriazol-1-yl, Preferred are exemplified by substituted or unsubstituted 2-thienyl, substituted or unsubstituted 4-pyridyl, substituted or unsubstituted 2-furyl, substituted or unsubstituted 2-pyrimidine Base, substituted or unsubstituted 1-pyridyl.

Next, a metal atom or a metal compound which forms a dipyrromethene-based metal-miscible compound will be described.

As the metal or metal compound, any metal atom or metal compound which can form a complex compound may be any, including a divalent metal atom, a divalent metal oxide, a divalent metal hydroxide, or a divalent metal chloride. . For example, in addition to Zn, Mg, Si, Sn, Rh, Pt, Pd, Mo, Mn, Pb, Cu, Ni, Co, Fe, B, etc., also includes AlCl ₃ , InCl ₃ , FeCl ₂ , TiCl ₂ , SnCl ₂ Metal chlorides such as SiCl ₂ and GeCl ₂ , metal oxides such as TiO and VO, and metal hydroxides such as Si(OH) ₂ .

Among these, Fe, Zn, Mg, Si, Pt, Pd, Mo, Mn, and Cu are preferred from the viewpoints of stability, spectral characteristics, heat resistance, light resistance, and suitability of the self-aligning compound. , Ni, Co, TiO, B, or VO, more preferably Fe, Zn, Mg, Si, Pt, Pd, Cu, Ni, Co, B, or VO, and most preferably Fe, Zn, Cu, Co , B, or VO (V=O). Particularly preferred among these are Zn.

The dipyrromethene-based metal-doped compound in which the compound represented by the above formula (I) is bonded to a metal atom or a metal compound is preferably shown below. That is, in the general formula (I), R ¹ and R ⁶ each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a decyl group, a hydroxyl group, a cyano group, an alkoxy group, or the like. Aryloxy, heterocyclic oxy, fluorenyl, alkoxycarbonyl, aminemethanyl, amine, anilino, heterocyclic amine, carboxy oxime, ureido, quinone, alkoxycarbonyl Amino, aryloxycarbonylamino, sulfonylamino, azo, alkylthio, arylthio, heterocyclic thio, alkylsulfonyl, arylsulfonyl, or phosphinium decylamine Phosphonyl amino, R ² and R ⁵ each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a hydroxyl group, a cyano group, a nitro group, an alkoxy group, an aryloxy group, Heterocyclicoxy, fluorenyl, alkoxycarbonyl, aryloxycarbonyl, aminecarboxamido, oximeimido, alkoxycarbonylamino, sulfonylamino, azo, alkylthio, aromatic sulfur a heterocyclic thio group, an alkylsulfonyl group, an arylsulfonyl group, or an amine sulfonyl group, and R ³ and R ⁴ each independently represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an aryl group, or a hetero Cyclic group, decyl group, hydroxyl group, cyanide , alkoxy, aryloxy, heterocyclic oxy, decyl, alkoxycarbonyl, amine carbaryl, anilino, carboxy oxime, ureido, quinone, alkoxycarbonylamino, Sulfonyl, azo, alkylthio, arylthio, heterocyclic thio, alkylsulfonyl, arylsulfonyl, sulfonyl, or phosphinylamino, R ⁷ represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, or a heterocyclic group, and a metal atom or a metal compound means Zn, Mg, Si, Pt, Pd, Mo, Mn, Cu, Ni, Co, TiO, B, or VO. The form of representation.

A more preferred form of the dipyrromethene-based metal-doped compound is as follows. That is, in the above formula (I), R ¹ and R ⁶ each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a cyano group, a decyl group or an alkoxycarbonyl group. , Aminomethyl, Amino, Heterocyclic Amine, Carboxylammonium, Urea, Iminoimine, Alkoxycarbonylamino, Aryloxycarbonylamino, Sulfonylamino, Azo, Alkylsulfonyl, arylsulfonyl, or phosphiniumamino, R ² and R ⁵ each independently represent alkyl, alkenyl, aryl, heterocyclyl, cyano, nitro, fluorenyl An alkoxycarbonyl group, an aryloxycarbonyl group, an amine carbenyl group, a fluorenylene group, an alkylsulfonyl group, an arylsulfonyl group, or an aminesulfonyl group, and R ³ and R ⁴ each independently represent a hydrogen atom. An alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a cyano group, a decyl group, an alkoxycarbonyl group, an amine carbaryl group, a carbamoylamino group, a ureido group, a quinone imine group, an alkoxycarbonylamino group, Sulfonyl, alkylthio, arylthio, heterocyclic thio, alkylsulfonyl, arylsulfonyl, or aminesulfonyl, R ⁷ represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group Or a heterocyclic group, a metal atom or a metal compound means Zn Mg, Si, Pt, Pd, Cu, Ni, Co, or form B of VO.

A preferred form of the dipyrromethene-based metal-doped compound in which the compound represented by the above formula (I) is bonded to a metal atom or a metal compound is a compound represented by the following formula (I-3). .

In the above formula (I-3), R ² , R ³ , R ⁴ and R ⁵ each independently represent a hydrogen atom or a substituent, and R ⁷ represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, Or a heterocyclic group. R ⁸ and R ⁹ each independently represent an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylamino group, an arylamino group or a heterocyclic amino group. Ma represents a metal atom or a metal compound. X ³ and X ⁴ each independently represent NR ^a (R ^a represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkylsulfonyl group, or an arylsulfonyl group), an oxygen atom Or a sulfur atom. Y ¹ and Y ² each independently represent NR ^b (R ^b represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkylsulfonyl group, or an arylsulfonyl group), an oxygen atom , sulfur atom, or carbon atom. X ⁵ represents a group which can be bonded to Ma, and a represents 0, 1, or 2. R ⁸ and Y ¹ may also be bonded to each other to form a ring of 5 members, 6 members, or 7 members, and R ⁹ and Y ² may be bonded to each other to form a ring of 5 members, 6 members, or 7 members.

Formula (I-3) in the R ² ~ R ^5, and R ⁷ in the general formula (I), the R ² ~ R ^5, and R ⁷ is synonymous, the preferred shape is also the same.

In the formula (I-3), Ma represents a metal or a metal compound, and is synonymous with a metal atom or a metal compound in a complex compound in which the compound represented by the formula (I) is bonded to a metal atom or a metal compound. The preferred range is also the same.

In the formula (I-3), R ⁸ and R ⁹ each independently represent an alkyl group (preferably a linear, branched, or cyclic alkyl group having a carbon number of 1 to 36, more preferably carbon). a linear, branched, or cyclic alkyl group of 1 to 12, such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, hexyl, 2-ethyl a hexyl group, a dodecyl group, a cyclopropyl group, a cyclopentyl group, a cyclohexyl group, a 1-adamantyl group, an alkenyl group (preferably an alkenyl group having a carbon number of 2 to 24, more preferably a carbon number of 2 to 12 alkenyl groups such as vinyl, allyl, 3-buten-1-yl), aryl (preferably an aryl group having 6 to 36 carbon atoms, more preferably a carbon number of 6) An aryl group of ~18, such as a phenyl group, a naphthyl group, a heterocyclic group (preferably a heterocyclic group having 1 to 24 carbon atoms, more preferably a heterocyclic group having 1 to 12 carbon atoms, for example, 2 -thienyl, 4-pyridyl, 2-furyl, 2-pyrimidinyl, 1-pyridyl, 2-benzothiazolyl, 1-imidazolyl, 1-pyrazolyl, benzotriazol-1-yl And an alkoxy group (preferably an alkoxy group having a carbon number of 1 to 36, more preferably an alkoxy group having a carbon number of 1 to 18, such as a methoxy group, an ethoxy group, a propoxy group, or a butyl group) Oxyl, hexyloxy, 2- a hexyloxy group, a dodecyloxy group, a cyclohexyloxy group, an aryloxy group (preferably an aryloxy group having a carbon number of 6 to 24, more preferably an aryloxy group having a carbon number of 1 to 18) , for example, phenoxy, naphthyloxy), alkylamino group (preferably an alkylamino group having 1 to 36 carbon atoms, more preferably an alkylamino group having 1 to 18 carbon atoms, such as a Amino group, ethylamino group, propylamino group, butylamino group, hexylamino group, 2-ethylhexylamino group, isopropylamino group, tert-butylamino group, third octylamino group , cyclohexylamino, N,N-diethylamino, N,N-dipropylamino, N,N-dibutylamino, N-methyl-N-ethylamino), aromatic Alkylamino group (preferably an arylamine group having a carbon number of 6 to 36, more preferably an arylamine group having a carbon number of 6 to 18, such as a phenylamino group, a naphthylamino group, N, N a -diphenylamino group, N-ethyl-N-phenylamino group, or a heterocyclic amine group (preferably a heterocyclic amino group having 1 to 24 carbon atoms, more preferably a carbon number of 1) a heterocyclic amino group of ~12, such as 2-aminopyrrolyl, 3-aminopyrazolyl, 2-aminopyridyl, 3-aminopyridyl).

In the formula (I-3), an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylamino group, an arylamino group or a hetero group represented by R ⁸ and R ⁹ . When the cyclic amino group is a group which may be further substituted, it may be substituted by any of the substituents R, and when substituted by two or more substituents, the substituents may be the same or different.

In the formula (I-3), X ³ and X ⁴ each independently represent NR ^a , an oxygen atom or a sulfur atom. R ^a represents a hydrogen atom or an alkyl group (preferably a linear, branched or cyclic alkyl group having a carbon number of 1 to 36, more preferably a linear or branched chain having a carbon number of 1 to 12, Or a cyclic alkyl group, such as methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, hexyl, 2-ethylhexyl, dodecyl, cyclopropyl, Cyclopentyl, cyclohexyl, 1-adamantyl), alkenyl (preferably an alkenyl group having 2 to 24 carbon atoms, more preferably an alkenyl group having 2 to 12 carbon atoms, such as a vinyl group or an alkene group) a propyl group, a 3-buten-1-yl group, an aryl group (preferably an aryl group having a carbon number of 6 to 36, more preferably an aryl group having a carbon number of 6 to 18, such as a phenyl group or a naphthyl group; a heterocyclic group (preferably a heterocyclic group having 1 to 24 carbon atoms, more preferably a heterocyclic group having 1 to 12 carbon atoms, such as 2-thienyl, 4-pyridyl, 2-furan) , 2-pyrimidinyl, 1-pyridyl, 2-benzothiazolyl, 1-imidazolyl, 1-pyrazolyl, benzotriazol-1-yl), fluorenyl (preferably, carbon number is a thiol group of 1 to 24, more preferably a fluorenyl group having a carbon number of 2 to 18, such as an ethyl group, a trimethylethyl group, a 2-ethylhexyl group, a benzamidine group or a cyclohexyl group. Alkyl sulfonate ( Preferred is an alkylsulfonyl group having 1 to 24 carbon atoms, more preferably an alkylsulfonyl group having 1 to 18 carbon atoms, such as methylsulfonyl, ethylsulfonyl, isopropyl a sulfonyl group, a cyclohexylsulfonyl group, an arylsulfonyl group (preferably an arylsulfonyl group having a carbon number of 6 to 24, more preferably an arylsulfonyl group having a carbon number of 6 to 18) Base, for example, phenylsulfonyl, naphthylsulfonyl). Further, in the case where R ^a may be substituted, it may be further substituted by a substituent, and when substituted by a plurality of substituents, the substituents may be the same or different.

X ³ and X ^{4 are} preferably each independently an oxygen atom or a sulfur atom, and X ³ and X ^{4 are} particularly preferably all oxygen atoms.

In the formula (I-3), Y ¹ and Y ² each independently represent NR ^b , a sulfur atom or a carbon atom, and R ^b has the same meaning as R ^a in the X ³ .

Y ¹ and Y ^{2 are} preferably each independently NR ^b (R ^b is a hydrogen atom or an alkyl group having 1 to 8 carbon atoms), and Y ¹ and Y ^{2 are} particularly preferably all NH.

In the formula (I-3), R ⁸ and Y ¹ may be bonded to each other such that R ⁸ , Y ¹ and a carbon atom together form a 5-membered ring (for example, cyclopentane, pyrrolidine, tetrahydrofuran, dioxane). Pentane (dioxolane, tetrahydrothiophene, pyrrole, furan, thiophene, anthracene, benzofuran, benzothiophene), 6-membered ring (eg cyclohexane, piperidine, piperazine, morpholine, tetrahydropyran) , dioxane, pentamethylene sulfide, dithiane, benzene, piperidine, piperazine, pyridazine, quinoline, quinazoline, or 7-membered ring (eg, cycloglycan) Alkane, hexamethyleneimine).

In the formula (I-3), R ⁹ and Y ² may be bonded to each other such that R ⁹ , Y ² and a carbon atom together form a ring of 5 members, 6 members, or 7 members. The ring of the five members, the six members, and the seven members formed may be a ring in which one of the bonds formed by R ⁸ and Y ¹ and a carbon atom is changed to a double bond.

In the general formula (I-3), when R ⁸ and Y ¹ and R ⁹ and Y ^{2 are} bonded to each other, the ring of 5 members, 6 members, and 7 members is a ring which can be further substituted, and can be When the substituent described in any of the substituents R is substituted by two or more substituents, the substituents may be the same or different.

In the formula (I-3), X ⁵ represents a group which may be bonded to Ma, and examples thereof are the same as those of X ² in the above formula (I). a represents 0, 1, or 2.

Preferred embodiments of the compound represented by the formula (I-3) are shown below. That is, R ² to R ⁵ and R ⁷ are each a preferred form of R ² to R ⁵ and R ⁷ in the formula (I), and Ma is a metal forming the dipyrromethene metal complex compound. In a preferred embodiment of the atom or metal compound, X ³ and X ⁴ are each independently NR ^a (R ^a is a hydrogen atom, an alkyl group, a heterocyclic group) or an oxygen atom, and Y ¹ and Y ² are each independently NR ^b (R ^b is a hydrogen atom or an alkyl group, a nitrogen atom or a carbon atom, X ⁵ is a group bonded via an oxygen atom or a nitrogen atom, and R ⁸ and R ⁹ each independently represent an alkyl group, an aryl group or a heterocyclic ring. a group, an alkoxy group, or an alkylamine group, or R ⁸ and Y ¹ are bonded to each other to form a 5- or 6-membered ring, and R ⁹ and Y ² are bonded to each other to form a 5-membered, 6-membered ring, and a represents 0. Or the form of 1.

A more preferred form of the compound represented by the formula (I-3) is shown below. That is, R ² to R ⁵ and R ⁷ are each a preferred form of R ² to R ⁵ and R ⁷ in the formula (I), and Ma is a metal forming the dipyrromethene metal complex compound In a preferred embodiment of the atom or metal compound, X ³ and X ⁴ are oxygen atoms, Y ¹ is NH, Y ² is a nitrogen atom, and X ⁵ is a group bonded via an oxygen atom or a nitrogen atom, R ⁸ and R ⁹ Each independently represents an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, or an alkylamino group, or R ⁸ and Y ¹ are bonded to each other to form a 5- or 6-membered ring, and R ⁹ and Y ² are bonded to each other. A 5-member, 6-member ring is formed, and a represents a form of 0 or 1.

The compound represented by the above formula (I-3) is particularly preferable as the dye of the colored photosensitive composition of the present invention.

Specific examples of the dipyrromethene-based metal-substituted compound in which the compound represented by the above formula (I) used in the present invention is bonded to a metal atom or a metal compound are shown below. However, the present invention is not limited to these specific examples.

The exemplified compound (1) to the exemplified compound (39) are also exemplified compounds of the formula (I-3).

The exemplified compound (Ia-3) to the exemplified compound (Ia-83), the exemplified compound (Ia-1) to the exemplified compound (IIa-20), and the exemplified compound (I) are described in JP-A-2008-292970. -1) to exemplified compound (I-36), exemplified compound (II-1) to exemplified compound (II-11), and exemplified compound (III-1) to exemplified compound (III-103), Japanese Patent No. 3324279 The exemplified compound (I-1) to the exemplified compound (I-35), and the exemplified compound (I-1) to the exemplified compound (I-13) described in Japanese Patent No. 3279035, Japanese Patent Laid-Open No. 11 Illustrative compound (2-1) to exemplified compound (2-32) described in -256057, Exemplary compound (3-1) to exemplified compound (3-32), exemplified compound (4-1) to exemplified compound (4-26), and exemplified compound (5-1) to exemplified compound (5-26), Japan The exemplified compound (I-1) to the exemplified compound (I-6) and the exemplified compound (VII-1) to the exemplified compound (VII-8) described in JP-A-2005-77953, Japanese Patent Laid-Open No. Hei 11-352686 The exemplified compound (1-1) to the exemplified compound (1-45) described in the above, the exemplified compound (1-1) to the exemplified compound (1-50) described in JP-A-2000-19729, and the Japanese patent An exemplary compound (1-1) to an exemplified compound (1-45), which is described in JP-A-H11-352685, is a dipyrromethene group in which a compound represented by the formula (I) is bonded to a metal atom or a metal compound. An example of a metal miscible compound.

(pigment)

The colored photosensitive composition of the present invention may further comprise a pigment as a colorant.

Suitable pigments include the following pigments. However, the invention is not limited to these pigments.

CI Pigment Yellow 1, CI Pigment Yellow 2, CI Pigment Yellow 3, CI Pigment Yellow 4, CI Pigment Yellow 5, CI Pigment Yellow 6, CI Pigment Yellow 10, CI Pigment Yellow 11, CI Pigment Yellow 12, CI Pigment Yellow 13, CI Pigment Yellow 14, CI Pigment Yellow 15, CI Pigment Yellow 16, CI Pigment Yellow 17, CI Pigment Yellow 18, CI Pigment Yellow 20, CI Pigment Yellow 24, CI Pigment Yellow 31, CI Pigment Yellow 32, CI Pigment Yellow 34, CI Pigment Yellow 35, CI Pigment Yellow 35:1, CI Pigment Yellow 36, CI Pigment Yellow 36:1, CI Pigment Yellow 37, CI Pigment Yellow 37:1, CI Pigment Yellow 40, CI Pigment Yellow 42, CI Pigment Yellow 43 , CI Pigment Yellow 53, CI Pigment Yellow 55, CI Pigment Yellow 60, CI Pigment Yellow 61, CI Pigment Yellow 62, CI Pigment Yellow 63, CI Pigment Yellow 65, CI Pigment Yellow 73, CI Pigment Yellow 74, CI Pigment Yellow 77, CI Pigment Yellow 81, CI Pigment Yellow 83, CI Pigment Yellow 86, CI Pigment Yellow 93, CI Pigment Yellow 94, CI Pigment Yellow 95, CI Pigment Yellow 97, CI Pigment Yellow 98, CI Pigment Yellow 100, CI Pigment Yellow 101, CI Pigment Yellow 104, CI Pigment Yellow 106, CI Pigment Yellow 108, CI Pigment Yellow 109, CI Pigment Yellow 110, CI Pigment Yellow 113, CI Pigment Yellow 114, CI Pigment Yellow 115, CI Pigment Yellow 116, CI Pigment Yellow 117, CI Pigment Yellow 118, CI Pigment Yellow 119, CI Pigment Yellow 120, CI Pigment Yellow 123, CI Pigment Yellow 125, CI Pigment Yellow 126, CI Pigment Yellow 127, CI Pigment Yellow 128, CI Pigment Yellow 129, CI Pigment Yellow 137, CI Pigment Yellow 138, CI Pigment Yellow 139, CI Pigment Yellow 147, CI Pigment Yellow 148, CI Pigment Yellow 150, CI Pigment Yellow 151, CI Pigment Yellow 152, CI Pigment Yellow 153, CI Pigment Yellow 154, CI Pigment Yellow 155, CI Pigment Yellow 156, CI Pigment Yellow 161, CI Pigment Yellow 162, CI Pigment Yellow 164, CI Pigment Yellow 166, CI Pigment Yellow 167, CI Pigment Yellow 168, CI Yan Yellow 169, CI Pigment Yellow 170, CI Pigment Yellow 171, CI Pigment Yellow 172, CI Pigment Yellow 173, CI Pigment Yellow 174, CI Pigment Yellow 175, CI Pigment Yellow 176, CI Pigment Yellow 177, CI Pigment Yellow 179, CI Pigment Yellow 180, CI Pigment Yellow 181, CI Pigment Yellow 182, CI Pigment Yellow 185, CI Pigment Yellow 187, CI Pigment Yellow 188, CI Pigment Yellow 193, CI Pigment Yellow 194, CI Pigment Yellow 199, CI Pigment Yellow 213, CI Pigment Yellow 214, etc. CI Pigment Orange 2, CI Pigment Orange 5, CI Pigment Orange 13, CI Pigment Orange 16, CI Pigment Orange 17: 1, CI Pigment Orange 31, CI Pigment Orange 34, CI Pigment Orange 36, CI Pigment Orange 38, CI Pigment Orange 43, CI Pigment Orange 46, CI Pigment Orange 48, CI Pigment Orange 49, CI Pigment Orange 51, CI Pigment Orange 52, CI Pigment Orange 55, CI Pigment Orange 59, CI Pigment Orange 60, CI Pigment Orange 61, CI Pigment Orange 62, CI Pigment Orange 64, CI Pigment Orange 71, CI Pigment Orange 73, etc. CI Pigment Red 1, CI Pigment Red 2, CI Pigment Red 3, CI Pigment Red 4, CI Pigment Red 5, CI Pigment Red 6, CI Pigment Red 7, CI Pigment Red 9, CI Pigment Red 10, CI Pigment Red 14, CI Pigment Red 17, CI Pigment Red 22, CI Pigment Red 23, CI Pigment Red 31, CI Pigment Red 38, CI Pigment Red 41, CI Pigment Red 48:1, CI Pigment Red 48:2, CI Pigment Red 48:3 , CI Pigment Red 48:4, CI Pigment Red 49, CI Pigment Red 49:1, CI Pigment Red 49:2, CI Pigment Red 52:1, CI Pigment Red 52:2, CI Pigment Red 53:1, CI Pigment Red 57:1, CI Pigment Red 60:1, CI Pigment Red 63:1, CI Pigment Red 66, CI Pigment Red 67, CI Pigment Red 81:1, CI Pigment Red 81:2, CI Pigment Red 81:3, CI Pigment Red 83, CI Pigment Red 88, CI Pigment Red 90, CI Pigment Red 105, CI Pigment Red 112, CI Pigment Red 119, CI Pigment Red 122, CI Pigment Red 123, CI Pigment Red 144, CI Pigment Red 146, CI Pigment Red 149, CI Pigment Red 150, CI Pigment Red 155, CI Pigment Red 166, CI Pigment Red 168, CI Pigment Red 169, CI Pigment Red 170, CI Pigment Red 171 , CI Pigment Red 172, CI Pigment Red 175, CI Pigment Red 176, CI Pigment Red 177, CI Pigment Red 178, CI Pigment Red 179, CI Pigment Red 184, CI Pigment Red 185, CI Pigment Red 187, CI Pigment Red 188 , CI Pigment Red 190, CI Pigment Red 200, CI Pigment Red 202, CI Pigment Red 206, CI Pigment Red 207, CI Pigment Red 208, CI Pigment Red 209, CI Pigment Red 210, CI Pigment Red 216, CI Pigment Red 220 , CI Pigment Red 224, CI Pigment Red 226, CI Pigment Red 242, CI Pigment Red 246, CI Pigment Red 254, C.I. Pigment Red 255, C.I. Pigment Red 264, C.I. Pigment Red 270, C.I. Pigment Red 272, C.I. Pigment Red 279, C.I. Pigment Green 7, C.I. Pigment Green 10, C.I. Pigment Green 36, C.I. Pigment Green 37, C.I. Pigment Green 58, C.I. Pigment Violet 1, C.I. Pigment Violet 19, C.I. Pigment Violet 23, C.I. Pigment Violet 27, C.I. Pigment Violet 32, C.I. Pigment Violet 37, C.I. Pigment Violet 42, CI Pigment Blue 1, CI Pigment Blue 2, CI Pigment Blue 15, CI Pigment Blue 15:1, CI Pigment Blue 15:2, CI Pigment Blue 15:3, CI Pigment Blue 15:4, CI Pigment Blue 15:6, CI Pigment Blue 16, CI Pigment Blue 22, CI Pigment Blue 60, CI Pigment Blue 64, CI Pigment Blue 66, CI Pigment Blue 79, CI Pigment Blue 80, C.I. Pigment Black 1.

In particular, when the colored photosensitive composition of the present invention contains the dipyrromethene-based metal-doped compound as a dye, it is preferable to contain a blue pigment in order to form a blue colored pattern. It is preferred to contain a phthalocyanine blue pigment as a pigment.

Suitable phthalocyanine blue pigments include CI Pigment Blue 15, CI Pigment Blue 15:1, CI Pigment Blue 15:2, CI Pigment Blue 15:3, CI Pigment Blue 15:4, CI Pigment Blue 15:6, CI Pigment Blue 16, CI Pigment Blue 17:1, CI Pigment Blue 75, and CI Pigment Blue 79, and the like. Among them, C.I. Pigment Blue 15:6 is excellent in heat resistance, light resistance, and contrast, and can be used more suitably.

The content of the pigment used in the coloring photosensitive composition of the present invention is preferably 20% by mass or more and 90% based on the total content of the dye and the pigment. The mass% or less is more preferably 40% by mass or more and 70% by mass or less. By setting it as the range, it is possible to obtain a coloring photosensitive composition having a low dielectric constant and good contact hole formation properties without detracting from the effects of the present invention.

Further, in the colored photosensitive composition of the present invention, in addition to the phthalocyanine-based blue pigment, a violet pigment may be contained as a pigment for adjusting the chromaticity. By including a purple pigment, a deep blue color capable of achieving a high NTSC ratio can be provided.

As the purple pigment, C.I. Pigment Violet 19, C.I. Pigment Violet 23, and C.I. Pigment Violet 32 can be used. Among them, C.I. Pigment Violet 23 is more preferable from the viewpoints of obtaining brightness, light resistance, heat resistance, and high contrast.

The total content of the coloring agent of the dye (A) and the pigment is preferably 5% by mass or more and 40% by mass or less, and more preferably 5% by mass or more based on the mass of all the solid matter of the coloring photosensitive composition. 30% by mass or less. By setting it as this range, it becomes easy to obtain desired chromaticity, brightness, and film thickness, and the shape of a pixel or a contact hole also becomes favorable.

(coated pigment)

The pigment used in the present invention is an organic pigment, and in the step of refining or dispersing the organic pigment, it is preferred to use a pigment obtained by coating an organic pigment with a polymer compound.

By coating the pigment with the polymer compound, the formation of the secondary aggregates is suppressed in the finely divided pigment, and the particles can be dispersed in the state of the primary particles. In other words, the dispersibility of the coated pigment is improved, and the dispersion stability of the dispersed primary particles is stably maintained.

Regarding the coating method of the polymer compound or the pigment used in the coating pigment, it is more preferable to use the treatment method described in paragraph number [0025] to paragraph number [0078] of JP-A-2009-1441269. And polymer compounds.

In the present invention, the pigment is preferably used by dispersing a pigment using at least one of dispersing agents to form a pigment dispersion composition. The same applies to the case of using the coated pigment as described above. By using the dispersant, the dispersibility of the pigment can be improved.

As the dispersant, for example, a known pigment dispersant or a surfactant can be suitably used.

Examples of the dispersant include an organic siloxane polymer KP341 (manufactured by Shin-Etsu Chemical Co., Ltd.), a (meth)acrylic (co)polymer Polyflow No. 75, a Polyflow No. 90, and a Polyflow No. 95 (above Cationic surfactants such as Kyoei Chemical Industry Co., Ltd., W001 (manufactured by Yushang Co., Ltd.); polyoxyethylene lauryl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, poly Nonionic surfactants such as oxyethylene octyl phenyl ether, polyoxyethylene nonylphenyl ether, polyethylene glycol dilaurate, polyethylene glycol distearate, sorbitan fatty acid ester Anionic surfactants such as W004, W005, W017 (manufactured by Yushang Co., Ltd.); EFKA-46, EFKA-47, EFKA-47EA, EFKA Polymer 100, EFKA Polymer 400, EFKA Polymer 401, EFKA Polymer 450 (both For Ciba Specialty Chemicals Co., Ltd.), Disperse Aid 6, Disperse Aid 8, Disperse Aid 15, Disperse Aid 9100 (both St. Polymer Co., Ltd.) and other polymer dispersants; Solsperse 3000, Solsperse 5000, Solsperse 9000, Solsperse 12000, Solsperse 13240, Solsperse 13940, Solsperse 17000, Solsperse 24000, Solsperse 26000, Solsperse 28000 and other Solsperse dispersants (above by Japanese Road) Manufactured by Borun Co., Ltd.; Adeka Pluronic L31, Adeka Pluronic F38, Adeka Pluronic L42, Adeka Pluronic L44, Adeka Pluronic L61, Adeka Pluronic L64, Adeka Pluronic F68, Adeka Pluronic L72, Adeka Pluronic P95, Adeka Pluronic F77, Adeka Pluronic P84, Adeka Pluronic F87, Adeka Pluronic P94, Adeka Pluronic L101, Adeka Pluronic P103, Adeka Pluronic F108, Adeka Pluronic L121, Adeka Pluronic P-123 (above manufactured by Asahi Denki Co., Ltd.) and IONNET S-20 (Sanyo Chemicals Co., Ltd.) Co., Ltd.), Disperbyk 101, Disperbyk 103, Disperbyk 106, Disperbyk 108, Disperbyk 109, Disperbyk 111, Disperbyk 112, Disperbyk 116, Disperbyk 130, Disperbyk 140, Disperbyk 142, Disperbyk 162, Disperbyk 163, Disperbyk 16 4, Disperbyk 166, Disperbyk 167, Disperbyk 170, Disperbyk 171, Disperbyk 174, Disperbyk 176, Disperbyk 180, Disperbyk 182, Disperbyk 2000, Disperbyk 2001, Disperbyk 2050, Disperbyk 2150 (above BYK-CHEMIE) ).

Other than this, an acryl-based copolymer is exemplified as an oligomer or a polymer having a polar group at a molecular terminal or a side chain.

The content of the dispersant is preferably 1 mass with respect to the mass of the pigment. %~100% by mass, more preferably 3% by mass to 70% by mass.

Further, from the viewpoint of the pigment dispersibility, it is preferred to prepare a pigment dispersion composition containing a pigment and a dispersant in advance when a pigment is added to the coloring photosensitive composition, and to prepare it. A pigment derivative may be added to the pigment dispersion composition as needed.

A pigment derivative into which a moiety having a affinity for a dispersing agent or a polar group is introduced is adsorbed on a surface of a pigment, and is used as a site of adsorption of a dispersing agent, whereby the pigment is dispersed in a state of fine particles in a pigment dispersion composition. . The colored photosensitive composition containing such a pigment dispersion composition can prevent re-agglomeration of the pigment, and therefore is effective in forming a color filter having high contrast and excellent transparency.

Specifically, the pigment derivative is a compound in which an organic pigment is used as a matrix and an acidic group or a basic group or an aromatic group is introduced as a substituent in the matrix.

Specific examples of the organic pigment to be the parent skeleton include quinacridone pigments, phthalocyanine pigments, azo pigments, quinophthalone pigments, isoporphyrin pigments, and isoindolinones. Pigments, quinoline pigments, diketopyrrolopyrrole pigments, benzimidazolone pigments, and the like. Further, in general, a pale yellow aromatic polycyclic compound such as a naphthalene, an anthracene, a triazine or a quinoline which is not called a dye may be used as a matrix.

For the pigment derivative, Japanese Patent Laid-Open No. Hei 11-49974, Japanese Patent Laid-Open No. Hei 11-189732, Japanese Patent Laid-Open No. Hei 10-245501, Japanese Patent Laid-Open No. Hei. No. Hei. -295810, Japanese Patent Laid-Open No. Hei 11-199796, Japanese Patent Laid-Open A pigment derivative described in, for example, Japanese Laid-Open Patent Publication No. 2001-356210, and the like.

The content of the pigment derivative in the pigment dispersion composition is preferably from 1% by mass to 30% by mass, and more preferably from 3% by mass to 20% by mass based on the mass of the pigment. When the content is within the above range, the dispersion can be favorably dispersed while suppressing the viscosity, and the dispersion stability after dispersion can be improved. As a result, the colored photosensitive composition containing such a pigment dispersion composition has high transmittance, excellent color characteristics, and is suitable for producing a high-contrast color filter having good color characteristics.

The method of dispersing the pigment can be carried out, for example, by preliminarily mixing the pigment with a dispersing agent using a particle dispersing machine or the like, and then performing microdispersion by pre-dispersing with a homogenizer or the like, wherein the particle dispersing machine uses oxidation. Zirconium particles and the like.

[(B) Photopolymerization initiator]

The colored photosensitive composition of the present invention contains (B) a photopolymerization initiator.

The photopolymerization initiator is a compound which is decomposed by light to cause polymerization of a polymerizable compound having at least two ethylenically unsaturated double bonds in the molecule (C), which is preferably at a wavelength of ultraviolet rays. Sensitive compound.

The photopolymerization initiator is preferably a photopolymerization initiator having absorption at an exposure wavelength of ultraviolet rays, and may be used in combination with a sensitizing dye described later even when ultraviolet rays are not absorbed at a wavelength of ultraviolet rays. It has sensitivity at the wavelength of ultraviolet light. Further, the photopolymerization initiator may be used singly or in combination of two or more.

The photopolymerization initiator used in the present invention is exemplified by organic halogenation. a compound, an oxadiazole compound, a carbonyl compound, a ketal compound, a benzoin compound, an acridine compound, an organic peroxidation compound, an azo compound, a coumarin compound, an azide compound, a metallocene compound, a hexaaryl group An imidazole compound, an organoboric acid compound, a disulfonic acid compound, an oxime ester compound, a phosphonium salt compound, or a mercaptophosphine (oxide) compound.

Specific examples of the organic halogenated compound include, for example, "National Chemical Society Bulletin (Bull Chem. Soc. Japan)" 42, 2924 (1969), U.S. Patent No. 3,905,815, and Japanese Patent Publication No. Sho 46-4605. Japanese Patent Laid-Open No. Sho-48-36281, Japanese Patent Laid-Open Publication No. SHO-55-32070, Japanese Patent Laid-Open Publication No. SHO-60-239736, Japanese Patent Laid-Open No. 61-169835, and Japanese Patent Laid-Open No. 61 Japanese Laid-Open Patent Publication No. SHO-62-58241, JP-A-62-212401, JP-A-63-70243, JP-A-63-298339, and JP-A-63-298339 The compound described in the "Journal of Heterocyclic Chemistry" 1 (No. 3), (1970), and the like, in particular, may be exemplified by a trihalomethyl group-substituted oxazole compound or a s-triazine compound.

Examples of the carbonyl compound include benzophenone, Michler's ketone, 2-methylbenzophenone, 3-methylbenzophenone, 4-methylbenzophenone, and 2-chlorodiphenyl. Benzophenone derivatives such as ketone, 4-bromobenzophenone, 2-carboxybenzophenone, 2,2-dimethoxy-2-phenylacetophenone, 2,2-diethoxy Acetophenone, 1-hydroxycyclohexyl phenyl ketone, α-hydroxy-2-methylphenylacetone, 1-hydroxy-1-methylethyl-(p-isopropylphenyl)one, 1-hydroxyl -1-(p-dodecylphenyl)one, 2-methyl-1-(4'-(methylthio)benzene 2-morpholinyl-1-propanone, 2-benzyl-2-dimethylamino-1-(4-morpholinylphenyl)-butanone-1, 2,4,6-three Methyl benzhydryl-diphenyl-phosphine oxide, 1,1,1-trichloromethyl-(p-butylphenyl) ketone, 2-benzyl-2-dimethylamino-4-? Acetophenone derivatives such as phenyl phenylbutanone, thioxanthone, 2-ethyl thioxanthone, 2-isopropyl thioxanthone, 2-chlorothiazinone, 2, 4 a thioxanthone derivative such as dimethylthiazinone, 2,4-diethylthiaxanone or 2,4-diisopropylthiaxanone, p-dimethylaminobenzoic acid a benzoate derivative such as an ester or p-diethylaminobenzoate.

Examples of the hexaarylbiimidazole compound include various compounds described in the respective specifications, such as Japanese Patent Publication No. Hei. 6-29285, U.S. Patent No. 3,479,185, U.S. Patent No. 4,311,783, and U.S. Patent No. 4,622,286. Is 2,2'-bis(o-chlorophenyl)-4,4',5,5'-tetraphenylbiimidazole, 2,2'-bis(o-bromophenyl)-4,4',5, 5'-tetraphenylbiimidazole, 2,2'-bis(o-, p-dichlorophenyl)-4,4',5,5'-tetraphenylbiimidazole, 2,2'-double (ortho) Chlorophenyl)-4,4',5,5'-tetrakis(m-methoxyphenyl)biimidazole, 2,2'-bis(ortho-o-dichlorophenyl)-4,4', 5,5'-tetraphenylbiimidazole, 2,2'-bis(o-nitrophenyl)-4,4',5,5'-tetraphenylbiimidazole, 2,2'-double (neighbor Phenyl)-4,4',5,5'-tetraphenylbiimidazole, 2,2'-bis(o-trifluorophenyl)-4,4',5,5'-tetraphenylbiimidazole Wait.

The oxime ester compound can be listed in the British Chemical Society, JC Perkin II (1979) 1653-1660, British Chemical Society, JC Perkin II (1979) 156-162, photopolymer Compounds disclosed in Journal of Photopolymer Science and Technology (1995) 202-232, Japanese Patent Laid-Open Publication No. 2000-66385, Japanese Patent Laid-Open A compound or the like described in JP-A-2004-534797, and JP-A-2004-534797. As a specific example, Irgacure OXE-01, Irgacure OXE-02, etc. manufactured by Ciba Specialty Chemicals Co., Ltd. are suitable.

As a photopolymerization initiator, from the viewpoint of exposure sensitivity, it is preferably selected from the group consisting of a trihalomethyltriazine compound, a benzil dimethyl ketal compound, an α-hydroxyketone compound, An α-amino ketone compound, a mercaptophosphine compound, a phosphine oxide compound, a metallocene compound, an anthraquinone compound, a triallyl imidazole dimer, an anthraquinone compound, a benzothiazole compound, and a benzophenone system a group consisting of a compound, an acetophenone-based compound and a derivative thereof, a cyclopentadiene-benzene-iron complex compound and a salt thereof, a halomethyl oxadiazole compound, and a 3-aryl-substituted coumarin compound Compound.

More preferably, it is a trihalomethyltriazine-based compound, an α-aminoketone compound, a mercaptophosphine compound, a phosphine oxide compound, an anthraquinone compound, a triallyl imidazole dimer, an anthraquinone compound, and a diphenyl group. The ketone-based compound and the acetophenone-based compound are preferably selected from the group consisting of a trihalomethyltriazine-based compound, an α-aminoketone compound, an anthraquinone compound, a triallyl imidazole dimer, and a benzophenone. A compound of at least one group consisting of compounds.

Hereinafter, the details of the oxime compound which is preferably used as a polymerization initiator in the present invention will be described.

The oxime compound represented by the following formula (5) is exemplified as the oxime compound.

In the formula (5), R ⁸ and P each independently represent a monovalent substituent, and Q ¹ and Q ² each independently represent a divalent organic group, and Ar represents an aryl group. n is an integer from 0 to 5. In the case where P is present in plurality, a plurality of P each independently represent a monovalent substituent.

The one-valent substituent represented by R ⁸ is preferably a one-valent non-metal atom group shown below.

The one-valent non-metal atomic group represented by R ⁸ may, for example, be an alkyl group which may have a substituent, an aryl group which may have a substituent, an alkenyl group which may have a substituent, an alkynyl group which may have a substituent, or The alkylsulfinyl group having a substituent, the arylsulfinyl group which may have a substituent, the alkylsulfonyl group which may have a substituent, the arylsulfonyl group which may have a substituent, or a mercapto group having a substituent, an alkoxycarbonyl group which may have a substituent, an aryloxycarbonyl group which may have a substituent, a phosphonium fluorenyl group which may have a substituent, a heterocyclic group which may have a substituent, Further, it may have an alkylthiocarbonyl group having a substituent, an arylthiocarbonyl group which may have a substituent, a dialkylaminocarbonyl group which may have a substituent, a dialkylaminothiocarbonyl group which may have a substituent, and the like.

The alkyl group which may have a substituent is preferably an alkyl group having 1 to 30 carbon atoms, and examples thereof include a methyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, an octyl group, a decyl group, and a dodecyl group. Octadecyl, isopropyl, isobutyl, t-butyl, tert-butyl, 1-ethylpentyl, cyclopentyl, cyclohexyl, trifluoromethyl, 2-ethylhexyl, benzo Methyl (phenacyl), 1-naphthoylmethyl, 2-naphthylmethylmethyl, 4-methylsulfanylphenacyl, 4-phenylmercaptobenzophenone , 4-dimethylaminobenzimidylmethyl, 4-cyanobenzhydrylmethyl, 4-methylbenzimidylmethyl, 2-methylbenzimidylmethyl, 3-fluorobenzamide Methyl, 3-trifluoromethylbenzimidylmethyl, 3-nitrobenzimidylmethyl, and the like.

The aryl group which may have a substituent is preferably an aryl group having 6 to 30 carbon atoms, and examples thereof include a phenyl group, a biphenyl group, a 1-naphthyl group, a 2-naphthyl group, a 9-fluorenyl group, and a 9-phenanthrene group. 1, 1-mercapto, 5-cyphthene, 5-mercapto, 2-indenyl, 9-fluorenyl, terphenyl, quaterphenyl, O-tolyl, m-tolyl, and p-tolyl, xylyl, o- cumenyl, m-cumenyl, and p-cumenyl, mesityl, pentalenyl , binaphthyl, binaphthyl, tetratetraphthyl, heptalenyl, biphenylenyl, indacenyl, propadiene Fluorhenhenyl, acenaphthenyl, aceanthrylenyl, phenalenyl, sulfhydryl, fluorenyl, bianthracenyl, teranthracenyl, hydrazine Quarterthracenyl, anthraquinolyl, phenanthryl, triphenylenyl, pyrenyl, Chrysenyl, thick tetraphenyl, Pleiadenyl, fluorenyl, fluorenyl, pentaphenyl, pentacenyl, tetraphenylenyl, hexaphenyl, hexacenyl, ru Rubicenyl, coronenyl, trinaphthylenyl, heptaphenyl, heptacenyl, pyranthrenyl, ovalenyl, and the like.

The alkenyl group which may have a substituent is preferably an alkenyl group having 2 to 10 carbon atoms, and examples thereof include a vinyl group, an allyl group, and a styryl group.

The alkynyl group which may have a substituent is preferably an alkynyl group having 2 to 10 carbon atoms, and examples thereof include an ethynyl group, a propynyl group, a propargyl group and the like.

The alkylsulfinyl group which may have a substituent is preferably an alkylsulfinyl group having 1 to 20 carbon atoms, and examples thereof include a methylsulfinyl group, an ethylsulfinyl group, and a propyl group. Sulfonyl, isopropylsulfinyl, butylsulfinyl, hexylsulfinyl, cyclohexylsulfinyl, octylsulfinyl, 2-ethylhexylsulfinyl, hydrazine A sulfinyl group, a dodecylsulfinyl group, an octadecylsulfinyl group, a cyanomethylsulfinyl group, a methoxymethylsulfinyl group or the like.

The arylsulfinyl group which may have a substituent is preferably an arylsulfinylene group having a carbon number of 6 to 30, and examples thereof include a phenylsulfinyl group, a 1-naphthylsulfinyl group, and 2 -naphthylsulfinyl, 2-chlorophenylsulfinyl, 2-methylphenylsulfinyl, 2-methoxyphenylsulfinyl, 2-butoxyphenylsulfin Sulfhydryl, 3-chlorophenylsulfinyl, 3-trifluoromethylphenylsulfinyl, 3-cyanophenylsulfinyl, 3-nitrophenylsulfinyl, 4- Fluorophenylsulfinyl, 4-cyanophenylsulfinyl, 4-methoxyphenylsulfinyl, 4-methylphenylsulfinyl, 4-phenylmercaptophenylsulfin Indenyl, 4-dimethylaminophenylsulfinyl, and the like.

The alkylsulfonyl group which may have a substituent is preferably an alkylsulfonyl group having 1 to 20 carbon atoms, and examples thereof include a methylsulfonyl group, an ethylsulfonyl group, and a propylsulfonyl group. Isopropylsulfonyl, butylsulfonyl, hexylsulfonyl, cyclohexylsulfonyl, octylsulfonyl, 2-ethylhexylsulfonyl, decylsulfonyl, dodecylsulfonate Anthracenyl, octadecylsulfonyl, cyanomethylsulfonyl, methoxymethylsulfonyl, perfluoroalkylsulfonyl and the like.

The arylsulfonyl group which may have a substituent is preferably an arylsulfonyl group having a carbon number of 6 to 30, and examples thereof include a phenylsulfonyl group, a 1-naphthylsulfonyl group, and a 2-naphthylsulfonyl group. Sulfhydryl, 2-chlorophenylsulfonyl, 2-methylphenylsulfonyl, 2-methoxyphenylsulfonyl, 2-butoxyphenylsulfonyl, 3-chlorophenylsulfonate Sulfhydryl, 3-trifluoromethylphenylsulfonyl, 3-cyanophenylsulfonyl, 3-nitrophenylsulfonyl, 4-fluorophenylsulfonyl, 4-cyanophenyl Sulfonyl, 4-methoxyphenylsulfonyl, 4-methylnonylphenylsulfonyl, 4-phenylmercaptophenylsulfonyl, 4-dimethylaminophenylsulfonyl, and the like.

The fluorenyl group which may have a substituent is preferably a fluorenyl group having 2 to 20 carbon atoms, and examples thereof include an ethyl fluorenyl group, a propyl fluorenyl group, a butyl fluorenyl group, a trifluoromethylcarbonyl group, a amyl group, and a benzamidine group. 1-naphthylmethyl, 2-naphthylmethyl, 4-methylbenzyl benzhydryl, 4-phenylmercaptobenzyl, 4-dimethylaminobenzimidyl, 4-diethylamine Benzobenzyl, 2-chlorobenzhydryl, 2-methylbenzhydryl, 2-methoxybenzimidyl, 2-butoxybenzhydryl, 3-chlorobenzylidene , 3-trifluoromethylbenzhydryl, 3-cyanobenzylidene, 3-nitrobenzhydryl, 4-fluorobenzhydryl, 4-cyanobenzylidene, 4-methyl Oxyl benzyl group and the like.

The alkoxycarbonyl group which may have a substituent is preferably an alkoxycarbonyl group having 2 to 20 carbon atoms, and examples thereof include a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, and a hexyloxycarbonyl group. Oxycarbonyl, octyloxycarbonyl, decyloxycarbonyl, octadecyloxy A carbonyl group, a trifluoromethoxycarbonyl group or the like.

Examples of the aryloxycarbonyl group which may have a substituent include a phenoxycarbonyl group, a 1-naphthyloxycarbonyl group, a 2-naphthyloxycarbonyl group, a 4-methylnonylphenoxycarbonyl group, a 4-phenylmercaptophenoxycarbonyl group, and 4 - dimethylaminophenoxycarbonyl, 4-diethylaminophenoxycarbonyl, 2-chlorophenoxycarbonyl, 2-methylphenoxycarbonyl, 2-methoxyphenoxycarbonyl, 2-butoxyphenoxycarbonyl, 3-chlorophenoxycarbonyl, 3-trifluoromethylphenoxycarbonyl, 3-cyanophenoxycarbonyl, 3-nitrophenoxycarbonyl, 4-fluoro Phenoxycarbonyl, 4-cyanophenoxycarbonyl, 4-methoxyphenoxycarbonyl, and the like.

The phosphinium group having a substituent may preferably be a phosphinium group having a total carbon number of 2 to 50, and examples thereof include a dimethylphosphinium group, a diethylphosphonium group, and a dipropyl group. Phosphonium, diphenylphosphinium sulfhydryl, dimethoxyphosphonium sulfhydryl, diethoxyphosphinium decyl, benzoylphosphonium sulfhydryl, bis(2,4,6-trimethyl) Phenyl phenyl) phosphinium fluorenyl and the like.

The heterocyclic group which may have a substituent is preferably an aromatic or aliphatic heterocyclic ring containing a nitrogen atom, an oxygen atom, a sulfur atom, and/or a phosphorus atom. For example, a thienyl group, a benzo[b]thienyl group, a naphtho[2,3-b]thienyl group, a thiol group, a furyl group, a piperidyl group, an isobenzofuranyl group, a benzopyranyl group (chromenyl) may be mentioned. , xanthenyl, phenoxathiinyl, 2H-pyrrolyl, pyrrolyl, imidazolyl, pyrazolyl, pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, anthracene Pyridazinyl, isodecyl, 3H-indenyl, fluorenyl, 1H-carbazolyl, fluorenyl, 4H-quinazinyl, isoquinolyl, quinolinyl, phthalazinyl, Naphthyridinyl, Base, quinazolinyl, Cinnolinyl, pteridinyl, 4aH-carbazolyl, carbazolyl, β-carbolinyl, phenanthridinyl, acridinyl, Perimidinyl, phenanthrolinyl, phenazinyl, phenarsazinyl, isothiazolyl, phenothiazinyl, isoxazolyl , furazanyl, phenoxazinyl, different Isochromanyl, Chromyl, pyrrolidinyl, pyrrolinyl, imidazolidinyl, imidazolinyl, pyrazolidinyl, pyrazolinyl, piperazine Piperidyl, piperazinyl, indolinyl, isoindolinyl, Quinuclidinyl group, morpholinyl, thioxantholyl, and the like.

Examples of the alkylthiocarbonyl group which may have a substituent include a methylthiocarbonyl group, a propylthiocarbonyl group, a butylthiocarbonyl group, a hexylthiocarbonyl group, an octylthiocarbonyl group, a decylthiocarbonyl group, an octadecylthiocarbonyl group, and a third group. Fluoromethylthiocarbonyl and the like.

Examples of the arylthiocarbonyl group which may have a substituent include 1-naphthylthiocarbonyl, 2-naphthylthiocarbonyl, 4-methylnonylphenylthiocarbonyl, 4-phenylmercaptophenylthiocarbonyl, 4-dimethylamine. Phenylthiocarbonyl, 4-diethylaminophenylthiocarbonyl, 2-chlorophenylthiocarbonyl, 2-methylphenylthiocarbonyl, 2-methoxyphenylthiocarbonyl, 2-butoxy Phenylthiocarbonyl, 3-chlorophenylthiocarbonyl, 3-trifluoromethylphenylthiocarbonyl, 3-cyanophenylthiocarbonyl, 3-nitrophenylthiocarbonyl, 4-fluorophenylthiocarbonyl, 4-cyanophenylthiocarbonyl, 4-methoxyphenylthiocarbonyl, and the like.

The dialkylaminocarbonyl group which may have a substituent may, for example, be a dimethylaminocarbonyl group. Aminocarbonyl, dipropylaminocarbonyl, dibutylaminocarbonyl, and the like.

Examples of the dialkylaminothiocarbonyl group which may have a substituent include a dimethylaminothiocarbonyl group, a dipropylaminothiocarbonyl group, a dibutylaminothiocarbonyl group and the like.

Among them, R ^{8 is more} preferably a mercapto group from the viewpoint of high sensitivity, and particularly preferably an ethyl fluorenyl group, a propyl fluorenyl group, a benzamidine group or a tolylmethyl group.

The divalent organic group represented by the above Q ² may, for example, be an alkylene group having a substituent of 1 to 12 carbon atoms, a cyclohexylene group which may have a substituent, or an alkynyl group which may have a substituent.

Examples of the substituent which can be introduced into these groups include a halogen group such as a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, an alkoxy group such as a methoxy group, an ethoxy group or a third butoxy group, and a phenoxy group. An aryloxy group such as a tolyloxy group, an alkoxycarbonyl group such as a methoxycarbonyl group, a butoxycarbonyl group or a phenoxycarbonyl group; a fluorenyloxy group such as an acetoxy group, a propyl fluorenyloxy group or a benzhydryloxy group; Base, ethyl fluorenyl, benzhydryl, isobutyl fluorenyl, acryl fluorenyl, methacryl fluorenyl, methoxalyl, etc., anthracenyl group such as formazan or tributyl fluorenyl, phenyl fluorenyl, An aryl fluorenyl group such as p-tolyllyl, an alkylamino group such as a methylamino group or a cyclohexylamino group, a dimethylamino group, a diethylamino group, a morpholinyl group, a N-hexahydropiperidino group, or the like An alkylamino group such as a dialkylamino group, a phenylamino group or a p-tolylamino group; an alkyl group such as a methyl group, an ethyl group, a t-butyl group or a dodecyl group; a phenyl group, a p-tolyl group or a xylene group; Examples of the aryl group such as a benzyl group, a cumyl group, a naphthyl group, an anthranyl group, and a phenanthryl group include a hydroxyl group, a carboxyl group, a methyl group, a mercapto group, a sulfo group, a methanesulfonyl group, and a p-toluene group. Acyl, amino, nitro, cyano, trifluoromethyl, trichloromethyl, alkyl trimethyl silicon, phosphinico (phosphinico), acyl phosphine (phosphono), Trimethylammoniumyl, dimethylsulfoniumyl, triphenylphenacylphosphoniumyl, and the like.

Among them, as Q ² , from the viewpoint of improving the sensitivity and suppressing the coloring caused by the heating over time, an unsubstituted alkylene group and an alkyl group (for example, a methyl group, an ethyl group, a third butyl group) are preferred. , dodecyl) substituted alkylene, alkyl substituted by alkenyl (eg vinyl, allyl), aryl (eg phenyl, p-tolyl, xylyl, cumenyl, An alkylene group substituted with a naphthyl group, an anthracenyl group, a phenanthryl group or a styryl group.

The aryl group represented by Ar is preferably an aryl group having 6 to 30 carbon atoms, and may have a substituent.

Specific examples thereof include a phenyl group, a biphenyl group, a 1-naphthyl group, a 2-naphthyl group, a 9-fluorenyl group, a 9-phenanthryl group, a 1-fluorenyl group, a 5-fused tetraphenyl group, and a 1-fluorenyl group. 2-indenyl, 9-fluorenyl, triphenyl, tetraphenyl, o-tolyl, m-tolyl, and p-tolyl, xylyl, o- cumenyl, m-cumenyl, and Alkenyl, mesitylene, cyclopentadienyl, binaphthyl, binaphthyl, tetratetraphthyl, cycloheptatrienyl, phenylene, dicyclopentadienyl, Propadienyl fluorenyl, ethane naphthyl, ethylene fluorenyl, fluorenyl, fluorenyl, fluorenyl, hydrazino, hydrazinyl, hydrazino, fluorenyl, phenanthryl, hydrazine Phenyl, sulfhydryl, Base, thick tetraphenyl, Base, fluorenyl, fluorenyl, pentaphenyl, fused pentaphenyl, tetraphenyl, hexaphenyl, hexaphenyl, ruthenyl, fluorenyl, hydrazine, heptaphenyl, hexaphenyl Base, sulfhydryl, sulfhydryl and the like. Among them, a substituted or unsubstituted phenyl group is preferred from the viewpoint of improving sensitivity and suppressing coloring caused by heating over time.

When the phenyl group has a substituent, the substituent may, for example, be a halogen atom such as a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, or an alkoxy group such as a methoxy group, an ethoxy group or a third butoxy group, or a benzene group. An aryloxy group such as an oxy group or a p-tolyloxy group; an alkylthioketone group such as a methylthioxy group, an ethylthioxy group or a t-butylthioxy group; An arylthioketone group such as a thioketone group or a p-tolylthioketone group; an alkoxycarbonyl group such as a methoxycarbonyl group, a butoxycarbonyl group or a phenoxycarbonyl group; an ethyl fluorenyloxy group; a propyl fluorenyloxy group; Anthracenyloxy group such as benzamidine oxy group, fluorenyl group such as ethyl fluorenyl group, benzamidine group, isobutyl fluorenyl group, acryl fluorenyl group, methacryl fluorenyl group, methoxycyanyl group, formazan group and tert-butyl group An alkyl group such as an alkyl fluorenyl group, a phenyl fluorenyl group or a p-tolyl fluorenyl group, an alkylamino group such as a methylamino group or a cyclohexylamino group, a dimethylamino group, a diethylamino group, a morpholinyl group or an N-hexahydro group. a dialkylamino group such as piperidinyl group, an arylamine group such as a phenylamino group or a p-tolylamino group; an alkyl group such as an ethyl group, a tert-butyl group or a dodecyl group; a hydroxyl group, a carboxyl group or a methyl group; Sulfhydryl, sulfo, methanesulfonyl, p-toluenesulfonyl, amine, nitro, cyano, trifluoromethyl, trichloromethyl, trimethyldecyl, phosphoric acid, phosphino, tri Methyl ammonium group, dimethyl fluorenyl group, triphenyl benzamidine methyl fluorenyl group and the like.

In the general formula (5), in terms of sensitivity, the structure of "SAr" formed by the Ar and the adjacent S is preferably the structure shown below.

The one-valent substituent represented by P may, for example, be an alkyl group which may have a substituent, an aryl group which may have a substituent, an alkenyl group which may have a substituent, an alkynyl group which may have a substituent, or Alkoxy group having a substituent, an aryloxy group which may have a substituent, an alkylthioketone group which may have a substituent, an arylthioketone group which may have a substituent, and an alkyl halide which may also have a substituent And a fluorenyl group which may have a substituent on N, a mercapto group which may have a substituent, an alkane group which may have a substituent, an aryl group which may have a substituent, or a substituent An alkylsulfinyl group, an arylsulfinyl group which may also have a substituent, an alkylsulfonium group which may also have a substituent An arylsulfonyl group which may have a substituent, an anthracenyl group which may have a substituent, an alkoxycarbonyl group which may have a substituent, an amine mercapto group which may have a substituent, or a substituent The aminesulfonyl group, an amine group which may have a substituent, a phosphonium group which may have a substituent, a heterocyclic group which may have a substituent, a halogen group, and the like.

The alkyl group which may have a substituent is preferably an alkyl group having 1 to 30 carbon atoms, and examples thereof include a methyl group, an ethyl group, a propyl group, a butyl group, a hexyl group, an octyl group, a decyl group, and a dodecyl group. Octadecyl, isopropyl, isobutyl, t-butyl, tert-butyl, 1-ethylpentyl, cyclopentyl, cyclohexyl, trifluoromethyl, 2-ethylhexyl, benzo醯Methyl, 1-naphthylmethylmethyl, 2-naphthylmethylmethyl, 4-methylbenzyl benzhydrylmethyl, 4-phenylmercaptobenzylidenemethyl, 4-dimethylaminobenzene Methyl hydrazine, 4-cyanobenzhydrylmethyl, 4-methylbenzhydrylmethyl, 2-methylbenzimidylmethyl, 3-fluorobenzhydrylmethyl, 3-trifluoromethyl Benzomethazine methyl, 3-nitrobenzhydrylmethyl, and the like.

The aryl group which may have a substituent is preferably an aryl group having 6 to 30 carbon atoms, and examples thereof include a phenyl group, a biphenyl group, a 1-naphthyl group, a 2-naphthyl group, a 9-fluorenyl group, and a 9-phenanthrene group. 1, 1-fluorenyl, 5-thick tetraphenyl, 1-indenyl, 2-indenyl, 9-fluorenyl, triphenyl, tetraphenyl, o-tolyl, m-tolyl, and p-toluene , xylyl, o- cumenyl, m-cumenyl, and p-cumenyl, mesityl, cyclopentadienyl, binaphthyl, dinaphthyl, tetratetraphthyl, hydrazine Heptatrienyl, biphenyl, dicyclopentadienylphenyl, propadienyl fluorenyl, ethane naphthyl, vinyl fluorenyl, fluorenyl, fluorenyl, fluorenyl, hydrazino,联三蒽基, 蒽四蒽基, fluorenyl, phenanthryl, triphenylene, fluorenyl, Base, thick tetraphenyl, Base, fluorenyl, fluorenyl, pentaphenyl, fused pentaphenyl, tetraphenyl, hexaphenyl, hexaphenyl, ruthenyl, fluorenyl, hydrazine, heptaphenyl, hexaphenyl Base, sulfhydryl, sulfhydryl and the like.

The alkenyl group which may have a substituent is preferably an alkenyl group having 2 to 10 carbon atoms. For example, a vinyl group, an allyl group, a styryl group, etc. are mentioned.

The alkynyl group which may have a substituent is preferably an alkynyl group having 2 to 10 carbon atoms, and examples thereof include an ethynyl group, a propynyl group, a propargyl group and the like.

The alkoxy group which may have a substituent is preferably an alkoxy group having 1 to 30 carbon atoms, and examples thereof include a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group, and an isobutyl group. Oxyl, second butoxy, tert-butoxy, pentyloxy, isopentyloxy, hexyloxy, heptyloxy, octyloxy, 2-ethylhexyloxy, decyloxy, twelve Alkoxy, octadecyloxy, ethoxycarbonylmethyl, 2-ethylhexyloxycarbonylmethoxy, aminocarbonylmethoxy, N,N-dibutylaminocarbonylmethoxy, N-methylaminocarbonylmethoxy, N-ethylaminocarbonylmethoxy, N-octylaminocarbonylmethoxy, N-methyl-N-benzylaminocarbonylmethoxy, benzyl Oxyl, cyanomethoxy, and the like.

The aryloxy group which may have a substituent is preferably an aryloxy group having 6 to 30 carbon atoms, and examples thereof include a phenoxy group, a 1-naphthyloxy group, a 2-naphthyloxy group, and a 2-chlorophenoxy group. 2-methylphenoxy, 2-methoxyphenoxy, 2-butoxyphenoxy, 3-chlorophenoxy, 3-trifluoromethylphenoxy, 3-cyanophenoxy , 3-nitrophenoxy, 4-fluorophenoxy, 4-cyanophenoxy, 4-methoxyphenoxy, 4-dimethylaminophenoxy, 4-methylnonylphenoxy Base, 4-phenylmercaptophenoxy, and the like.

The alkylthioketone group which may have a substituent is preferably a thioalkoxy group having 1 to 30 carbon atoms, and examples thereof include a methylthioketone group, an ethylthioketone group, a propylthione group, and a different Propylthioketo, butyl thioketo, isobutyl thioketone, second butyl thioketone, third butyl thioketone, pentyl thioketone, isoamyl thioketone, hexyl sulphur Keto group, heptyl thioketo group, octyl thioketone group, 2-ethylhexyl thioketone group, mercapto thioketone group, dodecyl thioketone group, octadecyl thioketone group, benzyl thioketone Base.

The arylthioketone group which may have a substituent is preferably a carbon number of 6 to 30. Examples of the arylthioketone group include a phenylthioketone group, a 1-naphthylthioketone group, a 2-naphthylthioketone group, a 2-chlorophenylthione group, and a 2-methylphenylthioketone group. 2-methoxyphenylthioketone, 2-butoxyphenylthioketone, 3-chlorophenylthione, 3-trifluoromethylphenylthione, 3-cyanophenylsulfide Keto group, 3-nitrophenylthioketone group, 4-fluorophenylthioketone group, 4-cyanophenylthioketone group, 4-methoxyphenylthioketone group, 4-dimethylamino group Phenylthioketone, 4-methylnonylphenylthioketone, 4-phenylmercaptophenylthione, and the like.

The mercaptooxy group which may have a substituent is preferably a mercaptooxy group having 2 to 20 carbon atoms, and examples thereof include an ethyl fluorenyloxy group, a propyl fluorenyloxy group, a butyl fluorenyloxy group, and a pentyloxy group. And a trifluoromethylcarbonyloxy group, a benzylideneoxy group, a 1-naphthylcarbonyloxy group, a 2-naphthylcarbonyloxy group, or the like.

The alkane group which may have a substituent is preferably an alkene group having 1 to 20 carbon atoms, and examples thereof include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, a hexyl group, a cyclohexyl group, and a octyl group. , 2-ethylhexyl fluorenyl, fluorenyl fluorenyl, dodecyl fluorenyl, octadecyl fluorenyl, cyanomethyl fluorenyl, methoxymethyl fluorenyl and the like.

The arylsulfonyl group which may have a substituent is preferably an arylsulfonyl group having 6 to 30 carbon atoms, and examples thereof include a benzoinyl group, a 1-naphthylfluorenyl group, a 2-naphthylfluorenyl group, a 2-chlorophenyl fluorenyl group, and a 2- Methyl phenyl fluorenyl, 2-methoxyphenyl fluorenyl, 2-butoxyphenyl fluorenyl, 3-chlorophenyl fluorenyl, 3-trifluoromethylphenyl fluorenyl, 3-cyanophenyl fluorenyl, 3-nitrophenyl fluorenyl, 4-fluorophenylindenyl, 4-cyanobenzoinyl, 4-methoxyphenylhydrazino, 4-methylmercaptobenzoyl, 4-phenylmercaptophenylhydrazine, 4-dimethylaminophenylhydrazino, and the like.

The alkylsulfinyl group which may have a substituent is preferably an alkylsulfinyl group having a carbon number of 1 to 20, and examples thereof include a methylsulfinyl group, an ethylsulfinyl group, and a C. Isosulfonyl, isopropylsulfinyl, butylsulfinyl, hexylsulfinyl, cyclohexylsulfinyl, octylsulfinyl, 2-ethylhexylsulfinyl , mercaptosulfinyl, dodecylsulfinyl, octadecylsulfinyl, cyanomethylsulfinyl, methoxymethylsulfinyl, and the like.

The arylsulfinyl group which may have a substituent is preferably an arylsulfinylene group having a carbon number of 6 to 30, and examples thereof include a phenylsulfinyl group, a 1-naphthylsulfinyl group, and 2 -naphthylsulfinyl, 2-chlorophenylsulfinyl, 2-methylphenylsulfinyl, 2-methoxyphenylsulfinyl, 2-butoxyphenylsulfin Sulfhydryl, 3-chlorophenylsulfinyl, 3-trifluoromethylphenylsulfinyl, 3-cyanophenylsulfinyl, 3-nitrophenylsulfinyl, 4- Fluorophenylsulfinyl, 4-cyanophenylsulfinyl, 4-methoxyphenylsulfinyl, 4-methylphenylsulfinyl, 4-phenylmercaptophenylsulfin Indenyl, 4-dimethylaminophenylsulfinyl, and the like.

The alkylsulfonyl group which may have a substituent is preferably an alkylsulfonyl group having 1 to 20 carbon atoms, and examples thereof include a methylsulfonyl group, an ethylsulfonyl group, a propylsulfonyl group, and a different one. Propylsulfonyl, butylsulfonyl, hexylsulfonyl, cyclohexylsulfonyl, octylsulfonyl, 2-ethylhexylsulfonyl, decylsulfonyl, dodecylsulfonate A group, an octadecylsulfonyl group, a cyanomethylsulfonyl group, a methoxymethylsulfonyl group or the like.

The arylsulfonyl group which may have a substituent is preferably an arylsulfonyl group having a carbon number of 6 to 30, and examples thereof include a phenylsulfonyl group, a 1-naphthylsulfonyl group, and a 2-naphthylsulfonyl group. Sulfhydryl, 2-chlorophenylsulfonyl, 2-methylphenylsulfonyl, 2-methoxyphenylsulfonyl, 2-butoxyphenylsulfonyl, 3-chlorophenylsulfonate Sulfhydryl, 3-trifluoromethylphenylsulfonyl, 3-cyanophenylsulfonyl, 3-nitrophenylsulfonyl, 4-fluorophenylsulfonyl, 4-cyano Phenylsulfonyl, 4-methoxyphenylsulfonyl, 4-methylnonylphenylsulfonyl, 4-phenylmercaptophenylsulfonyl, 4-dimethylaminophenylsulfonyl, etc. .

The fluorenyl group which may have a substituent is preferably a fluorenyl group having 2 to 20 carbon atoms, and examples thereof include an ethyl fluorenyl group, a propyl fluorenyl group, a butyl fluorenyl group, a trifluoromethylcarbonyl group, a amyl group, and a benzamidine group. 1-naphthylmethyl, 2-naphthylmethyl, 4-methylbenzyl benzhydryl, 4-phenylmercaptobenzyl, 4-dimethylaminobenzimidyl, 4-diethylamine Benzobenzyl, 2-chlorobenzhydryl, 2-methylbenzhydryl, 2-methoxybenzimidyl, 2-butoxybenzhydryl, 3-chlorobenzylidene , 3-trifluoromethylbenzhydryl, 3-cyanobenzylidene, 3-nitrobenzhydryl, 4-fluorobenzhydryl, 4-cyanobenzylidene, 4-methyl Oxyl benzyl group and the like.

The alkoxycarbonyl group which may have a substituent is preferably an alkoxycarbonyl group having 2 to 20 carbon atoms, and examples thereof include a methoxycarbonyl group, an ethoxycarbonyl group, a propoxycarbonyl group, a butoxycarbonyl group, and a hexyloxycarbonyl group. Oxycarbonyl, octyloxycarbonyl, decyloxycarbonyl, octadecyloxycarbonyl, phenoxycarbonyl, trifluoromethoxycarbonyl, 1-naphthyloxycarbonyl, 2-naphthyloxycarbonyl, 4-methyl Nonylphenoxycarbonyl, 4-phenylmercaptophenoxycarbonyl, 4-dimethylaminophenoxycarbonyl, 4-diethylaminophenoxycarbonyl, 2-chlorophenoxycarbonyl, 2-methyl Phenoxycarbonyl, 2-methoxyphenoxycarbonyl, 2-butoxyphenoxycarbonyl, 3-chlorophenoxycarbonyl, 3-trifluoromethylphenoxycarbonyl, 3-cyanobenzene An oxycarbonyl group, a 3-nitrophenoxycarbonyl group, a 4-fluorophenoxycarbonyl group, a 4-cyanophenoxycarbonyl group, a 4-methoxyphenoxycarbonyl group or the like.

The amine mercapto group which may have a substituent is preferably an amine carbenyl group having a total carbon number of 1 to 30, and examples thereof include N-methylamine methyl sulfonyl group, N-ethylamine methyl fluorenyl group, and N- C Base amine methyl sulfhydryl, N-butylamine methyl sulfhydryl, N-hexylamine methyl sulfhydryl, N-cyclohexylamine methyl sulfhydryl, N-octylamine methyl sulfhydryl, N-decylamine methyl sulfhydryl, N-octadecylamine methyl sulfonyl, N-phenylamine methyl hydrazino, N-2-methylphenylamine carbhydryl, N-2-chlorophenylamine decyl, N-2-iso Propoxy phenylamine methyl hydrazino, N-2-(2-ethylhexyl) phenylamine decyl, N-3-chlorophenylamine decyl, N-3-nitrophenylamine Mercapto, N-3-cyanophenylamine, mercapto, N-4-methoxyphenylamine, mercapto, N-4-cyanophenylamine, N-4-mercaptobenzene Base amine methyl sulfonyl, N-4-phenylmercaptophenylamine methyl sulfhydryl, N-methyl-N-phenylamine methyl sulfhydryl, N,N-dimethylamine carbhydryl, N,N-di Butylamine, mercapto, N,N-diphenylamine, mercapto and the like.

The amine sulfonyl group which may have a substituent is preferably an amine sulfonyl group having a total carbon number of 0 to 30, and examples thereof include an amine sulfonyl group, an N-alkylamine sulfonyl group, and an N-aryl sulfonate. Anthracenyl, N,N-dialkylaminesulfonyl, N,N-diarylaminesulfonyl, N-alkyl-N-arylaminesulfonyl, and the like. More specifically, N-methylaminesulfonyl, N-ethylaminesulfonyl, N-propylaminesulfonyl, N-butylaminesulfonyl, N-hexylaminesulfonyl, N-cyclohexylamine sulfonyl, N-octylamine sulfonyl, N-2-ethylhexylamine sulfonyl, N-decylamine sulfonyl, N-octadecylamine sulfonyl, N-phenylamine sulfonyl, N-2-methylphenylamine sulfonyl, N-2-chlorophenylamine sulfonyl, N-2-methoxyphenylamine sulfonyl, N- 2-Isopropoxyphenylamine sulfonyl, N-3-chlorophenylamine sulfonyl, N-3-nitrophenylamine sulfonyl, N-3-cyanophenylamine sulfonyl , N-4-methoxyphenylamine sulfonyl, N-4-cyanophenylamine sulfonyl, N-4-dimethylaminophenylamine sulfonyl, N-4-methyl fluorenyl Phenylamine sulfonyl, N-4-phenylnonylphenylamine sulfonyl, N-methyl-N-phenylamine sulfonyl, N,N-dimethylamine sulfonyl, N,N- Dibutylamine sulfonyl, N,N-diphenyl Aminesulfonyl and the like.

The amine group which may have a substituent is preferably an amine group having a total carbon number of from 0 to 50, and examples thereof include -NH ₂ , an N-alkylamino group, an N-arylamino group, and an N-decylamino group. , N-sulfonylamino, N,N-dialkylamino, N,N-diarylamine, N-alkyl-N-arylamine, N,N-disulfonylamine Base. More specifically, N-methylamino group, N-ethylamino group, N-propylamino group, N-isopropylamino group, N-butylamino group, N-tert-butylamino group , N-hexylamino, N-cyclohexylamino, N-octylamino, N-2-ethylhexylamino, N-decylamino, N-octadecylamino, N-benzyl Amino group, N-phenylamino group, N-2-methylphenylamino group, N-2-chlorophenylamino group, N-2-methoxyphenylamino group, N-2-isopropyl Oxyphenylamino, N-2-(2-ethylhexyl)phenylamino, N-3-chlorophenylamino, N-3-nitrophenylamino, N-3-cyano Phenylamino, N-3-trifluoromethylphenylamino, N-4-methoxyphenylamino, N-4-cyanophenylamino, N-4-trifluoromethylbenzene Amino group, N-4-formylphenylamino group, N-4-phenylnonylphenylamino group, N-4-dimethylaminophenylamino group, N-methyl-N-phenylamine , N,N-dimethylamino, N,N-diethylamino, N,N-dibutylamino, N,N-diphenylamino, N,N-diethylhydrazine Amine, N,N-diphenylmercaptoamine, N,N-(dibutylcarbonyl)amine, N,N-(dimethylsulfonyl)amine, N,N-(diethyl Alkylsulfonyl)amino, N,N-(dibutylsulfonyl)amine N, N- (diphenyl sulfonic acyl) amino, morpholinyl, 3,5-dimethyl - morpholinyl, carbazolyl and the like.

The phosphinium group having a substituent may preferably be a phosphinium group having a total carbon number of 2 to 50, and examples thereof include a dimethylphosphinium group, a diethylphosphonium group, and a dipropyl group. Phosphonium, diphenylphosphinium sulfhydryl, dimethoxyphosphonium sulfhydryl, diethoxyphosphinium decyl, benzoylphosphonium sulfhydryl, bis(2,4,6-trimethyl) Phenyl phenyl) phosphinium fluorenyl and the like.

The heterocyclic group which may have a substituent is preferably an aromatic or aliphatic heterocyclic ring containing a nitrogen atom, an oxygen atom, a sulfur atom or a phosphorus atom. For example, there are thienyl, benzo[b]thienyl, naphtho[2,3-b]thienyl, thienyl, furyl, piperanyl, isobenzofuranyl, benzopyranyl, Benzopyranyl, morphothinyl, 2H-pyrrolyl, pyrrolyl, imidazolyl, pyrazolyl, pyridyl, pyrazinyl, pyrimidinyl, pyridazinyl, pyridazinyl, isodecyl, 3H-indenyl, fluorenyl, 1H-carbazolyl, fluorenyl, 4H-quinazinyl, isoquinolyl, quinolinyl, pyridazinyl, Pyridyl, Base, quinazolinyl, Lolinyl, acridinyl, 4aH-carbazolyl, oxazolyl, β-carbolinyl, phenanthryl, acridinyl, Pyridyl, morpholinyl, cyanozinyl, morphazinyl, isothiazolyl, phenothiazine, isoxazolyl, furazinyl, phenoxazinyl, iso base, , pyrrolidinyl, pyrrolinyl, imidazolidinyl, imidazolinyl, pyrazolidinyl, pyrazolinyl, piperidinyl, piperazinyl, porphyrinyl, isoindolyl, Pyridyl, morpholinyl, thioxanthone, and the like.

The halogen group has a fluorine atom, a chlorine atom, a bromine atom, an iodine atom or the like.

The halogenated alkyl group which may have a substituent may, for example, be a monofluoromethyl group, a difluoromethyl group, a trifluoromethyl group, a dichloromethyl group, a trichloromethyl group, a monobromomethyl group, a dibromomethyl group or a tribromomethyl group. Wait.

Examples of the sulfhydryl group having a substituent on N include N,N-dimethylammonium group, N,N-diethylguanamine group and the like.

Further, the above-mentioned alkyl group which may have a substituent, an aryl group which may have a substituent, an alkenyl group which may have a substituent, an alkynyl group which may have a substituent, an alkoxy group which may have a substituent, An aryloxy group which may have a substituent or may have a substitution An alkylthioketone group, an arylthioketone group which may have a substituent, a mercaptooxy group which may have a substituent, an alkylhydrazine group which may have a substituent, an arylsulfonyl group which may have a substituent, An alkylsulfinyl group which may have a substituent, an arylsulfinyl group which may have a substituent, an alkylsulfonyl group which may have a substituent, an arylsulfonyl group which may have a substituent, Further, it may have a substituent fluorenyl group, an alkoxycarbonyl group which may have a substituent, an amine carbhydryl group which may have a substituent, an amine sulfonyl group which may have a substituent, and an amine group which may have a substituent The heterocyclic group which may have a substituent may be further substituted with other substituents.

Examples of such a substituent include a halogen group such as a fluorine atom, a chlorine atom, a bromine atom or an iodine atom, an alkoxy group such as a methoxy group, an ethoxy group or a third butoxy group, or a phenoxy group or a p-tolyloxy group. An alkoxycarbonyl group such as an oxy group, a methoxycarbonyl group, a butoxycarbonyl group or a phenoxycarbonyl group; a mercaptooxy group such as an ethyl fluorenyloxy group, a propyl fluorenyloxy group or a benzhydryloxy group; a fluorenyl group such as a benzylidene group, an isobutylene group, an acryloyl group, a methacryloyl group, or a methoxycyl group; an alkyl group such as a methyl group or a tert-butyl group; an aryl group such as a benzoin or a p-tolyl group; , an alkylamino group such as a methylamino group or a cyclohexylamino group; a dialkylamino group such as a dimethylamino group, a diethylamino group, a morpholinyl group or an N-hexahydropiperidinyl group; and a phenylamino group. An arylamino group such as p-tolylamino, an alkyl group such as methyl, ethyl, t-butyl or dodecyl, phenyl, p-tolyl, xylyl, cumenyl, naphthyl or anthracenyl Examples of the aryl group such as a phenanthrenyl group and a phenanthryl group include a hydroxyl group, a carboxyl group, a decyl group, a fluorenyl group, a sulfo group, a methanesulfonyl group, a p-toluenesulfonyl group, an amine group, a nitro group, a cyano group, and a trifluoro group. A , Trichloromethyl, trimethyl silicon group, a phosphinicodioxy, acyl phosphine, trimethyl ammonium, dimethyl sulfonium group, benzoyl methyl triphenyl phosphonium group.

Among these bases, P is preferably an alkyl group which may have a substituent, an aryl group which may have a substituent, or a substituent, from the viewpoint of improvement in solvent solubility and absorption efficiency in a long wavelength region. An alkenyl group, an alkynyl group which may have a substituent, an alkoxy group which may have a substituent, an aryloxy group which may have a substituent, an alkylthioketone group which may have a substituent, or a substituent An arylthioketone group, a halogenated alkyl group which may have a substituent, an amine group which may have a substituent, or an anthranyl group which may have a substituent on N.

Further, n in the formula (5) represents an integer of 0 to 5, and from the viewpoint of easiness of synthesis, an integer of 0 to 3 is preferable, and an integer of 0 to 2 is more preferable.

In the general formula (5), when P is present in plurality, a plurality of P may be the same or different.

The divalent organic group represented by the above Q ¹ may be exemplified by the structure shown below. Further, in the group shown below, "*" indicates a bonding position of a carbon atom adjacent to Q ^{1 in} the formula (5).

Among them, from the viewpoint of high sensitivity, the structure shown below is preferred.

Among the photopolymerization initiators represented by the formula (5), the photopolymerization initiator represented by the following formula (6) has a particularly high sensitivity and is preferable.

R ⁸ , Q ² , Ar, P, and n in the formula (6) are synonymous with R ⁸ , Ar, P, and n in the above formula (5), and preferred examples are also the same.

Specific examples of the photopolymerization initiator represented by the formula (6) are shown below.

Furthermore, in the present invention, a compound represented by the following formula (A) is also suitable as the oxime ester compound as a photopolymerization initiator from the viewpoints of self-inductance, stability over time, and coloration at the time of heating.

In the formula (A), X ¹ , X ² and X ³ each independently represent a hydrogen atom, a halogen atom or an alkyl group, and R ¹ represents -R, -OR, -COR, -SR, -CONRR', or -CN, R ² and R ³ each independently represent -R, -OR, -COR, -SR, or -NRR'. R and R' each independently represent an alkyl group, an aryl group, an arylalkyl group or a heterocyclic group, and these groups may be substituted with one or more selected from the group consisting of a halogen atom and a heterocyclic group. One or more of the carbon atoms constituting the alkyl chain in the alkyl group and the aralkyl group may be substituted with an unsaturated bond, an ether bond or an ester bond, and R and R' may be bonded to each other to form a ring.

In the general formula (A), when the halogen atom in the case where X ¹ , X ² and X ³ represent a halogen atom, fluorine, chlorine, bromine or iodine, and X ¹ , X ² and X ³ represent an alkyl group. Examples of the alkyl group include a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a second butyl group, a tert-butyl group, a pentyl group, an isopentyl group, a third pentyl group, and a hexyl group. Heptyl, octyl, isooctyl, 2-ethylhexyl, trioctyl, decyl, isodecyl, decyl, isodecyl, vinyl, allyl, butenyl, ethynyl, C Alkynyl, methoxyethyl, ethoxyethyl, propoxyethyl, methoxyethoxyethyl, ethoxyethoxyethyl, propoxyethoxyethyl, methoxy A propyl group, a monofluoromethyl group, a difluoromethyl group, a trifluoromethyl group, a trifluoroethyl group, a perfluoroethyl group, a 2-(benzoxazole-2'-yl)vinyl group, and the like.

It is preferred that X ¹ , X ² and X ³ each represent a hydrogen atom, or X ¹ represents an alkyl group, and X ² and X ³ each represent a hydrogen atom.

In the general formula (A), the alkyl group represented by R and R' may, for example, be a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, a second butyl group, a third butyl group or a butyl group. Base, isopentyl, third amyl, hexyl, heptyl, octyl, isooctyl, 2-ethylhexyl, trioctyl, decyl, isodecyl, decyl, isodecyl, vinyl , allyl, butenyl, ethynyl, propynyl, methoxyethyl, ethoxyethyl, propoxy , methoxyethoxyethyl, ethoxyethoxyethyl, propoxyethoxyethyl, methoxypropyl, monofluoromethyl, difluoromethyl, trifluoromethyl, Trifluoroethyl, perfluoroethyl, 2-(benzoxazol-2'-yl)vinyl and the like.

Examples of the aryl group represented by R and R' include a phenyl group, a tolyl group, a xylyl group, an ethylphenyl group, a chlorophenyl group, a naphthyl group, an anthracenyl group, and a phenanthryl group.

Examples of the aralkyl group represented by R and R' include a benzyl group, a chlorobenzyl group, an α-methylbenzyl group, an α,α-dimethylbenzyl group, a phenylethyl group, and a phenylvinyl group.

Examples of the heterocyclic group represented by R and R' include a pyridyl group, a pyrimidinyl group, a furyl group, and a thienyl group.

Further, examples of the ring formed by bonding R and R' to each other include a piperidine ring and a morpholine ring.

Particularly preferred forms of R ² and R ³ are independently methyl, hexyl, cyclohexyl, -S-Ph, -S-Ph-Cl, and -S-Ph-Br.

In the general formula (A), as a photopolymerization initiator, a particularly suitable compound is a compound wherein X ¹ , X ² and X ³ are each a hydrogen atom; and R ¹ is a compound of an alkyl group, particularly a methyl group; R ² is a compound of an alkyl group, particularly a methyl group; and R ³ is a compound of an alkyl group, particularly an ethyl group.

Preferable specific examples of the photopolymerization initiator represented by the formula (A) include the compounds A to G exemplified below. However, the present invention is not limited by any of the following compounds.

The photopolymerization initiator represented by the formula (A) can be synthesized, for example, by the method described in JP-A-2005-220097.

The compound represented by the formula (5) and the compound represented by the formula (A) have an absorption wavelength in a wavelength region of from 250 nm to 500 nm. More preferably, it has an absorption wavelength in a wavelength region of 300 nm to 380 nm. Particularly preferred are compounds with high absorbance of light at wavelengths of 308 nm and 355 nm.

The content of the (D) photopolymerization initiator is preferably from 0.1% by mass to 20% by mass, more preferably from 0.5% by mass to 15% by mass, based on the mass of all the solids in the coloring photosensitive composition. Particularly preferred is 3 mass% to 15 mass%. to Good sensitivity and pattern formation are obtained in this range.

(sensitized pigment)

In the colored photosensitive composition of the present invention, it is preferred to add a sensitizing dye different from the dye structure of (A) from the viewpoint of improving the sensitivity. The sensitizing dye is a compound which promotes a radical generating reaction of a photopolymerization initiator component or a polymerization reaction of an ethylenically unsaturated compound caused thereby by exposure using light of absorbable wavelength.

Such a sensitizing dye may, for example, be a known spectroscopic sensitizing dye or dye different from the (A) dye structure, or a dye or an organic pigment which absorbs light and interacts with a photopolymerization initiator.

Preferred examples of the spectroscopic dye or dye which can be used as the sensitizing dye in the present invention include polynuclear aromatics (for example, fluorene, fluorene, triphenylene) and dibenzopyrans (for example). Fluorescein, eosin, erythrosine, rhodamine B, rose bengal, cyanine (eg thiacarbocyanine) , oxacarbocyanine, merocyanine (eg, merocyanine, carbomerocyanine), thiazides (eg, thionine, methylene blue, toluidine blue) ), acridines (such as acridine orange, chloroflavin, acriflavine), phthalocyanines (such as phthalocyanine, metal phthalocyanine), porphyrin (such as tetraphenyl) a porphyrin, a central metal-substituted porphyrin), a chlorophyll (such as chlorophyll, chlorophyllin, a central metal-substituted chlorophyll), a metal complex, Terpenes (for example, hydrazine), squarylium (for example, squaraine compounds), and the like.

Examples of better spectroscopic sensitizing dyes or dyes are exemplified below.

The styrene-based dye described in Japanese Patent Laid-Open Publication No. Hei 37-13034, and the cation dye described in Japanese Patent Laid-Open Publication No. Sho 62-143044; a quinoxalinium salt; a novel methylene blue compound described in Japanese Laid-Open Patent Publication No. SHO 64-33104; a scorpion described in Japanese Patent Laid-Open Publication No. SHO 64-56767; Japanese Patent Laid-Open No. 2 a benzoxanthene dye described in the publication No. -1714; an acridine described in Japanese Patent Laid-Open No. Hei 2-226148; Japanese Patent Publication No. Sho. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. And a ketone dye of the Japanese Patent Application Laid-Open No. Hei 2- 85858, and a conjugated ketone dye described in Japanese Patent Laid-Open Publication No. Hei No. Hei. -30321 The azo cinnamic-based derivative described in the Japanese Patent Laid-Open Publication No. Hei 2-187105, Japanese Patent Laid-Open No. Hei. No. Hei. No. 62-31844, and Japanese Patent Laid-Open No. 62-31848 The dibenzopyran-based dye described in Japanese Patent Publication No. Sho 62-143043, and the aminostyryl ketone described in Japanese Patent Publication No. Sho 59-28325; Japanese Patent Laid-Open No. 2 Pigment described in Japanese Patent Publication No. 179643; Japanese Patent Laid-Open No. 2-244050 A part of the cyanine dye described in the Japanese Patent Publication No. 59-28326, and a cyanine dye described in Japanese Patent Laid-Open Publication No. SHO 59-89303; The phthalocyanine dye described in Japanese Laid-Open Patent Publication No. Hei 8-334897.

Other preferred embodiments of the sensitizing dye include those belonging to the following group of compounds and having a maximum absorption wavelength at 350 nm to 450 nm.

Examples thereof include polynuclear aromatics (for example, hydrazine, hydrazine, and hydrazine), dibenzopyrans (for example, fluorescein, blush, red erythro, rose red B, and rose bengal), and cyanines. (eg, thiacarbocyanine, oxacarbocyanine), merocyanines (eg, merocyanine, carbocyanine), thiazides (eg, thioindigo, methylene blue, toluidine blue), acridine ( For example, acridine orange, chlorsulfurin, acriflavine, anthraquinones (such as hydrazine), squaraine compounds (such as squaraine compounds).

The content of the sensitizing dye is preferably from 0.1% by mass to 20% by mass, and more preferably from 0.5% by mass to 15% by mass based on the mass of all the solid matter in the colored photosensitive composition.

(thiol compound)

The colored photosensitive composition in the present invention preferably contains a thiol compound.

The thiol compound in the present invention can exhibit the effect of acting as a co-sensitizer and/or improving the adhesion between the formed color pixel and the substrate. The co-sensitizer has a function of further improving the sensitivity of the sensitizing dye and/or the photopolymerization initiator to the active radiation, and suppressing (C) having at least two ethylenically unsaturated double bonds in the molecule. The polymerizable compound is inhibited by polymerization due to oxygen or the like.

The thiol compound can be specifically exemplified by ethylene glycol dithiopropionate (EGTP), butanediol dithiopropionate (BDTP), trimethylolpropane trithiopropionate (TMTP), Pentaerythritol tetrathiopropionate (PETP), mercaptopropionic acid derivatives such as THEIC-BMPA represented by the following formula; ethylene glycol bisthioglycolate (EGTG), butanediol bis-mercaptoacetic acid Mercaptoacetic acid derivatives such as ester (BDTG), hexanediol bis-mercaptoacetate (HDTG), trimethylolpropane tridecyl acetate (TMTG), pentaerythritol tetradecyl acetate (PETG); 1,2- Thiodithiol, 1,3-benzenedithiol, 1,2-ethanedithiol, 1,3-propanedithiol, 1,6-hexamethylenedithiol (1,6-hexamethylenedithiol) , 2,2'-(Exoethyldithio)diethanethiol, meso-2,3-dimercapto succinic acid, p-xylenedithiophenol a mercaptan such as m-xylylenedithiol or a mercaptoether such as bis(decylethyl)ether.

These compounds may be used singly or in combination of two or more.

The thiol compound used in the present invention is more preferably a compound represented by the following formula (SH-1).

In the formula (SH-1), R represents a hydrogen atom, an alkyl group or an aryl group, and A represents an atomic group which forms a hetero ring together with N=C-N.

In the formula (SH-1), R represents a hydrogen atom, an alkyl group, or an aryl group.

The alkyl group represented by R may, for example, be a linear, branched or cyclic alkyl group having 1 to 20 carbon atoms, more preferably a linear alkyl group having 1 to 12 carbon atoms or a carbon atom. The number is a branched alkyl group of 3 to 12, and a cyclic alkyl group having 5 to 10 carbon atoms.

Specific examples thereof include methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, decyl, decyl, undecyl, dodecyl, tridecyl, and ten. Hexaalkyl, octadecyl, eicosyl, isopropyl, isobutyl, t-butyl, tert-butyl, isopentyl, neopentyl, 1-methylbutyl, isohexyl, 2-ethylhexyl, 2-methylhexyl, cyclohexyl, cyclopentyl, 2-norbornyl and the like.

The aryl group represented by R may include, in addition to the aryl group having a monocyclic structure, an aryl group in which one to three benzene rings form a condensed ring, an aryl group in which a benzene ring forms a condensed ring with a 5-membered unsaturated ring, and the like. Examples thereof include a phenyl group, a naphthyl group, an anthracenyl group, a phenanthryl group, an indenyl group, an ethanenaphthyl group, and an anthracenyl group. More preferably, those aryl groups are a phenyl group and a naphthyl group.

The alkyl or aryl group may further have a substituent which may be introduced and substituted The base may be a linear, branched or cyclic alkyl group having 1 to 20 carbon atoms, a linear, branched or cyclic alkenyl group having 2 to 20 carbon atoms, and a carbon number of 2 to 20 alkynyl group, aryl group having 6 to 20 carbon atoms, mercaptooxy group having 1 to 20 carbon atoms, alkoxycarbonyloxy group having 2 to 20 carbon atoms, and carbon atoms 7 to 20 aryloxycarbonyloxy group, amine carbenyloxy group having 1 to 20 carbon atoms, carboxyamino group having 1 to 20 carbon atoms, sulfonamide having 1 to 20 carbon atoms a group, an aminomethyl sulfonyl group having 1 to 20 carbon atoms, an amine sulfonyl group, a substituted sulfonyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, and a carbon atom An aryloxy group having 6 to 20 carbon atoms, an aryloxycarbonyl group having 7 to 20 carbon atoms, an alkoxycarbonyl group having 2 to 20 carbon atoms, and an N-decylamine sulfonate having 1 to 20 carbon atoms a mercapto group, an N-amine sulfonylaminocarboxamyl group having 1 to 20 carbon atoms, an alkylsulfonyl group having 1 to 20 carbon atoms, an arylsulfonyl group having 6 to 20 carbon atoms, An alkoxycarbonylamino group having 2 to 20 carbon atoms, an aryloxycarbonylamino group having 7 to 20 carbon atoms, an amine group, and a substituted carbon number of 1 to 20 An alkylene group having 1 to 20 carbon atoms, an ammonio group having 3 to 20 carbon atoms, a carboxyl group, a sulfo group, an oxy group, an anthracenyl group and an alkyl sulfinylene group having 1 to 20 carbon atoms. An arylsulfinyl group having 6 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, an arylthio group having 6 to 20 carbon atoms, and a urea having 1 to 20 carbon atoms a heterocyclic group having 2 to 20 carbon atoms, a mercapto group having 1 to 20 carbon atoms, an aminesulfonylamino group, a substituted sulfonylamino group having 1 to 2 carbon atoms, a halogen atom having 2 to 20 carbon atoms, an isocyanato group, an isocyanido group, a halogen atom (for example, a fluorine atom, a chlorine atom, a bromine atom, etc.), a cyano group, a nitro group, a sulfhydryl group, or the like. .

Further, in the formula (SH-1), A represents an atomic group which forms a hetero ring together with N = C-N.

Examples of the atom constituting the atomic group include a carbon atom, a nitrogen atom, a hydrogen atom, a sulfur atom, and a selenium atom.

Further, the hetero ring formed of A and N=C-N may further have a substituent, and the substituent which may be introduced may be the same as the substituent which may be introduced into the alkyl group or the aryl group.

Further, the thiol compound is more preferably a compound represented by the following formula (SH-2) or (SH-3).

In the formula (SH-2), R ¹ represents an aryl group, and X represents a hydrogen atom, a halogen atom, an alkoxy group, an alkyl group, or an aryl group.

In the formula (SH-3), R ² represents an alkyl group or an aryl group, and X represents a hydrogen atom, a halogen atom, an alkoxy group, an alkyl group, or an aryl group.

In the general formula (SH-2) and the general formula (SH-3), the halogen atom represented by X is preferably a fluorine atom, a chlorine atom, a bromine atom or an iodine atom.

In the general formula (SH-2) and the general formula (SH-3), the alkoxy group represented by X may, for example, be a methoxy group, an ethoxy group, a propoxy group, an isopropoxy group, a butoxy group or a pentyloxy group. base, Hexyloxy, dodecyloxy, benzyloxy, allyloxy, phenethyloxy, carboxyethyloxy, methoxycarbonylethyloxy, ethoxycarbonylethyloxy, methoxy Ethyloxy, phenoxyethoxy, methoxyethoxyethoxy, ethoxyethoxyethoxy, morpholinylethoxy, morpholinylpropoxy, allyloxy Ethoxyethoxy, phenoxy, tolyloxy, xylyloxy, mesityloxy, cumenyloxy, methoxyphenoxy, ethoxyphenoxy, chlorobenzene An oxy group, a bromophenoxy group, an etecyloxy group, a benzhydryloxy group, a naphthyloxy group or the like.

In the formula (SH-2) and the formula (SH-3), the alkyl group represented by R ² or X has the same meaning as the alkyl group represented by R of the formula (SH-1), and the preferred range thereof is also the same. .

Further, in the general formula (SH-2) and the general formula (SH-3), the aryl group represented by R ¹ , R ² or X is independently represented by the R represented by the formula (SH-1). Synonymous, the preferred range is the same.

In the formula (SH-2) and the formula (SH-3), each group represented by R ¹ , R ² or X may further have a substituent, and the substituent is the same as the formula (SH-1) The substituents which may be introduced into the alkyl group or the aryl group represented by R are the same.

In the general formula (SH-2) and the general formula (SH-3), it is more preferable that X is a hydrogen atom from the viewpoint of solubility in an organic solvent.

In the general formula (SH-2), from the viewpoint of sensitivity and solubility in an organic solvent, it is preferred that R ¹ is a phenyl group.

In the general formula (SH-3), it is more preferable that R ² is a methyl group, an ethyl group, a phenyl group or a benzyl group from the viewpoint of sensitivity and solubility in an organic solvent.

Among the compounds represented by the formula (SH-2) and the compound represented by the formula (SH-3), the compound represented by the formula (SH-3) is most preferable from the viewpoint of solubility in an organic solvent.

These thiol compounds can be synthesized by the method described in J. Appl. Chem., 34, 2203-2207 (1961).

In the colored photosensitive composition of the present invention, the compound represented by the formula (SH-1) may be used singly or in combination of two or more kinds, and may be selected from the group consisting of the formula (SH-2). A compound of the compound represented by the compound represented by the formula (SH-3) is used in combination.

The content of the thiol compound in the coloring photosensitive composition is preferably from 0.1% by mass to 5.0% by mass, and more preferably from 0.2% by mass to 4% by mass based on the mass of all the solid matter of the coloring photosensitive composition. %. If it is in this range, it is preferable because the polymerizability of the coloring photosensitive composition is not impaired.

[(C) a polymerizable compound having at least two ethylenically unsaturated double bonds in a molecule]

The colored photosensitive composition of the present invention contains (C) a polymerizable compound having at least two ethylenically unsaturated double bonds in the molecule (hereinafter referred to as "polymerizable compound" as appropriate).

The polymerizable compound which can be used in the present invention is a compound widely known in the industrial field, and these compounds can be used without particular limitation in the present invention. Such compounds have, for example, the following chemical forms: monomers, prepolymers, i.e., dimers, trimers, and oligomers, or mixtures thereof, and copolymers thereof.

As an example of a monomer and a copolymer thereof, an ester or unsaturated of an unsaturated carboxylic acid (for example, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, methacrylic acid, maleic acid, etc.) and an aliphatic polyol compound is used. An amide of a carboxylic acid and an aliphatic polyamine compound. Further, an unsaturated carboxylic acid ester having a nucleophilic substituent such as a hydroxyl group, an amine group or a fluorenyl group, or an addition reaction product of a polyfunctional isocyanate or an epoxy group, and a polyfunctional carboxy group can also be suitably used. An acid dehydration condensation reaction product or the like. Further, an unsaturated carboxylic acid ester having an electrophilic substituent such as an isocyanate group or an epoxy group or an addition reaction product of a guanamine and a polyfunctional alcohol, an amine or a thiol, or a halogen group or A substituted carboxylic acid ester such as a toluenesulfonyloxy group or a substituted carboxylic acid ester of a decylamine and a polyfunctional alcohol, an amine or a thiol is also suitable. Further, as another example, a group of compounds substituted with unsaturated phosphonic acid, styrene, vinyl ether or the like may be used instead of the above unsaturated carboxylic acid.

As a specific example of the monomer of the aliphatic polyol compound and the ester of the unsaturated carboxylic acid, the acrylate is: ethylene glycol diacrylate, triethylene glycol diacrylate, and 1,3-butylene glycol diacrylate. , tetramethylene glycol diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, trimethylolpropane triacrylate, trimethylolpropane tris(propylene decyloxypropyl Ether, trimethylolethane triacrylate, hexanediol diacrylate, 1,4-cyclohexanediol diacrylate, tetraethylene glycol diacrylate, pentaerythritol diacrylate, pentaerythritol triacrylate, Pentaerythritol tetraacrylate, dipentaerythritol diacrylate, dipentaerythritol hexaacrylate, sorbitol triacrylate, sorbitol tetraacrylate, sorbitol pentaacrylate, sorbitol hexaacrylate, tris(propylene fluorenyl) oxygen Ethyl isocyanate, polyester acrylate oligomer, ethylene oxide (EO) modified triacrylate, and the like.

The methacrylate is extended with butanediol dimethacrylate, triethylene glycol dimethacrylate, neopentyl glycol dimethacrylate, trimethylolpropane trimethacrylate, trishydroxyl Ethylene ethane trimethacrylate, ethylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, hexanediol dimethacrylate, pentaerythritol dimethacrylate, pentaerythritol trimethyl Acrylate, pentaerythritol tetramethacrylate, dipentaerythritol dimethacrylate, dipentaerythritol hexamethacrylate, sorbitol trimethacrylate, sorbitol tetramethacrylate, double [pair (3 -Methylacryloyloxy-2-hydroxypropoxy)phenyl]dimethylmethane, bis-[p-(methacryloyloxyethoxy)phenyl]dimethylmethane, and the like.

Iconic acid esters are ethylene glycol diconconate, propylene glycol diconconate, 1,3-butanediol diconconate, 1,4-butanediol diconcanate, and butyl Diol diconconate, pentaerythritol diconconate, sorbitol tetraconcanate, and the like. Butenoic acid esters include ethylene glycol bis-butyrate, butanediol dimethyl acrylate, pentaerythritol dimethyl acrylate, Wait.

Examples of the methacrylate include ethylene glycol dimethacrylate, pentaerythritol dimethacrylate, sorbitol tetramethacrylate, and the like. The maleate ester is exemplified by ethylene glycol dimaleate, triethylene glycol dimaleate, pentaerythritol dimaleate, sorbitol tetramaleate, and the like.

Examples of the other esters include, for example, the aliphatic alcohols described in JP-A-57-47231, and JP-A-57-196231. The ester having an aromatic skeleton described in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. An amine group-containing ester or the like described in JP-A-1-156613.

Further, the above ester monomers may also be used in the form of a mixture.

Further, specific examples of the monomer of the aliphatic polyamine compound and the decylamine of the unsaturated carboxylic acid include methylene bis-acrylamide, methylene bis-methyl acrylamide, 1,6-hexamethylene Bis-propyleneamine, 1,6-hexamethylenebis-methylpropenylamine, diethylenetriaminetripropenylamine, xylylene bisacrylamide, exophthalene Bis-methyl methacrylamide and the like.

Other examples of the preferred amide-based monomer include a compound having a cyclohexylene structure described in Japanese Patent Publication No. Sho 54-21726.

In addition, a urethane-based addition polymerizable compound produced by an addition reaction of an isocyanate and a hydroxyl group is also suitable, and a specific example thereof is exemplified by one molecule described in Japanese Patent Publication No. Sho 48-41708. A vinyl group-containing compound having a hydroxyl group represented by the following formula (IV) is added to a polyisocyanate compound having two or more isocyanate groups, and ethylene having two or more polymerizable vinyl groups per molecule is obtained. A carbamic acid ester compound or the like.

General formula (IV) CH ₂ =C(R ⁴ )COOCH ₂ CH(R ⁵ )OH

(wherein R ⁴ and R ⁵ each independently represent H or CH ₃ )

In addition, the urethane urethanes described in Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. The urethane-based urethane described in Japanese Patent Publication No. Sho 62-39417, Japanese Patent Publication No. Sho 62-39417, and JP-A-62-39418, the entire disclosure of which is incorporated herein by reference. Compounds are also suitable. In addition, an amine group structure or a thioether is contained in the molecule as described in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. A color-forming photosensitive composition having a very excellent photospeed can be obtained by adding an addition polymerizable compound.

Other examples include polyester acrylates described in each of the publications of JP-A-48-64183, JP-A-49-43191, and JP-A-52-30490. A polyfunctional acrylate or methacrylate such as an epoxy acrylate obtained by reacting a resin with (meth)acrylic acid. Further, a specific unsaturated compound described in Japanese Patent Publication No. Sho 46-43946, Japanese Patent Publication No. Hei. No. Hei. A vinylphosphonic acid-based compound or the like described in the publication No. 25493. Further, in some cases, a structure containing a perfluoroalkyl group described in JP-A-61-22048 can be suitably used. In addition, it can also be used as a photocurable monomer and oligomer in the Journal of the Next American Association, Vol. 20, No. 7, and pages 300 to 308 (1984). Compound.

The details of the structure of the polymerizable compounds, whether they are used singly or in combination, and the amount of addition can be arbitrarily set depending on the performance of the coloring photosensitive composition. For example, it can be selected according to the viewpoint described below.

In terms of sensitivity, a structure having a large content of unsaturated groups per molecule is preferable, and in order to increase the strength of the colored pixels, a compound having three or more functional groups is preferable, and the number of functional groups is different by using A method of adjusting both sensitivity and strength by using a compound having a different polymerizable group (for example, an acrylate, a methacrylate, a styrene compound, or a vinyl ether compound) is also effective. From the viewpoint of self-hardening sensitivity, it is preferred to use a compound containing two or more (meth) acrylate structures, and more preferably a compound containing three or more (meth) acrylate structures, and it is preferable to use A compound containing four or more (meth) acrylate structures. Further, from the viewpoint of the curing sensitivity and the developability of the unexposed portion, it is preferred to contain an ethylene oxide modified product. Further, in view of the degree of hardening sensitivity and the strength of the exposed portion, it is preferred to contain a urethane bond.

Further, the compatibility with the other components in the coloring photosensitive composition (for example, an alkali-soluble resin or a photopolymerization initiator), the selection and use of the polymerizable compound are important factors, for example, by using a low-purity compound. Or two or more types may be used together, and compatibility may be improved. Further, it is also possible to select a specific structure for the purpose of improving the adhesion between the substrate and the colored pixels.

From the above viewpoints, examples of the polymerizable compound include bisphenol A diacrylate, bisphenol A diacrylate ethylene oxide modified product, and trimethylolpropane triacrylic acid. Ester, trimethylolpropane tris(propylene decyloxypropyl) ether, trimethylolethane triacrylate, tetraethylene glycol diacrylate, pentaerythritol diacrylate, pentaerythritol triacrylate, pentaerythritol tetraacrylate Ester, dipentaerythritol pentaacrylate, dipentaerythritol hexaacrylate, sorbitol triacrylate, sorbitol tetraacrylate, sorbitol pentaacrylate, sorbitol hexaacrylate, tris(propylene decyloxy B As a preferred polymerizable compound, isomeric isocyanate, pentaerythritol tetraacrylate ethylene oxide modified product, dipentaerythritol hexaacrylate ethylene oxide modified product, and the like, and a commercially available product is preferably an amine group. Acid ester oligomer UAS-10, urethane oligomer UAB-140 (manufactured by Nippon Paper Chemical Co., Ltd.), DPHA (manufactured by Nippon Kayaku Co., Ltd.), UA-306H, UA-306T, UA-306I, AH -600, T-600, AI-600 (manufactured by Kyoeisha).

Among them, more preferred are bisphenol A diacrylate ethylene oxide modified product, pentaerythritol triacrylate, pentaerythritol tetraacrylate, dipentaerythritol pentaacrylate, dipentaerythritol hexaacrylate, tris(propylene decyloxyethyl) ) isomeric cyanurate, pentaerythritol tetraacrylate ethylene oxide modified product, dipentaerythritol hexaacrylate ethylene oxide modified product, etc., and commercially available products are more preferably DPHA (manufactured by Nippon Kayaku Co., Ltd.), UA- 306H, UA-306T, UA-306I, AH-600, T-600, AI-600 (manufactured by Kyoeisha Chemical Industry Co., Ltd.).

Further, the polymerizable compound of the present invention is preferably a polymerizable compound having at least two ethylenically unsaturated double bonds in the molecule and having at least one hydroxyl group.

The polymerizable compound is preferably a polymerizable compound having the following structural moiety (Mo) (hereinafter also referred to as "specifically polymerizable compound").

The polymerizable compound is subjected to a polymerization reaction by a radical derived from a photopolymerization initiator to form a cured film. Although the action of the specific polymerizable compound is not necessarily clear, it is presumed that the structure represented by the following structural moiety (Mo) has a structure in which the unsaturated double bond portion is rapidly reacted at the time of exposure, and thus the polymerization hardenability is excellent. Further, since the specific polymerizable compound has at least one hydroxyl group, the hydroxyl group reacts with the epoxy ring of the thermosetting resin to form a crosslinked structure, and is cured even at a relatively low temperature, and is excellent in solvent resistance or peeling resistance. The color layer.

In the structural moiety (Mo), X represents a hydrogen atom or a methyl group. Moreover, the "*" in the expression indicates a key bond.

The specific polymerizable compound in the present invention is not particularly limited as long as it has at least two of the structural moieties (Mo) in the molecule, and any one or two or more of the colored photosensitive compositions of the present invention may be selected. It is composed of a polymerizable compound.

The specific polymerizable compound may be a compound in which two or more structural moieties (Mo) are bonded via a divalent or trivalent or higher linking group between the respective bonding bonds (*), and two structural moieties (Mo). The compound is directly linked by a respective bonding bond (*).

The divalent or trivalent or higher linking group may be arbitrarily selected from the polyvalent group, and examples thereof include a hydrocarbon group having a divalent or trivalent or higher hydrocarbon group and a hydrocarbon group having a divalent or trivalent or higher hydrocarbon group. Or two or more ether bond (-O-) groups, -O-, -S-, ester bond, guanylamino group, amine group, etc., and a combination of at least two of these groups, such as a divalent group .

Specific examples of the linking group of two or more valences are as follows. However, in the present invention, it is not limited to these specific examples. In addition, "*" in a specific example represents a key bond.

Since polymerization is carried out rapidly upon exposure and good hardening can be performed, even if it is formed by a low temperature heating or no heat treatment to form a uniform pattern structure or a protective film, it is preferred to have two in the molecule or More than three specific structural compounds of the structural moiety (Mo).

From the same viewpoint, it is preferable to have two structural parts (Mo) in the molecule and the same two bases including the structural part (Mo). The structure, that is, the compound including the entire molecular structure linking the two structural moieties (Mo), constitutes a compound having a symmetrical structure. A preferred compound having a symmetrical structure is, for example, a compound represented by the following structural formula (Mo-2).

In the structural formula (Mo-2), R represents a group containing a divalent hydrocarbon group or a linking group containing at least one ether bond (-O-) between carbon-carbons of a divalent hydrocarbon group, preferably 2 The carbon-carbon of the valent hydrocarbon group contains at least one linking group of an ether bond (-O-). X represents a hydrogen atom or a methyl group.

Represented by the R "group of the divalent hydrocarbon group comprising 2", for example, include divalent group containing only _{C n H 2n (n ≧ 1} ) of the hydrocarbon groups represented by, and the _{C n H 2n (n ≧ 1} ) of the hydrocarbon group represented by A divalent group obtained by combining at least one selected from the group consisting of an ether bond, an ester bond, a guanamine group, and an amine group. The range of n is suitably 1-8.

Further, the "linking group containing at least one ether bond between carbon and carbon in the divalent hydrocarbon group" represented by R is one or two or more oxygen atoms and carbon atoms and hydrogen which are disposed between carbon and carbon. The divalent group of the atom is not particularly limited, and for example, -(AL and/or AR)-O-(AL and/or AR)-, -(AL and/or AR)-O-(AL can be suitably cited. And/or AR)-O-, -(AL and/or AR)-O-(AL and/or AR)-O-(AL and/or AR)-divalent group. Further, AL represents an alkylene group and AR represents an extended aryl group.

The alkylene group (AL) may be any of a straight chain and a branched chain, and the alkylene group and the extended aryl group (AR) may be unsubstituted or substituted with a substituent. Examples of the substituent in the case of substitution include the same substituents as those exemplified below for Ra.

In R, in the case where the polymerization at the time of exposure proceeds rapidly and good hardening is possible, it is preferable to contain two or more oxygen atoms, and more preferably -CH ₂ -O-Ra- O-CH ₂ - The case. Here, Ra represents a linking group selected from the group consisting of an alkyl group, an aryl group, and a combination of these sites. Further, one or two or more ether bonds may be further disposed between the carbon-carbon bonds of the alkylene group represented by Ra.

The alkyl group represented by Ra is not particularly limited and may be substituted with a substituent without being substituted. The substituent in the case of substitution may, for example, be a monovalent substituent such as an alkyl group having 1 to 8 carbon atoms (for example, a methyl group, an ethyl group, a butyl group, a hexyl group or an octyl group), a hydroxyl group or a halogen group.

Specific examples of the alkylene moiety include a methylene group, an exoethyl group, a propyl group, a butyl group, a 2-hydroxyl-propyl group, a 2-methyl-extended ethyl group, and a 2,2-dimethyl-methyl group. , stretching the ring and so on.

Among them, as the alkylene group, a substituted or unsubstituted alkylene group having a carbon number of 1 to 8 is preferred, and a carbon number is more preferred in terms of solvent solubility and inhibition of precipitation. It is a substituted or unsubstituted alkyl group of 1 to 6.

The aryl group represented by Ra is not particularly limited and may be substituted with a substituent without being substituted. As a substituent in the case of substitution, it can be enumerated The same substituent is used in the case of the alkyl group.

Specific examples of the aryl group include a phenyl group and a naphthyl group. Among them, as the aryl group, from the viewpoint of solvent solubility and inhibition of precipitation, a substituted or unsubstituted aryl group having a carbon number of 6 to 10 is preferred, and a carbon number of 6 is more preferred. a substituted or unsubstituted extended aryl group of 8.

Further, examples of the combination of the alkyl group and the aryl group include -C ₆ H ₄ -C(CH ₃ ) ₂ -C ₆ H ₄ -, -(CH ₂ ) ₂ -OC ₆ H ₄ -C ( CH ₃ ) ₂ -C ₆ H ₄ -O-(CH ₂ ) ₂ -, -(CH ₂ ) ₃ -OC ₆ H ₄ -C(CH ₃ ) ₂ -C ₆ H ₄ -O-(CH ₂ ) ₃ -Wait.

Specific examples of "-CH ₂ -O-Ra-O-CH ₂ -" represented by R are as follows. However, the specific examples are not limited in the present invention. In addition, "*" in a specific example represents a key bond.

Further, in terms of good polymerization reactivity at the time of exposure, the linking group represented by Ra is preferably a symmetrical structure. Specific examples of the linking group of the symmetrical structure include specific examples (1a), (2a), (4a) to (9a), and the like as specific examples.

The molecular weight of the specific polymerizable compound in the present invention is preferably from 100 to 3,000, more preferably from 100 to 2,000, still more preferably from 100 to 1,500, based on the weight average molecular weight. When the molecular weight of the specific polymerizable compound is 100 or more, it is preferable in terms of suppressing sublimation, and when it is 3,000 or less, it is preferable in terms of solubility.

In addition, the weight average molecular weight can be obtained by gel dialysis chromatography (Gel Determined by Permeation Chromatography, GPC). The GPC is shown in detail in the items of the embodiments to be described later.

Specific examples of the specific polymerizable compound having the structural moiety (Mo) are shown below [exemplified compound (1) to exemplified compound (20), exemplified compound (M-4), and exemplified compound (M-6) to exemplified compound ( M-8), and the exemplified compound (M-13) to the exemplified compound (M-15)]. However, the specific examples are not limited in the present invention.

The content of the polymerizable compound is preferably from 5% by mass to 55% by mass, more preferably from 10% by mass to 50% by mass, based on the mass of all the solid matter in the colored photosensitive composition of the present invention. Further preferably, it is 15% by mass to 45% by mass.

As described above, the colored photosensitive composition of the present invention is an essential component. Each component to be contained, a sensitizing dye which can be used arbitrarily, and a thiol compound are demonstrated. In the colored photosensitive composition of the present invention, a resin, a thermosetting resin, an organic solvent, a surfactant, or the like may be further added to the extent that the effects of the present invention are not impaired. The optional components are described below.

(resin)

The colored photosensitive composition used in the present invention can also contain a resin for the purpose of improving film properties, imparting development properties, and the like. Here, the resin means a polymer compound such as an alkali-soluble resin, a thermosetting resin, a pigment coating resin, or a polymer dispersing agent. When it is considered to develop by alkali, it is preferred to contain at least an alkali-soluble resin.

Hereinafter, the alkali-soluble resin and the thermosetting resin among the resins will be described in detail. In the case of using a pigment, a pigment coating resin, a polymer dispersant, or the like can be used for the purpose of improving the dispersibility of the pigment.

- alkali soluble resin -

The alkali-soluble resin used in the present invention can be suitably selected from the group consisting of a linear organic high molecular polymer and a molecule (preferably an acrylic copolymer or a styrene copolymer). An alkali-soluble resin having at least one base which promotes alkali solubility (for example, a carboxyl group, a phosphate group, a sulfonic acid group, a hydroxyl group, etc.) in the molecule of the main chain.

The compound which is more preferably the above-mentioned alkali-soluble resin is exemplified by a polymer having a carboxylic acid in a side chain. For example, Japanese Patent Publication No. Sho 59-44615, Japanese Patent Publication No. Sho 54-34327, and Japanese Patent Publication No. Sho-58- Japanese Patent Publication No. 12577, Japanese Patent Publication No. Sho 54-25957, and Japanese Patent Laid-Open No. 59-53836 The methacrylic acid copolymer, the acrylic copolymer, the itaconic acid copolymer, the butenoic acid copolymer, the maleic acid copolymer, and the partial ester described in each of the publications of Japanese Laid-Open Patent Publication No. 59-71048 An acrylic resin such as a maleic acid copolymer or the like, and an acid cellulose derivative having a carboxylic acid in a side chain and a compound obtained by adding an acid anhydride to a polymer having a hydroxyl group.

The acid value is preferably in the range of 20 mgKOH/g to 200 mgKOH/g, preferably 30 mgKOH/g to 180 mgKOH/g, more preferably 50 mgKOH/g to 150 mgKOH/g.

The alkali-soluble resin used in the present invention is particularly preferably a copolymer of (meth)acrylic acid with another monomer copolymerizable therewith.

Examples of the other monomer copolymerizable with (meth)acrylic acid include an alkyl (meth)acrylate, an aryl (meth)acrylate, and a vinyl compound. Here, the hydrogen atom of the alkyl group and the aryl group may be substituted by a substituent.

The alkyl (meth)acrylate and the aryl (meth)acrylate are CH ₂ =C(R)(COOR') [wherein R represents a hydrogen atom or an alkyl group having a carbon number of 1 to 5, R' represents an alkyl group having 1 to 8 carbon atoms or an aralkyl group having 6 to 12 carbon atoms, and specific examples thereof include methyl (meth)acrylate and ethyl (meth)acrylate. Base propyl acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, amyl (meth) acrylate, hexyl (meth) acrylate, octyl (meth) acrylate, (methyl) Phenyl acrylate, benzyl (meth) acrylate, tolyl (meth) acrylate, naphthyl (meth) acrylate, cyclohexyl (meth) acrylate, hydroxyalkyl (meth) acrylate ( The alkyl group is an alkyl group having 1 to 8 carbon atoms, hydroxyglycidyl methacrylate, tetrahydrofurfuryl methacrylate or the like.

The vinyl compound is represented by CH ₂ =CR ¹ R ² [wherein R ¹ represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and R ² represents an aromatic hydrocarbon ring having 6 to 10 carbon atoms]. Examples thereof include styrene, α-methylstyrene, vinyltoluene, acrylonitrile, vinyl acetate, N-vinylpyrrolidone, polystyrene macromonomer, polymethyl methacrylate macromolecular single Body and so on.

The other monomer which can be copolymerized as described above may be used alone or in combination of two or more.

Among the above, a benzyl (meth)acrylate/(meth)acrylic copolymer or a multicomponent copolymer comprising benzyl (meth)acrylate/(meth)acrylic acid/other monomer is particularly suitable.

Further, a resin having a polyalkylene oxide chain in a molecular side chain is also preferable as the alkali-soluble resin.

The polyalkylene oxide chain may be a polyethylene oxide chain, a polypropylene oxide chain, a polytetramethylene glycol chain, or a combination thereof, and the ends of the chains are a hydrogen atom or a linear or branched alkyl group.

The number of repeating units of the repeating unit contained in the polyethylene oxide chain and the polypropylene oxide chain is preferably from 1 to 20, more preferably from 2 to 12.

The acrylic copolymer having a polyalkylene oxide chain in a side chain is preferably, for example, an acrylic copolymer containing a compound as a copolymerization component: polyethylene glycol mono(meth)acrylate, polypropylene glycol mono(methyl). Acrylate, poly(ethylene glycol-propylene glycol) mono(meth)acrylate, etc., and compounds whose terminal OH groups are blocked with an alkyl group, such as methoxypolyethylene glycol mono(meth)acrylic acid Ester, ethoxylated polypropylene glycol Mono (meth) acrylate, methoxy poly (ethylene glycol-propylene glycol) mono (meth) acrylate, and the like.

The acrylic resin has an acid value in the range of 20 mgKOH/g to 200 mgKOH/g. When the acid value is 200 mgKOH/g or less, the solubility of the acrylic resin to the alkali does not become excessively large, and it is possible to prevent the development range (development latitude) from becoming narrow. On the other hand, when it is 20 mgKOH/g or more, it is difficult to reduce the solubility in alkali, and it is possible to prevent the development time from being prolonged.

Further, in order to achieve a viscosity range which is easy to use in the step of coating the coloring photosensitive composition, and to secure the film strength, the weight average molecular weight Mw of the acrylic resin (polystyrene equivalent value measured by the GPC method) is compared. The best is 2,000~100,000, and more preferably 3,000~50,000.

Further, in order to improve the crosslinking efficiency of the colored photosensitive composition usable in the present invention, it is preferred to use an alkali-soluble resin having a polymerizable group. The alkali-soluble resin having a polymerizable group may be used singly or in combination with an alkali-soluble resin having no polymerizable group.

The alkali-soluble resin having a polymerizable group can be used for a polymer having an aryl group, a (meth)acryl (meth) acryl, an aryloxyalkyl group or the like in a side chain. Such an alkali-soluble resin having a polymerizable double bond can be developed in an alkaline developing solution, and further has both photocurability and thermosetting property, which is preferable. Among them, a resin having an aryl group as a side chain polymerizable group has a high hardenability and a high heat decomposition resistance, and therefore is more preferable.

Preferred examples of the alkali-soluble resin containing a polymerizable group include an alkali-soluble group such as a COOH group or an OH group and a polymerizable double bond (carbon) in one molecule. The compound of the -intercarbon unsaturated bond is not limited to the compound shown below.

That is, you can list:

(1) by reacting an isocyanate group with an OH group in advance, leaving an unreacted isocyanate group, and a compound containing at least one (meth) acryloyl group and a carboxyl group-containing acrylic resin The resulting urethane modified acrylic resin containing a polymerizable double bond

(2) an unsaturated resin-containing acrylic resin obtained by a reaction of a carboxyl group-containing acrylic resin with a compound having an epoxy group and a polymerizable double bond in a molecule

(3) Acid side-chain epoxy acrylate resin

(4) An acrylic resin containing a polymerizable double bond obtained by reacting an OH group-containing acrylic resin with a dibasic acid anhydride having a polymerizable double bond.

Particularly preferred among the above are the resins of (1) and (2).

As a specific example, a copolymer having a OH group such as 2-hydroxyethyl acrylate, a COOH group-containing methacrylic acid, an acrylic or vinyl compound copolymerizable with the compounds, and the like may be used. The OH group is a compound obtained by reacting a reactive epoxy ring with a compound of a polymerizable double bond (for example, a compound such as glycidyl acrylate). In the reaction with the OH group, in addition to the epoxy ring, a compound having an acid anhydride, an isocyanate group or an acrylonitrile group can also be used.

Further, a compound obtained by reacting a compound having an epoxy ring with an unsaturated carboxylic acid such as acrylic acid as described in JP-A-6-102,936, and JP-A-6-1- 6-1938, may be used. With or not saturated The reactant obtained by reacting with a polybasic acid anhydride.

Examples of the compound having an alkali-soluble group such as a COOH group and a polymerizable double bond include, for example, Dianal NR series (manufactured by Mitsubishi Rayon Co., Ltd.); Photomer 6173 (polyurethane acrylate containing COOH group) Polyurethane acrylic oligomer, manufactured by Diamond Shamrock Co., Ltd.; Viscoat R-264, KS Resist 106 (all manufactured by Osaka Organic Chemical Industry Co., Ltd.); Cyclomer P series, PLACCEL CF200 series (all manufactured by Daicel Chemical Industry Co., Ltd.); Ebecryl 3800 (manufactured by Daicel Co., Ltd.).

The amount of addition of the alkali-soluble resin is preferably in the range of 3% by mass to 50% by mass, more preferably 5% by mass to 30% by mass based on the mass of all the solid matter of the coloring photosensitive composition. %.

- Thermosetting resin -

When the coloring photosensitive composition is prepared, it is preferred to further add a thermosetting resin in addition to the above alkali-soluble resin. By using a thermosetting resin, the strength of the formed coloring layer can be improved, heat resistance can be improved, chemical resistance can be improved, and resistance to a peeling liquid or the like can be improved.

The thermosetting resin is preferably an epoxy resin, and examples of the epoxy resin include a bisphenol A type, a cresol novolac type, a biphenyl type, and an alicyclic epoxy compound, which are equal to a compound having two or more epoxy rings in the molecule.

For example, bisphenol A type can be Epotohto YD-115, Epotohto YD-118T, Epotohto YD-127, Epotohto YD-128, Epotohto YD-134, Epotohto YD-8125, Epotohto YD-7011R, Epotohto ZX-1059, Epotohto YDF-8170, Epotohto YDF-170, etc. (above by Dongdu Chemical Co., Ltd.), DENACOL EX-1101, DENACOL EX-1102, DENACOL EX-1103 Etc. (the above is manufactured by Changchun Chemical Co., Ltd.), PLACCEL GL-61, PLACCEL GL-62, PLACCEL G101, and PLACCEL G102 (the above is manufactured by Daicel Chemical Industry Co., Ltd.), etc. These compounds are similar to bisphenol F type and bisphenol S type epoxy resins as compounds which can be used.

Further, an epoxy acrylate such as Ebecryl 3700, Ebecryl 3701, or Ebecryl 600 (manufactured by Daicel Co., Ltd.) can also be used.

Examples of the cresol novolak type include Epotohto YDPN-638, Epotohto YDPN-701, Epotohto YDPN-702, Epotohto YDPN-703, Epotohto YDPN-704 (above, manufactured by Tohto Kasei Co., Ltd.), DENACOL EM-125, etc. (manufactured by Nagase Chemical Co., Ltd.), the biphenyl type may be, for example, 3,5,3',5'-tetramethyl-4,4'-diglycidylbiphenyl, and the alicyclic epoxy compound may be exemplified by Celloxide 2021. Celloxide 2081, Celloxide 2083, Celloxide 2085, Epolead GT-301, Epolead GT-302, Epolead GT-401, Epolead GT-403, Epolead EHPE-3150 (above manufactured by Daicel Chemical Industries, Ltd.), Sun Tohto ST- 3000, Sun Tohto ST-4000, Sun Tohto ST-5080, Sun Tohto ST-5100, etc. (above by Dongdu Chemical Co., Ltd.), Epiclon 430, Epiclon 673, Epiclon 695, Epiclon 850S, Epiclon 4032 (above DIC Co., Ltd.) .

Further, 1,1,2,2-tetra(p-glycidoxyphenyl)ethane, tris(p-glycidoxyphenyl)methane, triglycidyltris(hydroxyethyl)isotrile can also be used. Polycyanate, diglycidyl phthalate, diglycidyl terephthalate, in addition to Epotohto YH-434, Epotohto YH-434L, as an amine epoxy resin, in bisphenol A A glycidyl ester obtained by modifying a dimer acid in a skeleton of an epoxy resin.

Among them, a compound having a molecular weight/epoxy ring number of 100 or more is preferable, and more preferably 130 to 500. When the "molecular weight/epoxy ring number" is small, the hardenability is high and the shrinkage at the time of curing is large. When the resin is too large, the curability is insufficient, the reliability is insufficient, and the flatness is deteriorated and the film is unsatisfactory.

Specific preferred compounds satisfying this condition include Epotohto YD-115, Epotohto 118T, Epotohto 127, Epotohto YDF-170, Epotohto YDPN-638, Epotohto YDPN-701, PLACCEL GL-61, PLACCEL GL-62, 3, 5 3',5'-tetramethyl-4,4'-diglycidylbiphenyl, Celloxide 2021, Celloxide 2081, Epolead GT-302, Epolead GT-403, Epolead EHPE-3150, and the like.

The amount of addition of the solid material in the case of using the thermosetting resin is preferably in the range of 0.1% by mass to 30% by mass, and more preferably 0.5% by mass to 20% by mass based on the mass of all the solid matter of the coloring photosensitive composition. The best is 1% by mass to 10% by mass. When the amount is in this range, sufficient exposure sensitivity can be obtained without hindering photopolymerization, and thermal polymerization property can be imparted, so that high heat resistance and chemical resistance can be imparted, and the resist liquid can be maintained. Storage stability.

(Organic solvents)

The colored photosensitive composition of the present invention can be prepared by using an organic solvent. Further, the pigment dispersion composition or the ceria fine particle dispersion may be prepared by using an organic solvent.

The organic solvent used in the present invention is preferably a boiling point from the viewpoint of the coating property, the nozzle clogging when the coloring photosensitive composition is applied by the inkjet method, and the solvent removal property when the cured film is formed. It is an organic solvent of 110 ° C or more and 200 ° C or less.

The organic solvent usable in the present invention may, for example, be an ester such as ethyl acetate, n-butyl acetate, isobutyl acetate, amyl formate, isoamyl acetate, isobutyl acetate, butyl propionate, butyl. Isopropyl acrylate, ethyl butyrate, butyl butyrate, methyl lactate, ethyl lactate, methyl oxyacetate, ethyl oxyacetate, butyl oxyacetate, methyl methoxyacetate, methoxy Ethyl acetate, butyl methoxyacetate, methyl ethoxyacetate, ethyl ethoxyacetate, and methyl 3-oxypropionate, ethyl 3-oxypropionate, etc. Acid alkyl esters (for example, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, etc.), 2 Alkyl 2-oxopropionates such as methyl oxypropionate, ethyl 2-oxypropionate or propyl 2-oxypropionate (for example, methyl 2-methoxypropionate, 2- Ethyl methoxypropionate, propyl 2-methoxypropionate, methyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, 2-oxy-2-methylpropanoate Ester, ethyl 2-oxy-2-methylpropanoate, methyl 2-methoxy-2-methylpropanoate, ethyl 2-ethoxy-2-methylpropionate Etc.), as well as methyl pyruvate, ethyl pyruvate, propyl pyruvate, methyl acetate, ethyl acetate, methyl 2-oxobutanoate, ethyl 2-oxobutanoate, 1,3-butanediol diacetate, etc.; ethers such as diethylene glycol dimethyl ether, tetrahydrofuran, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monomethyl ether, diethyl Glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol methyl ether acetate, propylene glycol diethyl ether acetate, propylene glycol propyl ether acetate, diethylene glycol diethyl ether, diethylene glycol monoethyl ether acetate, Diethylene glycol monobutyl ether acetate, propylene glycol n-propyl ether acetate, propylene glycol diacetate, propylene glycol n-butyl ether acetate, propylene glycol phenyl ether, propylene glycol phenyl ether acetate, dipropylene glycol monomethyl ether Acid ester, dipropylene glycol n-propyl ether acetate, dipropylene glycol n-butyl ether acetate, tripropylene glycol mono-n-butyl ether, tripropylene glycol methyl ether acetate, etc.; ketones, such as acetone, methyl ethyl ketone, ring Ethyl ketone, 2-heptanone, 3-heptanone, etc.; alcohols, for example, ethanol, isopropanol, propylene glycol methyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-n-butyl ether, aromatic hydrocarbons, such as toluene, two Toluene, etc.

Suitable among these are methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethyl lactate, diethylene glycol dimethyl ether, butyl acetate, 3-methoxypropionic acid Ester, 2-heptanone, cyclohexanone, ethyl carbitol acetate, butyl carbitol acetate, propylene glycol methyl ether, propylene glycol methyl ether acetate, propylene glycol diethyl ether acetate, and the like.

The organic solvent may be used in combination of two or more kinds in addition to the above.

The content of the organic solvent in the coloring photosensitive composition of the present invention can be appropriately selected according to the purpose. From the viewpoint of coating properties, it is preferred that all the solid content of the colored photosensitive composition is 10% by mass. 30% by mass range.

(surfactant)

When the concentration of the pigment is increased, the thixotropy of the coating liquid is generally increased. Therefore, it is easy to apply or transfer the colored photosensitive composition on the substrate to form a colored photosensitive composition layer (colored layer coating film). Uneven thickness. In particular, in the formation of the colored photosensitive composition layer (colored layer coating film) by a slit coating method or the like, it is important to form a coating liquid for forming a photosensitive composition layer before drying to form a coating liquid. A film of uniform thickness. Therefore, it is preferred to contain a suitable surfactant in the colored photosensitive composition. The surfactants disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei.

As the surfactant for improving the coating property, a nonionic surfactant, a fluorine-based surfactant, an anthrone-based surfactant, or the like can be added.

Nonionic surfactants are preferably, for example, polyoxyethylene glycols, polyoxypropylene glycols, polyoxyethylene alkyl ethers, polyoxyethylene alkyl aryl ethers, polyoxyethylene alkyl esters, poly Nonionic surfactants such as oxypropylene alkyl ethers, polyoxypropylene alkyl aryl ethers, polyoxypropylene alkyl esters, sorbitan alkyl esters, and monoglyceride alkyl esters.

Specifically, there are polyoxyalkylene glycols such as polyoxyethylene glycol and polyoxypropylene glycol; polyoxyalkylene groups such as polyoxyethylene lauryl ether, polyoxypropylene stearyl ether, and polyoxyethylene oleyl ether. Alkyl ethers; polyoxyethylene octyl phenyl ether, polyoxyethylene polystyrene ether, polyoxyethylene tribenzyl phenyl ether, polyoxyethylene-propylene polystyrene ether, polyoxyethylene oxime Polyoxyethylene aryl ethers such as phenyl ether; polyoxyethylene lauric Nonionic surfactants such as polyoxyalkylene dialkyl esters such as acid esters and polyoxyethylene distearate, sorbitan fatty acid esters, and polyoxyalkylene sorbitan fatty acid esters.

Specific examples of such nonionic surfactants include Adeka Pluronic series, ADEKA NOL series, Tetronic series (above manufactured by ADEKA Co., Ltd.), EMULGEN series, and RHEODOL series (above by Kao shares limited) Company manufacturing), Eleminol series, NONYLPOL series, OCTAPOL series, DODECAPOL series, NEWPOL series (above manufactured by Sanyo Chemical Co., Ltd.), PIONIN series (above manufactured by Takemoto Oil Co., Ltd.), NISSAN NONION series (above by Japanese fat Manufacturing company, etc.). These commercially available nonionic surfactants can be suitably used. A preferred HLB value is 8 to 20, and more preferably 10 to 17.

The fluorine-based surfactant can be suitably used as a compound having a fluoroalkyl group or a fluorine-extended alkyl group in at least any part of the terminal, the main chain and the side chain.

Specific commercial products are, for example, Megafac F142D, Megafac F172, Megafac F173, Megafac F176, Megafac F177, Megafac F183, Megafac 780, Megafac 781, Megafac R30, Megafac R08 (manufactured by DIC Corporation), and Fluorad FC-135. , Fluorad FC-170C, Fluorad FC-430, Fluorad FC-431 (above manufactured by Sumitomo 3M Co., Ltd.), Surflon S-112, Surflon S-113, Surflon S-131, Surflon S-141, Surflon S-145 , Surflon S-382, Surflon SC-101, Surflon SC-102, Surflon SC-103, Surflon SC-104, Surflon SC-105, Surflon SC-106 (The above is manufactured by Asahi Glass Co., Ltd.), Eftop EF351, Eftop 352, Eftop 801, Eftop 802 (above, manufactured by JEMCO Co., Ltd.).

Examples of the anthrone-based surfactants include Toray Silicone DC3PA, Toray Silicone DC7PA, Toray Silicone SH11PA, Toray Silicone SH21PA, Toray Silicone SH28PA, Toray Silicone SH29PA, Toray Silicone SH30PA, Toray Silicone SH-190, Toray Silicone SH-193, Toray Silicone SZ-6032, Toray Silicone SF-8428, Toray Silicone DC-57, Toray Silicone DC-190 (above manufactured by Dow Corning Toray Silicone Co., Ltd.), TSF-4440 , TSF-4300, TSF-4445, TSF-4446, TSF-4460, TSF-4452 (above, manufactured by Momentive Performance Materials Japan).

The surfactant is preferably used in an amount of 5 parts by mass or less, more preferably 2 parts by mass or less, based on 100 parts by mass of the coating liquid for forming the colored photosensitive composition layer. When the amount of the surfactant is more than 5 parts by mass, the surface roughness of the coating drying tends to occur, and the smoothness is easily deteriorated.

(other additives)

Further, in the colored photosensitive composition used in the present invention, in addition to the above components, various known additives may be further used as needed.

Hereinafter, such additives will be described.

When the alkali solubility of the uncured portion is promoted and the developability of the colored photosensitive composition is further improved, an organic carboxylic acid, preferably a molecule, may be used. The addition of a low molecular weight organic carboxylic acid in an amount of 1000 or less. Specific examples thereof include aliphatic monocarboxylic acids such as formic acid, acetic acid, propionic acid, butyric acid, valeric acid, trimethylacetic acid, caproic acid, diethylacetic acid, heptanoic acid, and caprylic acid; oxalic acid, malonic acid, and amber. Acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, tridecanedioic acid, methylmalonic acid, ethylmalonic acid, dimethylmalonic acid , an aliphatic dicarboxylic acid such as methyl succinic acid, tetramethyl succinic acid or citraconic acid; tricarballylic acid, aconitic acid, camphoronic acid And other aliphatic tricarboxylic acids; benzoic acid, toluic acid, acrylic acid, 2,3-dimethylbenzoic acid (hemellitic acid), 3,5-dimethylbenzoic acid (mesitylenic acid) and other aromatic monocarboxylic acids Acid; phthalic acid, isophthalic acid, terephthalic acid, trimellitic acid, trimesic acid, melophanic acid, pyromellitic Acid), such as aromatic polycarboxylic acid; phenylacetic acid, phenoxyacetic acid, methoxyphenoxyacetic acid, hydrogenated atropic acid, hydrogenated cinnamic acid, bitter almond , phenylsuccinic acid, atropic acid, cinnamic acid, methyl cinnamate, benzyl cinnamate, cinnamylideneacetic acid, coumaric acid, umbellic acid, etc. carboxylic acid.

(alkoxydecane compound)

In the colored photosensitive composition of the present invention, an alkoxydecane compound, particularly a decane coupling agent, can be used from the viewpoint of improving adhesion to a substrate.

The decane coupling agent preferably has an alkoxyalkyl group as a hydrolyzable group which can be chemically bonded to an inorganic material, and preferably exhibits affinity by interaction or formation of a bond with an organic resin (methyl group). Acetylene, phenyl, fluorenyl, epoxy More preferably, it is a (meth) propylene decyl propyl trimethoxy decane.

The amount of addition of the decane coupling agent is preferably in the range of 0.2% by mass to 5.0% by mass, more preferably 0.5% by mass to 3.0% by mass based on the mass of all the solid matter of the colored photosensitive composition. %.

(common sensitizer)

The colored photosensitive composition used in the present invention preferably further contains a co-sensitizer as needed. In the present invention, the co-sensitizer has a function of further improving the sensitivity of the sensitizing dye or the initiator to the active radiation or suppressing polymerization inhibition of the polymerizable compound due to oxygen.

Examples of such a co-sensitizer include amines, for example, "Journal of Polymer Society", Vol. 10, p. 3173 (1972) by MRSander et al., Japanese Patent Publication No. 44-20189 Japanese Laid-Open Patent Publication No. SHO-52-82102, Japanese Patent Laid-Open No. SHO-52-134692, Japanese Patent Laid-Open Publication No. SHO 59-138205 The compound or the like described in Japanese Patent Laid-Open Publication No. SHO-63-33104, and the disclosure of Research Disclosure No. 33825, specifically, triethanolamine and p-dimethylaminobenzene. Ethyl formate, p-nonyldimethylaniline, p-methylthiodimethylaniline, and the like.

Other examples of the co-sensitizer include a thioether such as a disulfide compound of JP-A-56-75643, and specific examples thereof include 2-mercaptobenzothiazole and 2-mercaptobenzoxazole. , 2-mercaptobenzimidazole, 2-mercapto-4(3H)-quinazoline, β-nonylnaphthalene, and the like.

Further, other examples of the co-sensitizer include an amino acid compound (for example, N-phenylglycine), and an organometallic compound (for example, tributyltin acetate) described in Japanese Patent Publication No. Sho 48-42965. A hydrogen compound (such as trithiane or the like) described in JP-A-H05-344727, and the like.

From the viewpoint of the improvement of the hardening speed by the balance between the growth rate of the polymerization and the chain transfer, the content of the co-sensitizer is preferably 0.1% by mass based on the total solid content of the colored photosensitive composition. The range of ~30% by mass, more preferably in the range of 1% by mass to 25% by mass, still more preferably in the range of 1.5% by mass to 20% by mass.

(polymerization inhibitor)

In the present invention, in order to prevent unnecessary thermal polymerization of the polymerizable ethylenically unsaturated compound during or during storage of the colored photosensitive composition, it is desirable to add a small amount of the thermal polymerization inhibitor.

The thermal polymerization inhibitor which can be used in the present invention may, for example, hydroquinone, p-methoxyphenol, di-tert-butyl-p-cresol, pyrogallol, or tert-butylcatechol ( T-butyl catechol), benzoquinone, 4,4'-thiobis(3-methyl-6-tert-butylphenol), 2,2'-methylenebis(4-methyl-6- Tributylphenol), N-nitrosophenylhydroxylamine sulfonium salt, phenoxazine, phenothiazine, and the like.

The amount of the thermal polymerization inhibitor added is preferably from 0.01% by mass to 5% by mass based on the coloring photosensitive composition. Moreover, in order to prevent polymerization inhibition due to oxygen, it is also possible to add advanced such as behenic acid or behenylamine as needed. A fatty acid derivative or the like is present on the surface of the photosensitive layer during drying after coating. The amount of the higher fatty acid derivative to be added is preferably from 0.5% by mass to 10% by mass based on the coloring photosensitive composition.

(Plasticizer)

Further, in the present invention, in order to improve the physical properties of the colored photosensitive composition, an inorganic filler, a plasticizer or the like may be added.

The plasticizer is, for example, dioctyl phthalate, di(dodecyl) phthalate, triethylene glycol dioctanoate, dimethyl phthalate, and tricresyl phosphate. The ester, dioctyl adipate, dibutyl sebacate, triethyl decyl glycerol, and the like may be added in an amount of 10% by mass or less based on the total mass of the ethylenically unsaturated compound and the resin.

In the exposure to ultraviolet light or the like, the colored photosensitive composition of the present invention containing the above-mentioned components is cured with high sensitivity, is excellent in pattern formability, and has good shape and visible light transmittance, and is suitable for use in the coloring pattern. The color filter is formed in a colored pattern.

<Color filter and method of manufacturing the same>

The color filter of the present invention comprises a coloring layer formed using the colored photosensitive composition. The coloring layer on the substrate includes a coloring layer (coloring pattern) having respective colored regions such as red, green, and blue which form respective pixels of the color filter.

The color filter of the present invention is formed by containing specific (D) heat-resistant particles, and thus can have fine contact holes and exhibit a low dielectric constant.

Therefore, the color filter of the present invention is suitable for use in a liquid crystal display device, The use of EL display devices and solid-state imaging devices. It is particularly suitable for use in liquid crystal display devices, and in particular, it is used in a liquid crystal display device of the COA mode. When used in a liquid crystal display device, high-intensity image display can be performed, and color tone and contrast are also excellent.

The color filter of the present invention can be formed by any method as long as it is a coloring layer (colored pattern) obtained by curing the colored photosensitive composition of the present invention.

Particularly preferably, the method for producing a color filter of the present invention comprises the steps of: a colored layer forming step of applying the colored photosensitive composition onto a substrate to form a colored layer; and an exposing step of patterning the colored layer The exposure process forms a latent image; and the developing step develops the color layer on which the latent image is formed to form a pattern.

Further, in the method of producing a color filter of the present invention, it is particularly preferable to further provide a post-baking (post-heating) step, that is, heat-treating the colored pattern formed in the developing step. In the case of setting a multicolor coloring pattern, the post-baking step can also be performed after setting the coloring pattern of the last color.

In addition, a step of irradiating the colored pattern with ultraviolet rays (post exposure) may be provided between the developing step and the post-baking step.

Further, a color filter can be produced by a method such as the transfer method described in Japanese Laid-Open Patent Publication No. 2009-116078, or the ink jet method described in Japanese Laid-Open Patent Publication No. 2009-134263.

Hereinafter, a method of producing the color filter of the present invention will be described more specifically.

- Colored layer forming step -

In the method for producing a color filter of the present invention, first, the color of the present invention is applied by a coating method such as spin coating, slit coating, cast coating, roll coating, bar coating, or inkjet. The photosensitive composition is applied onto a substrate to form a colored layer, which is pre-cured (prebaked) as needed, and the colored layer is dried.

Examples of the substrate include soda glass, alkali-free glass, borosilicate glass, quartz glass, and resin substrate used in a liquid crystal display device, and a charge coupled device (CCD) and a complementary metal used in a solid-state imaging device. An oxide semiconductor (Complementary Metal Oxide Semiconductor, CMOS), a photoelectric conversion element substrate in an organic CMOS, a germanium substrate, or the like.

Further, as a COA liquid crystal display device, a substrate for driving a liquid crystal display device of a thin film transistor (TFT) type is used.

Further, in order to improve the adhesion to the upper layer, prevent the diffusion of the substance, or planarize the surface, an undercoat layer, an interlayer insulating film, or the like may be provided on the substrates as needed.

The prebaking conditions include heating at 70 ° C to 130 ° C for about 0.5 minutes to 15 minutes using a hot plate or an oven.

Further, the thickness of the coloring layer formed of the colored photosensitive composition can be appropriately selected as needed. In the color filter for a liquid crystal display device, it is preferably in the range of 0.2 μm to 5.0 μm, more preferably in the range of 1.0 μm to 4.0 μm, and most preferably in the range of 1.5 μm to 3.5 μm. Further, in the COA liquid crystal display device color filter, it is preferably in the range of 2.5 μm to 3.5 μm. And, in solid photos In the color filter for the image element, it is preferably in the range of 0.2 μm to 5.0 μm, more preferably in the range of 0.3 μm to 2.5 μm, and most preferably in the range of 0.3 μm to 1.5 μm.

Further, the thickness of the colored layer is the film thickness after prebaking.

- Exposure step -

Then, in the method of producing a color filter of the present invention, for example, a coloring composition layer formed on a substrate is exposed through a photomask. The light or radiation to be applied in the exposure is preferably a g-line, an h-line, an i-line, a KrF light, or an ArF light, and particularly preferably an i-line.

Moreover, other exposure light sources can also use ultra-high pressure, high pressure, medium pressure, low pressure mercury lamps, chemical lamps, carbon arc lamps, xenon lamps, metal halide lamps, visible and ultraviolet laser light sources, fluorescent lamps, tungsten lamps. , the sun, etc.

In the case of being consistent with the photosensitive wavelength of the resist, it is preferable to use an ultraviolet laser as a light source, preferably an ultraviolet light having a wavelength of 300 nm to 380 nm. More preferably, it is an ultraviolet laser in the range of 300 nm to 360 nm. Specifically, in particular, a third harmonic (355 nm) of a Nd:YAG laser as a solid laser or a XeCl (308 nm) of a pseudo-molecular laser, XeF (353), which is large in output power and relatively inexpensive, can be suitably used. Nm).

The exposure amount of the colored layer is in the range of 1 mJ/cm ² to 100 mJ/cm ² , and more preferably in the range of 1 mJ/cm ² to 50 mJ/cm ² . When the exposure amount is in this range, it is preferable in terms of productivity in pattern formation.

The exposure device is not particularly limited, and a commercially available exposure device may use Callisto (manufactured by V Technology Co., Ltd.) or EGIS (manufactured by V Technology Co., Ltd.) or DF2200G (manufactured by Dainippon Screen Co., Ltd.) and the like. Further, it is also possible to suitably use a device other than the above.

The colored layer which has been exposed as described above can also be heated.

Further, in order to suppress oxidative fading of the colored material in the colored layer, exposure may be performed while circulating nitrogen gas in the chamber.

- development step -

Then, the colored layer after exposure is developed in a developing solution. Thereby, a colored pattern can be formed.

When the developer is a uncured portion (unexposed portion) in which the colored layer is dissolved and the hardened portion (exposed portion) is not dissolved, a combination of various organic solvents or an aqueous alkaline solution can be used. In the case where the developer is an alkaline aqueous solution, it is preferred to adjust the alkali concentration to pH 11 to 13, and more preferably to adjust the alkali concentration to pH 11.5 to 12.5. Examples of the alkaline aqueous solution include sodium hydroxide, potassium hydroxide, sodium carbonate, sodium hydrogencarbonate, sodium citrate, sodium metasilicate, aqueous ammonia, ethylamine, diethylamine, dimethylethanolamine, and tetramethyl. An aqueous alkaline solution of ammonium hydroxide, tetraethylammonium hydroxide, choline, pyrrole, piperidine, 1,8-diazabicyclo-[5.4.0]-7-undecene or the like.

In the color filter used in the COA liquid crystal display device, the developer is particularly preferably an organic alkaline developer from the viewpoint of damage to the circuit or the like of the underlayer.

The development time is preferably from 30 seconds to 300 seconds, more preferably from 30 seconds to 120 seconds. The development temperature is preferably from 20 ° C to 40 ° C, more preferably from 20 ° C to 30 ° C.

Development can be performed by immersing method, spraying method, spraying The fog method is performed.

Further, after development using an alkaline aqueous solution, it is preferred to wash with water.

Thereafter, in the method for producing a color filter of the present invention, the post-baking (post-heating) and/or ultraviolet irradiation (post-exposure) may be performed on the colored pattern formed by development as needed to promote coloring. Hardening of the pattern.

- UV irradiation (post exposure) step -

In the method for producing a color filter of the present invention, the colored pattern (pixel) formed by using the colored photosensitive composition may be exposed to light after irradiation with ultraviolet rays.

- post-baking (post-heating) steps -

It is preferable to further heat-treat the colored pattern (or the colored pattern subjected to post-exposure) which has been developed as described above. The colored pattern can be further cured by heat-treating the formed color pattern. This heat treatment can be performed, for example, by a heating plate, various heaters, an oven, or the like.

The temperature at the time of heat treatment is preferably from 100 ° C to 300 ° C, more preferably from 150 ° C to 250 ° C. Moreover, the heating time is preferably about 10 minutes to 120 minutes.

The colored pattern obtained as described above constitutes a pixel in the color filter. In the production of a color filter having a plurality of hues of pixels, the above-described steps and the optional ultraviolet (post exposure) step or post-baking may be repeated in accordance with the desired number of colors ( Late heating) steps.

In addition, the ultraviolet irradiation (post exposure) step or post-baking may be performed after the formation, exposure, and development of each of the monochromatic coloring composition layers (per color). The baking (post-heating) step may also perform the ultraviolet irradiation (post exposure) step or the post-baking (post-heating) after the formation, exposure, and development of all the colored composition layers of the desired number of colors. step.

<Liquid crystal display device, organic EL display device>

The liquid crystal display device and the organic EL display device of the present invention comprise the color filter of the present invention described above.

The definition of the liquid crystal display device, the organic EL display device, or the details of each display device, for example, "electronic display device (sasaki Sasaki, Industrial Research Association, issued in 1990)", "display device (Ibuki Shunzhang) , Industrial Book Co., Ltd., issued in the first year of Heisei (1989), etc. Further, the liquid crystal display device is described in, for example, "Next-Generation Liquid Crystal Display Technology (Endowed by Natsuda, Ltd., Industrial Investigations Co., Ltd., issued in 1994)". The liquid crystal display device to which the present invention is applied is not particularly limited, and can be applied to, for example, various types of liquid crystal display devices described in the "Next Generation Liquid Crystal Display Technology".

The color filter of the present invention is particularly effective for a liquid crystal display device of a thin film type transistor (TFT) type. A liquid crystal display device of a color TFT type is described, for example, in "Color TFT liquid crystal display (Kyoritsu Publishing Co., Ltd., issued in 1996)". In addition, the present invention is also applicable to a liquid crystal display device in which a viewing angle such as a horizontal electric field driving method such as In-plane Switching (IPS) or a multi-domain vertical alignment (MVA) is expanded. Or super Super Twisted Nematic (STN), Twisted Nematic (TN), Vertical Alignment (VA), Optically Compensated Splay (OCS), Fringe Field Switching (FFS) ), and Reflective Optically Compensated Bend (R-OCB).

In particular, since the color filter of the present invention is excellent in fine contact hole formation property and low in dielectric constant, the effect of the present invention can be sufficiently exhibited by being supplied to the COA system.

In the COA liquid crystal display device, the required characteristics of the color filter layer must have a low dielectric constant and a peeling resistance in addition to the above-mentioned usual required characteristics, and the color filter of the present invention can satisfy the above. Claim.

In order to satisfy the required characteristics of the low dielectric constant, a resin film may be further provided on the color filter layer.

Further, in the coloring layer formed by the COA method, in order to electrically connect the ITO electrode disposed on the colored layer and the terminal of the driving substrate below the colored layer, it is necessary to form one side having a length of about 1 μm to 40 μm. Rectangular, or circular or elliptical with a diameter of 1 μm to 40 μm, or The shape of the pixel cross section is a rectangular to tapered contact hole (guide path), and it is particularly preferable that the size of the via (that is, the length of one side) is 5 μm or less, by using the present invention. The colored photosensitive composition can form a conduction path of 5 μm or less. When the cross-sectional shape of the contact hole does not have a rectangular to a conical shape or the opening is insufficient, the disconnection or conduction failure of the transparent conductive film occurs, and the color filter is used for the image. In the case of the display device, there is a case where the display defect is caused. However, by using the colored photosensitive composition of the present invention, there is an advantage that the problem of the deterioration or collapse of the shape of the contact hole is suppressed.

These image display methods are described, for example, in "EL, PDP, LCD Display - Technology and Market Trends - (Dongli Research Center Investigation and Research Department, issued in 2001)" on page 43 and the like.

In addition to the color filter of the present invention, the liquid crystal display device of the present invention includes various components such as an electrode substrate, a polarizing film, a retardation film, a backlight, a spacer, and a viewing angle securing film. The color filter of the present invention can be applied to a liquid crystal display device including the known members.

For these components, for example, "'94 Liquid Crystal Display Peripherals, Chemicals Market (Ichishima Kentaro, CMC Co., Ltd., issued in 1994), "2003 LCD related market status and future prospects (volume) (Table It is described in "Fuji Chimera Research Institute, Inc., issued in 2003".

For backlighting, SID meeting Digest 1380 (2005) (A. Konno et al.) or Display Monthly, December 2005 issue, page 18 to page 24 (Island Kang Yu), Display Monthly, December 2005 No. 25th ~ 30th (Yumu Longming) has been recorded.

When the color filter of the present invention is used in a liquid crystal display device, high contrast can be achieved when combined with a conventionally known three-wavelength tube of a cold cathode tube, and in addition, by using red, green, and blue LED light sources ( RGB-LED) provides backlighting as a backlight A liquid crystal display device having high color reproducibility and high color purity.

Further, the color filter of the present invention can be used for a solid-state imaging device such as a CCD or a CMOS. When used in a solid-state imaging device, it can provide a color filter having high luminance and good color decomposability.

[Examples]

Hereinafter, the present invention will be specifically described by way of examples, but it is not limited to the examples below. In addition, unless otherwise stated, "%" and "parts" are quality standards.

[Example 1]

The following components were mixed and dissolved to prepare a coloring photosensitive composition.

Further, the blue pigment dispersion can be prepared as shown below.

6.9 parts of CI Pigment Blue 15:6 and a dispersing agent (Solsperse 5500 manufactured by Lubrizol Corporation of Japan) were mixed with 6.9 parts of propylene glycol monomethyl ether acetate, and the pigment was sufficiently dispersed by using a bead mill. A blue pigment dispersion is prepared.

[Example 2 to Example 10, Comparative Example 1 to Comparative Example 3]

The components constituting the composition of Example 1 were changed to the components shown in Table 2 and The coloring photosensitive compositions of Examples 2 to 10 and Comparative Examples 1 to 3 were prepared in the same manner as in Example 1 except that the amount of use was adjusted. The unit of the numerical value in Table 2 is gram (g).

Further, the components newly used in the examples 2 to 10 and the comparative examples 1 to 3 are as follows.

The other dyes (A-3) to other dyes (A-5) have the following structures (A-3) to (A-5), respectively, and are not equivalent to the dye of the formula (I).

Further, the cerium oxide microparticles 3 used in Comparative Example 3 were powders.

. Separation of cerium oxide microparticles 2: hollow particle type, through rear 1420 manufactured by Catalyst Chemical Co., Ltd., the average primary particle diameter of cerium oxide microparticles is 60 nm, the content of cerium oxide is 20.5%, and the dispersion medium is different. The refractive index of propanol and cerium oxide microparticles is 1.30

. Cerium dioxide microparticles 3: amorphous ceria, average primary particle size of 250 nm to 350 nm, SEAHOSTAR KE-P30 manufactured by Nippon Shokubai Co., Ltd. Powder, refractive index is 1.43

. Organic microparticles 1: Polymethyl methacrylate crosslinked product, EPOSTAR MX20W manufactured by Nippon Shokubai Co., Ltd., latex concentration of 7.5% to 10%, average particle size of organic fine particles of 10 nm to 30 nm, dispersion The medium is ethylene glycol

. Organic fine particles 2: crosslinked styrene-acrylic hollow particles, SX866A manufactured by JSR Co., Ltd., organic fine particles having an average primary particle diameter of 300 nm, powder

The heat resistance of the fine particles contained in the cerium oxide fine particle dispersion 1 to the cerium oxide fine particle 3 and the organic fine particle 1 to the organic fine particle 2 was evaluated by the following measurement method.

Each of the fine particles was heated in an oven at a predetermined temperature for 60 minutes, and the shape of the heated particles was compared with the shape of each of the fine particles before heating using a transmission electron microscope (TEM).

No particles were found to have any deformation at a heating temperature of 180 ° C, and these fine particles were all heat-resistant particles of the present invention. Further, the evaluation results at the heating temperatures of 200 ° C and 230 ° C are shown in Table 1 together with the results at 180 ° C.

The following evaluation was performed using each of the obtained coloring photosensitive compositions. The results are summarized in Table 3.

<reflow>

The coloring photosensitive composition was applied to the substrate (1737, manufactured by Corning Incorporated) so as to have a film thickness of 3.7 μm after prebaking (3.2 μm after post-baking) at 90 ° C for 120 seconds. Prebaking under conditions.

A contact hole having a diameter of 25 μm (hereinafter sometimes referred to as CH) is used in the pixel portion to form a mask having a perfect circular pattern, and a proximity exposure machine as a high-pressure mercury lamp (manufactured by Hitachi High-Technologies Corporation, LE5565A) is used. As an exposure light source, exposure was performed at an exposure of GAP=200 μm and an exposure amount of 50 mJ/cm ² , and a developing solution of 0.045 wt% of KOH (CDK-1, manufactured by Fujifilm Electronic Materials Co., Ltd.) was used at 23 ° C. A 50 second spray development was performed, and the rinse was performed by pure water. Thereafter, post-baking was carried out at 230 ° C for 30 minutes. The shape of the cross section after post-baking was observed by a scanning electron microscope.

The CH cross-sectional shape after development of the proximity exposure is in principle rectangular or undercut, so that the taper angle after post-baking can be used as an index for utilizing the reflow property of heat.

(judgment basis)

◎: The taper angle after post-baking is 45° or more

○: The taper angle after post-baking is 30° or more and less than 45°

×: the taper angle after post-baking is less than 30°

<Contact hole opening diameter>

The coloring photosensitive composition was applied to the substrate (1737, manufactured by Corning Incorporated) so as to have a film thickness of 3.7 μm after prebaking (3.2 μm after post-baking) at 90 ° C for 120 seconds. Prebaking under conditions.

A contact hole having a diameter of 25 μm is used in the pixel portion to form a mask having a perfect circular pattern, and a proximity exposure machine (manufactured by Hitachi High-Technologies Corporation, LE5565A) as a high-pressure mercury lamp is used as an exposure light source at exposure GAP= The exposure was carried out at 200 μm, and the exposure amount was 50 mJ/cm ² , and development was carried out using a developing solution of 0.045 wt% of KOH (CDK-1, manufactured by Fujifilm Electronic Materials Co., Ltd.), and rinsed with pure water. Thereafter, post-baking was carried out at 230 ° C for 30 minutes. The CH opening diameter of the obtained blue pixel was measured. The CH opening ratio was calculated by the following formula and evaluated by the following criteria.

CH opening ratio (%) = [CH opening diameter (after post baking) / CH mask diameter] × 100

(judgment basis)

◎: The opening ratio is 80% or more

○: The opening ratio is 60% or more ~ less than 80%

×: The opening ratio is less than 60%

<relative dielectric constant>

The relative dielectric constant is carried out by the following methods a) to i). a) On a chrome-coated glass substrate (75 mm on one side and 0.3 μm on the chrome film), the rotation speed is adjusted so that the film thickness after hardening (post-baking) is 3.2 μm, by rotary coating The coloring photosensitive composition was applied to a cloth machine.

b) Secondly, a chromium film formed with a colored film at 100 ° C for 120 seconds The coated glass substrate is prebaked on a hot plate to dry the solvent.

c) After prebaking, the colored film was irradiated with light at a exposure amount of 50 mJ/cm ² using a 2.5 kW ultrahigh pressure mercury lamp.

d) Next, a chromium-coated glass substrate on which a colored film was formed was subjected to heat curing (post-baking) at 220 ° C for 60 minutes by a hot air circulation dryer to prepare a test piece.

e) After the post-baking, the color film of one corner of the test piece is peeled off to expose the surface of the chrome.

f) Next, the silver paste was spin-coated on the back side of the test piece and air-dried. Thereafter, the silver exposed surface of the surface is electrically connected (connected) to the silver paste coated surface of the back surface by the silver paste.

g) After drying, on the surface of the coating film of the test piece, a vacuum evaporation apparatus (trade name: ion sputtering E1030, manufactured by Hitachi Co., Ltd.) was used, by Pt. The Pd target was formed on the test piece 1 in the manner shown in Fig. 1 to form a main electrode 2 (inner circle) having a thickness of about 50 nm and a protective electrode 3 (outer circle). Further, the chromium surface 4 cut out in the above e) is exposed on the test piece 1.

h) After the electrode was fabricated, the thickness of the coating film of the portion of the test piece to which the electrode was not attached was measured by a stylus type surface shape measuring device (trade name: DEKTAK3, manufactured by ULVAC Co., Ltd.).

i) Next, a dielectric test fixture 16451B and an electrode are mounted on a static capacitance measuring device (impedance analyzer 4294A, manufactured by Agilent Technologies, Inc.), and further, the test piece in the above g) is mounted, and the measurement is performed. The relative dielectric constant ε' at the application of an alternating voltage of 1 kHz and 0.5 V. The measurement results were evaluated by the following criteria.

(judgment basis)

◎: Relative dielectric constant ε' is less than 3.0

○: The relative dielectric constant ε' is 3.0 or more and less than 5.0.

×: The relative dielectric constant ε' is 5.0 or more

According to Table 3, it is understood that the colored photosensitive composition of the embodiment of the present invention containing 1% by mass to 10% by mass of the heat-resistant particles of all the solid matter of the colored photosensitive composition can form fine contact holes, and the obtained The colored layer shows a low dielectric constant. Therefore, it is understood that the colored photosensitive composition of the present invention can be used in the production of a color filter for a liquid crystal display device, and can be particularly used in a COA liquid crystal display device color filter.

1‧‧‧Substrate

2‧‧‧Main electrode

3‧‧‧Protective electrode

4‧‧‧Chromium surface

Claims (8)

A colored photosensitive composition comprising (A) a dye, (B) a photopolymerization initiator, (C) a polymerizable compound having at least two ethylenically unsaturated double bonds in a molecule, and (D) an average of one time The heat-resistant particles other than the organic pigment having a particle diameter of 100 nm or less, the content of the (A) dye is 2% by mass or more and 20% by mass based on the mass of all the solid matter of the colored photosensitive composition. In the following, the content of the heat-resistant particles (D) is 1% by mass or more and 10% by mass or less based on the mass of all the solid matter of the colored photosensitive composition. The colored photosensitive composition according to claim 1, wherein the (D) heat resistant particles are hollow ceria particles. The colored photosensitive composition according to claim 1 or 2, wherein the (A) dye is a metal which is represented by the following formula (I) and is coordinated to a metal atom or a metal compound. Compound: In the formula (I), R ¹ to R ⁶ each independently represent a hydrogen atom or a monovalent substituent, and R ⁷ represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group. The colored photosensitive composition according to claim 3, wherein the (A) dye is a metal-substituted compound represented by the following formula (I-3): In the formula (I-3), R ² , R ³ , R ⁴ and R ⁵ each independently represent a hydrogen atom or a monovalent substituent, and R ⁷ represents a hydrogen atom, a halogen atom, an alkyl group or an aryl group. Or a heterocyclic group; R ⁸ and R ⁹ each independently represent an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylamino group, an arylamino group, or a heterocyclic amino group. ;Ma represents a metal atom or a metal compound; X ³ and X ⁴ each independently represent NR ^a (R ^a represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkylsulfonyl group, or An arylsulfonyl group, an oxygen atom, or a sulfur atom; Y ¹ and Y ² each independently represent NR ^b (R ^b represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkyl group Sulfhydryl or arylsulfonyl), oxygen atom, sulfur atom, or carbon atom; X ⁵ represents a group bondable to Ma, a represents 0, 1, or 2; R ⁸ and Y ¹ may also Bonding to form a ring of 5 members, 6 members, or 7 members, and R ⁹ and Y ² may be bonded to each other to form a ring of 5 members, 6 members, or 7 members. A color filter comprising a coloring layer formed by using the coloring photosensitive composition according to any one of claims 1 to 4. A method of manufacturing a color filter, comprising: a colored layer forming step of applying a colored photosensitive composition according to any one of claims 1 to 4 to a substrate to form a colored layer; and an exposing step of patterning the colored layer Forming a latent image by exposure; and developing a step of developing the colored layer on which the latent image is formed to form a pattern. A liquid crystal display device comprising the color filter of claim 5 of the patent application. A liquid crystal display device comprising the coloring photosensitive composition according to any one of claims 1 to 4, which is formed on a substrate for driving a thin film transistor (TFT) liquid crystal display device. Picture.