201241119 六、發明說明： 【發明所屬之技術領域】 本發明係有關一種具有防污表面之複合瓷磚製造方法及該複合瓷碑， 特別是指一種將抗滲性覆膜層與瓷磚基材複合之製法，可用於施釉磁磚基 材表面形成結構穩固之透明覆膜層，該覆膜層具有高平整度、高亮度、防 污潰、耐酸鹼等優良特性’可提供玻陶業界之產品加值運用。 【先前技術】 一般瓷磚係以瓷土、長石、石英等陶瓷原料經調配成適當配料，經過 調漿、喷粉、高壓成型、施轴、燒成等步驟，將胚體燒結緻密化成瓷碑。 目前瓷磚的生產技術，不論生產速度及良品率都頗為進步，但是因為陶瓷 燒結後，胚體仍留有細小孔隙，會有吸水現象，例如：瓷磚mg國家標準吸 水率為< i%-m不等’究質之& 土經· t以上高溫燒製，随粉料溶合， 吸水率_下。因此糾齡在雜表舰—層釉層，做為改善粗縫面及 隔離水氣’此施釉層雖可在碑胚表面形成玻璃㈣水及減少孔隙，但是在 燒結過程巾’胚土與轉會因為高溫躲產生細微暖形，使得施轴曼碑 之表面平整度不如無施釉的拋光石英碑。 "'石英磚燒成後，經機械研磨、拋光，表面平整光亮者，簡稱拋光石英 碑。-般拋光石英磚表面常有細小孔隙容易藏污_，毛細孔时因累積 灰塵也亏懸浮物或滲透力較強之物質如：咖啡、茶等侵人，使其失去 光澤度或改變原有顏色，即俗稱之「吃色」，且毛孔、坑洞㈣積滋生之細 菌或黴菌’除絲岐鄕料觀外，亦讀人體鎌產生不良影響。為 了改善基材之缺點’目前已開發出多種功能性材料，例如：具有光觸媒、 抗菌、或自料魏之材料，將這些材料塗佈於基材表面，使基材具有特 定之功能。 般的拋光石央碑’因表面不上轴，僅由拋光處理，故竟磚基材表面 仍會留有許麵小孔洞，細小孔湖會因為灰__人，使表面污穢， 201241119 使得必須繁複地定期塗上防護液保養。 然，基材表面若施以一般塗佈方式，會降低基材表面的亮度，且不易 將功能性材·著於基材表面，覆層極易脫落，而導致功能喪失。 天然石材有財磨耗的優點，由石材所做成的壁磚或地磚，其天然的色 心及紋路各具特色’向來是建築巾重要的高級建材。天然石材又因其採集 自原石礦，在加及運輸成本都高，此外天⑼材的表面看似平整光亮， 事實上表©仍有喊磚更多的細小裂縫及毛細孔，通常使用者都會以市售 的防護液或清糊來處理保養石材表面，以聽行走雜及落塵所留下的 髒污，使石材失去光澤，甚至變色。 -般竟碑不論是施喊磚或無絲的拋光^英磚，硬度通常比天然石 材高，孔隙也較小，若運用天然石材的表面去污防護方法處理，效果不彰， 且殘留於孔隙中的微粒污垢，若未完全清除即施以防護，汙垢將會被包覆 而更難移除。 【發明内容】 人：本發明主要目的係提供—種具有防污表面之複合竟磚製造方法及該複 合竟磚’藉此形成-具有抗雜覆膜層與基材的複合體，而複合體表面具 有如鏡面般rfj平整度、高亮度、防水、抗污潰及猶鱗功能特性。 人：本發明另-目的係提供—種具有防污表面之複合糾製造方法及該複 究碑藉由利用種奈米級材料填入釉層表面，經過機械研磨、抛光等 程序形成抗滲性覆膜層與基材的複合體，能於複合體表面達到無毛細孔， 除具有防污效果外，更能達到防止水氣滲入之功效。 〜本發明又-目的係提供—種具雜污表面之複合究磚製造方法及該複 合竟磚’究磚紐具有仿天然石材的紋路，經過表面塗膜處理程序之奈米 級覆膜層具有透0雅’能充分表現仿天然石材的紋路。 本發縣-目的係提供_種具有防污表面之複合曼销造方法及該複 合究碑’城表®塗膜處理程序，可使接觸於£磚表面的污垢不會殘留於 201241119 表面的孔隙，使瓷磚表面容易清理，並可減少化學清潔劑的使用，係一種 具有環保概念的瓷磚。 本發明再-目的係提供-種具有防污表面之複合究碑製造方法及該複 合瓷碑，藉由經機械研磨、拋光等程序使基材表面平整度提高，且所製成 之複合瓷磚表面平整如鏡面並具有增亮效果。 為達成上述目的，本發明之製造方法係以一種施釉瓷碑為基材，特別 疋.於該基材表面被覆奈恤材料之被覆塗麟；該被覆塗膜層係以一種 表面塗膜處理程序，利时米級材料，填人糾基材的釉層表面而形成之 薄模層’再⑽魏_層表錢佈__防護獅，並經職械研磨、抛光 等程序’錄面平整麟高，絲絲面平整如鏡面且具有增亮效果 之複合瓷磚。 【實施方式】 為了讓貴審查委員對本發明揭示目的有更進一步了解，兹舉一較佳 實施例佐以圖示詳細說明本發明的製造方法及其物品。在下列叙述中，應 理解者為本發日种所有之較佳實例僅為例示之用，並非㈣聞本發明。 熟知該項技術者祕轉，本㈣之實制^貞―❹狀 定方法、組成物或材料等。 特 本發明具有防污表面之複妓韻造方紐該複錢磚，^如下述 =參閲第-圖所示’係本發雜佳實酬之複錢射基材剖面示意圖； 、中該基材⑴騎磚频，其主要以喊補娜，秘包含但不限於信 :石、黏土、瓷土、石英等礦物粉料’可先於胚體表面印刷仿石 ' 於基祕喊材釉_⑵之剌玻璃質釉藥，其主要包含 但不限於使用長石、陶古 '女 ^ 1〇〇〇〇r 1?nn〇r N嶺土 K等原料調配，經過高溫燒結，溫 二c-戰不等，製成一種施釉_糾，高溫燒結之雜非是完全燒 :有：體Γ含許多細小孔洞⑶，釉藥層表面也可能不是平坦的，且 含有許多細小的釉藥層孔洞(4)。 201241119 關於具有防污表©之複合i磚製造方法，首先，如第二圖所示，步驟 (S01)，選擇或準備-種施釉究磚為基材，其表面含有許多細小的孔洞。 之後，步驟(S02) ’以機械研磨法將基材釉藥層⑵研磨平整，並可適 時地增加以清搞其表面清絲淨及細小孔洞_灰歸除，且烘乾水份 之步驟(S02-1)。 之後’步娜03) ’備置m級功紐有機溶液為_，於塗劑中 了採用彳_不限於含有奈#4級—氧化Θ溶液等功能性物質n級微粒易 於填補細小孔洞或縫隙，該塗劑可為溶液或混合物。將此塗劑均勻塗佈被 覆於基材轴藥層⑵表面’塗佈方式可採用但不限於喷雜膜法或旋轉舞 法等，只要能將塗劑塗佈於該表面即可形成一層薄膜型態。 之後’步驟(S04)，進行研磨，將塗劑均勻分散，將細小孔洞填補，於 此研磨程巾產生溫度’使塗舰生黏著性反應與釉層結合，得到如第四 圖所示，較高平整度之被覆塗膜層（10)被覆於基材（1)表面。 之後’步驟(S05)，在被覆塗膜層（1〇)上塗佈奈米級防護蠘液，塗佈方 式可採用但不限於喷霧塗膜法或旋轉塗膜法等，只魏將塗劑塗佈於該表 面即可形成一層薄膜型態。 之後，步驟(S06)，以羊毛輪或棉布輪等進行抛光打冑，拋除多餘之壤 液，形成一拋光防護層（20)，並與被覆塗膜層（10)相結合，並藉此形成拋 光防護層（20)、被覆塗膜層（1〇)與基材（1)緊密結合之複合體。 經由上述本發明製造方法所得之具有防污表面的複合瓷磚，如第四圖 所示，其結構為包括由基材（1)、被覆塗膜層（10)及拋光防護層（20)所組 成；由於該被覆塗膜層（10)具有抗滲性且呈透明狀，並覆合於基材（丨）表 面，再於被覆塗膜層（10)上所設有拋光防護層（20)，藉此形成一複合體結 構，且表面呈鏡面狀。 本發明中之複合體結構的覆層表面幾乎完全透明，可充分表現基材之 質感，且具有如鏡面般高平整度、高亮度、防污潰、耐酸驗等特性。 6 201241119 另外’本發明製造方法所製成之複合究磚，因具有仿天然石材的紋路， 經過表面麵處理程序之奈米級覆膜層具有翻性，能充分表現仿天然石 材的紋路。再者’經過表面塗膜處理程序之複合糾，可使接觸於免碑表 面的污垢不會殘留於表面的孔隙，使曼碑表面容易清理並可減少化學清 潔劑的使用’係―種具有雜概念賴新複合竟碑。 【圖式簡單說明】 第-圖·係本判—較佳實_之紐剖面示意圖。 第一圖.係本發明製造方法之步驟流程圖。 第三圖：係本發明製造方法中研磨後清除孔洞内細小灰塵之基材剖面示意 圖。 第四圖.係本發明—較佳實施例之複合兗碑獅示意圖。 【主要元件符號說明】 ⑴·· •基材 (2) · · ·基材轴藥層 〇···基材孔洞 (4)· ··釉藥層孔洞 ⑽）· · ·選擇基材 (502) · . ·研磨 (S02-1) · ·清洗 (503) · · ·被覆塗膜 (504) ·..研磨 (505) · · ·防護蠟 CS06) · · ·拋光 (10) · · ·被覆塗膜層 (20) · ·.拋光防護層201241119 VI. Description of the Invention: [Technical Field] The present invention relates to a composite tile manufacturing method having an antifouling surface and the composite porcelain monument, in particular to a composite of a barrier coating layer and a tile substrate The method can be used for forming a transparent and transparent coating layer on the surface of the glazed tile substrate, and the coating layer has the characteristics of high flatness, high brightness, anti-fouling, acid and alkali resistance, etc. Value application. [Prior Art] In general, ceramic tiles are prepared by mixing ceramic materials such as china clay, feldspar, and quartz into appropriate ingredients. After the steps of slurrying, dusting, high-pressure molding, shafting, and firing, the body is sintered and densified into a porcelain monument. At present, the production technology of ceramic tiles, regardless of production speed and yield rate, is quite advanced, but because the ceramic body still has fine pores left after the sintering of the ceramic, there will be water absorption, for example: the national standard water absorption rate of the tile mg < i%- m does not wait for 'quality> &earth; t above the high temperature firing, with the powder dissolved, water absorption _ lower. Therefore, the age of the miscellaneous watch-layer glaze layer is used to improve the rough surface and to isolate the water vapor. Although the glazing layer can form glass (4) water and reduce the pores on the surface of the monument, but in the sintering process, the soil and the rotation of the soil Because of the high temperature to avoid the slight warm shape, the surface flatness of the Axis Man monument is not as good as that of the polished quartz stone without glazing. "'Quartz brick after firing, mechanically polished, polished, surface smooth and bright, referred to as polished quartz monument. -The surface of the polished quartz brick often has small pores and is easy to be smudged. When the pores are piled up, the dust is also lost or suspended. The substances such as coffee and tea invade people, causing them to lose their gloss or change the original. Color, commonly known as "eat color", and pores, potholes (four) accumulate bacteria or mold 'except for silkworms, also read the human body 镰 has adverse effects. In order to improve the disadvantages of the substrate, various functional materials have been developed, for example, materials having photocatalyst, antibacterial, or self-propelled materials, which are applied to the surface of the substrate to impart a specific function to the substrate. The polished stone inscription "because the surface is not on the axis, only polished, so the surface of the brick substrate will still have a small hole in the surface, the small hole lake will be dirty because of the gray __ people, 201241119 It must be regularly applied with protective fluid maintenance. However, if a general coating method is applied to the surface of the substrate, the brightness of the surface of the substrate is lowered, and it is difficult to apply the functional material to the surface of the substrate, and the coating is easily peeled off, resulting in loss of function. Natural stone has the advantage of being worn out. The wall or floor tile made of stone has its own natural color and texture. It has always been an important building material for construction towels. Natural stone is also collected from the original stone mine, and the transportation cost is high. In addition, the surface of the sky (9) material seems to be flat and bright. In fact, there are still more small cracks and capillary holes in the bricks. Usually users will The surface of the stone is treated with a commercially available protective liquid or clear paste to listen to the dirt left by the walking and falling dust, so that the stone loses its luster and even discolors. -Generally, whether it is a brick or a silkless polished brick, the hardness is usually higher than that of natural stone, and the pores are also small. If the surface treatment method of natural stone is used, the effect is not good, and it remains in the pores. In the case of particulate dirt, if it is not completely removed, it will be protected and the dirt will be coated and more difficult to remove. SUMMARY OF THE INVENTION Human: The main object of the present invention is to provide a composite brick manufacturing method having an antifouling surface and a composite brick formed thereby - a composite having an anti-aliasing layer and a substrate, and the composite The surface has the characteristics of mirror-like rfj flatness, high brightness, water resistance, anti-fouling and scales. Person: Another object of the present invention is to provide a composite correction manufacturing method having an antifouling surface, and the resolving monument is formed by using a nano-grade material to fill the surface of the glaze layer, and mechanically grinding and polishing to form impermeability. The composite of the coating layer and the substrate can achieve the pore-free pores on the surface of the composite body, and in addition to the antifouling effect, the effect of preventing moisture infiltration can be achieved. ~ The present invention is also directed to providing a composite brick manufacturing method with a dirty surface and the composite brick brick having a texture resembling a natural stone, and the nano-layer coating layer having a surface coating treatment process has Through the 0 ya 'can fully express the texture of the imitation of natural stone. Benfa County - the purpose of providing a composite man-made method with anti-fouling surface and the composite monument 'city table ® coating process, so that the dirt contacting the surface of the brick will not remain on the surface of 201241119 It makes the tile surface easy to clean and reduces the use of chemical cleaners. It is a ceramic tile with an environmentally friendly concept. The invention further provides a method for manufacturing a composite monument having an antifouling surface and the composite porcelain monument, wherein the surface of the substrate is improved by mechanical grinding, polishing, etc., and the composite tile surface is prepared. It is flat like a mirror and has a brightening effect. In order to achieve the above object, the manufacturing method of the present invention is based on a glazed porcelain monument, in particular, the coated surface of the substrate is covered with a coating material; the coated coating layer is treated with a surface coating film. , Lishi rice-grade material, filling the surface of the glaze layer of the substrate to form a thin mold layer 're-(10) Wei _ layer table money cloth __ protective lion, and through the mechanical grinding, polishing and other procedures 'recording plane flat A composite tile that is high and has a smooth surface as a mirror and has a brightening effect. [Embodiment] In order to provide a more detailed understanding of the present invention by the reviewing committee, a preferred embodiment will be described in detail to illustrate the manufacturing method of the present invention and its articles. In the following description, it should be understood that all of the preferred embodiments of the present invention are for illustrative purposes only and not for the purpose of the invention. Those who are familiar with the technology, such as the actual method, composition or material. The invention has the antifouling surface of the complex 妓 造 造 造 造 ^ ^ ^ ^ ^ ^ ^ ^ ^ = = = = = = = = = = = = = = = = = = = = = = = = = = = = The substrate (1) rides on the brick frequency, which mainly consists of shouting, the secret includes but not limited to the letter: stone, clay, porcelain clay, quartz and other mineral powders 'can print the imitation stone before the surface of the embryo body' (2) After the glass glaze, it mainly includes but is not limited to the use of feldspar, Tao Gu 'female ^ 1〇〇〇〇r 1?nn〇r N Ling soil K and other raw materials, after high temperature sintering, Wenji c-war Unequal, made a kind of glazing _ correction, high temperature sintering is not completely burned: there are: many small holes (3), the surface of the glaze layer may not be flat, and contains many small glaze layer holes (4 ). 201241119 Regarding the method for manufacturing a composite i-brick having an anti-fouling sheet, first, as shown in the second figure, in step (S01), a glazed tile is selected or prepared, and the surface thereof contains a plurality of fine holes. After that, step (S02) 'grinding and polishing the base glaze layer (2) by mechanical grinding, and adding the time to clear the surface clear wire and fine holes _ ash, and drying the water ( S02-1). After that, 'Buna 03', the m-level organic solution is prepared as _, and 于 is used in the paint. _ _ not limited to functional substances such as Nai #4- yttrium oxide solution, n-stage particles are easy to fill small holes or gaps. The coating agent can be a solution or a mixture. The coating agent is uniformly coated on the surface of the base drug layer (2). The coating method can be applied to, but not limited to, a spray film method or a rotary dance method, as long as a coating agent can be applied to the surface to form a film. Type. After the 'step (S04), grinding is carried out, the coating agent is uniformly dispersed, and the small holes are filled, and the temperature of the grinding towel is generated, so that the coating adhesion reaction is combined with the glaze layer, as shown in the fourth figure, The high flatness coating film layer (10) is coated on the surface of the substrate (1). After the step (S05), a nano-scale protective sputum is applied on the coated coating layer (1 〇), and the coating method may be, but not limited to, a spray coating method or a rotary coating method, etc. The agent is applied to the surface to form a film type. Then, in step (S06), polishing or smashing is performed by a wool wheel or a cotton wheel, etc., and the excess soil liquid is discarded to form a polishing protective layer (20), and combined with the coating film layer (10), and thereby A composite body in which the polishing protective layer (20), the coating film layer (1〇) and the substrate (1) are tightly bonded is formed. The composite tile having the antifouling surface obtained by the above manufacturing method of the present invention, as shown in the fourth figure, is composed of a substrate (1), a coating film layer (10) and a polishing protective layer (20). Since the coating film layer (10) is impervious and transparent, and is coated on the surface of the substrate, a polishing protective layer (20) is disposed on the coating film layer (10). Thereby a composite structure is formed and the surface is mirror-like. The surface of the coating of the composite structure of the present invention is almost completely transparent, and can sufficiently express the texture of the substrate, and has characteristics such as high flatness, high brightness, anti-fouling, and acid resistance. 6 201241119 In addition, the composite brick made by the manufacturing method of the present invention has a texture of a natural stone, and the nano-layer coating layer subjected to the surface treatment process has a tumbling property, and can fully express the texture of the natural stone. Furthermore, the composite of the surface coating process can make the dirt exposed to the surface of the monument not remain on the surface of the surface, making the surface of the monument easy to clean and reducing the use of chemical cleaners. The concept of Lai Xin compound monument. [Simple diagram of the diagram] The first diagram is a schematic diagram of the section of the sentence. The first figure is a flow chart of the steps of the manufacturing method of the present invention. Fig. 3 is a schematic cross-sectional view showing a substrate in which fine dust in a hole is removed after grinding in the manufacturing method of the present invention. Figure 4 is a schematic view of a composite scorpion lion of the present invention - a preferred embodiment. [Explanation of main component symbols] (1)···Base material (2) · · ·Base material axis 〇···Substrate hole (4)···Glass layer hole (10)) · · Select substrate (502 · · · · ( ( ( ( ( ( ( ( ( Coating layer (20) · ·. Polishing protective layer