201236839 六、發明說明： 【發明所屬之技術領域】 塑膠及/或紙浆纖維加以分離而分材中之 【先前技術】 2;貧鐵 巧’以及其他各式用途’铭塑或紹塑紙複 :1之際，通“ili 能’亦即，包裝被打 但直至目前’其銘、塑膠及紙漿的回[ 則但此些相對便宜行事的作目 八μ近财式紐歸合㈣各成份轉化 :離、以^侍其中塑膠成份供為能源用途，另亦有利用酸解 複合包材中之塑膠’但高溫裂解處理方式耗 ^了額此源成本，酸解處理則汙染太大，因而皆難以普遍運 ⑽ϋ民國發明專利公告533〇%號「紹塑(紙)複合 刀離回收方法」揭示一種分離回收方法，其使用 浸泡處理_(紙)複合包裝材料。'為達 口 S=;處s法概度至少15%，高可達 紙複合雖》成^廢; 201236839 部分維，J致影響後續回收物之利用價值。 蝕設備’因此必須以集氣罩收集處理人體，亦會厭重腐 站“換/之，上述f知技術使用猶作為主要處理劑，童圓 的洗贼理需要消耗大量用水，其廢酸之處序 =中=產生舰性氣體之控管等，反 g 程度的其他環保問題。 个丨π玍買不问 【發明内容】 f &供之處理方法及其系統，其在有效^離右卞 m明不λ倾備，不需額外提 铝，^ϋ發^fl以及其他目的，本發明提供一種含至少 其鹼性水溶液係為氫氧 其氫氧化鈉水溶液之漠 離子態紹化物以便分離並筛出塑膠碎^其中之紹與驗反應形成 發法—較佳實補巾，至知，塑或紙之福入 二之i?;並收篩方$中步二包以 泡已筛出紙漿纖維之2=浸 態紹化物以便分離並篩出塑膠碎片：.與驗反應形成離子 在本發明方法一較佳實施例中 化鈉水溶液。 可為 度約ί?ί:1!法一較佳實施例中 在本發明方法一較佳實施例中 条条乂U如9 ·客技，•… … 4 201236839 化鎂，氨’次氣酸鈉或碳酸鈉之水溶液。 在本發明方法一較佳實施例中，其更以鋁/鹼反應步驟所 生熱能為該水浸泡步驟進行加熱以提升紙聚纖維溶散速率。 在本發明方法一較佳實施例中，其更以該鋁/驗反應步驟 所生熱能為該紹/驗反應步驟進行加熱以提升塑膠碎片分離速 率。 本發明亦提供一種含至少鋁，塑或紙之複合包裝材料之 分離，收系統，其包含一反應器，可以鹼性水溶液浸泡複合包 裝材料之碎片，使其中之鋁與鹼反應形成離子態鋁化物便分 離並篩出塑膠碎片。 f本發明方法一較佳實施例中，含至少鋁，塑或紙之複 二，裝材料之分離回收系統包含有一散漿槽，其以水浸泡該複 &匕巧材料之碎片以溶散並篩出其中之紙漿纖維；其更包含一 反應器，其以鹼性水溶液浸泡已篩出紙漿纖維之該▲碎片，可 中之鋁與鹼反應形成離子態鋁化物以便分離並筛出塑膠 石Φ )=! 〇 / 該反應器内所使用之鹼 該反應器内所使用之氫 該反應器内所使用之鹼 氫氧化約，氫氧化錢，氧 在本發明系統一較佳實施例中 性水溶液係為氫氧化納水溶液。 在本發明系統一較佳實施例中 氧化鈉水溶液之濃度約為2至6%。 在本發明系統一較佳實施例中 性水溶液可為氫氧化鉀，氫氧化鎮， 化鈣’，化鎂，氨，次氣酸鈉或碳酸鈉之水溶液 C實酬巾，該散漿槽更以該紹/驗反 g速率。斤生…、此為該水浸泡步驟進行加熱以提升紙漿纖維溶 麻舟ί充一較佳實施例中’該反應器更以該紹/驗反 ^離速^子”、、此為該鋁/驗反應步驟進行加熱以提升塑膠碎片 【實施方式] 含有ίί:〜所處理者主要是食品，藥物等至少包 夕卜塑複合包裝材料，以越減塑膠膜^ 3有、我片或紙層的紹塑紙複合包裝材料。不過，單純只 201236839 含塑膠的，諸如糖果餅乾之舍梦 — 膠膜的其蹄合雜絲，含有^或塑 i Sii^：SS：rssm^ ^ίίϊίί,ί 的，經回收隼乍之處理原料的’已使用過 塑複材廢以㈣⑽裝材料’於此以「銘 之處理步驟分f方法-實施例 離回收程序之前處理，或預處理，1發明1呂塑紙分 ^4：::rm^rfrm 2^ίί2：ίί 行反。祕⑽如錄倾的鹼液進 ^運送儲放的廢料塊必，須先^步 開，才得以有^地 鹼液分離處理才適於進行 titl 心由ft慮後ί廢料即可於步驟114中進行散漿。其# 化鋁^複S料2ίί之水力漿(物理力沖攪)效果，以犮 ίίί^ΐΐϊί纖維而予分離。此外，為提高其處理效 以下所將說明之後段加驗處理(步S 1 i環回流加入此散漿階段之漿液之中， 當控制所加人驗之量，以免驗液損傷降低_巾紙纖維 6 201236839 再生紙時的品質。 如确，驟114後分離出之紙裂常會含有未解離之紙塊’ S塑，ίΐ料，諸如竹換等的拋棄式餐具，甚至砂石等常出現 if收Ϊ質中产雜物雜質。其需要在步驟115經過利用比重， 力4，本技術或相關領域中所熟知之分離程序加以 驟115㈣處理之部份散漿6有提升其紙漿純 廠再抄製成紙張之要求。此經篩親化後之散 表步驟119中，經過濾、及愿榨等程序，於步驟159 中將、，、氏漿處理成低含水量之塊狀，以利儲存及運輸。 ，步驟114處理後之散漿經篩濾步驟115後，仍有 的^無法達_接製紙的鮮，針仍含有相當之雜 著在步驟116 +，可先以設定格目之篩板將 所處理後之散漿加以過濾、，以排除掉其令仍 i廢非為紹塑複合材料之雜質，其需要以，例 扉加以去除。浮沉處理步驟116係利用浮沉分 2 段之賴中之_複材廢料成份，以便 以冋效于進仃後續的鋁塑紙鹼液分離處理程序。 ns tbH’ $巧中經清潔純化後的鋁塑複材廢料便可於步驟 女mi修!，、一碎裂機進行碎裂處理。此碎裂處理可將 材利樂包(Tetra Pak)十數公分尺寸的紹塑複201236839 VI. Description of the invention: [Technical field of invention] Plastic and/or pulp fiber is separated and separated into [previously] 2; lean iron and other various uses 'Ming plastic or Shao plastic paper :1, on the occasion of the "ili can", that is, the packaging was hit but until now, the 'Ming, plastic and pulp back [but these relatively cheap behaviors of the eight-near-financial reunion (four) conversion of various components : Separate and use the plastic component for energy use, and also use the plastic in the acid-decomposition composite package. However, the pyrolysis treatment method consumes the source cost, and the acid hydrolysis treatment is too polluting. It is difficult to universally transport (10) The Republic of China Invention Patent Notice 533〇% “Shu Plastic (Paper) Composite Knife Separation Method” discloses a separation and recovery method using a soaking treatment_(paper) composite packaging material. '为达口 S=; The s method is at least 15%, the high can reach the paper composite, although it is a waste; 201236839 Partial dimension, J affects the utilization value of the subsequent recycled materials. Corrosion equipment 'Therefore, it is necessary to collect and treat the human body with a gas collecting hood, and it will also be ridiculously rotted." The above-mentioned technology is still used as the main treatment agent. The thief of the child's lion needs to consume a lot of water, and its waste acid is used. Preface = medium = control of the generation of ship-like gas, etc., other environmental problems of the degree of anti-g. 丨 玍 玍 玍 【 【 【 发明 发明 发明 发明 f f f f f f f f f f f f f f f f f f f f f f f The present invention provides a ionic state-containing salt containing at least an aqueous alkaline solution of hydrogen hydroxide and an aqueous solution of sodium hydroxide for separation and removal. Sift out the plastic pieces ^ and the test reaction to form the hair method - better to make up the towel, to know, plastic or paper into the second i?; and take the sieve side of the second step to soak the pulp Fiber 2 = dip state to separate and sift out the plastic chips: to form ions with the test reaction. In a preferred embodiment of the method of the invention, an aqueous sodium solution is used. The degree is about ί? ί:1! In the embodiment, in a preferred embodiment of the method of the present invention, the strips are as follows: 4 201236839 Magnesium, an aqueous solution of ammonia 'sodium hypocarbonate or sodium carbonate. In a preferred embodiment of the method of the invention, the heat generated by the aluminum/alkali reaction step is heated for the water soaking step to lift the paper. The poly fiber dissolution rate. In a preferred embodiment of the method of the present invention, the thermal energy generated by the aluminum/test reaction step is further heated to increase the separation rate of the plastic fragments. The present invention also provides a A separation and collection system comprising at least aluminum, plastic or paper composite packaging material, comprising a reactor for immersing the fragments of the composite packaging material in an alkaline aqueous solution, and reacting the aluminum with the alkali to form an ionic aluminide to separate and sieve The plastic shards are f. In a preferred embodiment of the method of the present invention, the separation and recovery system comprising at least a plurality of aluminum, plastic or paper, the material containing the separation and recovery system comprises a slurry tank, which is immersed in water with the composite material. Dispersing and sieving out the pulp fibers therein; further comprising a reactor for immersing the ▲ fragments of the pulverized pulp fibers with an alkaline aqueous solution, wherein the aluminum reacts with the alkali to form a separation Aluminide to separate and sift out the plastic stone Φ)=! 〇/ The base used in the reactor The hydrogen used in the reactor The alkali hydroxide used in the reactor is about hydr A preferred embodiment of the system of the present invention is a sodium hydroxide aqueous solution. In a preferred embodiment of the system of the present invention, the concentration of the aqueous sodium oxide solution is from about 2 to about 6%. In a preferred embodiment of the system of the present invention The aqueous solution can be potassium hydroxide, oxidized town, calcium sulphate, magnesium, ammonia, sodium hypocarbonate or sodium carbonate aqueous solution C. The granules are more than the rate of the anti-g. Raw, this is the water soaking step to heat the pulp fiber to dissolve the pulp. In a preferred embodiment, the reactor is further subjected to the test/reverse speed, and the aluminum/ The reaction step is heated to enhance the plastic fragments. [Embodiment] Contains ίί: ~ The main treatment is food, medicine, etc. at least the plastic composite packaging material, to reduce the plastic film ^ 3, my film or paper layer Shao plastic paper composite packaging materials. However, it is only 201236839 containing plastic, such as candy biscuits - the hoof of the film, containing ^ or plastic i Sii^: SS: rssm^ ^ ίίϊίί, ί, after recycling the raw materials 'Used plastic composite materials waste (4) (10) loaded materials 'here to the "Ming's processing steps sub-f method - the example before the recovery process, or pre-treatment, 1 invention 1 Lu plastic paper points ^ 4::: Rm^rfrm 2^ίί2: ίί 行反. Secret (10) If the recorded lye into the ^ transport storage of the waste block must be opened first, in order to have the separation of the alkali solution is suitable for the titl heart After ft, the scrap can be dispersed in step 114. Its #化铝^复料2ίί的水力浆(Physical force rushing) effect is separated by 犮ίίί^ΐΐϊί fiber. In addition, to improve The treatment efficiency will be described in the following paragraphs (the step S 1 i ring is refluxed into the slurry of the slurry stage, when the amount of the test is added to prevent the damage of the test liquid from being reduced _ tissue paper fiber 6 201236839 regeneration The quality of the paper. If it is true, the paper split after the separation of 114 will often contain undissociated paper blocks. ΐ , , 抛 抛 抛 抛 抛 抛 抛 抛 抛 抛 抛 抛 抛 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹 竹Part of the slurry 6 treated in step 115 (4) has the requirement to upgrade the pure pulp mill to be copied into paper. In the sieve step 119 after screening, the filter, and the pressing process are performed in step 159. The pulp is processed into a low water content block for storage and transportation. After the step 114 is processed, the slurry is filtered through the screening step 115, and the remaining is still unable to reach the fresh paper. Containing a considerable amount of impurities in step 116 +, the treated slurry can be filtered first by using a sieve plate of a set color to eliminate the impurities which are still used as a plastic composite material. In the case of the floating-sinking process, the floating-sinking process is based on the use of the slag-dissolving component of the slab of the aluminum-slurry paper in the second step of the slab. ns tbH' The cleaned and purified aluminum-plastic composite scrap can be used in the step mi repair! ,, a chipping machine for chipping process. This process can introduce chipping plastic-composite Tetra (Tetra Pak) ten centimeters in size
寸if料碎片可利於後續在步驟120;铭塑U 2 ?ΐίί；ϋ 理液中分離程序的快速進行。不 度尺寸亦不應小於約〇.5公分的程度，以 保留紙齡平均長度供时製紙用途。 進行發明之方法及系統以諸如氫氧化納的驗液所 理轉複材廢料，此時已完成其預處 步驟水溶液，而於—反應射進行反應。 廢料。^處理含铭塑或紹塑紙的複合包裝材料 廢抖相較於％知技術使用硝酸溶液，本發明之驗性處理液不 201236839 產资腐餘性霧氣傷害人員，亦不侵钱設備。由於本發明使用諸 如|氧化納的鹼性水溶液時，其所需反應液濃度很低，約3〇/〇 的濃度即已足夠，因此實質上對處理設備並不具腐蝕性。因 此，本發明不需使用不鏽鋼製作處理設備，此可大幅 設施之建置成本。 另一方面，以氫氧化鈉作為鹼性處理液為例，由於其所 |反應液約3%的濃度即足以快速反應，如此可使其排放^液 5理非常容易，不致於汙染環境。並且，鹼性處理液中氫氧化 鈉水溶液與回收廢材中之鋁之化學反應為放熱反應，其所釋出 之ί量可以進一步加速回收處理之速率。換言之，本發明之驗 ，處理液回收方法無需外來熱能即足以自我維持其高速回 處理之反應。 事實上，本發明實驗階段所作實驗調查數據顯示，以氫 氧化鈉之鹼性水溶液作為反應鹼液為例，鋁/驗反應所發出埶 j，於本發^回收處理速度有重大關鍵影響。以五嘲容量的g 肖式鹼反應器為例，由於反應熱的出現，每一筒次的鋁/ J只，時、，20 λ|、時即可完成’但若沒有銘，驗反應之自我加 ^ 至士5天才能獲得相同的反應程度效果。此顯著縮 短的鋁反應時間所代表的是操作時效的顯著提升與操作 本的顯著降低。 、、 ，且，若以氫氧化鈉作為本發明之方法及系統之處理鹼 劑丄則可以採用低成本之較低純度氫氧化鈉。這是因為本發明 =處理之鋁塑紙複合包裝廢材在經過垃圾回收系統收集後，本 他Ϊ質。換言之，以高級高純度之氫氧化 鈉作為處理劑在本發明中並無實質意義。 由^體工業，甚至整體社會的角度觀之，本發明 方3糸統可以消耗掉其他產業之非目標性氫氧化鈉 物。例如，生產PVC和電解海水以取得氣時，皆有此副 ϋϋ ϋ月理方法及系統於整體環境保護及資源 /月<=•源使用的「總體損益表」上，乃是極為正面有利的事。 -&採用氯氧化納驗性水溶液作為處理液的 應會產生氫氣。此氫氣副產品可於 ^驟129中被收集起來供作為其他用途。例如，在本方法 ^統之一較佳實施例中，步驟114的散漿處理便可以鋁/驗反 應步驟所生之氣作$能源，其燃燒所生熱量可為散i水浸泡步 8 201236839 驟1ϋ行加熱以提升紙浆纖維溶散速率。 在本發明一較佳實施例令， 密=產=㈣ί=ί 14,5〇ί莫式t計ΐ依據，射反應產生約 、★’二 Α斤的氫軋。若以氫氣每公斤34 154 kca卜 二kcal的熱含量計算，則此係等^於約100 反應因圭Λ施例申，步驟120的Na〇H鹼液處理 結劑⑶5;ϊί;:源’其為可應用於諸如水處理之凝 ’由於1s塑紙複合包裝材料的大規模回收 ί可3也會因國家’地區’文化等的不同而混有各式種類不 月ί等b，圾鹜物，並可能會被各式’主要是食物類油 °因此，依據本發明之回收處理系統的 驗;^ nn生的銘化合物成份比例亦難以精確估算形 力，明實驗結果發現，反應器之驗液裡面有大量的 3 Aim HfH)3)，以及包含銘酸納（sodium aluminate， NaAlOJ專的其他紹之化合物。 步f 120之鹼液反應處理，如同前述，可利用一外部鹼 =應來，所供應之NaOH 7]c溶液而得以進行。隨著驗液斑廢 1中之鋁產生反應而逐漸消耗，步驟181必須持續添加供S鹼 ^二因此，步驟120所使用之反應槽基本上是為循環流式的反 應槽。 在一較佳實施例中，步驟12〇反應後之鹼性處理液可在 步驟160中進行鹼液的循環處理。其中經過反應而鹼性降低且 變髒的鹼液可在’例如，過濾處理之後回流至步驟120的反應 g而重覆利用。本發明之實驗結果顯示，步驟160所處理的循 環鹼液中仍有足量未反應掉的氫氧化鈉，鹼的含量還是夠高， 201236839 此即其有再循環回駐步驟12G重覆進行反應的價值。 β + ，如同前述，若有需要的話，步驟16〇所處理 壞驗液可以有部份可被送至步驟114所進行的前段散 漿處理，以有助於散漿之進行。 么β 液回收循環利用程序可以充分使用驗液並降低 。在—較佳實施例中，一只五嘴容量的滾筒式 續反應—筒廢材約2G小時之後，便可排出其整 因1㈣層已被驗液反朗耗掉而_下來的塑膠膜 亡丄並將鹼液與塑膠膜片分離。分離後的「髒」鹼液 产處理後，可再補充添加一些新鮮鹼液，便可供下一 琦-人的銘/鹼反應’循環利用。 击’經過鹼液反應步驟120反應後’懸浮於鹼液 =固|^_片即可被軸出來並於清洗步驟13()中進行 高清潔度的塑膠膜片㈣。注意到，在驗液反應 應之後，此時廢材中_已被反應成為離子態。由 維主要在前段之散聚步驟114中被分離出 士 1於Λ漿師濾步驟115中被濾出，故此時的鹼液中只殘留 有少1仍黏附於塑膠臈片上的紙漿纖維。 湖贩換甘言^之，ί匕時的鹼液中主要是含有廢材中的膜片形態的 ^ 非ρρ ’非ΡΕ塑料可在步驟138中被分離出來 二:dt^4。。此些非ΡΡ，非ΡΕ塑膠可作為製造塑木⑼牆 接著經過步驟130篩濾清洗的ΡΡ/ΡΕ塑膠材料便可於 _進行造粒處理’以在步驟149愤集ΡΡ及/或ΡΕ 士 之示意圖顯示可執行圖1 _紙錄方法流程之一 ΐίϋϋ之方塊圖。換言之’圖2係執行圖1之主處理 齡統—實補之方顧。此域_統包含有 唯ίί iiif 可容納前處_序已散®並篩出紙黎纖 ίί 複材廢料與驗液進行反應之空間。在此滾動的反應 舰性水減可触鎌生化敍應，產生織 M 較佳實施例中，一氫氣收集系統229所收集 之虱矾即為本發明系統之資源性質產物，而驗 之__轉液形賴環於㈣收集池 201236839 器220之間。事實上，本發明處理鋁塑紙複材廢料所產生之鋁 化合物經脫水後’亦可作為廢水處理時所需之凝結種源。在本 發明一較佳實施例中，此鋁化合物係直接用於本發明系统所產 生廢水之4理之用。換言之，本發明處理系統本身所產出之廢 水，可以利用其本身之一產出物進行處理，而無需由外部 額外資源。 其手，主處理系統200之紙塑分離器250即可以將滾筒 式反應器220所輸出之處理液中的少量紙毁與塑膜 八 離開來。分離出的紙漿送至紙聚筛選器252触 於·收集槽259中。另-方面，分離器㈣所分g g 膠膜碎片則被送至LDPE (low-density p〇lyethylene，低密产^ 乙烯)塑膠浮除槽230中進行處理。 f LDPE塑膠浮除槽230中，pp及pE以外的塑膠 巧出來，並收集於非PP/PE塑膠收集槽Μ申,。如同前^，此 念ϊ ，塑膠雖^?於製作二次塑膠，但卻可被利用作為製 作塑木(plashcwood)的原料，亦可以製作成燃燒 〇农 w挪經LDPE塑膠浮除槽23G處理並分離出來的PP/PE材皙 料接ί即可於脫水機260中進行脫水， «S粒ΐί::準尺寸的回收塑膠料粒，並收集於回收 3大，率。廢料中之紙_塑膠成份皆ms ==¾¾銬i身廢水處理之用。另=出冗= 塑水作為原水’不但仍可以言:本： 規定之1本發明處理祕必其廢水處理到法令ί 施例本—統之較佳實 201236839 鈉等之水溶液亦皆可作為本發明之反應劑。其皆 ^材中之鋁反應為溶液離子態供作後端之廢水處理用丹 /驗反應所生熱能則皆可回饋提升回收反應速率。 、〃、 回收賊複合_料之分離 物之丨業之相麵值，較低純度副產 速卢$反g處理反應自生熱能’無需外來熱源即可自我維持高 環保，無毒 4. 細/可獲得由原料(即複合廢材中之鋁成份)以及處理 &( P虱氧^化納)其分別各於其先前產製過程中所存入之化學 月b ’而作為有用能源。 ，然本發明已配合圖式以較佳實施例揭示說明如上然 該些說明文字並非用以限定本發明。任何熟習於本技藝者在不 脫離本發明之精神範圍之情況下，當可進行相關更動盥變化， 但其皆應:屬本發日赠述制所揭权範·,b，本發$之專 利保護範圍因此即當以後附之申請專利範圍乙節文字所界定 者為準。 【圖式簡單說明】 f i之示意圖顯示依據本發明鋁塑紙分離方法一實施例之流 程圖。 圖2之示意圖顯示圖丨中主處理系統之方塊圖。 鋁塑紙分離主處理程序 鋁塑紙分離主處理系統 滾筒式反應器 氫氣收集系統 LDPE塑膠浮除槽 非PP/PE塑膠收集槽 塑膠造粒機 【主要元件符號說明】 20 200 220 229 230 238 240 12 201236839 249 回收塑膠料粒收集槽 250 紙塑分離器 252 紙漿篩選器 259 紙漿收集槽 260 脫水機 272 循環池 13The shards of the if material can be facilitated in the subsequent step 120; the molding process U 2 ΐ ίί; The size of the irregularities should not be less than about 〇5 cm to preserve the average length of the paper for the purpose of papermaking. The method and system for carrying out the invention converts the waste material into a waste material by a liquid test such as sodium hydroxide. At this time, the aqueous solution of the pre-treatment step is completed, and the reaction is carried out by the reaction. scrap. ^Processing composite packaging materials containing Ming plastic or Shao plastic paper Waste vibration compared with the use of nitric acid solution by the knowing technology, the inspective treatment liquid of the invention is not 201236839 The personnel who have invested in the residual fog will not invade the equipment. Since the present invention uses an alkaline aqueous solution such as sodium oxide, the concentration of the reaction solution required is very low, and a concentration of about 3 Torr / Torr is sufficient, so that it is substantially non-corrosive to the processing equipment. Therefore, the present invention does not require the use of stainless steel for processing equipment, which can greatly reduce the cost of installation. On the other hand, taking sodium hydroxide as the alkaline treatment liquid as an example, since the concentration of the reaction liquid is about 3%, it is sufficient to react quickly, so that it can be easily discharged without polluting the environment. Further, the chemical reaction of the aqueous solution of sodium hydroxide in the alkaline treatment solution with the aluminum in the recovered waste material is an exothermic reaction, and the amount released therefrom can further accelerate the rate of recovery treatment. In other words, in the test of the present invention, the treatment liquid recovery method does not require external heat energy, i.e., is sufficient to self-sustain the reaction of its high-speed back treatment. In fact, the experimental investigation data obtained in the experimental stage of the present invention shows that the alkaline aqueous solution of sodium hydroxide is used as the reaction alkali solution, and the aluminum/test reaction emits 埶 j, which has a major influence on the recovery rate of the present invention. Take the g-Shaw base reactor of the five-characteristic capacity as an example. Due to the heat of reaction, each tube of aluminum/J, time, 20 λ|, can be completed, but if there is no Ming, the reaction is tested. Self-adding ^ to 5 days to get the same degree of reaction. This significantly reduced aluminum reaction time represents a significant increase in operational aging and a significant reduction in operating experience. Further, if sodium hydroxide is used as the treatment agent for the method and system of the present invention, low-cost sodium hydroxide of lower purity can be used. This is because the aluminum-plastic paper composite packaging waste material of the present invention is processed and collected by the garbage collection system. In other words, the use of high-purity sodium hydroxide as a treating agent has no substantial meaning in the present invention. From the perspective of the industry, and even the whole society, the present invention can consume non-target sodium hydroxide in other industries. For example, when producing PVC and electrolyzed seawater to obtain gas, it is extremely positive for the method and system of the system to be used in the overall environmental protection and resources/months. Things. -& The use of a chlorine-oxygenated aqueous solution as a treatment liquid should produce hydrogen. This hydrogen by-product can be collected for other uses in step 129. For example, in a preferred embodiment of the method, the slurry treatment of step 114 can be used as the energy source of the aluminum/test reaction step, and the heat generated by the combustion can be the water soaking step 8 201236839 Step 1 is heated to increase the dissolution rate of the pulp fibers. In a preferred embodiment of the present invention, the density = production = (four) ί = ί 14, 5 〇 莫 莫 , , , , , , , , , , , , , , , , , , , , , , , , , , , 氢 氢 氢 氢If the calculation is based on the heat content of 34 154 kca per kilogram of hydrogen, then the system is equal to about 100 reactions. For example, the Na〇H lye treatment of the step 120 (3) 5; ϊί;: source' It can be applied to water treatment such as water treatment. Due to the large-scale recycling of 1s plastic paper composite packaging materials, it can also be mixed with various types of cultures, such as the national 'region' culture. And may be used in various types of 'mainly food oils'. Therefore, according to the inspection system of the present invention; it is difficult to accurately estimate the shape of the composition of the compound compound, and the experimental results show that the reactor There are a large amount of 3 Aim HfH)3) in the test solution, and other compounds containing sodium aluminate (NaAlOJ). The alkali solution reaction of step f 120, as mentioned above, an external base can be used. The supplied NaOH 7]c solution is carried out. As the aluminum in the test spot waste 1 is gradually consumed, the step 181 must be continuously added for the S base. Therefore, the reaction tank used in the step 120 is basically It is a reaction tank for circulating flow. In the embodiment, the alkaline treatment liquid after the reaction in step 12 can be subjected to a circulation treatment of the alkali liquid in step 160. The alkali liquid in which the alkalinity is reduced and becomes dirty after the reaction can be refluxed to the step after the filtration treatment, for example. The reaction g of 120 is used repeatedly. The experimental results of the present invention show that there is still a sufficient amount of unreacted sodium hydroxide in the circulating lye treated in step 160, and the alkali content is still high enough, 201236839 Circulating back to step 12G to repeat the value of the reaction. β + , as mentioned above, if necessary, some of the bad liquids processed in step 16 can be sent to the previous stage of the slurry processing in step 114 to It helps to carry out the slurry. The β liquid recovery recycling program can fully use the liquid test and reduce it. In the preferred embodiment, a five-nozzle drum type continuous reaction-tube waste material is about 2G hours later. The whole layer 1 (four) layer can be discharged and the plastic film is destroyed and the lye is separated from the plastic diaphragm. After the separation, the "dirty" alkali solution can be added and added. Some fresh lye, It can be used for the next Qi-man's inscription/alkali reaction. After the reaction in the lye reaction step 120, the suspension is suspended in the lye = solid | ^ _ sheet and can be shafted out and in the cleaning step 13 () Perform a high-clean plastic diaphragm (4). Note that after the liquid reaction, the waste material has been reacted into an ionic state. The dimension is separated from the first stage by the dispersion step 114. The pulper filter step 115 is filtered out, so only a small amount of pulp fiber sticking to the plastic bracts remains in the lye. The lake trader exchanges Ganyan^, and the lye in the case of 匕 is mainly waste. The non-ρρ 'non-antimony plastic of the diaphragm morphology in the material can be separated in step 138 two: dt^4. . These non-twisted, non-twisted plastics can be used as a plastic/wood (9) wall and then subjected to a sieving/twisting plastic material that has been screened and cleaned in step 130 to perform a granulation process to anger at 149 and/or a gentleman. The schematic diagram shows a block diagram of one of the processes of Figure 1 _ paper recording method. In other words, Fig. 2 is a method for executing the main processing age of Fig. 1 - the actual compensation. This domain contains the only ί iiif that can accommodate the front _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ In this preferred embodiment, the rolling ship's reactional water-reducing biosensing can produce the woven M. In the preferred embodiment, the enthalpy collected by a hydrogen collecting system 229 is the resource property product of the system of the present invention, and the test __ The liquid-transformed lysing ring is between (4) collection pool 201236839. In fact, the aluminum compound produced by the treatment of the aluminum-plastic composite waste material of the present invention can be used as a source of condensation for wastewater treatment. In a preferred embodiment of the invention, the aluminum compound is used directly in the treatment of wastewater produced by the system of the present invention. In other words, the waste water produced by the treatment system itself of the present invention can be processed by one of its own products without external additional resources. In its hand, the paper separator 250 of the main processing system 200 can detach a small amount of paper from the processing liquid output from the drum reactor 220 and leave the plastic film. The separated pulp is sent to the paper collecting filter 252 to be in contact with the collecting tank 259. On the other hand, the g g film fragments separated by the separator (4) are sent to an LDPE (low-density p〇lyethylene) plastic floating tank 230 for treatment. f In the LDPE plastic floatation tank 230, plastics other than pp and pE are produced and collected in a non-PP/PE plastic collection tank. Like the former ^, this chanting, although the plastic is used to make the secondary plastic, but can be used as a raw material for the production of plashcwood, can also be made into a burning 〇 农 w LDPE plastic floating trough 23G treatment And the separated PP/PE material can be dehydrated in the dewatering machine 260, «S grain ΐί:: quasi-size recycled plastic pellets, and collected in the recycling 3 large, rate. The paper in the waste _ plastic ingredients are used for the treatment of wastewater in ms == 3⁄43⁄4铐i. Another = redundant = plastic water as raw water 'not only can still be said: this: 1 of the invention to deal with the secret of its wastewater treatment to the law ί 例 例 例 例 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 实施 2012 The reactant of the invention. The aluminum reaction in the material is the solution ionic state for the wastewater treatment of the back end, and the heat generated by the reaction can be fed back to increase the recovery reaction rate. 〃, 回收, 贼 复合 _ _ 分离 分离 分离 分离 分离 分离 分离 , , , , , , 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低 较低A useful energy source is obtained from the raw material (i.e., the aluminum component in the composite waste material) and the chemical & chemical component (the chemical month b' stored in the previous production process). The present invention has been described in connection with the preferred embodiments, and the description is not intended to limit the invention. Anyone who is familiar with the art can make more relevant changes without departing from the spirit of the invention, but all of them should be: the rights of the gift system issued on this date, b, the issue of $ The scope of patent protection is therefore defined as defined in the text of the attached patent. BRIEF DESCRIPTION OF THE DRAWINGS A schematic diagram of f i shows a flow chart of an embodiment of an aluminum plastic paper separating method according to the present invention. The schematic of Figure 2 shows a block diagram of the main processing system in Figure 。. Aluminum plastic paper separation main processing program aluminum plastic paper separation main processing system drum type reactor hydrogen collection system LDPE plastic floatation tank non-PP/PE plastic collection tank plastic granulator [main components symbol description] 20 200 220 229 230 238 240 12 201236839 249 Recycled plastic pellet collection tank 250 Paper separator 252 Pulp filter 259 Pulp collection tank 260 Dewatering machine 272 Circulating tank 13