TW201234140A - Transparent conductive sheet, photosensitive material for manufacturing transparent conductive sheet, method for manufacturing transparent conductive sheet and electrostatic capacity type touch panel using the transparent conductive sheets - Google Patents

Abstract

This invention improves visibility of a touch panel by decreasing a difference between tones of a front surface and a rear surface of a transparent conductive sheet. The invention provides a photosensitive material for manufacturing the transparent conductive sheet. The photosensitive material forms photosensitive layers including silver halide emulsions on two surfaces (a front surface and a rear surface) of a transparent support body respectively. The photosensitive material is characterized in that the photosensitive layer on at least one side of the front surface or the rear surface includes a mercapto compound.

Description

201234140 VI. [Technical Field] The present invention relates to a transparent conductive sheet in which a conductive fine line of a high-definition pattern is formed on a transparent support, and a conductive thin line for forming a high-definition pattern is formed. Photosensitive material of transparent conductive sheet, manufacturing method of transparent conductive sheet, and capacitive touch panel using the transparent conductive sheet 0 [Prior Art] In the field of touch panel, projection type capacitive touch The panel is being widely used for a Personal Digital Assistant (PDA) or a mobile phone, and has begun to try to increase the size of the touch panel. In the case of increasing the size of the panel, the transparent electrode must have a low resistance. As a technique for reducing the resistance, for example, Patent Document 1 and Patent Document 2 describe a sensing portion in which a capacitance is formed by a mesh-shaped conductive thin wire. Methods. The method of forming the mesh-like conductive thin wires described in these documents is a printing method of a conductive ink, or a thinning of indium tin oxide (ITO) or a metal thin film by photolithography, but In the printing method of the former, there is a problem that it is difficult to stably form a thin line having a line width of 2 μm or less. In the latter, there is a problem that the photolithography step includes a plurality of steps and the cost is high. On the other hand, in the field of an electromagnetic wave shielding film or a printed wiring, a method of controlling a thin wire of a low-resistance silver image by a self-chemical silver-light-reducing material is being studied. The age-type _ (four) mask exposure and subsequent processing to form various patterns, the manufacturing steps are stable 4 201234140. For example, Patent Document 3 discloses an example in which a mesh pattern having a fine line width of 20 μm and a lattice interval of 250 μm and a surface resistance of 50 Ώ/□ to 1 □ □ is described. In the method of producing the capacitance sensing portion by using the conductive thin wires, when the first electrode and the second electrode shown in FIG. 7 of Patent Document 1 are laminated to form a touch panel, it is necessary to be on the self-toucher side. When the panel is seen through, it is laminated in a uniform mesh shape as shown in FIG. If it does not have a uniform mesh shape and uneven overlap or blank is generated, it becomes a defect that the kneading surface looks uneven and the visibility is poor. Therefore, the alignment of the two conductive sheets requires high precision, which results in high-precision alignment in each touch panel, and there is a problem that the productivity of the touch panel is poor. [PRIOR ART DOCUMENT] [Patent Document 1] Japanese Patent Laid-Open No. 2010-039537 (Patent Document 2) International Publication No. 2/〇丨4683 [Patent Document 3] Japanese Patent Application In the recent years, in order to make the sheets of the two conductive sheets bonded together, the table and the back _ == method of the transparent sheet are tried. The conductive H: the electrode formed on both sides of the front and back sides of the transparent slab body is required to be a uniform pattern as shown in FIG. 8 of Patent Document i. It is generally considered that the photosensitive material is used as the electrode forming material y for exposure and next to it. After the development process to form the electrode, however, it is known that the front and back sides of the transparent support form a contrast of the case where the surface of the 20124140 surface and the fluoroscopic image of the electrode become a uniform pattern, and a subtle color is also produced. The method of using two silver or the hue of the surface varies depending on the conditions for forming the electrode: in the case of 幵 ==). It is inferred that the phenomenon is as follows == K, that is, when a relatively thick electrode film is formed, = the fineness of the metal film in the film which has become a thick film == 提#本^5 The object of the invention is to produce a transparent conductive sheet having a hue of "==::r, which includes an electrode for developing silver". Further, the present invention provides a color tone for the control electrode of the large book, and a low resistance, which can be used for the transparent electrode of the panel. In addition, in the other eye-control panel of the present invention, the above-mentioned contact person who has improved the St-tone of i has intensively investigated the cause of the unevenness of the color tone, and the result was completed based on the following facts. invention. Electrode: the transparent cover of the sheet (4) is formed with the first panel on both sides of the front and back sides. The core 1 is turned on and cast into the (four) static 1 silk type touch panel, which also serves as the transmissive TM month support body 31, and also serves as an adhesive layer 41. 201234140 = the thin line 21, the transparent support 32 for the electrode, and the structure of the adhesive layer 41 which is also used as the insulating layer, and the contact person (the figure of the fish line (10) of the thin line 21 will be The conductivity of the upper electrode is the same. Further, the conductive thin wires 22 of the J electrodes are discriminated from each other in a direction other than bi. Shown 'for the conductive thin lines 21, from the surface of the arrow. The conductive thin wire 21 of the trap (10) is adjacent to the transparent wire 22' to recognize the surface of the conductive thin wire 2 2 located on the side of the support from the direction of the arrow b2. When the distance dl is a person's turn _ from the case of the majority (^.1_), it is not easy to feel the unevenness of the hue. [When a plurality of conductive thin wires are used to form one electrode (for example, the sensing portion of the electric capacitance is a mesh shape or a long lattice shape), as shown in Fig. = a plurality of conductive thin wires on the surface of the transparent support The area of the array 3 and the area on which the plurality of conductive thin lines are connected on the other side and the length of the d3 are usually recognized by a person, and the color is not recognized according to the formation conditions of the electrodes as shown in FIG. The following inventions were thus completed. In addition, Fig. 2 is a view schematically showing a cross section when the square lattice of Fig. 9 is cut parallel to the long side of the lattice. [1] A photosensitive material for producing a conductive sheet, wherein a photosensitive layer containing a silver-plated silver emulsion is formed on both surfaces (surface and back surface) of the transparent support, and is characterized by: a photosensitive layer on the surface side or a photosensitive layer on the back surface The photosensitive layer on at least one side contains a mercapto compound. [2012] [2] The photosensitive material for manufacturing a conductive sheet according to Item 1, wherein the photosensitive layer on the side close to the transparent support is contained in the photosensitive layer on the side closer to the transparent support than the photosensitive layer on the side away from the transparent support. A lot of Wei-based compounds contained in the photosensitive layer. [3] The photosensitive material for manufacturing a conductive sheet as described in the above item 1 or 2, or the photosensitive layer on either side of the surface or the back surface of the middle transparent laminate, does not contain a sulfhydryl compound. [4] The photosensitive material for producing a conductive sheet according to any one of item [1] to [3], wherein the surface of the towel and the surface of the transparent surface are covered by a Weiji y The photosensitive layer contains more Wei group compounds. [5] The photosensitive material for producing a conductive sheet according to Item 1 to Item 4, wherein the photosensitive layer is at least! The amount of the Weigelification & ampule contained in the photosensitive layer is 〇] mg or more and 15 Å or less with respect to 1 g (g) of silver contained in the silver-doped emulsion of the same layer as the sulfhydryl compound. The photosensitive material for the production of a conductive sheet according to item 4 or 5, wherein the compound is a county compound having a 5-membered ring saliva having a closed structure or a 6 M ring α丫嘻 having an NH structure as a skeleton. The leg structure refers to the pin or.氮 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ At least 8 201234140^ τν/-»^^, ριΙ as a substituent, and M is an alkali metal atom, selected from the group consisting of a hydrogen atom, a hydrogen atom, a lower oxy group, a silk, an i group, and a contig. Or ammonium group. [8] The photosensitive material for producing a conductive sheet according to any one of the items 1 to 7, wherein a silver halide emulsion having a photosensitive layer formed on both surfaces of the transparent support has a silver bromide content of 50 m. Above the ear %, and only has a mercapto compound in the photosensitive layer near the transparent support. [9] The photosensitive material for producing a conductive sheet according to any one of the items 1 to 8, wherein the volume ratio of silver to the binder contained in the photosensitive layer formed on both surfaces of the transparent support is 1.0. Above layer. [10] The photosensitive material for producing a conductive sheet according to any one of the items 1 to 9, wherein a volume ratio of silver to the binder of the layer is 丨5 or more. [11] The photosensitive material produced in the conductive sheet according to any one of the items 1 to 10, wherein silver is contained in the photosensitive layer on the side of the photosensitive layer of the surface and the back surface of the photosensitive layer which is close to the support. The volume ratio to the binder is less than 1.0. [12] The photosensitive material for the production of a conductive sheet according to any one of the preceding claims, wherein the at least one surface of the photosensitive layer on the surface and the back surface is away from the silver enamel of the photosensitive layer The combined volume ratio is less than 0.5. [13] The photosensitive material for producing a conductive sheet according to any one of the preceding claims, wherein the photosensitive layer of the photosensitive layer on the surface of the front surface and the back surface is silver contained in the photosensitive layer away from the side of the support body The volume ratio of the binder to the binder is less than 0.5. The volume ratio of silver to the binder contained in the photosensitive layer near the support is less than 0.5. [14] The conductive sheet manufacturing according to any one of the items 1 to 13 of the present invention, wherein the photosensitive layer of the (four) transparent support ship has an antihalation layer on the transparent support and each photosensitive layer m. . [15] A conductive sheet which is characterized in that imagewise pattern exposure is performed on both sides of a photosensitive material for producing a conductive sheet as described in any one of items 1 to 14, and then developed. At the same time, it is believed that the two sides of the business include a transparent electrode on the surface of the surface, and a back-transparent electrode including a conductive thin wire of developed silver. The conductive sheet according to the above item is formed by exposing and developing the conductive material in such a manner that the surface is transparent and the back surface transparent electric conduction direction is orthogonal to each other. [Π] The conductive sheet according to item 15 or item 16, wherein the inclusion

The transparent electrode of the electric thin wire is a chemicalized electrode including a plurality of conductive thin wires. q take IU

[18] The conductive sheet of item π, wherein the patterned electrical error is made of a conductive thin line and has a square lattice or a rectangular lattice in the electrode. [19] The conductive sheet according to any one of Item 15, wherein the conductive thin line constituting the patterned electrode has a line width of 1 μm or less and 10 μm or less. [2] The transparent conductive material according to any one of items 15 to 18, wherein the conductive thin line has a line width of 2 μη or more and 6 μππ or less. The conductive sheet according to any one of the items 15 to 20, wherein the conductive thin wire has a thickness of 0.1 μm or more and 1.5 μm or less. [Claim] [22] The conductive sheet according to any one of the items 15 to 21, wherein the conductive thin wire has a thickness of 〇·2 μmη or more and 〇8 or less. [23] The transparent conductive sheet according to any one of items 15 to 22, wherein the conductive chromaticity V of the surface of the electrode away from the side of the transparent support is opposite to the surface of the electrode The absolute value of the difference of the reflected chromaticity b2* of the electrode surface near the side of the transparent louver body is 2 or less (|ΔΙ) |=|bi 七2 丨S 2 ) 〇[24] as described in item 23 A conductive sheet in which the crucible * is less than t. [25] The transparent conductive sheet as described in item 23 or 24 wherein b/ and b2* are J.iXb/SO, and _i_〇<b2*$ i 〇. [26] The transparent conductive sheet of item 25, wherein b/ and '• are -l.OSbi $-0.5, and ·〇, 5<&2*^〇.2. [27] A capacitive touch panel using the conductive sheet according to any one of items 15 to 26. [28] A method of producing a conductive sheet, which comprises performing imagewise exposure on a photosensitive material for producing a conductive sheet according to any one of items [14], and then forming a web containing developed silver by development processing. A substantially transparent electrode of an eye-shaped conductor line is characterized in that the imagewise exposure method is a method of simultaneously exposing different electrode patterns to the photosensitive material on both sides of the photosensitive material for producing a conductive sheet. [29] The method of producing a conductive sheet according to Item 28, wherein the exposure is a known exposure. [30] The method of producing a conductive sheet according to Item 28, wherein the exposure is a face exposure via a different mask. 11 201234140 In the present invention, when the photosensitive material and the conductive sheet are configured as a device for recognizing a touch panel or the like, the surface close to the identifier is referred to as a surface, and is away from the recognizer. The face is called the back. Since the color tone-modified transparent conductive sheet of the present invention is improved in the color tone of the surface of the conductive material, it is not limited to the electrode material used in the above-mentioned capacitive touch panel, as long as it is human identification and conductivity. The uses involved can be applied to all uses. Illustrate the applicable uses. A transparent conductive sheet for a resistive touch panel, an electromagnetic wave shield for shielding electromagnetic waves from inside the display device, and the like, and a pattern of conductive thin wires formed by patterning of the electrode of the present invention is changed. The technique of the present invention can be utilized. Further, by adjusting the resistance value of the electrode of the present invention, a heat generating sheet or an antistatic sheet can be produced. When the photosensitive material for producing a conductive sheet of the present invention is subjected to pattern exposure and development treatment, an upper electrode and a lower electrode including fine lines for developing silver are formed on both sides of the transparent support. The pattern exposure is performed in such a manner that the upper f-pole and the lower electrode are perpendicular to the conduction direction of the lower electrode by the development process, and are recognized as two uniform meanings in the vertical direction. Therefore, = is the guide, the production mode of the film, the invention can be a stable and inexpensive party. On the other hand, the unevenness of the color tone at the time of discriminating the electrode as a problem of this aspect is solved by the photosensitive material for producing a conductive sheet of the present invention. According to the above, when the touch panel is formed by using the conductive sheet of the conductive sheet of the present invention, the touch panel of the electrode having a low color tone and a large surface can be obtained. Further, when the transparent conductive sheet of the present invention is applied, a transparent conductive sheet excellent in hue, an electromagnetic 12 201234140, a wave shielding sheet, a heat generating sheet or an antistatic sheet can be obtained. [Embodiment] Hereinafter, a photosensitive material of the present invention, a conductive sheet formed using the photosensitive material, a method for producing the conductive sheet, and a touch panel using the conductive sheet of the present invention will be described with reference to Figs. 1 to 12 . Example of embodiment. In the present specification, "~" is used in the sense that the numerical values described before and after are included as the lower limit and the upper limit. Further, in the present invention, in the touch panel to be described later, the surface on the side of the toucher is referred to as a surface, and the surface on the side far from the touch is referred to as a back surface. In the drawings used in the present invention, the upper surface is referred to as a surface, and the lower surface is referred to as a rear surface. [Photosensitive Material] The photosensitive material of the present invention is a photosensitive material for producing a conductive sheet, and a photosensitive layer containing a silver halide emulsion is formed on both surfaces (surface and back surface) of the transparent support, respectively, characterized by: a photosensitive layer on the surface side The photosensitive layer on at least one side of the photosensitive layer on the back side contains a mercapto compound. The photosensitive material of the present invention has a photosensitive layer on both surfaces of a transparent support, and a typical configuration will be described with reference to Fig. 3 . An upper photosensitive material layer (also referred to as a surface photosensitive material layer) 50 is formed on the surface side of the transparent support 32, and a lower photosensitive material layer (also referred to as a back photosensitive material layer) 60 is formed on the back side. Further, the upper photosensitive material layer 50 is formed with an undercoat layer 56, an antihalation layer 57, an upper photosensitive layer (also referred to as a surface photosensitive layer) 51 containing a silver halide emulsion, and a protective layer 55 on the transparent support 32. The undercoat layer, the anti-halation, and the protective layer are layers that are provided as needed. The upper photosensitive layer 51 may also be formed of a plurality of coating layers 13201234140 containing a silver halide emulsion and an intermediate layer between the photosensitive layers. In the present invention, the photosensitive layer 51 is divided into three photosensitive layers, that is, from the side of the transparent support 32, which is divided into an upper first photosensitive layer 52 (also referred to as an upper layer u) and an upper second photosensitive layer 53 (also The upper m-layer) and the upper first-photosensitive layer 54 (also referred to as the upper layer) are described. The lower photosensitive material layer 60 also has the same layer structure as the upper photosensitive material layer 50, and is preferably formed of a layer which is symmetrical with respect to the transparent support. [Transparent Support] As the transparent support used in the above-mentioned photosensitive material of the present invention, a plastic film, a plastic plate, a glass plate or the like can be used, but a plastic film is preferable. As a raw material of the plastic film, for example, a polyethylene terephthalate (PET), a polyethylene naphthalate (PEN), or the like can be used; a polyethylene (Polyethylene ' PE), polypropylene (p〇iypr〇pyiene, pp), polyolefins such as polystyrene; vinyl chloride resin such as polystyrene and polyvinylidene chloride; in addition, 'polyetheretherketone can be used _ ( Polyetheretherketone , PEEK ), Polysulfone (PSF), Polyertiersulfone (PES), Polycarbonate (PC), Polyamide, Polyimide, Acrylic, Triacetyl Cellulose , TAC) and so on. The plastic film in the present invention can be used in a single layer or as a multilayer film in which two or more layers are combined. As the support body, it is preferably PET (258 ° C), PEN (269 ° C), PE (135 ° C), PP (163 ° C), polystyrene (230 ° C), polyethylene 201234140. 18〇C), Polyethylene 2 B2 (2i2°c) or TAC (290°C) is about 29 (plastic film below rc, especially for PET. The value in () is a dazzling point. The transmittance of the film is preferably 85% to 1% by weight. The thickness of the transparent support film can be arbitrarily selected within a range of 5 〇μηι or more and 5 〇〇μηη or less, particularly in addition to the support of the transparent conductive sheet. When the function of the touch panel is also used in addition to the function of the body b, the design can be performed with a thickness of more than 5 μm. When a photosensitive layer containing a silver halide emulsion is provided on the transparent support by a coating method, The thickness of the film is 5 in terms of production, and more preferably 5 Å or more and 25 Å or less. [Mergic compound] The sulfhydryl compound must be contained in at least one of the surface photosensitive layer 51 or the back photosensitive layer 61. According to this aspect, it is possible to improve the unevenness of the color tone when the touch panel described later is produced. It is preferable to be away from the transparent branch of the photosensitive layer. The photosensitive layer on the side of the body contains more ruthenium-based compounds contained in the photosensitive layer than the photosensitive layer on the side close to the transparent support. That is, it is preferable to make the m layer or the u layer as compared with the ruthenium layer. It is preferable to contain a mercapto compound, and it is preferable to make a layer containing a mercapto compound. Or 'it is preferable to increase the concentration of the mercapto compound in the order of the 0 layer, the m layer, and the u layer. When the surface of the transparent support is on either side or the back side When the photosensitive layer contains a mercapto compound, it is preferable that the photosensitive layer on the other side does not contain a mercapto compound, and if the photosensitive layer containing no Wei group compound is a surface photosensitive layer, it is more preferable to use a transparent support. When both the photosensitive layer on the surface and the photosensitive layer on the back surface contain a sulfhydryl compound, it is preferable that the amount of the sulfhydryl group 15 201234140 in the surface photosensitive layer and the back surface photosensitive layer is different, and more preferably the amount of the sulfhydryl compound contained in the photosensitive layer on the surface The amount of the mercapto compound contained in the photosensitive layer on the back side is larger than that in the photosensitive layer on the back surface of the photosensitive layer of the plurality of photosensitive layers of the present invention, and the denture of the mercapto compound contained in at least the layer of the plurality of photosensitive layers. The silver 1 g (g) in the emulsion is preferably 〇·〗 mg or more, mg or less, more preferably ^5 ing or more, 〗 〖0 mg or less, particularly preferably ^ ～ or more, 6 or less. If 〇.1 mg In the above range of 15 mg or less, it is easy to adjust the color tone. The woven base compound used in the ί 明 , , 貌 貌 貌 : : : : : : : : ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' · 11613 = , slaves 34 to the compounds described in paragraph 1 〇 2); among the compounds of the paragraphs from the % to the paragraphs of the Japanese Patent Laid-Open No. 2-7-116137, preferably and/or There are five members of the ΝΗ 遍 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、疏 a base compound as a skeleton. The structure of fH is the nitrogen contained in the wow or the tenth Qin: Τ The hydrogen has the characteristics of being dissociable. Nitrogen-虱 bond, and ring "丫 „ 环 环. Sitting or 6 noble heterocyclic ring. The composite heterocyclic ring is preferably a complex 6-membered ring and benzene without a hetero atom The member of the ring can also be a 5-member ring and a 6-member ring. The azine is a complex: ring (condensed ring), body is 'preferably sneeze, more than saliva, taste saliva (condensed ring). The composite ring has a special ring structure: benzobenz = each ring is condensed to form the above ring-removing group, and may also be a group of a base group, a carboxyl group, a nitrate 16 201234140 HUJ^Zpif group, a halogen atom (for example, a chlorine atom, Fill in an atomic aryl group (eg, phenyl, 4-methyl decyl phenyl, 4 _f phenyl, dichlorophenyl, decyl), aryl (eg, benzyl, 4-methyl) a base group, a phenylethyl group), an anthracyl group (for example, a methylidene group, a ethyl sulfonyl group, a p-xylylene fluorenyl group), an amine sulfhydryl group (for example, an unsubstituted amine methyl group, a methyl group) An amine methyl group, a phenylamino group, an amine gamma (for example, an unsubstituted amine group, a methylamino group, a phenylamine group), preferably having a basis. Silk. The water is mixed Further, the structure of the (4) structure of the metal may be used. As the compound which can be preferably used in the present invention, the above-mentioned Japanese Patent Laid-Open Publication No. Hei 7 6137, paragraph 6 〇 ^, paragraph 65, can be cited. 39 compounds, 55 compounds described in paragraphs 9 to 93, and 3 compounds described in paragraph 101. Among the compounds, the compound which can be more preferably used in the present invention is paragraph 6 The compound described in Paragraph 65 and Paragraph 1〇1. Among the above mercapto compounds, it is preferred that the 4-position-benzimidazole has a s〇3M group as a substituent at any of the 4-position to the-position, and further has a hydrogen atom, a hydroxyl group, a lower alkyl group, and a lower group. A compound having at least one of an alkoxy group, a carboxyl group, a sulfonyl group and a sulfo group as a substituent and M is an alkali metal atomic ammonium group, and a particularly preferred compound is the three compounds described in Paragraph 1〇1. [Photosensitive layer containing a silver halide emulsion] Next, the photosensitive layer containing a silver halide emulsion will be described. Since the developed silver is used as an electrode material, the type of the photosensitive material and the type of development treatment can be selected from the following three methods. 17 201234140 , ^分〆易&,—(1) A method of illuminating a photosensitive _ silver black-and-white photographic material without a physical development nucleus (4) or thermal development to form a metal silver portion on the photosensitive material . (2) A method of dissolving a photosensitive silver-based black-and-white photosensitive material containing a physical developing core in a silver-tinized emulsion layer to form a metallic silver portion on the photosensitive material. (3) Combining a photosensitive silver halide black-and-white photosensitive material containing no physical development nuclei with an image-receiving sheet having a non-photosensitive layer containing a physical development nucleus, and performing diffusion transfer development to form a metallic silver portion on the surface light The way the sexual image is received on the slice. The form of the above (1) is a black-and-white development type, and a transparent electromagnetic wave screen is formed on the photosensitive material. The developed silver obtained is a chemically developed silver or a thermally developed silver, and is a filament having a high specific surface. Further, when the subsequent process of the coating treatment or physical development is high activity and the morphology of the above (2) is obtained, in the exposed portion, the toothed silver particles close to the physical development core are degenerately deposited on the (four) core. A translucent conductive film such as a translucent electromagnetic wave shielding film or a translucent conductive sheet is formed on the photosensitive material. It is also black and white developed. Since the development is toward the physical development of the core, it is highly active, but the developed silver obtained is a spherical shape of the surface. In the above (3), the silver halide particles are dissolved and diffused in the unexposed portion and deposited on the developing core on the image receiving sheet, and a light transmitting electromagnetic wave shielding film or light is formed on the image receiving sheet. The conductive sheet is transparent to the 201234140 optical conductive film. This is a so-called separation type of a double sheet, and is a form used for peeling off an image receiving sheet from a photosensitive material. Any of the negative development processing and the reverse development processing can be selected in any form (in the case of the diffusion transfer method, negative development processing can be performed by using an autopositive type photosensitive material as a photosensitive material) ). "Chemical development, thermal development, dissolved physical development, and diffusion transfer development as described herein are the meanings commonly used in the industry. In general textbooks for photographic chemistry, such as Kikuchi, "Photography Chemistry" ( A total of = publishing house, CEK Mees, "The Theory of Photogmphie" (the principle of photography, Can ed.) (Mcmillan, issued in 1977) towel explained. In addition, for example, the technique described in Japanese Laid-Open Patent Publication No. 2004-184693, Japanese Patent Application Laid-Open No. Hei No. Hei. Among the modes of the heart j (1) to (3), the mode (1) does not have a physical development nucleus before the development, and is not a diffusion transfer of the double material (the method is the simplest and stable processing) It is preferable to manufacture the conductive sheet of the present invention (4). Hereinafter, the use mode (1) will be described. However, when other methods are used, the image can be tilted up. Further, the development is not only the mode (2) # inherent development The method is a method in which the _ element element contained in the self-chemical silver emulsion can be any of gas, odor, and gas. It is also possible to combine these. For example, silver halide, evolved silver, and moth-silver as the main body of silver halide can be used better than 201234140, and teeth containing silver bromide or silver chloride as the main body can be more preferably used. In addition, it is also preferable to use silver bromide, iodine silver bromide, silver iodobromide. More preferably, air desertification silver, desertified silver, neon evolved silver, strontium filled silver, most Jia is using (4) silver, which contains 5G mol% or more of vaporized silver, and the rate of climate-induced silver. Moreover, here, "Silver silver with silver bromide as the main component" refers to a silver halide having a molar fraction of 5 % by mole or more of the bromide ion in the silver halide composition. The silver particles may contain iodide ions and chloride ions in addition to the bromide ions. Further, the silver iodide content in the functionalized silver emulsion is preferably not more than i in each of the toothed silver emulsions. 5 mol% range. By setting the moth-silver content to a range of not more than 1.5 mol%, it can prevent fogging and improve pressure. More preferably, the content of silver is in silver per mil (four) The amount of the silver oxide is 1 mol% or less. The average particle size of the silvery silver, the shape and dispersion of the silver particles, and the coefficient of variation can be referred to paragraph 37 of paragraph 37 of Japanese Patent Laid-Open Publication No. Hei. In addition, as for the metal compound of the νπι group and the νπ steroid group, the ruthenium compound or the ruthenium compound used for the stabilization or the sensitization of the dentate silver emulsion, the use of the palladium compound can be referred to paragraph 39 of Japanese Patent Laid-Open No. 2009-188360. ~ Paragraph 42. Further, regarding chemical sensitization, Reference may be made to the technical description of paragraph 43 of the Japanese Patent Laid-Open Publication No. Hei. No. 9_18836. The silver-doped silver emulsion used in the present invention is preferably a silver chlorobromide emulsion. 20 201234140 =Bu's for _lf彡The fogging of the front and the smear is more preferably about 0.5 mol% of silver moth. The bismuth p contains silver telluride to the above extent, and is not particularly indicated. The photosensitive layer 51 and the photosensitive layer 61 are divided into the first photosensitive layer U in order to adjust the reflection chromaticity of the conductive electrode _ electrode which is formed by the photographic processing of the photosensitive material 05 of the present invention. The layer), the second photosensitive layer (also layer), and the third photosensitive layer (layer) are coated as a three-layer photosensitive layer. The method in which the mercerized layer is divided into such a plurality of layers is the same as the method in which the emulsion layer of the silver halide photographic light-sensitive material is formed into a 〇 layer, an m layer, and a u layer in the order of sensitivity from 咼 to low, as described above. By performing multi-layering, sensitivity, gradation, and the like can be easily adjusted. In the present invention, in order to facilitate understanding of the layer, it is also abbreviated as a ruthenium layer, a m layer, and a u layer, but it does not indicate the level of sensitivity. The ruthenium layer as the third photosensitive layer is the photosensitive layer farthest from the transparent support, and the u layer as the first photosensitive layer is the photosensitive layer closest to the transparent support. The three-layer photosensitive layer (the 〇 layer/m layer/u layer) is preferably formed by simultaneous coating. In the present invention, the thickness of the photosensitive layer composed of the above-mentioned enamel layer/m layer/u layer after coating is formed to a thickness of 0.2/0.6/0.2 with respect to the total thickness of the photosensitive layer. Further, in the above description, the photosensitive layer is formed into three layers, but depending on the purpose, it may be composed of any two or more layers. Further, regarding the thickness of each layer, if the ruthenium layer and the u layer are regarded as the m-layer cap layer, it is preferable that the m layer accounts for 40% to 90% of the entire photosensitive layer, and the ruthenium layer and the u layer can be distributed depending on the purpose. 10% to 60% below. 21 201234140 ' L · The volume of silver and the binder contained in the photosensitive layer 51 and the photosensitive layer 61 formed on both surfaces of the transparent support of the present invention is preferably 1 Å or more, and more preferably 1.5 or more. By setting the volume ratio of silver to the binder to be 1 Torr or more, the conductivity of the developed silver after the development treatment can be improved. In addition, the volume ratio of the silver and the binder in the present invention is a value obtained by calculating the mass of the silver contained in the silver halide emulsion layer and the quality of the binder, and setting the density of the silver to 1〇.5, the density of the binder was set to 1.34 to calculate. The volume ratio of the silver to the binder may be the same ratio in the layer of the 0 layer and the photosensitive layer 51 and the photosensitive layer 61, and may be changed in each layer, preferably the photosensitive layer 51 or the photosensitive layer. At least one of the photosensitive layers of the u layer adjacent to the support of at least one of 61 is set to be less than 1 〇 更, and more preferably set to less than 0.5. Further, it is more preferable to have at least one photosensitive light = away from the support body. The ratio of silver to binder contained in the layer is set to less than 0.5. (Binder) In the photosensitive layer containing the functionalized silver emulsion, it is possible to use a binder for the purpose of dispersing the silver salt particles and assisting the adhesion between the emulsion layer and the support body, and as the above-mentioned binder, for example, List daily turnover, deer gum, poly ^ Alc〇h〇1 ' PVA ), polyglycane bite (P〇ly_ Py_id () ne ' PVP), (four) turn more health, cellulose and ^ bio 'poly Ethylene oxide '(4), polyethylamine, ^ lysine, poly-acid, polylysine, poly-acid, silk cellulose 'arabin gum, sodium alginate, etc., preferably gelatin. 22 201234140. 3 As gelatin's lime-removing gelatin, acid-treated gelatin can also be used, and the hydrolysate and enzyme decomposition products of the division can be used. In addition, the amine group and the m group can be repaired. Diethylated gelatin, acetylated gelatin). " In addition, the use of the knees as a binder. Here, as the latex, it is preferable to use the polymerized enamel latex described in Japanese Patent Application Laid-Open No. Hei No. Hei 2, No. 3,536, pp. 18, pp. 12 to page 18, left bottom, line 20, in the formation of the photosensitive layer of the present invention. The solvent to be used is not particularly limited, and examples thereof include water and an organic solvent (for example, an alcohol such as decyl alcohol or a ketone such as acetone: a guanamine such as guanamine or a sulfoxide such as dimethyl sulfoxide or ethyl acetate Particles, hydrazine, etc.), ionic lysate, and these (d) complex solvents. ( The content of the solvent in the photosensitive layer (4) is such that the total amount of f of the photosensitive layer of the human silver salt, the binder, etc. is in the range of 3 Q f % % to 9 G), preferably 50 mass. /〇~80% by mass range. 〇 The cereal additive used in the present embodiment is not particularly limited to the above-mentioned additives which are preferably known. For example, each controllable surface "I degree can be used. Further, the matting agent is preferably one which remains after the film, does not impede transparency, and dissolves in the processing step. In the photosensitive layer of the present invention, a protective composition (not shown) may be provided. The term "protective layer" means a coating containing a clear or high-molecular polymer, and in order to prevent scratches or improve mechanical properties. The axis is in the photosensitive layer of the device. The thickness is preferably Μ 23 ϋ 201234140 μηη or less. The coating method and the formation method of the protective layer are not particularly limited, and a known coating method and formation method can be appropriately selected. An antihalation layer 57 and an antihalation layer 67 may be provided between the photosensitive layer of the present invention and the transparent support. Regarding the materials used in the antihalation layer and the method of using the same, the descriptions of paragraphs 29 to 32 of Japanese Patent Laid-Open No. Hei. Although the optical density of the antihalation layer differs depending on the intensity or wavelength of the exposure light, it is preferably about 0 5 to 3 Torr. Next, a process for producing the transparent conductive sheet of the present invention using the material of the present invention described above will be described with reference to Figs. 4(a) to 4 . 4(a) is a transparent support 32, and FIG. 4(b) shows the photosensitive material of the present invention in which the upper photosensitive material layer 50 and the lower photosensitive material layer 60 are provided on both surfaces of the transparent support by coating. 5, FIG. 4(c) shows a view in which the photosensitive material of the present invention is exposed by a photomask, and FIG. 4(d) shows a developed silver electrode formed by a development fixing process immediately after exposure. Hereinafter, each step after exposure will be described. [Exposure] The photosensitive material 05 of the present invention is a photosensitive material in which a photosensitive layer is formed on both sides of a support. Therefore, in the present invention, as shown in FIG. 4(c), both sides of the photosensitive material are irradiated with l〇2a and l〇. 2b to expose. The light irradiation is performed on the photosensitive material via the photomask 110 and the photomask 120. Since the mask 11 and the mask 120 are masks for forming the electrode patterns of FIGS. 7 and 8 to be described later by developing silver, the mask 110 and the mask 12 are equivalent to those of FIGS. 7 and 8. A mask that transmits light through the thin line portion of the electrode. Therefore, the reticle 11 〇 and the reticle 12 〇 24 201234140 are masks that are different in pattern but not the same. As described above, 111 and 121 are openings of the mask, and 112 and 122 are light shielding portions of the mask. The light that has passed through the opening of the mask forms a latent image in the silver halide emulsion of the portions 131, 141 of the photosensitive layer. The portions of the latent images 131 and 141 are formed into a pattern of developed silver by subsequent development processing. In the non-photosensitive portion 132 and the non-photosensitive portion 142 of the photosensitive material which is not exposed by the light-shielding portion of the mask, the silver halide emulsion particles which are not photosensitive due to the shadowing treatment are dissolved and flow out from the layer to form a transparent film. 152. Film 162. As described above, when exposure of both surfaces of the photosensitive material is performed using masks having different patterns, the following problems occur. Although the light transmitted through the opening portion 111 of the mask 11 形成 forms a latent image on the portion of the photosensitive material, the remaining light also passes through the transparent support, and the photosensitive layer 61 on the opposite side also forms an unexpected image. Latent image. Such a problem is difficult to solve by merely adjusting the exposure amount. The antihalation layer 57 and the antihalation layer 67 having the optical density of light absorbed through the photosensitive layer 51 can be disposed in the photosensitive material. As another method, there is also a method of changing the color sensitivity of the silver halide emulsion of the photosensitive layer 51 and the photosensitive layer 61 by using a sensitizing dye.曰 Figure 5 is a model diagram of an exposure apparatus in the present invention. Light from both the light source 1a and the light source 100b is parallel light by the lens, and both surfaces of the photosensitive material are exposed through the mask. The exposure device portion including the light source from the light source in Fig. 5 is strictly positioned by the two exposure devices. The silver image formed by the mask 11 and the mask 12A having the pattern of Figs. 7 and 8 is strictly positioned so as to have a uniform pattern as shown in Fig. 9. In the form of FIG. 1〇25 201234140 to FIG. 12, the two conductive sheets are combined to form a touch panel, and the two conductive sheets are arranged in the same manner as the two-sided type of the present invention. As a light source for exposure, productivity is extremely poor. We can cite visible light and material (four) Wei. As the electromagnetic wave, for example, the exposure can also be carried out with a long amount of money. Further, the light source. The light source of the cloth may also be a specific wavelength exposure method, which may be as shown in FIG. 5, except that the conductive sheet formed in the above manner is a conduction direction of the surface and the conduction of the back surface of the through-pole. The directions are exposed to each other in an orthogonal manner, and then developed by a development process. 'Setting (Developing Process) In the present embodiment, the photosensitive layer is exposed and then processed. For the development treatment, a usual development treatment used in a silver salt photographic film or a printing paper, a film for dicing, a latex mask for a reticle, or the like can be used. The developer is not particularly limited, and it is also possible to use Phenidone-Hydroquinone 'PQ developer, Metol Hydroquinone (MQ) developer, and Metol®. : Acid (Met〇1 Ascorbic Acid 'MAA) developer, etc., commercially available ^^ 26 201234140 For example, Fujifilm Co., Ltd. can be used to liquefy the groove σ ClST-if; CR-56, CP45X, FD-3, Papitol, KODAK 八 ^ ** A-J sold C-41 E-6, RA-4, D-19, D-72 special developer 'or its reagents, some developer. In addition, you can also use Lissian, which is now included in τ

Developer) °, nth The development process in the present invention may include a fixing process for the purpose of stabilizing the unexposed portion and stabilizing it. In the present invention, a technique of using a silver salt photographic film or a printing paper, a film for printing plate, a fixing treatment used in a latex mask or the like can be used. The fixing temperature in the above fixing step is preferably about 2 (rc 〜 5 〇 ° C 'more preferably hunger ~ hunger. Further, the fixing time is preferably $seconds and two minutes, more preferably from 7 seconds to 50 seconds. The amount of the liquid to be replenished with respect to the amount of the photosensitive material 122 is preferably 600 ml/m2 or less, more preferably 5 Å/〆 or less, particularly preferably 300 ml/m2 or less. It is preferred to carry out development and fixing. The treated photosensitive material 122 is subjected to a water washing treatment or a stabilization treatment. In the above-described water washing treatment or stabilization treatment, the photosensitive material per 1 m 2 is usually washed with water in an amount of 2 liters or less, or may be 3 liters or less. The amount of replenishment (including hydrazine, that is, water storage and washing) is washed with water, and the mass of metallic silver contained in the exposed portion (conductive pattern) after the image processing is relative to the mass of silver contained in the exposed portion before exposure. The content of the content of the silver contained in the exposed portion is preferably 5% by mass based on the mass of the silver contained in the exposed portion before the exposure. With ±, high conductivity is obtained, so it is better. 01234140 The gray scale after the development treatment in the present embodiment is not particularly limited, but is preferably more than 4.0. If the gray scale after the development treatment exceeds 4 〇, the light transmittance of the light transmissive portion is kept high. , the genus

As a method of making the gradation exceeds 〇, for example, the doping of the ions and the cerium ions can be performed, and in addition, the developing portion is subjected to the epoxidation. It is preferred that the photosensitive layer is subjected to development treatment, and then immersed in a hard coating agent for dura mater treatment. Examples of the hard coat agent include a hard coat agent described in the Unexamined Patent Publication No. 2-141279. Transparent == step to obtain a transparent conductive sheet 'is preferably obtained inside, the resistance is in the range of W _.~, just in the range of 丨Q/sq.~5G n/sq _ 降Furthermore, the unit of surface resistance, and the other, can also be expressed as Ω/port or Ω/square. In addition, the obtained transparent conductive sheet _ low

χΩχηι以下,更佳A虚#]< n 1 乂平乂马16U and then better η. In the range of the step (10), the hard direction is more preferably in the manufacturing method of the range of 1.6 μΩχη1 to 1 () μΩχη (calendering treatment). Thereby, the conductivity of the transparent conductive sheet is remarkable

Si 2 can be carried out by pressing Wei. The rolling stick passes through the sling. In the following, _延_转 28 201234140 will be processed. - As the lysate used in the calendering treatment, an epoxy resin, a polyimine, a poly-suiamine, a polytheneamine, or a metal roll can be used. In the case of having an emulsion layer on both sides, it is preferred to treat it with the same metal. When the emulsion layer is provided on the surface, it can be set as a combination of metal and plastics from the viewpoint of preventing wrinkles. The upper limit of the line pressure is 1960 N/Cm (2〇〇kgf/cm, 699.4 kgf/cm2 if converted to surface pressure), more preferably 2940N/cm (3〇〇kgf/cm, if converted The surface pressure is 935.8 kgf/cm2 or more. The upper limit of the line pressure is below 688 〇 melon (· kgf / cm). The application temperature for the smoothing treatment represented by the calender roll is preferably 10 ° C (no temperature adjustment) ~ locrc 'better temperature, depending on the metal mesh pattern or metal wiring, the degree of brittleness or shape, the type of adhesive It is different, but it is about 10t (no temperature adjustment) ~50. Within the scope of 〇. (Process of Contact with Vapor) Further, in the production method of the present embodiment, the smoothed conductive material can be treated with vapor (vapor vaporization step). The vapor contact step includes a method of bringing the smoothed through-electrode sheet into contact with the superheated Wei, and a method of bringing the smoothed conductive pattern 108 to a saturated pressure of the pressure. Thereby, conductivity and transparency can be improved in a short time. It is considered that a part of the water-soluble binder is removed and the bonding sites of the metal (conductive substance) are increased. (Washing treatment) In the production method of the present embodiment, it is preferred to carry out a water washing treatment after bringing the transparent conductive sheet 29 201234140 接触 into contact with superheated steam or pressurized steam. The conductivity can be improved by performing a vacuum after the vapor contact treatment to wash away the binder which is dissolved or becomes brittle due to superheated steam or pressurized vapor. (Plating treatment) In the present embodiment, the smoothing treatment may be performed, or the transparent conductive sheet may be subjected to a plating treatment. By the mineral deposit treatment, the surface resistance '(4) can be further lowered to improve the conductivity. The smoothing treatment can be carried out in any period of the plating process or in the subsequent stage, but by the front stage of the weaving process, the weaving process becomes efficient (4) into a uniform woven layer. The plating treatment may be electrolytic recording or electroless plating. Further, the constituent material of the key layer is preferably a metal having sufficient conductivity, preferably copper. (Oxidation treatment) In the embodiment, it is preferable that the transparent conductive sheet after the development treatment and the conductive metal portion formed by the plating treatment are subjected to oxidation treatment, for example, #金属 slightly When deposited in the light-transmitting portion, the metal can be removed, and the permeability of the light-transmitting portion is substantially changed to just %. A conductive sheet comprising a conductive thin wire formed by the above process, and a plurality of patterned electrodes of conductive thin wires. The description will be made regarding the relationship between the patterned Ray's surface formed on the transparent support of the present invention and the electrostatic or control panel which can preferably use the transparent conductive sheet of the present invention. In the previous electrostatic panel, the ITO film as a transparent electrode material was set to _. 4 is used as the rod electrode, but in the present invention, the electrode is formed by using a combination of the conductive thin wires of the material 201234140 which is lower than the material of the ITO, and hence it is referred to as a patterned electrode. The capacitive touch panel using the transparent conductive sheet of the present invention is formed with an upper electrode (also referred to as a surface electrode) 11 and a lower electrode on both sides of the transparent support 32 as shown in FIG. 4(d) (also referred to as Back electrode) 12. The upper 卩 electrode (also referred to as a surface electrode) 11 has a pattern as shown in the upper diagram of FIG. 6, and each electrode includes a plurality of conductive lattice portions 14A that sense electrostatic capacitance, and a conductive portion 16A that connects the lattice to the lattice. And an extraction line 18A that connects the electrode to the external control unit. Fig. 7 is a shape of a guide lattice portion = a diamond shape, a rectangular lattice: guide == two: = ': a square lattice of the line 21, a circumference arranged in the square lattice =: a virtual guide of the ΐ part: two: and Conductive connection in the direction of the electrode: In order to prevent (4) less than (4) :: can be used to connect with a number of thin lines, (four) two = pattern, each electrode package::: surface static:) 丄 2, such as 圏 6 The MB of the figure, the grid and the grid are connected 2 = a plurality of conductive lattice portions and a connecting portion 16B for connecting the electrodes to the external control portion, so as to be clear from the description of the upper electrode. Pull out the line (10). As shown in Fig. 8, the patterned electrode is preferably a conductive sheet having a square lattice or a rectangular lattice in the electrode 201234140 by a conductive thin wire. 9 is not the self-contact of the electrode line when the perspective view of the contactor side is 6 and the T-section conductive sheet 12 is in the form of a panel which can be easily recognized by the valley. Moreover, the short line of the figure The partial IS is formed as a 'straight line portion and a graph including two strips. The solid line portion on the i^ side where the portion of the 〇 symbol is placed in FIG. 9 indicates the conductive grid portion B of the upper conductive sheet. A part of the electric thin wire 21, which is also a solid line 19 (21)

1 line part =;: = virtual thin line of the piece. Similarly, in the vicinity of the conductive thin line of the right-side eight-electrode conductive lattice portion (10), the same as the dotted line 19 (22), the conductive lattice portion 14B is not turned on. The line 22 is also non-conducting, and is imaginary; ::: -rt: rr == is formed on the extension line of the both ends of the long line of the square lattice and is preferably used for the large screen, the present invention] 2 ITO has a high resistance value and a mesh or lattice forms a diamond-shaped portion, and contains a low-resistance thin wire. Hereinafter, the description will be made by using a square square with a low square resistance and a bright square lattice, but it does not hinder the use of the long square 32 201234140. The line width of the conductive thin wires forming the conductive lattice portion is preferably 1 μm or more and 10 μm or less, more preferably 2 μm or more and 6 or less. When the range is Ιμηη or more and 10 μηη or less, an electrode having a low resistance can be formed relatively easily. The thickness of the conductive thin wire forming the conductive lattice portion is preferably 〇1 μm or more and 1.5 μπι or less, more preferably 〇 2 μmη or more, and 〇8 瓜瓜以下以下. When the right side is in the range of 0.1 μηι or more and 1.5 μηι or less, it is relatively easy to form an electrode having low resistance and excellent durability. The length of the side of the conductive lattice portion 14A and the conductive lattice portion 14A is preferably 3 mm to 10 mm, more preferably 4 mm to 6 mm. If the length of the side is 3 mm to 1 Gmm, it is less likely to cause the same problem as the problem that the detection is not caused by the shortage of the sensed electrostatic capacitance (4), or the position detection accuracy is lowered. ^2 = τ: μηι . When the length of the side of the unit lattice is in the above-described range, and the front side of the transparency can be favorably maintained, the display can be recognized without any sense of discomfort. 4 Furthermore, the upper and lower electrodes of the touch panel of Fig. 8 are orthogonal, but as long as the decision touch == sigh is set to be arbitrary. _ private does not make a mistake, then the thin line: two = rY: = r sub-guided control panel has the following characteristics: If the panel of this 33 201234140 = the direction of the electric display of the image display device (four), The conductive sheet in which the patterned electrode of the stack = 2 is less likely to be produced can significantly reduce the electric resistance as compared with the configuration using one sheet of 1το ❹田*. Therefore, although the conductive wire of the present invention is applied to, for example, a touch panel, the response speed can be increased, and the touch == size can be promoted. "Two-sided conductive sheet with improved color tone difference" As described in the means for solving the problem, the conductive sheet of the present invention is capable of reducing the upper electrode formed on both sides of a transparent support for improving productivity. A conductive sheet having a poor hue of the lower electrode. The improvement of the color difference can be achieved by a transparent conductive sheet having a surface electrode of a conductive sheet (also referred to as a double-sided conductive sheet) formed on both surfaces of the one transparent support and the lower electrode (away from the double-sided conductive sheet) away from the transparent support The transparent conductive sheet having an absolute value of the difference between the reflection chromaticity b!' of the electrode surface on the side of the electrode and the reflection chromaticity b2* of the electrode surface on the side of the transparent column body on the side of the electrode is substantially equal to or less than 2, and thus substantially Coordinate the face with a sense of coordination. Further, the color tone at the time of observation is preferably such that it is easily recognized as black on the visual field. The measured values of b/ and b/ are neutral in the vicinity of 〇. However, in the present invention, if it is set as follows, the recognizer can easily recognize black. In the present invention, 'as b/' is preferably 2. 2. 〇 < b/SO ' is more preferably -1.5 < br$-0.3, particularly preferably -l.Ocb/s-OJ. Preferably, b2#' is -10<b2, i.〇, more preferably -0.7<34 201234140 4U^y/pif b2 $〇·5 ’ is particularly good - 〇.5<b2 $0.2. As a combination of h and b2, it is preferable, and 丨〇 < b2 S1.0 ' is preferably -l.scbi $-0.3, and -〇.7<^2*^0_5, particularly preferably -l.CKb /S-OJ, and -〇, 5<b2*S0.2. By doing so, the unevenness of the color of the electrode surface and the hue (neutral) which is close to black can be removed, and the visibility is further improved. Here, the reflection chromaticity bi of the electrode surface on the side of the surface electrode away from the transparent support is measured when the reflection chromaticity of the electrode surface of the region of d2 of FIG. 2 is measured from the discriminator side of the upper portion of the figure. y value. In addition, the reflection chromaticity h of the surface of the electrode of the transparent support is measured, and the reflection chromaticity of the surface of the electrode of the ubiquitous region of Fig. 2 is measured from the discriminator side of the upper part of the figure. *value. The *, *, * reflection chromaticity b* is the characteristic value defined by the ιΛγ color system. The Lab color system is a method of coloring established by the International Commission on Illumination (intemati〇nai Comrmssion on Illuminati〇n, αΕ) in 19-6. The L value, a value, and b* value in the present invention are by jIS_z8729. : 1994 = The value obtained by the method of measurement is the measurement method of the muscle survey 9 /", there is a measurement method using reflection, and a measurement method using transmission, and the value measured by reflection is used in the present invention. * The L* value, the a* value, and the b value in the _b color system are as well known. The L value represents the brightness, and the a* value and the b* value represent the hue and chroma. Specifically, if the number is taken, it means the hue of red. If it is a negative sign, it does not show a green hue. If the b* value is positive, it is a yellow hue, and if it is negative, it is a blue hue. In addition, the greater the value of a, the b* value of the value of b* 35 201234140 both indicate that the color of the color is larger and brighter, and the smaller the absolute value, the smaller the chroma. In the present invention, the 'a* value is small in the observation direction (bi direction and b2 direction). On the other hand, the change in the b* value caused by the observation direction of the electrode is larger than the value of a, and specifically, it is easy to be color unevenness by changing from yellow to blue, or from blue to yellow. identify. The details of the measurement method are described in the examples. The improvement of the color tone of the electrode surface of the above-mentioned double-sided conductive sheet is achieved by the photosensitive material of the present invention which has been described. Hereinafter, a preferred embodiment of each layer of the photosensitive layer for reflection chromaticity adjustment described above will be briefly described. In the system for increasing the amount of silver for lowering the resistance and increasing the density of silver in order to impart conductivity to the silver image formed by development as in the present invention, the surface of the electrode of the silver electrode which is away from the side of the transparent support is developed. The hue tends to be blue, and the hue of the electrode surface of the developing silver electrode near the side of the transparent support tends to be yellowish. As a cause of the hue phenomenon, it is considered that in a system having a large amount of silver and a high silver density, the photosensitive layer is separated from the side of the photosensitive layer away from the transparent support, and the development is formed on the surface side by a fresh developing solution. In contrast, as the developer penetrates into the lower layer in the photosensitive layer, the accumulation of the shadowing material occurs, and the development of the developer is suppressed, and the surface layer is consumed. Therefore, the solution is composed of a solution having a small amount of the inhibitor. Development is carried out. Along with this, the shape of the filament of the developed silver was different on the upper layer side (the side of the enamel layer side)/the lower layer side of the photosensitive material, and it was estimated that it was observed as a color product. Based on such inference, the preferred form of the present invention is described in items [1] to [30] of the means for solving the problem. The above two-sided conductive sheet of the present invention can be preferably used for a touch panel, particularly an electrostatic capacitive touch panel. Further, the present invention can be used in appropriate combination with the techniques of the publications and the international publications described in Table 1 below. The expressions "Japanese Patent Special", "No. Bulletin", and "No. Manual" are omitted. Among them, the Japanese public bulletin, such as 2004-221564, uses a hyphen to indicate the year number, and the international public handbook, such as 2006/001461, slashes the year number. [Table 1] 2004-221564 2007-235115 2006- 332459 2007-102200 2006-228478 2006- 348351 2007- 134439 2007-310091 2005- 302508 2008- 267814 2008-283029 2009-4213 2008-147507 2008-218096 2008-241987 2006 /001461· 2006/098335 2004-221565 2007-207987 2009-21153 2006-228473 2006- 228836 2007- 270321 2007-149760 2007- 116137 2008- 218784 2008-270405 2008- 288305 2009- 10001 2008-159770 2008-218264 2008- 251, s, s, s, s, s, s -251275 2006/098333 2007/001008 2006-352073 2006-010795 2006-261315 2006-269795 2006- 336090 2007- 201378 2007-178915 2007- 207883 2008- 227351 2008-277676 2008-300720 2009- 21334 2008-171568 2008-235224 2008-252046 2006/098336 2007-129205 2006- 228469 2007- 072171 2006-324203 2006- 336099 2007- 335729 2007-334325 2007- 013130 2008- 244067 2008-282840 2008-300721 2009- 26933 2008-198388 20 08-235467 2008-277428 2006/098338 [Examples] Hereinafter, the present invention will be more specifically described by way of examples of the invention. In addition, the materials, the amounts, the ratios, the processing contents, and the processing procedures shown in the following examples can be appropriately changed without departing from the gist of the invention. 37 201234140 ~τ V/J _✓心 1 Therefore, the scope of the present invention should not be construed as being limited to the specific examples shown below. Example 1 (Preparation of Emulsion) The amount of each of the following two liquids and three liquids corresponding to 90% was simultaneously added to the following one liquid which was kept at 38 ° C and ρ Η 4.5 while stirring for one minute. The formation of 0.16 μηι of nuclear particles. Then, the following four liquids and five liquids were added over 8 minutes, and the remaining 10% of the following two liquids and three liquids were added over two minutes to grow the core particles until 〇21. Further, 0.15 g of potassium hydride was added and aged for 5 minutes to complete the formation of particles. 1 liquid: 750 ml 8g 3g 20 mg 10 mg 0.7 g 300 ml 150 g 300 ml 38 g water gelatin (o-phthalic acid gelatin) gasified sodium 1,3-dioxyl group m saliva-zine-sulfur Sodium thiobenzenesulfonate sodium citrate 2 solution: water silver nitrate 3 solution: water vaporized sodium 38 201234140 ^vjyz.pif potassium bromide 32 g hexachloroiridium (III) acid potassium (0.005% KC1 20% aqueous solution) 5 ml Ammonium hexafluoroantimonate (0.001% NaCl 20% aqueous solution) 7 ml 4 liquid: water 100 ml silver nitrate 50 g 5 liquid: water 100 ml gasification sodium 13 g potassium bromide Π g yellow blood salt 5 mg, then according to the routine The method was washed with a flocculation method. Specifically, the temperature was lowered to 35 ° C, and after adding 3 liters of distilled water, sulfuric acid was used to lower the pH until the silver halide precipitated (pH was in the range of 3.6 ± 0.2). Next, about 3 liters of supernatant (first water wash) was removed. Further, after adding 3 liters of steamed water, sulfuric acid was added until the precipitation of the functional silver. 3 liters of supernatant (second water wash) was removed again. Further, the same operation as the second water washing was repeated once (third water washing) to complete the water washing and desalting stroke. The emulsion after washing and desalting was adjusted to pH 6.4, pAg7.5, sodium thiophene sulphate was added, sodium benzophenone sodium 3 mg, sodium thiosulfate 15 mg and chloroauric acid ι were added. Apply chemical sensitization in a way that is optimal for the first time, then add Wa as a stabilizer, 'Four Nitrogen Shaw! (10) mg, as a preservative 39 201234140

Proxel (β brand name, manufactured by ICI c〇, Ltd) 1 〇〇 mg. The emulsion finally obtained was an iodine silver bromide cubic particle emulsion containing silver iodide 〇.〇8 mol%, and the ratio of the gas bromide was set to 7 g of silver vapor. /❶, silver bromide 30% by mole, the average particle size is 0.22 μηι, and the coefficient of variation is 9%. (Preparation of photosensitive layer coating liquid) To the above emulsion, l, 3, 3a, 7_4 atmosphere 茚l.2xl〇-4mol/mole is added.

Ag, hydroquinone 1·2χ1〇-2 mol/mol Ag, citric acid 3.〇χ1〇-4mol/mole~, 2,4-digas_6-radio-1,3 , 5-triazine sodium salt 0.90 g / mol ^ g, a small amount of hard coating agent, using citric acid to apply the coating solution? 11 was adjusted to 5 6, thereby preparing a photosensitive layer coating liquid. The composition of the photosensitive layer coating liquid was used as a standard, and the volume ratio of the silver to the binder in Table 2 was adjusted to adjust the type and amount of the sulphur compound, and the surface layer was prepared. (U layer, m layer, layer) and a coating liquid of three layers (u layer, 111 layer, layer) on the back surface. ^, 100 μΐη of the polyethylene terephthalate (PET) film was subjected to corona discharge treatment on both sides, and a gelatin primer having a thickness of 〇丨μιη was disposed on both sides to set an optical density on the undercoat layer. 1G and including the antihalation layer of the (four) material by the test of the f liquid, thereby forming a branch body. The photosensitive layer coating liquid prepared and prepared above was applied to both sides of the remote support. In the coating, the amount of silver is set as a reference so that the total amount of silver contained in the three layers (u layer, added layer, and 0 layer) of the photosensitive layer becomes the thickness of the silver image in Table 2 and Table 3 (unit The shape of the way is μιη). In the present case, the developed silver image thickness was calculated on the condition that the applied emulsion + all of the impurities were converted into developed silver ' and the developed silver density (indicating the silver/binder volume ratio) was 1 〇 5 201234140. Further, the film thickness of each layer of the photosensitive layer (u layer, m layer, and ruthenium layer) is set so that the film thickness becomes 1 · 2 · 1 in the photosensitive material 1 to the photosensitive material 15 in the photosensitive material 16 to The photosensitive material 31 is set so as to have a film thickness ratio recorded in () of the silver density row of the formulation value of Table 3. Further, a value of 1 in () indicates a single layer, and a value of 0.2 in () indicates that the film thickness of the layer is 20% of the entire photosensitive layer. Therefore, in Table 3, the total thickness of the silver and the binder of the photosensitive layer 3 layer is 0.7 μm in the surface other than the surface and the back surface of the photosensitive material 19 and the surface of the photosensitive material 31, respectively. The thickness of the photosensitive material 31 is set such that the silver and the binder are each 1.5 μm thick. The surface and the back surface of the photosensitive material 19 are the same as the silver/adhesive volume ratio of the ruthenium layer to the surface and the back surface of the photosensitive material 16. That is, the ruthenium layers of the two have the same coating thickness of the binder, and only the thickness of the silver is different. In the comparison of the photosensitive material 19 and the photosensitive material 18, in the photosensitive material 18, the amount of silver which is produced by setting the silver/binder volume ratio of the ruthenium layer to 〇.3 in the m layer and the binder In contrast, since the amount of decrease in the amount of silver in the ruthenium layer is not adjusted in the photosensitive material 19, the thickness of the developed silver image in Table 3 is thinner than that of the other photographic materials. The silver bromide content of the emulsion was from the photosensitive material 1 to the photosensitive material 15, and all the layers were set to 30 mol%, and the photosensitive material 16 to the photosensitive material 31 are described in Table 3. The volume of the silver and the binder in Table 2 was converted into a volume by the conditions of the development of the 201234140 male and the density of the adhesive of the silver (3) as described above. Further, the f ^ degree is 1.34, which is a density which can be _, and when # other high molecular compounds are used, the conversion corresponding to the compound is required. In addition to f, the amount of the sulfhydryl compound added to the photosensitive layer coating liquid is expressed as mg in an amount of 1 g of the silver base. The structure of the Wei group compound used is described after Table 3. Further, a protective layer containing a gelatin containing a preservative as a coating of 〇·15 μηι was provided on the above-mentioned enamel layer. The three layers of the photosensitive layer and the protective layer of the three layers were simultaneously coated by a coater to prepare a photosensitive material photosensitive material 31. ~ (exposure and development treatment) Next, the above-mentioned photosensitive material 1 to photosensitive material 31 were subjected to double-sided exposure using a high-pressure mercury lamp using the double-sided exposure machine of Fig. 5, and the mask for pattern formation of Fig. 7 was used as a surface. On the side mask, the mask for pattern formation of FIG. 8 was used as a back cover for exposure. The window for light transmission of the mask to be used is the same pattern as that of Figs. 7 and 8, and the unit square lattice (10) forming the lattice is 3 divisions, and the side length of the lattice is · μηι 〇 after exposure, using the following The developer is developed, and the solution (product name: N3X_R: manufactured by Fujifilm Co., Ltd., CN16X) is subjected to development treatment, then rinsed with pure water, dried, and then subjected to rolling treatment of the sample. A transparent conductive sheet 1 of a double-sided electrode type was obtained. The two-sided electrode type transparent conductive sheets 2 to 31 were obtained in the same manner. 42 201234140 Furthermore, the processing flow is as follows. [Processing Procedure] Processor: Automatic developing machine manufactured by Fujifilm Co., Ltd. (FG-710PTS) Processing conditions: development was 35 ° C 3 sec seconds 'Fixing was 34. (: 23 seconds' Washing is 20 seconds of running water (5 L/min). (Composition of developing solution)

0.037 mol/L 0.016 mol/L 0.140 mol/L 0.360 mol/L 0.031 mol/L 0.187 mol/L liter (L) of the developer containing the following compound hydroquinone N-nonylaminophenol sodium metaborate Sodium oxide desertification, sodium sulfite (manufacture of touch panel), polyethylene terephthalate with thickness μμη attached to the double-sided electrode obtained by the upper axial shadow treatment = electric sheet 1 The side of the cooking surface was prepared to prepare the lead of Comparative Example 1, and the transparent conductive sheet 2 to the transparent conductive sheet 31 were used instead of the transparent one. In the same manner as in Comparative Example 1, Comparative Example 2 and Comparative Control Panel, Example i to Example 28 were produced. of. (Evaluation) 43 201234140 The following evaluation was carried out using the double-sided electrode type transparent conductive sheet 1 to the transparent conductive sheet 31 produced above. (1) Measurement of reflection chromaticity b/ and reflection chromaticity b2* The sample for measurement was placed on a BCRA black tile (glossy plate), and the measurement was carried out from the direction of 0° at 45. The spectral reflectance of the light received in the direction. A preferred tile is a BCRA black tile (glossy version) manufactured by SAKATA INX ENG Co., Ltd., which has a reflection chromaticity of l* of 3.6 and a* of -0.9 ′b* of -0.6. As a reflection densitometer, a Spectro Eye LT manufactured by GretagMacbeth can be used. Furthermore, for the measurement sample of the reflected chromaticity, the mask 110 for surface exposure is a mask using a window having a size capable of performing reflection chromaticity measurement, instead of a normal mask for pattern exposure, and is exposed on the back side. The exposure of the entire face without the use of a mask is implemented. The measurement of the reflection chromaticity is performed from the surface side, and the reflection chromaticity of the exposed portion of the surface on which the silver image is formed is defined as the reflection chromaticity b/', and the reflection of the unexposed portion of the surface is measured. The chromaticity is set to the reflection chromaticity b2*, and the absolute value of the difference Δ!/ (also expressed as jb*) is calculated from the obtained reflection chromaticity b/ and the reflected chromaticity V. (2) Evaluation of the visibility The two-sided electrode type transparent conductive sheet produced by observing the oblique direction of the respective directions in the vertical direction is characterized by unevenness in the color of the reflected light, shaking of the reflected light, and contour of the electrode. Evaluation. Evaluation ◎ is not at all worrying. The evaluation 〇 almost does not recognize the level of the hue. Evaluation △ Even if there is a hue, it is an unrecognizable and identifiable bit 44 201234140. Evaluation is worrying. (3) Evaluation of conductivity The resistance value of the electrode of the transparent conductive sheet was directly read, and the resistance values of the electrode on the surface of Comparative Example 1 and the electrode on the back surface were evaluated as a standard. Evaluation ◎ The low resistance value was clearly shown as compared with the resistance value of Comparative Example 1. As the surface resistance value, less than 20 Ω / port. The evaluation value was substantially the same as the resistance value of Comparative Example 1. The surface resistance value is 20 Ω/□ or more and 50 Ω/□ or less. Evaluation X was inferior to the resistance value of Comparative Example 1 for some reason. As the surface resistance value, it is a value exceeding 50 Ω/□. The above results are summarized in Tables 2 and 3 below. 45 201234140 [Table 2] Example No. Differences in Photosensitive Material Number Surface Silver/Binder Volume Ratio Silver Image Thickness μηι 毓Base Compound Number ΜBase Compound Addition Number: mg/silver 1 gb, * b2· Zb* absolute Value-recognized conductive layer m layer m layer U layer Comparative Example 1 Table 1 0.7 - - - - 0.7 2.3 X Back 1 0.7 - - - - 1.6 Comparative Example 2 2 Table 1.5 0.7 - - - - 0 2.5 X ◎ Back 1.5 0.7 - - - - 2.5 Comparative Example 3 3 Table 2 0.7 - - - - 0.5 3.0 X ◎ Back 2 0.7 - - - - 3.5 Example 1 4 Table 1 0.7 - - - - -0.7 0.8 〇0 Back 1 0.7 F 0 0 3 0.1 Example 2 5 Table 1.5 0.7 - - - - 0 1.0 〇 ◎ Back 1.5 0.7 F 0 0 3 1.0 Example 3 6 Table 2 0.7 - - - - 0.5 1.0 〇 ◎ Back 2 0.7 F 0 0 3 1.5 Example 4 7 Table 1 0.7 - - - - -0.7 1.4 Back 1 0.7 A 0 0 3 0.7 Example 5 8 Table 1 0.7 - - - - -0.7 1.0 Back 1 0.7 G 0 0 3 0.3 Example 6 9 Table 1 0.7 - - - - -0.7 1.7 Δ Back 1 0.7 B 0 0 3 1.0 Example 7 10 Table 1 0.7 - - - - -0.7 1.8 Back 1 0.7 C 0 0 5 1.1 Example 8 11 Table 1 0.7 - - - - -0.7 1.9 〇0 Back 1 0.7 D 0 0 5 1.2 Example 9 12 Table 1 0.7 - - - - -0.7 1.8 Back 1 0.7 E 0 0 5 1.1 Example 10 13 Table 1 0.7 - - - - - 0.7 1.9 〇 ◎ Back 1 1.5 F 0 0 3 1.2 Example 11 14 Table 1 0.7 - - - - -0.7 1.2 Back 1 0.7 F 0 1 1 0.5 Example 12 15 Table 1 0.7 - - - - -0.7 1.5 〇〇 Back 1 0.7 G 0 1 1 0.8 46 201234140 Ja«N6g Inch bucket ε<] Evaluation of conductivity of touch panel 〇〇 〇〇 〇〇〇〇 〇〇〇〇 〇〇Ο 〇 〇 反射Chromaticity » χ> 00 〇do 〇ΓΛ 〇\ 〇ON 〇〇\ ο 〇 〇 〇-0.2 〇〇CN Ο 〇CN 〇1 CN 〇 casting00 〇as ο 〇\ o Os 〇cn fH 1 σ\ 〇 1 ΟΝ ο -0.9 1 Formulation value Addition amount of each layer of mg/silver 1 gmm cn mmm ro m cn cn mmmm Double Β 1 1 1 1 1 1 1 I 1 1 1 1 1 ί I 1 1 1 1 1 〇1 1 1 1 1 1 1 1 1 1 I 1 1 1 1 1 1 1 1 1 Compound ti, tLi Ph tin U-. PL, Ph Uh tL, (J-. (X. Ph Ph tL, S 上 invite' S ^ r, e 1 W \ Ρ 1.0 ( 0.2) 1.0 (0.2) 1.0 (0.2) 1.0 (0.2) 1.0 (0.2) 11.0 (0.2) i 1.0 (0.2) 1.0 (0.2) ! lo (0.2) I 11.0 (0.2) 1 11.0 (0.2) 1 1.0 (0.2 1 1.0 (0.2) 1.0 (0.2) 1 1.0 (0.2) 1 1.0 (0.2) 1.0 (0.2) 1.0 (0.2) 1.0 (0.2) 1.0 (0.2) m layer 1.0 (0.6) 1.0 (0.6) 1.0 (0.6) 1.0 (0.6) 1.43 (0.6) |1·43 (0.6) 1 1.0 (0.6) 1.0 (0.6) |1.43 (0·6) 1 |1.43 (0.6) | |1.25 (0.6) | 1.25 (0.6) 1.25 ( 0.6) 1.25 (0.6) 1.25 (0.6) 1.0 (0.6) 1.25 (0.6) 1.0 (0.6) 1.43 (0.6) 1.0 (0.6) 〇 1.0 (0.2) |1·0 (0.2) I LL〇(0.2) I 1.0 (0.2) | 0.3 (0.2) I 0.3 (0.2) |0.3 (0.2) 1 0.3 (0.2) 1 0.3 (0.2) 1 |0.3 (0.2) | 0.5 (0.2) 0.5 (0.2) 0.5 (0.2) 0.5 (0.2 0.5 (0.2) 1.0 (0.2) 0.5 (0.2) 1.0 (0.2) 0.3 (0.2) 1.0 (0.2) The silver bromide content of each layer is Mo %% P o 〇Ο Ο m layer oo ο ο 〇oo ο ο The thickness of the silver image μηι Ο 〇 〇 o o o o o d d d d d d d d d 〇 〇 d d d d d d d d ο ο ο d d d ο ο ο d 区 区 区 区 ο 区 区 区 区 区<<<<<<<<> Photosensitive material number and conductive sheet number 〇〇〇\w-> (N Example 13 Example 14 Example 15 Example 16 Example 17 Example 18 Example 19 Example 20 Example 21 Example 22 201234140 J -aCN650 inch ο Ο 〇〇Ο ◎ ο Ο << ◎ ◎ ο 00 ο ο ο ο L〇^J inch 〇-0.4 〇\ ο 〇\ ο m 1 W0 1 Ι^2Ί 1 mm 1 1 m 1 CO I cn 1 I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 f 1 1 tf 1 t 1 1 tin Ρη Uu 1 pu, 1 Ph 1 1 Uh |ι〇(〇·2) 1 1.0 (0.2 ) 1.0 (0.2) L〇-3 (0.2)1 11.0 (0.2) 1 | 0.3 (0.2) I Ll〇(〇-2) I Ι〇·3 (0.2) ! 1 1.0 (0.2) 1 l〇.3 (0.2)1 ll.O (0.2) I 0.3 (0.2) 1.43 (0.6) 1.0 (0.6) I 1.43 (0.6) 1 1.0 (0.6)" 1.43 (0.6) 1.0 (0.6) |1.43 (0.6) | 1.43 ( 0.6) 1 1.0 (0.6) 1 |1·43 (0.6) 1 |1.43 (0.6) 1 1.43 (0.6) |0.3 (0.2) 1 |1.0 (0.2) I 10.3 (0.2) 1 |1.0 (0.2) I | 0.3 (0.2) I 11.0 (0.2) I 10.3 (0.2) I |l.〇(0.2) 1 11.0 (〇·2) ι 11.0 (0.2) I l〇.3 (0.2) 1 1.0 (0.2) 〇Ο ο Ο 〇ο ο ο 〇ο ο ο 卜 Ο d d d d d d d d d d d d d d d d d d ο ο ο ο & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & & Example 28 201234140 HKjoyzpif [化i]

Compound c

Compound G HOOC h Compound Β Η

XVVsh

Na03S"^^N According to the results of Table 2 above, the following are known. The double-electrode-type transparent conductive sheet of Comparative Example 1 in which no compound is used in any of the photosensitive layers on the front surface and the back surface has a sufficient resistance value unevenness as an electrode constituting the i-type capacitive touch panel. Poor identification. Further, if Α π^ hue 2 and Comparative Example 3, the silver and the binder were increased as in the comparative example, and the color unevenness was further deteriorated. The volume ratio, that is, the increase in silver density, and on the other hand, in the photosensitive layer on either side of the surface or the back surface, in the examples 1 to 12 in which the 2012 20120140 mercapto compound is used, it can be reduced without increasing the resistance value with respect to the comparative example. The color is uneven and the recognition is improved. Regarding the surface on which the mercapto compound was used, although the radical compound was added only to the back surface in the present experiment, it was preferably added on the back side. Among the back surfaces, it is preferably added to the u layer as a photosensitive layer close to the support, as compared with the comparison of Example 1 and Example 11, or the comparison of Example 5 and Example 12, it is preferable to limit the radical compound. In the lower layer (ie, the layer near the support). Further, the effect of improving the color tone differs depending on the kind of the mercapto compound, and in the examples 7 to 9 in which the monocyclic compound C, the mercapto compound d, and the mercapto compound E are used, compared with the case where no mercapto compound is not used. In Example 1, the effect of color tone improvement is extremely small. On the other hand, it is understood that the use of the compound A, the compound B, the compound F, and the compound G as examples of the condensed ring compound, and the examples 4 to 6 show a large improvement effect of uneven color tone, and it is particularly preferable to use it in 2_酼. Examples 1 and 5 of Compound F having a sulfo group and a carboxyl group at the 4- to 7-position of the benzimidazole and Compound G. Further, in order to further reduce the resistance, the silver density was set to 2, and the color unevenness of Example 3 in which the compound F was added to the back surface photosensitive layer u was small, and the resistance was lowered. Further, in Example 10, although the fluorenyl compound F was added to the photosensitive layer on the back surface, and the thickness of the silver image was increased from 〇·7 to 15, the display was able to reduce the resistance of the lower electrode of the _ surface (four). The sensing ability of the electrostatic capacitance is improved, and the unevenness of the color of the electrode at the time of recognition can be improved. Further, the following can be seen from the results of Table 3. 50 201234140 Examples 1 to 12 of Table 2 above are examples of a composition in which a silver halide emulsion is used with a silver bromide emulsion containing 30 mol% of silver bromide and a volume ratio of silver to a binder (silver density) is used. The photosensitive layer is fixed, and the layer (u layer) of the photosensitive layer close to the branch body contains a composition example of a sulfhydryl compound. In contrast, Examples 13 to 28 of Table 3 are used to have a silver bromide content. Changed to 50% by mole or 70% by mole, or the volume ratio (silver density) of the silver and the binder in the photosensitive layer in the thickness direction of the photosensitive layer (changing the specificity of the bismuth layer, the m layer, and the u layer) The example of the electrode formed by the photosensitive material of the silver density of the layer and the touch panel was improved as compared with the examples 1 to 12, and the result of the absolute value of the difference in reflected chromaticity was improved. Examples 13 to 19 have the feature that the electrodes on both sides of the transparent support are designed to use a double-sided conductive sheet formed of the same photosensitive material. Each of the samples has a feature that the observed color tone does not change even if the direction of the conductive sheet is changed, and has the following advantages: it is easy to recognize in the formation of the touch panel, and the back surface of the watch is not generated. problem. The common points of Examples 13 to 16 are that the development inhibitor F (the sulfhydryl compound) of the present invention is added to the layer (u layer) of the side of the transparent support which is adjacent to the support on both sides, Example 13 and Examples 14 is a sample in which the silver bromide ratio of all layers was changed from 30 mol% to 50 mol% or 70 mol%. Example 15 and Example 16 are silver/adhesive layers of the tantalum layer to which the developing treatment liquid was initially contacted. The sample whose volume ratio was changed from 1.0 to 0.3 was obtained as the absolute value of the difference in reflection chromaticity (also expressed as |ΔΙ/| or |zlb*|), and the sample of 201234140 was re-conducted with no problem. The volume of the ί rate averages the silver and the thick money is less. _Π5^ ^The recording of the conductive layer _body ^!^, must help the case, if it contributes to conductivity, but the thickness of the silver/binder of the u layer); & For the melon layer and the improvement of the guide material, it is also possible to provide a layer having a wide color and a thickness of preferably 々Μ2. It is preferable that the contribution of the conductivity is less than 30%^the thickness of the silver-containing __thickness, and the ratio of the layer = the ratio of the layer is increased. Also, the volume fraction of human and an, the development inhibitor layer is added ΐ::=ίσΓ and is a sample according to Example 18, Example 19, Example (4) f slightly = clever blue side. By grouping the above three elements 5, the desired uneven color tone is obtained. Examples 20 to 28 have the following features: The two sides of the transparent slab body are made of a two-sided guide (also referred to as an asymmetrical type) formed of different photosensitive materials. Each of these samples has the advantage of independently controlling the color tone of the surface electrode and the back surface electrode, i.e., independently making the color tone of the surface electrode and the back surface electrode close to an optimum value. Examples 20 to 28 can be avoided by the content of the surface, the back, or the enamel layer, u 52 201234140. : body =; ===, silver/adhesive, and must be based on the surface of the surface. The result of m is _ preferably _ 2 or less, more preferably 1 thunder ΐΐ ΓΠ ΓΠ ΓΠ 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例 实例As an electromagnetic wave screen [the picture is simple and easy to use as an electromagnetic wave screen _, excellent in color before. Type: a touch panel model in which two sides of a transparent touch panel are formed with electrodes on the two sides of the touch panel model having electrodes; FIG. 3 is a photosensitive material for manufacturing the transparent conductive sheet of the present invention. Sectional view. Fig. 4 (a) to Fig. 4 (4) are views showing a process for producing a transparent conductive sheet in which electrodes are formed on both surfaces of a transparent support of the present invention. Figure 5 is a view showing exposure of both surfaces of the photosensitive material of the present invention via a photomask. Fig. 6 is a perspective view showing the laminated body of the upper conductive sheet 11 and the lower conductive sheet 12; ΐ ΐ 疋 疋 疋 疋 的 的 的 的 的 的 的 的 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电 导电The self-touching state is a pattern of a layered manner of the upper conductive sheet and the lower conductive sheet, and a mode of laminating the upper conductive sheet and the lower conductive sheet. The figure 一 is an illustration of a state in which the upper conductive sheet and the lower conductive sheet are laminated. [Main component symbol description] 01. Touch panel 05. Photosensitive material 10 for manufacturing transparent conductive sheet: Transparent conductive sheet (also referred to as double-sided conductive sheet) 11 · Upper electrode (surface electrode) 12: Lower electrode (back electrode) 14Α, 14Β. The plurality of conductive lattice portions 16Α and 16Β that sense the electrostatic capacitance. The conductive connecting portions 18Α and 18Β that connect the lattice to the lattice: the extraction line 19 that connects the electrode and the external control unit: the virtual thin line 21: Conductive thin wire 54 constituting the upper electrode 201234140 22 : Conductive thin wires 30 and 31 constituting the lower electrode: Transparent support 32 which also serves as a contact surface: Transparent support 33 for conductive sheet: Transparent support 41, 42: Double Adhesive layer of insulating layer 50: upper photosensitive material layer (surface photosensitive material layer) 51: upper photosensitive layer (surface photosensitive layer) 52: upper first photosensitive layer (upper u layer) 53: upper second photosensitive layer (upper m layer) 54: upper third photosensitive layer (upper layer) 55: upper protective layer 56: upper undercoat layer 57: upper antihalation layer 60: lower photosensitive material layer (back photosensitive layer) 61: lower feeling Layer (back surface photosensitive layer) 62: lower first photosensitive layer (lower u layer) 63: lower second photosensitive layer (lower m layer) 64: lower third photosensitive layer (lower layer) 65: lower protective layer 66 ·· Lower undercoat layer 67: lower antihalation layer 100a, 100b: light source a and b for exposure 101a, 101b: lenses a and b for exposure 102a, 102b: parallel light a and b for exposure 55 201234140 110 : The photomasks 112 and 122 forming the upper electrode 11 and the light transmissive electrode of the photomask are: the light shielding portion 120 of the photomask: the photomask portion for forming the lower electrode 13 and the surface electrode in the photosensitive layer) , the first part (the 151 (21) having the latent image formed: the conductive thin line of the upper electrode formed after the development process), the silver thin line of the electrode (the structure 152 ' 162 ' II (four) shadow processing removes the unexposed _ etc. The transparent layer w, 161 (22). The fine silver wire of the lower electrode formed after the development process (the conductive thin wire constituting the lower electrode) Μ The direction b2 of the conductive thin wire 21 is recognized: the direction d of the conductive thin wire 22 is recognized , dl : repeat distance (pitch) of the upper and lower electrode thin wires d2 : guide of the upper electrode D3 thin line regions arranged continuously: a lower region of the conductive thin wire electrode 56 is arranged continuously

Claims (1)

201234140 ίfVJyΔyLf VII. Patent Application Range: 1. A photosensitive material for manufacturing a conductive sheet, which is formed with a photosensitive layer containing a silver halide emulsion on both sides (front and back) of the transparent support, characterized in that the surface side is The photosensitive layer on at least one side of the photosensitive layer or the photosensitive layer on the back surface contains a mercapto compound. 2. The photosensitive material for manufacturing a conductive sheet according to claim 1, wherein the photosensitive layer of the photosensitive layer is closer to the side of the transparent support than the photosensitive layer of the photosensitive layer. The photosensitive layer contains more of the mercapto compound contained in the photosensitive layer. 3. The photosensitive material for producing a conductive sheet according to claim 1 or 2, wherein the photosensitive layer of the surface of the transparent support or the surface of the back surface does not contain the sulfhydryl group Compound. The conductive sheet according to Item 1 or 2 of the patent application of the Japanese Patent Application No. 2, wherein the photosensitive material of the back surface is compared with the amount of the sensitizing compound of the surface of the transparent pedestal body. The layer S has a greater amount of the sulfhydryl compound. 5. If the illuminating material is used in the patent application range, the espresso sheet I is formed in the same layer as _ _ _ _=, and the hetero compound is contained above, I5 mg or less. The silver 1 g (gram) is 0.1 mg to 6. The photosensitive material according to the patent application, wherein the conductive sheet formed in the second item is used to produce silver blood contained in the photosensitive layer. The volume ratio of the δ δ agent on both sides of the bright support is 1.0 or more. The photosensitive material for producing a conductive sheet according to Item 1 or 2, wherein the photosensitive layer on both sides of the transparent support is in the transparent support and each of the transparent supports An anti-halation layer is provided between the photosensitive layers. The conductive sheet is exposed to the image on both sides of the photosensitive material for manufacturing the conductive sheet according to the first or second aspect of the patent application. The development process is performed to form a surface transparent electrode including conductive thin wires for developing silver on both surfaces of the transparent support, and a back transparent electrode including the conductive thin wires of the developed silver. 9. The conductive sheet according to claim 8, which is formed by exposing and developing the conductive direction of the surface transparent electrode and the conduction direction of the back transparent electrode to be orthogonal to each other. . 10. The surface of the conductive sheet as described in claim 8 of the patent application, the reflection chromaticity V of the surface of the pole away from the transparent branch (4), and the side of the back, the side of the pole close to the transparent branch (4) The absolute value of the difference of the electric reflection chromaticity b2 is 2 or less (howling 11. - a capacitive type of difficult panel, the transparent conductive sheet of the 2nd item of the 2nd range. mi A.