201231266 六、發明說明： 【發明所屬之技術領域】 本發明係提供-種電容器結構及其製造方法，尤指主要 利用水性塗料合而為層狀之功能性薄膜，而不會污㈣境， 並具有耐化學性、耐刮雜、祕、耐料紐 抗菌性等優異的性能。 ”不 【先前技術】201231266 VI. Description of the Invention: [Technical Field] The present invention provides a capacitor structure and a method of manufacturing the same, and more particularly, a functional film which is mainly formed by using a water-based paint and is layered, without being contaminated. It has excellent properties such as chemical resistance, scratch resistance, secret resistance and antibacterial properties. "No [prior art]
按，現今印刷技術與應用領域遍及各個產業，除了應用 於紙張之外，更被敍翻在諸如筆記型電腦機殼、手機面 板、電路板、液晶面板、汽車儀表鱗各軸生活有關的產 品上’且被印物的材f包括有歸、紙、鐵、㈣、陶究、 紡織品、皮革等，並將__於其表面，俾能吸引消費者 的目光與購買慾，增進產品競爭力。 隨著社會的進步，消費者對於產品表面之圖案與質感要 求不斷提高，且因印刷技術與設備日新月異，促使印刷技術 從網印、移印、水轉印、熱轉印、雷射雕刻、—直到近年來 快速發展的模邮飾技術（IMD)，甚至有麵開發出結 合數位喷墨科技與移印技術的曲面影像轉印製成，可將圖案 直接轉寫至曲面_膠產品，具體而言，祕寫印刷係將圖 案、文字細容個浦印油墨騎於崎或轉寫膜等功能 性中間載體上，再經過相應的轉印設備在幾分鐘内加熱到一 定的溫度（通常為12〇。(：〜3Q(rc)後，把載體;;的圖 201231266 等轉移到不同材質上之製程，若以熱轉寫過程令功 王脫核熱轉料，而在啊加熱加m T程中，功紐體全部轉移娜卩物表面只剩下 土材是全脫模熱轉印之特點，使全脫模熱轉印方 rf與不同形體的被印物轉印，-般常見於熱轉寫： 处理係彻—具有職之熱轉印頭將帶有既定色彩、亮度 之金屬落(如電化峨或傳統之胸等)熱轉寫到:： 材或具有圖案之基板上。 _ 然而’ 一般射出成型可以完成之模型或基板之素材多為 塑膠材質，若是要在塑膠或其他不同材質與形體的被印物I 熱轉印金屬落通常會遇到金屬箱剥落的問題，因此，—般常 見的作法是在熱轉印好之金屬落圖案上，再上—、^， 漆與金屬私_合的力W與底材或 ，土板之結合力量時，金屬荡也將隨著保護漆的到捧、磨 損而脫落，造成金屬料耐磨損之問題，影響被印物熱 的品質且較不美觀’從而降低消費者再次購買的消費专願， 而無形之中商機上的損失更是難以估計，即為有待從雜此 行業者所亟欲研究改善之方向所在。 【發明内容】 故，發明人有鑑於制被印物熱轉印上之問題與缺失， 乃搜集相隱賴由多方的評估騎量，並_從事於此行 201231266 ==::::r與修改’―功能Press, today's printing technology and application fields cover all industries, in addition to paper, it is also described in products such as notebook computer cases, mobile phone panels, circuit boards, LCD panels, and automotive instrument scales. 'And the materials of the printed matter f include return, paper, iron, (four), ceramics, textiles, leather, etc., and __ on its surface, can attract consumers' attention and purchase desire, and enhance product competitiveness. With the advancement of society, consumers are constantly demanding the pattern and texture of the surface of the product, and because printing technology and equipment are changing with each passing day, the printing technology is promoted from screen printing, pad printing, water transfer printing, thermal transfer, laser engraving, Until recently, the rapid development of the Imprinting Technology (IMD), and even the development of a combination of digital inkjet technology and pad printing technology for the transfer of curved images, can be directly transferred to the surface of the plastic products, specifically In other words, the secret printing system uses a pattern of ink and ink to ride on a functional intermediate carrier such as a chip or a transfer film, and then heats it to a certain temperature (usually 12) in a few minutes through a corresponding transfer device. 〇. (:~3Q(rc), transfer the carrier;; Figure 201231266, etc. to the process of different materials, if the heat transfer process makes the power king denuclear heat transfer, and in the heating plus m In the middle, the whole body of the work is transferred to the surface of the material, and only the soil material is the feature of the full mold release thermal transfer, so that the full mold release heat transfer side rf and the different body of the printed matter are transferred, and are generally common in heat. Transfer: Handling the system - the thermal transfer head A metal drop (such as an electric enamel or a traditional chest) with a predetermined color and brightness is transferred to: a material or a patterned substrate. _ However, the material of the model or substrate that can be completed by general injection molding is mostly plastic. Material, if it is to be in the plastic or other different materials and shapes of the printed matter I thermal transfer metal falling will often encounter the problem of metal box peeling off, therefore, the common practice is on the heat transfer of the metal drop pattern , and then -, ^, lacquer and metal private _ combined force W and the substrate or the combination of soil, the metal sway will also fall off with the protective paint to wear, wear, resulting in metal wear resistance The problem affects the quality of the printed matter and is less aesthetically pleasing, thus reducing the consumer’s desire to purchase again. The invisible loss of business opportunities is even more difficult to estimate, that is, the desire of those who want to be from this industry. The reason for the research improvement is as follows. [Inventive content] Therefore, inventors have considered the problems and lack of thermal transfer on the printed matter, and collected the evaluation of the ride by many parties, and _ engaged in this line 201231266 == ::::r and modify ' -Features
本七明之主要目的乃在於基材表社利用特殊水性塗料 塗佈形成有水性離型層，並於水性離型層表面上為塗佈形成 有塗佈層，且塗佈層可依接著底材_的不同细接著劑塗 佈形成有接著層合而為層狀之功能性另，塗佈層上亦 可進一步形成有印獨，並於印獨上舰形成有金屬層， 也可在印卿與金屬層之_財倾層，雜功 主要細梅料所製成，而不會獅境，並具有耐化 子I·生耐到磨n、初性、耐紫外光性、耐揉擦、印刷性及抗 菌性等優異雜能，俾可確保舰性_成品製造的品質且 外觀更為精美。 【實施方式】 為達成上述目的及功效，本發明所採用之技術手段及盆 構造’崎_本發明之較佳實施_加·其概與功能 如下，俾利完全瞭解。 、明參閱第―、二、三、四圖所示，係分別為本發明之製 造流程圖、結構示意圖、較佳實施例之側視剖關及另一較 佳實施例之側視剖面圖’由財可清楚看出，本發明功能性 麵1為包括有基材1 1、水性離型層1 2、塗佈層1 3及 接者層1 4，當彻本發明功能性_之製造方法時，係依 照下列步驟實施處理： 201231266 (1 Ο 1)基材11表面上利用特殊水性塗料塗佈形成有水 性離型層12。 (1 0 2 )基材1 1之水性_層2 2表面上塗佈形成有塗 佈層1 3。 (1 〇 3 )基材i i之塗佈層！3表面上可依接著底材種類 的不同利用接著劑塗佈形成有接著層上4，便完 成本發明功能性薄膜之製造方法。 由上述之實施麵可清楚得知，上述之構件於製造時， 其實施步_先職材！丨表面上彻特殊水，睹料以旋轉 式、浸黏式、刮刀式、滾筒式、噴塗式或驗式等塗佈加工 Γ式塗佈形成有水性離型層12，而基材11可為聚乙烯 基酯薄膜（PET Flim，通稱為聚g旨薄膜） 旱又可為9/zm〜2〇〇_，使水性離型層丄2塗料乾 燥方式可騎溫、強魏燥或加熱方式，且水性離型層工2 (Wa t e r B a s e d)可利用特殊水 如水性樹脂7〇〜咖、溶㈣〜⑽及添二 〇 :二後調製而成’其中水性樹脂的固成分含量可為3 細爾，但於實際 兀τ為異丙醇、丙二醇單精p.M. 醇或乙二醇等所劁忐 r%乙 I成，用以產生共沸現象而縮 或改善塗膜之揮發性、w a 時間， 坦性、相雜姑料=桃現象，且紅二醇可増進平 及防/東雜能，並可依功能需求添加消泡劑、 201231266 、ι ^、乾燥劑、消光劑、硬化劑等各種促進劑， 至層12較佳實施可為水性聚碳酸樹脂（p c)、取、 酸乙酯（PU)、聚碳酸樹脂（p 錢基曱 PU)、㈣其㈣,“ L)+癌基甲酸乙酉旨（The main purpose of the present invention is that the substrate is coated with a special aqueous coating to form an aqueous release layer, and a coating layer is formed on the surface of the aqueous release layer for coating, and the coating layer can be followed by the substrate. The different fine adhesives of _ are coated to form a layered functional layer, and the coating layer can be further formed with a printed layer, and a metal layer is formed on the ship. With the metal layer of the phlegonic layer, the main work of the fine plum material, but not the lion environment, and has the resistance of I, raw resistance to grinding n, initial, UV resistance, scratch resistance, Excellent versatility such as printability and antibacterial properties, ensuring the quality of the ship's finished product and the appearance is more beautiful. [Embodiment] In order to achieve the above object and effect, the technical means and the pot structure used in the present invention are well-known and the functions are as follows, and the advantages are fully understood. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 2, and 3 are a side view of a manufacturing flow chart, a structural view, a side view of a preferred embodiment, and a side view of another preferred embodiment. It can be clearly seen from the financial situation that the functional surface 1 of the present invention comprises a substrate 11 , an aqueous release layer 1 2 , a coating layer 13 , and a carrier layer 14 . The treatment was carried out in accordance with the following procedure: 201231266 (1 Ο 1) The surface of the substrate 11 was coated with a water-based release layer 12 by a special aqueous coating. (1 0 2 ) The aqueous layer of the substrate 1 1 was coated with a coating layer 13 on the surface of the layer 2 2 . (1 〇 3) Coating layer of substrate i i! The method of manufacturing the functional film of the present invention can be completed by coating the surface layer 4 with an adhesive by a coating agent depending on the type of the substrate. It can be clearly seen from the above-mentioned implementation surface that the above-mentioned components are manufactured at the time of manufacture. The surface of the crucible is completely water-repellent, and the coating material is coated by a coating method such as a rotary type, a dip-coating type, a doctor blade type, a drum type, a spray type or a test type to form an aqueous release layer 12, and the substrate 11 may be Polyvinyl ester film (PET Flim, commonly known as polyg film) can be 9/zm~2〇〇_, so that the aqueous release layer coating can be heated in a warm, strong Wei or heating manner. And the water-based release layer 2 (Wa ter B ased) can use special water such as water-based resin 7〇~咖, dissolve (4)~(10) and add two 〇: after the second preparation of 'the aqueous resin can have a solid content of 3 Fine, but in actual 兀τ is isopropanol, propylene glycol mono-sperm pM alcohol or ethylene glycol, etc., used to produce azeotropic phenomenon to reduce or improve the volatility of the coating film, wa time , candid, mixed with the peach = peach phenomenon, and red glycol can be into the flat and anti-dong do not have energy, and can add defoaming agent according to functional requirements, 201231266, ι ^, desiccant, matting agent, hardener, etc. The various promoters, preferably to the layer 12, may be aqueous polycarbonate resin (pc), extract, ethyl acetate (PU), polycarbonate resin. p Yue Qian yl PU), (iv) (iv) that, "L) + acid yiyou purpose oncogene (
錢基酿曰（PU)+聚甲基丙物(PM β為壓克力樹脂）或聚甲基丙烯_旨（pmma)Qianji 曰 (PU) + polymethyl propyl (PM β is acrylic resin) or poly methacrylic _ (pmma)
1料添加聚四氟乙稀（PTFE，通稱為氟素或鐵氟龍） 硝化纖維素（NC)、聚：甲输（pDMs)、水簡 月曰或無機接枝物等，可增進耐刮磨性（耐磨、耐到損）= :叫、包等性能，且塗膜的彈性變化大、抗撓曲模數丄3 k g/c V以上’不但可高溫供乾也可在常溫下進行固 使其雜侧12_、_，綱料的耐化學 雜性症、良好的侧_，由於轉溶般水不再添加 其他的硬化劑’因此不含柯、苯等揮發性有機化合物有害 辦物質，無毒、無臭味、不燃性而不會㈣環境，並具有 壤保、不傷害人體·果，_加_產生化學反應使基材 11可易於脫離。 續以基材11之水性離朗12表面上騎佈形成有塗 佈層13，而塗佈層13可為水性樹脂添加有顏料、染料、 耐磨劑、硬化劑、奈米助劑、氧化銀、二氧化鈦等混合後調 製而成，用以增進塗佈層13不足的功能加強使用，以改善 視覺上的效果’且塗佈層i 3較佳實施可為水性聚碳酸樹脂 (PC)、聚胺基甲酸叫Pu)、聚碳酸樹脂（pc) 201231266 +永胺基曱酸乙酯（PU)、聚胺基曱酸乙酯（pu)+聚 甲基丙烯酸酯（PMMA)或聚曱基丙烯酸酯（pMMa) 材料添加奈米（1奈米=1n m)二氧化鈦（T i〇2)、 鈦（T i )、氧化鋅（z n〇）或銀（a g)等所製成，可 增進耐紫外光（U V)性、耐濕性、财燃性、耐刮磨性（耐 磨、耐刮損）、韌性、抗菌、金屬離子萃取功能。 而基材11之塗佈層13表面上可依接著底材（圖中未 不出）種類的不同利用水性熱塑性接著劑塗佈形成有接著層 14，其水性熱塑性接著劑可為尿素甲醛樹脂（UF — R e s i η)、紛甲酸樹脂（pf — Resin)、聚乙稀 醇縮丁駿（PVB)、聚甲基丙烯酸酯（PMMA)、熱塑 性聚胺基甲酸乙g旨（TPU)、環氧樹脂（EpQxy)、 聚乙烯醇（PVA)或醋酸乙烯（pVAC)等所製成，且 該底材可為聚苯乙烯（PS)、聚碳酸酯（pc)、熱塑性 聚胺基甲酸乙酯（TPU)、聚胺基甲酸乙醋（pu)、聚 氣乙烯（PVC)、聚丙烯（PP)薄膜或各種板材、木板 、人造皮革、天然皮革、玻璃、紙、布料、不織布等材質， 即可透過接著層1 4來作為功紐_1與底材之間的接著 劑’並可依溫度及壓力條件林_ ，軌絲材工丄 、水性離型層1 2、塗佈層1 3及接著層1 4依序合而為層 狀之功能性薄膜1，便完成本發明功能性_之製造方法， 且該功能性_為可應祕敎型電殼、手機面板、電 201231266 路板、液晶面板或汽車儀表板等各種與生活有關的產品上， 俾能吸引、;肖費者的目光與輕慾，增進產品之競爭力。 再者，上述之塗佈層13較佳實施例是以使用水性塗料 為例’但於實際應用時’則並非是以此作為傷限，塗佈層1 3亦可為溶劑型塗料添加染料（D y e )或顏料（ P i gm e n t)，並在塗佈層13與水性離型層12之間 可進-步設有油性離型層（圖中未示出），而具有基本的顏 色（如黃、紅、藍、綠等顏色），且該接著層i 4也可依接 著底材種類的不同_溶_接著劑〔如聚胺基f酸乙酯（ PU)、聚甲基丙烯酸g旨（pmma)、氯丁二烯橡膠（c R)或聚氣乙稀（pvc)〕塗佈於底材上，並可依接著時 底材種類的不同，部分底材必須先進行活性化處理，再將功 能性薄膜1施予燙印部分轉寫或全面轉寫、全面燙印至底材 (被印物）上，而於使用時，可利用轉印設備（圖中未示出 )加熱到一定的溫度將功能性薄膜2轉移至底材表面上，再 將基材1 1自功此性薄膜1上撕離後，便完成熱轉寫印刷程 序，藉此可將具有文字、圖案、數字、標記、符號等帶有既 定色彩、亮度之功能性薄膜1熱轉寫到底材上，惟該轉印設 備如何藉由熱壓機構以平燙（上下昇降式）或輥燙（壓輥滾 動式）等的燙印方式加熱、加壓及其溫度和壓力之控制係為 現有技術之範疇，且該細部構成並非本案發明要點，茲不再 作贅述。 201231266 本發明較佳實施例係將基材11 、水性離型層12、塗 佈層13及接著層14依序合而為層狀功能性薄膜i僅為一 種較佳之實施狀態，亦可依需求或設計的不同在塗佈層！3 與接著層1 4之間利用水性聚碳酸樹月旨（P C )、聚胺基曱 -曰（P U )、聚石反酸樹脂（p c) +聚胺基甲酸乙酉旨（ PU)、聚碳酸樹脂（Pc)+聚胺基曱酸乙酯或 聚甲基丙稀酸自旨（pMM A )材料添加奈米顏料、染料、水 性硝化纖維素(N C)、水性硬化劑、促進劑等以印刷加工 方式形成有印刷層15 (如第四圖所示），而印刷層丄5印 刷加工方式可為網版印刷、移轉印刷或轉寫印刷，並印刷於 塗佈層13上而具有文字、圖案、數字、標記等各種型態之 印紋’然’塗佈層丨3形成後便可具備有基本的顏色，但是 仍無法充分滿足使用者對於色光、純度、深淺度等的需求， 所以可透過印獨i 5添加、配製的奈米鱗、染料加深色 光或變淺’並具有鮮_色光、耐紫外光（uv)性可達到 6級以上，不㈣長細受到㈣光照射作訂所造成之變 暗或褪色之情況發生，_具備有良好的遮蓋力、耐候性、 耐溶劑性、耐雛等，而印刷層1 5也可糊多元醇或二液 型聚胺基甲酸乙醋（PU)添加促進劑形成有溶劑型印刷声 1 5，-般常__油墨依印度與效果可分為單液型 (分子量較大’可單獨使用）及二液型（分子量較小，需配 合異氰酸醋硬化劑混合使用），而在本發明較佳實施例是以 201231266 夕凡醇或二元醇基化合物與二異氰義、異氰化物反應製得 印刷油墨’且可透過奈米級尺寸滅形成化學鍵結以解決傳 ^上微相分離之問題，並提高奈米油墨的純度與密度，使功 能性薄膜1色彩展色性及耐到磨性、耐燃性更為良好。 月搭配參閱第五、六圖所示，係分別為本發明再一較佳 實知例之側視剖面圖及又—較佳實施例之側視剖面圖，由圖 中可q楚看出，本發明之功能性薄膜1係可依需求或設計的 不同予以增減層疊或設置數量’其魏性、賴丨層狀結構設 。十主要為依序將基材丄丄、水性離型層i 2、塗佈層丄3及 接著層1 4合而為層狀之功能性薄膜1，並於塗佈層丄3與 接著層14之間可形成有水性或溶劑型印刷層15，但於實 際應用時’亦可在印刷層1 5與接㈣1 4之間·真空鑛 膜或化學蒸鑛的方式將銘（A1)、銀（Ag)、硫化鋅（ z n S )或鈦（τ丨）等金屬材魏膜於其上形成有金屬層 16(如第五圖所示）’並可依需求或設計的不同製作蒸链 所需厚度’其金屬層；[6厚度較佳實施可為8从〜6 〇 〇 Α (簡稱埃，1Α= 1 cr1Qm=Q . 2 nm)，可增進金屬 光澤、色料紐及展色性，並具有高光澤度且色彩保持度 良好’俾使印刷層15色彩具有金屬感；再者，印刷層丄5 與金屬層16之間也可利用水性聚碳酸樹脂（P C)、聚胺 基甲酸6S|(PU)、聚胺基甲酸乙S旨（PU)+聚曱基丙 稀酸酯（PMMA)、聚甲基丙稀酸g旨（PMMA)材料添 201231266 加硬化劑後在溫度細1 3 (TC〜1 8 01：、加熱時間3 〇 秒（S'C .)〜1分鐘（min.)硬化後形成有保護層 17 (如第六圖所示），其硬化劑可為含有異氰輸旨基（― NCO)、_基（—Cqqh)之架橋劑，並與緩酸基（ -C00H)、胺基（_NH2)、祕（―〇h)以化學 鍵結方式反應職架橋後進行改性，可增進崎力、硬度、 韌性、耐揉擦（撓曲性）及耐刮磨性（耐磨、耐刮損）、耐 化學性（耐溶劑）、财水性等性能。 此外’以上所述僅為本發明較佳實施例而.已，非因此即 侷限本發明之專利翻’本發明最佳之—具體實施例為可包 括有基材1 1表面上水輯脂、溶·添加綱製成之 特殊水性塗料塗佈職有水性_層i 2，並於水性離型層 1 2表面上姻水性樹脂添加顏料、染料、耐磨劑、硬化劑 、奈米助劑、氧化銀、二氧化鈦等塗佈形成有塗佈層工3， 且塗佈層1 3表社侧湘水性無添加奈糊料、水性 石肖化纖維素、水性硬化劑、促進劑等以印刷加工方式形成有 印刷層15，其印刷層丄5表面上利用水性樹脂添加硬化劑 加熱硬化後形成有倾層！ 7，喻錄i 7表面上利用真 空鏡膜或化學驗的方式職、銀、硫倾紐等金屬材質 鑛膜於其上形成有金屬層i 6，再於金屬層i 6表面上可依 接者底材種_柯_水频贿接著雜佈形成有 層Η合而為層狀之魏性薄則，此種魏性薄膜丄主要 201231266 為利用水性塗料所製成，具有p71 material added polytetrafluoroethylene (PTFE, commonly known as fluorinated or Teflon) nitrocellulose (NC), poly: methyl transport (pDMs), water stagnation or inorganic grafts, etc., can improve scratch resistance Abrasive (wear resistance, damage resistance) = : call, bag and other properties, and the film has a large elastic change, anti-flexural modulus 丄 3 kg / c V or more 'not only high temperature dry or can be carried out at room temperature Solid-resistant side 12_, _, the chemical resistance of the material, good side _, because the water is no longer added to other hardeners due to the transfer of water, therefore does not contain volatile organic compounds such as ke, benzene, etc. It is non-toxic, odorless, non-flammable and does not (4) environment, and has soil protection, does not harm the human body and fruit, and produces a chemical reaction to make the substrate 11 easy to detach. The coating layer 13 is formed by riding on the surface of the substrate 11 and the coating layer 13 is added with a pigment, a dye, an anti-wear agent, a hardener, a nano-additive, and a silver oxide. Titanium dioxide and the like are mixed and prepared to enhance the function of the coating layer 13 to enhance the use of the coating layer 13 to improve the visual effect. The coating layer i 3 is preferably made of an aqueous polycarbonate resin (PC) or a polyamine. The carboxylic acid is called Pu), the polycarbonate resin (pc) 201231266 + the ethyl urethane (PU), the polyethyl phthalate (pu) + the polymethacrylate (PMMA) or the polydecyl acrylate. (pMMa) The material is made of nanometer (1 nm = 1 nm) titanium dioxide (T i〇2), titanium (T i ), zinc oxide (zn〇) or silver (ag) to enhance UV resistance. (UV), moisture resistance, flammability, scratch resistance (wear resistance, scratch resistance), toughness, antibacterial, metal ion extraction. The surface of the coating layer 13 of the substrate 11 may be coated with an aqueous thermoplastic adhesive to form an adhesive layer 14 according to the type of the substrate (not shown). The aqueous thermoplastic adhesive may be a urea formaldehyde resin ( UF — R esi η), benzoic acid resin (pf — Resin), polyvinyl condensate (PVB), polymethacrylate (PMMA), thermoplastic polyurethane urethane (TPU), epoxy Made of resin (EpQxy), polyvinyl alcohol (PVA) or vinyl acetate (pVAC), and the substrate may be polystyrene (PS), polycarbonate (pc), thermoplastic polyurethane ( TPU), polyethylene urethane (pu), polyethylene (PVC), polypropylene (PP) film or various plates, wood, artificial leather, natural leather, glass, paper, cloth, non-woven fabric, etc. Through the adhesive layer 14 as an adhesive between the work material_1 and the substrate, and can be used according to temperature and pressure conditions, the rail wire material, the aqueous release layer 1, the coating layer 13 and then The layer 14 is sequentially layered into the functional film 1 to complete the functional method of the present invention, and the method Functionality _ can be used in a variety of life-related products such as the secret shell, mobile phone panel, electric 201231266 road board, LCD panel or car dashboard, etc., can attract, and the eyes and light desires of Xiao Fei Product competitiveness. Furthermore, the preferred embodiment of the above-mentioned coating layer 13 is exemplified by the use of a water-based paint, but in practical use, it is not a limitation, and the coating layer 13 may also be a solvent-based paint. D ye ) or pigment (P i gm ent), and an oily release layer (not shown) may be further provided between the coating layer 13 and the aqueous release layer 12, and has a basic color ( Such as yellow, red, blue, green and other colors), and the adhesive layer i 4 can also be different depending on the type of substrate _ solvent_adhesive agent [such as polyamino-f-ethyl ester (PU), polymethacrylic acid g Pmma, chloroprene rubber (c R) or polyethylene oxide (pvc) are applied to the substrate, and some substrates must be activated first depending on the type of substrate. Then, the functional film 1 is applied to the hot stamping part for transfer or full transfer, and the hot stamping is performed on the substrate (printed matter), and in use, it can be heated by a transfer device (not shown). After the functional film 2 is transferred to the surface of the substrate at a certain temperature, and then the substrate 1 is peeled off from the film 1, the hot transfer printing process is completed. Therefore, the functional film 1 having a predetermined color and brightness, such as characters, patterns, numerals, marks, symbols, etc., can be thermally transferred to the substrate, but the transfer device can be flattened by a hot pressing mechanism (up and down The hot stamping method of the hot stamping method such as the lift type or the roll hot (rolling roll type) and the control of the temperature and pressure are in the prior art, and the detailed construction is not the main point of the invention, and will not be described again. 201231266 The preferred embodiment of the present invention is that the substrate 11, the aqueous release layer 12, the coating layer 13 and the adhesive layer 14 are sequentially combined into a layered functional film i, which is only a preferred embodiment, and may also be required. Or the design is different in the coating layer! 3 and the subsequent layer 14 using aqueous polycarbonate tree (PC), polyamine ruthenium-ruthenium (PU), poly stone acid-repellent resin (pc) + polyurethane (PU), polycarbonate Resin (Pc) + polyamino phthalic acid ethyl ester or polymethyl methacrylate acid (pMM A ) material is added with nano pigment, dye, aqueous nitrocellulose (NC), aqueous hardener, accelerator, etc. for printing The printing method is formed with a printing layer 15 (as shown in the fourth figure), and the printing layer 丄 5 printing processing method can be screen printing, transfer printing or transfer printing, and printed on the coating layer 13 with text, Patterns, numbers, marks, and other types of prints can be provided with a basic color, but still cannot fully satisfy the user's needs for color, purity, depth, etc. The nanoscales, dyes, darkening or lightening, which are added and prepared by Yinwu i5, have a fresh light color and ultraviolet light resistance (UV), which can reach grade 6 or above, and are not (four) long and thin (4) light irradiation. Causes darkening or fading, _ has good hiding power, weather resistance Solvent-resistant printing, sound-resistant, resistant to chicks, etc., and the printing layer 15 can also be paste polyol or two-liquid polyurethane urethane (PU) addition accelerator to form a solvent-based printing sound 1 5, - often __ ink According to India, the effect can be divided into single liquid type (larger molecular weight 'can be used alone) and two liquid type (small molecular weight, mixed with isocyanate sclerosing agent), and in the preferred embodiment of the present invention, 201231266 Xifan alcohol or glycol-based compound reacts with diisocyanide and isocyanide to obtain printing ink' and can form chemical bonds through nano-scale size to solve the problem of micro-phase separation and improve Nai The purity and density of the rice ink make the functional film 1 more excellent in color development, abrasion resistance and flame resistance. Referring to the fifth and sixth figures, respectively, a side cross-sectional view of a further preferred embodiment of the present invention and a side cross-sectional view of a preferred embodiment, which can be seen from the figure, The functional film 1 of the present invention can be added or removed according to the needs or design, and the number of layers or layers can be increased or decreased. The first is a functional film 1 in which the substrate crucible, the aqueous release layer i 2, the coating layer 3 and the subsequent layer 14 are combined to form a layer, and the coating layer 3 and the layer 14 are applied. An aqueous or solvent-based printing layer 15 may be formed between them, but in practical applications, it may also be between the printing layer 15 and the junction (four) 14 · vacuum ore film or chemical vaporization means Ming (A1), silver ( A metal film such as Ag), zinc sulfide (zn S) or titanium (τ丨) is formed with a metal layer 16 (as shown in the fifth figure), and can be made according to the needs or design of the steamed chain. Thickness 'its metal layer; [6 thickness can be preferably implemented from 8 to 6 〇〇Α (abbreviated as angstrom, 1 Α = 1 cr1Qm = Q. 2 nm), which can enhance metallic luster, color and color development, and It has high gloss and good color retention. The color of the printed layer 15 is metallic. Further, aqueous polycarbonate (PC) and polyurethane 6S can be used between the printed layer 5 and the metal layer 16. (PU), polyaminocarbamate (S) (PU) + polydecyl acrylate (PMMA), polymethyl acrylate acid (PMMA) material added 201231266 after hardening agent at a temperature of 1 3 (TC~1 8 01:, heating time 3 〇 seconds (S'C.)~1 minute (min.) After hardening, a protective layer 17 is formed (as shown in the sixth figure), and the hardener may contain isocyanide. Transfer agent (-NCO), _ base (-Cqqh) bridging agent, and react with the slow acid group (-C00H), amine group (_NH2), secret (―〇h) in a chemical bonding manner Sex, can improve the strength, hardness, toughness, scratch resistance (flexibility) and scratch resistance (wear resistance, scratch resistance), chemical resistance (solvent resistance), water and other properties. The present invention is only a preferred embodiment of the present invention. It is not intended to limit the invention to the present invention. The specific embodiment may include water-based grease, dissolution and addition on the surface of the substrate 1 1 . The special water-based paint is coated with water-based layer i 2, and the water-based resin on the surface of the aqueous release layer 12 is added with pigment, dye, anti-wear agent, hardener, nano-additive, silver oxide, titanium dioxide. The coating layer 3 is formed by coating, and the coating layer 1 3 side is water-free, no added naphthalate paste, water-based stone xiaohua cellulose, and water-based hardening. a printing layer 15 is formed by a printing process, and a printing layer 15 is formed on the surface of the printing layer 丄5 by a water-based resin-adding hardening agent to form a tilting layer. 7. A vacuum film or a chemical test is used on the surface of the image. The metal mineral film such as the job, silver, sulfur, etc. has a metal layer i6 formed thereon, and then the substrate of the metal layer i 6 can be connected to the substrate type _ _ _ water frequency bribe followed by the formation of miscellaneous cloth The layer is a thin layer of Wei, and the Wei film is mainly made of water-based paint with p7.
Phl值7〜9、固成份3 5% 〜4 0%、黏度2 5°C，c p s (mP Λ p bm P a . s ) < 2 〇 〇、 抗撓曲模數1〇〇kg/cm2以上 工抗拉強度1 〇 〇 k g /㈣2、伸長率1〇〇%以上之特性，由於稀釋溶劑是水 不含賢料揮發性有機化合物，無毒、無臭味、耐機性 而不會污染環境，並具有優異的耐化學性（咏容劑性）〔丁 酉同（MEK)擦拭（來回）i 〇次以上，甲苯（Phl value 7~9, solid content 3 5% ~ 40%, viscosity 2 5 ° C, cps (mP Λ p bm P a . s ) < 2 〇〇, flexural modulus 1〇〇kg/cm2 The above tensile strength is 1 〇〇kg / (4) 2, and the elongation is more than 1%. Since the dilution solvent is water, it does not contain volatile organic compounds, and is non-toxic, odorless, and resistant to environmental pollution. And has excellent chemical resistance (contaminant properties) [MEK) wiping (back and forth) i times more than toluene (toluene (
T〇 1 uene ) 20次以上〕、耐到磨性（表面硬度2b 以上，揉擦後更佳）、她（伸長率1() ◦灿上）、耐紫 外光（UV)性（5級以上）、耐揉擦（擦拭後無摺痕广、 印刷性（表面可再印刷）及抗菌性（添加奈米銀5〜2 〇 n m具有抗g的效果）能，俾能確保功能性薄則成品整 體的製造品質且外觀更為精絲，舉凡可達成前述效果之方 法、步驟、流程皆毅本發明所涵蓋，此_易料及等效 結構變化，均朗理包含於本發轉纖_，合予陳明。 綜上所述’本發明魏性_之製造方法為確實能達到 其功效及目的，故本發_為—實贿優異之發明，實符合 發明專利之申請要件，爰依法提出申請，盼審委早日_ ^案’以保障發明人之辛苦發明’倘*鈞局有任何稽疑， 請不吝來函指示，發明人定當竭力配合，實感公便。 13 201231266 【圖式簡單說明】 第一圖係為本發明之製造流程圖。 第二圖係為本發明之結構示意圖。 第三圖係為本發明較佳實施例之侧視剖面圖。 第四圖係為本發明另一較佳實施例之側視剖面圖 第五圖係為本發明再一較佳實施例之側視剖面圖 第六圖係為本發明又一較佳實施例之侧視剖面圖 ❿ 主要元件符號說明 功能性薄膜 水性離型層 1、基材 3、 塗佈層 4、 接著層 1 5、印刷層 1 6、金屬層 1 7、保護層 14T〇1 uene ) 20 times or more], abrasion resistance (surface hardness 2b or more, better after rubbing), her (elongation 1 () ◦ ) 、), UV resistance (UV) (5 or above ), resistant to rubbing (no crease after wiping, printability (surface reprintable) and antibacterial property (adding nano silver 5~2 〇nm has anti-g effect), can ensure functional thinness and finished product The overall manufacturing quality and the appearance are more delicate, and the methods, steps and processes that can achieve the aforementioned effects are all covered by the present invention, and the _ easy material and equivalent structural changes are included in the hair _ _ To Chen Ming. In summary, the manufacturing method of the invention is that it can achieve its efficacy and purpose, so the invention of the invention is in line with the application requirements of the invention patent, and the application is filed according to law. I hope that the trial committee will soon _ ^ case 'to protect the inventor's hard inventions'. If there is any doubt in the bureau, please do not hesitate to give instructions, the inventor will try his best to cooperate and feel punished. 13 201231266 [Simple diagram] A drawing is a manufacturing flow chart of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 3 is a side cross-sectional view of a preferred embodiment of the present invention. FIG. 4 is a side cross-sectional view of another preferred embodiment of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 6 is a side cross-sectional view showing still another preferred embodiment of the present invention. The main components are illustrative of a functional film aqueous release layer 1, a substrate 3, a coating layer 4, Next, the layer 15 , the printed layer 16 , the metal layer 17 , and the protective layer 14