M407829 I f 五、新型說明： 【新型所屬之技術領域】 本創作係提供一種功能性薄膜結構，尤指主要利用水性 塗料合而為層狀之功能性薄膜，而不會污染環境，並具有耐 化學性、耐刮磨性、韌性、耐紫外光性、耐揉擦及抗菌性等 優異的性能。 【先前技術】 按，現今印刷技術與應用領域遍及各個產業，除了應用 於紙張之外，更被廣泛應用在諸如筆記型電職殼、手機面 T、電路板、液晶面板、汽車儀表板等各種與生活有關的產 品上’且被印物的材質包括有塑膠、紙、鐵、玻璃、陶究、 紡織品、皮革等，並將圖案印刷於其表面，俾能吸引消費者 的目光與購買慾，增進產品競爭力。 、隨著社會的進步，消#者對於產品表面之圖案與質感要 求不斷提高，娜卩刷技術與設備日新月，異，促使印刷技術 從網印、移印、水轉印、熱轉印、雷射雕刻、一直到近年來 快逮發展的模内裝飾技術（iMD)，甚至有廢商開發出結 合數位喷墨科技與移印技術的曲面影像轉印製成，可將圖案 2接轉寫至曲面的塑膠產品，具體而言，熱轉寫印刷係將圖 =2細容使賴轉㈣墨脚於紙張鱗寫膜等功能 間载體上’再經過相應的轉印設備在幾分鐘内加敎到一 疋的溫度（通常為12(rc〜3 0 0。〇後，把载體上的圖 3 f、文字雜移到抑材質上之製程，若以熱轉寫過程中功 能性中間载難作方式和轉印後基底層脫離與否可分為模内 ί7厂、升華轉印、全脫模熱轉印等，而在同時加熱加愿的 轉Ρ製私中’功月匕財間載體全部轉移至被印物絲只剩下 基材是全賴_印之_，使全賴熱神方式能適應多 種材質與不同的被印㈣印，—財見於_寫、爱印 處理’係具有圖案之熱轉印頭將帶有既定色彩、亮度 之金屬V自（如電化銘鍍膜或傳統之烫金箱等）熱轉寫到一底 材或具有圖案之基板上。 然而，一般射出成型可以完成之模型或基板之素材多為 塑膠材質，若是要在瓣或其他不同材質與形體的被印物上 熱轉印金屬箔通常會遇到金屬落剝落的問題，因此，一般常 見的作法是在熱料好之金屬_案上，再上-層保護漆， 但是當保護漆與金屬落之間結合的力量大於金屬箱與底材或 塑膠基板之結合力量時，金屬箱也將隨著保護漆的刮擦、磨 損而脫落’造成金屬落不耐磨損之問題’影響被印物熱轉印 的品質且較不美觀’從轉低雜者再次顧㈣費意願， 而無形之中商機上的損失更是難以估計，即為有待從事於此 行業者所亟欲研究改善之方向所在。 【新型内容】 故’創作人有鑑於習用被印物熱轉印上之問題與缺失， 乃搜集侧資料經由多方的評估及考量，並從事於此行 M407829 業之多年研發經驗經由不斷試作與修改，始設計出此種功能 性薄膜結構的新型誕生。 本創作之主要目的乃在於基材表面上利用特殊水性塗料 塗佈形成有水性翻層，並於水性_層表面上為塗佈形成 有塗佈層’且塗佈層可依接著底材麵的不同利用接著劑塗 - 騎成有接著層合而為層狀之功能性薄膜；另，塗佈層上亦 - 可進—步形成有印刷層，並於印刷層上鐘膜形成有金屬層， • 也可在印刷層與金屬層之間形成有保護層，此種功能性薄膜 主要為利用雜塗料職成，科會污練境，並具有耐化 學性、耐刮磨性、章刀性、耐紫外光性、耐揉擦、印刷性及抗 菌性等優異的性能，俾可確保功能性薄膜成品製造的品質且 外觀更為精美。 、 【實施方式】 ' $達紅述目的及構造’摘伽_之技術手段及其 射，㈣®就本創作之較佳實施解加制其構造與功能 如下，俾利完全瞭解。 立請參閱第一、二、三圖所示，係分別為本創作之結構示 。圖W土實施例之側視剖面圖及另一較佳實施例之側視剖 面圖，由财可清楚看出，本創作功能為包括有基 材11、水性離型層12、塗佈層13及接著層14，其中 基材1 1表面上為细特殊水性塗料塗佈形成有水性離型層 12 ’並於水性離型層12表面上塗佈形成有塗佈層工3 7 5 且塗佈層13表面上則可依接著底材（圖中未示出）種類的 不同利用水性熱塑性接著劑塗佈職有接著層丨^依序合而 為層狀之功能性薄膜x。 口 而上述之基材11可為聚乙烯基對苯二曱g旨薄膜（ΡΕ 丁 F 1 1m，通稱為聚酯薄膜）、厚度可為9以❿〜2 〇 〇 ，且水性離型層2 (Wa t e r b a s e d )可 利用特殊水性塗料所製成，如水性樹脂7 〇〜8 〇%、溶劑 2 0〜15%及添加劑1〇〜5%混合後調製而成，其中水 性樹脂的固成分含量可為3Ό〜4 5%，而溶劑最佳之一具 體實施例可為水，但於實際應用時，亦可為異丙醇、丙二醇 早甲ϋΡ·Μ.、甲醇、乙醇或乙二醇等所製成，用以產生 共滞現象而肺__，姐善塗叙揮發性、防止表乾 現象，且該乙二醇可增進平坦性、相_及时等性能，並 可依功能需求添加消泡劑、平滑劑、乾燥劑、消光劑、硬化 劑等各種促進劑’ ^水性離型層丨2較佳實施可為水性聚碳 酉文樹脂（P C )、聚絲甲酸乙g旨（p u )、聚碳酸樹脂（ pc)+聚胺基甲酸乙醋（pu)、聚胺基甲酸乙醋（m )+聚甲基丙稀酸酉旨（PMMA ’通稱為壓克力樹脂）或聚 甲基丙烯iiJ曰（P MM A )材料添加聚四氟乙烯（p 丁 f e ，通稱為氟素或鐵氟龍）、硝化纖維素（Ν〇)、聚二甲基 氧燒（P DMS )、水性樹脂或無機接枝物等，可增進耐到 磨性（耐磨、耐刮損）、平滑性及消泡等性能，且塗膜的彈 性變化大、抗撓曲魏i 3 Q k g / G m2以上，使其水性 離型層1 2堅硬、耐磨’並具有優異的耐化學輕性能、良 好的耐溶雜等，由於稀釋溶縦水不再添加其他的硬化劑 因此不含曱路、苯等揮發性有機化合物有害化學物質，無 督、無臭味、稍性响會污染魏，並具有環保、不傷害 人體的效果，㈣加熱時產生化學反應使基材i Μ易於脫 離。 此外’塗佈層13可為水性樹脂添加有顏料、染料、耐 磨劑、硬化劑、奈米助劑、氧化銀、二氧化鈦等混合後調製 而成’用以增進塗佈層1 3从的功能加強使用，以改善視 覺上的效果，且塗佈層i 3較佳實施水性聚碳酸樹脂（p C )、聚胺基甲酸乙酯（PU)、聚碳酸樹脂（pc) +聚胺 基甲酸乙g旨（PU)、聚胺基甲酸乙g旨（PU)+聚甲基丙 烯酸酯（PMMA)或聚甲基丙烯酸酯（PMMA)材料添 加奈米（1奈米==1 n m)二氧化鈦（τ i〇2)、鈦（τ 1 )、氧化鋅（Ζ η〇）或銀（a g)等所製成，可增進耐 糸外光（U V)性、耐濕性、耐燃性、耐到磨性（耐磨、耐 刮損）、韌性、抗菌、金屬離子萃取功能。 另，接著層14之水性熱塑性接著劑可為尿素甲醛樹脂 (UF —Re s i η)、酚甲醛樹脂（PF —Re s 土 n) 、聚乙烯醇縮丁醛（PVB)、聚甲基丙烯酸酯（pMMA )、熱塑性聚胺基甲酸乙酯（TPU)、環氧樹脂（ EP〇Xy) '聚乙婦醇（PVA)或醋酸乙烯（PVAC )等所製成’且該底材可為聚苯乙稀（P S)、聚碳酸醋（ PC)、熱紐聚絲甲酸⑽（τρυ)、聚胺基甲酸乙 酉曰（PU)、聚氯乙烯（PVC)、聚丙烯（ρρ)薄膜或 各種板材、木板、人造皮革、天然皮革、玻璃、紙、布料、 不織布等㈣，即可魏接著層1 4來作為功能性薄膜工與 底材之間的接著劑’並可依溫度及壓力條件有不同的選擇， 藉此將基材1 1、水性離型層i 2、塗佈層i 3及接著層丄 4依序合而為層狀之功能性薄膜1，且該功能性薄膜為可應 用於筆記型電腦機殼、手機面板、電路板、液晶面板或汽車 儀表板等各種與生活有_產品上，俾能吸·費者的目光 與購買慾’增進產品之競爭力。 再者，上述之塗佈層13較佳實施例是以使用水性塗料 為例，但於實際應用時，則並非是以此作為侷限，塗佈層工 3亦可為溶劑型塗料添加染料（Dy e )或顏料（M407829 I f V. New description: [New technical field] This creation provides a functional film structure, especially a functional film which is mainly composed of water-based paint and is layered, without polluting the environment and having resistance. Excellent properties such as chemical resistance, scratch resistance, toughness, UV resistance, scratch resistance and antibacterial properties. [Prior Art] Press, today's printing technology and application fields cover all industries, besides being applied to paper, it is widely used in various types such as notebook electric notebooks, mobile phone T, circuit boards, LCD panels, car dashboards, etc. On the products related to life, and the materials of the printed materials include plastic, paper, iron, glass, ceramics, textiles, leather, etc., and the patterns are printed on the surface, which can attract consumers' eyes and purchase desires. Improve product competitiveness. With the progress of the society, the consumer's requirements for the pattern and texture of the product surface are constantly improving. The technology and equipment of Nayong brush are different from each other, which promotes the printing technology from screen printing, pad printing, water transfer printing and thermal transfer. Laser engraving, in-mold decoration technology (iMD), which has been developed in recent years, and even the development of a curved image transfer combined with digital inkjet technology and pad printing technology, can be used to transfer pattern 2 Write to the surface of the plastic product, specifically, the thermal transfer printing system will map = 2 to make the reliance (four) ink foot on the paper scale writing film and other functional inter-carriers 'and then through the corresponding transfer equipment in a few minutes Adding a temperature to the inside (usually 12 (rc~3 0 0. After that, the carrier on the carrier, Figure 3 f, the word is moved to the process of the material, if the middle of the functional process in the heat transfer process The difficult-to-work mode and the detachment of the base layer after transfer can be divided into the mold ί7 factory, sublimation transfer, full mold release thermal transfer, etc., while at the same time heating and wishing for the transfer of the private system The transfer of all the carriers to the substrate is only the basis of the _ _ _ _ Can adapt to a variety of materials and different printed (four) printing, - see the _ write, love printing process 'system with a pattern of thermal transfer head will have a given color, brightness of the metal V (such as odification or traditional bronzing The box is heat transferred to a substrate or a patterned substrate. However, the material of the model or substrate that can be completed by injection molding is mostly made of plastic material, if it is to be on the flap or other printed materials of different materials and shapes. Thermal transfer metal foil usually encounters the problem of metal falling off. Therefore, it is common practice to apply a protective coating on the metal with good heat, but when the protective paint is combined with the metal. When the strength is greater than the combined strength of the metal box and the substrate or the plastic substrate, the metal box will also fall off along with the scratch and abrasion of the protective paint, causing the problem that the metal is not resistant to abrasion, which affects the quality of the thermal transfer of the printed matter. And it is less beautiful. 'From the low-income people, once again, (4) the willingness to pay, and the loss in the invisible business opportunity is even more difficult to estimate, that is, the direction for those who want to work in this industry is to study and improve. Therefore, the authors have the problems and shortcomings in the use of the thermal transfer of the printed matter. The collection of data has been evaluated and considered by many parties, and the years of research and development experience of the M407829 industry has been continuously tested and revised. A new type of functional film structure was designed. The main purpose of this work is to form a water-repellent layer by coating with a special water-based paint on the surface of the substrate, and coating a coating layer on the surface of the water-based layer. 'And the coating layer can be coated with an adhesive according to the difference of the substrate surface - riding a functional film which is layered after lamination; in addition, the coating layer can also be formed with a printing layer. A metal layer is formed on the film on the printed layer. • A protective layer can also be formed between the printed layer and the metal layer. This functional film is mainly used for the use of miscellaneous coatings, which can be soiled and resistant. Excellent properties such as chemical, scratch-resistant, knife-knife, UV-resistant, scratch-resistant, printable, and antibacterial, ensuring the quality of functional film products and the appearance. [Embodiment] '$Achieve the purpose and structure of the red-characteristics' and the technical means and the shooting, (4)® Adding the structure and function of the preferred implementation of the creation as follows, the profit is fully understood. Please refer to the first, second and third figures for the structure of the creation. A side cross-sectional view of the embodiment of the present invention and a side cross-sectional view of another preferred embodiment are clearly seen from the financial value, and the present functional function includes a substrate 11, an aqueous release layer 12, and a coating layer 13. And a layer 14 on which the surface of the substrate 11 is coated with a fine release coating 12' and a coating layer formed on the surface of the aqueous release layer 12 and coated. On the surface of the layer 13, a functional film x which is layered in the form of an adhesive layer can be applied by means of an aqueous thermoplastic adhesive, depending on the type of the substrate (not shown). The substrate 11 described above may be a polyethylene terephthalate film (a styrene F 1 1m, generally referred to as a polyester film), a thickness of 9 ❿ 2 2 〇〇, and an aqueous release layer 2 (Wa terbased) can be made by using special water-based paints, such as 7 〇~8 〇% of water-based resin, 20~15% of solvent and 1〇~5% of additives. The solid content of water-based resin can be It is 3Ό~4 5%, and one of the best solvents may be water, but in practical applications, it may be isopropanol, propylene glycol, early methyl hydrazine, hydrazine, methanol, ethanol or ethylene glycol. Made to produce a phenomenon of co-stagnation and lung __, sister good to describe volatility, prevent surface dryness, and the ethylene glycol can improve flatness, phase _ timely performance, and can add defoaming according to functional requirements Various accelerators such as a agent, a smoothing agent, a desiccant, a matting agent, and a hardener. ^ The aqueous release layer 2 is preferably a water-based polycarbophoric resin (PC) or a polymethyl-formate (u). Polycarbonate (pc) + urethane (pu), polyurethane (m) + polymethyl acrylate PMMA 'commonly known as acrylic resin) or polymethacryl iiJ曰 (P MM A ) material added with polytetrafluoroethylene (p butyl, commonly known as fluorin or Teflon), nitrocellulose (Ν〇), Polydimethyloxygen (P DMS), water-based resin or inorganic graft, etc., can improve the wear resistance (wear resistance, scratch resistance), smoothness and defoaming properties, and the elasticity of the coating film changes greatly. It is resistant to flexing Wei i 3 Q kg / G m2 or more, making its aqueous release layer 12 hard and wear-resistant and has excellent chemical and light resistance, good resistance to miscibility, etc. Other hardeners are therefore free of harmful chemicals such as slag, benzene and other volatile organic compounds. No supervision, no odor, slight noise will pollute Wei, and it has environmental protection and does not harm the human body. (4) Chemical reaction when heating The substrate i Μ is easily detached. In addition, the coating layer 13 may be prepared by mixing a water-based resin with a pigment, a dye, an anti-wear agent, a hardener, a nano-additive, a silver oxide, a titanium oxide, etc. to enhance the function of the coating layer 13 . Strengthening the use to improve the visual effect, and the coating layer i 3 is preferably implemented with an aqueous polycarbonate resin (p C ), a polyurethane (PU), a polycarbonate resin (pc) + a polyurethane g (PU), polyurethane urethane (PM) + polymethacrylate (PMMA) or polymethacrylate (PMMA) material added with nanometer (1 nm = 1 nm) titanium dioxide (τ Made of i〇2), titanium (τ 1 ), zinc oxide (Ζη〇) or silver (ag), which can improve the resistance to external light (UV), moisture, flame and abrasion. (Abrasion resistance, scratch resistance), toughness, antibacterial, metal ion extraction. In addition, the aqueous thermoplastic adhesive of the subsequent layer 14 may be urea formaldehyde resin (UF-Resi η), phenol formaldehyde resin (PF-Res soil n), polyvinyl butyral (PVB), polymethacrylate. (pMMA), thermoplastic polyurethane (TPU), epoxy resin (EP〇Xy) 'polyethylene glycol (PVA) or vinyl acetate (PVAC), etc. and the substrate can be polystyrene Ethylene (PS), polycarbonate (PC), heat-growth formic acid (10) (τρυ), polyurethane urethane (PU), polyvinyl chloride (PVC), polypropylene (ρρ) film or various plates, Wood, artificial leather, natural leather, glass, paper, cloth, non-woven fabric, etc. (4), the Wei can be used as an adhesive between the functional film and the substrate, and can be different depending on temperature and pressure conditions. Alternatively, the substrate 1 1 , the aqueous release layer i 2 , the coating layer i 3 and the subsequent layer 丄 4 are sequentially combined to form a layered functional film 1 , and the functional film is applicable to notes Computer case, mobile phone panel, circuit board, LCD panel or car dashboard, etc. Fischer's gaze and desire to purchase 'to enhance the competitiveness of products. Furthermore, the preferred embodiment of the coating layer 13 described above is exemplified by the use of a water-based paint, but in practice, it is not limited thereto, and the coating layer 3 may also add a dye to a solvent-based paint (Dy e) or pigment (
Pigment)，並在塗佈層13與水性離型層12之間 可進-步設有油性離型層（圖中未示出），而具有基本的顏 色（如黃、紅、藍、綠等顏色），且該接著層i 4也可依接 著底材種類的不同利用溶劑型接著劑〔如聚胺基甲酸乙酯（ PU)、聚曱基丙烯酸酯（pmmA)、氣丁二浠橡膠（c R)或聚氣乙稀（P V C)〕塗佈於底材上，並可依接著時 底材種類的不同，部分底材必須先進行活性化處理，再將功 能性薄膜1施予燙印部分轉寫或全面轉寫、全面燙印至底材 (被印物）上，而於使用時，可利用轉印設備（圖中未示出 )加熱到一定的溫度將功能性薄膜i轉移至底材表面上，再 將基材1 1自功能性薄膜i上撕離後，便完成熱轉寫印刷程 序，藉此可將具有文字、圖案、數字、標記、符號等帶有既 定色彩、亮度之功能性薄膜丄熱轉寫到底材上，惟該轉印設 備如何藉由熱壓機構以平燙（上下昇降式）或輥燙（壓輥滾 動式）等的、料方式加熱、加壓及其溫度和壓力之控制係為 見有技術之範舜，且該細部構成並非本案創作要點，兹不再 作贅述。 本創作較佳實施例係將基材i i、水性離型層i 2、塗 佈層13及接著層14依序合而為層狀功能性薄膜1僅為一 種較佳之實施狀態，亦可依f求或設計的不同在塗佈層丄3 與接著層1 4之間_水性聚碳酸樹脂（P C )、聚胺基甲 酉夂乙酉曰（PU)、聚魏樹脂（pc) +聚胺基甲酸乙醋（ P u)、聚碳酸樹脂（P C) +聚胺基甲酸乙g旨（p u)或 聚甲基丙旨（PMMA)材料添加奈米顏料、染料、水 !·生硝化纖維素（N c )、水性硬化劑、促進劑等以印刷加工 方式形成有印刷層15 (如第四圖所示），而印刷層15印 、 方式可為網版印刷、移轉印刷或轉寫印刷，並印刷於 佈㈢13上而具有文字、圖案、數字、標記等各種型態之 P紋’然’塗佈層i 3形成後便可具備有基本的顏色，但是 财07829 仍無法充分滿足使用者對於色光、純度、深淺度等的需求， 所以可透過印刷層15添加、配製的奈米顏料、染料加深色 光或變淺，並具有鮮艷的色光、耐紫外光（Uv)性可達到 6級以上，不易因長期間受到紫外光照射作用下所造成之變 暗或腿色之情況發生’同時具備有良好的遮蓋力、耐候性、 而才溶wU生、耐燃性等，而印刷層1 5也可利用多元醇或二液 型聚絲憎⑽（PU)添加促進細彡成有溶_印刷層 15，而在本創作較佳實施例是以多元醇或二元醇基化合物 與二異氰酸鹽、異氰化物反應製得印刷油墨，且可透過奈米 級尺寸顏料形成化學鍵結，以解決傳統上微相分離之問題， 並提高奈米油·純度與密度，使功能性薄則色彩展色性 及耐刮磨性、耐燃性更為良好。 祕配參閱第四、五圖所示，係分別為本創作再一細 實施例之側視剖面駭又—較佳實施例之侧視剖面圖，由廣 1月疋看出本創作之功能簡膜〗係可依需求或設計的 ㈣予以增減層疊或設置數量，其功能性薄町層狀結構設 拉要為依序將基材丨i、水⑽縣1 2、塗佈層及 接㈣14合而為層狀之功能性薄則，並於塗佈層^與 二4:間可形成有水性或溶劑型印刷層1 5，但於實 ==:__15嶋層14彻用真空鑛 :_方式將銘(A"、銀(Ag)、硫化辞( :欽（Τ 1 )等金屬材質賴於其上形成有金屬層 10 16 (如第四圖所示），並可依需求或設計的不同製作蒸鍍 所需厚度’其金屬層16厚度較佳實施可為8 0A〜6 〇 〇 A (簡稱埃，1A= 1 CT10m=〇 . 1 nm)，可增進金屬 光澤、色彩鮮艷性及展色性，並具有高光澤度且色彩保持度 良好，俾使印刷層15色彩具有金屬感；再者，印刷層工5 與金屬層16之間也可利用水性聚碳酸樹脂（p c)、聚胺 基甲酸乙自旨（PU)、聚胺基甲酸乙g旨（pU)+聚甲基丙 烯酸酉旨（PMMA)、聚甲基丙烯酸g旨（PMMA)#料添 加硬化劑後在溫度範圍1 3 (TC〜1 8 Ot、加熱時間3 〇 秒（s e c .)〜！分鐘（m 土 n ·)硬化後形成有保護層 17 (如第五圖所示），其硬化劑可為含有異氰酸酯基 N C〇）、缓酸基（—c 〇◦H)之架橋劑，並與缓酸基（ —COOH)、胺基（-ΝΗ2)、經基（―〇Η)以化學 鍵結方式反應形成架橋後進行改性，可增進附著力、硬度、 勤性、耐揉擦（撓曲性）及耐刮磨性（耐磨、耐到損）、耐 化學性（耐溶劑）、耐水性等性能。 此外’以上所述僅為本創作較佳實施例而已，非因此即 侷限本創作之專利細，本創作最佳之—频實施例為可包 括有基材11、水性離型層！2、塗佈層丄3、印刷層工5 、保護層17、金屬層16及接著層i 4合而為層狀之功能 性薄膜1 ’此種功能性薄膜h要為利用水性塗料所製成， 具有pH值7〜9、固成份35%〜4Q%、黏度25。〇， M407829 cps (mPa . S) <2 0 0、抗撓曲模數1()〇kg/ c m以上、抗拉強度iQQkg / cm2、伸長率i 〇 〇 % 以上之特性，由於稀釋溶劑是水不含甲醛、苯等揮發性有機 化合物，無毒、無臭味、耐燃性而不會污染環境，並具有優 異的耐化學性（耐溶劑性）〔丁酮（MEK)擦拭（來回） 10次以上，甲苯（T〇1uene)2〇次以上〕、耐刮 磨性（表面硬度2B以上，揉擦後更佳）、(伸長率工 00%以上）、耐紫外光（uv)性（5級以上）、耐揉擦 (擦拭後無摺痕）、_性（表面可再印刷）及抗菌性（添 加不米銀5〜2 0 nm具有抗菌的效果）等性能，俾能讀保 功能性_i成品整體的製造品質且外觀更為精美者。 上述詳細說明為針對本紺乍一種較佳之可行實施例說明 而已’ _實_並_罐定本_帽糊範圍，舉凡 其它未脫穌__权簡婦下所完成之均等變化與 修倚變更，均應包含於本創作所涵蓋專機圍中。 =上所述，本_功紐_之製造綠為確實能達到 ”功效及目的，故本創作誠為—實用性優異之創作，實符合 新型專利之申請要件，轰° 魏枝出申4，盼審委早日賜准 ^二保障創作人之辛苦創作，絲釣局有任何稽疑， 來函細，創作人定相力配合，實感公便。 12 M407829 【圖式簡單說明】 第一圖係為本創作之結構示意圖。 第二圖係為本創作較佳實施例之側視剖面圖。 第三圖係為本創作另一較佳實施例之側視剖面圖。 第四圖係為本創作再一較佳實施例之側視剖面圖。 第五圖係為本創作又一較佳實施例之側視剖面圖。 【主要元件符號說明】 1、功能性薄膜 1 1、基材 1 5、印刷層 1 2、水性離型層 1 6、金屬層 1 3、塗佈層 1 7、保護層 1 4、接著層 13Pigment), and between the coating layer 13 and the aqueous release layer 12, an oily release layer (not shown) may be further provided, and has a basic color (such as yellow, red, blue, green, etc.). Color), and the adhesive layer i 4 can also utilize solvent-based adhesives (such as polyurethane, PUMM, styrene butadiene rubber) depending on the type of substrate. c R) or polyethylene oxide (PVC) is applied to the substrate, and depending on the type of substrate, the substrate must be activated first, and then the functional film 1 is stamped. Partial transfer or full transfer, full hot stamping onto the substrate (printed matter), and in use, can be transferred to a certain temperature by transfer device (not shown) to transfer the functional film i to On the surface of the substrate, after the substrate 11 is peeled off from the functional film i, the thermal transfer printing process is completed, thereby having characters, patterns, numerals, marks, symbols, etc. with a predetermined color and brightness. The functional film is transferred to the substrate by heat, but the transfer device is flattened by a hot pressing mechanism (on The heating, pressurization and temperature and pressure control of the material type, such as lifting type or roll hot (rolling roll type), are the technical specifications, and the detailed composition is not the main point of the case. Narration. The preferred embodiment of the present invention is that the substrate ii, the aqueous release layer i 2, the coating layer 13 and the adhesive layer 14 are sequentially combined into a layered functional film 1 as a preferred embodiment, and may also be The difference in design or design is between the coating layer 丄3 and the adhesion layer 14_aqueous polycarbonate resin (PC), polyaminomethazine (PU), polywei resin (pc) + polyaminocarboxylic acid Ethyl vinegar (P u), polycarbonate resin (PC) + polyglycolic acid (g) or polymethyl methacrylate (PMMA) material added with nano pigments, dyes, water! · Raw nitrocellulose (N c), an aqueous hardener, an accelerator, etc. are formed by a printing process with a printing layer 15 (as shown in the fourth figure), and the printing layer 15 may be printed, transferred, or transferred, and It can be printed on the cloth (3) 13 and has various patterns of characters, patterns, numbers, marks, etc., and the P-color coating layer i 3 can be formed with basic colors, but the money 07829 still cannot fully satisfy the user's color light. The purity, the depth, and the like, so that the nano pigment and dye added and prepared through the printing layer 15 can be added. The color light or lightening, and the bright color and ultraviolet light (Uv) resistance can reach 6 or above, and it is not easy to be darkened or leg color caused by ultraviolet light for a long period of time. The hiding power, the weather resistance, the dissolving wU, the flame resistance, etc., and the printing layer 15 can also be used to promote the fine-grained printing layer 15 by using a polyol or a two-liquid type polyfilament (10) (PU). In the preferred embodiment of the present invention, a printing ink is prepared by reacting a polyol or a glycol compound with diisocyanate or isocyanide, and a chemical bond can be formed through a nano-sized pigment to solve the conventional problem. The problem of microphase separation, and the improvement of the purity and density of the nano-oil, the thinness of the color, the color development, the scratch resistance and the flame resistance are better. The secret configuration is shown in the fourth and fifth figures, which are respectively a side view of a further embodiment of the creation, and a side cross-sectional view of the preferred embodiment. The function of the creation is shown by the wide January. Membrane can be added or reduced according to the needs or design (4) to increase or decrease the number of layers or sets. The functional thin layer layer structure should be set to sequentially order the substrate 丨i, water (10) county 1, 2 coating layer and connection (four) 14 The layered functionality is thin, and an aqueous or solvent-based printing layer 15 can be formed between the coating layer and the second layer: but the vacuum layer is used in the layer ==:__15 layer 14: The method will be based on the metal material such as A", silver (Ag), and vulcanization (: Qin (Τ 1)), which has a metal layer 10 16 formed thereon (as shown in the fourth figure), and can be designed or designed according to requirements or design. The thickness required for different evaporation processes is preferably such that the thickness of the metal layer 16 can be 80A~6 〇〇A (abbreviated as angstrom, 1A=1 CT10m=〇.1 nm), which can enhance the metallic luster, color and exhibition. Color, high gloss and good color retention, so that the color of the printed layer 15 has a metallic feel; in addition, water can be used between the print layer 5 and the metal layer 16 Polycarbonate (pc), polyurethane urethane (PU), polyurethane (gU) + polymethacrylic acid (PMMA), polymethacrylic acid g (PMMA) #料After the addition of the hardener, a protective layer 17 is formed in a temperature range of 13 (TC~1 8 Ot, heating time 3 sec (sec.) ~! minutes (m soil n ·)) (as shown in the fifth figure), The hardener may be a bridging agent containing an isocyanate group NC〇), a slow acid group (—c 〇◦H), and a slow acid group (—COOH), an amine group (—ΝΗ 2), a warp group (—〇Η) Modification by chemical bonding to form bridging, which can improve adhesion, hardness, workability, scratch resistance (flexibility) and scratch resistance (wear resistance, damage resistance), chemical resistance (solvent resistance) In addition, the above description is only a preferred embodiment of the present invention, and thus the patent of the present invention is not limited thereto. The best embodiment of the present invention may include a substrate 11 and water-based. The release layer! 2, the coating layer 丄 3, the printing layer 5, the protective layer 17, the metal layer 16 and the subsequent layer i 4 are combined into a layered functional film 1 ' The functional film h is made of water-based paint, with pH 7~9, solid content 35%~4Q%, viscosity 25. 〇, M407829 cps (mPa. S) <200, anti-flexion Modulus 1 () 〇 kg / cm or more, tensile strength iQQkg / cm2, elongation i 〇〇% or more characteristics, because the dilution solvent is water, does not contain formaldehyde, benzene and other volatile organic compounds, non-toxic, odorless, Flame-resistant without polluting the environment, and has excellent chemical resistance (solvent resistance) [butanone (MEK) wipe (back and forth) 10 times or more, toluene (T〇1uene) 2 times or more], scratch resistance (surface hardness 2B or more, better after rubbing), (elongation work 00% or more), ultraviolet light resistance (uv) (5 or higher), scratch resistance (no crease after wiping), _ sex (surface It can be reprinted) and has antibacterial properties (adding non-silver silver 5~20 nm with antibacterial effect), etc., and can read and protect functional _i the overall manufacturing quality of the finished product and the appearance is more beautiful. The above detailed description is for the description of a preferred embodiment of the present invention, and the scope of the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ All should be included in the special machine covered by this creation. = As mentioned above, the manufacturing green of this _ _ _ _ _ can really achieve the "efficiency and purpose, so the creation of this creative - practical and excellent creation, in line with the application requirements of the new patent, ° ° Wei Zhi Shen Shen 4, I hope that the trial committee will give you an early guarantee of the hard work of the creators. The Silk Fishing Bureau has any doubts, and the letter is fine. The creators agree to cooperate with each other and feel punished. 12 M407829 [Simple diagram] The first picture is BRIEF DESCRIPTION OF THE DRAWINGS The second drawing is a side cross-sectional view of a preferred embodiment of the present invention. The third drawing is a side cross-sectional view of another preferred embodiment of the present invention. Figure 5 is a side cross-sectional view of another preferred embodiment of the present invention. [Description of main components] 1. Functional film 1 1 , substrate 1 5, printing Layer 1 2, aqueous release layer 16 , metal layer 13 , coating layer 17 , protective layer 14 , and subsequent layer 13