CN102180047B - Insert mold transcription film including three-dimentional pattern of metal texture and method for fabricating the same - Google Patents
Insert mold transcription film including three-dimentional pattern of metal texture and method for fabricating the same Download PDFInfo
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- CN102180047B CN102180047B CN201010600127.9A CN201010600127A CN102180047B CN 102180047 B CN102180047 B CN 102180047B CN 201010600127 A CN201010600127 A CN 201010600127A CN 102180047 B CN102180047 B CN 102180047B
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/54—Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/40—Adhesives in the form of films or foils characterised by release liners
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
- C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
- C23C14/14—Metallic material, boron or silicon
- C23C14/20—Metallic material, boron or silicon on organic substrates
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacturing & Machinery (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Laminated Bodies (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Printing Methods (AREA)
Abstract
The invention discloses an insert mold transcription film including three-dimentional patterns of metal texture and a method for fabricating the same. According to the method, a release layer is formed on a basal membrane and a semi-rigid UV coating layer is formed on the release layer. Then a printing layer is formed on the semi-rigid UV coating layer and a three-dimensional pattern layer is formed on the printing layer by transparent ink. A metal layer is arranged on the surface of the three-dimensional pattern layer and an adhesive layer is formed on the metal layer. Various luxurious metallic textures of line patterns are exhibited by the invention.
Description
Technical field
The present invention relates to the manufacture method of the interspersed mould transfer printing film that comprises metal-like space pattern.Being specifically related to be transferred state is benchmark, forms space pattern below printed layers, to show the technology of Luxury metal texture of various forms.
Background technology
Generally speaking if the casing of the small-sized electronic products such as mobile phone is with synthetic resin injection mo(u)lding, for protection or outward appearance U.S. form UV coating on the surface of the shaped articles such as above-mentioned mobile phone shell.
In recent years, the panel bound edge of the keyboard of manual terminal or LCD liquid crystal display etc. is made with the good metal material of durability (metal), on the surface such as keyboard or panel bound edge making at this metal material, for enrichment aesthetic feeling forms a small thread pattern, thus performance decorative effect.
By out-of-date methods, for form fine rule on the surfaces such as above-mentioned metal keyboard or metal hemming edge, use steel brush repeatedly rub and form.But wearing into fine rule with steel brush needs carefully to grind one by one product surface, therefore operation is very loaded down with trivial details, and existence is used the also difficult problem of wearing into the processability declines such as metal level of steel brush.And the dust that produces when metal level of mill is attached to the surface of product, improve bad product incidence.Therefore also increase except adjunctive programs such as the dust of attachment removal product surface the problem of bringing productivity to decline along with additional works.
Therefore, the method that the one side of product is printed as to metallochrome is: by interspersed the synthetic resin transfer printing film that thread pattern printed layers is provided injection mo(u)lding, make printed layers be transferred to the method on shaped article surface.In can reproducing metal-like on the surface of shaped article like this, can also reproduce thread pattern.
By existing method, in order to form the printed layers of thread pattern on transfer printing film, operator republishes light transmission mask film after forming thread pattern with computer image processing software, then coating photosensitive liquid equably on silk-screen face, the mask film of above-mentioned printing fine line pattern is placed on above-mentioned silk-screen face, only allow the photographic fixing of above-mentioned thread pattern part develop to sensitization liquid, by above-mentioned silk-screen face on transfer printing film for the first time form thread pattern and be printed as metallochrome thereafter, then on transfer printing film, cover for the second time thread pattern part and silk-screen becomes the metallochrome of different color, finally by interspersed the transfer printing film that forms printed layers injection mo(u)lding, and at the existing metal-like in the surperficial upper body of shaped article and thread pattern.
But, as utilizing computer software, said method operator makes thread pattern by hand, and just can be printed onto on transfer printing film through again it being printed on to the successive projects such as film film, because being computer software, thread pattern forms, so on product surface, shown thread pattern seems not only merely but also very regular, has the factitious problem of pattern.
In addition,, as the transfer printing film that said method is manufactured, processing percentage elongation declines, and embodies the Luxury metal texture such as other various marks, decorative pattern and have boundary except thread pattern simultaneously.
Summary of the invention
In view of this, main purpose of the present invention is that starting up to form transfer printing film from basement membrane is below benchmark, uses transparent ink to form the space pattern of thread pattern or various decorative patterns on printed layers; Use in the above the method for deposited metal layer can embody Luxury metal texture, can also provide outstanding processing percentage elongation, be easy to be applicable to the shaped article of various forms simultaneously; After interspersed transfer printing, because there is no extra successive projects, be not transferred in the lip-deep Printing Department that is transferred of shaped article and from shaped article, separate very totally, thereby improve the productive generation that has simultaneously also prevented bad product; Interspersed mould transfer printing film and the manufacture method with metal-like that are made up of new component are provided.
Technical scheme
The manufacture method of interspersed mould transfer printing film provided by the invention, its feature comprises: the step that forms a release layer on basement membrane; On described release layer, form the step of semi-hard UV coating; On described semi-hard UV coating, form the step of printed layers; On described printed layers, use transparent ink to form the step of space pattern layer; In the step of the surface deposited metal metal level of described space pattern layer; On described metal level, form the step of an adhered layer.
Here, above-mentioned basement membrane, is characterized in that: by PET (Poly Ethylene Terephthalate) or PETG (Poly Ethylene Terephthalate Glycol) resin manufacture.Above-mentioned release layer, is characterized in that: use melamine mould release or silicone release agent to form.Above-mentioned semi-hard UV coating, is characterized in that: taking the photo-hardening solids of 100 % by weight as benchmark, use the material of the sensitization initiator of the soft acrylic ester oligomer that comprises 91～95 % by weight and 5～9 % by weight.Above-mentioned soft acrylic ester oligomer, is characterized in that: be selected from one or more in urethane acrylate, prestox acroleic acid polyurethane, epoxy acrylate, epoxy acrylic methyl esters, acrylate, methyl methacrylate, acrylic acrylate, polyester acrylate, eight amine modified acroleic acids.Above-mentioned semi-hard UV coating, is characterized in that: with respect to the photo-hardening solids of 100 weight portions, mix the organic solvent that uses 5～45 weight portions.
In addition, the manufacture method of interspersed mould transfer printing film, is characterized in that, also comprises: described printed layers is decorative pattern (Decoration) layer as background by metal level; In the middle of described semi-hard UV coating and described printed layers, further form primary coat (Primer) layer.
Further, the manufacture method of interspersed mould transfer printing film, is characterized in that, also comprises: the thickness of described space pattern layer is 0.2～20 μ m; The thickness of fine rule (Hairline) pattern is 0.2～2 μ m; Sun is carved or the thickness of cloudy needle drawing case is 2～20 μ m.
Further, the manufacture method of interspersed mould transfer printing film, is characterized in that, also comprises: described space pattern layer, comprises the dual component thermosetting ink that polyurethane resin is; Described metal level utilization be selected from aluminium, copper, titanium one or more and form; The thickness of described metal level is
between described metal level and adhered layer, further form and paste priming coat.
In addition, interspersed mould transfer printing film of the present invention method manufacture described above, is characterized in that, comprises the space pattern of metal-like.
As seen from the above, the manufacture method of interspersed mould transfer printing film of the present invention is: on printed layers, use transparent ink to form space pattern, deposited metal layer in its surface, make the various decorative patterns, trade mark, the mark that comprise thread pattern seem luxurious, also there is the simple effect of operating process simultaneously.
In addition, the interspersed mould transfer printing film of the invention described above is because percentage elongation is high, so there is outstanding mouldability, and after interspersed mould engineering, be transferred Printing Department and release film together, separate totally from being needed on the printed layers of shaped article, can omit successive projects, also simple to operate and have improve productive effect.
And strong point is: possess and be needed on the printed layers of shaped article and the stripping process of shaped article etc., and can obviously reduce the generation of bad product.
Brief description of the drawings
Fig. 1 is the decomposition section illustrating according to interspersed mould transfer printing film of the present invention and shaped article cohesive process;
Fig. 2 is according to the stereogram of interspersed mould transfer printing film space pattern layer of the present invention.
Detailed description of the invention
The present invention is to provide a kind of interspersed mould transfer printing film and manufacture method that comprises metal-like space pattern, its printing, tack, solvent resistance are outstanding, and embody distinct metal-like and the three-dimensional pattern of high rigidity.
Hereinafter, to interspersed mould transfer printing film and the manufacture method that comprises metal-like space pattern of the present invention, be described in detail.
Advantage of the present invention and feature and implementation method, clearly state with preferred embodiment with reference to the method for accompanying drawing.But the present invention is not limited to embodiment, embody various forms and can realize by distinct methods.The embodiment enumerating is convenient to those of ordinary skill in the art below and can be successfully realized the present invention and provide, the present invention is defined as claim category.Identical Reference numeral uses in all different accompanying drawings, to specify identical assembly.
Fig. 1 is the decomposition section that interspersed mould transfer printing film of the present invention and shaped article cohesive process are shown.
Be according to the diagram of interspersed mould transfer printing film of the present invention 180 structures referring to Fig. 1, specifically formed by the order of basement membrane 100, release layer 110, semi-hard UV coating 120, the adhesive priming coat 130 that increases printed layers, printed layers 140, the space pattern layer 150 that uses transparent ink, metal level 160, adhered layer 170 from top to bottom.Shaped article 200 below adhered layer 170, on the surface of shaped article 200 transfer printing intert mould transfer printing film 180.
As mentioned above, on the surface of shaped article 200, form the semi-hard UV coating 120 of hardening completely after printed layers, then remove basement membrane 100 and release layer 110, complete and intert mould transfer printing engineering.
Here, although according to having illustrated with order from top to bottom shown in Fig. 1, the cumulative orders of mould transfer printing film in fact interted is, bottom is basement membrane 100, and it forms in the above in order layer by layer.About the actual manufacture method of interspersed mould transfer printing film, be described as follows.
First, be the step of spraying mould release enforcement formation release layer 110 on basement membrane 100.Basement membrane 100 is by PET (Poly Ethylene Terephthalate) or PETG (Poly Ethylene Terephthalate Glycol) resin manufacture.Because PET or PETG have more outstanding hot percentage elongation compared with general basal lamina material, use and be selected from PET or PETG resin so intert mould transfer printing film, can make mouldability maximization.
And release layer 110 should use melamine mould release or silicone release agent.Because it is thin that melamine mould release or silicone release agent are that liquid condition can spread, in the time that successive projects UV coating 120 is hardened completely, have and make the two-layer characteristic that separates of being easy to.
Then, be the step of implementing to form UV coating 120 on release layer 110.Now, semi-hard UV coating 120 refers to by the UV hard resin layer of the partially hardened state that is shown as that UV irradiates for the first time.
Therefore, semi-hard UV coating is taking the photo-hardening solids of 100 % by weight as benchmark, uses the material of the sensitization initiator of the soft acrylic ester oligomer that comprises 91～95 % by weight and 5～9 % by weight.Above-mentioned soft propylene is selected from one or more in urethane acrylate, prestox acroleic acid polyurethane, epoxy acrylate, epoxy acrylic methyl esters, acrylate, methyl methacrylate, acrylic acrylate, polyester acrylate, eight amine modified acroleic acids.
And semi-hard UV coating 120, with respect to 100 weight portion photo-hardening solids, is mixed the organic solvent that uses 5～45 weight portions.If organic solvent is less than 5～45 weight portions, mobility is too reduced, and can increase the difficulty that forms film protection layer.If organic solvent exceedes 45 weight portions, mobility significantly increases in contrast, can not ensure normal film development.
Secondly, be the step of implementing to form printed layers 140 on semi-hard UV coating 120.For improving the adhesion strength of printed layers 140 and the absorbent properties of the rear ink of printing, on the surface of semi-harden UV coating 120, form primary coat (Primer) layer.Priming coat 130 uses and is selected from the outstanding acrylic acid of ink absorption or polyurethane polyol copolymer.Priming coat 130 should keep certain refractive index to be advisable with semihard voltinism UV coating 120, and this measure is for preventing rainbow (Rainbow) phenomenon.Be the outside video picture of semi-hard UV coating 120 based on considering that performance is smooth, will reflect outer surface at a certain angle time, can see that on outer surface, having the video picture of oil droplet is rainbow phenomena.For offsetting above-mentioned rainbow phenomena, in the middle of semi-hard UV coating and above-mentioned printed layers, further form priming coat 130.Above-mentioned priming coat utilizes polychrome gravure rotary press (Multi-color Gravuer Printing Machine) coating to be advisable, its thickness is 1.0～1.5 μ m, cross the dry of 10 seconds at the temperature back warp of 100 DEG C, then the sweat through 24 hours again in the temperature of 40 DEG C.
And, above-mentioned printed layers 140 parts are printed on above priming coat 130, show various designs, character or trade mark etc. with shades of colour.Especially printed layers 140 of the present invention is that metal level 160 is advisable as decorative pattern (Decoration) layer of background.
Above-mentioned printed layers 140 is used the material of the curing agent of synthetic resin, 5 weight portions of the pigment that comprises 25 weight portions, 15 weight portions to be advisable, and now curing agent should adopt and comprise the material that polyurethane copolymer is about 40% synthetic resin and be advisable.
This printed layers 140 is utilize polychrome gravure rotary press (Multi-color Gravuer Printing Machine) and form, and the print frequency setting according to polychrome gravure rotary press turns round.Now printed layers 140 thickness are 1.0～1.5 μ m, carry out through 10 seconds dryly in the temperature of 100 DEG C, and then the sweat through 24 hours again in the temperature of 40 DEG C, finally forms crosslinked printed layers 140.
Again secondly, be the step of implementing the space pattern layer 150 that uses transparent ink on printed layers 140.Described transparent ink comprises that the dual component thermosetting ink of polyurethane resin system is advisable.Because polyurethane resin system is very high with the adherence of panel fabric, so can also increase the dynamics of metal level 160 when improving the adhesion strength of panel fabric and printed layers 140.
Described space pattern layer 150 can freely form thread pattern and decorative pattern, Yang Ke or cloudy trade mark, sign etc. of carving video picture, select to adopt one of gravure, silk-screen, ink jet printing method, the characteristic of thread pattern that can exhibits excellent, can also show the outstanding the moon of third dimension and carve or positive needle drawing case.Now the thickness of space pattern layer 150 is 0.2～20 μ m, makes it to fully demonstrate third dimension and adhesiveness is advisable.
If the thickness of above-mentioned space pattern layer 150 is 0.2～2 μ m, its expression effect can reach not only meticulous but also super high-caliber thread pattern, and when the space pattern such as explicit identification, the thickness of above-mentioned space pattern layer 150 is 2～20 μ m the bests in addition.
If the thickness of above-mentioned space pattern layer 150, less than 0.2 μ m, just can not show third dimension fully, nor can guarantee and the adhesion strength of printed layers 140 or metal level 160.If the thickness of above-mentioned space pattern layer 150 exceedes 20 μ m, can increase the integral thickness of interspersed mould transfer printing film, therefore cause mouldability to decline and likely cannot intert normally mould transfer printing engineering.
Secondly, be the step of implementing deposited metal layer on the surface of space pattern layer 150 again.Described metal level utilization be selected from aluminium, copper, titanium one or more and form, utilize the deposited engineering of cathode vacuum spraying plating (Sputtering) to be advisable, its thickness is
if the thickness of described metal level 160 less than
can not fully show metal-like; If the thickness of described metal level 160 exceedes
destroy the peculiar texture that space pattern layer 150 shows, and increase the thickness of interspersed mould transfer printing film, the problem that may cause mouldability to decline.
In addition, metal level 160 of the present invention, except the intrinsic color of metal, can also comprise with other colors printed layers as a setting.Now only the part such as mark that shows metal-like is carried out to the deposited engineering of cathode vacuum spraying plating (Sputtering), can form background printed layers according to the step of above-mentioned printed layers formation for remainder.
Finally, be the step of implementing to form adhered layer 170 on metal level 160, the mould transfer printing film seamless sticky that makes to intert is attached to shaped article 200.Now the surface of described metal level 160 is because space pattern layer 150 shows irregular surface state.
In the middle of metal level 160 and adhered layer 170, further form and paste priming coat 165.But pasting priming coat 165 is not the step that must implement, only can append the effect of exercising priming coat to adhered layer 170 of the present invention.Because the formation of adhered layer 170, can make the planarization on metal level 160 surfaces seem more natural, can also successfully carry out the stickup building-up process of shaped article 200.
In sum, the present invention can show outstanding metal-like by space pattern layer 150, and then the decorative effect that can double.Particularly utilize the space pattern layer 150 that comprises thread pattern, as deposited aluminium shows the metal-like of silver color thread pattern; As deposited copper can show golden thread pattern.In addition,, as above-mentioned thread pattern is mixed to use with the mark of Yang Ke or cloudy needle drawing case, can demonstrate more outstanding decorative pattern.
Fig. 2 is the stereogram that the space pattern layer of interspersed mould transfer printing film according to the present invention is shown.
Fig. 2 illustrates that using transparent ink to form on surface is printed on the space pattern layer 150 that cloudy blaze is known, and embodies thread pattern on the surface of knowing at cloudy blaze, and forms an example of Luxury metal texture.
Form actually space pattern, cloudy blaze is known after contrary direction printing and just shown thread pattern; The mark that when the interspersed mould transfer printing film that comprises described pattern is applicable to shaped article, visible sun is carved.
As described above, according to the manufacture method of interspersed mould transfer printing film of the present invention, on printed layers, use transparent ink to form space pattern, the upper deposited metal layer in its surface, can show the various luxurious decorative pattern, trade mark, the mark that comprise thread pattern, operating process is easy simultaneously.
In addition,, if above-mentioned interspersed mould transfer printing film of the present invention is because using semi-hardization UV coating, so have very high percentage elongation, mouldability is also outstanding simultaneously.Implement to intert after mould transfer printing engineering, being transferred Printing Department and release film together can clean separation from the printed layers of shaped article institute transfer printing, thereby can omit successive projects, also can improve convenience and the productivity of operation.
As mentioned above, with reference to the accompanying drawings of embodiments of the invention, but the invention is not restricted to above-described embodiment, and can manufacture various form.In the technical field of the invention, those of ordinary skill does not need to change technological thought or essential characteristic, can implement according to the above description different concrete forms yet.Therefore, above-described embodiment should be interpreted as and be not limited only to this by the preference in all embodiment.
Claims (13)
1. the manufacture method of an interspersed mould transfer printing film, it is characterized in that, first on basement membrane, form a release layer, then on release layer, form a semi-hard UV coating, on semi-hard UV coating, form again a printed layers, on printed layers, re-use transparent ink and form space pattern layer, at space pattern layer surface deposited metal metal level, finally on metal level, form an adhered layer; The thickness of described space pattern layer is 0.2～20 μ m; Wherein, the thickness of described space pattern layer thread pattern is 0.2～2 μ m; Described space pattern layer sun carves or the thickness of cloudy needle drawing case is 2～20 μ m.
2. method according to claim 1, is characterized in that: described basement membrane is for using PET or PETG resin manufacture.
3. method according to claim 1, is characterized in that: described release layer uses melamine mould release or silicone release agent to manufacture.
4. method according to claim 1, is characterized in that: in described semi-hard UV coating, photo-hardening solids % by weight is 100%, and wherein soft acrylic ester oligomer % by weight is 91%～95%, sensitization initiator % by weight is 5%～9%.
5. method according to claim 4, is characterized in that: described soft acrylic ester oligomer is included as and uses in the middle of urethane acrylate, prestox acroleic acid polyurethane, epoxy acrylate, epoxy acrylic methyl esters, acrylate, methyl methacrylate, acrylic acrylate, polyester acrylate, eight amine modified acroleic acids one or more and generate.
6. method according to claim 1, is characterized in that: in described semi-hard UV coating, the weight portion of photo-hardening solids is 100 parts, mixes and form with 5～45 parts of organic solvent weight portions.
7. method according to claim 1, is characterized in that: described printed layers be one metal level decorative pattern layer as a setting.
8. method according to claim 1, is characterized in that: in the middle of described semi-hard UV coating and printed layers, increase priming coat.
9. method according to claim 1, is characterized in that: described space pattern layer comprises the response type ink that uses 2 kinds of polyurethane type resin main chemical compositions.
10. method according to claim 1, is characterized in that: described metal level is that in the middle of aluminium, copper, titanium, one or more form.
11. methods according to claim 1, is characterized in that: the thickness of described metal level is
12. methods according to claim 1, is characterized in that: in the middle of described metal level and adhered layer, increase and paste priming coat.
13. according to the interspersed mould transfer printing film that in claim 1-12, method is manufactured described in any one, it is characterized in that: described interspersed mould transfer printing film has the space pattern of metal-like.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR10-2009-0126206 | 2009-12-17 | ||
| KR1020090126206A KR101240027B1 (en) | 2009-12-17 | 2009-12-17 | Insert mold transcription film including three-dimentional pattern of metal texture and method for fabricating the same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102180047A CN102180047A (en) | 2011-09-14 |
| CN102180047B true CN102180047B (en) | 2014-08-06 |
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ID=44401283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010600127.9A Expired - Fee Related CN102180047B (en) | 2009-12-17 | 2010-12-16 | Insert mold transcription film including three-dimentional pattern of metal texture and method for fabricating the same |
Country Status (3)
| Country | Link |
|---|---|
| KR (1) | KR101240027B1 (en) |
| CN (1) | CN102180047B (en) |
| TW (1) | TWI414436B (en) |
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|---|---|---|---|---|
| KR101278162B1 (en) * | 2011-08-30 | 2013-06-27 | (주)크루디앤피 | A transcription film for in-mold injection having three-dimensional structure pattern layer and manufacturing method thereof |
| KR101382039B1 (en) * | 2011-12-01 | 2014-04-14 | (주)엘지하우시스 | Interior film including three-dimentional pattern and method for fabricating the same |
| KR101337137B1 (en) * | 2011-12-02 | 2013-12-05 | (주)엘지하우시스 | Insert molding film with 3d pattern and method of manufacturing the same |
| KR101426129B1 (en) * | 2012-01-11 | 2014-08-05 | (주)엘지하우시스 | Hard-coating composition and decoration film including thereof with improving yellowing |
| KR101417247B1 (en) | 2012-02-08 | 2014-07-08 | (주)엘지하우시스 | In-mold transcription film including elastic texture and method for manufacturing the same |
| CN102615882B (en) * | 2012-04-09 | 2014-12-03 | 昆山同寅兴业机电制造有限公司 | Composite appearance product with patterns and production method thereof |
| KR101479813B1 (en) | 2012-04-10 | 2015-01-06 | (주)엘지하우시스 | Hybrid cured pressure sensitive adhesive film |
| KR101437784B1 (en) | 2012-07-12 | 2014-09-15 | (주)엘지하우시스 | Interior Film having longitudinal hair line of various lengths and the manufacturing method thereof |
| CN102874003B (en) * | 2012-09-25 | 2016-01-20 | 深圳市杰瑞表面技术有限公司 | The printing transferring method of space pattern |
| CN102848757A (en) * | 2012-09-25 | 2013-01-02 | 深圳市杰瑞表面技术有限公司 | Rubbing method of stereoscopic pattern |
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- 2009-12-17 KR KR1020090126206A patent/KR101240027B1/en active IP Right Grant
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| KR100642839B1 (en) * | 2004-07-09 | 2006-11-10 | (주)창조아이엠디 | Printing film for Insert inmold and it's manufacturing method therefore |
| CN1939756A (en) * | 2005-09-30 | 2007-04-04 | 佛山市顺德区汉达精密电子科技有限公司 | Plastic surface treatment with metal character and three-dimensional pattern effect |
| CN200995575Y (en) * | 2006-12-18 | 2007-12-26 | 汕头市东田转印有限公司 | Transfer film with decorative-layer protection |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20110069462A (en) | 2011-06-23 |
| TW201121800A (en) | 2011-07-01 |
| KR101240027B1 (en) | 2013-03-06 |
| TWI414436B (en) | 2013-11-11 |
| CN102180047A (en) | 2011-09-14 |
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