TW201121800A - exture. - Google Patents

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Publication number
TW201121800A
TW201121800A TW099144103A TW99144103A TW201121800A TW 201121800 A TW201121800 A TW 201121800A TW 099144103 A TW099144103 A TW 099144103A TW 99144103 A TW99144103 A TW 99144103A TW 201121800 A TW201121800 A TW 201121800A
Authority
TW
Taiwan
Prior art keywords
layer
transfer film
manufacturing
film according
mold transfer
Prior art date
Application number
TW099144103A
Other languages
Chinese (zh)
Other versions
TWI414436B (en
Inventor
Sang-Hui Han
Kang-Youp Lee
Seung-Hun Lee
Young-Joo Ham
Original Assignee
Lg Hausys Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lg Hausys Ltd filed Critical Lg Hausys Ltd
Publication of TW201121800A publication Critical patent/TW201121800A/en
Application granted granted Critical
Publication of TWI414436B publication Critical patent/TWI414436B/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04Coating
    • C08J7/0427Coating with only one layer of a composition containing a polymer binder
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/54Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22Plastics; Metallised plastics
    • C09J7/25Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/255Polyesters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/40Adhesives in the form of films or foils characterised by release liners
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14Metallic material, boron or silicon
    • C23C14/20Metallic material, boron or silicon on organic substrates

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Laminated Bodies (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Printing Methods (AREA)

Abstract

The present invention provides a method for fabricating insert mold transcription film including three-dimensional pattern of metal texture, which comprises a step of forming a release layer on a base film; a step of forming a semi-rigid ultraviolet (UV) coating layer on the release layer; a step of forming a printing layer on the semi-rigid UV coating layer; a step of using a transparent ink to form a three-dimensional pattern layer on the printing layer; a step of melting and coating a metal layer on a surface of the three-dimensional pattern layer; and forming an adhesive layer on the metal layer. This is an invention relates to displaying of fine line patterns and various forms of luxurious metal texture.

Description

201121800 六、發明說明: 【發明所屬之技術領域】 ,發明係關於-種包括金射感立體_的穿插模具轉印膠 片的製造方法。制地,關於—種以被轉印狀態為基準,在印刷 層之下形成立體圖案,以表現各種形態之豪華金屬質感之技術。 【先前技術】 、-般而言,例如手機等小型電子產品之機殼以合成樹脂注塑 成型,為賴或美學外觀,在上述手機外殼等賴產品之表面上 形成紫外(uv)塗層。 近年來,手持終端機之鍵盤或減顯示裝置(lcd)液晶屏 之面板包邊等以敎性良好之金屬材f (她丨)製成,在此種金 屬材質製造之鍵盤或面板包邊等表面之上,為麟裝飾美感形成 一個微小之細線圖案,從而發揮裝飾之效果。 按照傳統之方法’為在金屬鍵盤或金屬包邊等表面上形成細 線’使用鋼刷多次摩擦而形成。但是使用鋼刷磨成細線需要仔細 地研磨產品之表面,因此操鱗,並且存在即使使用鋼刷 也難以研磨成金屬層等加:^性下降之問題。而騎磨金屬層時所 產生之粉_著於產品之表面,增加了不良產品率。因此還可增 加除去附著於產品表面之粉塵等補充作業,隨著追加工作而帶來 生產性下降之問題。 因此,將產品之-表面印刷成金屬色之方法為:將提供細線 圖案印刷層之合成樹脂轉印膠片穿插注塑成型,使得印刷層轉印 至成型產品表面。碰可以錢财品之表社魏金屬質感的 201121800 同時,還可以再現細線圖案。 根據現有H為在轉印膠片之上形成細線随之 操作者用電麵像處理軟體形細賴紐再_至透光性_ 膠片,然後在絲印面之上均勻塗抹感光液,將印刷細_案之掩 膜膠片放於此絲印面之上’僅讓細線圖案部份定影至感光液顯 影’其後透過此絲印面在轉印膠片之上第—次形成細線圖宰並印 刷成金屬^然後在轉印膠片之上第二次覆蓋細線圖案部份而絲 印成不同色彩之金屬色,最後將形成印刷層之轉印膠片穿播注 成型’並在成型產品之表面上體現金屬贼以及細線圖案。 ^而,按照上述方法’ #作者· 軟體手讀作細線圖 案’並經過將其印刷至薄膜膠片等後續作業才能印刷至轉印膠片 上,即,由於細線_為透過電腦軟體形成,所以產品表面^ 顯不之細、__得既單純又报有酬,具有圖案不自然之問題。 此外,按照上述方法製造之轉印膠片加工延伸率下降, 除了細線圖案以外,實現其他各種標識、花紋等 且 有限制。 勾貝4具 【發明内容】 μΖμΓ於上制題,本㈣之目的在於:自下方基膜開始 3幸=^ 基準,在印刷層之上翻墨水形成細線 圖案或各種化紋之立義案;在其上枝敷金朗之方 以體現豪華之金屬質感,同時還可以提供優秀的加工延伸率,極 容易適胁各種形態之·產品;穿插轉印之後,因為沒有 之後續作業’沒有前於成舰品表面上的被轉抑刷部份自成 4 201121800 ,產品中很乾淨地分離,從而在提高生產性之同時還可防止不良 “之出現,&供由新成分構相具有金屬_ 膠片及其S造方法。 卿 本發明之穿減具料膠4賴造紐包含··在基臈之上妒 成-個離型層之步驟,·在離型層之上形成半硬性料(uv)塗層 之步驟;在半硬化性料(uv)魏之上形成—印姆之步驟; 在印刷層之上使用透明墨水形成立體圖案層之步驟;在立體圖案 層之表面熔敷金制之步驟;在此金射之上形成_個黏合以 步驟。 s 攻裏’上絲膜之特徵在於:由聚乙稀對笨二甲酸醋(托丁) 或者聚對苯二甲酸乙二s旨(PETG)樹脂製造。離型層使用三聚氛 胺離型劑或者有機雜型縫造。其巾紫外(uv)塗層以光硬性 =體物之重量為1_,使用包含91〜95%重量的軟質丙烯酸醋低 聚物以及5〜9%重量_光起始劑之物f。其巾軟質⑽酸醋低聚 物選自聚氨S旨丙烯酸g旨、八曱基丙烯酸聚氨g旨、環氧丙稀酸醋、 環氧丙稀酸甲§旨、丙烯酸醋、曱基丙烯酸甲醋、丙烯酸丙稀酸醋、 聚醋丙烯酸®旨、人胺改性丙烯酸之中的至少-種。其中半硬性紫 外(UV)塗層相對於光硬性固體物之重量為100,混合使用5〜45 重量之有機溶劑。 此外’此種穿插模具轉印膠片的製造方法之中,印刷層將金 屬層用作背景之料_ (Dee()rati()n)層;半硬性紫外(w) 塗層與印刷層之間進一步形成一底塗(Primer)層。 此外’此種穿插模具轉印膠片的製造方法之中,立體圖案層 201121800 之厚度為0.2〜20微米(um);細線(Hairline)圖案之厚度為〇 2〜2 微米(um);陽刻或者陰刻圖案之厚度為2〜2〇微米 此外,此種穿插模具轉印膠片的製造方法之中,立體圖案層 包括聚氨醋樹脂系的雙組分反應性墨水;金屬層利用選自銘、銅、 鈦中至少—種形成;金屬狀厚度為兄〜⑼埃⑷;金屬層與黏 合層之間進一步形成一黏貼底塗層。 此外,本發明的穿插模具轉印膠片如上所述方法製造,其中 該穿插模具轉印膠片包括金屬質感的立體圖案。 以上所述,本發明的穿插模具轉印膠片的製造方法為:在印 刷層之上使用透水職立體_,在其表面上峨金屬層, 使%•包括細線圖案之各種花紋、商標、標識顯得豪華,同時還具 有操作流程簡單之效果。 此外,上述本發明的穿插模具轉印膠片因為延伸率高,所以 具有優良之成型性’並且縣減具健讀,被辨印刷部與 離型膠H自被轉印於成型產品的印刷層乾淨地分離,則可 省略後續之作業,操作簡單並具有提高生產性之效果。 並且,本發明之他點在於:具有被轉印於成型產品的印刷層 與成型產品之獅過轉,並且可㈣麟低不良產品之出現。 【實施方式】 本發明關於-種包括金屬質感立體圖案的穿插模具轉印膠片 以及製造方法’其印雌、附著性、啦雜優良,並可實現鮮 明之金屬質感及高硬度之三維立體圖案。 在下文中’將對本發明之包括金屬質感立體圖案的穿插模具 201121800 轉印膠片以及製造方法進行詳細描述。 以下’將結合圖式部份對本發明的較佳實施方式作詳細說 明。其中在些圖式部份中所使用的相同的參考標號代表相同或 同類部件。 「第1圖」係為本發明之穿插模具轉印膠片及成型產品結合 過程之分解剖視圖。 請參閱「第1圖」’其表示根據本發明之穿插模具轉印膠片18〇 結構,具體而言,自上至下係由一基膜100、一離型層110、一半 硬性紫外(UV)塗層12G、-增加印刷層之黏合性之底塗層13〇、 -印刷層140、-使用透明墨水之立體圖案層15〇、—金屬層16〇、 以及一黏合層170之順序構成。成型產品2〇〇位於黏合層17〇之 下,成型產品200之表面上轉印穿插模具轉印膠片18〇。 如上所述,成型產品2〇〇之表面上形成印刷層之後完全硬化 半硬性紫外(UV)塗層120,然後去除基膜100及離型層11〇, 由此完成穿插模具轉印作業。 這裏’雖然按照「第1圖」所示以自上至下之順序進行說明, 但實際上穿插模具轉印膠片之累積順序為,最下方為基膜1〇〇,其 在上方按照順序層層形成。關於穿插模具轉印膠片之實際製造方 法說明如下。 首先,為在基膜100之上噴塗離型劑實現形成一離型層u〇 之步驟。基膜100由聚乙烯對苯二曱酸酯(Poly Ethylene Terephthalate,PET)或者聚對苯二曱酸乙二酯(p〇lyEthylene Tei*ephthalateGlycol,PETG)樹脂製造。因為聚乙烯對苯二曱酸酯 201121800 (PET)或聚對苯二甲酸乙二酯(PETG)相比較於一般之基膜素 材具有更優秀之熱延伸率,因此穿插模具轉印膠片使用選自聚乙 稀對苯二曱酸酯(Poly Ethylene Terephthalate,PET )或者聚對苯二 曱酸乙二酯(Poly Ethylene Terephthalate Glycol,PETG )之樹脂, 可使得成型性最大化。 並且’離型層110可使用三聚氰胺離型劑或者有機石夕離型劑。 因為三聚氰胺離型劑或者有機矽離型劑為液體狀態可以鋪薄,在 後續作業中’當紫外(UV)塗層120完全硬化時,具有使得兩層 很容易分離之特性。 然後,為在離型層110之上實現形成紫外(UV)塗層120之 步驟。此時’半硬性紫外(U V )塗層〗2 〇係指透過第一次紫外(u v ) 照射顯示為部份硬化狀態之紫外(UV)硬性樹脂層。 因此,半硬性紫外(UV)塗層以1〇〇%重量之光硬性固體物 為基準,使用包含91〜95%重量比之軟質丙烯酸醋低聚物以及 5〜9%重量比之感缺始劑之物質。練奸烯選自聚氨自旨丙稀酸 醋、八曱基丙稀酸聚氨醋、環氧丙烯酸醋、環氧丙稀酸甲醋、丙 烯酸酯、甲基丙烯酸甲酯、丙烯酸丙烯酸酯、聚酯丙烯酸酯、以 及八胺改性丙烯酸之中的至少一種。 並且,半硬性紫外(uv)塗層12〇相對於ι〇〇重量比之光硬 性固體物’混合仙5〜45重量比之有機溶劑。如果有機溶劑未達 到5〜45之重量部,則流動性過分降低,會增加形成膠片保護層之 難度。如果有機溶劑超過45之重量部,與之相反,流動性大幅增 大,不能夠保障正常之膠片顯影。 201121800 其次’為在半硬性紫外(UV)塗層120之上實施形成印刷層 140之步驟。為提高印刷層140之黏合力以及印刷後墨水之吸收性 能,在半硬化紫外(UV)塗層120之表面上形成一底塗(Primer) 層底塗層130使用選自墨水吸收性優良之丙婦酸或聚氨酯多元 醇共聚物。底塗層130應與半硬化性紫外(uv)塗層12〇保持一 定之折射率為宜,這樣為防止彩虹(Rainbow)現象。即半硬性紫 外(UV)塗層120基於考慮表現平整之外部影像,以一定角度反 射外部表面時,會看到外部表面上具有油滴之影像即彩虹現象。 為抵消上叙扯絲’在半雖料(υγ)麵與印刷層之間 進步形成有-底塗層13〇。底塗層利用多色凹印輪轉印刷機 (Multi-c〇i〇rGravuerPrintingMachine)塗層為宜其厚度為 1·〇〜1.5微米一广在雇义之溫度下經過⑺秒鐘之乾:然後 在40°c之溫度下又經過24小時之發酵過程。 並且,將印刷層140部份印刷於底塗層13〇之上 色表現各種設計、字域商標等。_地,本發明之印刷層= 將金屬層_用作背景之料圖案办嶋㈣層為宜。 印刷層H0使用包含25重量部之顏料、15重量部之合成樹 部之硬化劑的素材為宜,此時硬化劑應期包含有聚氨 酉曰共聚物約為40%之合成樹脂之素材為宜。 it匕種卩刷層 …υ補用多色凹印輪轉印刷機⑽ti-color 在00ΡΓ而Γ此時印_14G之厚度為ιό〜L5微米() 在KK)C之溫度觸1G败麵,嶋4 201121800 經過24小時之發酵,最後形核聯印刷層⑽。 再次,為在印刷層140之上使用透明墨水實現立體圖案層15〇 之步驟。此透明墨水包含有聚氨酯樹脂系之雙組分反應性墨水為 宜。因為聚氨醋樹脂系與面板面料之黏合性很高,所以提高面板 面料與印刷層M0之黏合力的同時還可增加金屬層⑽之強度。 ,立體圖案層150可自由地形成細線圖案及花紋、陽刻或陰刻 影像之商標、標示等,選擇採用凹印、絲印、喷墨印刷方法之一, 可以表現優良之細線圖案之特性,還可表現立體感優良之陰刻或 陽刻圖案。此時立體_層15G之厚度為α2〜顧米(咖),使 之充分體現立體感及黏合特性為宜。 如果立體圖案層150之厚度為0.2〜2微米(mn),其表現效果 可達到既精細又超高林之細線_,除歧賴示標識等立體 圖案時’立體圖案層150之厚度為2〜2〇微米(啦)最佳。 如果立體圖案層150之厚度未達到〇 2微米(um),則不能夠 充分地顯示赠感,而且也不能夠確保與印㈣M0或金屬層16〇 之黏合力。如果立體圖案層15〇之厚度超過2〇微米(啦),會增 加穿插模具轉特片之整斷度,因料致成麵下降而有可曰能θ 無法進行正常之穿插模具轉印作業。 再次,為在立體_層15〇之表面上實施職金屬層之步驟。 該金屬層利用選自铭、銅、鈦中的至少一種而形成,利用陰極真 空噴鑛(Sputtering)熔敷工程為宜,其厚度為5〇〜15〇埃⑷。 如果金屬層脱之厚度未達㈣埃(A),财能触分顯示 質感;如果金屬層160之厚度超過15〇埃(A),則立體圖案層⑼ 201121800 所表現出來的特有質感失敗,並增加穿插模具轉印膠片之厚户, 可能會導致成型性下降之問題。 另外,本發明之金屬層160除了金屬固有的顏色以外,還可 =包括以其他顏色作為f景之印刷層。此時僅對顯示金屬質感的 样識等p伤進行陰極真空噴錄(Sp^_)溶敷作業,對於剩餘 部份可按照上述印刷層形成之步驟來形射景_層。、、 最後’為在金屬層16〇之上實施形成黏合層17G之步驟,使 穿插模具轉印膠片無縫黏貼於成型產品200。此時金屬層16〇之表 面因為立體圖案層15G,顯示不平整之表面狀態。 在金屬層160與黏合層17〇之間進一步形成黏貼底塗層⑹。 但’黏貼底塗層165並非必須實施之步驟,僅對本發明之黏合層 170而言可以追加行使底塗層之作用。因為黏合層170之形成,曰可 以使%•金屬層160表面之平坦化顯得更自然,還可順利地進行成 型產品200之黏貼合成過程。 、紅上所述’本發明透過立體圖案層15〇可顯示優良之金屬質 感’進而可倍增裝飾效果。特別是利用包含細線圖案之立體圖案 層15(M物熔敷銘則顯示銀色細線圖案之金屬質感;例如溶敷銅 則可以顯7F金色細線圖案。此外,如將上述細制案與陽刻或陰 刻圖案之標識混合使用,則可以顯示出更加優良之裝個案。 第2圖」係為根據本發明穿插模具轉印膠片之立體圖案層 之側視圖。 「第2圖」絲出使崎明墨水形絲面之上印有陰識 之讀随層150’在㈣標識之表面上體現細細案,而形成豪 201121800 華金屬質感的一個例子。 品時可見陽刻之標識 實際中,形成立麵案將陰刻標識向逆方向印刷以後 細線圖案·,將包含有所述圖案之穿插模具轉印膠片應用于成型= 如上所述,根據本發明的穿插模具轉印膠片的製造方法, 印刷層之上使用透明墨水形成立體_,其表面上_金屬層, 可以顯示包含細賴案之各種樣式之豪華花紋、商標、標識 時操作流程容易。 V» ’ = 此外,如上所述,本發明之穿插模具轉印膠片因使用半硬性 化紫外(uv)塗層,所以具有很高之延伸率,同時成型性也優良 實施穿插模具轉印作業之後’被轉印印刷部及離型膠片可一同自 成型產品娜印之_層乾淨地分離,從而可省略後續作業,還 可提高作業之便利性及生產性。 雖然本發日狀前狀健魏_露如上,雜並非用以限 定本發明。本賴之技術人㈣#意_在不麟本侧所附之 申睛專利範圍所揭*之本發明之精神和範_叙下,所作之更 動與潤飾’ 本侧之補職侧之内。齡本發明所界定 之保護範畴參照卿之申請專利範圍。 【圖式簡單說明】 第1圖係為本㈣之雜模具轉轉狀成型產品結合過程 之分解剖視圖;以及 第2圖係為根據本發明穿插模具轉印膠片之立體圖案層之側 201121800 【主要元件符號說明】 100 基膜 110 離型層 120 半硬性紫外(UV)塗層 130 底塗層 140 印刷層 150 立體圖案層 160 金屬層 165 黏貼底塗層 170 黏合層 180 穿插模具轉印膠片 200 成型產品 13201121800 VI. Description of the Invention: [Technical Field to Be Invented] The invention relates to a method of manufacturing an interpenetrating mold transfer film comprising a gold-like stereoscopic image. The system is a technique for forming a three-dimensional pattern under the printed layer based on the state of being transferred to express the luxurious metallic texture of various forms. [Prior Art] In general, a casing of a small electronic product such as a mobile phone is injection-molded with a synthetic resin, and an ultraviolet (uv) coating is formed on the surface of the above-mentioned mobile phone casing or the like. In recent years, the keyboard of a hand-held terminal or the panel of a liquid crystal panel of a display device (lcd) is made of a metal material f (here) which is made of a metal material, and a keyboard or a panel edging of such a metal material is used. Above the surface, a beautiful thin line pattern is formed for the decorative beauty of the lin, thereby exerting the effect of decoration. According to the conventional method, a thin wire is formed on a surface of a metal keyboard or a metal edging, and a steel brush is used for rubbing a plurality of times. However, the use of a steel brush to grind a thin wire requires careful grinding of the surface of the product, so that it is scaled, and there is a problem that it is difficult to grind into a metal layer or the like even if a steel brush is used. The powder produced when riding the metal layer is on the surface of the product, increasing the rate of defective products. Therefore, it is possible to increase the work of removing the dust adhering to the surface of the product, and the productivity is lowered as the work is added. Therefore, the method of printing the surface of the product into a metallic color is by insert molding a synthetic resin transfer film which provides a fine line pattern printing layer, so that the printing layer is transferred to the surface of the molded product. Touching the table of the real metal texture of the table of money can be used. 201121800 At the same time, it is also possible to reproduce the fine line pattern. According to the existing H, a thin line is formed on the transfer film, and the operator uses the electric surface image to process the soft-shaped ray-to-transparent _ film, and then uniformly applies the photographic liquid on the silk screen surface to print the _ The mask film is placed on the silk screen surface, 'only the thin line pattern is partially fixed to the photosensitive liquid development'. Then the fine line pattern is formed on the transfer film through the silk screen surface and printed into metal ^ then The second part of the transfer film covers the thin line pattern portion and is silk-printed into a metallic color of different colors. Finally, the transfer film forming the printing layer is formed by injection molding and the metal thief and the thin line pattern are displayed on the surface of the molded product. . ^,, according to the above method '# author · software hand read as a thin line pattern' and after printing it to a film film and other subsequent operations can be printed onto the transfer film, that is, because the thin line _ is formed by the computer software, the product surface ^ It is not obvious, __ has both simple and rewarded, and has an unnatural pattern. Further, the transfer film processed by the above method has a reduced elongation, and various other marks, patterns, and the like are realized in addition to the fine line pattern.勾贝4[Inventive content] μΖμΓ is on the top of the title, the purpose of this (4) is: starting from the base film below 3 fortunate = ^ benchmark, flipping the ink on the printed layer to form a thin line pattern or a variety of chemical lines; On the top of it, the golden metal is used to reflect the luxurious metal texture. At the same time, it can provide excellent processing elongation, and it is easy to threaten various forms of products. After inserting and transferring, because there is no follow-up operation, there is no previous ship. The part of the reversing brush on the surface of the product is self-contained 4 201121800, the product is very cleanly separated, so as to improve the productivity while preventing the occurrence of bad, & the composition of the new composition has metal _ film and The S manufacturing method of the invention. The invention discloses the wearing and lowering of the rubber material 4, which comprises the steps of forming a release layer on the base layer, and forming a semi-rigid material (uv) on the release layer. a step of coating; forming a step of printing on the semi-hardening material (uv); a step of forming a three-dimensional pattern layer on the printed layer using transparent ink; and a step of depositing gold on the surface of the three-dimensional pattern layer; Formed above this golden shot_ Bonding is a step. s Attacking 'on-line film is characterized by: polyethylene to benzoic acid vinegar (todidine) or polyethylene terephthalate (PETG) resin. The release layer uses trimer Amine release agent or organic miscellaneous. Its UV (uv) coating is light-hard = body weight is 1_, using 91~95% by weight of soft acrylic vinegar oligomer and 5~9% Weight_photoinitiator f. The soft (10) acid vinegar oligomer is selected from the group consisting of polyacrylic acid, acrylic acid, octadecyl acrylate, propylene acrylate, and acrylic acid. At least one of acryl vinegar, methacrylic acid methyl vinegar, acrylic acrylate vinegar, polyacetic acid acrylate, and human amine modified acrylic. Among them, semi-hard ultraviolet (UV) coating is relatively hard. The weight of the solid matter is 100, and 5 to 45 weights of the organic solvent is used in combination. In addition, in the manufacturing method of the interpenetrating mold transfer film, the printing layer uses the metal layer as a background material_ (Dee()rati() n) layer; a semi-hard UV (w) coating and a printed layer further form a primer layer. In the manufacturing method of the interpolating mold transfer film, the thickness of the three-dimensional pattern layer 201121800 is 0.2 to 20 micrometers (um); the thickness of the hairline pattern is 〇2 to 2 micrometers (um); the thickness of the positive or negative pattern In addition, in the manufacturing method of the interpenetrating mold transfer film, the three-dimensional pattern layer comprises a two-component reactive ink of a polyurethane resin type; and the metal layer is selected from at least one of Ming, copper and titanium. a metal-like thickness of the brother ~ (9) angstrom (4); a further adhesive undercoat layer is formed between the metal layer and the adhesive layer. Further, the interposer transfer film of the present invention is manufactured as described above, wherein the interpenetrating mold is transferred The printed film includes a three-dimensional pattern of metallic texture. As described above, the interposing die transfer film of the present invention is manufactured by using a water-permeable three-dimensional _ on the printed layer, and a metal layer on the surface thereof, so that various patterns, trademarks, and logos including the fine line pattern appear. Luxurious, but also has the effect of simple operation. Further, the above-described interpolating mold transfer film of the present invention has excellent moldability because of its high elongation, and the county is reduced in health reading, and the printed portion and the release rubber H are transferred from the printed layer of the molded product to be clean. If the ground is separated, the subsequent operations can be omitted, the operation is simple, and the effect of improving productivity is obtained. Further, the point of the present invention is that the lion having the printed layer and the molded product transferred to the molded product is overturned, and (4) the appearance of the poor product is low. [Embodiment] The present invention relates to a transmissive mold transfer film including a metallic texture three-dimensional pattern, and a manufacturing method thereof, which is excellent in imprinting, adhesion, and fineness, and can realize a three-dimensional three-dimensional pattern of a clear metallic texture and high hardness. Hereinafter, the interpenetrating mold 201121800 transfer film and the manufacturing method of the present invention including the metallic texture three-dimensional pattern will be described in detail. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, preferred embodiments of the present invention will be described in detail in conjunction with the drawings. The same reference numbers are used in the drawings to represent the same or equivalent parts. Fig. 1 is an exploded sectional view showing the process of joining the transfer film and the molded product of the present invention. Please refer to FIG. 1 which shows the structure of the interposer transfer film 18 根据 according to the present invention. Specifically, from top to bottom, a base film 100, a release layer 110, and a semi-hard ultraviolet (UV) are used. The coating 12G, the undercoat layer 13 which increases the adhesion of the printing layer, the printing layer 140, the three-dimensional pattern layer 15 of transparent ink, the metal layer 16A, and an adhesive layer 170 are sequentially formed. The molded product 2 is placed under the adhesive layer 17〇, and the transfer mold transfer film 18 is transferred onto the surface of the molded product 200. As described above, the semi-rigid ultraviolet (UV) coating layer 120 is completely hardened after the printing layer is formed on the surface of the molded product 2, and then the base film 100 and the release layer 11 are removed, thereby completing the interpeching mold transfer operation. Here, although it is described in the order from top to bottom in accordance with the "Fig. 1", in practice, the cumulative order of the transfer film transfer is: the base film is 1 最 at the bottom, and the layers are layered at the top. form. The actual manufacturing method for interposing a mold transfer film is explained below. First, a step of forming a release layer u 实现 is performed by spraying a release agent over the base film 100. The base film 100 is made of Poly Ethylene Terephthalate (PET) or polyethylene terephthalate (PETG) resin. Since polyethylene terephthalate 201121800 (PET) or polyethylene terephthalate (PETG) has superior thermal elongation compared to general base film materials, interspersed mold transfer film is selected from The resin of Poly Ethylene Terephthalate (PET) or Poly Ethylene Terephthalate Glycol (PETG) can maximize the formability. And the release layer 110 may use a melamine release agent or an organic talc release agent. Since the melamine release agent or the organic release agent can be thinned in a liquid state, in the subsequent operation, when the ultraviolet (UV) coating 120 is completely hardened, it has a property of making the two layers easy to separate. Then, a step of forming an ultraviolet (UV) coating layer 120 is performed over the release layer 110. At this time, the semi-rigid ultraviolet (U V ) coating layer 2 refers to an ultraviolet (UV) hard resin layer which is partially cured by the first ultraviolet (u v ) irradiation. Therefore, the semi-hard ultraviolet (UV) coating is based on a light hard solid of 1% by weight, using a soft acrylic vinegar oligomer containing 91 to 95% by weight and a feeling of 5 to 9% by weight. The substance of the agent. The medicinal olefin is selected from the group consisting of polyacrylic acid acrylic acid vinegar, octadecyl acrylate urethane, epoxy acryl vinegar, methyl acetonate, acrylate, methyl methacrylate, acrylic acrylate, At least one of a polyester acrylate and an octaamine-modified acrylic. Further, the semi-hard ultraviolet (uv) coating layer 12 混合 is mixed with the photohard solid matter by an amount of 5 to 45 by weight of the organic solvent. If the organic solvent does not reach the weight of 5 to 45, the fluidity is excessively lowered, which increases the difficulty in forming a film protective layer. If the organic solvent exceeds 45 parts by weight, the fluidity is greatly increased, and normal film development cannot be guaranteed. 201121800 Next is the step of forming a printed layer 140 over the semi-rigid ultraviolet (UV) coating 120. In order to improve the adhesion of the printing layer 140 and the absorption properties of the ink after printing, a primer layer primer layer 130 is formed on the surface of the semi-hardened ultraviolet (UV) coating layer 120, which is selected from the group consisting of excellent ink absorption properties. A sour or polyurethane polyol copolymer. The undercoat layer 130 should preferably maintain a certain refractive index with the semi-curable ultraviolet (uv) coating layer 12, in order to prevent a rainbow phenomenon. That is, when the semi-rigid ultraviolet (UV) coating 120 reflects the external surface at an angle based on the external image which is considered to be flat, the image of the oil droplet on the external surface, i.e., the rainbow phenomenon, is seen. In order to offset the above-mentioned rip-wire, the undercoat layer 13 形成 is formed by progressing between the half (υγ) plane and the printed layer. The undercoat layer is coated with a multi-c〇i〇r Gravuer Printing Machine (Multi-c〇i〇r Gravuer Printing Machine), preferably having a thickness of 1 〇 to 1.5 μm, dried at a temperature of (7) seconds: then at A fermentation process of 24 hours was passed at a temperature of 40 ° C. Further, a portion of the printed layer 140 is printed on the undercoat layer 13 色 to represent various designs, word domain trademarks, and the like. _, the printed layer of the present invention = the metal layer _ used as the background material pattern (4) layer is suitable. The printing layer H0 is preferably a material comprising a pigment of 25 parts by weight and a hardening agent of a synthetic portion of 15 parts by weight. In this case, the material of the synthetic resin containing about 40% of the polyurethane resin is expected to be should. It匕 卩 卩 υ υ υ υ 多 多 多 多 多 多 多 多 多 多 多 多 多 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 14 4 201121800 After 24 hours of fermentation, the final nucleation of the printed layer (10). Again, the step of implementing the three-dimensional pattern layer 15〇 using transparent ink over the printed layer 140. The transparent ink preferably contains a two-component reactive ink of a polyurethane resin system. Since the polyurethane resin has high adhesion to the panel fabric, the adhesion of the panel fabric to the printed layer M0 can be increased while the strength of the metal layer (10) can be increased. The three-dimensional pattern layer 150 can freely form a thin line pattern and a pattern, a logo of a positive or negative image, a label, etc., and one of the gravure, silk screen, and inkjet printing methods can be selected, and the characteristics of the fine line pattern can be expressed and expressed. An intaglio or embossed pattern with a good three-dimensional effect. At this time, the thickness of the three-dimensional layer 15G is α2 to gu (coffee), so that it is sufficient to sufficiently exhibit the three-dimensional feeling and the adhesive property. If the thickness of the three-dimensional pattern layer 150 is 0.2 to 2 micrometers (mn), the performance effect can reach the fine line of the fine and super high forest, and the thickness of the three-dimensional pattern layer 150 is 2 to 2 except for the three-dimensional pattern such as the logo. 〇Micron is the best. If the thickness of the three-dimensional pattern layer 150 is less than 微米 2 μm, the feeling of giving is not sufficiently displayed, and the adhesion to the (4) M0 or the metal layer 16 is not ensured. If the thickness of the three-dimensional pattern layer 15 is more than 2 μm, the degree of interspersing of the interpenetrating mold will be increased, and the surface of the sheet may be lowered due to the falling of the material, and the normal insertion of the mold cannot be performed. Again, the step of applying a metal layer on the surface of the solid layer 15 is performed. The metal layer is formed by using at least one selected from the group consisting of ingot, copper, and titanium, and is preferably a cathode sputtering welding project having a thickness of 5 Å to 15 Å (4). If the thickness of the metal layer is less than (four) angstroms (A), the financial touch shows the texture; if the thickness of the metal layer 160 exceeds 15 angstroms (A), the unique texture of the three-dimensional pattern layer (9) 201121800 fails, and Increasing the thickness of the interspersed mold transfer film may cause a problem of reduced formability. Further, the metal layer 160 of the present invention may include, in addition to the color inherent to the metal, a printed layer having other colors as the f-view. At this time, only the p-injection (Sp^_) deposition operation is performed on the p-injury such as the appearance of the metal texture, and the remaining portion can be formed in accordance with the above-described step of forming the printed layer. Finally, the step of forming the adhesive layer 17G on the metal layer 16A is performed so that the interposer transfer film is seamlessly adhered to the molded product 200. At this time, the surface of the metal layer 16 is displayed as an uneven surface state due to the three-dimensional pattern layer 15G. An adhesive undercoat layer (6) is further formed between the metal layer 160 and the adhesive layer 17A. However, the step of adhering the undercoat layer 165 is not necessary, and the effect of the undercoat layer can be additionally applied only to the adhesive layer 170 of the present invention. Because of the formation of the adhesive layer 170, the surface of the %• metal layer 160 can be made more natural, and the bonding process of the molded product 200 can be smoothly performed. In the above, the present invention can exhibit a superior metallic texture through the three-dimensional pattern layer 15 进而, thereby further enhancing the decorative effect. In particular, the three-dimensional pattern layer 15 including the fine line pattern is used (the M material is used to show the metallic texture of the silver thin line pattern; for example, the copper is applied to form the 7F gold thin line pattern. In addition, if the above-mentioned fine case is combined with the positive or negative engraving When the logo of the pattern is used in combination, a more excellent case can be displayed. Fig. 2 is a side view of the three-dimensional pattern layer of the transfer film of the insert mold according to the present invention. "Fig. 2" is a silky ink shape. On the surface of the silk, there is a reading of the layer of 150' on the surface of the (4) logo, which forms an example of the texture of the metal of 201121800. When the product is visible, the logo of the facade will be formed. The intaglio mark is printed in the reverse direction, and the fine line pattern is applied to the insertion mold transfer film containing the pattern. As described above, according to the manufacturing method of the interposer transfer film of the present invention, transparent use is performed on the printed layer. The ink forms a three-dimensional _, the surface of which is _ metal layer, which can display the luxurious patterns, trademarks and logos of various styles, which are easy to operate. V» ' = Further, as described above, the interposer transfer film of the present invention has a high elongation rate due to the use of a semi-hardened ultraviolet (uv) coating, and is also excellent in formability after being subjected to a transfer operation of a transfer mold. The printing department and the release film can be separated from each other by the self-forming product Nayin. The subsequent operations can be omitted, and the convenience and productivity of the operation can be improved. The invention is not intended to limit the invention. The technical person of the present invention (4) #意_ The spirit and scope of the invention as disclosed in the scope of the patent application attached to the side of the invention, the modification and retouching of the present side The scope of protection defined by the present invention refers to the scope of patent application of Qing. [Simplified description of the drawing] Figure 1 is an anatomical view of the process of combining the mold-forming products of the (4); 2 is a side of a three-dimensional pattern layer of a transfer mold transfer film according to the present invention 201121800 [Main element symbol description] 100 base film 110 release layer 120 semi-rigid ultraviolet (UV) coating 130 undercoat layer 140 Perspective brush layer 150 patterned metal layer 160 adhesive layer 165 adhesive layer 180, 170 undercoat layer transfer film 200 is inserted mold molded product 13

Claims (1)

201121800 七、申睛專利範圍: h 一種穿插模具轉印膠片的製造方法,係包含以下步驟:先在器 材之上形成-離型層,然後在該離型層之上形成一半硬性紫外 _塗層’在該紫外(υν)塗層之上再形成一印刷層,在 該印刷層之上使用透明墨水形成一立體圖案層,在該立體圖案 層之表面熔敷一金屬層,最後在該金屬層之上形成一黏貼層。 2.如請求項第!項所述之穿插模具轉印膠片的製造方法,其中該 穿插模具轉印膠片係使用一聚乙稀對苯二甲酸醋⑽)或者 聚對苯二甲酸乙二g旨(PETG)樹脂製造。 3·如請求項第1項所述之穿插模具轉印膠片的製造方法,其中該 離型層係使用二聚氰胺離猶彳或者有機⑦離型劑製造。 4. 如請求項第1項所述之穿插模具轉印膠片的製造方法,其中該 半硬性紫外(UV)塗層以光硬性固體物之重量為1〇〇%,其中 軟質丙烯酸酯低聚物之重量為91%〜95%、感光起始劑之重量 為5%〜9%。 5. 如睛求項第4項所述之穿插模具轉印膠片的製造方法,其中該 軟質丙稀酸S旨低聚物選自:聚氨醋丙烯酸g旨、八甲基丙烯酸聚 氨酯、瓖氧丙烯酸酯、環氧丙烯酸曱酯、丙烯酸酯、曱基丙烯 酸曱酯、丙烯酸丙烯酸酯、聚酯丙烯酸酯、八胺改性丙稀酸之 中的至少一種。 6·如請求項第1項所述之穿插模具轉印膠片的製造方法,其中該 14 201121800 - 半硬性紫外(UV)塗層以光硬性固體物之重量為100,與有機 溶劑之重量份數為5〜45混合而形成。 ' 7.如請求項第1項所述之穿插模具轉印膠片的製造方法,其中該 印刷層將該金屬層作為背景之裝飾圖案(Decoration)層。 8’如请求項第1項所述之穿插模具轉印膠片的製造方法,其中該 半硬性紫外(UV)塗層與該印刷層之間增加一底塗層 (Primer) 〇 9,如請求項第1項所述之穿插模具轉印膠片的製造方法,其中該 立體圖案層之厚度為0.2〜20微米(um)。 10. 如請求項第9項所述之穿插模具轉印㈣的製造方法,其中該 立體圖案層細線(Hairline)圖案之厚度為0.2〜2微米(um)。 11. 如請求項第9項所述之穿插模具轉印膠片的製造方法,其中該 立體圖案層之陽刻或者陰刻圖案之厚度為0.2〜20微米(um)。 12. 如請求項第1項所述之穿插模具轉印膠片的製造方法,其中該 立體圖案層包含使用2種以聚氨酯樹脂類為主要化學成八之反 應型墨水。 β 13. 如請求項第1項所述之穿插模具轉印膠片的製造方法,其中該 金屬層選自鋁、銅、鈦中至少一種形成。 R如請求項第1項所述之穿插模具轉印膠片的製造方法,其中該 金屬層之厚度為50〜150埃(Α)。 八 15.如請求項第1項所述之穿插模具轉印膝片的製造方法,其中該 15 201121800 金屬層與該黏貼層之間增加一黏貼底塗層。 16.如請求項第1項至第15項中任何一項所述之穿插模具轉印膠 片的製造方法製造之穿插模具轉印膠片,其中該穿插模具轉印 膠片包括金屬質感之立體圖案。 16201121800 VII. Applicable Patent Range: h A manufacturing method for interspersed mold transfer film, comprising the steps of: forming a release layer on the device first, and then forming a semi-hard UV-coating on the release layer. Forming a printed layer on the ultraviolet (υν) coating, forming a three-dimensional pattern layer on the printed layer using transparent ink, depositing a metal layer on the surface of the three-dimensional pattern layer, and finally on the metal layer An adhesive layer is formed on top. 2. As requested in the article! The method of manufacturing a transfer mold transfer film according to the invention, wherein the interpenetrating mold transfer film is made of a polyethylene terephthalate (10) or a polyethylene terephthalate (PETG) resin. 3. The method of producing a transfer mold transfer film according to claim 1, wherein the release layer is made of melamine or an organic 7 release agent. 4. The method of manufacturing a transfer mold transfer film according to Item 1, wherein the semi-hard ultraviolet (UV) coating is 1% by weight based on the weight of the photohard solid, wherein the soft acrylate oligomer The weight is 91% to 95%, and the weight of the photosensitive initiator is 5% to 9%. 5. The method for producing a transfer mold transfer film according to Item 4, wherein the soft acrylic acid S is selected from the group consisting of polyacrylic acid acrylic acid, octamethyl acrylate polyurethane, and argon oxygen. At least one of acrylate, epoxy acrylate, acrylate, decyl acrylate, acrylic acrylate, polyester acrylate, and octaamine modified acrylic. 6. The method of manufacturing a transfer mold transfer film according to claim 1, wherein the 14 201121800 - semi-hard ultraviolet (UV) coating has a weight of the photohard solid of 100, and the weight of the organic solvent. It is formed by mixing 5 to 45. 7. The method of manufacturing a transfer mold transfer film according to claim 1, wherein the printed layer uses the metal layer as a background decoration layer. The method of manufacturing a transfer mold transfer film according to claim 1, wherein the semi-hard ultraviolet (UV) coating and the printed layer are provided with an undercoat layer (Primer) ,9, as claimed. The method for producing a transfer mold transfer film according to Item 1, wherein the three-dimensional pattern layer has a thickness of 0.2 to 20 μm. 10. The method of manufacturing the interpenetrating mold transfer (4) according to claim 9, wherein the three-dimensional pattern layer has a thickness of 0.2 to 2 micrometers (um). 11. The method of manufacturing a transfer mold transfer film according to claim 9, wherein the thickness of the positive or negative pattern of the three-dimensional pattern layer is 0.2 to 20 micrometers (um). 12. The method of manufacturing a transfer mold transfer film according to claim 1, wherein the three-dimensional pattern layer comprises two types of reaction inks using urethane resin as a main chemical. The method of manufacturing a transfer mold transfer film according to Item 1, wherein the metal layer is formed of at least one selected from the group consisting of aluminum, copper, and titanium. The method of manufacturing a transfer mold transfer film according to claim 1, wherein the metal layer has a thickness of 50 to 150 angstroms. 8. The method of manufacturing a transfer mold transfer knee according to claim 1, wherein the adhesive layer is added between the metal layer of the 15 201121800 and the adhesive layer. The interpenetrating mold transfer film produced by the method of manufacturing a splicing die transfer film according to any one of claims 1 to 15, wherein the interpenetrating die transfer film comprises a metallic texture. 16
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Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101278162B1 (en) * 2011-08-30 2013-06-27 (주)크루디앤피 A transcription film for in-mold injection having three-dimensional structure pattern layer and manufacturing method thereof
KR101382039B1 (en) * 2011-12-01 2014-04-14 (주)엘지하우시스 Interior film including three-dimentional pattern and method for fabricating the same
KR101337137B1 (en) * 2011-12-02 2013-12-05 (주)엘지하우시스 Insert molding film with 3d pattern and method of manufacturing the same
KR101426129B1 (en) * 2012-01-11 2014-08-05 (주)엘지하우시스 Hard-coating composition and decoration film including thereof with improving yellowing
KR101417247B1 (en) 2012-02-08 2014-07-08 (주)엘지하우시스 In-mold transcription film including elastic texture and method for manufacturing the same
CN102615882B (en) * 2012-04-09 2014-12-03 昆山同寅兴业机电制造有限公司 Composite appearance product with patterns and production method thereof
KR101479813B1 (en) * 2012-04-10 2015-01-06 (주)엘지하우시스 Hybrid cured pressure sensitive adhesive film
KR101437784B1 (en) * 2012-07-12 2014-09-15 (주)엘지하우시스 Interior Film having longitudinal hair line of various lengths and the manufacturing method thereof
CN102848757A (en) * 2012-09-25 2013-01-02 深圳市杰瑞表面技术有限公司 Rubbing method of stereoscopic pattern
CN102874003B (en) * 2012-09-25 2016-01-20 深圳市杰瑞表面技术有限公司 The printing transferring method of space pattern
CN103351718B (en) * 2013-07-23 2015-01-07 东莞市卓艺印刷制品有限公司 3D stereoscopic printing ink, and transfer film provided with 3D stereoscopic decorative layer and made by same
TWI552888B (en) * 2014-05-14 2016-10-11 正美企業股份有限公司 Transfer film including inner texture, shell using the same and the manufacturing methods thereof
CN104210268A (en) * 2014-05-29 2014-12-17 昆山华冠商标印刷有限公司 Transfer printing membrane with outer line, shell structure using transfer printing membrane, making method of transfer printing membrane and making method of shell structure
CN107839316A (en) * 2016-11-11 2018-03-27 佛山市长盛兴隆装饰材料有限公司 A kind of transfer printing wood grain film/paper and preparation method thereof, printing transferring method and wood grain stock
KR102656141B1 (en) 2016-12-23 2024-04-08 엘지디스플레이 주식회사 Display device
CN107488389B (en) * 2017-08-17 2019-12-03 东莞市卓艺印刷制品有限公司 A kind of antibacterial transfer film and preparation method thereof
KR102239655B1 (en) * 2017-10-12 2021-04-12 (주)엘지하우시스 A decoration film and methods for manufacturing the decoration film
CN108407484B (en) * 2017-12-29 2020-12-01 东莞光群雷射科技有限公司 UV transfer film and production process and application thereof
CN108297315A (en) * 2018-03-16 2018-07-20 深圳市迪嘉机械有限公司 A kind of plating fast plastic mould and its manufacturing method for injection molding
CN109941026B (en) * 2019-04-04 2023-05-16 谭宏伟 Floor surface digital printing archaizing processing technology
KR102102751B1 (en) * 2019-12-03 2020-04-21 주식회사 에스지글로벌 Decoration film
KR102169043B1 (en) * 2020-02-03 2020-10-22 이우종 Portable tumbler to keep water warm and cool contain precious serpantine
CN113263847A (en) * 2021-05-17 2021-08-17 安徽金彩防伪技术有限公司 Heat transfer gold stamping stained paper and heat transfer anti-counterfeiting printing process
CN114228362B (en) * 2021-12-16 2023-05-12 英狮科技(东莞)有限公司 Film forming method of transfer film with printed pattern and optical texture aligned
CN116021710B (en) * 2023-02-13 2023-10-17 东莞市冠荣商标织造有限公司 Process for making stereoscopic pattern trademark resistant to washing water and not easy to deform

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100481627B1 (en) * 1996-12-04 2006-01-12 주식회사 엘지화학 Method of manufacturing a plastic sheet having metallic effect
JP2003145673A (en) * 2001-11-13 2003-05-20 Katani Sangyo Kk Metallic-tone decorative laminate sheet
KR20040032016A (en) * 2002-10-08 2004-04-14 (주)나크리 Method for manufacturing film for insert molding
KR100529593B1 (en) * 2002-11-14 2005-11-22 주식회사 신한씨엔엠 Hot stamping foil
KR100642839B1 (en) * 2004-07-09 2006-11-10 (주)창조아이엠디 Printing film for Insert inmold and it's manufacturing method therefore
KR100638675B1 (en) * 2005-03-09 2006-10-30 이덕수 Silver-nanometer infrared rays transcription film and manufacturing process thereof
CN1939756A (en) * 2005-09-30 2007-04-04 佛山市顺德区汉达精密电子科技有限公司 Plastic surface treatment with metal character and three-dimensional pattern effect
CN200995575Y (en) * 2006-12-18 2007-12-26 汕头市东田转印有限公司 Transfer film with decorative-layer protection
JP2008155441A (en) * 2006-12-22 2008-07-10 Dainippon Printing Co Ltd In-mold transfer foil and molding using the foil
KR101023252B1 (en) * 2007-11-01 2011-03-21 주식회사케노텍 Multilayer stacked transfer sheet and manufacturing method thereof
US8445102B2 (en) * 2007-11-05 2013-05-21 Laird Technologies, Inc. Thermal interface material with thin transfer film or metallization
JP5155645B2 (en) * 2007-12-10 2013-03-06 日本写真印刷株式会社 Transfer material manufacturing method and transfer material excellent in foil burr resistance
TWM335394U (en) * 2008-01-18 2008-07-01 Jiin Mei Specialize Printing Co Ltd Transfer sticker structure
JP2009186510A (en) * 2008-02-01 2009-08-20 Fujifilm Corp Photosensitive composition, photosensitive film, photosensitive laminate, method for forming permanent pattern, and printed wiring board
JP2009248477A (en) * 2008-04-08 2009-10-29 Dainippon Printing Co Ltd In-mold transfer foil and molded product

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KR101240027B1 (en) 2013-03-06
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KR20110069462A (en) 2011-06-23
CN102180047A (en) 2011-09-14

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