TW201226552A - Liquid detergent composition for food processing equipment and/or cooking equipment - Google Patents

Abstract

The present invention is a liquid detergent composition for food processing equipment and/or cooking equipment, which contains components (a)-(d), listed below, wherein the component (b)/component (c) mass ratio is 1/10-10/1, and the total content of the (b) component and the (c) component is 4%-20% by mass. Component (a): 0.5%-10% by mass of one or more types of compound selected from oxidative halogen acids and salts thereof (or the oxidative halogen acid equivalent if an oxidative halogen oxoate is included); component (b): 0.5%-18% by mass of an amine oxide-type surfactant with one C8-C14 hydrocarbon group; component (c): 0.5%-10% by mass of a compound selected from one or more types of C12-C16 fatty acid or a salt thereof (or the fatty acid equivalent if a fatty acid salt is included); component (d): water.

Description

201226552 VI. Description of the Invention: [Technical Field] The present invention relates to a liquid detergent composition for food processing equipment and/or conditioning equipment. [Prior Art] The food processing plant will periodically (4) machine and equipment used for processing and/or conditioning the food when the production plan is interrupted, and ensure the hygienic condition. Examples of the apparatus to be cleaned include a mesh belt conveyor, a refrigerator, a slicer, and a rice mill. Examples of the equipment include a floor, a wall, a work table, and the like. Since the size of the cleaning objects is large, or the parts are interlaced and complicated, the method of cleaning the cleaning materials is usually a foam cleaning method in which the cleaning agent is foamed and then applied to the cleaning object. . The hair/package/month cleansing may be exemplified by the fact that the diluted solution obtained by diluting the detergent composition with water by 2 to 200 times with water is put into the spraying device, and the beads are sprayed and adhered by water pressure or air pressure. On the machine or equipment to be cleaned, 'hold (4), rub the (10) or sponge, or rinse with water without rubbing', thereby cleaning or sterilizing; or put the detergent composition directly into the spray device as the stock solution In the case where it is mixed with water by water pressure, sprayed, and adhered to a cleaning object. In the foam cleaning as described above, by applying the cleaning agent in a foam form, the residence time of the cleaning agent on the cleaning object becomes long, and the cleaning and sterilization effect is improved. Further, in the contact cleaning using the foam, since the treatment portion can be easily discriminated by visually confirming the looseness of the detergent, the advantage of the unnecessary scattering of the detergent 160300.doc 201226552 can be suppressed. A detergent composition as a machine and a device (ie, a food processing device and/or a conditioning device) used for cleaning and/or conditioning a food by foaming and cleaning, disclosed in Japanese Patent Laid-Open No. 2007 002014 An aqueous liquid detergent composition comprising an alkali metal citrate, an organic phosphonate, and a high foaming surfactant. In addition, as a cleaning agent which exhibits a cleansing and sterilizing effect, Japanese Patent Laid-Open No. 2010-150319, Japanese Patent Laid-Open No. Hei 9_5〇2747, Japanese Patent Laid-Open No. Hei 9-500680, Japanese Patent Laid-Open No. Hei No. Hei No. 2-214545, Japanese Patent A detergent containing a hypoxanthate is disclosed in JP-A-2008-539301. Further, it is disclosed in Japanese Patent Laid-Open No. 2〇〇8_53〇32〇 (W〇A 2〇〇6/〇87〇99) containing a hypoxanthate, a quaternary ammonium salt, an amine oxide surfactant, and a fatty acid. combination. SUMMARY OF THE INVENTION The present invention relates to a liquid detergent composition for food processing equipment and/or conditioning equipment, comprising: (a) a compound selected from the group consisting of oxidizing functional acids and salts thereof [hereinafter referred to as (a) component: 0.5 to 10% by mass (wherein, in the case of containing an oxidizing acid salt, it is referred to as an amount of oxidized tooth acid), (b) having one hydrocarbon group having a carbon number of 8 to 14 The amine oxide type surfactant [hereinafter referred to as component (b)] is 0.5 to 18 mass. / 〇, (c) a compound selected from one or more of the above-mentioned fatty acids having a carbon number of 12 to 16 and the like (hereinafter referred to as component (c)): 0.5 to 10% by mass (wherein, in the case of containing a fatty acid salt) Refers to the conversion amount of fatty acid), and 160300.doc 201226552 (d) water [hereinafter referred to as (d) component]; and the mass ratio of component (b)/(c) is 1/10~1〇/1 'The total content of the component (b) and the component (c) is 4 to 20% by mass. The present invention relates to a method of cleaning a food processing device and/or conditioning device using the above-described food processing device and/or conditioning liquid cleaning composition of the present invention, comprising the following steps 1 to 3. Step 1: The liquid detergent composition for food processing equipment and/or conditioning equipment is pre-diluted by water at a dilution ratio of 2 to 200 times, and/or diluted on one side, and sprayed in a foam form to adhere to food processing. Steps on the equipment and/or conditioning equipment; Step 2: The step of maintaining the foam for a certain period of time; Step 3: The step of rinsing the food processing equipment and/or conditioning equipment with water. Further, the present invention relates to a method of cleaning a food processing device and/or a conditioning device, which has a step of spraying the cleaning liquid in a foam form to adhere to the food processing device and/or the conditioning device, and then rinsing with water. Step 'The cleaning liquid contains (a) a component of 0.0025 to 2% by mass, (b) a component of 〇_〇〇25 to 3.6 mass%, (c) a component of 0.0025 to 2 mass%, and (a component, and (b) component The mass ratio of the /(c) component is i/iOMOM, and the total content of the component (b) and the component) is 〇.〇2 to 4% by mass, and (a) component/[(b) component + (c) component The mass ratio is 1/10~2.5/1. [Embodiment] The cleaning composition used in the cleaning food processing equipment and/or the conditioning equipment has the ability to be cleaned and sterilized, and is suitable for the above foaming cleaning, and requires foaming property (ease of foaming) ), or the stability of the contact foam 160300.doc 201226552 Excellent. The previous liquid flocculating agent composition for food processing equipment and/or conditioning equipment was mainly developed for the development of secret or material (4), and represented by the technology described in Japanese Patent Laid-Open No. 2007_002014, and the prior food processing. Most of the equipment and/or conditioning liquid detergent compositions achieve sufficient foaming or soaking stability. These prior food processing equipment and/or conditioning liquid cleaning compositions are used in: (4) It is necessary to use a flushing water of A amount to rinse, which is disadvantageous in terms of economy, and it is a load change A (consumption f operation time), and is also disadvantageous in terms of environmental load. However, there is a trade-off between the foaming/bubble stability during cleaning and the scouring scouring during rinsing, and it is very difficult to satisfy both properties at the same time. On the other hand, as a cleaning agent which exhibits a clean and bactericidal effect, it is disclosed in Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei 9-502747, Japanese Patent Laid-Open No. Hei 9-502747, and Japanese Patent Laid-Open No. Hei 9-5-G. Metal salt, amine oxide type surfactant and fatty acid metal salt technology, but Japanese Patent Special Open 2010-15 () 319 is the technology for liquid cleaning of drain pipe (4), Japanese Patent Special Table 9-502747 is a sub-gas salt The technology of concentrating aqueous bleaching detergent on the base, in addition, the patent special specification 9_5〇〇68〇 is a technology of concentrated aqueous bleach cleaner containing short-chain surfactant, neither of which suggests food processing sigh and / or the problem in the cleaning agent for equipment and its solutions. Moreover, according to the contents of the above-mentioned Japanese Patent Laid-Open No. 2010-1503 19, Japanese Patent Special Table 9-5G2747, and Japanese Patent Special Table 9_5_8 (), it is not conceivable to use a specific ratio/specific content. The use of an amine oxide type surfactant and a fatty acid alkali metal salt can realize a food processing apparatus and/or conditioning capable of satisfying both the stability of the 160300.doc 201226552 foaming clear material and the foam flushing property during rinsing. Use a clean sword for the equipment. As noted above, in terms of adaptability to foam cleaning, detergent compositions used in cleaning food processing equipment and/or conditioning equipment require foaming/foam stability and bubble rinsing upon rinsing. coexist. Therefore, it is preferred to prepare an interfacial active sword in advance in the formulation composition in such a manner that it is filled with a splashing g such as a foaming/foam stability, and the granules must be formulated with rinsing properties. Higher surfactants act as surfactants. As a surfactant with high rinsing properties, soap is known, but the choice of the chain length of the base chain of the fattening is very important. If the base of the base is shorter, the dilution will reduce the irrigability, and if If the bond is long, the viscosity of the solution becomes high, even at low temperatures, or even at room temperature, which makes the formulation difficult. Therefore, it is very difficult to achieve a high concentration of the surfactant and maintain the stability of the solution at a low temperature, and the foaming/bubble stability and the rinsing property at the time of dilution use are all satisfied. Japanese Patent Laid-Open No. 2008-214545 ^^^^^^/^/ A liquid amine detergent composition of an amine oxide, but the concentration of soap or amine oxide in the liquid composition is low, if the liquid charm is directly The stock solution used in the product 'm must be used in large quantities, and the transportation cost becomes too large. In this regard, it is also desirable to formulate the surfactant at a high concentration in the detergent composition used in the cleaning food processing equipment and/or conditioning equipment. A composition containing an oxidizing compound, an alkali metal, a trialkylamine oxide, a buffer, and an electrolyte is disclosed in the Japanese Patent Laid-Open Publication No. Hei 8-539301, but is related to being easily injected and flowing through a fully automatic washing machine. Concentrated bleaching agent for dispenser 160300.doc 201226552 (dlspenser), it is not conceivable to implement a cleaning agent for food processing equipment and/or conditioning equipment. Further, the composition of the patent specification No. 2-8-5393 〇1 is inferior in foaming condition even if it is diluted to be foamed, and is not suitable for foam cleaning. The present invention provides a food processing apparatus and/or conditioning having a high concentration of a surfactant which exhibits excellent foaming/foam stability when used for foam cleaning and exhibits excellent foam flushing upon rinsing. Liquid detergent composition for equipment. Further, the present invention provides an interface which is excellent in stability at a low temperature and exhibits excellent foaming/foam stability when used for foaming cleaning, and exhibits excellent bubble washability upon rinsing. A liquid detergent composition for food processing equipment and/or conditioning equipment having a lower concentration of active agent. The applicant of the present invention conducted an effort to study the above-mentioned subjects, and as a result, found that an amine oxide type surfactant and a fatty acid (or a salt thereof) are used at a specific ratio/specific content in a system containing an oxidizing acid (or a salt thereof). The invention can realize the food processing equipment and/or the cleaning agent for conditioning equipment which simultaneously satisfy the foaming/bubble stability during foam cleaning and the foam flushing property during rinsing, thereby completing the present invention. . According to the present invention, it is possible to provide a food having a high concentration of a surfactant which exhibits excellent A-type/bubble stability when used for foaming cleaning and exhibits excellent bead flushing property upon rinsing. A liquid detergent composition for curing equipment and/or conditioning equipment. Further, according to the present invention, it is possible to provide a solution which is excellent in stability at a low temperature and which exhibits excellent foaming/foaming 160300.doc 201226552 stability when used for foam cleaning, and is excellent in rinsing. The surfactant concentration of the foam flushing agent is higher than that of the food processing equipment and/or the liquid detergent composition for conditioning equipment. The composition of the invention has a low viscosity. Before describing the configuration of the present invention in detail, please pay attention to the meaning of the following terms. That is, in the present invention, the term "food processing equipment and/or conditioning 5 is prepared" is a machine and equipment used in the processing of food and/or conditioning in an Italian food processing factory. Examples of the machine include a mesh belt conveyor, a refrigerator, a slicer, a rice mill, and the like. Further, examples of the apparatus include a floor, a wall, a work table, and the like. In the present invention, the phrase "liquid detergent composition for food processing equipment and/or conditioning equipment" means a liquid detergent composition for cleaning the above "food processing equipment and/or conditioning equipment", and more particularly, It means a liquid detergent composition for cleaning the above-mentioned "food processing equipment and/or conditioning equipment" by foam cleaning. Here, please note that the "liquid detergent composition for food processing equipment and/or conditioning equipment" of the present invention does not include a detergent composition for a drain pipe. The reason for this is that the "liquid detergent composition for food processing equipment and/or conditioning equipment" of the present invention is retained in the piping by foaming, which has an effect on the rinsing, and is therefore not suitable for a cleaning agent combination for a drain pipe. The matter (the foam cleaning cleaning composition is not suitable as a detergent for a drain pipe can also be referred to the above paragraph 0004 of the special opening 2〇i 0-150319). The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention contains the following components (a) to (d). <(a) component> 160300.doc 201226552 (4) The component is selected from oxidized teeth. a compound of more than one of the acid and its salts. Examples of the oxidizing property include a sub-gas acid, a hypo-acid acid, and a sub-gas acid. From the viewpoint of bactericidal properties, a sub-gas acid is preferred. Further, examples of the salt of the oxidizing functional acid include a metal salt of a sub-gas acid, a (tetra) acid, and a sub-gas acid. More preferably, it is a salt. In terms of bactericidal properties and versatility, t is preferably an alkali metal salt of a hypogastric acid, of which sodium hypochlorite is preferred. When the content of the component (4) in the liquid detergent composition for foodstuffs and/or conditioning equipment of the present invention is 〇5% by mass to 1, a sufficient bactericidal effect can be obtained', and from the viewpoint of use sensation Preferably, it is (four) mass% or less. The content of the component (4) is from 0.5 to 10% by mass, preferably from 5 to 8 mass%, more preferably from 2 to 5 mass%, from the viewpoint of obtaining a sufficient bactericidal effect and a good feeling of use. In the case where the oxidized dentate is contained in the component (4), the above content is a value which is a converted amount of oxidized dentate. <(b) Component> The component (b) is an amine oxide type surfactant having one hydrocarbon group having 8 to 14 carbon atoms. The hydrocarbon group having a carbon number of 8 to 14 contained in the molecule may, for example, be an alkyl group or an alkenyl group, and the like may be a direct bond or a branched chain, but may contribute to low-temperature stability of the solution and rinse time. The foam flushing property is preferably an alkyl group having a carbon number of 8 to 12. The component (b) is, for example, an amine oxide type surfactant having i hydrocarbon groups having 8 to 14 carbon atoms and 2 alkyl groups having 1 to 6 carbon atoms or hydroxyalkyl groups having 5 carbon atoms. The amine oxide type surfactant is preferably a compound represented by the following formula (A). 160300.doc •10· 201226552

R

X

2 R m

ο 3—>4 RINIR (wherein R4 is a hydrocarbon group having a carbon number of 8 to 14, R, a carbon number of η, and R, R is independently a carbon group having a carbon number of (1) or a base group. Base, X is a horse--...NHC0...c〇NH·, a base of 〇 or a number of 1) In the above formula (1), R1 is preferably a hospital base having a carbon number of 8 to 14 or a More preferably, the number is 8 to 12 alkyl groups or sulfhydryl groups from the viewpoint of the scouring property at the time of rinsing. Rl may also be an alkylene structure derived from natural fats and oils, and is preferably a direct bond from the viewpoint of using a natural raw material. Specific examples of the compound which is preferably a compound are exemplified in the formula: R) tR1 is a group selected from the group consisting of a sylvestre group, a fluorenyl group, a fluorenyl group, a decyl group, and a dodecaine group, R3, R4. Both are methyl and melon. Among the compounds, in view of the foam flushing property at the time of rinsing, it is more preferable that it is a decyl group, R3 and R4 are each a methyl group, and a compound of m*0 (ie, a dodecyl group) Dimethylamine oxide). The component (b) may be used singly or in combination of two or more. Among them, from the viewpoint of solution stability of the formulation solution and bubble washability at the time of rinsing, it is preferred to use an amine oxide type surfactant having one carbon number of 8 to 12 in the molecule. Or, an amine oxide type surfactant having a carbon number of 8 to 12 in the molecule may be used in combination of 160300.doc -II - 201226552. More preferably, it is used in combination with dodecyldidecylamine oxide and octyldimethylamine oxide. When the content of the component (b) in the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is 0.5% by mass or more, sufficient foaming can be obtained without being affected by the load of the fouling load. In view of the compatibility, it is preferably at least 8 mass% or less from the viewpoint of blending properties. The content of the component (b) is 〇5 to 18% by mass, preferably 0.5 to 15% by mass, from the viewpoint of achieving sufficient foaming property and foam stability at the time of foam cleaning and good blending property. More preferably 2 to 15 mass. /〇, further preferably 3 to 1% by mass. The present invention is in view of the solution stability of the solution preparation (the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, also referred to as the formulation solution, the same applies hereinafter) and the foam flushing property upon rinsing. The liquid detergent composition for food processing equipment and/or conditioning equipment preferably contains: an amine oxide type surfactant having a hydrocarbon group of 8 to 10 carbon atoms [hereinafter referred to as (bl) component], and having 1 An amine oxide type surfactant (hereinafter referred to as a component (b2)) having a hydrocarbon group of 12 carbon atoms. In this case, the mass ratio of the content of the (bl) component to the content of the component (b2) [mass ratio of the content of the (bl) component/the content of the (b2) component is preferably from 0.1 to 0.95, and further preferably. For 〇.2~〇5. The (bl) component is preferably an amine oxide type surfactant having one hydrocarbon group having 8 carbon atoms. As described above, as the component (b), it is preferably an octyl group which is equivalent to the (b 1) component. The base amine oxide is used in combination with the twelve-yard dimethyl amine oxide equivalent to the (b2) component. Further, from the viewpoint of low-temperature stability, the content of the amine oxide type surfactant having one hydrocarbon group having a carbon number of 160,300.doc -12 to 201226552 14 is preferably 〇~〇 〇 1% by mass. <(c) component> The component (c) is a compound selected from the group consisting of a fatty acid having 12 to 16 carbon atoms and a salt thereof. As an example of the preferable component (c), a salt of lauric acid, myristic acid, pentadecanoic acid, palmitic acid, or the like, which is a solution which contributes to the solution stability of the solution and the foam at the time of rinsing, may be mentioned. The flushing property is preferably a salt of lauric acid, myristic acid or the like. Here, as the salt, a metal salt can be enumerated, and among them, a sodium salt or a potassium salt is preferred. By setting the content of the component (c) in the liquid detergent composition of the food processing device and/or the conditioning device of the present invention to 5% by mass or more, good foaming property at the time of rinsing can be achieved, and From the viewpoint of foam stability at the time of foam cleaning, it is preferably i 〇 by mass or less. The content of the component (c) is from 0.5 to 10% by mass, preferably from 1 to 10% by mass, in terms of sufficient foam stability at the time of foaming cleaning and good foaming property at the time of rinsing. Good for 2.5 to 8 mass ° /. Further, it is preferably 3 to 5% by mass. In the case where the component (c) contains a fatty acid salt, the above content is a value which is a converted amount of the fatty acid. From the viewpoint of low-temperature stability, the liquid detergent composition for food processing equipment and/or conditioning apparatus of the present invention preferably contains (b2) as component (b) and as component (c) selected from carbon. The mass ratio of the content of the compound of one or more of the fatty acids of 14 or the like (hereinafter referred to as (cl) component] to the content of the component (b2) (hereinafter referred to as the content of the (cl) component / ( The mass ratio of the content of the component b2) is 0 to 2.5. The mass ratio of the (cl) component/(b2) component content is more preferably 〇2, and further preferably 〇~丨7. 160300.doc -13- 201226552 From the viewpoint of low-temperature stability, in the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, the content of the (bl) component is relative to the l(bl) component and The mass ratio of the total content of the Cl component (the content of the component ((8)) + the content of the component (C1)]] is described below as the content of the component (b) (the content of the (bi) component + the content of the (cl) component] The mass ratio is preferably a mass ratio of the content of 〇3 to 卜 component/the content of [(bi) component + content of (cl) component] is more preferably 0.4 to 1 ' and further preferably 〇5 to 1. In order to exert the desired effect of the present invention, it is important to set the content ratio of the component (b) to the component (c) and the total content thereof in a specific range. In other words, the ratio of the component (b) to (the content ratio of the bismuth component (described as the mass ratio of the component (b) component/(c) component, or the mass ratio of the component (b) component/(c) component), From the viewpoint of the solution stability of the formulation solution and the foam stability at the time of foam cleaning, § 'preferably 1 / 1 〇 or more' is preferably 丨0 from the viewpoint of the scouring property at the time of rinsing. /1 or less. The quality of (b) component / (c) component can be achieved at a higher level of solution stability of the formulation solution, foam stability during foam cleaning, and bubble flushing upon rinsing The ratio is preferably from 1/10 to 10/1, more preferably from 丨/8 to 6/1, still more preferably from 1/5 to 5/1. Regarding the total content of the components (b) and (c), The transportation cost of the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention and the sufficient foaming property at the time of foaming cleaning are preferably 4% by mass or more, and when used, The operability and the scouring property at the time of rinsing are preferably 20% by mass or less, so that the foaming can be cleaned at a higher level. The total content of the component (b) and the component (c) is suitably 4 to 2% by mass, 160300.doc -14 - 201226552 is preferably 5~ from the viewpoint of the coexistence of the foaming property at the time of rinsing. 20% by mass is further preferably 6 to 15% by mass, more preferably 7 to 1% by mass. The content of the U) component is based on the total content of the component (b) and the component (c) [described as (b) a ratio of the component + (c) component or the component (b) component + (c) component content (that is, the mass ratio of the component (a) component / [(b) component + (c) component], Or the content of the component (a) / the mass ratio of the content of the component (b) and the component of the component (c) are important for the foaming property or foam stability of the diluted solution. The liquid detergent composition for processing equipment and/or conditioning equipment is foamed by a dilution solution of water (especially water containing a hardness component) diluted by 2 to 200 times (preferably 5 to 200 times). The quality of the '(a) component / [(b) component + (c) component] is preferably 1/10 to 2.5/1 ' and further preferably 1/7-2 from the viewpoint of the stability of the bead and the stability of the bead. /1, better 1/5~1/ 1, and more preferably 1/5 to 7/10. Further, in terms of low-temperature stability of the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, (&) component / [ The quality of the component (b) component + (c) is preferably i/ioq/i, more preferably 1/7 to 1/1', more preferably 1/5 to 1/1, and still more preferably 1/1. 5 to 7/10. The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention exhibits excellent foaming/foam stability when used for foam cleaning in dilution, and has a rinse-up property From the viewpoint of excellent foam flushability and excellent low-temperature stability, it is preferred that the component (b) contains an amine oxide-type surfactant component having one hydrocarbon group having 8 to 10 carbon atoms, and has 1 An amine oxide type surfactant (component (b2)) having a hydrocarbon group of 12 carbon atoms, and an amine oxide type surfactant having a hydrocarbon group of 14 carbon atoms as component (b) is 0 to 0.01 mass % ' as component (c) is selected from carbon numbers 14 • 15 - 160300.d〇c

The content of the compound ((cl) component, the content of the (bl) component, and the content of the component (b2) of the fatty acid and the salt thereof in 201226552 satisfy the following conditions (i) and (ii), and (a) ) The mass ratio of the component / [(b) component + (4) component] is 1/10 to 1/1 〇 Condition (i) : The mass ratio of the content of (cl) component / the content of (b2) component is 0 to 2.5 ° Condition (ii): The mass ratio of the (bl) component/[(bl) component + (cl) component I] is 〇·3~1. <Component (d)> In the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention, the remainder other than the components (a) to (c) above may be referred to as water [i. d) ingredients]. As the water, ion-exchanged water containing no hardness component can be preferably used. The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is preferably strongly alkaline from the viewpoint of cleanability, and is preferably formulated as a base. As the test, 'the metal hydroxide or the metal test salt can be cited. Examples of the hydroxide of the alkali metal include sodium citrate, which is an alkali metal such as sodium hydroxide or potassium hydroxide, and examples thereof include sodium citrate and potassium citrate, and specific examples thereof include sodium hexanoate and sodium citrate. Original sodium, sodium citrate No. 1, sodium citrate No. 2, sodium citrate No. 3, sodium citrate No. 4, potassium citrate, potassium citrate. The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is preferably a 5 mass% aqueous solution diluted 2 times with water at a pH of 11.5 or more at 2 °C. Here, the value of 311 is a value measured using pH METER F_ 21 (manufactured by Horiba, Ltd.). 160300.doc -16· 201226552 The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention may also contain hydroxyethene-i,i- from the viewpoint of foam stability during foam cleaning. An organic phosphonate such as a phosphonate. However, if the amount of the organic phosphonic acid salt is large, there is a case where the foaming property at the time of rinsing is affected, and therefore it is important to adjust the amount so as not to impair the foaming property. Specifically, the content of the organic phosphonate in the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is preferably 〇% by mass or more and less than 0.5% by mass, and the foam is washed out during rinsing. From the standpoint of sex, it is more preferred to be free of the organic phosphonate. The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention may also be generally used in liquid detergent compositions for food processing equipment and/or conditioning equipment within a range that does not inhibit the desired effects of the present application. Any other surfactant, chelating agent, foaming agent, water-increasing solvent, coloring agent, perfume, builder, rust inhibitor, viscosity modifier and the like. The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is a liquid at a temperature ranging from 10 ° C to 60 ° C. Specifically, it is preferable that the fluidity having a viscosity of 3,000 mPa·s or less in the range of 10 C to 60 C is more preferably 2,000 mPa·s or less and further preferably 8 Å mPa·s or less. The liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention preferably does not impair the stability of the solution even below 10 ° C, and is preferably even below 〇 ° C or even -5 ° C. Transparency is also maintained in the environment without freezing. The preparation method of the liquid detergent group 160300.doc -17· 201226552 of the food processing equipment and/or conditioning equipment of the present invention is not particularly limited, and for example, it can be prepared by the following method: The raw materials (amine oxide, fatty acid, etc.) are mixed at 40 to 8 (TC temperature to obtain a homogeneous and transparent mixture, and then 7 is slowly cooled, and after confirming that it becomes 4 CTC or less, an oxidative dentate is prepared. '<Food Cleaning Method of Processing Apparatus and/or Conditioning Apparatus> The liquid cleaning composition for food processing equipment and/or conditioning apparatus according to the present invention is suitably used in a cleaning method comprising the following steps 1 to 3, 'Step 1: The liquid detergent composition for food processing equipment and/or conditioning equipment is pre-diluted by water at a dilution ratio of 2 to 200 times (preferably 5 to 2 times), and/or diluted while being sprayed in a foam form. a step of attaching it to the food processing equipment and/or conditioning equipment; Step 2: a step of maintaining the beads for a certain period of time; and Step 3: a step of rinsing the food processing equipment and/or conditioning equipment with water; In the first embodiment, the liquid detergent composition for food processing equipment and/or conditioning equipment of the present invention is pre-diluted by water at a dilution ratio of 2 to 200 times (preferably 5 to 2 times), and is foamed. Alternatively, the liquid detergent composition for food processing equipment and/or conditioning equipment may be placed in a dedicated container, and directly connected to the water pipe by a hose or the like, and mixed while being mixed and sprayed in a foam form. Combining the above pre-dilution and simultaneous dilution to spray the diluted solution of the liquid detergent composition for food processing equipment and/or conditioning equipment in a foam form. The dilution ratio in step! is 2 to 2 times, preferably 5~ 200 times 'better than 2〇~1〇〇 times. Here's the water used for dilution, which is generally assumed to be water containing hardness as water. For the hardness of the water used for dilution, 18 · 160300.doc

201226552 From the viewpoint of foam stability at the time of cleaning, it is preferably within the range of New Zealand, and more preferably within the range of U~Cai, and more preferably in the range of 0. Preferably, it is in the range of G1 to 12°dH, more preferably in the range of G.1 to 8°dH, and more preferably in the range of 〇"~4. New Zealand. The dilute solution of the liquid detergent composition for processing equipment and/or conditioning equipment is sprayed in a foam form, and preferably, the following aspect is adopted: a diluted solution obtained by diluting a specific ratio with water is appropriately filled into a special foam. In the cleaning machine, the air/compressed air from the outside is mixed and sprayed in a foam form. In the diluted solution (cleaning liquid), the components (b) and (c) of the composition of the present invention (in the case of containing a fatty acid salt) The total content of the fatty acid equivalent amount is preferably 〇〇2 to 4% by mass, more preferably 〇% by mass. When a processing area such as a production line in a food processing factory is large, a foam cleaning machine can be preferably used (for example, "SCU_HF", Spraying "KF-100", "KF_2〇〇", manufactured by Kao Co., Ltd.). Trigger sprayer or A manual sprayer capable of intermittently generating a foam, such as a foamer sprayer. In step 1, it is preferred to spray in a foam form without intermittently. Here, the stomach is "not intermittently" sprayed. , which means that the foam cleaning machine is used to continuously spray the cleaning agent in a foam shape during the opening period (for example, 5 seconds or more) by a lever or a switch, which is different from the "intermittent" injection, for example, using a trigger type. A manual sprayer such as a sprayer or a bubbler sprayer that ejects when the lever is pulled and instantaneously stops the spray-like spray pattern. 160300.doc •19· 201226552 Using a foam cleaner without intermittently foaming The sprayed state is more effective when the area or scale of the food processing equipment and/or conditioning equipment to be cleaned is large. When using a bead cleaner, the expansion ratio (the volume of the beads (mL) /bubble The weight (g) ratio) is preferably suitable 3~5〇 = 5 ~ 40 times further than the times 'more preferably! .~4. Times and' injection pressure at the time of the move). It is preferable to set it to 0.H MPa, and it is more preferable to set it as 〇2~〇8 chest, and it is more preferable to set it as 2 to G.5 MPa. When the manual foaming sprayer or the like is used, the foaming magnification is preferably 2 to 3 times, more preferably 2 to 20 times, and more preferably, the foaming magnification is preferably 2 to 3 times. It is 3 to 1 times. In the steps! The food processing equipment and/or the body cleaner composition of the present invention are used for the processing of the stock solution and/or the conditioning equipment, and the latter is kept small for the maintenance of the bubble in step 2 - time ( From the viewpoint of workability, ▲ X is preferably from (10) minutes to 45 minutes in terms of the mechanism and the viewpoint of each device. Further preferably, it is preferably 1 minute, more preferably 1 is better.八八姑· More preferably 1 to 2 0 minutes, more preferably 1 to 15 minutes, more preferably w clock. Also, from the viewpoint of cleanliness, it is preferably 1 to 5 minutes, preferably 1 to 6 〇min, more preferably J, step 2 to keep the beads for a minute. For 15~45 minutes, and then preferably 20~30, the time for holding the foam in step 2 is different depending on the occasion, there is no special dilution. The magnification or the dilution ratio τ of the W times) is, for example, 2 to 50 times (preferably, the clock is further preferably 50 to 200 times the time of the foaming process is preferably) to 60 minutes. Preferably, the foam is stably maintained at 160300.doc •20·201226552 for 1 to 10 minutes. During the period of 2iM, the foam is kept, a little water, etc. (4) Do not move, you can also add the bubble to keep the machine for a certain period of time, the equipment and / or conditioning equipment.,, medium, first '7 rinse food plus water temperature is suitable is preferably 7〇C, more preferably 2 〇~耽. As the rinsing water, tap water can be used, and it can be adjusted to the above-mentioned preferred water temperature, and can also be used after heating. Usually, it is washed by a human hand by a hose or the like. Or the liquid detergent composition for conditioning equipment has excellent blister flushing properties at the time of rinsing, and requires less flushing water than the previous detergent composition, and has a side effect in terms of genomics, and is also significantly helpful. The work load (work time or number of workers) or environmental load is reduced. 〃 The following 'is a view of the present invention. <First item> A method of cleaning food processing equipment and/or conditioning equipment, which is used as follows Liquid detergent composition for food processing equipment and/or conditioning equipment 'The liquid detergent composition contains: (a) selected from oxidative dentate (preferably hypogastric acid, hypobromous acid, nitrous acid, 吏佳Citric acid) and its One or more compounds ((a) component) of the salt (preferably an alkali metal salt, more preferably a sodium salt) 〇5 to 丨〇 mass% (preferably, 5 to 8 mass%, further preferably 2) ～5% by mass) (wherein, in the case of #oxidative dentate, it is referred to as oxidized tyrosine), and (b) has one hydrocarbon group having 8 to 14 carbon atoms (preferably linear) Or a branched alkyl group, or a linear or branched alkenyl group, an amine oxide type surfactant ((1?) into 160300.doc 21 201226552) 0·5~18% by mass (preferably 2~) 15% by mass, further preferably 3 to 〇 mass%), (c) a salt selected from the group consisting of a fatty acid having a carbon number of 12 to 16 and the like (preferably an alkali metal salt, more preferably a sodium salt or a potassium salt) And a compound of one or more kinds of "smooth components" is 0.5 to 1% by mass (preferably 1% by mass, more preferably 25% to 8% by mass, still more preferably 3 to 5% by mass) (where In the case of a fatty acid salt, it refers to the amount of the fatty acid), and (d) the water ((d) component); (b) the content of the component / the content of the component (c) is ι/ι〇〜ι 〇/ι (preferably 1/8~6/1, Further, it is preferably 1/5 to 5/1), and the total content of the component (b) and the component (c) is 4 to 20% by mass (preferably 5 to 2% by mass, and more preferably 6 to 15). % by mass, more preferably 7 to 1% by mass); and the cleaning method comprises the following steps 1 to 3: Step 1. Using a liquid detergent composition for food processing equipment and/or conditioning equipment by water 2~ 200 times (preferably 5 to 200 times, more preferably 2 〇 to 1 〇〇 times), the dilution ratio is pre-diluted 'and/or diluted on one side, and sprayed in a foam form to adhere to food processing equipment and/or Step of conditioning the device; Step 2: Maintaining the foam for a certain period of time (in terms of the mechanism and workability of each device, it is preferably 丨~6〇 minutes, more preferably 丨minute minutes; further preferably For the 30 minutes, it is more preferably 2 minutes, more preferably 1 to 15 minutes, more preferably 1 to 10 minutes, and even more preferably 1 to 5 minutes; again, the point of view is s, preferably 10~ 6 〇 minutes, more preferably 15 to 45 entries, push Z * and then preferably 20 to 30 minutes); Step 3. Wash food processing equipment and / or conditioning with water Prepare the steps. 160300.doc

• 22· 201226552 &lt; Item 2&gt; The method of cleaning food processing equipment and/or conditioning equipment according to &lt;Item 1&gt;, wherein step 1 is a combination of a liquid cleaning agent for food processing equipment and/or conditioning equipment The material is pre-diluted by water at a dilution ratio of 2 to 200 times (preferably 5 to 200 times, more preferably 2 to 100 L), and/or diluted while being sprayed in a foam-like manner without intermittently. Step of attaching to the food processing equipment and/or conditioning equipment &lt;Item 3&gt; The cleaning of the food processing equipment and/or conditioning equipment such as <Item 1> or &lt; Item 2&gt; The mass ratio of the content of the content component of the component to be used is 1/1 〇 to 2 5/1 (preferably 丨/(7) 丨 / 丨, more preferably 1/1 and further preferably A liquid detergent composition for food processing equipment and/or conditioning equipment of 1/5 to 1/1, and more preferably 1/5 to 7/10). &lt; Item 4&gt; The cleaning method of the food processing equipment and/or the conditioning apparatus according to any one of the items <1> to <3>, wherein the component (4) is selected from the group consisting of myristic acid a liquid detergent composition for food processing equipment and/or conditioning equipment for lauric acid and its salts (preferably a metal salt, more preferably a salt of a salt or a compound of the genius). 5 items&gt; The cleaning method of the food processing equipment and/or the rational equipment of the item [Item 1] to <4>, wherein the component (8) contains i having a carbon number of 8~ An amine oxide type surfactant (component) which is preferably a domain or a branched alkyl group or a linear or branched group, and a hydrocarbon group having i carbon number 160300.doc -23-201226552 12 An amine oxide type surfactant (a component of (b2)) which is preferably a linear or branched alkyl group or a linear or branched alkenyl group, and has one carbon number of 14 as component (b) The content of the hydrocarbyl amine oxide type surfactant is 0 to 0.01% by mass. &lt;6th item&gt; The method of cleaning a food processing device and/or a conditioning device according to the item <5>, wherein the component (c) is selected from the group consisting of a fatty acid having 14 carbon atoms and salts thereof The content of one or more of the compounds (component (cl)), the content of the (bl) component, and the content of the component (b2) satisfy the following conditions (1) and (ii): Condition (i): Content of the component (cl) / (b2) The mass ratio of the content of the component is 〇~2.5; Condition (ii): The mass ratio of the component (b)/[the content of the (bl) component + the content of the ((:1) component] is 0.3 to 1. The cleaning method of the food processing equipment and/or the conditioning apparatus according to any one of the items of the present invention, wherein the component (a) is selected from the group consisting of A liquid detergent composition for food processing equipment and/or conditioning equipment for a compound of one or more of a gas acid and a salt thereof. &lt;Item 8&gt; A liquid detergent composition for food processing equipment and/or conditioning equipment, It comprises: (a) a salt selected from the group consisting of oxidative dentate (preferably hypogas, hypobromous acid, more preferably hypochlorous acid) and the like (preferably an alkali metal salt) More preferably, one or more of the compounds ((4) component) 〇.5 to 1% by mass (preferably Jn. 5 to 8% by mass, and further preferably 2 to 5% by mass) (including Oxidizing south acid salt 160300.doc •24·201226552 in the case of oxidized tooth acid), (b) having one hydrocarbon group having 8 to 14 carbon atoms (preferably linear or branched) The alkylamine-type or linear or branched alkenyl group of the amine oxide type surfactant (〇3) is 0. 5 to 18% by mass (preferably 2 to 15% by mass, and more preferably 3 to 3). (1% by mass), (c) one or more compounds selected from the group consisting of a fatty acid having a carbon number of 12 to 16 and a salt thereof (preferably an alkali metal salt 'more preferably a sodium salt or a potassium salt) ((0) The component is 0.5 to 1% by mass (preferably 丨〇1 to 1% by mass, more preferably 2 5 to 8 and more preferably 3 to 5% by mass) (wherein the case of containing a fatty acid salt means (as a conversion amount of the fatty acid), and (d) water ((d) component); and the content of the component (b) / (the mass ratio of the content of the homogeneous component is 1/1 〇 to 1 〇 / 1 (preferably 1) /8~6/1, and further preferably i/5 5/1), and the total content of the component (b) and the component (c) is 4 to 2% by mass (preferably 5 to 2% by mass, more preferably 6 to 15% by mass, still more preferably 7). ~1 〇Quality./0). &lt;Item 9&gt; For example, &lt; Item 8> Liquid cleaning agent for food processing equipment and/or conditioning equipment, σ σ, (a) component content / [ The mass ratio of the content of the component (b) to the content of the component (c) is 1/10 to 2.5/1 (preferably 1/1 〇 to 1 η, more preferably i/7 to 1/1, and further preferably It is 1/5~1/1, and more preferably 1/5~7/1〇). The liquid cleaning composition for food processing equipment and/or conditioning equipment according to Item 8 or <9>, wherein the component (c) is selected from the group consisting of myristic acid and laurel Among the acids and their salts (preferably alkali metal salts, more preferably sodium or potassium salts) - 160300.doc -25- 201226552 more than one compound. The liquid detergent composition for food processing equipment and/or conditioning equipment according to any one of the items of the present invention, wherein the component (b) contains An amine oxide type surfactant ((bl) component) having a carbon number of 8 to 10 (preferably a linear or branched alkyl group or a linear or branched alkenyl group), and having 1 An amine oxide type surfactant (component (b2)) having a hydrocarbon group of 12 (preferably a linear or branched alkyl group or a linear or branched alkenyl group), and as component (b) The content of the amine oxide type surfactant having one hydrocarbon group having 14 carbon atoms is 0 to 0.01% by mass. <12> The liquid detergent composition for food processing equipment and/or conditioning equipment of <11>, wherein the component (c) is selected from the group consisting of a fatty acid having a carbon number of 14 and salts thereof The content of the compound ((cl) component, the content of the (bl) component, and the content of the component (b2) satisfying the following conditions (1) is preferably a metal salt (preferably a sodium salt or a salt-removing salt). And (ii): Condition (i): The mass ratio of the (cl) component/(b2) component is 0 to 2.5; Condition (ii): (bl) component content / [(bl) component content The mass ratio of the content of the +(cl) component is 0·3 to 1. The liquid detergent composition for food processing equipment and/or conditioning equipment according to any one of the items of the present invention, wherein the component (a) is selected from the group consisting of a compound of one or more of an acid and a salt thereof. • 26· 160300.doc

A liquid detergent composition for food processing equipment and/or conditioning equipment according to any one of the items of the present invention, wherein The cleaning method of the steps 1 to 3: Step 1: The liquid cleaning composition for the food processing equipment and/or the conditioning equipment is 2 to 200 times (preferably 5 to 200 times, more preferably 20 to 100 times) by water. The dilution ratio is pre-diluted, and/or diluted on one side, and sprayed on the foam to adhere to the food processing equipment and/or conditioning equipment; Step 2: Keep the foam for a certain period of time (for the mechanism of each device and From the viewpoint of workability, it is preferably 6 minutes, more preferably 丄 minutes to 45 minutes; further preferably ^ 30 minutes, more preferably 2 minutes, more preferably 1 15 knives. More preferably, it is 1 to 10 minutes, and still more preferably 1 to 5 minutes; and, in terms of cleanability, it is preferably 1 to 60 minutes, more preferably 15 to 45 minutes, and still more preferably 20 Steps of ~3〇 minutes); Steps of rinsing food processing equipment and/or conditioning equipment with water. Item 15. The liquid detergent composition for food processing equipment and/or conditioning equipment of the item <1> wherein the step 1 is a liquid detergent composition for food processing equipment and/or conditioning equipment by water The dilution ratio of 2 to 2 times (preferably 5 to 200 times, more preferably 20 to 1 () times) is pre-diluted, and/or - the surface is diluted, and is sprayed in a bubble shape without intermittently. The step of attaching it to a food sanitation device and/or conditioning device. &lt;Item 16&gt; Cleaning method for food and I equipment and/or conditioning equipment, which sprays the clean liquid 160300.doc •27·201226552 into a foam, attaches it to food processing equipment and/or conditioning After the step on the device, the step of rinsing with water, the cleaning solution comprises: (a) being selected from the group consisting of oxidative dentate (preferably hypochlorous acid, hypobromous acid, sulfamic acid, more preferably hypogas); a compound of one or more of the salts (preferably a metal salt, more preferably a sodium salt) 0.0 02 5 to 2% by mass, (b) having one hydrocarbon group having a carbon number of 8 to 14 (preferably a linear or branched alkyl group, or a linear or branched alkenyl group, an amine oxide type surfactant of 0.0025 to 3.6% by mass, (4) a fatty acid having a carbon number of 12 to 16 and the like (more) Preferably, the mass ratio of the compound of the metal salt (more preferably the sodium salt or the potassium salt) to the mass %, and (d) water; and the content of the component (b) / the content of the component (C) is 1/10 to 1 0/1 ; The total content of the component (b) and the component (C) is 0.02 to 4 mass 〇 / 〇. (17) The method of cleaning a food processing device and/or a conditioning device according to the item 16, wherein the cleaning liquid is sprayed in a bead shape to adhere to the food processing device and/or the conditioning device. The step is a step of spraying the cleaning solution intermittently in a bubble shape onto the food processing equipment and/or the conditioning equipment. <Item 18> If the cleaning method of food processing equipment and/or conditioning equipment of <16> or <17th item> is clear, complex, ^γ, component (a) in bone cleaning solution The mass ratio of the content of [(b) component + content of (4) component] is mo~2.5/1. The cleaning method of the food processing equipment and/or the conditioning equipment according to any one of the above-mentioned items, wherein the component (b) contains An amine oxide type surfactant ((bl) component) having one hydrocarbon group having a carbon number of 8 to 1 Torr (preferably a linear or branched bond group, or a linear bond or a branched base), and An amine oxide type surfactant ((b2) component) having one hydrocarbon group having 12 carbon atoms (preferably a linear or branched alkyl group or a linear or branched alkenyl group) and as (b The content of the amine oxide type surfactant having one hydrocarbon group having 14 carbon atoms is 〇0.01% by mass; the component (c) is selected from the group consisting of a fatty acid having a carbon number of 14 and the like (Comparative) The content of the compound ((cl) component), the content of the (bl) component, and the content of the (b2) component of the metal salt, preferably a sodium salt or a potassium salt, satisfy the following conditions (i) And (ii): Condition (i): The mass ratio of the (cl) component/(b2) component is 0 to 2.5; Condition (ii): (bl) component content / [(bl) component The mass ratio of the content of the content + (cl) is 〇·3 to 1. [Examples] The following examples are illustrative of the practice of the present invention. The examples are intended to be illustrative of the invention and are not intended to limit the invention. Examples 1 to 26 and Comparative Examples 1 to 15 The following tests were carried out by preparing the liquid detergent compositions for food processing equipment and/or conditioning equipment shown in Tables 1 and 2. The results are shown in Table 1, 2 〇 160300.doc • 29- 201226552 Furthermore, in Tables 1 and 2, the symbol “_” in the column of “Quality Ratio” indicates that the ratio cannot be obtained. Further, in Tables 1 and 2, the test results were marked with "-" indicating that the liquid detergent composition for food processing equipment and/or conditioning equipment was cured or gelled, and thus the test was not carried out. Those who are described as difficult to evaluate indicate that they have tried to evaluate but cannot evaluate them. Examples 2, 3, 5, 7, 10 to 13, 21, 22, and 24 to 26 are the embodiments of the invention of the sixth aspect &gt; and the 12th item. In addition, the content of the component (a) shown in Tables 1 and 2 is obtained by the following formula as the conversion amount of the oxidizing halogen acid (the effective number is two digits) based on the amount of the oxidizing halide. The method of counting is rounded off and calculated). (as a conversion amount of oxidized (tetra) acid) = (mixed mass of oxidized dentate [·[(money mass of oxidizing acid [g/m〇1]) / (oxidative dentate ear mass [g /mol])], Here, the molar mass [g/mol] used for the calculation is as follows: Sub-gas acid: 52.46 sub-gas sodium: 74.44 sub-gas acid: 68.46 sodium sulfite: 90.44, will The number of carbon atoms is 12 to 16 and the decimal point is equal to or less than the decimal point. The ratio of the fatty acid of the volatile oil fatty acid in Tables i and 2 is 89% by mass, and the calculation is performed by rounding off the three digits. (1) Foam stability test The liquid clearing is hereinafter referred to as the food processing equipment and/or the conditioning equipment cleaning agent set in Tables 1 and 2, which are described as "liquid detergent composition", 160300.doc 201226552 liquid detergent composition) Dilute 20 times with water having a hardness of 4 ° dH to prepare a 5 mass % aqueous solution, and put 100 mL into a pump-type foaming container (B 523, manufactured by Yoshino Industrial Co., Ltd.). To a 300 mL disposable cup ( The upper end is 9 cm in diameter, the lower end is 7 cm in diameter, and the height is 10 cm.) Pushing the bubbling head once to form a foam (pushing once The time taken is 1 second, 1 g of foam is produced per press; the expansion ratio is 20 times), and the time until the complete defoaming is visually determined, the time (minutes) is measured. In this test, 6 〇 is measured. In addition, in Comparative Example 7, Comparative Example 11, and Comparative Example 12, the foam stability test and the rinsing property test (the following (7) and (3)) were not performed because the foaming was not sufficiently foamed. (2) Model test for rinsing property The liquid detergent composition described in Tables 1 and 2 was diluted 20 times with water having a hardness of 4 &lt; JdH to prepare a 5 mass% aqueous solution, and 1 mL of the solution was poured into a pump-type foaming container. (B 523 'manufactured by Yoshino Industrial Co., Ltd.). Pushing the bubbling head to the 3〇〇mL disposable cup to form a bubble (1 g of foam per press; the expansion ratio is 20 times) After 1 minute, '100 mL of water (25t) having a hardness of 4°dH was put into the bubble, and the time until complete defoaming was visually determined. The time (seconds) was measured. In this test, 'will not reach 2'. The leap second is set to pass. (3) It is assumed that the flushing test at the site will utilize tap water (hard A 5% by mass aqueous solution obtained by diluting the liquid detergent composition by 20 times to 3.9 ° dH) was put into a bubble cleaning machine (κρ_200, manufactured by Kao Co., Ltd.), and a plastic container cleaning machine (dw_160300. Doc •31- 201226552 2000R/L 'Manufactured by Sanyo Electric Co., Ltd.) (The two cleaning machines are 50 cm apart and sprayed from the KF-200 injection port to DW-2000R/L) to 〇·4 MPa (gauge pressure) Pressure jet for 15 seconds (the total spray volume of the foam is 500 g; the expansion ratio is 20 times). After 30 minutes, the tap water was rinsed with a water volume of 1 〇 L/min (water temperature of 25 ° C 'hardness of 2.5 ° dH), and the time until the foam completely disappeared (seconds) was measured. In this test, 15 seconds or less was set as pass. Further, regarding the rinsing time (seconds) of the rinsing field test, the values of the parentheses in Tables 1 and 2 are estimated values obtained by the following estimation methods. The calculation method of the estimated value is the value of "(2) flushing model test" and "(3) flushing field test" of Examples 1 to 13 of Table 1, by the following first-order approximation (correlation) Calculated by function). Υ=4.9741·Χ+78.357 The rinsing time (seconds) of the rinsing field test is obtained by substituting the X of the approximate formula into the rinsing time (seconds) of the "(2) rinsing model test" in Table 1. Υ » The estimated value is rounded off to the first place of the decimal and is shown in Table 1 in the form of brackets. (4) Viscosity characteristic test For the liquid detergent composition described in Tables 1 and 2, the temperature of the composition was adjusted to 20 ° C using a Β-type viscometer (manufactured by TOKIMEC), and the rotation of Ν 0.2 or N 0.3 was used. (NO.2 is used when the viscosity is below 1000 mPa, N0.3 is used when the viscosity is 1〇〇〇~loooo mPa), the viscosity is measured at a speed of 6~60 rpm, and 60 seconds after the start of the rotation The value. In this test, 3,000 mPa.s or less was set as pass. In addition, it is difficult to measure the B-type viscosity normally, and it is considered that the viscosity is 10000 mPa·s or more, and it is described as 160300.doc -32 - 201226552 "gel", and further, it is described as "partial curing" for a part of the coagulation. For all coagulates, it is described as "curing". (5) Storage stability test Tables 1 and 2. The liquid detergent composition described is stored in the listening environment for 3 days, and the liquid which is said to be transparent is set to pass (.). In addition, it is difficult to measure normally using a Β-type viscometer, and it is considered that the viscosity is (10) (9) or more and it is described as "gel". In addition, those who produce precipitates are described as "separation" for those who have no precipitates but are separated. (6) Cleanability test on standard test board (SUS304: 1.0 mmx30 mmx80 mm,

Testpane Co., Ltd. manufactured) coated rapeseed oil containing 〇丨% sultanium ιπ 1〇 Μ ‘# as a clean model test plate. 5% liquid aqueous solution (4〇dH hard water) of ί liquid qingqing detergent composition is put into 1〇〇11^ to pump bubbling container (B 523, manufactured by Yoshino Industrial Co., Ltd.) and will be ignited once. The foam formed by the head (the foam which was produced by pressing each time; the expansion ratio was 20 times) was applied to the above-mentioned cleaning model test plate. After the application, the μ-breast was placed, rinsed with tap water, and dried, and the amount of residual oil was measured by hexane extraction, and the cleaning rate (%) was calculated by the following formula. In this test, 7% or more was set as pass. Cleaning rate (%) = 100 χ ((coating oil amount) - (residual oil amount)) / (coating oil amount) Examples, comparative examples (comparative examples, 5, 7, 8, and u 15) The cleaning rate is 70%~100%, which is within the qualified range. 160300.doc -33 - 201226552 Example 1 °9孑(Ν wm One remaining part 8 $ 00 〇- 00 〇〇ri «Λ rs g 00 00* B ΓΟ 00 〇S βο ^ (Ν S- cn — - m The remaining part 8 00 1 〇〇〇00 00 &lt;N «Λί CN· jN | 〇〇\ °® 7 &lt;Ν w Pair - m Remaining part 8 00 1 00 〇S rs rs \〇gv〇〇00 °〇 CN w inch — m For the remaining part 〇00 1 00 〇00 00 &lt;N «Λ Η eo «Λ&gt; S 〇\ oo 〇昧v〇1- Ξ tn «η Ο VJ 〇w-&gt; The remaining part 〇Ci fS fn Ο «Λ Ο •Λ Η »n v6 Ο /*«N 00 &lt;N w 沄ΓΟ •Λ °9 ^ CN w — m a m For the remainder § 2 «Λ IW» Ο OO 00 (N &lt ;Ν OO OO (N o κ (Ν) — m a remainder of 8 s W&gt; 1 *n 00 00 oi W-1 &lt;Ν oo 卜 in = Vi v〇°9 (Ν w oo VO 〇00 刺余Part § 12.4/2.41 00 — ΓΟ ο O 12.8/4.81 (S &lt;N 00 &lt;Ν M 〇tN 00 CN w so Ο &lt;N Ο — Remaining Part 〇d 00 — Ο 12.8/4.81 ίΝ p 00 ON g 〇= °〇^ &lt;Ν w&lt; m — CN 〇Ό o 制 制 § 00 00 — 1 0.067 1 fo oo o 12.8/4.81 W- 1 (Ν Ό SO Ο § o 〇Ο 00 CS w ο — Ό Tf The remaining part 8 ο - 12.8/17 | ιη &lt;Ν 00 ON 〇ss § «Λ» CS 〇〇\ °9 ^ &lt;Ν Ο - »Λ Ο Remaining part 〇d &gt;Λ inch · a 12.8/4.51 «Λ «Ν f*·» NO to s 00 (N 〇00 °〇7 CS w - the remaining part 〇5 V) ο o :C 00 (N (Ν S SO s &lt;N 〇卜°® (Ν w oo - inch remainder 8 »n § d 2 ο o | 2.8/10.51 «Λ &lt;Ν (N 00 00 2 (N 〇VO — &quot ;&quot;W m »Γ&gt; The remaining part〇*Ti S w-ί ,· WJ Ο ol〇2 CS o 00 s 卜〇*Λ Ρ ^ f^&gt; W &lt;N &lt;s inch spare part § $ 00 Ο - S2 «Λ &lt;Ν oo fS g «Λ 〇°°9 ^ (Ν w — m surplus part 〇$ 00 to CO inch · S2 00 (N CN m oc ΙΛί o r- X °9 ^(Ν w — one m remaining part 〇00 ίΛ Ο «η ο 00 00 fS iS «Λ 〇\ § S CN 〇η 00 ^ (Ν w - m — m inch remaining part 〇 5 00 - jn ο 00 oo ίΝ « Λ &lt;S OO SO «η 8 ΙΛ 〇〇—(Ν &gt;ί&gt; The remainder § 5 00 Ο ο 00 S3 (N &lt;S 00 00 s〇O jn 00 sodium hypochlorite #1 sodium chlorite #1 ( B2) dodecyl dimethyl amine oxide 1: (bl) decyl dimethyl amine oxide | | (bl) octyl dimethyl amine oxide | tetradecyl dimethyl amine oxide | I hexadecane Methyl dimethyl amine oxide | I octadecyl dimethyl amine oxide II (ci) myristic acid | lauric acid I scorpion oil fatty acid &lt; 1 1 stearic acid 1 I 1 alkyl benzene sulfonate | Polyoxyhexene lauryl acetic acid sodium I 1 sodium chloride 1 1 sodium carbonate 1 1 potassium hydroxide 1 1 sodium hydroxide 1 ion exchange water &lt;0 | (b) component / (c) component mass ratio 1 1 ( b) mass ratio of the total content of the component to the component (8) (mass% &gt; 1 | (cl) component / (b2) component mass ratio | l (bl) component / [(bl) component + (c丨) component] | I(8) component / [(8) component + (c) component] mass ratio | |ρ Value (20eC)" 1 1 (1) Foam supply test (minutes) | (2) Flushing type test (seconds) | 1 (3) Flushing field test (seconds) 1 1 (4) Formulation Viscosity (mPas) | |(5 stored stability (-5eC) | s 1 $ r*&gt; Evaluation results 诨运庙嗜 (輙申ι〇/〇) •34- 160300.doc 201226552 Military 鸯 ° ° ® ^ &lt;Ν wm — For the remainder of the inch 〇Tj· 〇 2.8/4 • • • Gel &gt; °® ^ &lt;Ν wi — r&gt; The remainder § 1 inch « ο \2.S/i\ CS 1 Gel 1 °9 ^ (Ν wi — m 8 S inch 1 ο 2.8/8 •Λ &lt;Ν 1 Gel 1 Cj CS σ\ ο ° o 卜&lt;Ν d OS Remaining part m1 m 〇ο 1 2.4/1.5 1 (Ν σ&lt; cone 1 is difficult to evaluate 1 [ϊ_ to evaluate 1 gel 1 = g? 〇W Os ο S: —og ο 〇\ surplus part § S 〇\ rl ο ο 1 0.98/ 1.9 1 〇\ 00 Rough 1 Difficult to evaluate 1 1 Difficult to evaluate 1 Bu gel 1 Ο 〇' ο — m &lt;NO 〇ΟΟ 〇 Remaining part 8 | 3.3/0.45 | Η ο ο 10.78/3.75 丨= 〇〇CS condensate Gum | ο 2δ &lt; — § • &lt;s ο ο \ιΜ 00 ο VO so ΓΟ fS § 〇00 «ϊ ^ (Ν w&lt; TT — cn The remaining part 8 〇 to * ο 2.8/4 ί • Bu — On ν〇/«- s «f: ° o Remaining part S | 1.9/0.71 1 &lt;N • ο 1 1.1/2.61 1 镊1 difficult to evaluate 1 1 difficult to evaluate 1 1 - partially cured • VO —-»—0 (Ν+ Ο ν〇 ο ο 〇&lt;N ΓΛ d Ο 00 〇C &lt;N ο — The remaining part 〇11.45/1.07| &lt;N «Λ «Ν ο ίΐ ο 1 2.1/2.52 1 00 (N 8 &lt;Ν 〇«η 5S «Ν CS «η T}- The remaining part 〇m Os ο — On 1 1 S • 00 ^ (Ν ^ ΙΛ&gt; ΓΛ The remaining part of the inch 8 I fS (Ν R ο Μ ο 12.8/221 «Λ fS 〇〇00 〇 (N inch 〇 00 ^ oi ^ m — rj- Ιί § &gt; ο — 2.8/4 &lt; Ν 8 ΓΝ 〇fS 00 ^ «Ν w — m Ν 〇 制 制 制 〇 | 4/0.2 1 CN ( Ν Ο ο 12.8/4.2 丨Ν «Λ 〇Ά 1〇〇— °9 ί? w CS ο Remaining part 8 | 0.2/4 | &lt;Ν — ο ο 12.8/4.21 ' * * • • fN οο ^ ri 3-inch τΤ The remaining part of the inch 〇I rj - «Λ ο 12.8/121 «Ο &lt;Ν SO 1 (108) rs 〇ΙΛ ΓΊ 00 ^ &lt;Ν w inch CO inch inch Φ ¥龟S - ο |2·8/111 ΙΛ CS 〇W-» 1(103) «η 〇Ά 00 ^ &lt;Ν w &lt;N inch umbrella Φ 8 S Ο &lt;Ν to d |2.8/ί〇| &lt;Ν § 〇〇 〇〇ο 〇&lt;Ν °9 ^ &lt;Ν w For «Λ| The remainder of the inch 〇1 5.5/_4_\ «Λ Ον 卜tN fN d 12.8/9.51 •Ο rs inch 〇〇1300 X &lt;Ν (Ν 00 — °· ό - cn inch 8 5 00 r&gt; d «Λ d ο , CS in 卜 in' ο 〇 sodium soda 41 chlorite Sodium" | (b2) + dialkyl dimethyl amine oxide 1 | (bl) decyl dimethyl amine oxide 1 (bl) octyl dimethyl amine oxide 1 | tetradecyl dimethyl oximation Amine 1 1 Cetyl dimethyl amine oxide 1 | octadecyl dimethyl amine oxide 1 | (cl) myristic acid | lauric acid] hazelnut oil fatty acid #4 1 hard eric acid I 1 citric acid 1 1 alkyl stupid sodium 1 | polyoxyethylene lauryl ether acetate | I Sodium chloride 1 1 Sodium carbonate i 1 Potassium argon oxide 1 1 Sodium hydroxide 1 Ion exchange water tr &lt; Mass ratio of 〇1 (b) component / (c) component | 1 (b) component and (C) component Total content (% by mass) | | (cl) component / (b2) mass ratio 1 | (b丨) component / [(bl) component + (cl) component mass ratio | 1 (8) component / [(b) Component + (c) component] mass ratio _I | ρ Η value (20 ° (: Γ 1 (1) bubble stability test (division) (2) rinsing chess type test (seconds) I (3) rinsing site Test (seconds) | (4) Viscosity of the formulated solution (mPas) (5) Storage stability (-5°c) | 2 5 S5 Stepping over the twist (twist * W〇 / 〇) 160300.doc 35· 201226552 "As the amount of oxidizing _acid (in the table, the value in parentheses is the amount of oxidizing halide) + 2 (b) component of comparative component + 3 (c) component of comparative component sinter composition [mass %]: The carbon number is 10 or less: 5%; the carbon number is 12: 57°/. ; carbon number is 14 : 22 ° /. The carbon number is 16: 10%; the carbon number is 18 or more: 4. /〇 (In the table, the value in parentheses is the content of the fatty acid having a carbon number of 12 to 16) *5 The pH of the 5 mass% aqueous solution obtained by diluting the liquid detergent composition by 2 times with water (20 ° C) Value (Note 1) The components of the order are as follows. • Sodium hypogasate: sodium salt of sodium hypochlorite, manufactured by Nanhai Chemical Co., Ltd.. Sodium sulphate: Silbrite 25, manufactured by Japan Carlit Co., Ltd.. 12-alkyl dimethylamine oxide: Amphitol 20N, Kao shares Made by the company, the active ingredient is 35 mass 0 /, 2 octyl monodecylamine oxide: can be obtained by making dimethyl octylamine and hydrogen peroxide solution at 50 ° C ~ 80. (: The next reaction is obtained *1, and the active ingredient is 50% by mass. *2. Mercapto-didecylamine oxide: by using dimethyl decylamine and hydrogen peroxide solution at 50 ° C to 80 ° (: Obtained by the reaction, the active ingredient is 40.4 mass. /, 2 • tetradecyl dimethyl amine oxide: by using dimethyltetradecylamine and hydrogen peroxide solution at 50 ° C ~ 80 ° C The reaction is carried out to obtain 851, and the active ingredient is 25 masses of hexadecyl dimethylamine oxide: it can be obtained by reacting didecyl hexadecylamine with hydrogen peroxide solution at 50 ° C to 80 ° C. w, the active ingredient is -36-160300.&lt;|〇c

201226552 15.5 Quality. /〇*2 • Octadecyldidecylamine oxide: 581 can be obtained by reacting dimethyloctadecylamine with hydrogen peroxide solution at 50 ° C to 80 ° C, and the active ingredient is 6.8. Quality X8*2 • Myristic acid: Lunac MY-98, manufactured by Kao Co., Ltd. • Lauric acid: Lunac L-98, manufactured by Kao Co., Ltd. • Coconut oil Fatty acid: Lunac L-55, manufactured by Kao Co., Ltd. • 癸Acid: Lunac 10-98, manufactured by Kao Co., Ltd. • Sodium benzoate sodium: Neopelex G-15, manufactured by Kao Co., Ltd., active ingredient is 16% by mass*2 • Polyoxyethylene ether acetate: Kao-Akypo RLM-100NV, manufactured by Kao Co., Ltd., with an active ingredient of 23.5 mass ο/, 2 • Potassium hydroxide: liquid caustic potash (48% by mass), manufactured by Asahi Glass Co., Ltd. 虱 Sodium oxide: sodium hydroxide (48 mass) %), manufactured by Tosoh Co., Ltd. *1 by the manufacturing method described in Japanese Patent Laid-Open No. Sho 57-54160 (i.e., in the presence of a polybasic acid having one or more hydroxyl groups (citric acid) or a salt thereof Tertiary amine and hydrogen peroxide water soluble The method of the reaction of the liquid is manufactured. * The composition of Tables 1 and 2 describes the actual concentration (Note 2). • The mass ratio of (b) component/(c) component in the table indicates the content of component (9) / (4) The mass ratio of the content of the ingredients. The "mass ratio of (cl) component / (b2) component" in the table indicates the mass ratio of the content of the (cl) component / the content of the (b2) component. 160300.doc •37· 201226552 . The mass ratio of (bl) component/[(bl) component+(cl) component] in the table indicates the content of (bl) component/[(bl) component content + (cl (mass ratio of component content) 0 • The mass ratio of "(a) component / [(b) component + (c) component]" in the table indicates the content of (a) component / [(b) component content + (c) The mass ratio of the content of the component]. Example 27 and Comparative Example 16 The liquid detergent composition shown in Table 3 was prepared. The following test was conducted. The result is not in Table 3. (1) Viscosity characteristic test The liquid detergent composition described in Table 3 was measured for viscosity at 20 ° C under the same conditions as in the above (4) viscosity characteristic test. (2) Storage stability test The liquid detergent composition described in Table 3 was stored at -5 ° C for 3 days, and the liquid of 逯明 at -5 C was set to pass (〇). 160300.doc -38- 201226552 [Table 3] Example Comparative Example 27 16 Liquid cleaning composition formulated composition f amount (a) sodium soda sodium 2.8 (4) 2.8 (4) (b) dodecyldidecylamine oxide 3 0.2 Octyl dimethylamine oxide 1 (c) Myristic acid 1 1 Lauric acid 3 3 Potassium hydroxide 4 4 Total remaining part of ion-exchanged water 100 100 (b) Component/(c) Component mass ratio 4 /4 0.2/4 Total content of (b) component and (c) component (% by mass) 8 4.2 Mass ratio of (8) component / [(b) component + (c) component] 2.8/8 2.8/4.2 pH (20 〇亭2 12.5 _ Evaluation results (1) Viscosity of the formulated liquid (mPa-s) 280 Curing (2) Storage stability (-5 °C) 〇Cure 1 as the conversion amount of oxidizing halogen acid (in the table, in brackets) Numerical value of the amount of oxidized dentate) ^ pH of the 5% by mass aqueous solution obtained by diluting the liquid detergent composition 20 times with water (20 ° C) value 160300.doc • 39·

Claims (1)

201226552 VII. Patent Application Range: 1 · A liquid detergent composition for food processing equipment and/or conditioning equipment, comprising: (a) a compound selected from the group consisting of oxidizing acids and salts thereof [ The component (4) is referred to as 0.5 to 10% by mass (wherein, in the case of containing an oxidizing tooth-acid salt, it is referred to as an amount of oxidizing acid), and (b) having one hydrocarbon group having a carbon number of 8 to 14 The amine oxide type surfactant (hereinafter referred to as component (b)) is 0.5 to 18% by mass, and (c) one or more compounds selected from the group consisting of fatty acids having a number of 12 to 16 and salts thereof [hereinafter referred to as c) component] 0.5 to 1% by mass (wherein, in the case of a fatty acid salt, it means a conversion amount as a fatty acid), and (d) water; and the mass ratio of the component (b)/(c) is 1/ 1〇~1〇/1, and the total content of the component (b) and the component (c) is 4 to 20% by mass. 2. The liquid detergent composition for food processing equipment and/or conditioning equipment of claim 1, wherein the mass ratio of (4) component / [(b) component + (e) component] is 1/10 to 2.5/1. 3. The liquid cleaning device composition for food processing equipment and/or conditioning equipment according to the item 1 or 2, wherein the component (c) is one or more selected from the group consisting of myristic acid, lauric acid, and the like. Compound. 4. The liquid detergent group for food processing equipment and/or conditioning equipment of claim 1. The component (b) contains an amine oxide type surfactant having a hydrocarbon group of 8 to 1 Torr (hereinafter referred to as (b 1) component), and an oxidation of a hydrocarbon group having 1 carbon number of 12 The amine type surfactant [hereinafter referred to as (b2) is 160300.doc 201226552], and the content of the amine oxide type surfactant having one hydrocarbon group of 14 as the component (b) is 0 to 〇. 〇 1 quality 〇 / 〇. 5. The liquid detergent composition for food processing equipment and/or conditioning equipment of claim 4, wherein the mass ratio of (a) component / [(b) component + (c) component] is 1/10 to 1/1 6. The liquid detergent composition for food processing equipment and/or conditioning equipment of claim 4, wherein the compound (c) is one or more selected from the group consisting of a fatty acid having 14 carbon atoms and salts thereof [ Hereinafter, the content of the component (cl), the content of the (bl) component, and the content of the component (b2) satisfy the following conditions (1) and (ii): Condition (i): Content of the component (cl) / Component (b2) The mass ratio of the content is 0-2.5; Condition (ii): The mass ratio of the content of the (bl) component / the content of the [(M) component + the content of the (ci) component] is 〇·3~1. The liquid detergent composition for food processing equipment and/or conditioning apparatus according to any one of claims 1 to 6, wherein the component (a) is one or more compounds selected from the group consisting of hypogas acids and salts thereof. 8. The liquid detergent composition for food processing equipment and/or conditioning equipment according to claim 1 or 2, wherein the mass ratio of the component (b) to the component (c) is 1/5 to 5/1. 9. The liquid detergent composition for food processing equipment and/or conditioning equipment of claim 6, wherein the mass ratio of (a) component / [(b) component + (c) component] is 1/7 to 1/1 〇1 〇. The liquid detergent composition for food processing equipment and/or conditioning equipment of claim 6 wherein the total content of component (b) and component (c) is 6 to 15 mass 160300.doc 201226552%. 11. The liquid detergent composition for food processing equipment and/or conditioning equipment of claim 6 is for use in a cleaning method comprising the following steps 1 to 3: Step 1: using food processing equipment and/or conditioning equipment The liquid detergent composition is pre-diluted by water at a dilution ratio of 2 to 200 times, and/or diluted on one side by a foam spray to adhere to a food processing device and/or a conditioning device; Step 2: The step of holding the foam for (9) minutes; Step 3: The step of rinsing the food processing equipment and/or conditioning equipment with water. 12. The liquid detergent composition for food processing equipment and/or conditioning equipment of claim 11 wherein step 1 is to use a liquid detergent composition for food processing equipment and/or conditioning equipment by water 2 to 2 〇〇 The dilution ratio is diluted in advance, and/or diluted on one side, and sprayed onto the food processing equipment and/or conditioning equipment without intermittently spraying in a foam form. 13. A method of cleaning food processing equipment and/or conditioning equipment comprising the steps 1 to 3 of claim 11 or 12, and using the food processing equipment and/or conditioning of any one of claims 1 to 1 Liquid detergent composition for equipment. 14. The method of cleaning food processing equipment and/or conditioning equipment according to claim 13, wherein the step 1 is to dilute the food processing equipment and/or the liquid detergent composition for conditioning equipment by water at a dilution ratio of 2 to 200 times. The step of pre-dilution, and/or dilution on one side, without being intermittently sprayed in a bubble form, to adhere to the food processing equipment and/or conditioning equipment. 15. A method of cleaning food processing equipment and/or conditioning equipment which is rinsed with water after the step of spraying 160300.doc 201226552 cleansing liquid onto the food processing equipment and/or conditioning equipment In the step, the cleaning liquid contains: (a) a compound selected from one or more selected from the group consisting of oxidizing citric acid and salts thereof (hereinafter referred to as component (a)) 0.0025 to 2% by mass, (b) having one carbon An amine oxide type surfactant having a hydrocarbon group of 8 to 14 (hereinafter referred to as component (b)] 0.0025 to 3.6% by mass, (c) one selected from the group consisting of a fatty acid having a carbon number of 12 to 16 and a salt thereof The above compound [hereinafter referred to as (c) component] 〇, 0025~2% by mass, and (d) water; and the mass ratio of the component (b) component/(c) is 1/1〇~i〇/j; The total content of the component (b) and the component (c) is 〇·〇2 to 4 by mass. /. And (4) the mass ratio of the component / [(b) component + (c) component] is 1/1 〇 ~ 2 5 / 1. 16. The method of cleaning food processing equipment and/or conditioning equipment according to claim 15, wherein the component (b) comprises an amine oxide type surfactant having one hydrocarbon group having a carbon number of 8 to 1 Torr [hereinafter referred to as (bl) a component] and an amine oxide type surfactant (hereinafter referred to as a component (b2)) having one hydrocarbon group having 12 carbon atoms, and an amine oxide having a hydrocarbon group having 14 carbon atoms as the component (b) The content of the surfactant is 〇 〇 〇 〇 1% by mass; the compound selected from the group consisting of a fatty acid having 14 carbon atoms and a salt thereof (hereinafter referred to as (cl) component) The content, the content of the (bl) component, and the content of the component (b2) satisfy the following conditions (1) and (ϋ): Condition (1): The mass ratio of the content of the component (c1)/the content of the component (b2) is 160,300. .doc 201226552 0~2.5 ; Condition (ii) : The mass ratio of the content of (bl) component / the content of [(bl) component + the content of (cl) component] is 0.3 to 1. 160300.doc 201226552 IV. Designated representative map: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: (none) 160300.doc