TW201225386A - Method for manufaturing battery - Google Patents

Method for manufaturing battery Download PDF

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Publication number
TW201225386A
TW201225386A TW099143521A TW99143521A TW201225386A TW 201225386 A TW201225386 A TW 201225386A TW 099143521 A TW099143521 A TW 099143521A TW 99143521 A TW99143521 A TW 99143521A TW 201225386 A TW201225386 A TW 201225386A
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Taiwan
Prior art keywords
battery according
battery
manufacturing
chlorophyll
carbon
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TW099143521A
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Chinese (zh)
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TWI426645B (en
Inventor
Chung-Pin Liao
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Innot Bioenergy Holding Co
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Priority to TW099143521A priority Critical patent/TWI426645B/en
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Publication of TWI426645B publication Critical patent/TWI426645B/en

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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Battery Electrode And Active Subsutance (AREA)

Abstract

Embodiments of the present invention provide a manufacturing method of a battery. The method includes the steps of S1: manufacturing high aggregation solution; step S2: manufacturing a cathode structure; step S3: manufacturing an isolation structure; step S4: assembling the negative electrode structure and the isolation structure into a housing; and step S5: inseting a mass flow body into the housing and filling the cathode material to the structure to form a positive electrode structure, wherein at least one of the cathode structure and the anode structure includes chlorophyll. In at least one of the embodiments of the present invented cell manufacturing method, a battery can be produced using the chlorophyll in the positive and the negative electrode structures to store hydrogen thereby achieving power supply. Because the battery using an environment-protecting material instead of the conventional battery contamination component, even if discarded after exhausted, it does not pollute the environment, which is more environmentally-friendly than conventional batteries.

Description

201225386 六、發明說明: 【發明所屬之技術領域】201225386 VI. Description of the invention: [Technical field to which the invention belongs]

本申請請求於遞年12月24日遞交的美國專利申請第 麵如號以及於2_年5月16日遞交的臺灣專利申請第 97U8207號的在先權益。以上兩件專利文獻的全部内容在此 作為參考Μ用引入本申請。 本發明涉及-種電献其製紗法,_涉及-種使用葉 綠素來產生電能之電池及其製造方法。 【先前技術】 近年來,陸續出現了行動電話、手提式攝影機'筆記型電 腦、數位相機、PDA、CDplayer等輕便型電子機器,並謀求 其小型及輕量化’而俩此,作為可卿之輕便祕電池也 同樣受_注。電池種類包括乾電池,氫電池、鐘電池無 料電池等。下面將簡單介紹常見電池。 •日禮用的乾電池大多是雜電池,也叫碳鋅電池。碳辞 電池的外殼-般由鋅構成,細可以作為電池的容器,又可以 乍為電池的負極。石反鋅電池是從液體Lec】anch合電池發展而 來。傳統或-般型碳辞電池以氣化錢為電解質;超級或高能碳 鋅電池則通常是使用氣化鋅為電解質的碳鋅電池,是一般廉價 電池的改良版。碳!辛電池的正極主要是由粉末狀的二氧化锰和 201225386 碳構成。電解液是把氯化鋅和氯化銨溶於水中所形成的糊狀溶 液。碳鋅電池是最便宜的原電池,因此成為很多廠商的首選’ 因為這些廠商所銷售的設備中常常需要配送電池。鋅碳電池可 以用於遙控器、閃光燈、玩具或電晶體收音機等功率不大的設 備0 • 然而,當碳鋅電池使用一段時間以後,由於金屬鋅被氧化 成為鋅離子,鋅外殼會逐漸變薄。目此,氣化辞溶液常常可以 從電池中洩漏出來。洩漏出來的氣化鋅往往會使電池表面變 粘。一些老的電池沒有洩漏保護。鋅碳電池的使用壽命比較 短’保存期-般為-年半。另外’就算電池沒有使用,電池内 的氣化錄有紐性,可以與鋅反應,鋅外殼也會冊的變薄。 現在3C產業常提電池其實是贿電池,廣義的可 • 充放料池是指由—個石墨貞極、—娜祕、贼姐鐵的 正極、以及-種用於傳送鐘離子的電解液所構成。而一次雜 子電池則可贿金屬或者嵌崎料作為貞極。㈣池產業發展 夕年來直集中在3C產業為主’鮮少應用在市場經濟規模 ^大的儲能和動力電池(瞬間f要較大電流)市場,這市場涵 蓋純電動車、油電混合車、中大型哪、太陽能、大型儲能 電池、電動手工具、電動摩托車、電動自行車、航太設備與飛 機用電池等領域。其主要原因是過去鐘電池採用的錄正極材 201225386 料(LiCo〇2 ’就是現在最常見的锂電池)’無法應用在需要大 電流、高電壓、高扭力以及具有耐受穿刺、衝撞和高溫、低溫 等條件等特殊環境’更重要的是,因無法滿足人們對安全的絕 對要求而飽受詬病。 同時’鋰鈷電池也無法達到快速充電與完全避免二次污染 等目的,而且,一定要設計保護電路以防止過度充電或過度放 電’否則就會造成爆炸等危險,甚至出現如Sony電池爆炸導 致全球品牌NB業者投下矩資回收的情況。 另外,始的價格愈來愈高昂,全球始元素最大生產國剛 果,戰亂紛擾多,導致銘元素價格不斷升高。鐘銘電池的粉體 因鈷元素價格不斷上漲,現在已從原先的每公斤4〇美元漲價 到60〜70美元。碟酸鐘鐵粉體依品質好壞,每公斤售價在3〇〜6〇 美元。 錄虱電池的&又计源於錄錦電池。1982年美國ovonic公 司請求儲氫合金用於電極製造之專利,使得此一材料受到重 視,繼之為1985年荷蘭飛利浦公司突破了儲氫合金在充放電 過程中容量衰減的問題終使鎳氫電池脫穎而出。目前在日本有 8家以上銻氫電池製造薇,德國,美國,香港,台灣亦有錄氫 電池生產,市場反應良好。而⑽氫電池所造成之污染,會比 含有錫之鎳麟池小㈣,目此’目前舰電池已逐漸被鎳氫 201225386 電池取代。 燃料電池(Fuel cell)是一種使用秦料進行化學反應產生 電力的裝置’最早於腳年由英_ Giwe所發明。最常見 疋以氫氧為騎的質子交細轉電池,由浦料價格平宜, 加上對人體無化學危險、對環境無害,發電後產生純水和熱,The present application claims the prior benefit of U.S. Patent Application Serial No., filed on Dec. 24, and Taiwan Patent Application No. 97U8207, filed on May 16, the same. The entire contents of the above two patents are incorporated herein by reference. The present invention relates to a method of making a yarn by electrospinning, and relates to a battery using chlorophyll to generate electric energy and a method of manufacturing the same. [Prior Art] In recent years, there have been mobile phones, portable cameras, notebook computers, digital cameras, PDAs, CDplayers and other portable electronic devices, and they are seeking small and lightweight ones. Constipation batteries are also subject to _ note. The battery types include dry batteries, hydrogen batteries, and battery batteries. A brief description of common batteries is given below. • Most of the dry batteries used for the day are miscellaneous batteries, also called carbon-zinc batteries. Carbon word The outer casing of the battery is made of zinc. It can be used as a battery container or as a negative electrode. The stone anti-zinc battery was developed from a liquid Lec]anch battery. Traditional or general-type carbon batteries use gasification as an electrolyte; super or high-energy carbon-zinc batteries are usually carbon-zinc batteries using zinc-xide as an electrolyte, which is an improved version of a general-purpose battery. The positive electrode of the carbon! xin battery is mainly composed of powdered manganese dioxide and 201225386 carbon. The electrolyte is a paste solution formed by dissolving zinc chloride and ammonium chloride in water. Carbon-zinc batteries are the cheapest primary batteries, so they are the first choice of many manufacturers' because they often need to distribute batteries in the equipment sold by these manufacturers. Zinc-carbon batteries can be used in low-power equipment such as remote controls, flashlights, toys or transistor radios. 0 However, when the carbon-zinc battery is used for a period of time, the zinc casing will gradually become thinner due to the oxidation of metallic zinc to zinc ions. . Therefore, the gasification solution can often leak out of the battery. The leaked zinc oxide tends to make the surface of the battery sticky. Some old batteries have no leakage protection. The service life of zinc-carbon batteries is relatively short. The shelf life is generally - half a year. In addition, even if the battery is not used, the gasification in the battery is marked with a new property, which can react with zinc, and the zinc casing can also be thinned. Now the 3C industry often mentions that the battery is actually a bribe battery. The generalized charge and discharge tank refers to the anode of a graphite crucible, Na Na, the iron of the thief, and the electrolyte used to transport the clock ions. Composition. A miscellaneous battery can be used as a bungee. (4) The development of the pool industry is focused on the 3C industry in the past year. The market is small and the energy storage and power battery (the instantaneous current is large). This market covers pure electric vehicles and hybrid vehicles. , medium and large, solar, large energy storage batteries, electric hand tools, electric motorcycles, electric bicycles, aerospace equipment and aircraft batteries. The main reason is that the cathode material used in the past clock battery 201225386 material (LiCo〇2 ' is the most common lithium battery now) can not be applied to the need for high current, high voltage, high torque and withstand puncture, collision and high temperature, Special circumstances such as low temperatures, etc., more importantly, they have been criticized for failing to meet people's absolute requirements for safety. At the same time, 'lithium-cobalt batteries can't achieve the purpose of fast charging and completely avoiding secondary pollution. Moreover, it is necessary to design protection circuits to prevent overcharging or over-discharging. Otherwise, there will be dangers such as explosions, and even explosions such as Sony battery will cause the world. The brand NB industry casts the situation of the recovery of the moment. In addition, the starting price is getting higher and higher, the world's largest element of the country's largest production country, the war is more and more troublesome, resulting in the price of the element is rising. The powder of Zhongming battery has risen from the original price of 4 US dollars to 60 to 70 US dollars due to the rising price of cobalt. Dish acid bell powder is good or bad according to the quality, and the price per kilogram is 3〇~6〇. The recording of the battery & also counts from the recording battery. In 1982, the United States ovonic company requested the hydrogen storage alloy patent for electrode manufacturing, which made this material pay attention to. In 1985, Philips of the Netherlands broke through the problem of capacity decay of hydrogen storage alloy during charge and discharge, and finally made nickel-hydrogen battery. stand out. At present, there are more than 8 hydrogen batteries in Japan, and Germany, the United States, Hong Kong, and Taiwan also have hydrogen battery production, and the market has responded well. The pollution caused by (10) hydrogen batteries will be smaller than that of nickel-containing nickel pools. The current battery has been gradually replaced by nickel-hydrogen 201225386 batteries. Fuel cell is a device that uses Qin material to carry out chemical reaction to generate electricity. It was first invented by English _ Giwe. The most common 质 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢 氢

膽年代朗在美國軍方,後於聰年應聽美·子星座 雙子星座5號飛船。現在也有—些筆記㈣腦開始研究使 料電池。但由於產生的電量太小,且無法柳提供大量電 能’只能用於平穩供電上。燃料電池是—個電池本體與燃料箱 組合而成的動力機制。雌的選擇性非常高,包括純氮氣、甲 醇、乙醇、天然氣’甚至於現在運用最廣泛的汽油,都可以做 為燃料電池的燃料。 不論是新型強調環保的碳鋅電池、鹼性電池及二次電池, 在製程上奴會朗少#贼或其他重賴等, 原料及制程上—的物質,對環境以及人體都 具有較大危害。 曰則應用贋泛的鋰電池屬不穩定的電化風 裝不當、運作於低負載,都可:暴炸:= 夕重複雜的保護機制,比如包括保護電路、 其中保護電__止财、贩、顿、7孔、隔離膜等 喷…、,排亂孔用东 201225386 避免電池内部壓強過大;隔離膜具有較高的抗穿刺強度,以防 止内部短路1在電池内部溫度過高時還能融化,阻止裡離子 通過,阻滯電池反應,升高内p^2kn)。 (-{jn . Lii.xc〇〇2), (LixC) 鐘礦越來奶、,使其價格快速上漲。 • mi度稍之室外或環境之下效能與壽命皆開始 快速降減。 錄鑛電池或錢電池因具有記憶效應,很容㈣充放電不 良,而造成可用容量降低。 【發明内容】 本發明的目的是提供—種電池的製造方法。 為解決上述問題,本發明實施例提供了一種電池的製造方 • 法,其包括步驟S1 :製作高聚體溶液;步驟S2 :製作負極結 構;步驟S3 :製作隔離結構;步驟S4 :將負極結構以及隔離 結構組裝進外殼中;以及步驟85 :將集流體插入外殼中並填 充正極材料至上述結射以形成正極結構,其中所述負極結構 及所述正極結構令的至少之一包括葉綠素。 根據本發明的-優選實施例,所述步驟si包括步驟川: 在溫度4〇攝氏度的溶劑中緩慢添加高聚體粉末;步驟犯: 利用磁石授拌機以轉速500〜700RpM_上述溶液;步驟 201225386 S13 :使用導電度計檢測上述溶液的導電度是否達到 50-250ms/cm ;當上述檢測結果為否時,則返回執行步驟犯, 而當上述檢測結果為是時,則執行步驟S14 ;以及步驟SM : 完成。 根據本發明的一優選實施例,所述高聚體粉末包括金屬離 子與各類酸根離子的化合物以及高聚體’其濃度含量皆在 0.1-10莫耳/升間。 根據本發明的一優選實施例,所述高聚體粉末還包括維生 素。 根據本發明的一優選實施例’所述維生素為維生素D。 根據本發明的一優選實施例’所述高聚體為葡萄糖的高聚 體。 根據本發明的一優選實施例’所述葡萄糖的高聚體為馬鈴 薯澱粉、菱角澱粉、玉米澱粉、地瓜粉、蓮藕澱粉、芬末粉和 葛根粉中的一種或多種。 根據本發明的一優選實施例,所述金屬離子與各類酸根離 子的化合物為碳酸妈。 根據本發明的一優選實施例,所述金屬離子與各類酸根離 子的化合物為天然植物化學成分,所述天然植物化學成分包括 木脂素類、低聚糖、多糖、黃酮類、環烯醚萜類、脂肪酸、東 201225386 笑君内醋、兒茶素、β穀固醇、虎刺素和生物鹼類。 根據本發明的一優選實施例,所述溶劑為帶極性、pH值 大於3之溶劑。優選地,所述溶劑選自水、海水、茶、咖啡、 果汁、酒中的一種或多種。 根據本發明的一優選實施例,所述高聚體溶液的PH值為 5.5-8。 根據本發明的一優選實施例,所述步驟S2包括步驟S21 : 以濾、網過濾葉綠素粉末;步驟S22 :倒入高聚體溶液;步驟 523 .利用磁石攪拌機以轉速500〜700RPM進行攪拌;步驟 524 .判斷是否達到均勻流體;當上述判斷結果為否時’則返 回執行步驟S22,當上述判斷結果為是時,則執行步驟S25 ; 步驟S25 :將上述流體塗佈至導電材料層上;以及步驟S26 : 將上述結構放置於100攝氏度的烤箱中,烘烤至水份蒸發從而 完成負極結構之製作。 根據本發明的一優選實施例,所述導電材料層由導電材料 而製成。 根據本發明的一優選實施例,所述導電材料為金屬。 根據本發明的一優選實施例,所述金屬選自銘和/或金。 根據本發明的一優選實施例,所述導電材料為金屬化合 物。 9 201225386 根據本發明的一優選實施例,所述金屬化合物選自一氧化 猛、氧化鋅和氧化鎂中的一種或多種。 根據本發明的一優選實施例,所述導電材料為導電高分子 材料。 根據本發明的一優選實施例,所述導電高分子材料選自雜 環或芳麵雜環化合物。 根據本發明的一優選實施例,所述導電高分子材料選自以 下化合物中的一種或多種:聚乙炔、聚芳香烴乙烯、聚噻吩、 &笨胺、聚唼咯、聚吡咯和上述化合物的衍生物。 根據本發明的一優選實施例,所述葉綠素為葉綠素a、葉 、素b、葉綠素cl和、葉綠素c2、葉綠素d、及葉綠素e中 的-種或多種。 根據本發明的一優選實施例,所述葉綠素不包括葉綠素氧 化酶。 根據本發明的一優選實施例’所述負極結構為膜片狀。 根據本發明的—優選實施例,所述負極結構的長度為 111 ’而其寬度為50mm。 根據本發明的一優選實施例,所述步驟S3包括步驟S31 : 裁減好隔離膜;步驟S32 :將裁減好的隔離獏浸泡在高聚體溶 液中,步驟S33 :取出隔離膜並將其放置於1〇〇攝氏度的烤箱 201225386 中’供烤至水份蒸發以製作兩麵離膜;步驟 :取出一個 隔離膜,均勻噴讓電解質材料;以及步驟S35:覆蓋上另一個 隔離膜。 根據本發明的—優選實關,所賴__高纖維材質 製成。 根據本發明的一優選實施例,所述高纖維材質為紙類。 根據本發明的一優選實施例,所述紙類包括玻璃紙、棉 紙、宣紙及絹紙。 根據本發明的一優選實施例,所述高纖維材質的孔隙大小 介於Ο.ΟΙμιη〜lcm之間。 根據本發明的一優選實施例,所述隔離膜為膜片狀。 根據本發明的一優選實施例,所述隔離膜的長度為 55mm ’寬度為5〇mm,而其厚度為〇.2mm。 根據本發明的一優選實施例,所述電解質材料為有機或無 機鹽類水溶液或者有機鹽類與葉綠素的水溶液。 根據本發明的一優選實施例,所述有機鹽類水溶液的導電 度為 10ms/cm-500ms/cm。 根據本發明的一優選實施例’所述有機鹽類為非含鋰的有 機鹽類。 根據本發明的一優選實施例’所述有機或無機鹽類為包含 11 201225386 峨化鈉、氣化鋼和氫氧化財的一種或多種。The daring age is in the US military, and after Yu Congnian should listen to the Mei Zizi constellation Gemini constellation No. 5 spacecraft. There are also some notes (four) that the brain began to study the battery. However, due to the small amount of electricity generated, it is not possible to provide a large amount of electricity. The fuel cell is a dynamic mechanism that combines a battery body and a fuel tank. The selectivity of the female is very high, including pure nitrogen, methanol, ethanol, natural gas, and even the most widely used gasoline, it can be used as fuel for fuel cells. Whether it is a new type of carbon-zinc battery, alkaline battery and secondary battery that emphasizes environmental protection, the slaves will be less than the thieves or other materials, raw materials and processes, which are harmful to the environment and the human body. .曰 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 赝 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂 锂,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, , to prevent the passage of ions, block the battery reaction, raise the internal p^2kn). (-{jn. Lii.xc〇〇2), (LixC) The clock mine is getting milk, making its price rise rapidly. • Performance and longevity begin to decrease rapidly in outdoor or ambient environments. Because of the memory effect, the mining battery or the money battery is very difficult (4) poor charge and discharge, resulting in reduced available capacity. SUMMARY OF THE INVENTION An object of the present invention is to provide a method of manufacturing a battery. In order to solve the above problems, an embodiment of the present invention provides a method for manufacturing a battery, comprising: step S1: preparing a polymer solution; step S2: fabricating a negative electrode structure; step S3: fabricating an isolation structure; and step S4: forming a negative electrode structure And assembling the isolation structure into the outer casing; and step 85: inserting a current collector into the outer casing and filling the positive electrode material to the above-described junction to form a positive electrode structure, wherein at least one of the negative electrode structure and the positive electrode structure includes chlorophyll. According to a preferred embodiment of the present invention, the step si includes the step of: slowly adding a polymer powder in a solvent having a temperature of 4 〇 Celsius; the step is: using a magnetizer at a speed of 500 to 700 RpM_the above solution; 201225386 S13: Using a conductivity meter to detect whether the conductivity of the solution reaches 50-250 ms/cm; when the above detection result is no, returning to the execution step, and when the above detection result is YES, executing step S14; Step SM: Finish. According to a preferred embodiment of the invention, the high polymer powder comprises a metal ion and a compound of various acid ions and a high polymer, wherein the concentration is between 0.1 and 10 m/l. According to a preferred embodiment of the invention, the high polymer powder further comprises a vitamin. According to a preferred embodiment of the invention the vitamin is vitamin D. According to a preferred embodiment of the invention the polymer is a polymer of glucose. According to a preferred embodiment of the present invention, the high polymer of glucose is one or more of potato starch, water chestnut starch, corn starch, sweet potato powder, lotus root starch, fennel powder and pueraria powder. According to a preferred embodiment of the invention, the compound of the metal ion and various acid ion ions is a carbonic acid mother. According to a preferred embodiment of the present invention, the metal ion and various acid ion compounds are natural phytochemical components including lignans, oligosaccharides, polysaccharides, flavonoids, and cyclic ethers. Terpenoids, fatty acids, East 201225386 Laughing vinegar, catechins, beta-sitosterol, sucralose and alkaloids. According to a preferred embodiment of the invention, the solvent is a solvent having a polarity and a pH greater than 3. Preferably, the solvent is one or more selected from the group consisting of water, sea water, tea, coffee, fruit juice, and wine. According to a preferred embodiment of the invention, the high polymer solution has a pH of 5.5-8. According to a preferred embodiment of the present invention, the step S2 includes the step S21: filtering the chlorophyll powder by filtering and meshing; step S22: pouring the polymer solution; and step 523. stirring by using a magnet mixer at a rotation speed of 500 to 700 RPM; 524. determining whether the uniform fluid is reached; when the determination result is no, then returning to step S22, when the determination result is YES, proceeding to step S25; step S25: applying the fluid to the conductive material layer; Step S26: The above structure is placed in an oven at 100 degrees Celsius, and baked until the water is evaporated to complete the fabrication of the negative electrode structure. According to a preferred embodiment of the invention, the layer of electrically conductive material is made of a conductive material. According to a preferred embodiment of the invention, the electrically conductive material is a metal. According to a preferred embodiment of the invention, the metal is selected from the group consisting of Ming and/or Gold. According to a preferred embodiment of the invention, the electrically conductive material is a metal compound. 9 201225386 According to a preferred embodiment of the invention, the metal compound is selected from one or more of the group consisting of oxidized, zinc oxide and magnesium oxide. According to a preferred embodiment of the invention, the electrically conductive material is a conductive polymeric material. According to a preferred embodiment of the invention, the electrically conductive polymeric material is selected from the group consisting of heterocyclic or aromatic heterocyclic compounds. According to a preferred embodiment of the present invention, the conductive polymer material is selected from one or more of the group consisting of polyacetylene, polyaryl hydrocarbon, polythiophene, & strepamine, polypyrrole, polypyrrole and the above compounds Derivatives. According to a preferred embodiment of the present invention, the chlorophyll is one or more of chlorophyll a, leaf, element b, chlorophyll cl and chlorophyll c2, chlorophyll d, and chlorophyll e. According to a preferred embodiment of the invention, the chlorophyll does not comprise a chlorophyll oxidase. According to a preferred embodiment of the present invention, the negative electrode structure is in the form of a diaphragm. According to a preferred embodiment of the invention, the negative electrode structure has a length of 111 ′ and a width of 50 mm. According to a preferred embodiment of the present invention, the step S3 comprises the step S31: cutting the separator; the step S32: soaking the cut separator in the polymer solution, step S33: taking out the separator and placing it on the membrane In a 1 degree Celsius oven 201225386, 'bake to moisture to evaporate to make a double-sided film; step: take out a separator and evenly spray the electrolyte material; and step S35: cover another separator. According to the invention, it is preferably made of high-fiber material. According to a preferred embodiment of the invention, the high fiber material is paper. According to a preferred embodiment of the invention, the paper comprises cellophane, cotton paper, rice paper and crepe paper. According to a preferred embodiment of the invention, the high fiber material has a pore size between Ο.ΟΙμιη~lcm. According to a preferred embodiment of the invention, the separator is in the form of a membrane. According to a preferred embodiment of the invention, the separator has a length of 55 mm' width of 5 mm and a thickness of 0.2 mm. According to a preferred embodiment of the invention, the electrolyte material is an aqueous solution of an organic or inorganic salt or an aqueous solution of an organic salt and chlorophyll. According to a preferred embodiment of the invention, the organic salt aqueous solution has a conductivity of from 10 ms/cm to 500 ms/cm. According to a preferred embodiment of the present invention, the organic salt is an organic salt other than lithium. The organic or inorganic salt according to a preferred embodiment of the present invention is one or more comprising 11 201225386 sodium telluride, gasified steel and hydrogen hydroxide.

根據本發明的—優選實施例,所述步驟s4包括步驟S41: 將負極結構貼合至外殼中;步驟s42 :使用第一中空棒將隔離 、”。構緊雜起;步驟S43 :將捲起隔離結構之第一中空棒以順 夺访向方疋入具有負極結構的外殼中;步驟S44:以逆時針方 =將第一中空棒取出以將隔離結構保留在具有負極結構的外 中,步驟S45 .檢視隔離結構是否貼附於外殼中的負極釺 構;當上雜視結果為科,職行步驟S46 ;當上述檢視处 果為是時’則執行步步驟s46 :抽出隔離結構並判斷 隔離結構是否損壞;當上述判斷結果為否時,則返回 他當上述判斷結果為是時,則執行步驟咖;步驟S46a驟 更換隔離結顧返回執行辣⑽;以及_ π :完成組裝。 根據本發明的—優選實施例,所述第—中空棒的内直徑為 4.5_ ’外直徑為6.36_,長度為47.2mm。 根據本發明的一優選實施例,所述外殼為一個外徑為 14.5mm,内徑為12 5腿,長度為48 4咖的紙管。“ 根據本發明的-優選實施例,所述步驟S5包括步驟如· 於具有負__及隔離結構之外財緩慢填蚊極材料·步 驟松:將集流體插人外殼財心;步驟S53 :使用第一中1 棒與虎钳_並_填人正輯料;步驟⑸:檢視正極材: 12 201225386 是否達到所需的重I·大 驟w,A、 為否時,則返回執行步 虽上述檢視結果為是時,則執行 S55:以第竭奶,以及步驟 製作。 _正極_,其巾從岭紅極結構的 根據本發明的―優選實施例,所述第二中空棒的内直徑為According to a preferred embodiment of the present invention, the step s4 includes a step S41 of: attaching the negative electrode structure to the outer casing; step s42: using the first hollow rod to isolate, "close the structure; step S43: rolling up The first hollow rod of the isolation structure is inserted into the outer casing having the negative electrode structure in the direction of the visitor; step S44: taking the first hollow rod in a counterclockwise direction to retain the isolation structure in the outer portion having the negative electrode structure, the steps S45. Detecting whether the isolation structure is attached to the negative electrode structure in the outer casing; when the upper miscellaneous result is the section, the occupation step S46; when the above inspection result is YES, then step s46 is performed: the isolation structure is extracted and the isolation is determined Whether the structure is damaged; when the above judgment result is no, returning to him, when the above judgment result is YES, executing the step coffee; step S46a, replacing the isolation check to return to execute the spicy (10); and _π: completing the assembly. According to the present invention Preferably, the first hollow rod has an inner diameter of 4.5_' outer diameter of 6.36_ and a length of 47.2 mm. According to a preferred embodiment of the invention, the outer casing has an outer diameter of 14.5 mm. A paper tube having an inner diameter of 12 5 legs and a length of 48 4 coffee. "In accordance with a preferred embodiment of the present invention, the step S5 includes steps such as a negative filling material with a negative __ and an isolation structure. · Step loose: insert the current collector into the shell; Step S53: Use the first 1 rod and the vise _ and _ fill in the positive material; Step (5): View the cathode material: 12 201225386 Whether the required weight I is reached - Large step w, A, if no, return to the execution step. If the result of the above-mentioned inspection is YES, then S55 is executed: the first milk is executed, and the step is made. _ positive _, its towel from the ridge red pole structure. According to a preferred embodiment of the present invention, the inner diameter of the second hollow rod is

外直徑為9.94mm,長度為47.2mm。 根據本發明的-優選實施例,所述集流體為—圓柱體。 根據本發_-優選實關,所述集流體的紐為4麵, 而其長度為47.2mm。 根據本發明的—優選實施例,所述正極材料為粉末狀。 根據本發明的—優選實施例’所述正極㈣包含葉綠素粉 根據本發明的—優選實細,所述正極材料包括碳布、碳 末或者奈米導電高分子粉末。 "根據本發明的-優選實施例,所述碳布或者碳末為白碳或 徵石奴黑、石反煙、玻璃碳或者玻碳、奈米碳管、活性碳、 鐵石金剛石、非晶質碳、石墨稀、富勒烯、石墨、碳炔、雙 原子杈、C3、原子碳、石墨化性碳素、熱分解碳類,焦炭類 中的一種或多種。 根據本發明的一優選實施例,所述導電高分子的材料選自 13 201225386 雜環或芳香族雜環化合物。 本發明實施例的電池製作方法所製造出的電池可利用其 正、負極結構中的葉綠素即可進行儲氫從而達到供電的目的。 亦即,在電池之氧化還原反應中,當葉綠素因其中之鎂離子脫 離而形成脫鎂葉綠素(pheophytin)之際,出缺鎂的部份即能 結合兩個氫離子’故能儲氫。且由於本發明實施例的電池製作 方法所製造出的電池採用天然的環保物質代替傳統電池中的 污染成分,用完即使丟棄也不會對環境造成污染,環保程度遠 勝於傳統電池。 【實施方式】 下面結合附圖和實施例對本發明實施例進行詳細說明。 圖1繪示為本發明一實施例所揭示的電池的結構示音The outer diameter is 9.94 mm and the length is 47.2 mm. According to a preferred embodiment of the invention, the current collector is a cylinder. According to the present invention, the current collector has four sides and has a length of 47.2 mm. According to a preferred embodiment of the invention, the positive electrode material is in the form of a powder. The positive electrode (four) according to the present invention - a preferred embodiment, comprises chlorophyll powder. According to the present invention, preferably, the positive electrode material comprises carbon cloth, carbon powder or nano conductive polymer powder. "In accordance with a preferred embodiment of the present invention, the carbon cloth or carbon is white carbon or stone black, stone anti-smoke, glassy carbon or glassy carbon, carbon nanotube, activated carbon, iron diamond, amorphous One or more of carbonaceous, graphite, fullerene, graphite, carbyne, diatomic cesium, C3, atomic carbon, graphitized carbon, thermal decomposition carbon, and coke. According to a preferred embodiment of the present invention, the material of the conductive polymer is selected from the group consisting of 13 201225386 heterocyclic or aromatic heterocyclic compounds. The battery manufactured by the battery manufacturing method of the embodiment of the present invention can utilize the chlorophyll in the positive and negative electrode structures to perform hydrogen storage to achieve the purpose of power supply. That is, in the redox reaction of the battery, when chlorophyll is decomposed from magnesium ions to form pheophytin, the magnesium-depleted portion can combine two hydrogen ions to store hydrogen. Moreover, since the battery manufactured by the battery manufacturing method of the embodiment of the present invention uses a natural environmentally-friendly material to replace the pollution component in the conventional battery, even if it is discarded, it does not pollute the environment, and the environmental protection degree is far superior to the conventional battery. [Embodiment] Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings and embodiments. 1 is a schematic diagram showing the structure of a battery according to an embodiment of the invention.

圖。如圖1所示,本發明實施例提供了一種電池1〇〇,其包括 集流體110 '正極結構120、隔離結構130、負極結構14〇以 及外殼150。其中正極結構120、隔離結構13〇、負極結構_ 以及外殼150依次環繞地設置於集流體110週圍。 圖2繪示為本發明-實施例所揭示之負極結構的結構示 意圖。如圖2所示’本發明實施例所揭示的負極結構^包括 導電材料層⑷以及負極材料層142,其中負極材料層⑷可 形成在導電材料層141之上。 曰 14 201225386 其中,導電材料層141由導電材料而製成。導電材料可以 是金屬、金屬化合物或導電高分子材料。金屬可以選自銘和/ 或金。金屬化合物可以選自一氧化結、氧化辞和氧化鎮中的一 種或多種。導電高分子材料選自雜環或芳香族雜環化合物。根 據本發明的-優選實施例’導電高分子材料選自町化合物中Figure. As shown in FIG. 1, an embodiment of the present invention provides a battery 1A including a current collector 110' positive electrode structure 120, an isolation structure 130, a negative electrode structure 14A, and a casing 150. The positive electrode structure 120, the isolation structure 13A, the negative electrode structure_, and the outer casing 150 are circumferentially disposed around the current collector 110. Fig. 2 is a view showing the structure of a negative electrode structure disclosed in the embodiment of the present invention. As shown in FIG. 2, the negative electrode structure disclosed in the embodiment of the present invention includes a conductive material layer (4) and a negative electrode material layer 142, wherein the negative electrode material layer (4) may be formed on the conductive material layer 141.曰 14 201225386 wherein the conductive material layer 141 is made of a conductive material. The conductive material may be a metal, a metal compound or a conductive polymer material. The metal can be selected from the group and / or gold. The metal compound may be selected from one or more of a oxidized, oxidized, and oxidized town. The conductive polymer material is selected from a heterocyclic ring or an aromatic heterocyclic compound. According to the preferred embodiment of the present invention, the conductive polymer material is selected from the group of compounds.

的一種或多種:聚乙块、聚㈣烴乙烯、料吩、聚苯胺、聚 哒咯、聚吡咯和上述化合物的衍生物。 負極材料層M2包括葉綠素以及高聚體溶液,且負極材料 層142可藉由涂佈等方式形成在導電材料層⑷上。葉綠素可 以為葉綠素a、葉綠素b、葉綠素el和、葉綠素&、料素d、 及葉綠素e中的-種或多種。_素可以為粉絲或液狀。所 採用的葉綠素已去除葉綠素氧化酶。 高聚體溶液具有黏合_,制此附著並靖導電材料層 之物理及化學雛,使得負姆料層142更黏瞻導電材料層 ⑷。此外’高聚體溶液的導電度為抑❻邮/咖。高聚體溶 液可以包括硼、L㉟、财鋅讀之—種或數種。高聚 體溶液還祕調餅電材料層141的功函數俾使正負電極間 之電位差能達致所欲之伏特數,如15V。 高聚體溶液可㈣金·子與各_根離子的化合物、高 聚體及溶劑按_調配而成。絲體可以摘雜的高聚體。 201225386 葡萄糖的高聚體可以為植物膽,例如為馬铃著殿粉、菱角殿 粉、玉米殿粉、地瓜粉、蓮藕澱粉、芬末粉和葛根粉中的一種 或多種。金屬離子與各類酸根離子的化合物可以為碳酸妈。金 屬離子與各鏡_子的化合物可叫城鋪化學成分。天 然植物化學齡包括木脂·、低輪、錄、黃瞒、輯 醚_、脂肪酸、東衫内酯、兒茶素、β穀固醇、虎刺素和 生物鹼類。溶劑可以為帶極性、ΡΗ值大於3之溶劑,例如: X海X余咖非、果汁或者酒等等。高聚體溶液的ΡΗ值 優選為5.5-8。高聚體溶液還可以包括維生素,例如維生素d。 負極結構140可製成膜片狀,從而提高葉綠素的使用量, 、曰大接觸Φ積以提呵電池的反應面積等。此外,本領域技術人 員可理解的是’本發明還可以藉由任何已知技術提高葉綠素的 使用量,增大接觸面積以提高電池的反應面積等。優選地,在 本實%例巾’貞極結構14〇的長度為6Gmm,喊度為。 請繼續參閱圖卜以下將繼續介紹本發明所揭示之電池 100的其餘結構。集流體110為一圓柱體,優選地,集流體n〇 的直徑為4mm,而其長度為47.2mm。 正極結構120由粉末狀的正極材料而構成。優選地,正極 結構120中的粉末狀的正極材料包含葉綠素粉末。此外,粉末 狀的正極材料可進—步包括碳布、碳末或者奈米導電高分子粉 201225386 末。碳布或者碳末包括白碳或稱蠟石(Chaoite)、碳黑、碳煙 (Carbon black)、玻璃礙或者玻碳(Glassy carbon)、奈米碳管 (Carbon nanotube)、活性碳(Activated carbon)、鑽石、金剛石 (Diamond)、非晶質碳(Amorphous carbon)、石墨稀(Graphene)、 富勒稀(Fulerene)、石墨(Graphite)、碳炔(Carbyne)、雙原子碳 φ (Diatomic carbon)、C3(Tricarbon)、原子碳(Atomic carbon)、石 墨化性碳素、熱分解碳類,焦炭類及其他碳的同素異形體。導 電咼分子的材料選自雜環或芳香族雜環化合物。優選地,導電 尚分子的材料選自以下化合物中的一種或多種:聚乙炔、聚芳 香烴乙烯、聚噻吩、聚苯胺、聚π必咯、聚吡咯和上述化合物的 衍生物。 隔離結構130包括第一隔離膜131、第二隔離膜132以及 • 夾設於兩隔離膜之間的電解質材料133。第一隔離膜131以及 第二隔離膜132分別採用高纖維材質而製成,其中高纖維材質 可以為紙類,紙類包括玻璃紙、棉紙、宣紙及絹紙等,且高纖 維材質孔隙大小優選為〇.0_〜lem。此外,在本實施例中, 第-隔離膜131以及第二隔離膜132分別為膜片狀,且其長度 為55mm,寬度為50mm,厚度為〇 2mm的薄膜。電解質材料 Π3可為錢或錢麵水錄絲有_賴葉綠素的水 溶液。其中’有機鹽類水溶液的導電度為1〇ms/cm 5〇〇ms/cm。 201225386 有機鹽類為非含鐘的有機賴。有機或無機贿選自包含以下 離子化:物中的-種或多種·職化納、氣化鈉和氮氧化納。 外Λ又150疋一個外徑為14 5_,内徑為12 5_,長度為 48,4mm的崎’其包覆上難越Π0、正極結構U0、隔離 結構130以及負極結構14〇。 ▲在本實施例中’負極結構14〇與正極結構12〇中均包含有 葉’.、彔素’因此’電池卿工作時,負極結構⑽中的葉綠素及One or more of: a poly(block), a poly(tetra)hydrocarbyl ethylene, a phenol, a polyaniline, a polypyrrole, a polypyrrole, and a derivative of the above compound. The negative electrode material layer M2 includes chlorophyll and a high polymer solution, and the negative electrode material layer 142 may be formed on the conductive material layer (4) by coating or the like. The chlorophyll may be one or more of chlorophyll a, chlorophyll b, chlorophyll el and chlorophyll & phytochemical d, and chlorophyll e. _ can be a fan or liquid. The chlorophyll used has removed chlorophyll oxidase. The high polymer solution has a bond, which is attached to the physical and chemical layers of the conductive material layer, so that the negative electrode layer 142 is more adhesive to the conductive material layer (4). In addition, the conductivity of the high polymer solution is suppressed by the mail/coffee. The high polymer solution may include boron, L35, or zinc. The high polymer solution also secretly adjusts the work function of the layer of electrically conductive material 141 such that the potential difference between the positive and negative electrodes can reach a desired volt, such as 15V. The high polymer solution can be prepared by blending (4) gold, a compound, a polymer, and a solvent of each ion. The filaments can be mixed with high polymer. 201225386 The high polymer of glucose can be plant gall, such as one or more of Ma Lingya Dian powder, Lingjiaodian powder, corn house powder, sweet potato powder, lotus root starch, fennel powder and kudzu root powder. The compound of metal ions and various acid ions can be a carbonic acid mother. The metal ion and the compound of each mirror can be called the chemical composition of the city. Natural phytochemical ages include lignan····················································································· The solvent may be a solvent having a polarity and a enthalpy value greater than 3, for example: X sea X, coffee, wine or wine. The enthalpy of the high polymer solution is preferably 5.5-8. The high polymer solution may also include a vitamin such as vitamin D. The negative electrode structure 140 can be formed into a diaphragm shape, thereby increasing the amount of chlorophyll used, and increasing the contact Φ product to increase the reaction area of the battery. Further, it will be understood by those skilled in the art that the present invention can also increase the amount of chlorophyll used, increase the contact area to increase the reaction area of the battery, and the like by any known technique. Preferably, in the present embodiment, the length of the 贞 贞 structure 14 〇 is 6 Gmm, and the screaming degree is . Please continue to refer to the drawings. The remaining structure of the battery 100 disclosed in the present invention will be further described below. The current collector 110 is a cylinder, and preferably, the current collector n〇 has a diameter of 4 mm and a length of 47.2 mm. The positive electrode structure 120 is composed of a powdery positive electrode material. Preferably, the powdery positive electrode material in the positive electrode structure 120 contains chlorophyll powder. In addition, the powdery positive electrode material may further include carbon cloth, carbon powder or nano conductive polymer powder 201225386. Carbon cloth or carbon powder includes white carbon or waxite (Chaoite), carbon black, carbon black, glass barrier or glassy carbon, carbon nanotube, activated carbon ), Diamond, Diamond, Amorphous carbon, Graphene, Fulerene, Graphite, Carbyne, Diatomic carbon , C3 (Tricarbon), Atomic carbon, graphitized carbon, thermal decomposition of carbon, coke and other carbon allotropes. The material of the electron-conducting molecule is selected from a heterocyclic ring or an aromatic heterocyclic compound. Preferably, the electrically conductive material is selected from one or more of the group consisting of polyacetylene, polyaramid ethylene, polythiophene, polyaniline, polyπ-pyrrole, polypyrrole, and derivatives of the above compounds. The isolation structure 130 includes a first isolation film 131, a second isolation film 132, and an electrolyte material 133 interposed between the two isolation films. The first isolation film 131 and the second isolation film 132 are respectively made of high fiber material, wherein the high fiber material can be paper, the paper type includes cellophane, cotton paper, rice paper and crepe paper, and the high fiber material preferably has a pore size. For 〇.0_~lem. Further, in the present embodiment, the first-isolation film 131 and the second separator 132 are each in the form of a diaphragm, and have a length of 55 mm, a width of 50 mm, and a film thickness of 〇 2 mm. Electrolyte material Π3 can be used as a water solution for money or money surface. The 'organic salt aqueous solution has a conductivity of 1 〇ms/cm 5 〇〇ms/cm. 201225386 Organic salts are organically based on non-clocks. The organic or inorganic bribe is selected from the group consisting of: - or a variety of sodium, sodium hydride and sodium oxynitride. The outer cymbal is 150 疋, an outer diameter of 14 5 _, an inner diameter of 12 5 _, and a length of 48, 4 mm, which is coated with a hard surface, a positive electrode structure U0, an isolation structure 130, and a negative electrode structure 14 〇. ▲ In the present embodiment, both the negative electrode structure 14A and the positive electrode structure 12A contain a leaf '., a halogen', and thus, when the battery is in operation, the chlorophyll in the negative electrode structure (10)

正極結構120中的葉綠素相接收光線或遇到溶液而產生電 子或空穴,從而在電池⑽的正極結構12G與負極結構14〇 之間形成電位差以提供持續的^也就是說,本發明的電池 卿以負極結構14G以及正極結構m中的葉綠素來作為能量 來源來提供電能。優選地,負極結構⑽中的葉綠素與正極結 構120中的葉綠素具有不同之功函數(丽I—。 雖然在本實施例中,負極結構 v …穴‘'此阳>r再丄zu中均( 含有葉綠素,但是,本領域技術人貝可以理解的是本發明戶 揭示的電池,亦可僅在負極結構⑽中設置葉綠素,或細 正極結構120中設置葉綠素, 電池提供魏。 料魏量來源㈣ *圖增示為本剌_實施_揭私電池的製作方法的 机程圖。如圖3所示’上述魏的製作方法包括以下步驟: 18 201225386 步驟S1:製作高_溶液; 步驟S2 :製作負極結構; 步驟S3 ••製作隔離結構; 步驟S4 :將貞極結構以及隔離結構組裝進外殼中;以及 步驟S5 .將集流體插入外殼中並填充正極材料至上述結 % 構中以开》成正極結構從而完成整個電池的製作。 圖4繪示為圖3所示之步驟S1的具體流程圖。如圖4所 示’步驟S1之製作高聚體溶液包括以下步驟: 步驟S11 :在溫度40攝氏度的溶劑中緩慢添加高聚體粉 末; 步驟S12 .利用磁石撥掉機以轉速500〜700RPM授拌上述 溶液; • 步驟S13 :使用導電度計檢測上述溶液的導電度是否達到 5〇-250ms/cm ;當上述檢測結果為否時’則返回執行步驟§11, 而當上述檢測結果為是時’則執行步驟S14 ;以及 步驟S14 :完成。 在本實施例中,所述溶劑為帶極性、PH值大於3之溶劑。 優選地,所述溶劑選自水、海水、茶、咖啡、果汁、酒中的一 種或多種。 圖5繪禾為圖3所系之步驟S2的具體流程圖。如圖5所 201225386 示’步驟S2之製作負極結構包括以下步驟: 步驟S21 :以濾網過濾葉綠素粉末; 步驟S22 :倒入高聚體溶液; 步驟S23.利用磁石攪拌機以轉速5〇〇〜7〇〇RpM進行授摔; 步驟S24 ·判斷是否達到均勻流體;當上述判斷結果為否 • 時,則返回執行步驟S22,當上述判斷結果為是時,則執行步 驟 S25 ; 步驟S25 :將上述流體塗佈至導電材料層上; 步驟S26 ·將上述結構放置於刚攝氏度的烤箱中供烤 至水份蒸發從而完成負極結構之製作。 —圖6繪示為圖3所示之步驟幻的具體流程圖。如圖6所 不,步驟S3之製作隔離結構包括以下步驟: • 步驟S31 ··裁減好隔離膜; 步驟S32 :將裁減好的隔離膜浸泡在高聚體溶液中; 步驟S33 :取出隔離膜並將其放置於励 中’烘烤至水份蒸發以製作兩個隔離膜; 烤相 步驟S34 :取出一個隔離膜,均勾喷灑電解質材料;以及 步驟S35H另—侧_躺完成_結構之製作。 _圖7緣示為圖3所示之步驟S4的具體流程圖。如圖7所 不’步驟S4之將負極結構以及隔離結構組裝進外殼♦包括以 20 201225386 下步驟: 步驟S41 :將負極結構貼合至外殼中; 步驟S42 :使用第-中空棒將隔離結構緊密捲起,其中第 一中空棒的内直徑為4.5mm,外直徑為6 36mm,長度為 47.2mm » 步驟S43 :將捲起隔離結構之第一中空棒以順時針方向旋 入具有負極結構的外殼中; 步驟S44 :以逆時針方向將第—中空棒取出轉隔離結構 保留在具有負極結構的外殼中; 步驟S45 :檢視隔離結構是否貼附於外殼中的負極結構; 當上述檢視結果為否時,則執行步驟撕;當上述檢視結果為 是時,則執行步驟S47 ; 步驟S46 :抽出隔離結構朗斷隔雜構是否損壞;當上 述判斷結果為否時,則返回執行步驟S42 ;當上述判斷結:為 是時’則執行步驟S46a ; 步驟S46a .更換隔離結構並返回執行步驟S42 ;以及 步驟47 ··完成組裝。 八圖曰不為圖3所示之步驟%的具體流程圖。如圖s所 2步驟S5之將集流體插人外財並填充正極材料至上述結 以形成正極結構包括以下步驟: 201225386 步驟S51 :於具有負極結構以及隔離結構之外殼中緩慢填 充正極材料; 、 v驟S52 ·將集流體插入外殼的中心; 步驟S53 .使用第一中空棒與虎鉗填壓並繼續填入正極材 料; • ^驟S54 ·檢視正極材料是否達到所需的重量;當上述檢 視、。果為否時’則返回執行步驟S53,當上述檢視結果為是 時’則執行步驟S55 ;以及 v驟S55 .以第二中空棒修飾正極結構,其中第二中空棒 ^内直徑為4.5mm,外餘為9.94mm,長度為47 2mm從而 完成正極結構的製作。 、本發明所揭示的電池可利用其正、負極結構中的葉綠素即 _ 3進行儲氫從而達到供電的目的。優選地,所述正、負極結構 皆包含葉綠素,但具有不同之功函數。亦即,在電池之氧化還 '、…中®葉綠素因其巾之鎂離子脫離而形成顧葉綠素 (Phe〇Phytln)之際,出缺鎂的部份即能結合兩個氫離子,故 能儲氫。此外由於本發明的電池採用天然的環保物質代替傳統 電池中·染成分,用完即使丢棄也不會對環境造成污染,環 保程度遠勝於傳統電池。 而要指出的是,在本發明實施例巾提朗“第一”、 22 201225386 第二,等用語僅是根據需要採用的文字符號,在實務中 並不限於此,並且該文字符號可以互換使用。 上文所揭露之主題可被認爲是說明性的而不是限制 性的,且預期所附申請專利範圍涵蓋屬於本發明之真實精 神和範«内之所有修改'改進和其他實施例。因此,在法 律允許的最大範圍,可藉由對騎中料利制和其均等The chlorophyll phase in the positive electrode structure 120 receives light or encounters a solution to generate electrons or holes, thereby forming a potential difference between the positive electrode structure 12G of the battery (10) and the negative electrode structure 14A to provide continuity. That is, the battery of the present invention Qing provides electrical energy using the negative electrode structure 14G and the chlorophyll in the positive electrode structure m as a source of energy. Preferably, the chlorophyll in the negative electrode structure (10) has a different work function from the chlorophyll in the positive electrode structure 120 (in the case of the present embodiment, the negative electrode structure v ... the hole ''this yang> (containing chlorophyll, however, it is understood by those skilled in the art that the battery disclosed by the present invention can also be provided with chlorophyll only in the negative electrode structure (10), or chlorophyll in the fine positive electrode structure 120, and the battery provides Wei. (4) * The diagram is shown as a machine diagram of the method for manufacturing the battery. As shown in Fig. 3, the method for manufacturing the above-mentioned Wei includes the following steps: 18 201225386 Step S1: Making a high_solution; Step S2: Making a negative electrode structure; step S3 • making an isolation structure; step S4: assembling the drain structure and the isolation structure into the outer casing; and step S5. inserting the current collector into the outer casing and filling the positive electrode material into the above-mentioned structure to open The positive electrode structure is completed to complete the fabrication of the entire battery. Figure 4 is a detailed flow chart of the step S1 shown in Figure 3. As shown in Figure 4, the preparation of the high polymer solution of the step S1 comprises the following steps: Step S11: slowly adding the polymer powder in a solvent having a temperature of 40 degrees Celsius; Step S12. Mixing the solution at a rotation speed of 500 to 700 RPM using a magnet dialing machine; • Step S13: detecting the conductivity of the solution using a conductivity meter Up to 5〇-250ms/cm; when the above detection result is no, then return to step §11, and when the above detection result is YES, then step S14 is performed; and step S14: is completed. In this embodiment, The solvent is a solvent having a polarity and a pH of more than 3. Preferably, the solvent is selected from one or more of water, sea water, tea, coffee, fruit juice, wine, etc. Figure 5 is a step S2 of Figure 3 The specific flow chart is as shown in Fig. 5, 201225386. The negative electrode structure of the step S2 includes the following steps: Step S21: filtering the chlorophyll powder with a sieve; Step S22: pouring the polymer solution; Step S23: using a magnet mixer at a rotation speed 5〇〇~7〇〇RpM is given to the drop; Step S24··determine whether the uniform fluid is reached; when the above judgment result is No, the process returns to step S22, and when the above judgment result is YES, the execution is performed. Step S25: Step S25: applying the above fluid onto the conductive material layer; Step S26: placing the above structure in an oven just after Celsius for baking until the water is evaporated to complete the fabrication of the negative electrode structure. - Figure 6 is a diagram A specific flow chart of the steps shown in Fig. 3. As shown in Fig. 6, the fabrication of the isolation structure of the step S3 comprises the following steps: • Step S31 ··Removing the isolation film; Step S32: Soaking the cut isolation film in the high concentration In the body solution; Step S33: taking out the separator and placing it in the excitation 'baking until the water is evaporated to make two separators; baking step S34: taking out a separator, spraying the electrolyte material; and steps S35H is another side-side _ complete _ structure production. The edge of Fig. 7 is shown as a specific flow chart of step S4 shown in Fig. 3. As shown in Figure 7, the negative electrode structure and the isolation structure are assembled into the outer casing as shown in step S4. ♦ include the steps of 20 201225386: Step S41: attaching the negative electrode structure to the outer casing; step S42: using the first hollow rod to close the isolation structure Rolled up, wherein the first hollow rod has an inner diameter of 4.5 mm, an outer diameter of 6 36 mm, and a length of 47.2 mm. » Step S43: screwing the first hollow rod of the winding structure into the outer casing with a negative electrode structure in a clockwise direction Step S44: retaining the first hollow rod take-out isolation structure in a counterclockwise direction in the outer casing having the negative electrode structure; step S45: checking whether the isolation structure is attached to the negative electrode structure in the outer casing; when the above inspection result is no If the result of the above-mentioned inspection is YES, step S47 is performed; step S46: whether the isolated structure is broken or not; if the result of the determination is no, the process returns to step S42; Knot: If yes, then step S46a is performed; step S46a. The isolation structure is replaced and the process returns to step S42; and step 47 is completed. Figure 8 is not a specific flow chart of the step % shown in Figure 3. The step of inserting the current collector into the foreign material and filling the positive electrode material to form the positive electrode structure as shown in step S5 of FIG. 2 includes the following steps: 201225386 Step S51: slowly filling the positive electrode material in the outer casing having the negative electrode structure and the isolation structure; vStep S52: Insert the current collector into the center of the outer casing; Step S53. Fill the pressure material with the first hollow rod and the vise and continue to fill the positive electrode material; • Step S54 • Examine whether the positive electrode material reaches the required weight; ,. If the result is no, then go back to step S53, when the above-mentioned inspection result is YES, then step S55 is performed; and v is step S55. The positive structure is modified by the second hollow rod, wherein the inner diameter of the second hollow rod is 4.5 mm. The outer balance is 9.94 mm and the length is 47 2 mm to complete the fabrication of the positive electrode structure. The battery disclosed in the present invention can utilize the chlorophyll in its positive and negative structures to store hydrogen to achieve the purpose of power supply. Preferably, the positive and negative structures all comprise chlorophyll, but have different work functions. That is, in the oxidation of the battery, the chlorophyll is formed by the detachment of the magnesium ions of the towel to form chlorophyll (Phe〇Phytln), and the magnesium-deficient portion can combine two hydrogen ions, so that hydrogen can be stored. . In addition, since the battery of the present invention replaces the dyeing component of the conventional battery with a natural environmentally-friendly substance, it does not pollute the environment even if it is discarded, and the degree of environmental protection is much better than that of the conventional battery. It should be noted that in the embodiment of the present invention, the words "first", 22 201225386 second, and the like are only used as needed, and are not limited to this in practice, and the characters can be used interchangeably. . The subject matter disclosed above is considered to be illustrative and not restrictive, and the scope of the appended claims are intended to cover all modifications and other embodiments of the invention. Therefore, the maximum range allowed by law can be improved by riding and equalizing

物之最歧許可之崎來確定本㈣之料且並不受到前 述實施方式的詳細描述的局限或限制。 【圖式簡單說明】 入本對於本發明的進一步理解,且附圖併 入本說明書巾並且構成本㈣書的—部份 明之示範性實施例。在諸圖中: 、Θ έ本發 圖i是本發明一實施例所揭示的電池的結構示意圖。 圖2是本發明—實施例所揭示㈣極結構的結構示意圖。 圖3是本發明-實施例所揭示之電池的製作方法的流程 圖。 圖4繪示為圖3所示之步驟S1的具體流程圖。 圖5繪示為圖3所示之步驟S2的具體流程巴 圖6繪示為圖3所示之步驟S3的具體流程圖 圖7繪示為圖3所示之步驟S4的具體济^圖 圖8繪示為圖3所示之步驟S5的具體济矛。圖 【主要元件符號說明】 23 201225386 100 電池 110 集流體 120 正極結構 130 隔離結構 131 第一隔離膜 132 第二隔離膜 133 電解質材料 140 負極結構 141 導電材料層 142 負極材料層 150 外殼The most discriminating of the substance is to determine the material of this (4) and is not limited or limited by the detailed description of the foregoing embodiments. BRIEF DESCRIPTION OF THE DRAWINGS [0009] A further understanding of the present invention is incorporated in and constitutes an exemplary embodiment of the present disclosure. In the drawings: FIG. 1 is a schematic structural view of a battery disclosed in an embodiment of the present invention. 2 is a schematic view showing the structure of a (four) pole structure disclosed in the present invention. Fig. 3 is a flow chart showing a method of fabricating a battery according to the present invention. FIG. 4 is a detailed flowchart of step S1 shown in FIG. 3. 5 is a specific flow chart of step S2 shown in FIG. 3, FIG. 6 is a specific flowchart of step S3 shown in FIG. 3, and FIG. 7 is a specific diagram of step S4 shown in FIG. 8 is illustrated as a specific spear of step S5 shown in FIG. Figure [Main component symbol description] 23 201225386 100 Battery 110 Current collector 120 Positive structure 130 Isolation structure 131 First isolation film 132 Second isolation film 133 Electrolyte material 140 Negative electrode structure 141 Conductive material layer 142 Anode material layer 150 Case

S卜 S2、S3、S4、S5、Sll、S12、S13、S14、S2卜 S22、 S23、S24、S25、S26、S31、S32、S33、S34、S35、S4卜 S42、 S43、S44、S45、S46、S46a、S47、S51、S52、S53、S54、S55 : 步驟Sb S2, S3, S4, S5, S11, S12, S13, S14, S2, S22, S23, S24, S25, S26, S31, S32, S33, S34, S35, S4, S42, S43, S44, S45, S46, S46a, S47, S51, S52, S53, S54, S55: Steps

24twenty four

Claims (1)

201225386 七、申請專利範圍: 1. -種電相製造方法,其特徵在於包細下步驟: 步驟S1:製作高聚體溶液; 步驟S2 :製作負椏結構; 步驟S3 :製作隔離結構; • 步驟S4 :將負極結構以及隔離結構組裝進外殼中;以及 步驟S5 :將集流體插入外殼中並填充正極材料至上述結 構中以形成正極結構; 其中所述負極結構及所述正極結構中的至少之一包括葉 綠素。 2. 根據申请專利範圍第1項所述之電池的製作方法,其特 徵在於’所述步驟S1包括以下步驟: • 步驟SU :在溫度40攝氏度的溶劑中緩慢添加高聚體粉 末; 步驟S12 :利用磁石攪拌機以轉速5〇〇〜7〇〇RpM攪拌上述 溶液; 步驟S13 .使用導電度計檢測上述溶液的導電度是否達到 50-250ms/cm;當上述檢測結果為否時,則返回執行步驟su, 而當上述檢測結果為是時,則執行步驟S14 ;以及 步驟S14 :完成。 25 201225386 3. 根據申請專利範圍第2項所述之電池的製作方法,其特 徵纽,所述躲體粉末金屬離顿各_贿子的化合 物以及高聚體’其濃度含量皆在0.U10莫耳/升間。 口 4. 根據申請專利範圍第3項所述之電池的製作方法,其特 徵在於,所述高聚體粉末還包括維生素。 φ 5.根據申請專利範圍第4項所述之電池的製作方法,其特 徵在於,所述維生素為維生素D。 6. 根據申請專纖圍第3摘述之電池㈣作方法,其特 徵在於,所述高聚體為葡萄糖的高聚體。 7. 根據申請專植圍第6項所述之電池的製作方法,其特 徵在於’所述葡萄糖的高聚體為馬鈴薯澱粉、菱角搬粉、玉米 澱粉 '地瓜粉 '蓮藕ί殿粉、芥末粉和葛根粉中的—種或多種 • 8·根據申請專觀圍第3項所述之電池的製作方法,其特 於,麟金屬離子與各紐根離子的化合物為碳酸約。、 9. 根據申料利範圍第8項所述之電池的製作方法,其特 徵在於,所述金屬離子與各類酸根離子的化合物為天然植物化 學成分,所述天然植物化學成分包括木脂素類、低聚糖、多糖、 黃酮類、環烯㈣類、脂肪酸、東蓖菪内醋、兒茶素、Ρ縠固 醇、虎刺素和生物驗類。 10. 根據申請專利範圍第2項所述之電池的製作方法,其 26 201225386 特徵在於,所述溶劑為帶極性、pH值大於3之溶劑。 11. 根據申請專利範圍第10項所述之電池的製作方法,其 特徵在於,所述溶劑選自水、海水、茶、咖啡、果汁、西中的 一種或多種。201225386 VII. Patent application scope: 1. A method for manufacturing an electric phase, characterized in that the steps are as follows: Step S1: preparing a polymer solution; Step S2: fabricating a negative structure; Step S3: fabricating an isolation structure; S4: assembling the negative electrode structure and the isolation structure into the outer casing; and step S5: inserting the current collector into the outer casing and filling the positive electrode material into the above structure to form a positive electrode structure; wherein at least the negative electrode structure and the positive electrode structure One includes chlorophyll. 2. The method of manufacturing a battery according to claim 1, wherein the step S1 comprises the following steps: • Step SU: slowly adding a polymer powder in a solvent having a temperature of 40 degrees Celsius; Step S12: The solution is stirred by a magnet mixer at a rotation speed of 5 〇〇 to 7 Torr RpM; Step S13. Using a conductivity meter to detect whether the conductivity of the solution reaches 50-250 ms/cm; when the above detection result is no, return to the execution step. Su, and when the above detection result is YES, step S14 is performed; and step S14: is completed. 25 201225386 3. According to the method for manufacturing a battery according to claim 2, the feature of the battery is that the compound powder and the high polymer are in a concentration of 0. U10. Moor / liter. The method for producing a battery according to the third aspect of the invention, wherein the polymer powder further comprises a vitamin. The method for producing a battery according to the fourth aspect of the invention, wherein the vitamin is vitamin D. 6. The method according to claim 3, wherein the polymer is a polymer of glucose. 7. According to the method for preparing the battery according to Item 6 of the application, the high polymer of the glucose is potato starch, water chestnut powder, corn starch 'sweet potato powder' lotus root lotus powder, mustard powder And one or more of the puerarin powders. 8. The method for producing a battery according to the third aspect of the application, which is characterized in that the compound of the lining metal ion and each nucleus ion is about carbonic acid. 9. The method according to claim 8, wherein the metal ion and the compound of the various acid ions are natural phytochemical components, and the natural phytochemical comprises lignans. Classes, oligosaccharides, polysaccharides, flavonoids, cycloolefins (tetra), fatty acids, sorghum, catechins, steroids, succulents and bioassays. 10. The method according to claim 2, wherein the solvent is a solvent having a polarity and a pH greater than 3. 11. The method of producing a battery according to claim 10, wherein the solvent is one or more selected from the group consisting of water, sea water, tea, coffee, fruit juice, and west. 12. 根據申請專利範圍第1項所述之電池的製作方法,其 特徵在於,所述高聚體溶液的PH值為5.5-8。 13. 根據申請專利範圍第2項所述之電池的製作方法,其 特徵在於,所述步驟S2包括以下步驟: 步驟S21 :以據網過濾葉綠素粉末; 步驟S22 :倒入高聚體溶液; 步驟S23:利用磁石擾拌機以轉速·〜7〇〇RpM進行擾摔; 步驟S24 :判斷是否達到均勻流體;當上述判斷結果為否 時’則返回執行步驟S22,當上述判斷結果為是時,、:二 驟S25 ; 、執仃乂 步驟S25 :將上述流體塗佈至導電材料層上; 步驟S% :將上述結構放置於卿攝氏度的烤箱中, 至水份蒸發從而完成負極結構之製作。 ,、烤 根據申請專利範圍第13項所述之電池的製作方法 特徵在於,所述導電材料層由導電材料而製成。/,其 根射請專利第14項所述之電池的製作方法, 其 27 201225386 特徵在於,所述導電材料為金屬。 16.根據申請專利範圍第】5項所述之電池的製作方法苴 特徵在於,所述金屬選自鋁和/或金。 / 17·根據申請專利範圍第14項所述之電池的製作方去苴 特徵在於’所述導電材料為金屬化合物。12. The method of producing a battery according to claim 1, wherein the polymer solution has a pH of 5.5-8. The method for manufacturing a battery according to claim 2, wherein the step S2 comprises the following steps: Step S21: filtering the chlorophyll powder according to the net; step S22: pouring the polymer solution; S23: using a magnet scrambler to perform the scrambling at a rotation speed of ~7〇〇RpM; step S24: determining whether a uniform fluid is reached; when the determination result is no, then returning to step S22, when the determination result is yes, , step S25, and step S25: applying the above fluid to the conductive material layer; Step S%: placing the above structure in an oven of a degree Celsius, and evaporating the water to complete the fabrication of the negative electrode structure. The method for fabricating the battery according to claim 13 is characterized in that the conductive material layer is made of a conductive material. The method for fabricating the battery of claim 14, wherein the conductive material is a metal. 16. A method of fabricating a battery according to claim 5, characterized in that the metal is selected from the group consisting of aluminum and/or gold. The battery according to claim 14 is characterized in that the conductive material is a metal compound. 18.根據申請專利範圍第π項所述之電池的製作方法,其 特徵在於’所述金屬化合物選自一氧化錳、氧化鋅和氧化鎂中 的一種或多種。 、 19. 根據申請專利範圍第14項所述之電池的製作方法,其 特徵在於,所述導電材料為導電高分子材料。 〃 20. 根據申請專利範圍第19項所述之電池的製作方去,其 特徵在於,所述導電高分子材料選自雜環或芳香族雜環化人 物。 21. 根據申請專利範圍第20項所述之電池的製作方法,其 特徵在於,所述導電高分子材料選自以下化合物中的一種戋夕 種:聚乙炔、聚芳香烴乙烯、聚噻吩、聚笨胺、聚哒咯、聚^ 咯和上述化合物的衍生物。 22. 根據申請專利範圍第13項所述之電池的製作方法,其 特徵在於,所述葉綠素為葉綠素a、葉綠素b、葉綠素cl和 葉綠素c2、葉綠素d、及葉綠素e中的一種或多種。 28 201225386 23.根據申請專利範圍第22項所述之電池的製作 特徵在於,所述葉綠素不包括葉綠素氧化酶。 / 、 24·根據申請專利範圍第13項所述之電池的製作方法立 特徵在於,所述負極結構為膜片狀。 ’其 25. 根據申請專利範圍帛24項所述之電池的製作方法,复 • 特徵在於,所述負極結構的長度為6〇mm,而其寬度為5〇仿其 26. 根據申請專利範圍第13項所述之電池的製作方法咖复 特徵在於,所述步驟S3包括以下步驟: 、其 步驟S31 :裁減好隔離膜; 步驟S32 :將裁減好的隔離膜浸泡在高聚體溶液中; 步驟S33 :取出隔離膜並將其放置於卿攝氏度的烤箱 中,烘烤至水份蒸發以製作兩個隔離膜; 鲁㈣S34:取出-個隔離膜’均勻喷灑電解質材料;以 步驟S35 :覆蓋上另一個隔離膜。 ' 27. 根據申請專利範圍第26項所述之電池的製作方法,其 特徵在於’所述隔離膜採用高纖維材質製成。 、 根據申凊專利範圍第π項所述之電池的製作方去,复 特徵在於’所述高纖維材質為紙類。 、 29·根據申請專利範圍第28項所述之電池的製作方法,苴 特徵在於,所述紙類包括破璃紙、棉紙、宣紙及頌、紙。、18. The method of producing a battery according to the invention, wherein the metal compound is selected from one or more of the group consisting of manganese monoxide, zinc oxide and magnesium oxide. 19. The method of manufacturing a battery according to claim 14, wherein the conductive material is a conductive polymer material. The battery according to claim 19, wherein the conductive polymer material is selected from a heterocyclic or aromatic heterocyclic human. The method for fabricating a battery according to claim 20, wherein the conductive polymer material is selected from the group consisting of polyacetylene, polyarylene, polythiophene, poly A strepamine, a polypyrrole, a poly(R) and a derivative of the above compound. 22. The method of producing a battery according to claim 13, wherein the chlorophyll is one or more of chlorophyll a, chlorophyll b, chlorophyll cl and chlorophyll c2, chlorophyll d, and chlorophyll e. The production of the battery according to claim 22 is characterized in that the chlorophyll does not include chlorophyll oxidase. The method for producing a battery according to claim 13 is characterized in that the negative electrode structure is in the form of a diaphragm. '25. According to the method of manufacturing the battery according to claim 24, the negative electrode structure has a length of 6 mm and a width of 5 〇. 26. According to the scope of the patent application The method for manufacturing the battery according to claim 13 is characterized in that the step S3 comprises the following steps: Step S31: cutting off the separator; Step S32: immersing the cut separator in the polymer solution; S33: taking out the separator and placing it in an oven at a temperature of Celsius, baking until the water is evaporated to make two separators; Lu (4) S34: taking out a separator film to uniformly spray the electrolyte material; in step S35: covering Another barrier film. 27. The method of manufacturing a battery according to claim 26, wherein the separator is made of a high fiber material. According to the manufacturer of the battery described in the πth patent application scope, the feature is that the high-fiber material is paper. The method for producing a battery according to claim 28, characterized in that the paper comprises a glass paper, a cotton paper, a rice paper, and a paper or paper. , 29 201225386 30.根攄_絲_圍第π項所述之電池的製作方法,发 特徵在於,所述高纖維材質的孔隙大小介於〇 〇ι帅〜_ /、 間。 < 31. 根據申請專利範圍第27項所述之電池的製作 特徵在於,所述隔離膜為臈片狀。29 201225386 30. The method for manufacturing a battery according to the item _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ < 31. The battery according to claim 27, wherein the separator is in the form of a sheet. 32. 根據申請專利範圍第31項所述之電池的製作方 舰在於’所述隔_的長度為55mm,寬度為5Qmm遺 厚度為0.2mm。 $ 处根據申請專利範圍第%項所述之電池的製作方法, 特徵在於’所述轉_料財誠織_水者應 鹽類與葉《的水麵。 μ者有機32. The battery according to claim 31, wherein the said ship has a length of 55 mm and a width of 5 Qmm and a thickness of 0.2 mm. The manufacturing method of the battery according to item % of the patent application scope is characterized by the fact that the water is produced by the salt and leaf of the water. μ organic 3:據申請專利範圍第幻項所述之電池的製作方法,龙 」在於’所述有機鹽類水溶液的導電度為 ” 10ms/cm-500ms/cm。 35. 根獅請專利_第%顿述之電池 特徵在於’所述有触_含_有機_。法’其 36. 根據申請專利範圍第%項所述之電池的 特徵在於,所述右嫌 作方法,其 汁边有機或無機鹽類為包含碘化 化鈉中的1衫種。 贱納和氫氧 37·根據申請專利範圍第26項所述之電池的製作方法,其 30 201225386 特徵在於,所述步驟S4包括以下步驟: 步驟S41 ··將負極結構貼合至外殼中; 步驟S42 :使用第-中空棒將隔離結構緊密捲起; 步驟S43 :將捲起隔離結構之第一中空棒以順時針方向旋 入具有負極結構的外殼中; 步驟S44 :以逆時針方向將第一中轉取出以將隔離結揭 保留在具有負極結構的外殼中; ,4S45 .檢視隔雜構是否朗於外殼巾的負極結構; 2述檢視結果為否時’則執行步驟撕;當上述檢視結果為 疋時’則執行步驟S47 ; 步驟S46 :抽出隔離結構並判斷隔離結觀否損壞;當上 ^斷結_時,_執行步細;#上_結: 疋時,則執行步驟S46a ; 步驟S46a .更換隔離結構並返回執行步驟S42 ;以及 步驟S47 :完成組裝。 38. 根射請糊_ 37項所述之電池的製作方法 ^在於’所述第-中空棒的内直徑為45咖,外直經為、 636mm ’ 長度為 47,2mm。 39. 根據申請專利範圍第37項所述之電池的製作方法,龙 特徵在於’所述外殼為-個外徑為R5_,内徑為12 5_ 31 201225386 長度為48.4mm的紙管。 /〇.根射請專利綱第37項所述之電池的製作方法,其 特徵在於,所述步驟S5包括以下步驟: 步驟S51 充正極材料; 於具有負極結構以及隔離結構之外殼中緩慢填3: According to the method for manufacturing the battery according to the illusion of the patent application scope, the dragon is in that the conductivity of the aqueous solution of the organic salt is “10 ms/cm-500 ms/cm. 35. The lion is invited to patent _ The battery is characterized by 'the touched-containing_organic_. The method' is 36. The battery according to claim 100, characterized in that the right-handed method, the juice-side organic or inorganic salt The method of manufacturing a battery according to claim 26 of the invention, wherein the step S4 comprises the following steps: S41 · attaching the negative electrode structure to the outer casing; step S42: using the first hollow rod to tightly wind up the isolation structure; step S43: screwing the first hollow rod of the winding isolation structure into the negative electrode structure in a clockwise direction Step S44: taking the first intermediate rotation in a counterclockwise direction to retain the isolation knot in the outer casing having the negative electrode structure; 4S45. Whether the inspection structure is perpendicular to the negative electrode structure of the outer casing; If no Then, step tearing is performed; when the above-mentioned viewing result is 疋, then step S47 is performed; step S46: extracting the isolation structure and judging whether the isolation node is damaged or not; when the upper part is broken, the _ execution step is fine; #上_结:疋, then step S46a is performed; step S46a. The isolation structure is replaced and the process returns to step S42; and step S47: the assembly is completed. 38. The method of making the battery according to the item 37 is described in the The inner diameter of the hollow rod is 45 coffee, and the outer straight diameter is 636 mm 'the length is 47, 2 mm. 39. According to the method for manufacturing the battery according to claim 37, the dragon is characterized in that the outer shell is - outer A paper tube having a diameter of R5_, an inner diameter of 12 5_31 201225386 and a length of 48.4 mm. The method of manufacturing the battery according to the invention of claim 37, wherein the step S5 comprises the following steps: Step S51, filling the positive electrode material; slowly filling in the outer casing having the negative electrode structure and the isolation structure 步驟S52 :將集流體插入外殼的十心; 步驟S53 .使用第—中空棒與虎钳填壓並繼續填入正極材 ^S54 .檢視正極材料是否達到所需的重量丨當上述右 ^吉果為否時,則返回執行步驟的,當上述檢視結田果為是 時,則執行步驟S55 ;以及 ·以第二中空棒修飾正極結構,其中從而完成』 極結構的製作。 .艮據申請專概圍第⑽賴述之電池的製作 特徵在於,所述第二中空棒的内直徑為45_靜’ 9·9— ’長度為47.2咖。 ^為 42·根據申請專利範圍第4〇項所述之電池的製作方法,其 特徵在於,所述集流體為一體。 / /3.根據申請專利範圍第42項所述之電池的製作方法,其 特徵在於’所述集流體的直徑為4_,而其長度為47.2mm。 32Step S52: inserting the current collector into the ten cores of the outer casing; Step S53. Filling with the first hollow rod and the vise and continuing to fill the positive electrode material ^S54. Check whether the positive electrode material reaches the required weight. If no, return to the execution step. When the above-mentioned inspection result is YES, step S55 is performed; and the second hollow rod is used to modify the positive electrode structure, thereby completing the fabrication of the pole structure. The battery according to the application (10) is characterized in that the inner diameter of the second hollow rod is 45_static'9·9-' and the length is 47.2 coffee. The method for producing a battery according to the fourth aspect of the invention, wherein the current collector is integrated. The method of manufacturing a battery according to claim 42, wherein the current collector has a diameter of 4 mm and a length of 47.2 mm. 32 201225386 44.根據申請專利範 $ 4G摘叙電池的_方法,Λ 所逃正極材料為粉末狀。 其特=在44撕述之祕_作方法, 、、;视正極材料包含葉綠素粉末。 特徵:據所申Γ專利範圍第45項所述之電池的製作方法,其 高分子粉末/正極材料進—步包括碳布、碳末或者奈米導電 仪根據申請專利範圍第46項所述之電池的製作方法,其 特徵在於’所述碳布或者碳末為自销稱似、碳黑、碳煙、、 玻璃碳或者玻碳、奈米碳管、活性碳、鑽石、金甽石、曰 碳、石墨稀、富勒稀、石墨、碳炔、雙原子碳、C3、原::質 石墨化性碳素、熱分解碳類’焦炭類中的一種或多種 48·根據申請專利範圍第46項所述之電池的製作方去其 特徵在於’所述導電高分子的材料選自雜環或芳香姨雜@ > 物。 33201225386 44. According to the patent application model 4 4, the method of extracting the battery is 粉末, and the escaping cathode material is powdery. Its special = secretive at 44, as a method, ,;; depending on the cathode material contains chlorophyll powder. The method of manufacturing the battery according to claim 45, wherein the polymer powder/positive electrode material further comprises a carbon cloth, a carbon powder or a nanometer conductivity meter according to claim 46 of the patent application scope. The manufacturing method of the battery is characterized in that 'the carbon cloth or carbon powder is self-selling, carbon black, soot, glass carbon or glassy carbon, carbon nanotube, activated carbon, diamond, diamond, bismuth One or more of carbon, graphite thin, fullerene, graphite, carbyne, diatomic carbon, C3, original: graphitized carbon, thermal decomposition carbon type 'coke' 48. According to the scope of patent application 46 The battery described in the item is characterized in that the material of the conductive polymer is selected from a heterocyclic ring or an aromatic noisy @>. 33
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