201225387 六、發明說明： 【發明所屬之技術領域】 本申請請求於2008年12月24曰遞交的美國專利申請第 觀伽號以及於時5月16日遞交的臺灣專利申請第 97卿7號的在先權益。以上树專利文獻的全部内容在此 作為參考引用引入本申請。 本發明涉及-種電池及其製造方法，特別涉及一種使用葉 綠素來產生電能之電池及其製造方法。 【先前技術】 近年來’陸續出現了行動電話、手提式攝影機、筆記型電 腦、數位相機、PDA、CD player等輕便型電子機器，並謀求 其小型及輕量化’崎此，作為可攜帶之輕便電源·電池也 同樣受到關注。電池種類包括乾電池、鎳氫電池、經電池與燃 料電池等。下面將簡單介紹常見電池。 曰常使用的乾電池大多是鋅錳電池，也叫碳鋅電池。碳鋅 電池的外殼一般由鋅構成，其既可以作為電池的容器 ，又可以 作為電池的負極。碳鋅電池是從液體Leclanch6電池發展而 來。傳統或一般型碳鋅電池以氣化銨為電解質；超級或高能碳 鋅電池則通常是使用氣化辞為電解質的碳鋅電池，是一般廉價 電池的改良版。碳鋅電池的正極主要是由粉末狀的二氧化錳和 201225387 碳構成。電解液是把氯化鋅和氯化銨溶於水中所形成的糊狀溶 液。碳鋅電池是最便宜的原電池，因此成為很多廠商的首選’ 因為這些廠商所銷售的設備中常常需要配送電池。鋅碳電池可 以用於遙控器、閃光燈、玩具或電晶體收音機等功率不大的設 備。 然而’當碳鋅電池使用一段時間以後，由於金屬鋅被氧化 成為鋅離子’鋅外殼會逐漸變薄。因此，氣化鋅溶液常常可以 從電池中洩漏出來。洩漏出來的氯化鋅往往會使電池表面變 枯。一些老的電池沒有洩漏保護。鋅碳電池的使用壽命比較 短’保存期一般為一年半。另外，就算電池沒有使用，電池内 的氣化銨有弱酸性，可以與鋅反應，辞外殼也會慢慢的變薄。 現在3C產業常提到的鋰電池其實是鋰鈷電池，廣義的可 充放鋰電池是指由一個石墨負極、一個採用鈷、錳或磷酸鐵的 正極以及種用於傳送鍾離子的電解液所構成。而一次链離 子電池則可以链金屬或者嵌鋪料作為負極。㈣池產業發展 20多年來一直集中在3C產業為主，鮮少應用在市場經濟規模 更大的儲能和動力電池（_f要較大電流）市場，這市場涵 蓋純電動車、油電混合車、中大型UPS、太陽能、大型儲能 電池、電動手工具、電動摩托車、電動自行車、航太設備盘飛 機用電料镇。其主要·是過核f池採_錄正極材 201225387 料（LiCo〇2，就是現在最常見的鋰電池），無法應用在需要大 電流、高電壓、高扭力以及具有耐受穿刺、衝撞和高溫、低溫 等條件等特殊環境，更重要的是，因無法滿足人㈣安全的絕 對要求而飽受話病。 同時’細τ電池也無法達雜速充電與完全避免二次污染 等目的’而且’-定要設計賴餘雜止過度充電或過度放 電，否則齡造祕料危險，甚至城如SQny電池爆炸導 致全球品牌NB業者投下鉅資回收的情況。 另外姑的f貝格愈來愈尚昂，全球敍元素最大生產國剛 果戰亂紛擾夕，導致銘元素價格不斷升高。經姑電池的粉體 因钻元素彳胃格不斷H現在已從原先的每公斤*美元漲價 到60〜70美元。麟酸鐘鐵粉體依品質好壞，每公斤售價在％〜⑹ 美元。 錄氫電池的設計祕麟電池。1982年漏OVONIC公 司請求儲氫合知於電極製造之專利，使得此—材料受到重 視’繼之為1985年荷蘭飛利浦公司突破了儲氫合金在充放電 過程中容量衰減的問題终使鎳氫電池脫穎而出。 目前在日本有 8家以上錄氫電池製造薇，德國，美國，香港，台灣亦有錄氫 電池生產’市;％反應良好。而且錄氫電池所造成之污染，會比 3有録之频電池顿乡，因此，目前賴電池已逐漸被錄氮 201225387 電池取代。 燃料電池（Fuel cell)是-種使用燃料進行化學反應產生 電力的裝置，最早於1839年由英國的Gr〇ve所發明。最常見 是以氫氧為鋪的質子交換麵料電池，由於罐價格平宜， 加上對人體無化學危險、對環境無害，發電後產生純水和熱， 1960年代剌在美國軍方，後於1%5年應餘朗雙子星座 • 計劃雙子星座5號飛船。現在也有一些筆記型電腦開始研究使 用燃料電池。但由於產生的電量太小，且無法_提供大量電 能，只能用於平穩供電上。燃料電池是一個電池本體與燃料箱 組合而成的動力機制。燃料的選擇性非常高，包括純氣氣、甲 醇、乙醇、天然氣，甚至約見在運用最廣泛的汽油，都可以做 為燃料電池的燃料。 不論是新型強調環保的碳鋅電池'鹼性電池及二次電池， I在製程上還是會使用少量躲或其健金屬如料而且在原 料及制程上使用具污紐的物¥，對環境以及人_具有較大 危害。 曰月 ，‘用贋泛的鋰電池屬不穩定的電化學裝置，若 私、封裝不當、運作於低貞載，都可能會引起_。因此需要 多重複雜的保護機制’比如包括保護電路、排氣孔、隔離膜等， 其中保護電路用於防止過充、過放、超載、過熱；排氣孔用於 201225387 避免電池内部壓強過大; 隔離膜具有較高的抗穿刺強度，以防 止内。p紐路且在電池内部溫度過高時還能融化，阻止裡離子 通過’阻滯電池反應，升高 向内阻(至2kQ)。201225387 VI. Description of the Invention: [Technical Field of the Invention] This application claims the US Patent Application No. 380, which was filed on December 24, 2008, and the Taiwan Patent Application No. 97, No. 7, which was filed on May 16, 2008. Prior rights. The entire disclosure of the above patents is incorporated herein by reference. The present invention relates to a battery and a method of manufacturing the same, and more particularly to a battery using chlorophyll to generate electric energy and a method of manufacturing the same. [Prior Art] In recent years, mobile electronic devices such as mobile phones, portable cameras, notebook computers, digital cameras, PDAs, CD players, etc. have emerged, and they are seeking to be small and lightweight. Power and battery are also receiving attention. Battery types include dry batteries, nickel-metal hydride batteries, batteries and fuel cells. A brief description of common batteries is given below. Most of the dry batteries commonly used are zinc-manganese batteries, also called carbon-zinc batteries. The outer casing of a carbon-zinc battery is generally made of zinc, which can serve as both a battery container and a battery negative electrode. Carbon zinc batteries are developed from liquid Leclanch6 batteries. Conventional or general-purpose carbon-zinc batteries use vaporized ammonium as an electrolyte; super- or high-energy carbon-zinc batteries are usually carbon-zinc batteries that use gasification as an electrolyte, and are an improved version of a generally inexpensive battery. The positive electrode of the carbon zinc battery is mainly composed of powdered manganese dioxide and 201225387 carbon. The electrolyte is a paste solution formed by dissolving zinc chloride and ammonium chloride in water. Carbon-zinc batteries are the cheapest primary batteries, so they are the first choice of many manufacturers' because they often need to distribute batteries in the equipment sold by these manufacturers. Zinc-carbon batteries can be used in low-power devices such as remote controls, flashlights, toys, or transistor radios. However, when the carbon-zinc battery is used for a while, the zinc alloy is gradually thinned due to oxidation of the metal zinc to zinc ions. Therefore, the zinc vapor solution can often leak out of the battery. The leaked zinc chloride tends to make the battery surface dry. Some old batteries have no leakage protection. The service life of zinc-carbon batteries is relatively short. The shelf life is generally one and a half years. In addition, even if the battery is not used, the vaporized ammonium in the battery is weakly acidic, and it can react with zinc, and the outer shell will gradually become thinner. The lithium battery often mentioned in the 3C industry is actually a lithium-cobalt battery. The generalized rechargeable lithium battery refers to a graphite anode, a cathode using cobalt, manganese or iron phosphate, and an electrolyte for transporting clock ions. Composition. The primary chain ion battery can be chain metal or embedded material as the negative electrode. (4) The development of the pool industry has been concentrated in the 3C industry for more than 20 years. It is rarely used in the market for larger energy storage and power batteries (_f to be larger current) in the market economy. This market covers pure electric vehicles and hybrid electric vehicles. Medium and large UPS, solar energy, large-scale energy storage batteries, electric hand tools, electric motorcycles, electric bicycles, and aerospace equipment. Its main · is the nuclear f pool mining _ recorded cathode material 201225387 material (LiCo 〇 2, is now the most common lithium battery), can not be applied to the need for high current, high voltage, high torque and withstand puncture, collision and high temperature Special circumstances such as low temperature and other conditions, and more importantly, suffering from the inability to meet the absolute requirements of human (4) safety. At the same time, 'thin τ battery can not achieve the purpose of random charging and completely avoid secondary pollution, and '- must be designed to rely on excessive charging or over-discharge, otherwise the age of secret materials is dangerous, even the city like SQny battery explosion The global brand NB industry has invested heavily in recycling. In addition, the aunt's f-beige is becoming more and more prosperous, and the world's largest production country, Gangguo, is in a state of chaos, causing the price of the element to rise. The powder of the abundance battery has been increased from the original price per kilogram of US dollar to 60 to 70 US dollars. The price of cinnabar iron powder is good or bad, and the price per kilogram is in the price of US~(6) USD. The design of the hydrogen battery is the secret battery. In 1982, OVONIC Company requested the storage of hydrogen to know the patents for electrode manufacturing, which made this material worthy of attention. In 1985, Philips of the Netherlands broke through the problem of capacity decay of hydrogen storage alloy during charge and discharge. stand out. At present, there are more than 8 hydrogen-producing batteries in Japan, Germany, the United States, Hong Kong, and Taiwan also have hydrogen production batteries; the market has responded well. Moreover, the pollution caused by the hydrogen storage battery will be better than that of the recorded battery. Therefore, the battery has been gradually replaced by the 201225387 battery. A fuel cell is a device that uses a fuel to chemically generate electricity. It was first invented in 1839 by Gröve of the United Kingdom. The most common proton exchange fabric battery is hydrogen and oxygen. Because the price of the tank is reasonable, and it is chemically harmless to the human body, it is harmless to the environment. It produces pure water and heat after power generation. It was in the US military in the 1960s. 1% 5 years should be Yulang Gemini Constellation • Plan Gemini Constellation 5 spacecraft. There are also some notebook computers that are beginning to study the use of fuel cells. However, since the generated power is too small and cannot provide a large amount of power, it can only be used for smooth power supply. A fuel cell is a dynamic mechanism that combines a battery body with a fuel tank. Fuel selectivity is very high, including pure gas, methanol, ethanol, natural gas, and even the most widely used gasoline, can be used as fuel for fuel cells. Regardless of the new environmentally-friendly carbon-zinc battery 'alkaline batteries and secondary batteries, I will use a small amount of hiding or its metal in the process, and use contaminated materials on raw materials and processes. People _ have a greater hazard. Hao Yue, ‘Using a wide range of lithium batteries is an unstable electrochemical device, which may cause _ if it is private, improperly packaged, or operated at low load. Therefore, multiple complex protection mechanisms are needed, such as protection circuits, vents, isolation membranes, etc., where the protection circuit is used to prevent overcharging, overdischarging, overloading, and overheating; the venting holes are used for 201225387 to avoid excessive internal pressure of the battery; The membrane has a high puncture resistance to prevent internal. The p-newway also melts when the internal temperature of the battery is too high, preventing the ions from passing through the 'blocking battery response, raising the inward resistance (to 2kQ).
鐘電池在溫雜高之料或環境之下效能與壽命皆開始 快速降減。 鎳錫電池_氫電池目具有記憶效應，很容易因充放電不 良，而造成可用容量降低。 【發明内容】 本發明的目的是提供一種電池。 為解決上述問題，本發明實施例提供了一種電池，其包括 碳精棒、正極結構、隔離結構、負極結構以及外殼，所述正極 結構、隔離結構、負極結構以及外殼依次地環繞所述碳精棒， 其中所述正、負極結構中的至少之一包括葉綠素。 根據本發明的一優選實施例，所述負極結構包括導電材料 層以及負極材料層，其中負極材料層形成在導電材料層上。 根據本發明的一優選實施例，所述導電材料層由導電材料 而製成。 根據本發明的一優選實施例，所述導電材料為金屬。 201225387 根據本發明的一優選實施例’所述金屬選自銘和/或金。 根據本發明的一優選實施例，所述導電材料為金屬化合 物0 根據本發明的一優選實施例，所述金屬化合物選自一氧化 猛、氧化鋅和氡化鎂中的一種或多種。 根據本發明的一優選實施例，所述導電材料為導電高分子 材料。 根據本發明的一優選實施例，所述導電高分子材料選自雜 環或芳麵雜環化合物。 根據本發明的一優選實施例，所述導電高分子材料選自以 下化合物中的一種或多種：聚乙炔、聚芳香烴乙烯、聚噻吩、 聚苯胺、聚吆咯、聚吡咯和上述化合物的衍生物。 根據本發明的一優選實施例，所述導電材料層的面積為 5cmX5cm。 根據本發明的一優選實施例，所述負極材料層包括葉綠素 以及高聚體溶液。 根據本發明的一優選實施例’所述葉綠素為葉綠素a、葉 綠素b、葉綠素cl和、葉綠素C2、葉綠素d、及葉綠素e中 的一種或多種。 根據本發明的一優選實施例，所述葉綠素為粉末狀或液 201225387 狀。 根據本發明的一優選實施例，所述葉綠素不包括葉綠素氧 化酶。 根據本發明的一優選實施例，所述高聚體溶液包括：金屬 離子與各類酸根離子的化合物、高聚體及溶劑，其濃度含量皆 在0.1-10莫耳/升間。 鲁 根據本發明的一優選實施例，所述尚聚體溶液還包括維生 素。 根據本發明的一優選實施例，所述維生素為維生素D。 根據本發明的—優選實施例，所述高聚體為葡萄糖的高聚 體。 根據本發明的一優選實施例，所述葡萄糖的高聚體為馬鈴 薯澱粉、菱角澱粉、玉米澱粉、地瓜粉、蓮藕澱粉、芥末粉和 _ 葛根粉中的-種或多種。 根據本發明的_優選實施例，所述金屬離子與各類酸根離 子的化合物為碳酸鈣。 根據本發明的—優選實施例，所述金屬離子與各類酸根離 子的化α物為天然植物化學成分，所述天然植物化學成分包括 木月曰素類低聚糖、多糖、黃峨、輯_類、麟酸、東 Κ宮内醋、兒茶素、Ρ穀轉、虎刺素和生物驗類。 201225387 根據本發明的一優選實施例，所述溶劑為帶極性、PH值 大於3之溶劑。優選地，所述溶劑選自水、海水、茶、咖啡、 果汁、酒中的一種或多種。 根據本發明的一優選實施例，所述高聚體溶液的PH值為 5.5-8。 根據本發明的一優選實施例，所述高聚體溶液的導電度為 • 50-250ms/cm ° 根據本發明的一優選實施例，所述隔離結構包括第一隔離 膜以及第二隔離膜，且所述第二隔離膜設置於所述第一隔離膜 之上。 根據本發明的一優選實施例，所述第一隔離臈以及第二隔 離膜分別採用高纖維材質製成。 根據本發明的一優選實施例，所述高纖維材質為紙類。 • 根據本發明的一優選實施例，所述紙類包括玻璃紙、棉 紙、宣紙及絹紙。 根據本發明的一優選實施例，所述高纖維材質的孔隙大小 介於Ο.ΟΙμιη〜lcm之間。 根據本發明的一優選實施例，所述第一隔離膜與第二隔離 膜的面積分別為5cmX5cm。 根據本發明的一優選實施例，所述第一隔離膜吸附有有機 10 201225387 或無機鹽類水溶液。 根據本發明的一優選實施例，所述古 • 、 延有機或無機鹽類水溶液 的導電度為 10ms/cm-500ms/cni。 根據本發明的-優選實施例，所迷第二隔離膜吸附有有機 或無機鹽類與葉綠素的水溶液。 根據本發明的-優選實施例，所述有機鹽類為非含鐘的有 機鹽類。 根據本發明的-優選實施例，所述有機或無機鹽類選自包 含碘化鈉、氣化鈉和氫氧化鈉中的一種或多種。 人根據本發明的一優選實施例，所述有機或無機鹽類選自包 3八化鈉氣化鈉和氫氧化納中的一種或多種。 根據本發明的一優選實施例，所述正極結構包括導電高分 子膜以及奈料電高分子粉末層，且所述奈料電高分子粉末 層設置在導電高分子膜上。 根據本發明的一優選實施例，所述奈米導電高分子粉末層 包含葉綠素粉末。 根據本發明的一優選實施例，所述導電高分子的材料選自 雜環或芳麵雜環化合物。 根據本發明的一優選實施例，所述導電高分子材料選自以 下化0物中的一種或多種：聚乙炔、聚芳香烴乙烯、聚噻吩、 201225387 聚苯胺、聚各、聚咐^各和上述化合物的衍生物。 根據本發明的一優選實施例，所述導電高分子膜具有孔 隙。 根據本發明的一優選實施例，所述孔隙的大小為 3 Α〜1000Α 〇 根據本發明的一優選實施例，所述導電高分子膜的面積為 5cmX10cm ° 根據本發明的一優選實施例，所述奈米導電高分子粉末層 進一步包含奈米導電高分子粉末。 根據本發明的一優選實施例’所述奈米導電高分子粉末與 葉綠素粉末的重量和為0.1克。 根據本發明的一優選實施例，所述外殼為一紙管。 本發明實施例的電池可利用其正、負極結構中的葉綠素即 可進行儲氫從而達到供電的目的。亦即，在電池之氧化還原反 應中，當葉綠素因其中之鎂離子脫離而形成脫鎂葉綠素 (pheophytm)之際，出缺鎂的部份即能結合兩個氫離子，故 此儲虱。且由於本發明的電池獅天朗環保物質代替傳統電 池中的污_分’物卩使丟棄衫會對魏造成污染，環保 程度遠勝於傳統電池。 【實施方式】 12 201225387 下面結合附圖和實施例對本發明實施例進行詳細說明。 圖1繪示為本發明一實施例所揭示的電池的結構示意 圖。如圖1所示，本發明實施例提供了一種電池1〇〇，其包括 碳精棒110、正極結構12〇、隔離結構13〇、負極結構⑽以 及外殼150。其中正極結構、隔離結構13〇、負極結構_以 及外殼150依次地環繞碳精棒110。 圖2繪示為圖1所示的負極結構的結構示意圖。如圖2所 示’負極結構M0包括導電材㈣141以及負極材料層142， 其中負極材料層142可形成在導電材料層141之上。 具體地，導電材料層141由導電材料而製成。導電材料可 以是金屬'金屬化合物或導電高分子材帐金屬可以選自紹和 /或金。金屬化合物可以選自—氧恤、氧化鋅和氧傾中的 一種或多種。導電高分子㈣選自雜縣環化合物。 根據本發明的-優選實施例，導電高分子材料選自以下化合物The performance and life of the clock battery in the high temperature or high environment begin to decrease rapidly. The nickel-tin battery _ hydrogen battery has a memory effect, and it is easy to cause a decrease in usable capacity due to poor charge and discharge. SUMMARY OF THE INVENTION It is an object of the invention to provide a battery. In order to solve the above problems, an embodiment of the present invention provides a battery including a carbon rod, a positive electrode structure, an isolation structure, a negative electrode structure, and a casing, and the positive electrode structure, the isolation structure, the negative electrode structure, and the outer casing sequentially surround the carbon alloy. A rod, wherein at least one of the positive and negative structures comprises chlorophyll. According to a preferred embodiment of the present invention, the negative electrode structure includes a conductive material layer and a negative electrode material layer, wherein the negative electrode material layer is formed on the conductive material layer. According to a preferred embodiment of the invention, the layer of electrically conductive material is made of a conductive material. According to a preferred embodiment of the invention, the electrically conductive material is a metal. 201225387 A metal according to a preferred embodiment of the invention is selected from the group consisting of Ming and/or Gold. According to a preferred embodiment of the invention, the electrically conductive material is a metal compound. According to a preferred embodiment of the invention, the metal compound is selected from one or more of the group consisting of oxidized, zinc oxide and magnesium hydride. According to a preferred embodiment of the invention, the electrically conductive material is a conductive polymeric material. According to a preferred embodiment of the invention, the electrically conductive polymeric material is selected from the group consisting of heterocyclic or aromatic heterocyclic compounds. According to a preferred embodiment of the present invention, the conductive polymer material is selected from one or more of the following compounds: polyacetylene, polyaryl hydrocarbon, polythiophene, polyaniline, polypyrrole, polypyrrole, and derivatives of the above compounds. Things. According to a preferred embodiment of the invention, the electrically conductive material layer has an area of 5 cm x 5 cm. According to a preferred embodiment of the invention, the negative material layer comprises chlorophyll and a high polymer solution. According to a preferred embodiment of the present invention, the chlorophyll is one or more of chlorophyll a, chlorophyll b, chlorophyll cl and chlorophyll C2, chlorophyll d, and chlorophyll e. According to a preferred embodiment of the invention, the chlorophyll is in the form of a powder or a liquid 201225387. According to a preferred embodiment of the invention, the chlorophyll does not comprise a chlorophyll oxidase. According to a preferred embodiment of the present invention, the polymer solution comprises: a compound of a metal ion and various acid ions, a polymer and a solvent, and the concentration thereof is between 0.1 and 10 m/l. According to a preferred embodiment of the invention, the agglomerate solution further comprises a vitamin. According to a preferred embodiment of the invention, the vitamin is vitamin D. According to a preferred embodiment of the invention, the high polymer is a polymer of glucose. According to a preferred embodiment of the present invention, the high polymer of glucose is one or more of potato starch, water chestnut starch, corn starch, sweet potato powder, lotus root starch, mustard powder, and puerarin powder. According to a preferred embodiment of the invention, the metal ion and the various acid ion ion compound are calcium carbonate. According to a preferred embodiment of the present invention, the metal ion and the chemical substance of each type of acid ion are natural phytochemical components, and the natural phytochemical constituents include muscarinic oligosaccharides, polysaccharides, scutellaria, and _ class, linalic acid, medicinal vinegar, catechin, glutinous rice, tiger thorn and biological test. 201225387 According to a preferred embodiment of the invention, the solvent is a solvent having a polarity and a pH greater than 3. Preferably, the solvent is one or more selected from the group consisting of water, sea water, tea, coffee, fruit juice, and wine. According to a preferred embodiment of the invention, the high polymer solution has a pH of 5.5-8. According to a preferred embodiment of the present invention, the conductivity of the polymer solution is 50-250 ms/cm. According to a preferred embodiment of the present invention, the isolation structure comprises a first isolation film and a second isolation film. And the second isolation film is disposed on the first isolation film. According to a preferred embodiment of the invention, the first barrier rim and the second barrier film are each made of a high fiber material. According to a preferred embodiment of the invention, the high fiber material is paper. • According to a preferred embodiment of the invention, the paper comprises cellophane, cotton paper, rice paper and crepe paper. According to a preferred embodiment of the invention, the high fiber material has a pore size between Ο.ΟΙμιη~lcm. According to a preferred embodiment of the present invention, the areas of the first and second separators are 5 cm x 5 cm, respectively. According to a preferred embodiment of the present invention, the first separator is adsorbed with an organic 10 201225387 or an inorganic salt aqueous solution. According to a preferred embodiment of the invention, the conductivity of the ancient, extended organic or inorganic salt aqueous solution is from 10 ms/cm to 500 ms/cni. According to a preferred embodiment of the present invention, the second separator is adsorbed with an aqueous solution of an organic or inorganic salt and chlorophyll. According to a preferred embodiment of the invention, the organic salt is an organic salt other than a bell. According to a preferred embodiment of the invention, the organic or inorganic salt is selected from one or more of the group consisting of sodium iodide, sodium carbonate and sodium hydroxide. According to a preferred embodiment of the invention, the organic or inorganic salt is selected from one or more of sodium sulphate sodium sulphate and sodium hydride. According to a preferred embodiment of the present invention, the positive electrode structure includes a conductive polymer film and a nano-electropolymer powder layer, and the green polymer powder layer is disposed on the conductive polymer film. According to a preferred embodiment of the invention, the nano-conductive polymer powder layer comprises chlorophyll powder. According to a preferred embodiment of the present invention, the material of the conductive polymer is selected from a heterocyclic or aromatic heterocyclic compound. According to a preferred embodiment of the present invention, the conductive polymer material is selected from one or more of the following: polyacetylene, polyaromatic ethylene, polythiophene, 201225387 polyaniline, poly, polyfluorene, and A derivative of the above compound. According to a preferred embodiment of the present invention, the conductive polymer film has a pore. According to a preferred embodiment of the present invention, the size of the pores is from 3 Α to 1000 Α. According to a preferred embodiment of the present invention, the area of the conductive polymer film is 5 cm×10 cm. According to a preferred embodiment of the present invention, The nano conductive polymer powder layer further contains a nano conductive polymer powder. According to a preferred embodiment of the present invention, the sum of the weight of the nano conductive polymer powder and the chlorophyll powder is 0.1 g. According to a preferred embodiment of the invention, the outer casing is a paper tube. The battery of the embodiment of the present invention can utilize the chlorophyll in the positive and negative structures to perform hydrogen storage to achieve the purpose of power supply. That is, in the redox reaction of the battery, when chlorophyll is decomposed to form pheophytm due to the detachment of magnesium ions, the magnesium-depleted portion can combine two hydrogen ions, so that it is stored. Moreover, since the battery of the present invention, the lion's environmentally-friendly material replaces the dirt in the conventional battery, the discarded shirt will cause pollution to the Wei, and the environmental protection degree is far better than that of the conventional battery. [Embodiment] 12 201225387 Hereinafter, embodiments of the present invention will be described in detail in conjunction with the accompanying drawings and embodiments. FIG. 1 is a schematic structural view of a battery according to an embodiment of the present invention. As shown in FIG. 1, an embodiment of the present invention provides a battery 1 including a carbon rod 110, a positive electrode structure 12, an isolation structure 13A, a negative electrode structure (10), and a casing 150. The positive electrode structure, the isolation structure 13A, the negative electrode structure_and the outer casing 150 sequentially surround the carbon rod 110. 2 is a schematic view showing the structure of the negative electrode structure shown in FIG. 1. As shown in Fig. 2, the negative electrode structure M0 includes a conductive material (four) 141 and a negative electrode material layer 142, wherein the negative electrode material layer 142 may be formed over the conductive material layer 141. Specifically, the conductive material layer 141 is made of a conductive material. The conductive material may be a metal 'metal compound or a conductive polymer material. The metal may be selected from the group consisting of Shaohe and/or gold. The metal compound may be selected from one or more of the group consisting of an oxygen shirt, zinc oxide, and oxygen. The conductive polymer (4) is selected from the group consisting of heterocyclic compounds. According to a preferred embodiment of the invention, the electrically conductive polymeric material is selected from the group consisting of
中的-種或多種：聚乙块、聚芳香烴乙稀、聚。塞吩、聚苯胺、 ”洛、聚对和上述化合_触物。此外，導紐料層的 面積可设定為5cmX5cm。 負極材料層142主要以葉綠素作為負極材料，其中負極材 料層M2的製備是將葉綠素與高聚體溶液依照丨:丨的比例進行 調和，然後以磁石游機以6〇轉/分的速率半大約⑽小 201225387 時，再利用塗佈機塗佈在導電材料層141上，其中塗佈的厚度 大約為0.5_。最後’將上述結構放置入1〇〇攝氏度的烤箱中 洪烤大約6分鐘從而在導電材料層141上形成負極材料層。 葉綠素可以為葉綠素a、葉綠素b、葉綠素cl和、葉綠素 c2、葉綠素d、及葉綠素6中的—種或多種。葉綠素可以為粉 末狀或液狀。所採用的葉綠素已去除葉綠素氧化酶。 咼聚體溶液具有黏合作用，能因此附著並調制導電材料層 之物理及化學特性，使得負極材料層142更黏附於導電材料層 141。此外’高聚體溶液的導電度為5〇 25〇ms/cm。高聚體溶 液可以包括碉、鎂、鋁、鈣、錳及鋅元素之一種或數種。高聚 體/谷液還用於調制導電材料層141的功函數，俾使正負電極間 之電位差能達致所欲之伏特數，如1 5V。 高聚體溶液可以由金屬離子與各類酸根離子的化合物、高 聚體及溶劑按比例調配而成。高聚體可以為葡萄糖的高聚體。 葡萄糖的高聚體可以為植物澱粉，例如為馬鈴薯澱粉、菱角澱 粉、玉米澱粉、地瓜粉、蓮藕澱粉、芬末粉和葛根粉中的一種 或多種。金屬離子與各類酸根離子的化合物可以為碳酸鈣。金 屬離子與各類酸根離子的化合物可以為天然植物化學成分。天 然植物化學成分包括木脂素類、低聚糖、多糖、黃酮類、環烯 醚萜類、脂肪酸、東莨菪内酯、兒茶素、P縠固醇、虎刺素和 201225387 生物驗類。溶劑可以為帶極性、PH值大於3之溶劑，例如： 水、海水、茶、咖脅、果汁或者酒等等。高聚體溶液的PH值 優選為5.5_8。高聚體溶㈣可吨姉生素，例如維生素D。 負極結構140可製成膜片狀，從而提高葉綠素的使用量， 增大接觸_以提高電池的反應面料。此外，本領域技術人 員可理解的是’本發明還可以藉由任何已知技術提高葉綠素的 使用1，増大接觸面積以提高電池的反應面積等。 圖3繪示為圖i所示的隔離結構的結構示意圖。如圖3所 不，隔離結構130包括第一隔離膜131以及第二隔離膜132， 中第一隔離膜132設置在第一隔離膜丨31之上。第一隔離膜 131與第二隔離膜132均分別採用高纖維材質而製成其中高 纖維材質可以為紙類，紙類包括玻璃紙、棉紙、冑紙及絹紙等， 且南纖維材質孔隙大小優選為G⑴卿〜丨⑽。優選地，第一隔 離膜131與第二隔離膜132的面積亦分別為5cmX5cm。 此外，第一隔離膜131吸附有有機或無機鹽類水溶液，其 中有機或無機魏水溶液的導電度為1Qms/em雙ms/cm。而 第二隔離膜132 _材__葉缝的水滅。有機鹽類 為非含鐘的有機鹽類。有機或無機鹽類選自包含以下離子化合 物中的-種或多種：雜鈉、氯化鈉和氫氧化納。 圖4繪不為圖1所示的正極結構12〇的結構示意圖。如圖 201225387 4所示’正極結構120包括導電高分子膜121以及奈米導電高 分子粉末層122，其中奈米導電高分子粉末層122設置在導電 高分子膜121上。導電高分子的材料選自雜環或芳香族雜環化 合物。優選地，導電高分子的材料選自以下化合物中的一種或 多種：聚乙炔、聚芳香烴乙烯、聚噻吩、聚苯胺、聚。必咯、聚 吡咯和上述化合物的衍生物。此外，導電高分子膜的面積為 5cmX10cm ’且具有3A〜1000A的孔隙。 奈米導電高分子粉末層122包括葉綠素粉末，此外，奈米 導電高分子粉末層122可進一步包括奈米導電高分子粉末，其 可藉由在導電高分子膜121上塗佈奈米導電高分子粉末以及 葉綠素粉末而形成，且奈米導電高分子粉末與葉綠素粉末的重 量和約0.1克。 外殼150可為一紙管，用以包覆上述碳精棒11〇、正極結 構120、隔離結構130以及負極結構14〇。 在本實施例中，負極結構14〇與正極結構12〇中均包含有 葉綠素’因此’電池1〇〇工作時，負極結構14〇中的葉綠素及 正極結構層120中的葉綠素會因接收光線或遇到溶液而產生 電子或空穴，從而在電池卿的正極結構12〇與負極結構_ 之間形成雜差啸供_的電流。也就是說，本發明的電池 100以負極結構H0以及正極結構m中的葉綠素來作為能量 16 201225387 來源來提供電能。優選地，負極結構14〇 +的葉綠素與正極斧 構120中的葉綠素具有不同之功函數(woridbnetior^。 雖然在本實施例_，負極結構M0與正極結構12〇令均包 含有葉綠素，但是，本領域技術人員可以理解的是，本發明二 揭不的電池，亦可儘在貞極結構⑽巾設置魏素或者僅在 正極結構m中設置葉綠素，以__素作為能量來源而使 電池提供電能。 圖5繪示為本發明一實施例所揭示之電池的製作方法的 流程圖。如圖5所示，上述電池的製作方法包括以下步驟： 步驟S1 :以碳精棒捲繞正極結構； 步驟S2 :捲繞隔離結構； 步驟S3 :捲繞負極結構；以及 步驟S4，將捲繞了正極結構、隔離結構以及負極結構的 碳精棒套人紙管中從而完成電池的製作。 本發明所揭示的電池可利用其正、負極結構中的葉綠素即 可進行儲氫從而達到供電的目的。優選地，所述正、負極結構 白is葉、彔素’但具有不同之功函數（^触⑽）。亦即， 在電池之氧化_反射，當葉綠雜其巾之_子脫離而形 成脫鎂葉綠素（pheQphytm)之際，出職卩能結合兩 個氮離子’魏職。此外由於本發_電池_天然的環保 201225387 物質代替傳崎池巾的污喊分，用完即使丟棄也不會對環境 造成污染，環保程度遠勝於傳統電池。 “需，要指出的是，在本發明實施例中提到的“第一”、 第二等用語僅是根據需要採㈣文字符號，在實務中 並不限於此，並且該文字符號可以互換使用。 上文所揭露之主題可被認爲是說明性的而不是限制 性的，且預期所附申請專利範圍涵蓋屬於本發明之真實精 朴範伽之所有修改、改進和其他實施例。因此，在法 律允許的最大範圍，可藉由對所附申請專利範圍和其均等 物之最廣泛許可之理解來確定本發明之範，且並不受到前 述實施方式的詳細描述的局限或限制。 【圖式簡單說明】 包括附圖以提供對於本發明的進一步理解，且附圖併 入本說明書中並且構成本說明書的—部份，圖說明 明之示範性實施例。在諸圖十·· • 圖1是本發明一實施例所揭示的電池的結構示意圖。 圖2繪示為圖1所示的負極結構的結構示意圖。 圖3繪示為圖1所示的隔離結構的結構示意圖。 圖4繪示為圖1所示的正極結構的結構示意圖。 圖5繪示為本發明一實施例所揭示之電池的製作方法的 流程圖。 【主要元件符號έ尤明】 100 :電池 18 201225387 11 ο .碳精棒 120 :正極結構 121 :導電高分子膜 122 :奈米導電高分子粉末層 130 :隔離結構 131 :第一隔離膜 132 :第二隔離膜 133 :電解質材料 140 :負極結構 141 :導電材料層 142 :負極材料層 150 :外殼 SI、S2、S3、S4 :步驟Among the species or a variety: poly-b-block, poly-aromatic hydrocarbon, poly. The phenophene, the polyaniline, the ruthenium, the poly-pair, and the above-mentioned compound _ touch. In addition, the area of the guide layer can be set to 5 cm X 5 cm. The anode material layer 142 mainly uses chlorophyll as the anode material, wherein the preparation of the anode material layer M2 The chlorophyll and the high polymer solution are blended according to the ratio of 丨:丨, and then coated on the conductive material layer 141 by a coater at a rate of 6 rpm/minute at a rate of 6 rpm/min. Wherein the thickness of the coating is about 0.5 mm. Finally, the above structure is placed in an oven at 1 ° C for about 6 minutes to form a layer of the negative electrode material on the conductive material layer 141. The chlorophyll can be chlorophyll a, chlorophyll b , chlorophyll cl and chlorophyll c2, chlorophyll d, and chlorophyll 6 in one or more. Chlorophyll may be in powder or liquid form. The chlorophyll used has removed chlorophyll oxidase. The chelating solution has adhesion and can therefore The physical and chemical properties of the conductive material layer are attached and modulated such that the negative electrode material layer 142 is more adhered to the conductive material layer 141. In addition, the conductivity of the 'polymer solution is 5 〇. 25 〇ms/cm. The polymer solution may include one or more of elements of cerium, magnesium, aluminum, calcium, manganese and zinc. The polymer/guar solution is also used to modulate the work function of the layer 141 of the conductive material, The potential difference between the positive and negative electrodes can reach the desired volts, such as 15 V. The polymer solution can be prepared by compounding metal ions with various acid ion compounds, polymers and solvents. The polymer can be A polymer of glucose. The polymer of glucose can be plant starch, for example, one or more of potato starch, water chestnut starch, corn starch, sweet potato powder, lotus root starch, fennel powder and pueraria powder. The acid ion compound may be calcium carbonate. The metal ion and various acid ion compounds may be natural phytochemicals. Natural phytochemicals include lignans, oligosaccharides, polysaccharides, flavonoids, iridoids, Fatty acids, sorghum lactone, catechins, P steroids, sucrose and 201225387 bioassay. Solvents can be solvents with polarity and pH greater than 3, such as: water, sea water, tea, coffee Threat, juice or wine, etc. The pH of the polymer solution is preferably 5.5_8. The polymer is soluble (4) can be tons of vitamins, such as vitamin D. The negative electrode structure 140 can be made into a sheet shape, thereby increasing the use of chlorophyll. The amount of contact is increased to increase the reactive fabric of the battery. Further, it will be understood by those skilled in the art that the present invention can also improve the use of chlorophyll by any known technique, and increase the contact area of the battery to increase the reaction area of the battery. 3 is a schematic structural view of the isolation structure shown in FIG. 3. As shown in FIG. 3, the isolation structure 130 includes a first isolation film 131 and a second isolation film 132, wherein the first isolation film 132 is disposed in the first isolation. The first isolation film 131 and the second isolation film 132 are respectively made of high-fiber material, wherein the high-fiber material can be paper, and the paper includes cellophane, cotton paper, crepe paper and crepe paper, etc. And the pore size of the south fiber material is preferably G(1) qing~丨(10). Preferably, the areas of the first isolation film 131 and the second isolation film 132 are also 5 cm x 5 cm, respectively. Further, the first separator 131 is adsorbed with an aqueous solution of an organic or inorganic salt, wherein the conductivity of the organic or inorganic Wei aqueous solution is 1 Qms/em double ms/cm. The water of the second separator 132 _ material __ sewed off. Organic salts are organic salts that do not contain bells. The organic or inorganic salt is selected from the group consisting of one or more of the following ion compounds: sodium, sodium chloride and sodium hydroxide. 4 is a schematic view showing the structure of the positive electrode structure 12A shown in FIG. 1. As shown in Fig. 201225387, the positive electrode structure 120 includes a conductive polymer film 121 and a nano-conductive high molecular powder layer 122, wherein the nano-conductive polymer powder layer 122 is disposed on the conductive polymer film 121. The material of the conductive polymer is selected from a heterocyclic ring or an aromatic heterocyclic compound. Preferably, the material of the conductive polymer is selected from one or more of the following compounds: polyacetylene, polyarylethylene, polythiophene, polyaniline, poly. A azole, a polypyrrole and a derivative of the above compound. Further, the conductive polymer film has an area of 5 cm x 10 cm ' and has pores of 3 A to 1000 A. The nano-conductive polymer powder layer 122 includes a chlorophyll powder. Further, the nano-conductive polymer powder layer 122 may further include a nano-conductive polymer powder which can be coated with a nano-conductive polymer on the conductive polymer film 121. The powder and the chlorophyll powder are formed, and the weight of the nano conductive polymer powder and the chlorophyll powder is about 0.1 g. The outer casing 150 may be a paper tube for covering the carbon rod 11 〇, the positive electrode structure 120, the isolation structure 130, and the negative electrode structure 14 〇. In the present embodiment, both the negative electrode structure 14〇 and the positive electrode structure 12〇 contain chlorophyll. Therefore, when the battery 1 is operated, the chlorophyll in the negative electrode structure 14〇 and the chlorophyll in the positive electrode structure layer 120 may receive light or Electrons or holes are generated when the solution is encountered, thereby forming a current of a miscellaneous whistling between the positive electrode structure 12 电池 of the battery and the negative electrode structure _. That is, the battery 100 of the present invention uses the negative electrode structure H0 and the chlorophyll in the positive electrode structure m as a source of energy 16 201225387 to supply electric energy. Preferably, the chlorophyll of the negative electrode structure 14〇+ has a different work function from the chlorophyll in the positive axe 120 (woridbnetior^. Although in the present embodiment, the negative electrode structure M0 and the positive electrode structure 12 both contain chlorophyll, however, It will be understood by those skilled in the art that the battery of the second invention can also be provided with a sulphate in the smear structure (10) or chlorophyll only in the positive electrode structure m, and the battery is provided by using __ as a source of energy. Figure 5 is a flow chart of a method for fabricating a battery according to an embodiment of the present invention. As shown in Figure 5, the method for fabricating the battery includes the following steps: Step S1: winding a positive electrode structure with a carbon rod; Step S2: winding the isolation structure; step S3: winding the negative electrode structure; and step S4, winding the positive electrode structure, the isolation structure, and the negative electrode structure of the carbon rod into the paper tube to complete the fabrication of the battery. The disclosed battery can utilize the chlorophyll in its positive and negative structures to perform hydrogen storage for power supply purposes. Preferably, the positive and negative structures are white isi, alizarin' It has a different work function (^ touch (10)). That is, in the oxidation-reflection of the battery, when the chlorophyll (pheqphytm) is formed by the detachment of the leaf green, the sputum can combine two nitrogens. Ion 'Wei's job. In addition, due to the hair _ battery _ natural environmental protection 201225387 substance instead of the Chuanqi pool towel shouting points, even if discarded, it will not pollute the environment, the environmental protection is far better than the traditional battery. "Need, It should be noted that the terms “first”, “second” and the like mentioned in the embodiments of the present invention are only used to select (four) text symbols as needed, and are not limited to this in practice, and the text symbols can be used interchangeably. The subject matter disclosed is considered to be illustrative and not restrictive, and it is intended that the appended claims The scope of the invention is to be determined by the understanding of the scope of the appended claims and the claims BRIEF DESCRIPTION OF THE DRAWINGS [0009] The accompanying drawings are included to provide a further understanding of the invention 1 is a schematic structural view of a battery according to an embodiment of the present invention. FIG. 2 is a schematic structural view of the negative electrode structure shown in FIG. 1. FIG. 3 is a schematic structural view of the isolation structure shown in FIG. 4 is a schematic structural view of the positive electrode structure shown in FIG. 1. Fig. 5 is a flow chart showing a method of fabricating the battery according to an embodiment of the present invention. [Main component symbol έ尤明] 100: Battery 18 201225387 11 ο. Carbon rod 120: positive electrode structure 121: conductive polymer film 122: nano conductive polymer powder layer 130: isolation structure 131: first isolation film 132: second isolation film 133: electrolyte material 140: negative electrode structure 141: Conductive material layer 142: negative electrode material layer 150: outer casing SI, S2, S3, S4: steps
1919