TWM418395U - Battery - Google Patents

Description

M418395 April 14, 2010 Replacement Page 5, New Description: [New Technology Field] This application claims US Patent Application No. 12/344, 2U filed on December 24, 2008 and May 2nd Prior interest in Taiwan Patent Application No. 97118207 filed on the 16th. The entire contents of the above two patents are incorporated herein by reference. The present invention relates to a battery and a method of manufacturing the same, and more particularly to a battery using chlorophyll to generate electric energy and a method of manufacturing the same. [Prior Art] In recent years, portable electronic devices such as mobile phones, portable cameras, notebook computers, digital cameras, PDAs, and CD players have emerged, and they are being small and lightweight, and as such, they are portable. Light power and battery are also concerned. The battery types include dry batteries, hydrogen recording batteries, clock batteries, and fuel cells. A brief description of common batteries is given below. Most of the dry batteries used in slings are zinc clock batteries, also called carbon zinc batteries. The outer casing of a carbon zinc battery is generally made of zinc, which can serve as both a battery container and a battery negative electrode. Carbon batteries are developed from liquid Leclanche batteries. Conventional or general-purpose carbon-zinc batteries use ammonium chloride as an electrolyte; super- or high-energy carbon-zinc batteries are usually carbon-zinc batteries using vaporized zinc as an electrolyte, which is a general-purpose low-cost battery. Dioxide fierce and 3 M418395 April 14, 100 replacement page carbon composition. The electrolyte is a paste solution formed by dissolving chloride and chloride in water. Carbon-zinc batteries are the cheapest primary batteries, so they are the first choice for many manufacturers, because the batteries sold by these manufacturers often need to be distributed. Zinc-carbon batteries can be used in low-power devices such as remote controls, flashlights, toys, or transistor radios. However, when the carbon-zinc battery is used for a period of time, the metal shell is oxidized # becomes a zinc ion' zinc shell will gradually (four). Therefore, zinc chloride solution can often leak out of the battery. The leaked zinc chloride tends to make the surface of the battery sticky. Some old batteries have no leakage protection. The service life of zinc-carbon batteries is relatively short. The shelf life is generally one and a half years. In addition, even if the battery is not used, the gasification in the battery is weakly acidic, and it can react with zinc, and the zinc casing will gradually become thinner. Now 3c production f often mentions that the battery is actually a battery. The generalized rechargeable battery is a graphite negative electrode, a mining secret, a fierce or a helium iron, a positive electrode, and a turn-on battery. The test chamber constitutes a cesium ion battery, which can be used as a negative electrode. In the past few years, the development of the clock battery industry has focused on the 3C industry. It is rarely used in the market with larger market economy and more power batteries (instant demand for large current). This market covers pure electric vehicles, hybrid vehicles, and medium-sized vehicles. Large-scale ws, solar energy, large-scale energy storage battery electric hand tools, electric motorcycles, electric bicycles, aerospace equipment and aircraft batteries. The main reason is that the recording materials used in the past clock batteries replaced the material on April 14, 100 (LiCo〇2 ' is the most common lithium battery now), and the applications are current, high voltage, high torque and It has a special environment that is resistant to punctures, collisions, high temperatures, low temperatures, etc., and more importantly, it has been criticized for failing to meet people's absolute safety requirements. At the same time, 'Wei drill battery can not achieve the purpose of fast charging and completely avoid secondary pollution. Moreover, it is necessary to design a protection circuit to prevent overcharging or over-discharging. Otherwise, it will cause an explosion and other dangers, and even a battery explosion such as S〇ny This has led to the situation of global brand NB operators investing in the recovery of the moment. In addition, the price of cobalt is getting higher and higher, and the world's largest cobalt-producing country, the fruit of the chaos, has caused more and more wars. The powder of Zhongshi Battery has risen from the original price of 4 US dollars per kilogram to 60 to 70 US dollars due to the rising price of cobalt. Phosphoric acid powder is based on good quality and is priced at 3〇~6〇 per kg. NiMH batteries are designed from nickel-cadmium batteries. In 1982, the United States 〇v〇NIC Company requested the patent of hydrogen storage alloy for electrode manufacturing, which made this material pay attention to it. In succession, in 1985, Philips of the Netherlands broke through the problem of capacity decay of hydrogen storage alloy during charge and discharge. Nickel-metal hydride batteries stand out. At present, there are more than 8 nickel-hydrogen battery manufacturers in Japan, and nickel-hydrogen batteries are also produced in Germany, the United States, Hong Kong and Taiwan. The market has responded well. Moreover, the pollution caused by nickel-hydrogen batteries will be more than that of nickel-cadmium batteries containing cadmium. Therefore, nickel-cadmium batteries have been replaced by hydrogen-removed M418395 replacement pages on April 14, 100. Fuelcell is a device that uses fuel to chemically generate electricity. Originally created in 1839 by Grove, England. The most common proton exchange membrane fuel cell fueled by hydrogen and oxygen, because of the cheap fuel, coupled with no chemical danger to the human body, harmless to the environment, and pure water and heat after power generation, was applied to the US military in the i96 era. After the 190S, the US Gemini constellation

- Ten-stroke Gemini; t 5 shot ^ now also has some notes-type electric switch to start researching the female battery. However, since the amount of production (four) f is too small, and New Zealand provides a large amount of electricity, it can only be used for smooth power supply. The fuel cell is a combination of a battery body and a bin. Fuel selectivity is very high, including pure gas, methanol, ethanol, and impurities. Even the most widely used rail oil can be used as fuel for fuel cells.

Whether it is a new type of carbon-zinc battery, an inspective battery and a secondary battery that emphasizes environmental protection, slaves in the process will make money, amount of hiding or other heavy gold knowing and make a dirty new one on the raw materials. Electrochemical devices with large hazard am, ~, and secret instability, improper packaging: operating at low loads, may be (10) rods and therefore require complex and complex protection mechanisms, such as protection circuits, where protection circuits are used to prevent Overcharge, over-emulsion, isolation membrane, etc. 'Super-planting, overheating, • Vent hole for April 14, 100 replacement page to avoid battery (four) pressure is too large; the diaphragm has a higher ship strength, to prevent - Stop inside. P Newway's can also melt when the internal temperature of the battery is too high, preventing the passage of impurities, retarding the battery reaction, and raising the internal resistance (to 2kn). The positive electrode of the clock battery (such as: 1^(:0〇2), negative electrode (LixC) has less and less main raw material lithium ore, which makes its price rise rapidly. The performance and life of the clock battery in the temperature outside the environment or environment Both of them start to reduce rapidly. The golden pot battery or the nickel-metal hydride battery g has a memory effect, which is easy to reduce the available capacity due to poor charging and discharging. [New content] The purpose of this creation is to provide a battery. To solve the above problem, The authoring embodiment provides a battery including a current collector, a JL pole structure, an isolation structure, a drain structure, and a casing, the positive electrode structure, the isolation structure, the negative electrode structure, and the outer casing are sequentially disposed around the current collector, wherein At least one of the positive and negative electrode structures includes chlorophyll. Preferably, the chlorophyll in the positive electrode structure and the chlorophyll in the negative electrode structure have different work functions. According to a preferred embodiment of the present invention, the negative electrode structure comprises a layer of conductive material. And a negative material layer, wherein the negative material layer is formed on the conductive material layer. According to a preferred embodiment of the present creation, the negative The material layer comprises a replacement page of chlorophyll on April 14, 100, and a polymer solution. According to a preferred embodiment of the present invention, the negative electrode structure is in the form of a membrane. According to a preferred embodiment of the present invention, the negative electrode structure The length is 60 mm and the width is 50 mm. According to a preferred embodiment of the present invention, the current collector is a cylinder. According to a preferred embodiment of the present invention, the current collector has a diameter of 4 mm and a length of 47.2 mm. According to a preferred embodiment of the present invention, the isolation structure includes a first isolation film, a second isolation film, and an electrolyte material interposed between the first isolation film and the second isolation film. In a preferred embodiment of the present invention, the first isolation film and the second isolation film are respectively in the form of a film. According to a preferred embodiment of the present invention, the first isolation film and the second isolation film have a length of 55 mm. The width is 50 mm and the thickness is 〇2 mm. According to a preferred embodiment of the present invention, the outer casing is a paper tube having an outer diameter of 14.5 mm and an inner diameter of 12.5 mm and a length of 48.4 mm. The battery can use the chlorophyll in its positive and negative structures to store hydrogen to achieve the purpose of power supply. That is, in the redox reaction of the battery, 'the chlorophyll is formed by the removal of magnesium ions from the chlorophyll. At the same time, the magnesium deficiency part can combine two hydrogen ions, so M418395 can replace hydrogen on April 14th, 100. Because the battery of this creation uses natural environmental protection instead of the pollution component in traditional batteries, Even if it is discarded, it will not cause pollution, and the degree of environmental protection is much better than that of the conventional battery. [Embodiment] The present invention will be described in detail below with reference to the accompanying drawings and embodiments. Fig. 1 shows an embodiment of the present invention. Schematic diagram of the disclosed battery. As shown in FIG. 1, the present embodiment provides a battery 100 including a current collector 110, a positive electrode structure 120, an isolation structure 13A, a negative electrode structure 14A, and a casing 150. The positive electrode structure 120, the isolation structure 13A, the negative electrode structure 14A, and the peripheral device 150 are circumferentially disposed around the current collector HQ. 2 is a schematic view showing the structure of a negative electrode structure disclosed in an embodiment of the present invention. As shown in FIG. 2, the negative electrode structure 14A disclosed in the present embodiment includes a conductive material layer 141 and a negative electrode material layer 142, wherein the negative electrode material layer 142 may be formed on the conductive material layer 141. Among them, the conductive material layer 141 is made of a conductive material. The conductive material may be a metal, a metal compound or a conductive polymer material. The metal may be selected from aluminum and/or gold. The metal compound may be selected from one or more of oxidized, zinc oxide and oxidized towns. The conductor molecular material is selected from heterocyclic or aromatic heterocyclic compounds. According to a preferred embodiment of the present invention, the conductive polymer material is selected from one or more of the following compounds: polyacetylene, polyaromatic ethylene, polythiophene, polyaniline, poly 9 M418395, April 14, 2010 replacement page Ol, polypyrrole and derivatives of the above compounds. The negative electrode material layer 142 includes a chlorophyll and a high polymer solution, and the negative electrode material layer 142 may be formed on the conductive material layer 141 by coating or the like. The chlorophyll may be one or more of chlorophyll a, chlorophyll b, chlorophyll ci, chlorophyll c2, chlorophyll d, and chlorophyll e. The chlorophyll can be in the form of a powder or a liquid. The chlorophyll used has removed chlorophyll oxidase. The high polymer solution has a bonding property, so that the physical and chemical properties of the conductive material layer can be attached and modulated, so that the gate material layer M2 is more adhered to the conductive material layer 141. Further, the conductivity of the polymer solution was 5 〇 25 μms/cm. The high polymer solution may include one or more of rotten, magnesium, ingredient, matry, and zinc elements. The high polymer solution is also used to modulate the work function of the conductive material layer 141 so that the potential difference between the positive and negative electrodes can reach a desired volt, such as 1.5V. The polymer solution can be prepared by compounding metal ions with various acid ion compounds, high (4) and solvent. The high polymer can be a polymer of glucose. The high polymer of glucose may be a plant house powder, for example, one or more of potato powder, water chestnut powder, corn starch, sweet potato powder, lotus root starch, mustard powder and kudzu root powder. The combination of the Golden Lepton and various acid ion ions can be a carbonated metal ion and a compound of each lion can be a tiannuum component. Natural phytochemicals include lignans, oligosaccharides, polysaccharides, flavonoids, ethers, fatty acids, sorghum, catechins, P-sterols, tiger thorns and April 14th, 100 Replace page 7 to verify the class. The solvent may have a polarity, a pH greater than -, a coffee, a fruit/ten or a wine, etc. The pH of the high polymer solution is preferably 5.5_8. The high polymer solution may also include a vitamin such as vitamin D. The negative electrode structure 14G can be formed into a film >{likeness] to increase the amount of chlorophyll used, increase the contact area to increase the reaction area of the battery, and the like. Further, it is understood by those skilled in the art that the present invention can also increase the amount of chlorophyll used by any known technique to increase the contact area to increase the reaction of the battery. Preferably, in the present embodiment, the negative electrode structure (10) has a length of 6 mm and a width of 2. With continued reference to Figure 1, the remainder of the structure of the battery 100 disclosed in this creation will be continued below. The current collector 11 is a cylinder. Preferably, the current collector u has a diameter of 4 mm' and a length of 47.2 mm. The positive electrode structure 120 is composed of a powdery positive electrode material. Preferably, the powdery positive electrode material in the positive electrode structure 120 contains chlorophyll powder. Further, the powdery positive electrode material may further include carbon cloth, carbon powder or nano conductive polymer powder. Carbon cloth or carbon powder includes white carbon or waxite (Chaoite), carbon black, carbon black, glass carbon or Giassy carbon, carbon nanotube, activated carbon. ), diamond, diamond, amorphous carbon, Graphene, Fulerene, Graphite, Carbyne, Diatomic carbon, C3 (Tricarbon), Atomic carbon, and stone M418395 On April 14, 100, the page was replaced by inkized carbon, aged, coke, and lion-free. The material of the conductive polymer is selected from a heterocyclic ring or an aromatic heterocyclic compound. Preferably, the material of the electrically conductive polymer is selected from one or more of the group consisting of a polystyrene block, a polytetramethylene ring, a polybenzazole, a polyphenylamine, a polypair, a polycondensation, and a derivative of the above compound. The secret structure 130 includes a first isolation film 13 and a second isolation film 132 and an electrolyte material 133 interposed between the two spacers. The first isolation film 131 and the second isolation film 132 are respectively made of high-fiber material, wherein the high-fiber material can be paper, the paper includes cellophane, cotton paper, rice paper and crepe paper, and the high fiber material preferably has a pore size. It is α〇1μιη~lcm. Further, in the present embodiment, the first-islet film 131 and the second separator 132 are respectively in the form of a film, and have a length of 55 mm' of a film having a width of 50 mm and a thickness of 0.2 mm. The electrolyte material 133 may be an aqueous solution of an organic salt or an aqueous solution of an organic salt and chlorophyll. The conductivity of the 1 t 'organic salt aqueous solution is 1 () ms / em 5 (8) (10) / (10). Organic salts are organic salts that do not contain bells. The organic salt is selected from one or more of the following ionic compounds: sodium iodide, sodium carbonate, and sodium hydroxide. The outer casing 150 is a paper tube having an outer diameter of 14 5 mm, an inner diameter of 12 5 and a length of 48.4, which is coated with the above-mentioned current collector 11 〇, the positive electrode structure 12 〇, the isolation structure 130, and the negative electrode structure. In this embodiment, the negative electrode structure 140 and the positive electrode structure 12 are both included in the 12 M418395 ^ April 14 replacement page

Chlorophyll, therefore, when the battery is operated, the chlorophyll in the negative electrode structure 14 and the chlorophyll in the positive electrode structure 120 may generate electrons or holes by receiving light or preparing a solution, thereby forming the positive electrode structure W and the negative electrode structure of the battery 100. A potential difference is formed between 14 turns to provide a continuous current. That is, the extracted battery 100 uses the negative electrode structure 140 and the chlorophyll in the positive electrode structure 12 as an energy source to supply electric energy. Preferably, the chlorophyll in the negative electrode structure H0 has a different work function from the chlorophyll in the positive electrode structure 120 (w〇rk. Although in the present embodiment, both the negative electrode structure 14〇 and the positive electrode structure 12〇 contain chlorophyll' but ' Ben Lai can be transferred to a battery that can not be removed from the creation of the battery. It is also possible to set chlorophyll only in the negative electrode structure 14 or to provide chlorophyll only in the positive electrode structure 120 to use the chlorophyll as an energy source to supply electricity to the battery. 3 is a flow chart showing a method for fabricating a battery according to an embodiment of the present invention. As shown in FIG. 3, the method for manufacturing the battery includes the following steps: Step S1: preparing a polymer solution; Step S2: a negative electrode structure; step S3: fabricating an isolation structure; step S4: assembling the negative electrode structure and the isolation structure into the outer casing; and step S5: inserting a current collector into the outer casing and filling the positive electrode material into the above structure to form a positive electrode structure to complete the entire battery 13 M418395 April 14th, 2010 Replacement page®4 is shown as the specific flow of step si shown in Figure 3, the production of step S1 The polymer solution comprises the following steps: Step S11 U slowly adding a polymer powder in a solvent of 40 degrees Celsius; Step S12: _Magnetron_machine speed 500~700KPM to mix the above solution; Step Yang: Using a conductivity meter to detect the conductivity of the solution Whether the degree reaches 50-25 〇 mS/cm; when the above detection result is no, the execution step is returned, and when the above detection result is YES, step S14 is performed; and step S14: completion. In this embodiment The solvent is a solvent having a polarity of less than 3. Preferably, the solvent is selected from one or more of water, sea water, tea, coffee, fruit juice, and wine. FIG. 5 is a step shown in FIG. A specific flow chart of S2. As shown in FIG. $, the negative electrode structure of step S2 includes the following steps: Step S21: filtering the chlorophyll powder with a sieve; Step S22: pouring the polymer solution; Step S23: using a magnet mixer at a rotation speed 500~700RPM for stirring; Step S24: judging whether a uniform fluid is reached; when the above judgment result is no, then returning to step S22, when the above judgment result is YES, step 14 is executed. Step 14: Replace step S25; Step S25: Apply the above fluid to the conductive material layer; Step S26: Place the above structure in an oven at 1 ° C for baking until the water is evaporated to complete the fabrication of the negative electrode structure. 6 is a specific flowchart of the step S3 shown in FIG. 3. As shown in FIG. 6, the manufacturing isolation structure of step S3 includes the following steps: Step S31: cutting the isolation film; Step S32: cutting the isolation film Soaking in the polymer solution; Step S33: taking out the separator and placing it in an oven at 100 degrees Celsius, baking until the water is evaporated to make two separators; Step S34: taking out a separator and uniformly spraying the electrolyte Material; and step S35: covering another isolation film to complete the fabrication of the structure. FIG. 7 is a specific flowchart of step S4 shown in FIG. 3. As shown in FIG. 7, the step of assembling the negative electrode structure and the isolation structure into the outer casing in step S4 includes the following steps: Step S41: attaching the negative electrode structure to the outer casing; step S42: using the first towel to loosen the difficult structure tightly Wherein the first hollow rod has an inner diameter of 4.5 mm, an outer diameter of 6 36 mm, and a length of 47.2 mm; and step S43: the first hollow rod that is rolled up in the isolation structure is rotated in a clockwise direction M418395 is replaced on April 14, 100 Inserting into the outer casing having the negative electrode structure; one-------- step S44: taking out the first hollow rod in a counterclockwise direction to retain the isolation structure in the outer casing having the negative electrode structure; · Inspecting whether the isolation structure is attached to the negative electrode structure in the outer casing; when the above-mentioned inspection result is correct, the job line is turned (10); when the above-mentioned inspection result is yes, then step S47 is performed; step S46: extracting the isolation structure and judging whether the isolation structure is Corruption; when the above judgment result is YES, the ship is step S42; #If the above judgment result is YES, step S46a is performed; step S46a: replacing the isolation structure and returning to step S42; and step 47: completing the assembly. The figure is shown as a specific_picture of step S5 shown in FIG. Inserting the current collector into the outer casing and filling the positive electrode material into the above structure to form the positive electrode structure as shown in FIG. 8 does not include the following step: 'Step S51 slowly filling the positive electrode material in the outer casing having the negative electrode structure and the isolation structure; Step S52 · Insert the current collector into the center of the outer casing; Step S%· Fill the pressure with the first hollow rod and the vise and continue to fill the positive electrode material; Step S54. Check whether the positive electrode material reaches the required weight, Check 16 M418395 on April 14, 100 to replace the page view. If the answer is no, the process returns to step S53. When the result of the above-mentioned ▲ is $-, step S55 is performed; and the step S55 is performed. The positive structure is modified by the second hollow rod, wherein the inner diameter of the second hollow rod is 4.5. Mm, the outer material is 994mm, and the length is 472 coffee to complete the fabrication of the positive electrode structure. This work reveals that (4) the pool can be _ its positive 'negative chlorophyll that can be used to store hydrogen to achieve the purpose of power supply. Preferably, the positive and negative structures all comprise chlorophyll, but have different work functions. That is, in the oxidation reduction reaction of the battery, when the leaf green (4) is separated from the chlorophyll jpheophytm, the part of the vacant town can combine two chloride ions, so that hydrogen can be stored. In addition, because the battery of this creation uses natural environmentally friendly substances to replace the polluting components in the traditional battery, even if it is discarded, it will not pollute the environment, and the degree of environmental protection is far better than that of the traditional battery. I need to point out that the terms “first,”, “second” and the like mentioned in the present embodiment are only used to select (four) text symbols according to needs, and the practice towel is not limited thereto, and the text symbol can be Used interchangeably. The above-disclosed subject matter is to be considered as illustrative and not restrictive. The maximum extent of the transfer is permitted by the most extensive license of the scope of the appended claims and its equivalents. 17 M418395 Replacement page on April 14, 100 and is not subject to the detailed description of the foregoing [Simplified illustration] The accompanying drawings are included to provide an exemplary embodiment of the present invention which is incorporated herein by reference. In the pictures...

FIG. 1 is a schematic structural view of a battery disclosed in an embodiment of the present invention. A schematic structural view of a negative electrode structure disclosed in an embodiment. Figure π Flow of a method for fabricating a battery disclosed in an embodiment

The understanding is to determine the limitations or limitations of the description of this creation. The figure is shown as a specific flow chart of the steps shown in FIG. Figure 5 shows the listening flow diagram of the ® 3 _ turn S2. 6 is a specific flow chart of the step S3 shown in FIG. 3. FIG. 7 is a specific flowchart of the step S4 shown in FIG. 3, and FIG. 8 is a green flow chart showing the step S shown in FIG. [Description of main component symbols] 100: Battery 110: Current collector UO: Positive electrode structure 130: Isolation structure 13ι: First isolation film 132: Second isolation film 18 M418395 Replacement page on April 14, 100 Page 137: Electrolyte material 140: Negative electrode Structure 141: conductive material layer 142: negative electrode material layer 150: outer casing S, S2, S3, S4, S5, S11, S12, S13, S14, S2, S22, S23, S24, S25, S26, S31, S32, S33, S34, S35, S4, S42,

S43, S44, S45, S46, S46a, S47, S51, S52, S53, S54, S55: Steps

19

Claims (1)

M418395 April 2014 U-day replacement page VI, the scope of application patent: ~~~ ~ 1. - The battery is characterized in that the battery includes a current collector, a positive electrode structure, an isolation structure, a negative electrode structure and a casing The structure, the isolation structure, the negative electrode structure, and the outer casing are sequentially disposed around the current collector, wherein at least one of the positive and negative electrode structures includes chlorophyll. 2. The battery according to claim 1, wherein the negative electrode structure comprises a conductive material layer and a negative electrode material layer, wherein the negative electrode material layer is formed on the conductive material layer. 3. The battery according to claim 2, wherein the negative electrode material layer comprises a chlorophyll and a high polymer solution. 4. The battery according to claim 1, wherein the negative electrode structure is in the form of a diaphragm. The battery according to claim 1, wherein the negative electrode structure has a length of 60 mm and a width of 50 mm. 6. The battery according to claim 1, wherein the current collector is a cylinder. 7. The battery according to claim 6, wherein the current collector has a diameter of 4 mm and a length of 47.2 mm. 8. The battery according to claim 1, wherein the isolation structure comprises a first spacer, a second spacer, and a second replacement page of the first 20 M418395, April 14, 100. An electrolyte material between the membrane and the second separator. The battery according to claim 8, wherein the first separator and the second separator are respectively in the form of a diaphragm. 10. The battery according to claim 9, wherein the first and second separators have a length of 55 mm, a width of 50 mm', and a thickness of 0.2 mm. 11. The battery according to claim 1, wherein the peripheral is a paper tube having an outer diameter of 14.5 mm and an inner diameter of 12.5 mm and a length of 48.4 mm. twenty one