TW201224185A - Sputtering apparatus - Google Patents

Sputtering apparatus Download PDF

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Publication number
TW201224185A
TW201224185A TW100132540A TW100132540A TW201224185A TW 201224185 A TW201224185 A TW 201224185A TW 100132540 A TW100132540 A TW 100132540A TW 100132540 A TW100132540 A TW 100132540A TW 201224185 A TW201224185 A TW 201224185A
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Taiwan
Prior art keywords
target
substrate
incident control
opening
film
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TW100132540A
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Chinese (zh)
Inventor
Takahiro Nanba
Koichi Nakajima
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Ulvac Inc
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Publication of TW201224185A publication Critical patent/TW201224185A/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3464Sputtering using more than one target
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/54Controlling or regulating the coating process
    • C23C14/548Controlling the composition
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3402Gas-filled discharge tubes operating with cathodic sputtering using supplementary magnetic fields
    • H01J37/3405Magnetron sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3411Constructional aspects of the reactor
    • H01J37/3414Targets
    • H01J37/3417Arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3411Constructional aspects of the reactor
    • H01J37/3447Collimators, shutters, apertures

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

A sputtering apparatus (1) for forming a thin film on a substrate (S) disposed in a film-forming space (2S) is provided with: a plurality of targets (13A to 13C); and shutter mechanisms (M) which are disposed between the targets (13A to 13C) and the film-forming space (2S) and have openings (22) that expose a selected target to the film-forming space (2S). The shutter mechanisms (M) are provided with injection control units (30A to 30C) that control the number of sputtering particles released from the selected target toward a substrate outer peripheral section (S2). The plurality of injection control units have a plurality of shielding levels with respect to the sputtering particles. An injection control unit that is suitable for the selected target is used from among the plurality of injection control units in accordance with the film thickness distribution when the selected target that is exposed to the film-forming space (2S) is individually sputtered.

Description

201224185 六、發明說明: 【發明所屬之技術領域】 本發明疋關於—種濺錢裝置 【先前技術】 的2體f置、磁裝置等的製造程序中被廣泛使用 ."^ ^使離子衝撞於濺鍍靶(sputtering target) 主不f鍍面二藉由使從該靶釋出的濺鍍粒子堆積在基板 、面“ t成薄膜。做為此濺錄裝置之—,為了形成從合 金:化合物等組成的薄膜’具有複數個陰極(cathode) 的夕元式濺鍍裝置被開發。靶分別被配置在多元式濺鍍 襄,的複數個陰極。* 般來說這錄與基板的相; 距離為固定,所以各靶的被濺鍍面被設有成相對於成膜 對象的基板表面傾斜。 、 在使靶的被濺鍍面相對於基板表面傾斜的狀況,在 基板表面,產生與被濺鍍面的相對距離為短的區域,以 及與被濺鍍面的相對距離為長的區域。在通常的狀況, 在與被藏鍵面的相對距離為相對短的區域,賤鐘粒子入 射至基板表面的粒子數會相對變多。在與被濺鍍的相對 距離為長的區域’由於散亂至基板的周圍的濺鍍粒子變 多’入射至基板表面的粒子數會相對變少。因此,—般 來說,被多元式濺鍍裝置形成的薄膜的膜厚會散此^ 均。具體來說,在薄膜的同一面内,會有在與被濺鍍面 的相對距離為短的區域,膜厚變大,在與被濺鍍面的相 201224185 對距離為長的區域,膜厚變小的傾向。 對於膜厚分佈不均的問題的對策,提案了將從旋轉 的基板的旋轉軸線到基板的外周緣部的距離、從旋轉軸 線到陰極(乾)表面的中心點的距離、與從基板表面到 陰極表面的中心點的距離的比,做為特定範圍者(參照 專利文獻1 )。 ’ 【先前技術文獻】 【專利文獻】 【專利文獻1】國際公開第2006/077837號公報 但是,即使是在同樣成膜條件進行濺鍍的狀況,在 基板上所形成的薄膜的膜厚分佈會因為靶材質而不 第十五圖表示分別使用以不同材質組成的三個乾進 :濺鍍時賴厚分佈。縱軸表示膜厚,橫軸表示與基板 離。例如,在材料1以及材料2,與基板中心 的f離在-定抱_,薄膜的厚度大致 ==的位置’膜厚會變小,可看到與以;問題; ;心變p L 在材料3 ’可看到膜厚在基板 大,作若。中Ί遺著從基板中心分離,膜厚會變 右與基板中心的距離到達固定值,則膜厚會變小。 的〆百i此*乾的材質不同,則在同—面内的膜厚分佈 ::由大幅不同。在用以往的贿= _成㈣膜⑽厚分佈會對餘材 所以在同時使用不同把來形成薄膜的狀況,薄 电方向會變得不均句’同-層内的薄膜 、成在㈣向也有不同。例如,假設基板騎在第十五 201224185 圖的材料3的曲線的頂峰位 鍍裝置將複數個材料卜2、3的狀況。用以在的濺 厚分佈,所以在i:L寻=斗由綱 周緣形成越厚的薄膜。又,二:心附近變薄’越” 到在中心附近變低,越靠緣,料3的比率,付 條件的變更,不财可即使猜供給電力等 均勾化也有限制。W到想要的膜質,在膜厚的 【發明内容】 鍵沪置,即上述問題點’其目的在於提供一種滅 =升=二同材質組成的複數個爾況,也 薄種膜r内均勻性。 靶,在成膜空門所;>5 φ八種'賤鍍襞置,具備複數個 備閘門機構,心二薄臈。該濺鍍裝置具 間之間,前述f句機構開::複= 前述成:空 成膜空間被暴露的前述献應在則述 射控制部運用在該選擇=种將適合該選擇乾的入 根據此結構,複數個入射控制部中,對應在成膜空 201224185 單體的膜厚分佈’將入射控制部的任 傾*所以即使在使用乾單體的膜厚分佈 傾向彼此相異的複數錄的狀況,可 粒子數的分佈錄每—面内均句化。因此,提$ = 所形成的薄膜的膜厚面㈣勻性,並可以 ^ 薄膜組成的均勻性。 m 在較佳例中,前述複數個入射控制部, ”個靶的外側所配置的壁部高度,具有不二= 根據此結構’藉由不同高度的壁部,可以使 入射控制部的遮蔽度不同。因此, 驟複雜化,相力求錢^置或成膜步 部,=圭::控複數個入射控制 周所設有_: 外 忒開口可暴露前述靶的被濺鍍面。 、且成 入射==包==構設有入射控制部,該 穴2由開口部組成的入射 = 控制:相面對,可力求膜厚以及組成的均句化。的入射 右μ·二車乂仏例中’別述閘門機構,具備:第-閘門,豆 數量少的開口部,對於前述』數個 轉地被δ又有,前述選擇乾是經由前述第1門的 引迷開σ部’在前述賴m選擇性地被暴露的乾;以 201224185 及第二閘門,被設於比該第一閘門靠近前述基板的位 置,具有前述複數個入射控制部,使適合藉由前述第一 閘門被選擇性地露出的前述選擇靶的入射控制部,面對 該選擇乾。 根據此結構,藉由第一閘門選擇性地暴露靶,第二 閘門使適合該暴露靶的入射控制部面對於該把。因此, 即使在使乾選擇性地暴露,由於可以適用適合該乾的入 射控制部,所以不會妨礙成膜步驟的自由度,可力求膜 厚以及組成的均勻化。 ' 在較佳例中’前述複數個入射控制部中,具有相對 大的遮蔽度的入射控制部,具有壁部,該壁部妨礙從前 述選擇靶的被濺鍍面釋放並前往前述基板外周部的濺 鍍粒子。選擇靶是一材質,使得在該靶單體濺鍍時形成 的薄膜在基板外周部的膜厚比基板中央部大,在此狀 況,對於該選擇靶,適用具有前述相對大的遮蔽度的前 述入射控制部。 —、根據此結構,選擇靶是一材質,使得在該靶單體進 行濺鍍時形成的薄膜在基板外周部的膜厚比基板中央 部大,在此狀況,藉由對於該選擇靶,適用具有相對大 的遮蔽度的人射控制部’以遮蔽從該乾的被贿面釋放 並向著基板外周面去的濺鍍粒子。因此,不會使裝 成膜步驟複雜化’可以使遮蔽度不同,可力求薄膜的二 厚以及組成均勻化。 、 在一例中,前述閘門機構,包含可在前述成膜办 内旋轉的圓蓋(dome)狀部材,前述複數個人射控制 201224185 具備:第一入射控制部,包含:第一開口部,被形成於 前述圓蓋狀部材;以及第一遮蔽部,包圍前述第一開口 部,該第一遮蔽部從前述圓蓋狀部材向著前述基板僅以 第一高度突出;以及第二入射控制部,包含第二開口 部,該第二開口部,未被向著前述基板突出的遮蔽部包 圍,被形成在前述圓蓋狀部材,前述濺鍍裝置,更具備 使前述圓蓋狀部材旋轉的驅動馬達,前述驅動馬達,使 前述圓蓋狀部材旋轉,使得在前述複數個入射控制部的 前述開口部中,經由對應前述選擇靶的材質所選擇的開 口部,暴露該選擇靶。 根據此結構,藉由驅動馬達的動作,可以切換遮蔽 度。 在一例中,前述複數個入射控制部,更包含第三入 射控制部,該第三入射控制部包含:第三開口部,被形 成在前述圓蓋狀部材;以及第二遮蔽部,包圍前述第三 開口部,從前述圓蓋狀部材向著前述基板僅以不同於前 述第一高度的第二高度突出。 根據此結構,可以對應處理選擇靶的種類增加。 在一例中,前述第一遮蔽部,是包圍前述第一開口 部的環狀壁部。 根據此結構,以簡單的結構,可以賦予複數個遮蔽 度在閘門機構(例如第二閘門)。 【實施方式】 [第一實施形態] 201224185 以下,根據第-圖〜第十一圖來說明本發明的第一 實施形態的濺鍍裝置。 賤鑛裝置1是磁控_ (magnet麵Sputtering)裝 置。具有内部空間,即成m空間2S的腔室2,包含例 如有底筒狀的腔室本體2a以及將腔室本體厶内密閉至 真空狀態的上壁部2b。腔室本體2a,經由被形成在底 壁部2c等的排氣口 2d,被連接至由真空泵所組成的排 氣機構3。 在腔室本體2a’形成有用來導人濺鍍氣體的氣體導 入口 2e,在該氣體導入口 2e,連接有氣體供給機構9, 該氣體供給機構9是由質量流動控制器(massfl〇w controller)等組成。氣體供給機構9經由氣體導入口 2e,控制氬(Ar)、氮(Kr)、氙(Xe)等氣體流量,並 導入至腔室本體2a。又,做為濺鍍氣體,也可以是包含 氮或一氧化碳等反應氣體的結構。 在腔室2,經由圖未顯示的搬送口,搬入例如矽基 板、玻璃基板等基板S。基板S被载置於設在腔室2内 的旋轉式基板夾4的基板位置。 基板失4被形成為圓盤狀,在其底面經由驅動轴5 以及傳達機構7,連接驅動馬達6。驅動馬達6的驅動 軸5,可旋轉地被支持在腔室2的底壁部2c。當驅動馬 達ό旋轉,則經由傳達機構7,旋轉被傳達至驅動軸5, 基板夾4與驅動馬達6的旋轉方向同方向旋轉。此驅動 馬達6在濺鍍執行時,使基板夾4旋轉,堆積在被載置 在基板夾4的基板S的滅鍍粒子的偏離會被抑制。 201224185 在腔室2的内部,設有複數個防附著板8,防附著 板8覆蓋基板夹4的外周面或腔室本體2a的内壁。防 附著板8抑制濺嫂粒子附著於基板夾4的外周面 — 本體2a的内壁。 ° s二至 在腔室2的上壁部2b,可傾斜移動地固定有複數 個(在圖示例中為3個)陰極(cath〇de) 1〇。第二圖表 示被固定在上壁部2b的陰極1〇。如第二圖所示,在^ 實施形態,第一陰極10A、第二陰極10B、第三陰極1〇匸 係沿著周方向相隔角度〇 ( = 12〇。)而被固定二201224185 VI. Description of the Invention: [Technical Field of the Invention] The present invention is widely used in a manufacturing process of a 2-body f-set, a magnetic device, etc., in a prior art technique. In the sputtering target, the main surface of the plating surface is formed by depositing the sputtered particles released from the target on the substrate and the surface to form a film. A film composed of a compound or the like is developed with a plurality of cathode sputtering devices. The targets are respectively disposed in a plurality of cathodes of a plurality of sputtering sputterings. * Generally speaking, this phase is recorded with the substrate; Since the distance is fixed, the sputtered surface of each target is provided so as to be inclined with respect to the surface of the substrate on which the film formation object is formed. When the sputtered surface of the target is inclined with respect to the surface of the substrate, the surface of the substrate is generated and splashed. The relative distance between the plating surface is short, and the relative distance from the sputtered surface is long. In the normal situation, the cesium clock particle is incident on the substrate in a relatively short distance from the hidden key surface. Surface The number of particles will increase relatively. In the region where the relative distance from the sputtering is long, the number of particles that are scattered to the periphery of the substrate increases due to the amount of sputtered particles scattered around the substrate. Therefore, the number of particles is relatively small. In other words, the film thickness of the film formed by the multi-component sputtering device is dispersed. Specifically, in the same surface of the film, there is a region where the relative distance from the sputtered surface is short, and the film thickness is small. In the region where the distance from the sputtered surface is longer than 201224185, the film thickness tends to be small. The countermeasure against the problem of uneven film thickness distribution is proposed from the rotation axis of the rotating substrate to the substrate. The ratio of the distance from the outer peripheral edge portion, the distance from the rotation axis to the center point of the cathode (dry) surface, and the distance from the substrate surface to the center point of the cathode surface is regarded as a specific range (see Patent Document 1). [Patent Document 1] [Patent Document 1] International Publication No. 2006/077837 However, even in the case where sputtering is performed under the same film formation conditions, the film thickness distribution of the film formed on the substrate may be The target material, instead of the fifteenth figure, shows three dry feeds made of different materials: the thickness distribution on the sputtering, the vertical axis represents the film thickness, and the horizontal axis represents the separation from the substrate. For example, in material 1 and material 2, With the thickness of the substrate at the center of the substrate, the thickness of the film is approximately == the position of the film becomes smaller, and the thickness of the film becomes smaller; the problem can be seen; the problem; the cardiac change p L can be seen in the material 3 ' If the substrate is large, it will be separated from the center of the substrate, and the film thickness will change to a fixed value when the distance between the right and the center of the substrate reaches a fixed value. The thickness of the film is small. - The film thickness distribution in the surface: It is greatly different. In the case of using the previous bribe = _ (4) film (10) thick distribution, the thin material will become uneven when the film is formed by using different materials at the same time. The film in the same layer is also different in the (four) direction. For example, suppose the substrate rides on the top of the curve of material 3 of the fifteenth 201224185 figure. The plating device will count the conditions of the materials 2 and 3. The thickness of the splash is used, so the thicker the film is formed at i:L. In addition, there is a limit in the vicinity of the heart, and it is lower in the vicinity of the heart. It is lower in the vicinity of the center, and the ratio of the material is 3, and the ratio of the material is changed, and the condition is changed. The film quality, in the film thickness [invention content] key Shanghai, that is, the above problem point 'the purpose is to provide a variety of conditions of the composition of the extinction = liter = two materials, but also the uniformity of the thin film r. In the film-forming empty door; >5 φ eight kinds of '贱 贱 襞 , , , , , , , , , , , , , 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 具备 臈 臈 臈 臈 臈 臈 臈 臈: the aforementioned contribution of the empty film formation space is applied to the description control unit, and the selection is determined to be suitable for the selection of the dry input according to the structure, and the plurality of incident control portions correspond to the film formation void 201224185 In the case where the thickness distribution of the incident control unit is set to be equal to each other, even if the film thickness distribution of the dry monomer is different from each other, the distribution of the number of particles can be recorded in each surface. $ = film thickness of the formed film (four) uniformity, and can be composed of film In a preferred embodiment, the plurality of incident control units, the height of the wall portion disposed outside the target, has a difference = according to the structure, the incident control portion can be made by the wall portion having a different height The degree of shielding is different. Therefore, the complexity is complicated, and the force is required to set or form a film step. = Gui:: Control a plurality of incident control cycles. _: The outer opening can expose the sputtered surface of the target. And the incident == package == is configured with the incident control portion, and the hole 2 is composed of the opening portion of the incident = control: facing each other, the film thickness and the composition of the composition can be achieved. In the case of the incident right μ·two car ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' The imaginary opening portion σ of the door is selectively exposed to the front surface; the 201224185 and the second gate are disposed at a position closer to the substrate than the first gate, and have the plurality of incident control portions It is suitable for the selection control unit of the selection target selectively exposed by the first shutter to face the selection. According to this configuration, the target is selectively exposed by the first gate, and the second gate makes the incident control portion suitable for the exposed target face to the handle. Therefore, even if the drying is selectively exposed, since the irradiation control portion suitable for the drying can be applied, the degree of freedom of the film forming step is not hindered, and the film thickness and composition can be made uniform. In a preferred embodiment, the incident control unit having a relatively large shielding degree has a wall portion that prevents the release from the sputtered surface of the selective target and proceeds to the outer peripheral portion of the substrate. Sputtered particles. The selection target is a material such that the film formed at the time of sputtering of the target monomer has a larger film thickness at the outer peripheral portion of the substrate than at the central portion of the substrate. In this case, the aforementioned relatively large shielding degree is applied to the selected target. Incidence control unit. According to this configuration, the selection target is a material such that the film formed when the target monomer is sputtered has a larger film thickness at the outer peripheral portion of the substrate than at the central portion of the substrate, and in this case, by the selection target The human radiation control unit 'having a relatively large degree of shielding' shields the sputtered particles released from the dry bribed surface and toward the outer peripheral surface of the substrate. Therefore, the film-forming step is not complicated, and the degree of shielding can be made different, and the thickness and composition of the film can be made uniform. In one example, the shutter mechanism includes a dome-shaped member rotatable in the film forming apparatus, and the plurality of individual shot control 201224185 includes a first incident control unit including a first opening and is formed The first cover portion surrounds the first opening portion, the first shielding portion protrudes from the dome-shaped member toward the substrate only at a first height; and the second incident control portion includes a first cover portion a second opening portion that is not surrounded by a shielding portion that protrudes toward the substrate, is formed in the dome-shaped member, and the sputtering device further includes a driving motor that rotates the dome-shaped member, and the driving The motor rotates the dome-shaped member so that the selection target is exposed through the opening selected in accordance with the material of the selection target in the opening of the plurality of incident control portions. According to this configuration, the degree of shielding can be switched by the action of the drive motor. In one example, the plurality of incident control units further include a third incident control unit including: a third opening formed in the dome-shaped member; and a second shielding portion surrounding the first The three opening portions protrude from the dome-shaped member toward the substrate at a second height different from the first height. According to this configuration, the type of the selection target can be increased correspondingly. In one example, the first shielding portion is an annular wall portion surrounding the first opening portion. According to this configuration, a plurality of shielding degrees can be imparted to the shutter mechanism (e.g., the second gate) with a simple configuration. [Embodiment] [First Embodiment] 201224185 Hereinafter, a sputtering apparatus according to a first embodiment of the present invention will be described based on the first to eleventh drawings. The antimony ore device 1 is a magnetron _ (magnet surface sputtering) device. The chamber 2 having an internal space, i.e., an m-space 2S, includes, for example, a chamber body 2a having a bottomed cylindrical shape and an upper wall portion 2b for sealing the inside of the chamber body to a vacuum state. The chamber body 2a is connected to the exhaust mechanism 3 composed of a vacuum pump via an exhaust port 2d formed in the bottom wall portion 2c or the like. A gas introduction port 2e for guiding a sputtering gas is formed in the chamber body 2a', and a gas supply mechanism 9 is connected to the gas introduction port 2e, and the gas supply mechanism 9 is a mass flow controller (massfl〇w controller) ) and other components. The gas supply mechanism 9 controls the flow rate of gas such as argon (Ar), nitrogen (Kr), or xenon (Xe) via the gas introduction port 2e, and introduces it into the chamber body 2a. Further, as the sputtering gas, a reaction gas containing a reaction gas such as nitrogen or carbon monoxide may be used. In the chamber 2, a substrate S such as a ruthenium substrate or a glass substrate is carried through a transfer port (not shown). The substrate S is placed on the substrate position of the rotary substrate holder 4 provided in the chamber 2. The substrate loss 4 is formed in a disk shape, and the drive motor 6 is connected to the bottom surface via the drive shaft 5 and the transmission mechanism 7. The drive shaft 5 of the drive motor 6 is rotatably supported by the bottom wall portion 2c of the chamber 2. When the drive motor is rotated, the rotation is transmitted to the drive shaft 5 via the transmission mechanism 7, and the substrate holder 4 is rotated in the same direction as the rotation direction of the drive motor 6. When the sputtering motor is executed, the substrate motor 4 rotates, and the deviation of the chipping particles deposited on the substrate S placed on the substrate holder 4 is suppressed. 201224185 Inside the chamber 2, a plurality of anti-adhesion plates 8 are provided, and the anti-adhesion plate 8 covers the outer peripheral surface of the substrate holder 4 or the inner wall of the chamber body 2a. The adhesion preventing plate 8 prevents the splash particles from adhering to the outer peripheral surface of the substrate holder 4 - the inner wall of the body 2a. ° s 2 to In the upper wall portion 2b of the chamber 2, a plurality of (three in the illustrated example) cathodes (cath〇de) 1〇 are fixed in a tiltable manner. The second graph shows the cathode 1 被 fixed to the upper wall portion 2b. As shown in the second figure, in the embodiment, the first cathode 10A, the second cathode 10B, and the third cathode 1 are fixed in the circumferential direction by an angle 〇 (= 12 〇.).

如第一圖所示,各陰極10具有扁平形狀的背板 (backing p丨ate) n。在此背板„的底面,即基板側的 面,設有地屏障(ground shield) 12。地屏障12具有. 圓盤狀靶收容部12a,用來收容靶13 ;以及環狀、凸部 12b’被形成為包圍收容部12a。此環狀凸部i2b的言^ 為例如數mm程度。 η X 各背板11,被連接於對應的外部電源G,將來自該 外部電源G的直流或交流電力’供給至被收容在㈣g 部12a的靶13。 a在各背板11的底面,各地屏障12的靶收容部12a, ,疋有靶13。靶13的材質沒有特別限定,由金屬金 舄化,物、絕緣物等構成。三個陰極1〇的靶13,彼此 是相異的材質。在本實施形態,在第一陰極1〇Α固 疋$由錄(Ni)組成的第一靶13A,在第二陰極1〇B, 固,有由鈷(Co)組成的第二靶13B,在第三陰極1〇(:, 口疋有由氧化鎮(Mg〇)組成的第三乾13C。 201224185 被固定在各陰極10的把13的基板側的表面,即被 濺鑛面13a ’係街於基板s的表面S1傾斜。例如,從 靶13的中心向著基板S的邊緣中的最遠位置的直線, 與基板表面所成角度在〇。以上30。以下。在本實施形 態,被濺鍍面l3a的法線稱為乾軸線X1 ’此靶軸線XI 與通過基板s的表面si的法線(基板中心)的中心軸 線X2所成角度為靶13的傾斜角。 如第二圖所示,第--第三靶13A〜13C分別形成 為圓盤狀。第一〜第三靶13A〜13C的中心點PC1〜PC3 位於同一圓周上。第*--第三靶13A〜13C在周方向相 隔角度α = 12〇。)被設置。又,在本實施形態,第一 乾13Α被配置在腔室2的正面,第二乾被配置在 從腔室2的正面來看的左侧,在右侧配置有第三乾13C。 在各陰極10,以背板11為界’在乾13對面的位置 設有磁氣裝置14。各磁裝置14具備磁迴路15。來自外 部電源G的電力在被供給至背板11的狀態下,當磁迴 路15被驅動,則在靶13的被賤鑛面13a產生磁控管 (magnetron)磁場。然後’猎由被產生的磁控管磁場貢 獻於被濺鍍面13a的附近的電梁產生’電漿被高密度 化,被滅鍍面13a被藏锻氣體的離子賤鍍。 在腔室2的上壁部2t>,設有閘門機構Μ。此閘門 機構Μ具有第一閘門20以及第二閘門30。如第三圖所 示,閘門20、30沿著中心軸Χ4被配置在同軸。從腔室 2的上方來看時,閘門20、30為重疊。第二閘門被 設有在第一閘門20的下方(内侧)° c 11 201224185 如第三圖所示,第一閘門20,具有大致半球形狀 或圓蓋狀的閘門本體21,閘門本體21在其外周緣具有 簷部21a。在閘門本體21,兩個開口部22被貫穿形成。 各開口部22是用來使靶13相對於成膜空間2S露出的 孔,配合靶13的形狀形成為圓形狀,其内徑被形成為 比乾13的直徑略大。 第四圖表示第一閘門20的下面20a。開口部22被 形成在閘門本體21的頂點PC4與簷部21a之間。開口 部22在閘門本體21的周方向僅以角度α隔開而被設 有。換言之,一方的開口 22的中心點PC5與第一閘門 20的頂點PC4相連的直線,與另一方的開口部22的中 心點PC6與上述頂點PC4相連的直線所成角度α是120 。。又,一方的開口部22的中心點PC5位於腔室2的正 面,從腔室2的正面來看,在另一方的開口部22位於 其右側的狀態,稱為第一閘門20的基準位置。在基準 位置所配置的第一閘門20,如上述,使在腔室2的正 面所配置的第一靶13Α與從正面來看在右側所配置的 第三靶13C,在成膜空間2S露出。 此第一閘門20可在腔室2内部旋轉。如第一圖所 示,第一閘門20經由傳達機構25被連接於驅動馬達 23的驅動軸24。此驅動軸24被支持成可在腔室2的上 壁部2b轉動。驅動軸24與第一閘門20之間所設有的 傳達機構25,將驅動軸24的旋轉傳達至第一閘門20。 雖然傳達機構25的結構並沒有特別限定,但例如構成 為具有馬達等驅動源、齒輪(gear )、棘輪(ratchet)等, 12 201224185 來切換將驅動軸24的旋轉傳達至第一閘門2〇的傳達模 式,與將驅動軸24的旋轉不傳達至第一閘門2〇的非傳 達模式。 當將驅動馬達23驅動,使第一閘門20轉動,則如 第四圖所示’各開口部22在具有與開口部22直徑相同 的寬度的環狀軌跡R1上移動。如第二圖所示,在此軌 跡R1内包含各乾13。因此,當使第一閘門20從基準 位置轉動120°,則第一閘門20的開口部22分別與三 個乾13中的兩個13的位置重疊,面對這些開口部 22的兩個靶13選擇性地暴露在成膜空間2S。此時,三 個靶13中的一個靶在第一閘門20被遮蔽並未暴露在成 膜空間2S。 接下來’說明關於第二閘門30。如第三圖所示, 第二閘門30與第一閘門20 —樣,具有大致半球形狀或 圓蓋狀的閘門本體31,閘門本體31在下端具有筹部 31 a。閘門本體31被形成為與第一閘門2〇的閘門本體 21幾乎同樣大小。在此閘門本體31設有第__第三入As shown in the first figure, each cathode 10 has a flat-shaped backing plate n. A ground shield 12 is provided on the bottom surface of the backing plate, that is, the surface on the substrate side. The ground barrier 12 has a disk-shaped target receiving portion 12a for receiving the target 13 and an annular, convex portion 12b. The annular convex portion i2b is formed to surround the accommodating portion 12a. For example, the thickness of the annular convex portion i2b is about several mm. η X Each of the back plates 11 is connected to the corresponding external power source G, and DC or AC from the external power source G is used. The electric power is supplied to the target 13 accommodated in the (four) g portion 12a. a The target accommodating portion 12a of each of the barriers 12 is provided on the bottom surface of each of the back plates 11. The target 13 is not particularly limited, and is made of metal iridium. The composition of the three cathodes 1 is different from each other. In the present embodiment, the first cathode 1 is fixed to the first target composed of the recording (Ni). 13A, at the second cathode 1〇B, solid, having a second target 13B composed of cobalt (Co), and at the third cathode 1〇 (:, the third dry 13C composed of oxidized town (Mg〇) 201224185 is fixed on the surface of the substrate 13 of each cathode 10, that is, the surface of the substrate s is inclined by the splash surface 13a'. The straight line from the center of the target 13 toward the farthest position in the edge of the substrate S is at an angle of 〇 to 30. or less. In the present embodiment, the normal to the sputtered surface l3a is called the dry axis. X1 'The angle formed by the target axis XI and the central axis X2 passing through the normal line (substrate center) of the surface si of the substrate s is the inclination angle of the target 13. As shown in the second figure, the first-third target 13A to 13C The center points PC1 to PC3 of the first to third targets 13A to 13C are located on the same circumference. The *--third targets 13A to 13C are arranged at an angle α = 12 周 in the circumferential direction. Further, in the present embodiment, the first stem 13 is disposed on the front surface of the chamber 2, the second stem is disposed on the left side as viewed from the front of the chamber 2, and the third stem 13C is disposed on the right side. Each of the cathodes 10 is provided with a magnetic gas device 14 at a position opposite to the dry plate 13 by the back plate 11. Each of the magnetic devices 14 is provided with a magnetic circuit 15. The electric power from the external power source G is supplied to the backing plate 11, When the magnetic circuit 15 is driven, a magnetron magnetic field is generated at the beryllium surface 13a of the target 13. Then 'hunting The generated magnetron magnetic field contributes to the electric beam in the vicinity of the sputter surface 13a, and the plasma is densified, and the deplating surface 13a is plated with the ion enthalpy of the forged gas. In the upper wall portion of the chamber 2 2t>, there is a gate mechanism Μ. The gate mechanism Μ has a first gate 20 and a second gate 30. As shown in the third figure, the gates 20, 30 are arranged coaxially along the central axis 。 4. From the chamber 2 When viewed from above, the gates 20, 30 are overlapped. The second gate is provided below (inside) the first gate 20 ° c 11 201224185 As shown in the third figure, the first gate 20 has a substantially hemispherical shape or circle In the lid-shaped shutter body 21, the shutter body 21 has a crotch portion 21a on its outer periphery. In the shutter body 21, the two opening portions 22 are formed to penetrate. Each of the openings 22 is a hole for exposing the target 13 to the film formation space 2S, and the shape of the target 13 is formed into a circular shape, and the inner diameter thereof is formed to be slightly larger than the diameter of the stem 13. The fourth figure shows the lower surface 20a of the first shutter 20. The opening portion 22 is formed between the apex PC4 of the shutter body 21 and the weir portion 21a. The opening portion 22 is provided only at an angle α in the circumferential direction of the shutter body 21. In other words, the angle α between the straight line connecting the center point PC5 of one opening 22 and the vertex PC4 of the first shutter 20 to the straight line connecting the center point PC6 of the other opening portion 22 to the vertex PC4 is 120. . Further, the center point PC5 of one opening portion 22 is located on the front surface of the chamber 2, and the state in which the other opening portion 22 is located on the right side as viewed from the front side of the chamber 2 is referred to as the reference position of the first shutter 20. As described above, the first shutter 13 disposed at the reference position exposes the first target 13A disposed on the front side of the chamber 2 and the third target 13C disposed on the right side as viewed from the front side in the film forming space 2S. This first gate 20 is rotatable inside the chamber 2. As shown in the first figure, the first shutter 20 is coupled to the drive shaft 24 of the drive motor 23 via the communication mechanism 25. This drive shaft 24 is supported to be rotatable in the upper wall portion 2b of the chamber 2. A transmission mechanism 25 provided between the drive shaft 24 and the first shutter 20 transmits the rotation of the drive shaft 24 to the first shutter 20. Although the configuration of the communication mechanism 25 is not particularly limited, for example, it is configured to have a drive source such as a motor, a gear, a ratchet, etc., 12 201224185 to switch the rotation of the drive shaft 24 to the first gate 2〇. The communication mode is a non-communication mode in which the rotation of the drive shaft 24 is not transmitted to the first gate 2〇. When the drive motor 23 is driven to rotate the first shutter 20, the respective opening portions 22 are moved on the annular track R1 having the same width as the diameter of the opening portion 22 as shown in Fig. 4 . As shown in the second figure, each stem 13 is included in this track R1. Therefore, when the first shutter 20 is rotated by 120° from the reference position, the opening portion 22 of the first shutter 20 overlaps with the position of two of the three stems 13 respectively, and the two targets 13 facing the opening portions 22 are respectively It is selectively exposed to the film forming space 2S. At this time, one of the three targets 13 is shielded at the first gate 20 and is not exposed to the film forming space 2S. Next, the second gate 30 will be described. As shown in the third figure, the second shutter 30 has a substantially hemispherical shape or a dome-shaped shutter body 31 as in the first gate 20, and the shutter body 31 has a preparation portion 31a at the lower end. The shutter body 31 is formed to be almost the same size as the shutter body 21 of the first gate 2〇. In this gate body 31, there is a __third entry

射控制部30A〜30C’第--第三入射控制部30A〜30C 控制從靶13釋放並向著基板外周部的濺鍍粒子數。 第五圖表示第二閘門30的下面3〇a。入射控制部 30A〜30C分別具有貫穿閘門本體31的開口部33〜 35。各開口部33〜35是用來使在第一閘門2〇夫祐披結 的靶13暴露在成膜空間2S的孔,與第一閘門2〇的各 ,口部22 —樣,配合靶13的形狀形成為圓形狀,其内 徑被形成為略大於乾13的直徑。The radiation control units 30A to 30C' first-third incidence control units 30A to 30C control the number of sputtered particles released from the target 13 toward the outer peripheral portion of the substrate. The fifth figure shows the lower side 3〇a of the second shutter 30. The incident control units 30A to 30C have openings 33 to 35 that penetrate the shutter body 31, respectively. Each of the openings 33 to 35 is a hole for exposing the target 13 of the first gate 2 to the film formation space 2S, and the target portion 22 of the first gate 2 is matched with the target 13 The shape is formed into a circular shape whose inner diameter is formed to be slightly larger than the diameter of the stem 13.

S 13 201224185 開口部33〜35被形成在閘門本體31的頂點PC8 與簷部31a之間。開口部33〜35在閘門本體31的周方 向,相隔角度α以等間隔地被設有。換言之,開口部 33〜35的中心點PC9〜PC11與閘門本體31的頂點PC8 相連的直線中,鄰接的直線彼此所成角度α為120°。 入射控制部30Α〜30C對應做為壁部的屏障部高 度,具有不同的遮蔽度,該壁部被設於開口部33〜35 外側。例如,第一入射控制部30Α在開口部33的外周 具備第一屏障部36。第一屏障部36是包圍開口部33 的環狀壁部。第一屏障部36的下面36u分隔開口 36Ρ。 如第三圖所示,第一屏障部36,具有高度,即第一屏 障長ΙΠ。又,雖然第一屏障長H1沒有特別限定,但較 佳為50〜120mm。 第一入射控制部30A的屏障部36的高度,在入射 控制部30A〜30C中是最高,因此,第一入射控制部30A 的遮蔽度也是最大。 第二入射控制部30B僅被開口部34構成。與第一 入射控制部30A不同,第二入射控制部30B在開口部 34的外周不具備向著基板S突出的環狀壁部。換言之, 第二入射控制部30B的開口部34的外周的壁部高度為 「零」。因此,第二入射控制部30B的遮蔽度在入射控 制部30A〜30C中是最小。 第三入射控制部30C在開口部35的外周具備第二 屏障部37。第二屏障部37是包圍開口部35的環狀壁 部。第二屏障部37的下面37u分隔開口 37P。此第二 14 201224185 屏障部37具有高度,即第二屏障長H2。第二屏障長 H2比第一屏障長H1短。第二屏障長H2是在上述範圍 50〜120mm,且比第一屏障長H1短就行。第三入射控 制部30C具有次於第一入射控制部30A大的遮蔽度。 如第一圖所示,此第二閘門30也可以在腔室2的 内部旋轉。第二閘門30經由例如傳達機構25被連接至 驅動馬達23成為第二閘門30的中心軸X4 (參照第三 圖)一致於驅動馬達23的驅動軸24的中心線。第二閘 門30在與驅動馬達23的轉動方向相同的方向轉動。 當將驅動馬達23驅動,使第二閘門30轉動,·則如 第五圖所示,入射控制部30A〜30C的開口部33〜35, 在具有與開口部33〜35的直徑相同寬度的環狀軌跡R2 上移動。如第二圖所示,在此執跡R2内,包含各乾13 的位置。因此,對於被第一閘門20選擇性暴露的兩個 靶13,第二閘門30的開口部33〜35中的任兩個被停 止成一致於第一閘門20的開口部22的位置時,該兩個 靶13經由第一閘門20以及第二閘門30變成暴露於成 膜空間2S。又,藉由使第二閘門30每次旋轉120°,就 可以變更面對被暴露的靶13的屏障部36、37或開口部 34 ° 又,第一屏障部36位於腔室2的正面的狀態,稱 為第二閘門30的基準位置。當將第一閘門20以及第二 閘門30分別配置在基準位置,則經由第一閘門20的開 口部22被暴露的第一靶13A,面對於第一屏障部36。 又,經由開口部22被暴露的第三靶13C,面對於第二 201224185 屏障部37。 接下來,根據第六圖〜第人圖來說明關於入射控制 部30A〜30C的作用。第六圖表示—乾13經由第一問 門20的開口部22 ’面對第二閘門3〇的第一入射控制 部30A的狀態。此乾13,經由第一間門2〇的開口部22 以及第二閘H30的開口部33,被暴露在成膜空間. 在韻進行時,從該執13的被崎面仏向著基板s 釋放贿粒子。㈣放並向著基板相部去的舰粒子 的-部分’被第-屏障部36遮蔽。因此,第一屏障部 36’使在基板外周部堆積的粒子數相較於沒有第一屏障 邻36的狀況減少,使在基板外周部的膜厚變小。 具體來說,例如從靶13的周緣部,距離通過基板 中心的中心轴線X2相對遠的基準點pu釋放並向著基 板S去的粒子執跡SP1,如圖中兩點虛線所示,在第一 屏障部36未被遮蔽。又,從位於靶13的中心部的基準 點Pk2釋放並向著基板s去的粒子執跡sp2,也沒有被 第一屏障部36遮蔽。 另一方面,從位於靶13的周緣部,距離通過基板 中心的中心軸線X2相對近的Pk3釋放並向著基板s去 的粒子軌跡SP3 ’其一部分被第一屏障部36遮蔽。也 就是說,若將基準點Pk3做為起始點,接近第一屏障部 36的下面36u後以最短距離到達基板S的表面S1的直 線L1,與該表面S1所成角度做為入射角0 inl,則以比 該入射角(9 ini小的角度入射的濺錢粒子被第一屏障部 36遮蔽。因此,以比該入射角0 ini小的角度釋放的藏 201224185 鑛粒子’不會堆積在基板s上’所以此舰粒子到 之前航的區域,係相較於在沒有屏障部的狀態雜的 狀況,膜厚會變小。此區域從基準點pk3來看,是^於 基板中心軸線X2的另一側的基板外周部S2。又, -屏障部36賴厚變小的基板外周部S2的寬度 wi。又,在本實施形態,從基準點pkl、pk2釋放向 基板表面去的賤鑛粒子’雖然沒有被第一屏障部 蔽’也可以將第-屏障部36構成為該賴遮 第七圖表示一乾13經由第一閑門2〇的—口敝部 22 ’面向第一閘Π 30的第三入射控制部3〇c的狀綠。 此靶13經由第-閘門20的開口部22以及第 ; 的開口部35,被暴露在成膜空間2S。在濺鍍進 從該靶13的被濺鍍面13a向著基板s釋放濺鍍粒早。 該釋放的濺鍍粒子的一部分中,向著基板外周部S2 的一部分粒子的飛行,被第一屏障部37遮蔽。° 第二屏障部37,使在基板外周部S2堆積的粒子 較於沒有第二屏障部37的狀況減少,使在基 目 S2的膜厚變小。但是,由於第二屏障部37的高声° = -屏障部36低,所以藉由第二屏障部37產生的ς 小的基板外周部S 2的寬度,比藉由第一屏障部3 6 : ^ 者小。 座生 具體來說,在乾13的被濺鍍面i3a中,從上 準點Pkl、Pk2釋放並向著基板s去的濺鍍粒子^二 SP1、SP2 ’並不會被第二屏障部37遮蔽。另一方面 從上述基準點Pk3釋放,並向著基板s去的粒子轨跡S 13 201224185 The opening portions 33 to 35 are formed between the vertex PC8 of the shutter body 31 and the flange portion 31a. The openings 33 to 35 are provided at equal intervals in the circumferential direction of the shutter body 31 at intervals of α. In other words, of the straight lines connecting the center points PC9 to PC11 of the openings 33 to 35 to the apex PC8 of the shutter body 31, the adjacent straight lines form an angle α of 120°. The incident control units 30A to 30C correspond to the height of the barrier portion of the wall portion and have different shielding degrees, and the wall portions are provided outside the openings 33 to 35. For example, the first incident control unit 30 includes the first barrier portion 36 on the outer circumference of the opening 33. The first barrier portion 36 is an annular wall portion that surrounds the opening portion 33. The lower surface 36u of the first barrier portion 36 separates the opening 36A. As shown in the third figure, the first barrier portion 36 has a height, i.e., a first screen length. Further, although the first barrier length H1 is not particularly limited, it is preferably 50 to 120 mm. Since the height of the barrier portion 36 of the first incident control portion 30A is the highest among the incident control portions 30A to 30C, the degree of shielding of the first incident control portion 30A is also the largest. The second incident control unit 30B is constituted only by the opening 34. Unlike the first incident control unit 30A, the second incident control unit 30B does not include an annular wall portion that protrudes toward the substrate S on the outer circumference of the opening 34. In other words, the height of the wall portion on the outer circumference of the opening portion 34 of the second incident control portion 30B is "zero." Therefore, the degree of shielding of the second incident control unit 30B is the smallest among the incident control units 30A to 30C. The third incident control unit 30C includes a second barrier portion 37 on the outer circumference of the opening 35. The second barrier portion 37 is an annular wall portion that surrounds the opening portion 35. The lower surface 37u of the second barrier portion 37 separates the opening 37P. This second 14 201224185 barrier portion 37 has a height, that is, a second barrier length H2. The second barrier length H2 is shorter than the first barrier length H1. The second barrier length H2 is in the above range of 50 to 120 mm and is shorter than the first barrier length H1. The third incident control unit 30C has a larger degree of shielding than the first incident control unit 30A. This second gate 30 can also rotate inside the chamber 2 as shown in the first figure. The second gate 30 is connected to the drive motor 25 via the communication mechanism 25 to become the center axis X4 of the second shutter 30 (refer to the third drawing) in accordance with the center line of the drive shaft 24 of the drive motor 23. The second shutter 30 is rotated in the same direction as the rotational direction of the drive motor 23. When the drive motor 23 is driven to rotate the second shutter 30, as shown in FIG. 5, the openings 33 to 35 of the incident control portions 30A to 30C have rings having the same width as the diameter of the openings 33 to 35. Move on the trajectory R2. As shown in the second figure, the position of each stem 13 is included in this trace R2. Therefore, when two of the openings 13 to 35 selectively exposed by the first shutter 20 are stopped to coincide with the position of the opening 22 of the first shutter 20, The two targets 13 become exposed to the film forming space 2S via the first gate 20 and the second gate 30. Further, by rotating the second shutter 30 by 120° each time, the barrier portion 36, 37 or the opening portion 34 facing the exposed target 13 can be changed. The first barrier portion 36 is located on the front surface of the chamber 2. The state is referred to as the reference position of the second gate 30. When the first shutter 20 and the second shutter 30 are respectively disposed at the reference position, the first target 13A exposed through the opening portion 22 of the first shutter 20 faces the first barrier portion 36. Further, the third target 13C exposed through the opening portion 22 faces the second 201224185 barrier portion 37. Next, the actions of the incident control units 30A to 30C will be described based on the sixth to the human figures. The sixth diagram shows the state in which the stem 13 faces the first incident control portion 30A of the second gate 3A via the opening portion 22' of the first door 20. The stem 13 is exposed to the film forming space via the opening portion 22 of the first door 2〇 and the opening portion 33 of the second gate H30. When the rhyme is performed, the surface of the handle 13 is released toward the substrate s Bribe particles. (4) The portion - of the ship particle that is placed toward the substrate phase portion is shielded by the first barrier portion 36. Therefore, the first barrier portion 36' reduces the number of particles deposited on the outer peripheral portion of the substrate as compared with the case where the first barrier 36 is not provided, and the film thickness at the outer peripheral portion of the substrate is reduced. Specifically, for example, from the peripheral portion of the target 13, the particles released from the reference point pu which is relatively far from the central axis X2 of the center of the substrate and directed toward the substrate S are traced SP1, as indicated by the dotted line at the two points in the figure. A barrier portion 36 is unobstructed. Further, the particle displacing sp2 released from the reference point Pk2 located at the center portion of the target 13 and directed toward the substrate s is not blocked by the first barrier portion 36. On the other hand, a part of the particle track SP3' which is released from Pk3 which is relatively close to the central axis X2 of the center of the substrate and which is directed toward the substrate s is shielded by the first barrier portion 36 from the peripheral portion of the target 13. That is, if the reference point Pk3 is used as the starting point, the line L1 that reaches the surface S1 of the substrate S at the shortest distance after approaching the lower surface 36u of the first barrier portion 36 is formed at an angle of incidence with the surface S1. Inl, the splash particles incident at an angle smaller than the incident angle (9 ini are blocked by the first barrier portion 36. Therefore, the 201224185 mineral particles released at an angle smaller than the incident angle of 0 ini does not accumulate in On the substrate s', the film thickness of the ship to the previous voyage is smaller than that of the state without the barrier. This area is from the reference point pk3 and is the center axis X2 of the substrate. The outer peripheral portion S2 of the other side of the substrate. Further, the width of the outer peripheral portion S2 of the substrate is reduced by the thickness of the barrier portion 36. Further, in the present embodiment, the antimony ore discharged to the surface of the substrate is released from the reference points pk1 and pk2. The particle 'may not be covered by the first barrier portion'. The first barrier portion 36 may be configured such that the seventh figure indicates that the stem 13 is facing the first gate 30 via the mouth portion 22' of the first idle door 2' The third incident control unit 3〇c is green. The target 13 is via the first gate 2 The opening portion 22 of the 0 and the opening portion 35 of the first portion are exposed to the film forming space 2S. The sputtering is released from the sputtered surface 13a of the target 13 toward the substrate s. The released sputter particles In some of the particles, the flight of a part of the particles toward the outer peripheral portion S2 of the substrate is blocked by the first barrier portion 37. The second barrier portion 37 reduces the amount of particles deposited on the outer peripheral portion S2 of the substrate compared to the case where the second barrier portion 37 is not provided. The film thickness at the base S2 is made small. However, since the high sound of the second barrier portion 37 is lower than the barrier portion 36, the outer peripheral portion S 2 of the substrate which is generated by the second barrier portion 37 is small. The width is smaller than that of the first barrier portion 3 6 : ^. Specifically, in the sputtered surface i3a of the stem 13, the sputtered particles released from the upper quasi-points Pk1, Pk2 and directed toward the substrate s ^ The two SP1, SP2' are not obscured by the second barrier portion 37. On the other hand, the particle trajectory released from the above reference point Pk3 and going toward the substrate s

S 17 201224185 ϋ 刀被第二屏障部37遮蔽。也就是說,若將 土準黑 做為起始點,接近第二屏障部37的下面37u 後以最短距_達基板s的表面si的直線L2,與該表 面si所成角度做為入射角^ in2,則以比該入射角心2 1的角度來入射的濺鑛粒子,會被第二屏障部遮 蔽口此從基準點Pk3以比入射角θ μ小的角度所 釋放的麟好;^會_在基板s上,所以此濺鑛粒子 到達的之雨預定的基板外周部Μ,相較於在沒有屏障 部的狀態濺錢的狀況,膜厚會變小。 又’以第一屏障部37將膜厚變小的基板外周部Μ 的寬度’比在第—屏障部36的狀況的基板外周部 S2的寬度AW1小。又’上述入射角…以,比在第一 屏障部36的狀況的入射角0inl小。 第八圖表示-乾13經由第—閘門2()的―開口部 22,面向第二閘H 3G的第二人射控制部遞的狀離。 在此狀況,由於沒有包圍開口部34的屏障部,所以 上述基準點Pkj〜Pk3向著基板s的表面S1去的賤錄粒 子’並不會被第二入射部30B遮蔽。因此,從面 部34的把13釋放的機鍍粒子,與在沒有第二 的狀態下被濺鍍的狀況,以幾乎相同的膜厚分佈堆積在 基板上。 接下來,根據第九圖〜第十一圖,來說明關於一 閘門20以及第二閘門30的配置模式(旋轉位置)。 九圖〜第十-圖是在第—閘門2〇以及第二閘門3 口 ’被重疊在把13的狀態,從下面施來看第二^ 201224185 30的圖。 在第九(a)圖〜第九(c)圖,第一閘門20被配 置在基準位置。在此狀況,第一閘門20的開口部22, 分別面對於第一靶13A以及第三靶13C。因此,第一靶 13A以及第三靶13C經由開口部22被暴露在成膜空間 2S,第二靶13B被閘門本體21遮蔽。 如此,對於在成膜空間2S所暴露的第一把13 A以 及第三靶13C,第二閘門30的配置模式係如第九(a) 圖〜第九(c)圖所示的三個配置模式中,配合第一靶 13A以及第三靶13C的材質來選擇。 第九(a)圖表示將第二閘門30配置在基準位置的 狀態。在此狀態,第一屏障部36面對第一靶13A,第 二屏障部37面對第三靶13C。因此,如本實施形態, Ni傾向於在基板外周部S2使膜厚增大,在用Ni做為 第一靶13A的狀況,可以藉由第一屏障部36來抑制在 基板外周部S2的膜厚增大,所以結果,可以均勻化在 基板S所形成的薄膜膜厚以及組成。又,在用MgO做 為第三靶13C的狀況,也可以抑制在基板外周部S2的 膜厚增大,結果,可以均勻化在基板S所形成的薄膜膜 厚以及組成。 在用上述材質做為第一靶13A以及第三靶13C的 狀況,第九(a)的配置模式在膜厚的均勻化上有效, 但在第一靶13A以及第三靶13C為其他材質的狀況, 對應該材質的膜厚分佈傾向,也可以將第二閘門30做 為其他配置模式。又,在僅使第二閘門30轉動至想要 201224185 的配置模式的狀況,驅動傳達機構25,做為旋轉力未 被傳達至第一閘門20的非傳達狀態,可以僅使第二閘 門30從基準位置旋轉到想要的配置模式。 在以下的說明,從第二閘門30的下面來看第一閘 門20以及第二閘門30的旋轉方向是順時針,但即使是 逆時針也可以,彼此相異也可以。 第九(b)圖表示使第二閘門30從基準位置旋轉 120°的狀態。在此狀況,第一靶13A面對開口部34, 第三靶13C面對第一屏障部36。此配置模式例如在以 下狀況是有效的:將即使在沒有屏障部的狀態也能獲得 相對均勻的膜厚分佈的材質使用在第一靶13A,將一材 質使用在第三靶13C,該材質在沒有屏障部的狀態,使 在基板外周部S2的膜厚變大,且使在基板外周部S2膜 厚增大的區域(以下稱為膜厚增大區域)的寬度特別增 大。 第九(c)圖表示使第二閘門30從基準位置旋轉240 °的狀態。在此狀況,第一靶13A面對第二屏障部37, 第三靶13C面對開口部34。此配置例如在以下狀況是 有效的:將即使在沒有屏障部的狀態,在基板外周部 S2膜厚也會變大的材質使用在第一靶13A,將即使沒 有屏障部也可獲得相對均勻的膜厚分佈的材質使用在 第三靶13C。 又,在沒有屏障部的狀態下濺鍍時,在基板外周部 S2使用膜厚會變大的材質做為靶13的狀況,進行預先 實驗或模擬來調查其膜厚增大區域的寬度。在本說明S 17 201224185 The boring tool is shielded by the second barrier portion 37. That is to say, if the ground quasi black is used as the starting point, the angle L2 with the surface si at the shortest distance_to the surface si of the substrate s is approached to the incident angle after approaching the lower surface 37u of the second barrier portion 37. ^ in2, the splashed particles incident at an angle of the incident angle 2 1 will be released by the second barrier portion from the reference point Pk3 at an angle smaller than the incident angle θ μ; The _ is on the substrate s, so that the rain reaches the predetermined outer peripheral portion of the substrate, and the thickness of the substrate becomes smaller than in the case where the barrier is not present. Further, the width 'the width of the outer peripheral portion 基板 of the substrate whose thickness is reduced by the first barrier portion 37 is smaller than the width AW1 of the outer peripheral portion S2 of the substrate in the state of the first barrier portion 36. Further, the above incident angle is smaller than the incident angle of 0in1 in the state of the first barrier portion 36. The eighth diagram shows that the stem 13 passes through the opening 22 of the first gate 2 () and faces the second human radiation control portion of the second gate H 3G. In this case, since there is no barrier portion surrounding the opening portion 34, the grading particles "toward the surface S1 of the substrate s from the reference points Pkj to Pk3 are not shielded by the second incident portion 30B. Therefore, the plated particles released from the handle 13 of the face portion 34 are deposited on the substrate with almost the same film thickness distribution in a state where the plated particles are not sputtered in the second state. Next, the arrangement pattern (rotational position) of one gate 20 and the second gate 30 will be described based on the ninth to eleventh drawings. Fig. 9 to Fig. 10 are diagrams showing the state of the second gate 20122185 30 when the first gate 2〇 and the second gate gate 3 are overlapped in the state of the handle 13. In the ninth (a)th to ninth (c)th drawings, the first shutter 20 is disposed at the reference position. In this case, the opening portion 22 of the first shutter 20 faces the first target 13A and the third target 13C, respectively. Therefore, the first target 13A and the third target 13C are exposed to the film forming space 2S via the opening portion 22, and the second target 13B is shielded by the shutter body 21. Thus, for the first 13 A and the third target 13C exposed in the film forming space 2S, the arrangement pattern of the second gate 30 is as shown in the ninth (a) to ninth (c) In the mode, the materials of the first target 13A and the third target 13C are selected to be selected. The ninth (a) diagram shows a state in which the second shutter 30 is placed at the reference position. In this state, the first barrier portion 36 faces the first target 13A, and the second barrier portion 37 faces the third target 13C. Therefore, in the present embodiment, Ni tends to increase the film thickness in the outer peripheral portion S2 of the substrate, and in the case where Ni is used as the first target 13A, the film on the outer peripheral portion S2 of the substrate can be suppressed by the first barrier portion 36. The thickness is increased, and as a result, the film thickness and composition of the film formed on the substrate S can be made uniform. Further, in the case where MgO is used as the third target 13C, the film thickness at the outer peripheral portion S2 of the substrate can be suppressed from increasing, and as a result, the film thickness and composition of the film formed on the substrate S can be made uniform. In the case where the above-described materials are used as the first target 13A and the third target 13C, the arrangement pattern of the ninth (a) is effective in uniformizing the film thickness, but the first target 13A and the third target 13C are made of other materials. In other cases, the second gate 30 may be used as another arrangement mode in accordance with the tendency of the film thickness distribution of the material. Further, in a state where only the second shutter 30 is rotated to the configuration mode of 201224185, the transmission mechanism 25 is driven, and as the non-transmission state in which the rotational force is not transmitted to the first shutter 20, only the second shutter 30 can be The reference position is rotated to the desired configuration mode. In the following description, the rotation directions of the first shutter 20 and the second shutter 30 are clockwise from the lower side of the second shutter 30, but they may be different from each other even if they are counterclockwise. The ninth (b) diagram shows a state in which the second shutter 30 is rotated by 120 from the reference position. In this case, the first target 13A faces the opening portion 34, and the third target 13C faces the first barrier portion 36. This configuration mode is effective, for example, in a case where a material having a relatively uniform film thickness distribution can be obtained even in a state without a barrier portion, and a material is used in the third target 13C, and the material is used in the third target 13C. In the state where there is no barrier portion, the thickness of the substrate outer peripheral portion S2 is increased, and the width of the region where the film thickness of the substrate outer peripheral portion S2 is increased (hereinafter referred to as the film thickness increasing region) is particularly increased. The ninth (c) diagram shows a state in which the second shutter 30 is rotated by 240 ° from the reference position. In this case, the first target 13A faces the second barrier portion 37, and the third target 13C faces the opening portion 34. This configuration is effective in the case where, for example, a material having a large film thickness at the outer peripheral portion S2 of the substrate is used in the first target 13A even in the state without the barrier portion, and a relatively uniform portion can be obtained even without the barrier portion. The material of the film thickness distribution is used in the third target 13C. In the case where the barrier is not in the state of the barrier portion, a material having a large film thickness is used as the target 13 in the outer peripheral portion S2 of the substrate, and the width of the region where the film thickness is increased is examined by a preliminary experiment or simulation. In this description

20 201224185 書,在不具有屏障部(36、37)的濺鍍裝置,用給予的 靶濺鍍時所形成的薄膜的膜厚分佈,稱為「依照靶材料 的膜厚分佈」或「以靶單體濺鍍時的膜厚分佈」。然後 在濺鍍進行時,從藉由第一屏障部36可以抑制膜厚增 大的寬度Δλνΐ與藉由第二屏障部37可抑制膜厚增大 的寬度AW2中,選擇接近預先調查的膜厚增大區域的 寬度者,做為面對該靶13的屏障部。再者,使具備被 選擇的屏障部的陰極10傾斜移動,並變更靶13的傾斜 角,藉此能進行微調整,使得以該屏障部可以抑制膜厚 增大區域的寬度,接近實際膜厚增大區域的寬度。例如 當靶13的傾斜角變大,則藉由屏障部可抑制膜厚增大 的區域寬度會變小。當靶13的傾斜角變小,則藉由屏 障部可以抑制膜厚增大的區域寬度變大。 用第二靶13Β以及第三靶13C進行濺鍍時,如第 十(a)〜(c)圖所示,使第一閘門20從基準位置配 置至旋轉120 °的位置。在此位置所配置的第一閘門 20,經由開口部22,使第二靶13B以及第三靶13C選 擇性地暴露在成膜空間2S,藉由閘門本體21遮蔽第一 靶 13A。 然後,第二閘門30,係如第十(a)〜(c)圖所示 的三個配置模式中,被配置在配合其選擇靶(13B、13C) 材質的配置模式。 第十(a)圖表示將第二閘門30配置在基準位置的 狀態。第二靶13B面對開口部34,第三靶13C面對第 二屏障部37。此配置模式為例如本實施形態,用Co做20 201224185 The film thickness distribution of a film formed by sputtering of a given target in a sputtering apparatus without a barrier portion (36, 37) is called "distribution according to the film thickness of the target material" or "target Film thickness distribution during single sputtering. Then, when the sputtering is performed, the width Δλν 抑制 which can suppress the increase in the film thickness by the first barrier portion 36 and the width AW2 at which the film thickness can be suppressed by the second barrier portion 37 are selected, and the film thickness close to the investigation is selected. The width of the area is increased as a barrier facing the target 13. Further, by tilting the cathode 10 having the selected barrier portion and changing the inclination angle of the target 13, it is possible to finely adjust the width of the region where the film thickness is increased by the barrier portion, and to approach the actual film thickness. Increase the width of the area. For example, when the inclination angle of the target 13 is increased, the width of the region where the film thickness is increased by the barrier portion can be reduced. When the inclination angle of the target 13 becomes small, the width of the region where the film thickness is increased can be suppressed by the barrier portion. When sputtering is performed by the second target 13A and the third target 13C, as shown in the tenth (a) to (c), the first shutter 20 is disposed from the reference position to a position rotated by 120°. The first gate 20 disposed at this position selectively exposes the second target 13B and the third target 13C to the film forming space 2S via the opening portion 22, and shields the first target 13A by the shutter body 21. Then, the second shutter 30 is arranged in an arrangement mode in which the materials of the selected targets (13B, 13C) are matched in the three arrangement modes shown in the tenth (a) to (c). The tenth (a) diagram shows a state in which the second shutter 30 is placed at the reference position. The second target 13B faces the opening portion 34, and the third target 13C faces the second barrier portion 37. This configuration mode is, for example, the present embodiment, and is made with Co.

S 21 201224185 為第二乾13B,用MgO做為第三把nc的狀况 的。也就是說,第二乾13B係如c。,在即使没有= 部,也獲得相對均勻的膜厚分佈的材f的狀況 二 門30藉由使沒有壁部的開口部34面對第二靶,甲 會妨礙到達至基板外周部S2的賴粒子的飛行,可= 使第一靶13B的濺鍍粒子堆積在該基板外周部幻。 二靶13B係如MgO,在沒有屏障部的狀態下, 外周部S2膜厚變大的材質的狀況,第二閘門3〇,二f 使第二屏障部37面對第二耙13B,結果可以均2 基板S所形成的薄膜的膜厚以及組成。 —在 第十(b)圖表示使第二閘門3〇從基準位 120的狀態。第二靶13B面對第二屏障部37,第= 13C面對第一屏障部36。此配置模式例如在以下狀 有效的:將在沒有屏障部的狀態下於基板外周部$ = 厚會變大的材質使用在第二靶13B,在第三耙l3c 、 一材質,該材質在沒有屏障部的狀態下於基板 , S2膜*厚會變大,該骐厚之增大區域的寬度特別大。邻 。第十(〇圖表示使第二閘門30從基準位置旋 。的狀態。第二靶13B面對第一屏障部36,第三靶240 面,開口部34。此配置模式例如在以下狀況是有l3c 在第一乾13B使用一材質,該材質在沒有屏障部、乂 下於基板外周部S2犋厚會變大,該膜厚之增大區^ ^ 寬度特別大的,而在第三靶13C使用即使在沒有 的狀態下也可獲得相對均勻的膜厚分佈的材質。率部 用第一靶13A以及第二靶13B進行濺鍍時,如w 22 201224185 十一(a)〜(c)圖所示,使第一閘門20從基準位置 配置至旋轉240°的狀態。配置在此位置的第一閘門 20,經由開口部22使第一靶13A以及第二靶13B選擇 性地暴露於成膜空間2S,以閘門本體21遮蔽第三靶 13C。 然後,第二閘門30係如第十一(a)〜(c)圖所 示的三個配置模式中,被配置在配合其選擇靶(13A、 13B)材質的配置模式。 第十一(a)圖表示將第二閘門30配置在基準位置 的狀態。第一靶13A面對第一屏障部36,第二靶13B 面對開口部34。此配置模式為例如本實施形態,用Ni 做為第一靶13A,用Co做為第二靶13B的狀況是有效 的。也就是說,對於第一靶13A,第二閘門30藉由第 一屏障部36來抑制在基板外周部S2的膜厚增大,對於 第二靶13B,第二閘門30不會妨礙到達基板外周部S2 的藏鑛粒子的飛行。 第十一(b)圖表示使第二閘門30從基準位置旋轉 120°的狀態。第一靶13A面對開口部34,第二靶13B 面對第二屏障部37。此配置模式例如在以下狀況是有 效的:即使沒有屏障部也可獲得相對均勻的膜厚分佈的 材質使用在第一靶13A,在沒有屏障部的狀態下於基板 外周部S2膜厚會變大的材質使用在第二靶13B。 第十一(c)圖表示使第二閘門30從基準位置旋轉 240°的狀態。第一靶13A面對第二屏障部37,第二靶 13B面對第一屏障部36。此配置模式例如在以下狀況是S 21 201224185 is the second stem 13B, using MgO as the third nc. That is to say, the second stem 13B is like c. In the case where the material f of the relatively uniform film thickness distribution is obtained even in the absence of the portion, the two doors 30 prevent the particles reaching the outer peripheral portion S2 of the substrate from being blocked by the opening portion 34 having no wall portion facing the second target. The flight can be made to deposit the sputtered particles of the first target 13B on the outer periphery of the substrate. In the state in which the second target 13B is MgO, in the state where the barrier portion is not provided, the material of the outer peripheral portion S2 is increased in thickness, and the second gate 3〇, the second barrier portion 37 faces the second crucible portion 13B, and the result is The film thickness and composition of the film formed by the substrate S. - In the tenth (b)th diagram, the state in which the second gate 3〇 is taken from the reference bit 120 is shown. The second target 13B faces the second barrier portion 37, and the third = 13C faces the first barrier portion 36. This configuration mode is effective, for example, in a state in which the outer peripheral portion of the substrate is thicker in the state without the barrier portion, and the material is used in the second target 13B, and in the third 耙l3c, a material, the material is not present. In the state of the barrier portion, the thickness of the S2 film is increased on the substrate, and the width of the increased region of the thickness is particularly large. Neighbor. Tenth (the figure shows a state in which the second shutter 30 is rotated from the reference position. The second target 13B faces the first barrier portion 36, the third target 240 surface, and the opening portion 34. This configuration mode is, for example, in the following cases L3c uses a material in the first stem 13B, and the material becomes thicker without the barrier portion and under the outer peripheral portion S2 of the substrate, and the enlarged region of the film thickness is particularly large, and the third target 13C A material having a relatively uniform film thickness distribution can be obtained even in a state where it is not present. When the rate portion is sputtered by the first target 13A and the second target 13B, for example, w 22 201224185 eleven (a) to (c) As shown, the first shutter 20 is disposed from the reference position to a state of rotation of 240. The first shutter 20 disposed at this position selectively exposes the first target 13A and the second target 13B to the film formation via the opening portion 22. The space 2S shields the third target 13C with the shutter body 21. Then, the second gate 30 is configured to match the selected target (13A) in the three configuration modes shown in the eleventh (a) to (c). , 13B) Configuration mode of the material. Figure 11 (a) shows the second gate 30 placed in the reference The first target 13A faces the first barrier portion 36, and the second target 13B faces the opening portion 34. This arrangement mode is, for example, the present embodiment, using Ni as the first target 13A and Co as the second The condition of the target 13B is effective. That is, for the first target 13A, the second gate 30 suppresses an increase in film thickness at the outer peripheral portion S2 of the substrate by the first barrier portion 36, and for the second target 13B, the second The shutter 30 does not hinder the flight of the ore particles reaching the outer peripheral portion S2 of the substrate. Fig. 11(b) shows a state in which the second shutter 30 is rotated by 120° from the reference position. The first target 13A faces the opening 34, The two targets 13B face the second barrier portion 37. This arrangement mode is effective, for example, in a state in which a relatively uniform film thickness distribution is obtained even in the absence of the barrier portion, and the material is used in the first target 13A without the barrier portion. The material which becomes thicker in the outer peripheral portion S2 of the substrate is used in the second target 13B. The eleventh (c) shows a state in which the second shutter 30 is rotated by 240 from the reference position. The first target 13A faces the second The barrier portion 37, the second target 13B faces the first barrier portion 36. This configuration mode is for example The following conditions are

S 23 201224185 有效的:在沒有屏障部的狀態下於基板外周部S2膜厚 會變大的材質使用在第一靶13A,而在第二靶13B使用 一材質,該材質在沒有屏障部的狀態下於基板外周部 S2膜厚會變大,該膜厚之增大區域的寬度特別大。 接下來,說明關於濺鍍處理的順序。對於基板S進 行成膜處理時,將基板搬入腔室2内,將該基板S載置 於基板夾4,並使其旋轉至特定的成膜開始位置。再者, 將來自氣體供給機構9的濺鍍氣體導入至成膜空間 2S,並調整腔室2内的壓力至特定壓力。 接下來,藉由驅動馬達23.將第一閘門20以及第二 閘門30轉動至想要的旋轉位置,選擇兩個靶13。使適 合這些靶13的入射控制部面對。此時,第一閘門20以 及第二閘門30到達至想要的旋轉位置的旋轉角度,若 彼此為相同角度,使閘門20、30在同方向旋轉相同角 度就可以。在旋轉角度彼此相異的狀況,使第一閘門 20旋轉至想要的旋轉位置。其後,將傳達機構25切換 至非傳達模式,在驅動馬達23的旋轉不被傳達至第一 閘門20的狀態下,使驅動馬達23在順時針或反時針方 向,旋轉與第二閘門30的想要的旋轉位置相對應的角 度。藉此,第一閘門20被保持在停止狀態,僅第二閘 門30被轉動至想要的旋轉位置。如此,可以使適合選 擇靶的屏障部36、37或開口部34面對這些選擇靶。 各閘門20、30旋轉至想要的旋轉位置後,驅動對 於選擇靶的陰極10的磁迴路15,在選擇靶的被濺鍍面 13a產生磁控管磁場。將特定直流或交流電力施加至該 24 201224185 選擇靶。藉此,在選擇靶的被濺鍍面13a與成膜空間2S 之間開始放電,用該被濺鍍面13a進行濺鍍。 此時,適合各選擇靶材質的屏障部36、37或開口 部34面對著各選擇靶。因此,屏障部36或37面對在 沒有屏障部的狀態濺鍍時使基板外周部S2的膜厚增大 的靶13。在此狀況,藉由因屏障部36、37導致濺鍍粒 子的遮蔽,到達基板外周部S2的濺鍍粒子會變少,在 基板外周部S2的膜厚增大會被抑制。又,在沒有屏障 部的狀態下可獲得相對均勻膜厚分佈的靶13,面對開 口部34,所以不遮蔽濺鍍粒子也可以進行成膜。如此, 對與選擇靶的膜厚分佈傾向相應的屏障部36、37或開 口部34,該選擇靶被選擇性地面對,因此可抑制每個 選擇靶的膜厚的偏差。氣體流量、靶的傾斜角、來自外 部電源G的供給電力等諸條件不變更下,結果在薄膜的 徑方向的膜厚偏差會被抑制。因此,不變更膜質下,膜 厚的面内均勻性被提升,並可以均勻化同一層内的組 成。 在接著變更選擇靶進行濺鍍的狀況,使第一閘門 20轉動並使第一閘門20的開口部22,面對變更後的選 擇靶13。又,使第二閘門30旋轉,並使適合變更後的 各選擇靶的材質的屏障部36、37或開口部34面對各選 擇靶。其後,進行濺鍍。 根據上述實施形態,可以獲得如下效果。 (1)在上述實施形態,濺鍍裝置1是具備複數個 靶的多元式裝置,在複數個靶13與成膜空間2S之間,S 23 201224185 Effectively: a material having a large film thickness at the outer peripheral portion S2 of the substrate in the state without the barrier portion is used for the first target 13A, and a material having a material for the second target 13B without the barrier portion is used. The film thickness is increased in the outer peripheral portion S2 of the substrate, and the width of the increased region of the film thickness is particularly large. Next, the order of the sputtering process will be described. When the substrate S is subjected to a film forming process, the substrate is carried into the chamber 2, and the substrate S is placed on the substrate holder 4 and rotated to a specific film formation start position. Further, the sputtering gas from the gas supply mechanism 9 is introduced into the film forming space 2S, and the pressure in the chamber 2 is adjusted to a specific pressure. Next, the first gate 20 and the second shutter 30 are rotated to the desired rotational position by the drive motor 23. Two targets 13 are selected. The incident control portion suitable for these targets 13 is faced. At this time, the first shutter 20 and the second shutter 30 reach the rotation angle to the desired rotation position, and if the angles are the same at the same angle, the shutters 20 and 30 can be rotated by the same angle in the same direction. The first shutter 20 is rotated to a desired rotational position in a state where the rotation angles are different from each other. Thereafter, the communication mechanism 25 is switched to the non-transmission mode, and the drive motor 23 is rotated in the clockwise or counterclockwise direction with the second shutter 30 in a state where the rotation of the drive motor 23 is not transmitted to the first shutter 20. The angle at which the desired rotational position corresponds. Thereby, the first shutter 20 is maintained in the stopped state, and only the second shutter 30 is rotated to the desired rotational position. Thus, the barrier portions 36, 37 or the openings 34 suitable for selecting the target can be faced to these selective targets. After each of the shutters 20, 30 is rotated to a desired rotational position, the magnetic circuit 15 for the cathode 10 of the selected target is driven to generate a magnetron magnetic field on the sputtered surface 13a of the selected target. Apply specific DC or AC power to the 24 201224185 Select Target. Thereby, discharge is started between the sputtered surface 13a of the selective target and the film forming space 2S, and sputtering is performed by the sputtered surface 13a. At this time, the barrier portions 36, 37 or the opening portion 34 suitable for each of the selected target materials face the respective selection targets. Therefore, the barrier portion 36 or 37 faces the target 13 which increases the film thickness of the outer peripheral portion S2 of the substrate at the time of sputtering without the barrier portion. In this case, by the shielding of the sputtered particles by the barrier portions 36 and 37, the number of sputtered particles reaching the outer peripheral portion S2 of the substrate is reduced, and the increase in the thickness of the outer peripheral portion S2 of the substrate is suppressed. Further, the target 13 having a relatively uniform film thickness distribution can be obtained without the barrier portion, and the opening portion 34 can be formed, so that the film can be formed without shielding the sputtering particles. Thus, the barrier target 36, 37 or the opening portion 34 corresponding to the tendency of the film thickness distribution of the selected target is selectively faced, so that the variation in the film thickness of each of the selected targets can be suppressed. When the conditions such as the gas flow rate, the inclination angle of the target, and the supply electric power from the external power source G are not changed, the film thickness variation in the radial direction of the film is suppressed. Therefore, the in-plane uniformity of the film thickness is improved without changing the film quality, and the composition in the same layer can be made uniform. Next, the sputtering of the selected target is performed, and the first shutter 20 is rotated to open the opening 22 of the first shutter 20 to face the changed selection target 13. Further, the second shutter 30 is rotated, and the barrier portions 36, 37 or the opening portion 34 which are suitable for the material of each of the selected selected targets face each of the selected targets. Thereafter, sputtering is performed. According to the above embodiment, the following effects can be obtained. (1) In the above embodiment, the sputtering apparatus 1 is a multi-component apparatus including a plurality of targets, and between the plurality of targets 13 and the film forming space 2S,

S 25 201224185 具備閘門機構Μ,閘門機構Μ具有使選擇靶 膜空間2S的開口部22。此閘門機構Μ是由第 20與第二閘門30所構成。第二閘門3〇具備^ 部30Α、30B、30C (屏障部36、37以及開口部341 入射控制部30Α、30Β、30C:控制經由開口部^ 靶釋放並向著基板外周部S2去的濺鍍粒子數。, 進行濺:鑛時’根據經由第一閘門20的開〇部2;二 在成膜空間2S的選擇靶,以單體賤鍍時的“ 向,將從人射控制部30A〜30C之中適合該選擇乾的任 一入射控制部適用於該選擇靶。例如如恥的材 盥 ^ Co、Ti等材料,在料㈣鍍時的轉分佈彼此相 異。即使搭載複數個靶13在相同裝置,在靶每一面内 可以均勻化到達基板s的濺鍍粒子數的分佈。因此,在 不改變氣體流量、靶的傾斜角、來自外部電源g 電力等諸條件以變更膜質之前提下,可以提升在某ϋ 膜膜厚的面内均句性’並提升同-層内土的薄 膜組成的均句性。 (2 )在上述貫施形悲,入射控制部、3〇b、3〇c (屏障部36、37以及開口部34),對應壁部高度有不 同的遮蔽部,該壁部包圍#13的被賤鑛自仏的外周。 也f是說,入射控制部3〇Α具備即為相對高(Η1)的 壁部的第-屏障部36,所以有大遮蔽度,入射控制部 30C具備即為比第一屏障部36低(Η2)的壁部的第二 屏障部37,所以具有比入射控制部3〇α 入射控制部地具備簡單關口部34。沒;開 201224185 口部34的壁部,即高度為「零」。因此,入射控制部 30B具有最小的遮蔽度。因此’不會複雜化裝置或成膜 步驟,對應靶13可以使遮蔽度不同。 (3)在上述實施形態,閘門機構Μ是由具有兩個 開口部的第一閘門20與具有屏障部36、37以及開口部 34的第二閘門30所構成。第一閘門20被設為對於靶 13可旋轉,使兩個乾13,經由兩個開口部22,對於成 膜空間2S選擇性地暴露。第二閘門30被設於比第一間 門20靠近基板S的位置,藉由轉動至想要的位置,與 以第一閘門20選擇性地被暴露的兩個乾丨3相對應地, 使屏障部36、37以及開口部34中的兩者分別面對該兩 個靶13。因此,即使在選擇性地暴露複數個靶13並濺 鍍的狀況’由於可以適用適合這些靶13的入射控制部 哪叼目由度,刁以力求 薄膜的膜厚以及組成的均勻化。 也就是說’如第十五圖所示,膜厚分佈是依照乾的 材貝。因此’驅動馬達2 3使第二閘門3 〇旋轉,第二間 部3GA〜3GC之中,經由對餘的材 貝所選擇的入射控制部的開口 可以解除依照該並在Μ 錄暴路。错此, 者。可以在基板上以大厂部膜厚會變厚 膜。在糖為複數個:^ 部的開口部,使嗲u斤選擇的複數個入射控制 亥贿個選擇衫別暴露。藉此,可以 201224185 在基板上以大致均勻的膜厚、大致均勻的組成,形成複 數個選擇靶所對應的複合組成薄膜。 [第二實施形態] 接下來,根據第十二圖〜第十三圖來說明將本發明 具體化的第二實施形態。又,由於第二實施形態只是變 更第一實施形態的第一閘門20的結構,所以關於同樣 的部分省略其詳細說明。 如第十二圖所示,本實施形態的第一閘門20,是 一個開口部22在其閘門本體21被貫穿形成。與第一實 施形態相同,開口部22為圓形狀,其内徑被形成為略 大於靶13的直徑。因此,在本實施形態,在濺鍍進行 時,一個靶13經由開口部22被暴露在成膜空間2S。 第十三(a)圖表示第一閘門20以及第二閘門30 被配置在基準位置的狀態。此位置所配置的第一閘門 20,經由開口部22,使第一靶13A在成膜空間2S露出。 第二閘門30的第一屏障部36面對於該第一靶13A。僅 用例如由Ni所組成的第一靶13A進行成膜時,第十三 (a)圖的配置模式是有效的。又,在本實施形態,雖 然使第一屏障部36面對第一靶13A,但對應靶的膜厚 分佈,也可以使第二屏障部37面對第一靶13A。 第十三(b)圖表示使第一閘門20從基準位置旋轉 120°,將第二閘門30配置在基準位置的狀態。此位置 所配置的第一閘門20,經由開口部22,使第三靶13C 在成膜空間2S露出。第二閘門30的第二屏障部37面 對於該第三靶13C。僅用例如由MgO所組成的第三靶S 25 201224185 has a shutter mechanism Μ, and the shutter mechanism Μ has an opening 22 for selecting the target membrane space 2S. This gate mechanism 构成 is composed of the 20th and second gates 30. The second gate 3A includes the portions 30A, 30B, and 30C (the barrier portions 36 and 37 and the opening portion 341. The incident control portions 30A, 30B, and 30C: control the sputtering particles that are released through the opening portion and toward the outer peripheral portion S2 of the substrate. No.: Splashing: According to the opening portion 2 passing through the first gate 20; and the selection target in the film forming space 2S, the "direction" when the single element is plated, will be from the human shot control unit 30A to 30C Any one of the incident control portions suitable for the selection is suitable for the selected target. For example, materials such as smear materials such as Co, Ti, etc., have different transfer profiles when the material (4) is plated. Even if a plurality of targets 13 are mounted In the same apparatus, the distribution of the number of sputtered particles reaching the substrate s can be uniformized in each surface of the target. Therefore, it is lifted before changing the film quality without changing the gas flow rate, the tilt angle of the target, and the power from the external power source g. It can improve the uniformity of the film in the in-plane of a certain film thickness and improve the uniformity of the film composition of the soil in the same layer. (2) In the above-mentioned form, the incident control section, 3〇b, 3〇 c (barriers 36, 37 and opening 34), the height of the corresponding wall is different In this part, the wall portion surrounds the outer circumference of the strontium ore from ##. In other words, the incident control unit 3 includes the first barrier portion 36 which is a wall portion which is relatively high (Η1), so that there is a large shielding. The incident control unit 30C includes the second barrier portion 37 which is a wall portion which is lower than the first barrier portion 36 (Η2). Therefore, the incident control portion 30C has a simple closing portion 34 than the incident control portion 3〇α incident control portion. The wall portion of the mouth portion 34 is opened 201224185, that is, the height is "zero." Therefore, the incident control portion 30B has the minimum degree of shielding. Therefore, the shielding target can be made different depending on the target 13 without complicating the device or the film forming step. 3) In the above embodiment, the shutter mechanism 构成 is constituted by the first shutter 20 having the two opening portions and the second shutter 30 having the barrier portions 36 and 37 and the opening portion 34. The first shutter 20 is set as the target 13 is rotatable such that the two stems 13 are selectively exposed to the film forming space 2S via the two opening portions 22. The second shutter 30 is disposed closer to the substrate S than the first door 20 by rotating to The desired position, and two cognacs 3 selectively exposed with the first gate 20 Correspondingly, both of the barrier portions 36, 37 and the opening portion 34 face the two targets 13, respectively. Therefore, even in the case of selectively exposing a plurality of targets 13 and sputtering, "since suitable for these The entrance control portion of the target 13 is focused on the degree of film thickness and uniformity of the composition. That is, as shown in the fifteenth figure, the film thickness distribution is in accordance with the dry material. Therefore, 'driving The motor 2 3 rotates the second shutter 3, and among the second partitions 3GA to 3GC, the opening of the incident control unit selected for the remaining material can be released in accordance with the accident. It is possible to thicken the film on the substrate with a large film thickness. In the opening of the sugar: a part of the ^ part, the number of incident control that the 嗲u jin chooses is not exposed. Thereby, a composite film corresponding to a plurality of selected targets can be formed on the substrate by a substantially uniform film thickness and a substantially uniform composition on 201224185. [Second embodiment] Next, a second embodiment in which the present invention is embodied will be described based on the twelfth to thirteenth drawings. Further, since the second embodiment only changes the configuration of the first shutter 20 of the first embodiment, the detailed description of the same portions will be omitted. As shown in Fig. 12, in the first shutter 20 of the present embodiment, one opening portion 22 is formed to penetrate through the shutter body 21. As in the first embodiment, the opening portion 22 has a circular shape whose inner diameter is formed to be slightly larger than the diameter of the target 13. Therefore, in the present embodiment, when sputtering is performed, one target 13 is exposed to the film formation space 2S via the opening portion 22. The thirteenth (a) diagram shows a state in which the first shutter 20 and the second shutter 30 are disposed at the reference position. The first shutter 20 disposed at this position exposes the first target 13A in the film forming space 2S via the opening 22. The first barrier portion 36 of the second gate 30 faces the first target 13A. The pattern of the thirteenth (a) diagram is effective only when the film formation is performed by, for example, the first target 13A composed of Ni. Further, in the present embodiment, although the first barrier portion 36 faces the first target 13A, the second barrier portion 37 may face the first target 13A in accordance with the film thickness distribution of the target. The thirteenth (b) diagram shows a state in which the first shutter 20 is rotated by 120° from the reference position and the second shutter 30 is placed at the reference position. The first shutter 20 disposed at this position exposes the third target 13C in the film forming space 2S via the opening 22. The second barrier portion 37 of the second gate 30 faces the third target 13C. Using only a third target consisting, for example, of MgO

28 201224185 13C進行成膜時,第十三(b)圖的配置模式是有效的。 又,在本實施形態,雖然使第二屏障部37面對第三靶 13C,但對應靶的膜厚分佈,也可以使第一屏障部36 面對第三靶13C。 第十三(c)圖表示使第一閘門20從基準位置旋轉 240°,將第二閘門30配置在基準位置的狀態。此位置 所配置的第一閘門20,經由開口部22,使第二靶13B 在成膜空間2S露出。開口部34面對於該第二靶13B。 僅用例如由Co所組成的第二靶13B進行成膜時,第十 三(c)圖的配置模式是有效的。 因此,根據第二實施形態,除了第一實施形態所記 載的效果,還可以得到以下的效果。 (4)在第二實施形態,將在第一閘門20所形成的 開口部22做為一個,在濺鍍進行時,用一個靶13來進 行成膜。又,在第二閘門30,設有適合複數個靶13的 屏障部36、37以及開口部34。因此,即使在使一個靶 13選擇性地暴露並進行成膜的狀況,由於可以適用適 合該靶13的入射控制部30A〜30C,所以不會妨礙成膜 步驟的自由度,可以力求膜厚以及組成的均勻化。 [第三實施开i態] 接下來,根據第十四圖說明將本發明具體化的第三 實施形態。又,第三實施形態,是僅變更第一實施形態 的閘門機構Μ的結構,所以關於同樣的部分省略掉其 詳細說明。 在本實施形態的濺鍍裝置1,設有兩個靶13Α、28 201224185 13C When the film formation is performed, the configuration mode of the thirteenth (b) diagram is valid. Further, in the present embodiment, the second barrier portion 37 faces the third target 13C, but the first barrier portion 36 may face the third target 13C in accordance with the film thickness distribution of the target. The thirteenth (c) diagram shows a state in which the first shutter 20 is rotated by 240° from the reference position and the second shutter 30 is placed at the reference position. The first shutter 20 disposed at this position exposes the second target 13B in the film forming space 2S via the opening 22. The opening portion 34 faces the second target 13B. The arrangement pattern of the thirteenth (c) diagram is effective only when the film formation is performed by, for example, the second target 13B composed of Co. Therefore, according to the second embodiment, in addition to the effects described in the first embodiment, the following effects can be obtained. (4) In the second embodiment, the opening 22 formed in the first shutter 20 is formed as one, and when the sputtering is performed, the film is formed by using one target 13. Further, in the second shutter 30, barrier portions 36, 37 and openings 34 suitable for a plurality of targets 13 are provided. Therefore, even in the case where one target 13 is selectively exposed and formed into a film, since the incident control portions 30A to 30C suitable for the target 13 can be applied, the degree of freedom of the film forming step is not hindered, and the film thickness and the film thickness can be obtained. Homogenization of the composition. [Third Embodiment] Next, a third embodiment of the present invention will be described based on the fourteenth embodiment. Further, in the third embodiment, only the configuration of the shutter mechanism 第一 of the first embodiment is changed. Therefore, the detailed description of the same portions will be omitted. In the sputtering apparatus 1 of the present embodiment, two targets 13 are provided,

S 29 201224185 13B,閘門機構μ具有一閘門40。閘門40與上述實施 形態一樣’被連接於驅動馬達23的驅動軸24,被構成 為相對於被固定在腔室2的陰極1〇的把13轉動。 閘門40在其閘門本體41設有兩個入射控制部 50Α、50Β。入射控制部5〇Α、50Β分別具備開口部51、 52。第一入射控制部5〇α具備環狀的屏障部53,屏障 部53被設於開口部51的外周。第二入射控制部5〇β僅 具備開口部52。在此開口部52的外周並未設有環狀的 屏障部。又,開口部51、52與上述實施形態的開口部 33、34是同樣的結構。 在濺鍍時,閘門40被旋轉,兩個靶13經由開口部 52、53被暴露在成膜空間2S。靶13Α為例如Ni,在基 板外周部S2是使臈厚變小的材質的狀况,罝有屏障部 =的第一入射控制部50A面向靶13A。靶別為例二 Co,即使在沒有屏障部的狀態下,相對的财變成 =的狀況’沒有屏障部的第二人射控制部观面向& :,根據第三實施形態’除了第—實施形態所記 載的(1)以及(2)的效果,還可以得到以下的效果。 (5)在上述實施形態,閘門機構Μ是由一片閘 40所構成,在該閘門4〇,設有:具有屏障部兄的第一 入射控制部50Α與沒有屏障部的第二入射控制部5〇β。 因此’以一片閘門40在每靶均勻化膜厚分佈,所以會 提升在基板S所形成的薄膜膜厚的面内均句性,並可以 提升同一層内的薄膜級成的均勻性。 30 201224185 又,上述各實施形態也可以變更如下。 •在上述實施形態,複數個入射控制部包含環狀屏 障部36、37與開口部34。複數個入射控制部對應開口 部33〜35的周圍壁部的高度(也包含高度為零),具有 不同的遮蔽部。入射控制部的壁部也可以是其他形狀。 例如環狀,而且也可以是隨著從靶侧向著基板側,其内 徑會變小的尖細形狀。或者是,環狀部件的内側,也可 以設有準直儀(collimator) ’該準直儀在靠近基板s的 中心軸X4處具有分隔板’在遠離中心軸處不設有 準直儀,藉由使準直儀通過,使到達基板外周部S2的 濺鍍粒子數減少。重要的是遮蔽度高的入射控制部只要 疋使到達基板外周部S2的濺鍵粒子數減少的形狀就 行。 •在第一實施形態’屏障部36、37彼此有不同高 度’但依輕13的材質,屏障部3 6、3 7彼此也可以形成 為相同高度。 •在上述實施形態’在各屏障部36、37的壁部高 度為固定。但沿著對應各屏障部的開口部的周方向連續 的壁部高度也可以不同。在此狀況,可以提高壁部的一 部分’降低其他部分’使到達基板外周部S2的濺鑛粒 子數減少。 •在上述實施形態,將濺鍍裝置具體化成磁控濺鍍 裝置’但也可以具體化成ECR ( Electron Cyclotron Resonance)濺鍍裝置。即使在具體化成此裝置的狀況, 對應乾所對應的膜厚分佈的傾向,妨礙向著欲將膜厚變 201224185 小的區域的濺鍍粒子的飛行的屏障部,被設有成面對該 把。 【圖式簡單說明】 第一圖:满:鐘裝置的概略剖面圖。 第二圖:表示乾的配置的概略圖。 第三圖:閘門機構的分解斜視圖。 第四圖:第一閘門的下面圖。 第五圖:第二閘門的下面圖。 第六圖:乾以及第一遮蔽部的剖面圖。 第七圖:靶以及第二遮蔽部的剖面圖。 第八圖:把及開口部的剖面圖。 第九圖.(a)〜(e)是表示第一及第二閘門的配置模 式的概略圖。 第十圖.(a)〜(c)是表示第一及第二閘門的配置模 式的概略圖。 =十圖.(a)〜(c)是表示第一及第二閘門的配置 模式的概略圖。 ^十=圖:第二實施形態的閘門機構的分解斜視圖。 二十二圖:(a)〜(c)是表示第一及第二閘門的配置 模式的概略圖。 =十四圖.變形例的濺鍍裝置的概略剖面圖。 第十五圖:表示不同材質的靶的膜厚分佈的曲線圖。 【主要元件符號說明】 32 201224185 1濺鍍裝置 2腔室 2a腔室本體 2b上壁部 2c底壁部 2d排氣口 2e氣體導入口 2S成膜空間 4基板爽 5、 24驅動轴 6、 23驅動馬達 7、 25傳達機構 8防附著板 9氣體供給機構 10陰極 10A〜10C陰極 11背板 12地屏障 12a收容部 13、13A〜13C 靶 13a被藏鑛面 14磁裝置 15磁迴路 20、30、40 閘門 20a、30a 下面 33 201224185 21、 31、41閘門本體 簷部 21a、31a 22、 33〜35、51、52 開口部 30A〜30C、50A、50B入射控制部 36、37、53屏障部 36u下面 36P 開口 37u下面 37P 開口 G外部電源 HI、H2 長 LI、L2直線 Μ閘門機構 PC1 〜PC3、PC5、PC6、PC9〜PC11 中心點 PC4、PC8 頂點S 29 201224185 13B, the shutter mechanism μ has a gate 40. The shutter 40 is connected to the drive shaft 24 of the drive motor 23 in the same manner as the above-described embodiment, and is configured to rotate with respect to the handle 13 fixed to the cathode 1 of the chamber 2. The shutter 40 is provided with two incident control portions 50A, 50A in its shutter body 41. The incident control units 5A and 50B are provided with openings 51 and 52, respectively. The first incident control unit 5A includes an annular barrier portion 53, and the barrier portion 53 is provided on the outer circumference of the opening 51. The second incident control unit 5〇β only includes the opening 52. An annular barrier portion is not provided on the outer circumference of the opening portion 52. Further, the openings 51 and 52 have the same configuration as the openings 33 and 34 of the above-described embodiment. At the time of sputtering, the shutter 40 is rotated, and the two targets 13 are exposed to the film forming space 2S via the openings 52, 53. The target 13A is, for example, Ni, and the outer peripheral portion S2 of the substrate is a material having a reduced thickness, and the first incident control unit 50A having the barrier portion is facing the target 13A. The target is the second example, Co, even in the state where there is no barrier, the situation in which the relative wealth becomes = 'the second person-injection control unit that does not have the barrier portion faces &:, according to the third embodiment, except for the first embodiment The effects of (1) and (2) described in the form can also provide the following effects. (5) In the above embodiment, the shutter mechanism 构成 is constituted by a single gate 40. The gate 4 is provided with a first incident control unit 50 having a barrier portion and a second incident control portion 5 having no barrier portion. 〇β. Therefore, the thickness distribution of the film thickness is uniformed for each target by the one gate 40, so that the in-plane uniformity of the film thickness formed on the substrate S is improved, and the uniformity of the film formation in the same layer can be improved. 30 201224185 Further, the above embodiments may be modified as follows. In the above embodiment, the plurality of incident control units include the annular barrier portions 36 and 37 and the opening portion 34. The plurality of incident control portions have different heights (including the height of zero) corresponding to the peripheral wall portions of the opening portions 33 to 35, and have different shielding portions. The wall portion of the incident control portion may have other shapes. For example, the ring shape may be a tapered shape in which the inner diameter thereof becomes smaller as it goes from the target side toward the substrate side. Alternatively, a collimator may be provided on the inner side of the annular member. 'The collimator has a partition plate near the central axis X4 of the substrate s'. There is no collimator at a distance from the central axis. By passing the collimator, the number of sputtered particles reaching the outer peripheral portion S2 of the substrate is reduced. It is important that the incident control unit having a high degree of shielding has a shape in which the number of splash-bonded particles reaching the outer peripheral portion S2 of the substrate is reduced. In the first embodiment, the barrier portions 36 and 37 have different heights, but the materials of the light portions 13 are lighter, and the barrier portions 36 and 37 may be formed at the same height. In the above embodiment, the wall portions of the respective barrier portions 36 and 37 are fixed in height. However, the height of the wall portion continuous along the circumferential direction of the opening corresponding to each barrier portion may be different. In this case, it is possible to increase a portion of the wall portion "reducing the other portion" to reduce the number of splash particles reaching the outer peripheral portion S2 of the substrate. In the above embodiment, the sputtering apparatus is embodied as a magnetron sputtering apparatus, but it may be embodied as an ECR (electron Cyclotron Resonance) sputtering apparatus. Even in the case where the device is embodied, the barrier layer corresponding to the film thickness distribution corresponding to the dryness is prevented from interfering with the movement of the sputtering particles in the region where the film thickness is reduced to 201224185. [Simple description of the diagram] The first picture: full section: a schematic sectional view of the clock device. Second figure: A schematic diagram showing the dry configuration. Figure 3: Exploded oblique view of the gate mechanism. Fourth picture: The following picture of the first gate. Fifth picture: The following picture of the second gate. Figure 6: Sectional view of the stem and the first shield. Figure 7 is a cross-sectional view of the target and the second shield. Figure 8: Sectional view of the handle and the opening. Fig. 9(a) to (e) are schematic diagrams showing arrangement patterns of the first and second shutters. Fig. 10(a) to (c) are schematic diagrams showing the arrangement patterns of the first and second shutters. = Fig. (a) to (c) are schematic diagrams showing the arrangement patterns of the first and second gates. ^10 = Diagram: An exploded perspective view of the shutter mechanism of the second embodiment. Twenty-two diagrams: (a) to (c) are schematic diagrams showing the arrangement patterns of the first and second gates. = fourteenth. A schematic cross-sectional view of a sputtering apparatus according to a modification. Figure 15: A graph showing the film thickness distribution of targets of different materials. [Main component symbol description] 32 201224185 1 Sputtering device 2 chamber 2a Chamber body 2b Upper wall portion 2c Bottom wall portion 2d Exhaust port 2e Gas introduction port 2S Film forming space 4 Substrate cool 5, 24 Drive shaft 6, 23 Drive motor 7, 25 transmission mechanism 8 anti-adhesion plate 9 gas supply mechanism 10 cathode 10A to 10C cathode 11 back plate 12 barrier 12a accommodating portion 13, 13A to 13C target 13a is deposited surface 14 magnetic device 15 magnetic circuit 20, 30 40 gates 20a and 30a 33 below 201224185 21, 31, 41 gate body jaws 21a, 31a 22, 33 to 35, 51, 52 Openings 30A to 30C, 50A, 50B are incident control portions 36, 37, 53 barrier portion 36u Below 36P opening 37u below 37P opening G external power supply HI, H2 long LI, L2 linear Μ gate mechanism PC1 ~ PC3, PC5, PC6, PC9 ~ PC11 center point PC4, PC8 apex

Pld、Pk2、Pk3 基準點 R1、R2環狀執跡 S基板 S1表面 S2基板外周部 SP1、SP2、SP3粒子執跡 XI靶軸線 X2中心轴線 X4中心軸 α角度Pld, Pk2, Pk3 Reference points R1, R2 ring-shaped S-substrate S1 surface S2 substrate outer peripheral portion SP1, SP2, SP3 particle tracking XI target axis X2 central axis X4 central axis α angle

34 201224185 0 ini、Θ in2入射角 △ W1、△ W2 寬度 s: 3534 201224185 0 ini, Θ in2 incident angle △ W1, △ W2 width s: 35

Claims (1)

201224185 七 申請專利範圍: 1. 一種濺鍍裝置,具備複數個靶,在成膜空間所配置 的基板形成薄膜,其特徵在於:具備閘門機構,該閘 門機構配置在前述複數個靶與成膜空間之間, 前述閘門機構,具有開口部,該開口部使前述 複數個靶中的選擇靶露出於前述成膜空間, 前述閘門機構具備:複數個入射控制部,控制 從前述選擇靶釋放並前往基板外周部的濺鍍粒子 數,該複數個入射控制部,對於濺鍍粒子具有複數個 遮蔽度, 對應在前述成膜空間被暴露的前述選擇粗被單 獨濺鍍時的膜厚分佈,從前述複數個入射控制部中, 將適合該選擇靶的入身f控制部運用在該選擇靶。 2. 如申請專利範圍第1項所述的濺鍍裝置,其中前述 複數個入射控制部,對應在前述複數個靶的外側所配 製的壁部高度,具有不同的遮蔽度。 3. 如申請專利範圍第1項所述的濺鍍裝置,其中前述 閘門機構的前述複數個入射控制部,包含: 入射控制部,具有在前述選擇靶的被濺鍍面的 外周所設有的壁部;以及 入射控制部,僅由開口所組成,該開口可暴露 前述選擇靶的被濺鍍面。 4. 如申請專利範圍第1項所述的濺鍍裝置,其中前述 閘門機構,具備: 第一閘門,具有比前述複數個靶的數量少的開 口部,對於前述複數個靶可旋轉地被設有,前述選擇 靶是經由前述第一閘門的前述開口部,在前述成膜空 36 201224185 間選擇性地被暴露的靶;以及 第二閘門,被設於比該第一閘門靠近前述基板 '的位置,具有前述複數個入射控制部,使適合藉由前 述第一閘門被選擇性地露出的前述選擇靶的入射控 制部,面對該選擇靶。 5. 如申請專利範圍第1項所述的濺鍍裝置,其中前述 複數個入射控制部中,具有相對大的遮蔽度的入射控 制部,具有壁部,該壁部妨礙從前述選擇靶的被濺鍍 面釋放並前往前述基板外周部的丨賤艘粒子, 前述選擇靶是一材質,使得在該靶單體濺鍍時 形成的薄膜在基板外周部的膜厚比基板中央部大,在 此狀況,對於該選擇靶,適用具有前述相對大的遮蔽 度的前述入射控制部。 6. 如申請專利範圍第1項所述的濺鍍裝置,其中前述 閘門機構,包含可在前述成膜空間内旋轉的圓蓋 (dome)狀部材, 前述複數個入射控制部,具備: 第一入射控制部,包含:第一開口部,被形成 於前述圓蓋狀部材;以及第一遮蔽部,包圍前述第一 開口部,該第一遮蔽部從前述圓蓋狀部材向著前述基 板僅以第一高度突出;以及 第二入射控制部,包含第二開口部,該第二開 口部,未被向著前述基板突出的遮蔽部包圍,被形成 在前述圓蓋狀部材, 前述濺鍍裝置,更具備使前述圓蓋狀部材旋轉的驅動 馬達, 前述驅動馬達,使前述圓蓋狀部材旋轉,使得 S. 37 201224185 在前述複數個入射控制部的前述開口部中,經由對應 前述選擇靶的材質所選擇的開口部,暴露該選擇靶。 7. 如申請專利範圍第6項所述的濺鍍裝置,其中前述 複數個入射控制部,更包含第三入射控制部,該第三 入射控制部包含: 第三開口部,被形成在前述圓蓋狀部材;以及 第二遮蔽部,包圍前述第三開口部,從前述圓 蓋狀部材向著前述基板僅以不同於前述第一高度的 第二高度突出。 8. 如申請專利範圍第6項所述的濺鍍裝置,其中前述 第一遮蔽部,是包圍前述第一開口部的環狀壁部。201224185 Seven patent application scope: 1. A sputtering apparatus having a plurality of targets and forming a film on a substrate disposed in a film forming space, characterized in that: a gate mechanism is provided, and the gate mechanism is disposed in the plurality of targets and film forming spaces. The shutter mechanism has an opening that exposes a selected one of the plurality of targets to the film forming space, and the shutter mechanism includes a plurality of incident control units that control release from the selected target and proceed to the substrate The number of the sputter particles in the outer peripheral portion, the plurality of incident control portions having a plurality of shielding degrees for the sputtered particles, and the film thickness distribution when the selected rough portion exposed to the film forming space is separately sputtered, from the plural Among the incident control units, an in-fuse control unit suitable for the selection target is applied to the selection target. 2. The sputtering apparatus according to claim 1, wherein the plurality of incident control units have different shielding levels corresponding to heights of the wall portions disposed outside the plurality of targets. 3. The sputtering apparatus according to claim 1, wherein the plurality of incident control units of the shutter mechanism include: an incident control unit having an outer circumference of the sputtered surface of the selective target; The wall portion; and the incident control portion are composed only of openings that expose the sputtered surface of the selected target. 4. The sputtering apparatus according to claim 1, wherein the shutter mechanism includes: a first gate having an opening smaller than a number of the plurality of targets; and the plurality of targets are rotatably provided The selected target is a target selectively exposed between the film forming spaces 36 201224185 via the opening portion of the first gate; and the second gate is disposed closer to the substrate than the first gate The position includes the plurality of incident control units, and the incident control unit suitable for the selective target selectively exposed by the first shutter faces the selective target. 5. The sputtering apparatus according to claim 1, wherein the plurality of incident control units have an incident control unit having a relatively large shielding degree, and have a wall portion that hinders the selection of the target from the selection target The sputtered surface is released and travels to the outer peripheral portion of the substrate, and the selected target is a material such that a film formed at the time of sputtering of the target monomer has a larger film thickness at a peripheral portion of the substrate than a central portion of the substrate. In the case of the selected target, the incident control unit having the relatively large degree of shielding described above is applied. 6. The sputtering apparatus according to claim 1, wherein the shutter mechanism includes a dome-shaped member rotatable in the film formation space, and the plurality of incident control units include: The incident control unit includes a first opening formed on the dome-shaped member, and a first shielding portion surrounding the first opening, the first shielding portion being oriented only from the dome-shaped member toward the substrate The second incident control unit includes a second opening that is not surrounded by the shielding portion that protrudes toward the substrate, and is formed in the dome-shaped member, and the sputtering device further includes a drive motor that rotates the dome-shaped member, and the drive motor rotates the dome-shaped member so that S. 37 201224185 selects a material corresponding to the selection target in the opening of the plurality of incident control portions The opening portion exposes the selected target. 7. The sputtering apparatus according to claim 6, wherein the plurality of incident control units further includes a third incident control unit, wherein the third incident control unit includes: a third opening portion formed in the circle The lid-shaped member and the second shielding portion surround the third opening, and protrude from the dome-shaped member toward the substrate at a second height different from the first height. 8. The sputtering apparatus according to claim 6, wherein the first shielding portion is an annular wall portion surrounding the first opening. 3838
TW100132540A 2010-09-10 2011-09-09 Sputtering apparatus TW201224185A (en)

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TWI778947B (en) * 2015-12-20 2022-10-01 美商應用材料股份有限公司 Methods and apparatus for processing a substrate

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