201221639 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種硬質表面用液體清潔劑組合物。 【先前技術】 一般而言，作為硬質表面用之清潔劑，為了去除浴室、 厨房、地板等處理對象之不同污垢，而使用適合各自之組 成者。例如作為爐灶、烤箱、爐灶周圍之牆壁或地板、換 氣扇等廚房周圍所使用之廚房周圍用清潔劑，為了去除因 熱、曰光、空氣中之氧氣等之作用而變質之油污，目前使 用含有界面活性劑、溶劑及鹼劑等之清潔劑。又，作為浴 池、浴室之牆壁及地板等浴室所使用之浴室用清潔劑，為 了去除金屬4、尤其是脂肪酸之⑪鹽之污垢，目前使用含 有界面活性劑、溶劑、金屑離子螯合劑等之清潔劑。 該等巧'㈣巾’厨房所制之清潔#!剌於爐灶周圍之 牆壁或烹#台等之硬質表面之—部分。應用於硬質表面 後，使用毛巾或海綿等用具於大範圍塗抹開，同時去除油 或灰塵等污垢。由曰常之烹#作業所產生之油煙附著於爐 圍之牆壁或烹#台等之硬質表面上，多數之該等污垢 纟後以成乎不受由氧化或熱引起之改性影響的狀 〜^在4 了去除此種烹每油污，需要利用界面活性劑之 可洛化力:戈乳化力、溶劑之溶解力或膨潤力等，作為溶劑 :(厌數為2〜4) 一醇之單燒（碳數為4〜叫、尤其是烷 土反數為4〜8之一丙二醇之單院基越於上述改性度較低 之咖由污之除去性方面優異，業界期待調配有其之清潔 I59213.doc 201221639 。由於單獨之上述溶劑不溶於水，故而若無界面活性 ，則會成為兩層分離系，使用非常不便。 專利文獻1中揭示有含有二丙二醇單頂作為二醇系溶 d的對頑©之改性油污顯示出優異之清潔力的硬表面用主 潔劑組合物，但關於改性度較低之烹佐油污之除: 任何提示。 … 專利文獻2中揭示有含有作為二醇系溶劑之二丙二醇單 丁醚、界面活性劑之空調翅片用液體清潔劑組合物。但 是’並未提示對廚房中產生之油污之清潔效果或作業容易 性。 專利文獻3中揭示有含有、陰離子界面活性劑、作為疏 水性洛劑之二丙二醇單丁 Μ、非離子界面活性劑之硬質表 面用清潔劑組合物’但關於改性度較低之烹飪油污之除去 性方面並無任何提示。 專利文獻4中才焉示有|有丁氧基丙氧基丙醇等溶劑而成 之相穩定性液體織物復原組合物，但關於改性度較低之亨 飪油污之除去性方面並無任何提示。 先前技術文獻 專利文獻 專利文獻1:曰本專利特開2008-45108號 專利文獻2 :曰本專利特開2000-290699號 專利文獻3:日本專利特開|〇93/〇4151號 專利文獻4 :曰本專利特開平11-511 800號 【發明内容】 I59213.doc 201221639 解決問題之技術手段 本發明者進行努力研究，結果發現：於如下組合物中， 形成無混濁或分離之均勻液相，並且對油污之清潔力或洗 劑之擦除性優異，尤其是對改性度較低之烹飪油污發揮優 異之清潔性，從而完成本發明，該組合物含有下述式（al) 所表示之聚烷二醇之單烷基醚[(a)成分）]、氧化胺[(1))成 分]、及選自碳數為8〜18之脂肪酸及其鹽中之一種以上之 界面活性劑[(c)成分](其中，（c)成分中之鹽之質量於以下 之說明書中係換算為酸形態之質量）作為必須成分，並且 (c)成分/((b)成分+(c)成分）之質量比為〇 〇〇1/1〜ιη，（幻成 分之60〜1〇〇質量％為二丙二醇之單烷基（碳數為4〜8)醚[(a_ 1)成分]。201221639 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a liquid detergent composition for a hard surface. [Prior Art] In general, as a cleaning agent for a hard surface, in order to remove different dirt of a treatment object such as a bathroom, a kitchen, or a floor, a component suitable for each component is used. For example, as a stove, an oven, a wall or floor around a stove, a ventilator, etc., a cleaning agent is used around the kitchen, and in order to remove oil stains that are deteriorated by heat, sunlight, oxygen in the air, etc., the interface is currently used. A cleaning agent for active agents, solvents and alkaline agents. In addition, as a detergent for bathroom used in bathrooms such as baths, bathroom walls, and floors, in order to remove the dirt of the metal 4, especially the fatty acid 11 salt, a surfactant, a solvent, a gold ion ion chelating agent, or the like is currently used. detergent. The cleaning made by the kitchen is made of the hard surface of the wall around the stove or the cooking table. After application to a hard surface, use a towel or sponge to spread it over a wide area while removing dirt such as oil or dust. The fumes produced by the cooking of the 之 cooking are attached to the hard surface of the wall of the furnace or the cooking table, etc., and most of the dirt is not affected by the modification caused by oxidation or heat. ~^ In 4 to remove this cooking oil, you need to use the surfactant can be used: the emulsifying power, the solvent's solubility or swelling power, as a solvent: (the number of disgusts is 2~4) Single-burning (the number of carbon atoms is 4~, especially the single-base of the one-way propylene glycol with a reciprocal number of 4 to 8 is superior to the above-mentioned degree of modification, and the industry is expected to have a blending effect. Cleaning I59213.doc 201221639. Since the above solvent alone is insoluble in water, if it has no interfacial activity, it becomes a two-layer separation system, which is very inconvenient to use. Patent Document 1 discloses that a dipropylene glycol monotope is included as a glycol solution. The hard-surface main detergent composition exhibiting excellent cleaning power of the modified oil stain of d, but the removal of the oil stain with lower modification degree: any suggestion. Dipropylene glycol monobutyl ether as a glycol solvent A liquid detergent composition for air-conditioning fins of a surfactant, but 'does not suggest a cleaning effect or workability for oil stains generated in the kitchen. Patent Document 3 discloses that it contains an anionic surfactant as a hydrophobic agent. The dipropylene glycol monobutyl hydrazine and the non-ionic surfactant hard surface cleaning agent composition 'but there is no suggestion regarding the removal property of the cooking oil having a low degree of modification. Patent Document 4 shows that there is | A phase-stable liquid fabric reconstituting composition having a solvent such as butoxypropoxypropanol, but there is no suggestion regarding the removability of the koji oil having a low degree of modification. PRIOR ART DOCUMENTS Patent Literature Patent Literature Patent Document No. 2008-45108 Patent Document 2: Japanese Patent Laid-Open No. 2000-290699 Patent Document 3: Japanese Patent Laid-Open No. 〇93/〇4151 Patent Document 4: 曰本专利专开平11- 511 800 [Contents of the Invention] I59213.doc 201221639 Technical Solution to Problem The present inventors conducted an effort to find that a uniform liquid having no turbidity or separation was formed in the following composition. And the cleaning property of the oil stain or the erasability of the lotion is excellent, and in particular, the cleaning property of the cooking oil having a low degree of modification is excellent, thereby completing the present invention, and the composition contains the following formula (al) a monoalkyl ether of the polyalkylene glycol [(a) component], an amine oxide [(1)) component], and a surfactant selected from one or more of a fatty acid having a carbon number of 8 to 18 and a salt thereof [(c) component] (wherein the mass of the salt in the component (c) is converted into the mass of the acid form in the following description) as an essential component, and (c) component / ((b) component + (c) The mass ratio of the component is 〇〇〇1/1 to ηη, (60 to 1% by mass of the magic component is a monoalkyl group (carbon number: 4 to 8) ether [(a-1) component] of dipropylene glycol).
Rla(OR2a)丨 OH (al) [式中R為碳數4〜8之烧基，1為1〜4之數，R2a為碳數2-4 之伸烷基] 本發明提供一種調配有伸烷基之碳數為2〜4且烷基之碳 :為4 8之聚烷二醇之單烷基醚的對烹飪油污具有優異之 力之硬質表面用之清潔劑組合物，其可利用儘可能少 量之界面活性劑而形成均勻液體組合物。 進而本务明提供一種烹备油污之清潔性優異形成無 混濁或分離之均勾液相，並且作為清潔步驟之一部分之洗 - 7驟十之作業性變得簡便的硬質表面用液體清潔 劑組合物。 進而I發明尤其提供一種對改性度較低之烹飪油污發 159213.doc 201221639 揮出優異之清潔性之硬質表面用液體清潔劑組合物。 本發明之硬質表面用液體清潔劑組合物具有如下效果·· 不僅對文飪油污具有較高之清潔力，而且以無混濁或分離 之均勻液相之形式存在，發揮出洗劑之優異之擦除性或優 中洗〖生本發明之硬質表面用液體清潔劑組合物可應 用於各種硬質表面，尤其適宜於廚房周圍之硬f表面，因 而適合作為廚房用液體清潔劑組合物。由於本發明之硬質 表面用液體清潔劑組合物對改性度較低之油污發揮出優異 月潔性故而可較佳地應用於大量存在此種油污之廚房 周圍之硬質表面。再者，於本說明書卜組合物「以均勻 液相之形式存在」之狀態係指撥掉組合考勿，並於室溫（例 如抑）下靜置！小時後，目測未確認到混濁或分離之狀 態。 【實施方式】 本發明之硬質表面用液體清潔劑組合物含有下述式(a 1) 二表不之聚烷—醇之單烷基醚作為⑷成分。就對油污之清 :與保存穩疋性之觀點而言，尤其就清潔力之觀點而 里較佳為本發明之組合物之1~15質量？ 更佳為1.5〜8質景〇/ft，、社^ Α 進而較佳為2〜6質量。/。。就對油μ f潔力之觀點而言，較佳為工質量。/。以上，更佳為丄·” =上’進而較佳為2質量％以上，就保存穩定性之觀f 吕’較佳為1 5質量％ w π ^ 置。以下，更佳為8質量％以下，進而幸 為6質量。/。以下。作 马式（al)中之Ru，就對油污之清g 保存穩定性之觀點一 規點而s ，可列舉：丁基、異丁基、 159213.doc 201221639 基、2-乙基己基等，較佳為丁基及己纟，更佳為丁基。作 為式（al)中之R2a’就對油污之清潔力與保存穩定性之觀點 而言，較佳為伸乙基、伸丙基、伸丁基，更佳為伸丙基。 進而，就對油污之清潔力與保存穩定性之觀點而言，U 1〜4之數，更佳為2〜3之數，進而較佳為2之數。 Rla(OR2a),OH (αΐ) ’ 1為1〜4之數，R2a為碳數 [式中，1113為碳數為4〜8之烷基 為2〜4之伸烷基] 進而’作為⑷成分，㈣二丙二醇之烧基碳數為4〜8之 早烧基㈣H亏之清潔力與保存穩定性之觀點而言較 佳，更佳為二丙二醇單丁越、二丙二醇單異丁趟、二丙二 醇單己I二丙二醇單（2_乙基己基）㈣，進而較佳為二: -醇早頂、二丙二醇單異丁驗、二丙二醇單己趟，進而 更佳為—丙 <一醇单丁 Si® $ - 1¾ - 1 H一丙—醇早己醚’尤佳為二丙二 醇單丁縫。作為⑷成分，可為單獨之化合物，亦可為㈣ 種化合物之混合物，就對油污之清潔力之觀點而 分中之㈤)成分為60〜100質量％，較佳為80〜 更佳為90〜100質量％，進而較佳為1〇〇質量％。 置。’ 本發明之硬質表面用液體清潔劑組合物含有 二成分。⑻成分之含量較佳為本發明之組合J: M，更佳為CU〜5„%，進而較佳為 15 進而更佳為1〜2質量％。钟徂六趙A 貝里/〇， 為"5質量。/以上 穩定性之觀點而言，較佳 “加上，進而更佳為】質量％«上，就於清為= 159213.doc 201221639 成殘留性之觀點而言，較佳為15質量％以下，更佳為5 質里以下進而車父佳為3.5質量％以下，進而更佳為2質 量％以下。 作為⑷成分與（b)成分及下述⑷成分之合計量的質量 比，較佳為⑷/((b)+(c))=1/1〜15/1，更佳為ι ，進 而較佳為1.2/1〜3/1。就對油污之清潔力之觀點而言，較佳 為1/1U上，更佳為丨m以上，進而較佳為丨以丨以上，就 高溫保存穩定性之觀點而言較佳為15/1以下，更佳為％以 下，進而較佳為3/1。 作為（b)成分之氧化胺，例如可列舉以下者。 就對油污之清潔力之觀點而言，可列舉：具有碳數為 8〜18之烴基，較佳為直鏈或支鏈之烷基或烯基，較佳為烷 基的烷基或烯基氧化胺《作為更佳之氧化胺，可列舉下述 通式（bl)所表示之烷基或烯基氧化胺。 [化1] R2bRla(OR2a)丨OH (al) [wherein R is a carbon number 4 to 8 alkyl group, 1 is a number of 1 to 4, and R 2a is a carbon number of 2 to 4 alkyl groups]. The present invention provides a blending extension. A carbonaceous carbon group having a carbon number of 2 to 4 and an alkyl group: a monoalkyl ether of a polyalkylene glycol of 48, which has an excellent force for cooking oil stains, and which can be used up A small amount of surfactant may be present to form a uniform liquid composition. Further, the present invention provides a liquid surface cleaner composition which is excellent in cleanliness of cooking oil to form a liquid phase which is free from turbidity or separation, and which is a part of the cleaning step. Things. Further, the invention of the present invention provides, in particular, a liquid surface cleaner composition for hard surface which imparts excellent cleanliness to a cooking oil having a low degree of modification 159213.doc 201221639. The liquid surface cleaner composition for hard surfaces of the present invention has the following effects: · It not only has a high cleaning power for the oil of the oil, but also exists in the form of a uniform liquid phase free from turbidity or separation, and exhibits excellent rubbing of the lotion. The liquid surface cleaner composition for hard surfaces of the present invention can be applied to various hard surfaces, and is particularly suitable for a hard f surface around a kitchen, and is therefore suitable as a liquid detergent composition for kitchen use. Since the liquid surface cleaner composition for hard surfaces of the present invention exhibits excellent cleanliness for oils having a low degree of modification, it can be preferably applied to a hard surface around a kitchen in which such a large amount of oil is present. Furthermore, in the state in which the composition of the present specification is "in the form of a homogeneous liquid phase", the combination is taken out and allowed to stand at room temperature (for example, inhibition)! After the hour, the state of turbidity or separation was not confirmed by visual observation. [Embodiment] The liquid detergent composition for a hard surface of the present invention contains a monoalkyl ether of a polyalkanol of the following formula (a1) as the component (4). It is better to clear the oil: from the viewpoint of preservation stability, especially from the viewpoint of cleansing power, it is preferably 1 to 15 mass of the composition of the present invention? More preferably, it is 1.5 to 8 mass 〇 / ft, and the body ^ Α is further preferably 2 to 6 mass. /. . In terms of oil μ f clean power, it is preferably a work quality. /. The above is more preferably 丄·”=upper, and further preferably 2% by mass or more, and the storage stability f ′ is preferably 15% by mass w π ^. Hereinafter, more preferably 8% by mass or less. Fortunately, it is 6 mass%. The following is the term "Ru" in the horse type (al), and the viewpoint of the stability of the oil stain g is stable, and s, butyl, isobutyl, 159,213. Doc 201221639, 2-ethylhexyl, etc., preferably butyl and hexanyl, more preferably butyl. As the R2a' in the formula (al), from the viewpoint of the cleaning power and storage stability of the oil stain, Preferably, it is an ethyl group, a propyl group, a butyl group, and more preferably a propyl group. Further, in terms of the cleaning power and storage stability of the oil, the number of U 1 to 4 is more preferably 2 The number of 〜3, and further preferably the number of 2. Rla(OR2a), OH(αΐ) '1 is a number from 1 to 4, and R2a is a carbon number [wherein, 1113 is an alkyl group having a carbon number of 4 to 8 It is preferably 2 to 4, and further preferably, as the component (4), (4) dipropylene glycol, the alkyl group having a carbon number of 4 to 8 is preferably a cleaning power and a storage stability. Dipropylene glycol monobutyl , dipropylene glycol monoisobutyl hydrazine, dipropylene glycol monohexyl I dipropylene glycol mono (2-ethylhexyl) (four), and further preferably two: - alcohol early top, dipropylene glycol monoisobutyl test, dipropylene glycol monohexane, and further More preferably, it is a compound of (4), which may be a single compound or (4) as a component (4). The mixture of the compounds is in the range of 60 to 100% by mass, preferably 80 to more preferably 90 to 100% by mass, and more preferably 1% by mass, based on the viewpoint of the cleaning power of the oil. The liquid cleansing composition for hard surface of the present invention contains two components. The content of the component (8) is preferably the combination J: M of the present invention, more preferably CU 〜 5 „%, and still more preferably 15 and further Good is 1 to 2% by mass. Zhong Rong Liu Zhao A Berry / 〇, for "5 quality. From the viewpoint of the above-mentioned stability, it is preferable that the "additional, and more preferably, the mass %" is preferably 15% by mass or less from the viewpoint of the residue of 129213.doc 201221639. More preferably, it is preferably 5 mass% or less, and more preferably 2 mass% or less. The mass ratio of the total amount of the component (4) to the component (b) and the component (4) described below is preferably (4). / ((b) + (c)) = 1 / 1 to 15 / 1, more preferably ι, further preferably 1.2 / 1 to 3 / 1. From the viewpoint of the cleaning power of the oil, it is preferably In the case of 1/1 U, more preferably 丨m or more, further preferably 丨 丨 or more, and from the viewpoint of high-temperature storage stability, it is preferably 15/1 or less, more preferably % or less, and further preferably 3/. 1. The amine oxide of the component (b) is, for example, the following. The viewpoint of the cleaning power of the oil stain includes a hydrocarbon group having a carbon number of 8 to 18, preferably a linear or branched chain. The alkyl group or the alkenyl group is preferably an alkyl group or an alkenyl amine oxide of an alkyl group. As a more preferable amine oxide, an alkyl group or an alkenyl amine oxide represented by the following formula (bl) can be mentioned. R2b
Rlb-(D)nT(E)n-N-^ O (bl) R3b (式中’ Rlb表示碳數為8〜18之烴基，較佳為表示烷基或缔 基，較佳表示為烧基，尺21)及R3b表示相同或不同之$炭數為 1~3之烧基，D表示-NHC(=〇)-基或-C(=〇)nh-基，E矣- 數為1〜5之伸坑基，m及η表示m=0且n=〇，或m=i且n 159213.doc 201221639 於上述通式⑻）中，π就對油污之清潔力之觀點而言， 為碳數為8~18之烷基或烯基’較佳為碳數為…“之烷 基’更佳為碳數為i2〜M之院基’進而較佳為碳數為以之 坑基。R2b、’為碳數為η之貌基，更佳為碳數 基。 作為通式（bl)所表示之院基或稀基氧化胺之較佳例，就 對油污之清潔力之觀點而言，較佳可列舉烷基（碳數為 8〜18)二烷基（碳數卜3)氧化胺，作為其具體例，例如可列 舉：辛醯基二甲基氧化胺、辛基二甲基氧化胺、月桂基二 甲基氧化胺、肉豆謹基二甲基氧化胺等。$而，月桂醒胺 丙基二甲基氧化胺、肉豆蔻醯胺丙基二甲基氧化胺、棕橺 醯胺丙基二甲基氧化胺等亦包括在較佳例中。進而，月桂 醯胺丙基二甲基氧化胺亦為較佳例。 本發明之硬質表面用液體清潔劑組合物含有選自由碳數 為8〜18之脂肪酸及其鹽所組成之群中之一種以上作為成 分。 (c)成分中之月日肪酸之碳數為8〜18，較佳為12〜18，更佳 為14〜16 。 作為（c)成分中之脂肪酸之具體例，可列舉：辛酸、癸 酸、月桂酸、肉豆蔻酸、棕櫚酸、硬酯酸、油酸、亞麻油 酸、次亞麻油酸等。 作為（C)成分為脂肪酸鹽之情形之抗衡離子，就對油污之 清潔力之方面而言，適宜為鈉、鉀、鎂、鈣、烷醇胺、 銨，較佳為鈉、鉀、烷醇胺。因此，作為脂肪酸鹽之較佳 159213.doc 201221639 具體例’可列舉：月桂酸鈉、肉豆謹酸鈉、肉豆寇酸單乙 醇胺等。 (C)成分之含量於本發明之硬質表面用液體清潔劑組合物 中，宜為0·001〜15質量％，較佳為0.001〜3.5質量％，更佳 為0.005H質量％，達而較佳為〇1〜〇5質量％。就高溫穩定 性及沖洗性之觀點而言為〇 〇〇1質量％以上， 議:更佳為。」質量%以上，就清潔性之觀點二 質里％以下，較佳為3·5質量％以下，更佳為1質量％以下， 進而較佳為0.5質量％以下。 ⑷成分不僅用以使本發明之組合物於使用條件下形成穩 定之均句液相’而且具有提高清潔步驟中之洗劑之沖洗性 之效果H就對油污之清潔力之觀點而言’作為⑷成 刀與⑻成分及⑷成分之合計量的質量比， ⑷/((b)+(c))=0.001/1 〜1Λ ’ 較佳為 〇 〇〇3/ι〜〇 6/1 O.OOSS/POM，更佳為 0.01/1 〜 為 ，更佳為0.03/1〜 ㈣’更佳伽〜〇.33/1，更佳為〇1/1〜〇3/1，進而較佳 為 0.1 7/1 〜0.29/1。 藉由調配⑷成分使組合物之高溫穩定性及沖洗性提高之 原因目前耗尚未明確，以下說明認為可能之_。 作為（b)成分之親水基與水之 要之相互作用的偶極-偶 極作用力隨溫度上升而減小。因此，伴隨溫度上升，⑻成 为具有與水發生層分離之傾向。若如此，則⑻成分無法作 為界面活性劑而使（a)成分可溶化。 但是’由於⑻成分之氧化胺部分之氧為電子吸引性， 】592 J3.doc -10· 201221639 故而認為（b)成分之親水基中之與氧鄰接之氮原子稱帶正 電。因此，認為於（b)成分與具有羧酸部分之（c)成分之間 有較弱之電氣相互作用發揮作用。因此，認為若調配（c)成 分，則（b)成分變得難以發生與水之層分離，（b)成分可作 為界面活性劑而發揮功能，並且可抑制於溫度上升時可產 生之（a)成分及（b)成分與水之分離。 若推測為上述機制，則認為作為（c)成分之特性之一，長 度為可形成混合微膠粒之程度的疏水基之存在較為重要。 該假說係根據如下情況推測：僅含有疏水基之碳數為6以 下之烷基、或碳數為10以下之芳基的羧酸（例如檸檬酸' 丙酸、苯甲酸）及其鹽有作為本發明中之⑷成分之效果較 弱之傾向》 又，（c)成分與自來水中所含有之鈣離子進行相互作用而 八有4泡作用。該效果係對碳數為丨8之脂肪酸或其鹽之 特異性作用，而作為於具有羧基之方面共通之物質的聚氧 乙烯烷基醚羧酸或其鹽、聚氧乙烯醯胺烷基醚羧酸或其鹽 則不“有效果。推測⑷成分與⑷成分及⑻成分密切地進 灯相互作用而有助於組合物之溶液穩定性，若⑷成分因自 " 鈣而自此合微膠粒中失去，則溶液結構迅速地崩 解而變化為低泡性之溶液。 廚房用清潔劑之一般使用法係使用喷霧器、海綿、毛 、 不織布、紙等用具將清潔劑應用於硬質表面， 並利用擦)^ S 4:¾ ΙΤ/ν 。f k用具擦除污垢後，再利用自來水進行沖洗操 作迄今為止之技術係基於清潔性能之觀點研究最佳化， 159213.doc 201221639 未考慮到清潔後之沖洗作堂 較高之清潔性能，：且::：簡便性，術係提供實現 牛二：烕輕清潔後之沖洗作業負擔的更進 一步之價值。 於本發明之硬質表面用液體清潔劑組合物中，就進 提高清潔性能之觀點而言， ’ 化鹼作為⑷成分。作為貌醇胺，了二手私及/或氫救 户乃沉％胺，可列舉：單乙醇胺、二 醇胺、三乙醇胺，就對油污之清潔力之方面而言㈣ 單乙醇胺》本說明蚩申±人广 ^ "之氫氧化鹼係指鹼金屬或鹼土金屬 之虱氧化物。作為氫氧化驗， 鉀等。 J歹彳舉.氫氧化納、氫氧化 為了賦予對油污充分之清潔力，於本發明之硬質表面用 液體清潔劑組合物中，⑷成分之含量較佳為0.01〜20質旦 %，更佳為0.05〜17質量％，更佳為15〜15質量 ： 2〜10質量％，更佳為3〜7質量 尺住馮 進而較佳為5〜6質量％。 作為⑷成分，可為單獨之化合物，亦可為複數種化合物之 混合物。 二本發明之硬質表面用液體清潔劑組合物中，就進一步 “清潔性能之觀點而言，可調配助洗劑成分作為⑷成 分。作為助洗劑成分，可使用下述所列舉之一種或兩種以 (1)氮川三乙酸、亞胺基二乙酸 、乙二胺四乙酸、經乙 ^ 乙二胺五乙酸、乙二醇醚二胺四乙 酉义私乙基亞胺基二乙酸、三乙四胺六乙酸、金龜胺酸等 胺基多乙酸之驗金屬鹽或烧醇胺鹽。 基乙二胺 乙酸 159213.doc 201221639 (2)二甘醇酸、氧雙琥珀酸、m甲基氧基琥珀酸、羧甲 基號拍酸、缓甲基酒石酸、檸檬酸、乳酸、酒石酸、草 西欠蘋果I、葡萄糖酸等有機酸之驗金屬鹽或烧醇胺鹽。 »亥等中較佳為#檬酸、蘋果酸、乙二胺四乙酸、羥乙 基乙一胺二乙酸或該等之鹽。作為鹽之形態，較佳為鈉 鹽、鉀鹽、銨鹽、烷醇胺鹽。 (e)成分於組合物中之含量就對油污之清潔力之方面而 吕，較佳為〇·01〜5質量％，更佳為〇1〜3質量％，進而較佳 為0.2〜1質量％。 於本發明之硬質表面用液體清潔劑組合物中，除上述成 刀以外，亦可調配不損害本發明之目的或效果之範圍之其 他成分。例如可列舉：聚氧乙烯烷基醚、烷基（聚）糖苷等 界面活丨生劑、乙醇、丙醇、甘油、乙二醇、丙二醇、丙二 醇單甲醚、烷基碳數為3〜8之烷基單甘油醚、E〇(ethylene oxide ’裱氧乙烷）平均加成莫耳數為卜5之聚氧乙烯苯醚或 苄峻·#’谷劑，BHT(butylated hydroxytoluene，二丁基經基 曱苯）等抗氧化劑、防菌/防黴劑、及防腐劑。再者，於本 發明之硬質表面用液體清潔劑組合物中，亦可調配聚丙烯 酸及其鹽、烯烴與順丁烯二酸酐之共聚物及其鹽，此外之 曰本專利特開平7_292398號公報之段落〇〇35〜〇〇38所記載 之羧酸系聚合物或磺酸系聚合物等分散劑作為任意成分。 作為聚氧乙烯烷基醚，可列舉以下所示之〇)或（2)者。 (1)聚氧乙烯烷基醚或烯基醚，其中烷基或烯基之平均 石反數就對油污之清潔力之觀點而言為1〇〜18，較佳為 159213.doc •13- 201221639 10〜16，環氧乙烷（以下記為E〇)加成莫耳數平均為丨〜3〇莫 耳’較佳為平均為6〜20 ^作為此種（1)之較佳例，可列舉 烧基之碳數為8〜18之聚氧乙烯直鏈烷基醚。 (2) I氧乙稀烧基苯醚，其中烧基之平均碳數就對油污 之α冬力之觀點而言為6〜12，EO加成莫耳數平均為1〜μ 莫耳。 作為烷基（聚）糖苷，就對油污之清潔力之觀點而言，可 列舉下述通式（b2)所表示之烷基（聚）糖苷。 R4b(〇R5b)xGy (b2) (式中，R4b表示直鏈或支鏈之總碳數為8〜18之烷基、烯基 或烷基苯基，R5b表示碳數為2〜4之伸烷基，g表示碳數為 5〜6之源自還原糖之殘基，χ表示〇〜y表示丨〜5) 於本發明之硬質表面用液體清潔劑組合物中，與上述各 成分一併調配水。水之調配量係以合計成為1〇〇質量氕之 方式而調整之量組合物之剩餘部分為水。作為水之 量，就對油污之清潔力與高溫穩定性之觀點而言，較佳為 組合物之70〜98質量％，更佳為75〜96質量％，進而較佳為 8㈣4質量％。又，本發明之硬質表面用液體清潔劑组合 物於25。(：下之pH值就對油污之清潔力與確保使用時之安全 性之觀點而言為8〜14。為了獲得較高之清潔力，較佳為pH 值為8.5以上，更佳為阳值為9以上，進而較佳為pH值為ι〇 以上’進而更佳為PH值為U以上。另—方面，就確保使用 時之安全性之觀點而言’該pH值較佳為"以下，更佳為 PH值為13以下，更佳為阳值為12以下，進而較佳為pH值 159213.doc 201221639 為11.5以下。即，本發明之硬質表面用液體清潔劑組合物 於25°C下之pH值較佳為8.5〜14，更佳為9〜13 ’進而較佳為 10〜12,進而更佳為u〜n.5 ^ pH值係使用堀場製作所製造 之pH值計D-52S、pH值電極6367-10D而測得者。 本發明之硬質表面用液體清潔劑組合物可藉由適當混人 各成分而製造。 本發明係關於一種以硬質表面作為對象之液體清潔劑組 合物，此處所謂「硬質表面」，意指不論為平面或立體而 保持固定形狀者，只要為可清潔處理者，則硬度之程度並 不受限定。作為該硬質表面，除包括塑膠、橡膠、金屬' 瓷磚、磚、混凝土、水泥、玻璃、木等之地板、階梯、牆 壁等固定物以外，亦可列舉包含此等之各種器械、器具、 用具、傢具、餐具等人所接觸之所有物品。更佳可列舉塑 膠、金屬、玻璃等。 因此，本發明之硬質表面用液體清潔劑組合物可用作廚 房周圍用清潔劑、浴室用清潔劑、地板用清潔劑、餐具用 清潔劑、全自動洗衣機洗滌槽用清潔劑、排水管用清潔 劑、廚房或盥洗室之小物件用清潔劑等，可更佳地用作廚 房周圍用清潔劑。 將本發明之態樣例示如下。 [1]—種硬質表面用液體清潔劑組合物，其含有： (a) 下述式（al)所表示之聚烷二醇之單烷基醚、 (b) 氧化胺、 ⑷選自由碳數為8〜18之脂肪酸及其鹽所組成之群中之一 159213.doc •15- 201221639 種以上0.001〜15質量％、較佳為〇 〇〇1〜3 5質量％、更佳為 0.005〜1質量％、更佳為〇.1〜0.5質量％(其中，為鹽之情形 之質量係換算為酸形態之質量）、及水；並且 ⑷成分/(⑻成分+(c)成分）之質量比為o.ooi/i〜1/〗，⑷ 成分之60〜1〇〇質量。/。、較佳為80〜100質量、更佳為9〇〜1〇〇 質量°/〇、更佳為100質量％為（3_丨）二丙二醇之燒基碳數為 4〜8之單烷基醚； 該硬質表面用液體清潔劑組合物於25°C下之pH值為 8〜14 〇Rlb-(D)nT(E)nN-^O(bl) R3b (wherein Rlb represents a hydrocarbon group having a carbon number of 8 to 18, preferably an alkyl group or a hydrazine group, preferably represented by a calcining group, a ruthenium 21) and R3b represent the same or different calcined groups having a carbon number of 1 to 3, D represents -NHC(=〇)-yl or -C(=〇)nh-group, and E矣-number is 1 to 5 Extending the pit base, m and η represent m=0 and n=〇, or m=i and n 159213.doc 201221639 In the above formula (8)), π is the carbon number for the cleaning power of the oil stain The alkyl group or alkenyl group of 8 to 18 is preferably a carbon number of "the alkyl group" is more preferably a hospital base having a carbon number of i2 to M. Further preferably, the carbon number is a pit group. R2b, ' It is a carbon number base of η, more preferably a carbon number base. As a preferred example of the hospital base or the dilute amine oxide represented by the formula (bl), it is preferred from the viewpoint of the cleaning power of the oil stain. The alkyl group (carbon number: 8 to 18) dialkyl (carbon number 3) amine oxide is exemplified, and specific examples thereof include: octyl dimethyl amine oxide, octyl dimethyl amine oxide, and lauryl Dimethylamine oxide, nutmeg dimethylamine oxide, etc., while laurel aminopropyl dimethyl oxide Amine, myristyl propyl dimethyl amine oxide, palm amide dimethyl dimethyl amine oxide, etc. are also included in the preferred embodiment. Further, lauryl propyl dimethyl amine oxide is also preferred. The hard surface liquid detergent composition of the present invention contains one or more selected from the group consisting of a fatty acid having a carbon number of 8 to 18 and a salt thereof. (c) The carbon of the fatty acid in the component The number is 8 to 18, preferably 12 to 18, more preferably 14 to 16. Specific examples of the fatty acid in the component (c) include caprylic acid, capric acid, lauric acid, myristic acid, palmitic acid, and the like. Stearic acid, oleic acid, linoleic acid, linoleic acid, etc. As the counter ion in the case where the component (C) is a fatty acid salt, it is suitable for sodium, potassium, magnesium, and the like in terms of the cleaning power of the oil stain. Calcium, alkanolamine, ammonium, preferably sodium, potassium, alkanolamine. Therefore, as a fatty acid salt, preferred 159213.doc 201221639 specific examples 'may be lauric sodium, sodium cinnamate, nutmeg Acid monoethanolamine, etc. The content of the component (C) is the liquid surface cleaner group for hard surfaces of the present invention. It is preferably from 0.001 to 15% by mass, preferably from 0.001 to 3.5% by mass, more preferably from 0.005 to 9% by mass, and preferably from 〇1 to 5% by mass. In terms of high temperature stability and rinsing properties. In view of the above, it is preferably 1% by mass or more, and more preferably: "% by mass or more, and the viewpoint of cleanliness is not more than 5% by mass, preferably 3% by mass or less, more preferably 1% by mass. % or less is further preferably 0.5% by mass or less. (4) The component is not only used to make the composition of the present invention form a stable homogenous liquid phase under the use conditions, but also has an effect of improving the rinsing property of the lotion in the cleaning step, from the viewpoint of the cleaning power of the oil stain. (4) The mass ratio of the knives to the total of the components (8) and (4), (4) / ((b) + (c)) = 0.001 / 1 ~ 1 Λ ' Preferably 〇〇〇 3 / ι ~ 〇 6 / 1 O. OOSS/POM, more preferably 0.01/1 〜 is, more preferably 0.03/1~ (four) 'better gamma 〇.33/1, more preferably 〇1/1 〇3/1, and further preferably 0.1 7/1 ~ 0.29/1. The reason why the high temperature stability and rinsing property of the composition is improved by blending the component (4) is not clear at present, and the following description considers it possible. The dipole-dipole force acting as the interaction between the hydrophilic group of the component (b) and water decreases as the temperature rises. Therefore, (8) tends to have a separation from the water generating layer as the temperature rises. If so, the component (8) cannot be used as a surfactant and the component (a) is solubilized. However, since the oxygen of the amine oxide moiety of the component (8) is an electron attracting property, 592 J3.doc -10·201221639, it is considered that the nitrogen atom adjacent to the oxygen in the hydrophilic group of the component (b) is said to be positively charged. Therefore, it is considered that there is a weak electrical interaction between the component (b) and the component (c) having a carboxylic acid moiety. Therefore, it is considered that when the component (c) is blended, the component (b) hardly separates from the water layer, and the component (b) functions as a surfactant, and can be prevented from being generated when the temperature rises (a). Separation of the components and (b) components from water. If it is presumed to be the above mechanism, it is considered that as one of the characteristics of the component (c), it is important that the length is a hydrophobic group which can form a mixed micelle. This hypothesis is based on the assumption that a carboxylic acid having only a hydrocarbon group having 6 or less carbon atoms or an aryl group having 10 or less carbon atoms (for example, citric acid 'propionic acid, benzoic acid) and salts thereof is used. In the present invention, the effect of the component (4) is weak. Further, the component (c) interacts with the calcium ion contained in the tap water to have an eight-bubble action. The effect is a specific effect of a fatty acid having a carbon number of 8 or a salt thereof, and a polyoxyethylene alkyl ether carboxylic acid or a salt thereof, a polyoxyethylene guanamine alkyl ether which is a substance common to a carboxyl group. The carboxylic acid or its salt does not have an effect. It is presumed that the (4) component interacts closely with the (4) component and the (8) component to contribute to the solution stability of the composition, and if the component (4) is recombined with calcium from the " If the rubber particles are lost, the solution structure rapidly disintegrates and changes to a low foaming solution. The general use method of kitchen cleaners uses a sprayer, sponge, wool, non-woven fabric, paper, etc. to apply the cleaning agent to the hard material. Surface, and use rub) ^ S 4:3⁄4 ΙΤ / ν. fk utensils to remove dirt, and then use tap water for rinsing operations. The technology to date is based on the viewpoint of cleaning performance research optimization, 159213.doc 201221639 did not consider The cleaning performance after cleaning is higher, and:::: Simplicity, the system provides a further value to realize the burden of the washing operation after the cattle two: 烕 light cleaning. The hard surface liquid of the present invention. In the detergent composition, from the viewpoint of improving the cleaning performance, 'chemical base is used as the component (4). As a prolamine, the second-hand private and/or hydrogen rescuer is a heavy amine, which may be exemplified by monoethanolamine and diol. Amine, triethanolamine, in terms of the cleansing power of oil (4) monoethanolamine, the description of the invention is based on the alkali metal or alkaline earth metal cerium oxide. Potassium, etc. J. Sodium hydroxide, hydrogen hydroxide In order to impart sufficient cleaning power to the oil stain, in the liquid surface cleaner composition for hard surfaces of the present invention, the content of the component (4) is preferably 0.01 to 20% by mass. More preferably, it is 0.05 to 17% by mass, more preferably 15 to 15% by mass: 2 to 10% by mass, more preferably 3 to 7 parts by mass, and further preferably 5 to 6% by mass. As the component (4), The compound may be a mixture of a plurality of compounds. In the liquid detergent composition for hard surfaces of the present invention, the builder component may be added as the component (4) from the viewpoint of "cleaning performance". As the builder component, one or two of the following may be used as (1) nitrogen triacetic acid, iminodiacetic acid, ethylenediaminetetraacetic acid, ethylenediaminepentaacetic acid, ethylene glycol. A metal salt or an alkaloid amine salt of an amine polyacetic acid such as an ether diamine tetraethylene sulfonyl ethyl iminodiacetic acid, triethylenetetraamine hexaacetic acid or melamine. Ethylenediamineacetic acid 159213.doc 201221639 (2) diglycolic acid, oxydisuccinic acid, m-methyloxysuccinic acid, carboxymethyl sulphonic acid, slow methyl tartaric acid, citric acid, lactic acid, tartaric acid, grass West owes apple I, gluconic acid and other organic acids to test metal salts or alkanolamine salts. Preferably, it is # citric acid, malic acid, ethylenediaminetetraacetic acid, hydroxyethylethylamine diacetic acid or the like. As the form of the salt, a sodium salt, a potassium salt, an ammonium salt or an alkanolamine salt is preferred. The content of the component (e) in the composition is preferably from 〇01 to 5 mass%, more preferably from 1 to 3 mass%, still more preferably from 0.2 to 1 mass, in terms of the cleaning power of the oil stain. %. In the liquid detergent composition for a hard surface of the present invention, in addition to the above-mentioned forming, other components which do not impair the object of the object or effect of the present invention may be blended. For example, polyoxyethylene alkyl ether, alkyl (poly) glycoside and other interfacial living agents, ethanol, propanol, glycerin, ethylene glycol, propylene glycol, propylene glycol monomethyl ether, alkyl carbon number of 3 to 8 The alkyl monoglyceride, E 〇 (ethylene oxide '裱 乙烷 平均 平均 平均 ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene ethylene Antioxidants, antibacterial/mold inhibitors, and preservatives such as quinone. Further, in the liquid surface cleaner composition for a hard surface of the present invention, a polyacrylic acid and a salt thereof, a copolymer of an olefin and a maleic anhydride, and a salt thereof may be blended, and further, the patent publication No. 7-292398 A dispersing agent such as a carboxylic acid polymer or a sulfonic acid polymer described in paragraphs 35 to 38 is optional. Examples of the polyoxyethylene alkyl ether include those shown below or (2). (1) A polyoxyethylene alkyl ether or an alkenyl ether, wherein the average stone inverse of the alkyl or alkenyl group is from 1 to 18, preferably 159,213.doc • 13- from the viewpoint of the cleaning power of the oil. 201221639 10~16, the ethylene oxide (hereinafter referred to as E〇) addition molar number average is 丨~3〇 Moel' is preferably an average of 6~20 ^ as a preferred example of such (1), A polyoxyethylene linear alkyl ether having a carbon number of 8 to 18 in the alkyl group may be mentioned. (2) I ethoxylate phenylene ether, wherein the average carbon number of the alkyl group is 6 to 12 from the viewpoint of the oily α winter force, and the EO addition molar number is 1 to μ molar. As the alkyl (poly) glycoside, an alkyl (poly) glycoside represented by the following formula (b2) can be mentioned from the viewpoint of the cleaning power of the oil stain. R4b(〇R5b)xGy(b2) (wherein R4b represents a linear or branched alkyl group having 8 to 18 carbon atoms, an alkenyl group or an alkylphenyl group, and R5b represents a carbon number of 2 to 4 The alkyl group, g represents a residue derived from a reducing sugar having a carbon number of 5 to 6, and χ represents 〇 y y represents 丨 〜 5) in the liquid surface cleaner composition for hard surfaces of the present invention, together with the above components. Mix water. The amount of water to be blended is adjusted to be 1 〇〇 mass 氕. The remainder of the composition is water. The amount of water is preferably from 70 to 98% by mass, more preferably from 75 to 96% by mass, even more preferably from 8 (four) to 4% by mass, from the viewpoint of the cleaning power of the oil stain and the high temperature stability. Further, the hard surface liquid detergent composition of the present invention is at 25. (The pH value below is 8 to 14 from the viewpoint of the cleaning power of the oil and the safety at the time of use. In order to obtain a high cleaning power, the pH is preferably 8.5 or more, more preferably a positive value. It is 9 or more, and further preferably, the pH is ι〇 or more', and more preferably the pH is U or more. On the other hand, from the viewpoint of ensuring safety at the time of use, the pH is preferably " More preferably, the pH is 13 or less, more preferably 12 or less, and further preferably pH 159213.doc 201221639 is 11.5 or less. That is, the hard surface liquid detergent composition of the present invention is at 25 ° C. The pH value is preferably 8.5 to 14, more preferably 9 to 13' and further preferably 10 to 12, and more preferably u to n. 5 ^ pH is a pH meter D-52S manufactured by Horiba. The liquid surface cleaner composition for hard surfaces of the present invention can be produced by appropriately mixing the components. The present invention relates to a liquid detergent composition for a hard surface. Here, "hard surface" means a person who maintains a fixed shape regardless of plane or solid shape, as long as In order to clean the processor, the degree of hardness is not limited. As the hard surface, in addition to plastic, rubber, metal 'tile, brick, concrete, cement, glass, wood, etc., floors, stairs, walls and other fixtures. Also, all the articles which are in contact with the various instruments, utensils, utensils, furniture, tableware, and the like, etc., may be cited. More preferably, plastic, metal, glass, etc. may be mentioned. Therefore, the liquid surface cleaner composition for hard surfaces of the present invention It can be used as a cleaning agent for kitchen, detergent for bathrooms, detergent for floor use, detergent for tableware, detergent for washing machine for automatic washing machine, detergent for drain pipe, detergent for small items in kitchen or bathroom, etc. It can be more preferably used as a cleaning agent for kitchens. The aspect of the present invention is exemplified below. [1] A liquid surface cleaner composition for a hard surface, comprising: (a) represented by the following formula (al) a monoalkyl ether of a polyalkylene glycol, (b) an amine oxide, (4) one selected from the group consisting of a fatty acid having a carbon number of 8 to 18 and a salt thereof 159213.doc • 15 - 201221639 or more 0.001 to 15 The amount %, preferably 〇〇〇1 to 35 mass%, more preferably 0.005 to 1 mass%, more preferably 〇1 to 0.5 mass% (wherein the mass in the case of salt is converted into an acid form) (mass) and water; and (4) component / ((8) component + (c) component) mass ratio is o.ooi / i ~ 1 /, (4) component 60 ~ 1 〇〇 mass / /, preferably 80 〜100质量优选优选为9〇~1〇〇质量度/〇, more preferably 100% by mass of (3_丨) dipropylene glycol, a monoalkyl ether having a carbon number of 4 to 8; The pH of the liquid detergent composition at 25 ° C is 8 to 14 〇
Rla(〇R2a),OH (al) [式中，1113為碳數為4〜8之烷基，1為1〜4之數，較佳為2〜3 之數’更佳為2，尺23為碳數為2~4之伸烷基，較佳為伸丙 基] [2]如上述[1]之組合物，其中（a)成分/((b)成分+(c)成分） 之質量比為1/1〜15/1 ，較佳為I.1/1-571 ，更佳為 1.2/1 〜3/1 〇 [3]如上述[1]或[2]之組合物，其中（b)成分為下述通式 (bl)所表示之烷基或烯基氧化胺。 [化2]Rla (〇R2a), OH (al) [wherein, 1113 is an alkyl group having a carbon number of 4 to 8, and 1 is a number of 1 to 4, preferably a number of 2 to 3', more preferably 2, and a size of 23 The alkylene group having a carbon number of 2 to 4, preferably a propyl group. [2] The composition of the above [1], wherein the mass of the (a) component / ((b) component + (c) component) The ratio is 1/1 to 15/1, preferably I.1/1-571, more preferably 1.2/1 to 3/1 〇[3] as the composition of the above [1] or [2], wherein b) The component is an alkyl or alkenyl amine oxide represented by the following formula (b1). [Chemical 2]
-(D)mHlji 一 〇R3b (bl) 1592l3.doc 201221639 (式中，Rlb表示碳數為8〜18之烴基，較佳為表示烷基或烯 基，更佳為表示烷基，R2b及R3b表示相同或不同之碳數為 1〜3之烷基，D表示_NHC(=0)-基或·c(=〇)NH基，E表示碳 數為1〜5之伸烷基，m及η表示m=0且n=0，或111=1且11=1。） [4]如上述⑴至[3]中任一項之組合物，其中⑻成分為烷 基之碳數為8〜18、較佳為12〜18、更佳為14〜16之烷基二曱 基氧化胺。 [5] 如上述[1]至[4]中任一項之組合物，其進而含有烷醇 胺，較佳為單乙醇胺及/或氫氧化鹼〇 〇1〜2〇質量％，較佳 為0.05 17質量％，更佳為丨5〜15質量〇/〇，更佳為2〜1〇質量 %，更佳為3〜7質量％，更佳為5〜6質量％作為（d)成分。 [6] 如上述[1]至[5]中任一項之組合物，其中㈤）成分為 —丙《—醇早丁醚。 [7] 如上述⑴至[6]中任一項之組合物，其含有成分 0.05〜15質量％，較佳為〇」〜5質量％，更佳為〇 5〜3 5質量 %，更佳為1〜2質量％。 [8] 如上述[1]至⑺中任一項之組合物，其中⑷成分為包 含（a-1)成分者。 [9] 如上述⑴至[8]中任一項之組合物其含有⑷成分 i〜15質里/〇，較佳為丨5〜8質量％，更佳為質量％。 [10] 如上述[1]至[9]中任—項之組合物，#中⑷成分/ (⑻成分+(c)成分）之質量比為〇.〇〇3/1〜〇.6/1，較佳為 0.0033/1 〜0.5/1 ’ 更佳為 〇 〇1/1〜〇 5/1，更佳為 〇 〇3/1〜 0.4/1 ’更佳為Ο.ι/^ο 33/1，更佳為〇 3/丨，更佳為 159213.doc -17· 201221639 0.17/1-0.29/1。 [11] 如上述[1]至[1〇]中任一項之組合物，其含有水〜％ 質量％，較佳為75〜96質量％，更佳為8〇〜94質量％。 [12] 如上述[1 ]至[11 ]中任一項之組合物，其於它下之 卩11值為8.5〜14，更佳為9〜13，更佳為1〇〜12，更佳為 11〜11.5。 [1 3 ]如上述[1 ]至[12]中任一項之組合物，其以均勻液相 之形式存在。 [14] 如上述[1 ]至[13]中任一項之組合物，其可用作廚房 周圍用清潔劑。 [15] —種清潔方法，其係將如上述⑴至[14]中任一項之 組合物應用於存在油污之硬質表面進行清潔。 實施例 實施例1〜1 8、比較例1〜17 以下，藉由實施例進一步記載、揭示本發明之態樣。該 實施例僅為本發明之例示，並非意在做出任何限定。使用 下述表中所不之各成分，獲得實施例、比較例之各硬質表 面用液體清潔齊j組合物。中之各成分之量之數值為 質里/◦，剩餘部分為水。表中之成分之質量比之值係省略 分母（/1)而記載。 所製備之實施例及比較例卜8、1〇〜17之各組合物係以無 混濁或分離之均勻液相之形式存在，但若利用比較例9之 組成，則無法製成均勻液體之組合物，無法進行評價。因 此，將比較例9之評價記為F。又，對於（b)成分，可見如 159213.doc •18· 201221639 下傾向··使用b-3、b_3^b_3，，之實施例i、3〜18與使用卜4 之實施例2相比，發揮出更優異之清潔性能。 且&物之pH值(25 C )視需要利用6 N_氫氧化鈉水溶液或 6 N-鹽酸進行調整。使用各硬質表面用液體清潔劑組合 物’藉由下述方法’進行混濁溫度、清潔性能、作業容易 性之各試驗。將結果示於下述表。 (混濁溫度） 對各組合物原液進行以下之處理。於容量為5〇 mL之玻 璃製容器（Maruemu螺旋管No_7)中放入組合物4〇 g。將該 容器浸潰於溫度調整為15。〇±2。(：之水浴中30分以上後，短 時間（1〜ίο秒）浸潰於溫度調整為7(rc 士5<»c之水浴中並攪 拌，重複上述插作，同時以5〜1 〇艺/min之速度使組合物之 溫度升高。觀察容器内之組合物，記錄組合物開始混濁時 之溫度。對相同組合物測定3次’將其中最低之溫度設為 該組合物之混濁溫度。混濁溫度越高，則該組合物之穩定 性越優異，若考慮流通時或保存時之溫度，則作為混濁溫 度’例如為50°C以上係較佳基準之一。 (清潔性能I) 使用組合物原液評價對改性大豆油污之清潔效果。 於預先塗佈有改性大豆油污之下述不鏽鋼板上，以成為 直徑約為35 mm之圓形狀之方式應用1 g之組合物。於室溫 (25±5 C )下接觸5分鐘後，利用去離子水進行沖洗操作。 利用數位相機拍攝經以上清潔操作之試樣與未經清潔操作 之下述不鏽鋼板（參考）。將沖洗後之試樣之圓形部分之污 1592J3.doc -19- 201221639 垢除去部面積數值化。即， ，將圓形部分之污垢完全脫落之- (D) mHlji - R3b (bl) 1592l3.doc 201221639 (wherein Rb represents a hydrocarbon group having a carbon number of 8 to 18, preferably an alkyl group or an alkenyl group, more preferably an alkyl group, R2b and R3b An alkyl group having the same or different carbon number of 1 to 3, D represents a _NHC(=0)- group or a c-(c)-NH group, and E represents an alkylene group having a carbon number of 1 to 5, m and The composition of any one of the above (1) to [3], wherein the carbon number of the (8) component is an alkyl group is 8~ 18. An alkyldidecylamine oxide of preferably from 12 to 18, more preferably from 14 to 16. [5] The composition according to any one of the above [1] to [4] further comprising an alkanolamine, preferably monoethanolamine and/or alkali hydroxide hydrazine 1 to 2% by mass, preferably 0.05% by mass, more preferably 〜5 to 15 parts by mass / 〇, more preferably 2 to 1% by mass, more preferably 3 to 7% by mass, still more preferably 5 to 6% by mass as the component (d). [6] The composition according to any one of the above [1] to [5] wherein the component (5)) is -propyl alcohol-butyl butyl ether. [7] The composition according to any one of the above (1) to (6), which contains a component of 0.05 to 15% by mass, preferably 〇" to 5% by mass, more preferably 〇5 to 315 % by mass, more preferably It is 1 to 2% by mass. [8] The composition according to any one of the above [1] to (7) wherein the component (4) is a component comprising (a-1). [9] The composition according to any one of the above (1) to (8) which contains (4) a component i to 15 gypsum/twist, preferably 丨5 to 8 mass%, more preferably mass%. [10] The composition of the composition of any of the above [1] to [9], the mass ratio of the (4) component / ((8) component + (c) component) is 〇.〇〇3/1~〇.6/ 1, preferably 0.0033/1 ～0.5/1 ' More preferably 〇〇1/1~〇5/1, more preferably 〇〇3/1~0.4/1 'better Ο.ι/^ο 33 /1, more preferably 〇3/丨, more preferably 159213.doc -17· 201221639 0.17/1-0.29/1. [11] The composition according to any one of the above [1] to [1], which contains water to % by mass, preferably 75 to 96% by mass, more preferably 8 to 94% by mass. [12] The composition according to any one of the above [1] to [11], which has a 卩11 value of 8.5 to 14, more preferably 9 to 13, more preferably 1 to 12, more preferably For 11~11.5. [1] The composition according to any one of the above [1] to [12] which is present in the form of a homogeneous liquid phase. [14] The composition according to any one of the above [1] to [13] which can be used as a cleaning agent for the periphery of the kitchen. [15] A cleaning method of applying the composition according to any one of the above (1) to [14] to a hard surface in which oil is present for cleaning. EXAMPLES Examples 1 to 18 and Comparative Examples 1 to 17 Hereinafter, the aspects of the present invention will be further described and disclosed by way of examples. This embodiment is merely illustrative of the invention and is not intended to be limiting. A liquid cleansing composition for each of the hard surfaces of the examples and the comparative examples was obtained by using the respective components not shown in the following tables. The amount of each component in the quantity is in the mass/◦, and the remainder is water. The mass ratio of the components in the table is described by omitting the denominator (/1). The prepared examples and the comparative examples of each of the compositions 8, 8 to 17 were present in the form of a homogeneous liquid phase free from turbidity or separation, but if the composition of Comparative Example 9 was used, a combination of uniform liquids could not be obtained. Unable to evaluate. Therefore, the evaluation of Comparative Example 9 is referred to as F. Further, with respect to the component (b), it can be seen that 159213.doc • 18·201221639 has a tendency to use b-3 and b_3^b_3, and the examples i and 3 to 18 are compared with the embodiment 2 using the cloth 4, Gives better cleaning performance. And the pH value of the & (25 C) was adjusted as needed using 6 N aqueous sodium hydroxide solution or 6 N-hydrochloric acid. Each of the tests for the turbid temperature, the cleaning performance, and the ease of work was carried out by using the liquid detergent composition for each hard surface by the following method. The results are shown in the following table. (turbidity temperature) Each of the composition stock solutions was subjected to the following treatment. The composition 4 〇 g was placed in a glass container (Maruemu spiral tube No. 7) having a capacity of 5 〇 mL. The container was immersed at a temperature adjusted to 15. 〇±2. (: After 30 minutes or more in the water bath, dipped in a water bath adjusted to a temperature of 7 (rc ± 5) in a short time (1 to ίο sec) and stir, repeat the above insertion, and take 5~1 The temperature of the composition was raised at a rate of /min. The composition in the container was observed and the temperature at which the composition began to turbid was recorded. The same composition was measured 3 times 'the lowest temperature was set as the turbid temperature of the composition. The higher the turbidity temperature, the more excellent the stability of the composition. When considering the temperature at the time of circulation or storage, the turbidity temperature is, for example, one of the preferred criteria of 50 ° C or higher. (Cleaning performance I) The stock solution was evaluated for the cleaning effect of the modified soybean oil stain. The 1 g composition was applied to a stainless steel plate previously coated with modified soybean oil to a circular shape having a diameter of about 35 mm. After 5 minutes of contact at (25 ± 5 C), rinse with deionized water. Use the digital camera to take the sample of the above cleaning operation and the following stainless steel plate without uncleaning operation (reference). Round part Stain 1592J3.doc -19- 201221639 The area of the scale removal part is digitized. That is, the dirt of the round part is completely detached.
對應之清潔率（以5%為刻度進行數值化）。 [改性大豆油污之製作法] 使用購買後3個月 將市售大豆油（使用和光純藥工業品， 以内者）添加於不鏽鋼製5〇 mL燒杯中4〇 mL，於上部開放 於大氣之狀態下於180°C下加熱1小時，自然冷卻至室溫 (25±5°C)。相對於99重量份之該熱處理油，添加1質量份 由板S S於至値·下充分混合。將該模型污垢以相對於每 1平方厘米成為1.4〜1.6 mg之方式儘可能均勻地塗佈於不鏽 鋼板上，於室溫下放置1週。將該污垢用於清潔評價。 [污垢除去部面積之數值化方法] 使用圖像處理軟體（Win ROOF Ver.3.30(MITANI Corporation 公司））對利用數位相機拍攝之圖像進行灰化處理。藉由將 處理後之圖像二值化，計數污垢除去部分，將污垢除去部 面積數值化。各圖像中，二值化時所使用之閾值係使用圖 像中之參考之污垢部分全部未計數之值。 (作業容易性） 針對下表所示之組合物，令2〇名試用者實施以下之清潔 操作’根據下述基準評價此時之沖洗容易性。 [清潔操作] 於15 cmx30 cm之不鏽鋼板上，使用噴霧器（花王股份有 限公司製造之Magi clean所使用者（2〇 10年製造品）），以成 為「細小之泡沫」之設定均等地喷霧3次。其次，使用用 159213.doc -20- 201221639 力擰乾水之海綿（Kikulon)，以遍及不鏽鋼板整體之方式將 喷霧之洗劑塗抹開。利用流水（流速為100 mL/s)沖洗海綿 並擰乾水後，利用該海綿清潔擦拭不鏽鋼板。 [沖洗容易性] 4 :回答擦將洗劑塗抹開後之海綿容易沖洗之試用者為 18名以上。 3 :回答擦將洗劑塗抹開後之海綿容易沖洗之試用者為 15〜17名。 2 :回答擦將洗劑塗抹開後之海綿容易沖洗之試用者為 10〜14名。 1 :回答擦將洗劑塗抹開後之海綿容易沖洗之試用者為9 名以下。 (使用低改性油之清潔性能II) 於不鏽鋼製50 mL燒杯中添加市售大豆油（使用和光純藥 工業品，使用購入後3個月以内者）4〇 mL，於上部開放於 大氣中之狀態下於180。(：下熱處理50小時（使用電恆溫機）， 自然冷卻至室溫。相對於99重量份之該熱處理油，添加丄 質量份之油橙ss，於室溫（25±5〇c)下充分混合。將該模型 污垢以相對於每1平方厘米成為14〜16 mg之方式儘可能均Corresponding cleaning rate (quantified on a 5% scale). [Preparation method of modified soybean oil] The commercially available soybean oil (using Wako Pure Chemical Industries, Ltd.) was added to a stainless steel 5-inch mL beaker for 4 〇mL, and opened to the atmosphere at the upper part. The mixture was heated at 180 ° C for 1 hour and naturally cooled to room temperature (25 ± 5 ° C). To the heat-treated oil of 99 parts by weight, 1 part by mass was added, and the mixture was sufficiently mixed with the plate S S to the bottom. The model soil was applied to the stainless steel plate as uniformly as possible in an amount of 1.4 to 1.6 mg per 1 cm 2 and allowed to stand at room temperature for one week. This dirt was used for the cleaning evaluation. [Method for Numerically Calculating Area of Dirt Removal Unit] An image captured by a digital camera was subjected to ashing processing using an image processing software (Win ROOF Ver. 3.30 (MITANI Corporation)). By binarizing the processed image, the dirt removing portion is counted, and the area of the dirt removing portion is quantified. In each image, the threshold used in binarization is the value of all the uncounted parts of the reference in the image. (Ease of Work) For the composition shown in the following table, the following cleaning operations were carried out for the two testers. The ease of rinsing at this time was evaluated based on the following criteria. [Cleaning operation] Spray on a stainless steel plate of 15 cm x 30 cm, using a sprayer (manufactured by Kamari Clean, manufactured by Kao Co., Ltd. (2 〇 10 years)), and sprayed equally to become a "small foam" setting. 3 times. Next, use a sponge (Kikulon) that was wrung with water using 159213.doc -20- 201221639 to spread the spray lotion throughout the stainless steel plate as a whole. After rinsing the sponge with running water (flow rate of 100 mL/s) and wringing the water, use the sponge to clean and wipe the stainless steel plate. [Ease of rinsing] 4: Answer: The number of trials that are easy to rinse after smearing the lotion is 18 or more. 3: Answering the sponge after the application of the lotion is easy to rinse, the tester is 15~17. 2: Answering the sponge after the lotion is easily smeared, the tester is 10 to 14 people. 1 : The number of trials for the sponge that is easy to rinse after the application of the lotion is 9 or less. (Use the low-modified oil to clean the performance II) Add a commercially available soybean oil (using Wako Pure Chemical Industries, which is used within 3 months after purchase) to a 50 mL beaker of stainless steel, and open it in the atmosphere at the top. The state is at 180. (: heat treatment for 50 hours (using an electric thermostat), and naturally cool to room temperature. Add 99 parts by mass of the heat-treated oil to the oil orange ss at room temperature (25 ± 5 〇 c). Mixing. The model soil is as uniform as possible with 14 to 16 mg per 1 cm 2
勻地塗佈於不鏽鋼板上，利用與上述相同之方法立刻進行 清潔評價。 T 159213.doc -21· 201221639 οο τ·^ 3.50 1.00 1.50 1 0.300 0.05 Ο) 1-Η mil od N〇| 寸 os 卜 2.50 1.00 1 1.00 o 〇 5.00 ^Η 0.33 in >60 *r> os 寸 ο νο 2.50 1.00 1 1.00 o o 5.00 r-； 1-Η 0.33 H >60 Os 寸 On in 3.50 2.00 0.640 1.50 o o 5.00 (Ν r4 0.06 in >60 〇\ 寸 寸 1-Η 10.0 1.00 3.00 0.500 5.00 as CN r"H >60 iT) ON m o m 2.50 「1.00 0.100 0.100 5.00 m 0.50 in >60 冢 寸 窆 <Ν 1-Η Ο o r—H 3.50 5.00 〇 0.50 I-H >60 寸 Os 1—Η τ-Η 3.50 1.00 r-H o o 5.00 cs CN 0.06 >60 ^T) ON 寸 in CTn Ο 3.50 l.oo | 1.50 | o s o o [Too | cn (N Γδ.00331 in r*H ON 寸 On ΟΝ I 2.00 1.00 1.20 0.500 7.00 CN r-H 0.29 >62 〇\ 寸 冢 ΟΟ 3^ 1.00 1.50 1 0.300 5.00 Os mil >60 ON 寸 ON 卜 3.50 1.00 1.50 1 o m c5 5.00 ON mii >60 On m ^Ti G\ 3.50 1.00 1.50 1 0.300 5.00 σ\ τ-Η N〇| Os 寸 ON ν〇 3.50 1.00 1.50 0.300 5.00 O) T—^ \MU r*H N〇l 〇\ 寸 m 〇\ 寸 3.50 1.00 1.50 o m 〇 1 5.00 as 0.17 T—H >60 to CTs m On m 3.50 1.00 1.50 0.300 1 5.00 O) LO^Tl >60 m On <Ν 2.50^ 1.00 1 1.00 〇 in 〇 5.00J 0.33 i-H >60 00 寸 ON 2.50 1.00 1.00 0.500 5.00 l> H 0.33] τ-Η >60 in 0's 寸 CTn 實施例 1 τ-Η ά <N κ} CN ά m CO Xi cn ^j· τ-Η 6 <N o CO 6 o in ώ 6 單乙醇胺 /^s 'o 混濁溫度(°C) 清潔性能I 作業容易性 清潔性能II (a-l) 成分 (a)成分 (b)成分 (C)成分 1 (d)成分1 數值條件 Oh ~1 τ-Η 159213.doc ·22· 201221639 159213.doc cn (N I 1 1 ο ο ?—Η 1 1 0.500 1 1 1 1 〇 in (N ο in r*^ 寸 (N (N 1 1 1 Ο Ο Ο ϊ—4 I 1 I 1 1 1 ^.500 O iri CN ο 1—H (N 〇 oi 1 1 1 Ο Ο »-Η 1 1 I 1 1 ^.500 1 O CN ο S A CN 〇 ΓΟ 另 rn 1 1 ^.500 1 1 ^.100^ 1 1 1 1 O <N (N 0.060 »n 1-H 1-H S Λ 寸 Os 1 1 1 <N 1 Ο 1 1 0.500 1 1 1 1 o 〇 ΓΛ m Ο in 1—H Ph PH 00 1 1 〇 in CN 1 1 ο Τ—Η 1 1 ^50〇Ί 1 1 1 1 o u-J 〇 m m ο to r—^ s Λ yn CN m 卜 1 CN t 1 1 ο 1 1 0.500 1 1 1 1 o iri o cn cn ο in t-H S Λ 〇 m m v〇 1 1 1 1 1 Ο 1 1 0.500 1 1 1 1 o uS o m ο iTi H s 宕 <N 〇 <N 1 1 1 ο 1 1 ο I 1 0.300 1 1 o in ν-ϊ CN ο <r^ r-H as (N 寸 (N 1 1 1 ο 1 1 ο V—Η 1 0.300 1 1 1 o (N ο U-) 〇\ CN m CN 1 t 1 ο Τ-Η 1 1 Ο 幽 1 1 1 1 O vn (N ο ^T) G\ <N CN CN 1 1 1 Ο 1 ο 1 1 1 1 1 1 o CN ο to T—^ CTs (N r*H CN 1 1 1 Ο ο Ο 1 1 1 1 1 f 1 O v〇 «η oi ο <n H ^T) (N 比較例 (a-1)成分 a-1-1 CN ά DPG 十二烷 a-1/a r-H χ> CN X) CO 1 ,£> ΓΟ ΰ 丙酸 苯曱酸 LAS(混合 CIO-14) AES 單乙醇胺 1¾ Xi pH值 混濁溫度(°c) 清潔性能I 作業容易性 (a)成分 非(a)成分 φ § e ir TTV' 1⑹成分 非(C)成分 1 (d)成分1 數值條件 -23- 201221639 [表3] 表3 比較例 14 15 16 17 ⑻成分 (ί a"1-1 2.50 2.50 2.50 3.50 (al)成刀 a l 2 - - - - a-1/a 1.00 1.00 1.00 1.00 (b)成分 或 非(b)成分 b-1 1.00 - - b-2 - 1.00 - b-3 - • 1.50 b-5 - • 1.00 - ⑹成分 c-3 0.500 0.500 0.500 0.300 ⑷成分 單乙醇胺 5.00 5.00 5.00 數值條件 a/(b+c) 1.7 1.7 1.7 1.9 c/(b+c) 0.33 0.33 0.33 0.17 pH值 11.5 11.5 11.5 8.0 混濁溫度(°C) >60 >60 >60 >60 清潔性能I _ 90 90 80 80 作業容易性 4 4 4 4 清潔性能II 75 75 75 75 根據上述表所總結之結果得知以下事項。 知知本發明品之清潔性能優異，混濁溫度亦充分高，作 業容易性亦良好。 根據比較例6〜9 ’得知於不含（a-1)成分之情形時，诗 性能差或未成為均勻液體之組合物。於（a)成分中之（ad 刀過v之If形時（比較例丨〇)，清潔力不充分。若對實施 與=車乂例1〜5、11、12進行比較，則於（c)成分之含量诗 特疋之範圍之情形時，混濁溫度為超過60°C之值，作| 易m问’但於不含⑷成分之情形時混濁溫度較仓 或^業谷易性較低。若對實施例1與比較例13進行比巷 特定之範圍之情形時，混濁溫度成; S右未達特定之範圍，則混濁溫度變低。 159213.doc -24- 201221639 而’根據實施例18與比較例17，得知於組合物之pH值為 8.5以上之情形時，對低改性油之清潔性能顯著較高。進 而’得知於使用聚氧乙烯烷基醚或烷基（聚）糖苷代替（b)成 分之情形時，對低改性油之清潔性能差（比較例14〜16) » 各表中之（a)成分、非（a)成分如下所述。 a-1-1 :二丙二醇單丁醚 a-1-2 :二丙二醇單己醚 a-2 :二乙二醇單丁醚 DPG :二丙二醇 各表中之（b)成分、非（b)成分如下所述。 b-Ι :聚氧乙烯（EO平均加成莫耳數=8)月桂醚 b-2:聚氧乙烯（EO平均加成莫耳數=7)二級烷基（碳數 12〜14之混合）醚 b-3 :月桂基二曱基氧化胺 b-3’ ：辛基二甲基氧化胺 b-3":硬脂基二曱基氧化胺 b-4 :月桂醯胺丙基二曱基氧化胺 b-5 :烷基（碳數10〜14之混合）糖苷（葡糖苷之平均縮合度 = 1.3) 各表中之（c)成分、非（c)成分如下所述。 c-Ι ： 辛酸 c-2 : 月桂酸 c-3 : 肉豆蔻酸 c-4 : 棕櫚酸 159213.doc -25- 201221639 c-5 :硬酯酸 c-6 :肉豆蔻酸鈉 1^八8((：10-14混合）：直鏈烷基（碳數10〜14之混合）苯磺酸 納（linear alkylbenzene sulfonate) AES:聚氧乙烯（EO平均加成莫耳數=2)直鏈烷基（碳數 12 與 14 之混合）醚硫酸鈉（Sodium lauryl polyoxyethylene ether sulfate) 產業上之可利用性 本發明之硬質表面用液體清潔劑組合物可應用於各種硬 質表面，但由於更適宜於廚房周圍之硬質表面，故而適合 作為廚房用液體清潔劑組合物。 159213.doc 26-The coating was uniformly applied to a stainless steel plate, and the cleaning evaluation was immediately performed by the same method as described above. T 159213.doc -21· 201221639 οο τ·^ 3.50 1.00 1.50 1 0.300 0.05 Ο) 1-Η mil od N〇| inch os 卜 2.50 1.00 1 1.00 o 〇5.00 ^Η 0.33 in >60 *r> os inch ο νο 2.50 1.00 1 1.00 oo 5.00 r-; 1-Η 0.33 H >60 Os inch On in 3.50 2.00 0.640 1.50 oo 5.00 (Ν r4 0.06 in >60 〇\ inch inch 1-Η 10.0 1.00 3.00 0.500 5.00 as CN r"H >60 iT) ON mom 2.50 "1.00 0.100 0.100 5.00 m 0.50 in >60 冢 inch 窆<Ν 1-Η Ο or-H 3.50 5.00 〇0.50 IH >60 inch Os 1—Η τ- Η 50 50 50 50 50 50 0.0 7.00 CN rH 0.29 >62 〇\ inch 冢ΟΟ 3^ 1.00 1.50 1 0.300 5.00 Os mil >60 ON inch ON Bu 3.50 1.00 1.50 1 om c5 5.00 ON mii >60 On m ^Ti G\ 3.50 1.00 1.50 1 0.300 5.00 σ\ τ-Η N〇| Os ON ν〇3.50 1.00 1.50 0.300 5.00 O) T—^ \MU r*HN〇l 〇\ inch m 〇\ inch 3.50 1.00 1.50 om 〇1 5.00 as 0.17 T—H >60 to CTs m On m 3.50 1.00 1.50 0.300 1 5.00 O) LO^Tl >60 m On <Ν 2.50^ 1.00 1 1.00 〇in 〇5.00J 0.33 iH >60 00 inch ON 2.50 1.00 1.00 0.500 5.00 l> H 0.33] τ-Η >60 In 0's inch CTn Example 1 τ-Η ά <N κ} CN ά m CO Xi cn ^j· τ-Η 6 <N o CO 6 o in ώ 6 monoethanolamine /^s 'o turbidity temperature (° C) Cleaning performance I Ease of workability Cleaning performance II (al) Component (a) Component (b) Component (C) Component 1 (d) Component 1 Numerical condition Oh ~1 τ-Η 159213.doc ·22· 201221639 159213. Doc cn (NI 1 1 ο ο ?—Η 1 1 0.500 1 1 1 1 〇in (N ο in r*^ inch (N (N 1 1 1 Ο Ο Ο ϊ—4 I 1 I 1 1 1 ^.500 O iri CN ο 1—H (N 〇oi 1 1 1 Ο Ο »-Η 1 1 I 1 1 ^.500 1 O CN ο SA CN 〇ΓΟ another rn 1 1 ^.500 1 1 ^.100^ 1 1 1 1 O <N (N 0.060 »n 1-H 1-HS Λ inch Os 1 1 1 <N 1 Ο 1 1 0.500 1 1 1 1 o 〇ΓΛ m Ο in 1—H Ph PH 00 1 1 〇in CN 1 1 ο Τ—Η 1 1 ^50〇Ί 1 1 1 1 o uJ 〇mm ο to r—^ s Λ yn CN m 1 CN t 1 1 ο 1 1 0.500 1 1 1 1 o iri o cn cn ο in tH S Λ 〇mmv〇1 1 1 1 1 Ο 1 1 0.500 1 1 1 1 o uS om ο iTi H s 宕<N 〇<N 1 1 1 ο 1 1 ο I 1 0.300 1 1 o in ν-ϊ CN ο <r^ rH as (N inch (N 1 1 1 ο 1 1 ο V-Η 1 0.300 1 1 1 o (N ο U-) 〇\ CN m CN 1 t 1 ο Τ-Η 1 1 Ο 幽1 1 1 1 O vn (N ο ^T) G\ <N CN CN 1 1 1 Ο 1 ο 1 1 1 1 1 1 o CN ο to T—^ CTs (N r*H CN 1 1 1 Ο ο Ο 1 1 1 1 1 f 1 O v〇«η oi ο <n H ^T) (N Comparative Example (a -1) Ingredient a-1-1 CN ά DPG dodecane a-1/a rH χ> CN X) CO 1 , £> ΓΟ 曱 Propionic acid phenyl decanoic acid LAS (mixed CIO-14) AES monoethanolamine 13⁄4 Xi pH turbidity temperature (°c) Cleaning performance I Ease of operation (a) Component non-(a) component φ § e ir TTV' 1 (6) component non-(C) component 1 (d) component 1 Numerical condition -23- 201221639 [ Table 3] Table 3 Comparative Example 14 15 16 17 (8) Ingredients (ί a"1-1 2.50 2.50 2.50 3.5 0 (al) into a knife al 2 - - - - a-1/a 1.00 1.00 1.00 1.00 (b) component or non-(b) component b-1 1.00 - - b-2 - 1.00 - b-3 - • 1.50 b -5 - • 1.00 - (6) Component c-3 0.500 0.500 0.500 0.300 (4) Ingredients Monoethanolamine 5.00 5.00 5.00 Value Condition a/(b+c) 1.7 1.7 1.7 1.9 c/(b+c) 0.33 0.33 0.33 0.17 pH 11.5 11.5 11.5 8.0 Haze temperature (°C) >60 >60 >60 >60 Cleaning performance I _ 90 90 80 80 Ease of operation 4 4 4 4 Cleaning performance II 75 75 75 75 According to the results summarized in the above table Know the following matters. It is known that the product of the present invention is excellent in cleaning performance, turbid temperature is also sufficiently high, and workability is also good. According to Comparative Examples 6 to 9', a composition having poor poetic performance or not being a homogeneous liquid was obtained in the case where the component (a-1) was not contained. In the component (a) (when the ad is shaped like the v-form of the v (comparative example), the cleaning power is insufficient. If the comparison is performed with the example of the vehicle 乂1, 5, 11, and 12, then (c) When the content of the component is in the range of the poem, the turbidity temperature is more than 60 ° C, and it is easy to ask, but the turbidity temperature is lower than that of the quarantine or the glutinous product. When the specific range of the specific embodiment is compared with the case of the first embodiment and the comparative example 13, the turbidity temperature becomes; if the right side does not reach the specific range, the turbidity temperature becomes low. 159213.doc -24- 201221639 and 'according to the embodiment 18 and Comparative Example 17, it was found that when the pH of the composition was 8.5 or more, the cleaning performance of the low-modified oil was remarkably high. Further, it was known that polyoxyethylene alkyl ether or alkyl group was used. When the glycoside is substituted for the component (b), the cleaning performance against the low-modified oil is poor (Comparative Examples 14 to 16) » The components (a) and (a) in the respective tables are as follows. 1 : dipropylene glycol monobutyl ether a-1-2 : dipropylene glycol monohexyl ether a-2 : diethylene glycol monobutyl ether DPG : dipropylene glycol (b) component, non-component (b) B-Ι : Polyoxyethylene (EO average addition mole number = 8) Lauryl ether b-2: Polyoxyethylene (EO average addition mole number = 7) Secondary alkyl group (carbon number 12 a mixture of ~14) ether b-3: lauryl didecyl amine oxide b-3': octyl dimethyl amine oxide b-3 ": stearyl didecyl amine oxide b-4: lauryl amide Base bisindenylamine oxide b-5: alkyl group (mixture of carbon numbers 10 to 14) glycosides (average degree of condensation of glucoside = 1.3) The components (c) and (c) in the respective tables are as follows. C-Ι : octanoic acid c-2 : lauric acid c-3 : myristic acid c-4 : palmitic acid 159213.doc -25- 201221639 c-5 : stearic acid c-6 : sodium myristate 1^8 ((: 10-14 mixed): linear alkylbenzene (mixed carbon number 10 to 14) linear alkylbenzene sulfonate AES: polyoxyethylene (EO average addition mole number = 2) linear alkane Sodium lauryl polyoxyethylene ether sulfate (Sodium lauryl polyoxyethylene ether sulfate) Industrial Applicability The hard surface liquid detergent composition of the present invention can be applied to various hard surfaces, but is more suitable for kitchens. Hard table around , And therefore suitable as a kitchen with a liquid detergent composition. 159213.doc 26-