CN103228777A - Hard surface liquid cleaner composition - Google Patents
Hard surface liquid cleaner composition Download PDFInfo
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- CN103228777A CN103228777A CN201180055532XA CN201180055532A CN103228777A CN 103228777 A CN103228777 A CN 103228777A CN 201180055532X A CN201180055532X A CN 201180055532XA CN 201180055532 A CN201180055532 A CN 201180055532A CN 103228777 A CN103228777 A CN 103228777A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
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- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
A hard surface liquid cleaner composition containing (a) a polyalkylene glycol monoalkyl ether, (b) amine oxide, (c) at least one type selected from a group consisting of C8-18 aliphatic acids and salts thereof in the amount of 0.001-15% by mass, and water. The mass ratio of (c)/((b)+(c)) is 0.001/1 to 1/1. 60-100% by mass of the (a) component is a dipropylene glycol (C4-8 alkyl group) monoalkyl ether. The pH at 25 DEG C is 8-14. This hard surface liquid cleaner composition not only exhibits strong cleaning power against cooking oil buildup, but also remains in a uniform liquid state with no turbidity or separation, and furthermore, has the effect of exhibiting excellent wiping and rinsing properties of a cleaner.
Description
Technical field
The present invention relates to the hard surface liquid cleanser composition.
Background technology
Usually, the sanitising agent as hard surface is used in order to remove the different dirt of process object such as bathroom, kitchen, floor, uses the sanitising agent of the composition that is suitable for separately.For example, kitchen periphery sanitising agent as wall that is used for cooking stove, baking box, cooking stove periphery or kitchen peripheries such as floor, ventilator, rotten greasy dirt can use the sanitising agent that contains tensio-active agent, solvent and alkaline agent etc. owing to the effect of heat, daylight, airborne oxygen etc. in order to remove.In addition, as the bathroom sanitising agent in bathrooms such as wall that is used for bath, bathroom and floor, the dirt for the calcium salt of removing metallic soap, particularly lipid acid can use the sanitising agent that contains tensio-active agent, solvent, metal ion chelation agent etc.
In these sanitising agents, the sanitising agent that is used for the kitchen is applicable to a part of hard surface of the wall of cooking stove periphery or kitchen range top etc.Be applied to after the hard surface, use instruments such as towel or sponge to be spread to vast scope, and remove and deoil or dirt such as dust.The oil smoke that produces owing to daily cooking operation is attached to the hard surface of the wall of cooking stove periphery or the kitchen range top etc., and these dirts great majority are if about a week, then not to be subjected to substantially since oxidation or the hot state that sex change takes place exist.In order to remove such culinary art greasy dirt, need utilize the dissolving power of the solubilising of tensio-active agent or emulsifying capacity, solvent or swelling ability etc., but monoalkyl (carbonatoms is 4～8) ether as two alkylidene groups (carbonatoms is 2～4) glycol of solvent, especially the carbonatoms of alkyl is monoalky lether culinary art smeary the removing property excellence low to above-mentioned sex change degree of 4～8 dipropylene glycol, and wishing has the sanitising agent that cooperates it.Above-mentioned solvent is owing to be not dissolved in the water separately, therefore, if do not have tensio-active agent then become the double layer separation system, the non-constant of service condition.
In patent documentation 1, disclose and contained the dipropylene glycol single-butyl ether as glycolic solvents, and show the crust cleanser compositions of excellent cleaning capacity for the sex change greasy dirt of stubbornness, but do not provide any technology enlightenment about low the removing property of culinary art smeary of sex change degree.
In patent documentation 2, the dipropylene glycol single-butyl ether that contains as glycolic solvents, the air-conditioner fin liquid cleanser composition of tensio-active agent are disclosed.Yet, do not provide any technology enlightenment for smeary cleaning effect that produces in the kitchen or processing ease.
In patent documentation 3, disclose contain nonionogenic tenside, as the dipropylene glycol single-butyl ether of hydrophobic solvent, the hard surface cleanser compositions of anion surfactant, but provide the enlightenment of any technology for low the removing property of culinary art smeary of sex change degree.
In patent documentation 4, disclose and contained the phase stability liquid fabric cleaning combination that butoxy propoxy-propyl alcohol equal solvent constitutes, but do not provided any technology enlightenment for low the removing property of culinary art smeary of sex change degree.
The prior art document
Patent documentation
Patent documentation 1: TOHKEMY 2008-45108 number
Patent documentation 2: TOHKEMY 2000-290699 number
Patent documentation 3:WO93/04151 number
Patent documentation 4: Japanese kokai publication hei 11-511800 number
Summary of the invention
The technique means of technical solution problem
The present inventor specializes in, it found that: at the monoalky lether that contains the represented polyalkylene glycol of following formula (a1) [(a) composition], amine oxide [(b) composition], and to be selected from carbonatoms be 8～18 lipid acid and the tensio-active agent more than a kind in the salt [(c) composition] thereof as must composition (wherein, (c) quality of the salt of composition is the quality that is scaled sour form in the following description book), and, (c) mass ratio of composition/((b) composition+(c) composition) is 0.001/1～1/1, (a) 60～100 quality % of composition are in the composition of monoalkyl (carbonatoms is 4～8) ether [(a-1) composition] of dipropylene glycol, form muddy or isolating even liquid phase do not take place, and wiping excellence to smeary cleaning capacity and washing composition, particularly the low culinary art greasy dirt of sex change degree is given play to excellent spatter property, thereby finished the present invention.
R
1a(OR
2a)
1OH (a1)
[in the formula, R
1aFor carbonatoms is 4～8 alkyl, l is 1～4 number, R
2aIt for carbonatoms 2～4 alkylidene group.]
The present invention relates to provide a kind of the carbonatoms that is combined with alkylidene group be 2～4 and the carbonatoms of alkyl be in the cleanser compositions used of the monoalky lether of 4～8 polyalkylene glycol and the hard surface that the culinary art greasy dirt is had excellent cleaning capacity, can form the composition of homogeneous liquid composition with a spot of as far as possible tensio-active agent.
In addition, the present invention relates to provide a kind of culinary art smeary spatter property excellence, form muddy or isolating even liquid phase do not take place, and become easy the hard surface liquid cleanser composition as the operability of the flushing operation of the washing composition of the part of cleaning process.
In addition, the present invention relates to provide a kind of hard surface liquid cleanser composition of particularly having given play to excellent spatter property for the low culinary art greasy dirt of sex change degree.
Hard surface of the present invention not only has high cleaning capacity to cooking greasy dirt with liquid cleanser composition, goes back conduct muddy or isolating liquid phase existence does not take place, and have the effect of wiping with the washability of excellence of the excellence of bringing into play washing composition.Hard surface of the present invention goes for various hard surfaces with liquid cleanser composition, owing to be specially adapted to the hard surface of kitchen periphery, therefore, is suitable for as liquid cleanser composition for kitchen use.Hard surface of the present invention because the low greasy dirt of sex change degree has been given play to excellent spatter property, therefore, can preferably be applicable to the hard surface of a large amount of kitchen peripheries that exist of such greasy dirt with liquid cleanser composition.In addition, in this manual, the state that composition " exists as even liquid phase " is meant composition stirred, and after leaving standstill 1 hour under the room temperature (for example, 25 ℃), visually can not confirm to have muddy or isolating state.
Embodiment
Hard surface of the present invention contains the monoalky lether of the represented polyalkylene glycol of following formula (a1) as (a) composition with liquid cleanser composition.From viewpoint to smeary cleaning capacity and storage stability, particularly from the viewpoint of cleaning capacity, (a) content of composition is preferably 1～15 quality % of composition of the present invention, and more preferably 1.5～8 quality % are more preferably 2～6 quality %.From viewpoint to the smeary cleaning capacity, be preferably more than the 1 quality %, more preferably more than the 1.5 quality %, be more preferably more than the 2 quality %; From the viewpoint of storage stability, be preferably below the 15 quality %, more preferably below the 8 quality %, be more preferably below the 6 quality %.As the R in the formula (a1)
1a, from viewpoint, can enumerate butyl, isobutyl-, hexyl, 2-ethylhexyl etc. to smeary cleaning capacity and storage stability, be preferably butyl and hexyl, more preferably butyl.As the R in the formula (a1)
2a,, be preferably ethylidene, propylidene, butylidene, more preferably propylidene from viewpoint to smeary cleaning capacity and storage stability.Further, from the viewpoint to smeary cleaning capacity and storage stability, 1 is 1～4 number, and more preferably 2～3 number is more preferably 2 number.
R
1a(OR
2a)
1OH (a1)
[in the formula, R
1aFor carbonatoms is 4～8 alkyl, l is 1～4 number, R
2aIt for carbonatoms 2～4 alkylidene group.]
In addition, as (a) composition, from viewpoint to smeary cleaning capacity and storage stability, preferably the carbonatoms of the alkyl of (a-1) dipropylene glycol is 4～8 monoalky lether, dipropylene glycol single-butyl ether more preferably, dipropylene glycol list isobutyl ether, dipropylene glycol list hexyl ether, dipropylene glycol list (2-ethylhexyl) ether, be more preferably the dipropylene glycol single-butyl ether, dipropylene glycol list isobutyl ether, dipropylene glycol list hexyl ether, further more preferably dipropylene glycol single-butyl ether or dipropylene glycol list hexyl ether are preferably the dipropylene glycol single-butyl ether especially.As (a) composition, it can be independent compound, it also can be the mixture of multiple compound, from viewpoint to the smeary cleaning capacity, (a) (a-1) composition in the composition is 60～100 quality %, be preferably 80～100 quality %, more preferably 90～100 quality % are more preferably 100 quality %.
Hard surface of the present invention contains amine oxide as (b) composition with liquid cleanser composition.(b) content of composition is preferably 0.05～15 quality % of composition of the present invention, and more preferably 0.1～5 quality % is more preferably 0.5～3.5 quality %, further 1～2 quality % more preferably.From the viewpoint of storage stability, be preferably more than the 0.05 quality %, more preferably more than the 0.1 quality %, be more preferably more than the 0.5 quality %, further more preferably more than the 1 quality %; From the viewpoint of composition to the residual of cleaning object, be preferably below the 15 quality %, more preferably below the 5 quality %, be more preferably below the 3.5 quality %, further more preferably below the 2 quality %.
As the mass ratio of (a) composition with the total amount of (b) composition and (c) described later composition, the mass ratio of preferred (a)/((b)+(c)) is 1/1～15/1, more preferably 1.1/1～5/1, be more preferably 1.2/1～3/1.From viewpoint to the smeary cleaning capacity, be preferably more than 1/1, more preferably more than 1.1/1, be more preferably more than 1.2/1; From the viewpoint of high temperature storage stability, be preferably below 15/1, more preferably below 5/1, be more preferably 3/1.
As (b) composition, for example can enumerate following compound.
From viewpoint to the smeary cleaning capacity, can enumerate have carbonatoms be 8～18 alkyl, preferably have the alkyl of straight chain or side chain or thiazolinyl, preferably have the alkyl amine oxide or a thiazolinyl amine oxide of alkyl.As preferred amine oxide, can enumerate represented alkyl amine oxide of following general formula (b1) or thiazolinyl amine oxide.
(in the formula, R
1bThe expression carbonatoms is 8～18 alkyl, is preferably alkyl or thiazolinyl, more preferably alkyl; R
2bAnd R
3bRepresent that identical or different carbonatoms is 1～3 alkyl; D represents-NHC (=O)-group or-C (=O) NH-group; E represents that carbonatoms is 1～5 alkylidene group; M and n represent m=0 and n=0 or m=1 and n=1.)
In above-mentioned general formula (b1), from the viewpoint to the smeary cleaning capacity, R
1bFor carbonatoms is 8～18 alkyl or thiazolinyl, be preferably carbonatoms and be 10～16 alkyl, more preferably carbonatoms is 12～14 alkyl, is more preferably carbonatoms and is 12 alkyl.R
2b, R
3bFor carbonatoms is 1～3 alkyl, more preferably carbonatoms is 1 methyl.
As the represented alkyl amine oxide of general formula (b1) or the preferred example of thiazolinyl amine oxide; from viewpoint to the smeary cleaning capacity; preferably can enumerate alkyl (carbonatoms is 8～18) dialkyl group (carbonatoms is 1～3) amine oxide; as its object lesson, for example can enumerate capryloyl dimethyl oxidation amine, decanoyl dimethyl oxidation amine, lauryl dimethyl amine oxide, myristyl dimethyl amine oxide etc.In addition, also comprise preferred example such as lauric amide propyl-dimethyl amine oxide, tetradecanoic acid amido propyl dimethyl oxidation amine, palmitic amide propyl-dimethyl amine oxide.Further, lauroyl amido propyl dimethyl oxidation amine also is preferred example.
Hard surface of the present invention with liquid cleanser composition contain be selected from carbonatoms be in 8～18 lipid acid and the salt thereof more than a kind as (c) composition.
(c) carbonatoms of the lipid acid of composition is 8～18, is preferably 12～18, more preferably 14～16.
As the object lesson of the lipid acid of (c) composition, can enumerate sad, capric acid, lauric acid, tetradecanoic acid, palmitinic acid, stearic acid, oleic acid, linolic acid, linolenic acid etc.
Be the gegenion under the situation of soap as (c) composition,, be preferably sodium, potassium, magnesium, calcium, alkanolamine, ammonium, be preferably sodium, potassium, alkanolamine from viewpoint to the smeary cleaning capacity.Therefore, as the preferred object lesson of soap, can enumerate sodium laurate, Sodium tetradecanoate, tetradecanoic acid monoethanolamine etc.
(c) content of composition is 0.001～15 quality % at hard surface of the present invention in liquid cleanser composition, is preferably 0.001～3.5 quality %, and more preferably 0.005～1 quality % is more preferably 0.1～0.5 quality %.From the viewpoint of high-temperature stability and washability, be more than the 0.001 quality %, be preferably 0.005 quality %, more preferably more than the 0.1 quality %; From the viewpoint of spatter property, be below the 15 quality %, be preferably below the 3.5 quality %, more preferably below the 1 quality %, be more preferably below the 0.5 quality %.
(c) composition not only makes composition of the present invention become stable and uniform liquid phase under working conditions, also has the effect of the washability that improves the washing composition in the cleaning process.In addition, from viewpoint to the smeary cleaning capacity, as (c) composition and (b) composition and (c) mass ratio of the total amount of composition be (c)/((b)+(c))=0.001/1～1/1, be preferably 0.003/1～0.6/1, more preferably 0.0033/1～0.5/1, more preferably 0.01/1～0.5/1, more preferably 0.03/1～0.4/1, more preferably 0.1/1～0.33/1, more preferably 0.1/1～0.3/1, more preferably 0.17/1～0.29/1.
Now also indeterminate by cooperating (c) to become to assign to improve the reason of the high-temperature stability of composition and washability, below illustrate to be considered to potential mechanism.
Rise along with temperature and reduce as the main interactional dipolar forces of the hydrophilic group of (b) composition and water.Therefore, be accompanied by temperature and rise, (b) composition has and the isolating tendency of water generates layer.So (b) composition can not be with (a) composition solubilising as tensio-active agent.
Yet, think since (b) oxygen of the amine oxide part of composition be electrophilic, therefore, with the little positively charged of nitrogen-atoms of the oxygen adjacency of the hydrophilic group of (b) composition.Therefore, think (b) composition and have and produce weak electricity between (c) composition of carboxylic moiety and interact.Therefore, can think if be combined with (c) composition that then (b) composition is difficult to take place separate with the layer of water, (b) composition can be used as tensio-active agent and works, and can be suppressed at separating of (a) composition of taking place when temperature rises and (b) composition and water.
If infer above-mentioned mechanism,, think importantly the hydrophobic group of the length that has the degree that can form mixed micelle as a characteristic of (c) composition.This hypothesis infers that this is is that alkyl below 6 or the carbonatoms carboxylic acid (for example, citric acid, propionic acid, phenylformic acid) that is the aryl below 10 and salt thereof tend to a little less than the effect as (c) of the present invention composition because only contain the carbonatoms of hydrophobic group.
In addition, (c) in composition and the tap water contained calcium ion interact and have the froth breaking effect.This effect is that carbonatoms is 8～18 lipid acid or the specific effect of its salt, as have carboxyl aspect Voranol EP 2001 carboxylic acid or its salt, polyoxyethylate amide alkyl ether carboxylic acid or its salt of common material do not have above-mentioned effect.Infer (c) composition and (a) composition and (b) composition interact nearly and help the stability of solution of composition, if lose (c) composition owing to the calcium in the tap water makes mixed micelle, then solution structure is disintegrated fast, changes in the solution of low bubble property.
In the common using method of sanitising agent for kitchen use, use instruments such as atomizer, sponge, towel, rag, non-woven fabrics, paper that sanitising agent is applied to hard surface, after wiping instrument wiping dirt, carry out flushing operation with tap water.Probe into existing technology and be conceived to the clean-up performance optimization, but be indifferent to the simplicity of the flushing operation after the cleaning.Present technique provides and realizes the abrasive performance, and alleviates the further value of the flushing operation burden after the cleaning.
With in the liquid cleanser composition,, preferably contain alkanolamine and/or alkali hydroxide at hard surface of the present invention as (d) composition from the viewpoint of further raising clean-up performance.As alkanolamine, can enumerate monoethanolamine, diethanolamine, trolamine, from the viewpoint to the smeary cleaning capacity, more preferably monoethanolamine.Alkali hydroxide in this specification sheets (alkali hydroxide) is meant the oxyhydroxide of basic metal or alkaline-earth metal.As alkali hydroxide, can enumerate sodium hydroxide, potassium hydroxide etc.
In order to give to the sufficient cleaning capacity of smeary, (d) content of composition is preferably 0.01～20 quality % at hard surface of the present invention in liquid cleanser composition, 0.05～17 quality % more preferably, 1.5～15 quality % more preferably, be more preferably 2～10 quality %, be more preferably 3～7 quality %, be more preferably 5～6 quality %.As (d) composition, can be independent compound, also can be the mixture of multiple compound.
From the viewpoint of further raising clean-up performance, can cooperate in liquid cleanser composition the washing assistant composition as (e) composition at hard surface of the present invention.As the washing assistant composition, can use following enumerate more than a kind or 2 kinds.
(1) an alkali metal salt or the alkanolamine salt of poly-acetate such as the amino of nitrotrimethylolmethane acetate, iminodiethanoic acid, ethylenediamine tetraacetic acid (EDTA), hydroxyethylethylene diamine tri-acetic acid, diethylenetriamine pentaacetic acid, glycoletherdiaminotetraacetic acid(GEDTA), hydroxyethyliminodiacetic acid, teiethylene tetramine-hexacetic acid, djenkolic acid etc.
(2) organic acid an alkali metal salt or alkanolamine salts such as diglycollic acid, oxygen base disuccinic acid, carboxymethyl oxygen base succsinic acid, carboxymethyl succsinic acid, carboxymethyl tartrate, citric acid, lactic acid, tartrate, oxalic acid, oxysuccinic acid, gluconic acid.
Wherein, optimization citric acid, oxysuccinic acid, ethylenediamine tetraacetic acid (EDTA), hydroxyethylethylene diamine tri-acetic acid or their salt.As the form of salt, particular certain cancers, sylvite, ammonium salt, alkanolamine salt.
(e) content of composition in composition from the viewpoint to the smeary cleaning capacity, is preferably 0.01～5 quality %, and more preferably 0.1～3 quality % is more preferably 0.2～1 quality %.
With in the liquid cleanser composition, except mentioned component, can also in the scope of not damaging purpose of the present invention or effect, cooperate other composition at hard surface of the present invention.For example, the carbonatoms that can enumerate tensio-active agents such as Voranol EP 2001, alkyl (gathering) glucosides, ethanol, propyl alcohol, glycerine, ethylene glycol, propylene glycol, propylene glycol monomethyl ether, alkyl is that 3～8 alkyl list glyceryl ether, the average addition mole number of EO are antioxidant, antibiotic mould resistant and sanitass such as 1～5 polyoxyethylene phenyl ether or polyoxyethylene benzylic ether equal solvent, BHT.In addition, also can cooperate dispersion agents such as the carboxylic-acid polymkeric substance of record in the multipolymer of polyacrylic acid and salt thereof, alkene and maleic anhydride and salt thereof, other the paragraph 0035～0038 of Japanese kokai publication hei 7-292398 communique or sulfonic acid base polymer in liquid cleanser composition as any composition at hard surface of the present invention.
As Voranol EP 2001, can enumerate the compound of (1) or (2) shown below.
(1) Voranol EP 2001 or polyoxyethylene alkene ether, from viewpoint to the smeary cleaning capacity, the average carbon atom number of alkyl or thiazolinyl is 10～18, be preferably 10～16, the addition mole number of oxyethane (following table is shown EO) is on average to count 1～30 mole, preferably on average to count 6～20 moles.As the preferred example of such (1), the carbonatoms that can enumerate alkyl is 8～18 polyoxyethylene straight chained alkyl ether.
(2) polyoxyethylene alkyl phenyl ether, from the viewpoint to the smeary cleaning capacity, the average carbon atom number of alkyl is 6～12, EO addition mole number is on average to count 1～25 mole.
As alkyl (gathering) glucosides,, can enumerate represented alkyl (gathering) glucosides of following general formula (b2) from viewpoint to the smeary cleaning capacity.
R
4b(OR
5b)
xG
y (b2)
(in the formula, R
4bThe total carbon atom number of expression straight chain or side chain is 8～18 alkyl, thiazolinyl or alkyl phenyl; R
5bThe expression carbonatoms is 2～4 alkylidene group; G represents to come from and has the residue that carbonatoms is 5～6 reducing sugar, and x represents 0～5, and y represents 1～5.)
At hard surface of the present invention above-mentioned each composition of cooperation and water in the liquid cleanser composition.The use level of water is to be adjusted to the amount that becomes 100 quality % that adds up to.That is, the surplus of composition is a water.As the amount of water, from viewpoint, be preferably 70～98 quality % of composition to smeary cleaning capacity and high-temperature stability, more preferably 75～96 quality % are more preferably 80～94 quality %.In addition, hard surface of the present invention is with the pH of liquid cleanser composition 25 ℃ under, from the viewpoint to the security of smeary cleaning capacity when guaranteeing to use, is 8～14.In order to obtain high cleaning capacity, be preferably more than the pH8.5, more preferably more than the pH9, be more preferably more than the pH10, further more preferably more than the pH11.On the other hand, the viewpoint of the security when guaranteeing to use, this pH is preferably below 14, more preferably below the pH13, more preferably below 12, is more preferably below the pH11.5.That is, hard surface of the present invention is preferably 8.5～14 with the pH of liquid cleanser composition under 25 ℃, and more preferably 9～13, be more preferably 10～12, further more preferably 11～11.5.PH instrument D-52S, pH electrode 6367-10D that pH uses Horiba Ltd to make measure.
Hard surface of the present invention is with liquid cleanser composition can each becomes to assign to make by suitable mixing.
The present invention relates to the hard surface is the liquid cleanser composition of object, is not limited to planar or spatial at this " hard surface ", is meant the surface that can keep definite shape, as long as can carry out clean, unqualified to the degree of its hardness.As this hard surface, except fixtures such as the floor that constitutes by plastics, rubber, metal, ceramic tile, brick, concrete, cement, glass, timber etc., step, wall, can also enumerate all hard surfaces by people such as these various apparatuses that constitute, utensil, instrument, furniture, feeder contact.Further preferably can enumerate plastics, metal, glass etc.
Therefore, hard surface of the present invention with liquid cleanser composition can be used as kitchen periphery with sanitising agent, bathroom with sanitising agent, floor with sanitising agent, feeder with sanitising agent, automatic washing machine rinse bath with sanitising agent, water shoot with the small articles of sanitising agent, kitchen or washroom with uses such as sanitising agents, more preferably can be used as the kitchen periphery and be suitable for sanitising agent.
Below enumerate embodiments of the present invention.
[1] a kind of hard surface liquid cleanser composition, wherein, described hard surface is 8～14 with the pH of liquid cleanser composition under 25 ℃, and contains:
(a) monoalky lether of the represented polyalkylene glycol of following formula (a1);
(b) amine oxide;
(c) 0.001～15 quality %, be preferably 0.001～3.5 quality %, more preferably 0.005～1 quality %, be more preferably 0.1～0.5 quality % be selected from carbonatoms be in 8～18 lipid acid and the salt thereof more than a kind (wherein, the quality under the situation of salt is the quality that is scaled sour form);
And water,
And, (c) mass ratio of composition/((b) composition+(c) composition) is 0.001/1～1/1, (a) 60～100 quality % of composition, be preferably 80～100 quality %, more preferably 90～100 quality %, to be more preferably 100 quality % be 4～8 monoalky lether for the carbonatoms of the alkyl of (a-1) dipropylene glycol
R
1a(OR
2a)
1OH (a1)
[in the formula, R
1aIt for carbonatoms 4～8 alkyl; L is 1～4 number, is preferably 2～3 number, more preferably 2 number; R
2aFor carbonatoms is 2～4 alkylidene group, be preferably propylidene.]
[2] above-mentioned [1] described composition, wherein, (a) mass ratio of composition/((b) composition+(c) composition) is 1/1～15/1, is preferably 1.1/1～5/1, more preferably 1.2/1～3/1.
[3] above-mentioned [1] or [2] described composition, wherein, (b) composition is represented alkyl amine oxide of following general formula (b1) or thiazolinyl amine oxide.
(in the formula, R
1bThe expression carbonatoms is 8～18 alkyl, preferably represents alkyl or thiazolinyl, further preferred expression alkyl; R
2bAnd R
3bRepresent that identical or different carbonatoms is 1～3 alkyl; D represents-NHC (=O)-group or-C (=O) NH-group, E represents that carbonatoms is 1～5 alkylidene group, m and n represent m=0 and n=0 or m=1 and n=1.)
[4] each described composition in above-mentioned [1]～[3], wherein, (b) composition is that the carbonatoms of alkyl is 8～18, is preferably 12～18, more preferably 14～16 alkyl dimethyl amine oxide.
[5] each described composition in above-mentioned [1]～[4], wherein, contain 0.01～20 quality %, be preferably 0.05～17 quality %, more preferably 1.5～15 quality %, more preferably 2～10 quality %, more preferably 3～7 quality %, more preferably 5～6 quality % alkanolamine, be preferably monoethanolamine and/or alkali hydroxide as (d) composition.
[6] each described composition in above-mentioned [1]～[5], wherein, (a-1) composition is the dipropylene glycol single-butyl ether.
[7] each described composition in above-mentioned [1]～[6] wherein, contains 0.05～15 quality %, is preferably 0.1～5 quality %, more preferably 0.5～3.5 quality %, (b) composition of 1～2 quality % more preferably.
[8] each described composition in above-mentioned [1]～[7], wherein, (a) composition is made of (a-1) composition.
[9] each described composition in above-mentioned [1]～[8] wherein, contains 1～15 quality %, is preferably 1.5～8 quality %, (a) composition of 2～6 quality % more preferably.
[10] each described composition in above-mentioned [1]～[9], wherein, (c) mass ratio of composition/((b) composition+(c) composition) is 0.003/1～0.6/1, be preferably 0.0033/1～0.5/1, more preferably 0.01/1～0.5/1, more preferably 0.03/1～0.4/1, more preferably 0.1/1～0.33/1, more preferably 0.1/1～0.3/1, more preferably 0.17/1～0.29/1.
[11] each described composition in above-mentioned [1]～[10] wherein, contains 70～98 quality %, is preferably 75～96 quality %, the water of 80～94 quality % more preferably.
[12] each described composition in above-mentioned [1]～[11], wherein, the pH under 25 ℃ is 8.5～14, is preferably 9～13, more preferably 10～12, more preferably 11～11.5.
[13] each described composition in above-mentioned [1]～[12] wherein, exists as even liquid phase.
[14] each described composition in above-mentioned [1]～[13] wherein, is suitable for sanitising agent as the kitchen periphery.
[15] a kind of cleaning method wherein, is applicable to each described composition in above-mentioned [1]～[14] to exist the smeary hard surface to clean.
Embodiment
Embodiment 1～18, comparative example 1～17
Below, further put down in writing and open embodiments of the present invention by embodiment.Described embodiment only is an illustration of the present invention, without any the intention that limits.Use each composition shown in the following table, obtain each hard surface liquid cleanser composition of embodiment, comparative example.The numerical value of the amount of each composition in the table is quality %, and surplus is a water.The value of the mass ratio of the composition in the table is omitted denominator (/ 1) and is put down in writing.
Each composition of embodiment that makes and comparative example 1～8,10～17 does not exist as muddy or isolating even liquid phase does not take place, but the composition of comparative example 9 can not be made the composition of uniform liquid, can not estimate.Therefore, the evaluation of comparative example 9 is designated as F.In addition, in (b) composition, find to have used b-3, b-3 ' or b-3 " embodiment 1,3～18 tend to bring into play more excellent clean-up performance than the embodiment 2 that has used b-4.
The pH of composition (25 ℃) regulates with 6N-aqueous sodium hydroxide solution or 6N-hydrochloric acid as required.Use each hard surface liquid cleanser composition,, carry out each test of cloud point, clean-up performance, processing ease by following method.The results are shown in the following table.
(cloud point)
For each composition stoste, carry out following processing.At capacity is to add the 40g composition in the glass container (Maruemu threaded pipe No.7) of 50mL.With this container temperature regulation be in 15 ℃ ± 2 ℃ the water-bath dipping more than 30 minutes after, the operation that repeating on one side in temperature regulation is short period of time (1～10 second) dipping in 70 ℃ ± 5 ℃ the water-bath, stir, with the speed of 5～10 ℃/min the temperature of composition risen on one side.Observe the composition in the container, the temperature when the record composition begins muddiness.Carry out 3 times for identical composition and measure, with the cloud point of wherein minimum temperature as said composition.Cloud point is high more, and then the stability of said composition is excellent more, if consider when circulation or the temperature when preserving, for example is a preferred standard more than 50 ℃ as cloud point then.
(clean-up performance I)
Use composition stoste to estimate for sex change soybean smeary cleaning effect.
Being coated with on the following stainless steel plate of sex change soybean smeary to become diameter in advance is the composition that the mode of the toroidal of about 35mm is used 1g.After under room temperature (25 ± 5 ℃), making it to contact 5 minutes, carry out flushing operation with deionized water.Take the following stainless steel plate (reference) that has carried out the sample of above-mentioned clean operation and do not carried out clean operation with digital camera.The soil release part area of the circular portion of sample after the flushing is quantized.That is, the situation that the dirt of circular portion is removed fully is as 100, and the situation of not removing fully as 0, is transformed into the clean rate (amplitude by 5% quantizes) corresponding to area.
[sex change soybean smeary manufacture method]
Adding the commercially available soybean oil of 40mL in stainless steel 50mL beaker (uses and the pure medicine industrial goods of light.Use is bought back 3 months with interior product), under the state that top is opened in the atmosphere, heated 1 hour down at 180 ℃, naturally cool to room temperature (25 ± 5 ℃).Add the orange oil SS (Oil Orange SS) of 1 mass parts, at room temperature thorough mixing with respect to this heat-treated oil of 99 weight parts.On stainless steel plate, the mode of this model greasy dirt with per 1 square centimeter of 1.4～1.6mg is coated with evenly as far as possible, at room temperature placed for 1 week.This greasy dirt is used for cleaning evaluation.
[method that quantizes of soil release part area]
Use image processing software (Win ROOF Ver.3.30 (MITANI Corporation)) that the image of taking with digital camera is carried out the grey processing.By the image binaryzation after will handling, calculate the soil release part, and soil release part area is quantized.The dirt part that the threshold value of using during binaryzation in each image is used reference in the image is all less than the value of calculating.
(processing ease)
For the composition shown in the following table, by 20 clean operations of estimating below the personnel, according to following standard evaluation flushing easiness at this moment.
[clean operation]
On the stainless steel plate of 15cm * 30cm, use atomizer (atomizer (manufacture in 2010) that uses among the Magiclean that Kao Corp makes), spray equably 3 times with the setting that becomes " fine and smooth foam ".Then, use the sponge (Kikulon) firmly extract water, the washing composition of spraying with the mode wiping that spreads all over whole stainless steel plate.Extract after the water with flowing water (flow velocity 100mL/s) flushing sponge, with this sponge with the stainless steel plate wiped clean.
[flushing easiness]
4: answering the evaluation personnel that smear out the easy flushing of washing composition sponge afterwards has more than 18 people.
3: answering the evaluation personnel that smear out the easy flushing of washing composition sponge afterwards has 15～17 people.
2: answering the evaluation personnel that smear out the easy flushing of washing composition sponge afterwards has 10～14 people.
1: answering the evaluation personnel that smear out the easy flushing of washing composition sponge afterwards has below 9 people.
(using the clean-up performance II of low modified oils)
Adding the commercially available soybean oil of 40mL in stainless steel 50mL beaker (uses and the pure medicine industrial goods of light.Use is bought back 3 months with interior product), under the state that top is opened in the atmosphere,, naturally cool to room temperature 180 ℃ of following thermal treatments (using the electric constant-temp machine) 50 hours.Add the orange oil SS of 1 mass parts with respect to this heat-treated oil of 99 weight parts, thorough mixing under room temperature (25 ± 5 ℃).On stainless steel plate, the mode of this model greasy dirt with per 1 square centimeter of 1.4～1.6mg is coated with evenly as far as possible, directly carries out and above-mentioned same cleaning evaluation.
Table 3:
From the following as can be known situation of above-mentioned table result in the lump.
The clean-up performance excellence of the present invention's product as can be known, cloud point are also fully high, and processing ease is also good.
From comparative example 6～9 as can be known, under the situation that does not contain (a-1) composition, clean-up performance difference or do not become the composition of uniform liquid.Under the too small situation of (a-1) composition in (a) composition (comparative example 10), cleaning capacity is insufficient.If comparing embodiment 1 and comparative example 1～5,11,12 satisfy at the content of (c) composition under the situation of scope of regulation, cloud point is the value greater than 60 ℃, and processing ease is also high; Under the situation that does not contain (c) composition, cloud point is low or processing ease is low.If comparing embodiment 1 and comparative example 13 are as can be known, satisfy at pH under the situation of the scope of stipulating, cloud point is the value greater than 60 ℃, if less than the scope of stipulating, then cloud point step-down.Further, from embodiment 18 and comparative example 17 as can be known, under the pH of composition is situation more than 8.5, significantly high to the clean-up performance of low modified oils.Further, using Voranol EP 2001 or alkyl (gathering) glucosides to replace under the situation of (b) composition, as can be known to hanging down the clean-up performance poor (comparative example 14～16) of modified oils.
(a) composition, non-(a) composition in each table are as described below.
A-1-1: dipropylene glycol single-butyl ether
A-1-2: dipropylene glycol list hexyl ether
A-2: Diethylene Glycol single-butyl ether
DPG: dipropylene glycol
(b) composition, non-(b) composition in each table are as described below.
B-1: polyoxyethylene (the average addition mole number of EO=8) lauryl ether
B-2: polyoxyethylene (the average addition mole number of EO=7) secondary alkyl (carbonatoms is 12～14 mixing) ether
B-3: lauryl dimethyl amine oxide
B-3 ': decanoyl dimethyl oxidation amine
B-3 ": stearyl dimethyl amine oxide
B-4: lauroyl amido propyl dimethyl oxidation amine
B-5: alkyl (carbonatoms is 10～14 mixing) glucosides (average condensation degree=1.3 of glucosides)
(c) composition, non-(c) composition in each table are as described below.
C-1: sad
C-2: capric acid
C-3: tetradecanoic acid
C-4: palmitinic acid
C-5: stearic acid
C-6: Sodium tetradecanoate
LAS (C10-14 mixing): straight chained alkyl (carbonatoms is 10～14 mixing) benzene sulfonic acid sodium salt
AES: polyoxyethylene (the average addition mole number of EO=2) straight chained alkyls (carbonatoms is 12 and 14 mixing) ether sodium sulfate
The possibility of utilizing on the industry
Hard surface of the present invention goes for various hard surfaces with liquid cleanser composition, owing to more be applicable to the hard surface of kitchen periphery, therefore, is preferably liquid cleanser composition for kitchen use.
Claims (15)
1. hard surface liquid cleanser composition, wherein,
Described hard surface is 8～14 with the pH of liquid cleanser composition under 25 ℃, and contains:
(a) monoalky lether of the represented polyalkylene glycol of following formula (a1);
(b) amine oxide;
(c) 0.001～15 quality % be selected from carbonatoms be in 8～18 lipid acid and the salt thereof more than a kind, wherein, the quality under the situation of salt is the quality that is scaled sour form;
And water,
And (c) mass ratio of composition/((b) composition+(c) composition) is 0.001/1～1/1, and (a) 60～100 quality % of composition are 4～8 monoalky lether for the carbonatoms of the alkyl of (a-1) dipropylene glycol,
R
1a(OR
2a)
lOH （a1）
In the formula, R
1aFor carbonatoms is 4～8 alkyl, l is 1～4 number, R
2aIt for carbonatoms 2～4 alkylidene group.
2. composition as claimed in claim 1, wherein,
(a) mass ratio of composition/((b) composition+(c) composition) is 1/1～15/1.
3. composition as claimed in claim 1 or 2, wherein,
(b) composition is represented alkyl amine oxide of following general formula (b1) or thiazolinyl amine oxide,
In the formula, R
1bThe expression carbonatoms is 8～18 alkyl, R
2bAnd R
3bRepresent that identical or different carbonatoms is 1～3 alkyl, D represents-NHC (=O)-group or-C (=O) NH-group, E represents that carbonatoms is 1～5 alkylidene group, m and n represent m=0 and n=0 or m=1 and n=1.
4. as each described composition in the claim 1～3, wherein,
(b) composition is that the carbonatoms of alkyl is 8～18 alkyl dimethyl amine oxide.
5. as each described composition in the claim 1～4, wherein,
Alkanolamine and/or alkali hydroxide conduct (d) composition of further containing 0.01～20 quality %.
6. as each described composition in the claim 1～5, wherein,
(a-1) composition is the dipropylene glycol single-butyl ether.
7. as each described composition in the claim 1～6, wherein,
(b) composition that contains 0.05～15 quality %.
8. as each described composition in the claim 1～7, wherein,
(a) composition is made of (a-1) composition.
9. as each described composition in the claim 1～8, wherein,
(a) composition that contains 1～15 quality %.
10. as each described composition in the claim 1～9, wherein,
(c) mass ratio of composition/((b) composition+(c) composition) is 0.003/1～0.6/1.
11. as each described composition in the claim 1～10, wherein,
The water that contains 70～98 quality %.
12. as each described composition in the claim 1～11, wherein,
PH under 25 ℃ is 8.5～14.
13. as each described composition in the claim 1～12, wherein,
Exist as even liquid phase.
14. as each described composition in the claim 1～13, wherein,
Be suitable for sanitising agent as the kitchen periphery.
15. a cleaning method, wherein,
Each described composition in the claim 1～14 is applicable to exists the smeary hard surface to clean.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010261701 | 2010-11-24 | ||
| JP2010-261701 | 2010-11-24 | ||
| PCT/JP2011/072208 WO2012070308A1 (en) | 2010-11-24 | 2011-09-28 | Hard surface liquid cleaner composition |
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| CN103228777A true CN103228777A (en) | 2013-07-31 |
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| JP (1) | JP5819684B2 (en) |
| CN (1) | CN103228777A (en) |
| SG (1) | SG190808A1 (en) |
| TW (1) | TWI547557B (en) |
| WO (1) | WO2012070308A1 (en) |
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| CN110612342A (en) * | 2017-10-17 | 2019-12-24 | 花王株式会社 | Liquid detergent composition for hard surface |
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| JP2014047313A (en) * | 2012-09-03 | 2014-03-17 | Pureson Corp | Liquid detergent and method for manufacturing the same |
| ES2704084T3 (en) * | 2015-07-13 | 2019-03-14 | Procter & Gamble | Cleaning product |
| EP3118295B1 (en) * | 2015-07-13 | 2018-10-17 | The Procter and Gamble Company | Use of glycol ether solvents in liquid cleaning compositions |
| CN108342259A (en) * | 2017-01-25 | 2018-07-31 | 花王株式会社 | Liquid cleanser composition |
| WO2019004014A1 (en) | 2017-06-26 | 2019-01-03 | 花王株式会社 | Liquid detergent composition for hard surfaces |
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| JPH08283778A (en) * | 1995-04-12 | 1996-10-29 | Lion Corp | Liquid detergent composition for housing |
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| GB8802086D0 (en) * | 1988-01-30 | 1988-02-24 | Procter & Gamble | Creamy scouring compositions |
| JPH08259997A (en) * | 1995-03-23 | 1996-10-08 | Lion Corp | Liquid detergent composition |
| US6495136B1 (en) * | 1998-03-26 | 2002-12-17 | The Procter & Gamble Company | Proteases having modified amino acid sequences conjugated to addition moieties |
| AU1613701A (en) * | 1999-11-16 | 2001-05-30 | Procter & Gamble Company, The | Ultrasonic cleaning |
| BR0015622A (en) * | 1999-11-16 | 2002-07-30 | Procter & Gamble | Cleaning process that uses ultrasonic waves |
| MXPA02004889A (en) * | 1999-11-16 | 2002-09-18 | Procter & Gamble | Cleaning process which uses ultrasonic waves. |
| EP1167500A1 (en) * | 2000-06-29 | 2002-01-02 | The Procter & Gamble Company | Process of cleaning a hard surface |
| ES2265133T3 (en) * | 2000-07-19 | 2007-02-01 | THE PROCTER & GAMBLE COMPANY | CLEANING COMPOSITIONS. |
| JP4916619B2 (en) * | 2001-03-28 | 2012-04-18 | 花王株式会社 | Liquid detergent composition for hard surfaces |
| JP4372533B2 (en) * | 2003-04-09 | 2009-11-25 | ライオン株式会社 | Spray cleaning products |
| PL1948769T3 (en) * | 2006-07-31 | 2009-08-31 | Reckitt Benckiser Uk Ltd | Improved hard surface cleaning compositions |
| EP2039748A1 (en) * | 2007-09-17 | 2009-03-25 | The Procter and Gamble Company | Process of treating inclined hard surface |
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2011
- 2011-09-14 JP JP2011200607A patent/JP5819684B2/en active Active
- 2011-09-28 CN CN201180055532XA patent/CN103228777A/en active Pending
- 2011-09-28 WO PCT/JP2011/072208 patent/WO2012070308A1/en active Application Filing
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| JPH08283778A (en) * | 1995-04-12 | 1996-10-29 | Lion Corp | Liquid detergent composition for housing |
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| CN110612342A (en) * | 2017-10-17 | 2019-12-24 | 花王株式会社 | Liquid detergent composition for hard surface |
| US11021678B2 (en) | 2017-10-17 | 2021-06-01 | Kao Corporation | Liquid detergent composition for hard surfaces |
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| TWI547557B (en) | 2016-09-01 |
| JP2012126883A (en) | 2012-07-05 |
| JP5819684B2 (en) | 2015-11-24 |
| TW201221639A (en) | 2012-06-01 |
| SG190808A1 (en) | 2013-07-31 |
| WO2012070308A1 (en) | 2012-05-31 |
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