TW201213336A - Colored curable composition, fabricating method of color filter, color filter, solid state imaging device, and liquid crystal display apparatus - Google Patents

Abstract

A colored curable composition, which forms a colored curable film having low development time dependence and high light-resistance while forming a pattern, is provided. The colored curable composition at least includes: (A-1) a complex containing a compound represented by the following formula (I) and a metal atom or a metal compound, (A-2) a phthalocyanine pigment, (B) a dispersant, (C) a polymerizable compound having a specific structure, (D) a photopolymerization initiator, and (E) a organic solvent. [In the formula (I), R1 to R6 independently represent a hydrogen atom or a substituent group respectively, R7 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group, wherein R1 and R6 are not bonded to each other to form a ring.]

Description

201213336 J/6. OBJECTS OF THE INVENTION: TECHNICAL FIELD The present invention relates to a color hardening composition, a method of manufacturing a color filter, a color filter, and solid photography having the color filter Component, liquid crystal display device. [Prior Art] As a method of producing a color filter used in a liquid crystal display device (LCD or the like) or a solid-state imaging device (CCD, CMOS, etc.), a pigment dispersion method is widely known. The pigment dispersion method is a method of producing a color filter by photolithography using a colored photosensitive composition obtained by dispersing a pigment in various photosensitive compositions. Since it is patterned by the photolithography method, it is a method for producing a large-screen, high-definition color filter suitable for positional accuracy. When a color filter is produced by a pigment dispersion method, a photosensitive composition is applied onto a glass substrate by a spin coater or a roll coater to form a coating film, and the coating film is formed. The pattern is exposed and developed, whereby the coloring elements are formed, and the operation is repeated for each color, whereby the color filter 0 is obtained as a coloring photosensitive composition using a pigment, for example, Japanese Patent Laid-Open No. 2 is known. A blue coloring composition for a color filter containing a phthalocyanine-based pigment described in Japanese Laid-Open Patent Publication No. Hei No. 33-16. When a color filter using a pigment is used to produce a display element such as a liquid crystal display device or a solid-state imaging device, since the contrast is improved, a pigment having a smaller particle size is required. The reason for this is that the polarization axis rotates due to the scattering of light, birefringence, etc. caused by the color of the film 20121336. J / /Z-Jpli. When the pigment is insufficiently refined, light is scattered and absorbed by the pigment, the light transmittance is lowered, the contrast is lowered, and the hardening sensitivity at the time of pattern exposure is lowered. In particular, in color filters for solid-state imaging devices, in recent years, further improvement in refinement has been desired. Therefore, there is a situation in which it is difficult to further improve the resolution by the pigment dispersion system performed by the prior art. That is, there are problems such as generation of color spots due to the influence of coarse particles of the pigment. Therefore, the pigment dispersion system is not suitable for applications such as solid-state imaging elements which require a fine pattern having a pixel size of 1.5 μm to 3.0 μm square. In order to cope with this situation, a technique of using a dye instead of a pigment has been proposed from the past. However, it is known that a dye is generally poor in light resistance and heat resistance as compared with a pigment, and is a problem in terms of performance of a color filter. Further, the dye has problems such as low solubility with respect to the photosensitive composition, low stability with time in the state of the liquid preparation or the coating film, and precipitation of the dye. In order to solve these problems, it is proposed to form a color-curable composition of a color filter 'light sheet having excellent storage stability and light resistance by using a dye containing a dipyrromethene-based compound and a phthalocyanine dye in combination (for example, Japanese Patent Laid-Open Publication No. 2008-292970). Further, a color hardening composition in which a dye and a pigment are combined is also known (for example, refer to the specification of U.S. Patent Application Publication No. 2008/0171271). As described above, 'the color-hardening composition for dyes, although 201213336 J//zopu: i used it, it can be used to form a high-growth color. Further 冋 、,,, 田化 or k high performance, it is expected that this effect [invention] - the fruit of the more progressive & In view of the above-mentioned composition, the object of the present invention is to provide a color-curable composition which is small in the development time in the formation of the film, and which can form a color-curable film having high light resistance. i Question 0 and 'The purpose is to provide a pure light film excellent in Nike, a method for producing the color filter, a light film, a solid-state imaging device having a color filter, and a liquid crystal display device, and the object is the second Question. The specific means for achieving the problem are as follows. < 1> A color curable composition comprising at least (Α_ι) a complex comprising a compound represented by the following formula (I) and a metal atom or a metal compound, and (A-2) a phthalocyanine system a pigment, (B) a dispersing agent, (c) at least one compound selected from the group consisting of a polymerizable compound represented by the following formula (MO-1) to (MO-5), and (D) a photopolymerization initiator And (E) organic solvents; 6 201213336 [Chemical]

[In the formula (I), R1 to R6 each independently represent a hydrogen atom or a substituent; and R7 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group; wherein R1 and R6 are not bonded to each other; Junction to form a ring]; 7 201213336 j / /z^pif [Chemical 2] CHz-fT^-R RfT^CH2-C-CH2-fT^R (HO-1) CHz-fT-tR CH2-fT-^ R 严2俳Rf%GH2-C~CH2-Z-CH2—C-CH2fT^-R (MO-2)

CH2fT^-R CH2-(-T^R R-fT)frCH2^C-CH2 -〇-CH2-C-CH2-(-T-^-R ίΜ0_3>

R~fT7 CH2 \:H2+T^R

CH2^RR~fTfnCH2-N CH2^R (HO-5) ch2|t^r 〇γΝγ〇(MO-4) R~fT七CH2'N 丫,〇12~(?·)^ [化3] Ch3 IJR: C-0 — Η2〇β0ΐ — G-0— 1L » 1 -0-C-fCH, VC-0H -0-C-NH-fCH, tC-0H ώ , 6 '

-OH T: -fCH2^- -OCHj~ , -OCH2CH2-, -OCH2CH2CH2-, -〇CH2CH2CH2CH2- in the formula (MO-1) to formula (MO-5), n is an integer from 0 to 14, m 1 to ni4 are integers of 1 to 8; a plurality of R and T existing in the same molecule may be the same or different; 8 201213336 ) / /zjpii in the formula (MO-1) to (MO-5) At least one of the plurality of R present in each of the polymerizable compounds represented represents -〇C(= 〇)CH=CH2, or -0C(=0)C(CH3)=CH2; In the case of 'Z is -Ο- in 'MO-2) 'n is 1 or more or R is _〇c( = 〇)CH = CH2. The colored hardening composition according to the above-mentioned item (1), wherein the (c) polymerizable compound is a compound represented by the above formula (M〇_2), and the formula (MO) At least one R present in -2) is an arbitrary base as shown below; [Chemical 4]

-o-c4ph2]-g-oh Ο ’ In the above base, 'ml and m2 are each an integer of 1 to 8. The colored curing composition according to <1> or <2>, wherein the (D) photopolymerization initiator is an anthraquinone compound. The colored hardening composition according to any one of the above-mentioned items, wherein the (A-1) comprises a compound represented by the formula (1) and a metal atom or a metal compound. The complex is a compound represented by the following formula (ΙΜ); 201213336 [Chemical 5]

[In the formula (II-1), R1 to R6 each independently represent a hydrogen atom or a substituent; R7 represents an argon atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group; and Ma represents a metal atom or a metal compound. X2 denotes a base necessary for neutralizing the charge of Ma, and X1 denotes a group which can be bonded to Ma; in addition, X1 and X2 may be bonded to each other to form a ring of 5 members, 6 members, or 7 members; R1 and R6 are not bonded to each other to form a ring]. The colored hardening composition according to any one of the above-mentioned, wherein the (A-1) comprises a compound represented by the formula (I) and a metal atom or The complex of the metal compound is a compound represented by the following formula (Π-2); 201213336 J / / L/ii.

[In the formula (II-2), R1 to R6 and R8 to R13 each independently represent a hydrogen atom or a substituent; and R7 and R14 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic ring. a group; a metal atom or a metal compound; wherein R1 and R8 or R13, and R6 and R8 or R13 are not bonded to each other to form a ring]. The colored hardening composition according to any one of the above-mentioned items, wherein the (A-1) comprises a compound represented by the formula (I) and a metal atom or The complex of the metal compound is a compound represented by the following formula (III); 11 201213336 J / /Δ〇ρ\[ [化

[In the formula (III), R2 to R5 each independently represent a hydrogen atom or a substituent; R7 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic ring; and Ma represents a metal atom or a metal compound, X3 Represents NR (R represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkylsulfonyl group, an arylsulfonyl group), a nitrogen atom, an oxygen atom, or a sulfur atom, and X4 represents NRa (Ra represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkyl group, or an arylsulfonyl group), an oxygen atom, or a sulfur atom, and γι denotes NRc (Rc represents hydrogen Atom, alkyl, alkenyl, aryl, heterocyclic, fluorenyl, fluorenyl sulfonyl or arylsulfonyl;), nitrogen atom, or carbon atom, Y2 table = nitrogen atom or carbon atom, R8 And R9 each independently represents an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylamino group, an arylamino group, or a heterocyclic amine group; R8 and γΐ may also be bonded to each other; Forming a ring of 5 members, 6 members, or 7 members, R9 and γ2 may also be bonded to each other to form a ring of 5 members, 6 members, or 7 members; X5 indicates a base that can be bonded to Ma, a form 0, 1, 2]. The colored hardening 12 201213336 J / / 厶 composition according to any one of <1>, wherein the metal atom or metal compound is Fe, Zn, Co, v. = 0, and any of Cu. &lt;8&gt; The colored hardening composition according to any one of <1>, wherein the oxime in the above formula (I) is phenyl. &lt;9&gt; A method of producing a color filter, comprising: step (A), applying a color hardening composition according to any one of &lt;1:&gt; to &lt;8&gt; The colored curable composition layer is formed as a material; Step (B) 'The mask is exposed to the colored curable composition layer formed in the step (A), and then developed to form a colored pattern. The method for producing a color filter according to <9>, comprising: a coloring pattern formed by the step (B) of the photographic purple (3) step (B), and the step (9), in the step (c) is irradiated with an ultraviolet color pattern for heat treatment. And a color filter 'made by a method of producing a color filter as taught in &lt;9&gt; or &lt;10&gt;. A solid-state photographic element having a color 遽 as described in <11:&gt;=a liquid crystal display device having a color as described in &lt;u&gt; [Effects of the Invention] Provided by the present invention Dependence on the development time in pattern formation, and can form a color hardening _ color hardening composition 13 201213336. According to the present invention, it is possible to provide a color filter excellent in light resistance, a method for producing the color filter, a solid-state imaging device having the color filter, and a liquid crystal display device. [Embodiment] "Coloring curable composition" First, the coloring composition of the present invention will be described. The color hardening composition of the present invention includes at least a complex comprising a compound represented by the following formula (1) and a metal atom or a metal compound, (A-2) a phthalocyanine-based pigment, (B) a dispersing agent, (c) a compound selected from the group consisting of a polymerizable compound represented by the following general formula (MCM) to (m〇_5), (D) a photopolymerization initiator, and (8) a color curable composition . & =, the components of (A_1), (a_2), (b), (c), (d) KE) will be described. The color-curable composition of the compound represented by the metal and the metal atom or the tantr contains (4) a complex compound containing the following compound and a metal atom or a metal compound as a colorant. Specific error: a compound containing a compound represented by the formula (1) and a dipyrromethene-based compound in a state in which the substance is usually deprotonated. First, a compound represented by the formula (1) constituting a specific complex compound 201213336 ^ · φ mm Λλ. Explain. [化8]

In the above formula (I), R1 to R6 each independently represent a hydrogen atom or a substituent. R7 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group. Wherein R1 and R6 are not bonded to each other to form a ring. In the general formula (I), the substituent represented by R1 to R6 may be exemplified by a monovalent group shown below (hereinafter, a group of one of the valence groups listed may be collectively referred to as "the base R 11". , ν · rolling 氧, oxygen ν atom), silk (preferably Wei 〗 〖48 money, branched chain burning base, more preferably carbon number 丨 ~ 24 linear, sub = 炫 base ' For example: f group, ethyl, propyl, isopropyl, butyl = f, =, hexyl, heptyl, octyl, 2-ethylhexyl, hexadecyl, cyclopropyl, cyclopentyl, ring 1 Burning base), base (preferably carbon number 2 to 48, =, diamond ~ 18 thin base, for example: ethylene A, =: basic query is carbon number 2 to make the B-based propyl, 3 · Ding Xiaoxiao, name

a group (preferably an aryl group having 6 to 48 carbon atoms, more preferably a carbon number of 6 to 2) J 15 201213336 = dioxin, a phenyl group, a naphthyl group, a heterocyclic group (preferably a carbon number) N32 heterozygous soil is more preferably a heterocyclic group of carbon number 18, such as 2_nonyl, 4_° ratio, 2, °, and 2, benzene, 2, benzene, 2, benzene And the base group, L t sit ί 'benzo tris-l-l-yl), and the base group (preferably carbon mono- to decyl group) is more preferably a C 3 to 18 alkyl group, for example: Methylweiki, triethylweiyl, tributylweil, tert-butyldimethylpropyl, trihexyldimethylpropanyl), silk, cyano, nitro alkoxy More preferably, the alkoxy group of the carbon number 48 is an alkoxy group having a carbon number of 1 to 24, for example, a methoxy group, an ethoxy group, a 1-butoxy group, a 2-butoxy group, an isopropoxy group, a third butoxy group, a decyloxy group; and, if it is a cycloalkyloxy group, for example, a cyclopentyloxy group, a cyclohexyloxy group, an aryloxy group (preferably an aromatic oxygen having a carbon number of 6 to 48) More preferably, the aryloxy group having a carbon number of 6 to 24, for example, a phenoxy group, a 1-naphthyloxy group, or a heterocyclic oxy group (preferably a carbon number of 1) 32 = heterocyclic oxy group, more preferably a heterocyclic oxy group having a carbon number of 丨 18 or 18, for example: phenyltetrazolium-5-oxy, 2-tetrahydrofuranyloxy), decyloxy ( It is preferably a decyloxy group having a carbon number of from 1 to 32, more preferably a decyloxy group having a carbon number of 丨 18 or 18, for example, a fluorenyloxy group, a butyl dimethyl oxime alkoxy group, Diphenylmethyl alkoxy), anthracenyloxy (preferably a decyloxy group having a carbon number of from 2 to 48, more preferably a decyloxy group having a carbon number of from 2 to 24, for example, an ethoxy group, a pentylene group a decyloxy group, a benzhydryloxy group, a dodecyloxy group, an alkoxycarbonyloxy group (preferably an alkoxycarbonyloxy group having a carbon number of 2 to 48, more preferably a carbon number of 2 to 24) An alkoxy greenoxy group, for example: an ethoxyoxyoxy group, a third butoxyoxy group; and 'if a cycloalkyloxycarbonyloxy group, for example, a cyclohexyloxycarbonyloxy group, An oxycarbonyloxy group (preferably an aryloxycarbonyloxy group having 7 to 32 carbon atoms, more preferably 201213336 j/ /ζ^ριι ί ί 24 an aryloxymethyloxy group, for example, a phenoxy oxy group), Female soil-based (preferably aminomethylamino group having a carbon number of 1 to 48, and a good K &lt; (i-carbon number 24 of the amine-brenyloxy group, for example: n, n-dimethylamine-mercaptooxy, N-butylamine-mercaptooxy, oxime-phenylamine-methoxyloxy , Ν 乙基 乙基 乙基 苯基 苯基 苯基 苯基 苯基 胺 胺 胺 胺 胺 胺 胺 胺 胺 胺 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Alkoxy group, for example, N,N diethylaminoheterooxy group, n-propylamine-fluorenyloxy group, calcinyl group (preferably carbon number More preferably, it is a fluorenyloxy group having a carbon number of from 1 to 24, for example, a methyl group, a decyloxy group, a hexanyl group, a fluorenyl group, a cyclyl group, and an aryl group. The aryl group which is difficult to have a carbon number of 6 to 32 is preferably an aryl group having a carbon number of 6 to 24, for example, a phenyl group of a methoxy group, and a fluorenyl group (preferably a carbon number 丨). 48 48 ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' ' An alkoxy group (preferably a carbon number of 2 to 48 in the base of the record, more preferably a carbon number of 2 to 24, such as: methoxy group, ethoxy Ke County, 18th Institute oxyl reduction, cyclohexyl, oxycarbonyl, 2,6-di-t-butyl-4-indolylcyclohexyloxy county), aryloxy group (preferably carbon number) 7 to 32 of an aryloxy group, more preferably an aryloxy group having 7 to 24 carbon atoms, for example, a phenoxy group, an amine methyl group (preferably an amine having 1 to 48 carbon atoms) Mercapto, more preferably an amine fluorenyl group having a carbon number of 2424, for example: amine aryl, N,N-diethylamino fluorenyl, aceto-N-octylamine fluorenyl , N, N-dibutylamine oxime, N_propylamine carbhydryl, N-phenylamine oxime, N_mercapto_N_phenylamine formazan, take-two 17 201213336 II μ /Αχ cyclohexylamine methyl hydrazide), an amine group (preferably an amine group having a carbon number of 32 or less, more preferably an amine group having a carbon number of 24 or less, for example, an amine group, a mercaptoamine group, N, N-dibutylamino group, tetradecylamino group, 2-ethylhexylamino group, cyclohexylamino group), anilino group (preferably an anilino group having a carbon number of 6 to 32, more preferably 6~) An anilino group of 24, for example, an anilino group, an N-mercaptoanilide group, or a heterocyclic amino group (preferably a heterocyclic amino group having a carbon number of 1 to 32) is more preferably 1 a heterocyclic amino group of 18, for example, a 4-pyridylamino group, a carboguanamine group (preferably a carboxamide group having a carbon number of 2 to 48, more preferably a carboxamide group of 2 to 24, for example : acetamino group, benzoguanamine group, tetradecylamino group, pentyl decylamino group, cyclohexylamino group), urea group (preferably a urea group having a carbon number of 1 to 32, more preferably Is a ureido group having a carbon number of 1 to 24, for example, a urea group, an anthracene, a fluorenyldithiourea group, an N-phenylureido group, or a quinone imine group (preferably a quinone imine having a carbon number of 36 or less) More preferably, the quinone imine group having a carbon number of 24 or less, for example, N-Boprene-based imine group, N-phthalimido group, or alkoxycarbonylamino group (preferably carbon) Alkoxycarbonylamino group of 2 to 48, more preferably an alkoxycarbonylamino group having 2 to 24 carbon atoms, for example, a methoxycarbonylamino group, an ethoxycarbonylamino group, a third butoxycarbonyl group Amino, octadecyloxycarbonylamino, cyclohexyloxycarbonylamino), aryloxycarbonylamino (preferably an aryloxycarbonylamino group having 7 to 32 carbon atoms, more preferably a carbon number) An aryloxycarbonylamino group of 7 to 24, for example, a phenoxycarbonylamino group, Amidino group (preferably a hydrazine group having a carbon number of 1 to 48, more preferably a sulfoniumamino group having a carbon number of 1 to 24, for example, a mercaptosulfonylamino group, a butylsulfonylamino group, a benzene group a sulfonamide, a hexadecylsulfonylamino group, a cyclohexylamine amide group, an amine hydrazide group (preferably an amine having a carbon number of 1 to 48, more preferably a carbon number) Aminosulfonylamino group of 1 to 24, for example: ν, Ν- 18 201213336 dipropylamine-non-amine amide group, N-ethyl-N-dodecanylamine amide group, azo group (preferably) It is an even number of carbon numbers of 1 to 32, more preferably an azo group of carbon number 24, for example, a phenyl group, 3_. More than a mercapto azo group, a sulfur-burning group (preferably an alkylthio group having a carbon number of 1 to 48, more preferably an alkylthio group having a carbon number of 2424, for example, anthracenylthio group, ethylthio group, octyl group) a thio group, a cyclohexylthio group, an arylthio group (preferably an arylthio group having 6 to 48 carbon atoms, more preferably an arylthio group having a carbon number of 6 to 24, for example, a phenylthio group) or a heterocyclic sulfur a base (preferably a heterocyclic thio group having a carbon number of 3232 to 32, more preferably a heterocyclic thio group having a carbon number of 1 to 18, for example, 2_ indenylthio group, 2-° ratio of alkylthio group , phenyltetra-β-ylthio), alkylsulfinyl (preferably an alkylsulfinyl group having 1 to 32 carbon atoms, more preferably an alkylsulfinyl group having 1 to 24 carbon atoms) 'Example: dodecylsulfinyl), ketone kiln (preferably an aryl aryl group having a carbon number of 6 to 32, more preferably an aryl sulfene having a carbon number of 6 to 24) A mercapto group, for example, a phenylsulfinyl group, a decyl group (preferably a sulfhydryl group having a hindrance of 1 to 48, more preferably an alkylsulfonyl group having a carbon number of 1 to 24) For example: methyl thiol, ethyl sulfonyl, propyl sulfonyl, butyl sulfonyl, isopropyl sulfonyl, 2 - B More preferably, the hexylsulfonyl group, the hexylsulfonyl group, the octylsulfonyl group, the cyclohexylsulfonyl group, the aryl group (preferably the aryl group having a carbon number of 6 to 48), more preferably An arylsulfonyl group having 6 to 24 carbon atoms, for example, a phenylsulfonyl group, a 1-naphthyl fluorenyl group, and an amine base group (preferably an amine having a carbon number of 32 or less, more Preferred is an amine sulfonyl group having a carbon number of 24, for example: amidoxime, anthracene, fluorenyl-dipropylamine sulfonyl, fluorenyl-fluorenyl-hydrazine-dodecylamine sulfonyl, hydrazine -ethyl-hydrazine-stupylamine sulfonyl, fluorenyl-cyclohexylsulfonyl), sulfo, phosphinyl (preferably a phosphinyl group having a carbon number of 1 to 32) more preferably a carbon number 1 to 24 phosphinyl group, 201213336 phosphinyl group, octyloxyphosphonium group, phenylphosphine _), phosphine oxime 32 oxyamino group, more preferably carbon number 1 to amine group). - soil, for example, diethoxyphosphonium amide, dioctyloxyphosphine 醯 = the above-mentioned monovalent group is a group which can be further substituted, and is further substituted by a radical . Further, in the case of having two soils, the substituents may be the same or different. In the general formula (I), one may form a five-member, six-member, or seven-member two, and as a ring formed, a saturated ring or an unsaturated ring may exist. 2.5Α 6 The saturated or unsaturated ring of the member or the 7 member can be exemplified, for example, the ring, the couple, the ring, the ring, the ring, the triple ring, the 嗤%, the 嗔 环 ring 0 ring, slightly bite ring, cyclopentate ring, ring rare ring, fine, tree benzene ring, and, in addition, the formation of the 5 members, 6 members, and 7 members of the ring can be replaced by In the case of a group, it may be substituted by any substituent of the substituent R, and when it is substituted by two or more substituents, the substituents may be the same or different. _ - Metal atom or metal compound _ Next, a description will be given of a metal atom or a metal compound constituting a specific complex. The metal or metal compound used herein may be any metal atom or metal compound which can form a chelating compound, and includes a valent atom of 201213336, a divalent metal oxide, a divalent metal hydroxide, Or a divalent metal vapor. For example, in addition to Zn, Mg, Si, Sn, Rh, Pt, Pd, Mo, Mn, Pb, Cu, Ni, Co, Fe, etc., A1C1, Ina,

Metal oxides such as FeCl, TiCl2, SnCl2'SiCl2, GeCl2, metal oxides such as Ti〇 and V〇, and metal hydroxides such as Si(OH)2. Among these, Fe, Zn, Mg, Si, Pt, Pd, Mo, Μη, Cu, Ni are preferable from the viewpoints of stability, spectral characteristics, heat resistance, light resistance, and manufacturing suitability of the self-aligning compound. , Co, TiO, or VO, more preferably Fe, Zn, Mg, Si, Pt, Pd, Cu, Ni, Co, or VO, most preferably Fe, Zn, Cu, Co, or VO (V= 〇). The preferred aspect of the complex comprising a compound represented by the formula (I) and a metal atom or a metal compound is shown below. That is, in the general formula (I), R1 and R6 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a decyl group, a hydroxyl group, a cyano group, an alkoxy group, or an aryloxy group. , heterocyclic oxy, fluorenyl, alkoxycarbonyl, aminyl, amine, anilino, heterocyclic amine, carboxy oxime, ureido, quinone, alkoxycarbonyl , aryloxycarbonylamino, sulfonylamino, azo, alkylthio, arylthio, heterocyclic thio, alkylsulfonyl, arylsulfonyl, or phosphonium amine, R2 and R5 independently represents a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a hydroxyl group, a cyano group, a nitro group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, a decyl group or an alkoxy group. Carbocarbonyl, aryloxycarbonyl, amine carbaryl, oximine, alkoxycarbonylamino, sulfonylamino, azo, alkylthio, arylthio, heterocyclic thio, alkyl sulfonate An anthracenyl group, an aryl group or an amine sulfonyl group, and R3 and R4 each independently represent a hydrogen atom 21 201213336 -&gt; / /Zjpif, a peptide, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, Decyl group, hydroxyl group , cyano, alkoxy, aryloxy, heterocyclooxy, decyl, alkoxycarbonyl, aminyl, anilino, carboxamide, ureido, quinone, alkoxycarbonyl Amine, hydrazine, azo, thiol, arylthio, heterocyclic thio, alkylsulfonyl, arylsulfonyl, sulfonyl, or phosphonium amino group 'R7 a hydrogen atom, a halogen atom, an alkyl group, an aryl group, or a heterocyclic group, a metal atom or a metal compound means a state of Zn, Mg, Si, Pt, Pd, Mo, Mn, Cu, Ni, Co, TiO, or VO . The following shows a more preferable aspect of the complex comprising a compound represented by the formula (I) and a metal atom or a metal compound.

That is, in the general formula (I), R1 and R6 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a cyano group, a decyl group, an alkoxycarbonyl group or an amine formamidine. Base, amine group, heterocyclic amine group, carboxylammonium group, gland group, quinone imine group, alkoxycarbonylamino group, aryloxycarbonylamino group, hydrazine group, azo group, base a aryl group or an arylphosphonium group, and R2 and R5 each independently represent an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a cyano group, a nitro group, a decyl group, an alkoxycarbonyl group, or an aryloxy group. a carbonyl group, an amine fluorenyl group, an oxime imine group, a decyl aryl group, an aryl aryl group, or an amine fluorenyl group, and R 3 and R 4 each independently represent a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, Heterocyclic group, cyano group, fluorenyl group, alkoxycarbonyl group, amine sulfhydryl group, retinoyl group, gland group, quinone imine group, alkoxycarbonylamino group, sulfonylamino group, alkylthio group, aromatic a thio group, a heterocyclic thio group, a decyl group, an aryl fluorenyl group, or an amine fluorenyl group, and R7 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, or a heterocyclic group, a metal atom or a metal compound Indicates Zn, Mg Si, Pt, Pd, Cu, Ni, Co, or VO 22 201213336, of aspects. The following is a particularly preferred aspect of the complex comprising a compound represented by the formula (I) and a metal atom or a metal compound. That is, in the general formula (I), R1 and R6 each independently represent a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an amine group, a heterocyclic amine group, a sulfhydryl group, a urea group, and a An imido group, an alkoxyamino group, a hydrazine group, an azo group, an alkyl group, an aryl group, or a phosphinium group, and R 2 and R 5 each independently represent an alkyl group or an aromatic group. a group, a heterocyclic group, a cyano group, a decyl group, an alkoxycarbonyl group, an amine carbaryl group, a decyl sulfonyl group, or an aryl fluorenyl group, and R 3 and R 4 each independently represent a hydrogen atom, an alkyl group, or an aryl group. Or a heterocyclic group, R7 represents a hydrogen atom, an alkyl group, an aryl group or a heterocyclic group, and a metal atom or a metal compound represents a state of Zn, Cu, Co, or VO. In particular, from the viewpoint of excellent fastness, it is preferably in the formula (D in the case where R3 and R4 are each a phenyl group. The reason is considered to be: (丨) Since R3 and R4 are each a phenyl group, the compound is split. The longer wavelength, the overlap with the splitting of the cocaine pigment used in combination (around 550 nm), and the easy movement of energy, and (2) the fastness of the compound itself due to the presence of a bulky bulky substituent. Further, from the viewpoint of excellent solvent solubility, it is preferred that in the formula (I), R 2 and/or R 5 are 2,6-di-t-butyl-4-indolylcyclohexyloxycarbonyl group. - a compound represented by the formula (II-1). As a specific complex in the present invention, a compound represented by the following formula (II-1) is one of preferable examples. 23 201213336 ό ΐ /z ^pif [化9]

In the above formula (II-1), R1 to R6 each independently represent a hydrogen atom or a substituent. R7 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group. Ma represents a metal atom or a metal compound, X2 represents a group necessary for neutralizing the charge of Ma, and X1 represents a group which can be bonded to Ma. In addition, X1 and X2 may also be bonded to each other to form a ring of 5 members, 6 members, or 7 members. Among them, R1 and R6 are not bonded to each other to form a ring. R1 to R6 in the formula (II-1) are the same as R1 to R6 in the formula (I), and preferred embodiments are also the same. In the formula (II-1), Ma represents a metal atom or a metal compound, and is synonymous with the above-mentioned metal atom or metal compound constituting a specific complex, and the preferred range thereof is also the same. R7 in the formula (II-1) is synonymous with R7 in the formula (I), and preferred embodiments are also the same. X1 in the general formula (II-1) may be any one as long as it can be bonded to Ma, and may be derived from water, alcohols (for example, decyl alcohol, ethanol, propanol), and the like. Chelate"[1]Sakaguchi Takeo, Ueno Jingping, 24 201213336 Λ. Year Nanjiangtang), "Metal F Compound" [2] Integrator, [3] ((10) Years, etc.) base. X2 in the formula (II-1) represents a group necessary for neutralizing the charge of Ma, and "T" exemplifies a halogen atom, a thiol group, an acid group, an acid group, a acid group, and the like. X1 and X2 in the general formula (11_1) may also be bonded to each other and together with Ma = a ring of 5 members, 6 members, or 7 members. The ring of the 5 members, 6 members, and 7 members formed may be a saturated ring or an unsaturated ring. Further, the ring of 5 members, 6 members, and 7 members may be composed only of a carbon atom and a hydrogen atom, or may be a hetero ring having at least one atom selected from the group consisting of a nitrogen atom and an oxygen atom. * Compound represented by the formula (II-2) - As a specific complex in the present invention, a compound represented by the following formula (II-2) is one of preferable examples. [化10]

In the above formula (II-2), R1 to R6 and R8 to R13 each independently represent a hydrogen atom or a substituent. R7 and R14 each independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group. Ma represents a metal former 25 201213336 sub or metal compound. Wherein R1 and R8 or R13, and R6 and R8 or Rl3 are not individually bonded to each other to form a ring. R1 to R6 in the formula (II-2) and ri~r6 in the formula (I) are preferably the same. The substituent represented by R8 to R13 in the formula (II-2) is synonymous with the substituent represented by R1 to R6 of the compound represented by the formula (q), and the preferred embodiment is also the same. When the substituent represented by R8 to R13 of the compound represented by the formula (II-2) is a group which may be further substituted, it may be substituted by any of the substituents R described above, and may be substituted by two or more. In the case of a base substitution, the substituents may be the same or different. R7 in the formula (II-2) is synonymous with R7 in the formula (I), and preferred embodiments are also the same. R14 in the formula (II-2) represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group, and a preferred range of R14 is the same as the preferred range of the above R7. In the case where R14 is a group which may be further substituted, it may be substituted by any of the substituents R described above, and when substituted by two or more substituents, the substituents may be the same or different. In the formula (II-2), Ma represents a metal or a metal compound, and is synonymous with the above-mentioned metal atom or metal compound constituting a specific complex, and the preferred range thereof is also the same. R^R9, r^r10, r1^r12, r12 and R13 in the formula (II-2) may be independently bonded to each other to form a 5- or 6-membered or 7-membered saturated or unsaturated ring. . The saturated ring or unsaturated ring formed as a synonym with the saturated ring or unsaturated ring formed by R1 and R2, the reverse 2 and R3, R4 and R5, and 26 201213336 R5 and R6 in the formula (I), The preferred examples are also the same. • Compound represented by the formula (III) _ As a specific complex of the present invention, a compound represented by the following formula (III) is one of preferable examples. [化11] ψ R7 R4

In the above formula (III), R2 to R5 each independently represent a hydrogen atom or a substituent. R7 represents a hydrogen atom, a halogen atom 'alkyl group, an aryl group, or a heterocyclic group. Ma represents a metal atom or a metal compound, and X3 represents NR (R represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkylsulfonyl group, an arylsulfonyl group), a nitrogen atom, and an oxygen. An atom or a sulfur atom, X4 represents NRa (Ra represents a hydrogen atom, a pyridyl group, an alkenyl group, an aryl group, a heterocyclic fluorenyl group, an alkylsulfonyl group, or an arylsulfonyl group), an oxygen atom, or a sulfur atom. , γ1 represents NRC (rc represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkylsulfonyl group, or an arylsulfonyl group), a nitrogen atom, or a carbon atom, Y2 Represents a nitrogen atom or a carbon atom, and R8 and R9 each independently represent an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkyl group, and an aryl group 27 201213336 ^ / /ζ^ριι Or a heterocyclic amine group. The ruler 8 and the γ1 may also be bonded to each other to form a ring of 5 members, 6 戎/g7 members, and &amp; 9 and ¥2 may also be bonded to each other to form a ring of 5 members, 6 members, and 5 members. Χ5 denotes a group which can be bonded to Ma, a denotes 〇, 丨, or 2 R R2 and R3 in the formula (III), and R4 and R5 may be independently bonded to each other to form 5 members and 6 members. , "saturated ring of 7 members, or unsaturated ring 2, formed by a saturated or unsaturated ring, and a saturated ring formed by R and R, and 4 and 5 in the formula (I) or The unsaturated ring is synonymous, and the preferred embodiment is also the same. 6 R2 to R5 and R7 in the formula (III) are synonymous with R1 to R and R7 in the formula (1), and preferred embodiments are also the same. In the formula (III), Ma represents a metal or a metal compound, and is synonymous with the above-mentioned metal atom or metal compound constituting a specific complex, and the preferred range thereof is also the same. In the formula (III), the dentine 8 and R9 each independently represent an alkyl group (f is a linear, branched, or cyclic alkyl group having a carbon number of 1 to 36, more preferably 1 to 12 straight). a chain, a branched chain, or a cyclic alkyl group, for example, anthracenyl, ethyl, propyl, isopropyl, butyl, isobutyl, tert-butyl, hexyl, 2-ethylhexyl, dodecane a group, a cyclopropyl group, a cyclopentyl group, a cyclohexyl group, a ruthenium alkyl group, an alkenyl group (preferably an alkenyl group having 2 to 24 carbon atoms, more preferably an alkenyl group of 2 to 12, for example, a vinyl group, Allyl, 3-buten-1-yl), aryl (preferably an aryl group having 6 to 36 carbon atoms, more preferably an aryl group of 6 to 18, such as a benzyl group or a naphthyl group), a ring group (preferably a heterocyclic group having 1 to 24 carbon atoms, more preferably a heterocyclic group of 1 to 12, for example, 2-thienyl, 4-pyridyl, 28 201213336 2-0-folyl, 2 -n-denyl group, l-α ratio π-group, 2-benzo-n-n-nylene, 1-m-sodium, 1-pyrazolyl, benzotriazol-1-yl), alkoxy Preferably, the alkoxy group having a carbon number of 3636 is more preferably an alkoxy group of 1 to 18, such as a decyloxy group, an ethoxy group, a propyloxy group, or a butoxy group. , hexyloxy, 2-ethylhexyloxy, dodecyloxy, cyclohexyloxy), aryloxy (preferably an aryloxy group having 6 to 24 carbon atoms, more preferably 1 to 18) An aryloxy group, for example, a phenoxy group, a naphthyloxy group, an alkylamino group (preferably an alkylamino group having 1 to 36 carbon atoms, more preferably an alkylamino group of 18, for example, a methyl group) Amino, ethylamino, propylamino, butylamino, hexylamino, 2-ethylhexylamino, isopropylamino, second butylamino, third octylamino, Cyclohexylamine, N,N_:ethylamino, N,N-dipropylamino, n,N-dibutylamino, N-fluorenyl-N-ethylamino), a group (preferably an arylamine group having 6 to 36 carbon atoms, more preferably an arylamine group of 1 to 18, for example, a phenylamino group, a naphthylamino group, an N,N-diphenylamino group , N-ethyl-N-phenylamino), or a heterocyclic amine group (preferably a heterocyclic amino group having 1 to 24 carbon atoms, more preferably a heterocyclic amino group of hydrazine~; ^, for example: 2_Aminopyrrolyl, 3-aminopyrazolyl, 2-aminopyridyl, 3·aminopyridyl). In the formula (III), an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, an alkoxy group, an aryloxy group, an alkylamino group, an arylamino group or a = cyclic amino group represented by R8 and R9. When it is a group which can be further substituted, it may be substituted by any substituent of the substituted soil R, and when substituted by two or more substituents, the substituents may be the same or different. In the formula (III), X3 represents NR, a nitrogen atom, an oxygen atom sulfur atom, X4 represents NRa, an oxygen atom, or a sulfur atom, and R and Ra are individually 29 201213336 independently represent a hydrogen atom, an alkyl group (preferably a carbon number) a straight chain, a branched chain, or a cyclic alkyl group of ～36, more preferably a linear chain, a branched chain, or a cyclic alkyl group of 1 to 12, for example, a thiol group, an ethyl group, a propyl group, or an isopropyl group. Base, butyl, isobutyl, tert-butyl, hexyl, 2-ethylhexyl, dodecyl, cyclopropyl, cyclopentyl, cyclohexyl, 1-adamantyl), alkenyl (preferably) It is an alkenyl group having 2 to 24 carbon atoms, more preferably an alkenyl group of 2 to 12, for example, a vinyl group, an allyl group, a 3-buten-1-yl group, or an aryl group (preferably a carbon number of 6~) 36 aryl, more preferably 6~18 The aryl group, for example, a phenyl group, a naphthyl group, a heterocyclic group (preferably a heterocyclic group having 1 to 24 carbon atoms, more preferably a heterocyclic group of 丨~12, such as a thiophene group or a pyridyl group) Base, 2_indolyl, 2-hydrazinyl, 1-acridinyl, 2-phenylthiazolyl, oxime-imidazolyl, oxime-pyrazolyl, benzotriazol-1-yl), fluorenyl ( It is preferably a fluorenyl group having 1 to 24 carbon atoms, more preferably a fluorenyl group having 2 to 18, such as an ethyl fluorenyl group, a pentylene group, a 2-ethylhexyl group, a benzoinyl group or a cyclohexyl group. /alkylsulfonyl (preferably an alkylsulfonyl group having a carbon number of 丨24, more preferably an alkylsulfonyl group of 疋1 to 18, such as a mercaptosulfonyl group, an ethylsulfonyl group, or a different A propylsulfonyl group, a cyclohexylsulfonyl group, an arylsulfonyl group (preferably, an aryl group having a number of from 6 to 24) is more preferably an aryl group of 6 to 18, for example Stupyl sulfonyl, naphthylsulfonyl). The R and Ra filaments, alkenyl, aryl, heterocyclic, aryl, sulfenyl, arylsulfonyl can be further Where the substituent of the substituent r is substituted, when substituted by a plurality of substituents, the substituents may be the same or not In the general formula (m), γΐ represents NRc, a nitrogen atom, or a carbon atom, and represents a nitrogen atom or a carbon atom, and Rc is synonymous with r in the X3. 30 201213336 J / In the general formula (III), Freckle carbon atoms form S-members to produce r/, and can also bond with each other, R8, Y1 and dioxane, four gas, such as % pentane, pyrrolidine, tetrahydrofuran, furan, benzopyrene吩]: members of the production of each, ^ Fu Fu, 嗟 、,, Duo, Lin and Lin, tetrahydro t South, two outside 1 such as the ring burned, money, travel, finally call, benzene, money, Hexamethyleneimine)., 7-membered ring (eg, cycloheptane, in formula (III), p9 &amp; carbon atoms together form 5 members, 6 M ^ ^ phase f-bond, R8, Yl And 6 members, and 5 members of the 5 ring. One of the % of the bonds formed by R8 and hydrazine and carbon atoms described in the solution of the five members formed in the #, is a ring of double bonds. s two-way: in the case of the formula I1?, when the ring of the beijing formed by the bonding of the ninth and the gamma 1, and the yttrium and the gamma 2 is a ring which can be further substituted, it can be explained by (4) of the substituent R. The substituent may be the same or different when substituted by two or more substituents. In the formula (III), X5 represents a group which may be bonded to Ma, and examples thereof are the same as those in the above formula (II-1). a means 0, 1 ' or 2. Preferred aspects of the compound represented by the formula (III) are shown below. That is, R2 to R5, R7, and Ma are each a preferred aspect of a complex comprising a compound represented by the formula (') and a metal atom or a metal compound, and X3 is NR (R is a hydrogen atom, a halogen group). ), a nitrogen atom, or an oxygen atom, X4 is NRa (Ra is a hydrogen atom, an alkyl group, a heterocyclic group), or an oxygen atom, and γΐ is NRc (Rc is a hydrogen atom or a thio group), a nitrogen atom, or a carbon atom. , γ2 31 201213336 is a nitrogen atom or a carbon atom, χ5 is a group bonded via an oxygen atom, and r8 and R9 each independently represent a vinyl group, an aryl group, a heterocyclic group, an oxy group, or an alkylamino group. Or 圮 and γ] are bonded to each other to form a 5-member or 6-member ring, and R9 and Υ2 are bonded to each other to form a 5-member, 6-member ring, and a represents 0 or! The situation. A more preferred aspect of the compound represented by the formula (III) is shown below. That is, 112 to 115, 117, and 3 are preferably a combination of a compound represented by the formula (1) and a metal atom or a metal compound, X3 and X4 are oxygen atoms, and γΐ is NH. Y2 is a nitrogen atom, X5 is a group bonded via an oxygen atom, and R8 and R9 each independently represent an alkyl group, an aryl group, a heterofluorenyl group, an alkoxy group, or an alkylamine group, or R8 and γι are bonded to each other. The formation of a 5-member or 6-member ring 'R9 and γ2 are mutually bonded to form a 5-member, 6-member ring, and a represents a 〇 or 1 aspect. Specific examples of the specific complex compounds in the present invention are shown below, but the present invention is not limited to these specific examples. [化 12] 32 201213336 /Zjpif

The compound number is thinner Nik. * 'fp 13⁄4 ~9Hk -rt m Μ -HvIHs: side ¢)3⁄43⁄4 mm V.=0 Ιϊ-5: -N. Sun chest\·· • 广·······* '.;» / Γ\ 1-» ..· -COO'r^hrCH^ -CHa: -d Ζή :iar6 ^HCOCHs wo -GOO-iT^CHa e&amp;t) —-GH3.; -B Cu : Ia-7 -NH.eQCHj mm V-TV. Side mm -CH? -pw3 Zri -NHCOCH2OOH2COOH ψφ ^OOr^-CH, 43⁄4 ~QH?: ^ch3 Zn* .灭^HGQGHidCHoCOOH -x\*· »·. R-·..-.·*.,, *,· . ............. mm rCOO-C^CH3 -^H-3: --93⁄4 Zn: Lions secretly secret 0 Hu mm Wft) - ό and auxiliary (4) - H Zn Ia-1; 1 HMHCOCHi 〇 CH2COOH ψψ &gt; -mim -C^3 Zft 13-121 ^HCd^CHi0GH2C00H ^OOhQ^C.M3 -3⁄4瞒^rH 0u 33 201213336 3/ /Zipif [化13]

Compound No. R^RSrR^rR13 F^=F^=F?-R12 F^=r4=r10=r1' R^R14 Ma Fa-13 —nh2 C^He(t) rCOO-(^)-CH3 cCHg( t) -C4Hg(t) &quot;CH3 Zn !a,14 —nh2 CJHs(t) Λ(ΐ) -C4He(t) —H Zn la-15 *-nh2 C4H9(t) COO-&lt;^)&quot ;CH3 -〇-Ή Zn la-16 —nhcoch3 C/}g(t) ooo-^)~ch3 c&amp;) ch3 -CH2S-0HCOOH -ch3 Cu la-17 -^h2 C^H9(t&gt; coo- ^)·01^ 〇—H Zn la-18 —NH 2 C&gt;[9(t) •CO〇H^}cH3 ώθ(〇-〇-H Cu la-19 —nh2 coo-&lt;^)ch3 &lt; ) —HV=0 la-20 —NHj OXH^€H3 Λα) 〇-gh3 Zr* la-21 —NHCOCH3 -coch^&gt;oh3 ώίω 〇-ch3 Zn la-22 -NHCOCH2OCH2COOH OOGH^&gt;&quot;CH3 άώ ) 〇-H Zn 34

201213336 J I I

[Chem. 14]

Compound No. R^R^R'R1'. r7=r14 Ma la-23 -N HCOCH 2〇Q,H2C〇〇HW) ^qo-&lt;Vch3 ciim -ch3 Zn la-24 '^COCH20C^C.〇 6h W(t) GOO-pK)H3 -ch3 Cu Ja-25 -N HC0CH20CH2C00H CM) &lt;Χ&gt;〇Η^ΗΖ QHgit) —gh3 Zn la-26 coCH2ochi:2coori Wt) &lt;XX3-T^CH3 Η · ρ *13. ~-ch3 Zn fa-27 COOH -NHCp-^ 〇άψ ~COQHpK&gt;l3 QHgP): -CH3 —H Cu and -28 COOH Wt) ^oo-/^gh3 i5Hg(t) -ch3 -CH3 Zn la-29 ^i503H W) •c〇P-^}*ch3 -ch3 -CH3 Cu Ia-30 -NHCO~^), -GGO-^^CH3 c2h5 —〇Η2-0Η〇4Η9 -CHg, Cu Ia—31 -coo -cVch3 -〇-CH3. Zn 35 201213336 - ---χ- [化15]

Compound number R'sR^R^R'3 ^=^=1^=^2 r3=^=r'°=r'' r7=r14 Ma la-32 JrCH3 C&gt;|9(t) -coo-^ )~ch3 QH9(t) O -ch3 Zn la-33 —nhso2ch3 QHs(t) ^oo-CVgh, —CH3 —ch3 Zn la-34 -CH70-Q^(y〇2 W) •coo-^)~ Ch3 W) -ch3 -ch3 Zn la-35 -ch2o-^-och3 QHs(t) •&lt;XX)-/~VcH3 QHs(t) &lt;}_οη3 Zn la-36 QH3 —N-SO2CH3 QH9( t) &lt;y〇〇-{ycH3 QHs(i) -ch3 Zn la-37 ch2cooh —Λ-δ〇2〇Η3 〇Ηβ(1) coo-^k;h3 cft(t) -〇-ch3 Zn Ia -38 —Cl QHs(t) -COO-T^CHs W) CH3 Cu la-39 «-s-ch2cooh W(t) -&lt;X»-&lt;3-GH3 W) —CH3 Cu Ia-40 ch3 —8-0HCOOH QHs(t) -CCO-Q-CH3 QHg(t) -ch3 -ch3 Cu 36 201213336 ----[一[化16]

Compound number R'=R^=R,3 R?=fi5=R0=R!2 R?=R^RW r7=r14 Ma la-41 ch3, —S-^HCOOH «t) Na^)~ch3 cS (t) —^h3 -CH3 y=〇fe-42 —eb2CH3 QHgit) -COO-Q-CHs c2S(t) -ch3 —ch3 v=o Iar43 ,—β02〇Η3 -CX50-Q-CH3 cvi(t Ό -ch3 Cu br44 f3 CHa W(t) ~coo-^^~ch3 -0 -ch3 Cu la-45 -coo-Qk^Hs C&amp;9(t) -CH3 —H Cu Ia~46 —CH3 C /|9(t) -coo-〇^h3 cS(t) -CH3 -CHj Zn Ia~47 -ch3 W) -coo-/^^33) -CH3 -ch3 Gu V48 -CH3 W) ~〇Ρ〇 -ζ^Η3 eS(t) -ch3 -ch3 Ni to -WT^CH? w) -ch3 -gh3 Zn 37 201213336 37723pif

Hb 17]

Compound No. rLr^B^r13^=1^=^=^2 r7=r'4 Ma la-50 -C4_ QH9(t) &lt;X50-〇-CH3 -CH3 -ch3 Pd la-51 —CH2CH2COOH QHg( t) 000-&lt;^)·€Η3 -ch3 -ch3 Zn la-52 —ch2ch2cooh C^Hgit) -COO-Q^Hj QHgit) ~o -ch3 Zn la-53 —·CH3 CJHgit) -ax)- (\cH3 -CH3 Zn b-54 -ch3 -CXX3-()-CH3 ^Fwt) -^Qhcooh -ch3 Zn la-55 -ch3 -COO-&lt;VcH3 QH^t) -Qkcooh -ch3 Cu la-56 -ch3. c^t) -&lt;xo-Q-ch3 Wt) ^Q-cooh 0 Zn la-57 0 C^Hgit) -cx)〇-&lt;\ch3 -ch3 —H Zn la-58 0 W &lt;XX5-〇-CH3 QH9(t) -ch3 -CH3 Zn la-59 W) -C00-&lt;\CH3 -CH2〇-〇-〇〇2 —ch3 Zn 38 201213336 j//zjpu [Chemistry 18 ]

Compound number R1=R^=R13 ff=R^=R9=R12 ^rW^R*· r7=r14 Ma ΙΜ0 -hQ^cooh CfiHis HD〇6w2-&lt;iHC^17 -ΟΗπΗττΡ-^^-ρρ^ - CH3 Zns la-61 NHCOCH^CH^CQbH -^00CH2-CHC4H9 -CH3 Zn la-62 ~Q Battle(t) -COOH^-CH: cS(t) -CH2CH^rO&quot;^^&quot;〇C|H3 -ch3 Zn la-63 -CH3 c^Hgit) ^OO-hQkjH: cS(t) -CH2CH2&quot;〇&quot;^~^~〇CH3 -ch3 Cu Ιβ-«7 -wh2 —CM —GH3 —H Zn Ia -ββ -NHCOCH3 -CN -CH3 -qH3 Zn la-69 -ch3 -CN -CH3 -CH3 Zn la-70 -CH3 -CN -0 -gh3 Zn 39 201213336 [Chem. 19]

Compound No. R'rR^^R13 R^R^R^R12 |^=^=^0=^1 r7=r'4 Ma la-71 Cl3H27 —CN —CH3 〇Cu la-72 —nh2 —QN —0F3 -〇Cu b_73 —nhcoch2och2cooh —CN —cf3 —Q Cu Ia»74 ^ηοο^ηο-&lt;〇^Γ^ο2 —CN —cf3 —CH3 Zn la-75 hQhCO-N(CH2CH2OCH3)2 —CN —C3H7( Iso) -ch3 Zn la-76 -^&gt;-CO-N(Ol2CH?OCH3)2 ««CN 0 —CH3 Zh la-77 -Q&gt;-CO&quot;N(CH2CH?OCH3)i -»CN -CF3 -ch3 Zn Ia-78 —NHCOCH2OCH2COOH —CN —Q»-CO-N(CH2CH2〇CH3b -ch3 Zn la-79 COO-&lt;^CH3 03⁄4) CH3 Zn la-80 C/[8(t) ^oo- /^ch3 03⁄4) -C4_ —H Zn la-81 —c13h27 C^HsU) &lt;:oo-(3-ch3 C%t) ~Q —H Zn la-82 —nhcoch2och2cooh —COOC2H5 S02N(CH2CH30G2Hg)2 — H Co la-83 &quot;Q ch2cooh S〇2-isl-CH2COOH QiHsO) όοο-(^&gt;·οη3 03⁄4) A CH3 —H Zn 40 201213336 [Chem. 20]

Compound number r&gt;,.—γλ ·*τ\.*-Γλ Ff=F^=F?=R,:i Ff=Ff=R,0=R,v r7=r'4 Ma la-A - Nhcoch3 c^(t) ^C0〇&quot;^CH3 -CHj Zn QHa(t) ch2cooh 41 201213336 J//23plf [化21] I la-1

42 201213336 [Chem. 22]

43 201213336 [Chem. 23]

H3 I l a-6

(t) C4H9CO-NH

-CH2COOH PH3 NHCOC4_ NHCOC4H9(t) (t)G4H9CX)-NH /Ni HC^r^U'

CN •oh2cooh 44 201213336 [Chem. 24] ΙΙδ-7 gh3—^ V~O00

%-CO〇Hf_V-CH3

HOOGtHapCHzCb-NH NH-GOGH2OCH2GOQH f 9 CHrC, CH person CH3 lla«8

GHS, GHj

€00-&lt; V-gh3 G4H9(t) ooc sun) ^NH2 / \ H3〇PCf .d; O b〇CH3 H〇人CH3 45 201213336 [Chem. 25]

I \ eriQ

46 201213336 n rii^n [化·26] I la-13 ila-a

I la-15

47

CH3 Q4H9(t)

C4H9(t) CHfW Χ:Η3 201213336 i//2ipif [Chem. 27] I la-16 /C4H9(t) GH3 )oc c4_) HOOCCH2CH2-CH2 I la-17

C4H9(t) C4H9(t)

I la-18

Q^OC HOOCCH2CH2-CH2

C2H500G-C 48 201213336 [化* 28]

HaH alkyne

49 201213336 j/ /zjpif C4H9(t)

C4Hg(t)

CH3

CH3 ch3 〇OC ~A^ch

C· / , NH2 C· zri 0··Η2 \〇-COCH3

C4H9(t) C00-&lt;&gt;-CH3

'. 4 feeding N’H N\ ./N, NH C4H9(t)

O-COCHs

1-4 ch3 ch3 C4H9(t) v COO- Λ&gt; mJ, 〇4H9(t) ..Zn, N -ch3 ch2och2cooh CH,

C4H9(t)

C4H9(t) Hrvi : Zn: N )=〇&quot;' xo-d CH3 , CH2OCH2〇〇〇H 50 201213336 [Chem. 30]

,s(t) -\^ y~CH3 cJC(t)

C4_ dW) 1-7

_t) 01⁄2 〇〇C^ ^

C4H9(t) G00~^^H3H3 c&gt;yt)

51 201213336 37723pif 〇4H9(t)

CH3 OOG·^ ^GH

C4H9(t), Fe:dH3

GOO 丨-&lt; C4H9(t)

-ch3 〇4H9(t) CH3

HO

C4H9(t) e4H9(t)

Ch3 -11

C4H9(t)

Ch3 C4H9(t)

CH3—C—CH=0-CH3 C4H9(t)

Ch3 C4H9(t) 52 201213336 [化32] 1-13 CH3

〇4Hg(t) QtH9(t) οοα

-COO

CH3 _ _ O'* \〇 H-(

1-14 CH

C4H9(t) (10) 3OOG^A^CHwAy^Qoo—Q^_ ‘,Νχ·则 'c=o;* CH3

1-15 GH3

P series CH3 00C~人〆CH

C·) ., Zrr&gt;=r- · O CH 〇4H9(t) Mi3 vΟΟό-^Λ-ΟΗ,N 'CH3

1-16 CH,

C4H9(t) CH3 Gh3 ooc^A^ch^A^coo

C4H9(t)

CH5 c4H9(t) N’H' : Jv! ^4Hg(t) (ί=〇Γ Ut*% bCsHs 53 201213336 [化 33] 1-17

C4H9(t) 〇μ

〇4H9(t) N^H Ν^Ζη:*·'Ν= N b=〇·

., II O-C C4H9{t)

Gh3 C4H9(t) nhc4h9 1-18 CH3

,C4H9(t) ch3 ch3

* u /f\ / . 4.--·Ν· ^Hg(t) NH Zn- N \ .·· N. if〇〇, s-c G4H9(t)

CH, C4H9(t) CH3 nhc4h9 1-19 ch3- 〇4H9(t)

CH3 ch3 OOC, CH^^A^COO C4H9(t)

O

G4H9(t)

Ch3 〇4Hg(t)

Ch3- \〇-cf bn3 ΌΗ

C4H9(t)

CH3 ch3OQC^y w-CHwV-COO 〇4H9(t)

O

Zrf

\〇-cf N C4H9(t)

CH3 C4H9(t) CHNHS02CH3 CH3_C, OH ch3 54 201213336 J / /ζοριι [化 34] 1-21

嘱t) A x〇0-/^)-CH3 ;Zrf N W) ‘ bHNHS02GH3 CH3 1-22 CHa

Zn

,_t) 〇〇C‘人 /CH

C4H9(t)〇〇〇~^y-cH2 CH, 1-23:

T NC, ^V^CHwV^e〇OH -CHj C4_)

N, .Ns v - , Zn·〆 \l QH9(t)

Ch3-“m

NHSO^H3 1-24

bHNHS〇2CH3 0H C4H9(t)

Hj 〇4 drying 55 1. 201213336 [化35] 1-25 〇4H9(t)

C4H9(t)

OOC

Zn* ch3 gh3

G4H9(t) )~\ COO -·*( 7CH3N cjCit) n 'chnhso2ch3 gh3 1-26

CHNHSOaCl· 6h3 CH3 C4W) COO-/^^CH3 Zn, N . This (1) σ \)-cf bHNHSO^CHa 1-27 CH3

p4H9(t) CH? OOC ~ :4 feeding

GN

CN ch3 oh2

bHNHS〇2CH3 CHS 1-28 CH3

P4H9(t) CH3 OOC ~A^gh

C4H9(t) ν7η ^Zn;

N , &lt;r 丨 \〇-d H3 6h2 bHNH5〇2CH3 6h3 56 201213336 377Z3pif [化36] 1-29

Close 9 copies CH^

CH

Mm GR3 6h2 eRNHS02GH2 CH3 (3⁄4 off)

CHa 0H3 GHj Lai Qing - iN,, N=^_ Qing

CHS:

•, '丨〆 N— nh2 04 “ “.’ 'n__^H2 C^t) ^hAJ^c〇〇- 57 201213336 37723pif [化 37] 1-32

1-33

C4H9(t) n&quot;H2 〇4H9(t) N^2 OOC C4H9(t) nh2 nh2

CHi

C4H9(t) coo-/~Vch3 is called 9(1)NH2 coo

:4H9(t) 1-34

CH3 ch3 CH

C4H9(t)

:4_ NH2, nhcoch3v CH3CQ-NH Zn, ... • / /NHG0CH3 〇4_)

丫, COO ch3 ch3

C4H9(t) 58 201213336 [化38] 1-3503⁄4

CHr ΘΗ^ NH2 GH3CQ-NH

N

QOC C4H9(t)

G4H9(t)

NHCOCH3C4H9(t)

OOC-^V&lt;^CH-^^COO CH3 ch3

C4H9(t)

Mm CH3 CH3

Ms NH, GH3CO-NH 〇ύ A? ‘ ’ooc

N

G4H9(t)

NHCOC^Hs^sW _OCH3 _ C4Hg(t): CH^ ^ '€〇〇— ~ζ~^~〇Η2 CH3 dHj C4Hg(t) 59 201213336 37723pif [化39]

X1··* R3 u R4 back coo-(~\-ch3 IX\ M C^Hgtt)

V Compound number R1 R3 R4 R9 X' U-1 -ch3 —COOC2H5 _CH3 -ch3 —CH3 h2o Π-2 -ch3 -COOC2Hs —ch3 -CHg -CHNHS02CH3 CH? h2o fl-3 -ch3 -cooc2hs -ch3 —CH3 NHS02CH3 H2o Π-4 nhso2ch3 —COOCH3 -ch3 -ch3 h2o Π-5 nhso2ch3 —COOC2H5 —CH3 —ch2och2cooH H?0 Π-6 nhso2ch3 -COOC2H5 -ch3 -0 —CH3 h2〇[40]

Compound 珑R1 R8 R9 R' X' Π-7 -ch3 -COC5C2H5 〇—CH3 h2o D-8 ~Q -COOC2H5 〇〇—CH3 h2o Π-9 ~ο nhso2ch3 —CM —CH3 —ch3 —CHa h3o Π- 10 nhso2ch3 —CN —ch3 —ch3 nhso2ch3 h2o Π-11 nhso3ch3 —CN ~oo -ch3 H20 60 201213336 [化41]

Compounds 珑 R1 R* R5 R4 R7 R9 X1 IJ-A ~ch3 -COOCjHs -ch3 —CH3: —ζ} ch2cooh —CH3 HjO 61 201213336 [Chem. 42]

Compound No. R9 Compound No. ΙΠ-1 -ch3 -ch3 ID-2 C2H6 —CHC4H9 -ch3 Uh3 -C4H9(t) -ch3 m-4 ?zh5 -CHC4Hg (p2H5 •&quot;CHC4H9 III-5 -c4_ -c4h9 (1) 1Π-β -ch3 1Π-7 s-c4H9 —chch3 -ch3 ma —CH2〇CH3 —CH3 ΙΠ-9 —CH—OQ-OCHs —ch3 ΠΜ0 —CH3 Π 11 11 —ch-s-ch2cooc2h5 0H3 —ch3 π 12 ch3 —0=CH2 —ch3 ΠΜ3 9H3 —C—COOCH, 0H3 —ch3 ΠΙ-14 a co-ch-coch3 ch3 -ch3 ΠΗ5 —ch2och2cooc2h5 —ch3 ΠΜ6 —ch2nhso2ch3 —ch3. ΠΙ-17 &quot;CHNHS02CH3 0H3 -ch3 ΠΙ-18 —chnhso2ch3 ύ2Η5 -ch3 ΠΗ19 —chnhso2ch3 c4h9 -ch3 Π卜20 —chnhso2ch3: ch3 ch3 -ch3. ΠΙ-21 -chnhso2-c4h9 ch3 -ch3 m-22 -CHNHS02-^Q)-CH3 CH3 —ch3 ΠΙ -23 —CHNHSO,一^” CH3 I H3C02SHN -ch3 Di-24 P2H5 -CHNHSd2-N CH3 'C2H5 ~〇H3. 62 201213336 J//2Jpif [化43]

Compound No. Re Re Compound No. R? (f UF25 - CHs Ili-26 -ch^ch2cooc2hs_ -ch3 Ιϊί-27 CHa -CH3 IHr28 CHg -6h-shQ- -CH3 :Π卜29 -CH2NHS02qH3, -CH^HSOjCHg ΙΪΙ -30 -ch2-chnhso2ch? 6H3 -CH2-CHNHS03CH3 0H3 -CH2NHSp2CHi repair-CHC4H3 IU-32 -ch2-chnhso2ch3 ch3 ΙίΙ-33 -CH3 Hl-34 -ch2-chnhso2ch3 CHs, 63 201213336 [化44]

Compound No. R8· R9 Compound Codification R9 f? 01-35 One CH3 ΠΙ-36 ~〇nhso2gh3 One ch3 II Bu 37 〇nhs〇2ch3 -CH3 10^38 &quot;^ihsoj-Q -ch3 ΠΙ-09 —CH3 ΠΙ -40 ~〇dCH3 -CH3 ΙΠ-41 -ch3 ΠΙ-42 ~Q ch3 so2nch3 -ch3 0卜43 -Q-SCH3 -CH3 ΠΜ4 -·^^-S〇2CH3 -ch3 64 201213336 [化45]

Compound number: R8 R® Compound number R9 UR5 —ch3. —ch3 HM6 92Ηδ ~CHC4H9 C2H5 —CHC4h% UF47 -c4h3 (1): U1H18 -0 ΙΠτ49 -CH2NHS〇2CH3, BI-50 —CH3NHS02〇H3 —CH2NHS02CH3 IU-51 — CHNhS〇2CH3 0H3 ^-ch3 Bi-62 -CHNHS02CH3 —CHNHSb2CH3 0H3 m-53 -CHNHSC^iCH^ 64Hg -CH3 ΠΙ-54 ~Q NHS〇2CHb -ch3 -q NHS^CH3 NHSQ2CH3 01-56 SOiNHCOCf^. TMch3 [Chem. 46] CHj

P Lin TOC ) R8 A K ! XR9

〇Sb&amp; c^m

X3H Compound No. R8 Compound No. R8: JD-57 -&lt;&gt;CH3 -ch3 11F58 -〇^H3 c% chT CHi IU-59 ~Q OCH^jOH -ch3 CXX)OH3 TMCH3 〇Ch3 7=\ Touch 1 0明—ch3 NHS02PH3 Ϊ0-63; ~Q —ch3 (4) ☆ 65 201213336 J / /zjpif [化47]

C^Hgd) ch3-/ \-ooc C,Hg(t) Compound 珑R3 R4 R5 R6 R9 [Π-65 A CHa -CHa —COOC2H5 -CH3 -ch3 Hi-66 —ch3 -CH3 —C00C2Hs —CHNHS〇 2CH3 0Ha —CHNHS02CH3 0H3 iil-67 ~ch3 —ch3. —COOC2H5 NHS〇2CH3 &lt;X NHSOsCHs m-68 O —CHg. —COOC2H5 —CHa —ch3 111-69 —o ~o —COOCaHg —CHa —c.h3 IH-70 -ch3 ~o C· -C00-/^)-CH3 —ch3 —CH2NHS02-^^-CH3 [化48]

Compound No. R3 R4 R5 R8 R* BI-71 CHa —co-nch3 —CH3 —CH2NHSP2^^^-CH3 ΠΙ-72 -〇C3H?(i8〇) -CO-iilC3H7(Iso) —ch3 —CH2NHS〇2- ^^-CM3 HI-73 ~o -〇—ch3 —CH2NHS〇2-^=^-CH3 DI-74 0 -0 CHa —conh^^^-ch3 —ch3 ~CH2NHSP2TM^^-CH3 QI-75 ~ o CH3 yaTM, -°0Ν-〇-ch3 -CH2NHS02-^^&quot;CH3 66 201213336 [化49]

Compound number R3 R4 Ff R9 ΗΗ7β -gh3 —ch3 —CH3 «Η7 -ch3 —chnhso2ch3. ch3 —ch3 ΠΗ78 ~~CH3 —0H3 —qHNHS02CH3 CHj —chnhso2ch3 έΗ3 ΗΙ-79 —ch3 —CH3 —chnhso2ch, 6h3 —CHNHS02CH3 ch3: Dh80 -ch3 -0 -ch3 -ch3 ΗΗ8ί -ch3 ~o -ch3 —chnhso2ch3 ch3 ΠΙ-82 -CH3 0 —CHNHS02eH3 ch3 -CHNHS02CH3 ch3 67 201213336 37723pif [化50]

Compound number R3 R8 R9 UF-83 a ch3 O -CHNHSO2CH3 0H3 —chnhso2ch3 0H3 ΠΙ-84 —ch3 ~o —CHNHS〇2pH3 nhso2ch3 m-85 -ch3 0 -CiH9(t) nhso2ch3 m-86 o -ch3 -ch3 —ch3 m-Bi -o -ch3 —ch2nhso2ch3 -ch2nhso2ch3 --o 〇~CH3 -ch3 ΙΠ-89 -~ch^ NHSO2CH3 —ch3 -CH3 68 201213336 [化51]

Compound number Rf* if R9 12-90 -ch3 -CH3 —ch3 DH91 -ph3 -ch3 ^Ch3 —CHNHS〇2QH3 C4H9 m-92 —CH3 —ch3 —chnhso2ch3 c4h9 —hCHNHSO^H3 C4H9 ΠΗ93 〇—cr3 —CH3 Dh$4 〇-C4He(t) -C4H90) 10-95 ~o ^O —chnhso2ch3 C4H9 -C4H9(t) ΠΗ9β -〇~o NHS〇2CsH17 .-rOHj m-97 ~o rgHS〇2GH3 ~Q rjHS〇2CH3 —ch3 ~PH3 69 201213336 [化52] R3 μ R4

Compound No. R3 R4 R9 ΙΠ-9Β p ch3 ch3 ^CHs —CH3 12-99 —CH3 —CH3 m-ioo ~O~°qH3 —(3~PCH3 -ch3 —CH3 ΠΗ101 ~Q ~Q a ch3 a ch3 m- 102 CH3 —0HC2H5 ch3 -CHC2H5 —chnhso2ch3 c4h9 —chnhso2ch3 04H9 hh〇3 -0 &quot;Q NHS02C3Hi7 ^Q NHS02CsH17 70 201213336 [Chem. 53]

Compound No. R7 R8 ΠΙ-Α -/j| CHzCQOH -c4_ —〇4Η9(ί) [Chem. 54]

Compound No. R, R5 R7 R8 R9 1Π-Β -CHj -ch3 -goog2h5 oi2cooh a ch3 a ch3 71 201213336 37723pif [化55]

Compound No. R3 R4 R7 R9 I1I-C —CH3 -ch3 CH2COON —CH3 -ch3.

[化56]

C4_ -^3~ch3 Compound number R8 R9 W-A σ 72 201213336 37723pif [化57]

OH: Compound No. r3 R4 Rs P7 Rs R9 «1-65-2 HjC 丫CH3 Κ3〇γ.ρΗ3 -cooc2h5 —H -ch3 -CH3 ,70,2 he:丫cri3 H3CyCH3 -coo-Q-ch3 One H &quot ;CH3i -ch2nhs〇2^^^-ch3 HhB-2 HaCyCHa ftc 丫C"3 -GOOC2H5 CHaCOOH -ch3 -ch3 [化58]

Compound No. R3 R4 r7 III-90-2 H3C CH3 T H3G^CH3 —H -ch3 -ch3 in-C-2 H3C^CH3 h3c 丫ch3 ~ψ CH2〇QQH , —ch3. -ch3; From the viewpoint of film thickness It is preferable that the Mohr absorption coefficient of the specific complex compound in the present invention is as high as possible. Moreover, from the viewpoint of improvement in color purity, 73 201213336 The maximum absorption wavelength Xmax is preferably 520 nm to 580 nm, more preferably 530 nm to 570 nm. Further, the maximum absorption wavelength and the molar absorption coefficient can be measured by using a spectrophotometer UV-2400PC (manufactured by Shimadzu Corporation). From the standpoint of solubility, it is preferred that the melting point of the specific complex in the present invention is not too high. The specific complexes in the present invention can be obtained by U.S. Patent No. 4,774,339, U.S. Patent No. 5,433,896, Japanese Patent Laid-Open Publication No. Hei No. Hei. No. 2002-155052, and Japanese Patent Laid-Open No. 2002-155052. No., Australian Chemical Journal (AustJChem), 1965, u, 1835-1845, JHB〇ger et al., Heteroatomatology (Heter〇at〇m

Chemistry) synthesized by the method described in 'V〇U, N〇 5' 389 (199 〇). With regard to the synthesis method of the specific complex in the present invention, the method described in paragraphs [〇131] to [〇157] of JP-A-2008-292970 can be specifically applied. The photosensitive coloring-curable composition of the present invention may be used alone or in combination of two or more. The content of the specific complex compound of the invention in the coloring curable composition varies depending on the ray absorption coefficient and the molar absorption coefficient, and is preferably 10 wt% with respect to all the solid content components of the colored curable composition. 70% by weight, more preferably i〇wt% 〜5Gwt%, most preferably 15wt%~3〇wt%. [(A-2) phthalocyanine-based pigment] The phthalocyanine-based pigment used in the present invention is not particularly limited as long as it has a phthalocyanine bone/member. In addition, as a phthalocyanine pigment, 74 201213336 constitutes a phthalocyanine skeleton metal. 'There is no special zinc, Shao Zuo i center ^ Use town, Qin, iron, aunt, Jin, steel, 15, month ^ 敝 敝For the pigment, specifically, C.1. Pigment Blue 1, Γ 抖 抖 Blue 15 · 1, C·1. Pigment Blue 15: 2, CL Pigment Blue 15: • • Pigment Blue 15: 4, CI Pigment Blue 15 :5 (:1 Pigment Blue 15:6, • j Material Blue 16, CI Pigment Blue 17: Bu C丄 Pigment Blue 75, c 颜颜&quot;C.1. Pigment Green 7, CI Pigment Green 36, CI Pigment Green 37, 1 chemistry, phthalocyanine, phthalocyanine oxide, zinc (4). Among them: from: in terms of twinning and coloring, preferably CJ pigment Μ 15 J staff material blue 15:6 , Pigment Blue 15:1, CI Pigment Blue 15:2, and especially CI·Pigment Blue 15:6. 疋The phthalocyanine pigment of the present invention is in the coloring curable composition. Preferably, all solid components are wt/〇~70 wt°/〇, more preferably 2〇wt%~6〇wt%, optimal wt%~5〇wt%. 疋35 and 'as The specific ratio of the specific complex to the phthalocyanine pigment is preferably, the phthalocyanine Material: Specific complex = 1 〇〇: 5~1 〇〇: 1 〇〇, better 疋 100. 15~100: 75 ' Further better is 1 〇〇: 25~1 〇〇: 5〇 [(B) Dispersing Agent] The colored curable composition of the present invention contains (B) a dispersing agent. (B) A known pigment dispersing agent or a surfactant is used as the dispersing agent. As the knife agent, various compounds are used, for example, Listed ugly phthalocyanine derivatives (commercial product EFKA-745 (manufactured by café, s〇lsperse 5〇〇〇75 201213336 (made by Lubrizol Co., Ltd.); organic poly oxyhydrogenated polymer KP341 (Shin-Etsu Chemical Co., Ltd.) Manufactured, (mercapto) malonic acid (co)polymer Polyflow Νο.75, Νο.90, Ν〇·95 (above manufactured by Kyoeisha Chemical Co., Ltd.), wool (袼商股份有限公/ Is a cationic surfactant; polyoxyethylene lauryl scale, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene octyl phenyl ether, polyoxyethylene nonyl phenyl ether, Polyethylene glycol dilaurate, polyethylene glycol distearate, sorbitan fatty acid ester, etc. Ionic surfactant; W004, W005, W017 (above manufactured by Yushang Co., Ltd.) and other anionic surfactants; EFKA-46, EFKA-47, EFKA_47EA, EFKA polymer 1〇〇, EFKA polymer 400, EFKA polymer 401, EFKA polymer 450 (above manufactured by Morishita Industrial Co., Ltd.) and other polymer dispersants; Solsperse 3000, 5000, 9000, 12000, 13240, 13940, 17000, 24000, 26000, 28000 and other Solsperse dispersants (manufactured by Sakamoto Lubrizol Co., Ltd.); Adeka Pluronic L31, F38, L42, L44, L61, L64, F68, L72, P95, F77, P84, F87, P94, L1 (U, P103, F108, L12, P- 123 (above manufactured by ADEKA Co., Ltd.) and isonet S-20 (manufactured by Sanyo Chemical Co., Ltd.). The content of the (B) dispersant of the present invention in the colored curable composition is preferably from 1 wt% to 80 wt%, more preferably from 5 wt% to 70 wt%, based on the pigment. Wt%~60 wt%. [(C) Polymerizable Compound] The colored curable composition of the present invention contains (C) at least one selected from the group consisting of polymerizable compounds represented by the following formula 76 201213336 37723pif (MO-1) to (MO-5) 1 compound. [化 59] 〒 (1) Juemin

Rfr]-GH2-c-eH2ip|rR rn-i) CH God R

CH2-f-TtR R#)iCH2-Q~GH2-^-CH2-C-CH2-HfrR (HO-2) ch2 butterfly; GH2-fT^RR oblique CH? CH24-T-tR —0-CH2 ~c —ch2^t4-r (MO-3) R-fT^.GHj CH2f%R ch2-Hr 1 (»〇-4) R~HCH2- 〇丫Ny〇-N r4_2-n 丫n'chA 0 , CH24TtR (MO-5) [Chem. 60] ch3. R: H2C*CH-C-0- H2C-CC-0- -〇^C-fCH2^-a-pH -0-C-^iH-(CH2^COH -OH T: . -〇CH2~ t -OCH2CH2- ^ -OCHsCHjCHj- , -OCHjCHjCHjCHj- Z: -Q-CrNH-(:CH3^NH-€-0-- in general formula (MO-1)~ (MO-5), n is 0 to 14 of 77 201213336 ^// ^^υιϊ integer, ml~m4 is an integer of 丨~8. Multiple R and T existing in the same molecule may be the same or different Further, in each of the polymerizable compounds represented by the general formula (MO-1) to the general formula (M0_5), at least one of the plurality of R present is represented by (MO-2), and Z is ··· In the case of the above, or w_〇c(=o)ch=ch2. In addition, in the description #, the general name of the propyl group and the fluorenyl acryl group are sometimes described as (meth) propyl _ And the general name of the acid ester is described as (meth) acrylate. /, methacrylic), preferably η 0. Moreover, it is preferably ml~ from the general formula (MO-1) to the general formula (M〇_5 to 14 integers, more preferably 〇~2, the integer m4 is an integer of 1 to 8, more preferably Is 丨~2. ~ r in the general formula (purchased), at least i of the plurality of R existing in the same knife can be ch2, or -0C(=0)C(CH3)=CH2. Other meanings' It is preferably the following group. 』 即江T之[化61] 0

• OH and f t groups and m2 are integers from 1 to 8. Preferably, ml and m2 are integers of 1 to 2. T, the above-mentioned knot is 78 of the general formula (MO-1) to the general formula (M〇_5). 201213336 3 Ί /Ζόρΐί The structure is preferably -(CH2)m-, -〇CH2_, particularly preferably - (CH2)m_. Moreover, Z is preferably -〇-. The presence of multiple R and τ in the same-molecule may be different, and is preferably the same from the standpoint of ease of synthesis. In the polymerizable compound represented by the formula (ΜΟ-1) to the formula (Μ〇_5), it is preferred that the compound represented by the formula (Μ(Μ), 35 ((αα)) is particularly preferable. a compound represented by the formula (ΜΟ-2), wherein 'excellent is represented by the formula (Μ0·2), and at least one of the groups represented by the formula (μ〇2) [化62]

'Q&quot;?^CH2fcrf0H In the above base, ml and m2 are each an integer of 〜8. - Object: ~ The polymerizable substance represented by the formula (M0_5): The system is not as follows. The present invention is not limited to these specific examples. Propionate=Diisocyanuric acid triacrylate, 8-hexene_modified tris-(2·ylethyl)isophthalic acid vinegar, ethoxylated glycerol three-purpose, Ϊ t propylene vinegar , tri-methyl methacrylate, di-trimperanthene, tetra-tetrapropene, ethoxylated pentaerythritol tetraacrylic acid, quaternary oxime, diquaternary hexapropene, dipentaerythritol Five = olefin H hexa(propylene oxyethyl ethoxy) dipentaerythritol, two quarters pentacene _ _ acid mono g |, trisyl propyl trimethyl propyl 79 201213336 The color hardening composition of the present invention The compound contains at least one type of polymerizable compound represented by the formula (MO-5) and is composed of two or more types. In the case of two or more types, the formula may be The two or more kinds of polymerizable compounds may be different from the above two types: two or more kinds of polymerizable compounds which are shown. In addition, the colored hardening composition of the present invention may also be (MCM) to the formula (M). (5) Polymerizable compound having a structure other than the polymerizable compound represented by the formula (5), which is a polymerizable property other than the poly-human compound represented by the formula (MO-1) to the formula (MO_5) The compound (hereinafter referred to as "other polymerizable compound") may, for example, be an unsaturated Wei (for example, C-/methacrylic acid, itaconic acid, crotonic acid, methacrylic acid or maleic acid) or an ester thereof or an anthracene thereof. The amine is preferably an ester of an unsaturated carboxylic acid and an aliphatic polyol compound, an amide of an unsaturated carboxylic acid and an aliphatic polyamine compound. Further, an addition reaction product of an unsaturated carboxylic acid vinegar or a urethane having a nucleophilic substituent such as a hydroxyl group, an amine group or a fluorenyl group with a monofunctional or polyfunctional isocyanate or an epoxy group, and a monofunctional or polyfunctional group The product of dehydration condensation reaction of a functional carboxylic acid or the like may be used in combination as another suitable polymerizable compound. Further, 'as another polymerizable compound, an unsaturated carboxylic acid ester having an isocyanate group or an electrophilic substituent such as an epoxy group or an oxime amine and an addition of a monofunctional or polyfunctional alcohol, an amine or a thiol The reactants, in addition to the derivatized substituents such as i groups or tosyloxy groups, the unsaturated carboxylic acid esters or guanamines and the monofunctional or polyfunctional alcohols, amines, sterols, substituted reactants good. Further, as another example, a compound group obtained by substituting an unsaturated phosphonic acid, 201213336 ± styrene, vinyl ether or the like may be used instead of the upper carboxylic acid. As specific examples of the monomer of the aliphatic polyol compound and the unsaturated acid-free ester, as the acrylate, there are ethylene glycol diacrylate, triethylene glycol diacrylate, and 1,3-butanediol diacrylate. , : ^butanediol diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, trimethylolpropane triacrylate, trishydroxypropyl propane tris(propylene oxypropyl) ether: Diol diacrylate, 1,4-cyclohexanediol diacrylate, tetraethylene glycol diacrylate, pentaerythritol polyacrylate (acrylate number i 10), pentaerythritol polyacrylate (acrylate number) It is i~i2), sorbitol tripropionate, sorbitol tetraacrylate, sorbitol pentaacrylate, sorbitol hexaacrylate, polyester acrylate oligomer, and the like. As a mercapto acrylate, there are 1,4-butanediol dimercapto acrylate, triethylene glycol dimethacrylate, neopentyl glycol dimercapto acrylate, trimethylolpropane trimethacrylate Ester, trihydroxydecylethane trimethyl methacrylate, ethylene glycol dimercapto acrylate, 1,3-butylene glycol dimethacrylate, hexanediol dimercapto acrylate, sorbitol Tridecyl acrylate, sorbitol tetradecyl acrylate, bis[p-(3·methacryloxy-2-hydroxypropyloxy)phenyl]dimercaptomethane, bis-[pair (methyl Acryloxyethoxyphenyl]didecyldecane, etc. Α As an isoconate, there are ethylene glycol di-conconate, propylene glycol diconic acid vinegar, and 1,3-butylene glycol diacon Acid ester, l,4-butanediol diitaconate, tetmmethylene glycol diitaconate, pentaerythritol diconic acid 201213336 37723pif ester, sorbus Sugar alcohol, tetraconcanic acid vinegar, etc. As crotonic acid vinegar, butyl diol dicroton vinegar, W, ethylene glycol disorbitol tetradecanoate, etc. Bean ester, quaternary tetraol: iso-diethylene glycol diacid vinegar, etc. As a maleic acid, there are ethylene glycol di horse = alcohol tetraisobutylate, etc. Penta-Malay _, Shanxu alcohol Four Malay sour vinegar as another cool example, for example, it can also be used in the Japanese version of the bulletin, the Japanese patent special _ 57 j public Zhao == family alcohol system _, or the patent special opening Kai = Shang, Japanese patent special opening Zhao Japanese Patent Publication No. 59-5241, No. 2, No. 2, which has an aromatic skeleton, == described in Japanese Patent Publication No. 1.165613, and the like, and the vinegar monomer can also be used as a mixture.土-曰= and 'As for its recorded compound, as a polyamine for the aliphatic occupation. _, with a monomer of _ _ _, has a cone of acrylamide, methylene bismethyl propyl _ Amine, W hexamethylene bis- oxalate = amine: 1,6-hexamethylene bis-decyl propylamine, diethylenetriamine tripropylamine, the present dimercapto bis acrylamide, benzene Methyl dimethyl propyl amide, etc. As an example of another preferred axial rotator, a sulphate structure having a stretched ring structure as disclosed in Japanese Unexamined Japanese Patent Publication No. 54-2Π26. As other aggregation A compound, a polyurethane-based addition polymerizable compound produced by an addition reaction of an oleic acid vinegar and a base group is also preferred, and 82 201213336 ^ / /z^pif is exemplified as such a specific example, for example, a Japanese woman (4) The polyisocyanate compound having a 2 _ upper hetero- hydroxy group in the oxime molecule described in Japanese Patent Publication No. _41708 is added to the i molecule containing the η group represented by the following formula (v) A vinyl urethane compound containing two or more polymerizable ethylenediyl groups, etc. [Chem. 63] CH. im) CO: aeH^G: H (R; ^j OH; Formula (V) CHi In the formula (V), the ruthenium and the ruthenium 5 each independently represent 11 or ruthenium, and other than the polymerizable compound represented by the formula (M〇_l) to ϋϋ5) in the compounds described in the following documents. The poly-5-formed σ material of another structure may also be combined with the polymerizable color-curable composition of the present invention. It is preferably used in the Japanese Patent Laid-Open Publication No. H07-37193, the Japanese Patent Laid-Open No. 2-32293, and the Japanese Patent Publication No. Hei 2_16765, or the Japanese Patent Publication No. Sho. Japanese Patent Publication No. 49,860, Japanese Patent Publication No. Sho 56-176, pp. H-Han, and Japanese Patent Publication No. Sho 62-39418, the amine phthalate compound of the 1 octyl oxyethylene skeleton, and the Japanese patent Japanese Patent No. 63_277653, Japanese Special (4) No. 0909-8, and Japanese Patent Special Kaiping No. 52, which are contained in the molecule, have an amine group structure or an thioether structure, and are added and polymerized. 83 201213336 Compound, Japan Polypropylene acrylate vinegar, epoxy resin and (meth) epoxide acrylate described in Japanese Patent Publication No. 83, Japanese Gazette, Japanese Gazette No. 52_3_ Polyfunctional propylene oxime esters such as methacrylic acid S, Japanese Patent Publication No. Sho 46_43946, Japanese Special Publications, Japan _ Fair MG336 f_ jin. Unsaturated compounds of the special enthalpy, 曰本专利专开平2_The ethylidene phosphonic acid compound contained in the U report, the structure containing the perfluoroalkyl group described in the Japanese Patent Publication No. VO1.20, Να7, and the third 〇〇~3〇8 pages ( a compound which is described as a photocurable monofilament in 198. The polymerizable compound in all the solids of the colored curable composition, the amount (the total content in the case of two or more kinds), is not particularly &amp; 疋 'from the more effective way to obtain the effect of the invention, better job ~ 80 wt%, more preferably 15 correction % ~ 75 (four) is

Wt% ~6〇wt〇/o.耵疋 20 [(D) Photopolymerization initiator] The color hardening composition of the present invention contains (D) a photopolymerization initiator. The photopolymerization initiator is preferably one which can limit the above-mentioned (c) compound which is selected from the above-mentioned (=_υ~polymerizable compound represented by the general formula (MO_5)). ^, start efficiency, absorption wavelength, availability, and cost are selected. For the photopolymerization initiator, for example, at least one selected from the group consisting of _methyl group, oxadi-salt a substance, and decyl-s-trimide活性Active tooth combination 84 201213336, 3-aryl substituted coumarin compound, phenanthrene 2 mer, benzophenone compound, acetophenone compound and its derivative, cyclopentadiene _ benzene-iron And a salt thereof, a ruthenium compound, etc. Specific examples of the photopolymerization initiator include the compounds described in paragraphs [〇〇7〇] to D077] of JP-A-2004-295116. The ruthenium-based compound (hereinafter also referred to as "anthraquinone photopolymerization initiator") is not particularly limited as long as it is rapid in terms of the polymerization reaction, etc. Open 2〇〇〇_8〇〇68 Bulletin, W002/100903ABu Japanese Patent Special Open 2 An anthraquinone compound described in 001-233842 or the like. Specific examples thereof include 2-(0-benzoquinone)-1-[4-(phenylthio)phenyl]-1,2·butanedione , 2-(0-benzoquinone)-1-[4-(phenylthio)phenyl]-152_pentanone, 2·(0-曱醯月曱醯 deficit)-1-[4_(phenylthio) ) stupid]-i, 2_hexanedione, 2-(0-abbreviated), ι·[4_(phenylhydrazo)phenyl]-1,2-heptanedion, 2-(〇- Benzoquinone-branched acetonitrile--1-[4-(phenylthio)phenyl]·1,2-octanedione, 2-(indole-benzoquinone) small [4-(methylphenylthio)benzene 1,2-butanedione, 2-(〇-benzoquinone M-[4-(ethylphenylthio)phenyl]-1,2-butanedione, 2-(〇_benzene -1-[)(4-(butylphenylphenyl)phenyl]-1,2-butanedione, _(〇_乙醯躬·)-1-[9-ethyl-6 -(2-methylbenzhydryl)-9H-leaf·β--3-yl]ethyl g, 1_(〇-乙糖)-1-[9·曱基-6-(2-曱Benzomethanyl)_9H-flavor-3-yl] ethyl ketone, 1-(〇_乙醯肟) small [9-propyl-6-(2-mercaptobenzoyl)_9H-咔-3-yl]ethyl brewing j, ι_(〇_乙醯躬τ)-1-[9-ethyl-6·(2-ethylbenzoinyl)-9Η-咔峻-3-yl]B Ketone, 1-(〇-乙糖)-1-[9-ethyl-6-( 2-butylbenzimidyl)-9H-flavor α-yl-3-yl]ethanone, but not limited to the compounds 85 201213336. In these compounds, the shape is obtained with less exposure. (especially in the case of solid-state imaging elements, the rectangular shape of the pattern). In terms of a good pattern, it is particularly preferable that 2_(0_benzamide)-1·[4-(phenylthio)phenyl ]-1,2-octanedione, 1-(〇·乙醯肥)-Η9-ethyl-6-(2-methylbenzhydryl)-9H-indazol-3-yl]ethanone, etc. Specific examples of the fat-hydrazine-based compound include OXE-01 and oxE-02 (all manufactured by BASF Corporation). Further, in the present invention, the self-sensitivity, the stability over time, and the compound represented by the sensation when used in the production of a color i-ray sheet. Considering that it is better to hire a compound, the viewpoint of the prevention of bleed, Π., ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,

General formula

In the above formula (d-1) to formula (d-4), R22 and X22 each independently represent a monovalent substituent, A22 represents a divalent organic group, and Ar represents an aryl group. η is an integer of 1 to 5. A plurality of R22, X22, A22, and Ar may be the same or different. R22 is preferably a mercapto group from the viewpoint of high sensitivity, and is particularly preferably an ethyl sulfonyl group, a propyl fluorenyl group, a ruthenium group or a toluene group. As A22, from the viewpoint of improving the sensitivity and suppressing the coloring caused by heating over time, an unsubstituted extended alkyl group, a burnt group (for example, methyl group, ethyl group, tert-butyl group, dodecane group) is preferred. a substituted alkyl group substituted with a benzyl group (eg, a vinyl group, an allyl group), an aryl group (eg, phenyl, p-tolyl, diphenyl, cumyl, naphthyl, anthracene) Alkyl, phenanthryl, styryl) substituted alkyl. As Ar, a substituted or unsubstituted phenyl group is preferred from the viewpoint of improving sensitivity and suppressing coloration caused by heating over time. In the case of a substituted phenyl group, the substituent is preferably, for example, a halogen atom such as a chlorine atom, a chloro atom, a bromine atom or an iodine atom. In the case of X22, from the viewpoint of improving solvent solubility and absorption efficiency in a long wavelength region, an alkyl group which may have a substituent, an aryl group which may have a substituent, or a substituent may be preferable. An alkynyl group which may have a substituent, an alkoxy group which may have a substituent, an aryl group which may have a substituent, a base which may have a substituent, a thiol group having a substituent, and an aryl group which may have a substituent Ducks may also have a silk of substituents. Further, it is preferred that n in the formula (d-Ι) to (d-4) is an integer of from 1 to 2. The compound represented by the formula (4)) to the formula (d_4) is represented by the following, but the present invention is not limited to these specific examples. 88 201213336 37723pif [化65]

89 201213336 [化66] Ο

Cl

Further, in the color hardening composition of the present invention, other known photopolymerization initiations as described in paragraph _9 of JP-A-2004-295116 may be used in addition to the above-mentioned photopolymerization initiator. Agent. The photopolymerization initiator may be contained alone or in combination of two or more. The effect of the silk of the present invention is effectively obtained, and the content of the photopolymerization initiator in all the solids of the colored hardened product (the total content in the case of two kinds of 201213336 or more) is preferably 3 wt. %~20 wt%, more preferably 4 wt%~19 wt% 'extra good is 5 wt%~18 wt%. - Sensitizing dye - The coloring composition of the present invention may also contain a sensitizing dye as needed. The sensitizing dye can promote the radical polymerization reaction of the photopolymerization initiator or the like, or the polymerization reaction of the photopolymerizable compound, by exposure to a wavelength at which the sensitizing dye can be absorbed. Examples of such a sensitizing dye include known spectroscopic dyes or dyes, or dyes or pigments which absorb light and interact with a photopolymerization initiator. (Specifying sensitizing dye or dye) The sensitizing dye used in the present invention is preferably a spectroscopic coloring dye or a dye, and examples thereof include polynuclear aromatics (for example, ruthenium, osmium, and terphenyl), and dibenzopyran. Classes (such as luciferin, blush, red erythro, red rose B, bengal rose red), cyanine (such as thiocyanine, carbocyanine), merocyanine (such as merocyanine, Carbon (Cyanine), thiazides (such as thioindigo, ^ I-blue, fluorene) "quote (such as ^ 丫 recorded, aflatoxin, decantane = prime), phthalocyanines (such as phthalocyanine) , metal phthalocyanine), porphyrins (such as four stupid base, center, metal substitution „Blin), chlorophyll (such as chlorophyll, chlorophyllin, central metal instead of chlorophyll), metal complex (for example, , onion noodles, (such as green onion), Squarlin (_

Such as Squarlin) and so on. An example of a better spectroscopic sensitizing pigment is exemplified below. "The vinyl-based coloring matter of the Japanese Patent Publication No. π. 4, Japanese Patent Publication No. 62-M3044, No. 91, 201213336, the cationic dye contained in the Japanese Patent Publication No. 62-M3044; Japanese Patent No.: the new indenyl blue compound described in the publication No. F24147; the benzoxene onion described in the No. 4, No. 4, No. 4 publication Dyes; in the 曰 公报 公报 日本 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 2 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 148 Patent Kaiping 2-85858, 曰^^ and °funan pigment; 曰本专利特=咖曰本本专开桂皮二==:== Recorded azo-Asian pigment; 曰本专利=3 == 2:Special ==Report: The merocyanine pigments described in the _Ethylene 2-244 (4) bulletin: 59-28326 1 The official statement of the tiger's bulletin 2 = Gong Zhao == recorded = -1292^ The phthalocyanine pigment recorded in the publication of the publication; benzoxanthene pigment described in the publication No. 8_334897. Special open thousand (pigment with a maximum absorption wavelength at 35〇nm~45〇nm) 92 201213336 J/VZJpif Combination: increase = other preferred aspects, which can be listed as the following compounds. Examples of the color having a maximum absorption wavelength at 35G (10) to 450 nm include polynuclear aromatics (for example, the present invention (for example, fluorescein North (four) one), the bengal rose red), and the cyanine class 1. Rose red β, methyl blue, toluidine blue; two: === flavonoid, class (7) (4), squarin sensitizing pigment, can improve the color hardening property of the present invention Various chemical biochemicals as described below were carried out ^h=lcal m〇dification). For example, by bonding a sensitizing dye to an addition polymerizable compound propyl group or methacryl oxime group by a covalent bond, an ionic bond or a hydrazone bond, a crosslinked cured film can be obtained. The effect of the south strength or the suppression of the pigment from the self-crosslinking hardening film is unnecessarily. The content of the sensitizing dye is preferably 0.01 wt% to 20 wt%, more preferably 〇〇1 wt% to ^ wt%, based on all solids of the colored curable composition. Further preferably ( u wt% 〜5 wt%. ° By setting the content of the sensitizing dye to this range, the sensitivity to the exposure wavelength of the ultrahigh pressure mercury lamp is high, and the film deep hardenability is obtained, and the development margin and pattern are obtained. It is also preferred in terms of formability. • Hydrogen-donating compound - 93 201213336. In the present invention, the color-hardening composition contains a hydrogen-donating chemical or a photopolymerization initiator having the following effects: sensitization The color height, or __ 细 之 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 进一步 。 。 。 。 。 M M M M M M M M M M M M M M M M M M M M M M M M M M Journal publication (Journal〇fP〇lymer 44-20139 ^1 bulletin, Japanese patent special ^2, Japanese patent special open 59_138205 Zhao 62-18537 No. 8 Hao Hao ^ 4305 bulletin, Japanese patent special open (RelearchDiLost!^ ^31°4' compound, etc., specific vinegar 'heryl dimethyl sulfonamide Formic acid = other examples of hydrogen compounds, can be classified as follows: 曰 专利 专利 专利 专利 专利 昭 公报 曰 曰 曰 曰 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 专利 硫 硫 硫 硫 硫 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Specific examples of the compound, the compound of Japanese Patent Laid-Open Publication No. JP-A No. 2-3, and the like, and the like are, for example, 2 - thiol benzopyrazine, 2 - hydrazino oxazolidine, 2-mercaptobenzimidazole sulfaphthalene, and the like. Η 2·_·4_· _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The organometallic compound described in the report (for example, tributyltin acetate 94 201213336 曰Ι ΐ 特 特 55 55 55-34414 供 供 Λ - - - - - - - - 55 55 Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ Λ - - - - - 。 。 。 。 。 。 。 。 。 。 。 The content of the hydrogen-donating compound with respect to the chain transfer is preferably m wt% to 3 g (10), more preferably 1 Wt, with respect to the weight of the color hardening property. ~. ~25 Wt% range, further better • 5 wt% ~ 2〇wt% range. [(E) Organic Solvent] f Invention The colored curable composition contains (E) an organic solvent. If it is an organic _ which satisfies the coating properties of the respective decomposable or sexual compositions, the merits of the work are to be considered. The binder is miscible, the coating property, and the safety are as long as the organic solvent. Examples of the vinegar include ethyl acetate, ethyl acetate, acetic acid, acetic acid, acetic acid, and acetic acid. C, Dingzhi, isopropyl butyrate, ethyl butyrate, butyl butyrate, milk ', nursery rhyme, ethyl ester, alkyl acetate oxidized (such as oxidized acetic acid 乙 'acetylated t-acid cool, The oxidized acetic acid butyl S (specifically, methoxy day, methoxyacetic acid ethyl acetate, methoxyacetic acid butyl vinegar, ethoxymethan-I ester, ethyl ethoxyacetate, etc.), 3_oxypropionic acid alkyl esters (dibenzylidene propionate, 3-oxypropionic acid) (specifically, alkoxypropionic acid methyl, 3, methoxypropionic acid B, 3, ethoxylated acid methyl 9, 3 - ethoxy propionate ethyl ester, etc.), 2 · oxypropionic acid alkyl esters (such as 95 201213336 2-oxopropionate, 2-oxygen Ethyl propionate, propyl 2-oxypropionate, etc. (specifically, decyl 2-methoxypropionate, ethyl 2-methoxypropionate, propyl 2-methoxypropionate, Ethyl 2-ethoxypropionate, ethyl 2-ethoxypropionate, etc.), 2-oxo-2-mercaptopropionate, ethyl 2-oxy-2-mercaptopropionate (Specifically, decyl 2-nonyloxy-2-mercaptopropionate, ethyl 2-ethoxy-2-mercaptopropionate, etc.), methyl pyruvate, ethyl pyruvate, pyruvic acid Propyl ester, acetamidine acetate, ethyl acetate, ethyl 2-oxobutanoate, ethyl 2-oxobutanoate, and the like. Further, examples of the ethers include diethylene glycol dioxime ether, tetrahydrofuran, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, methyl stilbene acetate, and ethyl stilbene acetate. Diethylene glycol monoterpene ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, propylene glycol monoterpene ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl ether acetate Wait. Examples of the ketones include methyl ethyl ketone, cyclohexanone, 2-heptanone, and 3-heptanone. Examples of the aromatic hydrocarbons include decene, diphenylbenzene, and the like. In view of the solubility of the above-mentioned respective components and the solubility in the case of containing an alkali-soluble binder, and the improvement of the coating surface, it is preferred to mix two or more kinds of these organic solvents. In this case, it is particularly preferred to comprise a decyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethyl celecoxib acetate, ethyl lactate, diethylene glycol Anthracene ether, butyl acetate, methyl 3-methoxypropionate, 2-heptanone, cyclohexanone, ethyl carbitol acetate, butyl carbitol, acetate, propylene glycol methyl ether, and A mixed solution of two or more kinds of propylene glycol oxime ether acetate. 96 201213336 The content of the organic solvent to be colored in the curable composition is preferably such that all solids concentration is from 10 Wt% to 80% by weight, and further, all solid concentrations in the confirmed substance are 15 wt%. ～60 wt% [(F) Other components] In addition to the above respective components, the color-curable composition of the present invention may not be known as a conjugate or a cross-linking component of the present invention. r ^ - alkali-soluble binder _ The 敕11 binder is not particularly limited in addition to the solubility m, and can be selected from the viewpoints of heat resistance, developability, and availability. The soluble binder is a linear organic high molecular polymer, and is preferably an organic compound, which can be developed by a secret aqueous solution. The organic polymer can be 59-446M%. Compounds, for example, Japanese Patent Laid-Open No. 58-12577 Γ 专利 专利 专利 343 343 343 A34327, Japanese Patent Special ^ 日 日 1 ^, 曰 专利 专利 54 54 54 54·25957, 曰 本 patent = household ^ 己53833 ! Tiger, Japanese Patent Laid-Open No. 59_71048, each of the public base thief copolymer, acrylic acid copolymer, itaconic acid &amp; material / touch copolymer, horse fabric, Ministry of money, maleic acid, can also be used It can be used as a soluble binder for the use of Wei's acid cellulose, or as a compound for the addition of sorrel on the poly-delta of the silk, or 97 201213336 Polylight-based benzophenone, fat, and Weiwei Resin, poly((mercapto)acrylic acid, base ethyl vinegar), polyethylene strontium. Ketone or polyethylene oxide, polyethylene glycol, and the like. Further, the linear organic high molecular polymer may be a polymer obtained by copolymerizing a hydrophilic monomer. Examples thereof include (indenyl) (10) acid alkoxy ketone, (mercapto) acrylic acid sulfonic acid vinegar, glycerol (meth) acrylic acid vinegar, (mercapto) acrylamide, N-methylol acrylamide, 2 or 3 alkyl acrylamide, dialkylaminoalkyl (meth) acrylate, morpholine (meth) acrylate, N-vinyl pyrrolidone , N-vinyl caprolactam, vinyl imidazole, vinyl triazole, (decyl) decyl acrylate, (mercapto) ethyl acrylate, branched or straight-bonded (fluorenyl) acrylate A butyl (meth) acrylate or a (meth) propyl acetophenoxy phenoxy propyl acetonate or the like. Further, as the monomer having hydrophilicity, a tetrahydrofuranyl group, a phosphate group, a phosphate group, a quaternary ammonium salt group, an extended ethyloxy chain, a propyloxy chain, a sulfonic acid group, and a source may also be used. A monomer such as a salt thereof or a N-morpholinylethyl group. Further, the alkali-soluble binder may have a polymerizable group in the side chain in order to increase the crosslinking efficiency. For example, the side chain may be an allyl group, a (meth) propyl group or a dipropyloxy group. Polymers, etc. As a polymer example containing the above-mentioned polymerizable group, KS resist-106 (manufactured by Osaka Organic Chemical Industry Co., Ltd.), Cyclomer P series (manufactured by DAICEL CHEMICAL INDUSTRIES, LTD.), and the like are commercially available. Further, in order to improve the strength of the hardened film, alcohol-soluble nylon or a polyether of 2,2-bis-(4-hydroxyphenyl)-propane and epigas alcohol may be used. Among these various soluble binders, from the viewpoint of heat resistance, 'preferably polyhydroxystyrene resin, polyoxyalkylene resin, propylene 98 201213336 acid resin, acrylamide resin, _(10), / The propylene shaft copolymer tree is preferably an acrylic acid resin, an acrylamide resin, or an acrylic/acrylamide copolymer resin from the viewpoint of self-developability control. The acrylic resin is preferably formed of a monomer selected from the group consisting of benzyl (meth)acrylate, (mercapto)acrylic acid, hydroxyethyl (meth)acrylate, and (meth)acrylamide. Copolymer, or Ks resist-106 (manufactured by Osaka Organic Chemical Industry Co., Ltd.),

Cyclomer P series (manufactured by DAICEL CHEMICAL INDUSTRIES LTD). The alkali-soluble binder is preferably a polymer having a weight average molecular weight (polystyrene equivalent value measured by a GPC method) of 1000 to 2×10 5 , more preferably 2 观点 from the viewpoints of self-developability, liquid viscosity, and the like. 〇~1χ1〇5 of the polymer, particularly preferably a polymer of 5000~5xl〇4. - Crosslinking agent - The coloring-curable composition of the present invention can also be used in a complementary manner to further improve the hardness of the colored cured film obtained by curing the colored curable composition. The crosslinking agent is not particularly limited as long as it can be cured by a crosslinking reaction, and examples thereof include an epoxy resin selected from a hydroxy group, an alkoxy group, and an anthracene group. a melamine compound, a guanamine compound, a glycoluril compound or a urea compound substituted with at least one substituent, and (c) a thiol group, an alkoxy fluorenyl group, and a fluorenyl fluorenyl group A substituted phenolic compound, a naphthalene compound or a genomic compound. Among them, a polyfunctional epoxy resin is preferred. 99 201213336 37/23pit For details of specific examples of the crosslinking agent, etc., reference is made to paragraphs [0134] to [0147] of JP-A-2004-295116. -Other Additives - Various additives such as a filler, a polymer compound other than the above, a surfactant, an adhesion promoter, an antioxidant, an ultraviolet absorber, and aggregation inhibition may be blended in the coloring-curable composition. Agent, development accelerator, and the like. The compounds described in paragraphs [0155] to [〇156] of JP-A-2004-295116 can be cited as such additives. (Interacting Agent) As the surfactant which can be added to the colored curable composition of the present invention, various surfactants can be added from the viewpoint of further improving the coatability. As the surfactant, a fluorine-based surfactant, a non-ionic surfactant, a cationic surfactant, an anionic surfactant, a poly-wet interface active fresh surfactant, and a secret carrier can be used. The colored hard ruthenium composition contains a fluorine-based boundary. The liquid property (special = fluidity) when the surface is prepared as a coating liquid can be improved to improve the uniformity of the coating thickness or the liquid-saving, / That is, in (4) the coating liquid (the coating liquid contains the gas-lined 3 active agent in the coloring hard recording group) (4) the shackles, you (4) the cloth surface and the coating boundary boundary are reduced, thereby And (4) Skin ^ is formed by a small amount of liquid to form a film of about _ = 100 201213336 J / / JiJlJll It is effective to form a film of uniform thickness having a small thickness unevenness. The fluorine content in the fluorine-based surfactant is preferably from 3 wt% to 40 wt%, more preferably from 5 wt% to 30 wt%, particularly preferably from 7 wt% to 25 wt%. The fluorine-containing surfactant having a fluorine content in this range is effective in terms of uniformity of coating film thickness or liquid-repellent property, and is also excellent in solubility in a coloring-curable composition. Examples of the fluorine-based surfactant include Megafac F171, Megafac F172, Megafac F173, Megafac F176, Megafac F177, Megafac F141'Megafac FI42'Megafac FI43'Megafac FI44'Megafac R30, Megafac F437, Megafac F475, Megafac F479, Megafac F482, Megafac F780, Megafac F781 (manufactured by DIC Corporation), Fluorad FC430, Fluorad FC431, Fluorad FC171 (above Sumitomo 3]y [manufactured by Suisse Co., Ltd.), Surflon S-382 - Surflon SC-101 ' Surflon SC- 103 ' Surflon SC-104 '

Surflon SC-105, Surflon SC 1068, Surflon SC-381, Surflon SC-383, Surflon S393, Surflon KH-40 (above manufactured by Asahi Glass Co., Ltd.), etc. Specific examples of the nonionic surfactant include glycerin, trihydroxydecylpropane, trimethylolethane, and ethoxylates and propoxylates thereof (for example, glycerol propoxylate, C). Triol ethoxylate, etc., polyoxyethylene lauryl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene octyl phenyl sulphate, polyoxyethylene decyl phenyl ether , polyethylene glycol dilaurate, polyethylene glycol distearate, sorbitan fatty acid ester (Pluronic L10, L31, L61, L62, 10R5, 17R2, 101 201213336 25R2, Tetronic manufactured by BASF Corporation) 304, 7 (U, 704, 901, 904, 150R1, Solsperse 20000 (made by Lubrizol Co., Ltd., Japan), etc. Specific examples of the cationic surfactant are phthalocyanine derivatives (trade name: EFKA-745, Morishita Industrial Co., Ltd.) Manufactured by the company), organopolyoxyalkylene polymer KP341 (manufactured by Shin-Etsu Chemical Co., Ltd.), (fluorenyl) acrylic (co)polymer Polyflow No.75, No.90, No.95 (Kyoeisha Chemical Co., Ltd.) Manufacturing Co., Ltd.), W001 (Yu Shang Co., Ltd. Specific examples of the anionic surfactants include W004, W005, W017 (manufactured by Yusei Co., Ltd.), etc. Examples of the polyoxo-based surfactants include "Toray Silicone DC3PA" manufactured by Toray Dow Corning Co., Ltd. , manufactured by Toray Silicone SH7PA, Toray Silicone DC11PA, Toray Silicone SH21PA, Toray Silicone SH28PA, Toray Silicone SH29PA, Toray Silicone SH30PA, Toray Silicone SH8400, Momentive Performance Materials Inc. "TSF_4440", "TSF-4300", "TSF-4445", "TSF-4460", "TSF-4452", "KP341", "KF6001", "KF6002", BYK Chemie manufactured by Shin-Etsu Trading Co., Ltd. "BYK307", "BYK323", "BYK330", etc. manufactured by the company. The surfactants may be used alone or in combination of two or more. (Thermal polymerization inhibitor) Further, the color-curable composition of the present invention The increase may be as described in paragraph [0078] of the Japanese Patent Laid-Open Publication No. 2004-295116. 201213336 37723pif 卿^^^^2·295116 The hardening of the section of the section i: into the second part of the 'in order to coloring is to add a small amount = two: the thing does not have two, p-methoxybenzene, two third, can be cited benzene tert-butyl tea Hope, benzene awake;, hope), 2, 2, - yttrium bis (4 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The addition amount of the A帛 dibutyl nucleus) and the N· succinyl benzene thermal polymerization inhibitor is preferably about O.Oi secret to about 5 sec. with respect to the amount of the coloring hardenability. '(Development accelerator) Moreover, in promoting the solubility in the non-exposed area, the odor of the composition is high-line, the organic nucleus below the composition surface, the molecular weight is _; Oxide (eg glycerol propoxylate (Mw 1500), glycerol propoxylate (Mw), propane-propoxylate (Mw75), glycerol propoxylate (back side) As the organic carboxylic acid having a molecular weight of less than or equal to the surface, for example, formic acid, acetic acid, propionic acid, butyl valproate, valeric acid, pivalic acid, hexanoic acid, diethyl acetic acid: heptanoic acid, octanoic acid, etc.; Oxalic acid, malonic acid, oxalic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, sebacic acid, 103 201213336 12-burned diacid, methylmalonic acid, ethyl An aliphatic dicarboxylic acid such as malonic acid, dif-propionic acid, methyl succinic acid, tetramethyl succinic acid or citraconic acid; an aliphatic tricarboxylic acid such as malonic acid, aconitic acid or decyl tricarboxylic acid; An aromatic monocarboxylic acid such as benzoic acid, benzoic acid, bactericinic acid, 2,3-dimethylbenzoic acid or 3,5-xylenecarboxylic acid; phthalic acid; Aromatic polycarboxylic acid such as dicarboxylic acid, terephthalic acid, trimellitic acid, 1'3'5-benzenetricarboxylic acid, 1,2,3'5-benzenetetracarboxylic acid, pyromellitic acid, phenylacetic acid , hydrogenated atropic acid, hydrogenated cinnamic acid, bitter almond acid, phenyl succinic acid, atopic acid, cinnamic acid, methyl cinnamate, benzyl cinnamate, decyl cinnamic acid, coumaric acid, diced acid (Umbdlic Other carboxylic acid, etc. [Preparation method of coloring thermosetting composition] The colored thermosetting composition of the present invention can be prepared by mixing the above-mentioned essential components and optional components as needed. In the case of a composition, the components which are constitutively colored and hardened, and the components of the product can be collectively formulated, and the components can be dissolved and dispersed in the solvent towel to be successively subjected to the step of arranging. It is not particularly limited. For example, all components may be simultaneously dissolved, dispersed in a solvent to prepare a composition, and each component may be suitably prepared into two or more solutions and dispersions as needed (at the time of coating) ) mixing these to prepare The color-hardening composition prepared as described above may preferably be a polypropylene having a pore diameter of 0.01 μm to 3 〇μηη, more preferably a pore diameter of 〇〇5 to 〇5 μ' (polypropylene). And the color-curable composition of the present invention is excellent in storage stability and can also form a color excellent in light resistance. Since the cured film is suitable for forming a coloring element such as a display device such as a liquid crystal display device or an organic EL display device, or a color filter used in a solid-state imaging device (for example, CCD or CMOS), and can be suitably used. It is used in the production of printing inks, inkjet inks, and paints. In particular, it can be suitably used for forming colored halogens for solid-state imaging elements such as CCD and CM〇s. <<Color filter and method for producing the same>> Next, a method of producing a color calender using the colored curable composition of the present invention (method for producing a color filter of the present invention) will be described. The method for producing a color light-receiving sheet of the present invention comprises: step (A), applying a colored hardenable composition layer of the present invention on a support body; and step (8), separating the mask to the step H): In the method for producing a colored aerial sheet, after the exposure of the color-curable composition layer, the colored pattern is formed in the second step (8), and the step (D) is performed. And heating the colored pattern of the line in the step (c). 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 Coating method such as roll coating, the above-described colored curable composition of the present invention is applied onto a support to form a colored curable composition layer 'subsequent', and preliminary hardening (pre-bake) is performed as needed. The colored curable composition layer is dried. Examples of the support used in the method for producing a color filter of the present invention include soda glass used in liquid crystal display devices and the like, and glass-free glass, and porphyrin glass (PYREX) (registered). (trademark) glass, quartz glass, and a transparent conductive film attached to the glass, or a photoelectric conversion element substrate used in a solid-state imaging device or the like, for example, a stone substrate or a complementary gold riding semiconductor (CMGS) Base (four). These substrates also have a black stripe that forms a barrier to each pixel. Further, on the support members, an undercoat layer may be provided in order to improve adhesion to the upper layer, prevent diffusion of the substance, or planarize the surface. The coating method of spin coating, slit coating, flow casting coating, roll coating, bar coating, spray coating, etc. can be applied to the substrate directly or through other layers by the coating method. A coating film for coloring the curable composition. In addition, when the colored curable composition is spin-coated on the support body, the amount of the low-liquid drop is added, and when the colored curable composition is dropped, the solvent is added dropwise to rotate the machine to cause color hardening. The affinity of the composition on the support becomes better. The conditions for pre-baking at 7 nt include a heating plate or a supply box, and heating at 〇C to 130 C for 5 minutes to 15 minutes. The color hardening composition formed by the acoustic hardening composition can be appropriately selected depending on the purpose, usually on the solid-state imaging element 106.

201213336 J / /jLJpiL The H-light film is preferably 0 2 μπι 5·〇 μυ!, more preferably μΜ~2·5 μΐη, and most preferably 0.3 μηι~1.5 μηι. Further, in the liquid crystal display device, color filter &gt; {material, preferably Q 2 is called 5 to 5 (7), more preferably 1·〇 μηη to 4.0 μηι, and most preferably j 5 μηι to 3 5 μιη. Further, the thickness of the color hardening composition layer referred to herein is the film thickness after prebaking. &lt;Step (Β) - Next, in the method of producing a color filter of the present invention, the colored curable composition layer formed on the support is exposed through a mask. As the light or radiation which can be applied to the exposure, it is preferable that the g-line, the h-line, the i-line, the KrF light, and the ArF light are earth lines. In the case where the soil line is used for the irradiation light, it is preferably irradiated with an exposure amount of l〇〇mj/cm2 to 10000 mJ/cm2. ' Moreover, as other exposure light, you can also use ultra-high pressure, high pressure, medium pressure, low pressure mercury lamps, chemical lamps, carbon arc lamps, xenon lamps, metal halide lamps, visible and ultraviolet laser light sources, fluorescent lamps. , tungsten light, sunlight, etc. (Exposure step using a laser light source) In the exposure mode using the laser light source of the present invention, an ultraviolet laser is used as a light source. Laser (LASER) is an abbreviation for Light Amplification by Stimulated Emission of Radiation in English. An oscillator and an amplifier for monochromatic light that is made more intense in interference and directivity due to amplification and oscillation of light waves, as an excitation 107 201213336 37723pif Crystals of the medium, glass, liquid, pigment, gas, etc., due to the medium, a solid laser, a liquid laser, a gas laser, a semiconductor laser, or the like, which is known to have an emission wavelength in ultraviolet light, can be used. Among them, solid lasers and gas lasers are preferred from the viewpoint of laser output and emission wavelength. As the wavelength which can be used in the present invention, from the viewpoint of conforming to the photosensitive wavelength of the resist, it is preferably an ultraviolet laser having a wavelength range of from 300 nm to 380 nm, more preferably from 3 〇〇 nm to 360. Ultraviolet laser at a wavelength in the range of nm. Specifically, in particular, a third harmonic of a Nd:YAG laser having a large output and a relatively inexpensive solid laser (355 nm), or a XeCl (308 nm) of a pseudo-molecular laser, and a XeF (353 nm) can be suitably used. . The exposure amount of the object to be exposed (pattern) is in the range of 1 mJ/cm 2 to 100 mJ/cm 2 , and more preferably in the range of 1 mJ/cm 2 to 50 mJ/cm 2 . When the exposure amount is in this range, it is preferably 0 in terms of productivity in pattern formation. The exposure apparatus usable in the present invention is not particularly limited, and a commercially available exposure apparatus can use Callisto (V Technology Co., Ltd). ·Manufacturing)

Or EGIS (manufactured by V Technology Co., Ltd.) or DF2200G (0洼丨1^卩〇113〇^11^^. (: 〇., 1^(1. manufactured)), etc. In addition to the device, 'light-emitting diode (LED) and laser diode (LD) can be used as the active radiation source. Especially in the case where an ultraviolet source is required, ultraviolet LED and ultraviolet LD can be used. For example, Asia Chemical Co., Ltd. has listed a purple emission of the wavelength of 365 nm and 420 nm at the wavelength of 365 nm and 420 nm. The US Patent No. 4,250 discloses that an emission center is at 3 〇. The active radiation between 〇nm and 370 nm. Moreover, other ultraviolet rays can be obtained, and the radiation of the same material can be taken care of. The preferred active radiation source in the present invention is UV_LED, especially preferably 34〇m~ 370 m UV-LED with peak wavelength. UV-visual (4) parallelism is good, so even if you don't make the mask, you can also order the pattern exposure. However, when using the mask to expose the pattern, ' The linearity of the pattern is higher and the step is higher. Preferably, the layer of the color-hardening composition which has been exposed can be used in a heating plate or an oven before the subsequent development treatment, and is applied to the machine for about 0.5 minutes to 15 minutes. Moreover, in order to suppress the coloring hardenability composition The oxidative fading of the colored material in the layer can be exposed while flowing nitrogen gas in the chamber. Then, the exposed color-curable composition layer is developed in the developer, thereby forming a negative or positive type. Coloring pattern (resist pattern). If the developing solution is an uncured portion (unexposed portion) in which the colored curable composition layer is soluble, and the developing solution of the hardened portion (exposure portion) is not dissolved, then various solvent solvents are used. When the (IV) liquid is an aqueous test solution, it is adjusted so that the alkali concentration is preferably pH 11 to 13'. More preferably, the pH is 11.5 to 12.5. Sodium hydroxide, potassium hydroxide, sodium carbonate, sodium hydrogencarbonate, sodium citrate, sodium metasilicate, aqueous ammonia, ethylamine, monoethylamine, dimethylethanolamine, tetradecyl ammonium hydroxide, tetraethyl hydrogen Oxidation 109 201213336 irrupii = sputum test, scale n diazabicyclo] [5, s-7 7 decene 4 aqueous solution. Off. In particular, the use of tetraethyl hydrazine can be adjusted to a concentration of 〇

10 wt/. Preferably, 〇 1 wt% to 5 wt% of alkaline water is dissolved as a developing solution. W ... Bay ~ time is preferably 3 seconds ~ 3 seconds, more preferably 3 seconds ~ seconds. The development temperature is preferably 2 (rc 4 4 (rc, more preferably 23 art). Development can be carried out by a dipping method, a shower method, a spray method, etc. Further, it is preferably carried out using an aqueous solution After the development, it is cleaned by water. The cleaning method is also suitable according to the purpose. The support of the Shixi wafer substrate can be rotated by the rotation speed of 1 rpm to 500 rpm. The pure water is supplied and rinsed. Thereafter, in the method for producing a color calender of the present invention, the colored pattern formed by the subsequent coloring may be subjected to post-heating and exposure, thereby promoting the hardening of the colored pattern. -Step (C) - In particular, in the method for producing a color filter of the present invention, the colored pattern formed by the colored curable composition of the present invention (the exposure of the halogen to the ultraviolet light (four) is effectively suppressed for the adjacent The color shift of the element or the lower layer of the layer. The color shift is a characteristic of the coloring composition of the present invention, which is produced when a dye composition such as a specific complex is used. The problem is that the color shift can be reduced by the subsequent exposure by ultraviolet irradiation as described below. 110 201213336 (exposure after exposure to ultraviolet light), in the subsequent exposure by ultraviolet irradiation, preferably as described above = The coloring pattern after the development processing is irradiated with ultraviolet light (uv light) of 1 m times or more of the exposure light amount [mj/cm] in the exposure process before development, and the development process and the steps described later. (D) heat treatment

By irradiating the developed color pattern with ultraviolet light (UV light) for a predetermined period of time, it is possible to effectively prevent the color shift from occurring after heating, thereby improving the light resistance. As the light source that illuminates the ultraviolet light, for example, an ultrahigh pressure mercury lamp, a high pressure mercury lamp, a low pressure mercury lamp, a deep ultraviolet lamp or the like can be used. Wherein 'preferably is light having a wavelength of 275 nm or less in the irradiated ultraviolet light' and illumination illuminance of the light having a wavelength of 275 nm or less [mW/cm2] is integrated with respect to light of all wavelengths in the ultraviolet light In terms of illuminance, it is 5% or more of light. By making the irradiance of light having a wavelength of 275 nm or less in the ultraviolet light 5% or more, the effect of suppressing the color shift between the adjacent pixels or the upper and lower layers and the effect of improving the light resistance can be further enhanced. In this respect, it is preferable to use a light source different from a light source such as an i-line or the like used for the exposure in the step (B), specifically, a high-pressure mercury lamp, a low-pressure mercury lamp, or the like, and to perform ultraviolet irradiation. Late exposure. Among them, for the same reason as described above, the irradiation illuminance [mW/cm2] of light having a wavelength of 275 nm or less is preferably 7% or more with respect to the integrated illuminance of light of all wavelengths in the ultraviolet light. Further, the upper limit of the irradiation illuminance of the light having a wavelength of 275 nm or less is preferably 25% or less. 111 201213336 37723pif In addition, the so-called integral illumination illuminance refers to the case where the illuminance per wavelength (the radiation energy per unit area per unit time; the vertical axis, the wavelength of the light [nm]) is plotted. The sum of the illuminances of the respective wavelengths of light contained in the illumination light (area). The irradiation of the ultraviolet light is preferably set to be more than 10 times the amount of exposure at the time of exposure in the above step (B) [mj/ If the amount of the illumination light in the step (C) is less than 10 times the exposure amount in the exposure in the above step (B), there is a case where the color shift between adjacent pixels or between the upper and lower layers cannot be prevented. Moreover, the light resistance is also deteriorated. Among them, the amount of the external light is preferably 12 times or more and 200 times or less, more preferably 15 times or more and 1 times as much as the exposure amount in the exposure in the above step (B). In this case, it is preferable that the integrated irradiation illuminance of the ultraviolet light to be irradiated is 200 mW/cm 2 or more. If the integrated illumination illuminance is 2 〇〇 mW/cm 2 or more, the south can be more effectively extracted. Suppression of color shift between prime or upper and lower layers The effect of improving the light resistance is preferably 25 〇 mW/cm 2 to 2000 mW/cm 2 ' more preferably 300 mW/cm 2 〜 1 〇〇〇 mW/cm 2 ° - step (D) - for the above As described above, the coloring pattern which is exposed after the ultraviolet irradiation is preferably subjected to heat treatment, and the colored domain can be further hardened by heating the colored pattern (so-called sufficiency). It can be carried out by a heating plate, various heaters, a supply box, etc. 112 201213336. The temperature during the heat treatment is preferably from 10 ° C to 3 °, more preferably from 150 ° C to 250 ° C. Further, the heating time is preferably 3 sec to 3 sec, more preferably 60 sec to 1000 sec. In the method of manufacturing the color filter of the present invention, the g line and the h line can also be used. Subsequent exposure of i-line, KrF, ArF, electron beam, X-ray, etc. instead of exposure after ultraviolet irradiation as in the above step (C). When using the later exposure of some means, the irradiation time It is seconds to 180 seconds, preferably 20 seconds to 120 seconds, and more preferably 3 seconds to 6 inches. Further, in the method of manufacturing a color filter of the present invention, it is also possible to perform the post-exposure by ultraviolet irradiation as in the above step (C), but only to perform the post-exposure as in the above step (D). In addition, as the post-exposure and post-heating, either of them may be performed first, but it is preferable to perform the post-exposure before the post-heating. The reason is that the hardening is promoted by the late exposure, and the post-heating process can be suppressed. Shape deformation caused by overheating (sphericalization of a rectangular pattern) or hem (reflow of a lower layer of the pattern) of the colored pattern. The colored pattern obtained as described above constitutes the gold in the color filter. In the production of a color filter having a plurality of shades of color, the above steps (A), (b), and optionally (C) may be repeatedly performed according to the number of colors* Or step (D). In addition, it can be formed in each of the monochromatic color hardening composition layers, 113 201213336 exposure, and development end (per color), and can be advanced (D), or in 』1 steps (〇 and/or steps) The formation of the layer, the color of the exposure/exposure color &amp; the curable composition and/or the step shadow after the completion of the above steps (6) the light sheet 1 clear color filter, the method of manufacturing the light sheet In the color filter composition of the color filter composition H*, the color hardening property of the present invention is used, and it is excellent in light resistance. CCD? The color filter of the invention can be used for liquid crystal display devices or ΓΓ Γ 、 、 、 、 、 CM CM CM CM 及 及 及 及 及 及 及 及 及 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机 照相机The use of a solid-state imaging element that forms a colored pattern on a film and requires a good rectangular cross-sectional profile, in particular, a CCD element or a CMOS having a high resolution of more than one million elements. <<Solid Photographic Element>> The solid-state imaging element of the present invention has the color filter of the present invention. The color filter of the present invention has high light resistance, and the solid-state imaging element having the color filter can obtain excellent color reproducibility. The configuration of the solid-state imaging device is not particularly limited as long as it has the color filter of the present invention and functions as a solid-state imaging device. For example, the following configuration can be cited. That is, 'the transfer electrode has a transfer electrode (the transfer electrode includes a plurality of photodiodes and polycrystalline germanium constituting a light receiving region of a CCD image sensor (solid-state imaging device)), and the present invention is disposed thereon The color filter is composed of the second laminated microlens. 114 201213336 and as a camera having the color filter of the present invention

In view of the light fading property of the material, it is desirable that the camera or the m-cut film has a two-color coating H. The optical properties of the material are preferably partially or wholly absorbed below nm. As a pure structure of the camera, it is preferable to form an oxygen-nitrogen seal to the color filter in order to make the oxygen color of the material. , the camera is a slave or the whole is displayed by a display device such as a liquid crystal display device or an organic a display device, etc. (liquid======liquid crystal display, strong organic display device) Organic EL display thousand =), liquid crystal projector, display device for job machine, display device for mobile terminal, digital city device, 2 mobile device, etc., _ is pure display, better display device The definitions or descriptions of the display devices are as follows:; set; Zuo Fukio, the Industrial Research Association, the limited company = 仃显不农 (I Bing Shunzhang, the industry book shares limited

It is recorded in the Si t year issue). Further, regarding the liquid crystal display device, for example, "the next generation of liquid crystal display technology (inner set, industrial 纽 份 3 3, just issued). The liquid crystal display device to which the present invention is applicable is not particularly limited. For example, the liquid crystal display device of the various methods described in the above-mentioned "lower generation liquid crystal display technology" is used. As a color 遽H, the towel system is effective for the color TFT moon liquid B0H. The color TFT type liquid crystal j = set is described, for example, in the "Color &amp; T F τ liquid crystal display (Kyoritsu Publishing Co., Ltd., "19% annual release"). In addition, the present invention is also applicable to a horizontal electric field driving method such as ips, a pixel division method such as mva, a liquid crystal display device with a viewing angle of $|丨, or stn, VA, 〇cs, FFS, and R-〇cb. in. Moreover, the color filter of the present invention is also available in a bright and high-precision = 〇A (C〇l〇r_filter 〇n An:ay, color enamel array) mode. =0A : 3⁄4 type liquid crystal display device +, the requirements for the color county layer, in addition to the usual required characteristics as described above, the required characteristics of the interlayer insulating film, that is, the low dielectric f number and the Receptive. As the color light-emitting sheet of the present month, in addition to the exposure method using ultraviolet laser light, the present invention improves the transmittance of ultraviolet laser light as exposure light by selecting the color tone or film thickness of the specified element. . In this way, the hardenability of the coloring pixels can be improved, and the defects of the coloring or the secrets can be formed. Therefore, the coloring layer which is grounded on the TFT substrate, especially the stripping liquid resistant to the skin can be used for c. 〇A mode liquid crystal display device. A resin film may also be provided on the color filter layer in order to satisfy the required characteristics of the dielectric constant. - In addition, in the coloring layer formed by the C〇A method, in order to make the ITO electrode disposed on the color layer and the terminal of the driving substrate below the coloring layer conductive, the length of the side must be formed. The moment of the heart (7) 116 201213336 The shape of the via hole or the mouth type pit, etc., the size of the conduction path (that is, the length of the side) is particularly preferably set to 5 μπι or less, by using the present invention, A conduction path of 5 μηι or less can be formed. _. This axis is described in, for example, "The latest development of EL, PDP, LCD display technology and market _ (T〇ray Research center, research and development department, _year issue)", page 43 and the like. The liquid crystal display device of the present invention includes various components such as an electrode substrate, a eccentricity, a retardation film, a backing, a spacer, and a viewing angle securing film in addition to the color grading sheet of the present invention. The color filter of the present invention can be applied to a liquid crystal display device including such known components. ^For these components, for example, "94 LCD Peripheral Materials, Chemical Markets (Island Kentaro, CMC Co., Ltd., issued in 1994)", "2003 LCD Related Markets Status and Future Outlook (Volume 2) , documented by Fuji Chimera Research Institute, Inc., issued in 2003. About the backlight, at the SID meeting (SID meeting Diges〇1380 (2005) (A.Konno), or the monthly display of the display for 5 years No. 18 to 24 (Island Kang Yu), Display Monthly, December 2005, No. 25 to 30 (Yumu Longming), etc. If the color filter of the present invention is used in a liquid crystal display device The combination of the three-wavelength tube of the previously known cold cathode tube can achieve high contrast, and the red, green and blue LED light source (RGB_LED) can be used as a backlight to provide high brightness and color. Liquid crystal display with good purity and high reproducibility. 117 201213336 37723pif And right for organic display device, and can provide high brightness, organic EL display device. [Examples] The present invention will be further clarified by the following examples. As long as the subject matter is not exceeded, it is not clear that the present invention has no special description, and the "parts" and "%" are weights ^ In addition, (Example 1) -1·Preparation of coloring curable composition ^ The following components are mixed and the coloring curable composition 1 is obtained. 'Combination, filtration and obtaining (A-2) Pigment blue _i5: 6 dispersion liquid is 17 · ·, color,

• A-1) Specific complex (exemplified compound Μ) 〇 84 parts • () First polymerization initiator (starting agent U of the following structure: • (C) polymerizable compound (monomer 0.27 wound • (6) polymerizability Compound (monomer ^ 0.20 part • test soluble binder: methyl propylene) from the purpose / methyl propylene riding ugly polymer 20% cyclohexidine solution (Mo Erbi is 7g: 3g: amount is: _ two It is called "tree," 〇, 〇 / (E ) &gt; mixture · propyl alcohol j js, private ΓΡΟΜΕΑ,) know 'acetic acid vinegar (hereinafter, 10.25 copies of the other used pigment blue seven: 6 Dispersion liquid is obtained by using a cerium oxide particle having a diameter of 118 201213336 of 0.5 mm, and dispersing the composition of the following formulation in a dispersing machine (trade name: Dispermat, manufactured by GETZMANN Co., Ltd.) for 2 hours. Blue-15 : 6 59.00 parts • Resin solution (benzyl methacrylate / mercaptoacrylic acid copolymer, molar ratio of 80/20, Mw of 10,000, resin solids concentration of 30%, solvent PGMEA 70%) 19.65 parts 342.7 servings

• Solvent: PGMEA • Dispersant: BYK-161 (manufactured by BYK) 30 〇 / 〇 solution (solvent is PGMEA, butyl acetate) 78.65 parts (preparation of colored curable composition 2 to colored curable composition 1 )) In the preparation of the colored curable composition 1, the types and amounts of the pigment dispersion liquid, the specific complex compound, the photopolymerization initiator, the polytropic compound, the polymer, and the solvent are individually changed as shown in Table ,. In the same manner as in the preparation of the colored curable composition of the example, the bodhisattva composition 2 to the colored curable composition 10 were prepared. Further, Table 1 shows an example of two kinds of polymerizable compounds, and the test examples show two types in combination. Further, '() is the amount used, and is converted into weight, and 'Resin A' indicates that the alkali-soluble adhesion ° cyH" in the example i is cyclohexanone. 119 201213336 Α· .

[Table 1] Pigment Dispersion Specific Complex Photopolymerization Initiator Polymerizable Compound Polymer Solvent Colored Curable Composition 1 PB15:6 (17.04) la-5 (0.84) Starting Agent 1 (0.27) Monomer A (0.20) Resin A (0.10) PGMEA (10.25) Monomer F (0.64) Colored hardening composition 2 PB15:6 (17.04) III-3 (0.84) Starting agent 1 (0.27) Monomer B (0.40) - PGMEA (10.25) Monomer F (0.44) Colored hardening composition 3 PB15:6 (17.04) III-5 (0.84) Starting agent 1 (0.15) Monomer C (0.40) - PGMEA (6.25) Starting agent 2 (0.12) Monomer F (0.44) CyH (4.00) Colored hardening composition 4 PB15:6 (17.04) ΙΙΙ-Α (0.84) Starting agent 2 (0.27) Monomer D (0.50) PGMEA (6.25) Monomer F (0.34) 2-heptanone (4.00) colored curable composition 5 PB15:6 (17.04) ΙΙΙ-45 (0.84) initiator 3 (0.27) monoterpene E (0.84) - PGMEA (10.25) color hardening Composition 6 PB15:6 (17.04) ΙΙΙ-Α (0.84) Starting agent 2 (0.27) Monomer C (0.84) - PGMEA (10.25) Colored hardening composition 7 PB15:6 (17.04) ΙΙΙ-65 (0.84 ) •&quot; 丨Starter 1 (0.27) Monomer E (0.50) Resin A (0.10) PGMEA (10.25) Monomer F (0.34) Colored hardening composition 8 PB15:6 (17.04) ΙΙΙ-68 (0.84) Starting agent 1 (0.27) Monomer D (0.84) - PGMEA (10.25) Colored curable composition 9 PB15 (17.04) ΙΙΙ -Β (0.84) Starting agent 2 (0.27) Monomer E (0.30) - PGMEA (10.25) Monomer F (0.54) Colored curable composition 10 PB15:3 (17.04) ΙΙΙ-47 (0.84) Starting agent 3 (0.27) Monomer E (0.20) - PGMEA (10.25) Monomer F (0.64) Preparation of colored curable composition 1 and polymerizable compound used in Table 1, initiator of photopolymerization initiator 1 ~Starter 3 is as follows. Monomer A to monomer D and monomer F are the polymerizable compounds of the present invention, but 120 201213336 monomer D is different from the polymerizable compound of the present invention. Polymerizable compound: Monomer A: Ethoxylated isocyanuric acid triacrylate Monomer B: Pentaerythritol triacrylate Monomer C: Pentaerythritol tetraacrylate Monomer D: The following structure [Chem. 67]

Monomer E: dipentaerythritol hexaacrylate monomer F: the following structure [Chem. 68]

121 201213336 _ . - - [Chem. 69]

Starting agent 1

Starting agent 2

Further, in Table 1, "PB15: 6" of the pigment dispersion was expressed as the pigment blue-15:6 dispersion. Further, "pBl5" and rpBl5: 3" mean that in the preparation of the pigment blue-15:6 dispersion, the pigment ΡΒ15 and the pigment ΡΒ15:3 are used instead of the pigment blue _15: 6, otherwise The pigment dispersion obtained in the same manner as in the preparation of the pigment blue-15:6 dispersion. (Example 2 to Example 9, Reference Example 2 to Example 9, and Reference Example 1 Each of the colored curable compositions shown in Table 2 was used. Each of Examples 1 to 9 and Reference Example i was evaluated as follows. The light resistance and development time dependence of the coloring curable composition were shown in Table 2. 122 201213336 ό//zjpif _ Monochrome color filter production and evaluation of light resistance _ Using a rotary coater Each of the colored curable compositions obtained above was applied to a glass substrate to have a film thickness of 0.6 μΐ after drying, and baked for 12° seconds to obtain an early color filter for evaluation of light resistance. Light resistance evaluation · Single color (10) light film, which is illuminated by a gas lamp for 100 hours (equivalent to 2 million lux · h). The color difference of the monochrome color filter before and after the gas meter illumination (The smaller the δ ε * 耐 value light resistance index H Δ ΕΜ value is, the better the light resistance is, and the judgment criteria are as follows. The results are shown in Table 2. ~ Determination criterion ~ ΔE*ab value &lt; 1 ^ △ E* Ab value &lt;3 3$ station* dip value $10 10&lt;^*ab value X: - evaluation of development time dependence - (1) Preparation of etching solution A (undercoating solution) The following components were mixed and dissolved to prepare an anti-residue * PGMEA 5.20 parts • 52.60 parts • 30.50 parts of a binder (methacrylic acid / methacrylic acid / mercaptopropyl Dilute acid _2 old US, molar ratio of 60: 20: 2 〇, weight average molecular weight is 'ο (I vinyl interchange), 41% cycloheximide solution) 123 201213336 • dipentaerythritol hexaacrylate 10.20 parts • polymerization inhibitor (p-methoxyphenol) 0.006 parts • fluorine-based surfactant (ρ_475, manufactured by DIC Corporation) 0.80 parts • photopolymerization initiator: 4-benzotetrahydrocarbamate-2, 6-double (three gas sulfhydryl)_ 均三唤 (TAZ-107 manufactured by Midori Kagaku Co., Ltd.) 0.58 parts (2) Preparation of glass substrate with undercoat layer Glass substrate (manufactured by Corning Incorporated) 1737) After ultrasonic cleaning in 0.5% NaOH water, washing with water and dehydration baking (200 ° C / 20 min). Next, using the rotary coater 'to dry the resist solution A obtained above (丄) The film thickness was applied to the glass substrate to be cleaned at a film thickness of 2 μm, and the film was allowed to stand at 220 ° C. The glass substrate with the undercoat layer was prepared by heating and drying for 1 hour. (3) The development time dependence was evaluated on the undercoat layer of the underlying coated wafer substrate obtained in (2) The coloring curable composition was applied to form a photocurable coloring curable composition layer so that the dried film thickness of the coating film was 0.7 μηη. Then, heat treatment (pre-baking) was carried out for 120 seconds using a hot plate of 100 °C. Next, the i-line stepper exposure apparatus FPA-3000i5 + (manufactured by Canon Co., Ltd.) was used to cover the islands of the 1.2 μm pattern with a patterned pattern of the pattern, in the range of 100 mJ/cm 2 to 2500 mJ/cm 2 . The 365 nm wavelength light was irradiated by changing the exposure amount by 100 mJ/cm 2 at a time. Thereafter, the Shihua wafer substrate on which the coating film is formed is placed on the rotary and spray developing machine 124 201213336

On the horizontal turntable of J / /ZjpiI (DW-30, manufactured by Chemitronics Co., Ltd.), using CD-2000 (manufactured by FUJIFILM Electronic Materials Co., Ltd.) at 23 ° C for 30 seconds and 120 seconds The dip-type development 'forms a colored pattern on the Shi Xi wafer substrate. The dependence of the development time was evaluated by the following formula. Development time dependence (%) =|D120-D3〇|/D12〇x1〇0 D30: In the case of 3 seconds of development, an exposure amount of D1 is formed in a 1.2 μm pattern: development is performed for 120 seconds. In the case of the case, the exposure amount of the pattern of 1.2 μπι is formed. ～: 5%: less than 5% 〇: 5% or more, less than 1〇0/〇 Δ: 10% or more, less than 15% X: 15% or more 125 201213336 [Table 2 Coloring Curable Composition Light Resistance Development Time Dependence Example 1 Coloring Curable Composition 1 〇 ◎ Example 2 Coloring Curable Composition 2 0 ◎ Example 3 Coloring Curable Composition 3 〇 ◎ Example 4 Coloring Curable Composition 4 〇 ◎ Example 5 Colored curable composition 7 〇 ◎ Example 6 Colored curable composition 9 〇 ◎ Example 7 Colored curable composition 10 〇 ◎ Example 8 Colored curable composition 6 〇〇 Example 9 Colored curable composition 8 〇〇Reference Example 1 Colored curable composition 5 〇Δ According to the results of Tables 1 and 2, it is understood that by using the color-curable composition of the present invention, color filter having small development time dependency and good light resistance can be obtained. Light film. [Simple description of the diagram] None. [Main component symbol description] None 0 126

Claims (1)

201213336 j / /z^pif VII. Patent application scope: 1. A color-hardening composition comprising at least: (eight _ 丨) 勹 eight compounds represented by the following formula (1) combined with metal atoms or metals = wrong Compound, (A_2) phthalocyanine pigment, (B) dispersant, (c) selected from, polymerizable compounds represented by the formula (MO 1) to formula (m〇_5) = less a compound, (8) a photopolymerization initiator, and (E) an organic solvent: [wherein, (1) + ' Ri~R6 independently represent a nitrogen atom or a substituent, ', an atom, an alkyl group, an alkyl group, an aryl group or a heterocyclic group; wherein R and R are not bonded to each other Forming a ring]; 127 201213336 J / /z^pif [Chemical 2] 〒H2+T%R RfT-^CHz-C-CHz-fT^rR (MO-1) iH Branch R CH2iT-tR. CH2^R Rfr -)frCH2 -C~CH2-Z-CH2-C-CHs-fT^-R (MO-2) ilH spell R CH2-fT-tR R-fT-^CH2 CH2-fT^R R-fTtCH^p- CH Factory Oa^—C^CHzfT^R R-fT-^CHz XCH2-fT^R ch2^r 〇丫N 丫〇(M0~4) R4T-feCH2-NYNXH2-fT^R o R-fT-)fiCH2 -N (MO-5) NCH24T-irR [Chemical 3] R: H2C-CH-C-0- H2C=CC-0~ -OC-fCHj^C-OH -0-C-NH-(CH2^C- Ai -OH T: ~W3H2~· -OCHjCHj- ( OCHgCHjCHj · OCH2CH2CH2CH2 - in the formula (MO-1) to the formula (MO-5), n is an integer from 0 to 14, and ml~m4 is 1~ An integer of 8; a plurality of R and T existing in the same molecule may be the same or different; 128 201213336 In each of the polymerizable compounds represented by the formula (MO-1) to (MO-5), At least i of the existing Rs represent _〇c(= 〇)CH=CH2&gt;, t.〇c(=〇)C(CH3) = CH2 ; (M〇.2) =, where z is -0., n is i or more, or R is a group other than _〇 to = 〇^^. I 2. The color-hardening composition as described in claim 1 of the patent application, ; The (C) polymerizable compound is a compound represented by the above formula (MO-2), and at least one group represented by R in the formula (M0-2); [Chemical 4] —0—C—NH Hch —· —OH ^ In the above group, ml and m2 are each an integer of 1 to 8. Among them, the color-hardening composition described in the above-mentioned patent application Scope 1 is 4 kg (D) The photopolymerization initiator is a lanthanide compound. The color-hardening composition according to item 1 of the patent application, the atom and the (A 1) include the compound and the metal compound represented by the formula (I) The complex compound of the genus compound is represented by the following formula (5)) 129 201213336 [Chemical 5] [In the formula (II-1), R1 to R6 each independently represent an argon atom or a substituent; R7 represents an argon atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group; and Ma represents a metal atom or a metal compound. X2 denotes a base necessary for neutralizing the charge of Ma, and X1 denotes a group which can be bonded to Ma; in addition, X1 and X2 may be bonded to each other to form a ring of 5 members, 6 members, or 7 members; R1 and R6 are not bonded to each other to form a ring]. 5. The color hardening composition according to claim 1, wherein the (A-1) complex comprising a compound represented by the formula (I) and a metal atom or a metal compound is as follows. a compound represented by the formula (II-2); 130 201213336 [Chemical 6] [In the formula (II-2), R1 to R6&amp;r8 to R13 each independently represent a hydrogen atom or a substituent; and R7 and R14 each independently represent a hydrogen atom, a halogen atom, a alkyl group, an aryl group or a heterocyclic ring. A group; a metal atom or a metal compound; wherein R1 and R8 or R13, and R6 and R8 or Rl3 are not individually bonded to each other to form a ring]. 6. The color-curable composition according to item 1, wherein the original (A-1) comprises a compound of the formula (1) and a complex of the metal t or the metal compound is the following The expression represented by the formula (111) 131 201213336 [Chem. 7] R7 R4 (ffl) [In the formula (III), R2 to R5 each independently represent a hydrogen atom or a = substituent; R1 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, or a heterocyclic ring =, and Ma represents a metal atom or a metal compound, χ3 represents NR (R represents an atom, an alkyl group, an alkenyl group, an aryl group, a heterocyclic group, a fluorenyl group, an alkylsulfonyl group, a hydryl group), a nitrogen atom, an oxygen atom, or a sulfur atom. , X4 represents that NRa ^ represents a hydrogen atom, a silk, a county, an aryl group, a heterocyclic group, a fluorenyl group, a decyl group, or an arylsulfonyl group), an oxygen atom, or a sulfur atom, and γ1 represents 】 (^c represents hydrogen Atom, alkyl, alkenyl, aryl, heterocyclic, fluorenyl, =%, or aryl, nitrogen or carbon, gamma 2, atom or carbon atom, Han 9 independently represents an alkyl group, an alkenyl group, or a aryldiaryloxy group, an alkylamino group, an aryl group, and a 7 amine group, and R and γ may be bonded to each other to form a 5-member, a 6-member, Or a ring of members, R9 and γ2 may also be bonded to each other to form a ring of 5 members, 6 members, or 7; Χ5 represents a base bondable with Ma, and a represents 0, 1, or 2]. 132 1 The colored hardening composition according to claim 1, wherein the metal atom or metal compound is any one of Fe, Zn, Co, V==〇, and Cu. 8. The color hardening composition according to claim 1, wherein R3 and R4 in the formula (I) are each a phenyl group. A method of producing a color filter, comprising: the step (A) of coating a support body as disclosed in claim 1 to the coloring hardening composition to form a color hardening-hardening mask Exposing the coloring composition layer formed by the step (4) to the coloring matter layer of the ninth item of the patent application. The method further comprising: a manufacturing step (C) of the slavish filter 'for the step (b illuminating the ultraviolet ray; and the opening) and forming the coloring pattern step (D), Step (c) describes coloring _ heat treatment. The middle surface of the ultraviolet light is U--a kind of color filter, which is produced by the coloring film of the above-mentioned color (fourth), and the photographic element of the ninth item U-type solid-state photographic element The color filter described is ―, as in the patent application range 11 U·---------------------------------------------------------------------------------------------------------------- (1) The representative representative of the case is: No. (2) The symbol of the symbol of the representative figure is simple: None. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: 3 201213336 Revision date: November 11, 100. For the Chinese manual No. 100丨30526, there is no sizing correction page for the aryloxycarboxyoxy group with a stone number of 7 to 24, for example: phenoxy-deoxyl) , an amidinoyloxy group (preferably a carboxyloxy group of a carbon number, more preferably an amine methyl fluorenyl group having a stone number of 1 to 24, for example: n, n-didecylamine oxime Acidoxy, N-butylamine, mercaptooxy, N-stylaminodecyloxy, quinoneethylphenylamine, fluorenyloxy, alkoxyoxy (preferably carbon) The number 1 to 32 of the amine 4-branched oxy group is more the carbon number of the amine, the base, for example: N, N-diethylamine sulfonyloxy, N-propylamine sulfonate a fluorenyl sulfonyloxy group (preferably an alkylsulfonyloxy group having 1 to 38 carbon atoms, more preferably a decyloxy group having a carbon number of 1 to 24, {column: a methyl group, an oxy group, a hexaalkylsulfonyloxy group, a cyclohexylsulfonyloxy group, an arylsulfonyl group (preferably an aryl group having a carbon number of 6 to 32, more preferably Preferred is an arylsulfonyloxy group having a carbon number of 6 to 24, for example, a phenylsulfonyloxy group, a decyl group (preferably a number of 1 to 48, more preferably a carbon number of 24, such as t. methyl ketone, ethyl fluorenyl, pentylene, benzhydryl, tetradecyl, cyclohexyl And an alkoxy group (preferably an alkoxy group having a carbon number of 2 to 48, more preferably an alkoxycarbonyl group having 2 to 24 carbon atoms, for example, a methoxycarbonyl group or a methyloxy group) , an octadecyloxy group, a cyclohexyloxy group, a 2,6-tributylmethylcyclohexyloxycarbonyl group, an aryloxycarbonyl group (preferably, an aryloxycarbonyl group having a number of 7 to 32, more Preferred are an aryloxycarbonyl group having 7 to 24 carbon atoms, for example, a phenoxycarbonyl group, an amine carbaryl group (preferably an amine carbaryl group having a carbon number i 〜, more preferably a carbon number of 1 to 24). Aminomethyl thiol group, for example: Aminomethyl sulfhydryl, N,N-diethylamine methyl fluorenyl, N-ethyl octylamine methyl fluorenyl, N,N-dibutylamine methyl sulfhydryl, N-propyl Amine oxime, N-phenylamine methyl sulfhydryl, N'methyl-N-phenylamine methyl hydrazino, hydrazine, hydrazine-dicyclohexylamine fluorenyl), 17 201213336 Revised date ·]〇〇 November 11, 2011 is the Chinese manual of No. 100130526 without a slash correction page amine base (preferably carbon number 3) 2 or less of an amine group, more preferably an amino group having 24 or less carbon atoms, for example, an amine group, a methylamino group, an N,N-dibutylamino group, a tetradecylamino group, a 2-ethylhexyl group. An amine group, a cyclohexylamino group, an anilino group (preferably an anilino group having a carbon number of 6 to 32, more preferably an anilino group of 6 to 24, for example, an anilino group or an N-methylanilino group) or a heterocyclic ring. An amine group (preferably a heterocyclic amine group having a carbon number, more preferably a heterocyclic amino group of 1 to 18, for example, a 4-pyridylamino group) or a carboguanamine group (preferably having a carbon number of 2 to 48) Further, the amine group is more preferably a 2 to 24 carboxamide group, for example, an acetamino group, a benzoguanamine group, a p-tetradecylamino group, a pentyl decylamino group, a cyclohexanyl group. Amino group, urea group (urea is preferably a ureido group having a carbon number of 1 to 32, more preferably a ureido group having a carbon number of 丨24, for example: urea group, N,N-dimethylureido group, N -phenylureido), quinone imino group (preferably a quinone imine group having a carbon number of 36 or less, more preferably a quinone imine group having a carbon number of 24 or less, for example, N-succinimide group, N _ 笨 曱醯 曱醯 曱醯 曱醯 ) 、 院 院 院 院 院 院 院 院 院 院 院 院 院 ( ( ( ( ( An anthranylamino group, more preferably an alkoxycarbonylamino group having 2 to 24 carbon atoms, for example, an anthraceneoxycarbonylamino group, an ethoxycarbonylamino group, a third butoxycarbonylamino group, octadecane An oxycarbonylamino group, a cyclohexyloxycarbonylamino group, an aryloxycarbonylamino group (preferably an aryloxycarbonylamino group having 7 to 32 carbon atoms, more preferably an aromatic oxygen having a carbon number of 7 to 24) a carbonylamino group, for example, a phenoxy-l-amino group, a synthetic amine group (preferably a decylamino group having a carbon number of 1 to 48, more preferably a sulfonylamino group having a carbon number of 1 to 24, For example: mercaptosulfonylamino, butyl decylamino, phenyl amidino, hexamethylene hexylamino, cyclohexylsulfonylamino), amine sulfonamide (preferably carbon)丨~48 of the amine sulfonium t-amine group, more preferably the amine having a carbon number of 1 to 24, such as: N, N_ 18 201213336 ^ t / Λ. For the specification of the Chinese Patent No. 100130526, no underline repair ^ &quot; Revision date: In the general formula (ΙΠ) on November 11, 1st, R8 and Y1 can also be bonded to each other, and R8 and Yj carbon atoms together form a 5-member ring (for example, ring Yao, (four) bite, four Nitrogen sulphate, alkane: f thiophene, Pr, furan, thiophene, anthracene, stupid and furan, benzide thiophene), 6-membered ring (you 丨P h clothing C such as soil burned, π 辰 bite, pyrazine, morphine, tetrahydrofuran, dioxins Burning, furnace servant) 丨 [Chemical 5 pentane' dithiane, benzene, piperidine, pyridazine, hydrazine, 啥琳, 噎 吸,, 杰 7 g, to! Porphyrin) or 7% (for example: cycloheptane, hexamethyleneimine). In the formula (10), R9 and Υ2 may be bonded to each other, and R9, Υ2 and carbon atoms together form a ring of 5, 6 or 7 tributaries. The ring of the 5 tribute, the 6 member, and the 7 member formed may be a ring in which one of the bonds formed by the Han 8 and γ 1 and a carbon atom is changed to a double bond. Yu Tong. In the case of the formula (III, where R8 and Y1, and R9 and Υ2 are bonded to each other, the ring of 5 members, 6 members, and 7 members is a ring which can be replaced by a step, the substituent R can be used. Any of the substituents described above may be the same or different when substituted by two or more substituents. In the formula (III), X5 represents a group which may be bonded to Ma, and The group of the formula (II-1) is the same group. The a represents Ο, 1, or 2. The preferred aspect of the compound represented by the formula (III) is as follows. That is, R2 to R5, R7, and Ma are each a preferred embodiment comprising a complex of a compound represented by the formula (1) and a metal atom or a metal compound, and X is NR (R is a hydrogen atom, a pyridyl group), a nitrogen atom, or An oxygen atom, X4 is NRa (Ra is a hydrogen atom, an alkyl group, a heterocyclic group), or an oxygen atom, γι is NRc (Rc is a hydrogen atom or an alkyl group), a nitrogen atom, or a carbon atom, and γ2 31 201213336 is No. 100130526 Chinese manual without scribe correction page Revision date: 1 year 1 month 110 is a nitrogen atom, or an atomic hindrance 'X5 is a bond through an oxygen atom Rs and R9 each independently represent an alkyl group, an aryl group, a heterocyclic group, an alkoxy group, or an alkylamino group, or R8 and Y1 are bonded to each other to form a 5- or 6-membered ring, and r9 and Y2 are bonded to each other. A 5-membered or 6-membered ring is formed, and a represents a ruthenium or a ruthenium. A more preferable aspect of the compound represented by the general formula (III) is as follows. That is, R2 to R5, r7, and Ma are individually included in the formula. (1) A preferred form of the compound of the broadly expressed compound with a metal atom or a metal compound, X3 and X4 are oxygen atoms, Υι is NH'Y2 as a nitrogen atom, χ5 is = two-bonded wire, R8 and r9 (four) are independent丝丝绿, aryl 乳基基, or alkylamine group ' or Han 8 and γ1 mutual bond = =: 9 and Υ 2 are bonded to each other to form 5 members, 6 members: Ming and = = = specific mismatch Specific example of the object 'But the original [Chemical 12] 32 201213336 is the Chinese version of the 100130526 No-line correction page Revision date: November 11, 100 [57] HN 广,," &gt;=0〆! ό·4 ^ 〇R.9 OH Compound No. r3 R4 R5 R7 Rs Rg IH-65-2 h3c 丫ch3 H3c^ch3 A cooc2h5 —H ~ch3 -CH3 ΗΪ-70 -2 h3c^ch3 h3c 丫ch3 G4Hflit) —ΌΡΟ— cmr —H —ch3 —CH2nhso2^^^-ch3 IlhB-2 h3c 丫ch3 h3c 丫ch3 —COOG2H5 CI^COOH —ch3 —ch3 ❹ [Chem. 58] Rs R , Compound No. f% R4 r7 ΙΠ-90-2 Hsc 丫 CH3 h3c 丫 ch3 —H —CH3 —ch3 ΙΠ-Ο-2 h3c 丫 ch3 HsC^CHa CHZQCX5H -ch3 ~ch3 From the viewpoint of film thickness, it is preferred that the molar absorption coefficient of the specific complex of the present invention is as high as possible. Moreover, from the viewpoint of improving the purity of color, 73 201213336 « f ^fM-Λ L· Date of revision: 100 years of the second day of the month of the month of the 100th day of the Chinese calendar No. 100130526 (the line correction page maximum absorption wavelength Xmax is preferably 520) From nm to 580 nm, more preferably from 53 〇 nm to 570 mn. In addition, the maximum absorption wavelength and the molar absorption coefficient can be measured by a spectrophotometer UV-2400PC (manufactured by Shimadzu Corporation). It is preferable that the melting point of the specific complex compound in the present invention is not too high. The specific complex in the present invention can be obtained by U.S. Patent No. 4,774,339, U.S. Patent No. 5,433,896, and Japanese Patent Laid-Open No. 〇ι'_24〇76ι, Japanese Patent Laid-Open No. 2002_155052, Japanese Patent No. 3614586, Australian Chemical Journal (AusU Chem), 1965, 1835-1845, JHB0ger, etc., heteroatom chemistry (brain Her Chemlstry), V〇U, N〇5 ' (199 〇), etc. are synthesized by the method described in the above. Regarding the synthesis method of the specific complex in the present invention, specifically, the Japanese Patent Laid-Open No. 2〇〇8_29297 No. paragraph In the photosensitive coloring-curable composition of the present invention, one type of specific complex may be used alone or two or more kinds may be used in combination. The specific complex of the present invention is in a colored curable composition. The content varies depending on the molar absorption coefficient. 'Compared with the solid content of the colored curable composition, it is preferably $i 〇wt%~7 〇%, more preferably Wt%~50'.岐15 wt% to 30 wt% [(A-2) phthalocyanine pigment] The phthalocyanine pigment used in the present invention is not particularly limited as long as it has a phthalocyanine bone ",". Furthermore, as a phthalocyanine pigment, 74 201213336 / / X : is the 100130130526 Chinese manual without a sizing correction page, and the date of the year of the year, U „ styrene, vinyl ether, etc. Saturated carboxylic acid. As a specific example of the monomer of the aliphatic polyol compound and the unsaturated decanoic acid ester, 'as acrylic acid vinegar' is ethylene glycol diacrylate vinegar, triethylene glycol diacrylate, 1,3- Butanediol diacrylate, 1,4-butanediol diacrylate, propylene glycol Acrylate, neopentyl glycol diacrylate, trimethylolpropane triacrylate, trimethylolpropane tris(propylene methoxypropyl) ether, hexanol dipropionyl ester, 1,4 -cyclohexanediol diacrylic acid vinegar, tetraethylene glycol diacrylate, pentaerythritol polyacrylate (acrylate number 1 to 10), pentaerythritol polyacrylate (acrylate number 1 to 12), Yamanashi Sugar alcohol triacrylate, sorbitol tetraacrylate, sorbitol pentaacrylate, sorbitol hexaacrylate, polyester acrylate oligomer, and the like. As the mercapto acrylate, there are 1,4-butanediol dimethacrylate, triethylene glycol dimercapto acrylate, neopentyl glycol dimercapto acrylate, trishydroxypropyl propane trimethacrylate , trihydroxydecylethane tridecyl acrylate, ethylene glycol dimercapto acrylate, 1,3-butylene glycol dimethacrylate, ◎ hexanediol dimercapto acrylate, sorbitol triterpene Acrylate, sorbitol tetradecyl acrylate, bis[p-(3-mercaptopropenyloxy-2-hydroxypropoxy)phenyl]didecyldecane, bis-[p-(mercaptopropene)醯oxyethoxy) stupyl] dimercaptomethane and the like. As the isoconate, there are ethylene glycol dicone ester, propylene glycol diconcanate, 1,3-butanediol diconcanate, 1,4-butanediol diconconate (1) , 4'butanediol diitaconate ), tetramethylene glycol diitaconate, pentaerythritol diconcan acid 81 201213336 ^ / /ZDpiLl is the 10th 13〇526 Chinese manual no line correction page correction After the flood season: November 11th, vinegar, Yamanashi (four) Ling miscellaneous materials.料巴域自意 crotonic acid vinegar, 1,4, butanediol dicrotonic acid 5, pentaerythritol disorbitol dicropped _. As the methacrylic acid vinegar, there are ethylene dimercaptoate, pentaerythritol dimethacrylate, mountain-two" vinegar, etc. As a maleic acid vinegar, there are ethylene glycol dimaleic acid vinegar, three maleic acid vinegar, Pentaerythritol dimale (4), sorbitol; - as other l diligence, etc.. No. 1 gazette, Sakamoto patent special opening - recorded fat _ _ _, or Japanese patent system 昭 59_5 ^ newspaper, Japanese patent special In the publication of the publication No. 59_5241, the amines and the like described in the Japanese Patent Publication No. 1-16, the vinegar monomer may be used as a mixture and/or 'Turning its silky compound, as a light _ multi-component sputum and sputum-free amine monomer _, there are propylene amide, methylene bis &quot; methacrylic amine, 1,6 _ hexamethylene double _ soil brewed hexamethylene bis-methyl propyl amide amine, diethylene triamine; double propylene :: : bis- propylamine, benzodimethyl dimethyl propyl amide, etc. Examples of the preferred amidoxime-based monomer include the (tetra)cyclohexyl structure described in Japanese No. 1726, and other polymeric compounds. Isocyanate with vinegar to secret produced by reacting a polyamine-based unitary purpose to force opening polymerizable compound is also preferred, said correction of 82: Shu 2000 January 11, said Shu 201213336 ^ I t x is the Chinese manual of No. 100130526 without a jf line correction stomach =. In the case of the need to enter a shorter wavelength, the sixth, 084, 250 notes that Kui Zhongfu from (four) search for you, "" is not able to reveal a kind of can be launched in the history of 300 miscellaneous (four) coffee. Moreover, other ultraviolet ray secrets j saki (four) material _ with radiation. In the middle of the month: Good: The source of sexual radiation is uv_led, especially the uv led with peak wavelength at 34〇(10) ~ 370 nm. Since the laser has a good parallelism, it can be exposed to the pattern even if it is not exposed. However, when the mask is used to expose the pattern to the lamp, the linearity of the pattern becomes higher and better. Moreover, it has exposed the exposure & hardening composition layer, which can be used to make a heating plate or oven before the treatment, in the thief ~ (10). Add c under 0.5 minutes to 15 minutes. ... and in order to suppress the emulsification fading of the colored material in the colored curable composition layer, it is possible to expose the surface by flowing a nitrogen gas in the chamber. &quot; Then j in the developer to the exposed color hardening composition layer after the exposure.,, page shirt. Thereby, a negative or positive coloring pattern (anti-surname pattern) can be formed. When the developer is a uncured portion (unexposed portion) in which the colored curable composition layer is soluble, and the developer of the cured portion (exposure portion) is not dissolved, a combined aqueous solution of various organic riders can be obtained. When the (iv) liquid is in the case of an aqueous test solution, the adjustment is made so that the test concentration becomes 11 to 13, and more preferably, the positive is .... Examples of the alkaline aqueous solution of the horse include sodium hydroxide, potassium hydroquinone, sodium carbonate, sodium hydrogencarbonate, sodium alginate, sodium metasilicate, aqueous ammonia, ethylamine, diethylamine, and dimethylethanolamine. ,four? Based on ammonium hydroxide and tetraethylnitrile 109 201213336 JI /Zjpui is the 1001305% Chinese manual without a slash correction page. Revision date: l〇G年丨丨月^日验, _, (4), diazabicyclo侃 (4) Dr. Shishanshan special aqueous solution. Further, it is possible to adjust the concentration of tetraethylammonium hydroxide to a concentration of wt% to 1% by weight, preferably 〇 〇丨, and 0/· 〇1 as a developing solution. For the 〇1 Wt/〇~5 which is an experimental aqueous solution, it is preferably 3 seconds to 3 (10) seconds, more preferably % seconds. The development temperature is preferably 2 Torr. (: ~4〇t, more preferably 23〇c. The shirt can be washed by water, by the way of immersion, shower, and mist: after developing with an alkaline aqueous solution, it is cleaned by water. The cleaning method is also suitable for the rotation speed of the J qing according to the purpose. (4) The circular base (four) support body is rotated 2 above the rinsing treatment, and the pure water is supplied from the discharge nozzle to the shower, and then the color filter of the present invention is applied. In the manufacturing method of the sheet, the colored pattern formed by the development is subjected to late exposure to promote the hardening of the colored pattern. After the sigh, the step (C) _ heart! 1 is the manufacture of the color light-emitting sheet of the present invention. In the method, the colored pattern (halogen) formed by the Taisha Tin t coloring hardenable composition is introduced; the light of the material is effectively suppressed for the adjacent: === color shift. The color shift is as follows ~ The unique problem caused by the color hard temple, the color shift can be reduced by using the ultraviolet exposure to the subsequent exposure. 斤迷110 201213336 Revision date: 100 years 丨January i is the 100130526 Chinese manual without painting !J line correction page temperature during heat treatment Preferably, it is 10 (rc~30 (rc, more preferably 15 (TC~25 (TC.), the heating time is preferably 3 sec to 3 〇 sec, more preferably 60 sec to 1 〇〇〇 sec. In the method for manufacturing a color light-emitting sheet of the present invention, a subsequent exposure using g lines, h, lines, i lines, KrF, ArF, electron beams, xenon rays, or the like may be performed instead of the step (C) as described above. Such _ ultraviolet radiation exposure after the period. 情形 In the case of using the means for subsequent exposure, 照射 seconds to (10) seconds' is preferably 20 seconds to 12 seconds, more preferably two seconds. ΑΊ%~ In the manufacturing method of 匕媳尤月, it is also possible to perform the ultraviolet ray riding as in the above step (6), but only to perform the late exposure as in the above step (D). With post-heating, either of them is performed first, but it is preferred to carry out the late stage before the late heating. The reason is that; ^ is promoted by the secret filaments in the future, and it is possible to suppress the shape deformation caused by the late addition of the coloring pattern, the overheating of the colored pattern (the spheroidization of the moment egg case), or the reflow of the hem portion. /, The colored pattern obtained as described above constitutes a color filter. The desired step (A), step x, and optionally step (C) or step (D) are used in the production of a color filter having a plurality of hues of color. In addition, the formation of the color-hardening composition layer in each single color, 113 201213336 ^ / /z^pm is the Chinese revision date of the 100130526: November 1st, 1G0 = page: at the end (per i color) The above step (C = (9)' may also be performed after all the colored hardenable layers of the desired number of secrets, exposure, (4), summing up and/or step (D). Step (C) The obtained color filter is used for the color hardening property of the present invention. The composition of the color filter of the color filter of the present invention (the color filter of the present invention) is used, so that it has excellent light resistance. (4) Displaying a P CCD shirt image sensor, a CM 〇 image sensor, etc., in the photographic age of the solid photographic elements, wherein a solid pattern is formed on the film and a good profile is required. The use of the photographic element is a CCD element or CMOS having a high resolution of more than (10) megapixels. [Solid photographic element] The solid photographic element of the present invention has the color filter of the present invention. Color filter with flaws In the light-resistant property, the solid-state imaging device having the color filter can obtain excellent color reproducibility. ^ As a solid-state imaging device, the color filter of the present invention functions as a solid-state imaging device. The configuration is not particularly limited. For example, the configuration may be as follows. That is, the transfer electrode has a transfer electrode (the transfer electrode includes a light receiving region constituting a CCD shirt image sensor (solid-state imaging device). A plurality of photodiodes, polycrystals, and the like are disposed thereon, and a color filter of the present invention is disposed thereon. The structure of the second layer of microlenses is set. ～ 114 201213336 ^*11 Λ. For the 100130526 Chinese manual, there is no scribe correction page. Revision date: The monomer E is different from the polymerizable compound of the present invention on November 11, 2010. Polymerizable compound: Monomer A: Ethoxylated isocyanuric acid triacrylate monomer B: Pentaerythritol triacrylate Ester monomer C: pentaerythritol tetraacrylate monomer D: the following structure [Chem. 67] Monomer E: dipentaerythritol hexaacrylate monomer F: the following structure [Chem. 68] 121 201213336 ^ i i Date of revision: November 1st, 1st of the following year No. 100130526 Chinese manual without line correction page [Chem. 69] Ο Starting agent 2 = 丨 starter 3 In addition, in Table 1, the pigment dispersion is "ρΒ15. 6 ^ shows the pigment blue: 6 dispersion. Moreover, "ΡΒ15" and "pm5 ^ 3" refer to the pigment blue In the preparation of the dispersion liquid of -15:6, a pigment dispersion liquid similar to the preparation of the pigment blue-15:6 dispersion liquid was used instead of PB15 and pigment PB15:3, respectively. However, (Example 2 to Example 9, Reference Example 1) Examples 2 to 9 and Reference Example i used the chemical composition of Table 2. The color of each of τ is hard as follows. Example 丨~Example 9, = Light resistance of the raw composition, and development time dependency, = 122