.201143808 六、發明說明： 【發明所屬之技術領域】 本發明’係關於兩親媒性物質處理的扁平纖維素粉體 及含有此之化妝料，更詳而言之，係關於一種具有扁平的 形狀、且其之表面經兩親媒性物質處理之兩親媒性物質處 理的扁平纖維素粉體及含有此之化妝料。 【先前技術】 含有粉體成分與油性成分等之粉體化妝料，廣泛使用 於化妝品的領域，其之例，可舉例如粉餅、眼影、香粉、 腮紅等。 該粉體化妝料，一般而言，係將塡充顏料、顏料等粉 體成分與油性成分之粉體混合物塡充於皿狀容器，藉由加 壓成形來製造。 該粉體化妝料所使用之粉體成分，爲了使於皮膚上之 延展及附著性佳，一直以來皆使用天然物由來之薄板狀之 雲母片、絹雲母、滑石等或其之表面處理物作爲塡充顏料 。又，爲了提昇塡充顏料於皮膚上之潤滑性或觸感，而與 上述塡充顔料一同使用球狀有機粉體。再者，顏料，係使 用二氧化鈦等白色顔料、氧化鐵紅等著色顏料、雲母鈦等 光澤顏料。 ' 上述粉體成分之中，作爲薄片狀者，泛用雲母片、絹 雲母、滑石等無機系粉體，該等皆爲鋁矽酸鹽系之礦物， 且隨產地不同性質會有若干差異，故例如會有油的吸收性 -5- 201143808 低、無法得到目的之物性等問題。另一方面，於有機物粉 體爲扁平狀者很少有報告提出，例如，僅知道有將纖維素 系物質與脂肪酸混合後，將其機械性的粉碎所得之扁平纖 維素粒子（專利文獻1)。 然而，於該專利文獻1，雖揭示扁平纖維素粒子，但 未揭示其具體的使用形態，於化妝品的應用亦僅揭示極爲 簡單者。 另一方面’亦已知將結晶纖維素之表面以加氫卵磷脂 處理之技術（專利文獻2)。然而，該結晶纖維素，長徑與 短徑之比（L/D)爲3以下，並非爲能稱作扁平者，當實際 與未處理者比較時’於化妝持久性雖有差別，但使用感之 「沾取性」、「延展性」、「完成性」並未揭示有差別。 專利文獻1:日本特開2004-230719號公報 專利文獻2:日本特開2003-146829號公報 【發明內容】 [發明欲解決之課題] 雖然已有許多的化妝料粉體被提供，但消費者要求更 佳使用感之化妝料已是自然的趨勢，本發明之課題在於， 提供一種可提供如此之化妝料之化妝料粉體及使用其之化 妝料。 [解決課題之手段] 本發明人等，著眼於平板狀之扁平纖維素，對於物性 201143808 更優異之扁平纖維素及其之製造法，進行硏究的結果發現 ，藉由使用特定之兩親媒性物質，以特定之方法調製扁平 纖維素，可得目前爲止沒有之物性之表面處理纖維素粉體 、以及藉由利用該表面處理纖維素粉末可極度提高粉體化 妝料等化妝料之商品性，而完成本發明。 亦即，本發明係一種兩親媒性物質處理的扁平纖維素 粉體，其係將纖維素系物質、與選自磷脂質、腦醯胺、膽 固醇及植物固醇所構成群中之兩親媒性物質之1種或2種 以上，經機械性之粉碎處理所得。 又，本發明係一種化妝料，其特徵係，含有上述兩親 媒性物質處理的扁平纖維素粉體。 再者，本發明係一種兩親媒性物質處理的扁平纖維素 粉體之製造方法，其特徵係，將纖維素系物質、與選自磷 脂質、腦醯胺、膽固醇及植物固醇所構成群中之兩親媒性 物質之1種或2種以上，進行機械性之粉碎處理。 [發明的效果] 本發明之兩親媒性物質處理的扁平纖維素粉體，對皮 膚之附著性佳，配合有其之化妝料，塗佈時具潤滑感，化 妝膜之均一性優異，且化妝持久性佳。 因此，利用本發明之兩親媒性物質處理的扁平纖維素 粉體之化妝料，較佳可作爲粉餅、眼影、香粉、腮紅等使 用。 又’上述兩親媒性物質處理的扁平纖維素粉體之中， 201143808 於處理時使用磷脂質之粉體，對於泛用油劑及水的分散性 特別優異。因此，較佳可作爲粉底液等上妝化妝料使用。 又，該粉體之附著性佳，化妝持久性優異。因此，較佳可 作爲粉餅等上妝化妝料使用。 再者，上述兩親媒性物質處理的扁平纖維素粉體之中 ，於處理時使用腦醯胺脂粉體，水分保持量及水分蒸散抑 制等特別保濕性優異。因此，較佳可作爲護膚化妝料或上 妝化妝料使用。 【實施方式】 本發明之兩親媒性物質處理的扁平纖維素粉體，係藉 由將纖維素系物質、與選自磷脂質、腦醯胺、膽固醇或其 之衍生物、植物固醇或其之衍生物所構成群中之兩親媒性 物質之1種或2種以上，經機械性之粉碎處理所製造。 具體而言，兩親媒性物質處理的扁平纖維素粉體，可 藉由下述方法製造：對於纖維素系物質，添加磷脂質、腦 醯胺、膽固醇或其之衍生物、植物固醇或其之衍生物所構 成群中之兩親媒性物質之1種或2種以上，視需要進行混 合等之後，對其進行機械性之粉碎處理。該方法，除將粉 碎助劑改變成兩親媒性物質以外，基本上可依據專利文獻 1之[0 02 0]〜[0041]所記載之方法進行。 作爲兩親媒性物質處理的扁平纖維素粉體之出發原料 使用之纖維素系物質，並無特別限制，例如，較佳可使用 以木材爲起源之纖維狀或粉末狀之木粉或木材紙漿、以棉 201143808 花爲起源之纖維狀或粉末狀之木棉或棉絨纖維、將該等精 製後之纖維狀或粉末狀之纖維素系物質，又，該等纖維素 系物質亦可經酸水解。又’以棉花爲起源之纖維素系物質 ，亦可爲以具有有機認證之棉花爲起源者。又，原料之纖 維素系物質容易吸附或吸收水分，故於通常狀態下具有吸 著水分3〜10質量％(以下，僅稱爲「％」）之程度。爲了有 效地製得扁平纖維素粉體，於將纖維素系物質進行粉碎處 理之前’較佳爲以熱風乾燥、真空乾燥、減壓乾燥等進行 事先乾燥。 上述處理纖維素系物質之磷脂質、腦醯胺、膽固醇及 植物固醇係生體內之脂質或近似於其之構造，亦即具有具 長鏈烷基構造與親水基之共通性質之兩親媒性物質。 上述兩親媒性物質之中，磷脂質係於構造中具有磷酸 酯部位之脂質的總稱。具體之磷脂質，可舉例如於蛋黃卵 磷脂、大豆卵磷脂等天然蛋黃卵磷脂加氫之天然物由來者 、將溶血卵磷脂、磷脂醯膽驗、磷脂醯乙醇胺、磷脂醯絲 氨酸、磷脂醯甘油、磷脂醯肌醇、鞘磷脂等加氫者等。該 等磷脂質之中，以加氫卵磷脂、磷脂醯膽羧、磷脂醯乙醇 胺、加氫磷脂醯甘油較佳。 又，腦醯胺係於分子中具有1個以上之長鏈之直鏈及 /或具支鏈之烷基或烯基、或至少2個以上之羥基、1個以 上之醯胺基（及/或胺基）之非離子兩親媒性物質的總稱。具 體之腦醯胺，可舉例如神經胺醇、植物鞘胺醇之長鏈脂肪 酸醯胺之腦醯胺1、腦醯胺2、腦醯胺3、腦醯胺3 B、腦 -9 - 201143808 醯胺4、腦醯胺5、腦醯胺6、腦醯胺61、腦醯胺611等天 然腦醯胺類等。該等腦醯胺之中，以腦醯胺2、腦醯胺3 較佳。又，該等腦醯胺，可爲天然物由來者、亦可爲合成 者。 再者，膽固醇係將動物油脂皂化之高級醇成分或由魚 油所得之蒸餾成分萃取、結晶化、乾燥而精製之白色至微 黃色的固體，其之分子式爲c27h46o。又，膽固醇之衍生 物，可舉例如膽固醇羥基硬脂酸酯、聚氧乙烯硬脂醚等。 該等膽固醇及其衍生物之中，以膽固醇爲佳。 再者，植物固醇係由植物所得之固醇化合物的總稱。 具體之植物固醇，可舉例如麥固醇、豆固醇、海藻固醇、 疲菜固醇、菜子固醇等。又，植物固醇衍生物，可舉例如 植物固醇羥基硬脂酸酯、聚氧乙烯植物固醇、聚氧乙烯植 物固烷醇等。該等植物固醇及其衍生物之中，以植物固醇 爲佳。 將上述之兩親媒性物質、與纖維素系物質以機械性的 粉碎處理，粉碎所致之壓力及剪切力必須連續施加一定時 間。因此，粉碎處理，較佳爲使用振動球磨機、旋轉球磨 機、行星式球磨機、輥磨機、介質硏磨機、盤式磨機、以 高速旋轉葉片之高速混合機、均質機等粉碎裝置，而特別 以行星式球磨機爲佳。粉碎處理方法，以不使用溶劑之乾 式粉碎處理爲佳。又，於進行粉碎處理時所施加之粉碎能 量爲3〜20G、較佳爲5〜15G。 於上述粉碎處理之際，相對於纖維系物質100質量份 -10- 201143808 ，兩親媒性物質可添加0.1〜12質量份左右、較佳爲1〜4 質量份左右。又，兩親媒性物質可使用1種或組合2種以 上使用。再者，添加兩親媒性物質之時期，只要爲粉碎處 理前即可，又，其之添加方法，可將兩親媒性物質直接添 加於纖維系物質，亦可將兩親媒性物質溶解於適當之溶劑 後，添加於纖維系物質。此處，兩親媒性物質之溶解所使 用之溶劑，可舉例如，己烷等烷、乙醇等醇、丙酮等酮、 四氫呋喃等醚、甲苯等芳香族烴等。 接著，於以下揭示用以製得本發明之兩親媒性物質處 理的扁平纖維素粉體之較佳樣態。首先，將精製後之木材 紙漿由來之纖維素粉末以30〜50°C進行減壓乾燥，將吸著 水分充分除去至〇」％以下。將該纖維素粉末，於可密閉 之氧化鋁製或氧化鍩製粉碎容器，並一倂投入氧化鋁製或 氧化鉻製之粉碎球，接著，以使相對於纖維素粉末爲上述 量的方式添加兩親媒性物質。之後，將上述粉碎容器設置 於行星式球磨機，以轉數100〜250rpm，進行粉碎處理。 粉碎處理，係以粉碎5〜15分鐘-停止5〜15分鐘爲1循 環，可連續地反覆進行2〜72循環左右，亦可不停止而連 續地進行5〜120分鐘左右。 又，於粉碎處理之後，亦可再藉由風乾、熱風乾燥、 真空乾燥、減壓乾燥等周知之乾燥手段除去附著於兩親媒 性物質處理的扁平纖維素粉體之水分等。 如上述所得之兩親媒性物質處理的扁平纖維素粉體， 例如，其之平均粒徑爲1〜l〇0Km、較佳爲1〜50μπι，其 -11 - 201143808 之平均厚度爲0.1〜ΙΟμηι、較佳爲o.l〜2μιη之薄片狀者 ，且扁平度爲4〜200、較佳爲6〜150、更佳爲10〜100。 又，此處所謂之平均粒徑，係指使用雷射繞射、散射 式粒度分布測定裝置等粒度分布測定裝置，於水中分散狀 態所測定之扁平纖維素粒子之寬度與長度之裝置上的平均 値（累積體積50%之粒徑値）。又，所謂平均厚度，係指以 掃描型電子顯微鏡等電子顯微鏡選擇複數之與上述所求得 之平均粒徑同等大小之粒子，測定其之厚度，而將該等平 均之値。再者，扁平度，係如上述所求得之平均粒徑/平 均厚度。 如此所得之兩親媒性物質處理的扁平纖維素粉體，可 利用於粉體化妝料、基礎（護膚）化妝料、上妝化妝料、頭 髮化妝料等各種化妝料。 具體而言，可利用兩親媒性物質處理的扁平纖維素粉 體之化妝料，由於該兩親媒性物質處理的扁平纖維素粉體 ，與以往之塡充顏料之滑石、絹雲母相比，爲薄的薄片狀 、具有透明感、柔軟感、延展性、自然之光澤等優異特性 ，且與所使用之油劑之親和性優異，故特別可舉例如含有 以往之粉體成分之化妝料、特別是粉餅、眼影、腮紅、香 粉等粉體化妝料》 當將本發明之兩親媒性物質處理的扁平纖維素粉體配 合於粉體化妝料時，其之配合量爲1〜90%、較佳爲5〜 9 0 %、特佳爲5〜7 0 %。 上述粉體化妝料中，亦進一步配合油性成分爲佳。配 -12- 201143808 合於粉體化妝料之油性成分，並無特別限制，可舉例如石 獵、地蠟（ceresin wax)、地繼（ozocerite)、微晶蠟、褐媒 熥、費雪·雀卜蠟（Fischer-Tropsch wax)、聚乙嫌獵、液體 石蠟、角鯊烷、凡士林、聚異丙烯、聚丁烯等烴類、棕櫚 蠟、蜜蠟、羊毛脂蠟、小燭樹蠟等之天然蠟類、甘油三二 十二烷酸酯、新戊四醇松香酸酯、荷荷芭油、異辛酸十六 烷基酯、肉豈蔻酸異丙酯、三辛酸甘油酯、三異硬脂酸二 甘油酯、二新戊四醇脂肪酸酯等酯類、硬脂酸、二十二酸 、12-羥基硬脂酸等脂肪酸類、鯨蠟醇、硬脂醇、二十二 醇等高級醇類、橄欖油、蓖麻油、貂油、木蠟等油脂類、 羊毛脂脂肪酸異丙酯、羊毛脂醇等羊毛脂衍生物、N-月桂 醯基-L-麩胺酸二（膽固醇酯•二十二烷酯.十八烷酯）等胺 基酸衍生物類、全氟聚醚、全氟癸烷、全氟辛烷等氟系油 劑類等。該等油性成分可使用1種或2種以上。於本發明 之粉體化妝料，當配合有該等油性成分時之配合量，並無 特別限定，而以0.1〜25%爲佳。 上述粉體化妝料，可與以往之粉體化妝料以同樣方法 製造。具體而言，含有以往之粉體成分與油性成分之化妝 料之製造方法中，可使用兩親媒性物質處理的扁平纖維素 粉體取代以往之粉體的一部分或全部。又，當於上述粉體 化妝料配合滑石等無機粉末或耐綸等有機粉末時，可與本 發明之兩親媒性物質處理的扁平纖維素粉體同時添加滑石 等無機粉末或耐綸等有機粉末、使其分散，並視需要添加 油分來製造。 -13- 201143808 又，於上述粉體化妝料，除上述兩親媒性物質處理的 扁平纖維素粉末及油性成分之外，於不損及本發明效果的 範圍內，亦可適當地配合通常化妝量所使用之成分，例如 ，界面活性劑、油凝膠化劑、多元醇類等保濕劑等水溶性 成分、粉體、紫外線吸收劑、防腐劑、美容成分、香料等 〇 又，具體而言，可利用兩親媒性物質處理的扁平纖維 素粉體之化妝料，由於該兩親媒性物質處理的扁平纖維素 粉體對肌膚的附著性高，故可舉例如基礎化妝料、上妝化 妝料等。 又，當兩親媒性物質處理的扁平纖維素粉體爲腦醯胺 處理扁平纖維素粉體時，水分保持量及水分蒸散抑制等保 濕性特別優異，故較佳可使用於基礎化妝料、特別爲美容 液或乳液、乳霜等護廄化妝料。 又，當兩親媒性物質處理的扁平纖維素粉體爲磷脂質 處理扁平纖維素粉體時，對於泛用油劑及水的分散性特別 優異’故較佳可作爲粉底液等上妝化妝料使用。又，該粉 體之附著性佳，化妝持久性優異，故較佳可作爲粉餅等上 妝化妝料使用。 當將本發明之兩親媒性物質處理的扁平纖維素粉體配 合於基礎化妝料時，其之配合量爲0.1〜10% >當配合於 上妝化妝料時，其之配合量爲0.5〜50%。 上述基礎化妝料，可與以往之基礎化妝料以同樣方式 製造。具體而言，可藉由使用水、油、乙二醇、界面活性 -14- 201143808 劑等，於加溫或室溫下將油分可溶化或分散、乳化後，分 散本發明之兩親媒性物質處理的扁平纖維素粉體來製造。 又，上述上妝化妝料，可與以往之上妝化妝料以同樣 方式製造。具體而言，可藉由使用水、油、乙二醇、界面 活性劑等，於加溫或室溫下將油分可溶化或分散、乳化後 ，分散本發明之兩親媒性物質處理的扁平纖維素粉體來製 造，亦可相反的於油分分散本發明之兩親媒性物質處理的 扁平纖維素粉體後，添加水系成分或界面活性劑，進行乳 化來製造》 實施例 以下，舉實施例以詳細說明本發明，但本發明並不因 該等實施例而產生任何限制。 實施例1 磷脂質處理扁平纖維素粉體之製造（1): 使用精製後之木材紙漿由來之纖維素粉末（W-400G/日 本製紙化藥公司）作爲原料。首先，將藉由以40°C之減壓 乾燥將吸著水分充分除去至0.1 %以下之纖維素粉末（48.5g) ，與氧化锆製之粉碎球（直徑20mm)，一併投入於可密閉 之氧化锆製粉碎容器（容積500ml)，並添加加氫卵磷脂（雷 西諾魯S-10/日光化藥公司製）1.5g，以使加氫卵磷脂相對 於纖維素粉末爲3%的方式調製。 之後，使用行星式球磨機（P-5型/德國Fritsch公司製 -15- 201143808 )，以轉速200rpm(約10G(重力加速度）之粉碎能量）’以粉 碎10分鐘、停止10分鐘爲1循環，進行36循環，製得磷 脂質處理扁平纖維素粉體（製品1)。 使用雷射繞射、散射式粒度分布測定裝置（LMS-24型/ 清新公司製）以流量槽（flow cell)，求出所得粉體之水中分 散狀態下之平均粒徑（寬度與長度之裝置上之平均値）。此 處之平均粒徑，係使用累積體積5 0%之粒徑値。 粒度分布測定，係將所得粉體之50mg分散於蒸餾水 1 0ml之懸浮液，滴下至以粒度分布測定裝置之水作爲介 質的試樣循環槽，於成爲適當之濃度後進行測定。其之結 果，粉體之平均粒徑爲17μπι。 又，所得之粒子的平均厚度，係使用掃描型電子顯微 鏡（S-2450/日立製作所公司製）直接觀察粒子，選擇複數之 與上述所求得之平均粒徑同等大小之粒子，測定厚度，並 將該等平均而求得。 以掃描型電子顯微鏡的觀察，係將極少量之所得粉體 放置於掃描型電子顯微鏡之試樣台上，以減壓乾燥後，蒸 鍍金或鉑等金屬作成鏡檢試樣。由將該鏡檢試樣以加速電 壓20〜25kV、以放大率500〜10,0 00倍觀察所得之影像， 測定與上述所求得之平均粒徑同等大小之粒子的厚度，由 該等求得平均厚度。其之結果，平均厚度爲2 μιη» 如此所得之製品1，係平均粒徑爲1 7μηι、平均厚度爲 2μιη、扁平度（平均粒徑/平均厚度）爲8.5之扁平的纖維素 粒子（磷脂質處理扁平纖維素粉體）。 -16- 201143808 又，作爲比較，測定扁平纖維素粉體之原料之精製後 之木材紙漿由來之纖維素粉末（w-4 0 0 G/日本製紙化藥公司 ，（以下，僅稱爲「纖維素粉末」））及麻纖維素粉末（Tosco 麻纖維素/Tosco公司製）之平均粒徑、平均厚度，求得扁 平度（平均粒徑/平均厚度）。纖維素粉末之形狀並非爲扁平 狀而爲薪材狀，求得平均粒徑爲28μιη、平均厚度爲1〇μ® 、扁平度爲2.8。另一方面，麻纖維素粉末之形狀並非爲 扁平狀也非薪材狀而爲粒狀，測得平均粒徑爲7.7μπι ’而 無法求得平均厚度與扁平度。 實施例2 磷脂質處理扁平纖維素粉體之製造（2): 除將加氫卵磷脂之量改成0.1 %與10%之外，與實施例 1同樣地，分別製得磷脂質處理扁平纖維素粉體（製0Ρ〇 2及 製品3)。該等之平均粒徑、平均厚度及扁平度’係如下所 示。 [表1].201143808 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a flat cellulose powder treated with an amphiphilic substance and a cosmetic containing the same, and more particularly, to a flat type A flat cellulose powder having a shape and a surface treated with an amphiphilic substance treated with an amphiphilic substance and a cosmetic containing the same. [Prior Art] A powder cosmetic containing a powder component and an oil component is widely used in the field of cosmetics, and examples thereof include a powder cake, an eye shadow, a powder, and a blush. In general, the powder cosmetic is produced by press-molding a powder mixture of a powder component such as a pigment or a pigment and an oil component into a dish-shaped container. In order to improve the spreadability and adhesion on the skin, the powder component used in the powder cosmetic has been conventionally used as a sheet-like mica sheet, sericite, talc, or the like as a surface treatment of natural materials. Fill the pigment. Further, in order to enhance the lubricity or feel of the pigment on the skin, a spherical organic powder is used together with the above-mentioned enamel pigment. Further, as the pigment, a white pigment such as titanium dioxide, a coloring pigment such as iron oxide red, or a gloss pigment such as mica titanium is used. Among the above-mentioned powder components, as the flakes, inorganic powders such as mica flakes, sericite, and talc are widely used, and these are all aluminosilicate-based minerals, and there are some differences depending on the nature of the place of origin. Therefore, for example, there is a problem that the oil absorption is low - 201143808 is low, and the physical properties of the purpose cannot be obtained. On the other hand, there has been little report on the fact that the organic powder is flat, and for example, only the cellulose cellulose obtained by mechanically pulverizing the cellulose-based substance and the fatty acid is known (Patent Document 1). . However, in Patent Document 1, although flat cellulose particles are disclosed, the specific use form is not disclosed, and the application to cosmetics is only extremely simple. On the other hand, a technique of treating the surface of crystalline cellulose with hydrogenated lecithin is also known (Patent Document 2). However, in the crystalline cellulose, the ratio of the long diameter to the short diameter (L/D) is 3 or less, which is not a flat one, and when it is actually compared with an untreated one, although there is a difference in makeup durability, it is used. The sense of "staining", "extensibility" and "completeness" did not reveal any difference. Patent Document 1: JP-A-2004-230719 (Patent Document 2) JP-A-2003-146829 SUMMARY OF INVENTION [Problems to be Solved by the Invention] Although many cosmetic powders have been provided, consumers A cosmetic material which requires a better feeling of use is a natural tendency, and an object of the present invention is to provide a cosmetic powder which can provide such a cosmetic and a cosmetic material using the same. [Means for Solving the Problem] The inventors of the present invention have focused on the flat cellulose of flat form, and have made the flat cellulose which is more excellent in physical properties 201143808 and the manufacturing method thereof, and found that by using the specific two parental media The preparation of the flat cellulose by a specific method, the surface-treated cellulose powder having no physical property so far, and the use of the surface-treated cellulose powder can greatly improve the commercial properties of the cosmetic such as the powder cosmetic. The present invention has been completed. That is, the present invention is an amphiphilic material-treated flat cellulose powder which is a cellulose-based substance and a parent selected from the group consisting of phospholipids, ceramide, cholesterol, and phytosterols. One or two or more kinds of the organic substances are obtained by mechanical pulverization treatment. Further, the present invention is a cosmetic characterized by comprising the above-mentioned amphiphilic material-treated flat cellulose powder. Furthermore, the present invention is a method for producing a flat cellulose powder treated with an amphiphilic substance, characterized in that a cellulose-based substance is selected from the group consisting of phospholipids, ceramide, cholesterol, and phytosterols. One or two or more kinds of two affinities in the group are subjected to mechanical pulverization treatment. [Effects of the Invention] The flat cellulose powder treated with the amphiphilic material of the present invention has good adhesion to the skin, is blended with the cosmetic thereof, has a lubricating feeling when applied, and is excellent in uniformity of the cosmetic film, and Make-up persistence. Therefore, the cosmetic of the flat cellulose powder treated with the amphiphilic material of the present invention is preferably used as a powder cake, an eye shadow, a powder, a blush or the like. Further, among the flat cellulose powders treated with the above-mentioned amphiphilic materials, 201143808 uses a phospholipid powder at the time of treatment, and is particularly excellent in dispersibility for a general-purpose oil agent and water. Therefore, it is preferably used as a makeup cosmetic such as a liquid foundation. Moreover, this powder has good adhesion and is excellent in makeup durability. Therefore, it is preferably used as a makeup cosmetic such as a powder cake. Further, among the flat cellulose powders treated with the above-mentioned amphiphilic materials, ceramide powder is used for the treatment, and the moisture retention property such as the water retention amount and the water evaporation inhibition is excellent. Therefore, it is preferably used as a skin care cosmetic or a makeup cosmetic. [Embodiment] The amphiphilic material-treated flat cellulose powder of the present invention is obtained by using a cellulose-based substance and a compound selected from the group consisting of phospholipids, ceramide, cholesterol or a derivative thereof, phytosterol or One or two or more kinds of the two affinities in the group of the derivatives are produced by mechanical pulverization treatment. Specifically, the amphiphilic material-treated flat cellulose powder can be produced by adding a phospholipid, ceramide, cholesterol or a derivative thereof, phytosterol or One or two or more kinds of the two affinities in the group of the derivatives are subjected to mechanical pulverization treatment after mixing or the like as necessary. This method can be carried out basically according to the method described in [0 02 0] to [0041] of Patent Document 1, except that the pulverization aid is changed to an amphiphilic substance. The cellulose-based material used as a starting material of the flat cellulosic powder treated with the amphiphilic material is not particularly limited. For example, it is preferred to use a fibrous or powdery wood powder or wood pulp of wood origin. a fibrous or powdered kapok or cotton fiber of cotton originating from cotton 201143808, or a fibrous or powdery cellulosic material which is refined, and the cellulosic material may also be hydrolyzed by acid . In addition, the cellulose-based substance originating from cotton may also be the origin of cotton with organic certification. In addition, the cellulose material of the raw material is likely to adsorb or absorb water, and therefore has a degree of absorption of water of 3 to 10% by mass (hereinafter, simply referred to as "%") in a normal state. In order to efficiently produce the flat cellulose powder, it is preferably dried by hot air drying, vacuum drying, vacuum drying or the like before the pulverization treatment of the cellulose-based material. The above-mentioned treatment of phospholipids, ceramide, cholesterol and phytosterols in the cellulosic material, or a structure similar to the structure thereof, that is, an amphiphilic substance having a common property of a long-chain alkyl structure and a hydrophilic group. Sexual substance. Among the above amphiphilic substances, phospholipids are a general term for lipids having a phosphate moiety in the structure. Specific phospholipids, for example, natural egg yolk lecithin hydrogenated natural sources such as egg yolk lecithin, soybean lecithin, lysolecithin, phospholipids, phospholipids, ethanolamine, phospholipid serine, phospholipid glycerol Hydrogenated phospholipids, sphingomyelins, etc. Among these phospholipids, hydrogenated lecithin, phospholipid carboxylate, phospholipid oxime ethanolamine, and hydrogenated phospholipid glycerin are preferred. Further, ceramide is a linear or branched alkyl or alkenyl group having at least one long chain in the molecule, or at least two or more hydroxyl groups, and one or more sulfhydryl groups (and / Or a generic term for a nonionic amphiphilic substance. Specific ceramides, for example, ceramide, long-chain fatty acid amide of sphingosine, ceramide, ceramide, ceramide, ceramide 3 B, brain-9 - 201143808 Natural ceramides such as indamine 4, ceramide 5, ceramide 6, ceramide 61, and ceramide 611. Among these ceramides, ceramide 2 and ceramide 3 are preferred. Further, these ceramides may be natural origin or synthetic. Further, cholesterol is a white to yellowish solid which is obtained by extracting, crystallizing, and drying the higher alcohol component which is saponified with animal fat or oil, and is obtained by drying. The molecular formula is c27h46o. Further, examples of the cholesterol derivative include cholesterol hydroxystearate and polyoxyethylene stearyl ether. Among these cholesterols and their derivatives, cholesterol is preferred. Further, a phytosterol is a generic term for a sterol compound obtained from a plant. Specific examples of the phytosterol include, for example, sterol, soybean sterol, seaweed sterol, phytosterol, rapeseed sterol, and the like. Further, the phytosterol derivative may, for example, be phytosterol hydroxystearate, polyoxyethylene phytosterol or polyoxyethylene plant stanol. Among these phytosterols and derivatives thereof, phytosterols are preferred. The above-mentioned two affinities and the cellulose-based material are mechanically pulverized, and the pressure and shearing force caused by the pulverization must be continuously applied for a certain period of time. Therefore, the pulverization treatment is preferably a pulverizing device using a vibrating ball mill, a rotary ball mill, a planetary ball mill, a roll mill, a media honing machine, a disc mill, a high-speed mixer that rotates blades at a high speed, and a homogenizer. A planetary ball mill is preferred. The pulverization treatment method is preferably a dry pulverization treatment without using a solvent. Further, the pulverization energy applied during the pulverization treatment is 3 to 20 G, preferably 5 to 15 G. In the above pulverization treatment, the amphiphilic substance may be added in an amount of about 0.1 to 12 parts by mass, preferably about 1 to 4 parts by mass, based on 100 parts by mass of the fiber-based substance -10-201143808. Further, the amphiphilic substance may be used alone or in combination of two or more. In addition, the period of adding the amphiphilic substance may be as long as it is before the pulverization treatment, and the method of adding the amphiphilic substance may be directly added to the fiber-based substance, or the amphiphilic substance may be dissolved. After appropriate solvent, it is added to the fiber-based material. Here, examples of the solvent used for the dissolution of the amphiphilic material include an alcohol such as hexane, an alcohol such as ethanol, a ketone such as acetone, an ether such as tetrahydrofuran, or an aromatic hydrocarbon such as toluene. Next, preferred embodiments of the flat cellulose powder for treating the amphiphilic material of the present invention are disclosed below. First, the cellulose powder from the refined wood pulp is dried under reduced pressure at 30 to 50 ° C to sufficiently remove the absorbing water to less than 〇%. The cellulose powder is placed in a pulverization container made of a sealable alumina or cerium oxide, and is put into a pulverized ball made of alumina or chrome oxide, and then added in such a manner as to be the above amount with respect to the cellulose powder. Amphiphilic substance. Thereafter, the pulverization container was placed in a planetary ball mill, and pulverized at a number of revolutions of 100 to 250 rpm. The pulverization treatment is carried out by pulverizing for 5 to 15 minutes - stopping for 5 to 15 minutes for 1 cycle, and continuously repeating about 2 to 72 cycles, or continuously for 5 to 120 minutes without stopping. Further, after the pulverization treatment, the moisture of the flat cellulose powder adhering to the amphiphilic material may be removed by a known drying means such as air drying, hot air drying, vacuum drying or reduced pressure drying. The flat cellulose powder treated with the above two amphiphilic materials, for example, has an average particle diameter of 1 to 10 Å, preferably 1 to 50 μm, and an average thickness of -11 to 201143808 is 0.1 to ΙΟμηι. Preferably, it is a sheet of ol~2μηη, and the flatness is 4 to 200, preferably 6 to 150, more preferably 10 to 100. In addition, the average particle diameter here means the average on the apparatus of the width and length of the flat cellulose particle measured by the particle size distribution measuring apparatus, such as a laser diffraction and a scattering particle size distribution measuring apparatus, in the state of dispersion of water.値 (50% cumulative particle size 値). In addition, the average thickness means that a plurality of particles having the same size as the average particle diameter obtained by the above-described electron microscopy are selected by an electron microscope such as a scanning electron microscope, and the thickness thereof is measured, and the average is made. Further, the flatness is an average particle diameter/average thickness as determined above. The flat cellulose powder to be treated with the two parent materials can be used for various cosmetic materials such as a powder cosmetic, a basic (skin care) cosmetic, a makeup cosmetic, and a hair cosmetic. Specifically, a cosmetic material of a flat cellulose powder treated with an amphiphilic material can be used, and the flat cellulose powder treated by the amphiphilic material is compared with talc and sericite which have been conventionally filled with pigments. It is excellent in properties such as a thin flaky shape, a feeling of transparency, softness, ductility, and natural luster, and is excellent in affinity with an oil agent to be used, and particularly, for example, a cosmetic containing a conventional powder component. In particular, a powdery cosmetic such as a powder cake, an eye shadow, a blush, or a fragrant powder. When the flat cellulose powder treated with the amphiphilic material of the present invention is blended with a powder cosmetic, the compounding amount thereof is 1~ 90%, preferably 5 to 90%, and particularly preferably 5 to 70%. In the above powder cosmetic, it is also preferable to further blend an oil component. -12- 201143808 The oily component of the powder cosmetic is not particularly limited, and examples thereof include stone hunting, ceresin wax, ozocerite, microcrystalline wax, brown worm, and Fisher. Fischer-Tropsch wax, polyethylation, liquid paraffin, squalane, petrolatum, polyisopropene, polybutene and other hydrocarbons, palm wax, beeswax, lanolin wax, candelilla wax, etc. Natural wax, glyceryl tridocate, pentaerythritol rosinate, jojoba oil, cetyl isooctanoate, isopropyl myristate, tricaprylate, triiso Esters such as stearic acid diglyceride, dipentaerythritol fatty acid ester, fatty acids such as stearic acid, behenic acid, 12-hydroxystearic acid, cetyl alcohol, stearyl alcohol, and stearyl alcohol Such as higher alcohols, olive oil, castor oil, eucalyptus oil, wood wax and other oils, lanolin fatty acid isopropyl ester, lanolin alcohol and other lanolin derivatives, N-lauric acid-L-glutamic acid II (cholesterol Amino acid derivatives such as ester, behenyl ester and octadecyl ester, perfluoropolyether, perfluorodecane, perfluorooctane, etc. Wait. These oily components can be used alone or in combination of two or more. The powder cosmetic of the present invention is not particularly limited as long as it is blended with the oily components, and is preferably 0.1 to 25%. The above powder cosmetic can be produced in the same manner as the conventional powder cosmetic. Specifically, in the method for producing a cosmetic containing a conventional powder component and an oil component, a part or all of the conventional powder may be replaced by a flat cellulose powder treated with an amphiphilic material. Further, when the powder cosmetic is blended with an inorganic powder such as talc or an organic powder such as nylon, an inorganic powder such as talc or an organic compound such as nylon can be simultaneously added to the flat cellulose powder treated with the amphiphilic material of the present invention. The powder is dispersed, and oil is added as needed to produce. In addition to the flat cellulose powder and the oily component treated with the above-mentioned amphiphilic material, the powder cosmetic may be appropriately blended with the usual makeup in the range which does not impair the effects of the present invention. a component used for the amount, for example, a water-soluble component such as a surfactant, an oil gelling agent, or a moisturizing agent such as a polyhydric alcohol, a powder, an ultraviolet absorber, a preservative, a cosmetic component, a perfume, etc., specifically, A cosmetic material of a flat cellulose powder which can be treated with an amphiphilic substance, and the flat cellulose powder treated with the amphiphilic substance has high adhesion to the skin, and therefore, for example, a basic cosmetic or a makeup Cosmetics, etc. In addition, when the flat cellulose powder treated with the amphiphilic material is a ceramide-treated flat cellulose powder, the moisture retention property such as the moisture retention amount and the moisture transpiration suppression is particularly excellent, and therefore it is preferably used for a base cosmetic, Especially for beauty liquids or lotions, creams and other ankle care cosmetics. In addition, when the flat cellulose powder to be treated with the amphiphilic material is a phospholipid-treated flat cellulose powder, it is particularly excellent in dispersibility for a general-purpose oil agent and water, so that it can be preferably used as a foundation or the like. Material used. Further, since the powder has good adhesion and excellent long-lasting makeup, it is preferably used as a cosmetic such as a powder cake. When the flat cellulose powder treated with the amphiphilic material of the present invention is blended with the base cosmetic, the blending amount thereof is 0.1 to 10% > when blended with the cosmetic, the blending amount is 0.5. ~50%. The above basic cosmetic can be produced in the same manner as the conventional basic cosmetic. Specifically, the two affinities of the present invention can be dispersed by dissolving or dispersing or emulsifying the oil after heating or room temperature by using water, oil, ethylene glycol, interfacial activity-14-201143808, or the like. The material is treated with a flat cellulose powder. Further, the above-mentioned makeup cosmetic can be produced in the same manner as the conventional makeup cosmetic. Specifically, the oil can be dissolved or dispersed or emulsified by heating or room temperature by using water, oil, ethylene glycol, a surfactant, etc., and then the flat of the amphiphilic substance treated by the present invention is dispersed. The cellulose powder may be produced by dispersing the flat cellulose powder treated with the amphiphilic substance of the present invention in the same manner as the oil, and then adding a water component or a surfactant to emulsifie and manufacturing the film. The invention is illustrated by the following detailed description, but the invention is not limited by the examples. Example 1 Production of phospholipid-treated flat cellulose powder (1): Cellulose powder (W-400G/Japan Paper Chemical Co., Ltd.) derived from refined wood pulp was used as a raw material. First, the cellulose powder (48.5 g) which is sufficiently removed by adsorption to a water content of 0.1% or less by drying under reduced pressure at 40 ° C, and a pulverized ball made of zirconia (20 mm in diameter) are simultaneously placed in a sealable state. a pulverized zirconia pulverization vessel (volume: 500 ml), and 1.5 g of hydrogenated lecithin (manufactured by Rexinolu S-10/Sunlight Chemical Co., Ltd.) was added to make hydrogenated lecithin 3% relative to cellulose powder. Mode modulation. After that, a planetary ball mill (P-5 type / -15-201143808, manufactured by Fritsch, Germany) was used, and the rotation speed was 200 rpm (pulverization energy of about 10 G (gravity acceleration)), and the cycle was performed by pulverizing for 10 minutes and stopping for 10 minutes. 36 cycles were carried out to prepare a phospholipid-treated flat cellulose powder (Product 1). Using a laser diffraction and scattering type particle size distribution measuring apparatus (LMS-24 type / manufactured by Shinsei Co., Ltd.), a flow cell is used to determine an average particle size (width and length) of the obtained powder in a state of dispersion in water. The average 値). The average particle size here is a particle size 値 using a cumulative volume of 50%. In the measurement of the particle size distribution, 50 mg of the obtained powder was dispersed in a suspension of 10 ml of distilled water, and the mixture was dropped to a sample circulation tank using water of a particle size distribution measuring apparatus as a medium, and the measurement was carried out at an appropriate concentration. As a result, the average particle diameter of the powder was 17 μm. Further, the average thickness of the obtained particles was measured by direct observation of particles using a scanning electron microscope (S-2450/manufactured by Hitachi, Ltd.), and a plurality of particles having the same size as the average particle diameter obtained above were selected, and the thickness was measured. The average is obtained. Observation by a scanning electron microscope was carried out by placing a very small amount of the obtained powder on a sample stage of a scanning electron microscope, drying it under reduced pressure, and then vapor-depositing a metal such as gold or platinum to prepare a microscopic sample. The microscopic sample was observed at an acceleration voltage of 20 to 25 kV at an amplification factor of 500 to 10,000 times, and the thickness of the particles having the same size as the average particle diameter obtained above was measured. Get the average thickness. As a result, the average thickness was 2 μηη» The thus obtained product 1 was a flat cellulose particle having an average particle diameter of 17 μm, an average thickness of 2 μm, and a flatness (average particle diameter / average thickness) of 8.5 (phospholipid) Treatment of flat cellulose powder). -16- 201143808 In addition, as a comparison, a cellulose powder derived from the refined wood pulp of the raw material of the flat cellulose powder (w-4 0 0 G/Nippon Paper Chemical Co., Ltd.) (hereinafter, simply referred to as "fiber The average particle diameter and the average thickness of the powder ") powder and hemp cellulose powder (Tosco hemp cellulose / Tosco Co., Ltd.) were determined to have flatness (average particle diameter / average thickness). The shape of the cellulose powder was not flat and was a fuel-like shape, and the average particle diameter was 28 μm, the average thickness was 1 〇μ®, and the flatness was 2.8. On the other hand, the shape of the hemp cellulose powder was not flat or non-foam, but was granular, and the average particle diameter was measured to be 7.7 μm·, and the average thickness and flatness could not be obtained. Example 2 Production of phospholipid-treated flat cellulose powder (2): Phospholipid-treated flat fibers were prepared in the same manner as in Example 1 except that the amount of hydrogenated lecithin was changed to 0.1% and 10%. Plain powder (made 0Ρ〇2 and product 3). The average particle size, average thickness and flatness of these are shown below. [Table 1]
平均粒徑 (μηι) 平均厚度 (μιη) 扁平度 製品1 17 2 8.5 製品2 18 3 6 製品3 17 1.5 Π-3___-J 實施例3 磷脂質處理扁平纖維素粉體之製造（3): -17- 201143808 作爲磷脂質，使用加氫溶血卵磷脂（日本精化公司製 :LP-70H)、磷脂醯乙醇胺（和光純藥公司製）及鞘憐脂（和 光純藥公司製）取代實施例1之加氫卵磷脂，以下與實施 例1同樣地，分別製得磷脂質處理扁平纖維素粉體（製品4 〜6)。該等之平均粒徑、平均厚度及扁平度，係如下所示 [表2] 平均粒徑 (μηι) 平均厚度 (μηι) 扁平度 製品1 17 2 8.5 製品4 18 2 9 製品5 19 2.5 7.6 製品6 17 2.5 6.8 實施例4 磷脂質處理扁平纖維素粉體之製造（4): 使用精製後之木材紙漿由來之纖維素粉末（W-400G /日 本製紙化藥公司）作爲原料。將其與氧化鋁製之粉碎球， —併投入於可密閉之氧化鋁製粉碎容器，於其以使相對於 棉花爲5 %的方式添加加氫卵磷脂（雷西諾魯S -1 0/日光化 藥公司製）。之後，使用行星式球磨機（P-5型/德國Fritsch 公司製），以轉速200rPm(約10G(重力加速度）之粉碎能量） ，連續進行粉碎60分鐘。所得之磷脂質處理扁平纖維素 粉體，平均粒徑爲20μιη、平均厚度爲1.2μπι、扁平度爲 16.7(製品 7)。 -18- 201143808 實施例5 磷脂質處理扁平纖維素粉體之製造（5): 使用有機棉花（7號梳棉條原色/亞班替公司製）作爲原 料。將其以粉碎機（楨野產業製：RC100型）切斷成粉碎後 ，與氧化鋁製之粉碎球，—倂投入於可密閉之氧化鋁製粉 碎容器，並於其以使相對於棉花爲1 %的方式添加加氫卵 磷脂（雷西諾魯S-10/日光化藥公司製）。之後’使用行星 式球磨機（P-5型/德國Fritsch公司製）’以轉速200rpm(約 10G(重力加速度）之粉碎能量），連續進行粉碎60分鐘。 所得之磷脂質處理扁平纖維素粉體，平均粒徑爲20 μιη、 平均厚度爲1.6 μιη、扁平度爲12.5(製品8)。 實施例6 磷脂質處理扁平纖維素粉體之製造（6): 原料爲精製後之木材紙漿由來之纖維素粉末（W-400G/ 曰本製紙化藥公司），將其與氧化鋁製之粉碎球，一倂投 入於可密閉之氧化鋁製粉碎容器，於其以使相對於棉花爲 2%的方式添加加氫卵磷脂（雷西諾魯S-10/日光化藥公司製 )。之後，使用行星式球磨機（P-5型/德國Fritsch公司製） ，以轉速2〇〇rpm(約10G(重力加速度）之粉碎能量），連續 進行粉碎50分鐘。所得之磷脂質處理扁平纖維素粉體， 平均粒徑爲17.8 μιη、平均厚度爲0.2 μιη、扁平度爲89.0( 製品9) » -19- 201143808 參考例1 硬脂酸處理扁平纖維素粉末之製造： 除使用硬脂酸取代加氫卵磷脂以外，與實施例1同樣 地進行處理。製得硬脂酸處理扁平纖維素粉末（比較製品 1)〇 對所得之硬脂酸處理扁平纖維素粉末，與實施例1同 樣地進行粒度分布測定的結果，其之平均粒徑爲1 6μιη。 又，與實施例1同樣地測定所得之比較製品1之平均 厚度及扁平度（平均粒徑/平均厚度）的結果，平均厚度爲 3μιη、扁平度爲5.3。 參考例2 磷脂質處理絹雲母之製造= 將絹雲母（艾德巴魯300S/角八魚燐箔公司製）99%以大 豆磷脂質（卵磷脂/味之素公司製）1 %進行被覆處理，製得 磷脂質處理絹雲母（比較製品2)。 參考例3 磷脂質處理纖維素粉末（非扁平）之製造： 將木材紙漿由來之纖維素粉末（W-10 0G/日本製紙化藥 公司），投入攪拌機，以使相對於纖維素粉末爲3%的方式 將加氫卵磷脂（雷西諾魯S -1 0/日光化藥公司製）溶解於己 烷後添加。之後，以轉數40rpm攪拌5分鐘，減壓乾燥後 -20- 201143808 ，進行粉碎，製得磷脂質處理纖維素粉末（非扁平）（比較製 品3)。 實施例7 分散性試驗： 以下述之分散性試驗方法，調查實施例1所得之磷脂 質處理扁平纖維素粉體（製品1)對於各種溶劑之分散性。 作爲比較及對照，使用參考例1之硬脂酸處理扁平纖維素 (比較製品1)及原料之纖維素粉末（對照品）。又，分散介 質（溶劑），係使用液體石蠟（KLEAROL)、三-(2-乙基己酸） 甘油酯（T.I.O)、矽酮油（10cs)(KF-96)及水。將其之結果示 於表3。 (試驗方法） 於6號規格瓶，混合各試樣〇.5g與分散介質24.5 g( 2 wt%) ’以超音波分散1小時後，移至沉降管觀察分散狀態 。而評價既定時間後之分散體積（粉體仍呈懸浮之部分的 體積），由下式求出分散率（％)。 分散率（％) =分散體積（ml)/總體積（ml)xl00 -21 - 201143808 【ε撇】 1小時後 2小時後 95.7 95.7 - 8.9 28.3 28.3 矽酮油 (10cs) 1小時後 2小時後 58.9 24.7 20.5 17.1 22.1 21.0 三-(2-乙基己酸） 甘油酯 1小時後 2小時後 99.6 99.6 99.2 99.2 62.3 27.2 液體石蠟 1小時後 2小時後 82.2 61.6 33.1 15.4 19.5 18.8 製品1 比較製品1 對照品 -22- 201143808 實施例8 附著性試驗： 使用人工皮膚以下述之附著性試驗方法’調査實施例 1所得之磷脂質處理扁平纖維素粉體（製品i)對皮膚的附著 性。作爲比較，使用參考例1之硬脂酸處理扁平纖維素（ 比較製品1)及參考例3之將纖維素粉末經磷脂質處理者（ 比較製品3)。將其之結果示於表4。 (試驗方法） 將各試樣60mg塗佈於聚胺基甲酸酯製人工皮膚（25cm2) 後，於該塗佈之面上放置艾連寇紙’使用油壓加壓機由上 施加100kg之荷重10秒鐘。之後，秤量附著於紙上之粉 體量，計算出粉體於人工皮膚的附著量。 [表4] 試樣 粉體於皮膚 的殘存量(g) 製品1 26 比較製品1 18 比較製品3 14 實施例9 固形粉末型粉底： 依一般方法，以下述表5所示組成調製固形粉末粉底 。對所得之固形粉末粉底，以下述評價方法，評價其之「 化妝膜之均一性」、「化妝持久性」及「使用感（塗佈時 之潤滑感）」。將其之結果一倂示於表5。 -23- 201143808 (評價方法） 使化妝品評價專門評價人員20名使用本發明品1〜3 及比較品1〜4之固形粉末型粉底，對於「化妝膜之均一 性」、「化妝持久性」及「使用感（塗佈時之潤滑感）」各 自依據以下之評價基準進行7階段評價，對每個樣品付以 評價點。接著，由總評價人員之評價點的平均點，依據以 下之判定基準判定各製品。 評價基準： (評價）：（內容） 6 : 非常佳 5 : 佳 4 :尙可 3 :普通 2 :稍差 1 : 差 〇 : 非常差 判定基準： : (判定） : ◎(非常良好） : 〇（良好） : △(稍不良） : x(不良） (評價點之平均點） 5.0以上 3.5以上未滿5.0 1 . 5以上未滿3.5 未滿1.5 結果： -24- 201143808 [表5]Average particle size (μηι) Average thickness (μιη) Flatness product 1 17 2 8.5 Product 2 18 3 6 Product 3 17 1.5 Π-3___-J Example 3 Production of phospholipid treated flat cellulose powder (3): 17-201143808 As a phospholipid, hydrolyzed lecithin (manufactured by Nippon Seika Co., Ltd.: LP-70H), phospholipid, ethanolamine (manufactured by Wako Pure Chemical Industries, Ltd.), and scabbard (manufactured by Wako Pure Chemical Industries, Ltd.) were used instead of Example 1. The hydrogenated lecithin was prepared in the same manner as in Example 1 except that the phospholipid-treated flat cellulose powder (Products 4 to 6) was obtained. The average particle size, average thickness and flatness are as follows [Table 2] Average particle size (μηι) Average thickness (μηι) Flatness product 1 17 2 8.5 Product 4 18 2 9 Product 5 19 2.5 7.6 Product 6 17 2.5 6.8 Example 4 Production of phospholipid-treated flat cellulose powder (4): A cellulose powder (W-400G / Nippon Paper Chemical Co., Ltd.) derived from refined wood pulp was used as a raw material. This was mixed with a crushed ball made of alumina, and placed in a closable container made of alumina, which was added to hydrogenated lecithin in a manner of 5% relative to cotton (Recino S-1 0/ Sunlight Chemical Co., Ltd.). Thereafter, the ball was continuously pulverized for 60 minutes using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany) at a rotation speed of 200 rPm (pulverization energy of about 10 G (gravity acceleration)). The obtained phospholipid-treated flat cellulose powder had an average particle diameter of 20 μm, an average thickness of 1.2 μm, and a flatness of 16.7 (Product 7). -18- 201143808 Example 5 Production of phospholipid-treated flat cellulose powder (5): Organic cotton (manufactured by No. 7 card stock/Abbott) was used as a raw material. After being pulverized by a pulverizer (manufactured by Sagino Industry Co., Ltd.: RC100 type), the pulverized ball made of alumina is placed in a closable container made of alumina and sealed so as to be relative to cotton. Hydrogenated lecithin (Rexinolu S-10/Daily Chemical Co., Ltd.) was added in a 1% manner. Thereafter, the pulverization was continued for 60 minutes using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany) at a number of revolutions of 200 rpm (pulverization energy of about 10 G (gravity acceleration)). The obtained phospholipid-treated flat cellulose powder had an average particle diameter of 20 μηη, an average thickness of 1.6 μηη, and a flatness of 12.5 (Product 8). Example 6 Production of Phospholipid-treated Flat Cellulose Powder (6): The raw material was a cellulose powder derived from refined wood pulp (W-400G/Sakamoto Paper Chemical Co., Ltd.), which was pulverized with alumina. The ball was placed in a closable container made of alumina, and hydrogenated lecithin (manufactured by Resinoru S-10/Sunlight Chemical Co., Ltd.) was added so as to be 2% with respect to cotton. Thereafter, the mixture was continuously pulverized for 50 minutes using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany) at a rotation speed of 2 rpm (a pulverization energy of about 10 G (gravity acceleration)). The obtained phospholipid-treated flat cellulose powder has an average particle diameter of 17.8 μηη, an average thickness of 0.2 μηη, and a flatness of 89.0 (Product 9) » -19- 201143808 Reference Example 1 Production of stearic acid-treated flat cellulose powder : Treatment was carried out in the same manner as in Example 1 except that stearic acid was used instead of hydrogenated lecithin. The stearic acid-treated flat cellulose powder (Comparative Product 1) was obtained. The obtained stearic acid-treated flat cellulose powder was subjected to particle size distribution measurement in the same manner as in Example 1, and the average particle diameter thereof was 16 μm. Further, as a result of measuring the average thickness and flatness (average particle diameter/average thickness) of the comparative product 1 obtained in the same manner as in Example 1, the average thickness was 3 μm and the flatness was 5.3. Reference Example 2 Production of phospholipid-treated sericite = 99% of sericite (Adebaru 300S / octopus oyster foil company) was coated with soybean phospholipid (manufactured by Lecithin/Ajinomoto Co., Ltd.) at 1% , a phospholipid treated sericite (Comparative Article 2) was prepared. Reference Example 3 Production of phospholipid-treated cellulose powder (non-flat): A cellulose powder (W-10 0G/Nippon Paper Chemical Co., Ltd.) from which wood pulp was obtained was put into a mixer so as to be 3% relative to the cellulose powder. The hydrogenated lecithin (manufactured by Resinoru S-1/Sunlight Chemical Co., Ltd.) was dissolved in hexane and added. Thereafter, the mixture was stirred at a number of revolutions of 40 rpm for 5 minutes, dried under reduced pressure, and then -20-201143808, and pulverized to obtain a phospholipid-treated cellulose powder (non-flat) (Comparative Product 3). Example 7 Dispersibility test: The dispersibility of the phospholipid-treated flat cellulose powder (Product 1) obtained in Example 1 for various solvents was examined by the following dispersibility test method. As a comparison and control, the flat cellulose (Comparative Product 1) and the cellulose powder (control) of the raw material were treated with the stearic acid of Reference Example 1. Further, as the dispersion medium (solvent), liquid paraffin (KLEAROL), tris-(2-ethylhexanoic acid) glyceride (T.I.O.), anthrone oil (10cs) (KF-96) and water were used. The results are shown in Table 3. (Test method) In a No. 6 size bottle, each sample was mixed with 55 g and 24.5 g (2 wt%) of the dispersion medium, and dispersed by ultrasonic waves for 1 hour, and then transferred to a sedimentation tube to observe a dispersed state. On the other hand, the dispersion volume after a predetermined period of time (the volume in which the powder was still suspended) was evaluated, and the dispersion ratio (%) was determined by the following formula. Dispersion rate (%) = dispersion volume (ml) / total volume (ml) xl00 -21 - 201143808 [ε撇] 2 hours after 2 hours 95.7 95.7 - 8.9 28.3 28.3 oxime oil (10cs) 2 hours after 1 hour 58.9 24.7 20.5 17.1 22.1 21.0 Tris-(2-ethylhexanoic acid) Glyceryl ester 1 hour after 2 hours 99.6 99.6 99.2 99.2 62.3 27.2 Liquid paraffin 1 hour later 2 hours later 82.2 61.6 33.1 15.4 19.5 18.8 Product 1 Comparative product 1 Control -22-201143808 Example 8 Adhesion test: The adhesion of the phospholipid-treated flat cellulose powder (product i) obtained in Example 1 to the skin was investigated using artificial skin by the following adhesion test method. For comparison, the cellulose powder treated with the stearic acid of Reference Example 1 (Comparative Article 1) and the cellulose powder of Reference Example 3 were treated with the phospholipid (Comparative Article 3). The results are shown in Table 4. (Test method) 60 mg of each sample was applied to artificial skin (25 cm 2 ) made of polyurethane, and then Ai Lian paper was placed on the coated surface. 100 kg was applied from above using a hydraulic press. The load is 10 seconds. Thereafter, the amount of powder adhering to the paper was weighed, and the amount of adhesion of the powder to the artificial skin was calculated. [Table 4] Residual amount of sample powder on skin (g) Product 1 26 Comparative article 1 18 Comparative article 3 14 Example 9 Solid powder type foundation: According to a general method, a solid powder foundation was prepared by the composition shown in Table 5 below. . The obtained solid powder foundation was evaluated for "uniformity of the cosmetic film", "lastingness of makeup" and "feeling of use (lubricating feeling at the time of coating)" by the following evaluation methods. The results are shown in Table 5. -23- 201143808 (Evaluation method) The cosmetics evaluation expert 20 used solid powder type foundations of the present invention products 1 to 3 and comparative products 1 to 4, and "smoothness of makeup film" and "lasting makeup" and "The feeling of use (lubrication feeling at the time of coating)" was evaluated in accordance with the following evaluation criteria in seven stages, and evaluation points were applied to each sample. Next, the average point of the evaluation points of the total evaluators is determined based on the following criteria. Evaluation criteria: (Evaluation): (Content) 6 : Very good 5 : Good 4 : 尙 可 3 : Normal 2 : Slightly worse 1: Difference: Very poor judgment criteria: : (Judgment) : ◎ (very good) : 〇 (Good) : △ (slightly bad) : x (bad) (average point of evaluation point) 5.0 or more 3.5 or more but less than 5.0 1 . 5 or less less than 3.5 less than 1.5 Result: -24- 201143808 [Table 5]
No. 成分 本發明品 比較品 1 2 3 1 2 3 4 1 氧化鈦 15 15 15 15 15 15 15 2 氧化鐵紅 0.2 0.2 0.2 0.2 0.2 0.2 0.2 3 黃氧化鐵 1.5 1.5 1.5 1.5 1.5 1.5 1.5 4 黑氧化鐵 0.2 0.2 0.2 0.2 0.2 0.2 0.2 5 群青 0.1 0.1 0.1 0.1 0.1 0.1 0.1 6 滑石 20 20 20 20 20 20 20 7 0.1%卵磷脂處理扁平纖 維素粉體(製品2) 10 - - - - - - 8 3%卵磷脂處理扁平纖 維素粉體(製品1) - 10 - - - - - 9 10%卵磷脂處理扁平纖 維素粉體(製品3) - - 10 - - - - 10 3%硬脂酸處理扁平纖 維素粉末(比較製品1) - - - 10 - - - 11 1%卵磷脂處理絹雲母 (比較製品2) - - - - 10 - - 12 粉末纖維素(W-400G/日 本製紙化藥公司製） - - - - - 9.7 - 13 加氫卵磷脂(雷西諾魯 s-io/日光化藥公司製） - - - - - 0.3 - 14 卵磷脂處理纖維素粉末 (非扁平)(比較製品3) - - - - - - 10 15 雲母 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 16 耐綸末 2 2 2 2 2 2 2 17 對經基苯甲酸甲酯 0.2 0.2 0.2 0.2 0.2 0.2 0.2 18 三2-乙基己酸甘油酯 4 4 4 4 4 4 4 19 液體石蠟 5 5 5 5 5 5 5 20 香料 0.1 0.1 0.1 0.1 0.1 0.1 0.1 <評價項目及判定結果> 化妝膜之均一 1 生 〇 ◎ ◎ Δ 〇 X X 化妝持久性 ◎ ◎ ◎ Δ 〇 X Δ 使用感(塗佈時之潤滑感） ◎ ◎ ◎ Δ X X X -25- 201143808 實施例1 〇 雙層化妝水 以下述方法製造以下所示組成之雙層化妝水。 诚分） (%) 1. 聚氧乙烯烷基醚磷酸酯注D 0.01 2. 精製水 2.5 3. 磷脂質處理扁平纖維素粉體(製品1) 0.5 4. 氯化鋁 0.1 5. 精製水 剩餘量 6. 乙醇 20.0 7. 異硬脂酸聚氧乙烯硬化蓖麻油**2) 0.1 8. 防腐劑 適量 9. 香料適量 注1)尼寇魯DDP-8(日本Surfactant工業公司製） 注2)艾瑪雷克斯RWIS-150(日本乳膠公司製） (製法） (1) 混合成分1〜3。 (2) 於（1)中添加成分4〜9,攪拌至均勻，製得雙層化 妝水。 所得之雙層化妝水，係粉體分散性優異、潤滑之使用 感、化妝持續效果優異之雙層化妝水。 實施例11 乳液： 以下述方法製造以下所示組成之乳液。 -26- 201143808 诚分） (%) 1. 硬脂酸 0.5 2. 單硬脂酸聚氧乙烯(20莫耳)山梨醇酐 1.0 3. 四油酸聚氧丙烯(40莫耳)山梨糖醇 1.0 4. 二十二醇 1.5 5. 液體石蠘 5.0 6. 三2-乙基己酸甘油酯 5.0 7. 二甲基聚矽氧院^3) 1.0 8. 丙烯酸/甲基丙烯酸烷基酯共聚物注4) 0.1 9. 三仙膠 0.1 10. 氫氧化鈉 0.05 11. 1，3-丁二醇 8.0 12. 防腐劑 適量 13. 香料 適量 14. 精製水 剩餘量 15. 磷脂質處理扁平纖維素粉體(製品1) 1.0 注3)KF-96(10CS)(信越化學工業公司製） 注 4) CARBOPOL 1342(LUBRIZOL ADVANCED MATERIALS 公司製） (製法） (1) 將成分1〜7以80°C混合均勻。 (2) 將成分8〜14以80°C混合均勻。 (3) 於（1)中添加（2)，進行乳化。 (4) 將（3)於攪拌之下冷卻’添加成分15後混合均勻， 製得乳液。 所得之乳液，係乳化安定性優異、潤滑之使用感、化 -27- 201143808 妝持續效果優異之乳液。 實施例1 2 乳霜= 以下述方法製造以下所示組成之乳霜。 減分） (%) 1. 五油酸十甘油酯 2.5 2. 二十二醇 1.5 3. 凡士林 3.0 4. 重質液體異院烴 1.0 5. 三2-乙基己酸甘油酯 3.0 6. 二甲基聚矽氧院^"3) 1.0 7. 磷脂質處理扁平纖維素粉體(製品2) 1.0 8. 精製水 剩餘量 9. 甘油 7.0 10. 丙烯酸/甲基丙烯酸院基酯共聚物S4) 0.2 11. 氫氧化鈉 0.09 12. 防腐劑 適量 13. 香料 適量 (製法） (1) 將成分1〜7以8(TC混合均勻。 (2) 將成分8〜13以80°C混合均勻。 (3) 於（1)中添加（2)，進行乳化。 (4) 將（3)於攪拌之下冷卻，製得乳霜。 所得之乳霜，係乳化安定性優異、潤滑之使用感、化 妝持續效果優異之乳霜。 -28- 201143808 實施例13 美容液： 以下述方法製造以下所示組成之美容液。 (成分） (%) 1. 丙稀酸/甲基丙烯酸院基酯共聚物s4) 0.2 2. U-丁二醇 7.0 3. 氯氧化納 Q Qg .4.甘油 10.0 5. 憐脂質處埋扁平纖維素粉體(製品3) 0.5 6. 精製ZK 剩餘量 7. 乙醇 6.0 8. 美容成分 適量 9. 防腐劑 適量 10. 香料 適量 (製法） (1)將成分1〜10於常溫下混合溶解，於攪拌之下製得 美容液。 所得之美容液，係安定性優異、潤滑之使用感、化妝 持續效果優異之美容液。 實施例14 面膜（可撕式）： 以下述方法製造以下所示組成之面膜。 -29- 201143808 (成分） (%) 1. 三2-乙基己酸甘油酯 0.2 2. 液體石蠟 7.0 3. 聚氧乙烯(20莫耳)聚氧丙烯(4莫耳)十六醚 1.0 4. 磷脂質處理扁平纖維素粉體(製品5) 1.0 5. 1，3-丁二醇 0.1 6. 甘油 10.0 7. 羥基乙基纖維素 0.5 8. 丙烯酸/甲基丙烯酸院基酯共聚物ϋ4) 0.05 9. 精製水 剩餘量 10. 乙醇 6.0 11. 防腐劑 適量 12. 香料 適量 (製法） (1) 將成分1〜4以8 0 °c混合均勻。 (2) 將成分5〜12以80 °C混合均勻。 (3) 於（1)中添加（2)，進行乳化。 (4) 將（3)於攪拌之下冷卻，製得面膜》 所得之面膜，係乳化安定性優異、潤滑之使用感、化 妝持續效果優異之面膜。 實施例1 5 洗面乳： 以下述方法製造以下所示組成之洗面乳。 -30- 201143808 诚分） (%) 1. 肉宣蔻酸 5.0 2. 十六酸 20.0 3. 硬脂酸 5.0 4. 聚乙二醇6000 3.0 5. 甘油 15.0 6. 1，3-丁二醇 5.0 7. 二硬脂酸乙二醇醋 1.5 8. 氫氧化鈉 6.0 9. 精製水 剩餘量 10. 防腐劑 適量 11. 香料 適量 12. 磷脂質處理扁平纖維素粉體(製品6) 1.0 (製法） (1) 將成分1〜7以80°c混合均勻。 (2) 將成分8〜1 1以80°C混合均勻。 (3 )於（1 )中添加（2)，進行中和。 (4) 於（3)中添加成分I2，混合均勻。 (5) 將（4)於攪拌之下冷卻，製得洗面乳。 所得之洗面乳，係潤滑之使用感優異之洗面乳。 實施例1 6 卸妝乳： 以下述方法製造以下所示組成之卸妝乳。 -31 - 201143808 (成分） (%) 1. 硬脂酸 3.0 2. 鯨鱲醇 2.0 3. 四油酸聚氧丙烯(40莫耳)山梨糖醇 1.0 4. 單硬脂酸聚氧乙烯(20莫耳)山梨醇酐 1.0 5. 三2-乙基己酸甘油酯 20.0 6. 液體石蠘 20.0 7. 十甲基環戊矽氧院 5.0 8. 磷脂質處理扁平纖維素粉體(製品1) 0.5 9. 丙烯酸/甲基丙烯酸烷基酯共聚物a4) 0.1 10. 1，3-丁二醇 7.0 11. 氫氧化鈉 0.05 12. 精製水 剩餘量 13. 防腐劑 適量 14. 香料 適量 (製法） (1) 將成分1〜8以80°C混合均勻。 (2) 將成分9〜14以80°C混合均勻。 (3) 於（1)中添加（2)，進行乳化。 (4) 將（3)於攪拌之下冷卻，製得卸妝乳。 所得之卸妝乳，係乳化安定性優異、潤滑之使用感優 異之卸妝乳。 實施例1 7 髮蠟： 以下述方法製造以下所示組成之髮蠟。 -32- 201143808 诚分） (%) 1.精製水 剩餘量 2.丙二醇 10.0 3.單硬脂酸聚乙二醇酯a5) 3.0 4.凡士林 10.0 5.石蠟 3.0 6.棕櫚醇 3.0 7.二十二醇 3.0 8.二甲基聚矽氧院&3) 2.0 9.乙醇 5.0 10.精製水 15.0 11.乙燃啦略院酮 1.0 12.磷脂質處理扁平纖維素粉體(製品4) 0.5 13.丙烯酸/甲基丙烯酸烷基酯共聚物a4) 0.15 14.氫氧化鈉 0.05 15.防腐劑 適量 16.香料 適量 注5)尼寇魯MYS-40V(曰本Surfactant工業公司製） (製法） (1) 將成分1〜3以80°C混合均勻。 (2) 將成分4〜8以80°C混合均勻。 (3) 於（1)中添加（2)，進行乳化。 (4) 於（3)中添加成分9〜16後，於攪拌之下冷卻，製 得髮蠟。 所得之髮蠘’係整髮性優異、潤滑之使用感優異之髮 蠘。 -33- 201143808 實施例1 8 油性眼線筆： 以下述方法製造以下所示組成之油性眼線筆。 诚分） (%) 1·地蠟 11.0 2. 聚異丁烯 16Ό 3. 聚乙烯蠟 &0 4. 輕質液體異烷烴 剩餘量 5. 聚矽氧處理黑氧化鐵15.0 6. 聚矽氧處理滑石注7) 5.0 7. 磷脂質處理扁平纖維素粉體(製品2) 0.5 8. 防腐劑 適量 9. 香料 適量 注6)SA-黑BL-10〇(l〇〇%)(三好化成公司製） 注7)SA-滑石JA-13R(三好化成公司製） (製法） (1) 將成分1〜4加溫至100°C，混合均勻。 (2) 將成分5〜9加溫至8(TC，混合均勻。 (3) 於（1)中添加（2)，混合均勻。 (4) 將（3)以輥進行處理，製得油性眼線筆。 所得之油性眼線筆，係潤滑之使用感、化妝持續效果 優異之油性眼線筆。 實施例1 9 -34- 201143808 水性眼線筆： 以下述方法製造以下所示組成之水性眼線筆。 1. 诚分） 1,3-丁二醇 (%) 15.0 2. 聚氧烷基醚磷酸酯注 0.2 3. 聚氧乙烯十六酸注9) 0.2 4. 黑氧化鐵 15.0 5. 矽酸酐 3.0 6. 磷脂質處理扁平纖維素粉體(製品1) 3.0 7. 丙烯酸烷基酯共聚物乳膠注叫 15.0 8. 精製水 剩餘量 9. 防腐劑 適量 10. 香料 適量 注8)尼寇魯DDP-6(日本Surfactant工業公司製） 注9)尼寇魯BC-20TX(日本Surfactant工業公司製） 注10)優德索魯32A707(45%固形分）（日本NSC公司製） (製法） (1) 將成分1〜6以輥分散均勻。 (2) 將成分6〜10混合均勻。 (3) 於（2)中添加（1)，混合均勻，製得水性眼線筆。 所得之水性眼線筆，係潤滑之使用感、化妝持續效果 優異之水性眼線筆。 實施例20 眉筆： -35- 201143808 以下述方法製造以下所示組成之眉筆° (成分） (%) 1. 丙烯酸院基酯共聚物乳膠S 1(0 30.0 2. L-精胺酸 1.0 3. 精製水 剩餘量 4. 乙醇 15.0 5. 單硬脂酸聚氧乙烯(2〇莫耳)山梨醇酐 0.5 6. 1,3-丁二醇 2.0 7. 磷脂質處理扁平纖維素粉體(製品3) 0.5 8. 黑氧化鐵 0.05 9. 黃氧化鐵 0.05 10. 氧化鐵紅 0.25 11. 防腐劑 適量 12. 香料 適量 (製法） (1) 將成分1〜4混合均勻· (2) 將成分5〜1〇以輥進行處理。 (3) 於（1)中添加（2)、成分1 1、12後，混合均勻’製得 眉筆。 所得之眉筆，係潤滑之使用感、化妝持續效果優異之 眉筆。 實施例2 1 0/W型睫毛資： 以下述方法製造以下所示組成之〇/w型睫毛膏。 -36- 201143808 诚分） (%) 1. 硬脂酸 2.0 2. 蜜蠘 10.0 3. 棕櫚醇 1.0 4. 單硬脂酸聚氧乙烯(20莫耳)山梨醇酐 1.5 5. 倍半油酸山梨醇酐 0.5 6. 黑氧化鐵 5.0 7. 磷脂質處理扁平纖維素粉體(製品υ 1.0 8. 矽酸酐 3.0 9. 精製水 剩餘量 10. 1,3-丁二醇 10.0 11. 三乙醇胺 1.5 12. 丙烯酸烷基酯共聚物乳膠al()) 30.0 13. 防腐劑 適量 14. 香料 適量 (製法） (1) 將成分1〜8以80 °C混合均勻，以輥進行處理。 (2) 將成分9〜14以80 °C混合均勻。 (3) 於（1)中添加（2)，進行乳化。 (4) 將（3)冷卻，製得睫毛膏（〇/W)。 所得之0/W型睫毛膏，係粉體分散性優異 '潤滑之 使用感、化妝持續效果優異之O/W型睫毛膏。 實施例2 2 非水系睫毛膏： 以下述方法製造以下所示組成之非水系睫毛膏 -37- 201143808 诚分） (%) 1. 樹脂酸新戊四醇酯 10.0 2. 小燭樹樹脂 3.0 3. 蜜蠟 2.0 4. 地蠟 2.0 5. 棕櫚酸糊精酯 2.0 6. 三甲基矽氧基矽酸酯 3.0 7. 二甲基二硬脂醯基鋁鋰膨潤石*" u) 5.0 8. 碳酸丙烯酯 1.0 9. 輕質液體石蠟 剩餘量 10. 黑氧化鐵 5.0 11. 磷脂質處理扁平纖維素粉體(製品2) 3.0 12. 氧化矽 3.0 13. 滑石 2.0 注 ll)BENTONE38VBC(Elementis 公司製） (製法） (1) 將成分1〜5加溫至ll〇°C。 (2) 於（1)中添加混合成分6〜9。 (3) 於（2)中添加混合成分1〇〜13。 (4) 將（3)以輥進行處理，製得非水系睫毛膏^ 所得之非水系睫毛脊，係潤滑之使用感、化妝持續效 果優異之非水系睫毛眘。 實施例2 3 條狀口紅： 以下述方法製造以下所示組成之條狀口紅。 -38 - 201143808 (成分） (%) 1. 聚乙烯蠟 7.0 2. 微晶蠟 3.0 3. 地蠟 2.0 4. 三2-乙基己酸甘油酯 20.0 5. 四2-乙基己酸新戊四醇酯 10.0 6. 二甲基聚矽氧院;"12) 3.0 7. 2-乙基己酸十六酯 剩餘量 8. 紅色202號 0.5 9. 黃色4號 2.0 10. 氧化鈦 0.5 11. 黑氧化鐵 0.1 12. 磷脂質處理扁平纖維素粉體(製品3) 0.5 13. 防腐劑 適量 14. 香料 適量 注12)KF-96(10CS)(信越化學工業公司製） (製法） (1) 將成分1〜7以100°C溶解混合至均勻。 (2) 於（1)中添加成分8〜14，混合均勻。 (3) 將（2)流入容器中，冷卻而製得條狀口紅。 所得之條狀口紅，係潤滑之使用感、化妝持續效果優 異之條狀口紅。 實施例24 唇蜜： 以下述方法製造以下所示組成之唇蜜。 -39- 201143808 (成分） (%) 1. 聚乙烯蠟 2.0 2. 微晶蠟 1.0 3. 三2-乙基己酸甘油酯 剩餘量 4. 蘋果酸異硬脂酯 2〇.〇 5. 液體石蠟 2〇-〇 6. 矽酸酐 2.0 7. 磷脂質處理扁平纖維素粉體(製品句 1.0 8. 氧化鐵紅 0.1 9. 紅色201號 0.3 10. 氧化飲 0.2 11. 黑氧化鐵 0.05 12. 防腐劑 適量 13. 香料 適纛 (製法） (1) 將成分1〜5以100°C溶解混合至均勻。 (2) 於（1)中添加成分6〜13，混合均勻。 (3) 將（2)流入容器中，冷卻而製得唇蜜。 所得之唇蜜，係潤滑之使用感、化妝持續效果優胃& 唇蜜。 實施例2 5 0/W型粉底： 以下述方法製造以下所示組成之〇/W型粉底。 -40 - 201143808 诚分） (%) 1. 單硬脂酸聚氧乙烯(20莫耳)山梨醇酐 0.5 2. 倍半油酸山梨醇酐 0.5 3. 1,3-丁二醇 10.0 4. 聚矽氧處理氧化鈦sl3) 10.0 5. 聚矽氧處理氧化鐵紅iil4) 0.4 6. 聚矽氧處理黃氧化鐵al5) 2.0 7. 聚矽氧處理黑氧化鐵tt6) 0.1 8. 磷脂質處理扁平纖維素粉體(製品5) 5.0 9. 羧基乙烯聚合物 0.3 10. 三乙醇胺 1.0 11. 精製水 剩餘量 12. 乙醇 2.0 13. 硬脂酸 1.0 14. 二十二醇 0.5 15. 液體石蠟 2.0 16. 三2-乙基己酸甘油酯 2.0 17. 對甲氧基桂皮酸2-乙基己酯 2.0 18. 凡士林 0.5 19. 防腐劑 適量 20. 香料 適量 注13)SA-鈦CR-50(三好化成公司製） 注14)SA-氧化鐵紅七寶（三好化成公司製） 注15)SA-黃檸檬（三好化成公司製） (製法） (1) 將成分1〜8以輥分散至均勻。 (2) 將成分9〜12混合均勻。 (3) 於（2)中添加（1)，混合均勻。 -41 - 201143808 (4)將成分13〜19以80°C混合溶解。 (5 )於（3 )中以8 0 °C添加（4) ’使其乳化。 (6)將（5)冷卻，添加成分20 ’製得0/W型粉底。 所得之0/W型粉底，係粉體分散性優異、潤滑之使 用感、化妝持續效果優異之0/W型粉底。 實施例26 W/0型粉底： 以下述方法製造以下所示組成之W/0型粉底^ 1. (成分） 聚氧乙烯甲基矽氧烷•聚氧丙烯油基甲基矽氧烷·：； 基矽氧烷共聚物**16) (%) 二甲 2.0 2. PEG-3聚二甲基矽氧 1.0 3. 二甲基聚矽氧院*^211 20.0 4. 聚矽氧處理黃氧化鐵al4) 1.0 5. 聚矽氧處理黑氧化鐵al5) 1.5 6. 聚砂氧處理氧化鈦S6) 0.5 7. 聚矽氧處理氧化鐵紅sl3) 10.0 8. 聚矽氧處理滑石a7) 2.0 9. 磷脂質處理扁平纖維素粉體(製品6) 5.0 10. 三2-乙基己酸甘油酯 10.0 11. 倍半油酸山梨醇酐 0.5 12. 精製水 剩餘量 13. 1,3-丁二醇 15.0 14. 防腐劑 適量 15. 香料 適量 注16)KF-6026(信越化學工業公司製） 注17)KF-6015(信越化學工業公司製） -42- 201143808 (製法） (1) 將成分1〜3混合均勻》 (2) 將成分4〜11以輥分散至均勻。 (3) 於（1)中添加（2)，混合均勻。 (4) 於（3)中添加成分12〜is，使其乳化，製得w/0型 粉底。 所得之W/0型粉底，係粉體分散性優異、潤滑之使 用感、化妝持續效果優異之W/0型粉底。 實施例2 7 0/W眼影： 以下述方法製造以下所示組成之0/W型眼影。 (成分） (%) 1. 丙烯酸/甲基丙烯酸院基酯共聚物a4) 0.3 2. 1，3-丁二醇 10.0 3. 乙醇 5.0 4. 三乙醇胺 0.5 5. 精製水 剩餘量 6. 液體石蠟 2.0 7. 二甲基聚砂氧院4"12) 2.0 8. 倍半油酸山梨醇酐 0.1 9. 單硬脂酸聚氧乙烯(2〇莫耳)山梨醇酐 0.1 10. 藍色404號 0.5 11. 黃氧化鐵 0.2 12. 聚矽氧處理雲母欽S18) 15.0 13. 磷脂質處理扁平纖維素粉體(製品5) 5.0 14. 防腐劑 適量 15. 香料 適量 注18)SA -福拉面哥寇魯德（三好化成公司製） -43- 201143808 (製法） (1) 將成分1〜5以80°C混合均勻。 (2) 於（1)中添加成分6、7，進行乳化。 (3) 將成分8〜14以輥分散至均勻。 (4) 於（2)中添加（3)、成分15，製得O/W型眼影。 所得之Ο/W型眼影，係粉體分散性優異、潤滑之使 用感、化妝持續效果優異之型眼影。 實施例2 8 油性固型粉底： 以下述方法製造以下所示組成之油性固型粉底。 1. (成分） 滑石 (%) 15.0 2. 磷脂質處理扁平纖維素粉體(製品4) 10.0 3. 聚矽氧處理氧化鈦al3) 15.0 4. 聚矽氧處理氧化鐵紅ttl4> 1.0 5. 聚矽氧處理黃氧化鐵al5) 3.0 6. 聚矽氧處理黑氧化鐵注6) 0.2 7. 聚乙烯蠟 7.0 8. 微晶蠟 6.0 9. 三2-乙基己酸甘油酯 剩餘量 10. 二甲基聚矽氧烷&12) 10.0 11. 液體石蠟 20.0 12. 聚氧乙烯甲基砂氧院•聚氧丙烯油基 甲基矽氧烷•二甲基矽氧烷共聚物*^19) 2.0 13. 防腐劑 適量 14. 香料 適量 注19)KF-6026(信越化學工業公司製） -44 - 201143808 (製法） (1) 將成分7〜13以90 °C加熱溶解。 (2) 於（1)中添加成分1〜6，以輥分散至均勻。 (3) 於（2)中添加成分14，以8〇°C溶解後，充塡至金皿 中，製得油性固型粉底。 所得之油性固型粉底，係粉體分散性優異、潤滑之使 用感、化妝持續效果優異之油性固型粉底。 實施例29 條狀遮瑕霜： 以下述方法製造以下所示組成之條狀遮瑕霜。 (%) 8.0 2.0 5.0 5.0 剩餘量 5.0 5.0 0.5 1.5 0.5 5.0 適量 適量 (成分） 1. 地蠟 2. 聚乙烯蠟 3. 二甲基聚矽氧院a 12) 4· 2·乙基己酸甘油酯 5. 二辛酸新戊二醇 6. 聚矽氧處理氧化欽注13) 7. 磷脂質處理扁平纖維素粉體(製品3) 8. 紅氧化鐵 9. 黃氧化鐵 10. 黑氧化鐵 11. 月桂酸鋅 12. 防腐劑 13. 香料 -45 - 201143808 (製法） (1) 將成分1〜5以90°c加熱溶解。 (2) 於（1)中添加成分6〜12，以輥分散至均勻》 (3) 於（2)中添加成分13，以80°C溶解後，充塡至容器 中，製得條狀遮瑕霜。 所得之條狀遮瑕霜，係粉體分散性優異、潤滑之使用 感、化妝持續效果優異之條狀遮瑕霜。 實施例3 〇 身體乳液： 以下述方法製造以下所示組成之身體乳液。 (成分） (%) 1. 硬脂酸 1.0 2. 單硬脂酸聚氧乙烯(20莫耳)山梨醇酐 0.5 3. 倍半油酸山梨醇酐 0.5 4. 二十二醇 0.5 5. 2-乙基己酸甘油酯 5.0 6. 液體石蠟 2.0 7. 二甲基聚砂氧烷*"12) 2.0 8. 乙醇 10.0 9. 二丙二醇 10.0 10. 三乙醇胺 1.0 11. 精製水 剩餘量 12. 甘油 5.0 13. 1，3-丁二醇 5.0 14. 丙烯酸/甲基丙烯酸烷基酯共聚物S4) 0.2 15. 防腐劑 適量 16. 香料 適量 17. 磷脂質處理扁平纖維素粉體(製品2) 2.0 -46 201143808 (製法） (1) 將成分1〜7以80°C混合均勻。 (2) 將成分8〜16以80°C混合均勻。 (3) 於（1)中添加（2)，進行乳化。 (4) 於（3)中添加成分17，混合均勻後，攪拌冷卻，製 得身體乳液。 所得之身體乳液，係乳化安定性優異、潤滑之使用感 、化妝持續效果優異之身體乳液。 實施例3 1 護髮乳： 以下述方法製造以下所示組成之護髮乳。 (成分） (%) 1. 二十二醇 2.0 2. 棕櫚醇 1.0 3. 三2-乙基己酸甘油酯 3.0 4. 氯化烷基三甲銨注20) 1.0 5. 丙二醇 4.0 6. 精製水 剩餘量 7. 羥基乙基纖維素 0.1 8. 防腐劑 適量 9. 香料 適量 10. 磷脂質處理扁平纖維素粉體(製品1) 2.0 注20)阿卡特22-80(LionAkzo公司製） (製法） -47- 201143808 (1) 將成分1〜5以80°C混合均勻。 (2) 將成分6〜9以8(TC混合均勻。 (3) 於（1)中添加（2)，進行乳化。 (4) 於（3)中添加成分1〇，混合均勻後，攪拌冷卻，製 得護髮乳。 所得之護髮乳，係乳化安定性優異、潤滑之使用感優 異之護髮乳。 實施例32 髮膜= 以下述方法製造以下所示組成之髮膜。 (成分） （％) 1. 二十二醇 2.0 2. 棕櫚醇 6.0 3. 液體石蠟 3.0 4. 氯化院基三甲錢注2°) 1.5 5. 丙二醇 4.0 6. 高聚合甲基聚矽氧院ii21) 1.0 7. 精製水 剩餘量 8. 防腐劑 適量 9. 香料 適量 10. 磷脂質處理扁平纖維素粉體(製品1) 3.0 注 21)BY22-050A(Toray · Dowcorning 公司製） (製法） (1)將成分1〜6以80°c混合均勻。 -48- 201143808 (2) 將成分7〜9以80°C混合均勻。 (3) 於（1)中添加（2)，進行乳化》 (4) 於（3)中添加成分10，混合均勻後，攪拌冷卻’製 得髮膜。 所得之髮膜，係乳化安定性優異、潤滑之使用感優異 之髮膜。 實施例3 3 W/O型防曬霜： 以下述方法製造以下所示組成之防曬霜。 (成分） (%) 1. 氧化鋅 15.0 2. 聚矽氧處理微粒子氧化鈦 5.0 3. 磷脂質處理扁平纖維素粉體(製品2) 2.0 4. 倍半異硬脂酸山梨醇酐 1.0 5. 三2-乙基己酸甘油酯 10.0 6. 掠橋酸2-乙基己酯 5.0 7. 十甲基環戊矽氧院 10.0 8. 對甲氧基桂皮酸2-乙基己酯 10.0 9. 甲基聚矽氧烷•十六基甲基聚矽氧院•聚 (氧乙烯•氧丙烯)甲基聚矽氧烷共聚物a22) 2.0 10. 精製水 剩餘量 11. 氯化鈉 0.2 12. 乙醇 5.0 13. 防腐劑 適量 14. 香料 適量 注 22)ABIL EM90(EVONIC GOLDSCHMIDT GMBH 公司製） -49- 201143808 (製法） (1) 將成分1〜5以輥分散至均勻。 (2) 於（1)中添加成分6〜9，混合均勻》 (3) 於（2)中添加成分10〜14，進行乳化，製得W/0型 防曬霜。 所得之W/0型防曬霜，係粉體分散性優異、潤滑之 使用感、化妝持續效果優異之防曬霜。 實施例34 指甲油： 以下述方法製造以下所示組成之指甲油。 (成分） (%) 1. 硝基纖維素 20.0 2. 乙酸丁酯 剩餘量 3. 乙酸乙酯 20.0 4. 甲苯 30.0 5. 有機性搬土 0.5 6. 紅色226號 1.0 7. 藍色404號 0.5 8. 氧化鈦 1.0 9. 磷脂質處理扁平纖維素粉體(製品3) 1.0 (製法） (1)將成分1〜9混合均勻，製得指甲油。 所得之指甲油’係粉體分散性優異、潤滑之使用感、 化妝持續效果優異之指甲油 -50- 201143808 實施例3 5 隔離霜： 以下述方法製造以下所示組成之隔離霜。 (成分） (%) 1. 棕櫚醇 2.0 2. 對甲氧基桂皮酸2-乙基己酯 5.0 3. 二甲基聚矽氧烷~2) 5.0 4. 三2-乙基己酸甘油酯 5.0 5. 精製水 剩餘量 6. N-硬脂醯基-N-甲基牛磺酸鈉 0.5 7. 羧基乙烯聚合物**23) 0.1 8. 丙烯酸/甲基丙烯酸院基酯共聚物a4) 0.1 9. 氫氧化鈉 0.05 10. 乙醇 10.0 11. 1，3-丁二醇 10.0 12. 防腐劑 適量 13. 磷脂質處理扁平纖維素粉體(製品4) 2.0 14. 香料 適量 注 23)CARBOP〇L940(LUBRIZOL ADVANCED MATERIALS 公司製) (製法） (1) 將成分1〜4以80 °C均勻地溶解。 (2) 將成分5〜12以80 °C均勻地溶解。 (3) 於（2)中添加（1)，進行乳化。 (4) 於（3)中添加成分13〜14，混合、冷卻，製得隔離霜。 所得之隔離霜，係乳化安定性優異、潤滑之使用感、 -51 - 201143808 化妝持續效果優異之隔離霜* 實施例36 白粉： 以下述方法製造以下所示組成之白粉。 (成分） (%) 1. 雲母 1〇·〇 2. 磷脂質處理扁平纖維素粉體(製品8) 10.0 3. 滑石 剩餘量 4. 雲母鈦 1〇-〇 5. 紅色226號 〇·5 6. 液體石蠟 〇·5 7. 三2-乙基己酸甘油酯 1.0 8. 防腐劑 適量 9. 香料 ΜΛ 10. 乙醇 1.0 (製法） (1) 將成分1〜5、成分8〜10混合均勻。 (2) 於（1)中添加成分6、7，混合均勻。 (3) 將（2)以粉碎機粉碎，製得白粉。 所得之白粉，係粉體分散性優異、潤滑之使用感、化 妝持續效果優異之白粉。 實施例3 7 固形粉末型粉底： -52- 201143808 以下述方法製造以下所示組成之固形粉末型粉底。 诚分） （%) 1. 聚矽氧處理氧化鈦al3) 15.0 2. 滑石 剩餘量 3. 聚矽氧處理氧化鐵紅aM) i.o 4. 聚矽氧處理黃氧化鐵al5) 3.0 5. 聚矽氧處理黑氧化鐵S6) 0.5 6. 磷脂質處理扁平纖維素粉體(製品9) 20.0 7. 耐綸末 2.0 8. 三2-乙基己酸甘油酯 9. 液體石蠟 3.0 10. 對甲氧基桂皮酸2-乙基己酯 3.0 11. 防腐劑 適量 12. 香料 適量 13. 乙醇 1.0 (製法） (1) 將成分1〜7、成分Η〜13混合均勻。 (2) 於（1)中添加成分8〜10’混合均勻。 (3) 將（2)以粉碎機粉碎。 (4) 將（3)充塡至金皿中’製得固形粉末型粉底。 所得之固形粉末型粉底，係粉體分散性優異、潤滑之 使用感、化妝持續效果優異之粉底。 實施例38 固形粉末型腮紅： 以下述方法製造以下所示組成之固形粉末型腮紅。 -53- 201143808 (成分） (%) L 雲母 30.0 2. 滑石 剩餘量 3 鱗脂質處理扁平纖維素粉體(製品3) lo o 4. 紅色226號 0.5 5. 液體石蠟 4.0 6. 三2-乙基己酸甘油酯 4.0 7. 防腐劑 適量 8. 香料 適量 9. 乙醇 1.0 (製法） (1) 將成分1〜4、成分7〜9混合均勻》 (2) 於（1)中添加成分5、6，混合均勻。 (3) 將（2)以粉碎機粉碎。 (4) 將（3)充塡至金皿中，製得固形粉末型腮紅。 所得之固形粉末型腮紅，係粉體分散性優異、潤滑之 使用感、化妝持續效果優異之腮紅。 實施例3 9 固形粉末型眼影： &下述方法製造以下所示組成之固形粉末型眼影。 -54- 201143808 (成分） (%) 1. 雲母鈦 20.0 2. 磷脂質處理扁平纖維素粉體(製品2) 10.0 3. 滑石 剩餘量 4. 群青 ， 2.0 5. 黃色401號 0.5 6. 耐綸末 2.0 7. 三2-乙基己酸甘油酯 4.0 8. 液體石蠟 4.0 9. 凡士林 1.0 10. 防腐劑 適量 11. 香料適量 12. 乙醇 1.0 (製法） (1) 將成分1〜6、成分10〜12混合均勻。 (2) 於（1)中添加成分7〜9，混合均勻。 (3) 將（2)以粉碎機粉碎。 (4) 將（3)充塡至金皿中，製得固形粉末型眼影。 所得之固形粉末型眼影，係粉體分散性優異、潤滑之 使用感、化妝持續效果優異之眼影。 實施例40 腦醯胺處理扁平纖維素粉體之製造（1): 使用精製後之木材紙漿由來之纖維素粉末（W_400G/曰 本製紙化藥公司）作爲原料。首先，將藉由以40°C之減壓 -55- 201143808 乾燥將吸著水分充分除去至0.1%以下之纖維素粉末（48g) ，與氧化鋁製之粉碎球（直徑20mm)，一倂投入於可密閉之 氧化鋁製粉碎容器（容積500ml)，並添加腦醯胺2(TIC-001/ 高砂香料公司製）使其相對於纖維素粉末爲2%。 之後，使用行星式球磨機（P-5型/德國Frits ch公司製 )’以轉速200rpm(約10G(重力加速度）之粉碎能量），連續 進行粉碎40分鐘，製得腦醯胺處理扁平纖維素粉體（製品 10) ° 與實施例1同樣地測定該腦醯胺處理扁平纖維素粉體 之平均粒徑、平均厚度及扁平度的結果，平均粒徑、平均 厚度及扁平度分別爲平均粒徑18μιη、平均厚度0.6μιη及 扁平度30。 實施例41 腦醯胺處理扁平纖維素粉體之製造（2): 使用精製後之木材紙漿由來之纖維素粉末（W-400G/日 本製紙化藥公司）作爲原料。首先，將藉由以40°C之減壓 乾燥將吸著水分充分除去至0.1 %以下之纖維素粉末（48 g) ，與氧化鋁製之粉碎球（直徑20mm)，一倂投入於可密閉 之氧化鋁製粉碎容器（容積500ml)，並添加腦醯胺6(腦醯 胺Vl/Cosmo farm公司製）使其相對於纖維素粉末爲2%。 之後，使用行星式球磨機（P-5型/德國Fritsch公司製） ，以轉速20〇rpm(約10G(重力加速度）之粉碎能量），連續 進行粉碎50分鐘，製得腦醯胺處理扁平纖維素粉體。 -56- 201143808 與實施例1同樣地測定該腦醯胺處理扁平纖維素粉體 之平均粒徑、平均厚度及扁平度的結果，平均粒徑、平均 厚度及扁平度分別爲平均粒徑20μιη、平均厚度1.5μιη及 扁平度13.3。 實施例42 腦醯胺處理扁平纖維素粉體之製造（3): 使用精製後之木材紙漿由來之纖維素粉末（W-4〇OG/日 本製紙化藥公司）作爲原料。首先，將藉由以40°C之減壓 乾燥將吸著水分充分除去至0.1%以下之纖維素粉末（48g) ，與氧化鋁製之粉碎球（直徑20mm)，一併投入於可密閉 之氧化鋁製粉碎容器（容積500ml)，並添加腦醯胺1(腦醯 胺I/Evonik Goldschmidt GmbH公司製）使其相對於纖維素 粉末爲1%、及辛基三乙氧矽烷（辛基三乙氧矽烷/東京化成 工業公司製）使其相對於纖維素粉末爲1%。 之後，使用行星式球磨機（P-5型/德國Fritsch公司製 )，以轉速20〇rpm(約10G (重力加速度）之粉碎能量），連續 進行粉碎20分鐘，製得腦醯胺處理扁平纖維素粉體。 與實施例1同樣地測定該腦醯胺處理扁平纖維素粉體 之平均粒徑、平均厚度及扁平度的結果，平均粒徑、平均 厚度及扁平度分別爲平均粒徑30μιη、平均厚度1.5μιη及 扁平度20.0。 實施例43 57- 201143808 腦醯胺處理扁平纖維素粉體之製造（4): 使用精製後之木材紙漿由來之纖維素粉末（W-400G/日 本製紙化藥公司）作爲原料。首先，將藉由以40°C之減壓 乾燥將吸著水分充分除去至0.1%以下之纖維素粉末（48g) ，與氧化鋁製之粉碎球（直徑20mm)，一倂投入於可密閉 之氧化鋁製粉碎容器（容積500ml)，並添加腦醯胺3(腦醯 胺III/Evonik Goldschmidt GmbH公司製）使其相對於纖維 素粉末爲1%、及單末端羧基變性聚矽氧（X-22-371 0/信越 化學公司製）使其相對於纖維素粉末爲1 %。 之後，使用行星式球磨機（P-5型/德國Fritsch公司製 )，以轉速200rpm(約10G(重力加速度）之粉碎能量），連續 進行粉碎30分鐘，製得腦醯胺處理扁平纖維素粉體。 與實施例1同樣地測定該腦醯胺處理扁平纖維素粉體 之平均粒徑、平均厚度及扁平度的結果，平均粒徑、平均 厚度及扁平度分別爲平均粒徑25μιη、平均厚度1·6μηι及 扁平度1 5.6。 實施例44 膽固醇處理扁平纖維素粉體之製造（1): 使用精製後之木材紙漿由來之纖維素粉末（W-400G/曰 本製紙化藥公司）作爲原料。首先，將藉由以40°C之減壓 乾燥將吸著水分充分除去至0.1 %以下之纖維素粉末（48 g) ，與氧化鋁製之粉碎球（直徑20mm)，一倂投入於可密閉 之氧化鋁製粉碎容器（容積500ml)，並添加膽固醇（膽固醇 -58- 201143808 /曰本精化公司製）使其相對於纖維素粉末爲2%。 之後，使用行星式球磨機（P-5型/德國Fritsch公司製 )’以轉速200rpm(約10G(重力加速度）之粉碎能量），連續 進行粉碎40分鐘，製得膽固醇處理扁平纖維素粉體（製品 11)° 與實施例1同樣地測定該膽固醇處理扁平纖維素粉體 之平均粒徑、平均厚度及扁平度的結果，平均粒徑、平均 厚度及扁平度分別爲平均粒徑22 μπι、平均厚度0.8 μιη及 扁平度27.5。 實施例45 膽固醇處理扁平纖維素粉體之製造（2): 使用精製後之木材紙漿由來之纖維素粉末（W-40 0G/日 本製紙化藥公司）作爲原料。首先，將藉由以4(TC之減壓 乾燥將吸著水分充分除去至0.1%以下之纖維素粉末（48g) ，與氧化鋁製之粉碎球（直徑20mm)，一倂投入於可密閉 之氧化鋁製粉碎容器（容積500ml)，並添加膽固醇（膽固醇 /日本精化公司製）使其相對於纖維素粉末爲3%、及全氟院 基磷酸酯使其相對於纖維素粉末爲2%。 之後，使用行星式球磨機（P-5型/德國Fritsch公司製） ，以轉速200rpm(約10G(重力加速度）之粉碎能量），連續 進行粉碎60分鐘，製得膽固醇處理扁平纖維素粉體。 與實施例1同樣地測定該膽固醇處理扁平纖維素粉體 之平均粒徑、平均厚度及扁平度的結果，平均粒徑、平均 -59- 201143808 厚度及扁平度分別爲平均粒徑27μηι、平均厚度1.8μπι及 扁平度15.0。 實施例46 植物固醇處理扁平纖維素粉體之製造： 使用精製後之木材紙漿由來之纖維素粉末（W-400 G/ 日本製紙化藥公司）作爲原料。首先，將藉由以40 °C之減 壓乾燥將吸著水分充分除去至〇.1 %以下之纖維素粉末 (48g)，與氧化鋁製之粉碎球（直徑20mm)，一倂投入於可 密閉之氧化鋁製粉碎容器（容積5 00ml)，並添加植物固醇 (植物固醇/Eisai食品化藥）使其相對於纖維素粉末爲2% 〇 之後，使用行星式球磨機（P-5型/德國Fritsch公司製 )，以轉速200rpm(約10G(重力加速度）之粉碎能量），連續 進行粉碎40分鐘，製得植物固醇處理扁平纖維素粉體（製 品 1 2)。 與實施例1同樣地測定該植物固醇處理扁平纖維素粉 體之平均粒徑、平均厚度及扁平度的結果，平均粒徑、平 均厚度及扁平度分別爲平均粒徑24μηι、平均厚度Ι.Ομπι 及扁平度24.0。 參考例4 腦醯胺處理絹雲母之製造： 將絹雲母（艾德巴魯3 00S/角八魚燐箔公司製）98%以腦 -60- 201143808 醯胺2(TIC-001/高砂香料公司製）2%使用硏磨機（岩谷產業 公司製）進行被覆處理’製得腦醯胺處理絹雲母（比較製品 4) 〇 參考例5 腦醯胺處理纖維素粉末（非扁平）之調製： 將木材紙漿由來之纖維素粉末（W-40 0G/日本製紙化藥 公司）作爲原料’投入攪拌機，以使相對於纖維素粉末爲 2%的方式將腦醯胺2(TIC-001/高砂香料公司製）溶解於己 烷後添加。之後，以轉數4 Orpm攪拌5分鐘，減壓乾燥後 ，進行粉碎，製得腦醯胺處理纖維素粉末（非扁平）（比較製 品5)。 實施例47 附著性試驗： 與實施例8同樣地調査實施例40、44及46所得之腦 醯胺處理扁平纖維素粉體、膽固醇處理扁平纖維素粉體、 植物固醇處理扁平纖維素粉體（製品1〇〜12)之對皮膚的附 著性。作爲比較，使用參考例1之硬脂酸處理扁平纖維素 (比較製品1)。將該等之結果示於表6。 -61 - 201143808 [表6] 試樣 粉體於皮膚的殘存量(g) 製品10 59 製品11 54 製品12 49 比較製品1 18 實施例48 固形粉末型粉底： 粉末型粉 地評價其 用感（塗佈 依一般方法，調製下述表7所示組成之固形 底。對所得之固形粉末型粉底，與實施例9同樣 之「化妝膜之均一性」、「化妝持久性」及「使 時之潤滑感）」。將其之結果一倂示於表7。 -62- 201143808 [表7]No. Ingredients Comparative product of the present invention 1 2 3 1 2 3 4 1 Titanium oxide 15 15 15 15 15 15 15 2 Iron oxide red 0.2 0.2 0.2 0.2 0.2 0.2 0.2 3 Yellow iron oxide 1.5 1.5 1.5 1.5 1.5 1.5 1.5 4 Black oxidation Iron 0.2 0.2 0.2 0.2 0.2 0.2 0.2 5 Ultramarine 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 6 talc 20 20 20 20 20 20 20 7 0.1% lecithin treated flat cellulose powder (product 2) 10 - - - - - - 8 3 % lecithin treated flat cellulose powder (Product 1) - 10 - - - - - 9 10% lecithin treated flat cellulose powder (Product 3) - - 10 - - - - 10 3% stearic acid treated flat Cellulose powder (Comparative product 1) - - - 10 - - - 11 1% lecithin-treated sericite (Comparative product 2) - - - - 10 - - 12 Powdered cellulose (W-400G/made by Nippon Paper Chemical Co., Ltd.) ) - - - - - 9.7 - 13 Hydrogenated lecithin (Rexinolu s-io / Solar Chemical Co., Ltd.) - - - - - 0.3 - 14 Lecithin-treated cellulose powder (non-flat) (Comparative product 3 ) - - - - - - 10 15 mica residual amount remaining amount remaining amount remaining amount remaining amount remaining amount remaining amount 16 nylon end 2 2 2 2 2 2 2 17 p-benzoic acid methyl ester 0.2 0.2 0.2 0.2 0.2 0.2 0.2 18 Triethyl 2-ethylhexanoate 4 4 4 4 4 4 4 19 Liquid paraffin 5 5 5 5 5 5 5 20 Perfume 0.1 0.1 0.1 0.1 0.1 0.1 0.1 <Evaluation item and judgment result> Uniformity of cosmetic film 1 ◎ ◎ Δ 〇 XX makeup durability ◎ ◎ Δ 〇X Δ feeling of use (lubrication feeling during coating) ◎ ◎ ◎ Δ XXX -25- 201143808 Example 1 Bilayer double-layered lotion A double-layered lotion having the composition shown below was produced by the following method. Sincerity) (%) 1. Polyoxyethylene alkyl ether phosphate injection D 0. 01 2. Refined water 2. 5 3. Phospholipid treated flat cellulose powder (Product 1) 0. 5 4. Aluminum chloride 1 5. Refined water remaining amount 6. Ethanol 20. 0 7. Isostearic acid polyoxyethylene hardened castor oil**2) 0. 1 8. Preservatives Appropriate amount of the fragrance Note 1) Nirvana DDP-8 (manufactured by Japan Surfactant Industrial Co., Ltd.) Note 2) Emma Rex RWIS-150 (manufactured by Nippon Lacquer Co., Ltd.) (Production method) (1) Mixed components 1 to 3. (2) Add the components 4 to 9 to (1), stir until uniform, and obtain a double-layer makeup water. The obtained double-layered lotion is a double-layered lotion having excellent powder dispersibility, a feeling of lubrication, and a long-lasting makeup effect. Example 11 Emulsion: An emulsion of the composition shown below was produced by the following method. -26- 201143808 诚分) (%) 1. Stearic acid 5 2. Polystearate (20 mol) sorbitan monostearate 1. 0 3. Tetra-oleic acid polyoxypropylene (40 mol) sorbitol 1. 0 4. Twenty diol 5 5. Liquid sarcophagus 5. 0 6. Triethyl 2-ethylhexanoate 5. 0 7. Dimethyl polyoxo hospital ^3) 1. 0 8. Acrylic/alkyl methacrylate copolymer note 4) 0. 1 9. Sanxianjiao 0. 1 10. Sodium hydroxide 05 11. 1,3-butanediol 8. 0 12. Preservatives Appropriate amount 13. The right amount of spices 14. Refined water Remaining amount 15. Phospholipid treated flat cellulose powder (Product 1) 1. 0 Note 3) KF-96 (10CS) (manufactured by Shin-Etsu Chemical Co., Ltd.) Note 4) CARBOPOL 1342 (manufactured by LUBRIZOL ADVANCED MATERIALS Co., Ltd.) (Production Method) (1) The components 1 to 7 are uniformly mixed at 80 °C. (2) The components 8 to 14 were uniformly mixed at 80 °C. (3) Add (2) to (1) and perform emulsification. (4) (3) Cooling under stirring 'Adding component 15 and mixing uniformly to obtain an emulsion. The obtained emulsion is excellent in emulsion stability, a feeling of lubrication, and an emulsion excellent in the sustained effect of the -27-201143808. Example 1 2 Cream = A cream of the composition shown below was produced by the following method. Subtraction) (%) 1. Decaglyceryl oleate 2. 5 2. Twenty diol 5 3. Vaseline 3. 0 4. Heavy liquid hydrocarbons 0 5. Triethyl 2-ethylhexanoate 3. 0 6. Dimethyl polyoxo hospital ^"3) 0 7. Phospholipid treated flat cellulose powder (Product 2) 1. 0 8. Refined water Remaining amount 9. Glycerin 7. 0 10. Acrylic/methacrylic acid ester copolymer S4) 0. 2 11. Sodium hydroxide 09 12. Preservatives Appropriate amount 13. Appropriate amount of the flavor (manufacturing method) (1) Mix the ingredients 1 to 7 at 8 (TC). (2) Mix the ingredients 8 to 13 at 80 ° C. (3) Add (2) to (1) for emulsification. (4) The cream is obtained by cooling (3) under stirring, and the obtained cream is a cream excellent in emulsion stability, a feeling of lubrication, and a makeup lasting effect. -28- 201143808 Example 13 Cosmetic lotion: A cosmetic liquid of the composition shown below is produced by the following method. (ingredient) (%) 1. Acrylic acid/methacrylic acid ester copolymer s4) 0. twenty two. U-butanediol 7. 0 3. Chlorine oxide nano Q Qg . 4. Glycerin 10. 0 5. Poor lipid embedded in flat cellulose powder (Product 3) 0. 5 6. Refined ZK remaining amount 7. Ethanol 6. 0 8. Beauty ingredients Appropriate amount 9. Preservatives A suitable amount of the flavor (manufacturing method) (1) The components 1 to 10 are mixed and dissolved at room temperature, and a cosmetic liquid is obtained under stirring. The obtained cosmetic liquid is a cosmetic liquid which is excellent in stability, a feeling of lubrication, and an excellent cosmetic effect. Example 14 Mask (Tearable): A mask of the composition shown below was produced by the following method. -29- 201143808 (Ingredients) (%) 1. Triethyl 2-ethylhexanoate 0. twenty two. Liquid paraffin 7. 0 3. Polyoxyethylene (20 mol) polyoxypropylene (4 mol) hexadecyl ether 1. 0 4. Phospholipid treated flat cellulose powder (Product 5) 0 5. 1,3-butanediol 0. 1 6. Glycerin 10. 0 7. Hydroxyethyl cellulose 0. 5 8. Acrylic/methacrylic acid ester copolymer ϋ4) 0. 05 9. Refined water Remaining amount 10. Ethanol 6. 0 11. Preservatives Flavor Appropriate amount (Preparation method) (1) Mix ingredients 1 to 4 at 80 ° C evenly. (2) The components 5 to 12 were uniformly mixed at 80 °C. (3) Add (2) to (1) and perform emulsification. (4) The mask obtained by cooling (3) under stirring to obtain a mask, is a mask which is excellent in emulsion stability, a feeling of lubrication, and a sustained effect of makeup. Example 1 5 Facial cleanser: A facial cleanser of the composition shown below was produced by the following method. -30- 201143808 Cheng Cheng) (%) 1. Meat sputum acid 5. 0 2. Hexadecane 20. 0 3. Stearic acid 5. 0 4. Polyethylene glycol 6000 3. 0 5. Glycerin 15. 0 6. 1,3-butanediol 5. 0 7. Di-stearic acid glycol vinegar 5 8. Sodium hydroxide 6. 0 9. Refined water Remaining amount 10. Preservatives The right amount of spices 12. Phospholipid treated flat cellulose powder (Product 6) 1. 0 (Production method) (1) The components 1 to 7 were uniformly mixed at 80 ° C. (2) The components 8 to 1 1 were uniformly mixed at 80 °C. (3) Add (2) to (1) and perform neutralization. (4) Add component I2 to (3) and mix well. (5) The (4) is cooled under stirring to prepare a facial cleanser. The obtained facial cleanser is a facial cleanser excellent in the feeling of lubrication. Example 1 6 Cleansing Milk: The cleansing milk of the composition shown below was produced by the following method. -31 - 201143808 (Ingredients) (%) 1. Stearic acid 3. 0 2. Whale sterol 2. 0 3. Tetra-oleic acid polyoxypropylene (40 mol) sorbitol 1. 0 4. Polystearate (20 mol) sorbitan monostearate 1. 0 5. Triethyl 2-ethylhexanoate 20. 0 6. Liquid sarcophagus 20. 0 7. Decylmethylcyclopentate oxygen hospital 5. 0 8. Phospholipid treated flat cellulose powder (Product 1) 0. 5 9. Acrylic/alkyl methacrylate copolymer a4) 0. 1 10. 1,3-butanediol 7. 0 11. Sodium hydroxide 05 12. Refined water Remaining amount 13. Preservatives Appropriate amount 14. Flavor Appropriate (Preparation method) (1) Mix ingredients 1 to 8 at 80 ° C. (2) The components 9 to 14 were uniformly mixed at 80 °C. (3) Add (2) to (1) and perform emulsification. (4) Cooling (3) under stirring to obtain a cleansing milk. The resulting cleansing lotion is a cleansing lotion with excellent emulsion stability and excellent lubricity. Example 1 7 Wax: A hair wax of the composition shown below was produced by the following method. -32- 201143808 诚分) (%) 1. Refined water Remaining amount 2. Propylene glycol 10. 0 3. Polyethylene glycol monostearate a5) 3. 0 4. Vaseline 10. 0 5. Paraffin 3. 0 6. Palmitol 3. 0 7. Twenty diol 3. 0 8. Dimethyl polyoxane & 3) 2. 0 9. Ethanol 5. 0 10. Refined water 15. 0 11. Ethylene burning 0 12. Phospholipid treated flat cellulose powder (Product 4) 0. 5 13. Acrylic/alkyl methacrylate copolymer a4) 0. 15 14. Sodium hydroxide 05 15. Preservatives Perfume Appropriate amount Note 5) Nissan MYS-40V (manufactured by S本Surfactant Industrial Co., Ltd.) (Production method) (1) The components 1 to 3 are uniformly mixed at 80 °C. (2) The components 4 to 8 were uniformly mixed at 80 °C. (3) Add (2) to (1) and perform emulsification. (4) After adding the components 9 to 16 in (3), the mixture was cooled under stirring to obtain a wax. The resulting hairpin is a hair with excellent hair styling property and excellent feeling of lubrication. -33- 201143808 Example 1 8 Oily Eyeliner: An oily eyeliner of the composition shown below was produced by the following method. Sincerity) (%) 1· Ground wax 11. 0 2. Polyisobutylene 16Ό 3. Polyethylene Wax &0 4. Light liquid isoparaffin remaining amount 5. Polyoxane treatment of black iron oxide 15. 0 6. Polyoxane treatment talc note 7) 5. 0 7. Phospholipid treated flat cellulose powder (Product 2) 0. 5 8. Preservatives Appropriate amount of spices 6) SA-black BL-10 〇 (l〇〇%) (made by Sankyo Chemical Co., Ltd.) Note 7) SA-talc JA-13R (manufactured by Sanhao Chemical Co., Ltd.) (Method) (1) Ingredients 1 to 4 Warm to 100 ° C and mix well. (2) Warm the ingredients 5 to 9 to 8 (TC, mix well. (3) Add (2) to (1) and mix well. (4) Treat (3) with a roller to obtain an oily eyeliner. The oily eyeliner obtained is an oily eyeliner excellent in the sense of use of lubrication and excellent in makeup. Example 1 9 -34- 201143808 Water-based eyeliner: A water-based eyeliner of the composition shown below was produced by the following method. Sincerity) 1,3-butanediol (%) 15. 0 2. Polyoxyalkyl ether phosphate ester injection 0. twenty three. Polyoxyethylene hexadecanic acid note 9) 0. twenty four. Black iron oxide 15. 0 5. Phthalic anhydride 3. 0 6. Phospholipid treated flat cellulose powder (Product 1) 3. 0 7. Acryl acrylate copolymer latex note 15. 0 8. Refined water Remaining amount 9. Preservatives Appropriate amount of spices 8) Nile DDP-6 (made by Japan Surfactant Industries Co., Ltd.) Note 9) Nilelu BC-20TX (made by Japan Surfactant Industries Co., Ltd.) Note 10) Youde Soru 32A707 (45% solids) (Japan (manufactured by NSC Corporation) (Production Method) (1) Distribute the components 1 to 6 uniformly with a roller. (2) Mix the ingredients 6 to 10 uniformly. (3) Add (1) to (2) and mix well to prepare a water-based eyeliner. The resulting water-based eyeliner is a water-based eyeliner with excellent lubrication and makeup lasting effect. Example 20 Eyebrow pencil: -35- 201143808 The eyebrow pencil (component) (%) of the composition shown below was produced by the following method. Acrylate based ester copolymer latex S 1 (0 30. 0 2. L-arginine 1. 0 3. Refined water remaining amount 4. Ethanol 15. 0 5. Monostearic acid polyoxyethylene (2 〇 mol) sorbitol 0. 5 6. 1,3-butanediol 2. 0 7. Phospholipid treated flat cellulose powder (Product 3) 0. 5 8. Black iron oxide 05 9. Yellow iron oxide 05 10. Iron oxide red 0. 25 11. Preservatives Flavor Appropriate amount (Preparation method) (1) Mix the ingredients 1 to 4 uniformly. (2) Treat the ingredients 5 to 1 by roller. (3) Add (2), (1), and 1 and 12 in (1), and mix uniformly to make an eyebrow pencil. The eyebrow pencil obtained is an eyebrow pencil that has a good sense of lubrication and a long-lasting makeup effect. Example 2 1 0/W type eyelashes: A 〇/w type mascara of the composition shown below was produced by the following method. -36- 201143808 诚分) (%) 1. Stearic acid 2. 0 2. Candied fruit 10. 0 3. Palmitol 0 4. Polystearate (20 mol) sorbitan monostearate 1. 5 5. Sesame oleic acid sorbitol 0. 5 6. Black iron oxide 5. 0 7. Phospholipid treated flat cellulose powder (product υ 1. 0 8. Phthalic anhydride 3. 0 9. Refined water Remaining amount 10. 1,3-butanediol 10. 0 11. Triethanolamine 5 12. Acryl acrylate copolymer latex ()) 30. 0 13. Preservatives Appropriate amount 14. Flavor Appropriate amount (Manufacturing method) (1) Mix the ingredients 1 to 8 at 80 °C and treat them with a roller. (2) The components 9 to 14 were uniformly mixed at 80 °C. (3) Add (2) to (1) and perform emulsification. (4) Cool (3) to make mascara (〇/W). The 0/W type mascara obtained is excellent in powder dispersibility. O/W type mascara which has excellent feeling of lubrication and excellent makeup effect. Example 2 2 Non-aqueous mascara: A non-aqueous mascara having the following composition was produced by the following method -37-201143808 诚分) (%) 1. Resin acid pentaerythritol ester 10. 0 2. Small candle tree resin 3. 0 3. Beeswax 2. 0 4. Ground wax 2. 0 5. Palmitic acid dextrin 2. 0 6. Trimethyl methoxy phthalate 3. 0 7. Dimethyl bis stearate-based aluminum lithium bentonite *" u) 5. 0 8. Propylene carbonate 0 9. Light liquid paraffin Residual amount 10. Black iron oxide 5. 0 11. Phospholipid treated flat cellulose powder (Product 2) 3. 0 12. Cerium oxide 3. 0 13. Talc 2. 0 Note ll) BENTONE38VBC (manufactured by Elementis) (1) Warm up the components 1 to 5 to ll 〇 °C. (2) Add the mixed components 6 to 9 in (1). (3) Add the mixed components 1〇 to 13 in (2). (4) The non-aqueous lash lashes obtained by the non-aqueous mascara^ are obtained by the treatment of the roller (3), which is a non-aqueous eyelash with excellent moisturizing feeling and long-lasting makeup effect. Example 2 3 Strip lipstick: A strip of lipstick of the composition shown below was produced by the following method. -38 - 201143808 (Ingredients) (%) 1. Polyethylene wax 7. 0 2. Microcrystalline wax 3. 0 3. Ground wax 2. 0 4. Triethyl 2-ethylhexanoate 20. 0 5. Tetrakilyl tetraethyl 2-hexanoate 10. 0 6. Dimethyl polyanion; "12) 3. 0 7. Hexadecyl 2-ethylhexanoate Remaining amount 8. Red 202 number 0. 5 9. Yellow No. 4 2. 0 10. Titanium oxide 5 11. Black iron oxide 1 12. Phospholipid treated flat cellulose powder (Product 3) 0. 5 13. Preservatives Appropriate amount 14. Ingredients: 12) KF-96 (10CS) (manufactured by Shin-Etsu Chemical Co., Ltd.) (Production Method) (1) Components 1 to 7 were dissolved and mixed at 100 ° C until homogeneous. (2) Add ingredients 8 to 14 in (1) and mix well. (3) The (2) is poured into a container and cooled to obtain a strip-shaped lipstick. The resulting strip of lipstick is a strip of lipstick with a good sense of lubrication and a long-lasting effect. Example 24 Lip gloss: Lip gloss of the composition shown below was produced in the following manner. -39- 201143808 (Ingredients) (%) 1. Polyethylene wax 2. 0 2. Microcrystalline wax 0 3. Triethyl 2-ethylhexanoate Remaining amount 4. Isostearyl malate 2〇. 〇 5. Liquid paraffin 2〇-〇 6. Phthalic anhydride 2. 0 7. Phospholipid treatment of flat cellulose powder 0 8. Iron oxide red 0. 1 9. Red No. 201 0. 3 10. Oxidized drink 0. 2 11. Black iron oxide 05 12. Preservatives Appropriate amount 13. Perfume suitable (Preparation method) (1) Dissolve ingredients 1 to 5 at 100 ° C until homogeneous. (2) Add components 6 to 13 to (1) and mix them evenly. (3) Put (2) into the container and cool to obtain lip gloss. The resulting lip gloss is a feeling of lubrication, a long-lasting effect of makeup, and a lip gloss. Example 2 50/W type foundation: A 〇/W type foundation having the composition shown below was produced by the following method. -40 - 201143808 诚分) (%) 1. Monostearic acid polyoxyethylene (20 mol) sorbitol 0. 5 2. Sesame oleic acid sorbitol 0. 5 3. 1,3-butanediol 10. 0 4. Polyoxygenated titanium oxide sl3) 10. 0 5. Polyoxygenated iron oxide red iil4) 0. 4 6. Polyoxane treatment of yellow iron oxide al5) 2. 0 7. Polyoxane treatment of black iron oxide tt6) 0. 1 8. Phospholipid treated flat cellulose powder (Product 5) 5. 0 9. Carboxyvinyl polymer 0. 3 10. Triethanolamine 0 11. Refined water Remaining amount 12. Ethanol 2. 0 13. Stearic acid 0 14. Twenty diol 0. 5 15. Liquid paraffin 2. 0 16. Tris-2-ethylhexanoate 2. 0 17. 2-ethylhexyl p-methoxycinnamate 2. 0 18. Vaseline 0. 5 19. Preservatives Appropriate amount of spices 13) SA-Titanium CR-50 (made by Sankyo Chemical Co., Ltd.) Note 14) SA-Iron Oxide Red Qibao (made by Sanhao Chemical Co., Ltd.) Note 15) SA-Yellow Lemon (made by Sankyo Chemical Co., Ltd.) (Method) ( 1) Disperse the ingredients 1 to 8 to a uniform roll. (2) Mix the ingredients 9 to 12 uniformly. (3) Add (1) to (2) and mix well. -41 - 201143808 (4) The components 13 to 19 were mixed and dissolved at 80 °C. (5) Emulsify (4) ' at 80 ° C in (3) to emulsify it. (6) Cooling (5) and adding the component 20' to obtain a 0/W type foundation. The obtained 0/W type foundation is a 0/W type foundation which is excellent in powder dispersibility, a feeling of lubrication, and a makeup lasting effect. Example 26 W/0 type foundation: The W/0 type foundation of the composition shown below was produced by the following method. (Component) Polyoxyethylene methyl decane • Polyoxypropylene oleyl methyl oxane •:; Hydrazine copolymer **16) (%) Dimethyl 2. 0 2. PEG-3 polydimethyl oxime 1. 0 3. Dimethyl polyoxo hospital *^211 20. 0 4. Polyoxane treatment of yellow iron oxide a4) 0 5. Polyoxane treatment of black iron oxide a5) 5 6. Polysilicate oxygen treatment of titanium oxide S6) 0. 5 7. Polyoxane treatment of iron oxide red sl3) 10. 0 8. Polyoxygenated talc a7) 2. 0 9. Phospholipid treated flat cellulose powder (Product 6) 5. 0 10. Triethyl 2-ethylhexanoate 10. 0 11. Sesame oleic acid sorbitol 0. 5 12. Refined water Remaining amount 13. 1,3-butanediol 15. 0 14. Preservatives Appropriate amount 15. Appropriate amount of spices 16) KF-6026 (manufactured by Shin-Etsu Chemical Co., Ltd.) Note 17) KF-6015 (manufactured by Shin-Etsu Chemical Co., Ltd.) -42- 201143808 (Manufacturing Method) (1) Mixing ingredients 1 to 3 uniformly (2) Ingredients 4 to 11 were dispersed by a roller to be uniform. (3) Add (2) to (1) and mix well. (4) The component 12~is is added to (3) to emulsify it to obtain a w/0 type foundation. The obtained W/0 type foundation is a W/0 type foundation which is excellent in powder dispersibility, a feeling of lubrication, and a makeup lasting effect. Example 2 7 0/W Eye Shadow: A 0/W type eye shadow of the composition shown below was produced by the following method. (ingredient) (%) 1. Acrylic/methacrylic acid ester copolymer a4) 0. 3 2. 1,3-butanediol 10. 0 3. Ethanol 5. 0 4. Triethanolamine 5 5. Refined water remaining amount 6. Liquid paraffin 2. 0 7. Dimethyl polyoxalate 4"12) 2. 0 8. Sesame oleic acid sorbitol 0. 1 9. Monostearic acid polyoxyethylene (2 〇 mol) sorbitol 0. 1 10. Blue No. 404 0. 5 11. Yellow iron oxide 2 12. Polyoxygenated Mica Chin S18) 0 13. Phospholipid treated flat cellulose powder (Product 5) 5. 0 14. Preservatives Appropriate amount 15. Perfume Appropriate amount 18) SA - Fula Noodle Gouraud (manufactured by Sanhao Chemical Co., Ltd.) -43- 201143808 (Method) (1) Mix ingredients 1 to 5 at 80 °C. (2) Adding components 6 and 7 to (1) and emulsifying them. (3) Disperse the ingredients 8 to 14 to a uniform roll. (4) Add (3) and component 15 to (2) to obtain an O/W type eye shadow. The obtained Ο/W type eye shadow is an eye shadow which is excellent in powder dispersibility, a feeling of lubrication, and an excellent makeup lasting effect. Example 2 8 Oily solid foundation: An oily solid foundation of the composition shown below was produced by the following method. 1. (ingredients) talc (%) 15. 0 2. Phospholipid treated flat cellulose powder (Product 4) 10. 0 3. Polyoxygenated titanium oxide al3) 0 4. Polyoxygenated iron oxide red ttl4> 0 5. Polyoxane treatment of yellow iron oxide a5) 3. 0 6. Polyoxane treatment of black iron oxide Note 6) 0. 2 7. Polyethylene wax 7. 0 8. Microcrystalline wax 6. 0 9. Triethyl 2-ethylhexanoate Residual amount 10. Dimethyl polyoxane & 12) 10. 0 11. Liquid paraffin 20. 0 12. Polyoxyethylene methyl oxalate • Polyoxypropylene oil based methyl oxa oxide • dimethyl methoxy olefin copolymer * ^ 19) 2. 0 13. Preservatives Appropriate amount 14. Perfume Appropriate amount Note 19) KF-6026 (manufactured by Shin-Etsu Chemical Co., Ltd.) -44 - 201143808 (Method) (1) Dissolve ingredients 7 to 13 at 90 °C. (2) Adding components 1 to 6 to (1), and dispersing them to a uniform roll. (3) Adding component 14 to (2), dissolving it at 8 ° C, and filling it into a gold dish to obtain an oily solid foundation. The oily solid foundation obtained is an oily solid foundation excellent in powder dispersibility, a feeling of lubrication, and a makeup lasting effect. Example 29 Strip concealer: A strip concealer of the composition shown below was produced by the following method. (%) 8. 0 2. 0 5. 0 5. 0 remaining amount 5. 0 5. 0 0. 5 1. 5 0. 5 5. 0 Appropriate amount (ingredient) 1. Ground wax 2. Polyethylene wax 3. Dimethyl polyanionine a 12) 4 · 2 · ethylhexanoic acid glyceride 5. Dioctanoic acid neopentyl glycol 6. Polyoxane treatment oxidation of the infusion 13) 7. Phospholipid treated flat cellulose powder (Product 3) 8. Red iron oxide 9. Yellow iron oxide 10. Black iron oxide 11. Zinc laurate 12. Preservatives 13. Perfume -45 - 201143808 (Preparation method) (1) Dissolve ingredients 1 to 5 by heating at 90 °C. (2) Adding components 6 to 12 to (1) and dispersing them to a uniform roll (3) Adding component 13 to (2), dissolving at 80 ° C, and filling it into a container to obtain a strip concealer Frost. The obtained strip concealer is a strip concealer which is excellent in dispersibility of powder, has a feeling of lubrication, and has excellent makeup lasting effect. Example 3 身体 Body lotion: A body lotion of the composition shown below was produced in the following manner. (ingredient) (%) 1. Stearic acid 0 2. Monostearic acid polyoxyethylene (20 mol) sorbitol 0. 5 3. Sesame oleic acid sorbitol 0. 5 4. Twenty diol 0. 5 5. 2-ethylhexanoic acid glyceride 5. 0 6. Liquid paraffin 2. 0 7. Dimethyl polyoxalate*"12) 2. 0 8. Ethanol 10. 0 9. Dipropylene glycol 10. 0 10. Triethanolamine 0 11. Refined water Remaining amount 12. Glycerin 5. 0 13. 1,3-butanediol 5. 0 14. Acrylic/alkyl methacrylate copolymer S4) 0. 2 15. Preservatives Flavor amount 17. Phospholipid treated flat cellulose powder (Product 2) 2. 0 -46 201143808 (Manufacturing Method) (1) Mix the ingredients 1 to 7 at 80 °C. (2) The components 8 to 16 were uniformly mixed at 80 °C. (3) Add (2) to (1) and perform emulsification. (4) Add component 17 to (3), mix well, stir and cool to obtain a body lotion. The obtained body lotion is a body lotion which is excellent in emulsion stability, a feeling of lubrication, and an excellent makeup effect. Example 3 1 Hair care lotion: A hair lotion of the composition shown below was produced by the following method. (ingredient) (%) 1. Twenty diol 2. 0 2. Palmitol 0 3. Triethyl 2-ethylhexanoate 3. 0 4. Alkyl trimethylammonium chloride injection 20) 1. 0 5. Propylene glycol 4. 0 6. Refined water Remaining amount 7. Hydroxyethyl cellulose 0. 1 8. Preservatives Spices moderate amount 10. Phospholipid treated flat cellulose powder (Product 1) 2. 0 Note 20) Akat 22-80 (manufactured by LionAkzo Co., Ltd.) (Method) -47- 201143808 (1) Mix components 1 to 5 at 80 °C. (2) Mix the components 6 to 9 at 8 (TC is uniform. (3) Add (2) to (1) and emulsify. (4) Add the component 1〇 to (3), mix well, stir and cool. The hair lotion obtained is a hair care lotion which is excellent in emulsion stability and excellent in the feeling of lubrication. Example 32 Hair Mask = The hair mask of the composition shown below was produced by the following method. (%) 1. Twenty diol 2. 0 2. Palmitol 6. 0 3. Liquid paraffin 3. 0 4. Chlorination yard base three money note 2 °) 5 5. Propylene glycol 4. 0 6. Highly polymerized methyl polyoxynium ii21) 0 7. Refined water Remaining amount 8. Preservatives Spices moderate amount 10. Phospholipid treated flat cellulose powder (Product 1) 3. 0 Note 21) BY22-050A (manufactured by Toray Dow Corning Co., Ltd.) (Production method) (1) The components 1 to 6 were uniformly mixed at 80 ° C. -48- 201143808 (2) Mix the ingredients 7 to 9 at 80 ° C. (3) Add (2) to (1) and emulsify. (4) Add component 10 to (3), mix well, and stir to cool to produce a hair mask. The hair mask obtained is an hair mask which is excellent in emulsion stability and excellent in the feeling of lubrication. Example 3 3 W/O type sunscreen: A sunscreen of the composition shown below was produced by the following method. (ingredient) (%) 1. Zinc oxide 15. 0 2. Polyfluorene treatment of particulate titanium oxide 5. 0 3. Phospholipid treated flat cellulose powder (Product 2) 2. 0 4. Sesame sesquistearate 1. 0 5. Triethyl 2-ethylhexanoate 10. 0 6. 2-ethylhexyl acrylate 0 7. Decylmethylcyclopentanium 10. 0 8. 2-Ethylhexyl p-methoxycinnamate 10. 0 9. Methyl polyoxyalkylene • Hexadecylmethyl polyoxane • Poly(oxyethylene • oxypropylene) methyl polyoxyalkylene copolymer a22) 2. 0 10. Refined water Remaining amount 11. Sodium chloride 0. 2 12. Ethanol 5. 0 13. Preservatives Appropriate amount 14. Flavours Appropriate amount 22) ABIL EM90 (manufactured by EVONIC GOLDSCHMIDT GMBH) -49- 201143808 (Production method) (1) Disperse the ingredients 1 to 5 to a uniform roll. (2) Adding components 6 to 9 to (1) and mixing them uniformly (3) Adding components 10 to 14 to (2) and emulsifying them to obtain a W/0 type sunscreen. The obtained W/0 type sunscreen is a sunscreen which is excellent in powder dispersibility, a feeling of lubrication, and an excellent makeup effect. Example 34 Nail Polish: Nail polish of the composition shown below was produced by the following method. (ingredient) (%) 1. Nitrocellulose 20. 0 2. Butyl acetate remaining amount 3. Ethyl acetate 20. 0 4. Toluene 30. 0 5. Organic soil movement 0. 5 6. Red 226 1. 0 7. Blue No. 404 0. 5 8. Titanium oxide 0 9. Phospholipid treated flat cellulose powder (Product 3) 1. 0 (Production Method) (1) The components 1 to 9 are uniformly mixed to obtain a nail varnish. The obtained nail polish' is a nail polish which is excellent in powder dispersibility, a feeling of lubrication, and a long-lasting effect of makeup. -50-201143808 Example 3 5 Cream: A barrier cream having the composition shown below was produced by the following method. (ingredient) (%) 1. Palmitol 2. 0 2. 2-ethylhexyl p-methoxycinnamate 5. 0 3. Dimethyl polyoxane ~ 2) 5. 0 4. Triethyl 2-ethylhexanoate 5. 0 5. Refined water remaining amount 6. N-stearyl sulfhydryl-N-methyl taurate sodium 0. 5 7. Carboxyvinyl polymer**23) 0. 1 8. Acrylic/methacrylic acid ester copolymer a4) 0. 1 9. Sodium hydroxide 05 10. Ethanol 10. 0 11. 1,3-butanediol 10. 0 12. Preservatives Appropriate amount 13. Phospholipid treated flat cellulose powder (Product 4) 2. 0 14. Perfume Appropriate amount Note 23) CARBOP(R) L940 (manufactured by LUBRIZOL ADVANCED MATERIALS) (Production method) (1) Components 1 to 4 were uniformly dissolved at 80 °C. (2) The components 5 to 12 were uniformly dissolved at 80 °C. (3) Add (1) to (2) and emulsify. (4) Adding ingredients 13 to 14 to (3), mixing and cooling to obtain a barrier cream. The obtained barrier cream is excellent in emulsion stability and a feeling of lubrication, and a cream having excellent makeup lasting effect. - Example 36 White powder: The white powder of the composition shown below was produced by the following method. (ingredient) (%) 1. Mica 1〇·〇 2. Phospholipid treated flat cellulose powder (Product 8) 10. 0 3. Talc remaining amount 4. Mica titanium 1〇-〇 5. Red 226 〇·5 6. Liquid paraffin 〇·5 7. Triethyl 2-ethylhexanoate 0 8. Preservatives Spices ΜΛ 10. Ethanol 0 (Production method) (1) The components 1 to 5 and the components 8 to 10 are uniformly mixed. (2) Add components 6 and 7 to (1) and mix well. (3) The powder was pulverized by (2) with a pulverizer to obtain white powder. The white powder obtained is excellent in powder dispersibility, a feeling of lubrication, and a white powder excellent in the lasting effect of makeup. Example 3 7 Solid powder type foundation: -52- 201143808 A solid powder type foundation of the composition shown below was produced by the following method. Sincerity) (%) 1. Polyoxygenated titanium oxide al3) 0 2. Talc remaining amount 3. Polyoxane treatment of iron oxide red aM) i. o 4. Polyoxane treatment of yellow iron oxide a5) 3. 0 5. Polyoxane treatment of black iron oxide S6) 0. 5 6. Phospholipid treated flat cellulose powder (Product 9) 20. 0 7. Nylon end 2. 0 8. Triethyl 2-ethylhexanoate 9. Liquid paraffin 3. 0 10. 2-ethylhexyl p-methoxycinnamate 3. 0 11. Preservatives The right amount of spices 13. Ethanol 0 (Production method) (1) Mix the components 1 to 7 and the components Η to 13 uniformly. (2) Adding ingredients 8 to 10' in (1) is uniformly mixed. (3) Smash (2) with a pulverizer. (4) Fill the (3) into a gold dish to make a solid powder type foundation. The obtained solid powder type foundation is a foundation excellent in powder dispersibility, a feeling of lubrication, and a makeup lasting effect. Example 38 Solid powder type eosin: A solid powder type blush having the composition shown below was produced by the following method. -53- 201143808 (Ingredients) (%) L Mica 30. 0 2. Talc remaining amount 3 scale lipid treated flat cellulose powder (product 3) lo o 4. Red 226 0. 5 5. Liquid paraffin 4. 0 6. Triethyl 2-ethylhexanoate 4. 0 7. Preservatives The right amount of spices 9. Ethanol 0 (Production method) (1) Mix the components 1 to 4 and 7 to 9 uniformly. (2) Add the components 5 and 6 to (1) and mix them evenly. (3) Smash (2) with a pulverizer. (4) Filling (3) into a gold dish to obtain a solid powder type blush. The obtained solid powder type blush is a blush which is excellent in powder dispersibility, a feeling of lubrication, and an excellent makeup lasting effect. Example 3 9 Solid powder type eye shadow: & The following method produced a solid powder type eye shadow of the composition shown below. -54- 201143808 (Ingredients) (%) 1. Mica titanium 20. 0 2. Phospholipid treated flat cellulose powder (Product 2) 10. 0 3. Talc remaining amount 4. Ultramarine, 2. 0 5. Yellow 401 0. 5 6. Nylon end 2. 0 7. Triethyl 2-ethylhexanoate 4. 0 8. Liquid paraffin 4. 0 9. Vaseline 0 10. Preservatives Proper amount of spices 12. Ethanol 0 (Production method) (1) Mix the components 1 to 6 and the components 10 to 12 uniformly. (2) Add ingredients 7 to 9 to (1) and mix well. (3) Smash (2) with a pulverizer. (4) Fill the (3) into a gold dish to obtain a solid powder eye shadow. The obtained solid powder type eye shadow is an eye shadow excellent in powder dispersibility, a feeling of lubrication, and a makeup lasting effect. Example 40 Production of ceramide-treated flat cellulose powder (1): Cellulose powder (W_400G/曰本本本本制药制药公司) derived from refined wood pulp was used as a raw material. First, the sorbed water is sufficiently removed to 0 by drying at a reduced pressure of -55 to 201143808 at 40 °C. 1% or less of cellulose powder (48g), and crushed ball made of alumina (20mm in diameter), put into a closable container made of alumina (500ml), and added ceramide 2 (TIC-001) / manufactured by Takasago Co., Ltd.) to 2% relative to cellulose powder. Then, using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany), continuous pulverization was carried out for 40 minutes at a rotation speed of 200 rpm (about 10 G (gravity acceleration)) to obtain ceramide-treated flat cellulose powder. Body (product 10) ° The average particle diameter, average thickness and flatness of the ceramide-treated flat cellulose powder were measured in the same manner as in Example 1. The average particle diameter, the average thickness and the flatness were respectively the average particle diameter. 18μιη, average thickness 0. 6μιη and flatness 30. Example 41 Production of ceramide treatment of flat cellulose powder (2): A cellulose powder (W-400G/Japan Paper Chemical Co., Ltd.) derived from refined wood pulp was used as a raw material. First, the sorbed water is sufficiently removed to 0 by drying under reduced pressure at 40 °C. 1% or less of cellulose powder (48 g), and crushed ball made of alumina (20 mm in diameter), put into a closable container made of alumina (500 ml), and added ceramide 6 (cerebral palsy) The amine Vl/Cosmo farm company made it 2% with respect to the cellulose powder. Thereafter, using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany), continuous pulverization was carried out for 50 minutes at a rotation speed of 20 rpm (about 10 G (gravity acceleration)) to obtain ceramide-treated flat cellulose. Powder. -56-201143808 The average particle diameter, average thickness, and flatness of the ceramide-treated flat cellulose powder were measured in the same manner as in Example 1, and the average particle diameter, the average thickness, and the flatness were respectively 20 μm. Average thickness 1. 5μιη and flatness 13. 3. Example 42 Production of ceramide treatment of flat cellulose powder (3): A cellulose powder (W-4〇OG/Japan Paper Chemical Co., Ltd.) derived from refined wood pulp was used as a raw material. First, the sorbed water is sufficiently removed to 0 by drying under reduced pressure at 40 °C. 1% or less of cellulose powder (48g) and pulverized ball made of alumina (20mm in diameter) are put into a closable container made of alumina (500ml), and ceramide 1 (ceramide) is added. I/Evonik Goldschmidt GmbH, 1%, and 1% of cellulose powder, and octyltriethoxysilane (manufactured by Tokyo Chemical Industry Co., Ltd.) to make 1% of cellulose powder. . Then, using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany), continuous pulverization was carried out for 20 minutes at a rotation speed of 20 rpm (about 10 G (gravity acceleration)) to obtain ceramide-treated flat cellulose. Powder. The average particle diameter, the average thickness and the flatness of the ceramide-treated flat cellulose powder were measured in the same manner as in Example 1. The average particle diameter, the average thickness and the flatness were respectively an average particle diameter of 30 μm and an average thickness of 1. 5μιη and flatness 20. 0. Example 43 57-201143808 Preparation of ceramide treatment of flat cellulose powder (4): A cellulose powder (W-400G/Japan Paper Chemical Co., Ltd.) derived from refined wood pulp was used as a raw material. First, the sorbed water is sufficiently removed to 0 by drying under reduced pressure at 40 °C. 1% or less of cellulose powder (48g), and crushed ball made of alumina (20mm in diameter), put into a closable container made of alumina (500ml), and add ceramide 3 (ceramide) III/Evonik Goldschmidt GmbH, 1%, and a single-end carboxyl group-denatured polyfluorene (X-22-371 0/Shin-Etsu Chemical Co., Ltd.) made 1% relative to cellulose powder . Thereafter, using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany), the pulverization was continued for 30 minutes at a rotation speed of 200 rpm (pulverization energy of about 10 G (gravity acceleration)) to obtain ceramide-treated flat cellulose powder. . The average particle diameter, the average thickness, and the flatness of the ceramide-treated flat cellulose powder were measured in the same manner as in Example 1. The average particle diameter, the average thickness, and the flatness were respectively an average particle diameter of 25 μm and an average thickness of 1·. 6μηι and flatness 1 5. 6. Example 44 Production of Cholesterol-Contained Flat Cellulose Powder (1): A cellulose powder (W-400G / 曰 Paper-making Pharmaceutical Co., Ltd.) derived from refined wood pulp was used as a raw material. First, the sorbed water is sufficiently removed to 0 by drying under reduced pressure at 40 °C. 1% or less of cellulose powder (48 g), and crushed ball made of alumina (20 mm in diameter), put into a closable container made of alumina (500 ml), and add cholesterol (cholesterol-58-201143808) / 曰本精化制制) made 2% relative to cellulose powder. Then, using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany), the powder was continuously pulverized for 40 minutes at a rotation speed of 200 rpm (about 10 G (gravitational acceleration)) to obtain a cholesterol-treated flat cellulose powder (product). 11) ° The average particle diameter, average thickness, and flatness of the cholesterol-treated flat cellulose powder were measured in the same manner as in Example 1. The average particle diameter, the average thickness, and the flatness were respectively an average particle diameter of 22 μm and an average thickness. 0. 8 μιη and flatness 27. 5. Example 45 Production of cholesterol-treated flat cellulose powder (2): A cellulose powder (W-40 0G/Japan Paper Chemical Co., Ltd.) derived from refined wood pulp was used as a raw material. First, the sorbed water is sufficiently removed to 0 by drying at 4 (TC). 1% or less of cellulose powder (48g), and crushed ball made of alumina (20mm in diameter), put into a closable container made of alumina (500ml), and add cholesterol (cholesterol / Japan Refinery) It is made 3% with respect to the cellulose powder, and the perfluoro-based phosphate is made 2% with respect to the cellulose powder. Then, using a planetary ball mill (P-5 type / manufactured by Fritsch, Germany), the powder was continuously pulverized for 60 minutes at a number of revolutions of 200 rpm (about 10 G (gravity acceleration)) to obtain a cholesterol-treated flat cellulose powder. The average particle diameter, the average thickness, and the flatness of the cholesterol-treated flat cellulose powder were measured in the same manner as in Example 1. The average particle diameter, the average thickness of -59 to 201143808, and the flatness were respectively an average particle diameter of 27 μm and an average thickness. 1. 8μπι and flatness 15. 0. Example 46 Manufacture of a phytosterol-treated flat cellulose powder: A cellulose powder (W-400 G/Nippon Paper Chemical Co., Ltd.) derived from refined wood pulp was used as a raw material. First, the sorbed water will be sufficiently removed to the crucible by drying under reduced pressure at 40 °C. 1% or less of cellulose powder (48g), and crushed ball made of alumina (20mm in diameter), put into a closable container made of alumina (volume 500m), and add phytosterol (phytosterol) /Eisai Food Chemicals) After using 2% 纤维素 with respect to cellulose powder, a planetary ball mill (P-5 type / manufactured by Fritsch, Germany) was used at a rotation speed of 200 rpm (about 10G (gravitational acceleration) pulverization energy). The pulverization was continued for 40 minutes to prepare a phytosterol-treated flat cellulose powder (Product 1 2). The average particle diameter, the average thickness and the flatness of the phytosterol-treated flat cellulose powder were measured in the same manner as in Example 1. The average particle diameter, the average thickness and the flatness were respectively an average particle diameter of 24 μm and an average thickness of Ι. Ομπι and flatness 24. 0. Reference Example 4 Production of ceramide treatment sericite: 98% of sericite (Adebaru 3 00S / angle octopus foil company) was brain-60- 201143808 guanamine 2 (TIC-001/Gaosha Spice Company) 2% using a honing machine (manufactured by Iwatani Co., Ltd.) for coating treatment to prepare ceramide treatment sericite (Comparative product 4) 〇 Reference Example 5 Preparation of ceramide treatment of cellulose powder (non-flat): Wood pulp powder (W-40 0G/Nippon Paper Chemical Co., Ltd.) was used as a raw material to put into a blender to make ceramide 2 (TIC-001/Gaosha Spice Co., Ltd.) in a manner of 2% with respect to cellulose powder. Prepared by dissolving in hexane. Thereafter, the mixture was stirred at a number of revolutions of 4 rpm for 5 minutes, dried under reduced pressure, and then pulverized to obtain ceramide-treated cellulose powder (non-flat) (Comparative Product 5). Example 47 Adhesion test: The ceramide-treated flat cellulose powder, the cholesterol-treated flat cellulose powder, and the phytosterol-treated flat cellulose powder obtained in Examples 40, 44 and 46 were examined in the same manner as in Example 8. (Product 1〇~12) adhesion to the skin. For comparison, the flat cellulose (Comparative Article 1) was treated with the stearic acid of Reference Example 1. The results of these are shown in Table 6. -61 - 201143808 [Table 6] Residual amount of sample powder on skin (g) Product 10 59 Product 11 54 Product 12 49 Comparative product 1 18 Example 48 Solid powder type foundation: Powder type powder was evaluated for its feeling ( Coating was carried out according to a general method, and a solid bottom having the composition shown in the following Table 7 was prepared. The solid powder type foundation obtained in the same manner as in Example 9 "sameness of the cosmetic film", "cosmetic durability" and "time-making" Lubrication)). The results are shown in Table 7. -62- 201143808 [Table 7]
No. 成分 本發明品 比較品 4 5 6 5 6 7 8 9 10 1 氧化駄 15 15 15 15 15 15 15 15 15 2 氧化鐵紅 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 3 黃氧化鐵 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 4 黑氧化鐵 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 5 群青 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 6 滑石 20 20 20 20 20 20 20 20 20 7 2%腦醯胺處理扁平纖維 素粉體(製品10) 10 8 2%膽固醇處理扁平纖維 素粉體(製品11) - 10 9 2%植物固醇處理扁平纖 維素粉體(製品12) - - 10 - - - - - - 10 3%硬脂酸處理扁平纖維 素粉末(比較製品1) - - - 10 - - - - - 11 2%腦醯胺處理絹雲母 (比較製品4) - - - - 10 - - - - 12 粉末纖.維素(W-100G/曰 本製紙化藥公司製） 9.8 - 9.8 9.8 13 腦醯胺2(TIC-001/高砂香 料公司製） - - - - - 0.2 - - - 14 2%腦醯胺處理纖維素粉 末(非扁平)(比較製品5) - - - - - - 10 - - 15 膽固醇(膽固醇/日本精化 公司製） 0.2 - 16 植物固醇(Eisai食品化藥） 0.2 17 雲母 剩餘 且 里 剩餘 量 剩餘 旦 里 剩餘 量 剩餘 量 剩餘 且 里 剩餘 旦 里 剩餘 量 剩餘 量 18 耐綸末 2 2 2 2 2 2 2 2 2 19 對羥基苯甲酸甲酯 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 20 三2-乙基己酸甘油酯 4 4 4 4 4 4 4 4 4 21 液體石蠟 5 5 5 5 5 5 5 5 5 22 香料 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 <評價項目及判定結果> 化妝膜之均一性 ◎ ◎ ◎ Δ Δ X X X X 化妝持久性 ◎ ◎ ◎ Δ 〇 Δ Δ Δ Δ 使用感(塗佈時之潤滑感） ◎ ◎ ◎ Δ Δ X 〇 X X -63- 201143808 又，使用腦醯胺處理扁平纖維素粉體、膽固醇處理扁 平纖維素粉體、植物固醇處理扁平纖維素粉體之粉底（本 發明品4〜6)，與改變成硬脂酸處理扁平纖維素粉體之比 較品5、改變成腦醯胺處理絹雲母之比較品6、改變成各 別配合纖維素與腦醯胺之比較品7、改變成腦醯胺處理纖 維素粉末之比較品8、改變成各別配合纖維素與膽固醇之 比較品9、改變成各別配合纖維素與植物固醇之比較品1 〇 相比，即使時間經過亦能維持化妝膜，於經時之化妝持久 性方面優異。又，本發明品4之粉底，與使用實施例9之 磷脂質處理扁平纖維素粉體之粉底（本發明品1〜3)相比， 即使時間經過亦能維持化妝膜之肌膚細緻度，於經時之化 妝持久性方面更爲優異。 實施例4 9 乳液： 以下述方法製造下述表8所示組成之乳液。以下述方 法調査將所得乳液塗佈於肌膚後之經時水分量變化（塗佈5 小時後）。其之結果亦一倂示於表8。 (製造方法） 將下述成分（1)〜（10)、（23)以70°C加熱溶解後，將 (1 1)〜（1 4)同樣地加熱後添加，進行攪拌。於室溫下放置 冷卻後，混合添加以（14)之一部分膨潤之（15)、U6)。再 -64- 201143808 者，將（17)〜（22)分散後，添加混合<» (試驗方法） <經時水分量變化> 首先，以既定之洗淨料洗淨塗佈部位，之後放入一定 條件之環境試驗室（溫度22°C、相對濕度50%)後經過20 分鐘以上之後，使用IBS公司製「SKICON200EX」測定4 次，使用其之平均値。於各被試驗者之下臂內側作一個邊 長2cm框的記號，將各樣品分別每人塗佈200ml於其中。 測定其之各部位中之塗佈前及塗佈5小時後之水分量，計 算出其對初期値比率。 <乳化安定性> 將各樣品以5 (TC保存1個月後，確認有無產生結晶析 出物，當無結晶析出物時判定爲〇、有時判定爲X。 (結果） -65- 201143808 [表8]No. Ingredients Comparative product of the invention 4 5 6 5 6 7 8 9 10 1 Cerium oxide 15 15 15 15 15 15 15 15 15 2 Iron oxide red 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 3 Yellow iron oxide 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 1.5 4 Black iron oxide 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 5 Ultramarine 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 6 talc 20 20 20 20 20 20 20 20 20 7 2% ceramide treatment of flat cellulose Powder (product 10) 10 8 2% cholesterol treated flat cellulose powder (Product 11) - 10 9 2% phytosterol treated flat cellulose powder (Product 12) - - 10 - - - - - - 10 3 % stearic acid treated flat cellulose powder (Comparative Article 1) - - - 10 - - - - - 11 2% ceramide treatment sericite (Comparative Article 4) - - - - 10 - - - - 12 Powder fiber. Wurzine (W-100G / manufactured by Sakamoto Paper Chemical Co., Ltd.) 9.8 - 9.8 9.8 13 Cerebral amide 2 (manufactured by TIC-001 / Takasago Co., Ltd.) - - - - - 0.2 - - - 14 2% ceramide treatment Cellulose powder (non-flat) (Comparative product 5) - - - - - - 10 - - 15 Cholesterol (Cholesterol / manufactured by Nippon Seika Co., Ltd.) 0.2 - 16 Plant sterol (Eisai food)品化药) 0.2 17 Mica remaining and remaining in the remaining amount of the remaining amount of the remaining amount of the remainder of the remaining amount of remaining in the remaining 18 of the end of nylon 2 2 2 2 2 2 2 2 2 2 19 methyl p-hydroxybenzoate 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 20 Triethyl 2-ethylhexanoate 4 4 4 4 4 4 4 4 4 21 Liquid paraffin 5 5 5 5 5 5 5 5 5 22 Perfume 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 <Evaluation item and determination result> Uniformity of cosmetic film ◎ ◎ Δ Δ XXXX Make-up durability ◎ ◎ Δ 〇 Δ Δ Δ Δ Sense of use (lubrication during coating) ◎ ◎ ◎ Δ Δ X 〇 XX -63- 201143808 Further, treatment of flat cellulose powder, cholesterol-treated flat cellulose powder, phytosterol-treated flat cellulose powder foundation (inventive products 4 to 6) using ceramide, and changing to stearin Comparison of acid-treated flat cellulose powder 5, comparison with ceramide treatment of sericite 6, change to a comparison of cellulose and ceramide, 7 changes to ceramide treatment cellulose powder Comparison product 8, change into each Comparison with cellulose cholesterol article 9, with the respective changes compared to the plant sterols of the cellulose square comparative product 1, even if the time elapsed cosmetic film can also maintain excellent lastingness of makeup and in economic terms of time. Further, the foundation of the present invention 4 can maintain the skin fineness of the cosmetic film even after the passage of time, using the foundation of the phospholipid-treated flat cellulose powder of Example 9 (inventive products 1 to 3). The durability of the makeup over time is even better. Example 4 9 Emulsion: An emulsion of the composition shown in Table 8 below was produced by the following method. The change in the amount of water over time after application of the obtained emulsion to the skin was examined by the following method (after 5 hours of application). The results are also shown in Table 8. (Production Method) The following components (1) to (10) and (23) were dissolved by heating at 70 ° C, and then (1 1) to (1 4) were heated in the same manner, and then stirred and stirred. After standing at room temperature for cooling, (15), U6) which is partially swollen with one of (14) is added by mixing. -64-201143808, after dispersing (17) to (22), adding a mixture <» (test method) <change in moisture content over time> First, the coated portion is washed with a predetermined washing material. After that, after 20 minutes or more of the environmental test room (temperature: 22 ° C, relative humidity: 50%) in a certain condition, it was measured four times using "SKICON200EX" manufactured by IBS, and the average enthalpy was used. Each of the subjects was given a mark of 2 cm in the side of the lower arm of each subject, and each sample was coated with 200 ml of each of them. The amount of water before and after application for 5 hours in each of the portions was measured, and the initial enthalpy ratio was calculated. <Emulsifying stability> Each sample was stored at 5 (TC for 1 month, and it was confirmed whether or not crystal precipitates were generated, and when there was no crystal precipitate, it was judged to be 〇, and it was judged to be X. (Result) -65- 201143808 [Table 8]
No. 成分 本發明品 比較品 7 11 12 13 14 1 硬脂酸 0.5 0.5 0.5 0.5 0.5 2 單硬脂酸甘油酯 0.2 0.2 0.2 0.2 0.2 3 聚山梨醇酯80 0.3 0.3 0.3 0.3 0.3 4 倍半油酸山梨醇酐 0.3 0.3 0.3 0.3 0.3 5 棕櫚醇 0.5 0.5 0.5 0.5 0.5 6 液體石蠘 0.2 0.2 0.2 0.2 0.2 7 三2-乙基己酸甘油酯 1.8 1.8 1.8 1.8 1.8 8 2-乙基己酸十六酯 3.6 3.6 3.6 3.6 3.6 9 二甲基聚矽氧烷 1.8 1.8 1.8 1.8 1.8 10 十甲基環戊矽氧烷 3.6 3.6 3.6 3.6 3.6 11 甘油 10 10 10 10 10 12 二丙二醇 4 4 4 4 4 13 三乙醇胺 0.4 0.4 0.4 0.4 0.4 14 精製水 39.7 42.7 39.7 39.7 39.7 15 丙烯酸院基酯共聚物 10 10 10 10 10 16 卡波姆(Carbomer) 5 5 5 5 5 17 1，3-丁二醇 8 8 8 8 8 18 對羥基苯甲酸甲酯 0.1 0.1 0.1 0.1 0.1 19 乙醇 7 7 7 7 7 20 2%腦醯胺處理扁平纖維 素粉體(製品10) 3 - - - - 21 3%硬脂酸處理扁平纖維 素粉末(比較製品1) - - 3 - - 22 纖維素粉末(W-100G/日 本製紙化藥公司製） - - - 3 2.94 23 腦醯胺2(TIC-001/高砂 香料公司製） - - - - 0.06 <經時水分量變化> 對初期値比率(％) 663 588 491 474 485 乳化安定性 〇 〇 〇 〇 X -66- 201143808 又，使用本發明品7之腦醯胺處理扁平纖維素粉體之 乳液，與未放入腦醯胺處理扁平纖維素粉體之比較品U、 改變成硬脂酸處理扁平纖維素粉體之比較品12、使用未處 理之纖維素粉體之比較品1 3、各別配合纖維素與腦醯胺之 比較品1 4相比，即使時間經過亦能維持肌膚的水分量， 於經時之保濕效果方面優異。 實施例50 凝膠美容液： 以下述方法製造下述表9所示組成之凝膠美容液。以 下述方法調査所得之凝膠美容液塗佈於肌膚後之經時水分 蒸散量變化（塗佈5小時後）。其之結果亦一倂示於表9 » (製造方法） 將下述成分（1)〜（4)溶解均勻後，同樣地將（5)〜（10) 溶解均勻後添加，並攪拌。添加混合以（18)膨潤之（16)、 (I7)。再將（11)〜（15)分散後，添加混合。 (試驗方法） 首先，以既定之洗淨料洗淨塗佈部位，之後放入一 定條件之環境試驗室（溫度22°C、相對濕度50%)後經過 20分鐘以上之後，使用Delfin Technologies公司製Vapometer SWL2型測定水分蒸散量（TEWL)4次，使用其之平均値。 -67- 201143808 於各被試驗者之下臂內側作一個邊長2cm框的記號，將各 樣品分別每人塗佈200ml於其中。測定其之各部位中之塗 佈前及塗佈5小時後之水分蒸散量，計算出其之對初期値 比。 (結果） [表9]No. Ingredients Comparative product of the present invention 7 11 12 13 14 1 Stearic acid 0.5 0.5 0.5 0.5 0.5 2 Glycerol monostearate 0.2 0.2 0.2 0.2 0.2 3 Polysorbate 80 0.3 0.3 0.3 0.3 0.3 4 sesquioleic acid Sorbitol 0.3 0.3 0.3 0.3 0.3 5 Palmitol 0.5 0.5 0.5 0.5 0.5 6 Liquid Dendrobium 0.2 0.2 0.2 0.2 0.2 7 Triethyl 2-ethylhexanoate 1.8 1.8 1.8 1.8 1.8 8 Hexadecyl 2-ethylhexanoate 3.6 3.6 3.6 3.6 3.6 9 Dimethyl polyoxane 1.8 1.8 1.8 1.8 1.8 10 Decamethylcyclopentaoxane 3.6 3.6 3.6 3.6 3.6 11 Glycerol 10 10 10 10 10 12 Dipropylene glycol 4 4 4 4 4 13 Triethanolamine 0.4 0.4 0.4 0.4 0.4 14 Refined water 39.7 42.7 39.7 39.7 39.7 15 Acrylate based copolymer 10 10 10 10 10 16 Carbomer 5 5 5 5 5 17 1,3-butanediol 8 8 8 8 8 18 methyl paraben 0.1 0.1 0.1 0.1 0.1 19 ethanol 7 7 7 7 7 20 2% ceramide treatment of flat cellulose powder (product 10) 3 - - - - 21 3% stearic acid treated flat cellulose Powder (Comparative Product 1) - - 3 - - 22 Cellulose powder (W-100G/Nippon Paper Chemical Co., Ltd.) - - - 3 2.94 23 Brain Amine 2 (manufactured by TIC-001 / Takasago Co., Ltd.) - - - - 0.06 <Change in moisture content over time> Initial 値 ratio (%) 663 588 491 474 485 Emulsification stability 〇〇〇〇X -66- 201143808 Further, the emulsion of the flat cellulose powder treated with the ceramide of the present invention 7 was changed to the flat cellulose powder treated with the stearic acid treated flat cellulose powder. Comparative product 12, comparative product using untreated cellulose powder 1 3, compared with the comparison product of cellulose and ceramide, each of which can maintain the moisture content of the skin even after passage of time. Excellent in moisturizing effect. Example 50 Gel cosmetic liquid: A gel cosmetic liquid having the composition shown in Table 9 below was produced by the following method. The amount of moisture evapotranspiration after the application of the gel cosmetic solution obtained by the method described below was applied to the skin (after 5 hours of application). The results are also shown in Table 9 » (Production method) After the following components (1) to (4) are uniformly dissolved, (5) to (10) are uniformly dissolved and added, and stirred. Add (18) to swell (16), (I7). After dispersing (11) to (15), mixing is added. (Test method) First, the coated part is washed with a predetermined washing material, and after being placed in a certain environmental test room (temperature: 22 ° C, relative humidity: 50%), after 20 minutes or more, the system is manufactured by Delfin Technologies. The Vapometer SWL2 type measures the amount of moisture evapotranspiration (TEWL) 4 times and uses the average enthalpy. -67- 201143808 A mark of 2 cm in the side of the lower arm of each subject was applied, and each sample was coated with 200 ml of each. The amount of water evapotranspiration before and after coating for 5 hours in each part was measured, and the initial enthalpy ratio was calculated. (Results) [Table 9]
No. 成分 本發明品 比較品 8 15 16 17 1 檸檬酸 0.02 0.02 0.02 0.02 2 檸檬酸鈉 0.04 0.04 0.04 0.04 3 甘油 2 2 2 2 4 精製水 64.518 65.518 64.518 64.518 5 三2-乙基己酸甘油酯 0..2 0..2 0..2 0..2 6 對甲氧基桂皮酸2-乙基己酯 0.06 0.06 0.06 0.06 7 倍半油酸山梨醇酐 0.03 0.03 0.03 0.03 8 聚山梨醇酯80 0.01 0.01 0.01 0.01 9 聚氧乙烯(8莫耳)烷基(12~15)醚磷酸 0.02 0.02 0.02 0.02 10 乙醇 8 8 8 8 11 對羥基苯甲酸甲酯 0.05 0.05 0.05 0.05 12 乙醇 5 5 5 5 13 2%腦醯胺處理扁平纖維素粉體(製品1〇) 1 _ - - 14 3%硬脂酸處理扁平纖維素粉末(比較製品1) - - 1 15 纖維素粉末(W-100G/日本製紙化藥公司製） - 1 16 卡波姆(Carbopol)l 342 0.15 0.15 0.15 0.15 17 氫氧化鈉 0.045 0.045 0.045 0.045 18 精製水 19.037 19.037 19.037 19.037 <經時水分蒸散量變化> 對初期値比 0.44 0.64 0.86 0.75 -68- 201143808 又，使用本發明品8之腦醯胺處理扁平纖維素粉體之 美容液，與未加入腦醯胺處理扁平纖維素粉體之比較品1 5 、使用未處理之纖維素粉體之比較品1 6、改變成硬脂酸處 理扁平纖維素粉體之比較品1 7相比，即使經過時間亦能 抑制肌膚的水分蒸散量，於經時之保濕效果方面更爲優異 。又，即使爲油劑少之難以抑制腦醯胺之結晶析出之美容 液的劑型，使用本發明品8之腦醯胺處理扁平纖維素粉體 之美容液，亦可抑制腦醯胺之結晶析出，於能夠容易地配 合腦醯胺方面上優異》 實施例5 1 雙層化妝水： 實施例10之雙層化妝水中，將磷脂質處理扁平纖維 素粉體（製品1)以實施例40所製造之腦醯胺處理扁平纖維 素粉體取代，除此之外，以同樣方式製造雙層化妝水。 所得之雙層化妝水，係潤滑之使用感優異、而水分蒸 散抑制效果較實施例1 〇者更優異之雙層化妝水。 實施例52 乳液： 實施例11之乳液中，將磷脂質處理扁平纖維素粉體（ 製品1)以實施例4 1所製造之腦醯胺處理扁平纖維素粉體 1.0%及實施例42所製造之膽固醇處理纖維素粉體1.0%取 -69- 201143808 代，除此之外，以同樣方式製造乳液。 所得之乳液，係乳化安定性優異、潤滑之使用感、水 分保持、蒸散抑制效果較實施例π者優異之乳液。 實施例5 3 乳霜： 實施例12之乳霜中，將磷脂質處理扁平纖維素粉體（ 製品2)以實施例42所製造之腦醯胺處理扁平纖維素粉體 取代，除此之外，以同樣方式製造乳霜。 所得之乳霜，係乳化安定性優異、潤滑之使用感、水 分保持、蒸散抑制效果較實施例12者優異之乳霜。 實施例5 4 美容液： 實施例13之美容液中，將磷脂質處理扁平纖維素粉 體（製品3)以實施例46所製造之植物固醇處理扁平纖維素 粉體取代，除此之外，以同樣方式製造美容液。 所得之美容液，係安定性優異、與實施例1 3者同樣 地潤滑之使用感、化妝持續效果優異之美容液。 實施例5 5 面膜： 實施例14之面膜中，將磷脂質處理扁平纖維素粉體（ 製品5)以實施例43所製造之腦醯胺處理扁平纖維素粉體 -70- 201143808 取代，除此之外，以同樣方式製造面膜。 所得之面膜，係乳化安定性優異、潤滑之使用感、水 分保持、蒸散抑制效果較實施例14者優異之面膜。 實施例5 6 洗面乳： 實施例15之洗面乳中，將磷脂質處理扁平纖維素粉 體（製品6)以實施例45所製造之植物固醇處理扁平纖維素 粉體取代，除此之外，以同樣方式製造洗面乳。 所得之洗面乳，係與實施例1 5者同樣的潤滑之使用 感優異之洗面乳。 實施例5 7 卸妝乳： 實施例16之卸妝乳中，將磷脂質處理扁平纖維素粉 體（製品1)以實施例42所製造之腦醯胺處理扁平纖維素粉 體取代，除此之外，以同樣方式製造卸妝乳。 所得之卸妝乳，係乳化安定性優異、與實施例1 6者 同樣的潤滑之使用感優異之卸妝乳。 實施例58 髮蠟： 實施例17之髮蠟中’將磷脂質處理扁平纖維素粉體（ 製品4)以實施例40所製造之腦醯胺處理扁平纖維素粉體 201143808 取代，除此之外，以同樣方式製造髮蠟。 所得之髮蠟，係整髮性優異、與實施例1 7者同樣的 潤滑之使用感優異之髮蠟。 實施例5 9 油性眼線筆： 實施例18之油性眼線筆中，將磷脂質處理扁平纖維 素粉體（製品2)以實施例43所製造之腦醯胺處理扁平纖維 素粉體取代，除此之外，以同樣方式製造油性眼線筆。 所得之油性眼線筆，係與實施例1 8者同樣的潤滑之 使用感、化妝持續效果優異之油性眼線筆。 實施例60 水性眼線筆： 實施例1 9之水性眼線筆中，將磷脂質處理扁平纖維 素粉體（製品1)以實施例46所製造之植物固醇處理扁平纖 維素粉體取代，除此之外，以同樣方式製造水性眼,線筆。 所得之水性眼線筆，係與實施例1 9者同樣的 '潤、滑之 使用感、化妝持續效果優異之水性眼線筆。 實施例61 眉筆： 實施例20之眉筆中，將磷脂質處理扁平纖維素粉體（ 製品3)以實施例44所製造之膽固醇處理扁平纖維素粉體 -72- 201143808 取代，除此之外，以同樣方式製造眉筆。 所得之眉筆，係與實施例20者同樣的潤滑之使用感 、化妝持續效果優異之眉筆。 實施例6 2 Ο/W型睫毛膏： 實施例21之0/W型睫毛膏中，將磷脂質處理扁平纖 維素粉體（製品1)以實施例42所製造之腦醯胺處理扁平纖 維素粉體取代，除此之外，以同樣方式製造o/w型睫毛 膏。 所得之O/w型睫毛膏，係與實施例21者同樣的附著 性優異、潤滑之使用感、化妝持續效果優異之Ο/W型睫 毛膏。 實施例63 非水系睫毛膏： 實施例22之非水系睫毛膏中，將磷脂質處理扁平纖 維素粉體（製品2)以實施例42所製造之腦醯胺處理扁平纖 維素粉體取代，除此之外，以同樣方式製造非水系睫毛膏 〇 所得之非水系睫毛膏，係與實施例2 2者同樣的潤滑 之使用感、化妝持續效果優異之非水系睫毛膏。 實施例64 -73- 201143808 條狀口紅： 實施例23之條狀口紅中，將磷脂質處理扁平纖維素 粉體（製品3)以實施例41所製造之腦醯胺處理扁平纖維素 粉體取代，除此之外，以同樣方式製造條狀口紅。 所得之條狀口紅，係與實施例2 3者同樣的潤滑之使 用感、化妝持續效果優異之口紅。 實施例6 5 唇蜜： 實施例24之唇蜜中，將磷脂質處理扁平纖維素粉體（ 製品4)以實施例46所製造之植物固醇處理扁平纖維素粉 體0.5 %取代，除此之外，以同樣方式製造唇蜜。 所得之唇蜜，係與實施例2 4者同樣的潤滑之使用感 、化妝持續效果優異之唇蜜。 實施例6 6 0/W型粉底： 實施例25之0/W型粉底中，將磷脂質處理扁平纖維 素粉體（製品5)以實施例43所製造之腦醯胺處理扁平纖維 素粉體取代’除此之外’以同樣方式製造〇/W型粉底。 所侍之〇 / W型粉底，係與實施例2 5者同樣的潤滑之 使用感、化妝持續效果優異之0/W型粉底。 實施例6 7 • 74 - 201143808 w/ο型粉底·· 實施例26之w/o型粉底中，將磷脂質處理扁平纖維 素粉體（製品6)以實施例45所製造之植物固醇處理扁平纖 維素粉體3.0 %取代，除此之外，以同樣方式製造W/Ο型 粉底。 所得之W/O型粉底，係與實施例26者同樣的潤滑之 使用感、化妝持續效果優異之W/〇型粉底。 實施例68 〇/w型眼影： 實施例27之o/w型眼影中，將磷脂質處理扁平纖維 素粉體（製品5)以實施例44所製造之膽固醇處理扁平纖維 素粉體取代，除此之外’以同樣方式製造Ο/W型眼影。 所得之0/W型眼影，係與實施例27者同樣的潤滑之 使用感、化妝持續效果優異之Ο/W型眼影。 實施例69 油性固型粉底： 實施例28之油性固型粉底中，將磷脂質處理扁平纖 維素粉體（製品4)以實施例42所製造之腦醯胺處理扁平纖 維素粉體取代，除此之外，以同樣方式製造油性固型粉底 〇 所得之油性固型粉底，係與實施例2 8者同樣的潤滑 之使用感、化妝持續效果優異之油性固型粉底。 -75- 201143808 實施例70 條狀遮瑕霜： 實施例29之條狀遮瑕霜中’將磷脂質處理扁平纖維 素粉體（製品3)以實施例40所製造之腦醯胺處理扁平纖維 素粉體取代，除此之外，以同樣方式製造條狀遮瑕霜。 所得之條狀遮瑕霜，係與實施例29者同樣的潤滑之 使用感、化妝持續效果優異之條狀遮瑕霜。 實施例7 1 身體乳液： 實施例30之身體乳液中，將磷脂質處理扁平纖維素 粉體（製品2)以實施例45所製造之膽固醇處理扁平纖維素 粉體取代，除此之外，以同樣方式製造身體乳液。 所得之身體乳液，係乳化安定性優異、與實施例3 0 者同樣的潤滑之使用感、化妝持續效果優異之身體乳液。 實施例72 護髮乳： 實施例31之護髮乳中，將磷脂質處理扁平纖維素粉 體（製品1)以實施例41所製造之腦醯胺處理扁平纖維素粉 體取代，除此之外，以同樣方式製造護髮乳。 所得之護髮乳，係乳化安定性優異、與實施例31者 同樣的潤滑之使用感、化妝持續效果優異之護髮乳。 -76- 201143808 實施例7 3 髮膜： 實施例32之髮膜中’將磷脂質處理扁平纖維素粉體（ 製品1)以實施例44所製造之膽固醇處理扁平纖維素粉體 取代，除此之外，以同樣方式製造髮膜。 所得之髮膜，係乳化安定性優異、與實施例3 2者同 樣的潤滑之使用感優異之髮膜。 實施例7 4 W/0型防曬乳： 實施例3 3之W/0型防曬乳中，將磷脂質處理扁平纖 維素粉體（製品2)以實施例43所製造之腦醯胺處理扁平纖 維素粉體取代，除此之外，以同樣方式製造W/O型防曬 乳。 所得之W/0型防曬乳，係與實施例3 3者同樣的潤滑 之使用感、化妝持續效果優異之防曬乳。 實施例75 指甲油： 實施例34之指甲油中，將磷脂質處理扁平纖維素粉 體（製品3)以實施例45所製造之膽固醇處理扁平纖維素粉 體取代，除此之外，以同樣方式製造指甲油。 所得之指甲油’係與實施例34者同樣的潤滑之使用 -77- 201143808 感、化妝持續效果優異之指甲油。 實施例76 隔離霜： 實施例35之隔離霜中，將磷脂質處理扁平纖維素粉 體（製品4)以實施例46所製造之植物固醇處理扁平纖維素 粉體取代，除此之外，以同樣方式製造隔離霜。 所得之隔離霜，係乳化安定性優異、與實施例3 5者 同樣的潤滑之使用感、化妝持續效果優異之隔離霜。 實施例77 白粉： 實施例36之白粉中，將磷脂質處理扁平纖維素粉體（ 製品8)以實施例40所製造之腦醯胺處理扁平纖維素粉體 取代，除此之外，以同樣方式製造白粉。 所得之白粉，係與實施例3 6者同樣地附著性優異、 潤滑之使用感、化妝持續效果優異之白粉。 實施例7 8 固形粉末型粉底： 實施例37之固形粉末型粉底中，將將磷脂質處理扁 平纖維素粉體（製品9)以實施例4 1所製造之腦醯胺處理扁 平纖維素粉體取代，除此之外，以同樣方式製造固形粉末 型粉底。 -78- 201143808 所得之固形粉末型粉底，係與實施例3 7者同樣地附 著性優異、潤滑之使用感優異、化妝持續效果較實施例35 優異之粉底。 實施例7 9 固形粉末型腮紅： 實施例38之固形粉末型腮紅中，將磷脂質處理扁平 纖維素粉體（製品3)以實施例46所製造之植物固醇處理扁 平纖維素粉體取代，除此之外，以同樣方式製造固形粉末 型腮紅。 所得之固形粉末型腮紅，係與實施例3 8者同樣地附 著性優異、潤滑之使用感、化妝持續效果優異之腮紅。 實施例8 0 固形粉末型眼影： 實施例39中之固形粉末型眼影中，將磷脂質處理扁 平纖維素粉體（製品2)以實施例44所製造之膽固醇處理扁 平纖維素粉體取代，除此之外，以同樣方式製造固形粉末 型眼影。 所得之固形粉末型眼影，係與實施例39者同樣的潤 滑之使用感、化妝持續效果優異之眼影。 產業上之利用可能性 本發明之兩親媒性物質處理的扁平纖維素粉體’基材 -79- 201143808 之纖維素本身爲有機物，且爲扁平，故以往之扁平之無機 物之滑石或絹雲母相比，具附著性高之優異使用感。再者 ，兩親媒性物質處理的扁平纖維素粉體，其之表面係以兩 親媒性物質處理，故附著性、配合於化妝料之際之塗佈時 的潤滑感或化妝膜之均一性優異，且化妝持續特性等提昇 因此，本發明之兩親媒性物質處理的扁平纖維素粉體 ，可利用於許多化妝料中，而就特別容易發揮其之效果的 化妝料而言，於水分保持量或水分蒸散抑制等保濕性優異 之粉體，較佳可使用於基礎化妝料、特別是美容液或乳液 、乳霜等護0化妝料，而於泛用油劑或水之分散性優異之 化妝料，較佳可使用於液體粉底等上妝化妝料。又，該等 粉體’由於附著性佳、化妝持久性優異，故亦可作爲粉餅 等上妝化妝料使用。 -80-No. Ingredients Comparative product of the present invention 8 15 16 17 1 Citric acid 0.02 0.02 0.02 0.02 2 Sodium citrate 0.04 0.04 0.04 0.04 3 Glycerin 2 2 2 2 4 Refined water 64.518 65.518 64.518 64.518 5 Triethyl 2-ethylhexanoate 0..2 0..2 0..2 0..2 6-P-methoxycinnamate 2-ethylhexyl ester 0.06 0.06 0.06 0.06 7 sesquioleic acid sorbitan 0.03 0.03 0.03 0.03 8 Polysorbate 80 0.01 0.01 0.01 0.01 9 Polyoxyethylene (8 mole) alkyl (12 ~ 15) ether phosphate 0.02 0.02 0.02 0.02 10 ethanol 8 8 8 8 11 methyl p-hydroxybenzoate 0.05 0.05 0.05 0.05 12 ethanol 5 5 5 5 13 2% ceramide treatment of flat cellulose powder (product 1 〇) 1 _ - - 14 3% stearic acid treated flat cellulose powder (Comparative Article 1) - - 1 15 Cellulose powder (W-100G/Japan Paper-making pharmaceutical company) - 1 16 Carbopol l 342 0.15 0.15 0.15 0.15 17 Sodium hydroxide 0.045 0.045 0.045 0.045 18 Refined water 19.037 19.037 19.037 19.037 <Change in moisture evapotranspiration over time> 0.44 0.64 0.86 0.75 -68- 201143808 Further, the treatment of flat cellulose with ceramide of the present invention 8 Comparison of body beauty lotion, comparison with flattened cellulose powder without ceramide treatment, comparison with untreated cellulose powder, and comparison with stearic acid treated flat cellulose powder Compared with the product, it can suppress the amount of water evapotranspiration of the skin even after the passage of time, and is superior in the moisturizing effect over time. In addition, even if it is a dosage form of a cosmetic liquid which is less likely to inhibit the precipitation of ceramide, the ceramide can be inhibited by the use of the ceramide treatment of the flat cellulose powder of the present invention. It is excellent in that it can be easily combined with ceramide. Example 5 1 Double-layer lotion: In the double-layered lotion water of Example 10, the phospholipid-treated flat cellulose powder (Product 1) was produced in Example 40. In addition to the ceramide treatment of the flat cellulose powder, a double-layered lotion was produced in the same manner. The obtained double-layered lotion is a double-layered lotion which is excellent in the feeling of use and has a water vapor transpiration suppressing effect superior to that of the first embodiment. Example 52 Emulsion: In the emulsion of Example 11, the phospholipid-treated flat cellulose powder (Product 1) was produced by using ceramide-treated flat cellulose powder of Example 41 and 1.0% and Example 42. The cholesterol-treated cellulose powder was 1.0% from -69 to 201143808, and in addition, the emulsion was produced in the same manner. The obtained emulsion was excellent in emulsion stability, a feeling of lubrication, a moisture retention, and an evapotranspiration inhibitory effect compared with the example π. Example 5 3 Cream: In the cream of Example 12, the phospholipid-treated flat cellulose powder (Product 2) was replaced with the ceramide-treated flat cellulose powder produced in Example 42, except Make cream in the same way. The obtained cream was excellent in emulsion stability, a feeling of lubrication, a moisture retention, and an evapotranspiration inhibitor superior to those of Example 12. Example 5 4 Cosmetic liquid: In the cosmetic liquid of Example 13, the phospholipid-treated flat cellulose powder (Product 3) was replaced with the phytosterol-treated flat cellulose powder produced in Example 46, except , the beauty liquid is manufactured in the same way. The obtained cosmetic liquid is a cosmetic liquid which is excellent in stability and has a feeling of use which is lubricated in the same manner as in the case of Example 13 and which has excellent makeup lasting effect. Example 5 5 Mask: In the mask of Example 14, the phospholipid-treated flat cellulose powder (Product 5) was replaced with the ceramide-treated flat cellulose powder -70-201143808 manufactured in Example 43, In addition, the mask was produced in the same manner. The obtained mask was a mask which was excellent in emulsion stability, a feeling of lubrication, a moisture retention, and an evapotranspiration suppression effect compared with Example 14. Example 5 6 Facial Cleanser: In the facial cleanser of Example 15, the phospholipid-treated flat cellulose powder (Product 6) was replaced with the phytosterol-treated flat cellulose powder produced in Example 45, except Make facial cleanser in the same way. The facial cleanser obtained was the same facial cleanser as that of Example 15 except that it was excellent in lubrication. Example 5 7 Cleansing Milk: In the cleansing milk of Example 16, the phospholipid-treated flat cellulose powder (Product 1) was replaced with the ceramide-treated flat cellulose powder produced in Example 42, except Make cleansing milk in the same way. The cleansing milk obtained was excellent in emulsification stability, and was excellent in the feeling of use similar to the lubrication of Example 16. Example 58 Wax: In the hair wax of Example 17, 'the phospholipid-treated flat cellulose powder (Product 4) was replaced with the ceramide-treated flat cellulose powder 201143808 manufactured in Example 40, except Wax is produced in the same way. The hair wax obtained was excellent in hair styling property and was excellent in the same feeling of lubrication as in Example 17. Example 5 9 Oily Eyeliner: In the oily eyeliner of Example 18, the phospholipid-treated flat cellulose powder (Product 2) was replaced with the ceramide-treated flat cellulose powder produced in Example 43, In addition, an oily eyeliner is manufactured in the same manner. The oily eyeliner obtained was the same as the oily eyeliner which was excellent in the feeling of use and the makeup lasting effect similarly to those of Example 18. Example 60 Water-based eyeliner: In the aqueous eyeliner of Example 19, the phospholipid-treated flat cellulose powder (Product 1) was replaced with the phytosterol-treated flat cellulose powder produced in Example 46, except In addition, water-based eyes and line pens are manufactured in the same manner. The obtained water-based eyeliner was the same as the water-based eyeliner which was excellent in moisturizing, slipping, and makeup lasting effect as in the case of Example 19. Example 61 Eyebrow pencil: In the eyebrow pencil of Example 20, the phospholipid-treated flat cellulose powder (Product 3) was replaced with the cholesterol-treated flat cellulose powder-72-201143808 produced in Example 44, except In addition, the eyebrow pencil is manufactured in the same way. The eyebrow pencil obtained was the eyebrow pencil which was excellent in the feeling of use and the effect of the makeup last in the same manner as in Example 20. Example 6 2 Ο/W type mascara: In the 0/W type mascara of Example 21, the phospholipid-treated flat cellulose powder (Product 1) was treated with the ceramide treatment of the flat cellulose manufactured in Example 42 In addition to the powder replacement, an o/w type mascara was produced in the same manner. The obtained O/w type mascara was the same as the case of Example 21, and had excellent adhesion, a feeling of lubrication, and an excellent makeup lasting effect. Example 63 Non-aqueous mascara: In the non-aqueous mascara of Example 22, the phospholipid-treated flat cellulose powder (Product 2) was replaced with the ceramide-treated flat cellulose powder produced in Example 42 except In addition, the non-aqueous mascara obtained by producing the non-aqueous mascara in the same manner is a non-aqueous mascara which is excellent in the feeling of use and the long-lasting effect of the same as in the case of the second embodiment. Example 64 -73- 201143808 Strip-shaped lipstick: In the strip-shaped lipstick of Example 23, the phospholipid-treated flat cellulose powder (Product 3) was replaced with the ceramide-treated flat cellulose powder produced in Example 41. In addition, strip lipsticks were produced in the same manner. The obtained strip-shaped lipstick was the same as that of the Example 2, and the lipstick was excellent in the feeling of use and the makeup lasting effect. Example 6 5 Lip Gloss: In the lip gloss of Example 24, the phospholipid-treated flat cellulose powder (Product 4) was replaced with 0.5% of the phytosterol-treated flat cellulose powder produced in Example 46, except In addition, lip gloss is made in the same way. The resulting lip gloss was the same lubricious feeling of use as in Example 24, and lip gloss having excellent makeup lasting effect. Example 6 6 0/W type foundation: In the 0/W type foundation of Example 25, the phospholipid treated flat cellulose powder (Product 5) was treated with the ceramide treatment of the flat cellulose powder prepared in Example 43. Instead of 'other than this', a 〇/W type foundation is produced in the same manner. The 侍 / W type foundation is a 0/W type foundation which is excellent in the feeling of use and the makeup lasting effect similarly to the case of Example 2. Example 6 7 • 74 - 201143808 w/o type foundation · In the w/o type foundation of Example 26, the phospholipid-treated flat cellulose powder (product 6) was treated with the phytosterol produced in Example 45. A W/Ο type foundation was produced in the same manner except that the flat cellulose powder was replaced by 3.0%. The obtained W/O type foundation was a W/〇 type foundation having the same feeling of lubrication and excellent makeup lasting effect as in Example 26. Example 68 〇/w type eye shadow: In the o/w type eye shadow of Example 27, the phospholipid-treated flat cellulose powder (Product 5) was replaced with the cholesterol-treated flat cellulose powder produced in Example 44, except In addition to this, 'Ο/W eyeshadows are made in the same way. The 0/W type eye shadow obtained was the same as that of Example 27, and the Ο/W type eye shadow which was excellent in the feeling of use and the makeup lasting effect. Example 69 Oily solid foundation: In the oily solid foundation of Example 28, the phospholipid-treated flat cellulose powder (Product 4) was replaced with the ceramide-treated flat cellulose powder produced in Example 42 except In addition, the oily solid foundation obtained by the oily solid foundation was produced in the same manner as the oily solid foundation having the same feeling of lubrication and excellent makeup lasting effect as in Example 28. -75- 201143808 Example 70 Strip concealer: In the strip concealer of Example 29, the phospholipid-treated flat cellulose powder (Product 3) was treated with the ceramide treatment of the flat cellulose powder prepared in Example 40. In addition to the body substitution, a strip concealer was produced in the same manner. The strip concealer obtained in the same manner as in Example 29 was a strip concealer which was excellent in the feeling of lubrication and the effect of maintaining the makeup. Example 7 1 Body lotion: In the body lotion of Example 30, the phospholipid-treated flat cellulose powder (Product 2) was replaced with the cholesterol-treated flat cellulose powder produced in Example 45, except The body lotion is made in the same way. The obtained body lotion is a body lotion which is excellent in emulsification stability, and has the same feeling of use as the same as that of Example 30 and excellent in makeup lasting effect. Example 72 Hair Care: In the hair conditioner of Example 31, the phospholipid-treated flat cellulose powder (Product 1) was replaced with the ceramide-treated flat cellulose powder produced in Example 41, except In addition, hair care products are manufactured in the same manner. The obtained hair care lotion is a hair care lotion which is excellent in emulsification stability, and has the same feeling of lubrication and a makeup lasting effect as those of Example 31. -76- 201143808 Example 7 3 Hair Mask: In the hair mask of Example 32, the phospholipid-treated flat cellulose powder (Product 1) was replaced with the cholesterol-treated flat cellulose powder produced in Example 44, except In addition, the hair mask is manufactured in the same manner. The hair mask obtained was excellent in emulsion stability, and the same hair styling property as that of Example 32 was excellent. Example 7 4 W/0 type sunscreen lotion: Example 3 3 of the W/0 type sunscreen lotion, the phospholipid treated flat cellulose powder (Product 2) was treated with the ceramide treatment of the flat fiber manufactured in Example 43 In addition to the substitution of the plain powder, W/O type sunscreen lotion was produced in the same manner. The obtained W/0 type sunscreen lotion was the sunscreen lotion which was excellent in the feeling of use and the makeup lasting effect similarly to the case of Example 3. Example 75 Nail Polish: In the nail varnish of Example 34, the phospholipid-treated flat cellulose powder (Product 3) was replaced with the cholesterol-treated flat cellulose powder produced in Example 45, except that The way to make nail polish. The resulting nail polish was used in the same manner as in Example 34. -77- 201143808 Nail polish excellent in sensation and makeup. Example 76 A barrier cream: In the barrier cream of Example 35, the phospholipid-treated flat cellulose powder (Product 4) was replaced with the phytosterol-treated flat cellulose powder produced in Example 46, in addition to The cream is made in the same way. The obtained barrier cream is a barrier cream which is excellent in emulsification stability, and has the same feeling of lubrication and a makeup lasting effect as those of Example 35. Example 77 White powder: In the white powder of Example 36, the phospholipid-treated flat cellulose powder (Product 8) was replaced with the ceramide-treated flat cellulose powder produced in Example 40, except that The way to make white powder. The white powder obtained was excellent in adhesion similar to that of Example 36, and was excellent in the feeling of use of lubrication and the whitening effect of the makeup lasting effect. Example 7 8 Solid powder type foundation: In the solid powder type foundation of Example 37, the phospholipid treated flat cellulose powder (Product 9) was treated with the ceramide treatment of the flat cellulose powder prepared in Example 41 Instead of this, a solid powder type foundation was produced in the same manner. -78-201143808 The obtained solid powder type foundation was excellent in adhesion as in the case of Example 37, and was excellent in the feeling of use of the lubricant, and the makeup lasting effect was superior to that of Example 35. Example 7 9 Solid powder type eosin: In the solid powder type eosin of Example 38, the phospholipid-treated flat cellulose powder (Product 3) was treated with the phytosterol-treated flat cellulose powder produced in Example 46. Instead of this, a solid powder type blush was produced in the same manner. The obtained solid powder type blush was obtained in the same manner as in Example 38, and the blush was excellent in adhesion, a feeling of lubrication, and a makeup lasting effect. Example 8: Solid powder type eye shadow: In the solid powder type eye shadow of Example 39, the phospholipid-treated flat cellulose powder (Product 2) was replaced with the cholesterol-treated flat cellulose powder produced in Example 44, except In addition, a solid powder type eye shadow is produced in the same manner. The solid powder type eye shadow obtained was the same eye shadow as that of Example 39, which was excellent in moisturizing feeling and makeup lasting effect. Industrial Applicability The flat cellulose powder treated with the amphiphilic material of the present invention, the base material of the substrate-79-201143808, is an organic substance and is flat, so that the conventional flat inorganic substance talc or sericite Compared with the excellent use of high adhesion. Further, since the surface of the flat cellulose powder treated with the amphiphilic material is treated with an amphiphilic substance, the adhesion, the lubricating feeling at the time of application to the cosmetic, or the uniformity of the cosmetic film are uniform. Therefore, the flat cellulose powder treated with the amphiphilic material of the present invention can be used in many cosmetic materials, and the cosmetic material which is particularly easy to exert its effect is A powder excellent in moisture retention such as moisture retention or moisture evapotranspiration is preferably used for a base cosmetic, particularly a cosmetic liquid, an emulsion, a cream, and the like, and is used in a general purpose oil or water dispersibility. The excellent cosmetic material is preferably used for a makeup foundation such as a liquid foundation. Further, since these powders are excellent in adhesion and excellent in makeup durability, they can also be used as a makeup cosmetic such as a powder cake. -80-