TW201133141A - Coloring composition, color filter and color liquid crystal display element - Google Patents

Abstract

The present invention provides a novel coloring composition which is capable of forming a pixel that has an excellent adherence to transparent conductive films or inorganic films and further an excellent solvent resistance with low light exposure. The coloring composition is characterized by containing a basket-type sesquisiloxane having at least one component selected from the group consisting of (A) a coloring agent, (B) a binder resin, (C) a polyfunctional monomer and (D) sulfanyl group and polymerization unsaturated groups.

Description

201133141 6. Technical Field of the Invention The present invention relates to a coloring composition, a color filter, and a color liquid crystal display element, and more particularly to a colored composition for forming a colored layer, a color filter of a coloring layer formed of the coloring composition, and a liquid crystal display element having the color filter. The colored layer is used for a transmissive or reflective type color liquid crystal display device, a color image sensor element, A color filter used for an organic EL display element, electronic paper, or the like is extremely useful. [Prior Art] Conventionally, when a color filter is manufactured using a coloring sensitizing radiation linear composition, a coloring sensitizing radioactive composition is coated on a substrate or a substrate on which a light shielding layer of a desired pattern is formed in advance. After drying, the film is irradiated with radiation and developed into a desired pattern shape (hereinafter referred to as "exposure") to obtain pixels of respective colors (see, for example, Patent Document 1 and Patent Document 2). Further, a method of forming a black matrix using a photopolymerizable composition containing a black material is known (see, for example, Patent Document 3). Further, a method of obtaining a pixel of each color by an inkjet method using a colored resin composition (see, for example, Patent Document 4) is known. However, Patent Document 5 proposes a photosensitive composition which is excellent in developability and which is a coloring paste which can be sharply patterned, and contains a carboxyl group and an ethyl group in a side chain. A photosensitive composition of an unsaturated acrylic copolymer and a polyfunctional thiol. However, the color filter formed by using these photosensitive compositions in -3-201133141 is a transparent conductive film such as ITO or IZO formed thereon or an inorganic film such as a SiNx film or a Si〇X film. There is a problem of insufficient adhesion. Moreover, in recent years, in the technical field of color filters, although the amount of exposure is reduced and the takt time is shortened, although the previous color-sensing radioactive composition is used, the formed pixels are gradually becoming resistant. The problem of insufficient solvent properties is apparently present. We believe that the background of these problems is to respond to the requirements of high contrast, high brightness, and high color purity of color liquid crystal display elements in recent years, and to use pigments for various color-sensing radioactive compositions. Various kinds of refining treatments or surface treatments; or the tendency of the content ratio of the pigments in the coloring sensitizing radiation composition to become higher. [Patent Document 1] Japanese Laid-Open Patent Publication No. Hei No. Hei. No. Hei. No. Hei. SUMMARY OF THE INVENTION The present invention has been made in view of the above circumstances, and it is an object of the invention to provide a novel coloring composition, which is not in close contact with a transparent conductive film or an inorganic film. It is excellent in the properties, and further, it is possible to form a pixel excellent in solvent resistance even in a low exposure amount. -4-201133141 The problem of the problem is solved by the inventors of the present invention, and the first composition contains a reactive hemiphthalocyanine such as a sulfhydryl group (-SH) to solve the above problems. In the present invention, the present invention provides a coloring composition having a cage selected from the group consisting of (A) a colorant, (B) a binder resin, a body, and (D) a sulfonyl group and a polymerizable unsaturated group. Sesquiterpene oxide (hereinafter referred to as "semi-half-turn", the present invention provides a color filter, a liquid crystal display element of a light sheet, and the color filter is a color layer formed by the object. The colored composition of the present invention has excellent adhesion to a transparent conductive film or an inorganic film, and is excellent in further solvent resistance. Further, the colored layer of the present invention has high voltage holding ratio and excellent electrical properties. The radiation-sensitive linear composition of the invention is used for color conversion color filters, organic EL filters, and color filters for electronic papers for color image pickup elements for liquid crystal display elements in the electronic industry. first A cage-type invention by coloring a functional group was found, which was characterized by containing (C) at least a house of oxygen (D)" in a polyfunctional group. And the color filter device is provided with the coloring group pixel, and the pixel and the composition formed in the low exposure amount are extremely suitable for color filter and solid color display color filter for color display. [Embodiment] [Best Embodiment of the Invention] Coloring Composition The present invention will be described in detail below. - (A) Coloring agent In the present invention, the coloring property of the coloring agent (A) is not particularly limited. The color or material can be appropriately selected depending on the use such as a color filter. The coloring agent can be any one of a pigment, a dye, and a natural pigment. However, since the color filter is heat-resistant, it is preferably an organic pigment or an inorganic pigment. In the above-mentioned organic pigment, for example, a compound classified as a coloring matter in a coloring agent (CI; issued by The Society of Dyers and Colourists) can be exemplified, and specifically, the following coloring material index (CI) can be exemplified. ) numbered compounds. CI Pigment Yellow 12, CI Pigment Yellow 13, CI Pigment Yellow 14, CI Pigment Yellow 17, CI Pigment Yellow 20, CI Pigment Yellow 24, CI Pigment Yellow 31, CI Pigment Yellow 55, CI Pigment Yellow 83, CI Pigment Yellow 93, CI Pigment Yellow 109, CI Pigment Yellow 110, CI Pigment Yellow 138, CI Pigment Yellow 139, CI Pigment Yellow 150, CI Pigment Yellow 153, CI Pigment Yellow 154, CI Pigment Yellow 155, CI Pigment Yellow 166, CI·Pigment Yellow 168 , CI Pigment Yellow 180, CI Pigment Yellow 21 1 ; CI Pigment Orange 5, CI Pigment Orange 13, CI Pigment Orange 14, CI Pigment Orange 24, CI Pigment Orange 34, CI Pigment Orange 36, CI Pigment Orange 38, -6- 201133141 C.I_Fruit Orange 40, CI Pigment Orange 43, CI Pigment Orange 46, CI Pigment Orange 49, CI Pigment Orange 61, CI Pigment Orange 64, CI Pigment Orange 68, CI Pigment Orange 70, CI Pigment Orange 71, CI Pigment orange 72, CI pigment orange 73, CI pigment orange 74; C. I. Pigment red 1, C. I. Pigment red 2, C. I. Pigment red 5, C. I. Pigment red 1 7 , C. I Pigment Red 3 1 , C · I. Pigment Red 3 2, C. I. Pigment Red 4 1 , C . I. Pigment Red 1 2 2, C. I. Pigment Red 1 2 3, C. I. Pigment Red 1 4 4, C. I. Pigment Red 149, CI Pigment Red 166, CI Pigment Red 168, CI Pigment Red 170, C. I. Pigment Red 1 7 1 , C. I. Pigment Red 175, C. I. Pigment Red 1 7 6 , C. I. Pigment Red 1.7, C. I. Pigment Red 178, C. I. Pigment Red 179, C. I. Pigment Red 1800, CI Pigment Red 185, CI Pigment Red 187 , CI Pigment Red 202, CI Pigment Red 2 0 6 , C. I. Pigment Red 2 0 7 , C. I. Pigment Red 2 0 9 , C. I. Pigment Red 2 1 4, CI Pigment Red 220, CI Pigment Red 221, CI Pigment Red 224, CI Pigment Red 2 4 2, C. I. Pigment Red 2 4 3, C. I. Pigment Red 2 5 4, C. I. Pigment Red 2 5 5, CI Pigment Red 262, CI pigment red 264, CI pigment red 272; CI pigment purple 1, CI pigment purple 19, CI pigment purple 23, CI pigment purple 29, CI pigment purple 32, CI pigment purple 36, CI pigment purple 38; (:.1. Pigment Blue 15, (:.1. Pigment Blue 15:3, 0:.1. Pigment Blue 15:4, (:.1. Pigment Blue 15:6, CI Pigment Blue 60, CI Pigment Blue 80; CI Pigment Green) 7. CI Pigment Green 36, CI Pigment Green 58; CI Pigment Brown 23, CI Pigment Brown 25; CI Pigment Black 1, CI Pigment Black 7. 201133141 In the present invention, the 'organic pigments' can be purified by a recrystallization method, a reprecipitation method, a solvent washing method, a sublimation method, a vacuum heating method, or the like. Further, the 'organic pigment is preferably a method of mechanical kneading together with a water-soluble organic solvent which does not substantially dissolve a water-soluble inorganic salt and a water-soluble inorganic salt, that is, a so-called salt mining method. The primary particles are made fine for use. The method of the salt milling method is disclosed, for example, in Japanese Laid-Open Patent Publication No. 08-1791 1 1 . When an organic pigment which refines the primary particles is used, there is a tendency to lower the solvent resistance of the colored layer formed. However, if the colored composition of the present invention is used, such problems can be solved. Further, the above inorganic pigment may, for example, be titanium oxide, barium sulfate, calcium carbonate 'zinc white, lead sulfate, yellow lead, zinc yellow, iron oxide (red iron oxide (III)), cadmium red, ultramarine blue, Prussian blue, chrome oxide green, cobalt green, ambers, titanium black, synthetic iron black, carbon black, and the like. The colorants may be modified to allow the surface of the particles to be used as desired. The resin for modifying the surface of the pigment particles is, for example, a developer resin disclosed in JP-A No. 2001-1081, or a commercially available resin for dispersion of various pigments. In the method of the resin coating of the surface of the carbon black, a method described in, for example, JP-A-H09-71733, JP-A-9-95625, JP-A-9-124969, and the like can be employed. In the present invention, the coloring agent (A) may be used singly or in combination of two or more. -8 - 201133141 When the coloring composition of the present invention is used for the formation of a pixel, it is preferable that the coloring agent (A) is a coloring agent having high color rendering property because of fine color development in the pixel system. Specifically, an organic pigment can be suitably used. On the other hand, in the case where the coloring composition of the present invention is formed in a black matrix, since the light-shielding property is required in the black matrix, it is preferred to use an organic pigment or carbon black as the coloring agent (A). (A) The content of the coloring agent is preferably from 5 to 70% by mass, more preferably from 5 to 70% by mass of the total solid content of the coloring composition, from the viewpoint of forming a pixel excellent in transparency and color purity or a black matrix having excellent light blocking properties. Up to 60% by mass. The solid component is a component other than the solvent described later. In the coloring composition of the present invention, when the content of the coloring agent is 30% by mass or more in the total solid content of the coloring composition, a pixel excellent in solvent resistance can be formed. The coloring agent in the present invention can be used together with a dispersing agent and a dispersing aid as desired. As the above dispersing agent, a suitable dispersing agent such as a cationic type, an anion type or a nonionic type can be used, and a polymer dispersing agent is preferable. Specifically, an acrylic copolymer, a polyurethane, a polyester, a polyethyleneimine, a polyallylamine or the like can be exemplified. Such a dispersing agent can be obtained commercially, and examples thereof include Disperbyk-2000, Disperbyk-2001, B YK-LPN69 19, BYK-LPN2 1 1 16 (according to BYK) of acrylic copolymer; Urethane Disperbyk-161, Disperbyk-162,

Disperbyk-165, Disperbyk-167, Disperbyk-170, D isp er byk -1 8 2 (above, BYK), Solsperse -9 * 201133141 76 5 00 (made by Lubrizo I Co., Ltd.); Solsperse 24000 of polyethyleneimine (Lubriz〇) Co., Ltd.); A jisperp B 8 2 1 of polyester, Ajisper PB822, Ajisper PB880 (manufactured by Ajinomoto Fine Techno Co., Ltd.), and the like. These dispersing agents may be used singly or in combination of two or more. The content of the dispersant is usually 100 parts by mass or less, preferably 1 to 70 parts by mass, more preferably 1 to 50 parts by mass, per 100 parts by mass of the (A) colorant. When the content of the dispersant is too large, the developer property or the like may be impaired. The above-mentioned dispersing aid may, for example, be a pigment derivative, and specifically, a copper phthalocyanine, a diketopyrrolopyrrole or a quinoline yellow sulfonic acid derivative may, for example, be mentioned. - (B) Binder Resin - The (B) binder resin in the present invention is not particularly limited, and is preferably a resin having an acidic functional group such as a carboxyl group, a phenolic hydroxyl group or a sulfonic acid group. In order to enhance the desired effect of the present invention, the acidic functional group and the polymer further having a polymerizable unsaturated group are preferably contained in the total binder resin, preferably 10% by mass or more, and more preferably 30% by mass. the above. The acidic functional group may, for example, be a carboxyl group, a phenolic hydroxyl group or a sulfonic acid group. However, a carboxyl group is preferred from the viewpoint of alkali solubility and storage stability of the obtained colored composition. Further, the above polymerizable unsaturated group may, for example, be a vinyl aryl group, a (meth) acrylonitrile group or an allyl group, but it is preferably a (meth) propylene from the viewpoint of improving a desired effect.醯基. Further, the polymer having an acidic functional group and a polymerizable unsaturated group is preferably one having a polymerizable unsaturated group in its side chain. -10- 201133141 A polymer having an acidic functional group and a polymerizable unsaturated group is not particularly limited in the range of the above-mentioned requirements, for example, (b-1) is in a carboxyl group of a polymer having a polymerizable unsaturated compound, a polymer obtained by reacting a polymerizable unsaturated compound having a cyclic group (hereinafter referred to as a mixture resin (b-1)"); (b-2) a polymerizable unsaturated material having a hydroxyl group and a polymerization having an acidic functional group In the copolymer group of the unsaturated compound, a polymerizable unsaturated compound having an isocyanate group is reacted (hereinafter referred to as "binder resin (b-2)"); (b-3) has a ring In the epoxyethyl group of the polymer of the polymerizable unsaturated compound, a polymerizable unsaturated compound of a carboxyl group is reacted, and further, a polymer obtained by reacting an acid anhydride in the hydroxyl group produced by the reaction (hereinafter referred to as " a binder (b-3)"); (b-4) reacting a carboxypolymerizable unsaturated compound in an epoxy group of an epoxy resin, and further reacting an acid anhydride in a group derived from the reaction The obtained polymer (hereinafter referred to as "bonding" (b-4)"); (b-5) In a copolymer of styrene or a derivative thereof and a maleic anhydride ester, a polymerizable unsaturated compound having a hydroxyl group is reversed to obtain a polymer (hereinafter referred to as " Adhesive resin (b-5)"). The polymer of the polymerizable saturated compound having a carboxyl group used in the production of the binder resin (b-oxime) is not particularly limited as long as it has a carboxyl group, and is obtained by a polymerizable unsaturated compound having a carboxyl group. In the case of a polymerizable unsaturated compound having a carboxyl group, for example, an unsaturated compound of "addition of lactone-based" acrylic acid in addition to (meth)acrylic acid or maleic acid; addition of succinic acid, butylene The diacid satisfies the carboxy oxyethylene "adhesive hydroxy group", the hydroxy resin having the base of the agent, or the non-copolymerization thereof, as exemplified in (A, 酞-11-201133141 acid' or such anhydrides, etc. The dibasic acid or its anhydride is an unsaturated compound of a hydroxyalkyl (meth)acrylate, etc. These may also be used in plural. Among them, (meth)acrylic acid and 2-(methyl)acrylic acid succinate are preferable. Oxyethyl ester, ω-carboxypolycaprolactone mono(meth)acrylate, more preferably (meth)acrylic acid. Polymerization with epoxy ethyl group used in the manufacture of adhesive resin (b-Ι) The unsaturated compound may, for example, be: (meth)acrylic acid propyl acrylate, allyl epoxidized ether 'epoxypropyl-α-ethyl acrylate, crotonyl epoxidized propyl ether, ( Iso)crotonic acid glycidyl ether, Ν-(3,5-dimethyl-4-epoxypropyl An epoxy group-containing unsaturated compound such as benzyl acrylamide, 4-hydroxybutyl (meth) acrylate glycidyl ether, p-vinylbenzyl epoxidized propyl ether or the like; 2,3-epoxy ring An alicyclic epoxy group and a (meth) acrylonitrile group such as a pentyl group, a 3,4-epoxycyclohexyl group, a 7,8-epoxy[tricyclo[5.2.1.0]indol-2-yl] group An unsaturated compound of a polymerizable unsaturated group, etc. A plurality of these may be used. The polymerizable unsaturated compound having a hydroxyl group used for the production of the binder resin (b-2), and the polymerizable property having an acidic functional group The copolymer of the unsaturated compound is not particularly limited as long as it has a hydroxyl group and an acidic functional group, and is obtained by polymerizing a polymerizable unsaturated compound having at least a hydroxyl group and a polymerizable unsaturated compound having an acidic functional group. The vinyl polymerizable unsaturated compound may, for example, be 4-hydroxybutyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, hydroxypropyl (meth)acrylate, or mono(methyl). Glycerin acrylate etc. -12- 201133141 (meth)acrylic acid In addition to the hydroxyalkyl ester, N-methylol acrylamide, allyl alcohol, etc. may be used. Further, in the case of the polymerizable unsaturated compound having an acidic functional group, the above binder resin (b-1) may be mentioned. The polymerizable unsaturated compound having a carboxyl group, etc., may be used in a plurality of kinds. The polymerizable unsaturated compound having an isocyanate group used for the production of the binder resin (b-2) may, for example, be exemplified. Such as 2-(methyl)propenyloxyethyl isocyanate, 2-(2-isocyanate ethoxy)ethyl (meth)acrylate, 1,1-(bispropenyloxymethyl isocyanate) Ethyl ester, etc. A plurality of polymers may be used. The polymer of the epoxy group-containing polymerizable unsaturated compound used in the production of the binder resin (b-3) may be a polymerization having an epoxy group. The material is preferably a poly(meth)acrylate copolymer having an epoxy group, a polystyrene copolymer having an epoxy group, or the like. A poly(meth)acrylate copolymer having an epoxy group is a copolymer of a (meth) acrylate having an epoxy group and another polymerizable unsaturated compound. Examples of the (meth) acrylate having an epoxy group include glycidyl (meth)acrylate, 3,4-epoxybutyl (meth)acrylate, and (meth)acrylic acid (3, 4). - Epoxycyclohexyl) methyl ester, 4-hydroxybutyl (meth) acrylate glycidyl ether, and the like. These can also be used in multiples. Further, examples of the styrene having an epoxy group and a styrene-based copolymer having an epoxy group include o-vinylbenzyl epoxidized propyl ether, m-vinyl benzyl epoxidized propyl ether, and p-vinyl benzyl. Styrene with a glycidyl group of 1,3,2-diepoxypropyloxymethylstyrene, 3,4,5-triepoxypropylmethylstyrene, etc. class. These can also be used in a plurality of types. -13- 201133141 As the polymerizable unsaturated compound having a carboxyl group used in the production of the binder resin (b-3), (meth)acrylic acid, ω-carboxy-polycaprolactone mono(meth)acrylic acid may be exemplified. Ester, 2-(methyl) propylene decyl ethyl acrylate, and the like. These can also be used in multiples. Examples of the acid anhydride used in the production of the binder resin (b-3) include malonic anhydride, maleic anhydride, citraconic anhydride, succinic anhydride, glutaric anhydride, glutaconic anhydride, and itaconic anhydride. A polybasic acid anhydride such as dihydroxyacetic anhydride, decanoic anhydride, cyclohexane-1,2-dicarboxylic anhydride, 4-cyclohexene-1,2-dicarboxylic anhydride, or phthalic anhydride. These can also be used in a plurality of types. Further, a polymer having a carboxyl group-containing polymerizable unsaturated compound used in the production of the binder resin (b-1), a polymerizable unsaturated compound having a hydroxyl group used in the production of the binder resin (b-2), and having A copolymer of a polymerizable unsaturated compound having an acidic functional group and a polymer having an epoxyethyl group-containing polymerizable unsaturated compound used in the production of the binder resin (b-3) can be used without any polymerization property. Other polymerizable unsaturated compounds copolymerizable with the saturated compound are copolymerized. The other polymerizable unsaturated compound may, for example, be an N-position-substituted maleimide such as N-phenylmaleimide or N-cyclohexylmethyleneimine; An aromatic vinyl compound such as styrene, α-methylstyrene, p-hydroxy-α-methylstyrene, vinyl naphthalene or the like; methyl (meth)acrylate 'n-butyl (meth)acrylate, (a) 2-ethylhexyl acrylate, benzyl (meth) acrylate, cyclohexyl (meth) acrylate, isodecyl (meth) acrylate, tricyclo [5.2.1.0'6] decane-8- (meth) acrylate, (meth) propylene-14 - 201133141 dicyclopentenyl acid ester, 4-hydroxyphenyl (meth) acrylate, ethylene oxide modified (meth) acrylate (meth) acrylate such as ester. Further, a polymer of a polymerizable unsaturated compound having an epoxy group used for the production of a polymer 'polymer (b-3) having a carboxyl group-containing polymerizable unsaturated compound used for the production of a polymer (bl) In the above, a polymerizable unsaturated compound having a hydroxyl group such as 2-hydroxyethyl (meth)acrylate or glycerol mono(meth)acrylate may be copolymerized. These can also be used in a plurality of types. The epoxy resin used in the production of the binder resin (b-4) may, for example, be an epoxy obtained by reacting an alcoholic hydroxyl group of a bisphenol A epoxy resin or a bisphenol A epoxy resin with epichlorohydrin. Epoxy resin, bisphenol S type epoxy resin, biphenyl epoxidized propyl ether, phenol obtained by reacting alcoholic hydroxyl group of phenolic bisphenol F type epoxy resin and bisphenol F type epoxy resin with epichlorohydrin A novolac type epoxy resin, a cresol novolac type epoxy resin, a triglycidyl isocyanate, a phenolic methane type epoxy resin, an anthracene epoxy resin, an alicyclic epoxy resin, A cyclopentadiene type epoxy resin or the like. A copolymer type epoxy resin can also be used. The polymerizable unsaturated compound having a carboxyl group and the acid anhydride used in the production of the binder resin (b-4) may be the same as those used in the production of the binder resin (b-3). The copolymer of styrene or a derivative thereof and maleic anhydride used for the production of the binder resin (b-5) may, for example, be styrene, m-methoxystyrene or p-methoxystyrene. Etc.; with maleic anhydride' or maleic acid monomethyl ester 'maleic acid monoethyl ester, maleic acid mono-n-propyl-15- 201133141 ester, cis-butane diacid mono- Copolymerization of isopropyl ester, cis-butyl succinic acid mono-n-butyl succinate, maleic acid mono-isobutyl acrylate, maleic acid mono-tertiary butyl ester, maleic acid mono-lower alkyl ester Things. The polymerizable unsaturated compound having a hydroxyl group used in the production of the binder resin (b-5) may, for example, be a hydroxyalkyl (meth)acrylate, N-hydroxymethylpropenamide or allyl alcohol. In the present invention, the "adhesive resin" may be a polymer having an acidic functional group or a polymerizable unsaturated group, or may be used together with a polymer having an acidic functional group and a polymerizable unsaturated group. Specific examples of such a binder resin include, for example, JP-A-7-140654, JP-A-H09-311444, JP-A-10-31308, JP-A-10-300922, and JP-A The copolymer disclosed in JP-A-N-174224, JP-A-H11-258415, JP-A-2000-56118, JP-A-2002-296778, and JP-A-2004-101728. The acid value of the binder resin in the present invention is preferably from 1 to 200 KOH/mg, more preferably from 20 to 150 KOH/mg, still more preferably from 30 to 150 K〇H/mg. 凝胶 A gel of a binder resin in the present invention. The weight average molecular weight of the converted polystyrene (hereinafter referred to as "Mw") measured by osmometry (GPC, solvent: tetrahydrofuran) is preferably 1,000 to 100,000, more preferably 3, 〇〇〇 to 50. 〇〇〇» In this case, 'M w is too small', the residual film rate of the obtained film is lowered, or the shape, heat resistance, etc. are impaired, and the electrical characteristics are deteriorated. -16-201133141 ~ Aspect 'When the Mw is too large, the resolution is lowered, or the shape of the pattern is impaired', and there is a tendency to dry foreign matter during coating due to the slit nozzle method. Further, the ratio of the Mw of the binder resin in the present invention to the number average molecular weight (hereinafter referred to as ΓΜη) of the converted polystyrene measured by gel permeation chromatography (GPC 'dissolved solvent: tetrahydrofuran) (Mw/Mn) Preferably, it is from 1. 〇 to 5.0, more preferably from 1. 〇 to 3.0. In the present invention, the binder resin can be produced by a conventional method, but it can be disclosed by, for example, Japanese Patent Laid-Open Publication No. 2003-2227-1776, Japanese Patent Laid-Open No. Hei. No. 2006-259680, and International Publication No. 07/029871. The method 'to control its construction or Mw, Mw / Mn. Further, a polymer having the above-mentioned acidic functional group and a polymerizable unsaturated group can be obtained by a conventional method, for example, Japanese Patent Laid-Open No. Hei 5 _i 9 4 6 7 and Japanese Patent Laid-Open No. 5 _ 6丨i 9 6 It is produced by the method disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. In the present invention, the binder resin may be used singly or in combination of two or more. In the present invention, the content of the binder resin is preferably from 10 to 1,000 parts by mass, more preferably from 20 to 500 parts by mass, per 100 parts by mass of the (A) colorant. In the iw shape, when the content of the binder resin is too small, for example, the developability is lowered, or the residue or the surface stain is formed on the substrate of the unexposed portion or the light shielding layer. On the other hand, when the amount is too large, In contrast, since the concentration of the pigment is lowered, it is difficult to achieve a color density which is a purpose of the film. -17-201133141 - (c) Polyfunctional monomer - The (C) polyfunctional monomer in the invention is not particularly limited as long as it is a monomer having two or more polymerizable groups. The polymerizable group may, for example, be an ethylenically unsaturated group, an epoxy group, an oxetanyl group or an N-alkoxymethylamino group. In the present invention, the '(C) polyfunctional monomer is preferably a compound having two or more (meth) acrylonitrile groups or a compound having two or more N-alkyloxymethylamino groups. Specific examples of the compound having two or more (meth)acryl fluorenyl groups described above may be exemplified by an aliphatic polyhydroxy compound and an (meth)acrylic acid ester, and a caprolactone-modified polyfunctional (meth)acrylic acid. An ester, an oxyalkylene-modified polyfunctional (meth) acrylate, a polyfunctional urethane (meth) acrylate obtained by reacting a hydroxyl group-containing (meth) acrylate with a polyfunctional isocyanate, and having a hydroxyl group A polyfunctional (meth) acrylate having a carboxyl group obtained by reacting a (meth) acrylate with an acid anhydride. Here, the aliphatic polyhydroxy compound may, for example, be a divalent aliphatic polyhydroxy compound such as ethylene glycol, propylene glycol, polyethylene glycol or polypropylene glycol; glycerin, trimethylolpropane or neopentyl alcohol; An aliphatic polyhydroxy compound having a trivalent or higher valence of dipentaerythritol. The (meth) acrylate having the above hydroxyl group may, for example, be 2-hydroxyethyl (meth)acrylate, trimethylolpropyl di(meth)acrylate, or neopentaerythritol tri(meth)acrylate. Ester, dipentaerythritol penta(meth)acrylate, glyceryl dimethacrylate, and the like. The polyfunctional isocyanate may, for example, be toluene diisocyanate, hexamethylene diisocyanate, diphenylmethylene diisocyanate or diisoacetyl cyanide -18-201133141 ketone ester. The acid anhydride may, for example, be succinic anhydride, maleic anhydride, glutaric anhydride, itaconic anhydride 'phthalic anhydride, hexahydrophthalic anhydride-like dibasic acid anhydride; pyromellitic anhydride, biphenyl tetraindole Acid dianhydride, tetrabenzoic acid dianhydride like tetrabasic acid dianhydride. Further, the above-mentioned caprolactone-modified functional (meth) acrylate may, for example, be a compound described in paragraphs [〇〇15] to [〇018] of JP-A-11-4495. The above oxyalkylene-modified polyfunctional (meth) acrylate may, for example, be an ethylene oxide and/or propylene oxide-modified di(meth)acrylate of bisphenol A or an iso-cyanuric acid. Ethylene oxide and/or propylene oxide modified tri(meth)acrylate, trimethylolpropane ethylene oxide and/or propylene oxide modified tri(meth)acrylate, neopentyl alcohol Ethylene oxide and/or propylene oxide modified tri(meth)acrylate, neopentyl alcohol ethylene oxide and/or propylene oxide modified tetra(meth)acrylate, dipentaerythritol Ethylene oxide and / or propylene oxide modified penta (meth) acrylate, dipentaerythritol ethylene oxide and / or propylene oxide modified hexa (meth) acrylate. Further, the above-mentioned compound having two or more N-methoxymethylamino groups may, for example, be a compound having a melamine structure or a benzoguanamine structure urea structure. Further, the melamine structure and the benzoguanamine structure refer to the concept of containing melamine, benzoguanamine or the like. Specific examples of the compound having two or more N-alkoxymethylamino groups include, for example, 1^,^>1,>1-hexa(alkoxymethyl)melamine, N,N,N , N-tetrakis (decyloxymethyl) benzoguanamine, ν, Ν, Ν, Ν - tetra (homoyloxymethyl) acetylene urea and the like. 201133141 Among these polyfunctional monomers, a trivalent or higher aliphatic polyhydroxy compound and a (meth)acrylic acid ester, a caprolactone-modified polyfunctional (meth)acrylate, and a polyfunctional amine group are preferable. Formate (meth) acrylate and polyfunctional (meth) acrylate having carboxyl group, N, N, N, N, N, N-hexa(alkoxymethyl) melamine, N, N, N, N-tetrakis(alkoxymethyl)benzoguanamine. Among the trivalent or higher aliphatic polyhydroxy compounds and (meth)acrylic acid esters, especially trimethylolpropyl triacrylate, neopentyl glycol triacrylate, dipentaerythritol pentaacrylate··6 Dipentaerythritol acrylate; and in the polyfunctional (meth) acrylate having a carboxyl group, in particular, a compound obtained by reacting neopentyl glycol triacrylate with succinic anhydride, and dipentaerythritol pentaacrylate The compound obtained by the reaction of succinic anhydride has a high strength of the colored layer and excellent surface smoothness of the colored layer, and is particularly preferable from the viewpoint that the surface of the unexposed portion and the surface of the light-shielding layer are less likely to be stained or left. In the present invention, the (C) polyfunctional monomer may be used singly or in combination of two or more. In the present invention, the content of the (C) polyfunctional monomer is preferably from 5 to 500 parts by mass, particularly preferably from 20 to 300 parts by mass, based on 100 parts by mass of the (B) binder resin. In this case, when the content of the polyfunctional monomer is too small, sufficient curability may not be obtained. On the other hand, when the content of the polyfunctional monomer is too large, 'the alkali developability is provided in the coloring composition of the present invention, #the alkali developability is lowered, the surface of the unexposed portion or the light shielding layer is liable to be surface-stained. The tendency of spots, membrane residues, etc. -20- 201133141 - sesquiterpene oxide (D) - a coloring composition of the present invention, characterized in that the sesquiterpene oxide (D), that is, it contains a compound selected from the group consisting of a sulfonyl group and a polymerizable unsaturated group A cage sesquioxane of at least one of the group consisting of. The conventional sulfonyl group SH) is added to a bivalent unsaturated bond in a free radical or cationic manner, but the inventors first discovered that the sesquioxane structure having stereoregularity is via a mineral group or When the polymerizable unsaturated group is incorporated in the crosslinked structure of the above (C) polyfunctional monomer or the like, the adhesion to the inorganic film or the solvent resistance is extremely excellent. In the present invention, the sesquiterpene oxide (D) includes a completely cage type sesquioxanes as shown in the following formulas (^) to (D4) and also includes the following formulas (D-5) to (D). -6) A part of the cage shown is a commemoration of the incomplete cage-type sesquioxanes.

(D-1)

201133141

(D-3)

(D-4) RS Bu RSi — /1 -° /fiR 〇 j pi / o -〇- ΓΪ RS!— -0-1—SL > / O •°—r -〇〆

OH

:SiR RSl· (D-5)

0Ί si o

-22-201133141 (In the above formula, R is a monovalent organic group independently of each other, but at least two of all R have at least one selected from the group consisting of a sulfonyl group and a polymerizable unsaturated group. a basis). In the above formula, the group having a sulfonyl group is not particularly limited, and is preferably a hydrocarbon group having 1 to 8 carbon atoms having a sulfonyl group, particularly preferably an alkyl group having 1 to 8 carbon atoms having a sulfonyl group. Specific examples thereof include a thiomethyl group, a 2-hydrothioethyl group, a 3-hydrothiopropyl group, a 1,4-dihydrothio-2-butyl group, and a 1,2-dihydro group. Thioethyl, 2-hydrothiomethyl-3-hydrothiopropyl, etc., but particularly preferably 3-hydrothiopropyl. Further, in the above formula, the group having a polymerizable unsaturated group is not particularly limited, and is preferably a vinyl group, a vinyl aryl group, a (meth) acryloxy group, or an allyl group, and particularly preferably (Meth) propylene methoxyalkyl group, and specific examples thereof include 3-(meth) propylene methoxy propyl group, 2-(meth) propylene methoxyethyl group, and (meth) propylene group. Further, in the above formula, the monovalent organic base surface other than the group having a sulfonyl group or the like may, for example, be an alkyl group having 1 to 6 carbon atoms which may have a substituent, and may have a substitution. An aryl group having a carbon number of 6 to 18 or the like. In the present invention, the alkyl group having 1 to 6 carbon atoms is preferably an alkyl group having 1 to 5 carbon atoms, particularly preferably a methyl group, an ethyl group, a n-propyl group, an isopropyl group or a pentyl group. Further, in the above aryl group having 6 to 18 carbon atoms, an aryl group having 6 to 10 carbon atoms is preferable, and a phenyl group is particularly preferable. The substituent of the alkyl group having 1 to 6 carbon atoms may, for example, be an epoxyethyl group, a glycidoxy group, a 3,4-epoxycyclohexyl group, an oxetan-3-yl group, or -23. - 201133141 Oxetane-3-ylmethyloxyl, hydroxyphenylcarbonyloxy, hetero-, alkyl 1 to 6 alkyl propoxy, 3,4-epoxycyclohexyl butane Further, the -3-ylmethyloxy group may be substituted with an alkyl group at the 3-position of the above oxocyclic T-oxy group. Further, the above carbon number 6 to 18 is a halogen atom, a hydroxyl group or a cyanosesquioxane (D), and is produced by hydrolysis (hereinafter referred to as "the compound (dl). RSiX3 (in the above formula) R represents a J group, and X represents a hydrolyzable group. In the above formula X, for example, an alkoxy group, a cycloalkane, a hydrogen atom or the like can be exemplified. Among them, a cycloalkoxy group, an aryloxy group, an anthracene oxygen group Propyloxy, isopropoxy, n-butyl, phenoxy, ethoxylated, 2,3-cyclothiopropyloxy, carboxy, montanoic acid, amine, ureido, etc. Non-substituted, or having an epoxyethyl 'epoxy' oxetan-3-yl group or having an oxaheterocyclyl group. ~Alk-3-yl or oxetane-3-ylmethylmethyl Examples of the substituent of the aryl group having a carbon number of 1, for example, an ethyl group or a n-propyl group, and a nitro group or an alkyl group having 1 to 6 carbon atoms, etc., may be obtained by a compound represented by the following formula: The decane compound is present in the basic catalyst (dl). The sulfonyl group or the polymerizable unsaturated group is not particularly limited as long as it is a hydrolyzable group. The oxy group, the aryloxy group, the decyloxy group, and the halogen are reactive. Point, Best alkoxy group, group 're good methoxy, ethoxy, n-butyl, isobutyl' three-butyl, cyclohexyl oxygen to be good as a methoxy group, an ethoxy. Further, X may be all the same groups or two or more different groups in the above formula. Specific examples of the compound (d 1 ) include 3-hydrothiopropyltrimethoxydecane, 3-hydrothiopropyltriethoxydecane, and 3-hydrothiopropyltripropoxy group. Decane, 3-hydrothiopropyltributoxydecane, 1,4-dihydrothio-2-(trimethoxydecyl)butane, 1,4-dihydrothio-2-(triethyl) Oxidylalkyl)butane, 1,4-dihydrothio-2-(tripropoxydecylalkyl)butane, 1,4-dihydrothio-2-(tributyloxydecyl)butyl Alkane, 2·hydrothiomethyl-3-hydrothiopropyltritrimethoxydecane, 2-hydrothiomethyl-3-hydrothiopropyltriethoxydecane, 2-hydrogenthio Methyl-3-hydrothiopropyltripropoxydecane, 2-hydrothiomethyl-3-hydrothiopropyltributoxydecane, 1,2-dihydrothioethyltrimethoxy Decane, 1,2-dihydrothioethyltritriethoxydecane, 1,2-dihydrothioethyltripropoxydecane, 1,2-dihydrothioethyltributoxydecane , ethylene trimethoxy decane, ethylene triethoxy decane '(methyl) propylene methoxymethyl trimethoxy decane, (meth) propylene methoxymethyl triethoxy hydrazine Alkane, 2-(methyl)propenyloxyethyltrimethoxydecane, 2-(methyl)propenyloxyethyltriethoxydecane, 3-(methyl)propenyloxypropyltrimethyl Oxaloxane, 3-(meth)acryloxypropyltriethoxydecane, p-vinylphenyltrimethoxydecane, p-vinylphenyltriethoxydecane, and the like. The sesquioxane (D) may be a hydrolysis condensate of the above compound (dl), or may be a hydrolysis condensation of the above compound (dl) with a decane compound (hereinafter referred to as "compound (d2)") represented by the following formula: R1 SiXS (d2) -25- 201133141 (In the above formula, R1 represents an aryl group having a carbon number of 1 to 6 which may have a substituent or may have a substituent of 6 to 1.8, and X 1 represents hydrolysis. f. Suitable specific examples of the compound (d2) include methyl trimethyl decane, methyl triethoxy decane, ethyl trimethoxy decane, ethyl oxy decane, phenyl trimethoxy decane, and phenyl tri Ethoxy decane, oxypropoxypropyl trimethoxy decane, 3-glycidoxypropyl triethane decane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxy decane, 2- (3,4-Cyclohexyl)ethyltriethoxydecane, 3-(3'-ethyloxetane-3propyltrimethoxydecane, 3-(3,-ethyloxetane) Alkyl-3'-yl)propyloxydecane, (3-ethyloxetan-3-ylmethyloxy)propyltrimethylnonane, (3-ethyloxetan-3-yl) Methyloxy)propyltriethoxy, etc. In the alkane (D), the constituent unit content derived from the compound (dl) is usually from 5 to 100% by weight, preferably 1 〇, based on the repeating unit derived from the compounds (dl) and (d2). The weight of the inorganic film is formed by setting the single content ratio derived from the compound (d 1 ) to the above range by setting the weight to 1 〇〇 to 20% by weight. A coloring layer having excellent properties and electrical properties. A method for producing sesquiterpene oxide (D) from a compound (d 1 ) or the like can be disclosed in JP-A-11-29640 and JP-A No. 4-143449. For reference, the Mw of sesquioxane (D), 'usually 300 to 50,000, is more than 500 to 300,000. When Mw is too small, it will damage the desired effect of the present invention. 3-epoxy epoxy,-yl) triethoxy decane, the best position, the best resistance to the body is -26-201133141 虞, on the other hand, when it is too large, There is a problem that the applicability or the dispersibility of the colorant is deteriorated. In the present invention, the content of the sesquioxane (D) is preferably from 1 to 50 parts by mass, more preferably from 2 to 30 parts by mass, per 100 parts by mass of the (c) polyfunctional monomer. In this case, when the content of the sesquioxane (D) is too small, the desired effect of the present invention may be impaired, and if it is too large, the miscibility with other components may be lowered or the alkali developability may be lowered. Moreover, there is a tendency that surface stains, film residues, and the like on the substrate of the unexposed portion or on the light shielding layer are likely to occur. - (E) Photopolymerization Initiator - The colored composition of the present invention can provide a radiation-sensitive linearity to the colored composition by including a photopolymerization initiator. The term "radiation" as used herein refers to visible light, ultraviolet light, far ultraviolet light, electron beam, X-ray, and the like. In the present invention, the (E) photopolymerization initiator 'is exposed by radiation such as visible light, ultraviolet rays, far ultraviolet rays, electron beams, X-rays, etc., and can start the above (C) polyfunctional monomer and, as the case may be, A compound obtained by polymerization of a monofunctional monomer to give an active species and a compound produced by the active species. Examples of such a photopolymerization initiator include an acetophenone-based compound, a biimidazole-based compound, a triple-trapped compound, a ruthenium-based fluorene-based compound, a key-salt compound, a benzoin-based compound, and a benzophenone-based compound. A ketone-based compound, a polynuclear oxime-based compound, an anthranone-based compound, a disazo-based compound, or a quinone sulfonate-based compound. -27- 201133141 In the present invention, the photopolymerization initiator may be used singly or in combination of two or more. In terms of a photopolymerization initiator, at least one selected from the group consisting of a thioxanthone-based compound, an acetophenone-based compound, a biimidazole-based compound, a triple-trapped compound, and a ruthenium-based fluorene-based compound is preferable. In the all-photopolymerization initiator, the 0-fluorenyl-based compound is preferably contained in an amount of 50% by mass or more, and more preferably at most 75% by mass. The above-mentioned fluorene-based fluorene-based compound is not particularly limited as long as it has a fluorenyl fluorene structure (> C = N-0-C0-), and for example, International Publication No. 2002/100903 A compound described in the offer, International Publication No. 2006/018973, International Publication No. 2008/078678, and the like. Specific examples of the 0-fluorenyl fluorene compound may, for example, i,2-octanedione, 1-[4.(phenylthio)phenyl]-, 2-(indolyl-benzoguanidinyl), and B. Ketone, 1-[9-ethyl-6-.(2-methylbenzhydryl)-9^oxazol-3-yl]-, 1-(anthracene-ethenyl), ethyl ketone, 1 -[ 9 -ethyl-6-(2-methyl-4-tetrahydrofuranylmethoxybenzylidene)·9Η-oxazol-3-yl]-,l-(〇-ethenylhydrazine), Ethyl ketone, ΐ-[9·ethyl-6-{2-methyl-4-(2,2-dimethyl-1,3-dioxolanyl)methoxybenzylidene}- 91oxazol-3-yl]-, l-(〇-ethinylhydrazine). In the present invention, in the case of the fluorene-fluorenyl compound, a compound having a carbazole structure is preferred because it can improve the desired effect. In the present invention, the '0-fluorenyl fluorene-based compound may be used singly or in combination of two or more. Further, specific examples of the above thioxanthone-based compound include thioxanthone, 2-chlorothioxanthone, 2-methylthioxanthone, 2-isopropylthioxanthone, and 4-isopropyl-28. - 201133141 thioxanthone, 2,4-dichlorothioxanthone, 2,4-dimethylthioxanthone, 2,4·diethylthioxanthone, 2,4-diisopropylthioxanthone Wait. Further, specific examples of the above-mentioned acetophenone-based compound may, for example, be 2-methyl-1-[4-(methylthio)phenyl]-2-misopropanone, 2-phenyl-2- Dimethylamino-1-(4-carbolinephenyl)butan-1-one, 2-(4-methylphenyl)-2·(dimethylamino)-1-(4-flavor Phenylphenyl)butan-1-one, 1-hydroxy-cyclohexyl phenyl ketone, and the like. Further, specific examples of the above biimidazole-based compound include 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole. , 2,2,-bis(2,4-dichlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, 2,2'-bis (2,4 , 6-trichlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole, and the like. Further, in the case where a biimidazole-based compound is used as a photopolymerization initiator, it is preferable from the viewpoint of improving sensitivity by using a hydrogen donor. The term "hydrogen donor" as used herein means a compound which is supplied with a hydrogen atom with respect to a radical generated from a biimidazole compound by exposure. The hydrogen donor may, for example, be a thiol-based hydrogen donor such as 2-hydrothiobenzothiazole or 2-hydrothiobenzoxazole or a 4,4'-bis(dimethylamino group). An amine-based hydrogen donor such as benzophenone or 4,4'-bis(diethylamino)benzophenone. In the present invention, the hydrogen donor may be used singly or in combination of two or more types. However, it is also possible to use one or more thiol-based hydrogen donors and one or more amine-based hydrogen donors. The viewpoint is better. Further, specific examples of the above-described triple well-based compound may be exemplified by 2,4,6-parade(trichloromethyl)-s-tripper, 2-methyl-4,6-bis(trichloromethyl). -s-Triple, -29- 201133141 2-[2-(5-Methylfuran-2-yl)exylethyl]ο-bis(trichloromethyl)_s three tillage 2[2-(furan-2 -Based)Ethyl]_夂6 bis(trichloromethyl)_s_tri-trap, 2-[2-(4-~ethylamino-2-phenylphenyl)ethyl)_4,6 _Bis(trichloromethyl)-s-diindole, 2_[2-(3,4-dimethoxyphenyl)extended ethyl]_4,6-bis(trichloromethyl)-s-triterpene , 2-(4-methoxyphenyl)·4,6•bis(trichloromethyl)tride, 2-(4-ethoxybenzene ethylene-4,6-bis(trichloromethylbu s a triterpene compound having a halomethyl group such as a tri-trap, 2(4·n-butoxyphenyl)-4,6-bis(indolylmethyl)s_triterpene or the like. In the present invention, acetophenone is used. In the case of a photopolymerization initiator other than a biimidazole compound such as a compound, a sensitizer may be used. For such a sensitizer, for example, 4,4,-bis(dimethylamino)benzophenone may be mentioned. , 4,4,_bis(diethylamino)-benzophenone, 4.-ethyl Ethyl benzene, [: methylaminopropenylbenzene, 4-dimethylaminobenzoic acid ethyl acetate, 4-dimethylaminobenzoic acid h ethylhexyl ester, 2,5.·double (4 _monoethylaminobenzylidene)cyclohexanone, 7-diethylfeyl-3-(4-ethylethyl benzhydryl) coumarin, 4 (diethylamino) In the present invention, the content of the photopolymerization initiator is preferably from 0.01 to 12 parts by mass, particularly preferably from 1 to 1 part by mass, per part by mass of the (C) polyfunctional monomer. In this case, when the content of the photopolymerization initiator is too small, the curing due to exposure may be insufficient. On the other hand, when the amount is too large, the colored layer formed tends to fall off from the substrate during development. 30-201133141 - (F) Thermal polymerization initiator - In the present invention, by containing (F) a thermal polymerization initiator in the colored composition, adhesion between the colored layer and the inorganic film or solvent resistance can be improved. The polymerization initiator may, for example, be an azo compound, an organic peroxide or hydrogen peroxide. Among these, an azo compound is preferred. 2,2 '-azobisisobutyronitrile, 2,2'-azobis(2-methylbutyronitrile), 1,1'-azobis(cyclohexene-babonitrile) ^〇11^1^16)), 2,2'-azobis(2,4-dimethylvaleronitrile), 1_[(1_amino-1-methylethyl)azo]carbamamine (2-(Aminomethylmercaptoazo)isobutylene), 2,2_azobis{2-methyl-N-[l,l-bis(hydroxymethyl)-2-hydroxyethyl]propyl Amine}, I2, azobis[N _(2-propenyl I.2-methylpropionamide), 2), γ- and fine [N-(2-propenyl)-2-ethylpropionamidine Amine], 2,2'-azobis[N_butyl]巻_2_midylpropionamide], 2,2'-azobis(N-cyclohexyl-2-methylpropionamide, ) 2,2 - even

Nitrogen bis(dimethyl- 2·.methylpropionamide), 2,2'-azopropionate, 2,2,-azobis (2,4,4-trimethyl is 2,2 '-Azobisisobutyronitrile, 2,2'-even In the present invention, 100 parts by mass of the monomer of the thermal polymerization initiator is preferably 0.1 to parts by mass. - Additives - Steps include other colors of the present invention The composition ' can be added as needed to the additive. -3 1- 201133141 For the other additives mentioned above, there are agents such as glass and alumina; and polymers such as polyvinyl alcohol and poly(fluoroalkyl acrylate). It is a surfactant such as a surfactant, a cationic surfactant or an anionic surfactant; ethylene trimethoxy decane, ethylene trioxane, ethylene ginseng (2-methoxyethoxy) decane, n-(2- Amino Z-aminopropylmethyldimethoxydecane, N-(2-aminoethyl)-3-amine trimethoxydecane, 3-aminopropyltriethoxydecane, 3-epoxy Propyltrimethoxydecane, 3-glycidoxypropylmethyldimethane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxydecane, 3-chloropropadimethoxy sand , 3_chloropropyl trimethoxy sand yard , promoters such as 3-methylpropylpropyltrimethoxydecane and 3-hydrothiopropyltrimethoxydecane; 2,2-thiobis(4-methyl-6-tertiary butylphenol), 2 , an anti-oxidant such as 6-di-triterpene; an ultraviolet absorber of 2-(3-tributyl-5-methyl-2-hydroxybenzene 3 benzotriazole or alkoxybenzophenone; Anti-agglomerating agent such as polyacrylic acid; malonic acid, adipic acid, itaconic acid, citraconic acid, diacid, mesaconic acid, 2-aminoethanol, 3-amino-1-propanol, 5-amino alcohol , a residue improving agent such as 3-amino-1,2-propanediol, 2-amino-1,3-propanediol, 4-amine-butanediol or the like; succinic acid mono[2-(methyl)propene 醯g ester, A developability improving agent such as citric acid mono [2-(methyl) propylene oxy oxy] ester, ω-carboxy poly(mono) (meth) acrylate, etc. - Solvent _ The coloring composition of the present invention is as described above ( Α) to (D) as a component, the above-mentioned additive component may be contained as needed, but usually a solvent and prepared as a liquid component. The hydrazine complex; the phyllo-ether ethoxy group j)-3 Propyl propyloxyoxydecylmethyl oxime oxime oxime butyl I) - Sodium 5-chlorocarboxylate anti-butenyl-1-pentyl-1,2-tetraethyl]caprolactone is required to be formulated -32- 201133141 This solvent is a composition that is sensitive to radiation (A) The component (D) or the component of the additive may be dispersed or dissolved, and may be appropriately selected as long as it does not react with the component and has a moderate volatility. For the solvent, for example, Alcohol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono-n-propyl ether, ethylene glycol mono-n-butyl ether, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol mono- N-propyl ether, diethylene glycol mono-n-butyl ether, triethylene glycol monomethyl ether, triethylene glycol monoethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol mono-n-propyl ether, propylene glycol mono-n-butyl (poly)alkylene glycol monoalkane such as ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol mono-n-propyl ether 'dipropylene glycol mono-n-butyl ether, tripropylene glycol monomethyl ether, tripropylene glycol monoethyl ether Ethers; ethylene glycol monomethyl ether acetate, ethylene glycol monoethyl ether acetate, diethylene glycol monomethyl ether acetate, two Ethylene glycol monoethyl ether acetate, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, 3-methoxybutyl acetate, 3-methyl-3-methoxybutyl acetate, etc. An alkylene glycol monoalkyl ether acetate; diethylene glycol dimethyl ether, diethylene glycol methyl ether, diethylene glycol diethyl ether, tetrahydrofuran and other ethers; methyl ethyl ketone, cyclohexanone, 2-heptanone , ketones such as 3-heptanone; diacetate such as propylene glycol diacetate, 1,3-butylene glycol diacetate, 1,6-hexane glycol diacetate; methyl lactate, lactate B Ethyl lactate such as ester; -33- 201133141 2-hydroxy-2-methylpropanoate, methyl 3-methoxypropionate, ethyl 3-methoxypropionate, 3-ethoxypropane Methyl ester, ethyl 3-ethoxypropionate, ethyl ethoxyacetate, ethyl hydroxyacetate, methyl 2-hydroxy-3-methylbutanoate, 3-methyl-3-methyl propionate Oxybutyl butyl ester, ethyl acetate, n-propyl acetate, isopropyl acetate, n-butyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate, n-butyl propionate, ethyl butyrate, N-propyl butyrate, isopropyl butyrate, butyric acid Other esters such as butyl vinegar, methyl pyruvate, ethyl acetonate, propyl acetonate, ethyl acetate, ethyl acetate, ethyl 2-oxobutanoate, etc.; toluene, xylene, etc. Aromatic hydrocarbons; decylamines or indoleamines such as N,N-dimethylformamide, N,N-dimethylacetamide, hydrazine methylpyrrolidone, and the like. Among these solvents, propylene glycol monomethyl ether, ethylene glycol monomethyl ether acetate, propylene glycol monomethyl ether acetate, and propylene glycol monoethyl ether acetate are preferred from the viewpoints of solubility, pigment dispersibility, coating properties and the like. , 3-methoxybutyl vinegar, diethylene glycol dimethyl ether, diethylene glycol methyl ether, cyclohexanone, 2-heptanone, 3-heptanone, diacetate 1,3 -butylene glycolate , barium diacetate, 6-hexanediol vinegar, ethyl lactate, ethyl 3-methoxypropionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, propionic acid 3_ Methyl-3-methoxybutyl ester, n-butyl acetate, isobutyl acetate, n-amyl formate, isoamyl acetate, n-butyl propionate, ethyl butyrate, isopropyl butyrate, butyric acid N-butyl ester, ethyl pyruvate, and the like. These solvents may be used singly or in combination of two or more. -34- 201133141 Further, together with the solvent, benzyl ether, di-n-hexyl ether, acetone acetone 'isophorone, caproic acid, caprylic acid, 1-octanol, 1-nonanol, benzyl alcohol, High boiling point of acetic acid section ', ethyl benzoate' diethyl oxalate, maleic acid diacetate, γ-butyrolactone, ethylene carbonate, propylene carbonate, ethylene glycol monophenyl ketone acetate Solvent. These scent boiling solvents may be used singly or in combination of two or more. The content of the solvent is not particularly limited, and the total concentration of each component of the solvent in which the composition is removed is usually 5 to 50% by weight from the viewpoints of coatability and stability of the obtained radiation sensitive composition. It is preferably from 1 to 40% by weight. Color filter The color filter of the present invention has a coloring layer formed using the coloring composition of the present invention. In the method of manufacturing a color filter, the first method can be exemplified. First, on the surface of the substrate, a light shielding layer (black matrix) can be formed as needed to divide the portion where the pixels are formed. Next, on the substrate, for example, a liquid composition of the color-sensing radiation composition of the present invention in which a red coloring agent is dispersed is applied, and then pre-baked to evaporate the solvent to form a coating film. Next, the coating film was exposed to light through a mask, and then developed using an alkali developing solution to dissolve and remove the unexposed portion of the coating film. Thereafter, the pixel array is formed by post-baking, which causes the red pixel patterns to be arranged in a predetermined arrangement. -35- 201133141 Next, the liquid composition of each coloring radiation-releasing composition in which a green or blue coloring agent is dispersed is used in the same manner as described above for coating, prebaking, and exposure of each liquid composition. After the baking, the green pixel array and the blue pixel array are sequentially formed on the same substrate. Thereby, a color filter in which the pixel arrays of the three primary colors of red, green, and blue are arranged on the substrate can be obtained. However, in the present invention, the order in which the pixels of the respective colors are formed is not limited to the above. Further, the black matrix is formed by forming a desired pattern by photolithography using a metal thin film such as chromium which is formed by sputtering or vapor deposition, but a coloring feeling in which a black coloring agent is dispersed can be used. The liquid composition of the radiation linear composition is formed in the same manner as in the case of forming the above-described pixels. The substrate to be used in forming the color filter may, for example, be glass, ruthenium, polycarbonate, polyester, aromatic polyamide, polyamidamine, polyimine or the like. Further, in the above-mentioned substrates, a suitable pretreatment such as a drug treatment such as a decane coupling agent, a plasma treatment, ion plating, sputtering, a gas reaction method, or vacuum vapor deposition may be carried out in advance. When the liquid composition of the radiation sensitive composition is applied to a substrate, a suitable coating method such as a spray method, a roll coating method, a spin coating method (spin coating method), a slit die coating method, or a bar coating method may be employed. Particularly preferred is a spin coating method or a slit mold coating method. The pre-baking is usually carried out by combining dry-drying under reduced pressure and drying by heating. Depressurization is usually carried out until it reaches 50 to 200 Pass. Further, the condition of heating and drying is usually carried out at 70 to 110 ° C for about 1 to 10 minutes. -36- 201133141 The coating thickness, the film thickness after drying, is usually 0.1 to 10 μm, preferably 0.2 to 8.0 μm, and particularly preferably 0.2 to 6.0 μm. The light source of the radiation used in forming the pixel and/or the black matrix may, for example, be a xenon lamp, a halogen lamp, a tungsten lamp, a high pressure mercury lamp, an ultrahigh pressure mercury lamp, a metal halide lamp, a medium pressure mercury lamp, or a low pressure mercury lamp. Such as a light source or a argon ion laser, a YAG laser, a XeCl excimer laser, a nitrogen laser, etc., but preferably a radiation having a wavelength in the range of 190 to 45 Onm. The amount of exposure of the radiation is preferably from 10 to 10, OOO J/m 2 . The coloring layer formed of the color-sensing radiation composition of the present invention has sufficient solvent resistance even if it is less than 600 J/m2. Further, as the alkali developer, for example, sodium carbonate, sodium hydroxide, potassium hydroxide, tetramethylammonium hydroxide, choline or 1,8-diazabicyclo-[5.4.0]-7- is preferred. An aqueous solution of undecene, I,5-diazabicyclo-[4·3·〇]-5-decene. In the alkali developing solution, a water-soluble organic solvent such as methanol or ethanol or a surfactant may be added in an appropriate amount. Further, after alkali development, it is usually washed with water. In the development processing method, a rinsing development method, a spray development method, a immersion development method, a pud die development method, or the like can be applied. The developing conditions are preferably at room temperature, 5 to 300 seconds. Post-baking conditions are usually between 180 and 280 ° C for about 1 to 60 minutes. The film thickness of the pixel thus formed is usually 〇 5 to 5.0 μm, preferably 1.0 to 3 · Ομηη. -37-201133141 Further, in the second method of producing a color filter, it is known by an inkjet method as disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. The method of each color pixel. In this method, first, a partition wall having a light blocking function is formed on the surface of the substrate. Next, in the formed partition, the liquid composition of the colored composition of the present invention in which the red coloring agent is dispersed is discharged by, for example, an ink jet device, and then prebaked to evaporate the solvent. Then, the coating film can be exposed as needed, and then cured by post-baking to form a red pixel pattern. Next, using the liquid composition of each of the colored compositions in which the green or blue coloring agent is dispersed, the green pixel pattern and the blue pixel pattern are sequentially formed on the same substrate in the same manner as described above. Thereby, a color filter in which pixel patterns of three primary colors of red, green, and blue are disposed on the substrate can be obtained. However, in the present invention, the order in which the pixels of the respective colors are formed is not limited to the above. Further, the partition wall has a function of not only a light-shielding function but also a coloring composition of each color discharged in the division so as not to be mixed, so that the film thickness is thicker than that of the black matrix used in the first method. Therefore, the partition walls are usually formed using a black radiation-sensitive linear composition. The method or condition for pre-baking or post-baking of the substrate or the source of radiation used in forming the color filter is the same as that of the first method described above. The film thickness of the pixel formed by the ink jet method is as high as the height of the partition walls. -38- 201133141 On the color filter thus obtained, a protective film can be formed as needed, and a transparent conductive film is formed by sputtering. The transparent conductive film may, for example, be a NES A film composed of tin oxide (registered trademark of PPG, USA), an ITO film composed of indium oxide-tin oxide, or an IZO film composed of indium oxide-zinc oxide. Further, the protective film may, for example, be an organic film formed of a thermosetting resin composition, an inorganic film such as a SiNx film or an SiOx film. The color filter formed by using the colored composition of the present invention is excellent in adhesion to a transparent conductive film or an inorganic film such as a SiNx film or an SiOx film. The color filter of the present invention is extremely useful in color liquid crystal display elements, color cathode ray elements, color sensors, organic EL display elements, electronic paper, and the like. Color liquid crystal display element The color liquid crystal display element of the present invention is provided with the color filter of the present invention. The color liquid crystal display element of the present invention is suitably constructed. For example, the structure of the color filter may be formed on a substrate different from the substrate on which the thin film transistor (TFT) is disposed, and the substrate for driving may be opposed to the substrate on which the color filter is formed via the liquid crystal layer. In addition, the structure may be such that a substrate on which a color filter is formed on the surface of a driving substrate on which a thin film transistor (TFT) is disposed via a liquid crystal layer and a substrate having a transparent electrode are opposed to each other. . The latter structure allows the aperture ratio to be particularly improved, and has the advantage of obtaining a bright and high-definition liquid crystal display element. -39- 201133141 The color liquid crystal display device of the present invention has excellent long-term reliability. [Embodiment] The present invention will be further described in detail by way of examples. However, it is not limited by the following embodiments. Preparation of Colorant Dispersion Preparation Example 1 As a coloring agent of (A), 15.0 parts by mass of a mixture of pigment green 58/<: 1 50 = 60/40 (mass ratio) was used as BYK-LPN 21116. 11.2 parts by mass (manufactured by BYK Co., Ltd.), propylene glycol monomethyl ether acetate as a solvent, 73.8 bead mill, mixed and dispersed for 12 hours to prepare a colorant dispersion preparation Example 2 used as (A) CI pigment green 36/C. 1 50 = 60/40 (mass ratio) mixture of coloring agent 15.0 parts by mass, 11.2 parts by mass of BYK-LPN21116 (manufactured by BYK) (solid mass%), propylene glycol monomethyl as solvent Ether acetate 7.3 beads were mixed and dispersed for 12 hours to prepare a colorant dispersion preparation Example 3 CI color red 242/C 177/CI pigment yellow 1 3 9 = (A) colorant was used. 22/72/6 (mass ratio) mixture 15,0 as a dispersing agent Solsperse 76500 (Lubrizol AG parts (converted solid content), as solvent propylene glycol monomethyl ether glycol monoethyl ether = 8 0/20 (mass ratio The mixture is subjected to beading by a bead mill. The present invention and I. 4 0 'volume, to (Α-1). I. The concentration of pigment yellow dispersant is 40: parts, liquid (Α-2). I. Pigment red mass parts, tanning) 4.0 quality B Acid ester/acrylic mixture/dispersion-40-201133141 1 2 hours, the colorant dispersion liquid (A-3) is prepared so that the solid content concentration becomes 19 mass%. CI color blue 15 which is (A) coloring agent is used. :4/CI Pigment Violet 2 3 = 8 5 / 1 5 (mass ratio) mixture 1 2 . 〇 mass part of BYK-LPN21116 (BYK: manufactured by the company) as a dispersing agent 11.2 parts by mass (solid content concentration: 40% by mass) The propylene glycol monomethyl ether acetate as a solvent, 76.8 parts by mass, was mixed and dispersed by a bead mill for 12 hours to prepare a colorant dispersion (A - 4). Synthesis of the binder resin Synthesis Example 1 In the flask of the blender, 44 parts by mass of ethylene benzyl glycidyl ether, 40 parts by mass of N-phenyl maleimide, and 16 parts by mass of benzyl methacrylate were dissolved in propylene glycol monomethyl ether acetate. 300 parts by mass, further, 8 parts by mass of 2,2'-azobisisobutyronitrile and 8 parts by mass of α-methylstyrene dimer, substituted with nitrogen Thereafter, while slowly stirring, the surface was subjected to nitrogen foaming while the reaction solution was heated to 80 ° C. The temperature was maintained for 5 hours. Next, the methacrylic acid 17 mass was added to the reaction solution. The mixture was reacted with 0.5 parts by mass of p-methoxyphenol and 4.4 parts by mass of tetrabutylammonium bromide at a temperature of 120 ° C for 9 hours. Further, after adding 1 8 · 5 parts by mass of succinic anhydride to carry out a reaction at a temperature of 1 Torr for 6 hours, the temperature of the reaction solution was maintained at 85 ° C for 2 times, and was concentrated by decompression under reduced pressure. A binder resin solution (solid content concentration = 3 3 · 0 mass%) was obtained. The resulting binder resin, Mw = 7,800, Mn = 5,000. This binder resin solution was made into "adhesive resin solution (B-1)". -4 1-201133141 Synthesis Example 2 3 parts by mass of 2,2'-azobisisobutyronitrile and 200 parts by mass of propylene glycol monomethyl ether acetate were placed in a flask equipped with a cooling tube and a stirrer, followed by loading 15 parts by mass of methacrylic acid, 30 parts by mass of N-phenyl maleimide, 35 parts by mass of benzyl methacrylate, 20 parts by mass of styrene, and α-methylstyrene dimer (chain transfer) In the amount of 5 parts by mass, after the substitution with nitrogen, the reaction solution was heated to 80 ° C while stirring slowly, and the temperature was maintained, and polymerization was carried out for 3 hours. Thereafter, the reaction solution was heated to 1 〇〇 ° C, and 5 parts by mass of 2,2'-azobisisobutyronitrile was added thereto, and further polymerization was continued for 1 hour to obtain a binder resin solution (solid content concentration). = 3 2.5 wt%). The resulting binder resin, Mw = 1 2,000, Mn = 5,8 00. This binder resin solution was made into "adhesive resin solution (B-2)". Synthetic Synthesis Example 3 of sesquioxane (D) In a three-necked flask, 27.1 parts by mass of propylene glycol monomethyl ether acetate and 23.2 parts by mass of 3-hydrothiopropyltrimethoxydecane were placed in a nitrogen atmosphere. While stirring, warm up to 60 °C. To the solution, 9.6 parts by mass of a 0.2% by mass aqueous solution of malonic acid was added, and the reaction was carried out at 60 ° C for 2 hours. Thereafter, water and methanol were distilled off under reduced pressure, and propylene glycol monomethyl ether acetate was added to the obtained product so that the total amount became 75 parts by mass. Next, a solution of 4.5 parts by mass of triethylamine and 70.5 parts by mass of propylene glycol monomethyl ether acetate was mixed, and the mixture was dropped over 1 hour using a dropping funnel. Further, the reaction was carried out at 60 ° C for 2 hours, and water and triethylamine were distilled off under reduced pressure to obtain a half-sand mortar having a transalkyl group of -42-201133141. The obtained sesquifers were measured by GPC, and IJ Mw = 5,200 and Mn = 2,500. Further, the sesquiterpene oxide obtained by liquid chromatography mass spectrometry (L C - M S ) was confirmed to contain a cage type sesquiterpene oxide. This cage type sesquiterpene alkane was made into "sesquioxane (D-i)". Synthesis Example 4 According to the paragraph [〇〇30] of JP-A-2004-143449, a compound containing the 3-methylpropenyloxypropyl group of the above formula (ΟΙ) is obtained, and the above formula (D- 2) a compound wherein R is a 3-methylpropenyloxypropyl group, a compound of the above formula (D-3) wherein R is a 3-methylpropenyloxypropyl group, and R in the above formula (D-5) A mixture of a compound of 3-methylpropenyloxypropyl group and a cage sesquiterpoxide of a compound of the above formula (D-6) wherein R is a 3-methylpropenyloxypropyl group. This cage type sesquiterpene alkane was made into "sesquioxane (D-2)". Synthesis Example 5 In a three-necked flask, 27.1 parts by mass of propylene glycol monomethyl ether, argonthiopropyltrimethoxydecane 12-6 parts by mass, and 3-methylpropenyloxypropyl group were placed in a three-necked flask under a nitrogen atmosphere. 5.3 parts by mass of trimethoxydecane, while stirring, the surface was heated to 50 °C. To the solution, 5·8 parts by mass of a 0.2% by mass aqueous solution of oxalic acid was added, and the reaction was carried out at 50 ° C for 1 hour. Thereafter, water 'methanol was distilled off under reduced pressure, and propylene glycol monomethyl ether was added to the obtained product so that the total amount became 90 parts by mass. Next, while stirring the solution, the mixture was heated to 70 ° C, and 4,7 parts by mass of a 25 mass% aqueous solution of tetramethylammonium hydroxide, 2.3 parts by mass of pure water, and 6.3 parts by mass of propylene glycol monomethyl ether were added. The solution of 43-201133141 was reacted at 70 ° C for 3 hours. The obtained product was cooled under the following conditions, and the mass of the maleic acid was added while stirring. /. Propylene glycol monomethyl ether solution l4g. Then, 'butyl acetate was added, and the mixture was washed with water in a separatory funnel three times. After dehydration using a desiccant, water and butyl acetate were distilled off under reduced pressure to obtain a sulfopropyl group and a methacryloxy group. The base is half-sand. The sesquifers were obtained by GPC, and the results were mw = 2, 15 〇, Mn = 1, 7 50. Further, it was confirmed that the sesquiterpene oxide obtained by liquid chromatography mass spectrometry (lc_mS) contained cage sesquiterpene oxide. This cage type sesquiterpene oxide was made into "sesquioxane (D-3)". Synthesis Example 6 In a nitrogen atmosphere, 42.2 parts by mass of propylene glycol monopropyl ether, 4·5 parts by mass of pure water, and 32 parts by mass of triethylamine were placed in a three-necked flask, and the surface was stirred and heated to 55 ° C. . A solution of 4.9 parts by mass of 3-hydrothiopropyltrimethoxysilica, 3 parts by mass of n-butyltrimethoxydecane, and 42.2 parts by mass of propylene glycol monopropyl ether was mixed, and the mixture was dropped over 2 hours using a dropping funnel. Further, by carrying out a reaction at 55 ° C for 1 hour, methanol, water and triethylamine were distilled off under reduced pressure to obtain a sesquioxane having a sulfopropyl group and n-butyl group. The obtained sesquiterpene oxide was measured by GPC, and as a result, Mw = 3, 25 Å and Mn = 1,900. Further, it was confirmed by liquid chromatography mass spectrometry (lc_ms) that the obtained sesquioxides contained cage sesquioxanes. This cage type sesquiterpene oxide was made into "sesquioxane (D_4)". -44- 201133141 Synthesis of non-cage sesquioxanes Comparative Synthesis Example 1 In a nitrogen atmosphere, a 3-neck flask was charged with 32.6 parts by mass of 3-hydrothiopropyltrimethoxydecane and n-butyltrimethyl 31.9 parts by mass of oxydecane, 1 part by mass of methyl isobutyl ketone was added, and dissolved, and the resulting solution was heated to 6 (TC) while stirring with a magnetic stirrer. In the solution, 1% by mass of oxalic acid was contained. The aqueous solution of 8.6 parts by mass of oxalic acid was continuously added over 1 hour, and the reaction was carried out for 4 hours at 60 ° C. Thereafter, water, methanol, and methyl isobutyl ketone were distilled off under reduced pressure, and the obtained product was dissolved in toluene. After washing with water for 3 times in a separatory funnel and dehydrating with a drying agent, toluene was sufficiently removed under reduced pressure to obtain a sesquioxane having a sulfopropyl group and n-butyl group, which was confirmed by GPC measurement. The obtained sesquiterpene oxide is a random type or a ladder type. The sesquiterpene oxide is made into "sesquioxane (d-2)". Example 1 A coloring agent as a coloring agent (A) Dispersion (A - 1 ) 200 parts by mass; as (B) binder resin binder resin solution (Bl) 90 parts by mass; as a (C) polyfunctional monomer, caprolactone-modified dipentaerythritol hexaacrylate (manufactured by Nippon Kayaku Co., Ltd., trade name KAYARAD DPCA-60) 30 parts by mass and hexaacrylic acid 30 parts by mass of a polyfunctional acrylate having a pentaerythritol ester as a main component (manufactured by Nippon Kayaku Co., Ltd., trade name KAYARAD MAX-3510); and 5 parts by mass of sesquioxane (D-1) as a component (D) ( (Compound solid component); 2-benzyl-2-dimethylamino-tyrosolinylphenyl) butyl ketone 1-ketone (C), which is a photopolymerization initiator (trade name, manufactured by Ciba Specialty Chemicals Co., Ltd.) -45- 201133141

Irgacure 369) 25 parts by mass, 2,2'-bis(2-chlorophenyl)-4,4',5,5'-tetraphenyl-1,2'-biimidazole (manufactured by Hodogaya Chemical Co., Ltd., trade name 2 parts by mass of B-CIM), 2,4-diethylthioxanthone (manufactured by Nippon Kayaku Co., Ltd., trade name CAYACURE DETX-S); and propylene glycol monomethyl ether acetate as a solvent, The liquid composition (S-1) having a solid content concentration of 20% by mass was prepared. The liquid composition (S-1) was evaluated in the following order. The evaluation results are not shown in Table 2. Adhesion evaluation was carried out on a soda glass substrate having a diameter of 4 Å on a surface of a Si 02 film which was prevented from dissolving sodium ions, and the liquid composition (S-1) was applied by a spin coater, followed by a hot plate at 90 The film was prebaked at ° C for 1 minute to form a film having a film thickness of 2.5 μm. Next, a high-pressure mercury lamp was used, and the exposure film was exposed to radiation having a wavelength of 3 65 nm, 405 nm, and 436 nm at an exposure amount of 60 (H/m 2 ) without passing through a photomask. Thereafter, by using a coating film After discharging at 23 ° C and a 0.04% sodium carbonate aqueous solution at a developing pressure of lkgf/cm 2 (nozzle diameter: 1 mm), the film was washed and developed, and further baked at 23 (TC for 20 minutes) to form a green cured film on the substrate. An ITO film was formed on the obtained cured film by using an ITO sputtering apparatus (manufactured by U1 vac) to make the film thickness 500 A, and the cross-cut was performed in accordance with the Jis K5 400 specification to form a checkerboard-like shape. Sex test. As long as the number of leaves remaining in the checkerboard is not more than 90, the evaluation is 〇; as long as it is 80 or more and less than 90, the evaluation is △: as long as it is low -46- 201133141 at 80 The evaluation results are as follows. The evaluation results are shown in Table 2. As long as the checkerboard eyes are not peeled off, and the number of remaining leaves is 90 or more, it is good. Evaluation of solvent resistance The Si 02 film having the prevention of dissolution of sodium ions is formed on the surface. On a 4 inch diameter sodium glass substrate, use a spin After coating the liquid composition (S -1), it was prebaked on a hot plate at 90 ° C for 1 minute to form a coating film having a film thickness of 2 · 5 μm. Then, the substrate was cooled in the chamber. After the temperature, the high-intensity mercury lamp is used to expose the radiation containing the wavelengths of 365 nm, 405 nm, and 436 nm in the coating film by an exposure amount of 600 J/m 2 through the photomask, and thereafter, by 23 ° with respect to the substrate. The developing solution composed of 0.04% by weight of sodium carbonate aqueous solution of C was discharged at a developing pressure of lkgf/cm2 (nozzle diameter: 1 mm), and after rinsing and developing, it was further baked at 30 ° C for 20 minutes to form 200 on the substrate. The dot pattern of x 2 00 μηη. The obtained substrate was immersed in Ν-methylpyrrolidone at 25 ° C for 30 minutes, and the dot pattern before and after immersion was observed by a scanning electron microscope, and there was no change in the pattern. And the ratio of the film thickness before and after immersion (film thickness after immersion X 1 0 0 / film thickness before immersion) was 95% or more, and it was evaluated as 〇; the film thickness ratio before and after immersion was less than 9 5 % ' Or evaluate to △ in the case where one part of the pattern is chipped; The case where all the rear patterns were peeled off from the substrate was evaluated as X. The evaluation results are shown in Table 2. The evaluation of the voltage holding ratio was carried out on the surface to prevent the dissolution of sodium ions, and the ITO was further deposited on the ITO (indium- The tin oxide alloy electrode is formed on a soda glass substrate of a predetermined shape, -47- 201133141. After coating the liquid composition (S-ι) using a spin coater, it is pre-baked in a clean oven at 90 ° C for 1 minute. Bake to form a film with a film thickness of 2·Οηη. Next, using a high-pressure mercury lamp, radiation having wavelengths of 365 nm, 405 nm, and 436 nm was exposed to an exposure amount of 60 CU/m 2 in the coating film without passing through a photomask. Thereafter, the substrate was immersed in a developing solution composed of a 0.04% by weight aqueous sodium carbonate solution at 23 ° C for 1 minute, developed, washed with ultrapure water and air-dried, and further, at 230 ° C. After 20 minutes of baking, the coating film was hardened to form green pixels on the substrate. Next, the substrate on which the pixel is formed and the substrate on which the ITO electrode is deposited only in a predetermined shape are bonded together with a sealant in which glass beads of 〇. 18 mm are mixed, and then injected into a liquid crystal MLC6608 (trade name) manufactured by Merck. Make a liquid crystal cell. Then, the liquid crystal cell was placed in a constant temperature layer at 60 ° C, and the voltage holding ratio of the liquid crystal cell was measured by a liquid crystal voltage retention measurement system VHR-1A (trade name) manufactured by Toyo Corporation. At this time, a square wave having a voltage of 5.0 V was applied, and the measurement frequency was 60 Hz. Here, the voltage holding ratio means (the voltage applied by the liquid crystal cell potential difference / 0 milliseconds after 16.7 milliseconds). The evaluation results are shown in Table 2. Examples 2 to 14 and Comparative Examples 1 to 3 The liquid composition (S-2) was prepared in the same manner as in Example 1 except that the types and amounts of the respective components of the liquid composition were as shown in Table 1. To (S·17). -48-201133141 The evaluation was carried out in the same manner as in Example 1 except that the liquid compositions (S-2) to (S-17) were used instead of the liquid composition (S-1). The results are shown in Table 2. -49- 201133141 Thermal polymerization initiator mmm ΓΛ r 〇 聚合 聚合 聚合 n <n (N Ε-4 CN (Ν CN fN CN (Ν CN (Ν f CN (Ν CN (Ν CN (Ν CN (Ν CN (Ν CN (Ν CN (Ν CN (Ν CN (Ν CN N (Ν (N Ε-2 卜Ο卜卜ώ »η (Ν Ό (Ν CN «Τ> (Ν w-ι (Ν (Ν »Τ) CN fN (Ν ir> Ν Ν Compound <Ν *r\ -ό Wi D-5 D-4 D-3 yr\ D-2 yr\ 1 Q ι〇»〇•Ο i〇in Polyfunctional monomer C-2 黏 Binder resin solution Β-2 »〇Β-1 § § JO colorant dispersion Α-4 200 Α-3 500 Α-2 500 < 500 500 400 400 400 400 400 500 500 500 500 500 500 500 Liquid composition [/3 CN C/D χη 〇〇άι *"7 op ζλ Ον ΐλ S-10 S-ll ! S-12 S-13 S-14 S-15 S-16 S-17 Example 1 Example 2 Example 3 real Example 4 Example 5 Example 6 Example 7 Example 8 Example 9 Example 10 Example 11 Example 12 Example 13 Example 14 Comparative Example 1 Comparative Example 2 Comparative Example 3 -010- 201133141 Table 1 The composition is as follows: C -1 : caprolactone-modified dipentaerythritol hexaacrylate (manufactured by Nippon Kayaku Co., Ltd., trade name KAYARAD DPCA-60) C-2: dipentaerythritol hexaacrylate and five Mixture of dipentaerythritol acrylate (manufactured by Nippon Kayaku Co., Ltd., trade name KAYARAD MAX-3510) D-5: Commercial product of cage sesquioxane having a sulfonyl group (sulfonyl equivalent = 206 g) /eq) d-1: neopentyl alcohol oxime (3-hydrothiopropionate) El: 2-benzyl-2-dimethylamino-1-(4-morpholinylphenyl)butane- 1-ketone (manufactured by Ciba Specialty Chemicals, trade name lrgacure 3 69) E-2: ethyl ketone, 1-[9-ethyl-6-(2-methylbenzylidene)-9H-carbazole - 3-yl]-, 1-(0-ethenylhydrazine) (manufactured by Ciba Specialty Chemicals, trade name lrgacure OXE02) E-3: 2,2'-bis(2-chlorophenyl)-4 , 4',5,5'-tetraphenyl-1,2'-biimidazole (manufactured by Hodogaya Chemical Co., Ltd., trade name B-CIM) E-4·· 2,4-diethyl Toxane (manufactured by Nippon Kayaku Co., Ltd., trade name CAYACURE DETX-S) E-5: 1-hydroxy-cyclohexyl phenyl ketone (manufactured by Ciba Specialty Chemicals, trade name lrgacure 184) F-1 : azo Nitrile (manufactured by Otsuka Chemical Industry Co., Ltd., trade name AIBN) -5 1- 201133141 Table 2 Fiber composition adhesion and solvent resistance voltage retention rate Example 1 S-1 Δ Δ 90% Example 2 S-2 Δ Δ 91% Example 3 S-3 Δ Δ 90% Example 4 S-4 〇〇 97% Example 5 S-5 〇〇 97% Example 6 S-6 〇〇 96% Example 7 S-7 〇〇 95% Example 8 S-8 〇〇 95% Example 9 S-9 Δ 〇 92% Example 10 S-10 〇〇 93% Example 11 S-11 〇〇 95% Example 12 S-12 〇〇 95% Example 13 S-13 〇〇95% Example 14 S-14 〇〇95% Comparative Example 1 S-15 XX 78% Comparative Example 2 S-16 XX 82% Comparative Example 3 S-17 X 〇80% As is clear from Table 2, the pixel formed by the colored composition of the present invention containing (D) the cage sesquiterpoxysilane having a sulfonyl group and/or a polymerizable unsaturated group is densely bonded to the transparent conductive film or the inorganic film. Excellent combination and excellent in low exposure Solvent, furthermore also a high voltage holding ratio. [Simple description of the diagram] 〇

JWS [Main component symbol description] Μ 〇 y\\s -52-

Claims (1)

201133141 VII. Patent application scope: K A colored composition characterized by containing a coloring agent selected from (A), (B) a binder resin, (C) a polyfunctional monomer, and (D) a sulfonyl group and a polymerization. The at least one cage sesquioxane in the group consisting of unsaturated groups. 2. A colored composition according to the scope of the patent application of the present invention, which comprises a (Β) binder resin having a polymer functional group and a polymerizable unsaturated group. 3. The colored composition of claim 1 or 2, which further comprises (Ε) a photopolymerization initiator. 4. The colored composition of claim 3, wherein the (Ε) photopolymerization initiator comprises a ruthenium-fluorenyl ruthenium compound. A color filter comprising a coloring layer formed using the colored composition according to any one of claims 1 to 4. A liquid crystal display element is provided with a color light film as in item 5 of the patent application. -53- 3 201133141 IV. Designation of Representative Representatives (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: