TW201043715A - Deposition apparatus with high temperature rotatable target and method of operating thereof - Google Patents

Deposition apparatus with high temperature rotatable target and method of operating thereof Download PDF

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Publication number
TW201043715A
TW201043715A TW099108392A TW99108392A TW201043715A TW 201043715 A TW201043715 A TW 201043715A TW 099108392 A TW099108392 A TW 099108392A TW 99108392 A TW99108392 A TW 99108392A TW 201043715 A TW201043715 A TW 201043715A
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Taiwan
Prior art keywords
substrate
heating
temperature
deposition
front side
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TW099108392A
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Chinese (zh)
Inventor
Joachim Mueller
Roland Trassl
Jian Liu
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Applied Materials Inc
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Priority claimed from EP09155752A external-priority patent/EP2230325A1/en
Priority claimed from US12/408,409 external-priority patent/US20100236920A1/en
Application filed by Applied Materials Inc filed Critical Applied Materials Inc
Publication of TW201043715A publication Critical patent/TW201043715A/en

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/3407Cathode assembly for sputtering apparatus, e.g. Target
    • C23C14/3421Cathode assembly for sputtering apparatus, e.g. Target using heated targets
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • C23C14/35Sputtering by application of a magnetic field, e.g. magnetron sputtering
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/54Controlling or regulating the coating process
    • C23C14/541Heating or cooling of the substrates
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/32431Constructional details of the reactor
    • H01J37/32715Workpiece holder
    • H01J37/32724Temperature
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/32Gas-filled discharge tubes
    • H01J37/34Gas-filled discharge tubes operating with cathodic sputtering
    • H01J37/3402Gas-filled discharge tubes operating with cathodic sputtering using supplementary magnetic fields
    • H01J37/3405Magnetron sputtering

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Analytical Chemistry (AREA)
  • Physical Vapour Deposition (AREA)

Abstract

A deposition apparatus (100) and a method for sputtering material on a substrate is provided with a substrate holder (110) for holding the substrate, a rotatable target (120) adapted for being sputtered, and a heating system including a back side heating (130) for heating the substrate from the back and a front side heating for heating the substrate from the front. The rotatable target acts as the front side heating and is adapted for heating the substrate to a temperature of at least 100 DEG C.

Description

201043715 六、發明說明: 【發明所屬之技術領域】 本揭示大體而言係有關於沉積設備及其操作方法。本 揭示係有關於基板塗佈技術解決方案,牽涉設備、製程 及用於>儿積、圖案化、和基板及塗層處理的材料,擁有 代表性範例,包含(但不限於)牵涉如下元素的應用:半 導體和介電材料及設備、矽基晶圓、平板顯示器(例如 〇 TFT)、光罩及濾光片、能量轉換及儲存器(例如光伏電 池、燃料電池、及電池)、固態照明(例如LEDs* 〇LEDs)、 磁性及光學儲存器、微機電系統(MEMS)和奈米機電系統 (NEMS)、微光和光機電系統(〇EMS>、微光和光電元件、 透明基板、建築和汽車玻璃、用於金屬和聚合辖和封裝 的金屬化系統、以及微(micr〇„)和奈米化結合技術 (nano-molding)。更明確㈣,其係有關於具有可旋轉乾 的濺射設備及其操作方法。 0 【先前技術】 在許多應用中,必須在一基板上沉積薄層。在此所用 的「基板」-詞應包含無彈性基板,例如晶圓或玻璃板, 以及彈性基板,例如網片(web)或羯片(f〇ii)兩者。明讀地 說,用於沉積層的已知技術為蒸鍍及濺射。 在一蒸鑛製程中,加熱欲沉積的材料使其蒸發然後冷 凝在該基板上1射是—㈣來沉積各種材料薄膜至一 基板表面的真空塗佈製程。例如,可用減射來沉積一金 4 201043715 屬層’例如紹或陶究薄層。在濺射製 電壓加速的惰性氣體離子森擊該乾材表 材料從該材料組成的乾材傳送至欲塗佈的‘將:塗: 離子撞擊該㈣外表面時,其動量傳送㈣材料^ 因此其中某些能獲得足以克服其 ” ^ ^ ± 开莰σ能量的能量以從該201043715 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present disclosure relates generally to deposition apparatus and methods of operation thereof. The present disclosure relates to substrate coating technology solutions, involving equipment, processes, and materials for > grading, patterning, and substrate and coating processing, with representative examples including, but not limited to, the following elements Applications: Semiconductor and dielectric materials and devices, germanium-based wafers, flat panel displays (eg TFTs), reticle and filters, energy conversion and storage (eg photovoltaic cells, fuel cells, and batteries), solid state lighting (eg LEDs* 〇LEDs), magnetic and optical storage, microelectromechanical systems (MEMS) and nanomechanical systems (NEMS), low-light and opto-electromechanical systems (〇EMS>, low-light and optoelectronic components, transparent substrates, construction and Automotive glass, metallization systems for metals and polymerizations and packaging, and micro-molding and nano-molding. More specifically (4), it is about sputtering with spin dry Equipment and method of operation. 0 [Prior Art] In many applications, a thin layer must be deposited on a substrate. The term "substrate" as used herein shall include an inelastic substrate such as wafer or glass. a plate, and an elastic substrate, such as a web or a cymbal. For example, the known techniques for depositing layers are evaporation and sputtering. In a steaming process, Heating a material to be deposited to evaporate and then condense on the substrate to form a vacuum coating process for depositing a film of various materials onto a substrate surface. For example, a gold can be deposited by subtraction to form a layer of gold 4 201043715 Or arranging a thin layer. The inert gas ion accelerated by the sputtering voltage is transferred from the dry material composed of the material to the coating to be coated: when: the ion strikes the outer surface of the (four) Momentum transfer (4) material ^ so some of them can obtain enough energy to overcome their " ^ ^ ± open 莰 energy to

乾材表面脫出並沉積在該基板上。在基板上,立形成預 期的材料膜。所沉積薄膜的厚度,除了其他的以外,取 決於該基板暴露在該濺射製程中的時間長短。 例如,在薄膜太陽能電池的生產中使用濺射。一般而 言,一薄膜太陽能電池包含一背接觸、一吸收層、以及 一透明且導電的氧化層(TC0)。通常,該背接觸和該tc〇 層係利用濺射來生產,而該吸收層一般則是在化學氣相 沉積製程甲製造。與蒸鍍製程相比’例如化學氣相沉積’ 濺射也因為某些材料能夠濺射但無法蒸發而佔優勢。此 外,濺射製程所產生的層對該基板的附著度通常強於蒸 鑛製程者。再者,濺射是一種指向性製程,因此絕大部 分的材料轉移至基板,而不會塗佈該沉積設備的内部空 間(如在蒸鍍應用中一般)。 儘管減射具優勢,但濺射也有缺點存在》與蒸鍍相比, 錢射一基板需要較長時間。濺射速率通常比蒸鍍速率低 很多°因此持續希望能夠加快濺射製程的速度。 另一方面’除了濺射層對基板的較佳附著度之外’持 續希望能夠進一步改善沉積層的品質。 【發明内容】 5 201043715 鑑於上述,提供用來在一 » , μ β. ^ 暴扳上沉積一層的沉積設備 及方法β 根據一態樣,提供一種在一基板上職射材料的沉積設 備’其具有-基板固持件,用以固持該基板;—可旋轉 靶’適於受濺射;以及—加熱系統,包含一背側加熱, 用以從背側加熱該基板,以及一前側加熱,用以從前側 加熱該基板。該可旋轉㈣用為該前側加熱,並適於加 熱該基板至至少100 °c。 Ο 根據另-態樣,提供—種在一沉積設備中一基板上沉 積-沉積材料層的方法,該方法包含固持一基板,旋轉 -可旋轉無,在該基板上賤射材料,利用該前側加熱將 該基板加熱至至少loot,以及使用該可旋轉靶來從前 側加熱該基板。 必須將該前側加熱適於將該基板加熱至10(rc的描述 理解為該前側加熱適於使該基板升溫至1 〇〇£>c。 〇 根據另一態樣,提供一種在一基板上濺射材料的沉積 設備,其具有一基板固持件,用以固持該基板;一可旋 轉乾’適於受滅射;以及一加熱系統,包含一背侧加熱, 用以從背側加熱該基板’以及一前側加熱,用以從前側 加熱該基板。該可旋轉靶作用為該前側加熱,並適於使 該基板溫度增加至少loot:。 根據另一態樣’提供一種在一沉積設備中一基板上沉 積一沉積材料層的方法’該方法包含固持一基板,旋轉 一可旋轉靶,在該基板上濺射材料,利用該前側加熱使 6 201043715 該基板溫度增加至少10(rc,以及使用該可旋轉靶從前 侧加熱該基板。 根據實施例,該前側加熱適於將該基板加熱至至少 °c,更典型地加熱至至少30(rc。根據實施例,該前側 加熱適於使該基板溫度增加至少2〇〇〇c,更典型地择加 至少 300°c。 9 其他態樣、細節、優勢及特徵結構可從附屬項、實施 方式及附圖輕易看出β 〇 冑施例也針對執行每—種揭示方法㈣備,並包含執 行每一個所描述之方法步驟的設備部件。這些方法步驟 可利用硬體零組件執行、利用適#軟體的電腦程式、或 該兩者的任意組合或任何其他方式。此外,實施例也針 對所描述設備的操作方法或所描述設備的製造方法❶其 包含執行此設備功g或製造該設備部件法步 【實施方式】 Ο 纟如下對於圖式的描述中,相同的元件符號表示相同 零組件。一般而言,僅敘述個別實施例的相異處。 以在此所述材料塗佈基板的製程通常稱為薄膜應用。 在此使用的「塗佈」一詞及「沉積」一詞係同義性質。 該沉積設備包含—製程來源。一般而言,這是一個適 於被滅射的可旋轉乾。如會在後方更詳細討論者,該可 旋轉把可以是接合可旋轉乾或非接合可旋轉祀。 般而σ $射可以二極體藏射或磁&管滅射兩種形 201043715 式進行。磁控管濺射特別具優勢,因氣 ^ ”〉儿積速率相告 高。通常,一磁鐵係經設置在該可旌Μ 田 , 旋轉乾内。藉由將該 或該等磁鐵設置在該靶材後方,在—社 了旋轉耙的情況中 即在該靶材内部,以捕捉位於所產峰 π座生磁場内緊鄰該 表面下方的自由電子,這些電子被迫 你邊磁%内部移動 且無法脫離。這通常使離子化該等氣 *做知 軋體刀子的可能性增 加歲個數量級。這轉而顯著增加沉積速率。 ❹The dry material surface is extracted and deposited on the substrate. On the substrate, a desired material film is formed. The thickness of the deposited film depends, inter alia, on the length of time the substrate is exposed to the sputtering process. For example, sputtering is used in the production of thin film solar cells. In general, a thin film solar cell comprises a back contact, an absorbing layer, and a transparent and electrically conductive oxide layer (TC0). Typically, the back contact and the tc layer are produced by sputtering, and the absorber layer is typically fabricated in a chemical vapor deposition process. "Chemical Vapor Deposition' sputtering is also superior to evaporation processes because certain materials are capable of sputtering but cannot evaporate. In addition, the layer produced by the sputtering process is generally more adherent to the substrate than the vapor processing process. Furthermore, sputtering is a directional process whereby most of the material is transferred to the substrate without coating the interior space of the deposition apparatus (as in vapor deposition applications). Despite the advantages of shot reduction, there are disadvantages in sputtering. Compared with evaporation, it takes a long time to shoot a substrate. The sputtering rate is usually much lower than the evaporation rate and it is therefore desirable to speed up the sputtering process. On the other hand, 'except for the preferred adhesion of the sputter layer to the substrate', it is desirable to further improve the quality of the deposited layer. SUMMARY OF THE INVENTION 5 201043715 In view of the above, there is provided a deposition apparatus and method for depositing a layer on a », μ β. ^ burst. According to an aspect, a deposition apparatus for a job material on a substrate is provided. a substrate holder for holding the substrate; a rotatable target adapted to be sputtered; and a heating system including a back side heating for heating the substrate from the back side and a front side heating for The substrate is heated from the front side. The rotatable (four) is used to heat the front side and is adapted to heat the substrate to at least 100 °C. Ο According to another aspect, a method of depositing-depositing a layer of material on a substrate in a deposition apparatus, the method comprising: holding a substrate, rotating-rotatable, and projecting a material on the substrate, using the front side Heating the substrate to at least a loot, and using the rotatable target to heat the substrate from the front side. The front side heating must be adapted to heat the substrate to 10 (the description of rc is understood to mean that the front side heating is adapted to warm the substrate to 1 &> c. 〇 According to another aspect, a substrate is provided a sputtering material deposition apparatus having a substrate holding member for holding the substrate; a rotatable dry 'suitable for firing; and a heating system including a back side heating for heating the substrate from the back side And a front side heating for heating the substrate from the front side. The rotatable target acts to heat the front side and is adapted to increase the substrate temperature by at least a loot: according to another aspect 'providing a a method of depositing a layer of deposition material on a substrate, the method comprising: holding a substrate, rotating a rotatable target, sputtering a material on the substrate, using the front side heating to increase the temperature of the substrate by at least 10 (rc), and using the The rotatable target heats the substrate from the front side. According to an embodiment, the front side heating is adapted to heat the substrate to at least ° C, more typically to at least 30 (rc. According to an embodiment, the front side The heat is adapted to increase the temperature of the substrate by at least 2 〇〇〇c, more typically by at least 300 ° C. 9 Other aspects, details, advantages and features can be easily seen from the accompanying items, embodiments and figures. Embodiments are also directed to performing each of the disclosed methods (4) and include device components that perform each of the described method steps. These method steps can be performed using hardware components, using a computer program suitable for the software, or Any combination of the two or any other manner. In addition, the embodiment is also directed to the method of operation of the described device or the method of manufacturing the device described, which comprises performing the device or manufacturing the device component [embodiment] Ο 纟In the following description of the drawings, the same reference numerals indicate the same components. In general, only the differences of the individual embodiments are described. The process of coating a substrate with the materials described herein is generally referred to as a film application. The term "coating" and "deposition" are used synonymously. The deposition equipment contains - the source of the process. In general, this is a suitable for extinction. Turning dry. As will be discussed in more detail later, the rotatable handle can be a rotatably dry or non-engageable rotatable cymbal. Generally, σ $ can be either a diode or a magnetic & 201043715. Magnetron sputtering is particularly advantageous because of the high rate of gas accumulation. Usually, a magnet is placed in the sloping field, rotating in the dry. By this or A magnet is disposed behind the target, in the case of a rotating cymbal, that is, inside the target, to capture free electrons located in the magnetic field of the generated peak π, which is immediately below the surface, and these electrons are forced to magnetically % moves internally and cannot be detached. This usually increases the probability of ionizing the gas* to know the size of the knives. This in turn increases the deposition rate significantly.

G 當使用該無材做該基板的前側加熱時,通常會控㈣ 材溫度以使其受該靶材熔點溫度限制。此外,在兩件 或多件式靶材的情況中’例如在乾材管及乾材支; backing tube)的情況中’其必須受到限制以顧及 ::支皆和該靶材的不同熱膨脹係數。換句話說,該加熱 幻員Μ不會讓該多件式乾材因為加熱而破 :、:,通常更進-步的情況必須考慮到不能讓:: 超過特定溫度。 :據某些實施例’該前侧加熱係利用多個可旋轉乾來 ^ 也就疋說,該沉積設備包含至少兩個可旋轉靶。 ^多個靶作用為該基板的前側加熱。此外,根據某些實 施例,可名立工也ι、— 多個 干步驟中提供該基板的加熱剖面,例如, 可旋轉靶之一被加熱至比其他可旋轉靶低的溫度。 通常,用认 一 用於可旋轉靶内的磁鐵是永久磁鐵。永久磁鐵 总 要V卻,因為其係設置在該靶材管内而該靶材G When the uncoated material is used to heat the front side of the substrate, the temperature of the (four) material is usually controlled so as to be limited by the melting point temperature of the target. In addition, in the case of two or more pieces of the target 'for example, in the case of a dry tube and a backing tube', it must be limited to take into account: different thermal expansion coefficients of the support and the target . In other words, the heating of the illusion does not cause the multi-piece dry material to break due to heating: , :, usually more advanced steps must be considered to prevent:: exceed a certain temperature. According to some embodiments, the front side heating system utilizes a plurality of rotatable stems. That is, the deposition apparatus comprises at least two rotatable targets. ^ Multiple target effects heat the front side of the substrate. Moreover, in accordance with certain embodiments, the heating profile of the substrate can be provided in a plurality of dry steps, for example, one of the rotatable targets is heated to a lower temperature than the other rotatable targets. Usually, it is recognized that the magnet used in the rotatable target is a permanent magnet. The permanent magnet is always V, because it is placed in the target tube and the target

根據一態樣,係保持在高溫下。操作時,該 變得非當# U “、、這疋因為其係被受離子爲擊的可旋轉輕園 8 201043715 繞的緣故。由於所發生的碰撞,而致使靶材被加熱。 為此’常會提供該靶材及該等磁鐵的冷卻。這樣做的 目的在於將磁鐵保持在適當的操作溫度下。此外,一般 認為最佳沉積溫度係低於一特定溫度。 ΟAccording to one aspect, the system is kept at a high temperature. In operation, this becomes improper [U", because it is wound by the ion-driven rotatable light bulb 8 201043715. The target is heated due to the collision. This target and the cooling of the magnets are often provided. The purpose of this is to maintain the magnet at an appropriate operating temperature. Furthermore, it is generally believed that the optimum deposition temperature is below a certain temperature.

出於意料的,發明人發現當與較低溫的同樣應用相比 時,高溫靶材會增進沉積基板的品質。在本揭示中提及 °口質時,應理解為,例如,電阻係數(應當,取決於應用, 八有可间可低的特定值)、例如吸收光譜的光學參數、 厚度、密度、硬度、附著度、耐刮性等。取決於特定應 用,需將該塗層的這些性質的一或多個設定成一預期 值。此外,此值在同一^或在若干塗佈的基板間會不 在檢驗較高免材溫度的影響時,更發現將材料從該起 材轟擊出的製程’即嚴格來講是賤射,不會受到較高溫 度太多影響。也就是說,並未發現從料材溶出該材料 的賤射製程步驟會受溫度影響。進-步研究顯示出是基 板上的高溫乾材產生影響而造成改善的層沉積。因此: 據本揭不的態樣’提供來自基板前側的加熱是有優勢 :’以加熱該基板並且提供來自前侧的加熱。為了做到 者,使用可旋轉靶來做為前側加熱。 但疋,特別是就磁控管濺射 鐵保持在低於-特定㈣值㈣:應考慮到必須將磁 —般門限值是約8(rr β A τ祛& 、的 "、、 靶材能夠比磁鐵的門限溫 ”、、該外乾材和該把材内部之間提供熱隔離是可行 201043715 的。此種隔離可以是該把材材料自身(若其具隔熱性)。 但也可能在應受到藏射的外乾材和承載該外扭材的乾材 管之間設置—額外的層。例如,該額外的層也可以是將 乾材材料與該靶材管接合的接合層。 除了由該無材執行的前侧加熱之外,也提供由背侧加 熱該基板的背側加熱。利用此組合加熱系統可確保該 基板保持在高溫下。根據本發明態樣,該前側加熱使該 〇 基板升至至少10(rc。發現在此溫度下沉積的層之品質 優於在較低溫度下沉積的層。此影響在該前側加熱造成 溫度上升至至少20(rc、30(rc或甚至至少4〇〇。〇時更 強。一般而言,該靶材溫度和該基板溫度之間並沒有很 明確的相關性。可能會有靶材被加熱至例如高達 的高溫,然而該基板约略在室溫範圍内之實施例。因此, 根據本揭示,必須確保該基板會因為該靶材作用為前側 加熱的效應而至少是1〇〇或甚至更熱。 〇 本揭不係針對若干材料的塗佈。明確地說,其係有關 於玻璃的塗佈。玻璃板通常具有相當高的儲熱能力,因 此一旦被加熱,例如在進入沉積腔室之前,溫度下降是 很溫和的《但是,藉由提供前側加熱,整個生產製程變 得更符合經濟效益,因為可減少預熱。此外,若與晶圓 塗佈相比,額外的前側加熱之正面效應在較低溫度下生 效。明確地說,在塗佈破璃時,通常該前側加熱造成的 溫度上升是至少150°c或200°C。 本揭示通常也有關於晶圓塗佈。晶圓的儲熱能力通常 10 201043715 很低。因此,在先前技藝中, M ^^ 右在進入沉積腔室前先預 熱’其在沉積腔室內的、、 _至内的-度下降是可觀的。因此,藉由 應用本揭示’明確地說藉由 兄糟宙&供能夠將晶圓加熱至至少 1 〇〇°c的前側加熱,該腔室內 /股至0的溫度可保持在高溫腔室。 常會將晶圓加熱至高溫。—丄 叙而έ,前側加熱能將晶 圓加熱至至少250°C、300。「+甘r β c或甚至疋400。(:的溫度。在Unexpectedly, the inventors have found that high temperature targets enhance the quality of the deposited substrate when compared to the same application at lower temperatures. Reference in the present disclosure to the mouth is understood to mean, for example, the resistivity (should, depending on the application, a specific value that can be low), such as optical parameters of the absorption spectrum, thickness, density, hardness, Adhesion, scratch resistance, etc. One or more of these properties of the coating need to be set to an expected value, depending on the particular application. In addition, when the value is not in the same or between several coated substrates, the process of bombarding the material from the material is found to be strictly shot. Too much affected by higher temperatures. That is, it has not been found that the sputtering process step of dissolving the material from the material is affected by temperature. Further research has shown that the high temperature dry matter on the substrate produces an effect that results in improved layer deposition. Therefore: It is advantageous to provide heating from the front side of the substrate in accordance with the present invention: to heat the substrate and provide heating from the front side. For the sake of this, a rotatable target is used as the front side heating. But hey, especially in the case of magnetron sputtering iron is kept below the -specific (four) value (four): it should be considered that the magnetic threshold should be about 8 (rr β A τ 祛 & 、, ", target It is feasible to provide thermal isolation between the outer dry material and the interior of the material. The isolation can be the material itself (if it is thermally insulating). It is possible to provide an additional layer between the outer dry material that should be trapped and the dry material tube that carries the outer twisted material. For example, the additional layer may also be a bonding layer that joins the dry material to the target tube. In addition to the front side heating performed by the no-material, backside heating of the substrate is also provided by the back side. The combined heating system ensures that the substrate is maintained at a high temperature. According to aspects of the invention, the front side is heated. Raising the germanium substrate to at least 10 (rc. The quality of the layer deposited at this temperature was found to be better than the layer deposited at lower temperatures. This effect caused the temperature to rise to at least 20 (rc, 30 (rc) on the front side heating Or even at least 4 〇〇. It is stronger when it is. In general, the target There is no clear correlation between the degree and the substrate temperature. There may be embodiments in which the target is heated to, for example, a high temperature, but the substrate is approximately in the range of room temperature. Therefore, according to the present disclosure, it is necessary to ensure The substrate may be at least 1 〇〇 or even hotter due to the effect of the target acting as a front side heating. The disclosure is not directed to the coating of several materials. Specifically, it relates to the coating of glass. It usually has a fairly high heat storage capacity, so once it is heated, for example before entering the deposition chamber, the temperature drop is very mild. However, by providing front side heating, the entire production process becomes more economical because it can be reduced In addition, the positive effect of additional front side heating is effective at lower temperatures compared to wafer coating. Specifically, when coating the glass, the temperature rise caused by the front side heating is usually at least 150. °c or 200 ° C. This disclosure is also generally related to wafer coating. The heat storage capacity of the wafer is usually very low at 10 201043715. Therefore, in the prior art, M ^^ right is entering Before the chamber is preheated, the decrease in the _ to the inside of the deposition chamber is considerable. Therefore, by applying the present disclosure, it is clear that the wafer can be supplied by the Brother & Heated to the front side of at least 1 〇〇 °c for heating, the chamber/stock to 0 temperature can be maintained in the high temperature chamber. The wafer is often heated to a high temperature. - In other words, the front side heating can heat the wafer to At least 250 ° C, 300. "+ Gan r β c or even 疋 400. (: temperature.

許多塗佈晶圓的實施例中,例如介於3耽和5⑽。c或甚 至550 c之間的較高溫度造成特別引人注意的品質改善 之正面政貞 <列& ’這可在晶圓i塗佈氮化石夕層時發生。 通常’沉積層的厚度係小於!毫米,更常見的是小於 1微米,甚至更典型的是小於1〇〇奈米。 第1圖示出如在此所述之沉積設備之一實施例的概要 刮面圖。該沉積設備100包含一基板固持件110,用以 固持欲塗佈的基板。其更包含一可旋轉靶120,其係適 於受到濺射。第1圖所示箭頭強調出—在操作時一該靶 材係持續旋轉。該可旋轉靶作用為該基板的前側加熱。 此外,該基板也從背側加熱。為此,提供一背侧加熱13〇。 通常’該可旋轉靶包含一靶材管,該靶材管在第2圖 中以元件符號121表示。此外,根據在此所述實施例, 該可旋轉乾包含一磁性元件。在第2圖中,該磁性元件 係以元件符號122表示。通常,該磁性元件係設置在該 勒·材内部的下側。在此情況中,執行所謂的向下濺射 (sputter-down),其中該靶材係設置在該基板上方。在所 謂的向上濺射(sputter-up)製程中,靶材係設置在基板下 11 201043715 更普遍的說法係設置在該乾材上側。 塗佈二’該磁性疋件係設置在該乾材較靠近欲 基板那一侧。該可旋轉乾通常是圓柱狀。根據呼 多實施例,至少一部八的磁祕-Α 根據泎 —… 部刀的磁性70件表面-以其剖面而言 疋環形的。這也在第2和3 -^ ^ ^ 申幻不出,其中該磁性 件的較下側表面部份與該可旋轉乾的形狀共形。 在第2圖中,可看到該磁性元件122的共形表面部分In many embodiments of coated wafers, for example, between 3 and 5 (10). The higher temperatures between c or even 550 c cause a particularly noticeable improvement in quality. <Columns&' This can occur when the wafer i coats the nitride layer. Usually the thickness of the deposited layer is less than! Millimeters, more commonly less than 1 micron, and even more typically less than 1 nanometer. Figure 1 shows a schematic plan view of one embodiment of a deposition apparatus as described herein. The deposition apparatus 100 includes a substrate holder 110 for holding a substrate to be coated. It further includes a rotatable target 120 that is adapted to be sputtered. The arrow shown in Figure 1 emphasizes that the target is continuously rotating during operation. The rotatable target acts to heat the front side of the substrate. In addition, the substrate is also heated from the back side. To this end, a back side heating of 13 提供 is provided. Typically, the rotatable target comprises a target tube, which is indicated by element reference numeral 121 in Figure 2 . Moreover, in accordance with embodiments described herein, the rotatable stem comprises a magnetic element. In Fig. 2, the magnetic element is denoted by reference numeral 122. Usually, the magnetic member is disposed on the lower side of the inside of the material. In this case, so-called sputtering-down is performed in which the target is disposed above the substrate. In the so-called sputter-up process, the target is placed under the substrate. 11 201043715 More generally, it is placed on the upper side of the dry material. The coating of the magnetic member is disposed on the side of the dry material that is closer to the substrate. The rotatable dry is generally cylindrical. According to the embodiment, at least one of the eight magnetic secrets - Α is based on the magnetic surface of the knives - the surface of the knives - which is annular in its cross section. This is also unrealized in the 2nd and 3rd - ^ ^ ^, wherein the lower side surface portion of the magnetic member is conformal to the rotatable dry shape. In Figure 2, the conformal surface portion of the magnetic element 122 can be seen.

和該乾^ 121之間的距離d。根據典型實施例,該距 離係小於5毫米,更典型地小於3毫米,並且甚至更典 型地小於2毫米。因具備短距離,該磁性元件的磁效應 可完全發揮。此外’其避免絲材管和磁性元件間的狹 _内圍繞該磁性元件流動的冷卻劑有效冷卻該㈣ 官》這是因為該可旋轉乾有高操作溫度(詳情見後方), 而該磁性元件的溫度則受到操作門限溫度的限制,高於 該溫度磁鐵即不再運作。 如在此所述,_加熱該托材1一高1。一般而言, 同時希望保持該磁性元件低於該操作門限溫度。藉由縮 ,小該磁性元件和妹材間的空間,㈣材管此部分的冷 部會因為該冷卻劑流必須流經的微小間隙而不起作用。 因此,該靶材只會輕微冷卻。可藉由提供該靶材管隔離 材料而更增強此效果’這會在後方更詳細討論。 第3圖示出該可旋轉靶的另一實施例。除了第2圖所 八元件外,第3圖更包含該内管^23。通常,該内管係 適於固持該磁性元件。該内管和該磁性元件兩者皆是靜 12 201043715 態的’而該靶材管通常適於旋轉。根據某些實施例,該 内管與-界面配合。在第3圖中,以元件符號125來表 示該界面。通常,該界面上側與該内管連接,並且其下 侧與該磁性元件連接。在許多實施例中該内管係填充空 氣。内管和靶材管之間的其餘空間可填充冷卻劑,以冷 卻該磁性元件。第3圖中以元件符號124來表示此空間。 冷卻劑的選擇取決於該靶材管内部的溫度。通常,用油 或水來冷卻。一般該靶材管内的溫度係介於40。(:和80 ^ °c 間。 以冷卻劑填充該靶材管來提供一設置在該可旋轉靶内 部的冷卻系統。該冷卻系統作用為冷卻該靶材的内部空 間。最重要的;%’冷;gp該磁性元件。根據在此所述實施 例的冷卻系統必須適於將該磁性元件保持在低於該磁性 元件操作Π限溫度的溫度下。另一方面,其必須適於儘 可能不冷卻該可旋轉靶,以使該可旋轉靶仍然能執行該 ❹ 基板的前側加熱。根據一般實施例,提供一控制反饋迴 路,其控制該可旋轉靶的冷卻元件。通常,該控制反饋 迴路包含一基板溫度測量及控制設備,例如一計量閥, 以供應冷卻流體。另一種選擇或除了該靶材溫度測量之 外,可提供基板溫度測量。例如,可能將該基板溫度經 常控制在或大於預定的最低溫度。取決於溫度測量纟士果 來調整該冷卻流體溫度,即若該基板太冷則升溫,戋者 若該基板溫度太高則降溫。通常,用水來作為冷卻流體。 第4圖概要示出如在此所述之沉積設備之一實施例。 13 201043715 與已在第1圖實施例示出的特徵結構相比,帛4圖實施 例更包含狹縫410。狹縫作用為讓基板進入該沉積設備, 並在塗佈後將其送出沉積設備。該實施例更示出傳輪部 分420,例如適於移動該基板固持件ιι〇的滾輪例如 至該沉積設備右側以透過狹縫41〇接收新的基板。 此外,該沉積設備包含一出口 43〇,以與一真空幫浦 連結。在其他實施例中,元件符號43〇表示直接設置在 ❹ 該沉積設備上的至少-個真空幫浦。此外,該設備包含 激射氣體用的人口 44G。通常,該賤射氣體係在操作時 通入該沉積設備的惰性氣體。根據一典型實施例,該濺 射氣體是氬氣。該濺射氣體係利用電子來離子化,然後 朝該靶材加逮以從該靶材溶出該靶材材料。一般該沉積 設備内的氣壓係介於1〇_2毫巴和丨〇·4毫巴之間。 通入該沉積設備的氣體可更包含一種與該靶材材料接 合的元素。例如,可藉由提供塊狀矽做為靶材,然後通 〇 入氮氣至該設備内來產生氮化矽層。此外,在欲得到含 氫氮化矽層的情況中,除了氮氣之外也加入少量氨氣 (NH3)或氫氣(HO »這就鈍化性質觀點而言對層品質有 利。 第5圖係示出欲塗佈的基板溫度相對於時間的概要曲 線圖。必須比較第5至7圖以了解在此所述實施例的優 勢。 弟5圖描述技藝中一沉積製程的時間溫度關係。在其 中’欲塗佈的基板被加熱至在此稱為Tmax的高溫。通常, 201043715 該基板係在進入該沉積設備前從兩側加熱,因此在進入 該沉積設備或該處理區域時的溫度是Tmax。在時間A, 該基板進入該》儿積s免備且其溫度降低非常多,因為在該 沉積設備内沒有前側加熱。因此,在時間A和b之間, 該基板係在很快即變得比該溫度Ttnax低許多的降低溫度 下塗佈。通常’此溫度(例如在時間B)約是3〇〇»c。一旦 該基板已經塗佈,即將其從該沉積設備取出以進行冷 〇 卻°這在時間B之後的曲線中示出。在時間a之後的溫 度驟降是因為該沉積設備内沒有前側加熱,但可能僅有 背侧加熱。因此’該沉積設備内的總加熱能力不夠高, 而無法將該基板保持在高溫。 第6圖示出根據在此所述實施例之沉積製程的時間一 溫度關係。通常’所示溫度趨勢係在做為基板的晶圓上 測得。如前所述,根據某些實施例,該基板係在進入該 沉積設備前加熱至一預熱溫度Tmax。根據典型實施例, 〇 該溫度Tmax係在至少300°C等級’更典型地至少400°C, 甚至更典型地450°C或甚至5_00。€。但是,根據本揭示, 與習知預熱相比降低預熱是可能的,因為預期在該沉積 設備内不會降溫太多。因此’根據某些實施例,該預熱 溫度Tmax最高500°C ’更典型地最高450°C,甚至更典 型地最高400°C。藉由降低預熱功率,可減少總功率消 耗’導致較便宜的塗佈生產。在其他實施例中,特別是 若該濺射材料是TCO時,該預熱溫度最高400°C,更典 型地最高350°C,或甚至更典型地最高300°C。 15 201043715 然後將該基板饋送至該沉積設備,其包含一加熱系 統,具有背侧加熱以加熱該基板背側,以及一前侧加熱 以加熱該基板前側。因此,可能將基板溫度保持在高水 準。根據第6圖所示實施例,該溫度係經保持在溫度 如關於第5圖所述者,該基板係在時間入及Β期間塗 佈。因此,根據在此所述實施例,可利用如下影響的至 少一種:第一,與該溫度的絕對值相比,塗佈製程期間 ❹ 溫度降低很少。例如,該降低可小於Tmax的20。/。或甚至 小於10%。根據某些實施例,其係保持固定在此溫度下, 其中「固定」在此上下文中通常意指5〇/〇的最大偏差。 第二’該基板的絕對溫度係在高水準。根據一態樣, 該溫度係至少loot。根據又另一實施例,該基板溫度 係保持在至少200°C,更典型地至少300。(:或甚至400 °C。該基板的高溫改善層品質。 第7圖示出如在此所述之另一沉積實施例。如在第6 〇 圖實施例中者,設置在該沉積設備内的加熱系統係適於 將該基板保持高溫。但是,與參考第6圖例示說明的實 施例相反,此溫度係小於原先的預熱溫度Tmax。因此, 一旦該基板在時間A進入該沉積設備,該基板溫度會如 第7圖所示般稍微降低。在某些範例中,該降低最大限 度是該溫度Tmax的15%,通常最大限度是1〇%或甚至 5%〇在任何情況令,該降低必須符合沉積製程期間該基 板溫度仍保持至少1 00。(:的條件,因此與技藝中的沉積 技術相比,該層品質會改善《在典型實施例中,該基板 16 201043715 溫度仍保持至少200°C、300。(:或甚至40(TC。 第8圖係溫度對於所沉積基板的質量密度之曲線圖。 其係測量氮化矽(SiN)層並且以某g/cm3的數量級來表示 其值。溫度係在〇和400°C之間變化。該三條概要示出 的結果曲線係關於不同壓力下的濺射製程。更詳細的 說,線條610代表壓力等級在1〇微巴的高壓,線條62〇 代表約4微巴的壓力,而線條630代表約2微巴的壓力。 如可從這些研究結果中看到者,質量密度〇在較高基 板溫度下增加。除該基板質量密度ρ以外,總層品質也 隨之改善。 第9圖不出根據實施例之可旋轉靶的概要剖面圖。其 示出一圓柱狀乾材管121。 一般而言,所有導電度足夠的金屬和陶瓷皆可受到濺 也可形成介電層。所沉積的層通 射。取決於反應氣體, 常是非晶或單晶。通常,就金屬製程或來自陶竟無材的 介電層而言,使用直流功率來進行濺射。若是反應製程, 則慣常使用中頻(MF)功率。 一般而言,該靶材管通常是由金屬製成,用於 典型材料是矽(Si)、銦(in)、例如銦錫(InSn)的銦合金、The distance d from the dry ^ 121. According to an exemplary embodiment, the distance is less than 5 mm, more typically less than 3 mm, and even more typically less than 2 mm. Due to the short distance, the magnetic effect of the magnetic element can be fully exerted. In addition, it avoids the narrowness between the wire tube and the magnetic element. The coolant flowing around the magnetic element effectively cools the (4) official. This is because the rotatable dry has a high operating temperature (see the rear for details), and the magnetic element The temperature is limited by the operating threshold temperature above which the magnet is no longer functioning. As described herein, the tray 1 is heated to a height of one. In general, it is also desirable to keep the magnetic component below the operating threshold temperature. By shrinking and smalling the space between the magnetic element and the sister material, the cold portion of the portion of the (four) material tube will not function because of the small gap through which the coolant flow must flow. Therefore, the target will only cool slightly. This effect can be enhanced by providing the target tube isolation material' which will be discussed in more detail later. Figure 3 shows another embodiment of the rotatable target. In addition to the eight elements shown in Fig. 2, Fig. 3 further includes the inner tube ^23. Typically, the inner tube is adapted to hold the magnetic element. Both the inner tube and the magnetic element are in a state of static 12 201043715 and the target tube is generally adapted for rotation. According to some embodiments, the inner tube is mated with an interface. In Fig. 3, the interface is indicated by element symbol 125. Typically, the upper side of the interface is connected to the inner tube and the lower side is connected to the magnetic element. In many embodiments the inner tube is filled with air. The remaining space between the inner tube and the target tube can be filled with a coolant to cool the magnetic element. This space is indicated by element symbol 124 in Fig. 3. The choice of coolant depends on the temperature inside the target tube. Usually, it is cooled with oil or water. Typically the temperature within the target tube is between 40. (: and 80 ^ °c. The target tube is filled with a coolant to provide a cooling system disposed inside the rotatable target. The cooling system acts to cool the internal space of the target. Most importantly; %' Cold; gp the magnetic element. The cooling system according to the embodiments described herein must be adapted to maintain the magnetic element at a temperature below the operating temperature limit of the magnetic element. On the other hand, it must be adapted to be as low as possible. The rotatable target is cooled such that the rotatable target can still perform front side heating of the crucible substrate. According to a general embodiment, a control feedback loop is provided that controls the cooling elements of the rotatable target. Typically, the control feedback loop includes A substrate temperature measurement and control device, such as a metering valve, to supply a cooling fluid. Alternatively or in addition to the target temperature measurement, a substrate temperature measurement can be provided. For example, the substrate temperature may be often controlled at or greater than a predetermined temperature. The minimum temperature depends on the temperature measurement gentleman to adjust the temperature of the cooling fluid, that is, if the substrate is too cold, the temperature rises, if the substrate temperature is too Then, the temperature is lowered. Typically, water is used as the cooling fluid. Fig. 4 schematically shows an embodiment of the deposition apparatus as described herein. 13 201043715 Compared with the characteristic structure already shown in the embodiment of Fig. 1, Fig. 4 Embodiments further include a slit 410. The slit acts to allow the substrate to enter the deposition apparatus and feed it out of the deposition apparatus after coating. This embodiment further illustrates a transfer portion 420, such as adapted to move the substrate holder ιι The roller of the crucible, for example, to the right side of the deposition apparatus receives a new substrate through the slit 41. Further, the deposition apparatus includes an outlet 43〇 for coupling with a vacuum pump. In other embodiments, the symbol 43 indicates At least one vacuum pump disposed directly on the deposition apparatus. Further, the apparatus includes a population of 44 G for lasing gas. Typically, the helium gas system is supplied with inert gas into the deposition apparatus during operation. In a typical embodiment, the sputtering gas is argon. The sputtering gas system is ionized using electrons and then captured toward the target to dissolve the target material from the target. Typically within the deposition apparatus The gas pressure system is between 1 〇 2 mbar and 丨〇 4 mbar. The gas introduced into the deposition apparatus may further comprise an element joined to the target material. For example, by providing a block 矽As a target, a nitrogen nitride layer is then formed by introducing nitrogen gas into the apparatus. Further, in the case of obtaining a layer containing hydrogen oxynitride, a small amount of ammonia (NH3) or hydrogen is added in addition to nitrogen ( HO » This is advantageous for layer quality from the viewpoint of passivation properties. Fig. 5 is a schematic graph showing the temperature of the substrate to be coated with respect to time. It is necessary to compare Figures 5 to 7 to understand the embodiments described herein. Advantages. Figure 5 depicts the time-temperature relationship of a deposition process in the art in which the substrate to be coated is heated to a high temperature referred to herein as Tmax. Typically, 201043715 the substrate is from both sides before entering the deposition apparatus. Heating, so the temperature at the time of entering the deposition apparatus or the processing zone is Tmax. At time A, the substrate enters the slab and is exposed to a very high temperature because there is no front side heating in the deposition apparatus. Therefore, between times A and b, the substrate is coated at a reduced temperature which is rapidly becoming much lower than the temperature Ttnax. Usually 'this temperature (e.g., at time B) is about 3 〇〇»c. Once the substrate has been coated, it is taken out of the deposition apparatus for cooling, which is shown in the curve after time B. The temperature dip after time a is due to the absence of front side heating in the deposition apparatus, but may only have back side heating. Therefore, the total heating capacity in the deposition apparatus is not high enough to maintain the substrate at a high temperature. Figure 6 illustrates the time-temperature relationship of the deposition process in accordance with the embodiments described herein. Usually the temperature trend shown is measured on a wafer as a substrate. As previously mentioned, in accordance with certain embodiments, the substrate is heated to a preheat temperature Tmax prior to entering the deposition apparatus. According to an exemplary embodiment, 温度 the temperature Tmax is at least 300 ° C level 'more typically at least 400 ° C, even more typically 450 ° C or even 5 00. €. However, according to the present disclosure, it is possible to reduce the warm-up compared to the conventional preheating because it is expected that there will not be much temperature drop in the deposition apparatus. Thus, according to certain embodiments, the preheating temperature Tmax is at most 500 ° C' more typically at most 450 ° C, and even more typically up to 400 ° C. By reducing the preheating power, the total power consumption can be reduced' resulting in less expensive coating production. In other embodiments, particularly if the sputter material is TCO, the preheat temperature is up to 400 °C, more typically up to 350 °C, or even more typically up to 300 °C. 15 201043715 The substrate is then fed to the deposition apparatus comprising a heating system having backside heating to heat the back side of the substrate and a front side heating to heat the front side of the substrate. Therefore, it is possible to maintain the substrate temperature at a high level. According to the embodiment shown in Fig. 6, the temperature is maintained at a temperature as described in relation to Fig. 5, and the substrate is applied during the time-in and the enthalpy. Thus, in accordance with the embodiments described herein, at least one of the following effects can be utilized: first, the temperature of the crucible is reduced less during the coating process than the absolute value of the temperature. For example, the decrease can be less than 20 of Tmax. /. Or even less than 10%. According to some embodiments, it remains fixed at this temperature, wherein "fixed" in this context generally means the maximum deviation of 5 〇 / 。. The second 'the absolute temperature of the substrate is at a high level. According to one aspect, the temperature is at least loot. According to yet another embodiment, the substrate temperature is maintained at at least 200 °C, more typically at least 300. (: or even 400 ° C. The high temperature of the substrate improves the layer quality. Figure 7 shows another deposition embodiment as described herein. As in the 6th embodiment, disposed in the deposition apparatus The heating system is adapted to maintain the substrate at a high temperature. However, contrary to the embodiment illustrated with reference to Figure 6, this temperature is less than the original preheating temperature Tmax. Therefore, once the substrate enters the deposition apparatus at time A, The substrate temperature will decrease slightly as shown in Figure 7. In some examples, the reduction is at most 15% of the temperature Tmax, typically a maximum of 1% or even 5%, in any case, The reduction must be consistent with the substrate temperature during the deposition process remaining at least 100. (The condition of the layer is improved, therefore, the quality of the layer is improved compared to the deposition technique of the art. In the exemplary embodiment, the temperature of the substrate 16 201043715 remains at least 200 ° C, 300. (: or even 40 (TC. Figure 8 is a plot of temperature versus mass density of the deposited substrate. It is a layer of tantalum nitride (SiN) measured and expressed in the order of g/cm3 Its value. The variation between 〇 and 400 ° C. The results of the three summaries show the sputtering process for different pressures. In more detail, line 610 represents the high pressure of the pressure level of 1 〇 microbar, and the line 62 〇 represents 4 microbar pressure, while line 630 represents a pressure of about 2 microbars. As can be seen from these results, the mass density 〇 increases at higher substrate temperatures. In addition to the substrate mass density ρ, the total layer quality Figure 9 is a schematic cross-sectional view of a rotatable target according to an embodiment, showing a cylindrical dry material tube 121. Generally, all metals and ceramics having sufficient conductivity can be splashed. A dielectric layer can be formed. The deposited layer is incident. Depending on the reaction gas, it is usually amorphous or single crystal. Usually, in the case of a metal process or a dielectric layer from a ceramic material, DC power is used for sputtering. In the case of a reaction process, intermediate frequency (MF) power is conventionally used. In general, the target tube is usually made of metal, and the typical material is bismuth (Si), indium (in), such as indium tin (InSn). Indium alloy,

射。取決於反應氣體,也可形成介電層, 層係一結晶層》 J瓷皆可受到濺 ’例如含氫氮化 17 201043715 矽(SiN:H)。該等層通常是非晶或微晶。 根據某些實施例,該靶材管係與一靶材支管接合,其 在第9圖實施例中以元件符號910表示。該接合層在第 9圖中以元件符號920表示。通常’該接合材料是鋼美。 根據某些實施例’選擇導熱性低的材料做為接合材料。 該接合材料因此可以是一絕熱體,通常具有小於〇 3 W/mK的導熱性,更典型地小於〇.2W/inK或甚至小於〇 i W/mK。 ® 根據其他實施例’使用一非接合可旋轉靶來進行滅 射。在此情況中,例如’該靶材管若不是以非接合方式 連結至一靶材支管,例如運用機械性壓力,即是該可旋 轉把為僅由欲塗佈材料組成的一件式管。 根據參考第10圖例示說明的實施例,一額外的層係設 置在該靶材管121和該靶材支管910之間。此層在第1〇 圖中以元件符號1 〇 1 〇表示。例如,此層可由絕熱材料製 〇 成。通常’該額外層的導熱性係小於0.3 W/mK,更典型 地小於0.2W/mK或甚至小於ο ι w/mK。 另外可能此層並不完全填充該靶材支管和該靶材管間 的區域。例如,其可設計成設置在該靶材管和該靶材支 β門至j某些位置處的間隙壁,例如三或四個位置。因 為該靶材管係位於該沉積設備真空中,因此真空也存在 於該乾材支管和該靶材管間,此實施例也提供良好的熱 隔離。 由於該可旋轉乾保持高溫的事實,該沉積設備及其環 18 201043715 境變得非常熱’根據在此所述之一態樣。 因此,根據某 些實施例’提供該沉積設備一外部冷卻系 統。根據某些 實施例’該外部冷卻系統(未在圖式中示 25)係與該沉積 設備連結,例如在該靶材位置上方。該外 「4令卻系統避 免該沉積設備全面加熱。 本揭示的應用讓該基板溫度可在塗佈期間保持高水 準。這就塗佈薄層(例如’石夕晶圓)而言是特別有用的。Shoot. Depending on the reaction gas, a dielectric layer can also be formed, and a layer of a crystal layer can be splashed, for example, containing hydrogen nitriding 17 201043715 矽 (SiN:H). The layers are typically amorphous or microcrystalline. According to some embodiments, the target tube is joined to a target branch, which is indicated by the symbol 910 in the Figure 9 embodiment. The bonding layer is indicated by the symbol 920 in Fig. 9. Usually the joining material is steel. A material having a low thermal conductivity is selected as a bonding material according to some embodiments. The bonding material may thus be a thermal insulator, typically having a thermal conductivity of less than W 3 W/mK, more typically less than 22 W/inK or even less than 〇 i W/mK. ® is fired according to other embodiments using a non-joining rotatable target. In this case, for example, if the target tube is not joined to a target branch in a non-engaged manner, for example, mechanical pressure is applied, i.e., the rotatable handle is a one-piece tube composed only of the material to be coated. According to the embodiment illustrated with reference to Fig. 10, an additional layer is disposed between the target tube 121 and the target branch 910. This layer is represented by the symbol 1 〇 1 〇 in the first diagram. For example, this layer can be made of a heat insulating material. Typically the thermal conductivity of the additional layer is less than 0.3 W/mK, more typically less than 0.2 W/mK or even less than οι/mK. It is further possible that this layer does not completely fill the area between the target branch and the target tube. For example, it may be designed as a spacer, such as three or four locations, disposed at the target tube and at certain locations of the target member. Since the target tube is located in the vacuum of the deposition apparatus, vacuum is also present between the dry material branch and the target tube. This embodiment also provides good thermal isolation. Due to the fact that the rotatable dryness maintains a high temperature, the deposition apparatus and its ring 18 201043715 become very hot 'according to one of the aspects described herein. Thus, the deposition apparatus is provided with an external cooling system in accordance with certain embodiments. According to certain embodiments, the external cooling system (not shown in the drawings) is coupled to the deposition apparatus, such as above the target location. The external "4" system prevents the deposition equipment from being fully heated. The application of the present disclosure allows the substrate temperature to be maintained at a high level during coating. This is particularly useful for coating thin layers (eg, 'Shi Xi Wa Wa). of.

此外,其容許減少預熱功率,因此更具經濟效益。這在 塗佈擁有高比熱的玻璃或諸如此類的塗佈應用中是特別 有用的。 雖然前述係針對本發明實施例,但本發明之其他及進 -步實施例可在不背離其基本範圍下設計出,而其範圍 係由如下申請專利範圍界定。 此書面描述運用範例來揭示本發明,包含最佳模式, 並且讓熟知技藝者能夠製造及使用本發明。雖然:本發明 已依據多個特定實施例描述過,但熟知技藝者會了解可 利用落在申請專利範圍的精神及範疇内的調整方式來實 施本發明。特別是’上述實施例不互相排除的特徵結構 可彼此組合。本發明的可專利性範圍係由申請專利範圍 界疋並且了包含熟知技藝者發想的其他範例。此類其 他範例意欲被包含在申請專利範圍内,若其具有不與申 明專利範圍的字義不同的結構元件’或若其包含與申請 專利範圍的字義無實質差異的等效結構元件。 【圖式簡單說明】 201043715 在本發明之其他更詳細態樣中指出的某些發明内容在 實施方式内描述,並且參考該等圖式示出部分。其中: 第1圖係根據在此所述實施例的沉積設備之概要剖面 rgt · 圃, 第2圖係根據在此所述實施例的可旋轉乾之概要剖面 因 · 圃,In addition, it allows for a reduction in preheating power and is therefore more economical. This is particularly useful in coating applications that have high specific heat of glass or the like. While the foregoing is directed to embodiments of the present invention, other and further embodiments of the present invention can be devised without departing from the basic scope thereof. This written description uses examples to disclose the invention, including the best mode Although the present invention has been described in terms of various specific embodiments, it will be understood by those skilled in the art that In particular, the features of the above embodiments which are not mutually exclusive can be combined with each other. The patentable scope of the invention is intended to be limited by the scope of Such other examples are intended to be included in the scope of the patent application, if they have structural elements that do not differ from the meaning of the claims, or if they contain equivalent structural elements that are not substantially different from the meaning of the scope of the patent application. BRIEF DESCRIPTION OF THE DRAWINGS Some of the inventive aspects indicated in other more detailed aspects of the present invention are described in the embodiments, and the parts are illustrated with reference to the drawings. Wherein: Figure 1 is a schematic cross-section of a deposition apparatus according to embodiments described herein, and Figure 2 is a schematic cross-section of a rotatable stem according to embodiments described herein.

第3圖係根據在此所述實施例的可旋轉無之概要剖面 團, 第4圖係根據在此所述實施例的沉積設備之概要剖面 國, 溫度曲線圖; 間一溫度曲線 間一溫度曲線 第5圖係描述一沉積製程的概要時間— 第6圖係描述另一沉積製程的概要時 面 · 圃, 第7圖係描述另一沉積製程的概要時 圏, 第8圖係描述層密度對沉積溫度的依賴性之溫度—質 量密度曲線圖; 第9圖係根據在此所述實施例的可旋轉靶之概要剖面 圖;以及 第1 〇圖係根據在此所述實施例的可旋轉靶之概要剖 面圖。 【主要元件符號說明】 100 沉積設備 201043715 基板固持件 可旋轉靶 靶材管 磁性元件 内管 空間 界面 ❹ 背侧加熱 狹縫 傳輸部分 出口 入口 靶材支管 接合層 絕熱層Figure 3 is a schematic, cross-sectional view of a rotatable profile according to embodiments described herein, and Figure 4 is a schematic cross-sectional view of a deposition apparatus according to embodiments described herein, a temperature profile; a temperature between the temperature profiles Figure 5 of the curve depicts the summary time of a deposition process - Figure 6 depicts the outline of another deposition process, Figure 7 depicts the outline of another deposition process, and Figure 8 depicts the layer density. Temperature-mass density profile dependent on deposition temperature; Figure 9 is a schematic cross-sectional view of a rotatable target according to embodiments described herein; and a first diagram is rotatable according to embodiments described herein A schematic cross-sectional view of the target. [Main component symbol description] 100 Deposition equipment 201043715 Substrate holder Rotatable target Target tube Magnetic element Inner tube Space Interface ❹ Back side heating slit Transmission part Exit inlet Target branch Joint layer Insulation layer

Claims (1)

201043715 七、申請專利範圍: 種在基板上賤射材料的沉積設備,該沉積設備至 少包含: -基板固持件’用以固持該基板; 一可旋轉靶,適於受濺射; 一加熱系統,具有: 煮側加熱,用以從背側加熱該基板;以及 Ο —前側加熱,用以從前側加熱該基板; 其中該可旋轉乾作為該前侧加熱;以及 /、中該引侧加熱適於加熱該基板至一至少1 的溫 度。 2.如申請專利範圍第 _乐項所述之沉積設備,具有包含一 乾材管及—m件的可旋轉乾。201043715 VII. Patent application scope: a deposition device for spraying a material on a substrate, the deposition device comprising at least: - a substrate holder for holding the substrate; a rotatable target adapted to be sputtered; a heating system, Having: boiled side heating for heating the substrate from the back side; and Ο-front side heating for heating the substrate from the front side; wherein the rotatable dry is used as the front side heating; and/, the lead side heating is adapted The substrate is heated to a temperature of at least one. 2. A deposition apparatus as claimed in the scope of the patent application, having a dry tube and a m-piece rotatable dry. 3.如申請專利範圍第1 加熱係適於加熱該基板 項所述之沉積設備,其中該前側 至一至少200。(:妁溫度。 4.如申請專利範圍第1項所述 加熱係適於加熱該基板至一至 之沉積設備,其中該前側 少30〇°C的溫度。 5.如申請專利範圍第1或2 備’該沉積設備更包含一冷卻 項任何一項所述之沉積設 系統,設置在該可旋轉輕 22 201043715 ' 内’用以冷卻該乾的内部。 6·如申凊專利範圍第5項所述之沉積設備,其中該冷卻 系統係適於使該磁性元件保持在一低於80。(:的溫度下。 7. 如申請專利範圍第5項所述之沉積設備,更包含一控 制反饋迴路,用以控制該可旋轉靶的冷卻系統。 〇 8. 如申請專利範圍第! 3戈2項任何一項所述之沉積設 備,該加熱系統更包含—外部加熱系統,其係設置在該 沉積設備前方。 項所述之沉積設 可旋轉靶和該至 9.如申請專利範面第1或2項任何一 備,更包含至少一另外的可旋轉靶,該 少一另外的可旋轉靶作為前側加熱。3. The method of claim 1, wherein the first heating means is adapted to heat the deposition apparatus of the substrate, wherein the front side is at least 200. (: 妁 temperature. 4. The heating system according to claim 1 is suitable for heating the substrate to a deposition apparatus, wherein the front side has a temperature of 30 〇 ° C. 5. Patent Application No. 1 or 2 The deposition apparatus further includes a deposition system according to any one of the cooling items, disposed in the rotatable light 22 201043715 'to cool the interior of the dry. 6 · As claimed in claim 5 A deposition apparatus, wherein the cooling system is adapted to maintain the magnetic element at a temperature below 80. (7: 7. The deposition apparatus of claim 5, further comprising a control feedback loop A cooling system for controlling the rotatable target. 〇8. The deposition apparatus of any one of claims 3, wherein the heating system further comprises an external heating system disposed in the deposition The apparatus described above is provided with a rotatable target and the apparatus of claim 1 or 2, further comprising at least one additional rotatable target, the additional one being a rotatable target The front side is heated. π π述之沉積設 冷卻系統,與哕h灶 L ~項%積設備連結 10.如申請專利範圍第1 備,該沉積設備更擁有— 設置》 1 1 ,一丄_何科的沉積設傷, 基板固持件’用以固持該基板;^包含. 可旋轉靶,適於受濺射;以及 加熱系統,包含一普仇丨丄 方側加熱以及—I 則侧加熱,該背 23 201043715 而該前側加熱用以從前 側加熱用以從背側加熱該基板 側加熱該基板; 為該前側加熱,並適於使該基板溫 其中該可旋轉靶作 度增加至少l〇〇t。The π π deposition deposition system is connected with the 哕h stove L ~ item % product. 10. As claimed in the patent scope, the deposition equipment has more - set "1 1 , a 丄 _ He Ke deposition damage a substrate holder 'for holding the substrate; ^ comprising: a rotatable target adapted to be sputtered; and a heating system comprising a priming side heating and - I side heating, the back 23 201043715 and The front side is heated to heat from the front side to heat the substrate from the back side to heat the substrate; to heat the front side and to warm the substrate wherein the rotatable target is increased by at least 10 Torr. 12·如申請專利範圍第 備更包含一冷卻系統 該乾的内部。 11項所述之沉積設備,該沉積設 設置在該可旋轉靶内,用以冷卻 如申請專利範圍第12項所述之沉積設備,其中該冷 卻系統係適於使該磁性元件保持在―低⑨80。。的溫度 下。 14. 如申請專利範圍第丨丨或12項任何一項所述之沉積設 備’適於在一晶圓上沉積一層。 G 15. —種在一沉積設備中一基板上沉積一沉積材料層的 方法,該方法至少包含: 固持一基板: 旋轉一可旋轉靶; 在該基板上濺射材料; 藉由從前側加熱該基板來加熱該基板至一至少1 〇〇。匸 的溫度;以及 使用該靶材從前侧加熱該基板。 24 201043715 16·如申請專利範圍第15項所述之方法, 被加熱至一至少200°C的溫度。 其中該基板係 17·如申請專利範圍第15項所述之方法 被加熱至一至少300X:的溫度。 其中該基板係 ο I8·如申請專利範圍第15或16項任何—項所述之方法 更包含冷卻該乾的内部。 19.如申請專利範圍第ι5或16項任何一 更包含 項所述之方法 操作一磁性元件’其係設置在談可旋轉乾内 將該磁性元件保持在一低於80〇c的溫度下。 〇 2〇·如申請專利範圍第15或16項任何_項所述之方法 更包含在提供該基板至該沉積設備前加熱該基板。 21.如申請專利範圍第15或16項任何一項所述之方法 更包含冷卻該沉積設備的步驟。 22.如申請專利範圍第15或16項任何一項所述之方法 其中該固持的基板係一晶圓。 25 201043715 23. —種在一沉積設備中一基板上沉積一沉積材料層的 方法,該方法至少包含: 固持該基板: 旋轉一可旋轉靶; 在該基板上濺射材料; 利用該前侧加熱使該基板溫度增加至少100〇c ;以及 使用該可彡疋轉起從前侧加熱該基板。 項所述之方法,更包括冷卻該 24.如申請專利範圍第23 乾的内部。 項所述之方法, 25.如申請專利範圍第23或24項任何— 更包含12. If the scope of the patent application is further included in a cooling system, the interior of the dry. The deposition apparatus of claim 11, wherein the deposition device is disposed in the rotatable target for cooling the deposition apparatus of claim 12, wherein the cooling system is adapted to keep the magnetic element at "low" 980. . Under the temperature. 14. The deposition apparatus of any one of claims or 12, which is adapted to deposit a layer on a wafer. G 15. A method of depositing a layer of deposition material on a substrate in a deposition apparatus, the method comprising: holding a substrate: rotating a rotatable target; sputtering a material on the substrate; heating the substrate from the front side The substrate heats the substrate to at least one turn. a temperature of 匸; and heating the substrate from the front side using the target. 24 201043715 16 The method of claim 15, wherein the method is heated to a temperature of at least 200 °C. Wherein the substrate system is heated to a temperature of at least 300X: as described in claim 15 of the patent application. The method of any one of the above-mentioned items of the present invention is further comprising cooling the interior of the dry body. 19. The method of any of the preceding claims, wherein the magnetic element is disposed within the rotatable dry mass to maintain the magnetic element at a temperature below 80 〇c. The method of any of clauses 15 or 16, further comprising heating the substrate before providing the substrate to the deposition apparatus. 21. The method of any of clauses 15 or 16 further comprising the step of cooling the deposition apparatus. The method of any one of clauses 15 or 16, wherein the substrate to be held is a wafer. 25 201043715 23. A method of depositing a layer of deposition material on a substrate in a deposition apparatus, the method comprising: holding the substrate: rotating a rotatable target; sputtering a material on the substrate; heating the front side Increasing the temperature of the substrate by at least 100 〇c; and heating the substrate from the front side using the tampering. The method of the present invention further comprises cooling the interior of the invention as in the 23rd of the patent application. The method described in the item, 25. If any of the scope of claim 23 or 24 is included - more 一低於8(TC的溫度下。 操作一磁性元件, 將該磁性元件保持在一低於8〇 26One below 8 (TC temperature. Operating a magnetic component, keeping the magnetic component below 8 〇 26
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JP4768699B2 (en) * 2006-11-30 2011-09-07 キヤノンアネルバ株式会社 Power introduction apparatus and film forming method

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