TW201039060A - Photosensitive coloring composition and color filter - Google Patents

Abstract

The coloring layer with excellent stability of the pigment dispersion and good shape of cross section can be formed with good reproducibility in the present invention. The photo-sensitive coloring composition includes a resin (A), a pigment (B), an initiator (C) for the active energy linear polymerization, a monomer (D) for the active energy linear curing and a solvent (E). The ethylene resin (A) includes higher than 50 weight percent of ethylene resin (F). The resin (F) includes 2-50 weight percent of the constituting unit (a) containing the carboxylic group, and 2-50 weight percent of at least one of the constituting units (b) of a ring structure, which is selected from a group consisting of the aromatic ring shown in the following general formula (1), the aromatic ring shown in the following general formula (2), the aliphatic ring shown in the following general formula (3) and the aliphatic ring shown in the following general formula (4), and 10-80 weight percent of the other constituting unit (c). General formula (1): General formula (2): where in the general formulae (1) and (2), R is a hydrogen atom, an alkyl group with benzene ring or a C1-C20 alkyl group. General formula (3): General formula (4):.

Description

201039060 VI. Description of the Invention: [Technical Field] [0001] The present invention relates to a photosensitive coloring composition, for example, for use in forming a color filter for a color liquid crystal display device and a solid-state imaging device device Sexual coloring composition. Further, the present invention relates to a color filter formed using the photosensitive coloring composition. [Prior Art] A representative display ❹ mode employed in a twisted nematic (TN) mode liquid crystal display device. A transmissive liquid crystal display device using a TN mode has a structure in which a liquid crystal layer is sandwiched between first and second polarizing plates. When the TN mode is adopted, the liquid crystal layer is directly incident on the second polarizing plate by the first linear polarized light of the first polarizing plate, or converted into circularly polarized light or elliptically polarized light, and is incident on the second polarizing plate. Or converted into a second linear polarized light whose polarization plane is 90° out of phase with the first linear polarized light, and is incident on the second polarizing plate. The amount of light penetrating through the second polarizer is thus controlled. Liquid crystal display devices typically use color filters to display color images. The color filter is applied to a transparent substrate such as a glass substrate, and two or more kinds of fine band (striped) filter segments having different hue are arranged in parallel or intersecting each other, or in the longitudinal or lateral direction. In each direction, two or more kinds of fine filter segments having different hue are arranged in order. The filter segments have a fine size of several micrometers to several hundreds of micrometers, and are arranged neatly in a specific arrangement for each hue. Generally, in the manufacture of a color liquid crystal display device, a transparent electrode for driving liquid crystal molecules is formed by evaporation or sputtering, and further, an alignment film for aligning liquid crystal molecules in a certain direction is formed thereon. . 099108905 In order to fully derive the performance of these transparent electrodes and alignment films, it is generally necessary to use the form number A0101 page 7 / 94 pages 0993218555-0 201039060 200 °c or more, * 6 . The above I is preferably carried out at a high temperature of 230 C or higher. Nowadays, as a method for producing a color filter, a pigment dispersion method is used, and the pigment is used as a pigment having a main heat resistance and excellent heat resistance. = only in the light-resistant pigment dispersion method, the coloring layer such as color clearing is formed by, for example, the following method to form a film segmenting agent and a solvent. The resin is dispersed and μ is used as a resin such as acrylic resin. In the above-mentioned coloring composition, a photopolymerizable monomer and a polymerization initiator are added to obtain a photosensitive coloring composition. Thereafter, the photosensitive green composition is applied onto a substrate such as a glass substrate, and then the coating film is patterned by light micro-~. Further, the patterned coating film is post-baked at a high temperature of, e.g., 20 〇 ° C or higher, thereby imparting the tolerance required in the subsequent step. Finish the color layer as above. Color liquid crystal display devices have been widely used in television receivers and computer monitors in recent years. Therefore, the demand for the improvement of the color characteristics is high, and accordingly, the pigment content of the coloring composition used for the color filter tends to become high. However, in the above method using photolithography at the time of formation of a colored layer, when the pigment content of the composition is still colored, the following problems may occur. In the above method, a photosensitive coloring composition is used as a colored composition for a color filter. Therefore, when the pigment content of the colored composition is high, the exposure amount of the substrate side region may be insufficient even if the exposure amount of the surface side region is sufficient in the exposed portion of the coating film composed of the photosensitive coloring composition. At this time, in the exposed portion of the coating film obtained from the negative photosensitive coloring composition, the optical bridge is insufficient in the substrate side region, and the colored layer obtained by the subsequent developing step 099108905 has a drape (or undercut). . For example, in this case, the form number A0101, page 8 / 94 pages 0993218555-0 201039060 is obtained, and the color layer having an inverted conical shape is obtained, that is, a shape having a larger width as the distance from the substrate side becomes larger. The color layer. The cross section of the colored layer is a forward taper, that is, when the distance from the substrate side becomes larger and the width thereof is narrower, if the transparent electrode material is deposited by vapor deposition or sputtering on the colored layer, The transparent electrode material is not only coated on the colored layer but also on the inclined end faces thereof. Therefore, in this case, the electrical connection failure due to the discontinuous portion is less likely to occur on the transparent electrode. On the other hand, when the transparent electrode material is deposited by vapor deposition or sputtering on the colored layer having the overhang, it is difficult for the transparent electrode material to be deposited under the overhang, and thus the discontinuous portion is likely to be generated in the transparent electrode. That is, in this case, an electrical connection failure is likely to occur at a position below the suspension. Techniques for obtaining a colored layer having a cross-sectional shape are described in several documents. For example, Japanese Laid-Open Patent Publication No. 2007-57655 discloses the use of a specific plasticizer to prevent the occurrence of overhang. Japanese Laid-Open Patent Publication No. 2007-1-14604 discloses at least one type of acrylate and methacrylate, at least one of acrylic acid and methacrylic acid, and hydroxyethyl acrylate and hydroxyethyl methacrylate. A copolymer of at least one of the copolymers of 2-isocyanate trimethylolethane triacrylate. Japanese Laid-Open Patent Publication No. 2003-1671-15 discloses that a coloring layer having a dangling is heat-treated to deform its cross section into a forward taper. In the case of the photosensitive coloring composition, it is required to form a coloring layer having a forward tapered shape even when the pigment content is increased, and it is also required to have excellent long-term storage stability for the photosensitive coloring composition. . Japanese Laid-Open Patent Publication No. 2004-110778 discloses a photosensitive coloring composition containing a copolymer resin 099108905, Form No. A0101, Page 9 of 94, 0993218555-0 201039060. The copolymer resin is a side chain or a terminal having a phenoxy group in which a hydrogen atom having no substitution or para position is replaced by an alkyl group. The copolymer resin is easily adsorbed to the surface of the pigment by the effect of P electrons of the benzene ring, and the affinity of the pigment for the solvent is enhanced by adsorbing the previous copolymer resin. Therefore, the photosensitive coloring composition is excellent in long-term storage stability. SUMMARY OF THE INVENTION [0003] However, as the generalization of liquid crystal display devices progresses, it is expected that the price thereof will be greatly reduced. Along with this, various components of the liquid crystal display device have been attempted to reduce costs. For example, in recent years, it has been attempted to regenerate and reuse the glass substrate after the failure of the post-baking, thereby saving waste of the glass substrate. This is one of the methods for reducing cost and being simple and convenient. A series of programs that are reused are shown as "redo". The efficiency of redoing is marked as "reworkability." The redoing method is a method of peeling the colored layer after post-baking from the glass substrate by using a stripping liquid called a redo liquid, for example, by returning the edge and the glass substrate to a state before coating the photosensitive coloring composition. . Since the colored layer after post-baking has high heat resistance and high solubility, a high-temperature and high-concentration strong alkali solution is generally used as the redo liquid. Also, it is usually assumed that the redo liquid is to be recycled and reused. In this case, the release sheet must be removed from the used rework solution using, for example, a filter. The inventors of the present invention have investigated the reworkability when using the photosensitive coloring composition described in Japanese Laid-Open Patent Publication No. Hei. That is, the coloring layer obtained from the photosensitive resin does not peel off even after the post-baking treatment, and is used for the treatment of the re-working liquid even after baking. May be a larger block of 099108905 0993218555-0

Form No. A_1 ^ 10 I/* 94 I 201039060 The form produces a peeling piece. If the release sheet is present in the reforming liquid in the form of a large block, the filter clogging easily occurs. Accordingly, an object of the present invention is to provide a coloring layer which can form a coloring layer which is excellent in dispersion stability of a pigment and has a good cross-sectional shape, and can achieve a good reproducibility, and a color filter using the same.

According to a first aspect of the present invention, a photosensitive coloring composition comprising: a resin (A), a pigment (B), an active energy ray polymerization initiator (C), and an active energy ray-curable monomer is provided. (D) and the solvent (E); the resin (A) contains the ethylenic resin (F) in a ratio of 50% by weight or more; and the vinyl resin (F) has a carboxyl group in a ratio of 2 to 50% by weight. The constituent unit (a) contains an aromatic ring selected from the following general formula (1) and an aromatic ring represented by the following general formula (2) in a ratio of 2 to 50% by weight, the following The constituent unit (b) of one or more annular structures of the group consisting of the aliphatic ring represented by the general formula (3) and the aliphatic ring represented by the following general formula (4), and 10 The ratio to 80% by weight contains other constituent units (c). General formula (1):

General formula (2): 099108905 Form number A0101 Page 11 of 94 0993218555-0 201039060

(In the above general formulas (1) and (2), R is a hydrogen atom or may have a benzene ring and an alkyl group having 1 to 20 carbon atoms.) General formula (3):

General formula (4):

Form No. A0101, Page 12 of 94, 099108905 0993218555-0 201039060 According to a second aspect of the present invention, there is provided a photosensitive coloring composition according to the first aspect, characterized in that it is selected from the aforementioned constituent units (a) One or more constituent units of the group consisting of (b) and (c) have ethylene bonding. According to a third aspect of the present invention, there is provided a photosensitive coloring composition according to the first or second aspect, characterized in that the constituent unit (a) precursor (al) is selected from the group consisting of acrylic acid and methacrylic acid. One or more monomers in the group formed.

According to a fourth aspect of the present invention, there is provided a photosensitive coloring composition according to the first or second aspect, characterized in that at least a part of the carboxyl group containing the structural unit (a) is obtained by having a hydroxyl group. The constituent unit is added with a polyvalent acid anhydride, or is introduced by adding a polyvalent acid anhydride to a hydroxyl group formed by adding a constituent unit having an epoxy group and an unsaturated monovalent acid.

According to a fifth aspect of the present invention, there is provided a photosensitive coloring composition according to any one of the first to fourth aspects, characterized in that the constituent unit (b) precursor (bl) is selected from benzene. Ethylene: a-methylstyrene, anthracene, benzylpropionic acid S, benzyl propyl methacrylate, a monomer represented by the following general formula (5), the following general formula (6) One or more monomers selected from the group consisting of a monomer and a monomer represented by the following general formula (7). General formula (5):

^i〇—R2}〇 η Ο General formula (6): 099108905 Form number Α0101 Page 13 of 94 0993218555-0 201039060

General formula (7) R1

(In the above general formulas (5) to (7), R1 is a hydrogen atom or a methyl group, R2 is an alkylene group having 2 or 3 carbon atoms, and R3 may have a stupid ring and a carbon number of 1 to 2 Å. An alkyl group, η is an integer of 1 to 15, and m is an integer of 〇 to 2) According to a sixth aspect of the present invention, a photosensitive coloring composition according to any one of the first to fifth aspects is provided. Characterized by: the aforementioned constituent unit (c) The precursor (cl) comprises a group selected from the group consisting of methacrylate, methyl sulfonium methacrylate, ethyl propyl phthalate and methyl ethyl propyl acrylate. More than one monomer. According to a seventh aspect of the present invention, a color filter comprising at least one of a calender sheet segment and a black matrix formed of the photosensitive coloring composition of any one of the first to sixth aspects is provided. One party. The photosensitive coloring composition-based pigment is excellent in dispersion stability. Further, the photosensitive coloring composition has sufficient shape retention and high thermoplasticity until it is completely cured. Therefore, the coloring layer obtained from the photosensitive coloring composition can be made, for example, by 150 even if it has a dangling. 〇, 099108905 0993218555-0 Form No. A0101 Page 14 of 94 201039060 Typically, it is a heat treatment at a temperature above 200 °C, which deforms its profile into a positive cone shape. That is, a ''color layer' having a good cross-sectional shape can be formed. Further, when the photosensitive coloring composition is used, good reworkability can be achieved. [Embodiment] [0004] 感光 ο 099108905 A photosensitive coloring composition according to one embodiment of the present invention will be described below. The photosensitive coloring composition of one embodiment of the present invention is used in, for example, a display device such as a liquid crystal display device or a solid-state image sensor, or a color filter included in an electronic device. The photosensitive coloring composition contains a resin (A), a pigment (B), an active energy ray polymerization initiator (C), an active energy ray-curable monomer (D), and a solvent (E). The following are explained in turn about these components. <<Resin (A)>> In the above-mentioned photosensitive coloring composition, the resin (F) is contained in a ratio of 50% by weight or more to the resin (F), more preferably 60 to 100% by weight. The ratio is contained. The vinyl resin (F) will be described in detail later. The transmittance of the resin (Α) in the full wavelength region of 400 to 700 nm is preferably 80% or more, more preferably 95% or more, from the viewpoint of pigment dispersibility, and the resin (A) is preferably the weight of the pigment (B). It is used in a ratio of 30 to 700% by weight, more preferably in a ratio of 60 to 450% by weight. <Resin other than the vinyl resin (F) which may be contained in the resin (A)> The resin (A) may not contain a resin other than the vinyl resin (F), but may be further than the vinyl resin (F). Contains other resins. Before the description of the vinyl resin (F), a resin other than the vinyl resin (F) which the resin (A) may contain will be described. The resin other than the vinyl resin (F) which may be contained in the resin (A) may be, for example, Form No. A0101, page 15 / page 94, 0993218555-0 201039060 For example, a thermoplastic resin, a thermosetting resin, an active energy ray-curable resin, or the like. These may be used alone or in combination of two or more. Examples of the thermoplastic resin include butyral resin, styrene-succinic dicarboxylic acid copolymer, vaporized polyethylene, chlorinated polypropylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, and polyvinyl acetate. , polyurethane resin, polyester resin, acrylic resin, alkyd resin, polystyrene resin, polyamide resin, rubber resin, cyclized rubber resin, cellulose, high density polyethylene and low density polyethylene Such as polyethylene, polybutadiene and polyimine resin. The thermosetting resin may, for example, be an epoxy resin, a benzoamide resin, a rosin-denatured maleic acid resin, a rosin-denatured fumaric acid resin, a melamine resin, a urea resin or a resin. As the active energy ray-curable resin, for example, a linear polymer having a reactive substituent such as a hydroxyl group, a carboxyl group or an amine group, and a (meth) group having a reactive substituent such as an isocyanate group, an aldehyde group or an epoxy group are used. A resin which reacts with an acrylic acid compound or cinnamic acid to introduce a photo-branching group such as a (fluorenyl) acrylonitrile group or a styryl group into a conventional linear polymer. Further, as the active energy ray-curable resin, for example, a styrene-maleic anhydride copolymer or a is used by having a (fluorenyl)acrylic acid compound having a hydroxyl group such as a hydroxyalkyl (mercapto) acrylate. A linear polymer of an acid anhydride such as a maleic acid-maleic anhydride copolymer or the like is subjected to a half esterification. In addition, in the present specification, when "(mercapto) propylene" is used for a certain compound, it means that the compound is a compound in which "(meth) propylene" is changed to "propylene", and "(meth) propylene is added. Any one of the compounds that can be changed to "methacryl". Further, in the present specification, when "(fluorenyl)propenyl group" is used for a certain functional group, it means that the functional group will be "(曱099108905 Form No. A0101 Page 16 of 94 pages 0993218555-0 201039060) a propylene group. Any change to the functional group of "propenyl group" and the modification of r (meth)propenyl group to the functional group of "methacryl group" can be used. In other words, when "(meth) acrylate" is used for a certain compound, it means that the compound is a compound in which "(meth) acrylate" is changed to r acrylate, and "(meth)" Any of the compounds of "methacrylic acid vinegar" can be changed to acrylate. <Ethylene-based resin (F)> The above-mentioned photosensitive coloring composition contains a vinyl resin (F) in a specific ratio with respect to the resin (A). Such photosensitive coloring compositions have the following characteristics 〇 (1) to (4). (1) Excellent thermal fluidity of the colored layer, the photosensitive coloring composition is applied to the substrate, and the colored layer obtained by exposing and developing the coating film, that is, for example, the filter segment has a dangling, and thereafter The heat treatment performed, that is, for example, 15f &gt; c or more, is partially and fluidized after baking. As a result, the colored layer deformation cross section has a positive taper shape. 4 〇(2) The highly dispersible vinyl resin (F) of the photosensitive coloring composition is easily adsorbed by the pigment (B), and when the pigment (B) adsorbs the ethyl basal tree &amp; (F), it is solvent Since the affinity is high, it is possible to maintain an excellent dispersion state over a long period of time. (3) Excellent developability of the coating film obtained from the photosensitive coloring composition In the "developing step", the unexposed portion can be easily removed by, for example, a developing solution of a developing solution. (4) Good reworkability / such as a strong alkaline re-liquid, remove the colored layer after baking. Also, the potato &amp; a. 099108905 peeling sheet of the color layer does not become coarse. Form No. AOlo! 0993218555-0 Page 17 of 94201039060 Vinyl Resin (F) contains the following constituent units (&amp;) to ((. In addition, the term "constituting unit" is synonymous with unit of money and unit. [Structural unit (a)] The constituent unit (a) contributes to the formation of the above feature (3). That is, the constituent unit U) has a rebel base and functions as a soluble portion during development. The constituent unit (a) also contributes to the formation of the above feature (4). Further, the term "remediation" means _(3)(10), and does not include an ion other than an ester bond (-C00R) or a hydrogen ion. The constituting unit (a) further contains an atom or a radical other than the carboxylic acid. For example, the constituent unit (a) further contains a carbon atom constituting a part of the carbon chain of the vinyl resin (F). The carboxyl group may be directly or indirectly bonded to a carbon atom constituting a part of the carbon chain of the vinyl resin (F). In the latter case, the carboxyl group may also be bonded to the carbon chain by, for example, ester bonding and any other atom or atom group. Part of the carbon atom Further, the 'composition unit (a) may further contain a functional group other than a carboxyl group, which is directly or indirectly bonded to a carbon atom constituting a part of the 6-alkenyl (f) 4 bond. For example, the constituent unit (a) It can also be combined with the combination of ethylene. In addition, the term "ethylene bonding" means that the double bond of olefins does not imply a dual bond of aromaticity. The constituent unit (a) is made by using the following precursor (al) The polymerization 'is obtained especially for radical polymerization such as vinyl polymerization. Before the constituent unit (a), the precursor (a 1) is a compound having ethylene bonding, which can be polymerized, especially a radical such as vinyl polymerization. Polymerization is carried out to form a constituent unit (a). As the constituent unit (a), the precursor (al) may be, for example, a compound having a carboxyl group and having a combination of Form No. A0101, page 18/94, 0993218555-0 201039060. As such a compound, for example, an unsaturated monocarboxylic acid such as (fluorenyl)acrylic acid, crotonic acid or a-gas acrylic acid, or an unsaturated dicarboxylic acid such as maleic acid or fumarene can be used as a precursor ( Al) can also make In the case of a (meth) propylene compound having a hydroxyl group such as a hydroxyalkyl (meth) acrylate, an anhydride of an unsaturated carboxylic acid such as maleic anhydride is obtained by a half-S. From the viewpoint of easiness of control such as molecular weight, for example, (meth)acrylic acid is preferable, and methacrylic acid is more preferable. These may be used singly or in combination of two or more kinds of oxime from the viewpoint of developability. The constituent unit (a) is in the range of 2 to 50% by weight, more preferably 10 to 40% by weight, based on the ratio of the vinyl resin (F). When the ratio is too small, the alkali developer may not be present. Fully remove unexposed parts. When the ratio is too large, even the exposed portion may be dissolved in the alkali developer. [Structural unit (b)] The constituent unit (b) functions as a pigment (B) or a pigment composition containing a pigment (B) and a dispersion, and functions as an affinity site. The constituent unit (b) contains an aromatic ring represented by the following general formula (1), an aromatic ring represented by the following general formula (2), and an aliphatic ring represented by the following general formula (3). And one or more annular structures of the group consisting of the aliphatic rings represented by the following general formula (4). General formula (1): 099108905 Form number A0101 Page 19 of 94 0993218555-0 201039060

General formula (2):

General formula (3):

General formula (4): 099108905 Form number A0101 Page 20 of 94 0993218555-0 201039060

The 'R-based hydrogen atom in the above general formulas (1) and (2), or an alkyl group having a benzene ring and a carbon number of 1 to 20.

Further, in the general formula (1), for R, the alignment of the line segment does not mean that the methyl group is bonded to the benzene ring, but means that the benzene ring is aligned and bonded to other structures. Similarly, in the general formula (2), for R, the line segment of the meta and alignment does not mean that the methyl group is bonded to the benzene ring, but represents a stupid ring position and a para position and is combined with other structures. Further, in the general formula (3), the line segment extending from the left five-membered ring does not mean that the methyl group is bonded to the five-membered ring, but that one of the carbon atoms constituting the five-membered ring is bonded to the other structure. Similarly, in the general formula (4), the line segment extending from the five-membered ring at the left end does not mean that the thiol group is bonded to the five-membered ring, but means that one of the carbon atoms constituting the five-membered ring is combined with other structures. The constituent unit (b) further contains other atoms or radicals in addition to the cyclic structures represented by the general formulae (1) to (4). For example, the constituent unit (b) further contains a carbon atom constituting a part of the carbon chain of the vinyl resin (F). The cyclic structures represented by the general formulae (1) to (4) may be bonded directly to the carbon atom or indirectly. Further, the constituent unit (b) may further contain a functional group other than the cyclic structure represented by the general formulae (1) to (4), which directly or indirectly constitutes a vinyl group 099108905 0993218555-0 Form No. A0101 Page 21 / A total of 94 pages 201039060 A carbon atom of a part of the carbon chain of the resin (F) is combined. For example, the constituent unit (b) may also contain ethylene. The constituent unit (b) is obtained by subjecting the following precursor (bl) to polymerization, in particular, radical polymerization such as vinyl polymerization. As the precursor (bl), for example, styrene, a-methylstyrene, diphenylethylene, hydrazine, acetamidine, benzylpropionate, methyl benzyl acrylate, the following general formula (5) can be used. And one or more monomers selected from the group consisting of a monomer represented by the following general formula (6) and a monomer represented by the following general formula (7). General formula (5):

〇 General formula (6):

R1 〇 General formula (7): 0993218555-0 099108905 Form number A0101 Page 22 of 94 201039060

The above-mentioned general formula (5) to (7) t ' Rl is a hydrogen atom or a methyl group, and the r2 is a calcined group of 2 or 3, and the R 3 system may have a stupid ring and a carbon number of the other groups. An integer 'm of 1 to 15' is an integer from 〇 to 2. 0 As a monomer represented by the general formula, for example, NEW-FR0NT_CEA[E0(epoxyethylene)-denatrated phenol acrylate manufactured by First Industrial Pharmaceutical Co., Ltd., R1: hydrogen atom 'R2: vinyl group, methyl group can be used. , η—or 2], ΝΡ-2 [η_mercaptophenoxy polyethylene glycol acrylate, Ri: hydrogen atom 'R2: vinyl group, R3:n-fluorenyl group, n = 2] 'N-177E [n-mercaptophenoxy polyethylene glycol acrylate, R1: hydrogen atom, r2: vinyl 'R3: η-mercapto group, n = 16~17] or PEH [stupyloxyethyl acrylate S曰' R. 虱Atomic 'R. Ethyl, hydrogen 芋, η = ι]. Q As a monomer represented by the general formula (5), for example, IRR169 manufactured by DAICEL Co., Ltd. [ethoxylated phenyl acrylate (E0 lmol), R1: hydrogen atom, R2: vinyl 'R3: hydrogen atom, n = l] or EbecrylllO [ethoxylated phenyl acrylate (E0 2mol), R1: hydrogen atom, R2: vinyl group, R3: hydrogen atom, n = 2]. Alternatively, as the monomer represented by the general formula (5), for example, AR0NIX® 101A [phenol E0 modified (η and 2) acrylate, R1: hydrogen atom, R2: vinyl group, manufactured by Toagosei Co., Ltd., may be used. R3: hydrogen atom, η and 1], Μ-102 [phenol phenolphthalein 0 modified (η and 2) acrylate, R1: hydrogen atom, R2: 099108905 Form No. 1010101 Page 23 / 94 pages 0993218555-0 201039060 Ethylene Base, R3: hydrogen atom, η and 4], Μ-110 [phenol E0 modified (n and 2) acrylate, R1: hydrogen atom, R2: vinyl group, R3: p-cumyl, η and 1], Μ -111[η-mercaptobenzene Ε0 modified (η and 1) acrylic vinegar, R1: hydrogen atom, rule 2: vinyl, 1?3:11-fluorenyl, 11 and 1], --113[η - nonylphenol oxime 0 modified (η and 4) acrylate, R1: hydrogen atom, R2: vinyl group, R3: n - fluorenyl group, η and 4] or Μ-111 [η-nonyl phenol oxime 0 (epoxy Propylene) modified (η and 2.5) acrylate, R1: hydrogen atom, R2: ethylene group, R3: η-fluorenyl group, η and 2.5]. Alternatively, as the monomer represented by the general formula (5), for example, a light acrylate Ρ0-Α[phenoxyhexyl acrylate], R1: hydrogen atom, R2: vinyl group, R3: hydrogen atom, which is manufactured by Kyoei Co., Ltd., may be used. , n = l], P - 200A [phenoxy polyethylene glycol acrylate, R1: hydrogen atom, R2: ethyl sulfonyl group, R3: hydrogen atom 'η and 2], NP - 4EA [nonylphenol E0 addenda Acrylate,

Ri: hydrogen atom 'R2: vinyl group, R3: η-mercapto group, η and 4], or ΝΡ-8ΕΑ [nonylphenol oxime 0 add-on acrylate, R1: hydrogen atom, R2: vinyl 'R3: η - Sulfhydryl, η and 8] or light turtle Ρ 0 [phenol methacrylate acrylate, R1: hydrogen atom, R 2 : vinyl group, 0: hydrogen atom, η = 1] 〇 or 'as shown in general formula (5) For the monomer, for example, BLEMMER(R)-300 [Mercaptophenoxy polyethylene glycol acrylate] R1: hydrogen atom 'R2: vinyl group, r3: η-mercapto group, η and 5] can be used. , ΑΝΡ-300 [mercaptophenoxy polyethylene glycol acrylate, Ri: hydrogen atom, R2: acryl, R3: n-fluorenyl, n = 5], 43ANEP - 500 [mercaptophenoxy- Polyethylene glycol-polypropylene glycol-acrylate, hydrogen atom 2 'R: propylene group and propylene group, R3: η-fluorenyl group, η and 5+ 5], 70ΑΝΕΡ - 550 [mercaptoalkyloxy-polyethyl Glycol-polypropylene glycol-propylene 099108905 Form number Α0101 Page 24/94 pages 0993218555-0 201039060

Acid ester, R1: hydrogen atom, R2: propylene group and propylene group, R3: η-fluorenyl 'η and 9 + 3], 75ΑΝΕΡ - 600 [mercaptophenoxy-polyethylene glycol-polypropylene glycol-acrylate , R1 : a hydrogen atom, R 2 : a propenyl group and a propenyl group, R 3 : η -fluorenyl group, η 4 5 + 2], ΑΑΕ- 50 [phenoxy polyethylene glycol acrylate, R 1 : a hydrogen atom, R 2 : a vinyl group , R3: hydrogen atom, η== 1], ΑΑΕ_300 [壬 basic oxypolyethylene glycol acrylate vinegar, nitrogen atom 'R: ethylene group 'R: hydrogen atom, η and 5.5], PAE - 50 [Phenoxy polyethylene glycol methacrylate, R1: fluorenyl, R2: ethylidene 'R3: hydrogen atom' η = 2], ΡΑΕ - 1 〇〇 [phenoxy polyethylene glycol methyl Acrylate 'R1 : fluorenyl, R2: vinyl, R3: hydrogen atom, η = 2] or 43 Ρ APE - 600 Β [phenoxy-polyethylene glycol-polypropylene glycol-methacrylate, R1: methyl, R2 : vinyl and propenyl, R3: hydrogen atom, η and 6 + 6 ] 〇

Alternatively, as the monomer represented by the general formula (5), for example, NK ESTER AMP-l〇G [phenoxyethylene glycol acetoacetate (EO lm〇i), R1, manufactured by Shin-Nakamura Chemical Co., Ltd., may be used. : hydrogen atom, R2: vinyl group, r3: hydrogen atom, n = l], AMP-moving G [stupyloxyethylene glycol acrylate (E〇2mol) 'R1: hydrogen source, R2: vinyl, R3 : hydrogen atom, n and 2], AMP - 60G [phenoxyethylene glycol acrylate (Ε〇, Ri: hydrogen atom, R2: vinyl group, R3: hydrogen atom, n% 6 ] or pHE _ 1G [本EM lm〇i, R1: hydrogen atom, R2: vinyl group, r3: hydrogen atom, n=1;] 099108905 Alternatively, as a monomer represented by the general formula (5) For example, SR-339A [Phenoxyethylene glycol acrylate, R1: hydrogen atom, R, vinyl group, R3: hydrogen atom, 11 = 1] or [ethoxylated decylphenol) manufactured by Nippon Kayaku Co., Ltd. can also be used. Acrylate, R1: hydrogen atom, R2: vinyl, r3: n_mercapto 0993218555-0 Form No. A0101 Page 25 of 94 201039060

The monomer represented by the formula (5) may be a monomer represented by the above formula (5), and one type of material or two or more types may be used at the same time. All materials are available. As the monomer represented by the general formula (6), for example, FANCRYL FA-513A [dicyclopentyl acrylate, Ri: hydrogen atom 'R · no 'm = 〇] or fa - 513M manufactured by Hitachi Chemical Co., Ltd. can be used. [Dicyclopentyl acrylate, R1: hydrogen atom, R2: none, m = 0]. As the monomer represented by the general formula (6), (4) other than the ones exemplified herein may be used. In addition, it is used as a single element of the general formula (6)! Any material or two or more materials can be used at the same time. As a monomer represented by the general formula (7), for example, a scorpion made by 曰立化成公司, ^1^1^?8-511 people [dicyclopentenyl acrylate, 1:1?: a hydrogen atom, can be used. R. None 'm = 0], FA-512M [bicyclic oxiranyl acrylate 'R · hydrogen atom ' R2 : vinyl ' m = 1 ], FA _ 512A [bicyclopentaoxy methacrylate Ester 'R1: methyl 'r2: vinyl, m==1] or FA-512MT [bicyclopentaoxymethyl two _ green, r1: methyl, r2 • vinyl, m=l]. As the monomer represented by the general formula (7), materials other than those exemplified herein may be used. Further, as the monomer represented by the general formula (7), one type of material or two or more types of materials may be used at the same time. From the viewpoint of copolymerization with other precursors and the dispersibility of the pigment (B), the constituent unit (b) precursor (bl) is preferably styrene, a-mercaptostyrene, benzyl acrylate or benzyl. A methacrylate, a monomer represented by the general formula (5), a monomer represented by the general formula (6) or an early form represented by the general formula (7). Among them, especially styrene, a-methyl stupid ethylene, benzyl acrylate, benzyl methacrylate and the monomer represented by the general formula (5), since it can be 099108905 0993218555-0 form number A0101 page 26 / total 94 pages 201039060 It is particularly suitable to introduce a benzene ring into the side chain of the vinyl resin (F). The benzene ring introduced into the side chain can be aligned to form a ring-containing plane opposite to the surface of the pigment (8). Therefore, by introducing the benzene ring into the side chain of the vinyl resin (F), the rhythm of the resin pair (4) (B) can be promoted, and the aggregation of the pigment (8) can be suppressed. Further, in the case of the general formula (1), the polyethylene oxide or polyepoxyphenylene portion having a moderate length of a single system is effective as a solvent to function as an affinity site, and thus is most suitable. In the monomer represented by the general formula (5), R3 is a calcined group having 1 to 20 carbon atoms. 〇 Wei Ji's carbon number should be in the range of 1 to 10. The base of the hospital is only a direct bond base or a branch base. Further, the alkyl group may have one or more substituents containing a benzene ring in place of the hydrogen atom. In the monomer represented by the general formula (5), when the alkyl group having a carbon number of 1 to 1 Å is used as R3, the alkyl group-inhibiting vinyl resin (F) is close to each other. The adsorption of the surface of the pigment (B) by the vinyl resin (F) and the alignment of the surface of the pigment (8) with the vinyl resin (F) are promoted. However, when the carbon number of the base of the hospital exceeds 10, the effect of the steric barrier caused by the sulfhydryl group becomes large, which shows that the adsorption of the ethylene-based resin (F) on the pigment (8) or the ethylene-based tree 曰 (F) for the pigment is hindered. (B) The trend of alignment. This tendency becomes remarkable as the carbon bond of the alkyl group becomes longer, and when the carbon number exceeds 2 Å, the previous adsorption or alignment is greatly hindered. The alkyl group having a benzene ring in R may, for example, be a base group and a 2-phenyl (iso)propyl group. If a is added to the side chain of the ethylene-based resin (ρ), the solvent is The affinity and the ability to align the pigment (B) are improved. As a result, not only the dispersibility of the pigment (8) is enhanced, but also the development of the photosensitive coloring composition and the thermal fluidity of the coloring layer obtained by the coating are improved. In the monomer represented by the general formula (5), an integer of n4li15. If the increase is n, page 27, page 94, 099108905, the form number Λ0101 201039060, the affinity of the vinyl resin (F) for the solvent (E) is lowered, and the vinyl resin (F) is difficult to form a solvent with the solvent (E). As a result, the dispersibility of the pigment is lowered. From the viewpoint of solvent and medium, n should be an integer. Moreover, when η is increased, the viscosity of the vinyl resin (F) becomes high. Therefore, the viscosity of the photosensitive coloring composition containing the same becomes high, and the thermal fluidity of the colored layer may also be lowered. From the above points, in the monomer represented by the general formula (5), the cumyl oxy(poly)ethylene glycol acrylate (p-cumylphenol E 〇 denatured (η and 1) acrylate, R Hydrogen atom 'R2: alkenyl group, R3: p-cumyl (2-stupyl isopropyl), η and 1) are most suitable. The vinyl resin (F) obtained by using the monomer is excellent in the alignment property of the pigment surface due to the effect of the above-mentioned ρ electrons and the steric hindrance effect, and is easily adsorbed on the surface of the pigment. From the viewpoint of the dispersibility of the pigment (Β) and the thermal fluidity of the coloring layer, the ratio of the constituent unit (b) to the vinyl resin (j?) should be set in the range of 2 to wt%, more preferably It is in the range of 4 to 50% by weight. When the ratio is too small, it is difficult to uniformly disperse the pigment (B), and the dispersion stability of the pigment (B) may not be sufficient. When the ratio is too large, the thermal fluidity of the colored layer may not be sufficient. [Constituent unit CcOj The constituent unit (c) is a constituent unit of the vinyl resin (F) other than the constituent units (a) and (b). The constituent unit (c) mainly contributes to the formation of the above features (1) and also contributes to the excellent thermal fluidity of the colored layer. The constituent unit (C) may or may not have an ethylene bond. 099108905 When the human component (c) has a side chain, the side chain is preferably smaller than the larger annular structure constituting the main unit of the unit (b). The thermal fluidity of the colored layer is improved, and it is judged that the system is 0993218555-0. Form No. _ 帛 28 pages / Total 94 pages 201039060 Since the pigment (B) has affinity and has a large side chain constituent unit (b), and The solvent (E) has an affinity and has an addition effect of a constituent unit (c) having a small structure. The constituent unit (c) is obtained, for example, by polymerizing the following precursor (cl), and particularly by radical polymerization such as vinyl polymerization. The precursor (cl) may be a monomer having ethylene bonding other than the precursors (ai) and (a2). The precursor (cl) is, for example, a compound having an ethylene bond, and can be a constituent unit (c) by radical polymerization such as polymerization of a vinyl group. As such a precursor (cl), for example, an alkyl (mercapto) acrylate or an alkenyl (meth) acrylate can be used. As the alkyl (meth) acrylate or alkenyl (mercapto) acrylate, for example, methyl (mercapto) acrylate, ethyl (meth) acrylate, propyl (methyl. Acetate, isopropyl (decyl) acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, tertiary butyl (meth) acrylate, isopentyl ( Methyl) acrylate, octyl (mercapto) acrylate 'isooctyl (meth) acrylate, 2-ethylhexyl (decyl) propyl:: enoic acid g, sixteen yards Acrylate, mercapto (mercapto) acrylate, decyl decyl acrylate, isostearyl hydrazine (meth) acrylate, cyclohexyl (meth) acrylate, allyl (methyl) Acrylate, oleyl acrylate. These may be used alone or in combination of two or more. From the viewpoint of the dispersibility of the pigment (B) and the thermal fluidity of the coloring layer, the side chain of the constituent unit (c) should be short. It is preferable to obtain methyl (meth) acrylate or ethyl (meth) acrylate as a precursor of 5 重量% or more of the constituent unit (c). Other monomers can also be used as the precursor (cl). As another monomer, it can be exemplified by 099108905, Form No. A0101, Page 29/94, 0993218555-0 201039060, for example, tetrahydroindenyl (meth) acrylate or 3 _ _ _ 3 oxetanyl (meth) acrylate (meth)acrylates having a heterocyclic substituent, such as esters, alkoxy polyalkylene glycols such as methoxypolypropylene glycol (meth) acrylate and ethoxypolypropylene glycol (meth) acrylate (meth) acrylates, or (meth) acrylamide, N, N-dimethyl (meth) acrylamide, N, N-diethyl (meth) acrylamide, N- A propyl (meth) acrylamide-propanol-ol (meth) acrylamide and a propyl linoleine (meth) acrylamide. Other monomers may be further used as the precursor (cl). Further, examples of the other monomer include vinyl ethers such as ethyl vinyl ketone, ethyl ether, isopropyl vinyl ether, η-butyl vinyl ether, and isobutyl vinyl ether, and fatty acid vinyls such as vinyl acetate and vinyl propionate. . When the vinyl resin (F) is introduced into the ethylene bond, a monomer having an epoxy group or a monomer having a hydroxyl group can also be used as the precursor (cl). However, depending on the modification, some of the monomers may not be utilized as constituent units (c). Therefore, when using such a monomer, it is necessary to consider the influence of the reaction on the weight ratio of the constituent units (^ to (c)~ from the viewpoint of the dispersibility of the pigment and the heat flow of the colored layer, the constituent unit ( c) The ratio of the vinyl resin (F) should be in the range of 1 Torr to 8% by weight, more preferably in the range of 25 to 80% by weight. The ratio is over hour, and the heat flow of the colored layer When the ratio is too large, it is difficult to uniformly disperse the pigment (B). [Polymerization of Vinyl Resin (F)] The vinyl resin (F) is obtained by subjecting the above monomers to radical copolymerization. Bulk polymerization or solution polymerization using a radical polymerization initiator is generally carried out. 099108905 Form No. A0101 Page 30/94 9493218555-0 201039060 The radical polymerization initiator is set to 100 parts by weight. It is preferably used in an amount of from 0.001 to 5 parts by weight. The reaction temperature of the radical polymerization is preferably from 40 to 150 ° C, more preferably from 50 to 110 ° C. The reaction time of the radical polymerization is preferably from 3 to 30 hours, more preferably It is preferably 5 to 20 hours. As a radical polymerization initiator For example, an azo compound or an organic peroxide can be used. Examples of the azo compound include 2,2'-azobisisobutyronitrile and 2,2'-azobis(2-mercaptobutyronitrile). 1,1'-azobis(cyclohexane-1-carboxonitrile), 2,2'-azobis(2,4-dimethylvaleronitrile), 2,2'-azobis (2, 4 -Dimethyl-4 -methoxyvaleronitrile), dimethyl 2, 2'-azobis(2-mercaptopropionate), 4,4'-azobis(4-cyanovaleric acid) ), 2,2'-azobisC2-hydroxyindolyl nitrile) and 2,2'-azobis[2_(2-flavor. sitin_2_yl)propane]. Examples of the organic peroxide include benzoquinone peroxide, tertiary butyl peroxydiperoxide, diisopropyl peroxycarbonate, di-n-propyl peroxycarbonate, and di(2-ethoxyB). Peroxycarbonate, tertiary butyl peroxy neoacetate, (3,5,5-trimethylhexyl) peroxide, dipropyl hydrazine peroxide and diethyl hydrazine peroxide . These polymerization initiators can be used singly or in combination of two or more. The radical polymerization can be carried out without a solvent or using a solvent. As the solvent, for example, ethyl acetate, n-butyl acetate, isobutyl acetate, toluene, xylene, acetone, ketone, methyl ethyl ketone, cyclohexanone, propylene glycol monomethyl ether ethyl ester, dipropylene glycol monoterpene can be used. Ethyl ether ethyl ester, ethylene glycol monoethyl ether ethyl ester, ethylene glycol monobutyl ether ethyl ester, diethylene glycol monoethyl ether ethyl ester or ethylene glycol monobutyl ether ethyl ester. These solvents may be used alone or in combination of two or more. The amount of the solvent is preferably in the range of 0 to 300 099108905, part number A0101, page 31, 94 page 0993218555-0 201039060, more preferably in the range of 0 to 100 parts by weight, when the total amount of the monomer is 100 parts by weight. In the range. The solvent after use is removed after the completion of the reaction by distillation or the like, and may be used as a part of the product. [Incorporation of ethylene into the vinyl resin (F)] When ethylene is introduced into one or more of the constituent units (a) to (c), the dispersibility of the pigment, the thermal fluidity of the colored layer, and the pattern shape are not deteriorated. The bridging density of the colored layer can be increased, so that the tolerance of the color filter can be improved. Further, the following reaction can be carried out using a conventional catalyst. <Introduction of ethylene bond to constituent unit (a)> As a method for introducing ethylene bond in the constituent unit (a), for example, by introducing a precursor (bl), a precursor (cl), and a monomer having an epoxy group The method of copolymerizing the side chain epoxy group of the copolymer, reacting the retardation group of the unsaturated monovalent acid, and reacting the generated hydroxyl group to the polyvalent acid anhydride as needed. In this case, the ethylene monomer having an epoxy group as a constituent unit of the precursor may be a constituent unit containing ethylene (a) ° as a monomer having an epoxy group, and examples thereof include a transoxypropyl group. (Meth) acrylate, decyl epoxy propyl (meth) propylene sulphate, 2-glycidoxy (decyl) acrylate, 3, 4 epoxy butyl (meth) acrylate, and 3 , 4 epoxy cyclohexyl (meth) acrylate. These may be used alone or in combination of two or more. The viewpoint of reactivity with an unsaturated monovalent acid in the next step is preferably a glycidyl (meth) acrylate. Examples of the unsaturated monovalent acid include (meth)acrylic acid, crotonic acid, hydrazine-, m- or p-vinylbenzoic acid, and (meth)acrylic acid &amp; halothane, alkoxy, halogen, A monocarboxylic acid such as a nitrate or a cyanide substitute. These may be used alone or in combination of two or more. 0993218555-0 099108905 Form No. A010丨 Page 32 of 94201039060 Examples of the polyvalent acid anhydride include tetrahydrobenzene acid Sf, phthalic acid needle, hexahydrophthalic anhydride, succinic anhydride, and maleic anhydride. Wait. These may be used alone or in combination of two or more. When necessary, for example, when the number of carboxyl groups in the constituent unit (a) is increased, a tricarboxylic acid anhydride such as trimellitic anhydride or a tetracarboxylic dianhydride such as pyromellitic dianhydride may be used, and a hydroxyl group may be used. The anhydride group not used in the reaction is hydrolyzed. Further, when tetrahydrophthalic anhydride or maleic anhydride is used as the polyvalent acid anhydride, more ethylene bonds can be introduced by the constituent unit (a). <Incorporation of ethylene into the constituent unit (b)> As a method of introducing ethylene into the constituent unit (b), for example, in addition to the monomer represented by the general formula (7) or R3 having an ethylene bond, the use and the general formula are employed. (5) A method in which the monomer having the same structure is used as a copolymer of the constituent (b) precursor (bl). However, the ethylene combination contained in the precursor (bl) may be used in the polymerization. Since the reactivity of the ethylene bond in the ring structure is low, when the ethylene component is introduced into the constituent unit (b), it is preferred to use a monomer as shown in the formula (7) as a precursor (b1). A monomer having ethylene bonds in the structure. <Introduction of ethylene bond to the constituent unit (c)> As a method for introducing ethylene into the constituent unit (c), for example, a monomer having a hydroxyl group is used as a part of the constituent (c) precursor (cl). A method of copolymerizing a hydroxyl group in a side chain of a copolymer to react an isocyanate group of a monomer having an isocyanate group. As another method of introducing ethylene into the constituent unit (c), for example, the monomer having the epoxy group is used as a part of the constituent (c) precursor (cl), and copolymerized in the side chain of the copolymer. The epoxy group is subjected to an additional reaction of the carboxyl group of the above unsaturated monovalent acid, and further to the hydroxyl group, so that the isocyanate of the monomer of the cyanate vinegar having the different 099108905 Form No. A0101 Page 33 / 94 page 0993218555-0 201039060 The method of base reaction. Examples of the monomer having a hydroxyl group include 2-hydroxyethyl (meth)acrylic acid vinegar, 2- or 3-hydroxypropyl (meth) acrylate, 2- or 3- or 4-hydroxybutyl group (A). Bases (meth)propionates such as acrylates, glycerol (meth) acrylates and cyclohexane-sintered dimethanol mono(methyl)propionate. These may be used alone or in combination of two or more. Further, it can also be used in the above hydroxyalkyl (meth) acrylate, and the polyether mono(meth)acrylic acid obtained by additionally polymerizing an ethylene peroxide, an acryl peroxide, and/or a butyl peroxide. An ester, or a (poly)ester mono(meth)acrylate to which (poly)g-valerolactone, (poly)e-caprolactone, and/or (poly)12-hydroxystearic acid are added. From the viewpoint of the dispersibility of the pigment and the thermal fluidity of the coloring layer, it is preferably 2-hydroxyethyl (meth) acrylate or glycerol (methyl) acrylate vinegar. The monomer of the isocyanate group may, for example, be 2-indolylmethyl)acryloyloxyethyl isocyanate or 1,1-bis[(indenyl)propenyloxy]ethyl isocyanate. Other monomers may also be used as the monomer having an isocyanate group. Further, these may be used alone or in combination with two or more types. Further, from the viewpoint of dispersibility of the pigment and thermal beading of the coloring layer, 2-hydroxyethyl (meth) acrylate or glycerol (meth) acrylate is used as a constituent unit (c) precursor It is also suitable to use a part of (cl) for copolymerization, and a vinyl group-based resin (J?) obtained by reacting a hydroxyl group of a side chain of the copolymer with 2-hydroxyethyl(mercapto)acrylic acid vinegar. [Introduction of a carboxyl group to a vinyl resin (F) using a polyvalent acid anhydride] From the viewpoint of achieving both excellent thermal fluidity of a color layer and good reworkability with a substrate such as a glass substrate, it is preferable to use a vinyl resin (F). The valence acid 0993218555-0 anhydride is introduced into the carboxyl group. The polyvalent acid anhydride can be used singly or in combination of two or more. 099108905 Form No. A0101 Page 34 of 94 201039060 The method of introducing a carboxyl group in the constituent unit (a) using a polyvalent acid anhydride is described above in connection with the introduction of ethylene in the constituent unit (a). Further, it is not necessary to constitute a unit (a). When ethylene is introduced, a saturated monovalent acid may be used instead of the unsaturated monovalent acid. Further, when it is not necessary to introduce ethylene into the constituent unit (a), a carboxyl group may be introduced into the vinyl resin (F) using a polyvalent acid anhydride by another method. Namely, first, an epoxy group-containing monomer is subjected to an additional reaction such as a carboxyl group of an unsaturated monovalent acid, and a polyvalent acid anhydride is reacted with the generated hydroxyl group as needed. Thereby, a constituent unit (a) containing a carboxyl group can also be produced. ^ An additional reaction of a carboxyl group of an unsaturated monovalent acid with an epoxy group is carried out by gelation of a polyvalent acid anhydride with a hydroxyl group, and is added so that the residual ratio of the epoxy group of the vinyl resin (F) becomes, for example, 20 %the following. The residual ratio of the epoxy group is preferably small, and the total amount of the epoxy group is preferably consumed in the reaction. Further, the additional reaction of the polyvalent acid anhydride with the hydroxyl group is preferably 10 to 100%, more preferably 20 to 100%, of the hydroxyl group of the copolymer, and more preferably reacted with the polyvalent acid anhydride. When the ratio of the hydroxyl group in which the additional reaction occurs is small, it may be difficult to achieve excellent developability and good reworkability. Further, the addition of an excessive amount of the polyvalent acid anhydride causes a polyvalent acid anhydride to remain in the vinyl resin (F), which is not preferable. Examples of the monomer having an epoxy group include glycidyl (meth) acrylate, methyl glycidyl (f-) acrylate, 2-glycidylethyl (meth) acrylate, and 3 , 4 epoxybutyl (meth) acrylate and 3, 4 epoxy cyclohexyl (meth) acrylate. These may be used alone or in combination of two or more. From the viewpoint of the reactivity with the unsaturated monovalent-acid in the next step, it is preferred to be glycidyl (mercapto)acrylic acid. As the unsaturated monovalent acid, for example, (meth)acrylic acid, crotonic acid 099108905, form number Α0101, page 35/94, 0993218555-0 201039060, ο-, m- or p-ethyl benzoic acid, A monocarboxylic acid such as a-halogenane, alkoxy, halogen, nitrate, or a cyanide substitute of methyl)acrylic acid. These may be used alone or in combination of two or more. It is preferred to use (meth)acrylic acid. The polyvalent acid anhydride may, for example, be tetrahydro succinic anhydride, succinic anhydride, hexahydro succinic anhydride, succinic anhydride or maleic anhydride. These may be used alone or in combination of two or more. When necessary, for example, when the number of carboxyl groups in the constituent unit (a) is increased, a tricarboxylic anhydride such as trimellitic anhydride or a tetracarboxylic dianhydride such as tetraphenyltetrasuccinic anhydride may be used, and a reaction with a hydroxyl group may be used. The anhydride group not used is hydrolyzed. It is advisable to use a tetrahydrogen diacid needle. Furthermore, the ratio of the content of the compound to the polyvalent acid Sf in the radical is changed according to the ratio of the hydroxyl group to the carboxyl group present in the reaction. Then, the polyhydroxy acid anhydride is added to the hydroxyl group. The system forms a constituent unit (a) by introducing a carboxyl group. On the other hand, a system in which a polyvalent acid anhydride is not introduced into a hydroxyl group forms a constituent unit (c). Compared with the carboxyl group of the former ruthenium, for example, from (meth)acrylic acid, the base of the vinyl group (F) introduced by the additional reaction of the base group and the polyvalent acid needle is compared with the main chain of the vinyl group (F). It is long and therefore not susceptible to steric obstacles. Further, since the carboxyl group is excellent in affinity with a redosolution such as a strong alkali aqueous solution, the reducible liquid rapidly permeates the coating film having a high bridging density by exposure, and the coating film is swollen, reacted, and dissolved rapidly. Further, in the case where a functional group which reacts with a carboxyl group is present in the photosensitive coloring composition, in the post-baking, the functional group is bridged even if a part of the carboxyl group is introduced by using a polyvalent acid anhydride, and the bridging portion is bridged. The distance from the main chain of B 099108905 dilute base resin (1) is long, so it does not hinder the penetration of the redo liquid on the coating film on Form No. A0101 Page 36 of 94. Therefore, in this case, the removal of the coating film is also performed quickly. [E. 3 of the ethylenic resin (F): average molecular weight mw] From the viewpoint of achieving both excellent developability of the coating film and excellent thermal fluidity of the colored layer. The weight average molecular weight Mw of the vinyl eucalyptus (F) is preferably in the range of from 2,000 to 20,000' more preferably in the range of from 4 Å to 19 Å. When the weight average molecular weight Mw is too small, the optimum development time may be too short, or the pattern may not be sufficient for the adhesion of the substrate. When the weight average molecular weight Mw is too large, the 'optimal development time may be too long, or the thermal fluidity of the colored layer may not be enough. "Pigment (B)", the pigment (B) is an organic pigment of organic matter or inorganic of inorganic t-yang. The pigments may or may be a mixture thereof. As the organic pigment and the inorganic pigment, a substance called a dye is generally used or a natural pigment can be used. Among these, an organic pigment is suitably used, and it is excellent in heat resistance and color rendering property. <Organic Pigment> .1 Hereinafter, a specific example of the organic pigment is indicated by a color index number. For forming a red color filter segment, the red color. The color composition can be used, for example, CI Pigment Red 7, 9, 14, 41, 48: 1 '48: 2, 48: 3, 48: 4, 81 : 1, 81 : 2, 81 : 3, 97, 122, 123, 146, 149, 168, 177, 178, 180, 184, 185, 187, 192, 200, 202, 208, 210, 215, 216, Red pigments such as 217, 220, 223, 224, 226, 227, 228, 240, 242, 246, 254, 255, 264 and 272. In the red coloring composition, in addition to the red pigment, it can be used together with the yellow pigment and the orange pigment. Form No. A0101 Page 37/94 (10)(10) 201039060 In the red coloring composition, the yellow pigment which can be used together with the red pigment can be, for example, CI Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 12 , 13, 14, 15, 16, 17, 18, 20, 24, 31, 32, 34, 35, 35: 1, 36, 36: 1, 37, 37: 1, 40, 42, 43, 53, 55 , 60, 61, 62, 63, 65, 73, 74, 77, 81, 83, 86, 93, 94 '95, 97, 98, 100 '101, 104, 106, 108, 109, 110, 113, 114 , 115, 116, 117, 118, 119 '120, 123, 125, 126, 127 '128, 129'137, 138, 139, 147, 150, 151, 152, 153, 154, 155, 156, 161, 162 , 1|4, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, Π 9, 180, 181, 182, 185, 187, 188, 193, 194 and 199. Among these, c. I. Pigment Yellow 138, 139, 150 and 185 are preferred. In the red photosensitive coloring composition, the orange pigment which can be used together with the red pigment can be, for example, C.I.P.igment:::#range 36, 43, 51, 55, 59, 61 and 71. For the green coloring composition for forming a green filter segment, for example, C.I. Pigment Green 7, 10, 36, 37, and 58 can be used. In addition to the green pigment, the green coloring composition can also be used together with the yellow pigment. Among the green coloring compositions, yellow pigments which can be used together with the green pigment include, for example, CI Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 12, 13, 14, 15, 16, 17, 18 , 20, 24, 31, 32, 34, 35, 35: 1, 36, 36: 1, 37, 37: 1, 40, 42, 43, 53, 55, 60, 61, 62, 63, 65, 73 , 74, 77 099108905 Form No. A0101 Page 38 / 94 9493218555-0 201039060, 81, 83, 86, 93 ' 94 '95, 97 ' 98, 100, 101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 125, 126, 127, 128, 129, 137, 138, 139, 147, 150, 15 152, 153, 154, 155, 156, 16 162, 164, 166, 167, 168, 169, 170, 17 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 187, 188, 193, 194 and 199. Among them, C. I. Pigment Yellow 138, 139, 150 and 185 are preferred.

Blue coloring composition for forming a blue filter segment, use case

Such as C. I. Pigment Bluel5, 15:1, 15:2, 15:3, 15:4, 15: 6, 16, 22, 60 and 64 cyan pigments. In the blue colored composition, in addition to the blue pigment, C. L can be used at the same time.

Pigment Violet 1, 19, 23, 27, 29, 30, 32, 37, 40, 42 and 50 purple pigments. The yellow colored composition yang used to form the yellow filter segment can be used

Such as CI Pi g:ment Ye 11 ow' 1,2,3,4,5,6,10,12,13,14,15,16,17,18,20,24,3,32,34,35, 35 : 1, 36, 36 : 1, 37, 37 : 1, 40, 42, 43, 53, 55, 60, 61, 62, 63, 65, 73, 74, 77, 81, 83, 86, 93, 94, 95, 97, 98, 100, 101, 1〇4, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120, 123, 125, 126, 127, 128, 129, 137, 138, 139, 147, 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 099108905 Form No. A0101 Page 39 / 94 9493218555-0 201039060 181 ' 182, 185, 187 ' 188, 193, 194 and 199 yellow pigments. For the orange coloring composition for forming the orange color filter section, orange pigments such as C.I. Pigment Orange 36, 43, 51, 55, 59, 61 and 71 can be used. For the cyan coloring composition for forming the cyan filter and the light sheet section, a blue pigment such as C.I. Pigment Blue 15 : 1 , 15 : 2 , 15 : 4 , 15 : 3 , 15 : 6, 16 and 81 can be used. For the magenta colored composition for forming the magenta filter segment, for example, a violet pigment such as C.I. Pigment Violet 1 and 19, and a red pigment such as C.I. Pigment Red 144, 146, 177, 169 and 81 can be used. In the magenta colored composition, in addition to the purple pigment and the red pigment, the same yellow pigment as described above may be used simultaneously with respect to the yellow colored composition for forming the yellow filter segment. <Inorganic Pigments and Dyes> In order to achieve a balance between chroma and brightness, it is also possible to use an inorganic pigment in combination with an organic pigment in combination with the coating property and sensitivity of the good boat. Examples of the inorganic pigment include metal oxide powder such as yellow lead, zinc yellow, purple red paint (red iron oxide (III)), cadmium red, ultramarine blue, indigo, chrome oxide green, and cobalt green, metal sulfide powder, and metal powder. Wait. Further, in the above-mentioned photosensitive coloring composition, a dye may be contained in a range which does not lower the heat resistance for coloring. <Black pigment for light-shielding layer> A light-shielding layer of a black matrix, for example, can be formed as a pigment (B) from a photosensitive coloring composition containing black 099108905 color pigment. As the black pigment, for example, Mitsubishi Chemical Corporation can be used. Carbon Black #24〇〇,# 235〇,# Form No. A0101 Page 40/94 List 0993218555-0 201039060 2300, #2200, #1 000, #980, #970, #960,#950,#900, #850, MCF88, #650, MA600, MA7, MA8, MA11, MA100, MA220, IL30B, IL31B, IL7B, IL11B, IL52B, #4000, #4100, #55, #52, #50, #47, #45 , #44, #40, #33, #32, #30, #20, #10, #5, CF9, #3050, #3150, #3250, #3750, # 3950 ' DIABLACK A, DIABLACK N220M ' DI- ABLACK N234 ' DIABLACK I &gt; DIABLACK LI ' DIAB-LACK II , DIABLACK N339 , DIABLACK SH , DIABLACK SHA , DIABLACK LH , DIABLACK H , DIABLACK HA , DIABLACK SF-DIABLACK N550M 'DIABLACK E ' DIABLACK G'DIABLACK R ' DIABLACK N760M 'DIABLACK LR ; CANCAVE company's carbon black THERMAX Ν99Ό, N99 Bu N907, N908, N990, N9 91 or N908; A_HI CARBON company's carbon black Asahi #80, Asahi #70, Asahi #70L·, Asahi F-200, Asahi #66, Asahi #66HN, Asahi #β〇Η, Asahi #60U, Asahi #55 , Asahi #50H, Asahi #51, Asahi #50ϋ, Sister #50, Asahi #35, Asahi #15 or ASAHI THERMAL; or DEGUSSA's carbon black Color Black Fw200 'Color Black Fw2 ' Color Black Fw2V ' Color Black Fwl ' Color Black Fwl8 ' Color Black S170 ' Color Black S160 ' Special Black 6 ' Special Black 4 ' Special Black 4 ' Special Black 4 ' Special Black 250 ' Special Black 350 , Printex U , Printex V , Printex 140U , Printex 140V One is the name of the product). <Pigment Dispersant> 099108905 Form No. A0101 Page 41 of 94 0993218555-0 201039060 In order to uniformly disperse the pigment in a solvent, a pigment derivative can also be used as at least a part of the pigment. Further, the pigment derivative is, for example, an organic pigment obtained by introducing a substituent having affinity for a solvent. In the case where the pigment derivative is used together with a general pigment, the dispersibility is improved. That is, the pigment derivative can function as a pigment dispersant. Alternatively, a pigment dispersant such as a pigment, a resin type dispersant or a surfactant may be used in order to uniformly disperse the pigment in a solvent. The pigment dispersant is excellent in the ability to disperse the pigment and prevent the re-coagulation of the dispersed pigment. Therefore, if the ruthenium pigment dispersant is used, a filter segment excellent in transparency can be obtained. The pigment dispersant is used in a ratio of, for example, 0.1 to 30 parts by weight of the pigment 100 parts by weight. <Pigment Derivative> The pigment derivative is, for example, a compound represented by the following general formula (8). Pigment derivatives include those having an illustrative displacement group and those having an acidic substituent. General formula (8):

X - Y Further, in the general formula (8), X is an organic pigment residue, and Y is a basic substituent or an acidic substituent. As the pigment derivative, for example, JP-A-63-30551, JP-A-57-151620, JP-A-59-401, 72, JP-A-63-121-02, and JP-A Fair 5 - 9469. These may be used alone or in combination of two or more. When a pigment derivative is used together with a general pigment, the pigment derivative pigment derivative is a total of 100 parts by weight of the pigment derivative and the general pigment, 099108905 Form No. A0101 Page 42 / 94 pages 0993218555-0 201039060 0. Use a ratio of 5 to 25 parts by weight. When the ratio is too small, the effect of improving the dispersibility of the pigment is small. When the ratio is too large, the heat and light resistance of the colored layer may not be sufficient. In the general formula (8), as the organic pigment constituting the organic pigment residue X, for example, an azo-based pigment such as diketopyrrolopyrrole, disazo, or polyazo; copper phthalocyanine, toothed copper phthalocyanine, and the like can be used. a titanium-based pigment such as a metal-free phthalocyanine; an onion-based pigment such as anthraquinone, diamine dioxime, pyrimidine, xanthone, indolinone, standard reduction blue, furanone, anthrone violet dye; Quinacone pigment; quinophthalone pigment; dithiazine pigment; dioxopyrrolopyrrole pigment; anthraquinone pigment; anthraquinone pigment; thioindigo pigment; thiazin indigo pigment; a pigment; an isoindolinone pigment; a quinophthalone pigment; a durene pigment; or a metal complex pigment. <Resin-type pigment dispersant> 〇 The resin-type pigment dispersant has a pigment affinity site having a property of adsorbing to a pigment and a site compatible with a pigment carrier. Resin type pigment The dispersant functions to adsorb to the pigment to stabilize the dispersion of the pigment to the pigment carrier (dispersion medium). The resin type pigment dispersant can be classified into a polyethylene type, a polyurethane type, a polyester type, a polyether type, a formalin condensation system, an anthracene group or a composite dispersant. Examples of the pigment affinity site include a polar group such as a carboxyl group, a hydroxyl group, a phosphoric acid group, a phosphate group, a sulfone group, a hydroxyl group, an amine group, a quaternary ammonium salt group or a guanamine group, and a polyperoxyethane or poly group. Hydrophilic polymer chains such as peroxypropane and such composites. Further, examples of the site compatible with the dye carrier include a long-chain alkyl chain, a polyethylene chain, a polyether chain, and a poly-chain. 099108905 Form No. 101 0101 Page 43 / 94 9493218555-0 201039060 The resin type dispersant may, for example, be a styrene-maleic anhydride copolymer, a dilute hydrocarbon-cis-succinic anhydride copolymer, or a poly(methyl group). Acrylate, styrene-(meth)acrylic acid copolymer, (meth)acrylic acid alkyl (meth)acrylate copolymer, (meth)acrylic acid-polyethylene polymer copolymer, phosphate ester-containing Dilute resin, fumarin condensate containing aromatic carboxy acrylate resin, polystyrene salt, acrylamide-(meth)acrylic acid copolymer, carboxy-mercapto cellulose, polyurethane-naphthoate with carboxyl group Or an anionic resin type pigment dispersant such as alginic acid soda; a nonionic resin type pigment dispersant such as polyvinyl alcohol, polyalkylene polyamine, polyacrylamide or polymer powder; or polyethyleneimine, A cationic resin type pigment dispersant such as an aminoalkyl (meth) acrylate copolymer, a polyethylene imidazoline, a polyurethane having an amine group, a poly(lower alkylenimine), and a reaction product of a polyester having a free carboxyl group. These may be used alone or in combination of two or more. As a commercially available resin type pigment dispersant, for example, Disperbyk-101, 103, 107, 108, 110' 111, 116, 130, 140, 154, 161, 162, 163, 164, 165 manufactured by BYK-Chemi e Co., Ltd. can be used. , 166, 170, 171, 174, 180, 181, 182, 183, 184, 185, 190, 2000, 2001, 2020, 2090, 2091, 2164 or 2163, or person 111: Buding 61^3-11, 203 Or 204, or 8 ¥ 1 (-? 104, P104S or 220S, or Lactimon or Lactimom-WS, or Byku-men; SOLSPERSE 3000, 9000, 13240, 13650, 13940, 17000, 18000, 20000 manufactured by Lubrizol, Japan , 21000, 24000, 26000, 27000, 28000, 31845, 32000, 32500, 32600, 34750, 36600, 38500, 41 000, 41090 or 53095; or EFKA-46 '47, 48, 452, LP4008, manufactured by EFKA Chemicals, 4009 , LP4010 , LP4050 ' 099108905 Form No. A0101 Page 44 / Total 94 Page 0993218555-0 201039060 LP4055, 400, 401, 402, 403, 450, 451, 453, 4540, 4550, LP4560, 120, 150, 1501, 1502 Or 1 503. It can also be used as a pigment dispersant. In addition, these may be used singly or in combination of two or more kinds. <Interacting Agent> ❹ As the surfactant, for example, polyethylene oxide ether sulfate or dodecylbenzene Sodium acrylate, acetophenone-propionic acid copolymer, sodium morphine naphthalene sulfonate, sodium alkyl diphenyl ether disulfonate, ethanolyl lauryl sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate , anionic surfactants such as stearic acid ethanolamine, ammonium stearate, sodium lauryl sulfate, phenethyl: olefin-acrylic acid copolymer ethanolamine, polyethylene oxide ether phosphate ether;

Cationic surfactants such as polyethylene oxide oleyl ether, polyethylene oxide lauryl ether, poly(ethylene oxide decyl phenyl ether), polyethylene oxide ether phosphate, polyethylene oxide sorbitol glycerol stearic acid a raw rubber dry-running surfactant such as an alkyl 4-grade ammonium salt or an ethylene oxide additive thereof; an alkyl dimethylamine acetic acid quaternary ammonium carboxylate inner salt or the like; Bisexual surfactants such as Jimmy Lin. These can be used alone or in combination of two or more. <<Active energy ray polymerization initiator (C)>> The active energy ray polymerization initiator (C) is, for example, a photopolymerization initiator which imparts a property of curing a resin by irradiation with active energy rays such as ultraviolet rays and electron beams. The active energy ray polymerization initiator (C) is preferably used in a ratio of 5 to 200% by weight for the pigment (B), and is more preferably for the pigment (B) from the viewpoint of inductivity and developability to the active energy ray. It is used in a ratio of 150% by weight. As the active energy ray polymerization initiator (C), for example, acetamidine-based activity 099108905 can be used. Form No. A0101 Page 45 / 94 pages 〇 9932 丨 8555-〇201039060 Energy-line polymerization initiator, benzo-based active energy ray Polymerization initiator, benzophenone-based active energy ray polymerization initiator, thioxanthone-based active energy ray polymerization initiator, triazine-based active energy ray polymerization initiator, and borate ester-based active energy ray polymerization A starter, a carbazole-based active energy ray polymerization initiator or a bismuth-based active energy ray polymerization initiator. Examples of the benzene-based active energy ray polymerization initiator include, for example, 4-phenoxy-phenoxyphenethyl hydrazide, 4-t-butyldifluorophenylene ketone, diethoxy phenethyl _, 1- (4-isopropylphenyl)-2-hydroxy-2-methylpropanyl ketone, hydroxycyclohexyl benzophenone, 2-benzyldimethylamine-i-(4-morpholinylphenyl)_ Butane-1 -one or 2-mercapto-bu [4-tf-decyl) phenyl]-2-morpholinepropan-1-one. The benzoic active energy ray polymerization initiator may, for example, be benzo, benzo- & $, benzoethyl ether, benzoisopropyl ether or benzylidene dimethyl ketal. Examples of the benzophenone-based active energy ray polymerization initiator include dibenzophenone, alum benzoic acid, benzoquinone benzoic acid methyl, 4-phenylbenzophenone, and hydroxybenzophenone Arachidonic dimercapto ketone or 4-cracked 4-, 4-methyldiphenyl sulfide. Examples of the thioxanthene-based active energy ray-deficient initiator include, for example, 嗟 酿 j j, 2-gas α 嘲 嘲 steel, 2- 曱 售 售 、, isopropyl sinone, 2, 4 Isopropyl oxime _. Examples of the triazine-based active energy ray polymerization initiator include, for example, 2,4,6-diox-secondary three-noise, 2-phenyl-4,6-bis(dipyrene)-secondary three. Qin, 2-(p-methoxyphenyl) 4,6-bis(trimethylmethyl)-secondary triazine, 2-(p-tolyl) 4,6-bis(trimethyl)-sub-three Pyrazine, 2-piperidin-4,6-bis(trimethyl)-secondary triazine, 2,4-bis(trismethyl)-6-stupyl-sub-triterpenoid, 2- (naphtho-l-yl)-4,6-double (3,099,108,905 Form No. A0101, page 46/94, 0993218555-0 201039060 chloromethyl)-Secondary triazine, 2-(4-decyloxynaphthalene) And-l-yl)-4,6-bis(trichloromethyl)-secondary triazine, 2,4-trichloromethyl-(piperidyl)-6-triazine or 2,4-trisole Base (4'-methoxystyryl)-6-triazine. These may be used alone or in combination of two or more. A sensitizer can be used simultaneously with the active energy ray polymerization initiator (C). As the sensitizer, for example, an a-decyloxy bond, a mercaptophosphoric acid hydroxide, anthracene phenylglyoxylic acid, benzyl-9,10-phenanthrene, anthraquinone, an ethyl hydrazine, 4, 4'-diethyl phenol ketone, 3,3',4,4' - Ο tetrakis(tert-butylperoxycarboxy)benzophenone, 4,4-dimethylamine dibenzophenone . When the active energy ray polymerization initiator (C) and the sensitizer are simultaneously used, the sensitizer is preferably used in an amount of from 3 to 60% by weight for the active energy ray polymerization initiator (C), from the active energy ray. The viewpoint of inductivity and developability is preferably used in a ratio of 5 to 50% by weight for the active energy ray polymerization initiator (C). <Active energy ray-curable monomer (D)&gt; 活性 The active energy ray-curable monomer (D) is a monomer and/or oligomer which is cured by irradiation with an active energy ray to form a resin. As the active energy ray-curable monomer (D), for example, a linear or branched alkyl (meth) acrylate, a cyclic alkyl (meth) acrylate, or a fluoroalkyl (meth) acrylate can be used. Ester, (meth) acrylate having a hetero ring, (meth) acrylate having an aromatic ring, (poly) olefin diol monoalkyl ether (meth) acrylate, having a carboxyl group (Meth) acrylates, (hydroxy) acrylates having hydroxyl groups, (poly) alkene diol bis(indenyl) acrylates, di(meth) acrylates, having an amine group of 3,099,108,905 (Mercapto) acrylates, trifunctional or higher polyfunctional (methyl form number A0101, page 47 / 94 pages 0993218555-0 201039060) acrylate, epoxy (fluorenyl) acrylate, (fluorenyl) A propylene oxime modified resin condensed polymer, ethylene, vinyl ether, guanamine or acrylonitrile as a linear or branched alkyl (mercapto) acrylate, for example, a sulfhydryl group can be used. Methyl) acrylate, ethyl (meth) acrylate, C (fluorenyl) acrylate, isopropyl (meth) acrylate, butyl (meth) acrylate, isobutyl (meth) acrylate, tertiary butyl (fluorenyl) acrylate , isoamyl (mercapto) acrylate, octyl (decyl) acrylate, isooctyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, hexadecyl (a Acrylate, mercapto (meth) acrylate, isodecyl (meth) acrylate, lauryl (methyl hydrazine); dilute acid, thirteen (decyl) acrylate, isoform Alkyl (fluorenyl) propylene ester, hard ester cerium (meth) acrylate and hard ester cerium (meth) acrylate. Examples of the cyclic alkyl (meth) acrylate include cyclohexyl (meth) acrylate, tert-butylcyclohexyl (meth) acrylate, and dicyclopentyl (mercapto) propyl acrylate. Vinegar, one-ring penta-milk ethyl (meth) propionate vinegar, dicyclopentenyl (meth) acrylate, dicyclopentene oxyethyl (mercapto) acrylate and isobornyl (methyl) )Acrylate. Examples of the fluoroalkyl (meth) acrylate include trifluoroethyl (meth) acrylate vinegar, octfluentyl (meth) acrylate acid, and perfluorooctylethyl ( Methyl) acrylate and tetrafluoropropyl (decyl) acrylate. Examples of the (meth) acrylate having a hetero ring include tetrahydroindenyl (meth) acrylate and 3-methyl-3-oxetanyl (meth) acrylate vinegar. Examples of the (fluorenyl) acrylate having an aromatic ring include a sulfhydryl acrylate, a phenoxyethyl acrylate, and a phenoxy 099108905. Form No. A0101 Page 48 / Total 94 pages 0993218555-0 201039060 polyethylene glycol (fluorenyl) acrylate, p-cumyloxyethyl (meth) acrylate, p-cumyl phenoxy polyethylene glycol (mercapto) acrylate and Nonylphenoxy polyethylene glycol (meth) acrylate. Ο Ο 099108905 The (poly)olefin-based diol monoalkyl ether (meth) acrylate may, for example, be 2-methoxyethyl (indenyl) acrylate or 2-ethoxy (indenyl). Acrylate, 3-methoxybutyl (meth) acrylate, 2-methoxypropyl (meth) acrylate, diethylene glycol monodecyl ether (meth) acrylate, monoethyl ketone Ethyl-(indenyl)acrylic acid vinegar, triethylene glycol monomethyl ether (meth) acrylate, triethylene glycol monoethyl ether (meth) acrylate, monoethyl ketone early 2-4-B Hexyl-bonded (meth)propionic acid vinegar, diethylene glycol monomethyl ether (mercapto) acrylate, tripropylene glycol (meth) acrylate, polyethylene glycol monolauryl ether (mercapto) acrylate Stuffed, and polyethylene glycol mono-hard vinegar (indenyl) acetoin g. Examples of the (meth) acrylate having a carboxyl group include (mercapto) acrylic acid, acrylic acid dimer, itaconic acid, maleic acid, fumaric acid, crotonic acid, and 2-(methyl group). Ethyl propylene oxime oxime, 2-(methyl) propylene oxypropyl acetonate, hexahydroethyl 2-(methyl) propyl sulfonate, 2-(methyl) propylene oxime Hexahydropropyl acrylate, ethylene oxide modified succinic acid (meth) acrylate, b-carboxyethyl (meth) acrylate, and w-carboxycaprolactone (meth) acrylate. Examples of the (meth) acrylate having a hydroxyl group include 2-hydroxyethyl (meth) acrylate, 2- hydroxypropyl (decyl) acrylate, and 2-hydroxy butyl (fluorenyl) acrylate. Ester, 4-hydroxybutyl (meth) acrylate, 2-propenyl oxyethyl 2-hydroxyethyl (decyl) acrylate, diethylene glycol mono (meth) acrylate, dipropylene glycol mono ( Acrylate, acrylate, early (meth) acrylate, propylene glycol mono (meth) acrylate form number A0101 Page 49 / 94 pages 〇 () qq 201039060, polypropylene glycol single (曱Acrylate, polybutanediol mono(methyl)propionate vinegar, poly(ethylene glycol-butanediol) mono(methyl) acrylate vinegar, poly(ethylene glycol-butane propylene glycol) Mono(meth)acrylate, poly(propylene glycol-butanediol) mono(indenyl)acrylate and glycerol (mercapto)acrylate. Examples of the (poly)olefin-based diol di(indenyl) acrylate include ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, and triethylene glycol di( Methyl) acrylate, polyethylene glycol di(meth) acrylate, propylene glycol di(meth) acrylate, dipropylene glycol di(meth) acrylate, tripropylene glycol di(meth) acrylate, poly Propylene glycol di(meth)acrylate, poly(ethylene glycol-propylene glycol) di(meth)acrylate, poly(ethylene glycol-trimethyl glycol) di(meth)acrylate, poly(propylene glycol one) Trimethyl glycol) di(meth) acrylate, polytetradecyl glycol bis(decyl) acrylate, 1,3-butylene glycol di(meth) acrylate, neopentyl Fermented di(methyl) acrylate, 1,6-hexanedioxane (meth) acrylate vinegar, 1,9-nonanediol bis(indenyl) acrylate S and 2-methyl, 2 - Butyl-propylene glycol bis(indenyl) acrylate 4 As the di(meth) acrylate, for example, dihydroxyindenyl dicyclopentane (meth) acrylate Hydroxytrimethylacetic acid neopentyl glycol bis(indenyl) acrylate, stearic acid modified neopentyl alcohol di(meth) acrylate, ethylene oxide modified bisphenol A di(meth) acrylate , propylene oxide modified bisphenol A di(meth) acrylate, butyl oxide modified bisphenol A di(meth) acrylate, epoxy bake modified double expectant F di(methyl) Acrylate, propylene oxide modified bisphenol F di(meth) acrylate, butyl oxide modified bisphenol F di(meth) acrylate, zinc diacrylate, ethylene oxide modified phosphoric acid Acrylate and glycerol di(meth)acrylate. Examples of the (mercapto)acrylic acid vinegar having a 3-stage amine group include, for example, dimethyl 099108905. Form No. A0101 Page 50 / 94 pages 0993218555-0 201039060 Aminoethyl (meth) acrylate, two Ethylamine ethyl (meth) acrylate, dimercaptopropyl propyl (decyl) acrylate and diethylaminopropyl (decyl) acrylate. Examples of the polyfunctional (meth) acrylate having a trifunctional or higher functional group include glycerol tri(meth)acrylate, trishydroxypropylpropane (mercapto)acrylic acid s ruthenium, and neopentyl alcohol (methyl). Acrylate, neopentyltetrakis(meth)propacrylate, dipentaerythritol penta(meth)acrylate, and neopentyltetraol hexa(methyl) acrylate. &gt; Examples of the epoxy (meth) acrylate include glycerin triglycidyl ether-(meth)acrylic acid addenda, glycerol diglycidyl ether-(meth)acrylic acid addenda , polyglycerol polyglycidyl ether_(meth)acrylic acid addenda, 1,6-butanediol diglycidyl ether, alkyl glycidyl ether-(mercapto)acrylic acid addenda, aryl glycidol Addylate, phenyl glycidyl ether_(meth)acrylic acid addenda, epoxy styrene-(meth)acrylic acid addenda, bisphenol octahydroglycidyl ether-(methyl) Acrylic Addenda, Epoxy Propylene Modified Bisphenol diglycidyl ether (meth)acrylic acid addenda, bisphenol A diglycidyl ether-(meth)acrylic acid addenda, surface gas alcohol modified phthalic acid Acrylic addendum, gas alcohol modified hexahydrophthalic acid _ (meth) acrylate addenda, ethylene glycol diglycidyl ether _ (fluorenyl) acrylic acid addenda, polyethylene glycol II Glycidyl ether_(meth)acrylic acid addenda 'propylene glycol-glycidyl Ether-(indenyl)acrylic acid addenda, polypropylene glycol diglycidyl ether-(mercapto)acrylic acid addenda, novolac type epoxy resin - (meth)acrylic acid addenda, indophenol type epoxy resin - (methyl Acrylic addenda and other epoxy-(meth)acrylic addenda. Examples of the (fluorenyl) propylene oxime-modified resin oligomers include, for example, (A099108905 Form No. A0101, page 51/94 pages 〇 993218555-〇201039060), propylene-glued modified polyisocyanate, (Meth) propylene oxime modified polyurethane, (meth) propylene oxime modified polyester, (meth) propylene oxime modified melamine, (meth) propylene oxime modified ruthenium, (meth) propylene Oxygen-modified modified butadiene and (meth) propylene oxide-modified rosin. Examples of the ethylene compound include styrene, a-mercaptostyrene, vinyl acetate, ethylene (meth)acrylate, and allyl (meth)acrylate. Examples of the vinyl ethers include, for example, hydroxyethyl vinyl ether, ethylene glycol divinyl ether, and pentaerythritol triethylene. Examples of the guanamines include (decene) acrylamide, 1-hydroxymethyl (meth) acrylamide, and N-ethyl acetamide as active energy ray-curable monomers (D). Other compounds can be used. In addition, the above-mentioned compounds may be used singly or in combination of two or more kinds in the active energy ray-curable singularity (D). <<Solvent (E)>> The solvent (E) functions to sufficiently disperse the pigment (B) in the pigment carrier. In addition, the solvent (E) can be applied to a substrate such as a transparent substrate, that is, for example, on a glass substrate, so that the photosensitive resin can be easily applied to a dry film thickness, for example, in the range of 0.2 to 5 em. As the solvent (E), for example, 1,2,3-trichloropropane, 1 diol diacetate, 2-heptanone, 3,3,5-trimethyl-2·cyclohexen-1-one can be used. , 3,5,5 trimethylcyclohexanone, ethyl 3-ethoxypropionate, butyl 3-methoxy-3-methylacetate, 3-methoxybutanol, [-methoxy group Butyl acetate, 4-heptanone, m-xylene, m-diethylbenzene, m-benzene, N,N-dimercaptoacetamide, n-butylbenzene, n-propyl acetate, N-. Bile ketone, o-diphenylene, o-benzene, o-diphenyl, o-diox, p-toluene, p-diethylbenzene, dibutylbenzene, tertiary styrene, isophorone 099108905 0993218555-0 Form No. A0101 Page 52 / 94 pages 201039060, ethylene glycol diethyl ether, ethylene glycol dibutyl ether, ethylene glycol monoethyl ether acetate, ethylene glycol monobutyl ether, ethylene glycol monobutyl ether acetate , ethylene glycol monopropyl ether, diisobutyl ketone, cyclohexanol acetate, dipropylene glycol dimethyl ether, dipropylene glycol methyl ether acetate, dipropylene glycol monobutyl ether, diacetone alcohol, propylene glycol diacetate, propylene glycol phenyl Ether, propylene glycol monoethyl ether, propylene glycol monopropyl ether, propylene glycol monomethyl ether, propylene glycol monomethyl ether acetate, propylene glycol monomethyl ether propionate, phenyl alcohol, decyl isobutyl ketone, methyl cyclohexanol, n-amine acetate Base, n-butyl acetate, isoamyl acetate, isobutyl acetate, propyl acetate or dibasic acid ester. Ο Among these, it is preferable to use propylene glycol monodecyl ether acetate, propylene glycol monoethyl ether acetate, ethylene glycol monodecyl ether acetate, and propylene glycol from the viewpoint of good compatibility with the resin. An alcohol acetate such as ethyl ether acetate or a ketone such as cyclohexanone. Other solvents can also be used as the solvent (Ε). Further, these may be used alone or in combination of two or more. ❹ If a solvent (Ε) is used, the photosensitive coloring composition can be adjusted to an appropriate viscosity to form a color layer having a uniform film thickness as a target. From this point of view, the solvent (Ε) is preferably used in a ratio of 800 to 4000% by weight for the pigment (Β). "Leveling agent" In order to easily form a coating film having good flatness on the substrate, the photosensitive coloring composition is preferably further contained in a leveling agent. As the leveling agent, a dimercapto oxane having a polyether structure or a polyester structure in the main chain is preferred. Examples of the dimercaptodecane having a polyether structure in the main chain include FZ-2122 manufactured by TORAY Dow Corning Co., Ltd. and BYK-333 manufactured by BYK Corporation. Further, as the dimethyl methoxy alkane having a polyester structure in the main chain 099108905, Form No. A0101, page 53/94, 0993218555-0 201039060, for example, BYK-31 0 and ΒΥΚ-370 manufactured by BYK Co., Ltd. may be mentioned. It is also possible to use dimethyl methoxyoxane having a polyether structure in the main chain and dimethyl methoxy oxane having a polyester structure in the main chain. When a leveling agent is used, the concentration of the leveling agent in the photosensitive coloring composition is generally set in the range of 0.003 to 0.5% by weight.

In order to assist the function of the leveling agent, an anionic, cationic, nonionic or amphoteric surfactant may be added to the photosensitive coloring composition. In the photosensitive coloring composition, only one type of surfactant may be added, or two or more types may be mixed and added. Examples of the anionic surfactant which is an auxiliary leveling agent include polyethylene oxide ether sulfate, sodium dodecylbenzenesulfonate, styrene-acrylic acid copolymer acrylate, and alkylnaphthalenesulfonic acid. Sodium, sodium alkyl diphenyl ether disulfonate, ethanolyl lauryl sulfate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, ethanolamine stearate, ammonium stearate, sodium lauryl sulfate, styrene-acrylic acid copolymer Monoethanolamine and polyethylene oxide ether phosphate mystery.

The cationic interface-active sword as the auxiliary leveling agent may, for example, be a halogenated quaternary ammonium salt or the like. Examples of the nonionic surfactant which is an auxiliary leveling agent include polyethylene oxide oleyl ether, polyethylene oxide lauryl ether, polyepoxy phenyl phenyl ether, polyethylene oxide ether phosphate, and poly Ethylene ethene sorbitan glyceryl stearate and polyethylene glycol monolauryl ester. The amphoteric surfactant which is an auxiliary leveling agent may, for example, be an alkyl quaternary ammonium carboxylate inner salt such as a quaternary dimethylamine acetate quaternary ammonium carboxylate or an alkylimidazolium. As a surfactant for the auxiliary leveling agent, it is also possible to use a fluorine-based interface activity. 099108905 Form No. 1010101 Page 54 of 94 0993218555-0 201039060 ❸ Agent or Shiheji surfactant. <<Other Components>> The above photosensitive coloring composition may further contain other components. For example, in the photosensitive coloring composition, a storage stabilizer may be contained in order to improve the stability of the viscosity over time. Further, in order to improve the adhesion between the colored layer and the substrate, the photosensitive coloring composition may contain a adhesion promoting agent such as a decane coupling agent. Examples of the storage stabilizer include a quaternary ammonium chloride such as a mercaptotrienyl vapor and a dimethylhydroxylamine; an organic acid such as lactic acid or oxalic acid; a methyl ether of the organic acid; and a tertiary butyl group. A catechol such as a tea phenol; an organic phosphine such as triphenylphosphine, tetraethylphosphine or tetraphenylphosphine; and a phosphite. The storage stabilizer is used in a ratio of 100 parts by weight of the pigment, for example, 0.1 to 10 parts by weight. Examples of the decane coupling agent include ethylene decane such as ethylene tris(/5-methoxy oxy) decane, ethylene ethoxy decane, and ethylene trimethoxy decane; T-methyl propylene oxy propylene trioxane Alkane or the like (mercapto) propylene oxalate; /3 - (3,4-epoxycycloalkyl)ethyltrimethoxydecane, s-(3,4-epoxycycloalkyl)methyl three曱oxydecane, s-(3,4-epoxycycloalkyl)ethyltriethoxydecane, 10,000-(3,4-epoxycycloalkyl)decyltriethoxydecane, 7-ring Epoxy decanes such as oxypropoxypropyltrimethoxy decane and r-glycidoxypropyltriethoxy decane; N - /3 (amine ethyl-aminopropyltri:decyloxydecane) , N-yS (amine ethyl) τ-aminopropyl triethoxy decane, Ν - yS (amine ethyl) r - aminopropyl methyl diethoxy dream, amine propyl triethoxy dream Burning, hydrazine-aminopropyltrimethoxydecane, fluorenyl-phenyl-r-aminopropyltrimethoxy sulfhydryl*, N_stupyl-7-aminopropyltriethoxy sulphide Burning 099108905 Form No. A0101 Page 55/94 List 0993218555-0 201039060 Class; and τ-Mercaptopropyl The thioxane such as tridecyloxydecane or r-mercaptopropyltrimethylethyl decane. The weight of the pigment (Β) is 0. 01~10 by weight. The ratio is preferably used in a ratio of 0.05 to 5 parts by weight. <<Method for Producing Photosensitive Coloring Composition>> The photosensitive coloring composition is produced by, for example, the following method. First, a pigment (Β) is prepared. As the pigment (Β), it is preferable to use a salt mill treatment to refine the material. The salt mill treatment means a kneader, a 2-roll mill, a 3-roll mill, a ball mill, a grinder, a sand mill, etc. The mixture is heated by a mixture of a pigment, a water-soluble inorganic salt and a water-soluble organic solvent, and then mechanically mixed and stirred, and then washed with water to remove a water-soluble inorganic salt and a water-soluble organic solvent. The water-soluble inorganic salt is used as a water-soluble inorganic salt. It functions as a pulverization aid, and when salt grinding, the high hardness of the inorganic salt is used to pulverize the pigment.

It has been determined that crystal growth is caused by the production of an active surface. Therefore, the pigment is pulverized and crystallized at the same time during the mixing and stirring, and thus pigments having different primary particle diameters can be obtained in accordance with the conditions of the mixing and stirring. In order to promote crystal growth by heating, the heating temperature is preferably in the range of 40 to 150 °C. When the heating temperature is less than 40 ° C, crystal growth is not sufficiently caused, and the shape of the pigment particles is close to an amorphous shape, which is not preferable. On the other hand, when the heating temperature exceeds 150 °C, the crystal growth progresses excessively, and the primary particle diameter of the pigment becomes large. Therefore, it is not preferable as a coloring material for a coloring composition for a color filter. Further, from the viewpoint of the balance of the particle size distribution of the primary particles of the salt-milled pigment and the cost of the salt-grinding treatment, the mixing and stirring time of the salt-milling treatment is preferably from 2 to 24 hours. 099108905 Form No. A0101 Page 56 / 94 Page 0993218555-0 201039060 By optimizing the conditions for salt grinding of the pigment, the average particle size of the primary particle size is very small, and the particle size distribution of the primary particles is very wide. It is narrow, that is, a pigment having a clear particle size distribution is obtained. The primary particle diameter of the pigment (B) determined by TEM (transmission electron microscope) is preferably in the range of 20 to 100 nm. When the primary particle diameter is less than 20, it is difficult to disperse the pigment (B) in an organic solvent. Further, when the primary particle diameter is more than 100 nm, it is difficult to obtain a sufficient contrast ratio. A particularly suitable primary particle size ranges from 25 to 85 nm. The water-soluble inorganic salt used in the salt milling treatment is, for example, sodium chloride, cesium chloride, a gasification clock or sodium sulphate. From the price point of view, it is advisable to use gasification sodium (salt). The water-soluble inorganic salt is preferably used in a ratio of from 50 to 2000% by weight, more preferably from 300 to 1,000% by weight, based on the treatment efficiency and production efficiency. The water-soluble organic solvent used in the salt milling treatment functions as a wet pigment and a water-soluble inorganic salt, and is not particularly limited as long as it is dissolved (mixed) in water and substantially not dissolved in the water-soluble inorganic salt. However, in the salt milling treatment, the temperature rises and the solvent becomes a state of easy evaporation. Therefore, from the viewpoint of safety, the boiling point of the water-soluble organic solvent is preferably 120 ° C or more. The water-soluble organic solvent may, for example, be 2-(methoxymethoxy)ethane, 2-butoxyethane, 2-(isopropoxy)ethane or 2-(hexyloxy)ethane. 2-(Hexyloxy)ethane, diethylene glycol, diethylene glycol monodecyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, triethylene glycol, triethylene glycol Alcohol monomethyl ether, liquid polyethylene glycol, 1-methoxy-2-propane, 1-ethoxy-2-propane, dipropylene glycol, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether Or liquid polypropylene glycol. Water Soluble Organic Solubility 099108905 Form No. A0101 Page 57 / 94 9493218555-0 201039060 The agent should be used for the weight of the pigment 1 0 0, with a weight ratio of 5 to 1 000, more preferably 100 parts by weight of the pigment. It is used in a ratio of 50 to 500 parts by weight.

When salt grinding is used, the resin may be added as needed. The kind of the resin is not particularly limited, and for example, a natural resin, a modified natural resin, a synthetic resin or a synthetic resin modified with a natural resin can be used. The resin is preferably solid at room temperature and insoluble in water, and in addition, a part thereof is soluble in the above organic solvent. The resin is preferably used in a ratio of 5 to 200 parts by weight for 100 parts by weight of the pigment.

In the production of the above-mentioned photosensitive coloring composition, after preparing a pigment, a resin (Α), a pigment (Β), and a solvent (Ε) are mixed. Next, the pigment (Β) is uniformly dispersed in a mixture containing a resin (Α) and a solvent (Ε) using various dispersing means such as a three-roll mill, a two-roll mill, a sand mill, a kneader, and an attritor. in. Further, an active energy ray polymerization initiator (C), an active energy ray-curable monomer (D), and the like are added to the dispersion. A photosensitive coloring composition was obtained as above. When a photosensitive coloring composition containing two or more kinds of pigments is produced, first, a plurality of kinds of dispersions having different kinds of pigments are prepared, and then they may be mixed. From the photosensitive coloring composition obtained as described above, coarse particles of 5# m or more are removed by means of centrifugation, a sintered filter, and a membrane filter, and it is preferable to remove coarse particles of lgm or more, and it is preferable to remove 0.5//.粗1 or more of coarse particles and mixed dust. <<Color Filter>> Next, a color filter according to an aspect of the present invention will be described. A color filter according to one embodiment of the present invention is provided on a transparent substrate and a reflective substrate, and includes a filter segment 099108905 formed from the photosensitive coloring composition. Form No. A0101 Page 58 / 94 pages 0993218555-0 201039060 Or black matrix. A typical color filter includes at least one red filter segment, at least one green filter segment, and at least one blue filter segment, or includes at least one magenta filter segment At least one cyan filter segment and at least one yellow filter segment. As the transparent substrate, for example, a glass plate such as soda lime glass, low alkali borosilicate glass or alkali-free aluminoborosilicate glass, or a resin such as polycarbonate, polymethyl methacrylate or polyethylene glycol can be used. board. Also, in liquid crystal display

❹ 099108905 When used in the middle of the glass plate or resin plate, a transparent electrode composed of indium oxide and tin oxide may be formed in order to drive the liquid crystal molecules after the surface plate is formed. When the filter segment and the black matrix are formed by the photolithography method, for example, the following method is employed. First, the above-mentioned photosensitive coloring composition is applied onto a transparent substrate. This coating is carried out by a coating method such as spin coating or die coating. After the coating film is dried as needed, a mask having a specific pattern is set to be in contact with or separated from the coating, and the film is irradiated with ultraviolet light such as a film. Alternatively, instead of the exposure performed by the photomask, the coating film is subjected to laser beam scanning electron beam drawing. Thereby, the coating film is cured by irradiation to the irradiation portion of the light or the electron beam. W is supplied to the development process. Thereby, the unexposed portion of the uncured portion is removed from the coating film. As an inspection liquid system, the test solution such as the carbon axis aqueous solution and the hydrogen peroxide nano-aqueous solution may be closed, or the hydrazine methyl amide and the triethyl group == test. The developer may further contain an antifoaming agent or an interfacial activity, and the treatment may be carried out by, for example, a spray development method, a spray smear/drip (dip) development method, or an entrainment (liquid) development method. Thereafter, the graph # obtained by (4) is used to promote the heating of the polymerization reaction due to the form number A〇im „ _ _ _ 叩 U U used for 0993218555-0 201039060. Each of the black matrices is obtained in this way. Further, the 'black matrix is generally formed earlier than the formation of the filter segments. In the above method, after the coating film is dried and before the coating film is exposed, the previous coating is applied. The film is coated with a water-soluble or water-soluble resin such as a polyethylene glycol or a water-soluble acrylic resin, and dried. The coating film composed of a water-soluble or alkali-soluble resin prevents oxygen from blocking the polymerization reaction upon exposure. Therefore, if the coating film is formed, the sensitivity of the coating film composed of the photosensitive coloring composition to the exposure light can be improved. In the above method, the light beam is directly formed into a filter segment and black on the substrate. Each of the matrices is formed by using the photosensitive coloring composition described above to form a black matrix, but other materials may be used for the black matrix. For example, as a black matrix, a chromium layer, a chromium layer, and the like may be formed. Oxidized layer a layer composed of a multilayer film and an inorganic substance such as titanium nitride. A thin film transistor (TFT) may be formed on the substrate before the formation of the filter segment. In the active matrix slanting type liquid crystal display device, in the TFT When a color filter is formed on the substrate, a higher aperture ratio can be achieved as compared with the case where the filter segment is formed on the opposite substrate, thereby achieving higher brightness. On the color filter layer, a coating is formed. The film layer or the electrode may also be disposed on the color filter layer on the TFT substrate when the film layer and the plurality of pixel electrodes are sequentially formed, and may be disposed on the color filter layer and the film layer to electrically connect the pixels. Through-holes of electrodes and TFTs. "Redo" In the manufacturing steps of the above color filters, 'filter section and black matrix 099108905 Form No. A0101 Page 60 / 94 pages 0993218555-0 201039060 In this case, for example, a highly concentrated alkaline solution is used as a stripping solution, and the colored layer is peeled off from the substrate to regenerate the substrate, and the reproduced substrate may be reused in the production of a color filter. do The redo liquid system has a high pH and contains, for example, at least one of Κ0Η and NaOH, an organic base, a hydrophilic solvent, a surfactant, and water. For the redosolution, for example, PK-CFR310, PK-CFR320 or PK manufactured by PARKER CORPORATION can be used. CFR370, SEMICLEAN DF-7 from Yokohama Oil & Fats Co., Ltd., EP-10, and UNLASTCLEANER-22 from MITSUKAWA Institute of Pure Medicine.

In the redoing of the substrate, the coloring layer formed by baking the coating film composed of the photosensitive coloring composition at 231 TC for 60 minutes is expected to exhibit 30 to 120 mg for the 65 g of the re-grinding liquid of 65 ° C. Solubility. When the solubility is too small, the colored layer cannot be peeled off from the substrate by using the redo liquid, or the release sheet may be produced in a larger form. If the release sheet is present in the redo liquid in a large form, it is likely to cause clogging in the filter for purifying the used one. On the other hand, when the solubility is too large, the coloring liquid can be peeled off from the substrate even if a weak alkali solution is used as the redo liquid, but on the other hand, the development speed of the coating film composed of the photosensitive coloring composition is remarkably high. Therefore, it is difficult to manufacture a high-definition color filter. When the photosensitive coloring composition is used, the solubility can be controlled to 30 to 120 mg by the addition effect of the constituent unit (a) and the constituent unit (b) and/or the constituent unit (c). The release sheet is produced in a sufficiently small size. Therefore, excellent reworkability can be achieved. <<Liquid Crystal Display Device>> The above color filter can be, for example, a liquid crystal display device or a solid-state imaging device 099108905

Form number AG101 % 61 I/* 94 I 0993218555-0 201039060 Use. Hereinafter, an example of a liquid crystal display device including a color filter will be described. The color liquid crystal display device includes a liquid crystal display panel, and any backlight or front light including the illumination liquid crystal display panel. The liquid crystal display panel can display a color image using a color filter, for example, a twisted nematic (TN) mode, a super twisted nematic (STN) mode, an plane switching (IPS) mode, and a vertical alignment ( Any display mode such as VA) mode and optical compensation bending (0CB) mode can be used.

The liquid crystal display panel includes first and second substrates and a liquid crystal layer. The first and second substrates are opposed to each other with a gap interposed therebetween. The distance between the first and second substrates is kept constant by the granular spacers interposed therebetween or the column spacers formed on at least one of them.

A sealing material layer having a frame shape is provided between the first and second substrates. In the sealing layer, a notch portion functioning as an injection port is provided. The liquid crystal material is injected through the previous injection port in the space surrounded by the first and second substrates and the sealing material layer. A liquid crystal material filled with the space forms a liquid crystal layer. Furthermore, the injection port is sealed by a sealing material. Each of the first and second substrates includes an insulating substrate. At least one of the first and second substrates further includes an electrode between the insulating substrate and the liquid crystal layer. The electrode is covered by the alignment film as needed. Further, one of the first and second substrates further includes a color light guide sheet. The color light passing film is located between the insulating substrate including the first and second substrates and the liquid crystal layer. Typically, the liquid crystal display panel further includes a polarizing plate adhered to at least one of the first and second substrates. The liquid crystal display panel may further include a wavelength plate. Embodiments of the invention are described below. Furthermore, it should be understood that these embodiments are 099108905 Form No. A0101 Page 62 of 94 0993218555-0 201039060 I do not limit the scope of the present invention In order to make the present invention easy to understand and implement. (Definition) In the following examples and comparative examples, the weight portion and "% by weight". "Parts" and Γ%" mean the number average molecular weight or weight average molecular weight converted from polystyrene measured by the following tree-shaped (9) μ meal. Specifically, in the gel permeation chromatography apparatus "HLC-812〇GPC" manufactured by TORAY Co., Ltd., four separation columns were connected in series. "TSK-GEL SUPER _〇〇", "Tsk — GEl 邡H4000", "TSK-GEL SUPER H3〇〇〇j" are used for the packing materials of the separation columns. And "tskgel SUPER H2000"' mobile phase uses tetrahydrogen cough (modulation of resin solution 1)

In a separate four-stage flask equipped with a thermometer, a cooling tube, a nitrogen gas guide #, a dropping tube, and a drop device, 233 portions of the cyclohexane were injected to raise the temperature to the sail. After replacing the gas in the burned state with nitrogen gas, the bismuth methacrylate was added to the tube by dropping the tube for 2 hours, and the vinegar vinegar was modified with the acetal bromide (" Α_Ιχ Mug" manufactured by Toagosei Co., Ltd. ) 3 (), 19 methyl propyl groups, methyl propyl group 16 , 2 - ethyl methacrylate 15 and 2, 2, - azo diisobutyl _ mixture. After the completion of the dropwise addition, the reaction was further continued for 3 hours to obtain a resin solution having a weight average molecular weight (Mw) of 1,600. 099108905 After the resin is cooled to room temperature, the material is taken (4), and the temperature is heated for 10 minutes, and the non-volatile components are measured. As a result of the measurement, cyclohexanone was added so that the non-volatile content of Form No. A0101 on page 63 of the previously synthesized resin solution became 20 0993218555-0 201039060% by weight. The resin solution 1 was thus obtained. (Preparation of Resin Solutions 2 to 15 and Comparative Resin Solutions 1 to 6) The resin solutions 2 to 15 were prepared by the same method as described for the resin solution 1 except that the ratio of the various components was changed as shown in Tables 1 to 3. And comparing the resin solutions 1 to 6. Tables 1 to 3 show the results of measurement of the weight average molecular weight. 099108905 Form No. A0101 Page 64/94 Page 0993218555-0 201039060 [0005] Table 1 ◎ Rouge solution 1 T—T—in 00 ms 8 S oo 15000 〇s lf&gt; CO in § s 1—. Side 15000 σ» Lf&gt; CO m t-» ss § T- moo co sn to CO l〇sso 8 18000 卜 g in CO ie» sso 1 100 I 17000 CO S δ |Λ to sssg too 16000 ΙΟ 8 s ΙΑ in s 8 Ss B | 17000 | inch 8 CO lf&gt; CO to T·» s CO 5&gt; o Ύ^· 17000 s tft s 8 g § s 16000 CM S additional u&gt; CO lO s « so B j 15000 τ·» 03 &lt ;D LO s to O 16000 MAA maleic acid M110 M117 FA-513M FA-512MT BzMA MMA EMA BMA I vinyl acetate I HEMA (0 •Q o a+o | a+b+c | i constituent unit (a (MM%) constitutive unit (b) (% by weight) constitutive unit (c) (% by weight) 士1ΐ i (% by weight) 099108905 Form number Α0101 Page 65/94 pages 0993218555-0 201039060 I-_ 6 00 I__ 2 Table «« CNt s 宕σ&gt;&lt;〇τ~ ΙΟ s o 25000 1 s 03 &lt;〇r- ss Ε ss 1500 s •r— r— 〇CD CO CO 〇Ο) ss •fM» 6000 β&gt; 〇Τ·· 52 inch s CO inch so 6000 CO IJ 00 〇1ft Csl 5 CO Csl S sg T- 19000 r- r— 8 8 in sm ce S 〇CSJ g § o § 〇&gt; V·» Arch m (D 8 S IO lf&gt; oS to &lt;d S sss § 1 » § s ▼·» io 8 S in in s ο οι ss 100 io 8 2 s 8 S 00 IP s 8 s % soos Τ-» «〇S 8 in to s ο evi sgo T&quot; oo CO T-* s 8 to in s S § s _l〇〇_1 ! 17000 II MAA i 1 Maleic acid I 1 Additional αΜΑ-ΑΑ-ΤΉΡΑ (Note) 1 I Additional GMA&quot;MAA-THPAffi2) | | Additional HEMA-THPA ( Note 3) | 1 M110 II M117 II FA-513M II FA-512MT II BzMA II MMA II EMA II BMA | I 2-MTA II Vinyl Acetate I HEMA I _GLM_I i Lu δ I Additional GMARMA (Note 4) | I Additional MAA -GMA (Note 5) | (S JQ 0 a+ o I a+b+o 1 i Constituent unit (a) (% by weight) Constituent unit (b) (% by weight) Constituent unit (c) (quantity %) Constituent unit ratio (% by weight) .'i. ., 13⁄4 099108905 Form No. A0101 Page 66/94 Page 0993218555-0 201039060 [0007] Table 3

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Oocm i QL OH another 0 sl—I οε oeo ιε inch

s 1^1 H ooolool II o&gt;lcol oi ms isIVu.

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Vi 0+q+e O+B 5 ξ (ΰι ~~VW3H S00 (%w_) i* (%_e (%1Μβ (3S 爵(%s_) Silver ugly 5:&gt; 酹 chain_ i again, The substances or matters indicated in the abbreviations listed in Tables 1 to 3 are as follows: • MAA ··Methylacrylic acid • AA: Acrylic acid • GMA: glycidyl group • THPA: tetrahydro maleic anhydride 099108905 Form number A0101 Page 67 of 94 0993218555-0 201039060 • M110: ARONIX M110 manufactured by Toagosei Co., Ltd. (p- phenol oxirane modified acrylate) • FA-513M: FANCRYL FA-513M manufactured by Hitachi Chemical Co., Ltd. Cyclopentyl decyl acrylate) • FA-512MT: FANCRYL FA-512MT (bicyclopentaoxyalkenyl methacrylate) manufactured by Hitachi Chemical Co., Ltd. • BzMA: benzyl acrylate. 2MTA : 2- methoxyethyl Acrylate • St : Styrene • MMA : Methacrylate • EMA : Ethyl propionate S • BMA : η - Butyl acrylate • HEMA : 2-Hydroxyethyl methacrylate. GLMA : Glycerol Methacrylate • Μ0Ι : Karenz M0K2 - methacryloyloxyethyl isocyanate manufactured by Showa Denko) • Mw: Weight average molecular weight Notes to Tables 1 to 3 are described below. • Note 1: GMA in the copolymer is added with AA and THPA. • Note 2: GMA in the copolymer is added with MAA and THPA. • Note 3: in the copolymer HEMA added MAA. • Note 4: GMA in the copolymer is added with MAA. • Note 5: MAA is added to the copolymer in the copolymer. (Resin solution 16) with thermometer, cooling tube, nitrogen inlet tube, dropping tube and stirring In the separate four flasks of the apparatus, 207 parts of cyclohexanone were injected, and the temperature was raised to 099108905. Form No. A0101, page 68/94, 0993218555-0 201039060 to 80 ° C. After replacing the gas in the flask with nitrogen, borrow 20 pieces of methacrylic acid, 20 parts of p-cumylphenol ethylene oxide-modified acrylate ("ARONIX M110" by Toagosei Co., Ltd.), 45 parts of yttrium methacrylate, and 2 - hydroxyethyl group were dropped from the dropping tube over 2 hours. a mixture of 8.5 parts of methacrylate and 1.33 parts of 2,2'-azobisisobutyronitrile. After the completion of the dropwise addition, the reaction was further continued for 3 hours to obtain a copolymer solution. Next, the supply to the flask was stopped. Nitrogen, next, one side of the flask is supplied with dry air, one side The total amount obtained was stirred for 1 hour a solution of the copolymer. Thereafter, the copolymer solution was cooled to room temperature, and 6.5 parts of 2-mercapto propylene oxirane ethyl isocyanate (Karenz M0I by Showa Denko Co., Ltd.), 0.08 parts of dibutyltin laurate, and cyclohexane were dropped at 70 ° C for 3 hours. a mixture of 26 ketones. After the resin solution thus obtained was cooled to room temperature, it was sampled at about 2 g, and heated at 180 ° C for 20 minutes to measure a nonvolatile component. Using this measurement result, cyclohexanone was added so that the unvolatile component in the previously synthesized resin solution became 20% by weight. The tree ''fat solution 16 was thus obtained. Tables 1 to 3 show the results of measurement of the weight average molecular weight obtained for the resin solution 16. (Resin solution 17) In a separate four-stage flask equipped with a thermometer, a cooling tube, a nitrogen gas introduction tube, a dropping tube, and a stirring device, 207 portions of cyclohexanone were injected, and the temperature was raised to 80 °C. After replacing the gas in the flask with nitrogen gas, 20 parts of methacrylic acid and 20 parts of cumyl phenol ethylene oxide-modified acrylate ("ARONIX M110" manufactured by Toagosei Co., Ltd.) and methyl group were dropped by dropping the tube over 2 hours. A mixture of 45 parts of fluorenyl acrylate, 8.5 parts of glycerol monodecyl acrylate, and 1.33 parts of 2,2'-azobisisobutyronitrile. After the completion of the drop, further 099108905 Form No. A0101 Page 69/94 Page 0993218555-0 201039060 The reaction was continued for 3 hours to obtain a copolymer solution. Then, the supply of nitrogen gas to the flask was stopped, and then, the dry air was supplied to the flask, and the total amount of the copolymer solution obtained was mixed for 1 hour. Thereafter, the solution was cooled to room temperature to 7 Torr. A mixture of 2-methylpropionyloxyethyl isocyanate, butyl laurate G. G8 and 26 parts of cyclohexanone was added dropwise over 3 J. After cooling the resin solution thus obtained to room temperature, it was sampled at about 2 g of '18 (TC heating for 2 minutes, and the non-volatile component was measured. Using the measurement result, the ring (10) was added, and the resin was previously synthesized in the resin solution. The non-volatile component becomes a 2 G weight 'as stable as 丨7. From the table> to 3 shows the measurement result of the weight average molecular weight obtained for the resin solution (. (Resin solution 18) With thermometer, cooling tube, nitrogen In a separate flask of the introduction tube, the dropping tube, and the stirring device, the cyclohexanone 37 was injected, and the temperature was raised to 80 t. After the gas in the flask was replaced with nitrogen, the liquid in the flask was dropped by the tube. 18 parts of phenolic epoxide modified vinegar ("ARONIX M110" made by Toagosei Co., Ltd.), 10 parts of benzylmethylpropionate, and glycerol monomethacrylate were added dropwise over 2 hours. a mixture of two parts, 25 parts of methyl methacrylate and 2 parts of 2,2,-azobisisobutyronitrile. After the completion of the dropwise addition, the reaction was further carried out for 1 hour at 1 Torr. Liquid, added with cyclohexanone 5 〇 dissolved After the azobisisobutyronitrile, the reaction was further carried out in 1 hour (the TC was further reacted for 1 hour. Then, the gas in the flask was replaced with air, and 9.3 parts of the acrylic acid was supplied to the flask. ), 0.5 parts of trimethylamine phenol and 0.1 part of stupid phenol. By l〇 (TC continues to react for 6 hours, in solid content 099108905 Form No. A010I Page 70 / 94 pages 0993218555-0 201039060 The acid value was changed to 0.5. The reaction was terminated. The previous liquid was added to the liquid 'Additional tetrahydrophthalic acid (IV). 5 parts (100% of the generated starting group) and 5 parts of triethylamine oxime, The reaction was carried out at 12 (rc) for 3 hours, whereby an acrylic resin was obtained. After cooling the resin solution to room temperature, it was sampled at about 2 g to 180. The heating was carried out for 20 minutes, and the non-volatile component was measured. As a result of the measurement, cyclohexanone was added so that the non-volatile component in the previously synthesized resin solution became 20% by weight. Thus, the resin solution 18 was obtained. The results of measurement of the weight average molecular weight obtained for the resin solution 18 are shown in Tables 1 to 3. (Resin solution 19) with thermometer, cooling tube, nitrogen introduction In a separate flask of the dropping tube and the stirring device, 233 parts of cyclohexanone were injected, and the temperature was raised to 110 C. After replacing the gas in the flask with nitrogen, the liquid in the flask was dropped by a tube for 2 hours. 4 parts of stupid ethylene, 27 parts of glycerol decyl acrylate, 27 parts of methyl methacrylate, 8 parts of 2-methoxyethyl acrylate, 6 parts of 2-hydroxyethyl acrylate, and dimethyl 2 a mixture of 2'-azobis(2-methylpropionate) 13. After the completion of the dropwise addition, the mixture was further reacted at 110 ° C for 3 hours to obtain a copolymer. Next, the gas in the flask was replaced with air. 5 parts of methacrylic acid (100% of glycerol group), 16 parts of cyclohexanone, and 3 parts of trimethylamine are expected to be supplied to the flask. The reaction was continued at 1 〇 〇 °c for 6 hours, and the reaction was completed when the acid value of the solid component became 〇. Further, in the liquid of the prior art, 11 parts of tetrahydrobenzene acid needle (30% of the hydroxyl group in the acrylic resin) and 0.5 part of triethylamine were added, and the reaction was carried out at 9 ° C for 35 hours. In this way, the acrylic resin is obtained. After cooling the resin solution to room temperature, it was sampled to about 2 g to 18 Torr. 〇加 099108905 Form No. A0101 0993218555-0 Page 71 of 94 201039060 Heat for 20 minutes, a non-volatile content. __ The result was added cyclohexanone, and the non-volatile content in the (4) pre-synthesized resin solution was 20% by weight. The resin is thus obtained (four). The results of the measurement of the weight average molecular weight obtained for the resin solution 19 are shown. (Resin solution 20) In a separate four-piece flask equipped with a thermometer, a cooling tube, a nitrogen introduction tube, a dropping tube, and a stirring device, 233 portions of cyclohexanone were injected, and the temperature was raised to 110 C. After the gas in the flask was replaced with nitrogen gas, the liquid in the flask was dropped by a dropping tube for 3 hours, and 3 parts of methacrylic acid, 10 parts of sulfhydryl methacrylate, and 16 parts of methyl diacid acid methyl group were dropped. A mixture of 6 parts of methoxyethyl acrylate, 6 parts of 2-hydroxyethyl acrylate, and 2 parts of dimercapto 2 2,-azobis(2-mercaptopropionic acid vinegar). After the completion of the dropwise addition, the reaction was further carried out by ll 〇 t over 3 hours. Next, the gas in the flask was replaced with air, and 32 parts of glycerol methyl acrylate vinegar (66% of several groups), cyclohexane _32 part, and trimethylol phenol phenol were supplied to the flask. For the stupid two parts of the 0 · 1 part with 9 〇 t for 6 hours to continue the reaction 'to obtain the dissolution of acrylic resin. Here, the reaction rate of the glycerol methyl group to the enoate was determined from the change in the acid value of the polymer before and after the reaction. As a result, the reaction rate was 99%. After cooling the resin solution to room temperature, it was sampled to about 2 g, and the non-volatile component was measured by heating for 18 minutes at rc (rc was added. Using the result of the measurement, cyclohexanone was added to make the previously synthesized resin solution non-volatile. The composition was 20% by weight. The resin solution was obtained in this manner. Tables 1 to 3 show the results of measurement of the weight average molecular weight obtained for the resin solution 20. (Modulation of Resin Solution 21) A thermometer, a cooling tube, and a nitrogen gas were introduced. Tube, dripping tube and stirring 099108905 Form No. A0101 Page 72 / 94 9493218555-0 201039060 . In the separate four flasks of the device, 233 parts of cyclohexanone, 20 parts of methacrylic acid, p-nonylphenol ring 30 parts of oxyethylene modified acrylate, 19 parts of benzyl methacrylate, 16 parts of methacrylic acid methyl group, 15 parts of 2-hydroxyethyl methacrylate, and 15 parts of octyl thiol, and the temperature was raised to 80X. : After replacing the gas in the flask with nitrogen, the liquid in the flask was added with 2.33 parts of 2,2,-azobisisobutyronitrile. The reaction was continued for 5 hours, thereby obtaining a weight average molecular weight (Mw) of 1500. Resin solution. After the resin solution was cooled to room temperature, it was sampled by about 2 g, and heated at 18 ° C for 20 minutes to determine the non-volatile component. Using the result of the measurement, cyclohexylol was added to make the non-volatile component in the previously synthesized resin solution. 20% by weight of the resin solution 21 ^ is shown in Tables 1 to 3 as a result of measurement of the weight average molecular weight obtained for the resin solution 21. (Preparation of the resin solution 22) Mounted with a thermometer, a cooling tube, and a nitrogen gas introduction In the separate four flasks of the tube, the dropping tube and the stirring device, the injection of the ring 233, methacrylic acid 20 'p-cumyl phenol ethylene oxide modified acrylate 3 、, benzyl methacrylic acid 19 esters, 16 methyl methacrylates, 15 2-hydroxyethyl methacrylates, and 11 octyl thiols were heated to 8 Torr. The gas in the flask was replaced with nitrogen and then placed in a flask. The liquid inside was added with 0.9 parts of 2,2'-azobisisobutyronitrile. The reaction was continued for 5 hours, thereby obtaining a resin solution having a weight average molecular weight (Mw) of 25000. After cooling the resin solution to room temperature, it was Sampling about 2g, heating at 180 ° C The non-volatile component was measured over 20 minutes. Using the result of the measurement, cyclohexanone was added so that the non-volatile component in the previously synthesized resin solution became 20% by weight. Thus, the resin solution 22 was obtained. Tables 1 to 3 show the resin solution. The measurement results of the weight average molecular weight obtained in 22. 099108905 Form No. A0101 Page 73 / 94 9493218555-0 201039060 (Preparation of dispersion resin solution) Mounted with thermometer, cooling tube, nitrogen introduction tube, dropping tube and stirring device Into four separate flasks, 233 portions of cyclohexanone were injected, and the temperature was raised to 80 °C. After the gas in the flask was replaced with nitrogen, 13 parts of methacrylic acid, 10 parts of methacrylic acid methyl group, 77 parts of methacrylic acid butyl group, and 2,2'- were dropped from the liquid in the flask by dropping the tube over 2 hours. Mixture of 1.33 parts of azobisisobutyronitrile. After the completion of the dropwise addition, the reaction was further continued for 3 hours to obtain a resin solution having a weight average molecular weight (Mw) of 25,000. After cooling the resin solution to room temperature, it was sampled to about 2 g to 180. (: The non-volatile component was measured by heating for 20 minutes. Using the measurement result, cyclohexanone was added so that the non-volatile component in the previously synthesized resin solution became 2% by weight. The disperse tree solution was obtained as above. Preparation of Photosensitive Colored Composition of Light Sheet) Each of the pigment dispersions of Examples 1 to 18 and 20 to 26, and Comparative Examples 1 to 10 was prepared by the following method. First, a mixed pigment and a dispersant (Japan) Lubrizol "Solsparz 200000"), a dispersion resin solution and a solvent (propylene glycol monomethyl ether acetate) to uniformly disperse the pigment in the mixture. The mixing and knife dispersion utilizes a planetary ball mill using oxidized beads. As the pulverization medium, each of the pigment dispersions of Examples 1 to 18 and 20 to 26, and Comparative Examples 丨 to ^ was obtained. Further, the pigment dispersion of Example 19 was prepared by the following method: 099108905 First' Mixed pigments, dispersants ("S〇lsparz 200000" manufactured by Lubri zo 1 Co., Ltd.), resin solution 3, and solvent (propylene glycol monomethyl acetate) In the mixed solution, the mixing and dispersing system uses a planetary ball mill using zirconia beads as a pulverizing medium. 0993218555-0 Guard No. A0101 Page 74/94, 201039060 Thus, the pigment dispersion of Example 19 was obtained. Tables 4 to 6 describe the types and content ratios of the respective components of the pigment dispersions, and the color index numbers of the pigments. [0008] Table 4 〇〇099108905

Example 7 | I | P.R254 | 1__1661 | P.R177 I | 2.20 | | P乂t50 | I____I [__〇^zI | 4.50 1 23.30 Example 14 1 T—士1 PR254 1 丨1.66 I | RR.177 1 | 2.20 I | PY150 I i____i 1__^8?__1 | 4.50 1 23,30 Example 6 | P.R254 | !___1 I p.am | | 2,20 1 | PY150 j 0.51 l__I | 4.50 j 23,30 1 Example 13 1 PR254 1 t.60 PR177 2.20 | PY150 0.51 | 0.87 4.50 23.30 Example 5 1 | P.FL254 | 1__1 | PR177 I | 2.20 1 I ΡΎ.150 I I__mi__I I__0-87 j 4.50 | 23.30 I Example 12 | T·· | P.R254 | 1.66 P.R177 | 2.20 | PY150 I 丨(10)__I 1____1 | 4.50 | 23.30 Example 4 T-· ά | P.R254 | 11 -Qiu Wei P.R177 I 丨2.20 | I PX150 | I_____I I__〇^i__1 | 4,50 1 23.30 Example 11 R-1 | P'R254 | I__m__I | P.R177 | 2.20 | ΡΎ.150 I 0.51 1__〇^z__1 4.50 23.30 Example 3 1 | PR254 | 1^L681 | PR177 I | 2.20 I | PY150 1 I^__i 1^__1 | 4.50 | 23.30 Example 10 ί | P.R254 | I_M6__! P.R177 I | 2.20 | PY150 I^9^1__1 1〇^z1 | 4.50 | 23.30 Example 2 R-1 I ΡΛ25Α I 1.66 1 | PR17 7 | 1 2-20 1 ΡΎ.150 I 0.51 1 0.87 J | 4.50 I 23.30 Example 9 1 | PR.254 | | 1.66 IP'R177 I | 2.20 | ΡΎ.150 0-51 1 0.87 | 4.50 | Example 1 FM I P-R254 I 丨1-66 I | PR177 | | 2.20 I | ΡΎ-150 1 0-51 II 0-87 1 | 4.50 j 23.30 Example 8 I 1 | PR254 | I t.66 I PR177 II 2-20 i I ΡΎ.150 j 0-51 J 1 0.87 1 | 4J0 1 23.30 Pigment Dispersion Pigment 1 Pigment 2 Pigment 3 Dispersant Dispersion Resin Solution Solvent Pigment Dispersion Pigment 1 Pigment 2 Pigment 3 Dispersion Agent dispersion resin solution solvent chain charm chain 璀 w key paste listen ^ This Song Gong g chain chain play ess §liS Form No. A0101 Page 75 / 94 pages 0993218555-0 201039060 Example 20 Ϊ P.G36 I 3-94 I | ΡΎ.150 I 1.00 I 0.99 I 4.69 26.06 Example 26 I PR254 | 1 1-66 I ! P.R177 | 2-20 I PY,150 I 0.5t | 0.87 | 4.50 23.30 Example 19 | I 1 P.R254 1 CD (Ο τ- | P.R177 | 2L20 1 i RY.1S0 II^_1 I 0.87 | 4.50 Note 6 23.30 Example 25 FM | P.R254 | | t.66 1 | RR.177 | I 2.20 | RY.150 | 0.51 0.87 4,50 23-30 Example 18 ώ 1 P.R254 1 1 1*66 1 | P- R177 | | 2^0 1 | PY-150 I 1__Μί1 I_〇^7_I 4,50 23.30 Example 24 R-1 | P.R254 | 1.66 | P.R177 1 | 2.20 I Ρ·Υ·150 0.51 0- 87 | 4.50 23.30 Example 17 1 丨P.R254 | CO to | PR177 | | 2.20 | | ΡΎ.150 I 1____1 I_____I 4.50 I 23.30 I Example 23 R-1 S CM (T *〇1 CD (Ο P .R177 2.20 PY150 0.51 0.87 4.50 23.30 Example 16 I | P.RISA 1 1 1.66 I | PR177 I | Z20 1 | ΡΎ.150 I 1 0-51__I | 0.87 | 4.50 23.30 I Example 22 | K-1 CQ Ο \ 5.22 | 1.04 3.99 26.95 Example 15 Ύ&quot;· P.R254 CO &lt;〇| p.ai77 | | 2.20 ! | ΡΎ.150 II 〇-5t_I | 0.87 | 4.50 I 23.30 Example 21 B-1 丨Ρ·Β15:β I [2^0_I I ΡΛΛ23 j I 104 I | 0.48 | 3.75 16.40 Pigment Dispersion Pigment 1 Pigment 2 Pigment 3 I Dispersant I Disperse Resin Solution · Solvent Pigment Dispersion Pigment 1 丨 Pigment 2 Pigment 3 Dispersion Agent fiber resin solution Solvent 璀β瓖3松龚β 整糊豳A ¢3 Stupid i Pu 099108905 Form No. A0101 Page 76 / 94 Page 0993218555-0 201039060 [0010] Table 6 Comparative Example 5 1 士 | P.R254 | 1.66 I ! PR. 177 1 [2.20 j ΡΎ.150 | I__Mi___I IML" | 4.50 | 24.40 Comparative Example 10 1 CK-1 δ j 5.22 1 Γ t-04 j 3.99 j 26.95 Comparative Example 4 T·— (k | PR254 | I 1.66 j P.F1177 2.20 PYt50 0.51 | I 0.87 | | 4.50 | 24.40 丨Comparative Example 9 1 B-1 II P.B15:6 | 1 2.10 I 1 PV23 j inch Ο 1 0-48 1 3.75 16.40 Comparative Example 3 ί | FL254 | | 1.66 | | PR177 | 2.20 PY150 | 0.51 [0.87 | | 4.50 I 24.40 1 Comparative Example 8 1 G-1 | P.G36 | I 3.94 I PY150 L^oo_J | 0.99 j 4.69 | 27.56 Comparative Example 2 ck | P.R_254 | 1 —U6...1 | P.R177 j 2.20 | PY150 | i --0-51I I 0-87^I | 4.50 | 24.40 1Comparative Example 7 ! ά | P.R254 | ;〇CO | P.R177 I 1 2.20 1 ΡΎ.150 L0-51__I [0.87 | [4.50 | 24.40 丨Comparative Example 1 1 R-1 | P.F1254 ! L__ 1.66— I | P.R177 | { 2.20 | | PY150 | L0.51___I | 0.87 I | 4.50 I 24.40 g | PR254 | | 1.66 1 | P.R177 | 1 2.20 1 I Ρ.Υ.ίδΟ I o.st 1 〇·耵丨| 4.50 1 24.40 Pigment dispersion Bulk Pigment 1 Pigment 2 Pigment 3 Dispersant Dispersion Resin Solution Solvent Pigment Dispersion Pigment 1 Pigment 2 Pigment 3 Dispersant Dispersion Resin The solvent was I M chain charm worthy Cong Yi Cui SgifN £ Caryopteris leg veins but Φ -. _ Pine demon key listen ❹ ❹ Further, described in Tables 4 to 6 The substance or matter represented by the abbreviated as follows. • PR254: CI Pigment Red 254 (dione ratio 11 and 0 ratio of red pigment) • PR 177: CI Pigment Red 177 (brewed red pigment) • PY150: CI Pigment Yellow 150 (azo) Field 099108905 Form No. A0101 Page 77/94 Page 0993218555-0 201039060 Yellow pigment) • PG 36: CI Pigment Green 36 (Green Pigmented Green Pigment) • PB15:6: CI Pigment Blue 15:6 (Copper-titanium-based blue pigment) • PV23: CI Pigment Violet 23 (dioxazine-based violet pigment) • CB-carbon black (Pritex 75 manufactured by DEGUSSA Co., Ltd.) Further, the notes in Tables 4 to 6 are described below. • Note 6: Change to Resin Climbing 3 &lt; . . . . . . . . Next, each of Examples 1 to 26, and Comparative Examples 1 to 6 and the pigment dispersions of the names 10 to 10, As shown in Tables 7 to 9, together with the resin solution, the active energy ray-curable monomer (dipentaerythritol hexaacrylate), and the active energy ray polymerization initiator (2-(dimethylamine)-2 - [(4 - Methylphenyl)methyl]- 1-[4-(4-cylinyl)phenyl]-1-butanone), sensitizer (2,4-diethyl sultaneous _) and solvent (propylene glycol) Monomethyl ether acetate) mixed. After thorough stirring, the mixture was filtered through a filter to remove the granules; in addition to the coarse particles having a diameter of 1 or more. Each of the photosensitive coloring compositions of Examples 1 to 26 and Comparative Examples 1 to 6 and 8 to 1 was prepared as above. Further, the photosensitive coloring of Comparative Example 7 was prepared by the same method as that described for Comparative Example 1, except that a mixed solution containing a comparative resin solution and a resin solution 3 in a weight ratio of 1:1 was used as the resin solution. Composition. 099108905 Form No. A0101 Page 78/94 List 0993218555-0 201039060 οο 099108905 I Example 7 | R07 | I 33.05 I Resin Solution 7 I 7.25 | 3.38 j | t.08 1 0.27 I 55.00 I 62% j Example 14 R14 Rt J 33.05 inch g 麴im i 7.25 I 3.38 | I 1.08 1 ___m.__ 55.00 I δ CD Example 6 R06 D I 33.05 ] Resin solution 6 1_m__1 3.38 1,08 | 027 I 55-00 CM c〇丨Example 13 1 R13 1__Μ1 33.05 Resin solution 13 7.25 j 3-38 __m__ 0.27 I 55.00 CO Example 5 R05 Τ-· ά [33-05 | Resin solution 5 1__L25__I 1 3.38 | 1.08 __^27_ Example 12 R12 £33.05 CN»g Li i 1,.^ — | 3.38 1 _____ 55.00 62% Example 4 R04 Μ ___I 33,05 Old fat solution 4 I 7.25 1 3.38 1 1.08 0.27 55.00 CM &lt;〇Example 11 i 1 33.05 Resin solution 11" I___m__1 3.38 t.08 i_____] 650 SR CM &lt;D Example 3 J R03 τ* k | 33.05 | j resin solution 3 I 7-25 3-38 1.08 0.27 55Λ0 j &lt; NJ &lt;〇Example 10 I______1 R-1 33.05 Resin Solution 10 7.25 3.38 1.08 I__〇^z__I 55.00 g CO Example 2 | R02 | 丨R-1 I 33.05 | Resin Solution 2 7.25 | I 3.38 j 1.08 !_____I 55-00 62« Example 9 R09 R-1 33.05 Resin solution 9 | 7,25 1 3.38 j !_1^8I I________I 55.00 62% Example 1 1 τ·· | 33.05 | Resin solution 1 1____I 1 3.38 1 丨1.08 | I______I 55.00 | 62% I Example 8 R08 R-1 | 33.05 | Resin solution 8 1m__1 3.38 1 丨―1.08" I__0-27 | 55.00 1 Photosensitive coloring composition Pigment dispersion Resin (F) solution 1 Polymerizable monomer I Photopolymerization initiator I Sensitizer I Solvent resin (F) / Resin composition (A) Photosensitive coloring composition Pigment dispersion resin (F) Solution polymerizable monomer I Photopolymerization Initiator Sensitizer I Solvent Resin (F) / Resin Composition (A) Form No. 101 0101 Page 79 / 94 9493218555-0 201039060 099108905 Example 20 | S σ G-1 | I 36.68 I Resin Solution 3 I 4.80 | 3.38 I 1.08 0.27 I 53.80 51% Example 26 I R23 Butyl 33.05 | Resin Solution 22 1 7.25 I 3.38 I 1.08 ” 0.27 55.00 | 62% | Example 19 R19 R-2 ! 33.05 : ______I Resin solution 3 1_7^5 1 13^38_—_1_I I^^—I 0.27 55.00 | 100% | Example 25 | R22 1 33.05 Resin solution 21 1_L25I 3.3 8 t.08 0.27 55.00 Concentrated Csi CD Example 18 R18 Rt 33.05 Resin solution 18 1^m1 3.38 1.08 0*27 55.00 €M &lt;〇Example 24 R21 1_______1 33.05 Resin solution 20 7.25 3.38 t.08 0.27 55.00 Narrow&lt M CO Example 17 RI7 Rt | 33.05 Resin Solution 17 丨 7.25 | 3.38 | t.08 | IJ 55.00 62% Example 23 R20 33.05 Resin Solution 19 7.25 | 3.38 1.08 0.27 55.00 &lt;Example Example 16 R16 RH | 33 , 05 丨 resin solution 16 i 1__m__1 | 3.38 | IL〇e___I 1〇^z_____I 55.00 CM CO I Example 22 1 K-1 37.21 Resin solution 3 13.00 3.60 0.60 0.10 45.49 an Example 15 : R15 R-1 33.05 Resin solution 15 1L25_! 1 3.38 | I_____m__I | 0.27 I | 55.00 62% Example 21 B01 Bw1 | 23.78 I Resin Solution 3 | 10.00 | 4.20 | _I 0.32 60.40 Find CO Bu photosensitive coloring composition Pigment dispersion resin (F) solution 1 Polymerizable monomer I Photopolymerization initiator 1 Sensitizer 1 Solvent | Resin (F) / Resin composition (A) Photosensitive coloring composition Pigment dispersion resin (F) Solution I Polymerizable monomer I Photopolymerization Starter 1 Sensitizer 1 Solvent 1 Resin (F) / Resin Composition (A) Table No. A0101 Page 80/94 9493218555-0 201039060 [0011] Table 9 ο ; Comparative Example 5 | OR05 R-1 | 34,15 | Comparative resin solution 5 1__I 丨3,38 1 1-08 | 0.27 53.90 Ϊ Comparative Example 10 CK01 CK-1 37«21 Comparative resin solution 1 13.00 3,60 0.60 0,10 45.49 I Comparative Example 4 CR04 TQ: 34.15 Comparative resin solution 4 1_m_1 1 3.38 1 t.08 0.27 53.90 ! Comparative Example 9 CB01 B -1 | 23.78 | Comparative resin solution 1 10.00 4.20 1.30 0.32 60.40 I Comparative Example 3 CR03 34,15 Comparative resin solution 3 1__I 3.38 ί·08 0.27 53,90 I Comparative Example 8 CG01 G-1 | 3818 | Comparative resin solution 1 4.80 3.38 1.08 0.27 | 52.30 | Ϊ Comparative Example 2 CR02 丨34.15 I Comparative resin solution 2 7·25 3.38 1.08 J 53.90 ! Comparative example 7 CR07 Tr ek 34.15 S 1| 11 Si 7.25 3.38 1.08 0.27 53.90 Seek 5 Comparative example 1 CR01 R-1 34.15 Comparative resin solution 1 7.25 3.38 1.08 0.27 53.90 1 Comparative Example 6 CR06 τ— 34.15 Comparative resin solution 6 7.25 3.38 1.08 0.27 53.90 1 Photosensitive coloring composition I Pigment dispersion resin (F) Solution polymerizable monomer light Polymerization initiator sensitizer I solvent|resin (F) / resin composition (A) Pigment Dispersion Resin (F) Solution 1 Polymerizable Monomer 1 Photopolymerization Initiator I Sensitizer I Solvent | Resin (F) / Resin Composition (A) [0012] (Dispersion Stability Evaluation) Using E-type Viscosity The viscosity of the photosensitive colored composition obtained by the above method at 25 ° C was measured (TUE-20L type manufactured by TOKI SANGYO Co., Ltd.). Specifically, the number of rotations was set to 20 rpm, and on the day of manufacture of the photosensitive coloring composition, it was stored in a constant temperature room at 40 ° C for 7 days, and then entered into 099108905. Form No. A0101 Page 81 / 94 pages 0993218555-0 201039060 Line viscosity measurement. Then 'the viscosity of the photosensitive coloring composition on the day, ie the initial viscosity (77 〇: mpa · s), and the viscosity (π 7 : mPa · s) after 7 days of storage in a constant temperature chamber of 4 (π 7 : mPa · s) The storage stability of the photosensitive coloring composition was evaluated. The results are summarized in Tables 1 to 12 below. 〇: The ratio r? 7" 0 is less than 1.20, and the viscosity is hardly increased, and the dispersion stability is good.

△: The ratio of 7〇0 is 1.20 or more, less than UQ, and the viscosity is increased at the tip. The dispersion stability is somewhat poor (color pattern formation and developability evaluation). On a transparent glass substrate of 10×10 cm, spin coating of red, green, and The blue photosensitive coloring composition is prebaked by the &amp;70〇c for 2 minutes to obtain a dry film thickness of about 2. 〇em coating film. Next, an intermediate mask is irradiated to the coating film to irradiate ultraviolet rays β. Here, the exposure amount is 50 mJ/cm 2 . Further, the mask is provided in a stripe shape using the light shielding portion and the light transmission portion.

Then, the coating film is developed by the developer solution. Here, the progress of the development is observed, and the entire unexposed portion is obtained until the dissolution is completed, and the time passes through the film. The color patterns of the red, green, and blue colors are obtained as above. In addition, a black colored pattern was obtained in the same manner as described above except that the black coloring composition was used and the amount of the material was changed to 100 mJ/cm 2 . 099108905 Observe the coloring pattern obtained as above, investigate the presence or absence of peeling, and compare the results with time mi to evaluate the coloring composition of each color. Form No. A0101 Page 82 of 94 0993218555-0 201039060 Developability. The results are summarized in Tables 10 to 12 below. 〇: Time T1 is less than 60 sec and no pattern peeling. X: Time T1 is 60 sec or more or pattern peeling occurs. (Evaluation of Pattern Shape) A glass substrate having a colored pattern was formed by the above method, and cut into a half size (5 cm x 10 cm) to prepare two test pieces. Only one of the test pieces was post-baked in a high temperature oven set at 230 ° C for 20 minutes. Then, each of the test pieces after the post-baking was cut into a square of 1 cm square, and Pt and Pd were vapor-deposited using a sputtering apparatus (E-1 030) manufactured by Phillips. Next, using a scanning electron microscope (S-4300) manufactured by Hitachi Manufacturing Co., Ltd., the acceleration voltage was set at 15 kV, and the observation magnification was set at 1,000,000 times, and the cross-sectional shape of the colored pattern was observed. Then, the cross-sectional shape of the colored pattern and the angle (0) formed by the main surface of the glass substrate and the cross-sectional edge portion of the colored pattern were referred to the following reference, and the pattern shape was evaluated. The results shown in Tables 10 to 12 below are marked as "post-baking" and the results are recorded. Further, regarding the remaining test pieces which were not post-baked, the pattern shape evaluation was carried out by the same method as described above, and the results shown in the following Tables 10 to 12 are indicated as "after development", and the results are described. ◎ : 0 &lt; 20 is a cone. 〇: 20$ Θ $45 positive cone. △ : 45 S 0 S80 has a positive taper. X : 0 &gt; 8 0 Clear and conical or drape. Further, in the comparative example, the development time T1 was 60 sec, which was a defective product, and therefore the pattern shape evaluation was not performed. <Reworkability Evaluation> 099108905 Form No. A0101 Page 83 / 94 9493218555-0 201039060 The sample for the above-mentioned developability evaluation, that is, the substrate on which the colored pattern is formed, is post-baked at 230 ° C for 90 minutes. grilled. 2 mL of a reconstituted liquid heated to 65 ° C (SEMI CLEAN DF - 7 manufactured by Yokohama Oil and Fats Industry Co., Ltd.) was placed in the culture, and the sample was immersed in the redo liquid for 5 minutes. After 5 minutes, the redo liquid and the sample were transferred from the culture dish to the round bottom flask, and the redo liquid was passed through a crepe paper having a pore diameter of 5 &quot; m and a diameter of 3 cm. Then, using an optical microscope with a size measuring function, the size of the peeling sheet spread out on the filter paper was measured. Specifically, the measurement was carried out in the following manner. That is, the following area is observed at a magnification of 500: the central area of the filter paper; the distance from the central area is 1 cm, the central area is sandwiched therebetween and arranged in two areas in the lateral direction; and the distance from the previous central area is 1 cm, The central area is sandwiched between them and arranged in two areas in the longitudinal direction. Next, in each of the fields of view, 10 peeling pieces were sequentially selected from the largest maximum length, and the average of the maximum lengths was determined for the selected 50 peeling pieces. Then, the average of the maximum lengths thus obtained, that is, the average maximum length, is evaluated with reference to the following criteria, and the reworkability is evaluated. The results are summarized in Tables 10 to 12 below. ◎: Dissolved (there was no peeling sheet confirmed by an optical microscope). 〇: The average maximum length is less than 300/zm. △ ·· The average maximum length is 300 μπι or more and less than 500; am. X : The average maximum length is 500//m or more. 099108905 Form No. A0101 Page 84/94 List 0993218555-0 201039060 〇ο 099108905 Embodiment 7 | R07 ΙΟ ci V) ci 〇ο X ο ο &lt;1 Example 14 R14 to CO CO 〇〇X &lt;1 &lt &lt;Example 6 CO g CO CO 0 〇X &lt;1 &lt;! &lt; Example 13 R13 1Λ ci l〇〇ο X &lt;&lt;&lt;&lt;&lt;&gt; Example 5 R05 in CO in 〇ο X ο Ο &lt;Example 12 R12 in CO CO C3 ο ο X 〇〇 &lt; Example 4 R04 ιο pj xo CO 〇ο X &lt;J &lt;&lt; Example 11 1«· T-· X ir&gt; CO CO 〇 〇X 〇〇&lt; Example 3 R03 VO co ο ο X ◎ ◎ &lt; Example 10 R10 ¢9 l〇c6 〇ο X 〇〇 &lt; Example 2 R02 to LO CO 〇ο X ο 〇 &lt; Implementation Example 9 R09 UP) &lt;0 u&gt; c*i ο 〇X 〇〇 &lt; Example 1 § CO LO CO ο 〇X ο ο &lt; 〇〇R08 CO in CO ο 〇X 〇〇&lt; Photosensitive coloring Composition initial viscosity time viscosity viscosity stability I 1 Hall after post-baking heat transfer after baking 1 Redo sexy light coloring composition initial viscosity m bond 1 viscosity stability I 1 developability before baking Hot fluidity after baking, Recyclability, Stabilization, Shape, Dispersion, Stability, Shape, Form No. 1010101, page 85/94, 0993218555-0, 201039060 [0013] 099108905 Table 11 Example 20 § CD CQ CO CO ο 〇X ◎ ◎ &lt;Example 26 R23 in c6 in 〇〇X ◎ ◎ &lt;Example 19 R19 in CO 〇ο X ◎ ◎ ◎ Example 25 R22 CO CO &lt; 〇CO ο 〇X &lt;&lt; 1 Example 18" R18 in w &lt; 〇CO 〇〇X &lt;&lt; ◎ Example 24 2 CO CO CO CO ο XX ◎ ◎ ◎ Example 17 R17 CO CO CO 〇ο X 〇0 〇 Example 23 R20 | m CO In CO 〇〇X ◎ ◎ ◎ Example 16 R16 in CO ie&gt; CO ο ο X ◎ ◎ 〇丨 Example 22 | K01 卜CO ο 〇X ◎ ◎ &lt; Example 15 R15 \o cd 卜 CO 〇〇X 〇〇 ◎ 丨 Example 21 I B01 CO CO CO CO 〇〇X ◎ ◎ &lt; Photosensitive coloring composition _ί Initial viscosity time-dependent viscosity viscosity stability: I developability number thermal fluidity redo sexy light coloring composition Initial viscosity of time i viscosity viscosity stability 1 after development and baking after baking According to the dispersion stability s _ ί shape dispersion stability shape ill Form No. A0101 Page 86 / 94 pages 0993218555-0 201039060 [0014] Table 12 © ο 099108905 Comparative Example 5 CR05 | w&gt; e*i ΙΟ CO 〇〇XXX &lt 1 Comparative Example 10 CK01 00 CO 0 〇 XXX &lt; Comparative Example 4 CR04 CO ο &lt;f XXX 〇I Comparative Example 9 | CB01 &lt;〇CO CO CO 〇〇XXX 〇Comparative Example 3 CR03 CO CO 3 inch &lt;; 3 &lt; XXXX Comparative Example 8 CG01 CO CO &lt; 〇¢ 0 〇〇 XXX &lt; 1 | Comparative Example 2 | CR02 CO CO o &lt; XIII 1 Comparative Example 7 CR07 LO CO C0 〇〇 XXX &lt; Comparative Example 1 CR01 wl£&gt; ¢9 〇〇XXX 0 MD Μ 71UI J-Λ CR06 to to CO 〇〇XXX &lt; Photosensitive coloring composition initial viscosity time-adhesive viscosity stability stability after baking after baking: heat Fluidity Redo Sensitive Photochromic Composition Initial Viscosity Agarity Viscosity Stability: Thermal fluidity rework after baking after development and post-baking. Dispersion stability shape Dispersion stability shape [0015] Using resin solution 1 Examples 1 to 22 to 18 and Comparative Example 1 4 to 10, the viscosity change with time is small, the dispersion stability is good. Further, in Comparative Examples 2 and 3, the ratio of 7; 7/7/0 was 1.20 or more, and the viscosity with time passed greatly increased. Form No. A0101, page 87, page 94 0993218555-0 201039060 Further, in any of Examples 1 to 26 and Comparative Examples 1 to 10, the color patterns before post-baking were suspended. That is, in any of Examples 1 to 26 and Comparative Examples 1 to 10, the pattern shape before post-baking was poor. Then, in Comparative Examples 1 to 10, the shape of the pattern remained poor even after post-baking. In contrast, in Examples 1 to 26, the pattern shape after post-baking had a cross section of a forward taper. Namely, the color patterns of Examples 1 to 26 confirmed the thermal fluidity. Among these, the coloring patterns of Examples 3, 16, 19 to 24, and 26 have the most excellent pattern shapes. Further, in Examples 1 to 26, reworkability superior to that of Comparative Example 3 was achieved, and reworkability equivalent to or superior to Comparative Examples 3, 5 to 8, and 10 was achieved. In particular, in Examples 18 and 23, particularly good reworkability can be achieved. 9 [Simple description of the drawing] _] No [Main component symbol description] [0017] No 099108905 Form No. A0101 Page 88 of 94 Page 0993218555-0

Claims (1)

201039060 VII. Patent application scope: 1. A photosensitive coloring composition, comprising: resin (A), pigment (B), active energy ray polymerization initiator (C), active energy ray-curable monomer (D) and the solvent (E); the resin (A) contains a vinyl resin (F) in a ratio of 50% by weight or more, and the vinyl resin (F). A constituent unit (a) having a carboxyl group in a ratio of 2 to 50% by weight, and an aromatic ring selected from the following general formula (1) in a ratio of 2 to 50% by weight, the following general formula (2) One or more of the group consisting of an aromatic ring, an aliphatic ring represented by the following general formula (3), and an aliphatic ring represented by the following general formula (4) The constituent unit (b) of the structure is composed of other constituent units (c) in a ratio of 10 to 80% by weight. General formula (1): General formula (2): 099108905 Form number A0101 Page 89 of 94 0993218555-0 201039060 (In the above general formulas (1) and (2), R is a hydrogen atom or may have a benzene ring and an alkyl group having 1 to 20 carbon atoms.) General formula (3): General formula (4): 099108905 Form number A0101 Page 90 of 94 0993218555-0 201039060 2. The photosensitive coloring composition according to claim 1, wherein one of the groups consisting of the constituent units (a), (b), and (c) is selected from the group consisting of the above constituent units. It has a vinyl bond. 3. The photosensitive coloring composition according to claim 1 or 2, wherein the constituent unit (a) precursor (al) is selected from the group consisting of acrylic acid and methacrylic acid. The above monomers. 4. The photosensitive coloring composition according to claim 1 or 2, wherein at least a part of the carboxyl group of the structural unit (a) is added by adding a polyvalent acid anhydride to a constituent unit having a hydroxyl group, or borrowing It is introduced by adding a polyvalent acid anhydride to a hydroxyl group formed by adding a constituent unit having an epoxy group and an unsaturated monovalent acid. The photosensitive coloring composition according to any one of claims 1 to 4, wherein the constituent unit (b) precursor (bl) is selected from the group consisting of styrene and a-fluorenyl styrene. Anthracene, τ-based acrylate, benzyl methacrylate, a monomer represented by the following general formula (5), a monomer represented by the following general formula (6), and a general formula (7): One or more monomers in the group consisting of monomers. General formula (5): ' 099108905 Form number A0101 Page 91 of 94 0993218555-0 201039060 R1 〇一R2j-〇~ O General formula (7): R1 0— 〇 (In the above general formulas (5) to (7), R1 is a hydrogen atom or a fluorenyl group, and R2 is a calcined group having a carbon number of 2 or 3, and the R3 group may have a stupid ring and a carbon number of 1 to The photosensitive coloring composition of any one of Claims 1 to 5, wherein the alkyl group of the above is an integer of 1 to 15, and m is an integer of 〇 to 2). c) The precursor (cl) contains one or more monomers selected from the group consisting of methacrylate, methyl methacrylate, ethyl acrylate, and ethyl methacrylate. A color filter characterized by having a filter segment formed by a photosensitive coloring composition according to any one of the claims pp. 6 099108905 and a black form number A0101. 94 pages 0993218555-0 201039060 At least one of the matrices. Ο 099108905 Form No. A0101 Page 93 of 94 0993218555-0