TW201017744A - Method for manufacturing functional device, and method for manufacturing semiconductor device provided with functional device - Google Patents

Method for manufacturing functional device, and method for manufacturing semiconductor device provided with functional device Download PDF

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Publication number
TW201017744A
TW201017744A TW98133218A TW98133218A TW201017744A TW 201017744 A TW201017744 A TW 201017744A TW 98133218 A TW98133218 A TW 98133218A TW 98133218 A TW98133218 A TW 98133218A TW 201017744 A TW201017744 A TW 201017744A
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Taiwan
Prior art keywords
functional
substrate
wafer
protective sheet
adhesive
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TW98133218A
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Chinese (zh)
Inventor
Koji Tsuji
Yosuke Hagihara
Naoki Ushiyama
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Panasonic Elec Works Co Ltd
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Publication of TW201017744A publication Critical patent/TW201017744A/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C1/00Manufacture or treatment of devices or systems in or on a substrate
    • B81C1/00865Multistep processes for the separation of wafers into individual elements
    • B81C1/00873Multistep processes for the separation of wafers into individual elements characterised by special arrangements of the devices, allowing an easier separation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81BMICROSTRUCTURAL DEVICES OR SYSTEMS, e.g. MICROMECHANICAL DEVICES
    • B81B2207/00Microstructural systems or auxiliary parts thereof
    • B81B2207/01Microstructural systems or auxiliary parts thereof comprising a micromechanical device connected to control or processing electronics, i.e. Smart-MEMS
    • B81B2207/012Microstructural systems or auxiliary parts thereof comprising a micromechanical device connected to control or processing electronics, i.e. Smart-MEMS the micromechanical device and the control or processing electronics being separate parts in the same package
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B81MICROSTRUCTURAL TECHNOLOGY
    • B81CPROCESSES OR APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OR TREATMENT OF MICROSTRUCTURAL DEVICES OR SYSTEMS
    • B81C2201/00Manufacture or treatment of microstructural devices or systems
    • B81C2201/05Temporary protection of devices or parts of the devices during manufacturing
    • B81C2201/053Depositing a protective layers

Abstract

A method for manufacturing a functional device is provided with a wafer processing step, a bonding step, a dicing step, a peeling step and a removing step. In the wafer processing step, a functional thin film (2) is formed on one surface (3a) of a wafer (3) to be the base of a substrate (1). In the bonding step after the wafer processing step, a protection sheet (6), i.e., an adhesive sheet using an adhesive, is directly bonded on the surface (3a) of the wafer (3), and a dicing sheet (7) is bonded on the other surface (3b) of the wafer (3). In the dicing step after the bonding step, the protection sheet (6) and the wafer (3) are cut without cutting the dicing sheet (7), and the wafer (3) is divided into a plurality of functional devices (10). In the peeling step after the dicing step, the protection sheet (6) is peeled from each functional device (10). In the removing step after the peeling step, an organic material containing the adhesive of the protection sheet (6) adhered on each functional device (10) is removed.

Description

201017744 六、發明說明: 【發明所屬之技術領域】 , 本發明係有關功能装置的製造方法,及具有該 .功能裝置之半導體裝置的製造方法。 、^ 【先前技術】201017744 6. Description of the Invention: [Technical Field of the Invention] The present invention relates to a method of manufacturing a functional device, and a method of manufacturing a semiconductor device having the functional device. , ^ [Prior technology]

自以往就提供一種高週波裝置、熱動式紅外線 感測器、MEMS(Micr〇 Electro Mechanical Systems;微機電 系統)装置(例如,加速度感測器、陀螺儀感測器、 超音波感測器、微型閥)等之功能裝置(功能性穿 置)。 " 此種功能裝置係備有基板、及具有既定功能 並形成在上述基板上之功能性薄膜。在上述基板形 成有使上述基板和上述功能性薄膜呈空間上分離的 孔洞。 在製造功能裝置時,一般是使用基板的基礎 —晶圓(例如’矽晶圓)。在使用晶圓的情況,於晶 圓之一表面上形成上述功能性薄膜之後,藉由切割 將晶圓分割成複數個功能裝置。 上述的功能性薄膜係強度較低而脆弱。因此 在切割時,功能性薄膜有破損之虞。特別是在進行 將晶圓固定於切割台之真空吸引時或切割時之純粹 的喷射時,功能性薄膜有破損之虞。 3 201017744 有鑒於這樣的問題點,以文獻1 (日本國公 開專利公報第2 0 0 4 — 1 8 6 2 5 5號)所揭示 之功能裝置的製造方法而言,係在晶圓的一表面形 成T護層並於晶圓的另一表面貼附切割片之後再進 行晶圓的切斷。上述保護層係在晶圓切斷後被除 去。上述文獻1揭示使用黏著性的保護片來取代保 護層。 “ 以文獻2 (曰本國公開專利公報第2 〇 〇 5 1 9 7 4 3 6號)所揭示之功能裝置的製造方法 而。係於a曰圓上开> 成抗蚀膜後,利用此抗蚀膜將 保濩片貼附之後再進行晶圓的切斷。保護片係在晶 圓之切斷後藉由溶解抗蝕膜而被除去。 然而,上述文獻1所揭示之功能裝置的製造 方法中,在除去保護層或保護片之後,在功能裝置 $表面還是會有殘留保護層的一部份或保護片的黏 著劑等之虞。附著於功能裝置的表面上的保護層之 一部份或保護片的黏著劑乃成為使功能裝置的性能 降低之一因素。 又,上述文獻2所揭示之功能裝置的製造方法. 中,在透過旋塗等方式將抗蝕劑塗布於晶圓上之 後,使之熱硬化而形成抗蝕膜。因此,在抗蝕劑熱 硬化時發生抗蚀膜的膨脹收縮而對功能性薄膜施加 應力。依此,功能性薄膜有被破壞之虞。又,例如 在利用濕式蝕刻來除去抗蝕膜之際功能裝置亦有被 201017744 破壞之虞 【發明内容】 本發明乃有鑒於上述事由而作成者。本發明之 目的在於提供一種可提升良率且能防止因有機物之 附著而引起功能裝置的性能降低之功能裝置的 方法,及具有功能裝置之半導體裝置的製造方法\ 本發明所涉及之功能裝4的製造方法所製造之 功能裝置係具備基板;及 幵/成在上述基板上且具既定功能之功能性薄 膜,且在上述基板上形成有用以將上述基板和卫述 功能性薄膜作空間上分離之孔洞。 參 上述本發明所涉及之功能裝置的製造方法具備 晶圓處理步驟、貼附步驟、切割步驟、剝離步驟、 及除去步驟。上述於晶圓處理步驟,在上述基板為 基底的晶圓之—表面上形成上述功能性薄膜。在上 述,附步驟t ’於上述晶圓處理步驟之後,將用有 黏著劑的保護片直接地貼附於上述晶圓的一表面, 同時將切割片貼附於上述晶圓的另一表面。在切割 步驟中於上述貼附步驟之後,在未切斷上述切割 片之下將上述保護片和上述晶圓並將上述晶圓分割 成複數個上述功能裝置。在剝離步驟中,於上述切 °|J γ驟之後,從各上述功能裝置剝離上述保護片。 在上述除去步驟中,於上述剝離步驟之後,除去附 201017744 著於各上述功能裝置之含有上述保護片的上述黏著 劑之無用的有機物。 依據此發明,因為利用上述保護片和上述切割 片將上述晶圓切斷’故在切_時可防止上述功能性 薄膜破損’能提升良率。又’由於可除去附著於上 述功能裝置之無用的有機物,故可防止因有機物之 附著而造成上述功能裝置的性能降低。因而能提升 上述功能裝置的性能。 特別是,即使在上述剝離步驟後,上述功能裝❹ 置仍附著有上述黏著劑’亦可在上述除去步驟確實 ㈣去上述黏著劑。因此’可防止因上述黏著劑之 附著而造成上述功能裝置的性能惡化。 上述功能裝置係具有貫通上述功能性薄膜的厚 度方向並與上述孔洞連通之細縫。在上述除去步驟 中,除去附著於上述細縫的内面與上述孔洞的内面 至少一方之無用的有機物。 士此來由於可除去附著於上述功能裝置之 無用的有機物,故可防止因有機物之附著而造成上 述功能裝置的性能降低。因而能提升上述功能裝 的性能。 x 較佳為,上述剝離步驟令,於上述保護片中之 與上述晶圓相反侧的面上安裴剥離用構件之後,將- 上述保護片和上述剝離用構件一起自上述功 剝離。 、 201017744 如此一來可圖謀降低成本。 車乂佳為上述保5蒦片,係利用―經加熱黏著力 就會降低的黏著劑之加熱剝離型黏著片。 如此-來,藉由加熱上述保護片,可容易地將 上述保護片自上述功能裝置剝離。因此,在上述保 護片剝離時可抑制上述功能性薄膜發生破損。 更佳為’上述剝離步驟中,在將上述保護片從 ❿上述功能裝置剝離之前,對上述保護月全面均一地 -邊施加壓力一邊將上述保護片均一地加熱。 ^如此來,在上述保護片剝離時可防止上述保 護片被分斷’可將上述保護片確實地自上述功能性 薄膜剝離。 ,透過本發明所涉及之半導體裝置的製造方法所 製造之半導體裝置為具備功能裝置、及收容上述功 此震置之封跋體。上述功能裝置係具備:基板、及 ❹成在上述基板上之具既定功能的功能性薄膜。在 上=基板形成有用以使上述基板和上述功能性薄膜 呈空間上分離之孔洞。上述封裝體是由構裝有上述 功能裝置的基體、及和上述基體包圍上述功能裝置 的帽蓋所構成。 ‘ ^述本發明所涉及之半導體裝置的製造方法具 備θθ圓處理步驟、貼附步驟、切割步驟、剝離步 驟、除去步驟、構裝步驟、及密封步驟。於上述晶 圓處理步驟巾,在上述基板為基底的晶圓之一表面 201017744 上形成上述功能性薄膜。於上述貼附步驟,在上述 晶圓處理步驟之後,將用有黏著劑的保護片直接地 貼附於上述晶圓的一表面,同時將切割片貼附於上 述晶圓的另一表面。在上述切割步驟中,於上述貼 附步驟之後,在未切斷上述切割片之下將上述保護 片和上述晶圓並將上述晶圓分割成複數個上述功能 裝置。在上述剝離步驟中,於上述切割步驟之後, 從各上述功能裝置剝離上述保護片。在上述除去步 驟中,於上述剝離步驟之後,除去附著於各上述功❹ 月&裝置之3有上述保護片的上述黏著劑之無用的有 機物。在上述構裝步驟中,於上述切割步驟之後, 使用第一接著劑將上述功能裝置構裝於上述基體。 在上述密封步驟中,於上述除去步驟及上述構裝步 驟之後,使用第二接著劑將上述帽蓋接合於上述基 體並在上述封裝體將上述功能裝置氣密密封。 依據此發明,因為可除去附著於上述功能裝置 之無用的有機物,故可防止因有機物之附著而造成參 上述功能裝置的性能降低。因此,能防止上述半導 體裝置的性能降低。 較佳為,在上述密封步驟中,將上述帽蓋接合 於上述基體使上述封裝體内成為真空或正屢。 如此一來,因為從上述功能裝置除去無用的有-機物,沒有因有機物之脱氣而使上述封裴體内的壓 力變化的情形。因此,可防止上述半導體裝置的性 201017744 能降低。特別是,若將上述封裝體内設成真空,能 消除上述封裝體内之真空度的變化而可提高上述半 導體裝置的可靠性。又甚验 β, 又右將上述封裝體内詨為正 壓’則大氣等之上述封裝體外的氣體不會流入封裝 體内。因此,可提高上述半導體裝置的可靠性。 更佳為,上述第一接著劑與上述第二接著劑至 少一方係由無機材料所構成。 士此來,即使在上述封裝體設為氣密的情 ,,能消除因來自於上述第一接著劑、上述第二接 著劑的脱氣而造成内部壓力變化的情形。 較佳為,在上述密封步驟之前,除去附著於上 述基體與上述帽蓋至少一方上的有機物。 如此一來,可防止上述半導體裝置的性能降低。 較it為,在上述除去步驟之前進行上述構裝步 驟。在上述除去步驟中,除去附著於上述基體的有 ❿ 機物。 如此一來,在將上述功能裝置構裝於上述基體 之後,可同時除去上述功能裝置之無用的有機物和 上述基體之無用的有機物。因此,可防止上述半導 體裝置的性能降低,且能提升良率。 【實施方式】 【發明最佳實施形態】 (第一實施形態) 201017744 第二圖及第三圖顯示藉由本實施形態之功能裝 置的製造方法所製造的功能裝置1 〇。 功能裝置1 〇為紅外線陣列感測器(紅外線影 像感測器)。功能裝置i 0具備有基板i及具有既定 功能並形成在基板1上之功能性薄膜2。 基板1為矽基板。在基板i之厚度方向的一面_ 主表面(第- ® ( e )中的上面),形成有功能性薄 膜2。 如第二圖(a )所示,功能性薄膜2具備有呈 二維陣列狀配置的m X n個(在圖示例中為2 χ 2個) 功能性元件3 0。此外,功能性薄膜2亦可僅具備 一個功能性元件3 0。 功能性元件3 0係具有由熱電堆所成的熱電偶 型之感測元件2 0的熱動式紅外線檢測元件。功能 性元件3 0係作為紅外線影像感測器中之晝素的光 電變換元件而發揮作用。此外,在第二圖(b )中, 將感測元件2 0圖示成與感測元件2 〇的熱電動勢 對應之電壓源。 在此,於基板1上形成有孔洞5,用以使基板 1和功能性薄膜2在空間上呈分離。孔洞5係使功 能性薄膜2的功能性元件3 〇和基板χ形成熱隔 離。依此,可使屬紅外線檢測元件的功能性元件3 0之感度提升。在圖示例中,孔洞5係被形成在基 板1上的凹坑。孔洞5亦可為貫通基板丄厚度方向 201017744 的孔。 如第二圖(b )所示,功能性元件3 0的-部 知(功月匕1±薄膜2的-部份)係藉孔洞5而與基板 1呈空間上分離。功能性元件3 Q中之與基板工呈 空間上分離的部分係構成吸收紅外線的紅外線吸收 體j 1。在此紅外線吸收體2 i之矩形區域的四個 角落,形成有將功能性元件3 〇厚度方向貫通的細 ❹縫(貫通孔)4。細縫4與孔洞5連通。藉由形成 此種細縫4,可將紅外線吸收體2 和基板i形成 熱隔離。因此,可使紅外線檢測元件_功能性元件3 0的感度提升。此外,細縫4的形狀不僅是矩形, 可因應二角形、橢圓形或圓形等之期望而作各種選 擇。 如第三圖(b )所示’功能性元件3 〇係藉由 將積層構造體圖案化而形成,該積層構造體是由氧 Ο 化矽膜1 1、氮化矽膜1 2、感測元件2 0、層間 絶緣膜1 7、及純化膜1 9所構成。由此種積層構 造體所形成的功能性元件3 0係比基板1還薄很 多。 氧化碎膜1 1係被形成在基板1的主表面。氮 . 化矽膜1 2被形成在氧化矽膜1 1上。感測元件2 0被形成在氮化矽膜1 2上。層間絶緣膜1 7被形 成為藉氮化矽膜1 2的表面側(第三圖(b )中的 上面侧)覆蓋感測元件2 0。層間絶緣膜1 7例如 201017744 是 B P S G ( Boro-PhosphoSilicate Glass)膜。鈍化 膜1 9被形成在層間絶緣膜1 7上》鈍化膜1 9例 如是 P S G ( Phospho SilicateGlass)膜和被形成在 P SG 膜上的 NSG ( Non-doped Silicate Glass )膜 之積層膜。Since the past, a high-frequency device, a thermal infrared sensor, and a MEMS (Micr〇 Electro Mechanical Systems; MEMS) device have been provided (for example, an acceleration sensor, a gyro sensor, an ultrasonic sensor, Functional device such as microvalve) (functional wear). " Such a functional device is provided with a substrate and a functional film having a predetermined function and formed on the substrate. A hole is formed in the substrate to spatially separate the substrate from the functional film. In the manufacture of functional devices, the base of the substrate, such as a wafer (e.g., wafer), is typically used. In the case of using a wafer, after forming the above functional film on one surface of the wafer, the wafer is divided into a plurality of functional devices by dicing. The above functional film is weak and fragile. Therefore, the functional film is damaged when it is cut. In particular, when the wafer is fixed to the vacuum suction of the cutting table or the pure ejection at the time of cutting, the functional film is damaged. 3 201017744 In view of such a problem, the manufacturing method of the functional device disclosed in the document 1 (Japanese Laid-Open Patent Publication No. 2 0 0 - 1 8 6 2 5 5) is on a surface of the wafer. After the T-cladding layer is formed and the dicing sheet is attached to the other surface of the wafer, the wafer is diced. The protective layer is removed after the wafer is cut. The above document 1 discloses the use of an adhesive protective sheet in place of the protective layer. "Using the method of manufacturing the functional device disclosed in Document 2 (Japanese Laid-Open Patent Publication No. 2 No. 5 1 9 7 4 3 6). This is made by opening a circle and forming a resist film. After the resist film is attached to the resist film, the wafer is cut. The protective sheet is removed by dissolving the resist film after the wafer is cut. However, the method for manufacturing the functional device disclosed in the above document 1 After removing the protective layer or the protective sheet, there is still a part of the protective layer on the surface of the functional device or the adhesive of the protective sheet, etc. One part of the protective layer attached to the surface of the functional device The adhesive of the protective sheet is one of the factors for degrading the performance of the functional device. Further, in the method of manufacturing the functional device disclosed in the above document 2, after the resist is applied onto the wafer by spin coating or the like, Then, the resist film is thermally cured to form a resist film. Therefore, when the resist is thermally cured, expansion and contraction of the resist film occurs to apply stress to the functional film. Accordingly, the functional film is destroyed. In addition to using wet etching The functional device for removing the resist film is also destroyed by 201017744. [Invention] The present invention has been made in view of the above circumstances. It is an object of the present invention to provide an improvement in yield and prevention of adhesion due to organic matter. A method of a functional device having a reduced performance of a functional device, and a method for manufacturing a semiconductor device having a functional device. The functional device manufactured by the method for manufacturing the functional device 4 according to the present invention includes a substrate; and/or on the substrate And a functional film having a predetermined function, and forming a hole for spatially separating the substrate and the functional film on the substrate. The manufacturing method of the functional device according to the present invention includes a wafer processing step. The attaching step, the dicing step, the stripping step, and the removing step. The above-described functional film is formed on the surface of the wafer on which the substrate is a substrate in the wafer processing step. In the above, the step t' is applied to the crystal After the round processing step, a protective sheet with an adhesive is directly attached to a surface of the wafer. Simultaneously attaching the dicing sheet to the other surface of the wafer. After the attaching step in the dicing step, the protective sheet and the wafer are divided and formed into the wafer without cutting the dicing sheet. a plurality of the above-mentioned functional devices. In the peeling step, the protective sheet is peeled off from each of the functional devices after the cutting step. In the removing step, after the peeling step, the attached 201017744 is removed from each of the above According to the invention, the protective film and the dicing sheet are used to cut the wafer, so that the functional film can be prevented from being damaged. The yield is improved. Further, since the useless organic substances adhering to the functional device can be removed, the performance of the functional device can be prevented from being lowered due to the adhesion of the organic substances. Therefore, the performance of the above functional device can be improved. In particular, even after the above-mentioned peeling step, the above-mentioned adhesive device adheres to the above-mentioned adhesive agent, and the above-mentioned adhesive can be surely removed in the above-mentioned removing step. Therefore, the deterioration of the performance of the above functional device due to the adhesion of the above-mentioned adhesive can be prevented. The functional device has a slit that penetrates the thickness direction of the functional film and communicates with the hole. In the removing step, the useless organic matter adhering to at least one of the inner surface of the slit and the inner surface of the hole is removed. Since the use of the organic substance adhering to the functional device can be removed, the performance of the functional device can be prevented from being lowered due to the adhesion of the organic substance. Therefore, the performance of the above functional device can be improved. Preferably, the peeling step causes the protective sheet and the peeling member to be peeled off from the work together with the peeling member on the surface opposite to the wafer in the protective sheet. , 201017744 This can be used to reduce costs. Che Yujia is the above-mentioned protective sheet, which is a heat-peelable adhesive sheet that uses an adhesive which is lowered by heat. In this manner, the protective sheet can be easily peeled off from the functional device by heating the protective sheet. Therefore, the above-mentioned functional film can be prevented from being damaged when the protective sheet is peeled off. More preferably, in the peeling step, the protective sheet is uniformly heated while uniformly applying the pressure to the protective month before the protective sheet is peeled off from the functional device. Thus, the protective sheet can be prevented from being broken when the protective sheet is peeled off. The protective sheet can be surely peeled off from the functional film. A semiconductor device manufactured by the method of manufacturing a semiconductor device according to the present invention is provided with a functional device and a package that accommodates the above-described function. The functional device includes a substrate and a functional film that has a predetermined function on the substrate. The upper substrate is formed with holes which are spatially separated from the above-mentioned substrate and the above functional film. The package is composed of a base body that houses the functional device and a cap that surrounds the functional device with the base body. The method for manufacturing a semiconductor device according to the present invention has a θθ circle processing step, an attaching step, a dicing step, a stripping step, a removing step, a structuring step, and a sealing step. In the above-described wafer processing step, the functional film is formed on one surface 201017744 of the substrate on which the substrate is a substrate. In the attaching step, after the wafer processing step, a protective sheet with an adhesive is directly attached to one surface of the wafer while the dicing sheet is attached to the other surface of the wafer. In the dicing step, after the attaching step, the protective sheet and the wafer are divided into a plurality of the functional devices without cutting the dicing sheet. In the peeling step, after the cutting step, the protective sheet is peeled off from each of the functional devices. In the above removal step, after the above-mentioned peeling step, the useless organic matter adhering to the above-mentioned adhesive sheet of the above-mentioned protective sheet is removed. In the above-described structuring step, after the dicing step, the functional device is attached to the substrate using a first adhesive. In the sealing step, after the removing step and the structuring step, the cap is bonded to the substrate using a second adhesive, and the functional device is hermetically sealed in the package. According to the invention, since the useless organic matter adhering to the functional device can be removed, it is possible to prevent the performance of the functional device from being lowered due to the adhesion of the organic substance. Therefore, the performance of the above semiconductor device can be prevented from being lowered. Preferably, in the sealing step, the cap is joined to the base body to make the package body vacuum or positive. As a result, since the useless organic matter is removed from the functional device, there is no possibility that the pressure in the sealing body changes due to degassing of the organic matter. Therefore, it is possible to prevent the above-described semiconductor device property 201017744 from being lowered. In particular, if the package body is vacuumed, the change in the degree of vacuum in the package can be eliminated, and the reliability of the semiconductor device can be improved. Further, when β is detected, and the inside of the package is positively pressurized, the gas outside the package such as the atmosphere does not flow into the package. Therefore, the reliability of the above semiconductor device can be improved. More preferably, at least one of the first adhesive and the second adhesive is made of an inorganic material. In the case where the package is made airtight, it is possible to eliminate the internal pressure change caused by the degassing from the first adhesive and the second adhesive. Preferably, the organic substance adhering to at least one of the base body and the cap is removed before the sealing step. As a result, the performance of the above semiconductor device can be prevented from being lowered. More than this, the above-described constitutional steps are carried out before the above removal step. In the above removal step, the organic matter attached to the substrate is removed. In this manner, after the functional device is mounted on the substrate, the useless organic matter of the functional device and the useless organic matter of the substrate can be simultaneously removed. Therefore, the performance of the above-described semiconductor device can be prevented from being lowered, and the yield can be improved. [Embodiment] BEST MODE FOR CARRYING OUT THE INVENTION (First Embodiment) 201017744 The second and third figures show a functional device 1 manufactured by the manufacturing method of the functional device of the present embodiment. The functional device 1 is an infrared array sensor (infrared image sensor). The functional device i 0 includes a substrate i and a functional thin film 2 having a predetermined function and formed on the substrate 1. The substrate 1 is a germanium substrate. The functional film 2 is formed on one surface of the substrate i in the thickness direction - the main surface (the upper surface in the - (e)). As shown in the second diagram (a), the functional film 2 is provided with m x n (2 χ 2 in the illustrated example) functional elements 30 arranged in a two-dimensional array. Further, the functional film 2 may have only one functional element 30. The functional element 30 is a thermal infrared detecting element having a thermocouple type sensing element 20 made of a thermopile. The functional element 30 functions as a photo-electric conversion element of a pixel in an infrared image sensor. Further, in the second diagram (b), the sensing element 20 is illustrated as a voltage source corresponding to the thermoelectromotive force of the sensing element 2 。. Here, a hole 5 is formed in the substrate 1 for spatially separating the substrate 1 and the functional film 2. The hole 5 is such that the functional element 3 of the functional film 2 and the substrate are thermally isolated. Accordingly, the sensitivity of the functional element 30 belonging to the infrared detecting element can be improved. In the illustrated example, the holes 5 are formed in pits on the substrate 1. The hole 5 may also be a hole penetrating through the substrate 丄 thickness direction 201017744. As shown in the second diagram (b), the portion of the functional element 30 (the portion of the film 2) is spatially separated from the substrate 1 by the hole 5. The portion of the functional element 3 Q that is spatially separated from the substrate unit constitutes an infrared absorbing body j 1 that absorbs infrared rays. In the four corners of the rectangular region of the infrared absorbing body 2 i, a fine quilting (through hole) 4 penetrating the functional element 3 in the thickness direction is formed. The slit 4 is in communication with the hole 5. By forming such a slit 4, the infrared absorbing body 2 and the substrate i can be thermally isolated. Therefore, the sensitivity of the infrared detecting element_functional element 30 can be improved. Further, the shape of the slit 4 is not only a rectangle, but may be variously selected in accordance with the expectation of a square, an ellipse or a circle. As shown in the third figure (b), the functional element 3 is formed by patterning a laminated structure which is made of a ruthenium oxide film 1 and a tantalum nitride film. The element 20, the interlayer insulating film 17 and the purification film 19 are formed. The functional element 30 formed by such a laminated structure is much thinner than the substrate 1. The oxidized fragment film 11 is formed on the main surface of the substrate 1. Nitrogen The ruthenium film 12 is formed on the ruthenium oxide film 11. The sensing element 20 is formed on the tantalum nitride film 12. The interlayer insulating film 17 is formed to cover the sensing element 20 by the surface side of the tantalum nitride film 12 (the upper side in the third figure (b)). The interlayer insulating film 17 such as 201017744 is a B P S G (Boro-PhosphoSilicate Glass) film. The passivation film 19 is formed on the interlayer insulating film 17 by a passivation film such as a P S G (Phospho Silicate Glass) film and a laminated film of a NSG (Non-doped Silicate Glass) film formed on the P SG film.

在功能裝置1 0中’層間絶緣膜1 7和鈍化膜 1 9的積層膜係構成紅外線吸收膜2 2。紅外線吸 收膜2 2之厚度t為λ/4 η。在此,η是紅外線 吸收膜2 2的折射率,又是檢測對象的紅外線(例 如,由人體放射之波長8〜1 2 //m的紅外線)之 中心波長。如此一來,可提兩紅外線吸收膜2 2對 檢測對象的紅外線之吸收效率。例如,可作成在η = 1.4,Λ = 1〇/ζηι 的情況,t 与 在此情況下,可作成層間絶緣膜丄7的膜厚是〇 · 8//111,?8〇膜的膜厚是0.5#111,^^3(5膜In the functional device 10, the laminated film of the interlayer insulating film 17 and the passivation film 19 constitutes the infrared absorbing film 22. The thickness t of the infrared absorbing film 2 2 is λ/4 η. Here, η is the refractive index of the infrared absorbing film 22, and is the center wavelength of the infrared ray (for example, the infrared ray of the wavelength of 8 to 12 //m emitted by the human body) to be detected. In this way, the absorption efficiency of the infrared ray of the object to be detected by the two infrared absorbing films 2 2 can be extracted. For example, in the case where η = 1.4, Λ = 1 〇 / ζ ηι, t and in this case, the film thickness of the interlayer insulating film 丄 7 is 〇 · 8//111, ? The film thickness of the 8〇 film is 0.5#111, ^^3 (5 film)

的膜厚是0 . 5 // m。此外,鈍化膜丄9亦可為氮 化矽膜。 如第三圖(a )所示,感測元件2 〇係具備串 接的四個熱電偶2 〇 〇。各熱電偶2 〇 〇係由p型 複晶矽層1 5、n型複晶矽層丄3、及連接層2 3 所構成。p型複晶矽層1 5和η型複晶矽層2 3係 形成跨紅外線吸收體2 i和基板工。ρ型複晶矽層 1 5與η型複晶矽層1 3形成相互不接觸。連接層 2 3,係在紅外線吸收體2 i巾之基板丄侧的相^ 12 201017744 側之面紅外線人射面側(第三圖(b ) #的上面側: 將P 複曰曰矽層1 5和n型複晶矽層工3電性連 接:連接層23係例如由…Si等之金屬材料 所形成連接層2 3係通過被形成在層間絶緣膜工 7之接觸孔2 5而複晶#層i 3及。型複晶 矽層1 5各自電性連接。 /熱電偶2 0 〇之p型複晶矽層丄5的另一端, ⑩係在基板1的主表面側,藉由配線工8而被電性連 接在相㈣熱電偶之η型複晶㈣丄3的另一端。 配線1 8係例如由八1 — S i等之金屬材料所形 成。四個熱電偶2GQ係藉由配線18被串接^構 成由熱電堆所成的感測元件2 〇。感測元件2 〇具 有配置在紅外線吸收體2 1上的溫接點、及配置在 基板1上的冷接點。上述溫接點係由n型複晶矽層 1 3的一;^、ρ型複晶矽層1 5的一端、及連接層 ® 2 3所構成。上述冷接點係由ρ型複晶石夕層工5的 另一端、η型複晶矽層1 3的他端、及配線i 8所 構成。 如第二圖(a )所示,功能性薄膜2具備複數 個(圖示例中為四個)輸出用墊(24丄〜2 4 4 )及一個基準偏壓用墊2 6。各感測元件2 〇 的端係經由垂直讀出線2 7而電性連接於對應的 輸出用塾24。X,各感測元件2 〇的另一端,係 、、’i由基準偏壓線2 8而電性連接於共通基準偏壓線 13 201017744 f U通基準偏壓線2 9係電性連接於基準偏壓 2 6。亦即,於各輸出用塾2 4上,感測元件 2 〇各自的—端係各別連接。於基準錢用塾2 6 上’複數個_元件2 ◦的另—端係共通地連接。 在此功能裝置10令,例如,藉由將基權 :墊26的電位設為].“v,可從各輸出用塾 2 4取出功能性元件3 0的輸出電壓(i . 6 5 v +感測元件2 0的輸出電壓)。 在紅外線吸收體21的紅外線人射面,形成η 型補償複晶秒層1 4及Ρ型補償複晶梦層i 6。η 型補償複晶料1 4與Ρ型補償複晶硬層1 6配置 成相互不接觸。η型補償複晶㈣i 4係與η型複 1 曰石夕層13 一體地形成。亦即,在進行η型複晶石夕 1 3之圖案化時,保留η型補償複晶矽層工‘的 :位。Ρ型補償複晶石夕層! 6係與ρ型複晶石夕層丄 5—體地形成。亦即’在進行Ρ型複騎層15之 圖案化時’保留ρ型補償複晶傾i 6的部位。 此種η型補償複晶石夕層丄4、p型補償複晶矽 1 6乃提高功能性元件3 〇之應力平衡的均一 ,。依此,可圖謀功能性元件3 ◦的薄膜化並防止 翹曲。依此,可提升屬紅外線檢測元件之功能性元 件3 〇的感度。 A其次參考第一圖及第四圖,就本實施形態之功 處裝置的製造方法作說明。 201017744 功能裝置的製造方法係具有晶圓處理步驟(前 段步驟)、及於晶圓處理步驟之後進行的分割步驟 (後段步驟)。 在晶圓處理步驟中,於基板i為基底的晶圓3 的一表面上形成功能性薄膜2。如第一圖(a )所 不,藉由晶圓處理步驟而獲得具有基板1和功能性 薄膜2之晶圓3。在此晶圓3的一表面(厚度方向 中的一面)3 a,形成有複數個功能裝置1 〇。於 本實施形態中’晶圓3的一表面3 “系功能性薄膜 2中之與基板1側相反側的面(第一圖(a )中的 上面)。晶圓3的另一表面(厚度方向中的另面) 3 b係基板1之厚度方向的另一面(第一 中的下面)。 本實施形態之功能裝置的製造方法在分割步驟 ❿ 上具有特徵。因此,晶圓處理步驟係因應功能裝置 10的構成而被適宜地變更。 以下,兹就功能裝置工〇是紅外線感測器的情 況下之晶圓處理步驟的一例作簡單地說明。 在晶圓處理步驟令,最初係進行絶緣層形成步 驟。在絶緣層形成步驟中’於基板工的上述主表面 形成絶緣層(熱絶緣層)。絶緣層係既定臈厚(例如, 3 0 0 0 A)的氧化砍膜i工與既定膜厚(例如, 9 0 0 A)的氮化矽膜丄2之積層膜。氧化矽膜丄 1係透過以既定溫度(例如,1 1 ocrc)對基板 201017744 。氮化矽膜1 2係依 1的主表面進行熱氧化而形成 L P C V D法而形成。 、’色緣層形成步驟後, 驟。在複晶石夕層來…Φ 複晶石夕層形成步 Μ…步中,利用LPCVD法在 ;〇二述主表面的全面上形成既定膜厚(例 複_乃成 矽層]4 尘稷曰曰夕層1 3、η型補償複晶 16的基礎陶晶石夕層15、Ρ型補償複晶石夕層 複二層形成步驟之後,進行複晶㈣圖案化 在禝晶砂層圖案化步驟中,利用平版印刷技 術及㈣技術,以可_與上述無摻純晶石夕層中 之11型複晶矽層1 3、η型補償複晶矽層i 4、ρ y型複晶石夕層1 5、ρ型補償複晶妙層1 6對應的部 为之方式將上述無摻雜複晶矽層圖案化。 …複騎層圖案化步驟之後,進行ρ型複晶石夕層 形成步驟。在Ρ型複晶矽層形成步驟中,在與上述 無摻雜複晶矽層中之Ρ型複晶矽層丄5及口型補償 複晶石夕層1 6對應的部分,進行ρ型不純物(例如, 爛等)之離子佈植,之後透過進行驅動而形成㈣ 複晶矽層1 5及ρ型補償複晶矽層1 6。 Ρ型複晶矽層形成步驟之後,進行11型複晶矽 層形成步驟。在η型複晶矽形成步驟中,在與上述 無摻雜複晶矽層中之η型複晶矽層1 3、η型補償 201017744 複晶石夕層1 4對應的部分,進行n型不純物 罐等)之離子佈植,之後透過進行驅動 。型 複晶石夕層13、η型補償複晶㈣14。此= ,晶石夕層形成步驟和η型複晶石夕層形成步驟之順 序亦可相反。 胃 在Ρ型複晶矽層形成步驟及η型複晶矽層形 步驟結束之後’進行層間絶緣膜形成步驟。在The film thickness is 0.5 mM. Further, the passivation film 丄9 may also be a ruthenium nitride film. As shown in the third diagram (a), the sensing element 2 has four thermocouples 2 串 in series. Each of the thermocouples 2 〇 is composed of a p-type polycrystalline germanium layer 15 , an n-type polycrystalline germanium layer 3 , and a connecting layer 2 3 . The p-type polycrystalline germanium layer 15 and the n-type poly germanium layer 2 3 form a cross-infrared absorber 2 i and a substrate. The p-type polycrystalline germanium layer 15 and the n-type poly germanium layer 13 are not in contact with each other. The connecting layer 23 is on the side of the substrate on the side of the substrate of the infrared absorbing body 2, on the side of the infrared radiation surface of the surface (the third figure (b) #: the 曰曰矽 layer 1 5 and n-type polysilicon layer 3 electrical connection: the connection layer 23 is formed, for example, by a metal material such as Si, and the connection layer 23 is formed by a contact hole 25 formed in the interlayer insulating film 7 #层i 3 and the type of the polysilicon layer 15 are electrically connected. /The other end of the thermocouple 2 0 pp-type polysilicon layer 5, 10 is on the main surface side of the substrate 1, by wiring The other end of the n-type polycrystal (4) 丄3 of the phase (4) thermocouple is electrically connected to the electrode 8. The wiring 1 8 is formed, for example, of a metal material such as 八1-S i. The four thermocouples 2GQ are The wiring 18 is connected in series to form a sensing element 2 that is formed by a thermopile. The sensing element 2 has a temperature contact disposed on the infrared absorber 21 and a cold junction disposed on the substrate 1. The temperature contact is formed by one end of the n-type polysilicon layer 13; one end of the p-type polysilicon layer 15 and the connection layer ® 23. The cold junction is formed by a p-type polycrystalline stone. Floor The other end of the 5, the other end of the n-type polysilicon layer 13 and the wiring i 8 are formed. As shown in the second diagram (a), the functional film 2 has a plurality of (four in the illustrated example) The output pads (24丄~2 4 4 ) and one reference bias pad 26. The ends of the sensing elements 2 〇 are electrically connected to the corresponding output ports 24 via the vertical readout lines 27 . The other end of each of the sensing elements 2 〇 is electrically connected to the common reference bias line 13 by a reference bias line 28 . The reference bias line 2 9 is electrically connected to the reference. The bias voltage is 26. That is, on each output 塾2 4, the sensing element 2 〇 is connected to each other. The other end of the 'multiple _ component 2 ◦ on the reference money 塾 2 6 In this functional device 10, for example, by setting the potential of the base:pad 26 to [.], the output voltage of the functional component 30 can be taken out from each output 塾2 4 (i 6 5 v + output voltage of the sensing element 20). In the infrared human emitting surface of the infrared absorbing body 21, an n-type compensation complex crystal second layer 14 and a Ρ-type compensation complex crystal layer i 6 are formed. The polycrystalline material 14 and the Ρ-type compensating polycrystalline hard layer 16 are disposed so as not to be in contact with each other. The n-type compensation polycrystal (4) i 4 system and the n-type complex 1 曰 夕 layer 13 are integrally formed. That is, the n-type is performed. When the pattern of Fujing Shixi 13 is patterned, the η-type compensation of the polycrystalline 矽 layerer is retained: the Ρ-type compensation of the crystallization layer of the ceramsite layer; the formation of the hexa-type polycrystalline stone 夕 layer 丄5-body formation That is, 'when the patterning of the 复-type complex riding layer 15 is performed', the portion of the p-type compensation polycrystal tilting i 6 is retained. The η-type compensation isocyanite 丄 layer 丄 4, p-type compensation complex 矽 1 6 It is to improve the uniformity of the stress balance of the functional components. Accordingly, the functional element 3 can be patterned to prevent filming and warpage. Accordingly, the sensitivity of the functional element 3 that is an infrared detecting element can be improved. A Next, with reference to the first and fourth figures, a method of manufacturing the device of the present embodiment will be described. 201017744 The manufacturing method of the functional device has a wafer processing step (previous step) and a dividing step (the latter step) performed after the wafer processing step. In the wafer processing step, the functional film 2 is formed on one surface of the wafer 3 on which the substrate i is a substrate. As shown in the first figure (a), the wafer 3 having the substrate 1 and the functional film 2 is obtained by a wafer processing step. On one surface (one side in the thickness direction) 3 a of the wafer 3, a plurality of functional devices 1 形成 are formed. In the present embodiment, 'one surface 3 of the wafer 3' is the surface on the opposite side to the substrate 1 side of the functional film 2 (the upper surface in the first diagram (a)). The other surface (thickness) of the wafer 3 The other side of the direction 3b is the other surface in the thickness direction of the substrate 1 (the lower side in the first direction). The manufacturing method of the functional device of the present embodiment has a feature in the dividing step 。. Therefore, the wafer processing step is in response. The configuration of the functional device 10 is appropriately changed. Hereinafter, an example of a wafer processing procedure in the case where the functional device process is an infrared sensor will be briefly described. In the wafer processing step, the insulation is initially performed. a layer forming step: forming an insulating layer (thermal insulating layer) on the main surface of the substrate in the insulating layer forming step. The insulating layer is a predetermined thickness (for example, 3,000 A) of the oxidized chipping and the predetermined a film of a tantalum nitride film 2 having a film thickness (for example, 900 A). The yttrium oxide film 1 is transmitted through a substrate at a predetermined temperature (for example, 1 1 ocrc) 201017744. The main surface of 1 is thermally oxidized to form LPC Formed by the VD method. After the step of forming the color edge layer, the film is formed in the layer of the polycrystalline stone. The Φ layer is formed in the step of the crystallization of the crystallization layer. In the step, the LPCVD method is used; Forming a predetermined film thickness (in the case of 复 _ 矽 ] ] ] ] ] ] ] ] ] ] ] 4 1 1 1 、 的 的 的 的 的 的 的 的 的 的 的 的 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶 陶After the step, the polycrystal (four) patterning is performed in the patterning step of the twinned sand layer, using the lithographic printing technique and the (4) technique, and the 11-type polycrystalline germanium layer 13 and η in the above-mentioned non-doped pure crystal spar layer The type of the compensation-free polysilicon layer i 4, the ρ y-type polycrystallite layer 1 , the p-type compensation complex layer 16 is corresponding to the pattern to pattern the above-mentioned undoped polysilicon layer. After the layer patterning step, a p-type polycrystalline layer formation step is performed. In the formation process of the germanium-type polysilicon layer, the germanium-type polysilicon layer 5 and the port in the undoped polysilicon layer are Compensating for the portion corresponding to the hexagonal layer of the polycrystalline stone layer, performing ion implantation of the p-type impurity (for example, rotten, etc.), and then driving to form (4) polycrystalline The ruthenium layer 15 and the p-type compensation polysilicon layer 16. After the Ρ-type polysilicon layer formation step, the 11-type polysilicon layer formation step is performed. In the η-type polysilicon formation step, the above-mentioned non-doped The n-type polycrystalline germanium layer 13 in the hetero-polycrystalline germanium layer, the n-type compensation 201017744, the portion corresponding to the tetralithic layer of the polycrystalline quartz layer, the n-type impurity tank, etc., is ion-implanted, and then driven through. The spar layer 13, the n-type compensation polycrystal (4) 14. This =, the sequence of the formation of the spar layer and the step of forming the n-type polycrystalline layer can also be reversed. The step of forming the bismuth-type polycrystalline layer and the η After the end of the step of forming a polysilicon layer, the interlayer insulating film forming step is performed. in

絶緣膜形成步驟中,於基板1之上述主表面上形二 層間絶緣臈1 7。 層間絶緣膜形成步驟之後,進行接觸孔形成步 驟。在接觸孔形成步*中,Μ用平版印刷技術复儀 刻技術,於層間絶緣膜1 7形成接觸孔2 5。 接觸孔形成步驟之後,進行金屬膜形成步驟。 在金屬膜形成步驟中,於基板^之上述主表面的全 面上,利用濺鍍法等形成既定膜厚(例如,2 # m ) 的金屬膜(例如,A i — S i臈)。此金屬膜乃成為 連接層2 3、配線1 8、垂直讀出線2 γ、基準偏 壓線28、共通基準偏壓線29、各墊24、26 的基礎。 金屬膜形成步驟之後,進行金屬膜圖案化步 驟。在金屬膜圖案化步驟中,藉由利用平版印刷技 術及蝕刻技術將金屬膜圖案化,形成連接層2 3、 配線1 8、垂直讀出線2 7、基準偏壓線2 8、共 通基準偏壓線29、各墊24、26。 201017744 金屬膜圖案化步驟之後,進行鈍化膜形成步 驟。在鈍化膜形成步驟中,於基板1之上述主表面 上(亦即,層間絶緣膜1 7的表面上),利用c v D 法形成由既定膜厚(例如,5 0 0 0 A)的p s g 膜與既定膜厚(例如,5 0 0 0 A )的n S G膜之 積層膜所成的鈍化膜1 9。 鈍化膜形成步驟之後,進行積層構造體圖案化 步驟。在積層構造體圖案化步驟中,透過將上述的 積層構造體圖案化而形成功能性薄膜2。具體而參 言,在積層構造體圖案化步驟中,藉由形成細縫4 而獲得功能性薄膜2。 積層構造體圖案化步驟之後,進行開口形成步 驟。在開口形成步驟中,利用平版印刷技術及蝕刻 技術,开> 成使各墊2 4、2 6露出的開口(未圖式)。 在開口形成步驟中,使用r I E。 開口形成步驟之後,進行孔洞形成步驟。在孔❹ 洞形成步驟中,將各細縫4當作蝕刻液導入孔並導 入蝕刻液而對基板1進行異向性蝕刻,藉以在基板 1上形成孔洞5。依此,如第二圖所示,獲得功能 性元件3 0呈二維陣列狀配列的功能裝置i 〇。孔 洞形成步驟中,使用加熱至既定溫度(例如,8 5 C )的丁 M A Η溶液作為蝕刻液。蝕刻液不限為丁 M A Η溶液,亦可為其他的鹼系溶液(例如,κ 〇 Η溶液等)。 18 201017744 驟、除去,驟 步驟、切割步驟、剝離步 驟除去步驟、及分離步驟。分 進行貼附步驟。中最初疋 在貼附步驟中,於晶圓3的另—表面3 b上貼 附切割片7。本實施形態中,將切 附於晶圓3的另一表面3b。並後U直接地貼 m w m mo /、後,將用以保護功 ,、纟保護片6直接地貼附於晶圓3的一表In the insulating film forming step, two interlayer insulating layers 17 are formed on the main surface of the substrate 1. After the interlayer insulating film forming step, a contact hole forming step is performed. In the contact hole forming step*, a contact hole 25 is formed in the interlayer insulating film 17 by a lithography technique. After the contact hole forming step, a metal film forming step is performed. In the metal film forming step, a metal film (e.g., A i - S i 臈 ) having a predetermined film thickness (for example, 2 # m ) is formed on the entire surface of the main surface of the substrate by sputtering or the like. This metal film serves as the basis for the connection layer 23, the wiring 18, the vertical readout line 2γ, the reference bias line 28, the common reference bias line 29, and the pads 24 and 26. After the metal film forming step, a metal film patterning step is performed. In the metal film patterning step, the metal film is patterned by using a lithography technique and an etching technique to form a connection layer 23, a wiring 18, a vertical readout line 27, a reference bias line 28, and a common reference bias. Press line 29, each pad 24, 26. 201017744 After the metal film patterning step, a passivation film formation step is performed. In the passivation film forming step, on the above main surface of the substrate 1 (that is, on the surface of the interlayer insulating film 17), a psg film having a predetermined film thickness (for example, 500 A) is formed by the cv D method. A passivation film 19 formed of a laminate film of an n SG film having a predetermined film thickness (for example, 500 A). After the passivation film forming step, a laminated structure patterning step is performed. In the laminated structure patterning step, the functional thin film 2 is formed by patterning the above-described laminated structure. Specifically, in the step of patterning the laminated structure, the functional film 2 is obtained by forming the slit 4. After the layered structure patterning step, an opening forming step is performed. In the opening forming step, an opening (not shown) in which each of the pads 24, 26 is exposed is opened by a lithography technique and an etching technique. In the opening forming step, r I E is used. After the opening forming step, a hole forming step is performed. In the hole forming step, each slit 4 is used as an etching liquid introduction hole and an etching liquid is introduced to anisotropically etch the substrate 1, whereby a hole 5 is formed in the substrate 1. Accordingly, as shown in the second figure, the functional device i 功能 in which the functional elements 30 are arranged in a two-dimensional array is obtained. In the hole forming step, a solution of butyl M A ruthenium heated to a predetermined temperature (e.g., 8 5 C) is used as an etchant. The etching solution is not limited to a butyl M A Η solution, and may be other alkali-based solutions (for example, a κ Η solution, etc.). 18 201017744 Step, removal, step, cutting step, stripping step removal step, and separation step. The attachment step is performed. Initially, in the attaching step, the dicing sheet 7 is attached to the other surface 3b of the wafer 3. In the present embodiment, the other surface 3b of the wafer 3 is attached. After U directly attaches m w m mo /, the protective sheet 6 is directly attached to the wafer 3 for protection work.

。依此,獲得第一圖(a)所示的構造。此 定。佯::呆二片6和切割片7的順序並未特別限 λ、保€片6比切割片7還先貼附於晶圓3上比較 月巨迅速地保護功能性薄膜2。 , …保濩片(暫固定片)6係將功能性薄膜2暫固 定並:以保護。保護片6係利用了黏著劑(接著劑) ,黏著片(接著片)。此種黏著片係藉由在例如厚度 是1〜50〇em左右的塑膠或聚酯等之片狀或帶 狀的基材之表面塗布黏著劑而形成。特別是,保護 片6係以使用能保護功能性薄膜2免受晶圓3切割 時之切斷應力及冷却洗淨所產生之應力的影響,且 不妨礙晶圓3之切斷的黏著片者為宜。 作為保護片6,宜使用紫外線剝離型黏著片、 水溶性剝離型黏著片、熱剝離型黏著片。紫外線剝 離型黏著片是使用依紫外線之照射會降低黏著力的 黏著劑之黏著片。水溶性剝離型黏著片係利用了黏 著力會因浸泡於水溶液而降低的黏著劑之黏著片。 19 201017744 熱剝離型黏著片係利用了黏著力會因加熱而黏著力 的黏著劑之黏著片。 在此,若考慮量產性,則以能短時間降低黏著 力者為宜。由此觀點來看’相較於水溶性剝離型黏 著片’還是使用加熱剝離型黏著片、紫外線剝離型 黏著片者為宜。又’在將水溶性剝離型黏著片剝離 之際,有必要按保護片6將功能裝置i 〇浸潰於水 溶液’因而’功能裝置i 〇的功能性薄膜2之特性 有劣化之虞。 —又,當考慮處理後的黏著力時,加熱剝離型黏 著片之殘留黏著力比紫外線剝離型黏著片還低。因 此,若使用加熱剝離型黏著片,可在不造成功能性 薄膜2損傷之下容易地剝離保護片6。特別是可提 升具有孔洞5及與孔洞5連通的細縫4之功能裝置 1 0的良率。. Accordingly, the configuration shown in the first diagram (a) is obtained. This is fixed.佯:: The order of staying two sheets 6 and cutting sheets 7 is not particularly limited. λ, and the sheet 6 is attached to the wafer 3 in comparison with the dicing sheet 7, and the functional film 2 is quickly protected. , ... protective film (temporary fixed film) 6 series will temporarily fix the functional film 2 and: to protect. The protective sheet 6 utilizes an adhesive (adhesive) and an adhesive sheet (attach sheet). Such an adhesive sheet is formed by applying an adhesive to the surface of a sheet or a belt-like substrate such as plastic or polyester having a thickness of about 1 to 50 〇em. In particular, the protective sheet 6 is an adhesive sheet which is capable of protecting the functional film 2 from the stress caused by the cutting stress at the time of cutting the wafer 3 and the cooling and cleaning, and does not hinder the cutting of the wafer 3. It is appropriate. As the protective sheet 6, an ultraviolet peeling type adhesive sheet, a water-soluble peeling type adhesive sheet, and a heat-peelable type adhesive sheet are preferably used. The ultraviolet ray-off type adhesive sheet is an adhesive sheet using an adhesive which reduces the adhesion by ultraviolet rays. The water-soluble peel-off adhesive sheet utilizes an adhesive sheet in which the adhesive is lowered by immersion in an aqueous solution. 19 201017744 The heat-peelable adhesive sheet utilizes an adhesive sheet of an adhesive which adheres to heat by adhesion. Here, in consideration of mass productivity, it is preferable to reduce the adhesion for a short period of time. From this point of view, it is preferable to use a heat-peelable pressure-sensitive adhesive sheet or a UV-peelable pressure-sensitive adhesive sheet as compared with the water-soluble release-type pressure-sensitive adhesive sheet. Further, when the water-soluble peeling type adhesive sheet is peeled off, it is necessary to impregnate the functional device i with the protective sheet 6 in the aqueous solution. Thus, the characteristics of the functional film 2 of the functional device i are deteriorated. - Further, when considering the adhesive force after the treatment, the residual adhesive force of the heat-peelable adhesive sheet is lower than that of the ultraviolet-peelable adhesive sheet. Therefore, if a heat-peelable adhesive sheet is used, the protective sheet 6 can be easily peeled off without causing damage to the functional film 2. In particular, the yield of the functional device 10 having the hole 5 and the slit 4 communicating with the hole 5 can be improved.

作為此種加熱剝離型黏著片,可使用利用了含 有熱膨脹性微粒子的黏著劑(例如,橡膠系黏著劑、 丙烯酸系黏著劑、乙烯烷基醚系黏著劑、矽系黏著 劑、聚酯系黏著劑、聚醯胺系黏著劑、胺甲酸乙酯 系黏著劑、氟系黏著劑)之黏著片。熱膨脹性微粒 子可使用例如將容易因加熱而氣體化並膨脹的物質 (例如異丁烷、丙烷、戊烷)包於具彈性的殼内之 微膠囊。 於晶圓3的一表面3 a上貼附保護片6時,在 20 201017744 晶圓3的-表面3a上配置保護片6,利用橡膠滾 靖或則、壓機等之器具將保護^朝晶㈣的一 表面^按壓即可。此外,在是利用使用了帶狀基 材的黏者片來作為保護片6的情況,亦可藉由捲軸 (—oil)方式將保護片6貼附於晶圓3。 在切割步驟中,於貼附步驟之後,在未切斷切 割片7之下將保護片6和晶圓3切斷並將晶圓3分 割成複數個功能裝置1 0。 首先’在㈣步驟中,進行將晶圓3固定於平 ,環(未圖式)的晶圓安裝。晶圓3與平板環之固 疋係以使用了切割片7的通常方法來進行。因此, 晶圓3係藉另一表面3b而被固定於平板環。在晶 圓安裝之後,將固定有晶圓3的平板環固定於切割 裝置的切割台(未圖式)。例如,藉真空吸引將平板 環固定於切割台。 1 鲁 在平板環固定於切割台之後,從保護片6#κ — 表面3a側)切斷晶圓3。具體而言,使用切割刀 片(未圖式)’沿著晶圓3上之鋸切線“ t… t )’依各保護片6而切斷晶圓3。切割係進行全切 而非半切。依此,獲得第-圖(b)所示的構造。 切割步驟後’晶圓3係藉由溝(切割溝)8而被分 割成複數個功能裝置10。亦即,晶圓3被晶片化。 硬數個功能農置10被固定於切割片7。 置1〇的功能性薄膜2貼附有被分割的保護月6: 201017744 在切割步驟中,使用例如厚度數十微米(_) 的切割刀片。在切割時,使切割刀片以3 〇 〇 〇〜 4 0 0 0 r pm左右的速度高速旋轉。又,為了進 =切割刀片之冷却與切削屑之除去,係在切割時進 行喷吹洗淨用純水。切斷晶圓3之後,從切割裝置 卸下平板環。此外’至於要全切或半切,可依功能 裝置1 0的材質、構造而適宜地選擇。 在剝離步驟(保護片剝離步驟)中,於切割步 驟之後,從各功能裝置1 0剝離保護片6。例如,鲁 在保護片6是使用加熱剝離型黏著片的情況,係藉 由加熱器(例如熱風乾燥器、熱板、近紅外線燈) 進行力熱各功能裝置1 〇的保護片Θ之加熱處理。 特別是在本實施形態中的剝離步驟中,使用剝離用 構件9進行保護片6的卿。剝離用構件9係例如 具有熱傳導性優越的金屬板、及内建於該金屬板用 以加熱该金屬板的加熱器之加熱板。又,在剝離用 構件9的金屬板形成有複數個細孔(未圖式)以吸 引保護片6並予以固定。 本實施形態中的剝離步驟中,如第一圖(c ) 所不,首先,於保護片6中之與晶圓3相反側的面 (第一圖(c)中的上面)安裝剝離用構件9。其 ••人,藉剝離用構件9將保護片6全面均一地一邊施 力π壓力一邊將保護片6均一地加熱。例如,將保護 片6以1 2 CTC加熱一分鐘。 22 201017744 當藉剝離用構件9加熱保護片6時,保護片6 之黏著劑中的熱膨脹性微粒子脹大。因而,在由黏 著劑所成的層之表面產生微小的凹凸,保護片6和 功能性薄膜2係從面接觸的狀態變化成點接觸的狀 態。其結果’保護片6和功能性薄膜2之接觸面積 減少而大大地降低保護片6的黏著力。 如此’在利用剝離用構件9加熱保護片6使黏 著力降低的狀態,將保護片6和制離用構件9一起 自功能裝置1 〇剝離。例如’利用剝離用構件9的 細孔吸引保護片6並予以固^。其次,將剝離角構 件9和保濩片6 -起舉起。依此,將保護片6和剝 離用構件9-起自功能裝置i Q剝離。依此剝離步 驟如第一圖(d)所示,可在未破壞功能裝置1 0 (特別疋功敗|性薄膜2 )之下較簡單地剝離保護 片6 〇 此外,在保護片6使用紫外線剝離型黏著片的 情況,取代加熱處理,改成進行對保護片6照射紫 外線之紫外線照射處理。又,在保護片6使用水溶 性剝離型黏著片的情況,取代加熱處理,改成進行 將保護片6浸潰於既定的水溶液之水溶液注入處 理。如此一來,可容易剝離保護片6。 在除去步驟令,於剝離步驟之後,除去附著於 各功能裝置1 Q上的無用的有機物。在此,無用的 有機物例如是光抗蝕劑、樹脂、矽油、助溶劑等之 23 201017744 染物質。特別是在本實施形態之情況,有機 有保蠖片6的黏著劑(附著於功能性薄膜2表 面的保護片6之黏著劑)。 含有此種保護片6的黏著劑之無用的有機物, ::可利用臭氧除去。臭氧係可藉由對氧氣照射紫 卜線或高頻微波而生成。 ’ 例如,在本實施形態中之除去步驟中,係進行 =用紫外線臭氧洗淨法(uv臭氧洗淨法)的乾式As such a heat-peelable pressure-sensitive adhesive sheet, an adhesive containing heat-expandable fine particles (for example, a rubber-based adhesive, an acrylic-based adhesive, a vinyl alkyl ether adhesive, an anthraquinone adhesive, or a polyester adhesive) can be used. Adhesive sheet of a drug, a polyamido-based adhesive, an urethane-based adhesive, or a fluorine-based adhesive. As the heat-expandable fine particles, for example, a microcapsule in which a substance which is easily gasified and expanded by heating (e.g., isobutane, propane, or pentane) is enclosed in an elastic shell can be used. When the protective sheet 6 is attached to one surface 3 a of the wafer 3, the protective sheet 6 is placed on the surface 3a of the wafer 3 on 20 201017744, and the protective sheet is protected by a rubber rolling or a press or the like. (4) One surface can be pressed. Further, in the case where the adhesive sheet using the tape-shaped substrate is used as the protective sheet 6, the protective sheet 6 may be attached to the wafer 3 by an -oil method. In the cutting step, after the attaching step, the protective sheet 6 and the wafer 3 are cut off and the wafer 3 is divided into a plurality of functional devices 10 under the uncut cutting sheet 7. First, in the (fourth) step, wafer mounting for fixing the wafer 3 to the flat and ring (not shown) is performed. The fixing of the wafer 3 and the flat ring is carried out by a usual method using the dicing sheet 7. Therefore, the wafer 3 is fixed to the flat ring by the other surface 3b. After the wafer is mounted, the plate ring to which the wafer 3 is attached is fixed to a cutting table (not shown) of the cutting device. For example, the flat ring is secured to the cutting table by vacuum suction. 1 Lu After the flat ring is fixed to the cutting table, the wafer 3 is cut from the protective sheet 6#κ - surface 3a side. Specifically, the dicing blade (not shown) is used to cut the wafer 3 along the respective protective sheets 6 along the sawing line "t...t" on the wafer 3. The cutting system performs full cutting instead of half cutting. Thus, the structure shown in Fig. (b) is obtained. After the dicing step, the wafer 3 is divided into a plurality of functional devices 10 by grooves (cutting grooves) 8. That is, the wafer 3 is wafer-formed. A plurality of functional agricultural units 10 are fixed to the cutting piece 7. The functional film 2 placed is attached with a divided protection month 6: 201017744 In the cutting step, for example, a cutting blade having a thickness of several tens of micrometers (_) is used. During cutting, the cutting blade is rotated at a high speed of about 3 〇〇〇 to 400 rpm. In addition, in order to reduce the cooling of the cutting blade and the removal of the cutting chips, the cleaning is performed while cutting. Pure water is used. After the wafer 3 is cut, the flat ring is removed from the cutting device. In addition, the whole material or the half cut may be appropriately selected depending on the material and structure of the functional device 10. In the peeling step (protective sheet peeling) In the step), after the cutting step, the protective sheet 6 is peeled off from each functional device 10. For example, in the case where the protective sheet 6 is a heat-peelable adhesive sheet, the heat treatment of the protective sheet of each functional device 1 is performed by a heater (for example, a hot air dryer, a hot plate, or a near-infrared lamp). In particular, in the peeling step in the present embodiment, the peeling member 9 is used to perform the protective sheet 6. The peeling member 9 is, for example, a metal plate having excellent heat conductivity, and is built in the metal plate for heating the metal sheet. A heating plate for the heater of the metal plate. Further, a plurality of fine holes (not shown) are formed in the metal plate of the peeling member 9 to attract and fix the protective sheet 6. In the peeling step in the embodiment, (c) First, the peeling member 9 is attached to the surface of the protective sheet 6 on the opposite side to the wafer 3 (the upper surface in the first drawing (c)). 9 The protective sheet 6 is uniformly heated uniformly while applying a force of π. For example, the protective sheet 6 is heated at 1 2 CTC for one minute. 22 201017744 When the protective sheet 6 is heated by the peeling member 9, In the adhesive of the protective sheet 6 The heat-expandable fine particles are swollen. Therefore, minute irregularities are generated on the surface of the layer formed of the adhesive, and the protective sheet 6 and the functional film 2 are changed from the state of the surface contact to the point contact. The result is 'protective sheet 6'. The contact area with the functional film 2 is reduced to greatly reduce the adhesive force of the protective sheet 6. Thus, the protective sheet 6 and the separation member 9 are together in a state where the protective sheet 6 is heated by the peeling member 9 to lower the adhesive force. The functional device 1 is peeled off. For example, the protective sheet 6 is sucked by the pores of the peeling member 9 and fixed. Next, the peeling angle member 9 and the security sheet 6 are lifted up. Accordingly, the protective sheet 6 is lifted. And the peeling member 9 is peeled off from the functional device i Q. Accordingly, the peeling step is as shown in the first figure (d), and can be made simpler without destroying the functional device 10 (specially Further, in the case where the ultraviolet ray-removable pressure-sensitive adhesive sheet is used as the protective sheet 6, in place of the heat treatment, the ultraviolet ray irradiation treatment for irradiating the protective sheet 6 with ultraviolet rays is changed. When the water-soluble peelable pressure-sensitive adhesive sheet is used as the protective sheet 6, instead of the heat treatment, the aqueous solution injection treatment for immersing the protective sheet 6 in a predetermined aqueous solution is carried out. As a result, the protective sheet 6 can be easily peeled off. After the removal step, after the stripping step, the useless organic matter attached to each functional device 1 Q is removed. Here, the useless organic substance is, for example, a photoresist such as a photoresist, a resin, an eucalyptus oil, or a co-solvent. In particular, in the case of the present embodiment, the adhesive of the protective sheet 6 (adhesive attached to the protective sheet 6 on the surface of the functional film 2) is organic. The useless organic matter of the adhesive containing such a protective sheet 6 can be removed by ozone. The ozone system can be formed by irradiating oxygen to a purple line or a high frequency microwave. For example, in the removal step in the present embodiment, the dry method of the ultraviolet ozone cleaning method (uv ozone cleaning method) is performed.

理。此外’除去步驟t,亦可利較用臭氧水除 去有機物(有機污染物)的濕式處理。 紧外線臭氧洗淨法 …係藉由對無用的有機物E 射短波長的紫外線而除去無用的有機物之方法。’Reason. Further, the removal of step t can also facilitate the wet treatment of removing organic matter (organic contaminants) with ozone water. The method of ozone cleaning by the outside line is a method of removing unnecessary organic matter by irradiating ultraviolet rays of a short wavelength to the useless organic substance E. ’

種紫外線臭氧洗淨法係利用了短波長的紫外線之 光氧化製程。無用的有機物係藉由吸收短波長的 外線而被分解。作為短波長的料線,係利用波 是184 . 9nm的紫外線、和波長是2 5 3 . nm的紫外線。當對氧分子照射丄8 4 · 9 紫外線時,氧分子成為臭氧。當對臭氧照射2 5 3 7 nm的波長之紫外線時’臭氧被分解同時產生 性氧。2 5 3 · 7 钱乎是被碳氫化^ 物和臭氧所吸收°依紫外線分解有機物而產生的4 成物係與活性氧反應成揮發性分子而自功能裝置] 0脱離。透過照射1 8 4 · 9 11„1和2 5 3 · 7『 m兩波長的紫外線’氣元素持續產生,氧分子成; 24 201017744 六、氧’臭氧被分解。 在此種紫外線臭氧洗淨法中, 置的框體内密閉功能裝置 ’、於密閉處理裝 框體,設置放射例如i R。於密閉處理裝置的 -,卜線之低心 體内以1〜2〇JL/mi 處里扃置的框 一邊流通氧氣(〇2氣)— 1 r〇 理裝置的框體内之力維持成常麗。:,,:::處 裝置的框體内之溫度宜訊 检閉處理 又且°又在室溫至3 s η和〇 , 1 5 0。〇之間。進行紫 d 5 0 C (例如 宜設在1〜12〇mi 氣淨的處理時間 —丄 之間。 然而,在除去步驟中 之前的剝離步驟中被制離。因此,==驟 附者於細縫4的内面與孔祠5的内面雙方上之 的有機物亦被一起除去。 上之無用 φ ^ ^ ^ 舌如此’在除去步驟中’勉 佳為除去附者於細縫4的内 ώ 七u ^ 4的内面與孔洞5的内面至少 一方上的無用的有機物。又,更好的是,除去㈣ 於細縫4的内面與孔柯5的内面雙方上之無用的 機物。亦即,在除去牛 ”、 i 去步驟_,宜進行能將有可能附 著於細縫4的内面之益用的古 ^ ς “、、用的有機物、和有可能附著 理。、自之無用的有機物雙方予以除去的處 在除去步驟中,介γ + , # 亦可在功此裝置][Q進行韻刻 感光性有機抗飿劑之灰务r 、占退灯㈣ 蜊又灭化(ashmg)處理。於進行灰 25 201017744 化處理時,首先,在未圖示之灰 晶圓保持器上配置功能裝置! 〇。2的腔室:之 使氧以標準狀態1〜10QQee/ ]在腔室内 cm)(例如 2 c c/m i n ( s m、1 n ( s c —i# iil: ^ C m )) — 邊流通 如邊非二腔室内的壓力設為η,”、(例 於室、ίΓ二)。其次,使晶圓保持器的溫度穩定 射= (例如180。〇。接著,透過將 ==1〇〇〜1KW(例如,45〇W)供 i理Q㈣(^’6()㈣)以進行灰化 驟^離步驟之後,進行分離步驟(切割片剝離步 能裳署t離步驟中,例如使用晶片保持器將晶片(功 户:裳置10)自切割片7分離。依此,如第—圖(〇 :可獲得各自被分割之複數個功能農置工〇。 二成為可將各功能裝置10利用於半導體裝置 (參考第六圖)等。 鲁 理步=上所狀魏裝置㈣造方法係具備晶圓處 ::、貼附步驟、切割步驟、剝離步驟、以及除 ;驟:在晶圓處理步驟中,在基板1的基礎-晶圓 中:二表面3a形成功能性薄膜2。在貼 =晶圓處理步驟之後,將用有黏著劑的 ::地貼附於晶圓3的一表面同時 步::片7貼附於晶圓3的另一表面3b。 騍中,於貼附步驟之後,在未切斷切割片7之下 26 201017744 將保護片6和晶圓3切斷並將晶圓3分別成複數個 功能裝置1 0。在剝離步驟中,於切割步驟之後, 從各功能裝置1 〇剝離保護片6。在除去步驟中, 於剝離步驟之後,將附著於各功能裝置i 〇上之屬 無用的有機物之保護片6的黏著劑除去。 依據此功能裝置的製造方法,因為是利用保護 片6和切㈣7將晶圓3切斷,故在切斷時可防止 ❹功能性㈣2破損,能提升良率。又,因為能除去 附著於功能裝置1 0之無用的有機物_保護片6的 黏著劑,故可防止因這樣的有機物之附著而造成功 能裝置1 0的性能降低。特別在功能裝置工〇是紅 外線感測器的情況,可防止因保護片6的黏著劑之 附,而造成熱特性之變化。因此,可防止紅外線感 測益的感度降低。再者,複數個紅外線感測器形成 具有均一的感測特性。 ❿ 又,在除去步驟中,係除去附著於細縫4的内 面與孔洞5的内面至少一方上之無用的有機物。因 此,由於能除去附著於功能裝置丄〇之細縫4、孔 洞5的内面之無用的有機物,故可防止因有機物之 附著而造成功能裝置1 0的性能降低。因而,可提 升功能装置10的性能。 又,在剝離步驟中,於保護片6中之與晶圓3 相反側的面安襞剝離用構件g之後,將保護片6和 剝離用構件9 -起自功能裝置1 0剝離。因此,可 27 201017744 圓謀降低成本。 又’保護片6 ’係利用了黏著力會因加熱而降 低的黏著劑之加熱剝離型黏著片。因此,藉由加妖 保護片6可容易將保護片6自功能裝置10剝離。 因而’在剝離保護片6時可抑制功能性薄膜2破損。 #者’於剝離步驟中’在將保護片6自功能裝 置1 0剝離之前’對保護片6的全面均一地一邊施 加壓力一邊對保護片6均一加熱。因此,可防止在 保護片6剝離時保護片6被分斷。因此可將保護片⑩ 6確實地自功能性薄膜2剝離。 此外’功能裝置1 〇不限定為上述的紅外線陣 列感測器。功能裝置i 0亦可為例如,加速度感測 器(一軸〜三軸的加速度感測器)或陀螺儀感測器、 壓力感測器、微致動器、麥克風、超音波感測器。 (第二實施形態) 第六圖顯示由本實施形態之半導體裝置的製造❹ 方法所製造之半導體裝置1 0 〇。半導體裝置1 〇 0具備功能裝置1 0及由I C晶片所成的信號處理 裝置33。又’半導體裝置1 〇〇乃如第五圖(c) 所示,係具備收容功能裝置1 〇及信號處理裝置3 3的封裝體4 0。 信號處理裝置3 3係建構成與紅外線感測器-功能裝置1 0協同作動。信號處理裝置3 3係具有 複數個(圖示例中為四個)輸入用墊3 1 ( 3 1 1 28 201017744 〜3 1 4)、及一個墊3 2。各輸入用墊3 1 1〜3 1 4經由配線3 5而與功能裝置1 〇的複數個(圖 示例中為四個)輸出用墊2 4 i〜2 4 4分別電性 連接。墊3 2被使用在對功能裝置2 〇的基準偏壓 用墊2 6賦予基準電壓。墊;3 2係經由配線3 5而 電性連接於基準偏壓用墊;2 6。配線3 5例如是使 用了金或鋁的接合線(b 0 n d i n g w . r e ) ° 再者,信號處理裝置3 3係具備··放大輸入用 塾31的輸出電壓之放大電路42;及將複數個輸 入用墊3 1的輸出電壓擇一地輸入放大電路4 .2之 多工器4 1 。 就處理裝置3 3 你莛構成可依序 -----W出來自功 能裝置1 ◦之各輸出用墊2 4的輸出電壓。若使用 =號處理裝置33則可獲得紅外線晝像號處理 裝置3 3係與魏裝置! Q分卿成,但亦可利用 =能裝置1〇的基板1來形成。亦即,也能將信號 處理裝置3 3一體設置於功能裝置i 〇。 唬 封裝體4 〇 ’係由構裳有功能裝 處理裝置3 3之金屬製的基體3 6、 “唬 包圍功能裝置10及信號處理丄體36 所構成。基體36係形成在一面(”目盍39 的矩形相狀。在基體3 6的内底面 裝置1 0及信號處理裝置3 3。 ^ ^ 1目盍3 9係形成可 29 201017744 閉塞基體3 6之上述開口的大小之矩形板狀。在功 能裝置1 0是紅外線感測器的情況,帽蓋3 9的材 料係使用紅外線可穿透的材料(例如矽)。此外,在 功能裝置1 〇是可視光感測器的情況,帽蓋3 9的 材料係使用對可視光具透光性的材料(例如玻璃)。 又’在功能裝置1 〇是加速度感測器的情況,帽蓋 3 9的材料可使用金屬材料。如此一來,帽蓋3 gThe ultraviolet ozone cleaning method utilizes a short-wavelength ultraviolet light photooxidation process. Useless organic matter is broken down by absorbing short-wavelength outer lines. As a short-wavelength material, the wave is 184.9 nm ultraviolet light and ultraviolet light having a wavelength of 2 5 3 . nm. When oxygen molecules are irradiated with 丄8 4 · 9 ultraviolet rays, the oxygen molecules become ozone. When ozone is irradiated with ultraviolet rays having a wavelength of 2 5 3 7 nm, ozone is decomposed and oxygen is generated. 2 5 3 · 7 Money is absorbed by hydrocarbons and ozone. The four-phase system produced by the decomposition of organic matter by ultraviolet light reacts with active oxygen to form volatile molecules and is separated from the functional device. Through the irradiation of 1 8 4 · 9 11 „1 and 2 5 3 · 7′ m two wavelengths of ultraviolet ray elements continue to be produced, oxygen molecules are formed; 24 201017744 VIII, oxygen 'ozone is decomposed. In this ultraviolet ozone cleaning method In the inside of the frame, the sealing function device is installed, and the sealing treatment frame is provided, for example, i R. In the case of the sealing device, the low-hearted body of the wire is 1 to 2 inches JL/mi. The flow of oxygen in the frame is maintained (〇2 gas) - the force inside the frame of the 1 r treatment device is maintained as Changli.:,,::: The temperature inside the frame of the device should be closed and processed. Further between room temperature and 3 s η and 〇, 150 ° 〇. Perform purple d 5 0 C (for example, it should be set between 1 and 12 〇mi gas treatment time - 丄. However, in the removal step In the peeling step before the middle, it is separated. Therefore, the organic matter on both the inner surface of the slit 4 and the inner surface of the bore 5 is also removed together. The useless φ ^ ^ ^ tongue is so In the removal step, it is preferable to remove the inner surface of the slit 7 from the inner surface of the slit 4 and at least one of the inner surface of the hole 5 Further, it is better to remove (4) the useless objects on both the inner surface of the slit 4 and the inner surface of the Kongke 5. That is, in the removal of the cattle", i to the step _, it is desirable to have It is possible to adhere to the inner surface of the slit 4, the organic matter, the organic matter used, and the organic matter that may be attached. The organic matter that is removed from use is removed in the removal step, and the γ + , # It can be processed in this device] [Q for the photographic gray organic anti-caries agent, the ash, and the ash, and the ash is processed. When the ash 25 201017744 is processed, first, not shown The function device is arranged on the ash wafer holder! 腔.2 chamber: the oxygen is in the standard state 1~10QQee/] in the chamber cm) (for example, 2 cc/min (sm, 1 n ( sc — i# Iil: ^ C m )) — The pressure in the non-two-chamber chamber is set to η,” (in the case of chamber, Γ2). Secondly, the temperature of the wafer holder is stabilized by shot = (for example, 180. Then, after ==1〇〇~1KW (for example, 45〇W) is supplied to Q(4)(^'6()(4)) to perform the ashing step, the step is performed. The step (the dicing stripping step can be performed in the step, for example, using a wafer holder to separate the wafer from the dicing sheet 7). Accordingly, as shown in the first figure (〇: each can be obtained The plurality of functions are divided into a plurality of functional agricultural facilities. Second, each functional device 10 can be used for a semiconductor device (refer to the sixth figure), etc. Lu Libu = the upper Wei device (four) manufacturing method has a wafer::, The attaching step, the cutting step, the stripping step, and the removing step; in the wafer processing step, in the base-wafer of the substrate 1: the two surfaces 3a form the functional film 2. After the post-wafer processing step, a surface of the wafer 3 is attached to the surface of the wafer 3 with the adhesive:: the sheet 7 is attached to the other surface 3b of the wafer 3. In the middle, after the attaching step, under the uncut cut piece 7 26 201017744 The protective sheet 6 and the wafer 3 are cut and the wafer 3 is divided into a plurality of functional devices 10 respectively. In the peeling step, after the cutting step, the protective sheet 6 is peeled off from each functional device 1 . In the removing step, after the peeling step, the adhesive of the protective sheet 6 which is an unnecessary organic substance adhering to each functional device i is removed. According to the manufacturing method of the functional device, since the wafer 3 is cut by the protective sheet 6 and the cut (four) 7, the function (4) 2 is prevented from being broken at the time of cutting, and the yield can be improved. Further, since the adhesive of the organic matter-protecting sheet 6 attached to the functional device 10 can be removed, it is possible to prevent the performance of the device 10 from being deteriorated due to the adhesion of such organic substances. Particularly in the case where the functional device process is an infrared sensor, it is possible to prevent a change in thermal characteristics due to the adhesion of the protective sheet 6. Therefore, it is possible to prevent the sensitivity of the infrared sensation from being lowered. Furthermore, a plurality of infrared sensors are formed to have uniform sensing characteristics. Further, in the removing step, the useless organic matter adhering to at least one of the inner surface of the slit 4 and the inner surface of the hole 5 is removed. Therefore, since it is possible to remove the useless organic matter adhering to the inner surface of the slit 4 and the hole 5 of the functional device, it is possible to prevent the performance of the functional device 10 from deteriorating due to the adhesion of the organic matter. Thus, the performance of the functional device 10 can be improved. Further, in the peeling step, after the peeling member g is placed on the surface of the protective sheet 6 opposite to the wafer 3, the protective sheet 6 and the peeling member 9 are peeled off from the functional device 10. Therefore, 27 201017744 can reduce costs. Further, the 'protective sheet 6' is a heat-peelable adhesive sheet using an adhesive whose adhesive force is lowered by heating. Therefore, the protective sheet 6 can be easily peeled off from the functional device 10 by the addition of the demon protection sheet 6. Therefore, the functional film 2 can be prevented from being damaged when the protective sheet 6 is peeled off. In the peeling step, 'before the protective sheet 6 is peeled off from the functional device 10', the protective sheet 6 is uniformly heated while applying pressure to the protective sheet 6 in a uniform manner. Therefore, it is possible to prevent the protective sheet 6 from being broken when the protective sheet 6 is peeled off. Therefore, the protective sheet 106 can be surely peeled off from the functional film 2. Further, the functional device 1 is not limited to the above-described infrared array sensor. The functional device i 0 can also be, for example, an acceleration sensor (one-axis to three-axis acceleration sensor) or a gyro sensor, a pressure sensor, a microactuator, a microphone, and an ultrasonic sensor. (Second Embodiment) Fig. 6 is a view showing a semiconductor device 10 manufactured by the method of manufacturing a semiconductor device of the present embodiment. The semiconductor device 1 〇 0 includes a functional device 10 and a signal processing device 33 formed of an I C chip. Further, the semiconductor device 1 is provided with a package 40 that houses the functional device 1 and the signal processing device 33 as shown in Fig. 5(c). The signal processing device 3 3 is constructed in cooperation with the infrared sensor-function device 10. The signal processing device 3 3 has a plurality of (four in the illustrated example) input pads 3 1 ( 3 1 1 28 201017744 to 3 1 4), and a pad 3 2 . Each of the input pads 3 1 1 to 3 1 4 is electrically connected to a plurality of (four in the example) output pads 2 4 i to 2 4 4 of the functional device 1 through the wiring 35. The pad 3 2 is used to apply a reference voltage to the reference bias pad 26 of the functional device 2 。. The pad 3 2 is electrically connected to the reference bias pad via the wiring 35; The wiring 3 5 is, for example, a bonding wire using gold or aluminum (b 0 ndingw . re ). Further, the signal processing device 33 includes an amplifying circuit 42 for amplifying the output voltage of the input port 31; and a plurality of The output voltage of the input pad 3 1 is alternatively input to the multiplexer 4 1 of the amplifying circuit 4.2. As far as the processing device 3 3 is concerned, the output voltage of each output pad 24 from the functional device 1 is outputted in sequence. If the = number processing device 33 is used, the infrared ray image processing device 3 3 system and the Wei device can be obtained! Q is divided into two, but it can also be formed by using the substrate 1 which can be mounted one turn. That is, the signal processing device 33 can also be integrally provided to the functional device i. The 唬 package 4 〇 ' is composed of a metal substrate 36 made of a functional packaging device 3 3 and a "bend enclosing function device 10 and a signal processing body 36. The substrate 36 is formed on one side (" The rectangular shape of 39 is formed on the inner bottom surface of the base member 36 and the signal processing device 33. ^ ^ 1 mesh 盍 3 9 is formed into a rectangular plate shape of the size of the opening of the base member 36. The functional device 10 is a case of an infrared sensor, and the material of the cap 39 is made of an infrared permeable material (for example, 矽). Further, in the case where the functional device 1 is a visible light sensor, the cap 3 The material of 9 is made of a material that is transparent to visible light (for example, glass). In the case where the functional device 1 is an acceleration sensor, the material of the cap 39 can be made of a metal material. Thus, the cap Cover 3 g

的材料只要是不妨礙功能裝置i 〇的特性之材料即 可0 在驅動半導體裝置1 0 0之情況,例如,經由 信號處理裝置3 3的墊3 2而對功能裝置i 〇的基 準偏壓用墊2 6賦與基準電壓(例如i · 6 5 v )。 如此來,從各輸出用墊2 4輸出功能性元件3 〇The material may be a material that does not interfere with the characteristics of the functional device i. 0. When the semiconductor device 100 is driven, for example, the reference bias of the functional device i is via the pad 3 2 of the signal processing device 33. Pad 2 6 is assigned a reference voltage (e.g., i · 6 5 v ). In this way, the functional element 3 is output from each of the output pads 24

之輸出電壓(1 · 6 5 V +感測元件2 〇的輸出, 壓)。來自各輸出用墊2 4的輸出電壓被輸入信號屬 理裝置3 3之對應的輸人用墊3 1。信號處理裝f 3 3之多工器4 1係將複數個輸入用墊3 i之輸出 電壓擇一地輸入放大電路4 2。依此,可獲得屬攻 能裝置1 〇之輸出的紅外線畫像。 其次參考第五圖就本實施形態之半導體裝置的 製造方法作說明。 、 半導體裝置的製造方法具有:晶圓處理步驟、貼 附步驟 '切割步驟、剥離步驟、除去步驟、分離步 驟、構裴步驟、洗淨步驟、密封步驟。 30 201017744 本實施形態之半導體裝置的製造方法中,首先 =晶圓處理步驟。有關此晶圓處理步驟,在第— 實施形態已做過說明,故說明省略。 在晶圓處理步驟之後,與第一實施形態同樣 地’進行貼附步驟、切割步驟、剝離步驟、除去步 驟以及分離步驟。接著,在分離步驟之後進行構 裝步驟。此外,有關貼附步驟、切割步驟、剝離步 驟、除去步驟、分離步驟已在第—實施形態做過說 明’故省略說明。 在構裝步驟中,使用第—接著劑將功能裝置工 〇構裝於基體36。具體而言,利用第—接著劑將 功能裝置1 ◦之基板1的厚度方向之另-面(第五 圖(a)中的下面)接合於基體36的内底面。又, 在構裝步驟中,使用第—接著劑將信號處理褒置3 3構裝於基體3 6。具體而言,利用第 信號處理裝置33的背面(第五圖…中的者下:) 接合於基體36的内底面。依此,如第五圖( 《置10及信號處理裝置33各自透過 由弟一接者劑所成之第一接合層(安裴 7而被構裝於基體3 6 〇 又者層)3 了二::::=等一::劑可使用除 外’第-接著劑亦可使用環氧樹脂等之料此 然而,若考慮脱氣,則第—接著劑宜為無機材料 201017744 在將功能裝置1 〇及信號處理裝置3 3構裝於 基體3 6之後,利用配線3 5將功能裝置1 〇的各 輸出用墊2 4 1〜2 44連接於信號處理裝置3 3 之對應的輸入用墊3 1 1〜3 1 4。又,利用配線 3 5將功能裝置1 〇的基準偏壓用墊2 6連接於信 號處理裝置33的墊32。 ° 此外’半導體裝置i 〇 〇中,功能裝置工〇之 基板1的外周形狀是矩形狀。在基板i外周的第一 邊側之端部,用以取出從功能性元件3 〇所輸出的馨 輸出#號之全部的輸出用墊2 4 1〜2 4 4及基準 偏壓用墊2 6 ’係沿著基板工之上述第一邊而併 列。又’信號處理裝置3 3的外周形狀是矩形狀。 在信號處理裝置3 3外周的第二邊側之端部,全部 的輸入用墊3 1 1〜3 1 4及墊3 2,係沿著信號 處理裝置3 3的上述第二邊而併列。功能裝置1 〇 係以基板1的上述第一邊與信號處理裝置3 3的上 述第一邊之距離成為比與信號處理裝置3 3之其 任一邊的距離還近的方式搭載於封裝體4〇。'因 此,能縮短連接功能裝置1 0的輪出用墊2 4與信 姚處理裝置3 3的輸人用墊3 1用的配線3 5。 又’能縮短連接功能裝置1 〇的基準偏壓用12 6 與信號處理裝置3 3的墊3 2之配線3 5。依此, 能減低外來雜音的影響,提升耐雜音性。 在此,宜在密封步驟之前,從基體3 6及帽蓋 32 201017744 3 9除去有機污染物。於是’在構裝步驟之後,於 密封步驟之前要進行洗淨步驟。 洗淨步驟中,從基體3 6及帽蓋3 9除去無用 的有機物。在洗淨步驟中進行灰化處理。灰化處理 係考慮配置於基體3 6内的功能裝置1 〇、信號處 理裝置3 3的大小、功能裝置1 〇、信號處理襞置 3 3的數量、功能裝置i 〇、使用於信號處理裴置 3 3的材料而被適宜地進行。在灰化處理方面,例 如可採用使用了臭氧灰化裝置、電漿灰化裝置的光 激發灰化處理。此外,洗淨步驟亦可在構装步驟之 前進行。 又,構裝步驟亦可在除去步驟之前進行。在此 情況下,在除去步驟中,除去附著於基體3 Θ上的 有機物。具體而言,於晶圓處理步驟之後,進行貼 附=驟和切割步驟及剝離步驟後再進行分離步驟i 接著,在分離步驟之後進行構裝步驟,其後再進行 除去步驟。如此透過變更步驟的順序,可自功能裝 置1 〇及構裝基體3 6雙方同時地除去無用的有"機 物。在此情況下’亦可作成於除去步财,自帽蓋 3 9除去無用的有機物。又,在除去步财 基體3 6及帽蓋39至少一方除去無用的有機物。 此外,宜亦從信號處理裝置3 機物。在從信號處理裝置3 3|m…、用的有 除去無用的有機物之 處理上,亦可與在上述的除去 ㈣物之 于責步驟、洗淨步驟中自 33 201017744 ::裴f1 〇、基體3 6或帽蓋3 9除去有機物的 爽理一起推;^ + 亦可分別進行。但有必要在密封步 λ :就進行從信號處理裝置3 3除去有機物。 姑田哲密封步驟中,於除去步驟及構裝步驟之後, ,二接著劑將帽蓋3 9接合於基體3 6並在封 ::4〇將功能敦置]〇氣密密封。具體而言,係 體3 6之上述一面的開口緣上塗布第二接著 劑。其後,將帽蓋3 9載置於基體3 6的上述一面, 俾覆蓋基體3 6之上述—面的開口。依此,如第五® :C )所不,帽蓋3 9利用由第二接著劑所成的 一接合層(密封接著層)3 8而被接合於基體3 6 〇 、第二接著劑例如是玻璃。第二接著劑除了玻璃 以外還可使用銲料或人u — s i等之無機材料。此 外’第二接著劑亦可使用m氧樹脂等之有機材料。 然而,右考慮脱氣,則第二接著劑宜使用無機材料。⑩ 此外’在密封步驟令,將帽蓋3 9接合於基體 3 6俾使封裝體4 Q内成為真空。例如,藉由在除 去步驟、洗淨步驟之灰化處理後,以停止真空處理 裝置内進行灰化時所流通的氧俾使封裝體4 〇内不 被污¥的方式將封裝體4 〇真空密封。 抑或作成,在密封步驟中,將帽蓋3 9接合於 基體3 6俾使封裝體4 〇内成為正壓者亦可。例 如,取代在除去步驟、洗淨步驟之灰化處理時所流 34 201017744 通之氧’改成將即使曝露於各功能裝置1〇等亦實 質不影響的氣體(例如,A r氣等之惰性氣體或氮 氣(N 2 ))以加壓狀態封入封裝體4 〇内。依此, 將封裝體4 0内設成正壓。 如以上所述,本實施形態之半導體裝置的製造 方法係具備晶圓處理步驟、貼附步驟、切割步驟、 剝離步驟、除去步驟、分離步驟、構裝步驟、洗淨 步驟、及密封步驟。在晶圓處理步驟中,於基板工 的基礎-晶圓3的一表面3 a上形成功能性薄膜 2。在貼附步驟中,於晶圓處理步驟之後,將用有 $著劑的黏著片-保護片6直接地貼附於晶圓3的 表面3 a ’同時將切割片7貼附於晶圓3的另一 表面3 b。在切割步驟中,於貼附步驟之後,在未 切斷切割月7之下將保護片6和晶圓3切斷並將晶 圓3分割成複數個功能Q。在剝離步驟中, 於切割步驟之後,從各功能# 分力月b羞置1 〇剝離保護片 b。在除去步驟中’於剝離牛跡 j離步驟之後,除去附著於 各功能裝置1 〇之含有保護片 古她仏> \ a 更乃b的黏者劑之無用的 有機物。在分離步驟中,從 置10。在槿奘半挪i ’刀離各功月b裝 ◦在構裝步驟中’於切割步 -接者劑將功能裝置i〇構 :第 步驟中,於密封步驟之前,、先^體36。在洗淨 9並除去無用的有機污_==36及帽蓋3 丰牛β战壯止 在畨封步驟中,於降 去步驟及構裝步驟之後,係 Τ %除 用第二接著劑將帽蓋3 35 201017744 9接合於基體3 6並在封裝體4〇將功 氣密密封。 依據此種實施形態之半導體裝置的製造方法, 可自封㈣4 0内除去有機污染物、也就是附著於 功能裝置1 〇之無用的有機物(保護片6的黏著 劑)、附著於基體36及帽蓋39之有機物、附著於 信號處理裝置33的有機物。因而,可防止因無用 的有機物之附著而造成功能裝置i Q的性能降低, 例如’在功能裝置1()是紅外線感測器的情況,由 於來自於有機物等之脱氣而造成紅外線穿透特性亞 化。因此’可防止半導體裝置1〇〇的性能降低。 又’在密封步驟巾,將帽蓋39接合於基體3 下俾使封裝體4 0内成為真空或正壓。在此情況 從功i裝置1 〇除去無用的有機物,沒有因 :機物之脱氣而變化封裝體40内的壓力之情形:、 :防止半導體裝置1〇〇的性能降 :之=裝體4〇内真空,則能消除封裝體 可提高半導體裝置1〇心 讀封㈣4Q内設成正壓,則大 乳等之封裝冑4 0外的氣體不會流 内。因此,可提高半導體裝置1〇〇的可靠性。 又,因為第一接著劑與第二 由無機材料所成,故即使是在封裝: = 方式 況,亦能消除因來自於繁 0軋抢的情 來自於第一接著劑、第二接著劑之 36 201017744 脱氣而使内部壓力變化的情形。 除去附著於基體3 ,故可防止半導體 又,因為在密封步驟之前, 6與帽蓋3 9至少 —方的有機物 裝置1 〇 〇的性能降低。 驟,牛驟宜/除去步驟之前就進行構裝步 物。如此:來厂在二去附著於基體3 6上之有機 在功此裝置1 〇構裝於基體3 6 $The output voltage (1 · 6 5 V + the output of the sensing element 2 ,, voltage). The output voltage from each of the output pads 24 is input to the corresponding input pad 31 of the signal processing device 3 3 . The multiplexer 4 1 of the signal processing device f 3 3 selectively inputs the output voltages of the plurality of input pads 3 i to the amplifying circuit 42. According to this, an infrared image which is an output of the attack device 1 can be obtained. Next, a method of manufacturing the semiconductor device of the present embodiment will be described with reference to the fifth embodiment. The method of manufacturing a semiconductor device includes a wafer processing step, a attaching step 'cutting step, stripping step, removing step, separating step, constitution step, washing step, and sealing step. 30 201017744 In the method of manufacturing a semiconductor device of the present embodiment, first, the wafer processing step. This wafer processing step has been described in the first embodiment, and therefore the description is omitted. After the wafer processing step, the attaching step, the dicing step, the stripping step, the removing step, and the separating step are carried out in the same manner as in the first embodiment. Next, the construction step is carried out after the separation step. Further, the attaching step, the cutting step, the peeling step, the removing step, and the separating step have been described in the first embodiment, and thus the description thereof will be omitted. In the structuring step, the functional device is mounted to the substrate 36 using a first adhesive. Specifically, the other surface (the lower surface in the fifth diagram (a)) of the thickness direction of the substrate 1 of the functional device 1 is bonded to the inner bottom surface of the substrate 36 by a first adhesive. Further, in the structuring step, the signal processing device 3 3 is attached to the substrate 36 using a first adhesive. Specifically, the back surface (the lower one in the fifth diagram) of the first signal processing device 33 is joined to the inner bottom surface of the base 36. Accordingly, as shown in FIG. 5 (the first 10 and the signal processing device 33 are respectively configured by the first bonding layer formed by the sitter (the ampule 7 is mounted on the substrate 3 〇 〇 layer) 3 2::::= etc. One:: The agent can be used except for the 'first-adhesive agent, which can also use epoxy resin. However, if degassing is considered, the first adhesive should be inorganic material 201017744. 1A and the signal processing device 3 3 are mounted on the base 36, and the output pads 2 4 1 to 2 44 of the functional device 1 are connected to the corresponding input pads 3 of the signal processing device 3 3 by the wiring 35. 1 1 to 3 1 4. Further, the reference bias pad 26 of the functional device 1 连接 is connected to the pad 32 of the signal processing device 33 by the wiring 35. Further, in the 'semiconductor device i ,, the functional device process The outer peripheral shape of the substrate 1 is a rectangular shape. At the end portion on the first side of the outer periphery of the substrate i, the output pads 2 4 1 to 2 for taking out all of the sleek output # of the functional element 3 〇 are taken out. 4 4 and the reference bias pad 2 6 'is juxtaposed along the first side of the substrate work. Further 'signal processing device 3 3 The outer peripheral shape is a rectangular shape. At the end portion on the second side of the outer circumference of the signal processing device 3 3, all of the input pads 3 1 1 to 3 1 4 and the pad 3 2 are along the above-described first portion of the signal processing device 3 3 . The functional device 1 is mounted such that the distance between the first side of the substrate 1 and the first side of the signal processing device 33 is closer than the distance from either side of the signal processing device 3 3 . In the case of the package 4', it is possible to shorten the wiring 35 for the input pad 2 4 of the connection function device 10 and the input pad 31 for the letter processing device 3 3 . The reference bias voltage of 1 〇 is 12 6 and the wiring 3 5 of the pad 3 2 of the signal processing device 33. Accordingly, the influence of the external noise can be reduced, and the noise resistance can be improved. Here, it is preferable to remove the noise from the substrate before the sealing step. 3 6 and cap 32 201017744 3 9 Remove organic contaminants. Then 'after the sealing step, the cleaning step is carried out before the sealing step. In the cleaning step, the useless organic matter is removed from the substrate 36 and the cap 39. Ashing treatment is carried out in the washing step. The ashing treatment is considered The functional device 1 置于 placed in the base 36, the size of the signal processing device 33, the functional device 1 〇, the number of signal processing devices 3 3, the functional device i 〇, and the material used in the signal processing device 3 3 In the ashing treatment, for example, a photoexcitation ashing treatment using an ozone ashing apparatus or a plasma ashing apparatus may be employed. Further, the washing step may be performed before the structuring step. The loading step can also be carried out before the removing step. In this case, in the removing step, the organic matter attached to the substrate 3 is removed. Specifically, after the wafer processing step, the attaching step and the dicing step and the stripping step are performed after the separating step i. Next, the structuring step is performed after the separating step, and then the removing step is performed. By the order of the changing steps, the useless "machines can be simultaneously removed from both the functional device 1 and the structural substrate 36. In this case, it is also possible to remove the waste, and remove the useless organic matter from the cap 39. Further, at least one of the stepped material base 36 and the cap 39 is removed to remove unnecessary organic matter. In addition, it is also desirable to use the signal processing device 3 from the machine. In the process of removing the useless organic matter from the signal processing device 3 3|m..., it is also possible to use the substrate in the above-mentioned step (4) for removing the (4), from the step of washing, from 33 201017744 ::裴f1 〇, the substrate 3 6 or the cap 3 9 removes the organic matter and pushes it together; ^ + can also be carried out separately. However, it is necessary to remove the organic matter from the signal processing device 33 in the sealing step λ: In the Gutianzhe sealing step, after the removal step and the construction step, the two adhesives bond the caps 39 to the substrate 36 and hermetically seal the function at the seal. Specifically, a second adhesive is applied to the opening edge of the one side of the body 36. Thereafter, the cap 39 is placed on the one side of the base 36, and the opening of the above-mentioned surface of the base 36 is covered. Accordingly, as for the fifth ® :C), the cap 39 is joined to the base 3 6 利用 by a bonding layer (sealing adhesive layer) 38 formed of a second adhesive, for example, a second adhesive such as It is glass. The second adhesive may use, in addition to glass, an inorganic material such as solder or human u-s i. Further, as the second adhesive, an organic material such as an m-oxygen resin can also be used. However, considering degassing right, the second adhesive is preferably an inorganic material. Further, in the sealing step, the cap 39 is joined to the base 36 to make the inside of the package 4Q a vacuum. For example, after the ashing treatment in the removing step and the washing step, the package 4 is vacuumed in such a manner that the oxygen enthalpy flowing during the ashing in the vacuum processing apparatus is stopped so that the inside of the package 4 is not contaminated. seal. Alternatively, in the sealing step, the cap 39 may be joined to the base member 36 to make the inside of the package 4 into a positive pressure. For example, instead of the ashing treatment in the removal step and the cleaning step, the flow of the gas is changed to a gas that does not substantially affect even if it is exposed to each functional device (for example, inert gas such as Ar gas). The gas or nitrogen (N 2 )) is sealed in the package 4 in a pressurized state. Accordingly, the inside of the package 40 is set to a positive pressure. As described above, the manufacturing method of the semiconductor device of the present embodiment includes a wafer processing step, a attaching step, a dicing step, a peeling step, a removing step, a separating step, a structuring step, a washing step, and a sealing step. In the wafer processing step, a functional film 2 is formed on a surface 3a of the substrate-wafer 3 of the substrate. In the attaching step, after the wafer processing step, the adhesive sheet-protecting sheet 6 with the dose is directly attached to the surface 3a' of the wafer 3 while the dicing sheet 7 is attached to the wafer 3. The other surface 3 b. In the cutting step, after the attaching step, the protective sheet 6 and the wafer 3 are cut off and the wafer 3 is divided into a plurality of functions Q under the uncut cutting month 7. In the stripping step, after the cutting step, the protective sheet b is peeled off from each function #分力月b. In the removing step, after the step of peeling off the traces, the useless organic substances adhering to the respective functional devices 1 containing the protective sheet of the adhesive sheet, the adhesive agent, and the adhesive agent are removed. In the separation step, set to 10. In the 槿奘 槿奘 i i i 各 各 各 各 各 各 各 各 各 各 各 各 各 各 各 各 各 各 各 各 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于 于After washing 9 and removing useless organic stains _==36 and cap 3 Fengniu β battle in the sealing step, after the descending step and the construction step, the system Τ% will be replaced by a second adhesive The cap 3 35 201017744 9 is joined to the base 36 and hermetic seal is sealed in the package 4 . According to the method of manufacturing a semiconductor device of the embodiment, it is possible to remove organic contaminants, that is, useless organic substances (adhesives for the protective sheet 6) attached to the functional device 1 from the sealing (4) 40, and to adhere to the substrate 36 and the cap. Organic matter of 39, organic matter attached to the signal processing device 33. Therefore, it is possible to prevent the performance of the functional device iQ from being lowered due to the adhesion of unnecessary organic substances, for example, in the case where the functional device 1 () is an infrared sensor, the infrared penetrating property is caused by degassing from an organic substance or the like. Asianization. Therefore, the performance of the semiconductor device 1 can be prevented from being lowered. Further, in the sealing step, the cap 39 is joined to the base 3 to make the inside of the package 40 into a vacuum or a positive pressure. In this case, the useless organic matter is removed from the device i, and there is no change in the pressure in the package 40 due to the degassing of the device: : preventing the performance degradation of the semiconductor device 1 : In the vacuum inside the crucible, the package can be removed, and the semiconductor device 1 can be improved. (4) The positive pressure is set in 4Q, and the gas outside the package 胄40 such as large milk does not flow. Therefore, the reliability of the semiconductor device 1 can be improved. Moreover, since the first adhesive and the second inorganic material are formed, even in the case of encapsulation: = mode, it can be eliminated from the first adhesive and the second adhesive due to the situation from the rolling. 36 201017744 Degassing and changing internal pressure. Since the adhesion to the substrate 3 is removed, the semiconductor can be prevented because the performance of the organic device 1 at least 6 with the cap 39 is lowered before the sealing step. The steps are carried out before the removal of the bovine/pre-step. So: the organic plant attached to the base 3 6 in the factory is in the device 1 〇 is mounted on the base 3 6 $

後,可同時除去功能裝置1〇之血用的右:f6之 體3 6之…、用的有機物和基 in… 因此,可防止半導體裝置 1 〇 〇的性能降低,且能提升良率。 【圖式簡單說明】 第一圖係本發明的一 造方法步驟圖。 實施形態之功能裳置 的製Thereafter, the right side of the blood of the functional device can be removed at the same time: the body of the f6, the organic substance and the base in..., thereby preventing the performance of the semiconductor device 1 from being lowered and improving the yield. BRIEF DESCRIPTION OF THE DRAWINGS The first figure is a process diagram of a method of the present invention. The function of the implementation

第二圖係顯示同上的功能裝置,(a)係概略 圖,(b )係等效電路圖。 第三圖係顯示同上的功能裝置,(a )係放大 圖’(b )係同圖(a )之a _ a線剖面圖。 第四圖係同上的功能裝置的製造方法之說 圖。 第五圖係本發明的一實施形態之半導體装置的 製造方法之步驟圖。 第六圖係具備同上的功能裝置之半導體裝置之 概略平面圖。 37 201017744 第七圖係同上的半導體裝置之說明圖。 【主要元件符號說明】 33 a 3 b 45678910 2 基板 功能性薄膜 晶圓 表面 表面 細縫 孔洞 保護片 切割片 溝 剝離用構件 功能裝置 氧化矽膜 氮化矽膜The second figure shows the functional devices as above, (a) is a schematic diagram, and (b) is an equivalent circuit diagram. The third figure shows the functional device of the same, and (a) is an enlarged view of the figure (b) in the same line as the a-a line of the figure (a). The fourth figure is a diagram of the manufacturing method of the functional device of the above. Fig. 5 is a process chart showing a method of manufacturing a semiconductor device according to an embodiment of the present invention. The sixth drawing is a schematic plan view of a semiconductor device having the same functional device. 37 201017744 The seventh diagram is an explanatory diagram of the same semiconductor device. [Main component symbol description] 33 a 3 b 45678910 2 Substrate Functional film Wafer Surface Surface Slit hole Hole Protective sheet Cutting sheet Groove Peeling member Functional device Cerium oxide film Tantalum nitride film

13 η型複晶矽層 14 η型補償複晶矽層 15 ρ型複晶石夕層 16 ρ型補償複晶矽層 17 層間絶緣膜 18 配線 19 鈍化膜 38 201017744 〇 ❹ 2 0 2 1 2 2 2 3 2 4 2 4 1 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 11 3 2 3 7 3 8 3 9 4 0 4 1 4 2 感測元件 紅外線吸收體 紅外線吸收膜 連接層 輸出用塾 2 4 4 輸出用墊 接觸孔 基準偏壓用墊 垂直讀出線 基準偏壓線 共通基準偏壓線 功能性元件 輸入用墊 314 輸入用墊 墊 信號處理裝置 配線 基體 第一接合層 第二接合層 帽蓋 封裝體 多工器 放大電路 39 201017744 10 0 半導體裝置 2 0 0 熱電偶13 η-type polysilicon layer 14 η-type compensation complex 矽 layer 15 ρ-type compoundite layer 16 ρ-type compensation complex layer 17 layer 17 interlayer insulating film 18 wiring 19 passivation film 38 201017744 〇❹ 2 0 2 1 2 2 2 3 2 4 2 4 1 2 5 2 6 2 7 2 8 2 9 3 0 3 1 3 11 3 2 3 7 3 8 3 9 4 0 4 1 4 2 Sensing element Infrared absorber infrared absorbing film connection layer output塾2 4 4 Output pad contact hole reference bias pad vertical readout line reference bias line common reference bias line functional element input pad 314 input pad signal processing device wiring substrate first bonding layer second bonding Layer cap package multiplexer amplifying circuit 39 201017744 10 0 Semiconductor device 2 0 0 Thermocouple

Claims (1)

201017744 七、申請專利範圍: 1 種功能裝置的製造方法,該功能裝置包 含: 一基板;及 一功能性薄膜,形成在上述基板上且具既定功 能,且 在上述基板上形成有一孔洞,用以將上述基板 和上述功能性薄膜作空間上分離, ❿言亥功能裝置的製造方法之特徵包含: 一晶圓處理步驟,在以上述基板為基底的晶圓 之一表面上形成上述功能性薄膜; 一貼附步驟,於上述晶圓處理步驟之後,將用 有黏著劑的保護片直接地貼附於上述晶圓的一表 面,同時將切割片貼附於上述晶圓的另一表面; 一切割步驟,於上述貼附步驟之後,在未切斷 ® 上述切割片之下將上述保護片和上述晶圓並將上述 晶圓分割成複數個上述功能裝置; 一剝離步驟,於上述切割步驟之後,從各上述 功能襞置剝離上述保護片;及 一除去步驟,於上述剝離步驟之後,除去附著 於各上述功能裝置之含有上述保護片的上述黏著劑 之無用的有機物。 2、如申請專利範圍第1項所述之功能裝置的 製造方法,其中 201017744 上述功能裝置係具有一細縫,其貫通上述功能 性薄膜的厚度方向並與上述孔洞連通, 在上述除去步驟中’除去附著於上述細縫的内 面與上述孔洞的内面至少一方之無用的有機物。 3、 如申請專利範圍第1項所述之功能裝置的 製造方法,其中 上述剝離步驟中,於上述保護片中之與上述晶 圓相反側的面上安裝剝離用構件之後,將保護片和 上述剝離用構件一起自上述功能裝置剝離。 ❿ 4、 如申請專利範圍第1項所述之功能裝置的 製造方法,其中 上述保護片,係一利用加熱就會降低黏著力的 黏著劑之加熱剝離型黏著片。 5、 如申請專利範圍第4項所述之功能裝置的 製造方法,其中 上述剝離步驟中,在將上述保護片從上述功能 裝置剝離之前,對上述保護片全面均一地一邊施加© 壓力一邊將上述保護片均一地加熱。 6 種半導體裝置的製造方法,該半導體裝 置包含· 一功能裝置;及 封裝體,收容上述功能裝置,其中 上述功能裝置具備基板、及形成在上述基板上 具既定功能的功能性薄膜,在上述基板形成有孔 42 201017744 /同,用以使上述基板和上述功能性薄膜呈空間上 離, 上述封裝體是以安裝有上述功能裝置的基體、 及上述基體包圍上述功能裝置的帽蓋所構成, »玄半導體裝置的製造方法之特徵為具備: 一晶圓處理步驟,在以上述基板為基底的晶圓 之一表面上形成上述功能性薄膜; 一貼附步驟,於上述晶圓處理步驟之後,將用 °有黏著劑的保護片直接地貼附於上述晶圓的一表 面,同時將切割片貼附於上述晶圓的另一表面; 一切割步驟,於上述貼附步驟之後,在未切斷 上述切割片之下將上述保護片和上述晶圓並將上述 日日圓分割成複數個上述功能裝置; 一剝離步驟,於上述切割步驟之後,從各上述 功能裝置剝離上述保護片; _ 除去步驟,於上述剝離步驟之後,除去附著 於各上述功能襞置之含有上述保護片的上述黏著劑 之無用的有機物; 構裝步驟,於上述切割步驟之後,使用第一 接著劑將上述功能裝置構褒於上述基體;及 /一密封步驟,於上述除去步驟及上述構裝步驟 之後使用第二接著劑將上述帽蓋接合於上述基體 亚在上述封裝體將上述功能裝置氣密密封。 7如申請專利範圍第6項所述之半導體裝置 43 201017744 的製造方法,其中 在上述密封步驟中,將上述帽蓋接合於上述基 體使上述封裝體内成為真空或正壓。 8 '如申請專利範圍第7項所述之半導體裝置 的製造方法,其中 上述第一接著劑與上述第二接著劑至少一方係 由無機材料所構成。 參 9、如巾請專㈣圍第6項所述之半導體裝置 的製造方法,其中 在上述密封步驟之前,除去附著於上述基體斑 上述帽蓋至少一方上的有機物。 置:方ΠΓ範圍第6項所述之半導體裝 2==:;前進行上_步驟, 機物。 除去附者於上述基體的有 ❿ 44201017744 VII. Patent application scope: A manufacturing method of a functional device, comprising: a substrate; and a functional film formed on the substrate and having a predetermined function, and a hole is formed in the substrate for The method for manufacturing the above-mentioned substrate and the functional film is characterized in that: a wafer processing step comprises: forming a functional film on a surface of one of the substrates based on the substrate; a attaching step of directly attaching a protective sheet with an adhesive to a surface of the wafer after the wafer processing step, and attaching the dicing sheet to the other surface of the wafer; After the attaching step, the protective sheet and the wafer are divided into a plurality of functional devices under the uncut® dicing sheet; a stripping step, after the cutting step, Removing the protective sheet from each of the functional devices; and removing the step, after the stripping step, removing the adhesion Useless means of the functional organic material comprising the protective sheet of the adhesive. 2. The method of manufacturing a functional device according to claim 1, wherein the functional device has a slit that penetrates the thickness direction of the functional film and communicates with the hole, in the removing step. Unwanted organic matter adhering to at least one of the inner surface of the slit and the inner surface of the hole is removed. 3. The method of manufacturing a functional device according to claim 1, wherein in the peeling step, after the peeling member is attached to a surface of the protective sheet opposite to the wafer, the protective sheet and the protective sheet are The peeling members are peeled off together from the above functional device. The method of manufacturing the functional device according to the first aspect of the invention, wherein the protective sheet is a heat-peelable adhesive sheet of an adhesive which reduces adhesion by heating. 5. The method of manufacturing a functional device according to claim 4, wherein in the peeling step, before the protective sheet is peeled off from the functional device, the protective sheet is uniformly and uniformly applied with a pressure of The protective sheet is uniformly heated. A method of manufacturing a semiconductor device comprising: a functional device; and a package accommodating the functional device, wherein the functional device includes a substrate and a functional thin film having a predetermined function formed on the substrate, and the substrate Forming a hole 42 201017744 / the same for spatially separating the substrate and the functional film, the package is composed of a base body on which the functional device is mounted, and a cap that surrounds the functional device with the base body, » The method for manufacturing a semiconductor device includes: a wafer processing step of forming the functional film on a surface of one of the substrates on which the substrate is based; and an attaching step after the wafer processing step Applying a protective sheet having an adhesive directly to a surface of the wafer while attaching the dicing sheet to the other surface of the wafer; a cutting step, after the attaching step, is not cut The protective sheet and the wafer are divided into the plurality of functions described above under the dicing sheet a peeling step of peeling off the protective sheet from each of the functional devices after the cutting step; _ removing step, after the peeling step, removing the adhesive containing the protective sheet attached to each of the functional devices a useless organic substance; a step of structuring, after the dicing step, constructing the functional device on the substrate using a first adhesive; and/or a sealing step, using a second adhesive after the removing step and the structuring step Bonding the cap to the base body hermetically seals the functional device in the package. The method of manufacturing a semiconductor device according to claim 6, wherein in the sealing step, the cap is joined to the substrate to cause a vacuum or a positive pressure in the package. The method of manufacturing a semiconductor device according to claim 7, wherein at least one of the first adhesive and the second adhesive is made of an inorganic material. The method for manufacturing a semiconductor device according to Item 6, wherein the organic substance adhering to at least one of the caps of the base spot is removed before the sealing step. Set: The semiconductor package described in item 6 of the scope is 2==:; before proceeding to the step _, the machine. Remove the attached body from the above substrate.
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