201002357 六、發明說明： 【發明所屬之技術領域】 本發明係關於含有磷脂質組成係25 、25〜42%之磷脂乙醇胺（成份（a )) 1〜100mm2/s之動黏度之矽油（成份（b) 狀之酯油（成份（C ))，成份（b )及反 質量比（b ) / ( c )爲0 · 0 0 6〜0 · 4之油性固 更詳細地係關於手指拿取及使用時之塗抹 之黏腻感少，保存安定性優異並且保濕效 狀之化妝料者。 【先前技術】 憐脂質係一般作爲生態相關成份，肌 ’廣泛地被使用於化妝品領域，尤其作爲 、保濕劑、抗氧化劑使用（例如參考非專 外，矽油，尤其低黏度矽油係因該優異的 、清爽感、潤滑性、撥水性、安全性等， 途，亦被多數使用於化妝料（例如參考非 一般油性固體狀之化妝料係配合可可 脂類、巴西棕櫚蠟、鯨蠟等之蠟類、石蠟 蠟成份，使油性成份固體化者。另外，已 不同，使用糊精脂肪酸脂作爲油膠化劑之 於組合糊精脂肪酸脂及石蠟等之固體狀油 油之油性固體狀之化妝料（例如參考專利 -42 %之磷脂膽鹼 、於2 5 °C具有 )、於25t：爲液 Η分（c )之含有 體狀之化妝料， 性優異，塗佈後 果高之油性固體 膚適用感優異者 分散劑或乳化劑 利文獻1 )。另 光澤感、進展性 被使用於各種用 專利文獻2 )。 脂、木蠟等之油 、微晶紫蠟等之 知與此等蠟成份 技術等。例如關 性成份、及液狀 文獻 1 )、組合 201002357 糊精脂肪酸脂及重質流動異鏈院烴及液狀油性成 (例如參考專利文獻2 )。 然而，專利文獻1之技術中，藉由配合固體 於使用性上並不適宜。另外，專利文獻2之技術 用性或保存安定性上的問題，塗佈後感到黏腻。 此等技術，手指不易拿取化妝料，於肌膚上塗抹 不易抹開或黏腻感。 對此，如上所述，因矽油具有各種優異的特 檢討使油性固體狀之化妝料中含有矽油之技術。 關於組合糊精脂肪酸脂及平均碳數爲40〜200之 烴、固醇衍生物、及甲基苯基聚矽氧烷之固體狀 技術（例如參考專利文獻3 )、使用具有三次元 之有機聚矽氧烷聚合物、或丙烯基.聚矽氧烷系 物之技術（例如參考專利文獻4、5 )、關於組 醯胺化合物及烴油、矽油之凝膠狀化妝料之技術 考專利文獻6 )。另外，上述磷脂質中，使用氫 作爲油膠化劑之技術（例如參考專利文獻7 )、 糖硬脂酸酯作爲矽油之膠化劑之技術（例如參考 8 ) ° 然而，專利文獻3之技術係與上述專利文獻 地手指拿取或塗抹等之使用性或保存安定性上發 感到塗佈後之黏腻感。專利文獻4〜5之技術中， 與其他油性成份之互溶性差，不能得到充份的增 難以得到安定的凝膠化組成物。另外，專利文獻 份之技術 狀油份， 中，有使 另外，以 時亦發生 性，所以 揭示例如 液體鏈狀 化妝料之 交聯結構 交聯共聚 合含氟酸 (例如參 化磷脂質 或使用菊 專利文獻 1〜2同樣 生問題、 因爲砂油 黏作用， 6之技術 -6- 201002357 雖關於新穎的膠化劑之技術，但對於手指拿取仍不足。另 外，專利文獻7之技術，雖然保濕效果優異，但因大量使 用磷脂質，塗抹性差。另外，實際上磷脂質爲總成份中 4 0 %以下時，用以使油系固化之蠟成份爲必要的，因此以 手指拿取化妝料變得不易，另外，若使含有用以改善黏腻 感之矽油時，保存安定性將變差。另外，專利文獻8之技 術雖係關於將揮發性矽油凝膠化之化妝料者，使用性雖然 優異，但就保濕效果上仍不足。 [先前技術文獻] [非專利文獻] [非專利文獻1 ]「機能性脂質之開發及應用」，CMC 社，1 992年3月2日發行，P292 [非專利文獻2 ]「化妝品手冊」，日光化學股份有限 公司及其他，平成18年10月30日發行，P87 [專利文獻] [專利文獻1]特開2004-51500號公報 [專利文獻2 ]特開平9 - 2 3 5 2 1 0號公報 [專利文獻3 ]特開平1 1 - 2 2 2 4 1 3號公報 [專利文獻4]特開平ϊ_79 1 06號公報 [專利文獻5]特開平2-132141號公報 [專利文獻6]特開2005-68198號公報 [專利文獻7]特開昭60-226804號公報 [專利文獻8]特開2004-300094號公報 201002357 【發明內容】 發明所欲解決之課題 如此地，上述傳統技術 係使用固體狀油份或油膠化 善作爲化妝料之不易手指拿 改善塗抹性而含有矽油時， 差 '或增黏作用或凝膠化能 黏度降低、或發現自凝膠滲 等之有效物少係實情。另外 ，但至今仍未得到使用性或 ，要求開發可得到因矽油之 腻感之良好使用感，同時手 效果亦優異之油性固體狀之 本發明係以開發即使不 安定地配合於油性固體狀之 手指拿取、塗抹性優異，化 安定性、保濕效果優異之油 課題之解決手段 相關實情，本發明者努 組成之磷脂質、於2 5 t具窄 、於25 °C爲液狀之酯油，： 優異，塗抹化妝料後不黏腻 優異之油性固體狀之化妝料 中之油性固體狀之化妝料主要 劑，固化油性成份者，難以改 取、或塗抹性差。尤其，用以 因爲依油性成份種類而互溶性 力不足，而發現經時地製劑的 出油份之稱爲「排液」的現象 ，雖亦對膠化劑進行各種檢討 保存安定性面上充份者。因此 優異塗抹性或不感到塗佈後黏 指易拿取，保存安定性或保濕 化妝料。 使用固體狀之油份等，使矽油 化妝料中之方法，提供藉此而 妝料塗佈後不黏腻，進而保存 性固體狀之化妝料爲課題。 力硏究的結果，藉由組合特定 1〜100mm2/s之動黏度之砂油 發現可得到手指拿取、塗抹性 ’進而保存安定性及保濕效果 ’完成本發明。 ~ 8 - 201002357 亦即，本發明係關於含有下述成份（a )〜（c ): (a) 5〜25質量％之磷脂質，磷脂質組成係25〜42%之 磷脂膽鹼、25~42%之磷脂乙醇胺 (b )於25 °C具有1〜1 〇〇mm2/s之動黏度之矽油 (c)於25°C爲液狀之酯油 ，且成份（b)及成份（c)之含有質量比（b) / (c)爲 0.0 06〜0.4爲特徵之油性固體狀之化妝料。 關於成份（c )係碳數爲6〜3 0之支鏈脂肪酸及甘油之 三酯油爲特徵之油性固體狀之化妝料。 關於成份（c )係2-乙基己酸甘油酯及/或三異硬脂酸 甘油酯爲特徵之油性固體狀之化妝料。 關於更含有5〜20質量％之成份（d ) N-醯基賴胺酸爲 特徵之油性膠狀之化妝料。 關於塡充以7〇〜80°C溶融的成份（a )〜（c )於容器 ，將其冷卻所得者之油性固體狀之化妝料。 發明之功效 本發明之油性固體狀之化妝料係手指拿取或塗抹性優 異’黏腻感少，保存安定性及保濕效果優異者。 用以實施發明之最佳型態 以下係詳細地說明本發明。 本發明之成份（a )之磷脂質係作爲油性固體狀之化 妝料中之油固體化劑所使用者，作爲磷脂質種類，只要係 -9- 201002357 通常化妝料所使用者即可，並無特別限制，例如可使用大 豆來源磷脂質、大豆來源氫化磷脂質、蛋黃來源磷脂質、 蛋黃來源氫化磷脂質等。此等磷脂質一般係磷脂膽鹼（以 下簡稱爲PC )、磷脂乙醇胺（以下簡稱爲PE )、磷脂醯 肌醇（以下簡稱爲PI )等之混合物，該組成係依磷脂質 來源而異，但本發明使用之磷脂質係磷脂質組成爲 25〜42%之PC、25〜42%之PE者。若於此範圍，將成爲保 存安定性優異之油性固體狀之化妝料。磷脂質組成中PC 未達25 %者係與油劑之互溶性差，另外，大於42%者係不 能作爲油膠化劑運作。另外，磷脂質組成中PE未達2 5 % 者將難以作爲油膠化劑運作，若大於42%者係與油劑之互 溶性差。作爲本發明中之成份（a )，可使用一種或二種 以上之磷脂質，使用二種以上時，磷脂質組成之平均於此 範圍即可。作爲如此成份（a )之具體商品，可列舉曰光 化學股份有限公司所提供之Resinol S-10等。 本發明之成份（a)之含量爲5 ~25質量％ (以下簡稱 爲「％」），以8〜2 0 %爲宜。含量未達5 %，難以使油固 體化，保存安定性變差。另外，若超過2 5 %時，塗抹性變 差，另外，磷脂質獨特的氣味變強，不適合作爲化妝料。 若於5〜25 %之範圍時，可得到更不會有黏腻感，手指拿取 、塗抹性優異，肌膚適合性佳，保存安定性優異，且保濕 效果高之油狀固體狀之化妝料。 本發明之成份（b)之於25°C具有1〜l〇〇mm2/s之動 黏度之矽油係化妝料所使用之呈現液體之矽油，環狀、支 -10- 201002357 鏈狀等之分子形狀無特別限定。具體上，可列舉環狀矽油 之八甲基環四矽氧烷、十甲基環五矽氧烷、十二甲基環六 矽氧烷，鏈狀矽油之二甲基聚矽氧烷、甲基苯基聚矽氧烷 等。此於25°C具有l~l〇〇mm2/s之動黏度之矽油係可使用 1種或2種以上，就使用時不黏腻及塗抹性優異之觀點， 以直鏈狀矽油爲宜。另外，在此之動黏度係基於】IS-K-2 2 8 3記載之原油及石油製品-動黏度試驗方法及黏度指數 算出方法而測定者。 本發明之成份（b )係可使用市售品，可舉例如作爲 直鏈狀矽油之 KF96A-6cs、KF96A-100cs、KF56、KF50-l〇〇cs (以上係信越化學工業社製）、SH200C-6cs (以上 係 Toray. Dowcorning社製）、環狀砂油之 SH224、 SH3 44、SH24 5、DC345、DC246 (以上{系 Toray ·201002357 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to an eucalyptus oil (ingredient (containing) having a phospholipid composition of 25, 25 to 42% of phospholipid ethanolamine (ingredient (a)) 1 to 100 mm 2 /s ( b) the ester oil (component (C)), the component (b) and the inverse mass ratio (b) / (c) are 0 · 0 0 6~0 · 4 oily solids in more detail about finger picking and When applied, the stickiness of the smear is small, and the cosmetic which has excellent stability and moisturizing effect is preserved. [Prior Art] The pity lipid system is generally used as an ecologically relevant component, and the muscle is widely used in the field of cosmetics, especially as a moisturizing agent. For the use of agents and antioxidants (for example, refer to non-extraordinary, eucalyptus oils, especially low-viscosity eucalyptus oils due to the excellent, refreshing, lubricity, water repellency, safety, etc., are also mostly used in cosmetics (for example, reference non- A general oily solid cosmetic is formulated with a waxy or paraffin wax component such as cocoa butter, carnauba wax or cetyl wax to solidify the oily component. In addition, a dextrin fatty acid ester is used as an oil gelling agent. An oily solid cosmetic of a solid oily oil such as a dextrin fatty acid ester or a paraffin wax (for example, reference patent - 42% phospholipid, which has a concentration at 25 ° C), at 25t: liquid helium (c In addition, the dispersing agent or the emulsifier which is excellent in the application of the oily solid skin having a high coating effect, and the application of the dispersing agent or the emulsifier is also disclosed in the patent document 2). Oils such as fats, wood waxes, microcrystalline purple waxes, etc., such as wax components, etc., such as related ingredients, and liquid literature 1), combination 201002357 dextrin fatty acid fats and heavy mobile isochain hydrocarbons and Liquid oily (for example, refer to Patent Document 2). However, in the technique of Patent Document 1, it is not preferable to use a solid in terms of usability. Further, in Patent Document 2, the technical properties or the problem of preservation stability are sticky after application. With these techniques, it is not easy for the fingers to take the cosmetic material, and it is not easy to spread or sticky on the skin. On the other hand, as described above, since the eucalyptus oil has various excellent special reviews, the oily solid cosmetic contains eucalyptus oil. A solid-state technique in which a combination of a dextrin fatty acid ester and a hydrocarbon having a carbon number of 40 to 200, a sterol derivative, and a methylphenyl polyoxyalkylene are used (for example, refer to Patent Document 3), and a three-dimensional organic polymerization is used. A technique of a decyl alkane polymer or a propylene-based polyoxane-based compound (for example, refer to Patent Documents 4 and 5), and a technical examination of a group of decylamine compounds, a hydrocarbon-based oil, and a gel-like cosmetic of eucalyptus oil. ). Further, among the above phospholipids, a technique using hydrogen as an oil gelling agent (for example, refer to Patent Document 7) and a sugar stearate as a gelling agent for eucalyptus oil (for example, refer to 8). However, the technique of Patent Document 3 The feeling of stickiness after application is felt by the useability or preservation stability of the fingers taken or smeared by the above-mentioned patent documents. In the techniques of Patent Documents 4 to 5, the miscibility with other oily components is poor, and it is not possible to obtain a sufficient gelation composition which is difficult to obtain stability. In addition, in the technical oil of the patent document, there is another, and sometimes also occurs, so that, for example, a crosslinked structure of a liquid chain cosmetic is disclosed to cross-link a copolymerized fluorine-containing acid (for example, a phospholipid or a use thereof). The patent documents 1 to 2 of the chrysanthemum are also problematic, because of the viscosity of the sand oil, the technique of 6-6-201002357, although the technique of the novel gelling agent is still insufficient for the finger picking. In addition, the technique of the patent document 7 although It has excellent moisturizing effect, but it is poor in spreadability due to the large amount of phospholipids used. In addition, when the phospholipid is actually 40% or less of the total composition, it is necessary to make the oil-cured wax component necessary, so take the cosmetic with your fingers. In addition, when the eucalyptus oil for improving the feeling of stickiness is contained, the storage stability is deteriorated. The technique of Patent Document 8 relates to a cosmetic material which gels volatile eucalyptus oil, and is usable. Although it is excellent, it is still insufficient in moisturizing effect. [Prior Art Literature] [Non-Patent Document] [Non-Patent Document 1] "Development and Application of Functional Lipids", CMC, issued on March 2, 1992 Line, P292 [Non-Patent Document 2] "Cosmetic Handbook", Nikko Chemical Co., Ltd. and others, issued on October 30, 1999, P87 [Patent Document] [Patent Document 1] JP-A-2004-51500 [Patent [Patent Document 3] Japanese Unexamined Patent Publication No. Hei No. Hei No. Hei No. Hei No. 1 - 2 2 2 4 1 3 (Patent Document 4) Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. The problem to be solved is as follows. The above-mentioned conventional technique uses a solid oil or an oil gel as a cosmetic material, which is difficult to use, and improves the spreadability. When the eucalyptus oil is contained, the difference or the viscosity increase or the gelation viscosity is lowered. Or it is found that the effective substance such as gel permeation is less than the actual situation. However, it has not been used yet, and it is required to develop an oily solid which is excellent in the feeling of use due to the greasy feeling of the eucalyptus oil and also excellent in hand effect. The invention is developed even if it is not stable It is a combination of an oily solid finger, a good applicability, and a solution to an oil problem that is excellent in stability and moisturizing effect. The present inventors have a phospholipid, which is narrow at 25 ° C at 25 ° C. It is a liquid ester oil: It is excellent in oily solid cosmetics in an oily solid cosmetic which is excellent in application after application of a cosmetic. It is difficult to change or spread poorly when curing oily ingredients. For the lack of mutual solubility in oily ingredients, it is found that the oil content of the preparations over time is called "liquid discharge", although various evaluations of the gelling agent are also carried out to preserve the stability on the surface. By. Therefore, it is excellent in smearability or does not feel easy to handle after application, and preserves stability or moisturizing cosmetics. The use of a solid oily component or the like to provide a cosmetic material which is not sticky after application of the cosmetic material and which is a storage solid is desired. As a result of the investigation, it was found that by combining sand oil having a specific viscosity of 1 to 100 mm 2 /s, it was found that the finger can be taken, the spreadability was further saved, and the stability and moisturizing effect were saved. That is, the present invention relates to a phospholipid containing the following components (a) to (c): (a) 5 to 25% by mass, a phospholipid composition of 25 to 42% of phospholipid choline, 25~ 42% phospholipid ethanolamine (b) oyster oil having a kinetic viscosity of 1 to 1 〇〇mm2/s at 25 ° C (c) is a liquid ester oil at 25 ° C, and component (b) and component (c) An oily solid cosmetic having a mass ratio (b) / (c) of 0.006 to 0.4. The component (c) is a cosmetic solid in the form of an oily solid characterized by a branched fatty acid having a carbon number of 6 to 30 and a triglyceride oil of glycerin. The component (c) is an oily solid cosmetic characterized by 2-ethylhexanoic acid glyceride and/or triisostearic acid glyceride. It is an oily gelatinous cosmetic characterized by further containing 5 to 20% by mass of the component (d) N-mercaptolysine. It is an oily solid cosmetic which is obtained by cooling the ingredients (a) to (c) which are melted at 7 to 80 ° C in a container. EFFECT OF THE INVENTION The oily solid cosmetic of the present invention is excellent in finger grip or spreadability, and has less stickiness and excellent preservation stability and moisturizing effect. BEST MODE FOR CARRYING OUT THE INVENTION The present invention will be described in detail below. The phospholipid of the component (a) of the present invention is used as an oil solidifying agent in an oily solid cosmetic, and as a phospholipid type, as long as it is a user of the cosmetics, it is not Particularly, for example, a soybean-derived phospholipid, a soybean-derived hydrogenated phospholipid, an egg yolk-derived phospholipid, an egg yolk-derived hydrogenated phospholipid, or the like can be used. These phospholipids are generally a mixture of phospholipid choline (hereinafter abbreviated as PC), phospholipid ethanolamine (hereinafter abbreviated as PE), phospholipid creatinine (hereinafter abbreviated as PI), etc., and the composition varies depending on the source of the phospholipid, but The phospholipid phospholipid composition used in the present invention has a composition of 25 to 42% of PC and 25 to 42% of PE. If it is in this range, it will be an oily solid cosmetic which is excellent in stability. In the phospholipid composition, less than 25% of PCs have poor miscibility with oils, and more than 42% do not work as oil gelling agents. In addition, those with a PE content of less than 25 % in the phospholipid composition will be difficult to operate as an oil gelling agent, and if more than 42% are poorly miscible with the oil agent. As the component (a) in the present invention, one or more phospholipids may be used. When two or more kinds are used, the phospholipid composition may be in the range of the average. As a specific product of such a component (a), Resinol S-10 or the like provided by Shuguang Chemical Co., Ltd. may be mentioned. The content of the component (a) of the present invention is 5 to 25% by mass (hereinafter referred to as "%"), preferably 8 to 20%. When the content is less than 5%, it is difficult to solidify the oil and the storage stability is deteriorated. On the other hand, when it exceeds 25%, the spreadability is deteriorated, and the unique odor of the phospholipid becomes strong, and it is not suitable as a cosmetic. If it is in the range of 5 to 25%, it can be obtained as an oily solid cosmetic with no sticky feeling, excellent finger picking, excellent spreadability, good skin suitability, excellent preservation stability, and high moisturizing effect. . The component (b) of the present invention is a liquid-like emu oil used in an oil-based cosmetic having an kinetic viscosity of 1 to 1 〇〇 mm 2 /s at 25 ° C, and a molecule such as a ring, a branch, a 10-201002357 chain or the like The shape is not particularly limited. Specific examples thereof include octamethylcyclotetraoxane, decamethylcyclopentaoxane, dodecamethylcyclohexaoxane, and chain eucalyptus dimethylpolyoxane, Phenyl phenyl polyoxyalkylene and the like. The eucalyptus oil having an kinetic viscosity of 1 to 1 2 mm 2 /s at 25 ° C can be used in one or two or more types, and is preferably a non-sticky and smear-sensitive one. In addition, the dynamic viscosity is measured based on the crude oil and petroleum products described in IS-K-2 289, the dynamic viscosity test method, and the viscosity index calculation method. The component (b) of the present invention may be a commercially available product, and may be, for example, KF96A-6cs, KF96A-100cs, KF56, KF50-l〇〇cs (manufactured by Shin-Etsu Chemical Co., Ltd.), SH200C, which are linear eucalyptus oils. -6cs (above is made by Toray. Dowcorning), SH224, SH3 44, SH24 5, DC345, DC246 of ring sand oil (above {system Toray ·
Dowcorning社製）、KF-995 (以上係信越化學工業社製 )等，但並非受此局限者。 本發明之成份（b )之含量’雖無特別限定，但以總 組成物中之0.5〜20%爲宜，以5〜15%尤佳。於此範圍時， 可得到更不會有黏腻感，保存安定性或保濕效果良好之油 性固體狀之化妝料。 本發明使用之成份（c )之於25 °C爲液狀之酯油，通 常化妝料所使用物即可，無特別限制，可舉例如2-乙基 己基棕櫚酸酯、異丙基棕櫚酸酯、異丙基肉豆蔻酸酯、異 十三烷基異壬酸酯、異壬基異壬酸酯、新戊二醇二辛酸酯 、三異硬脂酸甘油酯、三-2-乙基己酸甘油酯、丙二醇二 -11 - 201002357 癸酸酯、丙二醇二辛酸酯、三（辛基·癸基）酸甘油酯等 ’可使用此等之1種或2種以上。 此等中，就無黏腻感之觀點上，以碳數6〜30之支鏈 脂肪酸及甘油之酯鍵結所得之三酯油爲宜。具體上可列舉 三異硬脂酸甘油酯、三-2-乙基己酸甘油酯等，作爲該市 售品，可列舉 TIO ( N ) 、salacos33 1 8 (皆爲日清 〇illi〇 社製）、TRIFAT S-3 08 (日光化學社製）等。 本發明之成份（c )之含量，雖無特別限定，但以總 組成中之30〜90%爲宜，以40〜80%尤佳。於此範圍時，可 製作塗抹性良好，不黏腻，保存安定性、保濕效果等優異 之油性固體狀之化妝料。 本發明之油性固體狀之化妝料中成份（b )及（c )之 含有質量比（b) / (c)爲0.00 6~0.4。配合比未達0.006 ，使用時黏腻，並不適宜。另外，配合比若超過0.4時， 就保存安定性面上並不適宜。以（b )/( c )爲 0.01〜0.2 爲宜，若於此範圍內，可得到使用時之塗抹性優異，不黏 腻，而且保存安定性或保濕效果優異之油性固體狀之化妝 料。 因爲本發明之油性固體狀之化妝料係以抑制塗抹後的 黏腻感，提升保存安定性爲目的，可再含有成份（d ) N-醯基賴胺酸。作爲N-醯基賴胺酸係只要通常的化妝品所 使用者即可，並無特別的限定。可舉例如Ν ε -月桂醯基 賴胺酸、Ν ε -椰醯基賴胺酸、Ν ε -硬化牛脂脂肪酸醯基賴 胺酸、Ν α -辛醯基賴胺酸、Ν α -月桂醯基賴胺酸、Ν α -肉 -12 - 201002357 豆蔻醯基賴胺酸、Να-油醢基賴胺酸、Να-二十二烷醯基 賴胺酸等。此等係可單獨或混合2種以上使用。就抑制對 肌膚之黏腻感，尤其以撥水發油性粉體之Ν ε -月桂醯基 賴胺酸優異，該形狀係以平均粒徑爲1〜30μηι之板狀爲宜 。作爲如此 Ν ε -月桂醯基賴胺酸之市售品，可列舉 Amihope LL (味之素社製）等。 本發明之成份（d )含量雖無特別限定，但以總組成 中之5〜20%爲宜，以1〇〜15%尤佳。若於此範圍時，可得 到肌膚適用性良好，保存安定性提升之油性固體狀之化妝 料。 本發明之油性固體狀之化妝料之製造方法，雖無特別 限定’但以由溶融塡充而製造爲宜。例如藉由將成份（a )、成份（b )、成份（c )及成份（d )混合，均勻溶融 後塡充於容器，可得到保存安定性更加良好之油性固體狀 之化妝料。溶融塡充之溫度係以7 0 °C以上，8 0。(：以下之 範圍爲宜，因爲若未達70 °C時，成份（a)磷脂質對油性 成份之分散性降低’另外，若超過801：時，成份（a)磷 脂質發生變質·變臭’並不適宜。藉由將於此溫度範圍溶 融塡充物冷卻至室溫’可製作油性固體狀之化妝料。 本發明之油性固體狀之化妝料中，於不妨礙本發明效 果之範圍’可配合通常化妝料等所配合之任意成份，亦即 成份（b )、成份（c )以外之油劑、粉體、界面活性劑、 成份（a )以外之油膠化劑、有機改性黏土礦物 '樹脂、 紫外線吸收劑、防腐劑、抗菌劑、香料、抗氧化劑、保濕 -13- 201002357 劑等。 本發明之油性固體狀之化妝料係藉由使用特定的磷脂 質，不使用傳統上必要之固體油等而可形成固體狀，但於 不損及本發明之效果之手指易拿取之範圍，亦可含有固體 油。此時之固體油含量係大約爲5 %以下，以1 %以下爲宜 〇 «· 如此所得之本發明之化妝料係固體狀者，但於本說明 書中，所謂固體狀係指例如藉由流變計（FUDOH RHEOMETER N RM - 2 0 0 2 D :不動工業社製），以 3 5 〇C， 針徑爲 1.0mm 0 ’入針速度爲 6cm/min，入針深度爲 2.0 mm之條件’測定之入針荷重値爲20.0g以上者，亦包 含所謂的膠狀物。另外，作爲本發明之油性固體狀之化妝 料’可列舉護膚、彩妝、頭髮用等之化妝料。更具體地可 列舉眼霜、按摩料、面膜料、護手霜、身體霜、口紅、亮 光唇膏、護唇膏、唇底膏等，尤其作爲眼圈用、口唇用等 之部份使用爲宜’其中以眼圈用乳霜爲宜。其他，可爲防 曬品、乳霜、美容液、面膜、整髮料、養髮料等之臉、手 腳、身體用之基礎化妝料、粉底、眼影、眼線、睫毛膏等 之彩妝化妝料。另外’該使用法雖非特別限定者，但可列 舉使用刮刀等小道具之方法或以手、指直接塗抹使用之方 法等。 【實施方式】 [實施例] -14- 201002357 以下係舉實施例’更詳細地說明本發明’但本發明並 非受此等限制者。 實施例1 本發明品1〜8及比較品1〜1 1 :固體狀乳霜 以表1及表2表示之組成及下述製法，調製固體狀乳 霜。使用感的評估係由專業評估員對（1 )手指拿取、（2 )塗抹性良好、（3 )不黏腻進行官能評估。作爲固體狀 乳霜之保存安定性係於50°C恆溫槽，放置1個月，對外 觀的變化（分離、排液），以目測進行評估。合倂結果如 表1及表2所示。 -15- 201002357 表1 (%) 本發明品 No 成分 1 2 3 4 5 6 7 8 1 氫化磷脂質(PC..32%、PE:32%) 10 25 5 10 10 10 10 10 2 氫化碟脂質(PC:9〇%、PE:5%) . . . . . 3 氫化磷脂質(PC:5% ' PE:92%) . _ . • _ . 4 巴西棕櫚蠘 . . . • . . . 5 棕櫚酸糊精 . . . . . . 6 二甲基聚矽氧烷（5〇_2/s) 10 10 10 麵 . 10 0.36 24 7 甲基苯基聚矽氧烷（14_2/s) . 10 . _ _ 8 八甲基環四矽氧烷（4mm2/s) . . 響 10 . _ 9 二苯基聚二甲基砂氧烷（175mm2/s) . . . . . 10 二甲基聚矽氧烷(200mm2/s) . . . . . . 11 三-2-乙基己酸甘油酯 60 60 60 60 60 60 60 60 12 硬脂酸硬化篦麻油（注1) . _ . . . . _ _ 13 Ν ε -月桂醯基賴胺酸（注2) . 10 . . 14 防腐劑 適量 適量 適量 適量 適量 適量 適量 適量 15 抗氧化劑 適量 適量 適量 適量 適量 適量 適量 適量 16 香料 適量 適量 適量 適量 適量 適量 適量 適量 17 流動鏈院烴 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 (b)/(c) 0.167 0.167 0.167 0.167 0.167 0.167 0.006 0.400 有無固體化 ◎ ◎ 〇 ◎ ◎ ◎ ◎ ◎ 評 保存安定性 ◎ ◎ ◎ ◎ ◎ ◎ ◎ 〇 估 使用試驗(1)手指拿取 ◎(4.9) 0(3.8) ◎(4.7) ◎(4.9) ©(4.9) ◎(4.7) ◎(4.9) 0(4.3) 項 使用試驗(2)塗抹良好性 ◎(4.9) 0(3.9) ◎(4.6) ◎(4.9) ◎(4.9) ◎(4.7) 0(4.1) 〇4.4) 巨 使用試驗(3)無黏腻感 ◎(4.6) ◎(4.6) 0(3.9) 0(3.9) 0(3.7) ©(4.9) 0(3.5) ◎(4.9) 成分Να6〜10之動黏度於25°C之値。 (注 1) castride MS ( nation 美松社製） (注2) Amihope LL (味之素社製） -16- 201002357 表2 (%) 比較品 No 成分 2 3 4 5 6 7 8 9 10 11 1 氫化磷脂質(PC:32%、PE:32%) 10 10 10 10 10 40 2 氫化磷脂質(PC:90%、PE.+5%) 10 3 氫化磷脂質(PC:5%、PE:92%) 10 4 巴西棕櫚蠟 10 5 棕櫚酸糊精 10 6 二甲基聚矽氧烷（50mm2/s) 10 10 10 10 10 30 10 0.1 10 7 甲基苯基聚矽氧烷（14mm2/s) 8 八甲基環四矽氧烷（4mm2/s) 9 二苯基聚二甲基矽氧烷（175 mm2/s) - - - - - - - 10 - - - 10 二甲基聚矽氧烷P〇〇mm2/s) 10 11 三-2-乙基己酸甘油酯 60 60 60 60 40 60 60 60 60 50 12 硬脂酸硬化篦麻油（注υ 60 13 Ν£-月桂醯基賴胺酸（注2) 14 防腐劑 適量 適量 適量 適量 適量 適量 適量 適量 適量 適量 適量 15 抗氧化劑 適量 適量 適量 適量 適量 適量 適量 適量 適量 適量 適量 16 香料 適量 適量 適量 適量 適量 適量 適量 適量 適量 適量 適量 17 流動鏈烷烴 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 剩餘量 (b)/(c) 0.167 0.167 0.167 0.167 0.167 0.750 0.167 0.167 0.167 0.002 0.200 有無固體化 X X X X X X Δ △ △ ◎ ◎ 評 保存安定1生 X Δ Δ ◎ ◎ 估 使用試驗⑴手指拿取 x(2.〇) △(3.0) △(3.0) ◎(4.8) 0(3.8) 項 使用試驗(2)塗抹良好性 因比較品No. 1〜6皆未固體化， 所以不能評估 △(3.0) x(1.4) x(l-9) △(3.1) 0(3.9) 巨 使用試驗(3)無黏膩感 △(3.1) △(3-0) △(3.2) x(l-4) x(2.4) 成分No.6〜10之動黏度於25°C之値。 (注 1) castride MS (nation 美松社製） (注2) Amihope LL (味之素社製） -17- 201002357 (製造方法） A :加熱成份（1 )〜（1 7 )成8 0 °C。 B:以分散攪拌機（disper mixer)混合攪拌。 C :塡充B ( 8 (TC )於容器，冷卻至室溫，得到固體狀乳 霜。 (評估方法：使用感） 要求20位2〇~4〇歲年齡層女性評估員，使用本發明 品及比較品之固體狀乳霜，對於（1 )手指拿取、（2 )塗 抹性良好、（3 )無黏腻感，依下沭々γ S ., 观之（a)或（e)5階 段評估基準進行官能評估’另外，令邮$仕M ^ + 芏部B平估貝評分之平均 値係使用（c ) 4階段判定基準判定。 (a ) 5階段評估基準（手指拿取） (評估） ··(評佶） 非常容易拿取 :5分 容易拿取 :4分 拿取方式普通 :3分 稍難拿取 :2分 非常難拿取 :1分 5階段評估基準 (塗抹性良好、無黏腻 (評估） '(評估） 非常感覺得到 :5分 '18、 201002357 稍微感覺到 ·· 4分 普通 :3分 不太感覺得到 :2分 未感覺到 :1分 (C ) 4階段判定基準 (全部評估員評分之平均値）：（判定） 平均分爲4.5以上 ：◎ 平均分爲3.5以上，未達45 : 〇 平均分爲2.5以上，未達3.5 : ΔDowcorning Co., Ltd., KF-995 (the above is manufactured by Shin-Etsu Chemical Co., Ltd.), etc., but is not subject to this limitation. The content ' of the component (b) of the present invention is not particularly limited, but is preferably from 0.5 to 20% in the total composition, more preferably from 5 to 15%. In this range, an oily solid cosmetic which is less sticky and has a good stability or moisturizing effect can be obtained. The component (c) used in the present invention is a liquid ester oil at 25 ° C, and is usually used for the cosmetic, and is not particularly limited, and examples thereof include 2-ethylhexyl palmitate and isopropyl palmitic acid. Ester, isopropyl myristate, isotridecyl isononate, isodecyl isodecanoate, neopentyl glycol dicaprylate, glyceryl triisostearate, tris-2-ethyl One or two or more kinds of these may be used, such as glyceryl hexanoate, propylene glycol di-11 - 201002357 phthalate, propylene glycol dicaprylate, or tris(octyl fluorenyl) glyceride. In the above, from the viewpoint of no stickiness, it is preferred to use a triester oil obtained by bonding a branched fatty acid having 6 to 30 carbon atoms and an ester of glycerin. Specific examples thereof include glyceryl triisostearate and glyceryl tris-2-ethylhexanoate. Examples of the commercially available product include TIO (N) and salacos 33 1 8 (all manufactured by Nissin 〇illi Co., Ltd.). ), TRIFAT S-3 08 (manufactured by Nikko Chemical Co., Ltd.). The content of the component (c) of the present invention is not particularly limited, but is preferably 30 to 90% in the total composition, and more preferably 40 to 80%. In this range, it is possible to produce an oily solid cosmetic which is excellent in spreadability, non-sticky, and excellent in stability and moisturizing effect. The mass ratio (b) / (c) of the components (b) and (c) in the oily solid cosmetic of the present invention is 0.006 to 0.4. The mixing ratio is less than 0.006, and it is not suitable when used. Further, when the blend ratio exceeds 0.4, it is not preferable to store the stability surface. It is preferable that (b)/(c) is 0.01 to 0.2, and in the above range, an oily solid cosmetic which is excellent in spreadability at the time of use, is non-sticky, and has excellent stability and moisturizing effect can be obtained. The oily solid cosmetic of the present invention further contains the component (d) N-mercapto lysine for the purpose of suppressing the sticky feeling after application and improving the preservation stability. The N-mercapto lysine acid is not particularly limited as long as it is a user of a general cosmetic. For example, Ν ε - laurel lysine, Ν ε - cocoyl lysine, Ν ε - hardened tallow fatty acid lysine lysine, Ν α - octyl lysine, Ν α - laurel Amine acid, Ν α - meat-12 - 201002357 Myristyl lysine, Να-oleoyl lysine, Να-docosanonyl lysine, and the like. These may be used alone or in combination of two or more. It is excellent in suppressing the stickiness to the skin, especially in the water-repellent powder ε-laurel-based lysine, and the shape is preferably a plate having an average particle diameter of 1 to 30 μm. As a commercial item of such Ν ε - laurel lysine, Amihope LL (made by Ajinomoto Co., Ltd.), etc. are mentioned. The content of the component (d) of the present invention is not particularly limited, but is preferably from 5 to 20% by weight based on the total composition, particularly preferably from 1 to 15%. When it is in this range, it is possible to obtain an oily solid cosmetic which has good skin applicability and preserves stability. The method for producing the oily solid cosmetic of the present invention is not particularly limited, but it is preferably produced by melt filling. For example, by mixing the component (a), the component (b), the component (c), and the component (d), the mixture is uniformly melted and then filled in a container, whereby a cosmetic which retains a more stable oily solid can be obtained. The temperature of the molten charge is above 70 °C, 80. (The following range is suitable, because if it is less than 70 °C, the dispersibility of the component (a) phospholipid to the oily component is lowered.] In addition, if it exceeds 801: the component (a) phospholipid deteriorates and becomes odorous. It is not preferable. The oily solid cosmetic can be produced by cooling the temperature in the temperature range to the room temperature. The oily solid cosmetic of the present invention does not hinder the effect of the present invention. Any combination of ingredients such as ingredients (b), ingredients (c), oils, surfactants, oil gelling agents other than ingredients (a), organically modified clays Mineral 'resin, UV absorber, preservative, antibacterial agent, perfume, antioxidant, moisturizing-13-201002357, etc. The oily solid cosmetic of the present invention is used conventionally by using a specific phospholipid. The solid oil or the like may form a solid, but may contain a solid oil in a range in which the fingers which do not impair the effects of the present invention are easily taken. The solid oil content at this time is about 5% or less and less than 1%. For Yizhen «· In the present invention, the solid material is a solid state, for example, by a rheometer (FUDOH RHEOMETER N RM - 2 0 0 2 D: manufactured by Immobilisation Co., Ltd.), and 3 5 〇C, the needle diameter is 1.0mm 0 'The needle insertion speed is 6cm/min, and the needle insertion depth is 2.0 mm. The measured needle load 値 is 20.0g or more, and the so-called jelly is also included. Examples of the oily solid cosmetic of the present invention include skin care, makeup, hair, and the like. More specifically, eye cream, massage material, facial mask, hand cream, body cream, lipstick, gloss lipstick, and care are mentioned. Lip balm, lip base cream, etc., especially for use as part of eye circles and lips, etc. It is suitable for eye cream. Others can be sunscreen, cream, beauty lotion, mask, hair styling, Cosmetics such as face, hands and feet, basic makeup for the body, foundation, eye shadow, eyeliner, mascara, etc. In addition, the method of use is not particularly limited, but a method of using a small blade such as a scraper can be cited. Or apply directly by hand or finger [Embodiment] [Embodiment] [Embodiment] -14-201002357 Hereinafter, the present invention will be described in more detail, but the present invention is not limited thereto. Embodiment 1 The present invention 1 to 8 and Comparative product 1 to 1 1 : The solid cream was prepared by the composition shown in Tables 1 and 2 and the following method to prepare a solid cream. The evaluation of the feeling of use was performed by a professional assessor (1) finger, (2) Good adhesion, (3) Non-sticky for functional evaluation. As a solid cream, the storage stability is placed in a 50 ° C thermostat, placed for 1 month, the appearance changes (separation, drainage), visual inspection The evaluation was carried out. The combined results are shown in Tables 1 and 2. -15- 201002357 Table 1 (%) Inventive product No component 1 2 3 4 5 6 7 8 1 Hydrogenated phospholipid (PC..32%, PE: 32%) 10 25 5 10 10 10 10 10 2 Hydrogenated disc lipid (PC: 9%, PE: 5%) . . . . 3 Hydrogenated phospholipids (PC: 5% 'PE: 92%) . _ . • _ . 4 Brazil palm 蠘 . . . . . . . . Palmitic acid dextrin. . . . . 6 Dimethyl polyoxane (5〇_2/s) 10 10 10 face. 10 0.36 24 7 methylphenyl polyoxyalkylene (14_2/s) . 10 _ _ 8 octamethylcyclotetraoxane (4mm2/s) . . . 10 _ 9 diphenyl polydimethyl oxa oxide (175mm2 / s) . . . . 10 dimethyl fluorene Oxyalkane (200mm2/s) . . . . . 11 Tris-2-ethylhexanoate 60 60 60 60 60 60 60 60 12 Stearic acid hardened castor oil (Note 1) . _ . . . . _ _ 13 Ν ε - laurel lysine (Note 2) . 10 . . 14 Preservatives Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount 15 Anti-oxidant Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount 16 Proper amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount 17 remaining in the mobile chain Remaining amount Remaining amount Remaining amount Residual amount (b)/(c) 0.167 0.167 0.167 0.167 0.167 0.167 0.006 0.400 With or without solidification ◎ ◎ 〇 ◎ ◎ ◎ ◎ ◎ Evaluation of storage stability ◎ ◎ ◎ ◎ ◎ ◎ ◎ Evaluation of use test (1) Finger picking ◎ (4.9) 0 (3.8) ◎ (4.7) ◎ (4.9) © (4.9) ◎ (4.7) ◎ (4.9) 0 (4.3) Test of use (2) Good application ◎ (4.9 0(3.9) ◎(4.6) ◎(4.9) ◎(4.9) ◎(4.7) 0(4.1) 〇4.4) Giant use test (3) No sticky feeling ◎(4.6) ◎(4.6) 0(3.9) 0(3.9) 0(3.7) ©(4.9) 0(3.5) ◎(4.9) The dynamic viscosity of the component Να6~10 is at 25 °C. (Note 1) castride MS (made by Matsusaka Co., Ltd.) (Note 2) Amihope LL (manufactured by Ajinomoto Co., Ltd.) -16- 201002357 Table 2 (%) Comparison product No. 2 3 4 5 6 7 8 9 10 11 1 Hydrogenated phospholipids (PC: 32%, PE: 32%) 10 10 10 10 10 40 2 Hydrogenated phospholipids (PC: 90%, PE. + 5%) 10 3 Hydrogenated phospholipids (PC: 5%, PE: 92 %) 10 4 carnauba wax 10 5 palmitic acid dextrin 10 6 dimethyl polyoxane (50mm2/s) 10 10 10 10 10 30 10 0.1 10 7 methylphenyl polyoxyalkylene (14mm2/s) 8 octamethylcyclotetraoxane (4mm2/s) 9 diphenylpolydimethyloxane (175 mm2/s) - - - - - - - - 10 - - - 10 dimethyl polyoxane P〇〇mm2/s) 10 11 Tri-2-ethylhexanoate 60 60 60 60 40 60 60 60 60 50 12 Stearic acid hardened castor oil (Note 60 13 Ν£-laurel lysine (Note 2) 14 Preservatives Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount 15 Anti-oxidant Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Amount 16 Amount of Spices Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Appropriate amount Residual amount Residual amount Residual amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount Remaining amount (b)/(c) 0.167 0.167 0.167 0.167 0.167 0.750 0.167 0.167 0.167 0.002 0.200 With or without solidification XXXXXX Δ △ △ ◎ ◎ Evaluation of stability and stability 1 sheng Δ Δ ◎ ◎ Estimated use test (1) Finger take x (2. 〇) △ (3.0) △ (3.0) ◎ ( 4.8) 0 (3.8) Tests for use (2) Goodness of application Because Comparative Products No. 1 to 6 are not solidified, it is not possible to evaluate △(3.0) x(1.4) x(l-9) △(3.1) 0 (3.9) Giant use test (3) No sticky feeling △ (3.1) △ (3-0) △ (3.2) x (l-4) x (2.4) Component No. 6 to 10 dynamic viscosity at 25 ° C After that. (Note 1) castride MS (made by Matsusaka Co., Ltd.) (Note 2) Amihope LL (made by Ajinomoto Co., Ltd.) -17- 201002357 (Manufacturing method) A : Heating component (1) to (1 7 ) to 80 ° C. B: Mix and stir with a disper mixer. C: 塡B (8 (TC) in a container, cooled to room temperature, to obtain a solid cream. (Evaluation method: feeling of use) 20 female evaluators of 2〇~4〇 age group are required to use the present invention And the solid cream of the comparative product, for (1) finger picking, (2) good spreadability, (3) no sticky feeling, depending on 沭々γ S., view (a) or (e) 5 The stage evaluation benchmark is used for the functional evaluation. In addition, the average rating of the postal estimate is used to determine the average rating of the grades. (c) The 4-stage evaluation criteria are determined. (a) The 5-stage evaluation criteria (finger take) ( Evaluation) ·· (Review) Very easy to take: 5 points easy to take: 4 points to take the ordinary: 3 points is difficult to take: 2 points is very difficult to take: 1 point and 5 stages of evaluation criteria (good spreadability It is not sticky (evaluation) '(Evaluation) I feel very much: 5 points '18, 201002357 I feel a little... 4 points Normal: 3 points don't feel it: 2 points are not felt: 1 point (C) 4 stages Judgment criteria (average 全部 of all evaluators' ratings): (Judgement) The average score is 4.5 or more: ◎ The average score is 3.5 or more, less than 45: 〇 Divided into more than 2.5, less than 3.5: Δ
平均分未達2.5 : X (評估方法：有無固體化） 對於冷卻上述方法製造之油性固體狀之化妝料至室溫 時之外觀’以目測觀察，以下述（d ) 4階段絕對判定基 準進行判定。 (d ) 4階段絕對判定基準 (評估方法：有無固體化） ：（判定） 固體化’幾乎完全未見到排液 ：◎ 見到少許排液，但未到成爲問題之程度：〇 見到些許排液，部份未固體化 ：△The average score is less than 2.5: X (Evaluation method: presence or absence of solidification) The appearance of the oily solid cosmetic prepared by the above method to room temperature is visually observed and judged by the following (d) 4-stage absolute criterion. . (d) 4-stage absolute criterion (evaluation method: presence or absence of solidification): (decision) Solidification 'Almost no drainage was observed: ◎ A little drainage was seen, but it did not become a problem: I saw a little Discharge, partially unsolidified: △
明顯見到排液，未固體化 ：X -19- 201002357 (評估方法：保存安定性） 放置各試料於5 (TC之恆溫槽1個月，對外觀的變化 (排液程度），以目測觀察，以下述之（e ) 4階段絕對 判定基準進行判定。 (e ) 4階段絕對判定基準 (排液程度） ：（判定） 幾乎完全未見到排液 ：◎ 見到少許排液，但未到成爲問題之程度 ：〇 見到些許排液 ：△Obviously see drainage, not solidified: X -19- 201002357 (Evaluation method: preservation stability) Place each sample in 5 (TC thermostat for 1 month, change in appearance (degree of drainage), visual observation The determination is based on the following (e) 4-stage absolute determination criteria. (e) 4-stage absolute determination criterion (degree of drainage): (decision) Almost no drainage is observed: ◎ A little drainage is seen, but it is not The extent of the problem: I saw some drainage: △
明顯見到排液 ：X 如表1及表2之結果顯示，本發明品1〜8之固體狀乳 霜係手指拿取、塗抹性佳，無黏腻感，保存安定性優異者 。相對於此，使用未含上述範圍之PC及PE組成之氫化 磷脂質之比較品1及比較品2中，氫化磷脂質不能均勻溶 融於其他成份，塡充冷卻時亦不能形成固體狀。使用磷脂 質以外之油膠化劑之比較品3、4係油膠化劑與矽油之互 溶性差，不形成固體狀，成爲矽油分離之結果。使用於 2 5 °C爲半固體狀酯油之硬脂酸硬化箆麻油之比較品5、成 份（b )及成份（c )之比率爲0_006~0.4之範圍外之比較 品6未成爲固體狀。另外’成份（A)碑脂質含;μ爲 5〜2 5 %範圍外之比較品7未充份固體化，保存安定性非常 差。取代成份（b)，含有動黏度分別爲 175mm2/s、 -20- 201002357 200mm 2/s之矽油之比較品8、9係凝膠之保存安定性差’ 並且使用時之塗抹性非常差，有黏腻感。幾乎不含有成份 (b )，成份（b )及成份（c )之比率低於〇·〇〇ό之比較 品1 0雖然成爲固體狀’保存安定性佳’但使用時感到黏 腻者。成份（a )之含量多於2 5 %之比較品1 1雖然形成凝 膠，保存安定性優異’但使用時之塗抹性差’感到黏腻者 實施例2 本發明品9〜1 0及比較品1 2 ~ 1 5 :固體狀乳霜[(業） 小野國際特許1 ] 以表3表示之組成及下述製法’調製固體狀乳霜。對 於所得之固體狀乳霜，測定水分透過速度、摩擦應力’以 及進行官能評估（（a )塗抹性、塗抹後之（b )緊繃感、 (c )保濕效果）。 -21 - 201002357 表3 發明品9 發明品10 比較品12 比較品13 比較品14 比較品15 氫化磷脂質 (PC : 32%、PE : 32%) 10 10 - - 氫化磷脂質 (PC ： 80% ' PE ： 5%) 10 - - 棕櫚酸糊精 - _ 10 小燭樹繼 _ 10 6 三異硬脂酸甘油酯 89 84 89 89 89 93 二甲基聚矽氧烷 (10mm2/s) 1 1 1 1 1 1 Νε月桂醯基賴胺酸（注2) - 5 - _ • (製造方法） A :加熱成份成8(TC。 B :將A以分散攪拌機混合攪拌。 C :塡充B ( 8 0 °C )於容器，冷卻至室溫，得到固體狀乳 (水分蒸散速度試驗） 對於發明品9、比較品1 2 ~ 1 4之固體狀乳霜，調査閉 塞性。將此等固體狀乳霜，使用流延法（doctor blade ) ，於放入〇.9%NaCl水溶液之Franz型擴散槽之聚氯化乙 烯膜上均勻塗佈’塗佈量爲〇.2g、塗佈面積爲8.03cm2、 厚度爲4 0 μ m。 測定開始8小時後’測定槽的重量變化’以此作爲累 積水分透過量，算出由下述式每1小時之每1 m2之水分 -22- 201002357 蒸散速度。另外，關於固體化的有無，與實施例1同樣地 評估。結果如表4所示。 水分蒸散速度（g/hr_m2)= (累積水分透過量（g)/時間（hr))x(l 00x 1 00/8.03 ) 表4 發明品9 比較品12 比較品13 比較品14 氫化磷脂質 (PC ： 32% ' PE ： 32%) 10 - - - 氫化磷脂質 (PC ： 80% ' PE ： 5%) - 10 - - 棕櫚酸糊精 _ _ 10 _ 小燭樹蠟 _ _ _ 10 三異硬脂酸甘油酯 89 89 89 89 二甲基聚矽氧烷 (10mm2/s ) 1 1 1 1 Νε月桂醯基賴胺酸(注2) • _ _ _ 有無固體化 ◎ X ◎ ◎ 水分蒸散速度 (g/hr · m2) 2.32 63.70 11.25 43.26 本發明9係因爲水分蒸散速度非常低，所以顯示閉塞 性高，保濕效果優異。另一方面，使用組成相異之磷脂質 之比較品1 2未形成凝膠。另外，使用取代磷脂質以外之 油膠化劑之比較品1 3、1 4係水分蒸散速度高，閉塞性低 者。 (測定摩擦應力） -23- 201002357 對於入針荷重値約相等之本發明品9、比較品15之 固體狀乳霜，爲評估塗抹時之塗抹性，測定摩擦應力。 C S L型壓力控制式流變計（圓錐爲4 c m 2。，測定溫度爲 15 °C)，自切變速率 （Shear rate)、切變應力（shear Stress)曲線之原點所拉直線，測定偏離點之切變應力。 結果如圖1所示。另外’入針荷重値係由流變計（ FUDOH RHEOMETER NRM-2002D :不動工業社製）測定 (φ 1.0mm，d=2mm，6cm/min，35 °C ，1 小時）。 表5 發明品9 比較品15 氫化磷脂質 (PC ： 32% ' PE ： 32%) 10 - 氫化磷脂質 (PC ： 80% ' PE ： 5%) - 棕櫚酸糊精 小燭樹蠟 _ 6 三異硬脂酸甘油酯 89 93 二甲基聚矽氧烷 (10mm2/s) 1 1 Νε月桂酿基賴胺酸(注2) _ 入針荷重値（35。。） 54 55 由圖1可知，即使相同入針荷熏，比較品1 5係結晶 結構硬’爲破壞結晶結構需要力道強。相對於此，本發明 品9係以弱的摩擦應力破壞凝膠，所以顯示滑順的塗抹性 -24- 201002357 另外’本發明品9之凝膠之掃描式電子顯微鏡照片如 圖2所示。由此相片顯示本發明品9之凝膠係形成層狀的 薄片（lamella)液晶。推測因爲形成如此層狀的薄片液晶 ，所以如上述抑制水分蒸散，並且以弱摩擦應力破壞凝膠 ，成爲塗抹性良好者。 (官能評估） 對於發明品9〜10及比較品1 1~12之凝膠，分別以20 位爲評估員，塗佈於臉部，對於塗佈時之（a )塗抹性、 塗佈後之（b )緊繃感、（c )保濕效果，依（A ) 5階段 評估基準進行評估，進而使用（B ) 4階段判定基準判定 各試料之評分平均分。結果如表6所示。 (A) 5階段評估基準 (評分）：（評估） 5分：非常良好 4分：良好 3分：普通 2分：差 1分：非常差 (B) 4階段判定基準 (判定）：（評分之平均分） ◎:平均分爲4·5以上 -25- 201002357 〇··平均分爲3.5以上，未達4.5 △:平均分爲2.5以上，未達3.5 X :平均分未達2.5 表6 發明品9 發明品10 比較品13 比較品14 氫化磷脂質 (PC ： 32% ' PE ： 32%) 10 10 氫化磷脂質 (PC ： 80% ' PE ： 5%) - - - - 棕櫚酸糊精 一 _ 10 小燭樹蠟 • _ 10 三異硬脂酸甘油酯 89 84 89 89 二甲基聚砂氧院（10mm2/s) 1 1 1 1 Νε月桂醯基賴胺酸(注2) _ 5 _ _ 塗抹良好性 ◎(4.5) ◎(4.8) X⑵ △⑶ 使用後之緊繃 ◎(4.5) ©(4.8) X⑵ 0(3.5) 保濕效果 ◎(4.5) ©(4.8) X⑵ △⑶ 發明品9、10係顯示「塗抹性良好」、「使用後之緊 繃」、「保濕效果」中任一項皆優異之效果。尤其發明品 1 〇係含有胺基酸衍生物之粉體月桂醯基賴胺酸，於任一 項顯示更優異的效果。另一方面，關於以棕櫚酸糊精 '或 小燭樹蠟凝膠化之比較品1 3、1 4，係感到含有油劑之黏 腻感者，Μ且肌膚適合性差，所以皆未達足任一項「塗抹 良好性」、「使用後之緊繃」、「保濕效果」者。 .26- 201002357 [(業）小野國際特許2 ]實施例3 :固體狀按摩料 由下述製法調製下述配方之固體狀按摩料。 (成份） （％ ) 1 氫化蛋黃磷脂質（注3 ) 25.0 2_二甲基聚矽氧烷（注4) 12.0 3 .維生素E 0.3 4 .油酸乙酯 〇 . i 5.三-2-乙基己酸甘油酯 32.〇 6 .尼龍粉末 7.0 7 · Ν ε -月桂醯基賴胺酸（注2 ) 8.0 8 ·流動鏈烷烴 剩餘量 9 .抗氧化劑 0.1 I 〇 _防腐劑 適量 II ·香料 適量 (注3 )磷脂質組成 PC : 28%，ΡΕ : 28% (注 4 )動黏度 20mm2/s ( 25°C ) (製造方法） A :加熱成份（1) ~ ( 11)成80°C。 B :以分散攪拌機混合攪拌。 C :塡充B ( 8 0 °C )於容器，冷卻至室溫，得到固體狀按 摩料。 -27- 201002357 實施例3之固體狀按摩料係於3 5 °C時顯示Λ ^ 八針荷蔞 値爲1 2 0 g ’手指拿取、塗抹良好性、無黏腻感、sn 肌膚_ 合性、保存安定性、保濕效果優異者。 實施例4 :固體狀護手霜 由下述製法調製下述配方之固體狀護手霜。 (成份） （％ ) 1 .氫化大豆磷脂質（注5 ) 5.0 2 .二十二烷醇 1 _ 0 3. 甲基苯基聚矽氧烷（注6 ) 20.0 4. 亞油酸生育酚 1.0 5. 流動鏈烷烴 30.0 6. 夏威夷果油 剩餘量 7·Ν ε -月桂醯基賴胺酸（注2 ) 10-0 8 ·抗氧化劑 〇.1 9 .防腐劑 適量 1 0 ·香料 適量 (注5 )磷脂質組成 PC : 32%，ΡΕ : 32% (注 6)動黏度 100mm2/s(25°C) (製造方法） A ·加熱成份（1 )〜（1 〇 )成8 0 °C。 B :以分散攪拌機混合攪拌A。 C :塡充B ( 8 0 °C )於容器，冷卻至室溫，得到固體狀護 -28- 201002357 手霜。 實施例4之固體狀護手霜係於3 5 t時顯示入針荷重 値爲60g，手指拿取、塗抹良好性、.無黏腻感、肌膚適合 性、保存安定性、保濕效果優異者。 實施例5 :眼霜（固體狀） 由下述製法調製下述配方之眼霜。 (成份） （％ ) 1 .氫化大豆磷脂質（注7 ) 10.0 2.氫化蛋黃溶血碟脂質 0.5 3 .醋酸維生素E 0.05 4 .油酸乙酯 1.0 5.2-乙基己酸十六烷酯 60.0 6 .羥基硬脂酸膽固醇 1.5 7 .二甲基聚矽氧烷（注8 ) 0.5 8 .八甲基環四矽氧烷（注9 ) 5.0 9 .甘油脂肪酸酯 剩餘量 1〇·Ν ε -月桂醯基賴胺酸（注2 ) 10.0 1 1 .抗氧化劑 0.1 1 2 .防腐劑 適量 1 3 .香料 適量 (注7 )磷脂質組成 P C : 3 1 %，Ρ Ε : 4 0 % (注 8 )動黏度 20mm2/S ( 25°C ) -29- 201002357 (注 9 )動黏度 40mm2/S ( 25t：) (製造方法） A :加熱成份（1 )〜（1 3 )成8 0 °C。 B :以分散攪拌機混合攪拌A。 C :塡充B ( 80°C )於容器，冷卻至室溫，得到眼霜。 實施例5之眼霜係於35 °C時顯示入針荷重値爲80g， 手指拿取、塗抹良好性、無黏腻感、肌膚適合性、保存安 定性、保濕效果優異者。 實施例6 :身體乳霜（固體狀） 由下述製法調製下述配方之身體乳霜。 (成份） （％ ) 1 .氫化大豆磷脂質（注1 〇 ) 8.0 2 .菊糖脂肪酸酯（注1 1 ) 1.5 3 .膽固醇 0.5 4 .流動鏈烷烴 剩餘量 5 .維生素E 1.0 6.二甲基聚矽氧烷（注12) 12.0 7 . α鏈烯烴寡聚物 2.0 8 .矽酸酐 0.2 9 . Ν ε -月桂醯基賴胺酸（注2 ) 25.0 1 0 .抗氧化劑 0.1 -30- 201002357 1 1 .防腐劑 適量 12.香料 適量 (注10 )磷脂質組成 PC : 28%，PE : 28% (注1 1 ) Rheopearl ISK (千葉製粉社製） (注 12)動黏度 20mm2/s(25°C) (製法） A :加熱成份（1 )〜（12 )成80°C。 B :以分散攪拌機混合攪拌A。 C :塡充B ( 8 0 °C )於容器，冷卻至室溫，得到固體狀身 體乳霜。 實施例6之身體乳霜係於3 5 °C時顯示入針荷重値爲 6 5 g，手指拿取、塗抹良好性、無黏腻感、肌膚適用性、 保存安定性、保濕效果優異者。 【圖式簡單說明】 [圖1 ]表示實施例2中本發明品9及比較品1 5之磨擦 應力圖。 [圖2]本發明9之掃描式電子顯微鏡照片。 -31 -Obviously, the liquid discharge was observed. X As shown in Tables 1 and 2, the solid creams of the present invention 1 to 8 were taken by fingers, had good spreadability, were not sticky, and had excellent preservation stability. On the other hand, in the comparative product 1 and the comparative product 2 which used a hydrogenated phospholipid which is not composed of PC and PE in the above range, the hydrogenated phospholipid was not uniformly dissolved in other components, and it could not form a solid when it was cooled. Comparative products using oil gelling agents other than phospholipids 3, 4 oil gelling agents are poorly miscible with eucalyptus oil and do not form a solid, which is the result of eucalyptus oil separation. Comparison product 5 of the stearic acid hardened castor oil used in the semi-solid ester oil at 25 ° C, the ratio of the component (b) and the component (c) is outside the range of 0_006 to 0.4, and the comparative product 6 is not solid. . Further, the component (A) is contained in the lipid; the comparative product 7 having a μ of 5 to 25% is not sufficiently solidified, and the storage stability is extremely poor. Substitute component (b), containing the viscous oils with kinetic viscosity of 175mm2/s and -20-201002357 200mm 2/s, the 8th and 9th series gels have poor preservation stability and are very poor in application and sticky. Feeling tired. The component (b) contains almost no component (b), and the ratio of component (b) to component (c) is lower than that of 〇·〇〇ό. Although it is solid, it has a good preservation stability, but it feels sticky when used. The comparative product 11 having a content of the component (a) of more than 25% is formed into a gel, and the storage stability is excellent, but the spreadability at the time of use is unpleasant. Example 2 The present invention 9 to 10 and the comparative product 1 2 ~ 1 5 : Solid cream [(Industry) Ono International License 1] The composition shown in Table 3 and the following method 'modulate a solid cream. For the obtained solid cream, the water permeation rate, the frictional stress, and the sensory evaluation ((a) spreadability, (b) tightness after application, and (c) moisturizing effect) were measured. -21 - 201002357 Table 3 Inventions 9 Inventions 10 Comparative products 12 Comparative products 13 Comparative products 14 Comparative products 15 Hydrogenated phospholipids (PC: 32%, PE: 32%) 10 10 - - Hydrogenated phospholipids (PC: 80% 'PE : 5%) 10 - - palmitic acid dextrin - _ 10 candelilla tree _ 10 6 triisostearate 89 84 89 89 89 93 dimethyl polyoxane (10mm2/s) 1 1 1 1 1 1 Νεlaurel lysine (Note 2) - 5 - _ • (Manufacturing method) A: Heat the ingredients to 8 (TC. B: Mix A with a dispersing mixer. C: 塡B (8) 0 ° C ) The container was cooled to room temperature to obtain a solid milk (water evaporation rate test). For the solid cream of the invention product 9 and the comparative product 1 2 to 14 , the clogging property was investigated. The frost was uniformly coated on a polyvinyl chloride film of a Franz-type diffusion tank placed in a 9% aqueous NaCl solution using a doctor blade. The coating amount was 〇.2 g and the coated area was 8.03 cm 2 . The thickness is 40 μm. After 8 hours from the start of the measurement, the change in the weight of the measurement tank is used as the cumulative moisture permeation amount, and the water per 1 m 2 per hour is calculated by the following formula. -22-201002357 Evapotranation rate. The presence or absence of solidification was evaluated in the same manner as in Example 1. The results are shown in Table 4. Moisture evapotranspiration rate (g/hr_m2) = (cumulative moisture permeation amount (g) / time ( Hr))x(l 00x 1 00/8.03 ) Table 4 Inventive product 9 Comparative product 12 Comparative product 13 Comparative product 14 Hydrogenated phospholipid (PC: 32% 'PE: 32%) 10 - - - Hydrogenated phospholipid (PC: 80% 'PE : 5%) - 10 - - palmitic acid dextrin _ _ 10 _ candelilla wax _ _ _ 10 triisostearic acid glyceride 89 89 89 89 dimethyl polyoxane (10mm2/s ) 1 1 1 1 Ν 月 月 月 醯 赖 lyric acid (Note 2) • _ _ _ with or without solidification ◎ X ◎ ◎ Moisture evapotranspiration rate (g / hr · m2) 2.32 63.70 11.25 43.26 The 9 series of the invention is very fast due to moisture evapotranspiration When it is low, it shows high occlusion property and excellent moisturizing effect. On the other hand, the comparative product of the phospholipids having different compositions is not formed into a gel. In addition, a comparative product using an oil gelling agent other than the phospholipid is used. The 1 4 series has a high water evapotranspiration rate and a low occlusion property. (Measuring the frictional stress) -23-201002357 The solid cream of the present invention 9 and the comparative product 15 having the same needle load enthalpy was evaluated for the smear property at the time of application, and the frictional stress was measured. CSL type pressure-controlled rheometer (cone is 4 cm 2 , measuring temperature is 15 ° C), straight line drawn from the origin of shear rate (shar rate) and shear stress curve, and deviation is measured. The shear stress of the point. The result is shown in Figure 1. Further, the needle-loading system was measured by a rheometer (FUDOH RHEOMETER NRM-2002D: manufactured by Immobilisation Co., Ltd.) (φ 1.0 mm, d = 2 mm, 6 cm/min, 35 ° C, 1 hour). Table 5 Inventive product 9 Comparative product 15 Hydrogenated phospholipid (PC: 32% 'PE: 32%) 10 - Hydrogenated phospholipid (PC: 80% 'PE: 5%) - Palmitic acid dextrin candlestick wax _ 6 Glyceryl isostearate 89 93 Dimethyl polyoxyalkylene (10mm2/s) 1 1 Νεlauric lysine (Note 2) _ Auxiliary load (35.) 54 55 As you can see from Figure 1, Even if the same needle is smoked, the comparative product of the 15 series crystal structure is hard to break the crystal structure. On the other hand, the present invention 9 is capable of destroying the gel with a weak frictional stress, so that the smooth spreadability is exhibited -24-201002357 In addition, the scanning electron micrograph of the gel of the present invention 9 is shown in Fig. 2 . From this photograph, it is shown that the gel of the present invention 9 is a layered lamella liquid crystal. It is presumed that since the lamellar liquid crystal is formed in such a layer, the moisture evapotranspiration is suppressed as described above, and the gel is broken by weak frictional stress, and the spreadability is good. (Functional evaluation) For the gels of the inventive products 9 to 10 and the comparative products 1 to 12, 20 coats were used as the assessor, and applied to the face, and (a) spreadability after application, after application. (b) Tightness, (c) Moisturizing effect, evaluation according to (A) 5-stage evaluation criteria, and determination of the average score of each sample using the (B) 4-stage determination criteria. The results are shown in Table 6. (A) 5-stage evaluation criteria (score): (assessment) 5 points: Very good 4 points: Good 3 points: Normal 2 points: Difference 1 point: Very poor (B) 4-stage judgment criterion (judgment): (Scoring Average score) ◎: Average score is more than 4·5-25-201002357 〇·· The average score is 3.5 or more, less than 4.5 △: The average score is 2.5 or more, and the score is less than 3.5 X: The average score is less than 2.5 Table 6 9 Inventions 10 Comparative Products 13 Comparative Products 14 Hydrogenated phospholipids (PC: 32% 'PE: 32%) 10 10 Hydrogenated phospholipids (PC: 80% 'PE: 5%) - - - - Palmitic acid dextrin _ 10 candelilla wax • _ 10 triisostearate 89 84 89 89 dimethyl polysoda (10mm2/s) 1 1 1 1 Νε laurel lysine (Note 2) _ 5 _ _ Good application ◎(4.5) ◎(4.8) X(2) △(3) Tightening after use ◎(4.5) ©(4.8) X(2) 0(3.5) Moisturizing effect ◎(4.5) ©(4.8) X(2) △(3) Inventions 9,10 It shows the effect of "good smear", "tightness after use", and "moisturizing effect". In particular, the indole 1 is a powdery lauryl lysine containing an amino acid derivative, and exhibits a more excellent effect in any of the items. On the other hand, regarding the comparison products 13 3 and 14 which are gelled with palmitic dextrin' or candelilla wax, it is felt that the oily agent is sticky, and the skin is not suitable for the skin, so it is not sufficient. Any one of "smear good", "tightening after use", "moisturizing effect". .26-201002357 [(Industry) Ono International License 2] Example 3: Solid massage mass The solid massage mass of the following formulation was prepared by the following method. (Ingredients) (%) 1 Hydrogenated egg yolk phospholipid (Note 3) 25.0 2_Dimethyl polyoxane (Note 4) 12.0 3 . Vitamin E 0.3 4. Ethyl oleate i. i 5. 3-2- Ethylhexanoate 32.〇6.Nylon powder 7.0 7 · Ν ε -lauryl lysine (Note 2) 8.0 8 ·Residual amount of flowing paraffin 9.Antioxidant 0.1 I 〇_Preservative amount II · Proper amount of flavor (Note 3) Phospholipid composition PC: 28%, ΡΕ : 28% (Note 4) Dynamic viscosity 20mm2/s (25°C) (Manufacturing method) A : Heating component (1) ~ (11) into 80° C. B: Mix and stir with a dispersing mixer. C: 塡B (80 ° C) was placed in a container and cooled to room temperature to obtain a solid material. -27- 201002357 The solid massage material of Example 3 shows that Λ ^ eight-needle lotus is 1 2 0 g at 3 5 ° C. 'Hands are taken, good spread, no sticky feeling, sn skin _ Sex, preservation stability, moisturizing effect is excellent. Example 4: Solid hand cream The solid hand cream of the following formulation was prepared by the following method. (ingredient) (%) 1. Hydrogenated soybean phospholipid (Note 5) 5.0 2 . Behenyl alcohol 1 _ 0 3. Methylphenyl polyoxyalkylene (Note 6) 20.0 4. Linoleic acid tocopherol 1.0 5. Flowing paraffin 30.0 6. Residual amount of macadamia oil 7. Ν ε - lauryl lysine (Note 2) 10-0 8 · Antioxidant 〇.1 9 . Preservative amount 1 0 · Proper amount of spices (Note 5) Phospholipid composition PC: 32%, ΡΕ: 32% (Note 6) Dynamic viscosity 100mm2/s (25°C) (Manufacturing method) A · Heat the ingredients (1) to (1 〇) to 80 °C. B: Mix A with a dispersing mixer. C: 塡B (80 °C) in a container, cooled to room temperature, to obtain a solid protection -28-201002357 hand cream. The solid hand cream of Example 4 showed a needle load of 60 g at 35 t, and the fingers were taken, applied well, and had no sticky feeling, skin suitability, preservation stability, and moisturizing effect. Example 5: Eye cream (solid form) The following formula eye cream was prepared by the following method. (ingredient) (%) 1. Hydrogenated soybean phospholipid (Note 7) 10.0 2. Hydrogenated egg yolk lysate disc lipid 0.5 3. Acetate vitamin E 0.05 4. Ethyl oleate 1.0 5.2-hexadecyl ethylhexanoate 60.0 6 . Hydroxy stearic acid cholesterol 1.5 7 . Dimethyl polyoxyalkylene (Note 8) 0.5 8 . Octamethylcyclotetraoxane (Note 9) 5.0 9. Residual amount of glycerin fatty acid ester 1〇·Ν ε - Laurel lysine (Note 2) 10.0 1 1 . Antioxidant 0.1 1 2 . Preservative amount 1 3 . Proper amount of fragrance (Note 7) Phospholipid composition PC : 3 1 %, Ρ Ε : 4 0 % (Note 8 Dynamic viscosity 20mm2/S (25°C) -29- 201002357 (Note 9) Dynamic viscosity 40mm2/S (25t:) (Manufacturing method) A: Heat the components (1) to (1 3) to 80 °C. B: Mix A with a dispersing mixer. C: 塡B (80 ° C) in a container, cooled to room temperature, to obtain eye cream. The eye cream of Example 5 showed a needle load of 80 g at 35 ° C, and the fingers were taken, applied well, free from stickiness, skin suitability, preservation stability, and moisturizing effect. Example 6: Body cream (solid form) The body cream of the following formulation was prepared by the following method. (Ingredient) (%) 1. Hydrogenated soybean phospholipid (Note 1 〇) 8.0 2 . Inulin fatty acid ester (Note 1 1) 1.5 3. Cholesterol 0.5 4. Residual amount of flowing paraffin 5. Vitamin E 1.0 6. II Methyl polyoxyalkylene (Note 12) 12.0 7 . α-olefin oligo 2.0 8 . phthalic anhydride 0.2 9 . Ν ε - lauryl lysine (Note 2) 25.0 1 0 . Antioxidant 0.1 -30- 201002357 1 1 . Preservative dosage 12. Proper amount of fragrance (Note 10) Phospholipid composition PC : 28%, PE : 28% (Note 1 1 ) Rheopearl ISK (manufactured by Chiba Powder Co., Ltd.) (Note 12) Dynamic viscosity 20mm2/s ( 25 ° C) (method) A: The heating components (1) ~ (12) into 80 ° C. B: Mix A with a dispersing mixer. C: 塡B (80 ° C) was placed in a container and cooled to room temperature to obtain a solid body cream. The body cream of Example 6 showed a needle load of 65 g at 35 ° C, and the fingers were taken, applied well, not sticky, skin applicability, preservation stability, and moisturizing effect were excellent. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing the friction stress of the present invention 9 and the comparative product 15 in the second embodiment. Fig. 2 is a scanning electron microscope photograph of the present invention 9. -31 -